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  • 8/8/2019 Jee 2010 BT

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    SOLUTIONS TO IIT-JEE 2010Paper-I (Code: 8)

    Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.

    INSTRUCTIONSA. General:

    1. This Question Paper contains 28 pages having 84 questions. The question paper CODE isprinted on the right hand top corner of this sheet and also on the back page of thisbooklet.

    2. No additional sheets will be provided for rough work.3. Blank papers, clipboards, log tables, slide rules, calculators, cellular phones, pagers and

    electronic gadgets in any form are not allowed.

    4. The answer sheet, a machine-gradable Objective Response Sheet (ORS), is providedseparately.

    5. Write your Registration No., Name and Name of centre and sign with pen in appropriateboxes. Do not write these anywhere else.

    B. Question paper format and Marking scheme:6. The question paper consists of 3 parts (Chemistry, Mathematics and Physics). Each part

    consists offour Sections.

    7. For each question in Section I, you will be awarded 3 marks if you have darkened onlythe bubble corresponding to the correct answer and zero mark if no bubbles aredarkened. In all other cases, minus one (1) markwill be awarded.

    8. For each question in Section II, you will be awarded 3 marks if you darken only thebubble(s) corresponding to the correct answer and zero mark if no bubbles are darkened.Partial marks will be awarded for partially correct answers. No negative marks will beawarded in this Section.

    9. For each question in Section III, you will be awarded 3 marks if you darken only thebubble corresponding to the correct answer and zero mark if no bubbles are darkened. Inall other cases, minus one (1) markwill be awarded.

    10. For each question in Section IV,you will be awarded 3 marks if you darken the bubblecorresponding to the correct answer and zero mark if no bubble is darkened. No negativemarkswill be awarded in this Section.

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    IITJEE 2010 SOLUTIONS

    Brilliant Tutorials Pvt. Ltd. Head Office: 12, Masilamani Street, T. Nagar, Chennai-600 017Delhi Office: 50-C, Kalu Sarai (Behind Azad Apartments), New Delhi-110 016 Ph.: 2653 7392/93/94/95 Fax: 2653 7396

    2

    SOLUTIONS TO IIT-JEE 2010CHEMISTRY: Paper-I (Code: 8)

    PARTI

    Useful Data

    Atomic numbers: Be = 4; C = 6; N = 7; O = 8; Al = 13; Si = 14; Cr = 24; Fe = 26; Zn = 30; Br = 35.

    1 amu= 1.66 1027 kg R = 0.082 L atm K1 mol1

    h = 6.626 1034 Js NA = 6.022 1023

    me = 9.1 1031 kg e = 1.6 1019 C

    c = 3.0 108 m s1 F = 96500 C mol1

    RH = 2.18 1018 J 4o = 1.11 10

    10 J1 C2 m1

    SECTION I

    Single Correct Choice Type

    This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D), out of which

    ONLY ONE is correct.

    Note: Questions with (*) mark are from syllabus of class XI.

    1. Plots showing the variation of the rate constant (k) with temperature (T) are given below. The plot that follows Arrheniusequation is

    (A) k

    T

    (B) k

    T

    (C) k

    T

    (D) k

    T

    Sol.: As per Arrhenius equation ),Aek(RT/Ea the rate constant increases exponentially with temperature.

    Correct choice: (A)

    2. In the reaction OCH3HBr the products are

    (A) OCH3 and H2Br (B) Br and CH3Br

    (C) Br and CH3OH (D) OH and CH3Br

    Sol.: OCH3H+

    OCH3

    H

    + BrOH + CH3Br

    Correct choice: (D)

    3. The correct statement about the following disaccharide is

    HO

    H

    OH

    H

    HO

    H

    H

    CH2OH

    OHOH

    H

    H

    HO

    HOH2C

    OCH2CH2O

    (a)

    H

    CH2OH

    O

    (b)

    (A) Ring (a) is pyranose with -glycosidic link. (B) Ring (a) is furanose with -glycosidic link.

    (C) Ring (b) is furanose with -glycosidic link. (D) Ring (b) is pyranose with -glycosidic link.

    Sol.: Correct choice: (A)

    *4. The synthesis of 3-octyne is achieved by adding a bromoalkane into a mixture of sodium amide and an alkyne. The

    bromoalkane and alkyne respectively are

    (A) BrCH2CH2CH2CH2CH3 and CH3CH2CCH (B) BrCH2CH2CH3 and CH3CH2CH2CCH

    (C) BrCH2CH2CH2CH2CH3 and CH3CCH (D) BrCH2CH2CH2CH3 and CH3CH2CCH

    Sol.: H3CH2CCHNaNH2

    NH3CH3CH2CC

    Na+CH3CH2CH2CH2Br

    (SN2)CH3CH2CCCH2CH2CH2CH3 + NaBr

    3-Octyne

    Correct choice: (D)

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    IITJEE 2010 SOLUTIONS

    Brilliant Tutorials Pvt. Ltd. Head Office: 12, Masilamani Street, T. Nagar, Chennai-600 017Delhi Office: 50-C, Kalu Sarai (Behind Azad Apartments), New Delhi-110 016 Ph.: 2653 7392/93/94/95 Fax: 2653 7396

    3

    5. The ionization isomer of [Cr(H2O)4Cl(NO2)]Cl is

    (A) [Cr(H2O)4(O2N)]Cl2 (B) [Cr(H2O)4Cl2](NO2)

    (C) [Cr(H2O)4Cl(ONO)]Cl (D) [Cr(H2O)4Cl2(NO2)].H2O

    Sol.: Ionization isomer of [Cr(H2O)4Cl(NO2)]Cl is [Cr(H2O)4Cl2]NO2.

    Correct choice: (B)

    6. The correct structure of ethylenediaminetetraacetic acid (EDTA) is

    (A)HOOCH2C

    NCH=CHNHOOCH2C

    CH2COOH

    CH2COOH(B)

    HOOCNCH2CH2N

    COOH

    COOHHOOC

    (C) NCH2CH2NHOOCH2C

    HOOCH2C

    CH2COOH

    CH2COOH(D) NCHCHN

    HOOCH2C

    H CH2COOH

    CH2

    COOH

    CH2

    HOOC

    H

    Sol.: The correct structure of EDTA is

    NCH2CH2NHOOCH2C

    HOOCH2C

    CH2COOH

    CH2COOH

    Correct choice: (C)

    *7. The bond energy (in kcal mol1) of a CC single bond is approximately

    (A) 1 (B) 10 (C) 100 (D) 1000

    Sol.: CC bond energy = 348 kJ/mol2.4

    348kcal/mol = 82.85 kcal/mol 100 kcal/mol.

    Correct choice: (C)

    *8. The species which by definition has ZERO standard molar enthalpy of formation at 298 K is

    (A) Br2 (g) (B) Cl2 (g) (C) H2O(g) (D) CH4 (g)

    Sol.: The species in its elemental form has zero standard molar enthalpy of formation at 298 K.

    Br2(l) Br2(g) ;ofH 0

    C(s) + 2H2(g) CH4(g) ;o

    f

    H 0

    H2(g) + O2(g) H2O(g) ;ofH 0

    Correct choice: (B)

    SECTIONII

    Multiple Correct Choice Type

    This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which

    ONE OR MORE is/are correct.

    9. In the reaction

    OH

    NaOH(aq)/Br2the intermediate(s) is(are)

    (A)

    Br

    BrO

    (B)

    Br

    O

    Br

    (C)

    Br

    O

    (D)

    Br

    O

    Sol.:

    OH

    NaOH

    O

    Br2

    O

    Br2Br

    O

    Br

    Br2Br

    O

    Br(I) (II) (III) (IV)

    Br

    Br

    H2O Br

    Br Br

    Product of reaction of phenol with NaOH/Br2 is sodium salt of 2,4,6-tribromophenol. Hence, species (I), (II), (III) are formed

    as intermediate.

    Correct choice: (A), (C)

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    IITJEE 2010 SOLUTIONS

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    4

    *10. Among the following, the intensive property is (properties are)

    (A) molar conductivity (B) electromotive force (C) resistance (D) heat capacity

    Sol.: Mass independent properties are intensive properties. Resistance and heat capacity are extensive properties.

    Correct choice: (A), (B)

    *11. The reagent(s) used for softening the temporary hardness of water is(are)

    (A) Ca3(PO4)2 (B) Ca(OH)2 (C) Na2CO3 (D) NaOCl

    Sol.: Temporary hardness is due to bicarbonates of calcium and magnesium. Temporary hardness can be removed by Clarksprocess, which involves the addition of slaked lime, Ca(OH) 2. Washing soda (Na2CO3) removes both the temporary and

    permanent hardness by converting soluble calcium and magnesium compounds into insoluble carbonates.

    Ca(HCO3)2 + Ca(OH)2 2CaCO3 + 2H2O

    Ca(HCO3)2 + Na2CO3 CaCO3 + 2NaHCO3

    2OCl + 2H2O 2HOCl + 2OH

    Ca(HCO3)2 + 2OH CaCO3 +

    23CO + 2H2O

    Correct choice: (B), (C), (D)

    *12. Aqueous solutions of HNO3, KOH, CH3COOH and CH3COONa of identical concentrations are provided. The pair(s) of

    solutions which form a buffer upon mixing is(are)

    (A) HNO3 and CH3COOH (B) KOH and CH3COONa

    (C) HNO3 and CH3COONa (D) CH3COOH and CH3COONaSol.: Any solution of a weak acid and its salt with strong base acts as an acidic buffer solution.

    If volume of HNO3 solution added is less as compared to that of CH3COONa solution, it results in the formation of an acidic

    buffer solution.

    CH3COONa + HNO3 CH3COOH + NaNO3

    Excess limiting

    reagent

    MV MV

    M(VV) 0 MV MV (V < V)

    Correct choice: (C), (D)

    *13. In the Newman projection for 2,2-dimethylbutane

    X

    H H

    Y

    H3C CH3

    X and Y can respectively be

    (A) H and H (B) H and C2H5 (C) C2H5 and H (D) CH3 and CH3

    Sol.: Structural formula of 2, 2-dimethylbutane is

    CH3CCH2CH3

    CH3

    CH3

    1 2 3

    (I) Newman projection using C1

    C2

    bond

    H

    H H

    C2H5

    H3C CH3

    1

    2

    (II) Newman projection using C3C2 bond

    H H

    CH3

    CH3 CH3

    3

    2

    CH3

    Correct choice: (B), (D)

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    IITJEE 2010 SOLUTIONS

    Brilliant Tutorials Pvt. Ltd. Head Office: 12, Masilamani Street, T. Nagar, Chennai-600 017Delhi Office: 50-C, Kalu Sarai (Behind Azad Apartments), New Delhi-110 016 Ph.: 2653 7392/93/94/95 Fax: 2653 7396

    5

    SECTION IIIParagraph Type

    This section contains 2 paragraphs. Based upon the first paragraph 3 multiple choice questions and based upon the second

    paragraph 2 multiple choice questions have to be answered. Each of these questions has four choices A), B), C) and D) out

    of which ONLY ONE is correct.

    Paragraph for Question 14 to 16

    Copper is the most noble of the first row transition metals and occurs in small deposits in several countries. Ores of copper

    include chalcanthite (CuSO4.5H2O), atacamite (Cu2Cl(OH)3), cuprite (Cu2O), copper glance (Cu2S) and malachite

    (Cu2(OH)2CO3). However, 80% of the world copper production comes from the ore chalcopyrite (CuFeS2). The extraction of

    copper from chalcopyrite involves partial roasting, removal of iron and self-reduction.

    14. Partial roasting of chalcopyrite produces

    (A) Cu2S and FeO (B) Cu2O and FeO (C) CuS and Fe2O3 (D) Cu2O and Fe2O3

    Sol.: 2CuFeS2 + 4O2 C14501400

    Cu2S + 3SO2 + 2FeO

    Partial roasting of FeS and Cu2S produces FeO and Cu2O respectively.

    2FeS + 3O2 2FeO + 2SO2

    2Cu2S + 3O2 2Cu2O + 2SO2

    Correct choice: (B)15. Iron is removed from chalcopyrite as

    (A) FeO (B) FeS (C) Fe2O3 (D) FeSiO3

    Sol.: FeO + SiO2 FeSiO3Correct choice: (D)

    16. In self-reduction, the reducing species is

    (A) S (B) O2 (C) S2 (D) SO2

    Sol.: Cu2S + 2Cu2O 6Cu + SO2The reducing species is the one which gets oxidized. So, it is S2ion getting oxidized to S4+.

    Correct choice: (C)

    Paragraph for Question 17 to 18

    The concentration of potassium ions inside a biological cell is atleast twenty times higher than the outside. The resulting

    potential difference across the cell is important in several processes such as transmission of nerve impulses and maintaining

    the ion balance. A simple model for such a concentration cell involving a metal M is

    M(s) | M+(aq; 0.05 molar) || M+(aq; 1 molar) | M(s)

    For the above electrolytic cell the magnitude of the cell potential |Ecell| = 70 mV.

    17. For the above cell

    (A) Ecell < 0; 0G (B) 0G;0Ecell (C) 0G;0Ecell (D) 0G;0Ecell

    Sol.: (A): M(s) e)aq(MA

    (C): )s(Me)aq(MC

    )aq(M)aq(M AC

    ]M[

    ]M[ln

    F

    RT

    ]M[

    ]M[ln

    F

    RTEE

    A

    C

    C

    Aocellcell

    )0E( ocell

    Ecell = 0.059 log05.0

    ]M[ C

    0.07V = 0.05905.0

    )M(log C

    = 0.059 log 20 ]M[ C = 0.059 (log 20 + log ]M[ C

    )

    Since ]M[ C is greater than 0.05 M, so Ecell is +ve.

    Ecell > 0 & .0G Correct choice: (B)

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    IITJEE 2010 SOLUTIONS

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    6

    18. If the 0.05 molar solution of M+ is replaced by a 0.0025 molar M+ solution, then the magnitude of the cell potential would be

    (A) 35 mV (B) 70 mV (C) 140 mV (D) 700 mV

    Sol.: Ecell = 0.0590025.0

    ]M[log C

    = 0.059 log 400 ]M[ C = 0.059 log (20)2 ]M[ C

    = 0.059(2 log 20 + log ]M[ C )

    = 0.059

    59.0

    07.02 = 0.14 V = 140 mV.

    Correct choice: (C)

    SECTIONIVInteger Answer Type

    This section contains TEN questions. The answer to each questions is a single digit integer ranging from 0 to 9.

    The correct digit below the question number in the ORS is to be bubbled.

    19. In the scheme given below, the total number of intramolecular aldol condensation products formed from Y is

    1. O32. Zn, H2O Y

    1. NaOH(aq)2. heat

    Sol.:

    1. O32. Zn, H2O

    NaOH(aq)

    O

    O

    (Y)

    OH

    O

    heat

    H2O

    O

    The number of intramolecular aldol condensation products (, -unsaturated carbonyl compound) formed from (Y) is 1.

    The answer is 1.

    20. Amongst the following, the total number of compounds soluble in aqueous NaOH is

    NCH3H3C COOH OCH2CH3

    CH2OH

    OH

    NO2 OH

    CH3H3CN

    CH2CH3

    CH2CH3

    COOH

    Sol.: All carboxylic acids and phenols are soluble in aqueous NaOH. Four compounds are soluble in aqueous NaOH.

    The answer is 4.

    *21. Amongst the following, the total number of compounds whose aqueous solution turns red litmus paper blue is

    KCN K2SO4 (NH4)2C2O4 NaCl Zn(NO3)2

    FeCl3 K2CO3 NH4NO3 LiCN

    Sol.: KCN, K2CO3 and LiCN are the salts of weak acid and strong base. So, their aqueous solutions turns red litmus paper blue.

    (NH4)2C2O4 is a salt of weak base (NH4OH ; Kb = 1.8 105) and weak acid (HOOC.COOH ;

    1aK = 5.4 102 and

    2aK = 5.2 105 ). As a result, the extent of hydrolysis of

    4NH will be more than that of

    242OC and hence the resulting

    solution will be acidic.The answer is 3.

    *22. Based on VSEPR theory, the number of 90 degree FBrF angles in BrF5 is

    Sol.: According to VSEPR theory, number of electron pairs around central atom (Br) are 6.

    2

    N=

    2

    57 = 6. (Five are bond pairs and one is lone pair )

    Its geometry is octahedral but due to lone pairbond pair repulsion, thefour fluorine atoms at corner are forced towards the upper fluorine atom

    thus reducing FBrF angle from 90 to 84.8.

    F

    ..F

    F

    F

    Br

    F

    The answer is 0.

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    IITJEE 2010 SOLUTIONS

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    7

    *23. The value of n in the molecular formula BenAl2Si6O18 is

    Sol.: It is the formula of Beryl (which has BeO, Al2O3 and SiO2).

    The formula of Beryl should be

    3BeO. Al2O3.6SiO2

    Or

    Total cationic charge = Total anionic charge

    2n + 6 + 24 = 36

    n = 3

    The answer is 3.

    *24. A student performs a titration with different burettes and finds titre values of 25.2 mL, 25.25 mL, and 25.0 mL. The number

    of significant figures in the average titre value is

    Sol.: The least significant figure in titre values is 3.

    Average titre value = 1.253

    4.75

    3

    2525.252.25

    The number of significant figures in average titre value will also be 3.

    The answer is 3.

    25. The concentration of R in the reaction PR was measured as a function of time and the following data is obtained:

    [R] (molar) 1.0 0.75 0.40 0.10

    t(min.) 0.0 0.05 0.12 0.18

    The order of reaction is

    Sol.: The integrated form of a zero-order reaction is

    [A0][At] = k0t

    1.00.75 = k0 0.05, k0 = 5

    1.00.4 = k0 0.12, k0 = 5

    The answer is 0.

    26. The number of neutrons emitted when U23592 undergoes controlled nuclear fission to Xe14254 and Sr

    9038 is

    Sol.: 1090

    38142

    541

    0235

    92 nySrXenU

    235 + 1 = 142 + 90 + yy = 4. The number of neutrons emitted are (41) = 3.

    The answer is 3.

    *27. The total number of basic groups in the following form of lysine is

    CHC

    H3NCH2CH2CH2CH2 O

    H2N O

    Sol.: The basic groups in the given form of lysine is NH2 and2CO . The answer is 2.

    *28. The total number of cyclic isomers possible for a hydrocarbon with the molecular formula C4H6 is

    Sol.: The number of cyclic isomers for a hydrocarbon with molecular formula C4H6 is 5.

    The structures are

    , , and,

    CH2CH3

    CH3.

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    IITJEE 2010 SOLUTIONS

    Brilliant Tutorials Pvt. Ltd. Head Office: 12, Masilamani Street, T. Nagar, Chennai-600 017Delhi Office: 50-C, Kalu Sarai (Behind Azad Apartments), New Delhi-110 016 Ph.: 2653 7392/93/94/95 Fax: 2653 7396

    8

    SOLUTIONS TO IIT-JEE 2010MATHEMATICS: Paper-I (Code: 8)

    PARTII

    SECTION I

    Single Correct Choice Type

    This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) for itsanswer, out of which ONLY ONE is correct.

    29. The value of

    x

    xdt

    t

    tt

    x0

    430 4

    )1ln(1lim is

    (A) 0 (B)12

    1(C)

    24

    1(D)

    64

    1

    Sol.:

    dt

    t

    tt

    x

    x

    x

    0 430 4

    1ln1lim

    form

    0

    04

    1ln

    lim

    3

    0

    4

    0 x

    dtt

    ttx

    x

    Applying L. Hospital Rule

    431ln

    lim3

    4

    1ln

    lim402

    4

    0

    xx

    x

    x

    x

    xx

    xx

    12

    1

    4

    1lim

    1lnlim

    3

    1

    400

    xx

    x

    xx

    Correct choice: (B)

    30. The number of 33 matricesA whose entries are either 0 or 1 and for which the system A

    0

    0

    1

    z

    y

    x

    has exactly two distinct

    solutions, is

    (A) 0 (B) 129 (C) 168 (D) 2

    Sol.: For any matricesA it form three planes. But three planes can not intersect exactly at two distinct points.

    Correct choice: (A)

    31. Let P, Q, R and S be the points on the plane with position vectors ,2 ji jii 33,4 and ji 23 respectively. The

    quadrilateral PQRS must be a

    (A) parallelogram, which is neither a rhombus nor a rectangle (B) square

    (C) rectangle, but not a square (D) rhombus, but not a square

    Sol.: IfO is origin jiOSjiORiOQjiOP 23;33;4;2

    jiOQOSQS 27

    jiPR 45

    53449 QS ; 411625 PR

    376 jiPQ ; 103 jiQR

    376 jiRS ; 103 jiSP

    Opposite sides are parallel and equal but diagonals are not equal.

    Correct choice: (A)

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    IITJEE 2010 SOLUTIONS

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    9

    32. Let be a complex cube root of unity with 1 . A fair die is thrown three times. If 21, rr and 3r are the numbers obtained

    on the die, then the probability that 321 rrr = 0 is

    (A)18

    1(B)

    9

    1(C)

    9

    2(D)

    36

    1

    Sol.: 21663 Sn

    Eis the event that 0321 rrr , is possible if one among 321 ,, rrr is of the form n3 ; another one is of the form

    13 n and the remaining one is of the form 23 n , where Zn .

    For n3 , two possible cases are 3, 6

    For 13 n , two possible cases are 1, 4

    For 23 n , two possible cases are 2, 5

    48!3222 En

    9

    2

    216

    48

    Sn

    EnEP

    Correct choice: (C)

    33. Equation of the plane containing the straight line432

    zyx and perpendicular to the plane containing the straight lines

    243

    zyx and

    324

    zyx is

    (A) 022 zyx (B) 0223 zyx (C) 02 zyx (D) 0425 zyx

    Sol.: Plane 2P contains the lineL 432

    zyx

    Plane 1P contains the lines 1L and 2L , where

    2431

    zyxL and

    3242

    zyxL

    Let direction ratio of normal to the plane 1P is ,, , then

    0243 and 0324

    1018

    Let direction ratio of normal of required plane is (a, b, c), then 0108 cba ; 0432 cba

    265226

    cba

    121

    cba

    Required plane is 02 zyx

    Correct choice: (C)

    Alternative:

    cbabcacban ..

    kjikji 3242624326 kji 265226 direction ratio of normal of required plane is 1,2,1

    Equation is 02 zyx

    *34. If the angles BA, and C of a triangle are in an arithmetic progression and if a, b and c denote the lengths of the sides

    opposite to BA, and Crespectively, then the value of the expression Aa

    cC

    c

    a2sin2sin is

    (A)

    2

    1(B)

    2

    3(C) 1 (D) 3

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    IITJEE 2010 SOLUTIONS

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    10

    Sol.: SinceA, B, Care in A.P.

    CAB 2

    180CBA

    1803B 60B

    Aa

    c

    Cc

    a

    2sin2sin

    AAA

    CCC

    C

    Acossin2

    sin

    sincossin2.

    sin

    sin 120sin22sin2sin2cossinsincos2 BCAACAC

    32

    32

    Correct choice: (D)

    35. Let f, g and h be real-valued functions defined on the interval [0, 1] by22

    )( xx eexf ,22

    )( xx exexg and

    222)( xx eexxh . Ifa, b and c denote, respectively, the absolute maximum off, g and h on [0, 1], then

    (A) ba and bc (B) ca and ba (C) ba and bc (D) cba

    Sol.: 22 xx

    eexf

    22

    2 xx eexxf

    22 xx exexg

    222

    2 xxx eexexxg

    222 xx eexxh

    222

    223 xxx eexexxh

    for ]1,0[x

    xgxf , and 0 xh

    xgxf , and xh will be increasing functions and their maximum values are

    e

    ec

    e

    eb

    e

    ea1

    ,1

    ,1

    at 1x

    cba

    Correct choice: (D)

    Alternative:

    ],1[]1,0[as1 2

    2

    2

    eex

    e

    exf x

    x

    x

    ],1[,1

    ett

    ttf ; e

    etf1

    max

    max e

    exf1

    xfxgxh

    e

    exg1

    but at 1x , e

    exg1

    and similarly at 1x , xh e

    e1

    So, cba

    *36. Let p and q be real numbers such that qpp 3,0 and qp 3 . If and are nonzero complex numbers satisfying

    p and q 33 , then a quadratic equation having

    and

    as its roots is

    (A) 0)()2()( 3323 qpxqpxqp (B) 0)()2()( 3323 qpxqpxqp

    (C) 0)()25()( 3323 qpxqpxqp (D) 0)()25()( 3323 qpxqpxqp

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    11

    Sol.: p (i)

    q 33 (ii)

    Sum of roots

    2

    222

    S (iii)

    Product of roots P = 1

    From (i) and (ii) 22pq

    32pq p

    pq

    3

    3

    3

    3

    3

    33

    3

    32

    2223

    3

    3

    2

    pq

    qp

    pq

    pqp

    p

    pq

    p

    pqp

    S

    Required quadratic equation is 02 PSxx

    02 3323 pqxqpxpq Correct choice: (B)

    SECTIONIIMultiple Correct Choice Type

    This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D) for its answer, out of

    which ONE OR MORE may be correct.

    *37. Let ABC be a triangle such that6

    ACB and let a, b and c denote the lengths of the sides opposite to A, B and C

    respectively. The value(s) ofx for which 1,1 22 xbxxa and 12 xc is (are)

    (A) 32 (B) 31 (C) 32 (D) 34

    Sol.:

    1121211

    6cos

    22

    22222

    xxx

    xxxx

    112

    123

    2

    3

    22

    2222

    xxx

    xxxxx

    1213 22 xxxxx 0313232 2 xx

    322

    3132432322

    x 31,32

    But 32 x (as 0,, cba 1x )Correct choice: (B)

    38. Letfbe a real-valued function defined on the interval ),0( by dttxxf

    x

    0

    sin1ln)( . Then which of the following

    statement(s) is (are) true?

    (A) )('' xf exists for all ),0( x

    (B) )(' xf exists for all ),0( x and xf' is continuous on ),0( , but not differentiable on ),0(

    (C) there exists > 1 such that |)(||)('| xfxf for all ),( x

    (D) there exists > 0 such that |)('||)(| xfxf for all ),0( x

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    Sol.: xx

    xf sin11

    Clearly xf exists and continuous for all 0x .

    Also xf is not differentiable at point where 1sin x .

    xgx

    xxfxf 1ln , where xdttxgx

    sin1sin1

    0

    Now dtt

    x

    0

    sin1 is always continuous, increasing and has range ,0 .

    So 0xg for some ,0k as 2sin1 x for ,0x

    Also 01

    ln x

    x for ,kx

    0 xfxf for all ,kkx

    xfxf for all ,x , where kk Correct choice: (B), (C)

    k1

    y = lnx

    y = 1/x

    *39. LetA andB be two distinct points on the parabola xy 42 . If the axis of the parabola touches a circle of radius rhavingABas its diameter, then the slope of the line joiningA andB can be

    (A)r

    1 (B)

    r

    1(C)

    r

    2(D)

    r

    2

    Sol.: Let mid-point ofAB is rh ,

    Equation ofAB is

    sincos

    ryhx

    SoA andB can be rh sin,cos

    But these will satisfy xy 42

    C(h, r)

    y2 = 4x

    B

    A

    xO

    hr cos4sin 2

    04cos2sin2sin 222 hrr Sum of roots = 0 CBAC

    cos2sinr r

    2tan

    Correct choice: (C), (D)

    Alternative:

    Slope of21

    2tt

    AB

    y-coordinate of mid-point of rttAB 21

    slope ofAB can ber

    2or

    r

    2

    222 2, tt B

    A

    x

    y

    121 2, tt r

    40. The value(s) of

    1

    0

    2

    44

    1

    )1(dx

    x

    xxis (are)

    (A) 7

    22(B)

    105

    2(C) 0 (D)

    2

    3

    15

    71

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    Sol.: dx

    x

    xdxxdxxxdx

    x

    xxxI

    1

    0

    2

    61

    0

    5

    1

    0

    24

    1

    0

    2

    224

    1

    441

    1

    21

    7

    224

    3

    4

    5

    4

    3

    2

    7

    1

    5

    1

    1

    114

    6

    4

    7

    1

    5

    11

    0

    2

    24dx

    xxx

    Correct choice: (A)

    *41. Let1Z

    and 2z be two distinct complex numbers and let 21)1( tzztz for some real number twith 10 t . If Arg(w)

    denotes the principal argument of a nonzero complex number w, then

    (A) |||||| 2121 zzzzzz (B) )(Arg)(Arg 21 zzzz

    (C) 01212

    11

    zzzz

    zzzz(D) )(Arg)(Arg 121 zzzz

    Sol.: 21 ,, zCzBzA are collinear

    ACBCAB

    2121 zzzzzz

    21 zzArgzzArg

    121 zzArgzzArg

    Equation of line CBA ,, is 01212

    11

    zzzz

    zzzz

    Correct choice: (A), (C), (D)

    SECTION IIIComprehension Type

    This section contains 2 paragraphs. Based upon the first paragraph 3 multiple choice questions and based upon the secondparagraph 2 multiple choice questions have to be answered. Each of these questions has 4 choices (A), (B), (C) and (D) out

    of which ONLY ONE is correct.

    Paragraph for Questions 42 to 44

    Letp be an odd prime number and pT be the following set of 2 2 matrices :

    }1.....,,2,1,0{,,: pcba

    ac

    baATp

    42. The number ofA in pT such thatA is either symmetric or skew-symmetric or both, and det (A) divisible byp is

    (A)2)1( p (B) )1(2 p (C) 1)1( 2 p (D) 12 p

    Sol.: ForA to be symmetric cb

    22 ba should be multiple ofp

    )()( baba should be multiple ofp

    Either )(or)( baba should be multiple ofp

    ba can be multiple ofp in )1( p ways (excluding 0 ba )

    )( ba can be multiple ofp inp ways (including 0 ba )

    Total number of ways = 2p1

    Correct choice: (D)

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    43. The number ofA in pT such that the trace ofA is not divisible byp but det (A) is divisible byp is

    [Note: The trace of a matrix is the sum of its diagonal entries.]

    (A) )1)(1( 2 ppp (B) 23 )1( pp (C) 2)1( p (D) )2)(1( 2 pp

    Sol.: As Atr is not amultiple ofp

    0a

    bca 2 will be a multiple ofp

    if remainder ofp

    a2

    andp

    bcis same.

    Let when 2a divided byp remainder is r

    when bc is divided byp for different values of }1...,1,0{ pc we get distinct remainder }1...,1,0{ p

    there exist only one value ofb for which remainder ofbc divided byp gives r

    a and c can be taken in )1( p ways each and b can be choose in only one way.

    Total ways 1)1(2

    p

    Correct choice: (C)

    44. The number ofA in pT such that det (A) is not divisible byp is

    (A) 22p (B) pp 53 (C) pp 33 (D) 23 pp

    Sol.: The total number ofAin3

    pTp (i)

    Now theA for which det A is divisible byp

    Case-I: 0a

    bc should be divisible byp

    either 0b or 0c or both

    total ways 12 p

    Case-II: 0a

    Total ways2)1( p [as in previous question]

    Total number of ways = 121 2 pp 2p (ii)

    Required ways = 23 pp

    Correct choice: (D)

    Paragraph for Questions 45 to 46

    The circle 0822 xyx and hyperbola 149

    22

    yx

    intersect at the pointsA andB.

    *45. Equation of a common tangent with positive slope to the circle as well as to the hyperbola is

    (A) 02052 yx (B) 0452 yx (C) 0843 yx (D) 0434 yx

    Sol.: Let sin4,cos14 be a point on the circle.

    Equation of tangent to the circle is cos14sincos yx = 0

    sin

    cos14

    sin

    cosxy (i)

    Condition of tangency for hyperbola is

    2222

    bmac

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    4sin

    cos9

    sin

    cos116

    2

    2

    2

    2

    020cos32cos3 2

    3

    2cos and 10 (rejected)

    35sin

    Slope of tangent from (i) is m =5

    2

    35

    32

    sin

    cos

    5

    4

    5

    2;

    35

    3214

    5

    2

    xyxy

    425 xy 0452 yx

    Correct choice: (B)

    *46. Equation of the circle withAB as its diameter is

    (A) 0241222 xyx (B) 0241222 xyx

    (C) 0122422 xyx (D) 0122422 xyx

    Sol.:22

    8 xxy

    14

    8

    9

    22

    xxx

    369724 22 xxx 0367213 2 xx 03667813 2 xxx

    0)6(6613 xxx 6,13

    6 xx

    Clearly 0,6 is the centre.

    if 6x , 36482 y 122 y 32y

    End points of diameter are 32,6,32,6 32r and 0,6C

    126 22 yx 123612 22 yxx 0241222 xyx

    Correct choice: (A)

    SECTION IVInteger Answer Type

    This section contains TEN questions. The answer to each of the questions is a single-digitinteger, ranging from 0 to 9. Thecorrect digit below the question numbers in the ORS is to be bubbled.

    47. If a

    and b

    are vectors in space given by5

    2 jia

    and

    14

    32 kjib

    , then the value of bababa 22 . is

    Sol.: 1,1 ba

    and 0. ba

    ]2..2[.2 22 abbabbaaba

    541.220.201 2

    2

    baabba

    Ans. 5

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    16

    *48. The line 12 yx is tangent to the hyperbola 12

    2

    2

    2

    b

    y

    a

    x. If this line passes through the point of intersection of the

    nearest directrix and the x-axis, then the eccentricity of the hyperbola is

    Sol.: 12 xy (i)

    222

    bmamxy (ii)

    (i) and (ii) identical 2m and 14 22 ba (iii)

    Satisfying 12 yx by 12

    e

    a

    224 ea (iv)

    Also 1222 eab 2222 aeab (v)From (iii) and (iv) 122 eb 11 222 eae 1a ae 2 2e

    Ans. 2

    49. If the distance between the plane dzyAx 2 and the plane containing the lines4

    3

    3

    2

    2

    1

    zyxand

    5

    4

    4

    3

    3

    2

    zyxis 6 , then || d is

    Sol.: Let d.c. of normal to the plane is nml ,, :

    0432 nml

    0543 nml

    121

    nml

    D.R. of normal to the plane is 1,2,1

    Equation of plane is dzyx 2

    Satisfying by 3,2,1 0d

    Required plane is 02 zyx (i)

    Given plane is dzyAx 2 (ii)

    From (i) and (ii) we get 1A because planes are parallel.

    Now, 6121

    0

    222

    d 6d

    Ans. 6

    50. For any real numberx, let [x] denote the largest integer less than or equal to x. Letfbe a real valued function defined on the

    interval [10, 10] by

    evenis[x]if][1

    odd,is[x]if][)(

    xx

    xxxf . Then the value of

    10

    10

    2

    cos)(10

    dxxxf is

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    Sol.: Period of 2xf

    Period of 2cos x

    So, period of 2cos xxf

    dxxxfdxxxf 2.5

    2.5

    10

    10

    coscos

    dxxxf cos102

    0

    1 0235 1 2 3 5

    Graph off(x)

    dxxxfdxxxf

    2

    1

    1

    0

    coscos10

    dxxxdxxx

    2

    1

    1

    0

    coscos110

    dxxxdxxx

    1

    0

    2

    1

    cos110cos110

    0

    22010coscoscoscos10

    22

    1

    0

    2

    1

    2

    1

    1

    0

    dxxdxxxdxxxxdx

    2

    40

    So, 4cos10

    10

    10

    2

    dxxxf

    Ans. 4

    51. Let be the complex number3

    2sin

    3

    2cos

    i . Then the number of distinct complex numbers z satisfying

    z

    z

    z

    1

    1

    1

    2

    2

    2

    = 0 is equal to

    Sol.: Given determinant is 0

    1

    1

    1

    2

    2

    2

    z

    z

    z

    By 3211 CCCC

    0

    1

    12

    2

    zz

    zz

    z

    0

    10

    102

    22

    2

    z

    z

    z

    0]3[ 222 zz 02 zz 0z

    So number of solution is 1.

    Ans. 1

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    *52. Let ,100...,,2,1, kSk denote the sum of the infinite geometric series whose first term is!

    1

    k

    kand the common ratio is

    k

    1.

    Then the value of

    100

    1

    22

    13!100

    100

    k

    kSkk is

    Sol.:

    kR

    k

    kA

    k

    k

    1

    !

    1

    !1

    1

    kSk for 1k

    The value of

    100

    1

    22

    13!100

    100

    k

    kSkk

    k

    k

    SkkSS

    100

    3

    221

    2

    131!100

    100

    100

    3

    2

    !1!2

    110

    !100

    100

    kk

    k

    k

    k

    !99

    100

    !98

    99........

    !3

    4

    !2

    3

    !2

    3

    !1

    210

    !100

    100 2 3

    !99

    100210

    !100

    100 2

    Ans. 3

    53. The number of all possible values of , where 0 , for which the system of equations 3sin)(3cos)( xyzzy ;

    zyx

    3sin23cos23sin ; 3sin3cos)2(3sin)( yzyxyz have a solution ),,( 000 zyx with 000 zy , is

    Sol.: 03cos1

    3cos1

    3sin zy

    x

    03sin21

    3cos21

    3sin zy

    x

    03sin3cos1

    3cos21

    3sin zy

    x

    The system of equations has solution, so

    0

    3sin3cos3cos23sin

    3sin23cos23sin

    3cos3cos3sin

    0

    3sin3cos00

    3sin23cos21

    3cos3cos1

    3sin

    03cos3cos3sin3sin

    03cos,03sin , 13tan

    But

    possiblenotiswhich0

    1,03sinfor03siny

    03cos ( for 01

    ,03cos z

    , not possible)

    13tan ( for 3 solutions4

    3,

    12

    5,

    12

    )

    So number of solution = 3.

    Ans. 3

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    54. Letfbe a real-valued differentiable function on R (the set of all real numbers) such that 1)1( f . If the y-intercept of the

    tangent at any point ),( yxP on the curve )(xfy is equal to the cube of the abscissa ofP, then the value of )3(f is equal

    to

    Sol.: According to given condition: 3xdx

    dyxy

    xdxx

    ydxxdy

    2

    dxx

    x

    yd c

    x

    x

    y

    2

    2

    But 11 f 2

    3c The curve is

    2

    3

    2

    3xx

    y 93 f

    Ans. 9

    *55. The number of values of in the interval

    2,

    2such that

    5

    nfor ,0n 2,1 and 5cottan as well as

    4cos2sin is

    Sol.: 5cottan 06cos

    2

    6

    n (i)

    3,36

    2,

    2as

    22,

    2,

    2,

    2,

    22,

    236

    Also 4cos2sin

    2

    2cos4cos Zmm

    ,2

    224

    2

    26

    m or2

    22

    m (ii)

    From (i) and (ii) The number of common solution = 3

    Ans. 3

    Alternative:

    4cos2sin (i)

    012sin2sin2 2 012sin212sin 12sin or2

    12sin

    2,

    2 ,2

    4

    or

    12,

    12

    5

    All the three values are satisfying the equation 5cottan

    Ans. 3

    *56. The maximum value of the expression 22 cos5cossin3sin

    1is

    Sol.: Maximum value of the expression 22 cos5cossin3sin

    1

    2

    2

    53

    1

    2

    2cos42sin33

    1

    12cos22sin2

    31

    1

    minmin

    Ans. 2

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    20

    SOLUTIONS TO IIT-JEE 2010

    PHYSICS: Paper-I (Code: 8)

    PARTIII

    SECTION I

    Single Correct Choice Type

    This Section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out ofwhich ONLY ONE is correct.

    57. A thin flexible wire of length L is connected to two adjacent

    fixed points and carries a current I in the clockwise direction, as

    shown in the figure. When the system is put in a uniform

    magnetic field of strength B going into the plane of the paper, the

    wire takes the shape of a circle. The tension in the wire is

    (A) IBL (B)

    IBL(C)

    2IBL

    (D)4

    IBL

    Sol.: dRILBdRT 2 2ILBT

    Correct choice: (C)

    58. An AC voltage source of variable angular frequency and fixed amplitude 0V is connected in series with a capacitance C

    and an electric bulb of resistance R (inductance zero). When is increased

    (A) the bulb glows dimmer (B) the bulb glows brighter

    (C) total impedance of the circuit is unchanged (D) total impedance of the circuit increases

    Sol.:2

    2

    22 1|| RC

    RXZ C

    When angular frequency of the source increases the impedance of the circuit decreases, therefore the current in the circuitincreases, hence the power through the resistance increases.

    Correct choice: (B)

    59. To verify Ohms law, a student is provided with a test resistorTR , a high resistance 1R , a small resistance 2R , two identical

    galvanometers1G and 2G , and a variable voltage source V. The correct circuit to carry out the experiment is

    G1

    G2

    V

    RT R1

    R2

    (A)

    G1

    G2

    V

    RT R2

    R1

    (B)

    G1

    V

    RT(C)

    R1

    G2

    R2

    G1

    V

    RT(D)

    R2

    G2

    R1

    Sol.: A galvanometer with a high resistance in series behaves as a voltmeter and a low resistance connected in parallel to the

    galvanometer behaves as an ammeter.

    Correct choice: (C)

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    21

    60. Incandescent bulbs are designed by keeping in mind that the resistance of their filament increases with the increase in

    temperature. If at room temperature, 100 W, 60 W and 40 W bulbs have filament resistances R100,R60,R40 respectively, the

    relation between these resistances is

    (A)604010 0

    111

    RRR (B)

    604010 0RRR (C) 406010 0 RRR (D)

    406010 0

    111

    RRR

    Sol.:P

    VR

    2

    , whereR is the resistance at working temperature and not at room temperature

    406010 0

    111

    RRR

    Correct choice: (D)

    *61. A real gas behaves like an ideal gas if its

    (A) pressure and temperature are both high (B) pressure and temperature are both low

    (C) pressure is high and temperature is low (D) pressure is low and temperature is high

    Sol.: Real gases behave like an ideal gas at very low densities.

    As

    0M

    TR

    P T

    P

    Correct choice: (D)

    62. Consider a thin square sheet of side L and thickness t, made of a material

    of resistivity . The resistance between two opposite faces, shown by theshaded areas in the figure is

    (A) directly proportional toL (B) directly proportional to t

    (C) independent ofL (D) independent oft

    L

    t

    Sol.: ttL

    LR

    Correct choice: (C)

    *63. A thin uniform annular disc (see figure) of mass Mhas outer radius 4R

    and inner radius 3R. The work required to take a unit mass from point P

    on its axis to infinity is

    (A) 5247

    2

    R

    GM(B) 524

    7

    2

    R

    GM

    (C)R

    GM

    4(D) 12

    5

    2

    R

    GM

    3R4R

    4R

    P

    Sol.: Potential due to disc on its axis =

    xxRG 222

    (R is radius of disc,x is the distance from the centre of the disc on its axis)

    By superposition principle potential due to annular disc at point P,

    222

    2212 xRxRGVP

    PVVW

    As RRRR 3,4 21 , Rx 4 and 22 34 RR

    M

    Work done 5247

    2

    R

    GM 0V

    Correct choice: (A)

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    *64. A block of mass m is on an inclined plane of angle . The coefficient of friction between the block andthe plane is and tan . The block is held stationary by applying a force P parallel to the plane.The direction of force pointing up the plane is taken to be positive. As P is varied from

    )cos(sin1 mgP to )cos(sin2 mgP , the frictional forcefversus P graph will look like

    P

    (A)P2

    P1 P

    f

    (B)

    P2P1 P

    f

    (C)

    P2

    P1

    P

    f

    (D)P2P1

    P

    f

    Sol.: (i) when sinmgP

    sinmgfP

    Pmgf sin

    P

    mgsin

    f

    tan >

    (ii) when P = mg sin ,f= 0

    (iii) when sinmgP

    Pmgf sin

    P2

    P1 P

    f

    Correct choice: (A)

    P

    mgsin f

    tan >

    SECTIONIIMultiple Correct Choice Type

    This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which ONE

    OR MORE may be correct.

    *65. A student uses a simple pendulum of exactly 1 m length to determine g, the acceleration due to gravity. He uses a stop watch

    with the least count of 1 sec for this and records 40 seconds for 20 oscillations. For this observation, which of the following

    statement(s) is (are) true?

    (A) Error Tin measuring T, the time period, is 0.05 seconds

    (B) Error Tin measuring T, the time period, is 1 second(C) Percentage error in the determination ofg is 5%

    (D) Percentage error in the determination ofg is 2.5%

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    Sol.: t= nT;n

    tT

    n

    tT

    05.0

    20

    1T sec.

    g

    l

    n

    t 2

    2

    224

    t

    lng

    ; 100

    2100

    t

    t

    g

    g= 5%

    Correct choices: (A), (C)

    66. A ray OP of monochromatic light is incident on the face AB of prism ABCD

    near vertexB at an incident angle of 60 (see figure). If the refractive index of

    the material of the prism is 3 , which of the following is (are) correct?

    (A) The ray gets totally internally reflected at face CD

    (B) The ray comes out through face AD

    (C) The angle between the incident ray and the emergent ray is 90

    (D) The angle between the incident ray and the emergent ray is 120 900 750

    1350

    600

    B

    C

    DA

    P

    O

    Sol.: 3sin

    60sin 0

    rr= 300

    Let ic be the critical angle, then,3

    1sin ci

    300 < ic < 450

    Also, the angle between incident and emergent ray is 900

    Correct choices: (A), (B), (C)750

    1350

    600

    B

    C

    DA

    300

    600

    450

    450

    300

    600

    67. A few electric field lines for a system of two charges Q1 and Q2 fixed at two

    different points on the x-axis are shown in the figure. These lines suggest that

    (A) |||| 21 QQ

    (B) |||| 21 QQ

    (C) at a finite distance to the left ofQ1 the electric field is zero

    (D) at a finite distance to the right ofQ2 the electric field is zero

    Q1 Q2

    Sol.: Number of field lines magnitude of charge and2

    r

    KQE

    Correct choices: (A), (D)

    *68. One mole of an ideal gas in initial stateA undergoes a cyclic processABCA, as

    shown in the figure. Its pressure atA is P0. Choose the correct option(s) from thefollowing

    (A) Internal energies atA andB are the same

    (B) Work done by the gas in processAB is 400 nVP

    (C) Pressure at Cis4

    0P

    (D) Temperature at Cis4

    0T

    A

    T

    V

    V0

    4V0 B

    C

    T0

    Sol.: ProcessAB is isothermal, so WAB = P0V0 ln 4 and UAB = 0

    ProcessBC is unknown (as its not given whether the lineBCis directed towards origin or not)

    Correct choices: (A), (B)

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    *69. A point mass of 1 kg collides elastically with a stationary point mass of 5 kg. After their collision, the 1 kg mass reverses its

    direction and moves with a speed of 2 ms1. Which of the following statement(s) is (are) correct for the system of these two

    masses?

    (A) Total momentum of the system is 3 kg ms1

    (B) Momentum of 5 kg mass after collision is 4 kg ms1

    (C) Kinetic energy of the centre of mass is 0.75 J

    (D) Total kinetic energy of the system is 4 J

    Sol.: Applying conservation of linear momentum

    2521051 VV (i)

    As collision is elastic,

    VV 22 (ii)

    112 ms3,ms1 VV

    Total momentum of the system = 3 kg m/s

    m/s2

    1

    51

    01cm

    VV

    J75.05121

    E.K 2cmcm V

    Correct choices: (A), (C)

    1kg V 5kg 1kg V25kg2m/s

    Before collision After collision

    SECTION IIIParagraph Type

    This section contains 2 paragraphs. Based upon the first paragraph 3 multiple choice questions and based upon the second

    paragraph 2 multiple choice questions have beanswered. Each of these questions has four choices (A), (B), (C) and (D) out

    of which ONLY ONE is correct.

    Paragraph for Question Nos. 70 to 72

    When a particle of mass m moves on the x-axis in a potential of the form ,)( 2kxxV it performs simple harmonic motion. The corresponding time period is proportional to

    ,k

    m as can be seen easily using dimensional analysis. However, the motion of the

    particle can be periodic even when its potential energy increases on both sides ofx = 0

    in a way different from kx2 and its total energy is such that the particle does not escape

    to infinity. Consider a particle of mass m moving on thex-axis. Its potential energy is

    )0()( 4 xxV for | x | near the origin and becomes a constant equal to V0 for

    0|| Xx (see figure).

    V(x)

    V0

    X0x

    *70. If the total energy of the particle isE, it will perform periodic motion only if

    (A)E< 0 (B)E> 0 (C) V0 > E> 0 (D)E> V0Sol.: 0,0 EVE

    Correct choice: (C)

    *71. For periodic motion of small amplitudeA, the time period Tof this particle is proportional to

    (A)m

    A (B)m

    A

    1(C)

    mA

    (D)

    mA

    1

    Sol.: Using dimensional analysis

    Correct choice: (B)

    *72. The acceleration of this particle for 0|| Xx is

    (A) proportional to V0 (B) proportional to0

    0

    mX

    V(C) proportional to

    0

    0

    mX

    V(D) zero

    Sol.: 0VU andF = 0dx

    dU

    Correct choice: (D)

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    Paragraph for Question Nos. 73 to 74

    Electrical resistance of certain materials, known as superconductors,

    changes abruptly from a nonzero value to zero as their temperature is

    lowered below a critical temperature TC (0). An interesting property of

    superconductors is that their critical temperature becomes smaller than

    TC(0) if they are placed in a magnetic field, i.e., the critical temperatureTC(B) is a function of the magnetic field strength B. The dependence of

    TC(B) onB is shown in the figure. B

    TC(B)

    O

    TC(0)

    73. In the graphs below, the resistance R of a superconductor is shown as a function of its temperature T for two different

    magnetic fieldB1 (solid line) andB2 (dashed line). If B2 is larger than B1, which of the following graphs shows the correctvariation ofR with Tin these fields?

    T

    R

    O

    (A)

    B2B1

    T

    R

    O

    (B)

    B2

    B1

    T

    R

    O

    (C)

    B1B2

    T

    R

    O

    (D)

    B1

    B2

    Sol.: Higher the magnetic field, lower is the temperature at which resistance abruptly becomes zero.

    Correct choice: (A)

    74. A superconductor has TC (0) = 100 K. When a magnetic field of 7.5 Tesla is applied, its TC decreases to 75 K. For this

    material one can definitely say that when

    (A)B = 5 Tesla, TC(B) = 80 K (B)B = 5 Tesla, 75 K < TC(B) < 100 K

    (C)B = 10 Tesla, 75 K < TC(B) < 100 K (D)B = 10 Tesla, TC(B) = 70 K

    Sol.: As the magnetic field decreases, TCincreases

    Correct choice: (B)

    SECTION IVInteger Type

    This section contains TEN questions. The answer to each question is a single-digit integer, ranging from 0 to 9. The correct

    digit below the question number in the ORS is to be bubbled.

    75. When two identical batteries of internal resistance 1 each are connected in series across a resistor R, the rate of heat

    produced inR isJ1. When the same batteries are connected in parallel acrossR, the rate isJ2. IfJ1 = 2.25J2 then the value of

    R in is

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    Sol.: In first case

    I rR 2

    2

    Rate of heat produced inR, RrR

    RIJ

    2

    21

    2

    2

    R

    r r

    I

    In second case

    2

    'r

    R

    I

    Rate of heat produced inR, Rr

    R

    J

    2

    2

    2

    As 21 25.2 JJ

    rR 4 = 4Answer is 4

    r

    R

    r

    'I

    *76. Two spherical bodies A (radius 6 cm) and B (radius 18 cm) are at temperatures T1 and T2, respectively. The maximum

    intensity in the emission spectrum ofA is at 500 nm and in that ofB is at 1500 nm. Considering them to be blackbodies, what

    will be the ratio of the rate of total energy radiated byA to that ofB?

    Sol.: For a black body,energyradiated per unit time = 4AT (whereR is radius of the body)

    42

    B

    A

    B

    A

    B

    A

    T

    T

    R

    R

    E

    E (i)

    According to Weins displacement law, Tm constant

    42

    500

    1500

    18

    6

    B

    A

    E

    E

    = 9

    Answer is 9

    *77. When two progressive waves

    262sin3and)62sin(4 21 txytxy are superimposed, the amplitude of the

    resultant wave is

    Sol.: cos2 2122

    21 AAAAA = 525

    2cos34234 22

    Answer is 5

    *78. A 0.1 kg mass is suspended from a wire of negligible mass. The length of the wire is 1 m and its cross-sectional areas is

    4.9 107 m2. If the mass is pulled a little in the vertically downward direction and released, it performs simple harmonic

    motion of angular frequency 140 rad s1. If the Youngs modulus of the material of the wire is n 109 Nm2, the value ofn is

    Sol.:m

    K

    Lm

    YA

    1.01

    109.410140

    792

    n

    Lm

    YA

    n = 4

    Answer is 4

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    *79. A binary star consists of two starsA (mass 2.2MS) and B (mass 11MS), whereMS is the mass of the sun. They are separated

    by distance dand are rotating about their centre of mass, which is stationary. The ratio of the total angular momentum of the

    binary star to the angular momentum of star B about the centre of mass is

    Sol.:CM

    2.2MS 11MS

    5d/6 d/6

    11 IL and 22 IL

    66/11

    6/52.26/112

    22

    2

    1

    2

    1

    dM

    dMdM

    I

    I

    L

    L

    S

    SS

    Answers is 6

    *80. Gravitational acceleration on the surface of a planet is ,11

    6g where g is the gravitational acceleration on the surface of the

    earth. The average mass density of the planet is3

    2times that of the earth. If the escape speed on the surface of the earth is

    taken to be 11 kms-1

    , the escape speed on the surface of the planet in kms1

    will be

    Sol.:2

    2

    EE

    PP

    P

    E

    E

    P

    eE

    eP

    R

    R

    R

    R

    M

    M

    V

    V

    (i)

    As2

    3

    2 3

    4

    R

    RG

    R

    GMg

    gR

    P

    E

    E

    P

    E

    P

    g

    g

    R

    R

    (ii)

    22

    E

    P

    P

    E

    E

    P

    eE

    eP

    g

    g

    V

    V2

    11

    6

    2

    3

    VeP = 3 km/s

    Answer is 3

    *81. A piece of ice (heat capacity = 2100 J kg1 C1 and latent heat = 3.36 105 J kg1) of mass m grams is at 5C at

    atmospheric pressure. It is given 420 J of heat so that the ice starts melting. Finally when the ice-water mixture is in

    equilibrium, it is found that 1 gm of ice has melted. Assuming there is no other heat exchange in the process, the value ofm is

    Ans.: Heat required for melting ice = 3361036.3100

    1 5 J

    Heat used for raising temperature of ice from (50C to 00C) = 336420Q = 84 J

    TmsQ 5210084 m

    m = 0.008 kg = 8 gm

    Answer is 8

    *82. A stationary source is emitting sound at a fixed frequency f0, which is reflected by two cars approaching the source. The

    difference between the frequencies of sound reflected from the cars is 1.2% off0. What is the difference in the speeds of the

    cars (in km per hour) to the nearest integer? The cars are moving at constant speeds much smaller than the speed of sound

    which is 330 ms1.

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    Sol.: Apparent frequency received by car is

    V

    VVff 001 (i)

    The frequency of the reflected wave is

    0

    11 'VV

    Vff =

    0

    00

    VV

    VVf (ii)

    Differentiating '1f with respect to V0

    3302

    330

    660

    330

    330330' 02

    0

    002

    0

    00

    0

    1 f

    V

    ff

    V

    VV

    dV

    df

    0

    10

    '165

    f

    dfdV 7 km/h

    Answer is 7

    83. The focal length of a thin biconvex lens is 20 cm. When an object is moved from a distance of 25 cm in front of it to 50 cm,

    the magnification of its image changes from m25 to m50. The ratio50

    25

    mm is

    Sol.:20

    1

    25

    11

    1

    V

    cm1001 V

    Similarly

    100

    3

    100

    25

    50

    1

    20

    11

    2

    V

    3

    1002 V cm

    503

    100

    25

    100

    50

    25

    m

    m= 6

    Answer is 6

    84. An -particle and a proton are accelerated from rest by a potential difference of 100V. After this, their de Broglie

    wavelengths are and p respectively. The ratio

    p

    , to the nearest integer, is

    Sol.: The momentum of a charged particle accelerated by potential difference V, qmVP 2

    de-Broglie wavelength,P

    h

    3222

    422

    Vme

    Vmep

    Answer is 3

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    SOLUTIONS TO IIT-JEE 2010Paper-II (Code: 8)

    Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.

    A. General:1. This Question Paper contains 24 pages having 57 questions. The question paper CODE is

    printed on the right hand top corner of this sheet and also on the back page of thisbooklet..

    2. No additional sheets will be provided for rough work.3. Blank papers, clipboards, log tables, slide rules, calculators, cellular phones, pagers and

    electronic gadgets in any form are not allowed.4. Log and Antilog tables are given in the paper.

    5. The answer sheet, a machine-gradable Objective Response Sheet (ORS), is providedseparately.

    6. Write your Registration No., Name, Name of the centre and sign with pen in theappropriate boxes. Do not write these anywhere else.

    B. Question paper format and Marking scheme:7. The question paper consists of 3 parts (Chemistry, Mathematics and Physics), and each

    Part consists offour Sections.

    8. For each question in Section I,you will be awarded 5 marks if you have darkened onlythe bubble corresponding to the correct answer and zero mark if no bubbles aredarkened. In all other cases, minus two (2) markwill be awarded.

    9. For each question in Section II, you will be awarded 3 marks if you darken only thebubble corresponding to the correct answer and zero mark if no bubble is darkened. Nonegative marks will be awarded for incorrect answers in this Section.

    10. For each question in Section III, you will be awarded 3 marks if you darken only thebubble corresponding to the correct answer and zero mark if no bubbles are darkened. Inall other cases, minus one (1) markwill be awarded.

    11. For each question in Section IV,you will be awarded 2 marks for each row in which youhave darkened the bubble(s) corresponding to the correct answer. Thus, each question inthis section carries a maximum of8 marks.

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    SOLUTIONS TO IIT-JEE 2010CHEMISTRY: Paper-II (Code: 8)

    PARTI

    SECTION I

    Single Correct Choice Type

    This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out ofwhich ONLY ONE is correct.

    Note: Questions with (*) mark are from syllabus of class XI.

    1. In the reaction H3C C

    O

    NH2

    (1) NaOH/Br2

    (2) C

    O

    Cl

    T

    the structure of the Product T is

    (A)H3C C

    O

    OC

    O(B) NH

    C

    O

    CH3

    (C) H3C NH

    O

    C

    (D)H3C C

    O

    NHC

    O

    Sol.: H3C C

    O

    NH2

    (1) NaOH/Br2Me NH2

    HCl

    C

    O

    ClMe NHC

    O

    Correct choice: (C)

    *2. Assuming that Hunds rule is violated, the bond order and magnetic nature of the diatomic molecule B 2 is

    (A) 1 and diamagnetic (B) 0 and diamagnetic (C) 1 and paramagnetic (D) 0 and paramagnetic

    Sol.: Molecular orbital configuration of B2 as per the condition will be

    1s2, *1s2, 2s2, *2s2, 2yP2

    Bond order of B2 =2

    46= 1.

    B2 will be diamagnetic.

    Correct choice: (A)

    3. The compounds P, Q and S

    HO

    COOH

    P H3C

    OCH3

    Q

    CO

    O

    Swere separately subjected to nitration using HNO3/H2SO4 mixture. The major product formed in each case respectively, is

    (A)

    HO

    COOH

    H3C

    OCH3 CO

    O

    NO2 NO2

    O2N

    (B)

    HO

    COOH

    H3C

    OCH3 CO

    O

    NO2NO2

    NO2

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    31

    (C)

    HO

    COOH

    H3C

    OCH3 CO

    O

    NO2NO2

    NO2

    (D)

    HO

    COOH

    H3C

    OCH3 C O

    O

    NO2NO2

    NO2

    Sol.:

    OH

    CO2H

    (P)

    HNO3/H2SO4

    OH

    CO2H

    NO2

    CH3

    OCH3

    (Q)

    HNO3/H2SO4NO2

    CH3

    OCH3

    O

    (S)

    HNO3/H2SO4O

    O

    O NO2

    Correct choice: (C)

    *4. The species having pyramidal shape is

    (A) SO3 (B) BrF3 (C) 23SiO (D) OSF2

    Sol.: OSF2:2

    N=

    2

    26 = 4.

    It has 1 lone pair.

    S (Shape is trigonal pyramidal)

    FO F

    ..

    The shapes of SO3, BrF3 and2

    3SiO are triangular planar, T-shaped and triangular planar respectively.

    Correct choice: (D)

    5. The complex showing a spin-only magnetic moment of 2.82 B.M. is

    (A) Ni(CO)4 (B) [NiCl4]2 (C) Ni(PPh3)4 (D) [Ni(CN)4]

    2

    Sol.: Ni(CO)4 and Ni(PPh3)4 have Ni in zero oxidation state, while CO and Ph 3P are strong field ligands. Thus, both these

    molecules have sp3 hybridization and are diamagnetic. [Ni(CN)4]2 has electronic configuration of Ni2+ as 3d8 and

    hybridization is dsp2. It is diamagnetic. [NiCl4]2 has sp3 hybridization with 2 unpaired electrons giving spin only magnetic

    moment as 8 or 2.82 B.M.

    Correct choice: (B)

    6. The packing efficiency of the two-dimensional square unit cell shown below is

    L

    (A) 39.27% (B) 68.02% (C) 74.05% (D) 78.54%

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    32

    Sol.: Packing efficiency =squareofArea

    circleseffectivebyoccupiedArea

    = 100L

    r22

    2

    = 100)r22(

    r2

    2

    2

    = 1004

    = 78.54%.

    Correct choice: (D)

    SECTIONIIInteger Type

    This section contains a group of 5 questions. The answer to each of the questions is a single digit integer, ranging from 0 to 9.

    The correct digit below the question no. in the ORS is to be bubbled.

    *7. One mole of an ideal gas is taken from a to b along two paths denoted by the solid and the dashed lines as shown in the

    graphs below. If the work done along the solid line path is ws and that along the dotted line path is wd, then the integer closest

    to the ratio wd/ws is

    0.5

    1.0

    1.5

    2.0

    25

    3.0

    3.5

    4.0

    4.5

    0.00.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 5.5 6.0

    P

    (atm)

    V (lit.)

    b

    a

    Sol.: wd =

    2

    5

    3

    211

    2

    34 =

    3

    516

    wd =3

    26 L atm

    ws =2.303 RT log2/1

    5.5=2.303 PV log 11

    ws =4.606 1.04 =4.8 L atm

    s

    d

    w

    w=

    8.4

    326

    = 1.80 ~2.0

    The answer is 2.

    *8. Among the following, the number of elements showing only one non-zero oxidation state is

    O, Cl, F, N, P, Sn, Tl, Na, Ti

    Sol.: Fluorine generally shows O and1 oxidation states while sodium shows 0 and +1 oxidation state.

    The answer is 2.

    9. Silver (atomic weight = 108 g mol1

    ) has a density of 10.5 g cm3

    . The number of silver atoms on a surface of area 1012

    m2

    can be expressed in scientific notation as y 10x. The value of x is

    Sol.: Silver has cubic close packed structure. It has fcc unit cell of edge length a cm.

    10.5 =323 )a(10023.6

    1084

    a =3/1

    23 5.1010023.6

    1084

    = 4.087 108 cm.

    (i) Assuming that surface area given is the area of any extended face of a FCC unit cell.

    Area of square face = (4.087 108)2 cm2

    Number of Ag atoms per unit area =2

    a

    2

    Surface area = 1012 m2 = 108 cm2.

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    33

    Number of Ag atoms in the given surface area =28

    8

    )10087.4(

    102

    = 1.197 107.

    x = 7.

    (ii) Assuming that surface area given is the area corresponding to closest packed layer.

    2 a = 4r, r =4

    a2 =4

    210087.4

    8

    = 1.44 108

    In a closest packed layer, the arrangement appears like

    2)r2(4

    36 =

    4

    36(2 1.44 108)2 =

    161007.244

    36

    = 21.5 1016 cm2

    Number of silver atoms on surface =16

    8

    105.21

    103

    = 0.139 108 = 1.39 107.

    x = 7.

    The answer is 7.

    10. Total number of geometrical isomers for the complex [RhCl(CO)(PPh3)(NH3)] is

    Sol.: Rh

    Cl PPh3

    CO NH3

    Rh

    Cl PPh3

    NH3 CO

    Rh

    Cl CO

    NH3 PPh3

    The number of geometrical isomers is 3.The answer is 3.

    *11. The total number of diprotic acids among the following is

    H3PO4 H2SO4 H3PO3 H2CO3 H2S2O7

    H3BO3 H3PO2 H2CrO4 H2SO3

    Sol.: Diprotic acids are H2SO4, H3PO3, H2CO3, H2S2O7, H2CrO4 and H2SO3.

    The answer is 6.

    SECTION IIIParagraph Type

    This Section contains 2 paragraphs. Based upon each of the paragraphs 3 multiple choice questions have to be answered.

    Each of these questions has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct.

    Paragraph for questions 12 to 14

    Two aliphatic aldehydes P and Q react in the presence of aqueous K 2CO3 to give compound R, which upon treatment with

    HCN provides compound S. On acidification and heating, S gives the product shown below.

    O O

    H3C

    H3C OH

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    12. The compounds P and Q respectively are

    (A)

    H3C

    CH

    CH3

    CH

    andH3C

    CH

    OO

    (B)

    H3C

    CH

    CH3

    CH

    andH

    CH

    OO

    (C)H3C CH2

    CH3

    CH

    andH3C

    CH

    OO

    CH (D)H3C CH2

    CH3

    CH

    andH

    CH

    OO

    CH

    Sol.: CH3CHCHO + OH CH3C

    CHO + H2O

    CH3 CH3

    CH3CCHO + CH2 = O CH3CCHO CH3CCHO

    H2O

    OH

    CH3 CH3 CH3

    CH2O CH2OH

    CH3CCH=O + HCN CH3CCHCN CH3CCHCOOHH+

    /H2O

    CH3 H3C OH OH

    CH2OHCH2OH CH2OH

    (S)

    O OH3C

    H3C OH

    Intramolecular esterificationH3C

    (P)

    (Q)

    (R)

    Correct choice: (B)

    13. The compound R is

    (A)

    H3C

    CH3C

    C

    CH2OH

    O

    H (B)

    H3C

    CH3C

    C

    CHOH

    O

    H

    H3C

    (C)CH

    CHC

    CH2OH

    O

    HH3C

    CH3

    (D)

    CH

    CH

    H3C

    C

    CHOH

    O

    HH3C

    CH3

    Sol.: Correct choice: (A)

    14. The compound S is

    (A)CH

    CH

    C

    CH2

    CN

    O

    HH3C

    CH3

    (B)H3C

    CH3C

    C

    CH2

    CN

    O

    H

    (C)CH

    CHCH

    CH2OH

    CN

    OHH3C

    CH3

    (D)H3C

    CH3C

    CH

    CH2OH

    CN

    OH

    Sol.: Correct choice: (D)

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    Paragraph for questions 15 to 17

    The hydrogen-like species Li2+ is in a spherically symmetric state S1 with one radial node. Upon absorbing light the ion

    undergoes transition to a state S2. The state S2 has one radial node and its energy is equal to the ground state energy of the

    hydrogen atom.

    *15. The state S1 is

    (A) 1s (B) 2s (C) 2p (D) 3s

    Sol.: The spherically symmetric state S1 of Li2+ with one radial node is 2s. Upon absorbing light, the ion gets excited to state S2,

    which also has one radial node. The energy of electron in S2 is same as that of H-atom in its ground state

    12

    2

    n En

    ZE where E1 is the energy of H-atom in the ground state

    2

    12

    n

    E)3( for Li2+

    3nEE 1n

    State S2 of Li2+ having one radial node is 3p.

    Orbital angular momentum quantum number of 3p is 1.

    Energy of state 112

    2

    1 E25.2E)2(

    )3(S

    Correct choice: (B)

    *16. Energy of the state S1 in units of the hydrogen atom ground state energy is

    (A) 0.75 (B) 1.50 (C) 2.25 (D) 4.50

    Sol.: Correct choice: (C)

    *17. The orbital angular momentum quantum number of the state S2 is

    (A) 0 (B) 1 (C) 2 (D) 3

    Sol.: Correct choice: (B)

    SECTION IV(Matrix Type)

    This section contains 2 questions. Each question contains has four statements (A, B, C and D) given in Column I and fivestatements (p, q, r, s and t) in Column II. Any given statement in Column I can have correct matching with one or more

    statement(s) given in Column II. For example, if for a given question, statement B matches with the statements given in q

    and r, then for that particular question, against statement B, darken the bubbles corresponding to q and r in the ORS.

    18. Match the reactions is Column I with appropriate options in Column II.

    Column I Column II

    (A) N2Cl + OHNaOH/H2O

    0C N=N OH (p) Racemic mixture

    (B) H3C

    C

    CH3

    O

    CH3CCCCH3

    OHOH

    H3C CH3

    H2SO

    4

    CH3

    CH3

    (q) Addition reaction

    (C) C CH

    O

    CH3

    1. LiAlH4

    2. H3O+

    OH

    CH3

    (r) Substitution reaction

    (D) HS ClBase S (s) Coupling reaction

    (t) Carbocation intermediate

    Sol.: (A)(r), (s) ; (B)(t) ; (C)(p), (q) ; (D) (r)

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    19. All the compounds listed in Column I react with water. Match the result of the respective reactions with the appropriate

    options listed in Column II.

    Column I Column II

    (A) (CH3)2SiCl2 (p) Hydrogen halide formation

    (B) XeF4 (q) Redox reaction

    (C) Cl2 (r) Reacts with glass

    (D) VCl5 (s) Polymerization

    (t) O2 formation

    Sol.: (A)(p), (s)

    (CH3)2SiCl2 + 2H2O HCl2 (CH3)2Si(OH)2 .Polymn

    [(CH3)2SiO]n.

    (B)(p), (q), (r), (t)

    XeF4 + H2O Xe + XeO3 + H2F2 + O2

    SiO2 + 4HF SiF4 + 2H2Oglass

    SiF4 + 2HF H2[SiF6]Soluble hexathorosilicic(IV) acid

    (C)(p), (q)

    Cl2 + H2O HCl + HOCl

    (D)(p), (q)

    VCl5 + 7H2O [V(H2O)6]3+ + 3Cl+ HCl + HOCl

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    SOLUTIONS TO IIT-JEE 2010MATHEMATICS: Paper-II (Code: 8)

    PARTII

    SECTION I

    Single Correct Choice Type

    This section contains 6 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for itsanswer, out of which ONLY ONE is correct.

    20. Letf be a real-valued function defined on the interval (1, 1) such that x

    x txfe

    0

    4 12)( dt, for all ),1,1(x and

    let 1f be the inverse function of f . Then )2()'( 1f is equal to

    (A) 1 (B)3

    1(C)

    2

    1(D)

    e

    1

    Sol.: dttxfe

    x

    x 0

    4 12)( (i)

    Putting 0x

    2)0( f 0)2(1 f xxff ))(( 1 1)()'(.))((' 11 xfxff )0('

    1)2()'( 1

    ff

    Differentiate equation (i) with respect tox

    1)()(' 4 xxfexfe xx

    Putting 0x

    12)0(' f 3)0(' f 3

    1)2()'( 1 f

    Correct choice: (B)

    21. A signal which can be green or red with probability5

    4and

    5

    1respectively, is received by station A and then transmitted to

    stationB. The probability of each station receiving the signal correctly is4

    3. If the signal received at station B is green, then

    the probability that the original signal was green is

    (A)5

    3(B)

    7

    6(C)

    23

    20(D)

    20

    9

    Sol.: GR Received signal is green

    GO Original signal was green

    If the eventXYZdenotes original single sent toA wasX, received atA was Yand received atB isZ

    )(

    )(

    G

    GG

    G

    G

    RP

    ROP

    R

    OP

    )()()()(

    )()(

    RGGPRRGPGGGPGRGP

    GGGPGRGP

    4

    3

    4

    1

    5

    1

    4

    1

    4

    3

    5

    1

    4

    3

    4

    3

    5

    4

    4

    1

    4

    1

    5

    4

    4

    3

    4

    3

    5

    4

    4

    1

    4

    1

    5

    4

    23

    20

    80

    4680

    40

    Correct choice: (C)

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    22. If the distance of the point )1,2,1( P from the plane zyx 22 , where 0 , is 5, then the foot of the perpendicular

    from P to the plane is

    (A)

    3

    7,

    3

    4,

    3

    8(B)

    3

    1,

    3

    4,

    3

    4(C)

    3

    10,

    3

    2,

    3

    1(D)

    2

    5,

    3

    1,

    3

    2

    Sol.: 5441

    241

    155 ( )0

    10

    Plane is 01022 zyx

    Let the foot of perpendicular be F, equation of line PFis

    2

    1

    2

    2

    1

    1

    zyx

    So the point Fcan be taken as

    F

    P

    )21,22,1(

    It will satisfy equation of plane.

    01042441 3

    5

    Point Fis

    3

    7,

    3

    4,

    3

    8

    Correct choice: (A)

    *23. Let }4,3,2,1{S . The total number of unordered pairs of disjoint subsets ofS is equal to

    (A) 25 (B) 34 (C) 42 (D) 41

    Sol.: Given set 4,3,2,1S

    For disjoint subsetsA andB

    Sa

    Ba

    Aa

    Ba

    Aa

    Ba

    Aa

    Then total number of disjoint subsets will be 12

    134

    = 41

    Correct choice: (D)

    *24. For 10,....1,0r let rr BA , and rC denote, respectively, the coefficient ofr

    x in the expansions of ,)1(10

    x 20)1( x and

    30)1( x . Then

    10

    1

    1010 )(

    r

    rrr ACBBA is equal to

    (A) 1010 CB (B) )( 101021010 ACBA (C) 0 (D) 1010 BC

    Sol.:

    10

    1

    21010

    302010

    2010

    r

    rrr CCCCC =

    10

    1

    10

    1

    21010

    30102010

    20

    r r

    rrr CCCCC

    = 11 1020103010301020 CCCC = 101010201030 BCCC Correct choice: (D)

    25. Two adjacent sides of a parallelogram ABCD are given by kjiAB 11102 and kjiAD 22 . The side AD isrotated by an acute angle in the plane of the parallelogram so that AD becomes 'AD . If 'AD makes a right angle with theside AB , then the cosine of the angle is given by

    (A) 9

    8

    (B) 9

    17

    (C) 9

    1

    (D) 9

    54

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    Sol.: ||||. ADABADAB )90cos(

    31540 sin

    sin9

    8;

    9

    17cos

    90

    D C

    BA

    'D

    Correct choice: (B)

    SECTIONII(Integer Type)

    This section contains 5 questions. The answer to each question is a singledigit integer, ranging from 0 to 9. The correctdigit below the question no. in the ORS is to be bubbled.

    26. Let kbe a positive real number and let

    02

    2021

    120

    and

    122

    212

    2212

    kk

    kk

    kk

    B

    kk

    kk

    kkk

    A .

    If det 610)adj(det)adj( BA , then [k] is equal to

    [Note: adjMdenotes the adjoint of a square matrixMand [k] denotes the largest integer less than or equal to k]

    Sol.: 122

    12120

    2212

    det

    kk

    kk

    kkk

    A

    kkkkk

    kkk

    k 81212

    1122

    100

    2412

    12 2

    312 k

    0det B [B is skew symmetric matrix of order 3]

    66 1012 k 1012 k 29k [k] = 4

    Ans. 4

    27. Letf be a function defined onR(the set on all real numbers) such that

    ,)2012()2011()2010)(2009(2010)(' 432 xxxxxf for all Rx . Ifg is a function defined on R with values in theinterval ),0( such that ))(ln()( xgxf , for all Rx , then the number of points inR at which g has a local maximum is

    Sol.:

    xgxg

    xf .1

    xgxfxg

    As 0xg , So xg will change sign as

    2009 2011

    ++

    one point of maxima is 2009x

    Ans. 1

    *28. Let 11321 ,....,, aaaa be real numbers satisfying 151 a , 0227 2 a and 212 kkk aaa for 11...,,4,3k .

    If 9011

    ... 21122

    21

    aaa, then the value of

    11

    ... 1121 aaa is equal to

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    Sol.: 151 a

    As 211 kkkk aaaa

    So ......,,, 321 aaa are in A.P.

    Also 0227 2 a

    2

    312 aa

    2

    3d

    9011

    ......211

    22

    21

    aaa 90115

    11

    111

    1

    2 r

    dr

    9035150225 2 dd 027307 2 dd 0973 dd 7

    9,3

    d

    But7

    9d

    2

    3d

    Now 030302

    11030

    2

    1

    11

    ...... 1121

    daaa

    Ans. 0

    29. Consider a triangle ABCand let ba, and c denote the lengths of the sides opposite to vertices A, B and C respectively.

    Suppose 6a , 10b and the area of the triangle is 315 . If ACB is obtuse and ifrdenotes the radius of the incircle of

    the triangle, then 2r is equal to

    Sol.: 315

    315sin1062

    1C

    2

    3sin C

    obtuseis

    3

    2CC

    120

    10036cos

    2c

    C

    14c

    Hence semi perimeter 15s

    3r 32 r

    Ans. 3

    30. Two parallel chords of a circle of radius 2 are at a distance 13 apart. If the chords subtend at the center, angles ofk

    and

    k

    2, where 0k , then the value of [k] is [Note : [k] denotes the largest integer less than or equal to k]

    Sol.: 1321 pp

    132

    cos2cos2

    kk

    2

    13

    2coscos

    kk

    3k

    Ans. 3

    /2k

    /k p1

    p22

    2

    A B

    DC

    O

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    SECTION III(Paragraph Type)

    This section contains 2 paragraphs. Based upon each of the paragraphs 3 multiple choice questions have to be answered.

    Each of these question has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct.

    Paragraph for Questions 31 to 33

    Consider the polynomial 32 4321)( xxxxf . Let s be the sum of all distinct real roots of )(xf and let || st .

    31. The real number s lies in the interval

    (A)

    0,

    4

    1(B)

    4

    3,11 (C)

    2

    1,

    4

    3(D)

    4

    1,0

    Sol.: Given function 32 4321)( xxxxf is monotonically increasing

    as Rxxxxf 0]136[2)(' 2 ]48/5)4/1[(12 2 x

    )(xf will have only one real root

    Since 0

    2

    1.

    4

    3

    ff s lies in

    2

    1,

    4

    3

    Correct choice: (C)

    32. The area bounded by the curve )(xfy and the lines 0x , 0y and tx , lies in the interval

    (A)

    3,

    4

    3(B)

    16

    11,

    64

    21(C) (9, 10) (D)

    64

    21,0

    Sol.: As || st

    4

    3,

    2

    1t

    Hence required area will be the shaded region shown in

    the figure.

    t1/23/4

    O

    Area t

    dxxxxtA

    0

    32 )4321()( 432 tttt which is increasing

    Area

    4

    3,

    2

    1AA

    256

    525,

    16

    15

    Correct choice: (A)

    33. The function )(' xf is

    (A) increasing in

    4

    1,t and deceasing in

    t,

    4

    1(B) decreasing in

    4

    1,t and increasing in

    t,

    4

    1

    (C) increasing in ),( tt (D) decreasing in ),( tt

    Sol.:

    4

    124 xxf xf increases

    ,

    4

    1x

    xf decreases

    4

    1,x

    Correct choice: (B)

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    42

    Paragraph for Questions 34 to 36

    Tangents are drawn from the point )4,3(P to the ellipse 149

    22

    yx

    touching the ellipse at pointsA andB.

    *34. The coordinates ofA andB are

    (A) (3, 0) and (0, 2) (B)

    15

    1612,

    5

    8and

    5

    8,

    5

    9

    (C)

    15

    1612,

    5

    8and (0, 2) (D) (3, 0) and

    5

    8,

    5

    9

    Sol.: Let 49 2 mmxy be the tangent passing through point 4,3 to the given ellipse.

    4934 22 mm 2

    1m and indeterminate.

    one tangent is2

    5

    2

    1 xy at

    5

    8,

    5

    9