jee 2010 bt
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SOLUTIONS TO IIT-JEE 2010Paper-I (Code: 8)
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
INSTRUCTIONSA. General:
1. This Question Paper contains 28 pages having 84 questions. The question paper CODE isprinted on the right hand top corner of this sheet and also on the back page of thisbooklet.
2. No additional sheets will be provided for rough work.3. Blank papers, clipboards, log tables, slide rules, calculators, cellular phones, pagers and
electronic gadgets in any form are not allowed.
4. The answer sheet, a machine-gradable Objective Response Sheet (ORS), is providedseparately.
5. Write your Registration No., Name and Name of centre and sign with pen in appropriateboxes. Do not write these anywhere else.
B. Question paper format and Marking scheme:6. The question paper consists of 3 parts (Chemistry, Mathematics and Physics). Each part
consists offour Sections.
7. For each question in Section I, you will be awarded 3 marks if you have darkened onlythe bubble corresponding to the correct answer and zero mark if no bubbles aredarkened. In all other cases, minus one (1) markwill be awarded.
8. For each question in Section II, you will be awarded 3 marks if you darken only thebubble(s) corresponding to the correct answer and zero mark if no bubbles are darkened.Partial marks will be awarded for partially correct answers. No negative marks will beawarded in this Section.
9. For each question in Section III, you will be awarded 3 marks if you darken only thebubble corresponding to the correct answer and zero mark if no bubbles are darkened. Inall other cases, minus one (1) markwill be awarded.
10. For each question in Section IV,you will be awarded 3 marks if you darken the bubblecorresponding to the correct answer and zero mark if no bubble is darkened. No negativemarkswill be awarded in this Section.
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SOLUTIONS TO IIT-JEE 2010CHEMISTRY: Paper-I (Code: 8)
PARTI
Useful Data
Atomic numbers: Be = 4; C = 6; N = 7; O = 8; Al = 13; Si = 14; Cr = 24; Fe = 26; Zn = 30; Br = 35.
1 amu= 1.66 1027 kg R = 0.082 L atm K1 mol1
h = 6.626 1034 Js NA = 6.022 1023
me = 9.1 1031 kg e = 1.6 1019 C
c = 3.0 108 m s1 F = 96500 C mol1
RH = 2.18 1018 J 4o = 1.11 10
10 J1 C2 m1
SECTION I
Single Correct Choice Type
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D), out of which
ONLY ONE is correct.
Note: Questions with (*) mark are from syllabus of class XI.
1. Plots showing the variation of the rate constant (k) with temperature (T) are given below. The plot that follows Arrheniusequation is
(A) k
T
(B) k
T
(C) k
T
(D) k
T
Sol.: As per Arrhenius equation ),Aek(RT/Ea the rate constant increases exponentially with temperature.
Correct choice: (A)
2. In the reaction OCH3HBr the products are
(A) OCH3 and H2Br (B) Br and CH3Br
(C) Br and CH3OH (D) OH and CH3Br
Sol.: OCH3H+
OCH3
H
+ BrOH + CH3Br
Correct choice: (D)
3. The correct statement about the following disaccharide is
HO
H
OH
H
HO
H
H
CH2OH
OHOH
H
H
HO
HOH2C
OCH2CH2O
(a)
H
CH2OH
O
(b)
(A) Ring (a) is pyranose with -glycosidic link. (B) Ring (a) is furanose with -glycosidic link.
(C) Ring (b) is furanose with -glycosidic link. (D) Ring (b) is pyranose with -glycosidic link.
Sol.: Correct choice: (A)
*4. The synthesis of 3-octyne is achieved by adding a bromoalkane into a mixture of sodium amide and an alkyne. The
bromoalkane and alkyne respectively are
(A) BrCH2CH2CH2CH2CH3 and CH3CH2CCH (B) BrCH2CH2CH3 and CH3CH2CH2CCH
(C) BrCH2CH2CH2CH2CH3 and CH3CCH (D) BrCH2CH2CH2CH3 and CH3CH2CCH
Sol.: H3CH2CCHNaNH2
NH3CH3CH2CC
Na+CH3CH2CH2CH2Br
(SN2)CH3CH2CCCH2CH2CH2CH3 + NaBr
3-Octyne
Correct choice: (D)
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5. The ionization isomer of [Cr(H2O)4Cl(NO2)]Cl is
(A) [Cr(H2O)4(O2N)]Cl2 (B) [Cr(H2O)4Cl2](NO2)
(C) [Cr(H2O)4Cl(ONO)]Cl (D) [Cr(H2O)4Cl2(NO2)].H2O
Sol.: Ionization isomer of [Cr(H2O)4Cl(NO2)]Cl is [Cr(H2O)4Cl2]NO2.
Correct choice: (B)
6. The correct structure of ethylenediaminetetraacetic acid (EDTA) is
(A)HOOCH2C
NCH=CHNHOOCH2C
CH2COOH
CH2COOH(B)
HOOCNCH2CH2N
COOH
COOHHOOC
(C) NCH2CH2NHOOCH2C
HOOCH2C
CH2COOH
CH2COOH(D) NCHCHN
HOOCH2C
H CH2COOH
CH2
COOH
CH2
HOOC
H
Sol.: The correct structure of EDTA is
NCH2CH2NHOOCH2C
HOOCH2C
CH2COOH
CH2COOH
Correct choice: (C)
*7. The bond energy (in kcal mol1) of a CC single bond is approximately
(A) 1 (B) 10 (C) 100 (D) 1000
Sol.: CC bond energy = 348 kJ/mol2.4
348kcal/mol = 82.85 kcal/mol 100 kcal/mol.
Correct choice: (C)
*8. The species which by definition has ZERO standard molar enthalpy of formation at 298 K is
(A) Br2 (g) (B) Cl2 (g) (C) H2O(g) (D) CH4 (g)
Sol.: The species in its elemental form has zero standard molar enthalpy of formation at 298 K.
Br2(l) Br2(g) ;ofH 0
C(s) + 2H2(g) CH4(g) ;o
f
H 0
H2(g) + O2(g) H2O(g) ;ofH 0
Correct choice: (B)
SECTIONII
Multiple Correct Choice Type
This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which
ONE OR MORE is/are correct.
9. In the reaction
OH
NaOH(aq)/Br2the intermediate(s) is(are)
(A)
Br
BrO
(B)
Br
O
Br
(C)
Br
O
(D)
Br
O
Sol.:
OH
NaOH
O
Br2
O
Br2Br
O
Br
Br2Br
O
Br(I) (II) (III) (IV)
Br
Br
H2O Br
Br Br
Product of reaction of phenol with NaOH/Br2 is sodium salt of 2,4,6-tribromophenol. Hence, species (I), (II), (III) are formed
as intermediate.
Correct choice: (A), (C)
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*10. Among the following, the intensive property is (properties are)
(A) molar conductivity (B) electromotive force (C) resistance (D) heat capacity
Sol.: Mass independent properties are intensive properties. Resistance and heat capacity are extensive properties.
Correct choice: (A), (B)
*11. The reagent(s) used for softening the temporary hardness of water is(are)
(A) Ca3(PO4)2 (B) Ca(OH)2 (C) Na2CO3 (D) NaOCl
Sol.: Temporary hardness is due to bicarbonates of calcium and magnesium. Temporary hardness can be removed by Clarksprocess, which involves the addition of slaked lime, Ca(OH) 2. Washing soda (Na2CO3) removes both the temporary and
permanent hardness by converting soluble calcium and magnesium compounds into insoluble carbonates.
Ca(HCO3)2 + Ca(OH)2 2CaCO3 + 2H2O
Ca(HCO3)2 + Na2CO3 CaCO3 + 2NaHCO3
2OCl + 2H2O 2HOCl + 2OH
Ca(HCO3)2 + 2OH CaCO3 +
23CO + 2H2O
Correct choice: (B), (C), (D)
*12. Aqueous solutions of HNO3, KOH, CH3COOH and CH3COONa of identical concentrations are provided. The pair(s) of
solutions which form a buffer upon mixing is(are)
(A) HNO3 and CH3COOH (B) KOH and CH3COONa
(C) HNO3 and CH3COONa (D) CH3COOH and CH3COONaSol.: Any solution of a weak acid and its salt with strong base acts as an acidic buffer solution.
If volume of HNO3 solution added is less as compared to that of CH3COONa solution, it results in the formation of an acidic
buffer solution.
CH3COONa + HNO3 CH3COOH + NaNO3
Excess limiting
reagent
MV MV
M(VV) 0 MV MV (V < V)
Correct choice: (C), (D)
*13. In the Newman projection for 2,2-dimethylbutane
X
H H
Y
H3C CH3
X and Y can respectively be
(A) H and H (B) H and C2H5 (C) C2H5 and H (D) CH3 and CH3
Sol.: Structural formula of 2, 2-dimethylbutane is
CH3CCH2CH3
CH3
CH3
1 2 3
(I) Newman projection using C1
C2
bond
H
H H
C2H5
H3C CH3
1
2
(II) Newman projection using C3C2 bond
H H
CH3
CH3 CH3
3
2
CH3
Correct choice: (B), (D)
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SECTION IIIParagraph Type
This section contains 2 paragraphs. Based upon the first paragraph 3 multiple choice questions and based upon the second
paragraph 2 multiple choice questions have to be answered. Each of these questions has four choices A), B), C) and D) out
of which ONLY ONE is correct.
Paragraph for Question 14 to 16
Copper is the most noble of the first row transition metals and occurs in small deposits in several countries. Ores of copper
include chalcanthite (CuSO4.5H2O), atacamite (Cu2Cl(OH)3), cuprite (Cu2O), copper glance (Cu2S) and malachite
(Cu2(OH)2CO3). However, 80% of the world copper production comes from the ore chalcopyrite (CuFeS2). The extraction of
copper from chalcopyrite involves partial roasting, removal of iron and self-reduction.
14. Partial roasting of chalcopyrite produces
(A) Cu2S and FeO (B) Cu2O and FeO (C) CuS and Fe2O3 (D) Cu2O and Fe2O3
Sol.: 2CuFeS2 + 4O2 C14501400
Cu2S + 3SO2 + 2FeO
Partial roasting of FeS and Cu2S produces FeO and Cu2O respectively.
2FeS + 3O2 2FeO + 2SO2
2Cu2S + 3O2 2Cu2O + 2SO2
Correct choice: (B)15. Iron is removed from chalcopyrite as
(A) FeO (B) FeS (C) Fe2O3 (D) FeSiO3
Sol.: FeO + SiO2 FeSiO3Correct choice: (D)
16. In self-reduction, the reducing species is
(A) S (B) O2 (C) S2 (D) SO2
Sol.: Cu2S + 2Cu2O 6Cu + SO2The reducing species is the one which gets oxidized. So, it is S2ion getting oxidized to S4+.
Correct choice: (C)
Paragraph for Question 17 to 18
The concentration of potassium ions inside a biological cell is atleast twenty times higher than the outside. The resulting
potential difference across the cell is important in several processes such as transmission of nerve impulses and maintaining
the ion balance. A simple model for such a concentration cell involving a metal M is
M(s) | M+(aq; 0.05 molar) || M+(aq; 1 molar) | M(s)
For the above electrolytic cell the magnitude of the cell potential |Ecell| = 70 mV.
17. For the above cell
(A) Ecell < 0; 0G (B) 0G;0Ecell (C) 0G;0Ecell (D) 0G;0Ecell
Sol.: (A): M(s) e)aq(MA
(C): )s(Me)aq(MC
)aq(M)aq(M AC
]M[
]M[ln
F
RT
]M[
]M[ln
F
RTEE
A
C
C
Aocellcell
)0E( ocell
Ecell = 0.059 log05.0
]M[ C
0.07V = 0.05905.0
)M(log C
= 0.059 log 20 ]M[ C = 0.059 (log 20 + log ]M[ C
)
Since ]M[ C is greater than 0.05 M, so Ecell is +ve.
Ecell > 0 & .0G Correct choice: (B)
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18. If the 0.05 molar solution of M+ is replaced by a 0.0025 molar M+ solution, then the magnitude of the cell potential would be
(A) 35 mV (B) 70 mV (C) 140 mV (D) 700 mV
Sol.: Ecell = 0.0590025.0
]M[log C
= 0.059 log 400 ]M[ C = 0.059 log (20)2 ]M[ C
= 0.059(2 log 20 + log ]M[ C )
= 0.059
59.0
07.02 = 0.14 V = 140 mV.
Correct choice: (C)
SECTIONIVInteger Answer Type
This section contains TEN questions. The answer to each questions is a single digit integer ranging from 0 to 9.
The correct digit below the question number in the ORS is to be bubbled.
19. In the scheme given below, the total number of intramolecular aldol condensation products formed from Y is
1. O32. Zn, H2O Y
1. NaOH(aq)2. heat
Sol.:
1. O32. Zn, H2O
NaOH(aq)
O
O
(Y)
OH
O
heat
H2O
O
The number of intramolecular aldol condensation products (, -unsaturated carbonyl compound) formed from (Y) is 1.
The answer is 1.
20. Amongst the following, the total number of compounds soluble in aqueous NaOH is
NCH3H3C COOH OCH2CH3
CH2OH
OH
NO2 OH
CH3H3CN
CH2CH3
CH2CH3
COOH
Sol.: All carboxylic acids and phenols are soluble in aqueous NaOH. Four compounds are soluble in aqueous NaOH.
The answer is 4.
*21. Amongst the following, the total number of compounds whose aqueous solution turns red litmus paper blue is
KCN K2SO4 (NH4)2C2O4 NaCl Zn(NO3)2
FeCl3 K2CO3 NH4NO3 LiCN
Sol.: KCN, K2CO3 and LiCN are the salts of weak acid and strong base. So, their aqueous solutions turns red litmus paper blue.
(NH4)2C2O4 is a salt of weak base (NH4OH ; Kb = 1.8 105) and weak acid (HOOC.COOH ;
1aK = 5.4 102 and
2aK = 5.2 105 ). As a result, the extent of hydrolysis of
4NH will be more than that of
242OC and hence the resulting
solution will be acidic.The answer is 3.
*22. Based on VSEPR theory, the number of 90 degree FBrF angles in BrF5 is
Sol.: According to VSEPR theory, number of electron pairs around central atom (Br) are 6.
2
N=
2
57 = 6. (Five are bond pairs and one is lone pair )
Its geometry is octahedral but due to lone pairbond pair repulsion, thefour fluorine atoms at corner are forced towards the upper fluorine atom
thus reducing FBrF angle from 90 to 84.8.
F
..F
F
F
Br
F
The answer is 0.
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*23. The value of n in the molecular formula BenAl2Si6O18 is
Sol.: It is the formula of Beryl (which has BeO, Al2O3 and SiO2).
The formula of Beryl should be
3BeO. Al2O3.6SiO2
Or
Total cationic charge = Total anionic charge
2n + 6 + 24 = 36
n = 3
The answer is 3.
*24. A student performs a titration with different burettes and finds titre values of 25.2 mL, 25.25 mL, and 25.0 mL. The number
of significant figures in the average titre value is
Sol.: The least significant figure in titre values is 3.
Average titre value = 1.253
4.75
3
2525.252.25
The number of significant figures in average titre value will also be 3.
The answer is 3.
25. The concentration of R in the reaction PR was measured as a function of time and the following data is obtained:
[R] (molar) 1.0 0.75 0.40 0.10
t(min.) 0.0 0.05 0.12 0.18
The order of reaction is
Sol.: The integrated form of a zero-order reaction is
[A0][At] = k0t
1.00.75 = k0 0.05, k0 = 5
1.00.4 = k0 0.12, k0 = 5
The answer is 0.
26. The number of neutrons emitted when U23592 undergoes controlled nuclear fission to Xe14254 and Sr
9038 is
Sol.: 1090
38142
541
0235
92 nySrXenU
235 + 1 = 142 + 90 + yy = 4. The number of neutrons emitted are (41) = 3.
The answer is 3.
*27. The total number of basic groups in the following form of lysine is
CHC
H3NCH2CH2CH2CH2 O
H2N O
Sol.: The basic groups in the given form of lysine is NH2 and2CO . The answer is 2.
*28. The total number of cyclic isomers possible for a hydrocarbon with the molecular formula C4H6 is
Sol.: The number of cyclic isomers for a hydrocarbon with molecular formula C4H6 is 5.
The structures are
, , and,
CH2CH3
CH3.
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SOLUTIONS TO IIT-JEE 2010MATHEMATICS: Paper-I (Code: 8)
PARTII
SECTION I
Single Correct Choice Type
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) for itsanswer, out of which ONLY ONE is correct.
29. The value of
x
xdt
t
tt
x0
430 4
)1ln(1lim is
(A) 0 (B)12
1(C)
24
1(D)
64
1
Sol.:
dt
t
tt
x
x
x
0 430 4
1ln1lim
form
0
04
1ln
lim
3
0
4
0 x
dtt
ttx
x
Applying L. Hospital Rule
431ln
lim3
4
1ln
lim402
4
0
xx
x
x
x
xx
xx
12
1
4
1lim
1lnlim
3
1
400
xx
x
xx
Correct choice: (B)
30. The number of 33 matricesA whose entries are either 0 or 1 and for which the system A
0
0
1
z
y
x
has exactly two distinct
solutions, is
(A) 0 (B) 129 (C) 168 (D) 2
Sol.: For any matricesA it form three planes. But three planes can not intersect exactly at two distinct points.
Correct choice: (A)
31. Let P, Q, R and S be the points on the plane with position vectors ,2 ji jii 33,4 and ji 23 respectively. The
quadrilateral PQRS must be a
(A) parallelogram, which is neither a rhombus nor a rectangle (B) square
(C) rectangle, but not a square (D) rhombus, but not a square
Sol.: IfO is origin jiOSjiORiOQjiOP 23;33;4;2
jiOQOSQS 27
jiPR 45
53449 QS ; 411625 PR
376 jiPQ ; 103 jiQR
376 jiRS ; 103 jiSP
Opposite sides are parallel and equal but diagonals are not equal.
Correct choice: (A)
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32. Let be a complex cube root of unity with 1 . A fair die is thrown three times. If 21, rr and 3r are the numbers obtained
on the die, then the probability that 321 rrr = 0 is
(A)18
1(B)
9
1(C)
9
2(D)
36
1
Sol.: 21663 Sn
Eis the event that 0321 rrr , is possible if one among 321 ,, rrr is of the form n3 ; another one is of the form
13 n and the remaining one is of the form 23 n , where Zn .
For n3 , two possible cases are 3, 6
For 13 n , two possible cases are 1, 4
For 23 n , two possible cases are 2, 5
48!3222 En
9
2
216
48
Sn
EnEP
Correct choice: (C)
33. Equation of the plane containing the straight line432
zyx and perpendicular to the plane containing the straight lines
243
zyx and
324
zyx is
(A) 022 zyx (B) 0223 zyx (C) 02 zyx (D) 0425 zyx
Sol.: Plane 2P contains the lineL 432
zyx
Plane 1P contains the lines 1L and 2L , where
2431
zyxL and
3242
zyxL
Let direction ratio of normal to the plane 1P is ,, , then
0243 and 0324
1018
Let direction ratio of normal of required plane is (a, b, c), then 0108 cba ; 0432 cba
265226
cba
121
cba
Required plane is 02 zyx
Correct choice: (C)
Alternative:
cbabcacban ..
kjikji 3242624326 kji 265226 direction ratio of normal of required plane is 1,2,1
Equation is 02 zyx
*34. If the angles BA, and C of a triangle are in an arithmetic progression and if a, b and c denote the lengths of the sides
opposite to BA, and Crespectively, then the value of the expression Aa
cC
c
a2sin2sin is
(A)
2
1(B)
2
3(C) 1 (D) 3
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Sol.: SinceA, B, Care in A.P.
CAB 2
180CBA
1803B 60B
Aa
c
Cc
a
2sin2sin
AAA
CCC
C
Acossin2
sin
sincossin2.
sin
sin 120sin22sin2sin2cossinsincos2 BCAACAC
32
32
Correct choice: (D)
35. Let f, g and h be real-valued functions defined on the interval [0, 1] by22
)( xx eexf ,22
)( xx exexg and
222)( xx eexxh . Ifa, b and c denote, respectively, the absolute maximum off, g and h on [0, 1], then
(A) ba and bc (B) ca and ba (C) ba and bc (D) cba
Sol.: 22 xx
eexf
22
2 xx eexxf
22 xx exexg
222
2 xxx eexexxg
222 xx eexxh
222
223 xxx eexexxh
for ]1,0[x
xgxf , and 0 xh
xgxf , and xh will be increasing functions and their maximum values are
e
ec
e
eb
e
ea1
,1
,1
at 1x
cba
Correct choice: (D)
Alternative:
],1[]1,0[as1 2
2
2
eex
e
exf x
x
x
],1[,1
ett
ttf ; e
etf1
max
max e
exf1
xfxgxh
e
exg1
but at 1x , e
exg1
and similarly at 1x , xh e
e1
So, cba
*36. Let p and q be real numbers such that qpp 3,0 and qp 3 . If and are nonzero complex numbers satisfying
p and q 33 , then a quadratic equation having
and
as its roots is
(A) 0)()2()( 3323 qpxqpxqp (B) 0)()2()( 3323 qpxqpxqp
(C) 0)()25()( 3323 qpxqpxqp (D) 0)()25()( 3323 qpxqpxqp
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Sol.: p (i)
q 33 (ii)
Sum of roots
2
222
S (iii)
Product of roots P = 1
From (i) and (ii) 22pq
32pq p
pq
3
3
3
3
3
33
3
32
2223
3
3
2
pq
qp
pq
pqp
p
pq
p
pqp
S
Required quadratic equation is 02 PSxx
02 3323 pqxqpxpq Correct choice: (B)
SECTIONIIMultiple Correct Choice Type
This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D) for its answer, out of
which ONE OR MORE may be correct.
*37. Let ABC be a triangle such that6
ACB and let a, b and c denote the lengths of the sides opposite to A, B and C
respectively. The value(s) ofx for which 1,1 22 xbxxa and 12 xc is (are)
(A) 32 (B) 31 (C) 32 (D) 34
Sol.:
1121211
6cos
22
22222
xxx
xxxx
112
123
2
3
22
2222
xxx
xxxxx
1213 22 xxxxx 0313232 2 xx
322
3132432322
x 31,32
But 32 x (as 0,, cba 1x )Correct choice: (B)
38. Letfbe a real-valued function defined on the interval ),0( by dttxxf
x
0
sin1ln)( . Then which of the following
statement(s) is (are) true?
(A) )('' xf exists for all ),0( x
(B) )(' xf exists for all ),0( x and xf' is continuous on ),0( , but not differentiable on ),0(
(C) there exists > 1 such that |)(||)('| xfxf for all ),( x
(D) there exists > 0 such that |)('||)(| xfxf for all ),0( x
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Sol.: xx
xf sin11
Clearly xf exists and continuous for all 0x .
Also xf is not differentiable at point where 1sin x .
xgx
xxfxf 1ln , where xdttxgx
sin1sin1
0
Now dtt
x
0
sin1 is always continuous, increasing and has range ,0 .
So 0xg for some ,0k as 2sin1 x for ,0x
Also 01
ln x
x for ,kx
0 xfxf for all ,kkx
xfxf for all ,x , where kk Correct choice: (B), (C)
k1
y = lnx
y = 1/x
*39. LetA andB be two distinct points on the parabola xy 42 . If the axis of the parabola touches a circle of radius rhavingABas its diameter, then the slope of the line joiningA andB can be
(A)r
1 (B)
r
1(C)
r
2(D)
r
2
Sol.: Let mid-point ofAB is rh ,
Equation ofAB is
sincos
ryhx
SoA andB can be rh sin,cos
But these will satisfy xy 42
C(h, r)
y2 = 4x
B
A
xO
hr cos4sin 2
04cos2sin2sin 222 hrr Sum of roots = 0 CBAC
cos2sinr r
2tan
Correct choice: (C), (D)
Alternative:
Slope of21
2tt
AB
y-coordinate of mid-point of rttAB 21
slope ofAB can ber
2or
r
2
222 2, tt B
A
x
y
121 2, tt r
40. The value(s) of
1
0
2
44
1
)1(dx
x
xxis (are)
(A) 7
22(B)
105
2(C) 0 (D)
2
3
15
71
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Sol.: dx
x
xdxxdxxxdx
x
xxxI
1
0
2
61
0
5
1
0
24
1
0
2
224
1
441
1
21
7
224
3
4
5
4
3
2
7
1
5
1
1
114
6
4
7
1
5
11
0
2
24dx
xxx
Correct choice: (A)
*41. Let1Z
and 2z be two distinct complex numbers and let 21)1( tzztz for some real number twith 10 t . If Arg(w)
denotes the principal argument of a nonzero complex number w, then
(A) |||||| 2121 zzzzzz (B) )(Arg)(Arg 21 zzzz
(C) 01212
11
zzzz
zzzz(D) )(Arg)(Arg 121 zzzz
Sol.: 21 ,, zCzBzA are collinear
ACBCAB
2121 zzzzzz
21 zzArgzzArg
121 zzArgzzArg
Equation of line CBA ,, is 01212
11
zzzz
zzzz
Correct choice: (A), (C), (D)
SECTION IIIComprehension Type
This section contains 2 paragraphs. Based upon the first paragraph 3 multiple choice questions and based upon the secondparagraph 2 multiple choice questions have to be answered. Each of these questions has 4 choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.
Paragraph for Questions 42 to 44
Letp be an odd prime number and pT be the following set of 2 2 matrices :
}1.....,,2,1,0{,,: pcba
ac
baATp
42. The number ofA in pT such thatA is either symmetric or skew-symmetric or both, and det (A) divisible byp is
(A)2)1( p (B) )1(2 p (C) 1)1( 2 p (D) 12 p
Sol.: ForA to be symmetric cb
22 ba should be multiple ofp
)()( baba should be multiple ofp
Either )(or)( baba should be multiple ofp
ba can be multiple ofp in )1( p ways (excluding 0 ba )
)( ba can be multiple ofp inp ways (including 0 ba )
Total number of ways = 2p1
Correct choice: (D)
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43. The number ofA in pT such that the trace ofA is not divisible byp but det (A) is divisible byp is
[Note: The trace of a matrix is the sum of its diagonal entries.]
(A) )1)(1( 2 ppp (B) 23 )1( pp (C) 2)1( p (D) )2)(1( 2 pp
Sol.: As Atr is not amultiple ofp
0a
bca 2 will be a multiple ofp
if remainder ofp
a2
andp
bcis same.
Let when 2a divided byp remainder is r
when bc is divided byp for different values of }1...,1,0{ pc we get distinct remainder }1...,1,0{ p
there exist only one value ofb for which remainder ofbc divided byp gives r
a and c can be taken in )1( p ways each and b can be choose in only one way.
Total ways 1)1(2
p
Correct choice: (C)
44. The number ofA in pT such that det (A) is not divisible byp is
(A) 22p (B) pp 53 (C) pp 33 (D) 23 pp
Sol.: The total number ofAin3
pTp (i)
Now theA for which det A is divisible byp
Case-I: 0a
bc should be divisible byp
either 0b or 0c or both
total ways 12 p
Case-II: 0a
Total ways2)1( p [as in previous question]
Total number of ways = 121 2 pp 2p (ii)
Required ways = 23 pp
Correct choice: (D)
Paragraph for Questions 45 to 46
The circle 0822 xyx and hyperbola 149
22
yx
intersect at the pointsA andB.
*45. Equation of a common tangent with positive slope to the circle as well as to the hyperbola is
(A) 02052 yx (B) 0452 yx (C) 0843 yx (D) 0434 yx
Sol.: Let sin4,cos14 be a point on the circle.
Equation of tangent to the circle is cos14sincos yx = 0
sin
cos14
sin
cosxy (i)
Condition of tangency for hyperbola is
2222
bmac
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4sin
cos9
sin
cos116
2
2
2
2
020cos32cos3 2
3
2cos and 10 (rejected)
35sin
Slope of tangent from (i) is m =5
2
35
32
sin
cos
5
4
5
2;
35
3214
5
2
xyxy
425 xy 0452 yx
Correct choice: (B)
*46. Equation of the circle withAB as its diameter is
(A) 0241222 xyx (B) 0241222 xyx
(C) 0122422 xyx (D) 0122422 xyx
Sol.:22
8 xxy
14
8
9
22
xxx
369724 22 xxx 0367213 2 xx 03667813 2 xxx
0)6(6613 xxx 6,13
6 xx
Clearly 0,6 is the centre.
if 6x , 36482 y 122 y 32y
End points of diameter are 32,6,32,6 32r and 0,6C
126 22 yx 123612 22 yxx 0241222 xyx
Correct choice: (A)
SECTION IVInteger Answer Type
This section contains TEN questions. The answer to each of the questions is a single-digitinteger, ranging from 0 to 9. Thecorrect digit below the question numbers in the ORS is to be bubbled.
47. If a
and b
are vectors in space given by5
2 jia
and
14
32 kjib
, then the value of bababa 22 . is
Sol.: 1,1 ba
and 0. ba
]2..2[.2 22 abbabbaaba
541.220.201 2
2
baabba
Ans. 5
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*48. The line 12 yx is tangent to the hyperbola 12
2
2
2
b
y
a
x. If this line passes through the point of intersection of the
nearest directrix and the x-axis, then the eccentricity of the hyperbola is
Sol.: 12 xy (i)
222
bmamxy (ii)
(i) and (ii) identical 2m and 14 22 ba (iii)
Satisfying 12 yx by 12
e
a
224 ea (iv)
Also 1222 eab 2222 aeab (v)From (iii) and (iv) 122 eb 11 222 eae 1a ae 2 2e
Ans. 2
49. If the distance between the plane dzyAx 2 and the plane containing the lines4
3
3
2
2
1
zyxand
5
4
4
3
3
2
zyxis 6 , then || d is
Sol.: Let d.c. of normal to the plane is nml ,, :
0432 nml
0543 nml
121
nml
D.R. of normal to the plane is 1,2,1
Equation of plane is dzyx 2
Satisfying by 3,2,1 0d
Required plane is 02 zyx (i)
Given plane is dzyAx 2 (ii)
From (i) and (ii) we get 1A because planes are parallel.
Now, 6121
0
222
d 6d
Ans. 6
50. For any real numberx, let [x] denote the largest integer less than or equal to x. Letfbe a real valued function defined on the
interval [10, 10] by
evenis[x]if][1
odd,is[x]if][)(
xx
xxxf . Then the value of
10
10
2
cos)(10
dxxxf is
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Sol.: Period of 2xf
Period of 2cos x
So, period of 2cos xxf
dxxxfdxxxf 2.5
2.5
10
10
coscos
dxxxf cos102
0
1 0235 1 2 3 5
Graph off(x)
dxxxfdxxxf
2
1
1
0
coscos10
dxxxdxxx
2
1
1
0
coscos110
dxxxdxxx
1
0
2
1
cos110cos110
0
22010coscoscoscos10
22
1
0
2
1
2
1
1
0
dxxdxxxdxxxxdx
2
40
So, 4cos10
10
10
2
dxxxf
Ans. 4
51. Let be the complex number3
2sin
3
2cos
i . Then the number of distinct complex numbers z satisfying
z
z
z
1
1
1
2
2
2
= 0 is equal to
Sol.: Given determinant is 0
1
1
1
2
2
2
z
z
z
By 3211 CCCC
0
1
12
2
zz
zz
z
0
10
102
22
2
z
z
z
0]3[ 222 zz 02 zz 0z
So number of solution is 1.
Ans. 1
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*52. Let ,100...,,2,1, kSk denote the sum of the infinite geometric series whose first term is!
1
k
kand the common ratio is
k
1.
Then the value of
100
1
22
13!100
100
k
kSkk is
Sol.:
kR
k
kA
k
k
1
!
1
!1
1
kSk for 1k
The value of
100
1
22
13!100
100
k
kSkk
k
k
SkkSS
100
3
221
2
131!100
100
100
3
2
!1!2
110
!100
100
kk
k
k
k
!99
100
!98
99........
!3
4
!2
3
!2
3
!1
210
!100
100 2 3
!99
100210
!100
100 2
Ans. 3
53. The number of all possible values of , where 0 , for which the system of equations 3sin)(3cos)( xyzzy ;
zyx
3sin23cos23sin ; 3sin3cos)2(3sin)( yzyxyz have a solution ),,( 000 zyx with 000 zy , is
Sol.: 03cos1
3cos1
3sin zy
x
03sin21
3cos21
3sin zy
x
03sin3cos1
3cos21
3sin zy
x
The system of equations has solution, so
0
3sin3cos3cos23sin
3sin23cos23sin
3cos3cos3sin
0
3sin3cos00
3sin23cos21
3cos3cos1
3sin
03cos3cos3sin3sin
03cos,03sin , 13tan
But
possiblenotiswhich0
1,03sinfor03siny
03cos ( for 01
,03cos z
, not possible)
13tan ( for 3 solutions4
3,
12
5,
12
)
So number of solution = 3.
Ans. 3
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54. Letfbe a real-valued differentiable function on R (the set of all real numbers) such that 1)1( f . If the y-intercept of the
tangent at any point ),( yxP on the curve )(xfy is equal to the cube of the abscissa ofP, then the value of )3(f is equal
to
Sol.: According to given condition: 3xdx
dyxy
xdxx
ydxxdy
2
dxx
x
yd c
x
x
y
2
2
But 11 f 2
3c The curve is
2
3
2
3xx
y 93 f
Ans. 9
*55. The number of values of in the interval
2,
2such that
5
nfor ,0n 2,1 and 5cottan as well as
4cos2sin is
Sol.: 5cottan 06cos
2
6
n (i)
3,36
2,
2as
22,
2,
2,
2,
22,
236
Also 4cos2sin
2
2cos4cos Zmm
,2
224
2
26
m or2
22
m (ii)
From (i) and (ii) The number of common solution = 3
Ans. 3
Alternative:
4cos2sin (i)
012sin2sin2 2 012sin212sin 12sin or2
12sin
2,
2 ,2
4
or
12,
12
5
All the three values are satisfying the equation 5cottan
Ans. 3
*56. The maximum value of the expression 22 cos5cossin3sin
1is
Sol.: Maximum value of the expression 22 cos5cossin3sin
1
2
2
53
1
2
2cos42sin33
1
12cos22sin2
31
1
minmin
Ans. 2
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SOLUTIONS TO IIT-JEE 2010
PHYSICS: Paper-I (Code: 8)
PARTIII
SECTION I
Single Correct Choice Type
This Section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out ofwhich ONLY ONE is correct.
57. A thin flexible wire of length L is connected to two adjacent
fixed points and carries a current I in the clockwise direction, as
shown in the figure. When the system is put in a uniform
magnetic field of strength B going into the plane of the paper, the
wire takes the shape of a circle. The tension in the wire is
(A) IBL (B)
IBL(C)
2IBL
(D)4
IBL
Sol.: dRILBdRT 2 2ILBT
Correct choice: (C)
58. An AC voltage source of variable angular frequency and fixed amplitude 0V is connected in series with a capacitance C
and an electric bulb of resistance R (inductance zero). When is increased
(A) the bulb glows dimmer (B) the bulb glows brighter
(C) total impedance of the circuit is unchanged (D) total impedance of the circuit increases
Sol.:2
2
22 1|| RC
RXZ C
When angular frequency of the source increases the impedance of the circuit decreases, therefore the current in the circuitincreases, hence the power through the resistance increases.
Correct choice: (B)
59. To verify Ohms law, a student is provided with a test resistorTR , a high resistance 1R , a small resistance 2R , two identical
galvanometers1G and 2G , and a variable voltage source V. The correct circuit to carry out the experiment is
G1
G2
V
RT R1
R2
(A)
G1
G2
V
RT R2
R1
(B)
G1
V
RT(C)
R1
G2
R2
G1
V
RT(D)
R2
G2
R1
Sol.: A galvanometer with a high resistance in series behaves as a voltmeter and a low resistance connected in parallel to the
galvanometer behaves as an ammeter.
Correct choice: (C)
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60. Incandescent bulbs are designed by keeping in mind that the resistance of their filament increases with the increase in
temperature. If at room temperature, 100 W, 60 W and 40 W bulbs have filament resistances R100,R60,R40 respectively, the
relation between these resistances is
(A)604010 0
111
RRR (B)
604010 0RRR (C) 406010 0 RRR (D)
406010 0
111
RRR
Sol.:P
VR
2
, whereR is the resistance at working temperature and not at room temperature
406010 0
111
RRR
Correct choice: (D)
*61. A real gas behaves like an ideal gas if its
(A) pressure and temperature are both high (B) pressure and temperature are both low
(C) pressure is high and temperature is low (D) pressure is low and temperature is high
Sol.: Real gases behave like an ideal gas at very low densities.
As
0M
TR
P T
P
Correct choice: (D)
62. Consider a thin square sheet of side L and thickness t, made of a material
of resistivity . The resistance between two opposite faces, shown by theshaded areas in the figure is
(A) directly proportional toL (B) directly proportional to t
(C) independent ofL (D) independent oft
L
t
Sol.: ttL
LR
Correct choice: (C)
*63. A thin uniform annular disc (see figure) of mass Mhas outer radius 4R
and inner radius 3R. The work required to take a unit mass from point P
on its axis to infinity is
(A) 5247
2
R
GM(B) 524
7
2
R
GM
(C)R
GM
4(D) 12
5
2
R
GM
3R4R
4R
P
Sol.: Potential due to disc on its axis =
xxRG 222
(R is radius of disc,x is the distance from the centre of the disc on its axis)
By superposition principle potential due to annular disc at point P,
222
2212 xRxRGVP
PVVW
As RRRR 3,4 21 , Rx 4 and 22 34 RR
M
Work done 5247
2
R
GM 0V
Correct choice: (A)
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*64. A block of mass m is on an inclined plane of angle . The coefficient of friction between the block andthe plane is and tan . The block is held stationary by applying a force P parallel to the plane.The direction of force pointing up the plane is taken to be positive. As P is varied from
)cos(sin1 mgP to )cos(sin2 mgP , the frictional forcefversus P graph will look like
P
(A)P2
P1 P
f
(B)
P2P1 P
f
(C)
P2
P1
P
f
(D)P2P1
P
f
Sol.: (i) when sinmgP
sinmgfP
Pmgf sin
P
mgsin
f
tan >
(ii) when P = mg sin ,f= 0
(iii) when sinmgP
Pmgf sin
P2
P1 P
f
Correct choice: (A)
P
mgsin f
tan >
SECTIONIIMultiple Correct Choice Type
This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which ONE
OR MORE may be correct.
*65. A student uses a simple pendulum of exactly 1 m length to determine g, the acceleration due to gravity. He uses a stop watch
with the least count of 1 sec for this and records 40 seconds for 20 oscillations. For this observation, which of the following
statement(s) is (are) true?
(A) Error Tin measuring T, the time period, is 0.05 seconds
(B) Error Tin measuring T, the time period, is 1 second(C) Percentage error in the determination ofg is 5%
(D) Percentage error in the determination ofg is 2.5%
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Sol.: t= nT;n
tT
n
tT
05.0
20
1T sec.
g
l
n
t 2
2
224
t
lng
; 100
2100
t
t
g
g= 5%
Correct choices: (A), (C)
66. A ray OP of monochromatic light is incident on the face AB of prism ABCD
near vertexB at an incident angle of 60 (see figure). If the refractive index of
the material of the prism is 3 , which of the following is (are) correct?
(A) The ray gets totally internally reflected at face CD
(B) The ray comes out through face AD
(C) The angle between the incident ray and the emergent ray is 90
(D) The angle between the incident ray and the emergent ray is 120 900 750
1350
600
B
C
DA
P
O
Sol.: 3sin
60sin 0
rr= 300
Let ic be the critical angle, then,3
1sin ci
300 < ic < 450
Also, the angle between incident and emergent ray is 900
Correct choices: (A), (B), (C)750
1350
600
B
C
DA
300
600
450
450
300
600
67. A few electric field lines for a system of two charges Q1 and Q2 fixed at two
different points on the x-axis are shown in the figure. These lines suggest that
(A) |||| 21 QQ
(B) |||| 21 QQ
(C) at a finite distance to the left ofQ1 the electric field is zero
(D) at a finite distance to the right ofQ2 the electric field is zero
Q1 Q2
Sol.: Number of field lines magnitude of charge and2
r
KQE
Correct choices: (A), (D)
*68. One mole of an ideal gas in initial stateA undergoes a cyclic processABCA, as
shown in the figure. Its pressure atA is P0. Choose the correct option(s) from thefollowing
(A) Internal energies atA andB are the same
(B) Work done by the gas in processAB is 400 nVP
(C) Pressure at Cis4
0P
(D) Temperature at Cis4
0T
A
T
V
V0
4V0 B
C
T0
Sol.: ProcessAB is isothermal, so WAB = P0V0 ln 4 and UAB = 0
ProcessBC is unknown (as its not given whether the lineBCis directed towards origin or not)
Correct choices: (A), (B)
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*69. A point mass of 1 kg collides elastically with a stationary point mass of 5 kg. After their collision, the 1 kg mass reverses its
direction and moves with a speed of 2 ms1. Which of the following statement(s) is (are) correct for the system of these two
masses?
(A) Total momentum of the system is 3 kg ms1
(B) Momentum of 5 kg mass after collision is 4 kg ms1
(C) Kinetic energy of the centre of mass is 0.75 J
(D) Total kinetic energy of the system is 4 J
Sol.: Applying conservation of linear momentum
2521051 VV (i)
As collision is elastic,
VV 22 (ii)
112 ms3,ms1 VV
Total momentum of the system = 3 kg m/s
m/s2
1
51
01cm
VV
J75.05121
E.K 2cmcm V
Correct choices: (A), (C)
1kg V 5kg 1kg V25kg2m/s
Before collision After collision
SECTION IIIParagraph Type
This section contains 2 paragraphs. Based upon the first paragraph 3 multiple choice questions and based upon the second
paragraph 2 multiple choice questions have beanswered. Each of these questions has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.
Paragraph for Question Nos. 70 to 72
When a particle of mass m moves on the x-axis in a potential of the form ,)( 2kxxV it performs simple harmonic motion. The corresponding time period is proportional to
,k
m as can be seen easily using dimensional analysis. However, the motion of the
particle can be periodic even when its potential energy increases on both sides ofx = 0
in a way different from kx2 and its total energy is such that the particle does not escape
to infinity. Consider a particle of mass m moving on thex-axis. Its potential energy is
)0()( 4 xxV for | x | near the origin and becomes a constant equal to V0 for
0|| Xx (see figure).
V(x)
V0
X0x
*70. If the total energy of the particle isE, it will perform periodic motion only if
(A)E< 0 (B)E> 0 (C) V0 > E> 0 (D)E> V0Sol.: 0,0 EVE
Correct choice: (C)
*71. For periodic motion of small amplitudeA, the time period Tof this particle is proportional to
(A)m
A (B)m
A
1(C)
mA
(D)
mA
1
Sol.: Using dimensional analysis
Correct choice: (B)
*72. The acceleration of this particle for 0|| Xx is
(A) proportional to V0 (B) proportional to0
0
mX
V(C) proportional to
0
0
mX
V(D) zero
Sol.: 0VU andF = 0dx
dU
Correct choice: (D)
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Paragraph for Question Nos. 73 to 74
Electrical resistance of certain materials, known as superconductors,
changes abruptly from a nonzero value to zero as their temperature is
lowered below a critical temperature TC (0). An interesting property of
superconductors is that their critical temperature becomes smaller than
TC(0) if they are placed in a magnetic field, i.e., the critical temperatureTC(B) is a function of the magnetic field strength B. The dependence of
TC(B) onB is shown in the figure. B
TC(B)
O
TC(0)
73. In the graphs below, the resistance R of a superconductor is shown as a function of its temperature T for two different
magnetic fieldB1 (solid line) andB2 (dashed line). If B2 is larger than B1, which of the following graphs shows the correctvariation ofR with Tin these fields?
T
R
O
(A)
B2B1
T
R
O
(B)
B2
B1
T
R
O
(C)
B1B2
T
R
O
(D)
B1
B2
Sol.: Higher the magnetic field, lower is the temperature at which resistance abruptly becomes zero.
Correct choice: (A)
74. A superconductor has TC (0) = 100 K. When a magnetic field of 7.5 Tesla is applied, its TC decreases to 75 K. For this
material one can definitely say that when
(A)B = 5 Tesla, TC(B) = 80 K (B)B = 5 Tesla, 75 K < TC(B) < 100 K
(C)B = 10 Tesla, 75 K < TC(B) < 100 K (D)B = 10 Tesla, TC(B) = 70 K
Sol.: As the magnetic field decreases, TCincreases
Correct choice: (B)
SECTION IVInteger Type
This section contains TEN questions. The answer to each question is a single-digit integer, ranging from 0 to 9. The correct
digit below the question number in the ORS is to be bubbled.
75. When two identical batteries of internal resistance 1 each are connected in series across a resistor R, the rate of heat
produced inR isJ1. When the same batteries are connected in parallel acrossR, the rate isJ2. IfJ1 = 2.25J2 then the value of
R in is
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Sol.: In first case
I rR 2
2
Rate of heat produced inR, RrR
RIJ
2
21
2
2
R
r r
I
In second case
2
'r
R
I
Rate of heat produced inR, Rr
R
J
2
2
2
As 21 25.2 JJ
rR 4 = 4Answer is 4
r
R
r
'I
*76. Two spherical bodies A (radius 6 cm) and B (radius 18 cm) are at temperatures T1 and T2, respectively. The maximum
intensity in the emission spectrum ofA is at 500 nm and in that ofB is at 1500 nm. Considering them to be blackbodies, what
will be the ratio of the rate of total energy radiated byA to that ofB?
Sol.: For a black body,energyradiated per unit time = 4AT (whereR is radius of the body)
42
B
A
B
A
B
A
T
T
R
R
E
E (i)
According to Weins displacement law, Tm constant
42
500
1500
18
6
B
A
E
E
= 9
Answer is 9
*77. When two progressive waves
262sin3and)62sin(4 21 txytxy are superimposed, the amplitude of the
resultant wave is
Sol.: cos2 2122
21 AAAAA = 525
2cos34234 22
Answer is 5
*78. A 0.1 kg mass is suspended from a wire of negligible mass. The length of the wire is 1 m and its cross-sectional areas is
4.9 107 m2. If the mass is pulled a little in the vertically downward direction and released, it performs simple harmonic
motion of angular frequency 140 rad s1. If the Youngs modulus of the material of the wire is n 109 Nm2, the value ofn is
Sol.:m
K
Lm
YA
1.01
109.410140
792
n
Lm
YA
n = 4
Answer is 4
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*79. A binary star consists of two starsA (mass 2.2MS) and B (mass 11MS), whereMS is the mass of the sun. They are separated
by distance dand are rotating about their centre of mass, which is stationary. The ratio of the total angular momentum of the
binary star to the angular momentum of star B about the centre of mass is
Sol.:CM
2.2MS 11MS
5d/6 d/6
11 IL and 22 IL
66/11
6/52.26/112
22
2
1
2
1
dM
dMdM
I
I
L
L
S
SS
Answers is 6
*80. Gravitational acceleration on the surface of a planet is ,11
6g where g is the gravitational acceleration on the surface of the
earth. The average mass density of the planet is3
2times that of the earth. If the escape speed on the surface of the earth is
taken to be 11 kms-1
, the escape speed on the surface of the planet in kms1
will be
Sol.:2
2
EE
PP
P
E
E
P
eE
eP
R
R
R
R
M
M
V
V
(i)
As2
3
2 3
4
R
RG
R
GMg
gR
P
E
E
P
E
P
g
g
R
R
(ii)
22
E
P
P
E
E
P
eE
eP
g
g
V
V2
11
6
2
3
VeP = 3 km/s
Answer is 3
*81. A piece of ice (heat capacity = 2100 J kg1 C1 and latent heat = 3.36 105 J kg1) of mass m grams is at 5C at
atmospheric pressure. It is given 420 J of heat so that the ice starts melting. Finally when the ice-water mixture is in
equilibrium, it is found that 1 gm of ice has melted. Assuming there is no other heat exchange in the process, the value ofm is
Ans.: Heat required for melting ice = 3361036.3100
1 5 J
Heat used for raising temperature of ice from (50C to 00C) = 336420Q = 84 J
TmsQ 5210084 m
m = 0.008 kg = 8 gm
Answer is 8
*82. A stationary source is emitting sound at a fixed frequency f0, which is reflected by two cars approaching the source. The
difference between the frequencies of sound reflected from the cars is 1.2% off0. What is the difference in the speeds of the
cars (in km per hour) to the nearest integer? The cars are moving at constant speeds much smaller than the speed of sound
which is 330 ms1.
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Sol.: Apparent frequency received by car is
V
VVff 001 (i)
The frequency of the reflected wave is
0
11 'VV
Vff =
0
00
VV
VVf (ii)
Differentiating '1f with respect to V0
3302
330
660
330
330330' 02
0
002
0
00
0
1 f
V
ff
V
VV
dV
df
0
10
'165
f
dfdV 7 km/h
Answer is 7
83. The focal length of a thin biconvex lens is 20 cm. When an object is moved from a distance of 25 cm in front of it to 50 cm,
the magnification of its image changes from m25 to m50. The ratio50
25
mm is
Sol.:20
1
25
11
1
V
cm1001 V
Similarly
100
3
100
25
50
1
20
11
2
V
3
1002 V cm
503
100
25
100
50
25
m
m= 6
Answer is 6
84. An -particle and a proton are accelerated from rest by a potential difference of 100V. After this, their de Broglie
wavelengths are and p respectively. The ratio
p
, to the nearest integer, is
Sol.: The momentum of a charged particle accelerated by potential difference V, qmVP 2
de-Broglie wavelength,P
h
3222
422
Vme
Vmep
Answer is 3
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SOLUTIONS TO IIT-JEE 2010Paper-II (Code: 8)
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
A. General:1. This Question Paper contains 24 pages having 57 questions. The question paper CODE is
printed on the right hand top corner of this sheet and also on the back page of thisbooklet..
2. No additional sheets will be provided for rough work.3. Blank papers, clipboards, log tables, slide rules, calculators, cellular phones, pagers and
electronic gadgets in any form are not allowed.4. Log and Antilog tables are given in the paper.
5. The answer sheet, a machine-gradable Objective Response Sheet (ORS), is providedseparately.
6. Write your Registration No., Name, Name of the centre and sign with pen in theappropriate boxes. Do not write these anywhere else.
B. Question paper format and Marking scheme:7. The question paper consists of 3 parts (Chemistry, Mathematics and Physics), and each
Part consists offour Sections.
8. For each question in Section I,you will be awarded 5 marks if you have darkened onlythe bubble corresponding to the correct answer and zero mark if no bubbles aredarkened. In all other cases, minus two (2) markwill be awarded.
9. For each question in Section II, you will be awarded 3 marks if you darken only thebubble corresponding to the correct answer and zero mark if no bubble is darkened. Nonegative marks will be awarded for incorrect answers in this Section.
10. For each question in Section III, you will be awarded 3 marks if you darken only thebubble corresponding to the correct answer and zero mark if no bubbles are darkened. Inall other cases, minus one (1) markwill be awarded.
11. For each question in Section IV,you will be awarded 2 marks for each row in which youhave darkened the bubble(s) corresponding to the correct answer. Thus, each question inthis section carries a maximum of8 marks.
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SOLUTIONS TO IIT-JEE 2010CHEMISTRY: Paper-II (Code: 8)
PARTI
SECTION I
Single Correct Choice Type
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out ofwhich ONLY ONE is correct.
Note: Questions with (*) mark are from syllabus of class XI.
1. In the reaction H3C C
O
NH2
(1) NaOH/Br2
(2) C
O
Cl
T
the structure of the Product T is
(A)H3C C
O
OC
O(B) NH
C
O
CH3
(C) H3C NH
O
C
(D)H3C C
O
NHC
O
Sol.: H3C C
O
NH2
(1) NaOH/Br2Me NH2
HCl
C
O
ClMe NHC
O
Correct choice: (C)
*2. Assuming that Hunds rule is violated, the bond order and magnetic nature of the diatomic molecule B 2 is
(A) 1 and diamagnetic (B) 0 and diamagnetic (C) 1 and paramagnetic (D) 0 and paramagnetic
Sol.: Molecular orbital configuration of B2 as per the condition will be
1s2, *1s2, 2s2, *2s2, 2yP2
Bond order of B2 =2
46= 1.
B2 will be diamagnetic.
Correct choice: (A)
3. The compounds P, Q and S
HO
COOH
P H3C
OCH3
Q
CO
O
Swere separately subjected to nitration using HNO3/H2SO4 mixture. The major product formed in each case respectively, is
(A)
HO
COOH
H3C
OCH3 CO
O
NO2 NO2
O2N
(B)
HO
COOH
H3C
OCH3 CO
O
NO2NO2
NO2
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(C)
HO
COOH
H3C
OCH3 CO
O
NO2NO2
NO2
(D)
HO
COOH
H3C
OCH3 C O
O
NO2NO2
NO2
Sol.:
OH
CO2H
(P)
HNO3/H2SO4
OH
CO2H
NO2
CH3
OCH3
(Q)
HNO3/H2SO4NO2
CH3
OCH3
O
(S)
HNO3/H2SO4O
O
O NO2
Correct choice: (C)
*4. The species having pyramidal shape is
(A) SO3 (B) BrF3 (C) 23SiO (D) OSF2
Sol.: OSF2:2
N=
2
26 = 4.
It has 1 lone pair.
S (Shape is trigonal pyramidal)
FO F
..
The shapes of SO3, BrF3 and2
3SiO are triangular planar, T-shaped and triangular planar respectively.
Correct choice: (D)
5. The complex showing a spin-only magnetic moment of 2.82 B.M. is
(A) Ni(CO)4 (B) [NiCl4]2 (C) Ni(PPh3)4 (D) [Ni(CN)4]
2
Sol.: Ni(CO)4 and Ni(PPh3)4 have Ni in zero oxidation state, while CO and Ph 3P are strong field ligands. Thus, both these
molecules have sp3 hybridization and are diamagnetic. [Ni(CN)4]2 has electronic configuration of Ni2+ as 3d8 and
hybridization is dsp2. It is diamagnetic. [NiCl4]2 has sp3 hybridization with 2 unpaired electrons giving spin only magnetic
moment as 8 or 2.82 B.M.
Correct choice: (B)
6. The packing efficiency of the two-dimensional square unit cell shown below is
L
(A) 39.27% (B) 68.02% (C) 74.05% (D) 78.54%
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Sol.: Packing efficiency =squareofArea
circleseffectivebyoccupiedArea
= 100L
r22
2
= 100)r22(
r2
2
2
= 1004
= 78.54%.
Correct choice: (D)
SECTIONIIInteger Type
This section contains a group of 5 questions. The answer to each of the questions is a single digit integer, ranging from 0 to 9.
The correct digit below the question no. in the ORS is to be bubbled.
*7. One mole of an ideal gas is taken from a to b along two paths denoted by the solid and the dashed lines as shown in the
graphs below. If the work done along the solid line path is ws and that along the dotted line path is wd, then the integer closest
to the ratio wd/ws is
0.5
1.0
1.5
2.0
25
3.0
3.5
4.0
4.5
0.00.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 5.5 6.0
P
(atm)
V (lit.)
b
a
Sol.: wd =
2
5
3
211
2
34 =
3
516
wd =3
26 L atm
ws =2.303 RT log2/1
5.5=2.303 PV log 11
ws =4.606 1.04 =4.8 L atm
s
d
w
w=
8.4
326
= 1.80 ~2.0
The answer is 2.
*8. Among the following, the number of elements showing only one non-zero oxidation state is
O, Cl, F, N, P, Sn, Tl, Na, Ti
Sol.: Fluorine generally shows O and1 oxidation states while sodium shows 0 and +1 oxidation state.
The answer is 2.
9. Silver (atomic weight = 108 g mol1
) has a density of 10.5 g cm3
. The number of silver atoms on a surface of area 1012
m2
can be expressed in scientific notation as y 10x. The value of x is
Sol.: Silver has cubic close packed structure. It has fcc unit cell of edge length a cm.
10.5 =323 )a(10023.6
1084
a =3/1
23 5.1010023.6
1084
= 4.087 108 cm.
(i) Assuming that surface area given is the area of any extended face of a FCC unit cell.
Area of square face = (4.087 108)2 cm2
Number of Ag atoms per unit area =2
a
2
Surface area = 1012 m2 = 108 cm2.
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Number of Ag atoms in the given surface area =28
8
)10087.4(
102
= 1.197 107.
x = 7.
(ii) Assuming that surface area given is the area corresponding to closest packed layer.
2 a = 4r, r =4
a2 =4
210087.4
8
= 1.44 108
In a closest packed layer, the arrangement appears like
2)r2(4
36 =
4
36(2 1.44 108)2 =
161007.244
36
= 21.5 1016 cm2
Number of silver atoms on surface =16
8
105.21
103
= 0.139 108 = 1.39 107.
x = 7.
The answer is 7.
10. Total number of geometrical isomers for the complex [RhCl(CO)(PPh3)(NH3)] is
Sol.: Rh
Cl PPh3
CO NH3
Rh
Cl PPh3
NH3 CO
Rh
Cl CO
NH3 PPh3
The number of geometrical isomers is 3.The answer is 3.
*11. The total number of diprotic acids among the following is
H3PO4 H2SO4 H3PO3 H2CO3 H2S2O7
H3BO3 H3PO2 H2CrO4 H2SO3
Sol.: Diprotic acids are H2SO4, H3PO3, H2CO3, H2S2O7, H2CrO4 and H2SO3.
The answer is 6.
SECTION IIIParagraph Type
This Section contains 2 paragraphs. Based upon each of the paragraphs 3 multiple choice questions have to be answered.
Each of these questions has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct.
Paragraph for questions 12 to 14
Two aliphatic aldehydes P and Q react in the presence of aqueous K 2CO3 to give compound R, which upon treatment with
HCN provides compound S. On acidification and heating, S gives the product shown below.
O O
H3C
H3C OH
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12. The compounds P and Q respectively are
(A)
H3C
CH
CH3
CH
andH3C
CH
OO
(B)
H3C
CH
CH3
CH
andH
CH
OO
(C)H3C CH2
CH3
CH
andH3C
CH
OO
CH (D)H3C CH2
CH3
CH
andH
CH
OO
CH
Sol.: CH3CHCHO + OH CH3C
CHO + H2O
CH3 CH3
CH3CCHO + CH2 = O CH3CCHO CH3CCHO
H2O
OH
CH3 CH3 CH3
CH2O CH2OH
CH3CCH=O + HCN CH3CCHCN CH3CCHCOOHH+
/H2O
CH3 H3C OH OH
CH2OHCH2OH CH2OH
(S)
O OH3C
H3C OH
Intramolecular esterificationH3C
(P)
(Q)
(R)
Correct choice: (B)
13. The compound R is
(A)
H3C
CH3C
C
CH2OH
O
H (B)
H3C
CH3C
C
CHOH
O
H
H3C
(C)CH
CHC
CH2OH
O
HH3C
CH3
(D)
CH
CH
H3C
C
CHOH
O
HH3C
CH3
Sol.: Correct choice: (A)
14. The compound S is
(A)CH
CH
C
CH2
CN
O
HH3C
CH3
(B)H3C
CH3C
C
CH2
CN
O
H
(C)CH
CHCH
CH2OH
CN
OHH3C
CH3
(D)H3C
CH3C
CH
CH2OH
CN
OH
Sol.: Correct choice: (D)
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Paragraph for questions 15 to 17
The hydrogen-like species Li2+ is in a spherically symmetric state S1 with one radial node. Upon absorbing light the ion
undergoes transition to a state S2. The state S2 has one radial node and its energy is equal to the ground state energy of the
hydrogen atom.
*15. The state S1 is
(A) 1s (B) 2s (C) 2p (D) 3s
Sol.: The spherically symmetric state S1 of Li2+ with one radial node is 2s. Upon absorbing light, the ion gets excited to state S2,
which also has one radial node. The energy of electron in S2 is same as that of H-atom in its ground state
12
2
n En
ZE where E1 is the energy of H-atom in the ground state
2
12
n
E)3( for Li2+
3nEE 1n
State S2 of Li2+ having one radial node is 3p.
Orbital angular momentum quantum number of 3p is 1.
Energy of state 112
2
1 E25.2E)2(
)3(S
Correct choice: (B)
*16. Energy of the state S1 in units of the hydrogen atom ground state energy is
(A) 0.75 (B) 1.50 (C) 2.25 (D) 4.50
Sol.: Correct choice: (C)
*17. The orbital angular momentum quantum number of the state S2 is
(A) 0 (B) 1 (C) 2 (D) 3
Sol.: Correct choice: (B)
SECTION IV(Matrix Type)
This section contains 2 questions. Each question contains has four statements (A, B, C and D) given in Column I and fivestatements (p, q, r, s and t) in Column II. Any given statement in Column I can have correct matching with one or more
statement(s) given in Column II. For example, if for a given question, statement B matches with the statements given in q
and r, then for that particular question, against statement B, darken the bubbles corresponding to q and r in the ORS.
18. Match the reactions is Column I with appropriate options in Column II.
Column I Column II
(A) N2Cl + OHNaOH/H2O
0C N=N OH (p) Racemic mixture
(B) H3C
C
CH3
O
CH3CCCCH3
OHOH
H3C CH3
H2SO
4
CH3
CH3
(q) Addition reaction
(C) C CH
O
CH3
1. LiAlH4
2. H3O+
OH
CH3
(r) Substitution reaction
(D) HS ClBase S (s) Coupling reaction
(t) Carbocation intermediate
Sol.: (A)(r), (s) ; (B)(t) ; (C)(p), (q) ; (D) (r)
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19. All the compounds listed in Column I react with water. Match the result of the respective reactions with the appropriate
options listed in Column II.
Column I Column II
(A) (CH3)2SiCl2 (p) Hydrogen halide formation
(B) XeF4 (q) Redox reaction
(C) Cl2 (r) Reacts with glass
(D) VCl5 (s) Polymerization
(t) O2 formation
Sol.: (A)(p), (s)
(CH3)2SiCl2 + 2H2O HCl2 (CH3)2Si(OH)2 .Polymn
[(CH3)2SiO]n.
(B)(p), (q), (r), (t)
XeF4 + H2O Xe + XeO3 + H2F2 + O2
SiO2 + 4HF SiF4 + 2H2Oglass
SiF4 + 2HF H2[SiF6]Soluble hexathorosilicic(IV) acid
(C)(p), (q)
Cl2 + H2O HCl + HOCl
(D)(p), (q)
VCl5 + 7H2O [V(H2O)6]3+ + 3Cl+ HCl + HOCl
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SOLUTIONS TO IIT-JEE 2010MATHEMATICS: Paper-II (Code: 8)
PARTII
SECTION I
Single Correct Choice Type
This section contains 6 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for itsanswer, out of which ONLY ONE is correct.
20. Letf be a real-valued function defined on the interval (1, 1) such that x
x txfe
0
4 12)( dt, for all ),1,1(x and
let 1f be the inverse function of f . Then )2()'( 1f is equal to
(A) 1 (B)3
1(C)
2
1(D)
e
1
Sol.: dttxfe
x
x 0
4 12)( (i)
Putting 0x
2)0( f 0)2(1 f xxff ))(( 1 1)()'(.))((' 11 xfxff )0('
1)2()'( 1
ff
Differentiate equation (i) with respect tox
1)()(' 4 xxfexfe xx
Putting 0x
12)0(' f 3)0(' f 3
1)2()'( 1 f
Correct choice: (B)
21. A signal which can be green or red with probability5
4and
5
1respectively, is received by station A and then transmitted to
stationB. The probability of each station receiving the signal correctly is4
3. If the signal received at station B is green, then
the probability that the original signal was green is
(A)5
3(B)
7
6(C)
23
20(D)
20
9
Sol.: GR Received signal is green
GO Original signal was green
If the eventXYZdenotes original single sent toA wasX, received atA was Yand received atB isZ
)(
)(
G
GG
G
G
RP
ROP
R
OP
)()()()(
)()(
RGGPRRGPGGGPGRGP
GGGPGRGP
4
3
4
1
5
1
4
1
4
3
5
1
4
3
4
3
5
4
4
1
4
1
5
4
4
3
4
3
5
4
4
1
4
1
5
4
23
20
80
4680
40
Correct choice: (C)
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22. If the distance of the point )1,2,1( P from the plane zyx 22 , where 0 , is 5, then the foot of the perpendicular
from P to the plane is
(A)
3
7,
3
4,
3
8(B)
3
1,
3
4,
3
4(C)
3
10,
3
2,
3
1(D)
2
5,
3
1,
3
2
Sol.: 5441
241
155 ( )0
10
Plane is 01022 zyx
Let the foot of perpendicular be F, equation of line PFis
2
1
2
2
1
1
zyx
So the point Fcan be taken as
F
P
)21,22,1(
It will satisfy equation of plane.
01042441 3
5
Point Fis
3
7,
3
4,
3
8
Correct choice: (A)
*23. Let }4,3,2,1{S . The total number of unordered pairs of disjoint subsets ofS is equal to
(A) 25 (B) 34 (C) 42 (D) 41
Sol.: Given set 4,3,2,1S
For disjoint subsetsA andB
Sa
Ba
Aa
Ba
Aa
Ba
Aa
Then total number of disjoint subsets will be 12
134
= 41
Correct choice: (D)
*24. For 10,....1,0r let rr BA , and rC denote, respectively, the coefficient ofr
x in the expansions of ,)1(10
x 20)1( x and
30)1( x . Then
10
1
1010 )(
r
rrr ACBBA is equal to
(A) 1010 CB (B) )( 101021010 ACBA (C) 0 (D) 1010 BC
Sol.:
10
1
21010
302010
2010
r
rrr CCCCC =
10
1
10
1
21010
30102010
20
r r
rrr CCCCC
= 11 1020103010301020 CCCC = 101010201030 BCCC Correct choice: (D)
25. Two adjacent sides of a parallelogram ABCD are given by kjiAB 11102 and kjiAD 22 . The side AD isrotated by an acute angle in the plane of the parallelogram so that AD becomes 'AD . If 'AD makes a right angle with theside AB , then the cosine of the angle is given by
(A) 9
8
(B) 9
17
(C) 9
1
(D) 9
54
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Sol.: ||||. ADABADAB )90cos(
31540 sin
sin9
8;
9
17cos
90
D C
BA
'D
Correct choice: (B)
SECTIONII(Integer Type)
This section contains 5 questions. The answer to each question is a singledigit integer, ranging from 0 to 9. The correctdigit below the question no. in the ORS is to be bubbled.
26. Let kbe a positive real number and let
02
2021
120
and
122
212
2212
kk
kk
kk
B
kk
kk
kkk
A .
If det 610)adj(det)adj( BA , then [k] is equal to
[Note: adjMdenotes the adjoint of a square matrixMand [k] denotes the largest integer less than or equal to k]
Sol.: 122
12120
2212
det
kk
kk
kkk
A
kkkkk
kkk
k 81212
1122
100
2412
12 2
312 k
0det B [B is skew symmetric matrix of order 3]
66 1012 k 1012 k 29k [k] = 4
Ans. 4
27. Letf be a function defined onR(the set on all real numbers) such that
,)2012()2011()2010)(2009(2010)(' 432 xxxxxf for all Rx . Ifg is a function defined on R with values in theinterval ),0( such that ))(ln()( xgxf , for all Rx , then the number of points inR at which g has a local maximum is
Sol.:
xgxg
xf .1
xgxfxg
As 0xg , So xg will change sign as
2009 2011
++
one point of maxima is 2009x
Ans. 1
*28. Let 11321 ,....,, aaaa be real numbers satisfying 151 a , 0227 2 a and 212 kkk aaa for 11...,,4,3k .
If 9011
... 21122
21
aaa, then the value of
11
... 1121 aaa is equal to
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Sol.: 151 a
As 211 kkkk aaaa
So ......,,, 321 aaa are in A.P.
Also 0227 2 a
2
312 aa
2
3d
9011
......211
22
21
aaa 90115
11
111
1
2 r
dr
9035150225 2 dd 027307 2 dd 0973 dd 7
9,3
d
But7
9d
2
3d
Now 030302
11030
2
1
11
...... 1121
daaa
Ans. 0
29. Consider a triangle ABCand let ba, and c denote the lengths of the sides opposite to vertices A, B and C respectively.
Suppose 6a , 10b and the area of the triangle is 315 . If ACB is obtuse and ifrdenotes the radius of the incircle of
the triangle, then 2r is equal to
Sol.: 315
315sin1062
1C
2
3sin C
obtuseis
3
2CC
120
10036cos
2c
C
14c
Hence semi perimeter 15s
3r 32 r
Ans. 3
30. Two parallel chords of a circle of radius 2 are at a distance 13 apart. If the chords subtend at the center, angles ofk
and
k
2, where 0k , then the value of [k] is [Note : [k] denotes the largest integer less than or equal to k]
Sol.: 1321 pp
132
cos2cos2
kk
2
13
2coscos
kk
3k
Ans. 3
/2k
/k p1
p22
2
A B
DC
O
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SECTION III(Paragraph Type)
This section contains 2 paragraphs. Based upon each of the paragraphs 3 multiple choice questions have to be answered.
Each of these question has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct.
Paragraph for Questions 31 to 33
Consider the polynomial 32 4321)( xxxxf . Let s be the sum of all distinct real roots of )(xf and let || st .
31. The real number s lies in the interval
(A)
0,
4
1(B)
4
3,11 (C)
2
1,
4
3(D)
4
1,0
Sol.: Given function 32 4321)( xxxxf is monotonically increasing
as Rxxxxf 0]136[2)(' 2 ]48/5)4/1[(12 2 x
)(xf will have only one real root
Since 0
2
1.
4
3
ff s lies in
2
1,
4
3
Correct choice: (C)
32. The area bounded by the curve )(xfy and the lines 0x , 0y and tx , lies in the interval
(A)
3,
4
3(B)
16
11,
64
21(C) (9, 10) (D)
64
21,0
Sol.: As || st
4
3,
2
1t
Hence required area will be the shaded region shown in
the figure.
t1/23/4
O
Area t
dxxxxtA
0
32 )4321()( 432 tttt which is increasing
Area
4
3,
2
1AA
256
525,
16
15
Correct choice: (A)
33. The function )(' xf is
(A) increasing in
4
1,t and deceasing in
t,
4
1(B) decreasing in
4
1,t and increasing in
t,
4
1
(C) increasing in ),( tt (D) decreasing in ),( tt
Sol.:
4
124 xxf xf increases
,
4
1x
xf decreases
4
1,x
Correct choice: (B)
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Paragraph for Questions 34 to 36
Tangents are drawn from the point )4,3(P to the ellipse 149
22
yx
touching the ellipse at pointsA andB.
*34. The coordinates ofA andB are
(A) (3, 0) and (0, 2) (B)
15
1612,
5
8and
5
8,
5
9
(C)
15
1612,
5
8and (0, 2) (D) (3, 0) and
5
8,
5
9
Sol.: Let 49 2 mmxy be the tangent passing through point 4,3 to the given ellipse.
4934 22 mm 2
1m and indeterminate.
one tangent is2
5
2
1 xy at
5
8,
5
9