inhomogeneous electronic states in superconductors ( chapelier , ioffe )

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Inhomogeneous electronic states in superconductors (Chapelier, Ioffe) How to disentangle the unavoidable atomic level inhomogeneity of real materials from the electronic inhomogeneity discussion-session

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discussion-session. Inhomogeneous electronic states in superconductors ( Chapelier , Ioffe ) How to disentangle the unavoidable atomic level inhomogeneity of real materials from the electronic inhomogeneity. Very Low Temperature STM: - PowerPoint PPT Presentation

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Page 1: Inhomogeneous electronic states in superconductors  ( Chapelier ,  Ioffe )

Inhomogeneous electronic states in superconductors (Chapelier, Ioffe)How to disentangle the unavoidable atomic level inhomogeneity of real materials from the electronic inhomogeneity

discussion-session

Page 2: Inhomogeneous electronic states in superconductors  ( Chapelier ,  Ioffe )

Maud VinetWalter EscoffierBenjamin SacépéThomas DubouchetCharlène Tonnoir

Claude ChapelierCEA INAC-SPSMS-LaTEQS, Grenoble

Very Low Temperature STM: a powerful probe for inhomogeneous superconducting states (tutorial)

Page 3: Inhomogeneous electronic states in superconductors  ( Chapelier ,  Ioffe )

Very Low Temperature STM: a powerful probe for inhomogeneous superconducting states (tutorial)

I. STM/STS and usual inhomogeneous superconducting states

II. Highly disordered superconductorsIII. Discussion

Page 4: Inhomogeneous electronic states in superconductors  ( Chapelier ,  Ioffe )

Coarse approach motor

Coarse positioning X-Y table

Sample holderTipPiezo tube10

cm

Scanning Tunneling Microscopy

Michael Schmid, TU Wien

Page 5: Inhomogeneous electronic states in superconductors  ( Chapelier ,  Ioffe )

P.Mallet et al., J. Vac. Sci. Technol. B 14, 1070 (1996) Michael Schmid, TU Wien

NbSe2

Scanning Tunneling Microscopy

Page 6: Inhomogeneous electronic states in superconductors  ( Chapelier ,  Ioffe )

P.Mallet et al., J. Vac. Sci. Technol. B 14, 1070 (1996)

D. Roditchev’s group, http://ln-www.insp.upmc.fr/

Michael Schmid, TU Wien

NbSe2

Scanning Tunneling Microscopy

Page 7: Inhomogeneous electronic states in superconductors  ( Chapelier ,  Ioffe )

Scanning Tunneling Spectroscopy

P.Mallet et al., J. Vac. Sci. Technol. B 14, 1070 (1996)

I

V

dI/dV

VeVfNd

dVdIVG T

S)()()(

NbSe2

D. Roditchev’s group, http://ln-www.insp.upmc.fr/

Page 8: Inhomogeneous electronic states in superconductors  ( Chapelier ,  Ioffe )

Scanning Tunneling Spectroscopy

P.Mallet et al., J. Vac. Sci. Technol. B 14, 1070 (1996)

I

V

dI/dV

VeVfNd

dVdIVG T

S)()()(

NbSe2

D. Roditchev’s group, http://ln-www.insp.upmc.fr/H. Hess et al., Physica B 169, 422 (1991)

Page 9: Inhomogeneous electronic states in superconductors  ( Chapelier ,  Ioffe )

I

V

dI/dV

Scanning Tunneling Spectroscopy

P.Mallet et al., J. Vac. Sci. Technol. B 14, 1070 (1996)

VeVfNd

dVdIVG T

S)()()(

NbSe2

D. Roditchev’s group, http://ln-www.insp.upmc.fr/H. Hess et al., Physica B 169, 422 (1991)

Page 10: Inhomogeneous electronic states in superconductors  ( Chapelier ,  Ioffe )

I

V

dI/dV

Scanning Tunneling Spectroscopy

P.Mallet et al., J. Vac. Sci. Technol. B 14, 1070 (1996)

VeVfNd

dVdIVG T

S)()()(

NbSe2

D. Roditchev’s group, http://ln-www.insp.upmc.fr/I. Guillamon et al., Phys. Rev.B 77, 134405 (2008)

Page 11: Inhomogeneous electronic states in superconductors  ( Chapelier ,  Ioffe )

http://www.oettinger-physics.de/

VortexNbSe2

Sachdev & Zhang, Science

Page 12: Inhomogeneous electronic states in superconductors  ( Chapelier ,  Ioffe )

http://www.oettinger-physics.de/

Vortex

H. Hess et al., Phys. Rev. Lett. . 62, 214 (1989)

NbSe2

Page 13: Inhomogeneous electronic states in superconductors  ( Chapelier ,  Ioffe )

http://www.oettinger-physics.de/

Vortex

H. Hess et al., Phys. Rev. Lett. . 62, 214 (1989)

NbSe2

Page 14: Inhomogeneous electronic states in superconductors  ( Chapelier ,  Ioffe )

http://www.oettinger-physics.de/

VortexNbSe2

H. Hess et al., Physica B 169, 422 (1991)

Page 15: Inhomogeneous electronic states in superconductors  ( Chapelier ,  Ioffe )

http://www.oettinger-physics.de/

Vortex

H. Hess et al., Physica B 169, 422 (1991)

Ch. Renner et al., Phys. Rev. Lett. (1991)

Nb1-x TaxSe2

Page 16: Inhomogeneous electronic states in superconductors  ( Chapelier ,  Ioffe )

http://www.oettinger-physics.de/

Vortex

J.E. Hoffman., Science 295, 466 (2002)

Bi2Sr2CaCu2O8+

Page 17: Inhomogeneous electronic states in superconductors  ( Chapelier ,  Ioffe )

Hybrid nanostructures

N. Moussy et al., Europhys. Lett. 55, 861 (2001)

M. Vinet et al., Phys. Rev. B 63, 165420 (2001)

-4 -2 0 2 4

0,5

1,0

1,5

dI/d

V (n

orm

aliz

ed)

V [mV]

195 nm

75 nm

12 nm

H. Le Sueur et al., Phys. Rev. Lett. 100, 197002 (2008)

Page 18: Inhomogeneous electronic states in superconductors  ( Chapelier ,  Ioffe )

Very Low Temperature STM: a powerful probe for inhomogeneous superconducting states (tutorial)

Page 19: Inhomogeneous electronic states in superconductors  ( Chapelier ,  Ioffe )

Superconductor-Insulator Transition

Granular systems Homogeneously disordered materials

H.M. Jaeger, et al., Phys. Rev. B 34, 14920 (1986)

D.B. Haviland, et al., Phys. Rev. Lett. 62, 2180 (1989)

GalliumBismuth

Page 20: Inhomogeneous electronic states in superconductors  ( Chapelier ,  Ioffe )

Superconductor-Insulator TransitionTiNReactive sputter deposition of TiN films

Homogeneously disordered ?

N. Hadaceket al., Phys. Rev. B 69, 024505 (2004)

100 nm

10 nm

Page 21: Inhomogeneous electronic states in superconductors  ( Chapelier ,  Ioffe )

Superconductor-Insulator TransitionTiN

100 nm

10 nm

T (K)

R (O

hms)

Reactive sputter deposition of TiN films

Granular ?Homogeneously disordered ?

N. Hadaceket al., Phys. Rev. B 69, 024505 (2004)

Page 22: Inhomogeneous electronic states in superconductors  ( Chapelier ,  Ioffe )

Superconductor-Insulator TransitionTiN

T (K)

R (O

hms)

Reactive sputter deposition of TiN films

Granular ?Homogeneously disordered ?

N. Hadaceket al., Phys. Rev. B 69, 024505 (2004)

≈ 80 × 80 × 2 nm

≈ 400

× 4

00 ×

3

nmW. Escoffier et al.,Phys. Rev. Lett. 93, 217005 (2004)

100 nm

10 nm

Page 23: Inhomogeneous electronic states in superconductors  ( Chapelier ,  Ioffe )

Superconductor-Insulator TransitionTiNReactive sputter deposition of TiN films

Homogeneously disordered ?

N. Hadaceket al., Phys. Rev. B 69, 024505 (2004)

≈ 80 × 80 × 2 nm

≈ 400

× 4

00 ×

3

nmW. Escoffier et al.,Phys. Rev. Lett. 93, 217005 (2004)

100 nm

10 nm

Page 24: Inhomogeneous electronic states in superconductors  ( Chapelier ,  Ioffe )

M. Baklanov and A. Satta (IMEC)

Superconductor-Insulator TransitionTiNAtomic layer deposition of 5 nm thick TiN films

Page 25: Inhomogeneous electronic states in superconductors  ( Chapelier ,  Ioffe )

-1,0 -0,5 0,0 0,5 1,00,0

0,5

1,0

1,5

2,0

G(V

), no

rmal

ized

V [mV]

= 260 µeVTeff = 0,25 K

-1,0 -0,5 0,0 0,5 1,00,0

0,5

1,0

1,5

2,0

= 225 µeVTeff = 0,32 K

G(V

), no

rmal

ized

V [mV]

0,0 0,5 1,0 1,5 2,0 2,5 3,0 3,5 4,00

1

2

3

4

5

6

7

8

R [k

]

T [K]

TiN 1 TiN 2 TiN 3

-1,0 -0,5 0,0 0,5 1,00,0

0,5

1,0

1,5

2,0

= 154 µeVTeff = 0,35 K

G(V

), no

rmal

ized

V [mV]

Increasing disorder

Superconductor-Insulator transition

Sacépé et al., Phys. Rev. Lett. 101, 157006 (2008)

TiN

Page 26: Inhomogeneous electronic states in superconductors  ( Chapelier ,  Ioffe )

Superconductor-Insulator transitionTiN

λ

Sacépé et al., Phys. Rev. Lett. 101, 157006 (2008)

Tc [K] Δ/TcVar.

[%]

4.7 1.8 ---1.3 2.3 121 2.6 20

0.45 4 50

A. Ghosal, M. Randeria, N. Trivedi, Phys. Rev. Lett. 81, 3940, (1998)Phys. Rev. B 65, 014501 (2001)

M. Ma and P.A. Lee, Phys. Rev. B 32, 5658, (1985)A. Kapitulnik, G. Kotliar, Phys. Rev. Lett. 54, 473, (1985)M. Feigel’man et al., Phys. Rev. Lett. 98, 027001, (2007)M. Feigel’man et al., Ann. Phys. 325, 1390 (2010)M. A. Skvortsov et al., Phys. Rev. Lett. 95,057002, (2005)

Page 27: Inhomogeneous electronic states in superconductors  ( Chapelier ,  Ioffe )

Pseudogap

B. Sacépé, et al., Nature Communications 1:140 (2010)

Page 28: Inhomogeneous electronic states in superconductors  ( Chapelier ,  Ioffe )

0,0 0,5 1,0 1,5 2,0 2,5 3,0 3,5 4,00

1

2

3

4

5

6

7

8

R [k

]

T [K]

TiN 1 TiN 2 TiN 3

Superconducting fluctuations correction to the DOSShort-lived Cooper pairs above Tc

A. Varlamov and V. Dorin, Sov. Phys. JETP 57, 1089, (1983)

Pseudogap

B. Sacépé, et al., Nature Communications 1:140 (2010)

Page 29: Inhomogeneous electronic states in superconductors  ( Chapelier ,  Ioffe )

0,0 0,5 1,0 1,5 2,0 2,5 3,0 3,5 4,00

1

2

3

4

5

6

7

8

R [k

]

T [K]

TiN 1 TiN 2 TiN 3

Superconducting fluctuations correction to the DOSShort-lived Cooper pairs above Tc

A. Varlamov and V. Dorin, Sov. Phys. JETP 57, 1089, (1983)

Pseudogap

B. Sacépé, et al., Nature Communications 1:140 (2010)

R□

[kΩ]Tc (R□) [K]

Tc (DOS)

[K]

3.5 1.31.3 1.271.27

4.3 1.01.0 0.980.98

7.4 0.450.45 0.450.45

An extreme sensitivity to Tc

Page 30: Inhomogeneous electronic states in superconductors  ( Chapelier ,  Ioffe )

Very Low Temperature STM: a powerful probe for inhomogeneous superconducting states (tutorial)

How to disentangle the unavoidable atomic level inhomogeneity of real materials from the electronic inhomogeneity ?

Which inhomogeneities ?

Down to which scale a real material must be considered granular or not ?

What is a homogeneously disordered material ?

How can we relate global macroscopic behavior (transport) and local signatures (STS) ?

Page 31: Inhomogeneous electronic states in superconductors  ( Chapelier ,  Ioffe )

Dilution fridge setup

Page 32: Inhomogeneous electronic states in superconductors  ( Chapelier ,  Ioffe )

Anomalous proximity effectSuperconducting granular TiN films

-1,5 -1,0 -0,5 0,0 0,5 1,0 1,50,0

0,5

1,0

1,5

2,0

2,5

3,0 xexp

= 0 nm x

cal = 0 nm

xexp

= 12 nm x

cal = 9 nm

xexp

= 20 nm x

cal = 21 nm

xexp

= 32 nm x

cal = 31 nmdI

/dV

E (meV)

dS,N

W. Escoffier et al., Phys. Rev. Lett. (2004)

≈ 80 × 80 × 2 nm

≈ 400

× 4

00 ×

3

nm

Theory : Zhang & Xiong,

Physica C (2006)

Page 33: Inhomogeneous electronic states in superconductors  ( Chapelier ,  Ioffe )

Anomalous proximity effectSuperconducting granular TiN films

B. Sacépé (unpublished)

1500 nm x 1500 nm

Page 34: Inhomogeneous electronic states in superconductors  ( Chapelier ,  Ioffe )

Superconducting fluctuations quantum corrections

Page 35: Inhomogeneous electronic states in superconductors  ( Chapelier ,  Ioffe )

Tc [K]

1.31

0.45

One parameter fit : Tc

Superconducting fluctuations quantum corrections