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Environmental Control Agency, or the Hazardous Waste representative at the nearest EPA Regional Office for guidance. Container Disposal: DO NOT reuse empty container. Triple rinse (or equivalent) and offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or incineration, or if allowed by state and local authorities, by burning. If burned, stay out of smoke.

WARRANTY AND LIMITATION OF DAMAGES Seller warrants that this material conforms to its chemical description and is reasonably fit for the purposes stated. on the label when used in accordance with directions under normal conditions of use and Buyer assumes the risk of any use contrary to such directions. SELLER MAKES NO OTHER EXPRESS OR IMPLIED WARRANTY, INCLUDING ANY OTHER EXPRESS OR IMPLIED WARRANTY OF FrINESS OR OF MERCHANTABILITY, AND NO AGENT OF SELLER IS AUTHORIZED TO DO SO. In no event shall Seller's liability for any breach of warranty exceed the purchase price of the material as to whIch a claim is made.

50 s 3 If -.2() I

UNITED STATES ENVIRONMENTAL PROTEcnON AGENCY

WASHINGTON, D.C. 20460

Ralph P. Burton ISK BIOTECH CORP. S966 Heisley Road P.O. Box 800 Mentor,OH 44061

JAN 6 1994

OFFICEOf' PREVENTION. PESTICIIES AND

TOXIC Sl.8STANCES

Subject: Label Amendment Submission of 00107/93 in Response to PR Notice 93-7 EPA Reg. No. 50534-201 BRAVO 825

Dear Registrant:

The labeling cited above and submitted in connection with registration under the Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA), as amended, is accepted. A copy of your proposed labeling stamped -ACCEPTED WITH COMMENTS- is enclosed.

WHAT THIS ACCEPTANCE MEANS:

Based on your certification, the Agency has accepted the labeling changes that are necessary to comply with the Worker Protection Standard (WPS) labeling requirements of 40 CFR part 156, subpart K, described in PR Notices 93-7 and 93-11. Any other labeling

. changes submitted in connection with this amendment application but not directly related to compliance with the WPS have not been reviewed or accepted by the Agency. If you wish to make such changes, you must submit a separate amendment application proposing them. If your product is currently suspended, the acceptance of this labeling amendment does not affect the suspension in any way.

WHAT YOU NEED TO DO NEXT:

Send to EPA one (I) copy of the fmal printed labeling:

• BEFORE selling or distributing any product bearing the final printed labeling AND • WITHIN one year from date of this acceptance.

Page 2

Submit the final printed labeling via the u.s. Postal Service to:

Document Processing Desk (FIN-LABEL) Office of Pesticide Programs (750SC) U.s. Environmental Protection Agency 401 M Street, SW Washington, D.C. 2046().()()()1

Hand or courier deliveries of final printed labeling may be made to:

Attachment

Document Processing Desk (FIN-LABEL) Office of Pesticide Programs Room 266A, Crystal Mall 2 1921 Jefferson Davis Highway Arlington, V A 22202

Sincerely,

o .. Ji I eputy Chief

R 'stration Division (750SW)

\

rb

Net Contents:

Bravo®825

Agricultural Fungicide

(82.S~ Water Dispersible <San ules)

Active Ingredient: Chlorothalonil (tetrachloroisophthalonitrile) 82.5~

Inert Incredlents: 17.5~

Total: 100.0~

Keep Git of Reach of OIlldren

DANGIlR - PElIGRO

3 1

Si listed no entiende la etiqlleta, bllsqlle a algllien para qlle Ie la expliqlle a IIsud in detalle. (If YOII do not IInderstand the label, find someone to explain it to YOII in detail.)

See side pan el for addition al precaution ar y statemen ts.

Preeallelon .1 (1s ••• 18. Si listed R 6 lee in gles, ft elise este "radde's h 8sta que 18 eti'ltleta h aye side explieade 8mplialfteft teo

ISK Biotech Corporation 5966 Heisley Road P.O. Box 8000 Mentor, Ohio 44061-8000

EPAReg. No. 50534-201 EPA Est. No. 50534-TX-I

Bravo is a Registered Trademark of 15K Biotech Corp.

AOCiJ"'iW ..... COIIIIENTI "'iPALettu~

v __ J!N F-2.. ~ d S' r '~I.I."" r" MI "II ..... PIP" ,... .. : :rr;' .. 6eq!'

1> 53 Lf - OJ

Ib

Bravo®825

A Broad Spectrum Agrlculturlll Fungicide

Read entire /abel carefully and use onty.. directed.

PRECAUTIONARY STATEMENTS Hazards to Humans and Domestic Animals

DANGER • PELIGRO

ConosIve. C8I as i'.'8IsIlIe 11)'8 dllhllglL HM.'" i ,L , 1 Avoid breIIhing cUt or spay mist. HInfU • absootJed IinJuItI &Icin. May be a pea iIiIIf lkilsa iiiItaN. ProIoi IgIId orfrequanlly lap i 11ki1 c:onIact may caa aIiIIIgic raadioI is i'i1OlllEl h:IvibIIs.

DO NOT ge?i'iayasorondotlilg. VteargsDI'ss:,slS.· i1 eraataty.1I I I, fIInII alaP'll IhIIt; iefIg 1181 lis, 11111 gieYe8: Avoid pckli..,ad w act w/tIlidn. W&8I, tiel e lI.iI)'''' Ie IIfIIlIlf 1'1_' ala, hili. II: RallIS .. BBAI8IIliI ated elalii.IIIII"aah lists,. iai8B • DO NOTtaIcIII ianaly.

Lf t I b

Note to User: This prodUct may produce mild bronchial irritation and te~nliY irritation of the skin characterized by redness or rash on exposed skin areas. Affected persons should consult a physician.

90 NOT IIPIIPy .1119111'8.I:I1II iA 111M 81Mh18F .. te 111.11111)', SF "' ........ ,iC:, 81,,918 _11181'8 8F allier perseRS. ; .. , area bei"a trellteel ",uetM tJIIeated 8)" 1:IAI',8teeled ,. .... .

FIRST AID:

If swaliowed: Call a physician or Poison ContIOi Cent8r. Drink 1 or 2 gPasses of water and induce vomiting by touching back of throat with finger. DO NOT induce vomiting or give anything by rnouIh to an unconscious person.

If In eyes: immediately flUsh eyes with plenty of water and continue for 15 mI"utes. Seek medical attention for eyes immediately.

If inhaled: Remove victim to fresh air. If not breathing give artif'lCial respiration, preferably mouth-to-mouth. Get medical attention.

If oro skin: Wash with plenty of soap and water. Get medical attention.

Note to physician: Persons having temporary irritation may respond to treatment with antihistamines or steroid creams and/or systemic steroids.

ENVIRONMENTAL HAZARDS This product is toxic to fish, aquatic: Inverteblates, and marinafestuarlne organisms. Runoff from treated areas may be hazardous to aquatic organisms i'il'llighbol'lng 8I8IlS. DO NOT apply dinIcIIy to water, to areas where SUlface water Is Pllllint or to iilBrtldll ...... below the mean high water III8/t(. DO NOT contaminate water when disposing of equipment Wlllhwatera. DO NOT apply when weather COl iditIoiiS favor drift from treated areas. Apply only to aiUS specified on label.

DIRECTIONS FOR USE It is a violation of Federal law to use this product in a manner inconsistent with its labeling.

A,ric"II"rai Use Req"ire .. elll. U.e this product only in accordance with its labeling and with the Worker Protection Standard, 40 CFR part 170. Refer to sllpplemental labeling under 'Agricultural Use Reollirements H in the Directions -for Use .ection for information about this standard.

See enclosed folder for Directions for Use.

STORAGE AND DISPO§AL DO NOT contaminate water, food or feed by storage or disposal. Open dumping is prohi bited. Storage: Store in a dry place.

Pesticide Disposal: Completely empty bag into application equipment. Then dispose of empty bag in a sanitary landfill, or by incineration. or if allowed by state and local authorities. by burning. If burned. stay out of smoke. Container Disposal: Triple rinse (or equivalent). Then offer for recycling or reconditioning. or puncture and dispose of in a sanitary landfill. or incineration. or, if allowed by state and local authorities. by burning. If burned, stay out of smoke.

WARRANTY AND LIMITATION OF DA.MA~ Seller warrants that this material conforms to its chemical description and is reasonably fit for the purposes stated on the label when used in accordance with directions under normal conditions of use and Buyer assumes the risk of any use contrary to such directions. SELLER MAKES NO OTHER EXPRESS OR IMPLIED WARRANTY, INCLUDING ANY OTHER EXPRESS OR IMPLIED WARRANTY OF fITNESS OR OF MERCHANT.J.BILITY, AND NO AGENT OF SELLER IS AUTHORIZED TO DO SO. In no event shall Seller's liability for any breach of warranty exceed the purchase price of the material as to which a claim is made.

Buyer and all users are responsible for all loss or damage from use or handling which results from conditions beyond the control of this company, including, but not limited to, incompatibility with products other than those set forth in the Directions for Use, weather conditions, moisture conditions or other environmental conditions outside of the ranges that are generally recognized as being conducive to good agricultural practice.

/b

Bravo® 825 Agricultural Fungicide (82.5% Water Dispersible Or an u les) Ac:the IDlredleat: Chlorothalonil (tetrachloroilophthaloaitrile) Inert l_credleDts: Total:

Kee p OIt of Reach of a.lldreD

DANGER - PELIGRO

(I NSERT F<I.DER)

Si usted no entiende 10 etiqueta, busque a alguien para que se la explique a usted in detalle. (If you do not understand the label. find someone to explain it to you in detail.)

See side panel for additional precautionary statements. Preealleioll .1 I:1s ••• le: Si Hsted He lee illiles. He Hse esle ,.eEtHels hast. qtle )8 eti'lliefa hay. side eJtplieade alllpliamente.

ISK Biotech Corporation 5966 Heisley Road P.O. Box 8000 Mentor, Ohio 44061-8000

EPAReg. No. 50534-201 EPAEst. No. 35982-TX-l

3298-4005-8046-9207

It:,

BraYo® 825 A Broad Spectrum Agricultural Fungicide Read entire label carefuly and use only as directed.

PRECAUTIONARY STATEMENTS

Hazard. to Hu .... n. ud Dom .. tlc Anllllll" DANGER

1 1- I h

Corrosive. Causes Irreversible eye damage. Hannful • Inhaled. Avoid breathing dust or spray nist. Hannlull absorbed through skin. May be a potential skin sensitizer. Prolonged or frequenlly repeated skin contact may cause alerglc reactions In some individuals.

DO NOT get In eyes or on cioIhIng. WeeF gagglee, _a ""Ialll eF eefety .nua, lB .. alllM 1IhIrt, lellg paAlI. 8M Ile'/s8. Avoid prolonged contact with skin. t/w,_ tttereHght)'1J.JIttt 1"111 aM rate, after haNlIin •• R8_1e 88MaltliM&81111elhilli MIl 'llIIIM 1111181'8 Muel. DO NOT take inlemaly.

Note to Ueer: This product may produce mild bronchial irritation and temporary Irritation of the skin characterized by redness or rash on exposed skin areas. Affected persons should consult a physician.

gO ~Jg:r a",,1y thie pl8dttet "suah. MaI'l,'" aa Ie diraol)" 8' _iii" drift. eupale \jU8 ..... IF ether 1181'98119. Tile aria lIeing tNatl1i ...... lie ' .. eatlllily Illlllretaetellll8F88l1B.

FIRST AID:

If swallowed: Call a physician or Poison Control Canter. Drink 1 or 2 glasses of water and IndUCtt vomHing by touching back of throat with finger. DO NOT induce vomiting or give anything by mouth to an unconscious person.

If In eyes: Immediately flush eyes with plenty of water and continue for 15 minutes, Seek medical attention for eyes immediately.

H Inhaled: Remove victim to fresh air. " not breathing give artificial respiration, preferably mouth-to-mouth. Get medical attention.

If on skin: Wash with plenty 01 soap and water. Get medical attention.

Note to physician: Persons having temporary irritation may respond to treatment with antihistamines or steroid creams andlor systemic steroids.

Personal Protective Eqllipment (PPE):

Applicators and other handlers mllst wear long·sluved sh irt an d Ion g pan ts, waterproof gloves, shoes plus soeles, protective eyewear, and a dust/mist filter in g respirator (MSHAINUBHapprolial number prefix TC2JC).

Discard cloth in g an doth er absorben t materials th at h aile bun dren ch ed or h eav ily con tam in ated with th is product's con cen trau. Do not reuse th em. Follow manufacturer's instructionsfor cleaning/maintaining PPE. If nosuch instructions for wash abies. use detu8en t an d h ot water. Keep an d wash PPE separately from oth u laundry.

Wh en han dlers use closed systems. en closed cabs, or aircraft in a man n er that meets th e requirem en IS listed in th e Worker Protection Standard (WPS) for agricultural pesticides {40 CFR 170.240 (d) (4·6)J. th e h an diu PPE requiremen IS may be reduced or modified as specified;~ th e WPS.

Unr Sa/.', R.co".". ... da'io .. '

Users should:

• Wash hands before eati .. ,. drillkilll. chewilll ,um. usill, tobacco or usillg tht toiltt.

• Removt clothilll immediately If ptsticidt Ittl illsidt. Thtll wash thoroulhly alld put 011 cltan clothi .. ll.

ENVIRONMENTAL HAZARDS this product Is toxic to flah. aquatic Invertebnllas. and marlnefestuallne organisms. Runoff from treated 8reas may be hazardous to aquatic organisms In neighboring at88S. DO NOT apply diracIIy to water. to areas whent surface water Is present or to Inteltldal .... below the mean high water mark DO NOT contaminate water when disposing of equipment waahwatenl. DO NOT apply when weather conditions favor drift from treated 8reas. Apply only to areas specified on label.

DIRECTIONS FOR USE It Is a violation of Federal law to use this product in a mamer inconsistent with Its labeling •

. ·Do not apply this product in a way that will cOlltact workers or other persons. tithtr dirtctly or through drift. Only protected ha,.dlers may be ill the area during application. For any requirtmtnts sptcific to your Statt or Tribt. consult tht age,.cy rtsponsible for puticidt ugulation.

AGRICULTURAL USE REQUIREMENTS

USt this product only in accordanct with its labtling and with tht Worktr Protection Standard. 40 CFR part 170. This Standard contains requirtmtnts for the protection of agricllltliral workers on farms. forests. nurstrits. and grttnhousts. and handltrs of agricultural puticidts. It contains rtquiremtnts for traininl. dtcontamination. notification. and tmtrgency assistanct. It also contains sptcific instrllctions and txetptions ptrtaining to tht stattments on this labtl about ptrsonal prottctivt tquipment (PPE) and rtstricted-e,.try inttrval. Tht requiremtnts in this box only apply to UStS of this product that art covtred by tht Worker Protection Standard.

Do not tnttr or allow worktr tntry into treattd artas during tht rtstricttd tntry inttrval (REI) of 48 hours.

PPE rtquirtd for tarly entry to treated areas that is ptrmitttd undtr thl! Worlctr Protection Standard and that involves contact with anything that has bttn treated. such as plants. soil. or water. is: coveralls. waterproof Ilovts. shoes plus socks. and Drottctivt tvtwear.

BRAVO 82515 an excellent fungicide when used according to label directions for control of a broad spectrum of plant diseases.

BRAVO 825 can be used effectively in dHute or concentrate spl&YS. Thorough. uniform coverage Is essential for disease control.

DO NOT use on greenhouse-grown crops.

DO NOT combine BRAVO 825 in the spray tank with pesticides. surfactants or fertilizers, unless your prior use has shown the combination physically compatible, effective and noninjurious under your conditions of

"

1 use. DO NOT combine BRAVO 825 wHh Dipel4L, Foil, Triton AG-98, Triton 8-1956, Latron B-1956 or Latron AG-98 as phytotoxicity may rasuIt from the combination when applied to some crops on this label.

Oipel is a registered trademar1t of Abbott Laboratories. Foil is a registered trademar1t of Ecogan Corporation. Triton, Triton 8-1956, Latron 8-1956 and Latron AG-98 are trademarks of Rohm and Haas Company.

Dosage rates on this IabeIlndlcata pounds of BRAVO 825 per acre, unless othetwise stated. Under conditions favoring dill .... development the high rate epedfIed and ehoItest appIicItion Intervallhould be used.

The required .mount of BRAVO 825 shoUld be added slowly into the spray tank during filing. With concentrate sprays, pnt-mix the raquIred amount of BRAVO 825 In a clean container and add to the spray tank as It is being filed. Keep agitator running when filling spray tank and during spray operations.

REENTRY Ne ••• e " .... I*H&T ..... , IN ... III .... te .,. .. "" ..... lHe'w .. , 24 MIII'8 ehplllieallell IIftlns PRtteetiYe elathiFtg is '."'_

Be_tl98 88M ... _MaINlY Mqu:re M8f8 reMttetNe Ment.,' ifttetWlla fe, 'IeASue e.e". tleatell '!lith this "reduet, esnetilt yeti. State 9a,. .. ...., ... ef 'Jgfieulluf8 fe, 'wiler iftl8ftNltiSR.

'IJFiHen SF etal ,,).fNAas "' .... be given te us ..... whe ape 81,s.ed ta be it a 'faated area SF if. an area absl:Jt Ie be 'Mated 'JJith thie "fa fltt ... 1wtJhe .. aPal wa ..... lIS .... p. 'R . ..-18Iftiftga ehaII be .,... WI a IMpas eustslNlFil)t ttAder9tsslt tty ........ g .. wa.n,.. MuM .. ..,., .. If theM II realeR te "elteve that wfilen 'A18FRiRgs eaARat be lfRdeP8tasd By '{MIlle .... OPal aM 1lJJfItta" WJ8ff'1iFtg& fftH81IRelyde the fallefiliAI iAlsfmatisA: ·9,,~jQER. "rea treate!! WIitII BRAVO 825 ell (!late sf IIfIlIl'ealiell). 00 NeT elltef '["elll EIIlIlFellfiate Ilf8teetilo'e eletlliflg fef 24 I'oelll9. III ee88 sf aeeldeAtal el"e8l11'8, ~ ..... ellllBeed .Fea witll ,leAl)' af water sAd get ",edieal atteAtieA. re, fyftMr iAfeFfMtisA aee 'Pre.tltisna.,. 8tate ... eAte· SA the label!.

Applicetlon and Calibration Techniques for Sprinkler I"igatlon

Apply this product only through center pivot, motorized lateral move, traveling gun, solid set or portable (wheel move. side roll, end tow, or hand move) Irrigation system(s). DO NOT apply this product through any other type of irrigation system.

Crop injury, lack of effectiveness, or Hlegal pesticide residues in the crop can result from non­unifonn distribution of treated water.

If you have questions about calibntion, you should contact State Extension 8.,rvice specialists. equipment manufacturers or other experts.

DO NOT apply this product through Irrigation systems connected to a public water system. 'Public water system' means a system for the provision to the public of piped water for human consumption if such system has at least 15 seIVice COl1i'18clions or regularly serves an average of at least 25 individuals c!aIIy at least 60 days per year.

Controls for both irrigation water and peslickle injection systems must be functionally Interfocked, 10 as to automa~:cally terminate pesticide Injection when the irrigation water pump motor stops. A person knowledgeable of the inigation system and responsible for ItS operation aha. be present 80 as to discontinue pesticide Injection and make necessary adjustments, should the need arlle.

The irrigation water pipeline must be fitted with a functional, automatic, quick-closing check valve to prevent the flow of treated irrigation water back toward the water source. ThE' pipeline must allO be fitted with a vacuum relief valve and low J)IaSUI'8 drain, located between the irrigation water pump and the check valve, to prevent back-siphoning of treated irrigation water into the water source.

,(,

lot (b

Alw.y. Inject BRAVO 125 Into Irrlg.tlon w.ter .fter It dl.cMrge. from the Irrigation pump .nd .fter It p..... through the check v.lve. Never ilqect pe.tlclde. Into the Intake line on .... auction .Ide of the pump. Pesticide injection equipment must be fiIted with a functional, normally ClOSed, soIenoid-operated valve located on the intake side of the injection pump. Interlock this valve to the power system, &0 as to pnlVent

fluid from being withdrawn from the chemical supply tank when the Irrigation system is either automatically or manudy turned 0/1. The pesticide injection pipeline must conIaIn a functional, automatic, quk:k·closillg check valve to prevent the flow of fluid back toward the Injection pump. The Irrigation line or water pump must include a functional prassure switch which wil stop the water pump motor when the water pressure decreases to the point where pesticide distribution is advar&eIy affected.

Spray mixture In the chemical supply tank must be agitated at all times, othet wise settling and uneven application may occur. DO NOT apply when wind speed f1IYOIS drift beyond the area IIUndad for treatment.

Posting of areas to be chemigatecI is required when 1) any part of a treated area is within 300 feet of sensitive areas such as residential areas, labor C8fI1I$, busin B S ses, day care centers, hospitals, in-patient clinics, nursing homes or any public areas such as schools, parks, playgrounds, or other public facilities not including public roads, or 2) when the chemigated erea is open to the public.

Posting must conform to the following requiraments. Treated areas shaI be posted with signs at all usual points of entry and along likely routes of appItI8Ch from the listed sensiIive areas. When there are no usual points of entry, signs must be posted in the corners of the treated areas and In any other location affording maximUm visibility to sensitive areas. The printed side of the sign should face away from the treated area towards the sensitive area. The signs shal be printed in English. Signs must be posted prior to application and must remain posted until foliage has dried and soli SUIface water has disappeared. Signs may remain in place indefinitely as long as they are composed of materials to prevent deterioration and maintain legibility for the duration of the posting period.

AI words shall consist of leiters at least 2·112 Inches tall, and alllellers and the symbol shaI be a color which sharply contrasts with their immediate background. At the top of the sig!\ shall be the words KEEP OUT, followed by an octagonal stop sign symbol at least 8 inches in diameter containing the word STOP. Below the symbol shaM be the wools PESTICIDES IN IRRIGATION WATER.

This sign is in addition to any sign posted to comply with the Worker Protection Standard.

BRAVO 825 may be used through 1V«", basic types of sprinkler iMgation systems as o:J1lineci in Sections A and B below. Determine which type of system Is in place, then refer to the appropriate directions provided for each type.

Fie Id .nd Row Crop.:

Apply BRAVO 825 in sufficient water to obtain adequate coverage of foliage. Gallonage to be used will vary with crop and amount of plant growth. Spray volume usually wII range from 20 to 150 gallons per acre (200 to 1400 liters per hectare) torcfilule sprays and 5to 10 gallons per acre (SO to 100 liters per hectare) flir concentrate ground sprays and aircraft applications. EIoIh ground and ailcraft methods of appIict.tion are recommended unless specific directions are civen for a crop. Application through sprinkler irrigation systems is no! recommended unless specific directions are given for a crop. See application and calibration instructions below.

- ------------- -------------------------

II

A. Center Pivot, Motorized Lateral Move and Travellnc Gun Irrigation Equipment For injection of pesticides. these continuously moving systems must use a positive displacement injection pump. of either diaphragm or piston type. constructed of materials that are compatible with pesticides and capable of being filled with a system interlock and capable of injection at pressures approximately 2-3 times those encountered within the irrigation ",ater line. Venturi applicator units cannot be used on these systems. Thoroughly mix recommended amount of BRAVO 825 for acreage to be covered into same amount of water used during calibration and inject into system continuously for one revolution or run. Mixture in the chemical supply tank must be continuously agitated during the injection run. Shut off injection equipment after one revolution or run. but continue to operate irrigation system until BRAVO 825 has been cleared from last sprinkler head.

B. Solid Set and Portable (Wheel Move, Side Roll, End Tow, or Hand Move) Irrigation Equipment With stationary systems. an effectively designed in-line venturi applicator unit is preferred which is constructed of materials that are compatible with pesticides; however. a positive-displacement pump can also be used.

1-

Determine acreage covered by sprinkler. Fill tank of injection equipment with water and adjust flow to use contents over a thiny to fony-five minute period. Mix desired amount of BRAVO 825 for acreage to be covered with water so that the total mixture of BRAVO 825 plus water in the injection tank is equal to the quantity of water used during calibration. and operate entire system at normal pressures recommended by the manufacturer of injection equipment used. for amount of time established during calibration. Agitation is recommended. BRAVO 825 can be injected at the beginning or end of the irrigation cycle or as a separate application. Stop injection equipment after treatment is completed and continue to operate irrigation system until BRAVO 825 has been cleared from last sprinkler head.

1&

.ar.yO 125 In •• rt "21"3 12.3' PM ,.V- 1 • • • • • ! • ·

- - _ .. - -- - - _ .. - ...... -~, """ • .25 .. 2.7. .... ~-- .. -.... -.- - -- tA ..... ....~ -- u. ----_. __ .... -. - -_ .. _ . .....,_ .. _ .. - -. ~- • II!

'''''- .... _001lOT __ .... _"1MVII105 -. ., .. ,._ ..... _ ..... _ooIlOT __ ' - -- .... 2.1. ...... .,.._001lOT .... __ • ...., __ - --- -_ .. - -• 1*"111). -- _ .... - -_tooY, A ..... _ '.25"". .... ~--.. -.... -.-- ,...... -.,....,-. _ ..... ___ .. _.' ... 0.,_· -- ---- _ror • ...,._ ... _", ...... " "'"

.,. ~"'"

_oollOT __ I ___ .oollOT -.... -.....: ............ _or 1IId1nllld_1IIIts -.. - -' ~. _ ........ 1.4. .... ~-- .. ----- ,.,...., .. 7.1. .... .

-'- .,....,- ---... ~-.---. (MIa 1 t..., -II1II- _._-...... _--- --.... , , b U .... , ........... ..., .. -, -. __ oollOT __ '.,.,,_ -- _ ..... loot .... 1.1 .. 1.4. .... .. -. AlOe_ u. ror _____ .... " ...- _ .... -a.-_. - ..... '-.... 1 -_ ... ._--- --- -• III, ......... 7.10 ___ •• ...., .. -- --- ...... .. -- .... ~ __ .. ___ SM_ -- --._, 1.4"",. - ____ .. _.' .. 10.,_ • ~ U ..... -"""- •• ...., ....... CIIMIlIJIU.VOI25..., ....... - ---- ,.25. ....~ _____ s.-_ .......... - ....

-~ -._, U .. U. UIIG. ... IA ....... , .. ,.,...., ............ -- - 1.'.,. __ .,., ___ - --~,- CIIt - .... ~ .. -.... ,~-- .. - ---.. ... .. 2." __ DDIIOT __ '.,.._ -, ,-...., ....., --..,.------ ..... -.s. ___ ... _. -,.. .. " " , - u. -'Dir-'

(00,_ 1.4 ........ ,..., __ '25_,. ___ ••

.... - ..... _ .. _------_ ...... 'W' ...... ------ ,. b ... • ... " ...... .... ~--.. ------- - ... .. c.-. ... _ .. d , ..........

... - A ... 4 .. '.,_ •• _ .. ___ ___ •• .4 ...... ,._001lOT __ .4.,."_001lOT_ .. __ .. • _001lOT __ ....... ~ __ OO.,., ......... CIII .................

-I*Y-,

--.. -. -+

'-

---_""',

.'21,t3 12.40 '" ~te 2

-----.. ~ . ~ --_ ... -----(--, _ ........ w. -.....

----. ---(..,-_ .. PM _ ...... ....... -_ ......

.... u.

Utl!.7,

UtiUIt

1 ........

....

I I I .

l1li.-_._-_ ...... _115_ ,' .................. ----_ ... _ .. --.--.-.-.. - .. -_ .- _.- ..... -. - ---_ ,._u. un .... ~ 10 .... 7.10 .... 7 .... fer •• .. _ .. (...,...,-_. _ .. ___ ......... _ • .25

..... IIIMVO as .. acrw. It i J l00.,T...., _7 ...... _ l1li10 __ • ___ ............ _ ..... ___ ... _ .. 7 •

..... - ....... _-_l1li ..

..... 7.,_ .. _-_-.

.... -.001llT __ 7 ...... _.-. _ .. __ ..... 10_-.--_ ........ -. ..... ---"--.', 1._ ................. .. .,--------'1 d, 100 lin.,. a..IICt; .. .., ....... .,.. ..-...-.-_10--.-__ - .. .._ ......... _.-_ .. _ .. ___ •• 7.10., _001llT ___ '_ .. _._ ........ _001llT ... ___ ._

_ .. __ 10-_._ ..... -_ ........ -. ..... -_ .. _ ... _ .... .,-----.... ... _. : IOOIllT __ 7 ...... _OOIllT __ ...... __ .... --_.-

- -- .,'_wI ..... 1 .•• DO 1IlT __ ..... 10 _ -- .., .......... __ ... _115.., .. ___ -.IIIIU ... _10 Il10.,14 .. .. ..... -.. _-_ .. -_ ........ _ ... -----.. _--_ ... .-- ~- G.7. ,." .. _---latt_ -_ .... _ ...... -_ ...... -- _ .. 7.10., __ -_ .. _-

o.'.'.n . .--..... ---_ ..... _-- ..... _ ........ -_ .. _ .. 7 ... .,_l1li ...... ---_ ... -_"_ .. _115 ........ _00.,'_ .. 7 ..... _ _115.., .. ___ -_ ... _---____ DO 1IlT _ ----------'- - _10 __ • __ - ........... - _ .. _ .. -.. -... -

.-0, - ___ 10 ... _. - "--• ____ 115 ...

~-~ ---.--........ - __ -_.MJYE:DI --- 3_ ... _001llT_" ~-...,.

_001llT __ ..,._ --... ..... ..... 1.

•.•• t.n ----_ .... , 11I(SQ ___ "",,,u ..... _._ ...... -_ ...... -UIOU.

___ -_l1li .. ......... ........ CII'~ .. _., ....... _ ...... _(II!

IBr8VO 825 Inaert , ./26/93 12.41 PM ~g. 2 , , ,

-..

__ I~U. ... WNW. --_ ...... ----I~_~ ---. c-,ora .... --. --...

O .•• u.

, , ,

- .... ~ ,.,.'0.20 ___ ... _ ... __ -_._----_ ...... _._-........ _--(¥I).I ______ ._IOII

• ___ 11_.1010 .. ,,_ ,.,. __ ._--_. ..... ___ ... _"' __ u.. .. --_. __ .-,.--• ___ .IAAVOI25 .... __ _____ I0Il_

____ 11011:1101101_""'. '_ ... _1101101 __ ' __ _0011lJT .... _ .... __ _ _.-... ...----..... _-__ .... , .... n_._ ... _ .. _ _' ...... _125 ...... __ _ ................ Cllhlil I _ ,_UIoU •• IAAVO 125"", __ ~Tt_ ... __ ..... __ • _ .... _ ... 112.' ............... _ _' ..... . -...-_-_ ....... _-­...... _ .. __ ., ... _ • .... Tt ... ___ E.I._._ .. ca. ... ,.,. __ ._----......... raII ..................... .. _ ...... _----­.......... lMvom.., .. ~ .... ...,_ .. EPA. .. ,... ....... _dllllCIfIIIIf ... -_ .... -"'---­.. -. CIIICII"~ w, ..... .-cIIc -_ .. _""'._­_125. 110 IIIT._ CIIfftII-couorr· ... _ __ , , _125 .... __ ---_ ... _--_".s. _____ . . _ .. _---­MilDs 'CAe.,.

cp

. ,

Tree Ind Orchard Crops AWr &RAllO 125 illIIIIiciInI __ ... _ _ ....... _ ............. 01 ... canopy. AppIi' __ ... .-~Is.....- .. lIriIIac ~rc." ... ground' Ttt r fm II genetaIy 1IivI __ 0I ...... _· • ....,..-. will or- 'I " .. ~ Is ""'_. &RAllO 125..., III ............. __ II _ 20 goIoos .... ..... _ ... _ . .." ......... -1mIinO- .... Itii .. ~~ ... _ .... 01 &RAllO 125 _..., 111_. DO IIOT __ .._In __ .lloo-.g ."ay_

IrI ilCOfill dId. pions" spray Pl'lel'll: ---. -TIII-" .... --------

201 ilia, • "(1l1li _

201 ., • 4CIO(1IIII_ -...-100

100

-+-

.Bravo 125 In.art , , "26/3 12.42 PH ~9. 2 , , , , ,

- l .. _ 2.1 .. o.t .. "" .... _ .. --_ ........... -. -. -- 11_ un. --_ .... _-_.-- I-, -----.... -_ ... -.,. ........... __ ... __ .""" ... "0IIId -. .""--_ .......... --_ ... - ___ .. .....,125 .. - .......... ...,00 _ . ..,.,.,.,._ .......... _-__ ~I-"'_--.

---_ .... ,,-SpII .. -.... -Ii ... rallIIOsSIIn 2 .... o.t. UIIU .. U .... ICIt .. t.-...... 20 ... .., - 5.0" 1.2,,, 2 .•• U .. ,.IaI ........................... .... 1'-1- _C""-.... ...,_..., ..... __ " I-, .......... _c..-.. .......... IIO,..III. _._--" ......... CMtryllll .... u. o.t. ................................... """. U .. us ..

____ .... OOIllT __ I25 __ _ ... ...... __ ._----...... - ------""_ .. ...., ...... -_ .... _--• __ 7 .... _ .... __ ... _ ... _ ............. __ ._-10-1 ....... - s __

U .. u. ...... __ .. __ .-5.0" 5.010. _ ... _ ..... ~ ........... SIIaII

_-112.2_ .. _ 5< __ US .. • .25. _ ...... --.. _-----I_'. UIDI U .. 112 .. 2_"_. ___ "'10. -- ---------SiiOcocaos .. _ "'10 ..... -.r. ... ..,_._ .. _ .... _. 12 .. 12 .. .,-....... -- 5 .... 5.01D1 I_I.

5mNIIIU." I_' . __ .... _"" .... _--~ ... on"'" IDf trIe 1IId .... "-'

c-. 0;:5" .... u. U .. -"..., ......... -, ' .... 5.0" S.O .. • \ .............. -I-, ""111. ____ •

..... u.t J .......... 1

~.-"--,, ------n $':S - 1.4. I .• " --_ ... _-, ... ~,,,, 2.5_ 1.5 .. _ ...... _ ... -..... ' ' ..............

-~---, -.... --, ... _. ..., ................ ,. --- u. u. --" ..... -... -.... - 2.1 .. 2.5" ..... _--_ ... ........., ........ 7 .. '.1 ----. __ ... -...... _--_ .... -....... -......

Container DlapouI: Completely empty bag Into application equipment. Then dispose of empty bag in a sanitary landfill, or by incineration, or if allowed by state and local authorities, by buming. If burned, stay out of smoke.

WARRANTY AND LIMITATION OF DAMAGES Seller warrants thai this material conforms to its chemical description and is reasonably fit for the purposes stated on the label when used in accordance with diraclions under normal conditions of use and Buyer assumes the risk of any usa contrary to such directions. SEllER MAKES NO OTHER EXPRESS OR IMPLIED WARRANTY, INCLUDING ANY OTHER EXPRESS OR IMPLIED WARRANTY OF FITNESS OR OF MERCHANTABILITY, AND NO AGENT OF SELlER IS AUTHORIZED TO DO SO EXCEPT IN WRITING WITH A SPECIFIC REFERENCE TO THIS WARRANTY. In no event shall Seller's liability for any breach of warranty exceed the purchase price of the material as to which a claim is made.

Buyer and all users are responsible for aN loss or damage frorn usa or handling which results from conditions beyond the control of this company, including, but not timited to, incompatibility with products other than those set forth in the Directions for Use, weather conditions, moisture conditions or other environmental conditions outside of the ranges that are generally recognized as being conducive to good agricultural practice.

ft

o

COMPANY NUMBER

PRODUCT SERIAL NO.~-----~

LABEL APPROVAL D ATE ---.-.....i __ ~ --- ----

50s3'f-IS7

UNITED STATES ENVIRONMENTAL PROTEcnON AGENCY

WASHII"IGTON. D.C. 20460

Ralph P. Burton ISK BIOTECH CORP. S966 Heisley Road P.O. Box 800 Mentor,OH 44061

JAN 6 1994

OFFlCEOF I'AEVENTION. PESTICIlES AKJ

TOXICIUlSTANCES

Subject: Label Amendment Submission of 00/07/93 in Response to PR Notice 93-7 EPA Reg. No. 50534-157 BRAV090DG

Dear Registrant:

The labeling cited above and submitted in connection with registration under the Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA), as amended, is accepted. A copy of your proposed labeling stamped "ACCEPTED WITH COMMENTS" is enclosed.

WHAT THIS ACCEPTANCE MEANS:

Based on your certification, the Agency has accepted the labeling changes that are necessary to comply with the Worker Protection Standard (WPS) labeling requirements of 40 CFR part 156, subpart K, described in PR Notices 93-7 and 93-11. Any other labeling changes submitted in connection with this amendment application but not directly related to compliance with the WPS have not been reviewed or accepted by the Agency. If you wish to make such changes, you must submit a separate amendment application proposing them. If your product is currently suspended, the acceptance of this labeling amendment does not affect the suspension in any way.

WHAT YOU NEED TO DO NEXT:

Send to EPA one (1) copy of the final printed labeling:

• BEFORE selling or distributing any product bearing the final printed labeling AND • WITHIN one year from date of this acceptance.

Page 2

Submit the final printed labeling via the U.s. Postal Service to:

Document Processing Desk (fIN-LABEL) OffICe ·f Pesticide Programs (7S05C) U.s. Environmental Protection Agency 401 M Street. SW Washington. D.C. 20460-000 I

Hand or courier deliveries of final printed labeling may be made to:

Attachment

Document Processing Desk (fIN-LABEL) Office of Pesticide Programs Room 266A. Crystal Mall 2 1921 Jefferson Davis Highway Arlington. V A 22202

~CereIY. ____ _

i

TO'rnJr - fp y Chief istratio~ranch R gistration Division (7505W)

11

Net Contents:

Bravo® 90DG Agricultural Fungicide (90% Water Dispersible Granules)

Active Ingredient: Chlorothalor,'l (tetrachlorolsophthalonltrlle)* Inert Ingredients: Total:

Keep Out of Reach of Children DANGER-PELlG.RO

90.0"10 10.0"10

100.0%

3>

Si usted no entiende lD etiqueta. busqlle a alguien para que se lD eJCplique a IIsred in detalle. (If you do not understand the label. find someone to uptain it to YOII in detail.)

P,ea. HeieR •• U •• ,lo: . Si listed 118 lee insles, 118 tlse este predaet8 hasta title Ie etiqueta hay. side explieade

alftpliamente

See s.de panel for additional precautionary statements.

ISK Biotech Corporation 5966 Heisley Road P.O. Box 8000 Mentor. Ohio 44061-8000

EPA Reg. No. 50534-157 EPA Est. No. 50534-TX-1

3298-3038-1033-9212

AU!EPiiD ... OOIlliEh.i

... EPA ·'-1IMeoI

JAH6_ u .... 1M Federal s.. dd'lI F ·1I ..... d'JAel

"'1'7 :_,'0*1, ,... 6e:Jf,fh'l r w EPA )If .. t>,s.. -I

17

Bravo 90DG® A Broad-Spectrum Agricultural Fungicide

Read entire label carefully and u.e only a. directed.

PRECAUTIONARY STATEMENTS Hazard. to Humans and Domestic Animals Danger Corrosive, causes severe eye damage. May cause skin irritation. May be a potential skin sensitizer. DO NOT get In eyes. Wear ,e"les, feee Ihield e, llIfety ,llltle,. Wash the.etl,hly with leep .IId water .fter h."dlilll. Relft8Ve eOllta.illated elethilll ."ft wa,h lIeHl,e ,elise. Avoid prolonged contact with skin. A void breathing spray mist. DO NOT take intemally. Note to User: This product may produce mild bronchial irritation and temporary irritation of the skin characterized by redness or r.sh on exposed skin areas. Affected persons should consult a physician. no NOT apply thi, pradllel ill s\leh a _lIer as la direetly, ar lhrall,h drift, ellpese 'Werkers or ether perseRs. The area heins treated IIIHst he vaeeted it)' ttftproteeted persons.

First Aid: In case of contact with eyes, immediately flush eyes with plenty of water and continue for 15 minutes. Seek medical attention for eyes immediately. Wash exposed areas of skin with soap and warm water after handling or using. Note to Physician: Persons having temporary irritation symptoms may respond to treatment with antihistamines or steroid creams andlor systemic steroids.

ENVIRONMENTAL HAZARDS This product is toxic to fish, aquatic invertebrates, and marinelestuarine organisms. Runoff from treated areas may be hazardous to aquatic organisms in neighboring areas. DO NOT apply directly to water, to areas where surface water is present or to intertidal areas below the mean high water mark. DO NOT contaminate water when disposing of equipment washwaters. DO NOT apply when weather conditions favor drift from treated areas.

Apply only to areas specifj'.d on label.

DIRECTIONS FOR USE It is a violation of Federal law to use this product in a manner inconsistent with Its labeling.

A,ric"It"ral Un Ref"iremellts Uu this product ollly in accordanu with its labeling and with th~ Worker Prouction Standard. 40 CFR part 170. Refer to supplemental labeling under 'Agricultural Use Requir~m~nts· in rh~ Dirf!Ctions 'for Use sf!Ction for information about this standard.

See enclosed folder for directions fo~ use. Place Insert Pouch Here

11

s C/{ (1

STORAGE AND DISPOSAL DO NOT contaminate water, food or feed by storage or disposal. Open dumping is prohibited.

Storage: Store in a dry place.

Pesticide dlspo .. l: Pesticide wastes are toxic. Improper disposal of excess pesticide, pesticide spray or rinsate Is a violation of Federal law. If these wastes ceMOt be disposed of by use ac:cording to .. bel instructions, contact your smte Pesticide or Environmental Control Agency, or the Hazardous Waste representative !It the nearest EPA Reglollal 0IIIce for guidance.

Container Disposal: DO NOT reuse empty container. Triple rinse (or equivalent) and offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or incineration, or if allowed by state and local authorities, by burning. If burned, stay out of smoke.

WARRANTY AND LIMITATION OF DAMAGES Seller wanants that this material conforms to its chemical deSCription and is reasonably fit for the purposes stated on the label when used in accordance with directions under normal conditions of use and Buyer assumes the risk of any use contrary to such directions. SEUER MAKES NO OTHER EXPRESS OR IMPLJED WARRANTY,INCLUDING ANY OTHER EXPRESS OR IMPLJED WARRANTY OF FITNESS OR OF MERCHANTABILITY, AM> NO AGENT OF SEll ER IS AUTHORIZED TO DO SO. In no event shall Seller's liability for any breach of warranty exceed the purchase price of the material as to which a claim is made.

Bravo® 90DG

Agricultural Fungicide (90% Water Dispersible Granule;) Active Ingredient: Ch.orothalonil (tetrachloroisophthalonitrile) Inert Ingredients: Total:

Keep Out of Reach of Children

DANGE~ - PELIGRO

(INSERT FOLDER)

90.0% 10.0%

100.0%

6 1 (7

Si usud no entiende la etiqueta, busque a alguien para que se La explique a usted in detalle. (If you do not understand the label, find someone to f'xplain it to you in detail.)

See side panel for additior.al precautionary statements. Preeeusla" el lIeu.rlo: Si IIsled lie lee ill~les, lie lise eSle p.edllele hesle qlle Ie eliqllellt ha, . side eltplieede

ISK Biotech Corporation 5966 Heisley Road P.O. Box 8000 Mentor, Ohio 44061-8000

EPAReg. No. 50534-157 EPAEst. No. 50534-TX-1

3298-4005-8046-9207

Bravo® 90DG A Broad Spectrum Agricultural R.:ad entire label carefully and

Fungicide use only as

PRECAUTIONARY STATEMENTS Hazards to Humans and Domestic Animals

Danler

I t 17

directed.

Corrosive, causes severe eye damage. May cause skin irritation. May be a potential skin sensitizer. DO NOT get in eye,. Weer lenle,. '.ee ,lIield II. ,afety Ilasle'. Wasil tIIerelllllly with seap .BtI water after hellcililll. Rtat8'1e contaMinated elethiftl .ft" wash t.efefe teille.

Avoid prolonged contact with skin. Avoid breathing spray mist. DO NOT take internally. Note to User: This product may produce mild bronchial irritation and temporary irritation of the skin characterized by redness or rash on exposed skin areas. Affected persolls should consult a physician. DO NOT al'l'l) this produet in stleh • ",allile. 8' to directly I o. lh'Otllh drift, expose worke,s o. ether perso",. The area heiftS treattd ""1St he -Jaeated hy I:IlIp,eteeted persons.

:<'irst I.id: In case of contact with eyes, immediately flush eyes with plenty of water and continue for 15 minutes. Seek medical attention for eyes immediately. Wash exposed areas of skin with soap 'lnd warm water after handling or using. Note to Physician: Persons having temporary irritation symptoms may respond to treatment with ant histamines or steroid creams and/or systemic steroids.

P~rsonal Prot~ctiv~ Equipment (PPE):

Applica/ors an doth u han dlus must w~ar Ion g-sluv~d sh irt an d Ion g pan ts, watuproof glolles, sh oes plus socks, protectill~ ~y~w~ar an d a dustlm ist filterin g uspirator (MSHAI NICBH approl/al n umbu prefix TC-21C).

Discard cloth in g an d oth ~r absorb~n t materials th at h all~ bun dr~n ch ~d or h ~allily contaminated with thisproduct·sconc~ntrate. Donotrf!useth~m. Follow man ufacturu 's in structions for c1~an in glmain tain ing PPE. If no such in struction s for wash ables, use deterlent and hot watu. Kup and wash PPEs~parately from othu laundry.

Wh en han dlus use closed systems, ~n closed cabs, or aircraft in a man n u th at meets th ~ r~quir~m~n IS listed in th e Worker p"otution Standard (WPS) for agricultural pesticides /40 a:R 170.240 (dJ (4-6J/, th ~ han dl~r PPE requirem~n IS may b~ r~duced or modifi~d as spuifi~d in the WPS.

User Sa/et, Recolfllflelldatiolll

Users should:

• Wash hands before eating. drinlcing. chewing gum. using tobacco or using the toilet.

• Remolle clothill, immediately if pesticide ,ets illside. Theil wash thorou,hly aM put 011 cleall clothill •.

ENVIRONMENTAL HAZARDS This product is toxic to fish. aquatic invertebrates. and marine/estuarine organisms. Runoff from treated areas may be hazardous to aquatic organisms in neighboring areas. DO NOT apply directly to water. to areas where surface water is p~sent or to intertidal areas below the mean high water mark. DONOT contaminate water when disposing of equipme!lt washwaters. DO NOT apply when weather conditions favor drift from treated areas. Apply only to areas specified on label.

DIRECTIONS FOR USE It is a violation of Federal law to use this product in a manner inconsistent with its labeling. Nate to V,er: Wear 1'81sleS, feee shield Of ,.fety ,II9Ie,_ Wear len,; Ilee-;e shift. 16111 pa"ts. and ,;18\'e5 while mixins, leadins Blld applyi". this ,retitlet.

Do not apply t"is product in a way that will contact worlcers or other persc.~s. either directly or through drift. Only protected handlers may be in the area during application. For any requirements specific to your State or Tribe. consult the agency responsible for pesticide regulation.

AGRICULTURAL USE REQUIREMENTS

Use this product only in accordance with its labeling and with the Worlcer Protection Standard. 40 CFR part 170. This Standard contains requirements for the protection of agricultural worlcers on farms. forests. nurseries. and greenhouses. and handlers of agricultural pesticides. It contains requirements for training. decontamination. notification. and emergency assistance. It also contains specific instructions and exceptions pertaining to the statements on this label about personal protectille equipment (PPE) and restricted-entry interllal. The requirements :n this bo;( only apply to uses of this product that a!'e cOllered by the Worlcer Protection Standard.

Do not enter or allow worlcer entry into treated areas during the restricted entry interllal (REI) of 48 hours.

PPE required for early entry to treated areas that is permitted under the Worlcer Protection Standard and thaI in vollies contact with anything that has been treated. such as plants. soil. or water. is: coveralls. waterproof glolles. shoes plus soeles. and I"roleclive evewear.

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BRA VO 90DG is an excellent fungicide when used according to label directions for control of a broad spectrum of plant diseases.

1

BRAVO 90DG can be used effectively in dilute or concentrate sprays. Thorough. uniform coverage is essential for disease control. DO NOT use on greenhouse-grown crops. DO NOT combine BRAVO 9000 in the spray tank with p:sticides. surfactants or fenilizen. unless your prior use hu shown the combination phYlio:a1ly compatible. effective and noninjurious under your conditions of use. DO NOT combi"" BRAVO 9000 with Oipel 4L. Foil. Triton AG-98. Triton B-1956. Latron B-1956 or LatrrJn AG-98 as phytotoxicity may result from the combination when applied to some sper.ies on this label. Dipel is a registered trademark of Abbott Laboratories. Foil is a registered trademark of Ecogen COCforation. Triton AG-98. Triton B-1956, Latton B-1956 and Latron AG-'ill are trademarks of Rohm and Haas Company. Dosage rates on this label indicate pounds of BRAVO 90DG per acre, unless otnerwise stated. Under conditions favoring disease development the high rate specified and shortest application interval should be used. The required amount of BRAVO 9000 should be added slowly into the spray tank during filling. With concentrate sprays, pre-mix the required amount of BRAVO 90DG in a

. clean container and add to the spray tank as it is being filled. Keep agitator running when filling spray tank and during spray operations.

REENTRY: Nete tel:Jle.tOOP'm enter treated area 16 perforM hand lahe, withi" 2 4 hell'! of applies.io" tlnless p.eteeti we elelhins is WO'". Bee.lIsc ernei" states .... y retltlire ",ere restrictive rerRlfY inte."als fer "aPiett! ereps .reateEi with 'hi! predtlel, eonlyt. yotl' State DepartMent of Apieylul.e fer hrther jnformation. Wrine" or 8f81 wlrni,,!! Intlst he siYe" te worker, who are ,.peeted te he ill • treated area or ill In area Bhetlt Ie he treated with Ibis ,'"lIel. '.\'hen 8NI ilarnins! are ,i'len, wapnin!! !hall he sif/en ill a la .. Sllale etl!lo",arily understood hy '-"Briten. Oral warnin!! "'IISI he sivell if there is reasell 10 he lie 'Ie thai 'OJ/ritte" waPllillSs eaRllel he IIllderllood hy worker.. 9 .. 1 a"tI w rille" ,r;.PIliIlSI IIUIII i"ehule the fellowilll iI,ferlll.tien: HDANCBR ,\-te, treated .. ·ith ERAVO 9QOO Oft (dMe of .pplie.tie,,~. oo~ur ellter !l/ithelll apppepriale preleeti'Je elothi"l fer 24 haan. I.. ease of .eeide,,'al eJtpesare. ')lash ewpesed area with pl(PI'Y of water and lei IIIedieal attentioll. Fer ftlrther infer",atio" see ·Ppee.alia .. _." State",ents' ell lhe lehe" It

Field and Row Crops: Apply BRAVO 9000 in sufficient water to obtain adequate coverage of foliage. Gallonage to be used will vary with crop and amount of plant growth. Spray volume usually wi1l range from 20 to I SO gallons per acre (200 ;:1 1400 Iiten per hectare) for dilute sprays and 5 to 10 gallons per acre (50 to 100 litHS per hectare) for concentrate ground sprays and aircraft applications. Both ground and f ircraft methods of 'lpplication are recommended unless specific directions are ~ ;ven for a crop. Application through sprinkler irrigation systems is not recommended unless specific directions are given for a crop. Sec application and calibration instruction below.

Appllcaaon and Calibration TechnIques for SprInkler IrrIgation

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/0

Apply this product only through center pivot. motorized lateral move. traveling gun. solid set and ponable (wheel move. side roll. end tow. or hand move) irrigation system(s). DO NOT apply this product through any other type of irrigation system. Crop injury. lack of effectiveness. or illegal pesticide residues in the crop can result from lion-uniform distribution of treated water. If you have questions about calibration. you should contact State Extension Service specialists. equipment manufacturen or other expens. DO NOT apply this product through irrigation systems connected to a public water system. 'Public water system' means a system for the provision to the public of piped water for human consumption if such system has at least 15 service connections or regularly serves an average of at least 25 individuals daily at least 60 days per year. Controls for both irrigation water and pesticide in!<ection systems must be functionally interlock<!ld. so as to automatically terminate pesticide injection when the irrigation water pump motor stops. A penon knowledgeable of the irrigation system and responsible for its operation shall be present so as to discontinue pesticide injection and make necessary adjustments. should the need arise. The irrigation water pipeline must be fitted with a functional. automatic. quick-closing check val ve to prevent the flow of treated irrigation water back toward the water source. The pipeline must also be fitted with a vacuum relief valve and low pressure drain. located between the irrigation water pump and the check valve. to prevent back­siphoning of treated irrigation water into the water source. Always inject BRAVO 90DG into Irrigation water after it discharges from the irrigation pump and after it passes through the check valve. Never inject pesticides into the Intake line on the suction side of the pump. Pesticide injection equipment must be fitted with a functional. normally closed. solenoid-operated valve located on the intake side of the injection pump. Interlock this valve to the power system. so as to prevent fluid from being withdrawn from the chemical supply tank when the irrigation system is either automatically or manually turned off. The pesticide injection pipeline must contain a functional. automatic. quick-clu.ing check valve to prevent the flow A fluid back toward the injection pump. The irrigation line or water pump must include a functional pressure switch which will stop the water pump motor when the water pressure decreases to tile point where pesticide distribution is adversely affected. Spray mixture in the chemical supply tank must be agitated at all times. otherwise settling and uneven application may occur. DO NOT apply when wind speed favors drift beyond the area intended for treatment. Posting of areas to be chemigated is required when: I) any pan of a treated area is within 300 feet of sensitive areas such as residential areas. labor camps. businesses. day care centers. hospitals. in-patient clinics. nursing homes or any public areas such as schools, parks. playgrounds. or other public facilities not inciuding public roads; or 2) when the chemigated area is open to the public. Posting must conform to the following requirements. Treated areas shall be posted with signs at all usual points of entry and along likely routes of approach from the listed sensitive areas. When there are no usual poi,lts of entry, signs must be posted in the comers of the treated areas lind in any other location affording maximum visibility to sensitive areas. The printed side of the sign should face away from the treated area towards the sensitive area. The signs shall be printed in English. Signs must be posted prior to application and must remain posted until foliage has dried and soil surf2ce water has disappeared. Signs may remain in place indefinitely as long as they are

( 1

II

composed of materials to prevent deterioration and maintain legibility for the duration of the posting period.

1

All words shall consists of lellers at least 2-112 inches tall, and all leiters and the symbol shall be a color which sharply contrasts with their immediate background. At the top of the sign shall be the words KEEP OUT, followed by an octagonal stop sign symbol at least 8 inches in diameter containing the word STOP. Below the symbol shall be the words PESTICIDES IN IRRIGATION WATER.

This sign is in addition to any sign posted to comply with the Worker Protection Standard.

BRAVO 9000 may be used through two basic types oi sprinkler irrigation systems as outlineri in Sections A and B below. Determine which type of system is in place, then refer to the appropriate directions provided for each type.

A, Center Pivot, Motorized Lateral Move and Traveling Gun Irrigation Equipment For injection of pesticides, these continuously moving systems must use a positive displacement injection pump, of either diaphragm or piston type, constructed of materials that are compatible with pesticides and capable of being filled with a system interlock and capable of injection at pressures approximately 2 - 3 times those encountered within the irrigation water line. Venturi applicator units cannot be used on these systems. Fill chemical supply tank of injection equipment with water. Operate system for one complete revolution or run across (he field, measuring time required, amount of water injected. and acreage covered. Thoroughly mix recommended amount of BRAVO 90DG for acreage to be covered into same amount of water used during calibration and inject into system continuously for one revolution or run. Mixture in the chemical supply tank must be continuously agitated during the injection run. Shut off injection equipment after one revolution or run, but continue to operate irrigation system until BRAVO 9000 has been cleared from last sprinkler head.

B. Solid Set and Portable (Wheel Move, Side Roll, End Tow, or Hand Move) Irrigation Equipment With stationary systems, an effectively designed in-line venturi applicator unit is preferred which is constructed of materials that are compatible with pesticides; however, a positive-displacement pump can also be used. Determine acreage covered by sprinkler. Fit! tank of injection equipment with water and adjust flow to use contents over a thirty to forty-five minute period. Mix desired amount of BRAVO 9000 for acreage to be covered with water so that the total mixture of BRAVO 90DG plus water in the injection tank :s equal to the quantity of water used during calibration and operate entire system at normal pressures recommended by the manufacturer of injection equipment used for amount of time established during calibration. Agitation is recommended. BRAVO ~oo can be injected at the beginning or end of the irrigation cycle or as a separate application. Stop injection equipment after treatment is completed and continue to operate irrigation system until BRAVO 90DG has been cleared from last sprinkler head.

Metric Conversion Guide 2-1/8 pints equals 1.0 liter 4-1/4 pints equals 2.0 liters

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