index [] · s1 supporting information for zirconium–mof catalysed selective synthesis of α-...
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S1
Supporting informationfor
Zirconium–MOF catalysed selective synthesis of α-hydroxyamide via transfer hydrogenation of α-ketoamide
Ashish A. Mishra† and Bhalchandra M. Bhanage†*†Department of Chemistry, Institute of Chemical Technology, Matunga, Mumbai-400019. India.
Tel: +91 22 33612601; Fax: +91 22 33611020.
E-mail: [email protected] ; [email protected]
INDEXNo. Characterization Analysed Page No.
1. Powder XRD of Catalyst S2
2. TGA-DTGA of Catalyst S3
3. FT-IR of Catalyst & Catalytic Recycle Study S4
4. 1H & 13C NMR of α-hydroxyl amide and its derivative
S5 - S20
Electronic Supplementary Material (ESI) for New Journal of Chemistry.This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2019
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S2
X-RAY DIFFRACTION OF UiO66 & UiO66-NH2
Figure 1: XRD pattern for UiO66
Figure 2: XRD pattern for UiO66-NH2
Figure 3: XRD pattern for UiO-66 fresh and 4th recyclable catalyst
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S3
Thermogravimetric analysis
Figure 4: Thermogravimetric analysis of UiO66 and UiO66-NH2
Figure 5: Thermogravimetric analysis and DTA of UiO66-NH2
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S4
Figure 6: Infra-Red Spectroscopy of UiO66 and UiO66-NH2
1 2 3 4 5102030405060708090
100
% Yield Recovered
Run Cycle
% Y
ield
of p
rodu
ct
Figure 7: Catalytic Cycle
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S5
1H and 13C NMR of α-hydroxyamide and its derivative
500 MHz 1H-NMR spectra of 2a in DMSO-d6
126 MHz 13C-NMR spectra of 2a in DMSO-d6
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S6
500 MHz 1H-NMR spectra of 2b in DMSO-d6
126 MHz 13C-NMR spectra of 2b in DMSO-d6
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S7
500 MHz 1H-NMR spectra of 2c in DMSO-d6
126 MHz 13C-NMR spectra of 2c in DMSO-d6
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S8
500 MHz 1H-NMR spectra of 2d in DMSO-d6
126 MHz 13C-NMR spectra of 2d in DMSO-d6
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S9
500 MHz 1H-NMR spectra of 2e in DMSO-d6
126 MHz 13C-NMR spectra of 2e in DMSO-d6
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S10
500 MHz 1H-NMR spectra of 2f in DMSO-d6
126 MHz 13C-NMR spectra of 2f in DMSO-d6
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S11
500 MHz 1H-NMR spectra of 2g in DMSO-d6
126 MHz 13C-NMR spectra of 2g in DMSO-d6
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S12
500 MHz 1H-NMR spectra of 2h in DMSO-d6
126 MHz 13C-NMR spectra of 2h in DMSO-d6
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S13
500 MHz 1H-NMR spectra of 2i in DMSO-d6
126 MHz 13C-NMR spectra of 2i in DMSO-d6
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S14
500 MHz 1H-NMR spectra of 2j in DMSO-d6
126 MHz 13C-NMR spectra of 2j in DMSO-d6
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S15
500 MHz 1H-NMR spectra of 2k in DMSO-d6
126 MHz 13C-NMR spectra of 2k in DMSO-d6
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S16
500 MHz 1H-NMR spectra of 2l in DMSO-d6
126 MHz 13C-NMR spectra of 2l in DMSO-d6
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S17
500 MHz 1H-NMR spectra of 2m in DMSO-d6
126 MHz 13C-NMR spectra of 2m in DMSO-d6
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S18
500 MHz 1H-NMR spectra of 2n in DMSO-d6
126 MHz 13C-NMR spectra of 2n in DMSO-d6
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S19
500 MHz 1H-NMR spectra of 2o in DMSO-d6
126 MHz 13C-NMR spectra of 2o in DMSO-d6
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S20
500 MHz 1H-NMR spectra of 2p in DMSO-d6
126 MHz 13C-NMR spectra of 2p in DMSO-d6