introduction to optical mineralogy
DESCRIPTION
Notiuni de baza in mineralogie. Geologie. Izotropie, anizotropie. Clivaj, habitus, pleocroism, opacitate, relief, incluziuni, polarizare, unghi de extinctie, unghi de orientare, birefringenta, tabele de identificare, grupe mineralogice, microscopie, structuri micro si macro, compozitie chimica, proprietati optice, etc.TRANSCRIPT
Gabi (Gelu) Costin
- 2011 -
Introduction to Optical Mineralogy
GLC 201 - Introduction to Optical Mineralogy
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Contents
INTRODUCTION _________________________________________________________________ 4
Recommended textbooks, websites; pracs, tests & exam info ______________________________ 5
Objectives of the course_____________________________________________________________ 5
1. WHAT IS LIGHT? ______________________________________________________________ 6
1.1. Light as a wave ........................................................................................................................ 6
1.2. Light as particle ....................................................................................................................... 7
1.3. Polarized light .......................................................................................................................... 7
2. ISOTROPIC AND ANISOTROPIC MATERIALS ____________________________________ 8
3. INTERACTION BETWEEN LIGHT AND MINERAL ________________________________ 9
3.1. Reflected light .......................................................................................................................... 9
3.2. Absorbed light ....................................................................................................................... 10
3.3. Refracted light ....................................................................................................................... 11 3.3.1. Refractive index ............................................................................................................................. 11 3.3.2. Important things to know about the refraction taking place in minerals ............................................ 12
3.4. Transmitted light ................................................................................................................... 14 3.4.1. Thin section for optical studies in transmitted light.......................................................................... 14
4. VECTORIAL AND CONTINUOUS CHARACTER OF REFRACTION ________________ 15
4.1. Indicatrix ............................................................................................................................... 15
4.2. Interference colours (IF); birefringence (δ) .......................................................................... 17
5. PETROGRAPHIC MICROSCOPE _______________________________________________ 21
6. MINERAL IDENTIFICATION USING THE PETROGRAPHIC MICROSCOPE ________ 23
6.1. Orthoscopic study .................................................................................................................. 23
6.1.1. Observations using plane polarized light (PPL) mode ______________________________ 23
a) Transparency ........................................................................................................................... 23
b) Shape, habit, size ...................................................................................................................... 23
c) Cleavage ................................................................................................................................... 25
d) Colour (absorption colour) ...................................................................................................... 28
e) Pleochroism .............................................................................................................................. 28
f) Relief ......................................................................................................................................... 28 Becke line; Becke method for estimating the relief .................................................................................... 29 Twinkling (relief changing) ...................................................................................................................... 30 Chagrin (roughness in appearance of the mineral surfaces)...................................................................... 30
g) Inclusions, alterations .............................................................................................................. 31
6.1.2. Observations using crossed polarized light (XPL) mode ____________________________ 32
a) Isotropy/anisotropy .................................................................................................................. 32
b) Extinction angle ....................................................................................................................... 32 Determination of the extinction angle ....................................................................................................... 32
c) Birefringence ............................................................................................................................ 34 Colour of interference (colours of birefringence) ...................................................................................... 34 Finding the value of birefringence (δ)....................................................................................................... 35
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d) Twinning/zoning ...................................................................................................................... 36 Twinning ................................................................................................................................................. 36 Zoning (compositional zoning) ................................................................................................................. 37
e) Orientation of nγ and nα ........................................................................................................... 38
f) Optical elongation ..................................................................................................................... 40
6.2. Conoscopic mode ................................................................................................................... 40 6.2.1. Interference Figures ........................................................................................................................ 41 Interference figure for uniaxial crystals .................................................................................................... 41 Interference figure for biaxial crystals ...................................................................................................... 41
Determination of the optic sign .................................................................................................... 42
Estimation of the 2V angle ........................................................................................................... 44
Useful charts for mineral identification: the Tröger Chart _______________________________ 46
27 Key minerals species ____________________________________________________________ 47
Key Characteristics of common minerals: Speeding up mineral identification_______________ 48
A few hints for the relation chemical composition - optical properties _____________________ 48
Tips for discriminate between different mineral groups _________________________________ 49
Mineral association: helpful in identifying minerals ____________________________________ 49
Mineral Identification – A Beginner’s Guide __________________________________________ 50
Identification Tables for Common Minerals in Thin Section _____________________________ 53
Tables for Common Minerals in Thin Section _________________________________________ 54
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INTRODUCTION
Why study minerals/crystal optics?
1) They assist in the identification of minerals – study their optical properties under the
microscope.
• Minerals are inorganic chemical compounds having a certain lattice shape, size and
symmetry, being a result of the geometrical arrangement of the constituents (chemical
elements such as Si, Al, O, etc).
• Lattice (symmetry) + chemistry (nature of the chemical elements of the lattice)
combine to make a unique mineral phase. The lattice (internal symmetry) of the mineral
is reflected not only in the symmetry of the external crystal shape but also in the
symmetry of optical properties of the mineral; therefore, determining the optical
properties of an unknown phase assists in identifying the mineral phase;
• Mineral identification is needed in petrological studies, structural geology, mineral
exploration etc…
2) Microscopic study is the cheapest and fastest method for identifying minerals; however, there
are limitations to the optical method, such as constraints of very small size (sub-
microscopic) of minerals, or complex solid solutions, etc.
3) Microscopic study is required for textural (natural arrangements of minerals) analysis; it is
useful in determining the rock type, the crystallization sequence, deformation history or
observing frozen-in reactions, constraining pressure-temperature history, noting
weathering/alteration, etc.
4) Because the principles of light refraction and reflection are also relevant to seismicity
(geophysics and geological exploration), water behaviour (groundwater management),
and even to real life!
Remember that minerals have an ordered internal lattice (with an internal symmetry) which is also
reflected in the external shape of the crystals. Therefore, it is expected that the optical properties of
minerals somehow demonstrate this internal symmetry. In order to “see” the symmetry of the optical
properties, and to determine the symmetry of a mineral, we need to understand:
a) What light is, and especially polarized light;
b) The difference between isotropic and anisotropic media (optical and other properties of minerals
can be isotropic and anisotropic);
c) The concept of vectorial and continuous properties;
d) The tool of studying the optical properties of minerals (the petrographic microscope);
e) The use of specific charts of physical properties in order to identify unknown minerals;
f) A few specific optical properties which can help in quick identification of the common rock-
forming minerals.
This handout represents a compilation realized by Dr. Gelu Costin from different resources:
previous versions of power-point presentations and notes: Dr. Steffen Bütner, Dr. Stephen
Prevec. Dr. Emese Bordy, Prof. Goonie Marsh
internet resources
several text explanations and some figures were added by Dr. Gelu Costin
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Recommended textbooks, websites; pracs, tests & exam info
A) Recommended TEXT BOOKS and WEBSITES
1) Perkins, D. & Henke, K.R. (2004): Minerals in Thin Section. Prentice Hall.
2) Deer, Howie & Zussman (1992): Introduction to rock forming minerals
3) Heinrich (1965): Microscopic identification of minerals
On short loan:
Bloss, F. D.: Optical crystallography 548.9 BLO
Shelley, D.: Optical mineralogy 549.125 SHE
Others:
Gribble, C.D. & Hall, A.J.: Optical mineralogy: principles and practice
Battey, M.H. & Pring, A.: Mineralogy for students
B) Lectures & Pracs
* All material presented in the lectures is relevant for the pracs. Polarisation Microscopy is a method used in:
1. 201 Mineralogy/Geochemistry
2. 201 Introductory Igneous Petrology
3. 202 Sedimentology
4. 202 Igneous Petrology
5. 301 Structural Geology
6. 301 Metamorphic Petrology
7. 302 Economic Geology
8. Almost all modules on Honours level
9. More or less all studies on Masters/PhD level and beyond
1. Optical properties of some common mineral species on the Web: http://www.brocku.ca/earthsciences/people/gfinn/minerals/database.htm
http://funnel.sfsu.edu/courses/geol426/Handouts/mintable.pdf
http://www.geolab.unc.edu/Petunia/IgMetAtlas/mainmenu.html
http://sorrel.humboldt.edu/~jdl1/minerals.list.html
http://geology.about.com/od/thinsections/Thin_Sections.htm
2. More or less everything about minerals:
http://webmineral.com/determin.shtml
3. More thin section photos + optical properties
http://www.und.nodak.edu/instruct/mineral/320petrology/opticalmin/
4. First aid for conoscopy problems
http://users.skynet.be/jm-derochette/conoscopy.htm
C) Tests & Exams
No formal 45 min theory test
Instead: daily quickies (5 minute tests)
Thin section microscopy work can be expected as main part of the GLG 201/202 Prac Exam
Objectives of the course
understanding the behaviour of minerals under transmitted polarized light
understanding and practicing the determination of optical properties of crystalline solids
identification of unknown minerals using optical property determinations and catalogues of
physical properties
rapid identification of common minerals in thin section
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1. WHAT IS LIGHT?
Light may be seen as electromagnetic waves and/or as particles (quantum theory).
1.1. Light as a wave
A wave* (Fig. 1) can be characterized by four parameters**: wavelength, frequency, velocity and
intensity.
* any kind of wave (e.g. optical, mechanical, thermal, acoustic, seismic etc) can be characterized by
these above-mentioned parameters
**a parameter is a physical property which can be measured
a) wavelength (λ - lambda): distance between two neighbouring points experiencing vibrations of
the same amount and in the same direction. Such points are said to be in phase. The wavelength is
important in optical mineralogy, since it is this that affects our perception of colour. (coherent light =
in phase, incoherent = not in phase).
Figure1. Graphical representation of light. λ = wavelength.
a= amplitude (related to ε = intensity or energy of the wave).
Visible (white) or polychromatic light (Fig. 2) with wavelengths between 390 and 780nm (nano
meter = 10-9
m = 1 billionth of a meter) is a small part of the electromagnetic spectrum which
includes gamma- and X-rays, ultraviolet as well as infrared light, radio- and micro-waves. Sunlight
contains the entire visible spectrum plus ultraviolet light and infrared light as well.
Visible light includes 7 monochromatic lights which correspond to the 7 primary colours of the
rainbow (as recognised by Sir Isaac Newton): violet, indigo, blue, green, yellow, orange, red.
Figure 2. Colours of the visible spectrum with their corresponding wavelength (in black and white).
The wavelength range of the colors from the visible spectrum are:
Violet: 390 - 420 nm
Indigo: 420 - 440 nm
Blue: 440 - 490 nm
Green: 490 - 570 nm
Yellow: 570 - 585 nm
Orange: 585 - 620 nm
Red: 620 - 780 nm
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b) Frequency (η - nu): number of wavelengths passing a fixed point in 1 second; “pulse rate”
c) Velocity (c) is related to frequency (η) and wavelength (λ) by: c = ηλ
The velocity of light in a vacuum is higher than in any other substance (2.99773 x 108 m/s);
(Slowing down waves = shortening their wavelength)
d) Intensity (ε = the amplitude of the wave). The amplitude of the wave is related to the energy
(the “higher” wave has more energy). The wave energy of light is given by the moving photons and
therefore, the amplitude (intensity) of the wave makes the connection between wave and particle
nature of light.
1.2. Light as particle
Light is interacting with the electric fields produced by the nuclei and electrons of atoms it will
slow down light passing through them the more atoms and/or e- that are in a given volume the
more the light rays will decelerate. Density of atoms in the mineral lattice and number of e- per atom
in the material are important (note that the number of e- per atom is directly dependent on the atomic
number of the element -see the Periodic Table of the Elements). As the atomic number is higher, the
mass of the element is higher, and consequently the mass of the compound made by the heavy
elements will be higher. Since density = mass/volume, this also reduces to considering density as the
main factor in slowing down the light speed within materials.
1.3. Polarized light
Natural light vibrates (oscillates) in all the directions perpendicular to the direction of propagation
(fig. 3). Therefore we can say that there is infinity of planes of vibrations (all possible planes that
intersects/contain the direction of propagation.
Figure 3: Propagation and vibration of natural light; note vibration in all directions perpendicular to
the direction of propagation (all vibration directions are perpendicular on the propagation line).
Plane polarized light (PPL) has one single plane of vibration, in which the direction of vibration is
always perpendicular to the direction of propagation (fig. 4). We can use this plane of vibration as a
geometrical reference for the optical properties of mineral. Keeping this plane fixed and rotating
(changing the orientation of) the mineral, all of the mineral‟s optical properties can be measured or
related to such a plane. Note that we can polarize light with a special designed material, called a
nicol or polarizer. The name “nicol” comes from Nicol (Nicol‟ prism), a French scientist who first
built a kind of prism of calcite, made of two halves of the same calcite crystal, adjusting the angles
of the prism to a convenient value in order to eliminate all other planes of vibration but one. More
commonly, these days, materials called polaroids are used for manufacturing polarisers (microscopic
oriented crystals of iodoquinine sulphate embedded in a nytrocelulose polymer film).
Note that the polariser does not absorb light (or the absorption is negligible), so it does not affect the
observed colour of the mineral (fig. 5a). See the difference between a polariser and a colour filter
(fig. 5b).
Direction of propagation
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Figure 4: Polarized light (plan polarized light -PPL)
Figure 5: a) Polariser: the light exiting from the polariser has one single plane of
vibration; The intensity of the light (amplitude of wave) is not affected; b)
colour filter: the intensity of polarised light entering the filter is attenuated
(some energy of the light was absorbed and the out light will be coloured but
still polarised). The amplitude of the wave will therefore decrease.
In order to relate the optical properties of a mineral to a particular symmetry, we need to find an
external optical-geometrical element (such as a reference plane – e.g. plane of polarization of the
incident light) and to relate to it all the optical properties that we want to consider for a mineral.
2. ISOTROPIC AND ANISOTROPIC MATERIALS
Isotropic (in a general sense) means that any physical property of the material is the same at any
point and in any direction through the material (it is independent of orientation). Concerning mineral
optics, the word “isotropic” refers to the optical properties of the mineral, which are the same and
independent of the orientation (e.g. isotropic minerals). However, if a mineral is isotropic, it means
that ALL of its physical properties are the same at any point. Minerals that are isotropic are the
minerals with cubic symmetry (remember the symmetry of minerals crystallized in the cubic system
have a=b=c and α=β=γ=90°), and materials that do not have a geometrical arrangement of the atoms,
so they do not have an internal lattice (e.g. non-crystalline materials), such as glass, liquids, and
gasses. Accordingly, an isotropic mineral has the same refractive index, the same absorption of light
(and the same for any other physical property) at any point and for any direction in the mineral.
Anisotropic (in a general sense) means that the properties of the material are not the same at all
points or directions, but may vary continuously with changing direction (orientation) of observation
(all minerals other than cubic are anisotropic). Examples of anisotropic behaviour when changing
orientation include different absorption of light, different refractive indexes, etc.
Anisotropic crystals have variable refractive indices because light travelling through the crystals will
do so at different speeds, depending on the direction of travel (the orientation of the crystal to the
incident light).
Plane of vibration
Direction of propagation
Direction of vibration
a)
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All minerals, other than those belonging to the isometric system, are anisotropic. But some of them
are “more anisotropic” than others, and the isotropy-anisotropy is related to the symmetry of
crystals. For example, all minerals can be grouped based on their symmetry according to 7 systems
of symmetry, and beyond that, we can subgroup the symmetry according to the presence or absence
of high order fold axes (A3, A4, A6):
-minerals with superior symmetry (cubic or isometric system: a=b=c and α=β=γ=90°); several high
order fold axes are present: 3 A4 or 3Ai4 and 4 A3.
-minerals with medium symmetry (trigonal, tetragonal and hexagonal systems); all of them have
one main axis of symmetry, only: A3, A4 or A6, respectively.
-minerals having inferior symmetry (orthorhombic, monoclinic and triclinic); no high order axis is
present (no fold axis superior to A2); among these, the symmetry decreases as the number of
A2 axes decreases: orthorhombic: maximum 3 A2; monoclinic: maximum 1 A2; triclinic has
the lowest symmetry, with no A2 axis.
3. INTERACTION BETWEEN LIGHT AND MINERAL
As light intersects an isotropic material (let‟s say glass or an isotropic mineral, such as garnet), the
light suffers several optical phenomena, and is decomposed into several components. The intensity
(or the energy) of the incident light splits up accordingly (Fig. 6):
a) Some fraction of the incident light is reflected by the surface of the mineral. The intensity
of the reflected light is (εrl)
b) Another component of light entering the mineral is refracted (εr): this refracted light is
plane polarized!!
c) a variable component of the light that enters the mineral is absorbed (εa)
d) The remaining light (intensity), if any, succeeds in escaping from/through the mineral
grain. This light is called transmitted light (εt); the transmitted light is also polarized by
the mineral (the mineral acts like a complex polarizer).
Thinking in terms of energies (or intensities), the budget of the initial incident light is:
εi = εrl + εr + εa + εt
3.1. Reflected light
The reflection depends on the surface properties of the mineral but also on its nature (some minerals
reflects more light than others). The strongly reflective minerals are those which reflect all (or
almost all) of the incident light and no other light component is able to cross through and exit the
mineral (no transmitted light). This means that the mineral is opaque to light. We can define
reflectivity (or reflectance) as the fraction of incident light (in terms of energy or intensity) which is
reflected from a surface. Reflectivity is therefore proportional to the intensity of the light reflected
by the mineral. The reflectivity index (R) is the ratio between reflected light intensity versus incident
light intensity (R= εrl/εi), a ratio which is lower than 1. However,typically R is expressed in
percentages; R= εrl/εi x 100 %. In order to study opaque minerals we need to analyze the light
reflected by the mineral (we need therefore to polish one surface of the mineral as well as possible in
order to get the best reflectivity). The opaque minerals are studied with the chalcographic (reflected
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light) microscopes (you will learn to use chalcographic microscopes another time, not within this
term).
Common experience (such as mirror imaging) tells us that the angle of incidence is equal to the
angle of reflection. However, at a certain incident angle, the incident ray is refracted at 90 ; this is
termed total reflection. The incident angle at which total reflection occurs is called the critical angle
(θi-cr).Total reflection is used to determine the refractive index of an unknown material:
θr = 90, nair ~ 1
ni sinθi-cr = nair sinθr sin θi-cr= 1 / ni
Figure 6: Light intensities splitting out at the interface of light with the mineral. Notice
the difference between the incidence angle (θi) and the refraction angle (θr). When
exiting the mineral, the (transmitted) light will resume propagation at the original
θi angle to the surface.
3.2. Absorbed light
One fraction of the light that enters the mineral is absorbed. This absorption is responsible for the
colours of materials that we see around us. How does it work? Inspired by the colours of the
rainbow, Newton decomposed the natural light into its components using an optical prism. Looking
at figure 2, we see that several colours can be distinguished in the visible spectrum (wavelengths
between ~400 nm (violet) to ~800 nm (red). All of them are the components of the yellow light. If
all the coloured lights from the visible spectrum are combined, we get a wave with an approximate
average value of wavelength λ~(400+800)/2~600 nm (the real value is 575 nm). This is the
wavelength of the yellow light (or natural light from the sun). It means that the yellow light contains
a combination of waves that include all the wavelengths from the visible spectrum.
incident light (εi) reflected light (εrl)
used by
CHALCOGRAPHIC
MICROSCOPE
absorbed light (εa)
transmitted light (εt) used by PETROGRAPHIC
MICROSCOPE
Plane perpendicular on the mineral surface
(and on the boundary) between air and mineral)
AIR
AIR
θr
θi
nair nm
θi
εo εe
refracted light (εr=εo+εe)
Isotropic MINERAL (or gass)
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When an incident yellow light (natural light from the window or the light emitted by a lamp) enters a
material, some of the wavelength components can be absorbed by the material (the electromagnetic
components of certain wavelengths of the incident light are consumed/combined into the
electromagnetic field produced by the atoms and molecules of the material or we can understand this
as the energy of the incident photons which is transferred to the electrons of the material, making
them moving faster; the result of this absorption of energy is heat). The interaction of the light with
the discrete nature of material is more complicated. For example, the transfer of energy from
incident photons to the electrons of the material can produce not only increasing vibration of the
molecules, but, if intensity of the incident photons is high enough, they can displace some electrons
from their position (moving one e- from an orbital to another). This happens with X-ray emission
(other photons vibrating with wavelengths in the X-ray spectrum (see fig. 2). The combination of the
remaining wavelength components which were not absorbed gives the colour of the material that we
observe. In other words, the colours that we observe around us are produced by selective absorption
of light by different objects, and the selectivity of absorption depends on the composition of the
material. If a material absorbs all the (visible) wavelengths in (proportionally) the same amount, the
material will be colourless. If the material absorbs more from the lower visible spectrum (violet,
blue), the colour of the material would be a combination of the remaining wavelengths from yellow
to red (the observable colour would then be orange). If a material does not absorb any components of
light at all, it would be… invisible. Well, this is not yet possible since the electromagnetic radiation
will interact with the atoms and electrons of the material, so at least some absorption has to take
place.
The wavelengths of the reflected light also affect the appearance of colour. Note that the thickness of
the medium can affect the eyes‟ interpretation of colour. Hence, many minerals which we are
accustomed to seeing as coloured are colourless in thin section (for example, the various coloured
varieties of quartz, such as amethyst).
3.3. Refracted light
A component of the non-reflected light is refracted into the mineral. Refraction is a fundamental
optical property of any medium which transmits light.
3.3.1. Refractive index
Refractive Index (R.I. or n) is a measure of refraction. The refractive index (n) is the ratio between
the velocity of light in vacuum (cv) and the velocity of light in the material (cm):
n = cv / cm In optical mineralogy we can‟t actually measure the speed of light, but we can utilise this ratio of the
speed of light in a mineral related to the speed in a vacuum. Since the speed of light in a vacuum, cv,
is the maximum possible speed of light, the refractive index will be always greater than 1.
Sometimes R.I. is defined as the ratio of “the velocity of light in air / the velocity of light in a
medium” (i.e., any physical material other than air, as distinct from “a person who talks to ghosts”),
as there is little difference for purposes of optical mineralogy (cvacuum almost = cair nvacuum= 1; nair
= 1.0003; nwater = 1.33). As we can see even from the above example, c depends largely on the
density of the material. The higher the density is, the more difficult it is for light to travel within
the material, so it gets slowed down. Since the cm is at the denominator in the definition of n, it
means that n is higher when cm is lower (therefore, when the density of the material is higher).
Accordingly, common sense tells as that nsolid > nliquid > nair.
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The direct optical effect of observing refraction is that, looking at an object
through a non-opaque material (liquid or solid), the margin of the object is
observed as “displaced or moved” if you look at it from the side (i.e., away
from the axis perpendicular to the material surface). The apparent
“displacement” is higher when the angle is higher and when the refractive
index of the material (or rather, the contrast in refractive indices) is higher.
For example, if you see a fish in the river and want to touch it, be sure that
you are exactly above him (and not laterally positioned) because otherwise
what you see is not actually there where you see it, it is a “displaced”
image of the fish produced by the difference in the refractive indices of air
and water. The “displaced” imaged is due to the refraction angle which is always different from the
incidence angle (see fig. 6). If you see a fish while looking through your petrographic microscope,
it‟s probably time to take a rest.
The angle of refraction (θr = angle of deviation from the incident direction) always depends on the
refractive index (n). As nm gets higher, the angle of refraction will also get higher (as the light is
“deflected” inside of the material). Therefore, given that n is related to cm, instead of measuring the
velocity of light in the material (which is not an easy task), we can measure the angle of refraction
and find the cm and n. Using Snell’s Law we have:
nair sinθi = nm sinθr
After measuring θi and θr, then:
nm = nair x sinθi / sin θr
The same is proceed for any two environments with different refractive indexes, ni and nr.
If ni < nr, light is going to be deflected towards the plane normal (┴) to the boundary on entering the
refracting medium. If ni > nr, light is going to be deflected away from the plane normal (┴) to the
boundary.
Note: if two materials in contact with one another have identical refractive indices, the optical
boundary (meaning the sharpness of the boundary, and not, for example, a colour difference)
between them is not observable. As the difference between the two refractive indexes gets greater,
the boundary between the two materials is sharper and appears to get “thicker”.
3.3.2. Important things to know about the refraction taking place in minerals
1. The light which enters the mineral is refracted (slowed down) according to the density of the
mineral (so also therefore according to the refractive index).
2. Light entering an isotropic media (glass or cubic minerals) produces a double refraction, such that
the incident light is separated into two components, or rays. Both of the rays are polarized. One ray
continues in the direction of incidence, and it is called the ordinary ray (εo); the other ray is
refracted, and it is called the extraordinary ray (εe). These rays display a special characteristic: the
polarization plane of the ordinary ray is always perpendicular to the polarization plane of the
extraordinary ray (fig. 7)! This is due to the nature of any electromagnetic wave, which has a
magnetic vector perpendicular to its electric vector. Since the refractive index is the same in any
direction in an isotropic material, the two rays travel with the same speed and when they exit the
mineral, there will be no delay between them. Therefore we can say that there is no retardation (Δ).
The term “retardation” comes from the French word “retarder” meaning “to delay”). Because the
retardation is zero, the isotropic materials are called “monorefringent” (because the refractive index
corresponding to the extraordinary ray is identical to the refractive index corresponding to the
ordinary ray; i.e., there is only one R.I. involved).
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Figure 7: Two plane polarized rays: the polarization planes are perpendicular to each other
3. The minerals with medium symmetry will also produce a double refraction, where the incident
light splits into an ordinary ray and an extraordinary ray, as in the isotropic media. However, since
the refractive index varies with orientation in anisotropic minerals, the extraordinary ray will also be
slowed down in comparison to the ordinary ray (Fig. 8b). In this case, the retardation (Δ) is different
from (greater than) zero. We call these minerals birefringent. The value of (Δ) should be directly
related to the difference between the refractive indices along the direction of the ordinary ray (with
the lowest refractive index, called nα) and that of the extraordinary ray (representing the highest
refractive index direction, called nγ). So, the retardation is therefore proportional to (nγ-nα), which is
known as the birefringence. The minerals with medium symmetry are called uniaxial, where the
main (A3, A4 or A6) symmetry axis of the lattice (known as the “c axis”) is always in the direction
of (i.e., parallel to) either nγ or nα.
4. The minerals of inferior symmetry produce one ordinary ray and two extraordinary rays (Fig. 8c),
all of them polarized (the three polarization planes being perpendicular to each other). Each of these
three rays corresponds to three different refractive indexes: the lowest one is nα and it corresponds to
the direction of the ordinary ray, the intermediate refractive index nβ corresponds to the least delayed
extraordinary ray, and nγ corresponds to the most delayed extraordinary ray. The minerals with
inferior symmetry are called biaxial (see explanations for the indicatrix and the optic axis). For the
orthorhombic minerals, the c, b and a axes are parallel to nγ, nβ and nα. For monoclinic crystals a
maximum of two of the crystallographic axis can be parallel to two of the nγ, nβ or nα directions. For
triclinic crystals, a maximum of one of their crystallographic axes can be parallel (or not) to any of
the nγ, nβ or nα directions (remember that for triclinic crystals the angles between the crystallographic
axis are α≠β≠γ≠90°, but nγ, nβ and nα are always mutually perpendicular).
Figure 8: Double refraction in minerals: a) in isotropic minerals or materials (nγ=nα); b) in
anisotropic uniaxial minerals (nγ>nα); c) in anisotropic biaxial minerals (nγ>nβ>nα)
O E O E O E2
E1
nα nγ=nα nα
nγ
nα
nγ nβ
a b c
GLC 201 - Introduction to Optical Mineralogy
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5. If the incident light is perpendicular to the surface of the mineral, according to Snell‟s Law, the
ordinary ray should then be also perpendicular to the surface of the mineral.
3.4. Transmitted light
The light that remains after some fractions of it have been reflected or absorbed then exits the
mineral. This is called transmitted light, and it has always a lower intensity than did the original
incident light. The ordinary and extraordinary ray(s) also recombine as they emerge from the crystal,
and since these rays are polarized, their recombined product is therefore also polarized (as either two
or three planes of polarization, perpendicular one to each other). Note that since light is slowed down
when passing through a material due to the refractive index contrast, and also part of the light is
absorbed, the thickness of the medium therefore affects the transmitted light. If the material is thick,
more of the energy of the light will be absorbed, and less light will exit the material. For example, a
thin glass is transparent to light but the same glass at 10 m thickness will probably not let light pass
through it. If a material (such as a mineral) has a high refractive index compared to air, it is likely to
be transparent to light only in thin section. When it is, such as in hand specimen, the mineral will
generally not allow light to be transmitted through it (although some minerals can be translucent in
hand specimen, allowing some light through).
The transmitted light intensity is related to the absorption, so measuring the intensity (energy) of the
transmitted light allows us to calculate the absorption (providing the principles of absorption
spectroscopy, infrared spectroscopy, etc.). However, since the transmitted light intensity is also
dependent upon the mineral thickness, slices of materials (known as thin sections) should be both
thin (for enhanced light transmission) and consistently the same thickness (or thinness). By
convention, mineral thin sections are made at a standard thickness of 30 microns.
3.4.1. Thin sections for optical studies in transmitted light Minerals are the constituents of rocks, and usually a rock is composed of several mineral species. In
order to study minerals we need to cut a slice of the rock, grind and polish a flat surface of it down to
30 microns thick, and glue it, using a polymerized resin, onto a glass slide (fig. 9). The refractive
index of the resin must be known, in order to estimate correctly the (unknown) refractive indexes of
minerals in thin sections (usually resin is 1.542 if the resin is Canada Balsam, as was traditionally
used, or around 1.54-1.55 if other resins are used, such as araldite). A cover slip is usually glued on
top of the thin section (with the same resin) in order to protect the sample from „weathering‟ but also
to have the same (known) refractive index below and above the sample.
Figure 9: Profile through a thin section
The optical methods normally used do not measure the intensity of the transmitted light, but instead
use this light to provide information about the optical behaviour of minerals. The microscopes using
transmitted light are called petrographic microscopes and they are used for studying the transparent
minerals (remember that for study of the opaque minerals, which do not transmit light, we would use
the chalcographic, or reflected light, microscopes).
Cover glass (<1mm; n~1.55)
Glass slide (~2 mm; n~1.55)
Synthetic resin; a few µm; n~1.55) Sample (~30 µm; n variable / unknown)
Synthetic resin; a few µm; n~1.55)
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4. VECTORIAL AND CONTINUOUS CHARACTER OF REFRACTION
Refraction is a vectorial, and continuous, property. A vectorial property is a property that varies with
direction (a different n is expected in any anisotropic material for each different direction of the
incident light coming through the mineral).
A continuous property is one which varies continuously and gradually (from a minimum value to a
maximum value) within the material (such as refractive index). By contrast, a non-continuous
property would abruptly change from one point to another (such as the cleavage of a mineral).
4.1. Indicatrix
We must imagine a geometrical figure which can depicts the continuous variation of a property with
a continuous variation of direction (orientation). Let‟s take the refractive index (n) as the optical
property that we want to graphically represent. First, we can attribute a vector direction to any
possible direction within the mineral. Secondly, we can attribute to each vector a value (length)
proportional to the refractive index on each direction. If we consider an infinite number of vectors
radiating from a central point within a medium, where each vector length is proportional to n, we
can imagine a geometrical figure given by the surface connecting the tips of the vectors. This
geometrical figure is called the indicatrix, and it graphically represents the variation in refractive
indices in a crystal. The indicatrix is a method of rationalising optical phenomena, and provides a
framework whereby optical phenomena of transparent media may be interpreted, remembered and
predicted.
If n has the same value in any direction, it means that all of the vectors (radiating from a point in the
mineral) would have the same length, and consequently will describe a sphere (fig. 10a). This is the
case for the isotropic minerals: the crystal has only one RI, and is optically isotropic. This applies to
the cubic minerals (garnet, spinel, sodalite etc), where all possible sections through a cubic crystal
produce a circular indicatrix section.
If n varies continuously from a minimum value (nα) to a maximum value (nγ) the indicatrix will have
the shape of an ellipsoid (fig. 10b), where the long axis is nγ and the short axis is nα. Different types
and shapes of ellipsoids (indicatrixes) can be imagined for the anisotropic minerals (fig. 10b,c).
However, two specific sections of the indicatrix are important for making the connection to the
symmetry of the mineral: a) the section that contains the maximum possible values of nγ and nα
which is called section of maximum birefringence and b) the sections with a circular shape (called
the isotropic section). The perpendicular direction on such sections is called optical axis (or
direction of monorefringence). Three main types of indicatrixes are possible (see Fig. 10a,b,c):
GLC 201 - Introduction to Optical Mineralogy
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Figure 10: a) indicatrix for an isotropic mineral (nγ=nα); b) indicatrix for an anisotropic mineral (nγ>nα)
called uniaxial indicatrix; by convention, always the higher refractive index is written as nγ , the
minimum refractive index is nα; c) indicatrix for anisotropic minerals (nγ> nβ >nα), called biaxial
indicatrix; nβ is the intermediate refractive index, being the radius of the circular section (and
always perpendicular to the optical axis).
Isotropic indicatrix (any section of the
sphere is a circle; n=radius of the
circle (fig. 10a).
Uniaxial indicatrix (revolution/rotation ellipsoid).
the direction perpendicular
to circle section is called the optic
axis.
If the optic axis is parallel to
(contains) the maximum R.I.,
nγ, then it is a positive
uniaxial indicatrix (a rugby
ball shape, positioned for a
penalty kick).
If the optical axis is parallel to
(contains) the minimum R.I.,
nα, then it is a negative
uniaxial indicatrix (a rugby
ball being passed?).
Biaxial indicatrix If the bisectrix of the 2V angle
is parallel to nγ, then it is a
positive biaxial indicatrix
(imagine a flattened rugby
ball; an ellipsoid elongated
in one direction (nγ) and
flattened from a perpendicular
direction (nα);
If the bisectrix of the 2V angle
is parallel to nα, then it is a
negative biaxial indicatrix
(imagine a sphere flattened
from one direction (nβ) and
even more flattened from a
perpendicular direction (nα).
Figure 10 a)
Figure 10 b)
Figure 10 c)
Biaxial positive Biaxial negative
GLC 201 - Introduction to Optical Mineralogy
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Optically positive? (slightly off-centred)
and negative
4.2. Interference colours (IF); birefringence (δ)
Interference colours are produced when the mineral is placed between two polarisers, having the
polarization planes orientated mutually perpendicular (i.e, perpendicular to one another). By
convention, the polarizer closest to the light source is called “the polarizer”, and the other one is
called “the analyzer”.
-The polarizer has a E-W privileged direction producing E-W oscillating white light waves.
-The analyser is consists of a polariser with a N-S privileged direction.
-The sample (thin section of a mineral) is in-between the polarizer and analyzer and can be
rotated to change its orientation (the nγ and nα orientation in relation to the polarization planes
of polarizer and analyzer) in a petrographic microscope.
Remember that:
-Transparent minerals are, in effect, polarisers with TWO privileged directions
-These privileged directions are ALWAYS mutually perpendicular
-Their orientation depends upon crystal lattice properties
-A polarised (E-W) light wave is split into two waves which can pass through the crystal along
its privileged directions
-The two waves pass through at different velocities, so that there is a faster wave with a lower
RI (nα) and a slower one with a higher RI (nγ)
Let us follow the behaviour of polarized light on its way from the polarizer through the sample and
on to the analyzer:
The EW-polarized white light leaves the polarizer with the normal speed of light in air (nair~1) and
hits the sample. Here (Fig. 11) the light is refracted and one ordinary (fast) ray and one extraordinary
(slow) ray (or two, if the crystal is biaxial) are created.
The vibration planes of the rays produced will always be mutual perpendicular. These polarized rays
will exit the sample with the speed of light in air and be recombined, but the extraordinary ray(s)
will have been delayed by the sample; therefore there will now be a difference in the „phase‟ of their
wavelengths, proportional to the retardation (the delay of the extraordinary –or slow) ray. This
difference in phase (also called path difference or retardation, Δ or R) is manifested as a wavelength
difference (in the range of microns to hundred of microns).
GLC 201 - Introduction to Optical Mineralogy
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Figure 11: Maximum interference colours obtained at 45° between nγ or/and nα and the N-S (and E-W)
polarization planes.
When hitting the analyzer, the mutually perpendicular rays coming from the sample will arrive at the
N-S “gate” of the analyzer. What will be the outcome? It will depend on the orientation of the
sample and its crystal lattice (and hence the orientation of the mutual perpendicular rays coming
from the sample). If nγ or nα comes out along the N-S plane (or the W-E plane, since nγ and nα are
mutually perpendicular), the two rays will be eliminated by the analyzer, such that the nγ and nα of
the sample will be compensated by the nγ and nα of the analyzer (Fig. 12, right). The result will be a
dark image (black or dark gray). This situation (or orientation) is called extinction (as the light has
become switched off; “extinct” comes from Latin extinct meaning „switched off, terminated,
ended‟).
Figure 12: Amplification (giving the increase of the intensity,) and
extinction (mutually compensation/annihilation of the intensity of the
light).
When the stage is rotated from this position, the grain will start to increase its light intensity and
become coloured. The colours are the result of interference (adding and/or subtracting wavelengths)
between the nγ or nα rays of the sample, which are forced to pass through the N-S plane only. The
AAmmpplliiffiiccaattiioonn EExxttiinnccttiioonn
W3 =0
E-W oscillation white light leaves the polariser
with normal speed of light (n=1)
The E-W wave hits the crystal and gets split up
into the faster nα wave and the slower nγ wave
Both waves pass through the crystal at different
velocity; nγ is getting delayed
Waves leave the crystal with a path difference:
the retardation Δ (or R) [nm]
The privileged directions nγ and nα of the crystal
at 45° to polariser and analyser
nγ and nα waves both propagate at the same velocity
(n=1) and hit the analyser at diagonal angles
The waves are forced into N-S direction;
because of Δ interference occurs interference colour!
polarizer
analyzer
mineral
GLC 201 - Introduction to Optical Mineralogy
19
interference colours will be at their maximum (Fig. 12, left) when nγ or nα of the sample are at
exactly 45° to the N-S plane of the analyzer (the N-S diameter of the field of view in the
microscope). In this position we observe the maximum intensity of the interference colours (IF),
called the birefringence colours (Fig. 13 - Michel Levy chart).
From the maximum interference position, continuing to rotate the stage in the same direction, the
intensity of the colours gradually decreases til we return to total extinction. After rotating the stage
for 45° from the maximum illumination position, another extinction position is obtained (i.e., the
grain becomes dark again).
When rotating the stage through 360°, all anisotropic minerals show 4 positions of extinction,
(interference = 0) one at every 90°, alternating with 4 positions of maximum interference colours
(interference = maximum) also at every 90° from one another. Between each position of extinction
and the following position of maximum interference there are 45° of rotation.
Note that:
1) There is no interference colour produced without the analyser!
2) The interference colour depends on the retardation Δ (i.e., the distance between nα and nγ when
leaving the crystal).
3) Only waves propagating in the same plane can interfere!
4) The maximum brightness of the crystal in the microscope if nγ and nα are at 45° to polariser and
analyser! At this position we observe the maximum birefringence.
Birefringence (δ) is the difference between nγ and nα , so δ = nγ - nα
nγ - nα = Retardation (Δ) x Thickness of the crystal (d)
δ = Δ / d and (Δ) correlates with the interference colour (IF)
Graphically, δ is a straight line, in a chart (Michel-Levy) where Δ and d are the x and y axes,
respectively. The line crosses the origin of graph (see the Interference Colour Chart, also known as
the birefringence chart or Michel LLéévvyy cchhaarrtt)).. The Michel-Levy table contains 4 orders of colours
(each order has a total wavelength of 550 nm). The orders are separated by a violet colour and, as we
can see in the chart (fig.13), as we go to higher retardation (Δ), the colours become more pale and
mixed, sometimes difficult to describe.
Figure 13: the Michel LLéévvyy cchhaarrtt
,, ,, dd,, IIFF ccoolloouurr:: aallll oonn tthhee MMiicchheell LLéévvyy cchhaarrtt!!
1st Order 2nd Order 3rd Order , IF
d
= 0.026
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5. PETROGRAPHIC MICROSCOPE
The petrographic microscope is used to analyze the properties of the transparent minerals. The main
components of petrographic microscopes are shown in Fig. 14. The light source (1) is on the bottom
of the microscope, under the blue filter. The blue filter is needed for absorbing the strong yellow-
orange component of the light emitted by the electric bulb, in order to produce normal-looking
white-coloured light (and therefore „normal‟ interference colours). The 2nd
diaphragm is used for
reducing the intensity of light (useful sometimes, for evaluating properties such as relief and
chagrin). Similar effects can also be obtained by using the light intensity control dial (2).
Let‟s once again follow the light on its way up to our eye (along the optical axis of the microscope);
The white light coming up from the blue filter passes through a group of other diaphragms and
apertures (13) also used for adjusting the light intensity and homogeneity. On its way up, the light
passes through the polarizer (3), which is mounted so that the polarization plane is East-West in the
image we see through the eye-piece, or ocular (fig. 15). Above the polarizer is mounted a mobile
lens (convergent lens, 4). In normal use, this lens is kept out of the way of the light path. Above the
convergent lens there is a rotating plate (11), which is the stage, and is graduated (360°) so that
angular measurements can be made. In the middle of the plate there is a round hole where the
polarized light goes through. Here we put the thin section (sample), so that the light from below can
pass up through the sample. The polarized light will interact with the sample and the resulted light
will continue upwards. To magnify the light transmitted through the sample, an objective (or a set of
objectives) is normally used (5), having different powers of magnification (usually 2.5x, 6.3x, and
10x, 20x, 40x or more). Up to 4 objectives are mounted on a typical nosepiece (6). Above the
objective, the analyzer (10) is mounted. It also polarizes light, and is mounted so that its plane of
polarization is perpendicular to the polarization plane of the polarizer (i.e., the analyzer has the
polarization plane mounted N-S -fig. 15). The analyzer is mobile, so it can be pushed in (or pulled
out) so that observations can be made either with or without the analyzer. The final magnification of
the image is provided by the ocular (9), which typically provides 10x additional magnification. The
total power of magnification of the microscope is equal to the power of magnification of the
particular objective in use, multiplied by the power of magnification of the ocular; these values are
written on both the objective and the ocular. For some specific determinations, the lamda plate (λ-
plate = gypsum plate, or λ/4-plate = muscovite plate; 7) and the Bertrand lens (8) can be used. In
normal use, these pieces are all kept out of the light path. The focused image through the
microscope is achieved by using the focus knobs (12) (one large, for coarse focusing, and one
smaller, for fine focus).
Looking through the microscope without any thin section present, and having all the mobile
components (the convergent lens, analyser, lambda plate, and Bertrand lens) kept out of the light
path, we should see a white field, homogenously lit (we see the white light, polarized by the
polarizer). This microscope mode is known as plane polarized light = PPL.
Introducing only the analyser, we get the microscope mode for crossed polarized light (CPL, or
colloquially XPL). With no sample, the observed field in the microscope should now be dark (all
light eliminated by the crossed polariser and analyser). Why? The analyser lets pass through only the
light vibrating in the N-S plane (the analyzer polarization plane). However, it does not receive any
vibrations in that plane since the incoming light from the polarizer is vibrating only in the W-E
plane. This is how we confirm the 90° angle between the polarization planes of the two nicols, the
polarizer and the analyzer (since the analyser can be rotated, this need not always be the case).
Both the above modes (PPL and XPL/CPL) use plane polarized light which is transmitted through
the mineral in mutual perpendicular planes. For this reason, the study of minerals using either of
these modes, or setups, is called orthoscopic study.
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In contrast, introducing the convergent lens and the Bertrand lens to the XPL mode, we get the
conoscopic mode (for identifying the optical symmetry of minerals using convergent polarized
light). The study of minerals using this mode is called conoscopic study.
The λ-plate (gips), as well as the λ/4 plate (muscovite) are called compensators. They can be used for
certain observations in both orthoscopic and/or conoscopic modes.
Figure 14: Petrographic microscope: main components
Figure 15: N-S and E-W direction of the polarization planes as seen at the microscope; polarizer has the
polarization plane oriented E-W and the analyzer has the polarization plane mounted N-S.
9) Ocular (eyepiece)
10) Analyser
11) Rotating stage
12) Focus
13) Diaphragm / aperture
8) Bertrand lens
7) Lambda (λ-) plate
(accessory plate)
5) Objective lens
4) Condenser lens
1) Light source & filter
2nd
diaphragm
2) Light intensity control dial
3) Polariser
Petrographic microscope
6) Objective nosepiece
N
S
W E
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6. MINERAL IDENTIFICATION USING THE PETROGRAPHIC MICROSCOPE
6.1. Orthoscopic study
-Condenser lens and the Bertrand lens are OUT!-
6.1.1. Observations using plane polarized light (PPL) mode
-Analyser is OUT!-
The observations typically made in PPL are transparency, shape/habit/size, colour,
pleochroism, cleavage, relief (Becke line, Chagrin), and inclusions/alterations.
a) Transparency
A mineral is opaque if it appears totally black and stays black regardless of the rotation of the
stage). The light cannot pass through the mineral, at all. Since the petrographic microscope is
designed for studying the transparent minerals only, we cannot get diagnostic reflected light
information here. However, we can observe shape, habit, and transparent inclusions, where
present. Usually the opaque minerals are either sulphides (e.g. pyrite, chalcopyrite, etc.), oxides
(e.g. magnetite, hematite, or ilmenite), or graphite.
If the mineral appears anything other than totally black (no matter what other colour is
observed!) it means that the light passes through the mineral, so the mineral is transparent.
b) Shape, habit, size
Shape: euhedral (or, if metamorphic, we call it idiomorphic), subhedral (hypidiomorphic)
or anhedral (xenomorphic);
Habit: isometric, prismatic, tabular, sheeted, etc.
Size: estimated in mm, based on the field of view determined from the magnification by the
objective and ocular lenses.
Looking at the mineral boundaries, we can see the shape of the analyzed grain. Remember that
the mineral as seen in thin sections is just a section through the mineral, which can have
different orientations related to the 3-dimensional (3-D) shape of the grain. In order to estimate
the habit, several grains of the same mineral should be examined. The shape can be regular
(geometrical features such as squares, rectangles, triangles, or combinations of these); different
regular sections of grains seen in the same thin section suggest a euhedral grain (all grain
boundaries are linear crystallographic faces with predictable interfacial angles). If the grain
shows irregular boundaries only, the grain is anhedral (xenomorphic). If the grain has both
regular and irregular boundaries, it is subhedral (hypidiomorphic) - see tables below. The
shape and size of the grains are related to the conditions of growth (crystallization). When
crystals grow, depending on how favourable the conditions are, they may develop all of their
crystal faces, or none of them at all (no preferred faces, so crystal grows as a shapeless blob =
anhedral growth), or anything in between.
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Crystal habits
Degree of crystal development Igneous minerals
(crystallised from a
liquid)
Metamorphic minerals
(crystallised by solid state
diffusion)
shaded grains as
examples
grain has most/all well-developed
crystal faces (i.e., linear grain
boundaries whose orientations are
controlled by the crystallography
of the particular mineral)
euhedral
(idiomorphic)
idioblastic
grain has some well-developed
crystal faces
subhedral
(subidiomorphic)
subidioblastic
(hypidioblastic)
grain has no well-developed
crystal faces (its boundaries are
defined by the shapes of the
adjacent crystals)
anhedral
(allotriomorphic)
xenoblastic
Straight, or linear, grain boundaries can occur by a variety of mechanisms:
Well-developed crystal faces;
grain should show the same or
similar shape throughout the rock,
and the same relationship to
cleavages (where present); the
shape is controlled by crystal
symmetry of the mineral.
Linear boundaries can be found in
interstitial grains adjacent to euhedral
or subhedral grains; the interstitial
grain is anhedral, and its shape is
controlled by its neighbours (and is
therefore not consistent throughout
the rock, and not consistent with
respect to cleavages, etc.).
Recrystallisation (solid-state
modification of grains to
accommodate energy from heating
or deformation) can result in linear
grain boundaries, but these will not
reflect the crystal symmetry of the
mineral, and will usually not
produce consistent mineral shapes
euhedral
interstitial (anhedral)
recrystallised (anhedral)
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More common crystal/grain habits
Name Description Shape
equant equidimensional (i.e., a ~ b ~ c)
columnar elongate in one direction, “blocky”, with
other two dimensions similar (i.e., c > a = b)
tabular rectangular, but flat (“table-like”) (i.e., c > a
> b).
lath-shaped Thin, narrow and flat (so a variant of
tabular, but specifically a narrow type).
(Actual laths are strips of wood).
fibrous elongate in one direction, tapering
acicular elongate and “pointy”, needle-like
prismatic elongated, with pyramidal pointed
terminations
sheaf radiating collection of elongate grains
rosette radiating collection of elongate grains
skeletal the framework of a mineral; partially
internally replaced
c) Cleavage
Cleavages are planar surfaces of low cohesion produced by weaker atom bonds across them.
They are visible when the cleavage is more or less vertical in the thin section. Cleavages seen
in thin sections are linear expressions of the intersection of particular planes of crystal faces
with the cut surface of the thin section; these faces have low surface energies and are therefore
favoured to “express themselves” in the crystal as preferred planes of growth and preferred
planes of splitting of the crystal. Not all faces have equal surface energies; some minerals may
have three “good” cleavages (e.g., calcite), some have a “perfect” cleavage (e.g., micas), and
some may have no cleavages at all (e.g., olivine, which therefore has no “preferred” planes of
GLC 201 - Introduction to Optical Mineralogy
26
splitting, and gets fractured, instead). All cleavage planes of a mineral must match that
mineral's symmetry. The same mineral will always have the same cleavage.
Cleavage is said to be basal when it occurs perpendicular to the major axis of the mineral, and
prismatic when it occurs parallel to the major axis. Multiple cleavages that produce geometric
polygons are referred to using the name of the geometric polygon, such as octahedral cleavage
in the mineral fluorite, cubic cleavage in the mineral halite, or rhombohedral cleavage in
calcite.
Cleavage, being related to structure, can be important in the correct identification of a mineral's
symmetry. Remember, cleavage must obey the symmetry of the mineral and must be parallel to
a possible crystal face. A mineral of the isometric symmetry class can either have no cleavage
or at least three directions of identical cleavage that form a closed three-dimensional polygon.
A mineral of a uniaxial class (trigonal, tetragonal or hexagonal) will potentially have a
cleavage perpendicular to the dominant axis and/or prismatic cleavage of either 3, 4 or 6
directions respectively, running parallel to the axis. Other cleavage directions are possible, but
will always be controlled by the symmetry of the crystal (Fig. 16). A biaxial mineral, those
belonging to orthorhombic, monoclinic or triclinic classes, cannot have more than two
identical cleavage directions.
Figure 16: Mineral cleavage: left: enstatite, with prismatic cleavage (parallel to the prismatic
faces) and two basal cleavages. Right: biotite, with one perfect basal cleavage.
The cleavage (quality and number of different cleavage planes) is diagnostic of some mineral
species. From the shape of the observed grain in thin section and the quality and orientation of
the cleavage(s), we can have an idea of the orientation of the section cut through the 3-D grain
morphology. In figure 17 we can see basal sections of amphibole (left) and pyroxene (right),
displaying two characteristic sets of cleavages.
a
ab
b
cc
d
d
Figure 17: Basal face with basal cleavage (two intersecting cleavages). Left: amphibole, where the angle
between the two cleavages is ~ 60° or 120°. Right: pyroxene, where the angle between the two cleavages is ~ 90°;
Enstatite (Opx) Biotite
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A crystal with one perfect
basal cleavage, such as a
phyllosilicate, could be
depicted as shown below:
When seen in a cross-section
cut parallel to the c-axis, we
would see this system of
cleavages represented as a set
of parallel lines of ~equal
spacing: planes or faces.
Although the mineral has 4
sets of faces (labelled a to d),
only 2 of them form
prominent cleavages (b and
d). In thin section, we might
see 2 cleavages at ~90° angles
to one another, or we might
see only one of them (with
the other poorly developed, or
absent), or none at all,
depending on how the crystal
has grown, and how it has
been cut, relative to the
orientations of these cleavage
c-axis
c-axis
basal cleavage
a
ab
b
cc
d
d
The quality of the cleavage is estimated observing the density, continuity and width of the
cleavage lines (which are always parallel lines) in thin section (Fig. 18). Remember, this
estimation should be done on grains cut almost perpendicular to the cleavages. The quality of
cleavage is described as perfect, imperfect, good, distinct, indistinct, poor, or absent. The
quality decreases from perfect (dense, almost continue and thin lines of cleavage) to weak
cleavage (few, disperse segments of thicker lines) to absent (no cleavage, different curved
and/or broken thick lines). For example:
Perfect cleavage: micas, all phyllosilicates;
Good cleavage: feldspars, pyroxenes, amphiboles;
Weak cleavage: apatite, sodalite, olivine;
Absent: quartz
Figure 18: Left: one good cleavage in K-feldspar (kfs) and absent cleavage in garnet (grt); Right: good cleavage
(prismatic) in pyroxenes (note that the centre of the image shows a whole in the thin section).
kfs
grt
px
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d) Colour (absorption colour)
The mineral is colourless if it appears white (we see the white light source!). If any other
colour is observed, the mineral is coloured (and the colour can be described). The observed
colour is the absorption colour (absorption of a part of the white spectrum). The observed
colour should be described as colour, nuances and intensity. For example: pale yellowish
brown, bluish light grey, etc. If when rotating the stage, the colour changes, then the mineral
has pleochroism (see below) and the range of colours should be described, rather than a single
colour.
e) Pleochroism
The term “pleochroism” comes from the Greek: pleos – many; chromos – colours. A mineral
shows pleochroism when the absorption colour (colour or nuance, or/and intensity) changes
when the stage is rotated. It means that absorption of specific light wavelengths depends on the
crystal orientation. This happens when the mineral is anisotropic. All anisotropic coloured
minerals have pleochroism. However, the intensity of pleochroism (the changing of colour) can
be different (from strong to weak). Common examples shown below include strong
pleochroism of biotite and hornblende (Fig. 19 and 20). We describe the pleochroism as ther
strong, moderate or weak, and try to describe the colour variation from the lightest to the
darkest colour/nuance (e.g. pleochroism from light yellowish green to dark bluish green).
Figure 19: Strong pleochroism of biotite, as stage is rotated 90°.
Figure 20: Strong pleochroism of hornblende, at 90° of rotation.
f) Relief
Refractive index (RI, n) is a measure of the speed of light in material relatively to the speed of
light in vacuum. The higher the RI, the slower the light propagation in the mineral.
“Relief” refers to the relative difference in RI between neighbouring crystals.
Examine the grain boundaries for the relief of a crystal (Fig. 21, 22):
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Figure 21: Crystals with higher RI (n) seem embossed compared to low-RI minerals or resin; Here:
Clinopyroxene (Cpx) has a high relief compared to the resin but does not have a high relief
compared to other Cpx crystals.
Figure 22: Left: low relief of quartz (it can hardly be distinguished from the resin because the
refractive indexes of quartz and resin are very similar). Right: High relief of garnet comparing
to the resin. It boundary appears extremely distinct and thick.
Becke line; Becke method for estimating the relief
The Becke line is a narrow bright line along grain boundaries caused by light refraction and
scattering along the crystal surface. When lowering the rotating stage (using the fine focus), the
Becke line migrates into the phase of higher RI (Fig. 23). This is called Becke method and it is
a very sensitive method (determines n to ± ~0.02).
The microscope mode for the Becke line test:
• PPL setup mode
• High power objective lens (40x or higher)
• Close the diaphragm for better contrast
Resin (hole) n=1.55
Cpx n~1.7
Cover glass (<1mm; n~1.55)
Glass slide (~2 mm; n~1.55)
Synthetic resin; a few µm; n~1.55)
Sample (~30 µm; n variable)
n=1.55
n=1.55
n=1.55
n=1.7
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Figure 23: Becke line observed at the boundary between garnet (Grt) and quartz-feldpar (Qtz/Fsp)
aggregate. The Becke line moves into the garnet (into the mineral with higher refractive index)
when slightly defocusing the image as the stage is lowered. Note also fine bright lines (also Becke lines) between the quartz and feldspar grains.
Although relief is most useful as a comparative term (some minerals show higher relief than
others), the relief can be positive or negative compared to a reference material of fixed and
known RI. This reference standard is the resin, which has a known refractive index (n = 1.54-
1.55). All minerals with relief higher than the resin have positive relief and all minerals with
lower relief than the resin, have negative relief. In order to determine if the relief is positive or
negative, we need therefore to directly compare the mineral with the resin (using the Becke
method). We should therefore look in the thin section where the unknown mineral is in direct
contact with the resin (usually look at the margin of the thin section, or look for holes in the
thin sections, if any).
Twinkling (relief changing)
This property is specific (diagnostic) for carbonates (calcite, dolomite, magnesite, etc). When
a mineral has nγ much higher than ~1.54 (nresin) and nα lower than ~1.54, it will show a
changing of relief (from positive to negative) when rotating the stage (Becke line moves from
one side to the other at the mineral boundaries, cleavage lines, or micro-fractures. This
movement of the Becke line when rotating the stage (and NOT when lowering the stage!)
produces a variation of the white light intensity (boundary and cleavages turn from fine to
thicker lines) and the mineral appears to have “pleochroism” (from colourless to light gray).
However, the phenomenon is not actually related to absorption, but to the high difference
between nγ and nα.
Chagrin (degree of rough appearance of the mineral surfaces)
Chagrin is a rarely used but an often useful term! It is produced by light refraction between the
mineral surface and the resin at the top (or bottom) of the thin section, as well as between the
mineral and very small cracks in it which are filled with resins. Fine, irregular, dense Becke
lines will form along micro-cracks, giving the image of a rough, irregular surface. The chagrin
is most obvious in minerals with strong relief and with absent or weak cleavages (where micro-
cracks are widespread in the volume of the grain). Olivine, apatite, sphene and garnet show
characteristic chagrin (all have high relief and absent or weak cleavage!). However, the chagrin
can be positive (olivine, apatite, sphene, garnet) or negative (sodalite, fluorite), depending on
the relief of the mineral (Fig. 24, 25).
Focused Stage slightly lower
Grt
Qtz/Fsp
Becke line
moves into Grt
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Figure 24: Positive and negative chagrin ordered by relief (relief ~zero is albite ~ resin).
Figure 25: Olivine (Ol): strong positive relief, weak or absent cleavage, strong positive chagrin
(roughness surface); clinopyroxene (Cpx): positive relief, good cleavage, weaker chagrin. Is
the grain in the middle of the image olivine or clinopyroxene? Why?
g) Inclusions, alterations
Minerals can have inclusions, which can be solid (other finer-grained minerals) or fluid (liquid
and/or gas) inclusions. Choose a higher magnification objective and describe the inclusions, if
present (transparent or opaque, colourless or coloured, relief, etc.).
If altered, other minerals (alteration minerals) can appear at the margin of the analyzed
mineral, or along its cleavages or cracks. Describe the alteration mineral separately using a
higher magnification objective.
Ol
Ol
Cpx
Cpx
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6.1.2. Observations using crossed polarized light (XPL) mode
-Analyser is IN!-
The observations in crossed nicols are: isotropy/anisotropy, extinction angle, birefringence colour,
twinning/zoning, finding the orientation of nγ and nα , optical elongation, and specific textures.
a) Isotropy/anisotropy
A transparent isotropic mineral is dark gray or black in crossed nicols, and the colour doesn‟t
change during rotation of the stage (there are no interference colours, since nγ=nα). NOTE: do not
confuse an isotropic mineral (or an isotropic section through an anisotropic mineral) with an
opaque mineral! An opaque mineral is totally black whether the analyser is in OR out, while the
transparent, isotropic mineral is not opaque!
If the mineral is anisotropic, it shows 4 positions of extinction and 4 positions of maximum
interference when rotating the stage.
b) Extinction angle
The extinction angle is the angle between one vibration direction of the mineral (nγ or nα) and the
N-S polarization plane of the analyzer (the N-S direction of the microscopic view).
The extinction can be parallel, symmetric or oblique.
In order to measure the extinction angle, we need to identify crystallographic features of the
mineral, such as cleavage planes, crystallographic faces or twinning planes (crystallographically-
controlled orientation). These features serve as reference directions. We rotate the stage to set the
crystallographic reference (e.g. an elongated face parallel to a cleavage, as shown in Fig. 26a)
parallel to the N-S (vertical) or E-W (horizontal) direction of the microscopic field (ensuring that
the cleavage lines are more or less either vertical or horizontal). Is the crystal in this position at
maximum extinction? If yes, it means that the angle of extinction is zero (or 90°), and the
extinction is called parallel extinction, meaning that the nγ or nα, (we don‟t know yet at this point
which one is which) is parallel to the N-S polarization plane. If in the vertical position the crystal is
not in maximum extinction but it shows an interference color, it means that the angle between nγ or
nα is different from zero (or 90°). We should rotate (incline) the crystal in order to find its
extinction position. It means that the crystal has an inclined extinction.
a) Parallel extinction: the cleavage is in N-S or E-W orientation when the crystal is
in extinction position
b) Oblique extinction: the cleavage is not // N-S or E-W when the crystal is in
extinction position. The extinction angle is usually <45%
c) Symmetrical extinction: When the nγ and nγ are parallel to the bisectrix of two
identical faces.
-Requires ALWAYS two (2!) equivalent crystallographic surfaces (cleavages, crystal
faces). -A crystal shows symmetrical extinction if both cleavages/crystal faces show
the same angle to the crosshairs at extinction.
Figure 26: a) Parallel extinction; b) Oblique extinction; c) symmetrical extinction.
It is as simple as that: what it is the position of the crystal when it is in extinction, compared to the
N-S plane of the microscopic view? Is it parallel to the N-S plane? If yes, the extinction is parallel
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(angle of extinction is zero), if not, the extinction is oblique (Fig. 26b). The angle of extinction will
be the angle we have to rotate the stage in order to get the nearest extinction position. Some
specific sections in minerals (e.g. basal faces) show symmetrical extinction (Fig. 26c).
Determination of the extinction angle
Move the stage so that the crystallographic reference (e.g. the crystal face, cleavage, etc.) is
aligned N-S (Fig.27, left). Record the position of the stage. Then rotate the stage (in the sense
where the crystal arrives faster in the extinction position) until the crystal has its maximum
extinction (remember that there are four positions of extinction at each 90°). In this second
position, when the crystal is extinct, record the stage position again (Fig. 27, right). The
difference between the two readings is the extinction angle.
Fig. 27: Extinction angle = angle between Reading 1 and Reading 2.
The extinction angle is characteristic for each anisotropic mineral. However, it can differ even
within the same mineral group (i.e., olivines, pyroxenes, etc.), because of compositional
differences caused by solid solution substitutions that also influence the mineral‟s crystal structure.
For example, see the variations in extinction angles in the pyroxene group (Fig. 28), below.
Figure 28: Variation of the extinction angle within the pyroxene group (Saggerson, p. 24).
Reading 1 Reading 2
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c) Birefringence
In order to describe the birefringence we should be able to: 1) describe the colour of
interference (also called colour of birefringence) and 2) find the value of the birefringence.
Interference colour (birefringence colour)
First, we need find the crystals of our particular unknown mineral with the highest interference
colours, using both PPL and XPL settings to identify grains of the same mineral (same relief,
absorption colour, pleochroism, cleavage, etc.). Then, we describe birefringence by comparing
the interference colours observed with the microscope with those within the Michel-Levy chart
(e.g. first order yellow). But how do we know it is first order yellow (as distinct from the other
order yellows)? Colours in the Michel-Levy chart are repeated in each order. ****. Remember
that although the colours usually repeat in each order, they are pale and diffuse as the order
gets higher (e.g. compare the yellow from each order). We have two methods to establish the
order of the interference colour: a) using the isochromatic lines (called isochromates, or
isochromes) and b) using the λ-plate.
a) using isochromates
The margin of grains are usually oblique to the light path, and because of this, the polarized
light is dispersed (as in the dispersion in Newton‟s prism; Fig. 29). A white light ray entering
an optically denser medium and leaving by a plane inclined to that of entry will have its
colours separated, analyzed, spread out. This is because each colour has a different wavelength
and so is differently slowed down (refracted) by the medium. Red (longest wavelength) is
slowed the least and violet (shortest wavelength) the most.
Figure 29: Dispersion of light at an oblique boundary of a refringent material.
Observing the dispersion of the interference colour of the mineral at oblique grain boundaries
allows us to estimate the order of birefringence by counting the number of violet colour bands
and adding 1. For instance, in Fig. 30a we observe a plagioclase with a gray colour of
birefringence (no violet isochromates at its boundary). The order of colour is therefore 0+1=1.
In Fig. 30b we have a muscovite. The bluish green colour of birefringence is in the second
order (we observe one violet isochromate, so the order is 1+1=2). In Fig. 30c we see calcite
with a diffuse, white-greyish colour of birefringence. At its rim, we notice 3 violet
isochromates, so the order of birefringence is 3+1=4.
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Figure 30a-c: Identifying the order of the interference colour using the isochromates (see text).
Finding the value of birefringence (δ)
Knowing the thickness of the thin section “d” (which is standard, 30 microns) and observing
the birefringence colours in Michel-Levy chart, we can graphically obtain the value of
birefringence (values written at the top and right of the Michel-Levy chart) by intersecting the
band of the observed colours with the “d” value horizontal line (Fig. 31). From that point,
going up right on the chart following the line δ=Δ / d, we get the value of δ (birefringence). For
example, the maximum interference colour of quartz is first order white. We look for the
intersection of the first order white band in the Michel-Levy table with the horizontal (d) line
corresponding to 30 microns thickness. From that point, going up (interpolating between the
radiating lines), we get a birefringence value of 0.009, as written at the top of the chart.
Looking in the same sample, we will also find grains of quartz with lower birefringence (gray)
which means that their orientation is different (the section is not cut parallel to the optic axis,
and therefore, our view is not completely perpendicular to the optic axis).
If we want to know what maximum colour of birefringence to expect from a particular mineral
(knowing the value of δ from mineral tables), we go down from the value on the δ line until we
intersect the d line. At this intersection we see the colour of birefringence that corresponds to a
particular δ value.
IMPORTANT:
-The standard thickness of thin sections is 30 microns (the “d” horizontal line of interest is at
30 microns!)
- The Michel-Levy chart is made for maximum birefringence of minerals, only!! Do not try
to memorize a mineral using a specific unique birefringence colour. It is pointless and wrong!
Always remember that different colours can be possible for differently-cut orientations.
What does this mean? Some specific cuts of anisotropic minerals (sections perpendicular to the
optic axis, called sections of monorefringence – circular sections of the optical indicatrix)
behave isotropically. For example, apatite (calcium phosphate) has a prismatic habit,
crystallized in the hexagonal system (with medium symmetry, so it has a uniaxial indicatrix). If
the section is cut parallel to the prism faces, it will show maximum interference colours
(section parallel with the optical axis). If the cut is perpendicular to the prism, the section will
be isotropic. We can understand from here that the interference colours of one mineral
species depends on the orientation of the section cut, so that the interference colours can
a) 1st order IF colours b) Isochromates indicate
Green 2nd
order c) High order white
in calcite
a b c
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vary from isotropic (black) when the cut is perpendicular to the optic axis, up to the maximum
interference colours when the cut is parallel to the optic axis.
d) Twinning/zoning
Twinning
A twin is a symmetrical growth of two or more crystals of the same mineral. The common
plane of the twinned crystals (which is called the twinning plane) is a symmetry plane, seen in
thin section as a straight line separating two identical crystals (e.g. crystal (1) and crystal (2))
which have a symmetrical optical orientation to the twinning plane, i.e., the indicatrices of the
two twinned crystals are symmetrical to the twinning plane. This is observable by rotating the
stage (Fig. 32); when crystal (1) is in extinction, its twin crystal (2) shows interference colours.
Continuing the rotation of the stage, crystal 1 shows interference colours and crystal (2) will
enter into a position of extinction. If the section is cut perpendicular to the twinning plane, the
extinction angles of crystal (1) and crystal (2) should be identical (if the crystallographic
reference for measuring the extinction is the twinning plane!). If the section cut is not
perpendicular to the twinning plane, the extinction angles will be different. If the section is cut
parallel to the twinning plane, the twin cannot be observed at all, in the plane of the thin
section.
Figure 32: Polysynthetic twins in plagioclase; section ~ perpendicular to the twinning plane
(useful for measuring the anorthite content in plagioclase)
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((ffrroomm SSaaggggeerrssoonn ((11998833))
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If more than two crystals are twinned, having parallel twinning planes, the twinning is called
polysynthetic (sometimes also called lamellar twinning). Plagioclase commonly shows this
type of twinning, called the Albite Twin Law, with {010} as the twin plane. Such twinning is
one of the most diagnostic features of plagioclase (Fig. 33). Several laws of twinning are
possible and they can be recognized using the microscope (e.g. Polysynthetic twins after the
“albite” and “pericline” laws in plagioclase, Carlsbad twins in plagioclase or orthoclase, cyclic
twins in leucite, etc.).
Orthoclase (K-feldspar)
Plagioclase (Na-Ca-feldspar)
Two ~ perpendicular polysynthetic
twin sets
(albite-law twins perpendicular to the
pericline-law twins)
Carlsbad twinning in plagioclase
(also common in orthoclase)
Polysynthetic albite-type twins in
plagioclase
(Tartan twinning, typical of
microcline – K-feldspar)
Figure 33: Examples of twinning in feldspars.
Zoning (compositional zoning)
Compositional variation within a crystal can be shown by different interference colours (Fig.
34). Zoning is possible in minerals which consist of solid solutions, where the compositional
differences reflect variation of major element ratios: e.g. Mg/Fe, Na/Ca, etc.). Note that the
difference in composition is visible as differences in the interference colours under the
petrographic microscope only if the symmetry of the crystal is low (it is visible for inferior
symmetry minerals, rarely visible for those with medium symmetry, and never visible in high
symmetry – isometric crystals, such as garnet, which is commonly zoned, but this is not
evident in thin section).
Figure 34: Compositional zoning in amphibole (a) and twinned plagioclase (b)
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e) Orientation of nγ and nα
What we know from maximum brightness and total extinction of a mineral under the
petrographic microscope in XPL mode is that, at complete extinction the privileged directions
nα and nγ are N-S and E-W, and at maximum brightness nα and nγ are NW-SE and NE-SW
oriented. However, we don‟t know which is which!
Why do we need to find the nα and nγ of a crystal? Because it is the only way to establish the
optical elongation, which is a characteristic of any anisotropic crystal!
How do we find out which is nα and which nγ?
The microscope is designed so that the input of the λ-plate is always at 45° to the polarizer and
analyzer. Looking at the λ-plate, we can read the orientation of nγ of the plate (Fig. 35).
Figure 35: λ-plate, showing the orientation of nγ of the plate. In
this case, nγ is perpendicular to the direction of input, meaning
that it is at 45° to the N-S and E-W polarization planes.
We rotate the crystal into its position of maximum brightness. Now, either nα and nγ is oriented
NE-SW, meaning parallel to nγ of the λ-plate. Note that:
- The wavelength of the λ-plate is 550 nm (~575 nm is the extent of one order in the
Michel-Levy table!);
- When introduced, nα and nγ of the λ-plate will interfere with the nα and nγ of the
mineral, modifying the retardation (Δ)
- The wave can combine their wavelengths by addition (increasing retardation) or
subtraction (decreasing retardation). The addition or subtraction will only be by 550
nm, meaning by 1 λ.
- Adding retardation is when nα and nγ of the plate are parallel with nα and nγ of the
mineral.
- Subtracting retardation is when nγ of the plate is parallel to nα of the mineral (and nα of
the plate is parallel to nγ of the mineral).
- Increasing or decreasing the retardation can be seen by the changes in the interference
colours in the Michel-Levy table (to the left with 550 nm or to the right with 550 nm
starting to the interference colours observed for the mineral).
Let us take an example (Fig 36a-c):
1) First, bring the mineral to total extinction (this example is for a crystal with parallel
extinction). Here, we know that the two directions of vibration of the mineral are vertical,
and also horizontal (but we don‟t know which is nα and nγ)(Fig. 36a)
2) Rotate the stage exactly 45° (preferably bringing the longest faces of the crystal parallel
with the direction of the introduction of the plate (meaning NW-SE). In this position the
two directions of vibration of the mineral will be at 45° to the N-S and E-W lines and the
mineral will show its maximum interference colours (Fig. 36b).
3) Observe and locate the interference colour in the Michel-Levy table (pay attention to the
order of the colour!)
4) Introduce the plate (λ-plate or λ/4-plate)(Fig. 36c)
nslow
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5) Observe the changed colour and locate this new colour in the Michel-Levy table
If the new colour is situated at the right of the first observed one, it means that the wavelengths
of the mineral and the plate were added (the retardation increased in the Michel-Levy table).
This means that nγ of the mineral is parallel with the nγ of the plate (Fig. 36c). Knowing the nα
is perpendicular to nγ we have determined now the position of both nα and nγ of the mineral.
Note that if we rotate the crystal another 90°, having already introduced the plate, the nγ of the
mineral will now be parallel to the nα of the plate, and so the wavelength will subtract one from
the other and the retardation will decrease (the interference colour will appear further to the
left, by 550 nm).
Figure 37: a) Bring first the mineral to total extinction (this example is for a crystal with
parallel extinction); in this position nγ and nα will ALWAYS be vertical for one, and the other
horizontal (at this stage, however, we don‟t know which direction is nγ or nα); b) rotate the stage
by 45° to arrive at maximum interference and identify the colour of interference in the Michel-
Levy chart; in this position, the nγ and nα will ALWAYS be positioned at 45° relative to N-S
polarisation planes of the nicols (therefore, one of the two will be EXACTLY along the
direction in which we introduce the λ-plate); c) introduce the plate and identify the modified colour using the Michel-Levy chart: check if the retardation (Δ) has increased or decreased. If Δ
increased (colour moved to the right in the Michel-Levy chart), then we know that nγ of the
mineral is parallel to nγ of the plate.
Variable birefringence in anisotropic minerals:
the problem of crystal orientation in thin sections
Figure 38: left: XPL image of plagioclase crystal showing cleavage (centre of the image); middle: same image
after introducing λ-pate colour moved to the right in the Michel-Levy chart (from grey to yellow), so we know
that in this position, the interference of λ-plate with the crystal produced an addition of (Δ) therefore, the nγ of
the crystal is parallel to the NE-SW direction of the microscope view (meaning parallel to the orientation of nγ
shown on the λ-plate). Relating this observation to the reference direction (cleavage) of the crystal, we can say
that nγ of the crystal is parallel to the cleavage; right: crystal rotated by 90°. Note that the interference colours
changed; in this position we get subtraction of Δ (colour moved to the left in the Michel-Levy chart) nγ of the
crystal is parallel to nα of the λ-plate. Don‟t be confused… No matter how we rotate the stage, even colour
changes, the orientation of nγ and nα of the crystal in relation to crystal shape or reference (cleavage) always stays
the same (in this example nγ of the crystal is always parallel to the cleavage, no matter how the stage is rotated).
nslow
nγ
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See the example in Fig. 38, for the grain in the centre of the microscope view (left: no plate;
middle: plate introduced; right: crystal rotated by 90°).
f) Optical elongation
Since we have determined the orientation of nα and nγ in the crystal, is easy now to derive the
optical elongation. Remember that nγ is higher than nα. The two directions of vibration
represent the two main axes of the indicatrix (ellipsoid). We now relate the determined
ellipsoid to the mineral form!
We know that the exterior form of crystals is directly related to its symmetry (therefore to its
a,b and c crystallographic axes). Usually (but not always), the longer faces are parallel (or
displaced by the extinction angle value) to the c axis.
How are nα and nγ placed in relation to the direction in which the crystal is more developed
(longer), in relation to the c axis? If nγ is parallel (or at the extinction value angle) with the
direction of the longer faces, we say that the crystal has a positive optical elongation (the
elongation of the ellipsoid corresponds to the direction of the c axis). This crystal can also be
described as “length-fast” (the long axis of the crystal is parallel to the direction of the lowest
R.I.). If nα is parallel to the c axis, then the optical elongation is negative (Fig. 39), and the
crystal is “length slow”.
Figure 39: a) parallel extinction, positive optical elongation; b) parallel extinction, negative
optical elongation; c) oblique extinction, positive optical elongation; d) oblique extinction,
negative optical elongation.
Question: what is the optical elongation of the plagioclase shown in figure 38?
6.2. Conoscopic mode
Microscope setup: XPL (crossed nicols), high magnification (powerful objective)
Convergent lens in! Bertrand Lens in!
Chose a coarser grain and make certain that the rotating stage and the objective are centred (by
rotating the stage, the crystal should remain at or near the crosshairs in the centre of the
microscopic field).
Conoscopic study helps us to see if a crystal is uniaxial or biaxial. (Note that a 2-D section
through a 3-D uniaxial (circular ellipsoid) or biaxial indicatrix (flattened ellipsoid) would have
the same (elliptical) form).
In conoscopic mode, light penetrates the crystal in a conical shape, not as parallel rays as in
orthoscopic mode. This gives a kind of three-dimensional impression of light propagation in
the crystal. Details can be found in the literature; here we will only discuss
the practical side of thin section conoscopy.
We can derive the real shape of the indicatrix by using the interference figures and determining
the optical sign.
c- axis c- axis c- axis c- axis
a) b) c) d)
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6.2.1. Interference Figures
The conical (convergent) shape of light interferes with the sample and the shape of the
interference result is an image (interference figure) that forms somewhere between the analyzer
and ocular. In order to bring the interference image closer to the ocular, the Bertrand Lens is
used.
An interference figure consists of two dark diffuse intersecting lines (or curves) called isogyres
(regions of zero path difference) and circular coloured rings called isochromates, representing
regions of identical path difference; The higher the (Δ), the more isochromates there are (e.g.
Fig. 40).
Interference figures for uniaxial crystals
Uniaxial interference figures ideally look like this:
Figure 40: Interference figure for calcite (section perpendicular to the optic axis).
When the section is perpendicular to the optical axis of an uniaxial crystal (e.g. calcite, which
is trigonal), the interference figure is a cross (Fig. 40) centred in the middle of the view.
Rotating the stage, the cross, as well the isochromates, do not move. At the intersection of the
isogyres is the optic axis (which corresponds to the A3 fold axis of symmetry of the calcite)
If the section is oblique to the optic axis, the cross will be out of view and we have to rotate the
stage. By rotating the stage, we will observe one vertical “arm” of the cross, moving
horizontally as we rotate the stage, and when it disappears, a horizontal arm will show up,
moving vertically (fig. 41).
Figure 41: Interference figure for a uniaxial crystal, section oblique to the optic axis. The optic
axis is outside the interference figure but the vertical and horizontal black lines move horizontally and vertically, respectively, as the stage is rotated.
Interference figure for biaxial crystals
If the section is perpendicular to one of the optic axes, the interference figure will appear as a
curved, dark, diffuse arm that rotates within the image view. If the curvature is high, it means
that the angle between the two optical axes (the 2V angle) is small, and if the curvature is
small, then the 2V angle is high. (Fig. 42).
Isochromates
Isogyres (regions of zero path difference)
Rotation of the stage does not
change the image
Optic axis
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Figure 42: Interference figure for a biaxial crystal, section perpendicular to one of the optic axes.
The most useful biaxial interference figures are those for sections perpendicular to the 2V
bisectrix (the bisectrix of the acute angle between the two optic axes). In these figures we can
see both optic axes (Fig. 43a).
How do we find the section cut most closely perpendicular to the acute bisectrix? Trial and
error! Start with the lowest interference colour section you can find and, in the Conoscopic
Mode, work your way up until you find the right (i.e., most useful) interference figure.
Determination of the optic sign
-using the λ-plate-
The optic sign can be either positive or negative, and this tells us if nγ or nα, respectively, is
parallel to the 2V bisectrix.
After finding the interference figure, we introduce the λ-plate. The wavelength introduced by
the plate can produce either addition or substraction in the retardation of the isochromates (Fig.
44)!
What does the optic sign mean? It shows the shape of indicatrix in relation to the optic axis of
the crystal. For uniaxial crystals: is the optical axis parallel or not with the nγ or nα? For
biaxial crystals: is the bisectrix of the acute 2V angle parallel with nγ or nα? See the shape of
biaxial indicatrices in Fig. 45.
Figure 43a: Position of the optic axes
SShheelllleeyy 11999933
Figure 43b: Movement of isogyres during stage rotation.
From top to bottom, the 2V angle increases.
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Figure 44: Determination of the optic sign
Observe the upper right or lower left quadrant:
Add the λ-plate
-Constructive (addition) colours indicate a positive
optic sign;
-destructive (subtraction) colours indicate a negative
optic sign.
Figure 45: Positive and negative optical sign
a) Crystal biaxial positive : Acute bisectrix: nγ nα and nβ T acute bisectr, δ > 0
b) Crystal biaxial negative Acute bisectrix: nα nβ and nγ T acute bisectr. δ > 0
A quick reference for the determination of the optic sign of minerals with low birefringence (IF
1st order grey-white) is provided in figure 46.
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Figure 46: Determination of the optic sign for crystals with low birefringence.
Estimation of the 2V angle
This estimation is an approximation using the interference figures. The best sections are those
perpendicular to the acute bisectrix (Fig. 47a). The estimate is done by comparison with
images from Fig. 47.
a) 2V=90: one straight line rotating in the opposite direction compared to the rotation of the
stage;
b) There is a moderate 2V angle if the isogyres are moderately curved;
c) There is a low 2V angle if the two wings of the cross meet and break slightly as we rotate
the stage. The two wings do not leave the interference figure when rotating the stage only if
the section is ~ perpendicular to the acute bisectrix (i.e. a uniaxial-like interference figure).
a) Uniaxial to optic axis
c) Biaxial to optic axis
b) Biaxial to acute bisectrix
Figure 47: Estimation of the 2V angle (see text). After Shelley (1993).
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Is the interference figure good enough for seeing the optical character and determining
the optical sign? Interference figures: The Good, the Bad and the Ugly (Fig. 48):
Figure 48: Types of possible sections obtained for biaxial crystals. Which one is good?
The Good: Section to the acute bisectrix
The Bad: Section oblique to the acute bisectrix
Another Good one: Section ± to OA
The Ugly: “Flash Figure”
Section to the obtuse bisectrix (biaxial minerals) or
parallel to the OA (uniaxial minerals): confusion
guaranteed.
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Useful charts for mineral identification: the Tröger Chart
A (sometimes dangerous) shortcut to identify minerals with the petrographic microscope
involves using the Tröger Chart, which has the refractive index on the x axis and birefringence
values on the y axis. The zero value of birefringence (isotropic crystals) positioned at the
middle of the chart, so that the birefringence values increase from zero up but also decrease
from zero down in the chart. In the upper part are found minerals with positive optical sign,
while in the lower part of the chart are minerals with negative optical sign. To make a
distinction between uniaxial and biaxial crystals, the uniaxial are represented with bold circles.
The steps to take are:
a) Check refractive index (n)/chagrin (low, medium, high); for n(RI)<1.65 use part one of
the chart (Fig. 49a) and for n>1.65 use part two of the chart (Fig. 49b)
b) Check the maximum birefringence (birefringence colour; then estimate the value of
birefringence using the Michel-Levy chart)
c) Determine the optic character (uni- or biaxial) and the optic sign
d) Find the region on the Tröger Chart corresponding to these determined values
e) Check the optical characteristics of minerals occurring in that region
f) Check the likelihood of the determined mineral occurring in the rock type investigated
g) Don‟t forget: there are more mineral species than shown on the charts!
Figure 49a: Tröger Chart part 1 (refractive indexes from 1.45 to 1.65)
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Figure 49b: Tröger Chart part 1 (refractive indexes from 1.65 to 2.80)
27 Key mineral species
It is useful to know the key optical characteristics for the minerals listed below (the common
rock-forming minerals).
1. Quartz 2. Plagioclase*
3. K-feldspar* 4. Cordierite*
5. Biotite* 6. Tourmaline*
7. Amphibole* 8. Muscovite
9. Talc 10. Chlorite*
11. Garnet* 12. Spinel*
13. Staurolite 14. Rutile
15. Chloritoid 16. Calcite/Dolomite
17. Titanite 18. Zircon/Monazite
19. Olivine* 20. Cpx*
21. Opx* 22. Epidote*
23. Apatite 24. Kyanite
25. Sillimanite 26. Andalusite
27. Nepheline
* Solid solutions with variable optical properties
Italics: learn formula; the rest: learn the general composition
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Key Characteristics of common minerals: Speeding up mineral identification
Many common mineral phases have unique characteristics (or combinations of two or three)
which make them unmistakable.
Examples
Quartz: low RI (~like the resin); low birefringence (1st order IF colour); uniaxial positive; no
(visible) twins.
Plagioclase: low RI and birefringence (~like Qtz); lamellar twinning; biaxial positive or
negative.
Staurolite: pale yellow pleochroism; high RI; frequently idiomorphic.
Carbonates: very high birefringence, relief changes when you turn the stage; uniaxial negative.
Identify the key characteristics and note them in your mineral catalogue.
A few hints for the relationship between chemical composition - optical properties
Some cations from the Transition Elements in the Periodic Table (including Fe, Cr, V, Ti, etc.)
which have several possible valence states in rocks, produce more intense but variable
absorption of light, and are called chromophores. The result is that minerals rich in these
elements will be more strongly coloured in thin sections (in PPL mode): Fe2+
gives gray,
yellow to greenish colours, depending on its concentration and on the absorption produced by
other cations (e.g. in olivine, pyroxene, amphibole, chlorite). Fe3+
gives brown colours (in
oxydated hornblende = brown hornblende) or green in oxydized biotite. Cr3+
gives pale green
colours (e.g. in spinels, Cr-diopside, fuxite (Cr-mica), Cr-staurolite, Cr-cordierite); Ti produces
reddish-brown colours (such as in Ti-rich biotite).
In addition to the strong selective absorption, the presence of these cations also increases the
refractive indices of the mineral, causing higher relief. This is useful in composition
estimations for minerals that are part of solid solutions. For example, in olivine or pyroxene,
Fe2+
shares a structural position with Mg2+
(so Fe2+
can substitute for Mg in any proportion).
The Mg-rich end member of the solution will be colourless, but the solid solution becomes
more coloured and the refractive index increases as it has more Fe2+
instead of Mg. The Fe2+
end members will be green with higher relief.
When dealing with silicates (as we usually are in rocks), coloured minerals as seen in PPL can
be expected to have a positive relief (have refractive indices superior to the resin). There are
few exceptions: the bluish hauyine and nosean from the sodalite group have negative relief, but
the bluish colour is given by the absorption produced by small amounts of the [SO4] molecule.
The silicates with Al, Ca, Mg, or with Ca, Na, K (note the absence of chromophores) are
typically colourless (e.g. all feldspars, feldspathoids, white mica).
The substitution of Ca for Na in plagioclase solid solutions produces no colour change, but
does induce an increase in the refractive index (relief) and the extinction angle. Michel-Levy
proposed a method to estimate the Ca-end member (Anorthite CaAl2Si2O8) in a plagioclase,
based on the extinction angle.
The carbonates always show twinkling (a modification of relief from positive to negative)
when the stage is rotated. Together with the high order birefringence (4th
order), the twinkling
is diagnostic for carbonates.
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Tips for discriminate between different mineral groups
All cubic minerals are isotropic.
All orthorhombic minerals, as well as all uniaxial minerals (medium symmetry: trigonal,
tetragonal, hexagonal), have parallel extinction (except for basal sections, which have
symmetrical extinction).
All monoclinic and triclinic minerals have oblique extinction (except for basal sections which
have symmetrical extinction).
All phyllosilicates have parallel extinction and perfect basal cleavage; the extinction is not total
(smooth) but „rough‟ (small bright coloured spots are present across its entire surface).
All orthosilicates have relatively high refractive indices (relief)
All tectosilicates have low or medium-low refractive indices (relief)
Sulphates (e.g. gypsum) have usually negative refractive indices (relief)
Heavy elements (down periods in the periodic table) produce high relief (Ba, U, REE etc) in
their host mineral
Sulphides are all opaque (as some of the oxides: magnetite, hematite, ilmenite); yellowish-
brown alterations on fissures (no pleochroism, no birefringence) are usually Fe-hydroxides
(goethite, lepidocrocite etc) or hematite (dark reddish).
Mineral associations: helpful in identifying minerals
Not all minerals can be naturally associated in a rock. Most rocks have 2-5 abundant minerals
and a few other minerals as possible accessories or alteration. The natural association of
minerals in rocks is controlled by their stability, which mainly depends on chemistry, pressure
(including water pressure), and temperature.
-olivine and quartz are never found together in equilibrium in the same thin section (one is
undersaturated in SiO2, the other is super-saturated in SiO2, respectively).
-feldspathoids (nepheline, sodalite, cancrinite, etc.) are never found together with quartz (same
explanation as above);
-if olivine has been recognised (medium-high relief, no cleavage, strong chagrin, high
birefringence), it is frequently associated with pyroxenes (no chagrin, good cleavage, similar
relief, parallel extinction = orthopyroxene; oblique extinction (30-45°) = clinopyroxene) and/or
amphiboles (longer prisms, stronger pleochroism, typical basal sections with 120° angle
between cleavages, medium relief, lower extinction angle), and/or plagioclase (colourless, low
birefringence first order, polysynthetic twinning)
-grid twinning is typical for microcline (K-feldspar), and is commonly associated with quartz
and (sodic) plagioclase
-perthitic textures - fine lamellae of albite (relief zero or negative) in a host of K-feldspar
(stronger negative relief than albite); perthites are typical for K-feldspar (orthoclase,
microcline, rare in sanidine).
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Mineral Identification – A Beginner’s Guide
to Identifying the Common Rock-Forming Minerals using Transmitted Light Microscopy
Is your mineral?:
COLOURLESS? COLOURED?
ISOTROPIC? low relief? hole in slide, or basal section of
a non-isotropic mineral ISOTROPIC? green? spinel
high relief? garnet black? “opaque” (oxides, sulphides)
NON-ISOTROPIC? NON-ISOTROPIC?
UNIAXIAL? UNIAXIAL?
LOW RELIEF? (relief masked by mineral colour)
positive? quartz pleochroic brown, green, orange (pseudo-
uniaxial or very low 2V)?
biotite
negative? nepheline, scapolite pleochroic pale brown to colourless? phlogopite
MODERATE RELIEF? BIAXIAL?
positive, usually as laths muscovite, talc very pale green to colourless, very
weakly pleochroic?
cpx, chlorite, chloritoid,
muscovite, serpentine
HIGH RELIEF? pleochroic pale pink to pale green to colourless?
hypersthene
Positive-negative (“relief
pleochroisme”, with distinct cleavages
calcite pleochroic yellow-brown to colourless? staurolite
BIAXIAL? pleochroic distinctly green, brown, blue-green?
hornblende, tourmaline
LOW RELIEF?
may have polysynthetic twinning feldspars, cordierite pleochroic brown to colourless, often
euhedral, very high δ?
titanite
HIGH RELIEF? reddish-brown needles, very high δ? rutile
conchoidal fracture? olivine pleochroic blue, purple? riebeckite, glaucophane
idio- to subidioblastic, in a
metamorphic rock?
Al2SiO5: andalusite, sillimanite,
kyanite
AMORPHOUS (no optic sign)
granular, with anomalous 1st order
colours? clinozoisite, epidote opaque interior, brown at thin edges chromite
up to 2 distinct cleavage directions opx, cpx, wollastonite, all
amphiboles other than
hornblende
red hematite
fine-grained, granular, with very high δ zircon, monazite
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A Birefringence Primer
Interference colours (birefringence) produced when the polariser and analyser are both “in” (crossed nicols, or crossed polars).
For mineral diagnostic purposes, the colours refer to “maximum birefringence”, produced only when mineral grains are aligned perpendicular to
their c-axis (i.e., many grains will show interference colours below the maximum, but the „average” or typical colour seen in a thin section is
usually close enough.
In strongly-coloured minerals, interference colours may be masked by the mineral colour; if the apparent interference colour looks “odd”,
compare it with the actual mineral colour in plane-polarised light, to avoid confusion.
Birefringence
(nγ - nα = δ)
0 to 0.005 0.005 to 0.01 0.01 to 0.015 0.015 to 0.018 0.018 to 0.028 0.028 to 0.08 0.08 to 0.2
“Order” Lower 1st Order Upper 1
st
Order
Lower 2nd
Order
Upper 2nd
Order
3rd
Order 4th
Order and beyond
Interference
Colours
black, grey, white
+ anomalous
colours: “Berlin”
or Prussian blue-
grey, green-grey
“straw
yellow”, red
purple to blue,
green
yellow,
orange/red
blue, green,
yellow, red
pale green,
pink
“bright brown”
Common
minerals
quartz,
plagioclase
feldspar,
microcline,
cordierite,
chlorite,
clinozoisite,
andalusite,
nepheline,
scapolite
quartz,
orthoclase
(yellow or
lower);
sillimanite,
opx,
wollastonite
kyanite,
amphiboles,
cpx, biotite
muscovite,
olivine
talc zircon titanite, calcite,
rutile
Some common problems:
How can I tell if I’m looking at “1st order” red, or 2
nd or 3
rd order colours?
Look at the edges of the grains, or along fractures, where they are thinnest; you should see fine rings of the lower interference colours
(e.g., so if it‟s 1st order red, there will be no blue-indigo edges)
Look at conoscopic figure; isochromes correspond to the same colour bands (usually these are subtle, but it works well in come cases, like
calcite & biotite, for example)
Lower order colours are “deeper”, higher order “brighter”, higher orders are pale, mixed, diffuse.
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If a mineral is black, does that mean it is automatically “1st order Black”?
Not necessarily; it could also be
o an opaque mineral (light is not transmitted through it), so it is also black under plane-
polarised light (i.e., with analyser “out”)
o an isotropic mineral is always black under cross-polars; it has no birefringence and is
therefore not “1st order” per se
o basal-orientated sections (looking directly down the c-axis, in general) can be 1st Order
black, but this is not the maximum birefringence for that particular mineral.
o a hole in the slide, often the result of “plucking” of certain minerals, or where there are
void spaces (not uncommon in volcanic rocks and sediments); it will have “very low
relief” and no crystal shape or other properties.
Got it narrowed down yet?
Yes? – Good! Now go look up the detailed properties of the possible minerals, and match them to
the observed properties & associated minerals and textures.
No? – Is it similar to anything? (probably); There may be some common “similar” minerals not
listed here in related mineral groups, other solid solution end-members, etc., so start with the
mineral(s) it looks the most similar to, and work from there.
Still stumped? Follow the identification Table for Common Minererals in Thin Sections. If still
stumped....Ask a petrologist…
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Identification Tables for Common Minerals in Thin Section
These tables provide a concise summary of the properties of a range of common minerals. Within the
tables, minerals are arranged by colour so as to help with identification. If a mineral commonly has a
range of colours, it will appear once for each colour.
To identify an unknown mineral, start by answering the following questions:
(1) What colour is the mineral?
(2) What is the relief of the mineral?
(3) Do you think you are looking at an igneous, metamorphic or sedimentary rock?
Go to the chart, and scan the properties. Within each colour group, minerals are arranged in order of
increasing refractive index (which more or less corresponds to relief). This should at once limit you to
only a few minerals. By looking at the chart, see which properties might help you distinguish between the
possibilities. Then, look at the mineral again, and check these further details.
Notes (refer to notations and observations in the tables below):
(i) Name: names listed here may be strict mineral names (e.g., andalusite), or group names (e.g.,
chlorite), or distinctive variety names (e.g., titanian augite). These tables contain a selection of some of
the more common minerals. Remember that there are more than 4000 minerals, although 95% of these
are rare or very rare. The minerals in here probably make up 95% of medium and coarse-grained rocks in
the crust.
(ii) IMS: this gives a simple assessment of whether the mineral is common in igneous (I), metamorphic
(M) or sedimentary (S) rocks. These are not infallible guides - in particular many igneous and
metamorphic minerals can occur occasionally in sediments. Bear this in mind, even if minerals are not
marked as being common in sediments.
(iii) Colour in thin sections (TS): the range of colours for each mineral is given, together with a
description of any pleochroism. Note that these are colours seen in thin-section, not handspecimen.
The latter will always be much darker and more intense than thin section colours.
(iv) RI: the total range of refractive index shown by the mineral with this coulour is shown: This covers
any range due to compositional variation by solid solution, as well as the two or three refractive indices of
anisotropic minerals.
(v) Relief : is described verbally, followed by a sign indicating whether the relief is positive or negative
(ie greater or less than the mounting medium of the thin-section - 1.54). Minerals with refractive indices
close to 1.54 have low relief, those with much higher or lower refractive indexes will have high relief.
(vi) Extinction: angles are only given where minerals usually show a linear feature such as a cleavage
and/or long crystal faces. For plagioclase feldspars (stippled) the extinction angles given are those
determined by the Michel-Levy method (see a textbook for details).
(vi) Int. Figure: this gives details of the interference figure. Any numbers given refer to the value of 2V
(normally a range is given), followed by the optic sign. For uniaxial minerals the word "Uni" is given,
followed by the sign. Your course may or may not have covered interference figures. If not, ignore this
section!
(vii) Birefr: Birefringence is described verbally. In some cases the maximum is given as a colour, in
other cases you will need to cross-refer to an interference colour chart.
(viii) Twinning etc.: a few notes about twinning, or other internal features of crystals may be given. If no
twinning is mentioned, then the phenomenon is not common in thin section, but this does not mean that it
NEVER occurs.
(ix) Notes: general tips on appearance, occurrence and distinguishing features. May include indication of
whether the mineral is length fast or slow - again a feature not covered in all courses - but a useful and
easily-determined property.
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Tables for Common Minerals in Thin Section
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bisectrix dominatrix optical dominatrix optical indicatrix