introduction to organic chemistry - mit esp - home€” 0— obeys octet rule phosphorus...

26
Introduction to Organic Chemistry HSSP 2010 Lecture 1 Slides modified from MIT 5.12 Organic Chemistry lecture notes, Spring 2007

Upload: vankien

Post on 11-Apr-2018

224 views

Category:

Documents


5 download

TRANSCRIPT

Page 1: Introduction to Organic Chemistry - MIT ESP - Home€” 0— Obeys Octet Rule Phosphorus trichloride H Hydrogen disulfide Expanded Valence Phosphoric acid ... All of the important

Introduction to Organic

Chemistry

HSSP 2010

Lecture 1

Slides modified from MIT 5.12 Organic

Chemistry lecture notes, Spring 2007

Page 2: Introduction to Organic Chemistry - MIT ESP - Home€” 0— Obeys Octet Rule Phosphorus trichloride H Hydrogen disulfide Expanded Valence Phosphoric acid ... All of the important

Organic chemistry

Page 3: Introduction to Organic Chemistry - MIT ESP - Home€” 0— Obeys Octet Rule Phosphorus trichloride H Hydrogen disulfide Expanded Valence Phosphoric acid ... All of the important

What: Carbon-containing compounds

Page 4: Introduction to Organic Chemistry - MIT ESP - Home€” 0— Obeys Octet Rule Phosphorus trichloride H Hydrogen disulfide Expanded Valence Phosphoric acid ... All of the important

Why: Life is based on organic

compounds

Page 5: Introduction to Organic Chemistry - MIT ESP - Home€” 0— Obeys Octet Rule Phosphorus trichloride H Hydrogen disulfide Expanded Valence Phosphoric acid ... All of the important

How: structure and reactivity

Page 6: Introduction to Organic Chemistry - MIT ESP - Home€” 0— Obeys Octet Rule Phosphorus trichloride H Hydrogen disulfide Expanded Valence Phosphoric acid ... All of the important

Atoms of organic molecules

Page 7: Introduction to Organic Chemistry - MIT ESP - Home€” 0— Obeys Octet Rule Phosphorus trichloride H Hydrogen disulfide Expanded Valence Phosphoric acid ... All of the important

Main atoms in organic chemistry

Page 8: Introduction to Organic Chemistry - MIT ESP - Home€” 0— Obeys Octet Rule Phosphorus trichloride H Hydrogen disulfide Expanded Valence Phosphoric acid ... All of the important

Background review

Page 9: Introduction to Organic Chemistry - MIT ESP - Home€” 0— Obeys Octet Rule Phosphorus trichloride H Hydrogen disulfide Expanded Valence Phosphoric acid ... All of the important

Chemical bonding

Page 10: Introduction to Organic Chemistry - MIT ESP - Home€” 0— Obeys Octet Rule Phosphorus trichloride H Hydrogen disulfide Expanded Valence Phosphoric acid ... All of the important

Obtaining valence shell octet

Page 11: Introduction to Organic Chemistry - MIT ESP - Home€” 0— Obeys Octet Rule Phosphorus trichloride H Hydrogen disulfide Expanded Valence Phosphoric acid ... All of the important

Ionic bonding

Page 12: Introduction to Organic Chemistry - MIT ESP - Home€” 0— Obeys Octet Rule Phosphorus trichloride H Hydrogen disulfide Expanded Valence Phosphoric acid ... All of the important

Covalent bonding

Page 13: Introduction to Organic Chemistry - MIT ESP - Home€” 0— Obeys Octet Rule Phosphorus trichloride H Hydrogen disulfide Expanded Valence Phosphoric acid ... All of the important

Polar covalent bonding

Page 14: Introduction to Organic Chemistry - MIT ESP - Home€” 0— Obeys Octet Rule Phosphorus trichloride H Hydrogen disulfide Expanded Valence Phosphoric acid ... All of the important

Describing covalent bonds

Page 15: Introduction to Organic Chemistry - MIT ESP - Home€” 0— Obeys Octet Rule Phosphorus trichloride H Hydrogen disulfide Expanded Valence Phosphoric acid ... All of the important

Lewis dot structures

Page 16: Introduction to Organic Chemistry - MIT ESP - Home€” 0— Obeys Octet Rule Phosphorus trichloride H Hydrogen disulfide Expanded Valence Phosphoric acid ... All of the important

Lewis dot structures

Page 17: Introduction to Organic Chemistry - MIT ESP - Home€” 0— Obeys Octet Rule Phosphorus trichloride H Hydrogen disulfide Expanded Valence Phosphoric acid ... All of the important

Lewis structures & formal charge

Page 18: Introduction to Organic Chemistry - MIT ESP - Home€” 0— Obeys Octet Rule Phosphorus trichloride H Hydrogen disulfide Expanded Valence Phosphoric acid ... All of the important

Exceptions to the octet rule

Page 19: Introduction to Organic Chemistry - MIT ESP - Home€” 0— Obeys Octet Rule Phosphorus trichloride H Hydrogen disulfide Expanded Valence Phosphoric acid ... All of the important

Exceptions to the octet rule

Page 20: Introduction to Organic Chemistry - MIT ESP - Home€” 0— Obeys Octet Rule Phosphorus trichloride H Hydrogen disulfide Expanded Valence Phosphoric acid ... All of the important

Bonding patterns

Page 21: Introduction to Organic Chemistry - MIT ESP - Home€” 0— Obeys Octet Rule Phosphorus trichloride H Hydrogen disulfide Expanded Valence Phosphoric acid ... All of the important

Bonding patterns

Page 22: Introduction to Organic Chemistry - MIT ESP - Home€” 0— Obeys Octet Rule Phosphorus trichloride H Hydrogen disulfide Expanded Valence Phosphoric acid ... All of the important
Page 23: Introduction to Organic Chemistry - MIT ESP - Home€” 0— Obeys Octet Rule Phosphorus trichloride H Hydrogen disulfide Expanded Valence Phosphoric acid ... All of the important

VSEPR theory: molecular geometry

Page 24: Introduction to Organic Chemistry - MIT ESP - Home€” 0— Obeys Octet Rule Phosphorus trichloride H Hydrogen disulfide Expanded Valence Phosphoric acid ... All of the important

Atomic orbitalsDescribes the volume of space where an electron is most likely to be found

Page 25: Introduction to Organic Chemistry - MIT ESP - Home€” 0— Obeys Octet Rule Phosphorus trichloride H Hydrogen disulfide Expanded Valence Phosphoric acid ... All of the important

Atomic orbital shape

Page 26: Introduction to Organic Chemistry - MIT ESP - Home€” 0— Obeys Octet Rule Phosphorus trichloride H Hydrogen disulfide Expanded Valence Phosphoric acid ... All of the important

Electron configuration