is 15201 (2002): hydrogen - code of safety · p, ;, ,-is 15201:2002 indian standard hydrogen —...

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Disclosure to Promote the Right To Information Whereas the Parliament of India has set out to provide a practical regime of right to information for citizens to secure access to information under the control of public authorities, in order to promote transparency and accountability in the working of every public authority, and whereas the attached publication of the Bureau of Indian Standards is of particular interest to the public, particularly disadvantaged communities and those engaged in the pursuit of education and knowledge, the attached public safety standard is made available to promote the timely dissemination of this information in an accurate manner to the public. इंटरनेट मानक !ान $ एक न’ भारत का +नम-णSatyanarayan Gangaram Pitroda “Invent a New India Using Knowledge” प0रा1 को छोड न’ 5 तरफJawaharlal Nehru “Step Out From the Old to the New” जान1 का अ+धकार, जी1 का अ+धकारMazdoor Kisan Shakti Sangathan “The Right to Information, The Right to Live” !ान एक ऐसा खजाना > जो कभी च0राया नहB जा सकता ह Bharthari—Nītiśatakam “Knowledge is such a treasure which cannot be stolen” IS 15201 (2002): Hydrogen - Code of Safety [CHD 8: Occupational Safety, Health and Chemical Hazards]

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Page 1: IS 15201 (2002): Hydrogen - Code of Safety · p, ;, ,-is 15201:2002 indian standard hydrogen — code of safety ics 13.300;11.100.20 c)bis 2002 bureau of indian standards manak bhavan,

Disclosure to Promote the Right To Information

Whereas the Parliament of India has set out to provide a practical regime of right to information for citizens to secure access to information under the control of public authorities, in order to promote transparency and accountability in the working of every public authority, and whereas the attached publication of the Bureau of Indian Standards is of particular interest to the public, particularly disadvantaged communities and those engaged in the pursuit of education and knowledge, the attached public safety standard is made available to promote the timely dissemination of this information in an accurate manner to the public.

इंटरनेट मानक

“!ान $ एक न' भारत का +नम-ण”Satyanarayan Gangaram Pitroda

“Invent a New India Using Knowledge”

“प0रा1 को छोड न' 5 तरफ”Jawaharlal Nehru

“Step Out From the Old to the New”

“जान1 का अ+धकार, जी1 का अ+धकार”Mazdoor Kisan Shakti Sangathan

“The Right to Information, The Right to Live”

“!ान एक ऐसा खजाना > जो कभी च0राया नहB जा सकता है”Bhartṛhari—Nītiśatakam

“Knowledge is such a treasure which cannot be stolen”

“Invent a New India Using Knowledge”

है”ह”ह

IS 15201 (2002): Hydrogen - Code of Safety [CHD 8:Occupational Safety, Health and Chemical Hazards]

Page 2: IS 15201 (2002): Hydrogen - Code of Safety · p, ;, ,-is 15201:2002 indian standard hydrogen — code of safety ics 13.300;11.100.20 c)bis 2002 bureau of indian standards manak bhavan,
Page 3: IS 15201 (2002): Hydrogen - Code of Safety · p, ;, ,-is 15201:2002 indian standard hydrogen — code of safety ics 13.300;11.100.20 c)bis 2002 bureau of indian standards manak bhavan,
Page 4: IS 15201 (2002): Hydrogen - Code of Safety · p, ;, ,-is 15201:2002 indian standard hydrogen — code of safety ics 13.300;11.100.20 c)bis 2002 bureau of indian standards manak bhavan,

p, ;, ,-

IS 15201:2002

Indian Standard

HYDROGEN — CODE OF SAFETY

ICS 13.300;11.100.20

C)BIS 2002

BUREAU OF INDIAN STANDARDSMANAK BHAVAN, 9 BAHADUR SHAH ZAFAR MARG

NEW DELHI 110002

September 2002

1

Price Group 4

i“

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lndustr-ial Safety and Chemical Hazards Sectional Committee, CHD 8

FOREWORD

This Indian Slandard was adopted by the Bureau of Indian Standards, after the draft finalized by the IndustrialSafely and chemical Hazards Sectional Committee had been approved by the Chemical Division Council.

Hydl ogen is used in the hydrogenation of edible and petroleum oils, in the synthesis of ammonia, methanol,hydrochloric acid, aluminium alkyls, higher alcohols and aldehydes, in the reduction of metal oxides ( such as ironore) and in welding. Liquid hydrogen is an important cryogemc fluid.

Hydrogen is a highly flammable liquid or gas and has a dangerous fire and explosion hazard. Exposure to highlc~cls of hydrogen g_asconcentration can cause suffocation for lack of oxygen. Contact with liquid hydrogen cancause frostbite.

There is no 1S0 Standard on this subject. In the preparation of this Code, considerable assistance has been derivedfrom the following publications:

a) Sax’s Dangerous Properties of Industrial Materials, Volume No. 3, 10th edition, Wiley—IntersciencePublication, John Wiley and Sons. Inc., 2000.

b) Recommendations on the Transport of Dangerous Goods, %h revised edition, United Nations, Geneva,1995.

c) Material Safety Data Sheets, Phase-I, by Indian Chemical Manufacturers Association, 1991.d) Handbook of Toxic and Hazardous Chemicals and Carcinogens, Volume II, 3rd edition, Marshall Sittig,

Noycs Publications, Park Ridge, New Jersey, USA,1991.

c) Chemical Safety Data Sheets, Flammable Chemicals, Volume 5, Royal Society of Chemistry, UnitedKingdom, 1992.

~ Hydrogen: Production and Marketing, W. N. Smith, J. G. Santangel, ACS Symposium series 116,1980.

g) Encyclopedia of Chemistry, S. P. Parker, McGraw Hill, 1982.h) Gaseous Hydrogen Stations, Industrial Gases Committee, 32 Boulevard de la Chapelle, 75880, Paris,

Ccdcx 18, France, September 1980.

The composition of the Committee responsible for formulation of this standard is given in Annex A.

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IS 15201:2002

Indian Standard

HYDROGEN— CODE OF SAFETY

1 SCOPE

1.1 This code prescribes physical and chemicalproperties of hydrogen gas, the nature of hazardsassociated with it, preventive measures for controllingthe hazards, and essential information on storage,handling, labelling, transportation, waste disposal,training of personnel, personal protective equipment,first aid and tire fighting.

1.2 This code does not, however, deal with anyspecification for design of buildings, chemicalengineering plants, method and ingredients used in themanufacture, equipment for waste disposal andoperation control.

2 REFERENCES

The Indian Standards listed below contain provisionswhich through reference in this text, constituteprovisions of this standard. At the time of publication,the editions indicated were valid. All standards aresubject to revisions, and parties to agreements basedon this standard are encouraged to investigate thepossibility of applying the most recent editions of thestandards:

IS No. Title

4155:1966 Glossary of terms relating tochemical and radiation hazards andhazardous chemicals

4379:1981 Identification of contents ofindustrial gas cylinders ~rst

revision)

3 TERMINOLOGY

For the purpose of this standard, the definitions givenin IS 4155 shall apply.

4 GENERAL INFORMATION ANDPROPERTIES

4.1 General Inforrnatioh

4.1.1 Chemical Name

Hydrogen.

4.1.2 Common Name

Liquid hydrogen, para hydrogen, hydrogen(compressed), dihydrogen.

4.1.3 Molecular Formula

H,.

4.1.4 UN Nunlber

1049 for gas (hydrogen, compressed), and

1966 for liquid (refrigerated liquid).4

4.1.5 CASNumber

1333 -74-0

4.1.6 Class

2 (flanimable gas).

4.1.? MolecularMass

2.01594.

4.2 Physigal Properties

4.2.1 Description

Colorless, odourless and tasteless gas.

4.2.2 Boiling Point

(-) 252.8”C.

4.2.3 Melting Point

(-) 259.2”C.

4.2.4 Vapour Density @lir = 1)

0.069.

4.2.5 Density, g/1

0.0899.

4.2.6 Vapour Pressure (Hg in mm)

1570 at –250”C.

4.2.7 Volubility

Slightly soluble in alcohol and ether. 1.82 percentsoluble in water at 20”C.

4.3 Chemical Properties

4.3.1 Reactivity

Hydrogen is stable under normal temperature andpressure. Violent reaction or ignitiov takes place withair in presence of catalyst like platitmm and similarmetals containing absorbed oxygen or hydrogen,bromine, iodine, dioxane + nickel, lithium, nitrogentrifluoride, nickel+ oxygen, oxygen difluoride.

4.4 Fke and Explosion Hazard

4.4.1 Auto Ignition Temperature

400”C

Properties

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IS 15201:2002

4.4.2 F1ashPoint

Not pertinent,

4.4.3 Flammability

4.4.3.1 Explosive limits with air, percent(v.lv)

a) Upper explosive limit (UEL) : 74.2b) Lower explosive limit (LEL) : 4.0

4.5 Corrosion Properties b

Not corrosive.

5 TOXICITY INFORMATION AND HEALTHEFFECTS

5.1 Toxicity

Hvdrogen is not toxic except that it may asphyxiate. Itn;ay displace the oxygen in a workplace atmosphereand thus act as an asphyxiant.

5.2 Routes of Entry

Skin and inhalation.

5.3 Health Effects

5.3.1 (.!ontac:t of [.iquid Hydrogen with Skin

Direct contact of body tissue with liquid hydrogen cancause cold burns or frost bite.

5.3.2 .4,@yxiation

Hydrogen displaces the oxygen in the workplaceatmosphere. If atmosphere does not contain enoughoxygen then inhalation can cause dizziness, un-consciousness or even death.

6 PERSONAL PROTECTIVE EQUIPMENT

6.1 General

Personal protective equipment is not an adequatesubstitute for good, safe working conditions, adequateventilation and intelligent conduct on the pafi’ of theemployees. One should keep firmly in mind thatpersonal pro[ect ive equipment protects only the pasonwearing it and other unprotected workers in the areamay be exposed to danger.

6.2 Non-Respiratory E(iuipment

Personal protecting equipment should include non-rcspirat ory equipment like splash-proof safety gogglesand face shield when working with liquid, unless fhllfacepiece respiratory protection is worn for eyeprotection. safety helmets for head protection and bootsor high top shoes for foot protection. Where exposureto cold equipment, vapours, or liquid may occur,cmp!oyccs should wear special clothing designed toprc~cn[ the freezing of body tissues. All protectiveclothing (suits, shirts with long sleeves, insulatedglo~cs) should be clean, available each day, and put

2

on before work. Cufflessoutside boots or over highliquid.

trousers should be worntop shoes to shed spilled

6.3 Respiratory Equipment

Hydrogen is a simple asphyxiant. It can replace oxygenand lead to suffocation. An approved self-containedbreathing apparatus with a full facepiece operated inpositive pressure mode should be used in oxygendeficient environments.

7 STORAGE, HANDLING, LABELLING ANDTRANSPORT

7.1 storage

7.1.1 General Precautions

7.1.1.1 Hydrogen must be stored to avoid contact withheat, flames, sparks and oxygen. Sources of ignitionsuch as smoking and open flames are prohibited wherehydrogen is used, handled or stored.

7.1.1.2 Metal containers involving transfer of largequantities of hydrogen should be grounded and bonded.Piping should be electrically bonded and grounded.

7.1.1.3 Containers must be equipped with self-closingvalves, pressure vacuum bungs and flame arrestors.

7.1.1.4 Only non-sparking tools and equipment,especially when opening and closing containers ofhydrogen should be used.

7.1.1.5 Wherever hydrogen is used (handled,manufactured or stored), approved explosion-proofelectrical equipment and fittings should be used.

7.1.1.6 Automatic or manual shutdown processes,sprinklers, gas and heat sensors with early warningaudio-visual alarms, flooding, water spraying,extinguishing systems, explosion relief devices shouldbe available in storage areas.

7.1.1.7 The building shall have good low and highlevel natural ventilation. In areas where naturalventilation is not possible, forced ventilation equip-ments should be installed.

7.1.2 Indoor Storage

7.1.2.1 Avoid mechanical damage or overheating ofstorage tanks and cylinders.

7.1.2.2 The vents from the storage tanks, relief valvemust be led to a safe location to avoid any explosionswith suitable flame arrestors fitted init.

7.1.3 Outdoor Storage

7.1.3.1 Outside storage tanks may be located at least15 metres away from building or adjacent to blankmasomy building walls. The location should be awayfrom any flammable liquid storage with adequateapproved fire protection system.

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7.1.3.2 Cylinders must be protected from direct sunrays. Prowsion of shed should be done for outdoorstorage of cylinders.

7.1.4 Bulk Storage (Non-refrigerated)

7.1.4.1 Hydrogen is lighter than air and any leak goesup the atmosphere readily. It shall be stored in gas tightcontainers either in atmospheric condition or underpressure.

7.1.4.2 Storage area should be protected by tirehydrants and automatic sprinklers for extinguishing atire.

7.1.4.3 The storage tanks shall be designed as perstandard code.

7.1.4.4 Each storage tank shall be equipped with reliefvalves. Vent pipes from the valves should terminateupward and should have a flame arrestor. Suitableprovision should be nrdde to prevent anything fromentering the vents. A drain should also be arranged atthe bottom of the vent pipe. Any discharge through therelief valves should not enter work area or contactsource of ignition.

7.2 Handling

7.2.1 General

7.2.1.1 Hydrogen should be handled wearing anapproved respirator, chemical resistant gloves andsafety goggles and other protective clothing (see 6).

7.2.1.2 Sources of ignition such as smoking and openflames are prohibited where hydrogen is handled.

7.2.1.3 Safety recommendations and safe operatingprocedures should be strictly followed by the personshandling hydrogen.

7.2.2 Handling of Cylinders

7.2.2.1 Before filling the cy~nder with hydrogen,check and contlrm for its vdldlty. It shall have validtest certtilcate from the concerned authorities. Cylindermust be hydraulically tested before filling hydrogengas. Both seller and consumer must verifi that theperiod of date of testing is still valid.

7.2.2.2 Cylinders should never be subjected to roughhandling or to abnornral mechanical shock such asdropping, bumping, dragging or sliding. They shouldalways be kept in vertical position.

7.2.2.3 Ropes, slings, hooks, tongs and similar handlingdevices which may produce sparks or static electricityshould not be used during handling and use of hydrogencylinder.

7.2.2.4 A suitable hand truck, fork truck or similardevice to which the cylinders can be firmly securedshould be used for transporting the cylinders.

IS 15201:2002

7.2.2.5 While handling by crane or derrick, a suitableplatform, cradle or boat should be used. Use rack or

d

‘.,

chain to hold cylinders in place when hooked up fordischarging.

7.2.2.6 Do not place or handle cylinders where theymight form part of an electrical circuit.

7.2.2.7 Do not remove protection cap unless ready to‘1

withdraw hydrogen from the cylinder. Appropriate andstandard valves must be used. Explosive gas check of !valves and fittings should be done before usage.

‘i7.2.2.8 Use only standard colour code (Red colourwithout any band) for hydrogen cylinders (see IS 4379).

7.2.2.9 Cylinders for hydrogen, whether full or emptyshould never be used as rollers for moving heavy orbulky articles.

7.2.2.10 No one should tamper with numbers,markings, or test dates stamped on cylinders.

7.2.2.11 When the cylinder is empty, disconnect it,insert the valve plug and replace the cylinder protectivecap.

7.2.2.12 Store empty cylinders separate from filledcylinders and fasten an ‘EMPTY’ tag on cylindersimmediately upon emptying. Close valve, replace plugor nut on valve outlet and secure valve protecting capsnugly.

7.3 Labellinga) Any vessel containing hydrogen should carry an

identi~ing label or stencil. , ‘ ---’-A

b) Label should be as per rules and regulations.c) Each cylinder must be labelled with

‘FLAMMAELE GAS’ ‘CLASS 2’.

~j

7.4 Transportation

7.4.1 Labelling

Labels : Class 2 labels must be displayed on thetransport vehicle:

a) Compressed gas : UN No. 1049, andb) Refrigerated liquid : UN No. 1966.

7.4.2 Pre-departure Checks for Vehicles CarqyingHydrogen in Cylinders in Manifold Systems Mountedon Trucks

,

7.4.2.1 Prior to and after loading, the drivers must takea complete inspection of the vehicle to ensure that itmeets all performance safety requirements and isroadworthy for transporting hydrogen. A few of thenumerous items that are checked are the lights, tyres,suspensions and brakes.

7.4.2.2 The driver should maintain a log entry bookfor critical parameters like pressure, etc, during transit.

7.4.2.3 Ensure availability of fire extinguishers( DCP/carbon dioxide ) on the vehicle.

3

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IS 15201:2002

7.4.2.4 Ensureavailabilit yofemergency kit on thevehicle.

7.4.2.5 Ensure availability of transport emergency(TREM) card and instruction manual duringtransportation on the vehicle.

7.4.3 During Transportation

7.4.3.1 Do not smoke in the cabin. All sources ofignition must be kept away from the truck duringtmnsportation.

7.4.3.2 Driver should follow specified route only,maintain speed limit, never park the truck nearresident ia] areas, drive truck carefully and observe allrules and signals, avoid overtaking of moving vehiclesand do not leave the truck without watch at anytime.

7.4.3.3 No repairs involving gas cutting, welding, etc,should be done during transportation period. If requiredat all, repairs should be done by authorized andcompetent personnel of maintenance departnlent/plantwho are deputed by manufacturer/supplier.

7.4.3.4 The driver should physically inspect completemounting periodically and immediately report anyabnormality to the supplier.

7.4.3.5 In case of emergency (for example leaks, fires,accident, etc) follow the instructions mentioned in the‘Instruction manual during transportation’ to controland mitigate an emergency. Immediately contactnu]nufacturer/supplier, police, RTO, fire brigade andother local authorities.

7.4.4 Drivers Training

7.4.4.1 The basics of any effective safety programmefor transportation of hydrogen is adequate training.

7.4.4.2 Each driver must be cmefidly selected andreceive adequate amount of classroom training, audio-visual instructions and job training. The trainingmust be done at certified regional training institutes.Management must personally qualifi each driverbefore he is allowed to deliver hydrogen.

7.4.4.3 Systematic traininghetraining and reviews mustbe carried out to ensure that proficiency is maintained.Drivers must be trained in the following:

a) Safe driving methods;b) Actions to be taken during emergencyc) Proper use of fire extinguishers, emergency kits,

TREM cards, instruction manuals, etc; andd) Communication with manufacturer/supplier.

8 SPILLAGE, LEAKAGE AND WASTEDISPOSAL

8.1 SIJill:lge/Leill{t~ges

8.1.1 Frequent inspections of equipment, containersand vessels containing hydrogen should be made todetect or prevent leaks.

8.1.2 If spills or leaks of hydrogen occur, only properlyprotected personnel should remain in the area and entryto”others should be restricted.

8.1.3 Eve~ organization handling hydrogen must forman emergency response team, which is available roundthe clock. Spills or leaks should be handled by theemergen~ response team specially trained to handleemergency situations.

8.1.4 If spills or leaks develop, take measures to hasten I~,

the dissipation of harmful vapours.

8.1.5 In case of a major spill or equipment rupture, theexposed area should be evacuated and unprotectedpersonnel must not re-enter the area unless declaredsafe.

8.1.6 Proper respirato~protection should be providedfor use by personnel entering the area for testsor to repair damaged equipment as high hydrogenconcentration may exist.

8.1.7 Stop flow of gas/shut off leak, if it can be donewithout risk.

8.1.8 If source of a leak is a cylinder and the leak cannotbe stopped in place, remove the leaking cylinder to asafe place in the open air, and repair leak or allow thecylinder to empty.

8.1.9 In both gas or liquid spills, remove all ignitionsources.

8.2 Evacuation

If the release is not contained in an appropriate device ..-.

or system, all personnel not appropriately protectedmust evacuate the contaminated spaces. Evacuationof additional areas should be considered as a precaution jagainst the spread ofthe release or subsequent explosionor fire.

8.3 Waste Disposal

To be burnt under control condition.

9 FIRE PREVENTION AND FIRE FIGHTING

9.1 General

Open flames;Electrical equipments;Electrostatic sparks;Sparks from striking objects;FrictiorKThermite sparks;Air or oxygen, other oxidants;Hot surfaces;Hot hydrogen leaking into ambient aiq dndCatalytic surfaces.

Hydrogen is highly flammable. Hydrogen flame isalmost invisible and can cause severe explosions. It iseasily ignited with many sources of energy, some ofwhich are listed below:

a)b)c)d)e)

f)g)h)

j)k)

4

I I

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9.2 Fire Prevention

9.2.1 Minimize all potential sources of leaks.

9.2.2 Eliminate as far as possible all sources of ignition.

9.2.3 Make provision for isolation of hydrogen, meansof escape and methods of controlling any fire.

9.2.4 Adequate means of detecting fire and giving earlywarning, alarms in the event of fire shall be provided.

!).2.5 Emergency Response Procedures and Systems

9.2.5.1 Full emergency procedures and systems shallbe established andperiodic rnockdrill sshouldbecarried out.

9.2.5.2 The emergency response team must be welltrained with respect to ‘Do’s’ and ‘Don’ts’, standardoperating procedures (SOP), mitigation systems andhazards of hydrogen handling.

9.3 Fire Fighting

9.3.1 For Spill.r Which have not Ignited

If a spill has not ignited, use water spray to directflammable gas-air mixtures away from sources ofignition.

9.3.2 For Spill.~ Which have Ignited

9.3.2.1 Hydrogen flame is almost invisible. Thereforeproper care should be taken while approaching anyflames for tire fighting.

9.3.2.2 Stop flow of the gas, if possible.

9.3.2.3 Because of danger of re-ignition, hydrogen firesnormally should not be extinguished until the supplyof hydrogen has been shut off. Flashback along trailmay’ OCCL1r.

9.3.2.4 If the flow cannot be stopped, allow the contentsof the cylinder to burn under control.

9.3.2.5 If liquid hydrogen has ignited, use water tokeep fire exposed containers cool and to protect mentrying to stop the source of a spill.

10 TRAINING AND HEALTH MONITORING

10.1 Training

10.1.1 All personnel engaged in the operation,maintenance and attending emergency of hydrogen andrelated systems shall receive training suitable for the\vork on which they are engaged.

10.1.2 Training shall be armnged to cover all theaspects and potential hazards that the particular operatoris likely to encounter. Training shall cover thefol lo\ving areas:

a) The potential hazards of hydrogen,

IS 15201:2002

b) Site safety regulations,c) Emergency response procedures (leaks/spills/

evacuation),

d) Use of tire fighting equipment,

e) Use of protective clothing/apparatus includingbreathing sets where required,

f) First aid, andg) Rescue operations.

10.1.3 In addition, individuals shall receive specifictraining in the activities for which they are employed.Refresher courses should be arranged on a periodicbasis. Older employees should be re-educated.

10.1.4 Each employee should know the location andcorrect operation of gas and fire alarm systems,sprinklers, monitors and other fire fighting equipment.They should know the location of safety showers, eyewashes and first aid boxes.

10.2 Health Monitoring

10.2.1 Personal Hygiene

Employees should take a bath daily after finishing work.Eating, drinking or storing of food should be prohibitednear the place where hydrogen is handled.

10.2.2 Physical Examination

10.2.2.1 Preplacement physical examinatiorz.v

Proper preplacement medical examinations of apersonnel should be carried out to determine the,physical fitness before assigning the job.

10.2.2.2 Periodic examination

Annual medical examination should be carried out asrequired by laws/regulations (Factories .4et/StateFactories Rules).

11 FIRST AID AND MEDICAL TREATMENT

11.1 General Principles

First aid treatment should be started at once in all casesof contact with hydrogen in any form or injury mayresult. Refer all injured persons to a physician evenwhen the injury appears to be slight. Give the physiciana detailed account of the accident.

11.2 First Aid Treatment

11.2.1 Inhalation /

Inhalation of hydrogen gas causes asphyxiation.Remove the affected person from exposure/contamination area. Place him in the recovery positionas necessary. If breathing has stopped begin rescuebreathing. If heart action has stopped begin CPR.If medical oxygen and trained personnel are available,administer oxygen to the affected person. If un-

5

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M 15201:2002

conscious, donotgive anything to drink. If conscious 11.2.3 Eyesmake the affected person lie or sit down quietly.

Treat for frostbite.11.2.2 Skin Contact With Liquid Hydrogen

11.2.4 AntidotelDosagesTreat for frost bite. Soak the affected part in luke warmwater. Seek medical attention. No specific antidote is available.

ANNEX A

( Foreword)

COMMITTEE COMPOSITION

Industrial Safety and Chemical Hazards Sectional Committee, CHD 8

Organization

National Safety Council, Mumbai

Airports Authority of India, New Delhi

Atomic Energy Regulatory Board, Mumbai

Bhabha Atomic Research Centre, Mumbai

(lmtral 130iler Board, New Delhi

Century Rayon, Thane

Central Leather Research Institute, Chennai

Central Mining Research Institute, Jharkhand

Centml Warehousing Corporation, New Delhi

Confederation of Indian Industries, New Delhi

Dcpartmerrt of Explosives, Nagpur

Department of Industrial Policy and Promotion,Ncw Delhi

Development Commissioner (SS1), New Delhi

Directorate General of Health Services, New Delhi

Directorate General Factory Advice Service andLhwr Institutes, Mumbai

Directorate of Industrial Safety and Health,(Factory Inspectorate), Mumbai

Directorate General of Mines Safety, Dhanbad

Employees State Insurance Corporation, New Delhi

EXCCIindustries Limited, Mumbai

I [industan Aeronautics Limited, Bangalore

I{industan Lever Limited, Mumbai

Indian institute of Chemical Technology, Hyderabad

Indian (Memical Manufacturers Association, Mumbai

Indian Drugs and Pharmaceuticals Limited, Rishikesh

Indian Petrochemical Corporation Limited, Vadodara

Indian Space Research Organization, Sriharikota

industrial ‘1’oxicology Research Centre, Lucknow

Ministry of Defence (DGQA), New Delhi

Representative(s)

SHRIK.C. GUPTA(Chairman)

REPRESENTATIVE

SHRIP. K. GHOSH

DR B. N. RATHI

REPRESENTATIVE

SHRIH. G. UITAMCHANDANISHRIS. K. MISHRA(Alternate)

REPRESENTATIVE

SHRIJ. K. PANDEY

REPRESENTATIVE

REPRESENTATIVE

REPRESENTATIVE

DR D. R. CHAWLA

Representative

REPRESENTATIVE

DR A. K. MAJUMDARSHRIS. P. RANA(Alternate)

REPRESENTATIVE

DIRECTOROF MrNESSAFETY(MSE)DEPUTYDIRECTOROF MINES SAFETY

(HQ) (Alternate)

REPRESENTATIVE

REPRESENTATIVE

SHRIB. B. DAVESHRIADITYAJHAVAR(Alternate)

SHRI S. VENKATESWARARAO

SHRIV. N. DASSHRIA. A, PANJWANI(Alternate)

REPRESENTATIVE

SHRIP. VUAYRAGHAVANSHRIM. R. PATEL(Alternate 1)SHRIA. V. SARATHY(Alternate 11)

SHRIP. N. SANKARANSHRIV. K. SRIVASTAVA(Alternale)

Dr VIRENDRAMISRADr V. P. SHARMA(Alternate)

SHRIM. S. SULTANIASHRISUJITGHOSH(Alternate)

(Continued on page 7)

6

,-.. .-’

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(Continuedfiom page 6)

Organization

Ministry of Ddknce, Directorate of Standardization,New Delhi

Ministry of Defence (OFB), Kolkata

Ministry of Defence (R&D), Kanpur

Ministry of Environment and Forest, New Delhi

National Institute of Occupational Health, Ahmedabad

National Organic Chemical Industries Limited, Thane

National Safety Council, Mumbai

Oil Industry Safety Directorate, New Delhi

Safety Appliances Manufacturers Association, Mumbai

Standing Fire Advisory Council, New Delhi

Steel Authority of India Limited, Ranchi

SIEL Chemical Complex, New Delhi

Southern Petrochemical Industries Corporation Limited,Tuticorin

Tata Al(l Risk Management Services Limited, Mumbai

BIS Directorate General

IS 15201:2002

Representative(s)

SHRIP. S. AHUJALT-COL TEJrNDERSIIWH(Alternate)

DR D. S. S. GANGULYSHRI R. SRINIVASAN(Alternate)

DR A. K. SAXENADR RAJmDRASINGH(Alternate)

REPRESENTATWE

RepreSentatiVe

DR B. V. BAPATSHRIV. R. NARLA (Alternate)

SHRIP. M. RAOSHRID. BISWAS(Alternate)

SHRIS. K.C~AKItABARTISHRIV. K. SRIVASTAVA(A1/ernate)

REpRESENTAmvE

Representative

REPRESENTATIVE

REPRESENTATIVE

SHRIV. JAYARAMANSHRI S. MURUGANADAM(Alternate)

SHRIURMISHD. SHAH’

SHRI S. K. CHAUDHURI,Director& Head (CHD)[ Representing Director General (llr-o@cio) ]

h4ember SecretaySHRIN. K. PAL

Director (CHD), BIS

Page 13: IS 15201 (2002): Hydrogen - Code of Safety · p, ;, ,-is 15201:2002 indian standard hydrogen — code of safety ics 13.300;11.100.20 c)bis 2002 bureau of indian standards manak bhavan,

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Bureau of Indian Standards

BISis:i st:ltutoq institution established under the Bureuuo~lndian .7tandards Act, 1986 topronlote harnloniousdevelopment of the activities of standardizal ion, marking and quality certification of goods and attending toconnected matters in the country.

Copyright

BIS has the copyright of all its publications. No part of these publications may be reproduced in any formwithout the prior permission in writing of BIS. This does not preclude the free use, in the course of implementingthe standard, of necessary details, such as symbols and sizes, type or grade designations. Enquiries relating tocopyright be addressed to the Director (Publication), 131S.

Review of Indian Standards

Amendments are issued to standards as the need arises on the basis of comments. Standards are also reviewedperiodically; a standard along with amendments is reafllrmed when such review indicates that no changes areneeded: if the review indicates that changes are needed, it is taken up for revision. Users of Indian Standardsshould ascertain that they are in possession of the latest amendments or edition by referring to the latest issue of‘BIS Catalogue’ and’ Standards: Monthly Additions’.

This Indiml Standard has been developed from Dot: No. CHD 8 (1033).

Amendments Issued Since Publication

Amend No. Date of Issue Text Affected

BUREAU OF INDIAN STANDARDSHeadquarters:

Manak Bhavan, 9 Bahadur Shah Zafar Marg, New Delhi 110002 Telegrams: ManaksansthaTelephones: 3230131,3233375, 3239402 (Common to all offices)

Regional Offices: Telephone

Central :

Eastern :

Northern :

Southern :

Western :

Branches :

Manak Bhavan, 9 Bahadur Shah Ztiar Marg 3237617,3233841NEW DELHI 110002

1/14 C.I.T. Scheme VII M, V.I.P. Road, Kankurgachi{

3378499,3378561KOLKATA 700054 3378626,3379120

SCO 335-336, Sector 34-A, CHANDIGARH 160022{

603843602025

C.I,T. Campus, IV Cross Road, CHENNAI 600113{

2541216,25414422542519,2541315

Manakalaya, E9 MIDC, Marol, Andheri (East){

8329295>8327858MUMBAI 400093 8327891,8327892

AHMEDABAD. BANGALORE. BHOPAL. BHUBANESHWAR. COIMBATORE. FARIDABAD.GHAZIABAD. GUWAHATI. HYDERA13AD. JAIPUR. KANPUR. LUCKNOW. NAGPUR.NALAGARH. PATNA. PUNE. RAJKOT. THIRUVANANTTMF’URAM. VISAKHAPATNAM.

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Printed at Sirmo Printing Press, Delhi