kaplan mcat

23
WELCOME TO KAPLAN! Today you begin your Kaplan MCAT preparation with a full “work-up” that includes a Personal Profile and two Diagnostic Tests to evaluate both your science knowledge and your critical thinking ability. Please note that in order to maintain your Higher Score Guarantee eligibility you must take the online (non PDF) version of the diagnostic found on your Kaptest.com student syllabus. From the information obtained here, we will prescribe a personalized study regimen designed to review and reinforce relevant science content as well as emphasize the “higher order” analytical thinking and problem-solving skills the MCAT is designed to test. The Science Diagnostic Test consists of 120 discrete science questions, 30 each in biology, general chemistry, organic chemistry, and physics. You will do this test first. The test is specifically designed to assess your raw knowledge in the science areas covered on the MCAT. The results of this test, in combination with the MCAT Diagnostic and the Personal Profile, will provide a more complete picture of your “MCAT health.” Please use the section of your Online Student Center labeled Science Diagnostic to complete this test. The Personal Profile contains questions about your academic background, study habits, perceived academic strengths and weaknesses, etc. Your responses to these questions will be integrated with your performance on the Diagnostic Tests, enabling us to tailor a study plan suited to your study habits and academic needs. PLEASE ANSWER EVERY QUESTION (UNLESS YOU ARE TOLD TO LEAVE IT BLANK), or incomplete feedback will be generated. You can input your Personal Profile answers into the last section of the Science Diagnostic input form,(see above for the location of this form) in a section labeled Personal Profile. The MCAT Diagnostic Test (half-length) simulates the actual MCAT experience. The test will indicate how well, at present, you can handle MCAT-style questions and passages that require critical thinking and problem-solving. Remember, the MCAT is not just a science exam. While it requires you to have a firm knowledge of fundamental science concepts, it also tests your ability to integrate new information presented in challenging science passages. As on the actual MCAT, there is no penalty for incorrect answers. Please use the input form labeled MCAT Diagnostic to input your responses to this test. Remember, your feedback from today’s “work-up” is only a baseline evaluation. The Kaplan MCAT Program is designed to help you master ALL the material and skills necessary for your success on the MCAT. Good luck! Team MCAT

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WELCOME TO KAPLAN!

Today you begin your Kaplan MCAT preparation with a full “work-up” that includes a Personal Profileand two Diagnostic Tests to evaluate both your science knowledge and your critical thinking ability.Please note that in order to maintain your Higher Score Guarantee eligibility you must take the online (non PDF)version of the diagnostic found on your Kaptest.com student syllabus. From the information obtained here, we will prescribe a personalized study regimen designed to review and reinforce relevant science content as well as emphasize the “higher order” analytical thinking and problem-solving skills the MCAT is designed to test.

The Science Diagnostic Test consists of 120 discrete science questions, 30 each in biology, generalchemistry, organic chemistry, and physics. You will do this test first. The test is specifically designed toassess your raw knowledge in the science areas covered on the MCAT. The results of this test, incombination with the MCAT Diagnostic and the Personal Profile, will provide a more complete picture ofyour “MCAT health.” Please use the section of your Online Student Center labeled Science Diagnostic tocomplete this test.

The Personal Profile contains questions about your academic background, study habits, perceivedacademic strengths and weaknesses, etc. Your responses to these questions will be integrated with yourperformance on the Diagnostic Tests, enabling us to tailor a study plan suited to your study habits andacademic needs. PLEASE ANSWER EVERY QUESTION (UNLESS YOU ARE TOLD TO LEAVE ITBLANK), or incomplete feedback will be generated. You can input your Personal Profile answers into thelast section of the Science Diagnostic input form,(see above for the location of this form) in a sectionlabeled Personal Profile.

The MCAT Diagnostic Test (half-length) simulates the actual MCAT experience. The test will indicatehow well, at present, you can handle MCAT-style questions and passages that require critical thinking andproblem-solving. Remember, the MCAT is not just a science exam. While it requires you to have a firmknowledge of fundamental science concepts, it also tests your ability to integrate new information presentedin challenging science passages. As on the actual MCAT, there is no penalty for incorrect answers. Pleaseuse the input form labeled MCAT Diagnostic to input your responses to this test.

Remember, your feedback from today’s “work-up” is only a baseline evaluation. The Kaplan MCATProgram is designed to help you master ALL the material and skills necessary for your success on theMCAT.

Good luck!

Team MCAT

Kaplan ScienceDiagnostic Test

You have 75 minutes to complete this exam. This test is composed of 4 sections.

SubjectSection 1: BiologySection 2: General ChemistrySection 3: Organic ChemistrySection 4: Physics

You must select an answer for every question. If you are uncertain of an answer, guess! (There is nopenalty for wrong answers, just like on the actual MCAT.)

Mark your responses in the input form found by navigating to your kaptest.com student homepage andchoosing Science Diagnostic from the menu options. Use sections 1-4 for input responses from thesesections.

After completing this section please proceed to the Personal Profile.

3 6

Section 1: Biology

1 . Steroid hormones:

A . bind to receptors on the surface of target cells.B . lower the activation energy of a specific

reaction.C . bind to specific antigens during an immune

response.D . bind to receptors in the cytoplasm of target

cells.

2 . Which of the following processes utilizes ATP?

I. DiffusionII. Facilitated diffusion

III. Active transport

A . II onlyB . III onlyC . II and III onlyD . I, II and III

3 . All of the following occur in the humanrespiratory system EXCEPT:

A . ventilation is controlled by the medullaoblongata.

B . gas exchange occurs across the alveolar-capillary membrane.

C . the rate of breathing is increased bysympathetic stimulation.

D . contraction of the diaphragm contracts thethoracic cavity and permits the lungs to fill.

4 . Which of the following is derived from themesoderm?

A . EyeB . HeartC . LungsD . Liver

5 . Which of the following is a function of thehypothalamus?

A . MemoryB . AppetiteC . Coordination of movementD . Control of heartbeat

6 . Which is not a function of the liver?

A . Formation of bile saltsB . Storage of glycogenC . Storage of bile pigmentsD . Detoxification of chemicals and drugs from

bloodstream

7 . In the nephron, increasing the permeability of thecollecting duct to water has the effect of:

A . diluting the urine.B . concentrating the urine.C . increasing the rate of glomerular filtration.D . buffering urine pH.

8 . A virus has:

A . ribosomes.B . transcription enzymes.C . genetic material.D . a polysaccharide coat.

9 . Which of the following statements is NOTdescriptive of enzymes?

A . Enzymes increase the rate of a reaction byincreasing the activation energy of thatreaction.

B . Enzyme activity varies with temperature andpH.

C . A zymogen is inactive until it is cleavedunder certain physiological conditions.

D . The most scientifically accepted model forenzyme activity is the induced fit hypothesis.

1 0 . Which of the following molecules linksglycolysis to the Krebs cycle?

A . LactateB . PyruvateC . Glucose-6-phosphateD . Glucose

1 1 . Which of the following cellular substituents ismade within the nucleus?

A . RibosomeB . LysosomeC . Golgi apparatusD . Cell membrane

3 7

1 2 . During metaphase I of meiosis:

A . chromatin shortens and thickens.B . homologous pairs of chromosomes migrate to

opposite poles of the cell.C . the cell’s complement of DNA is the same as

in the non-dividing diploid cell.D . homologous chromosome pairs line up along

the equatorial plate.

1 3 . Which of the following matings of ABO bloodtypes CANNOT produce type O offspring?

A . A x OB . B x BC . AB x OD . A x B

1 4 . Bacteria have all of the following EXCEPT:

A . ribosomes.B . a cell wall.C . a nucleus.D . a flagellum.

1 5 . The epidermis can best be classified as:

A . epithelial tissue.B . connective tissue.C . nervous tissue.D . muscle tissue.

Figure 1

1 6 . Figure 1 is an O2-Hb dissociation curve for ahuman adult Hb at 38 oC and pH 7.4. An increasein blood carbon dioxide levels would cause thecurve to:

A . shift to the left.B . shift to the right.C . remain the same.D . decrease to zero.

1 7 . Which of the following is a true statementconcerning muscle?

A . Cardiac muscle combines attributes of bothsmooth and skeletal muscle.

B . Skeletal muscle lacks striations.C . Muscle tissue only carries out aerobic

respiration.D . The presence of Ca2+ will inhibit muscular

contractions.

1 8 . During an immune reaction:

A . antibodies are produced by T-lymphocytes.B . cytotoxic B-lymphocytes destroy antigens

directly.C . antigens recognize and bind to specific

antibodies and trigger the immune system toremove them.

D . helper T-lymphocytes activate other T-cellsand B-cells via lymphokine secretion.

3 8

1 9 . During which phase of the menstrual cycle isprogesterone at the highest concentration?

A . Follicular phaseB . OvulationC . Luteal phaseD . Menstruation

Figure 2

2 0 . Figure 2 is a pedigree for dentinogenesisimperfecta, a dentine formation disorder.Dentinogenesis imperfecta is transmitted as a(n):

A . autosomal recessive trait.B . autosomal dominant trait.C . sex-linked recessive trait.D . sex-linked dominant trait.

2 1 . Which of the following is in a different chemicalcategory than the others?

A . CytosineB . ThymineC . ArginineD . Uracil

2 2 . According to Darwin’s theory of natural selection:

A . organisms of the same generation can adapt toa dramatic shift in environment.

B . an organism’s genotype mutates as a responseto the environment

C . well adapted individuals survive because theyhave traits that are selected by theenvironment.

D . evolution and extinction are unrelated.

2 3 . Which of the following occurs during DNAreplication?

A . An RNA primer is necessary for synthesisinitiation.

B . The leading strand is synthesized as a series ofOkazaki fragments.

C . Synthesis proceeds in the 3’ Æ 5’ direction.D . The enzyme DNA polymerase introduces

negative supercoils into the unwinding DNA.

2 4 . You have just sequenced a fragment of DNA thatreads:

5’ ATGCCA 3’

If this strand is the template for RNA synthesis,what is the sequence of bases of the resultingRNA strand?

A . 3’ ATGCCA 5’B . 3’ TACGGT 5’C . 3’ AUGCCA 5’D . 3’ UACGGU 5’

2 5 . Which of the following hormones elevatescalcium blood concentration?

A . Parathyroid hormoneB . CalcitoninC . GlucagonD . Aldosterone

2 6 . When an action potential is generated, which ofthe following events occurs first?

A . Increased permeability to K+

B . Increased permeability to Na+

C . Increased permeability to Cl-D . Decreased permeability to Ca2+

2 7 . Which of the following cannot cross the plasmamembrane without assistance?

A . Calcium ionsB . OxygenC . WaterD . Urea

3 9

2 8 . Which of the following digests proteins?

A . MaltaseB . CholecystokininC . AmylaseD . Chymotrypsin

2 9 . All arteries transport:

A . oxygenated blood.B . blood towards the heart.C . blood away from the heart.D . interstitial fluid.

3 0 . If hemophilia is a sex-linked recessive trait, and across between a female carrier and an affected maleoccurs, then in the progeny:

A . all offspring are hemophiliacs.B . all males are hemophiliacs.C . all females are hemophiliacs .D . half the males and half the females are

hemophiliacs.

GO ON TO THE NEXT PAGE.BEGIN GRIDDING AT SECTION 2.

4 0

Section 2: General Chemistry

1 . Which of the following will affect the speed of agas particle?

I. TemperatureII. Molar mass

III. Volume

A . I onlyB . III onlyC . I and IID . I, II, and III

2 . What is the pH of a solution with a hydrogen ionconcentration of 10–6 M?

A . 4B . 6C . 7D . 8

3 . Which of the following is true of a galvanic cell?

A . Oxidation occurs at the cathode, reductionoccurs at the anode, and the reaction isnonspontaneous.

B . Oxidation occurs at the anode, reductionoccurs at the cathode, and the reaction isnonspontaneous.

C . Oxidation occurs at the cathode, reductionoccurs at the cathode, and the reaction isspontaneous.

D . Oxidation occurs at the anode, reductionoccurs at the cathode, and the reaction isspontaneous.

4 . The reaction below is an example of:

CaCl2(aq) + 2AgNO3(aq) Æ Ca(NO3)2(aq) + 2AgCl(s)

A . a neutralization reaction.B . a decomposition reaction.C . a metathesis reaction.D . a single displacement reaction.

5 . Which of the following is the correct definition ofHund’s Rule?

A . Electrons will fill orbitals so that an atom hasthe highest possible energy.

B . No two electrons can possess the same fourquantum numbers.

C . Electrons prefer to occupy degenerate orbitalsand have parallel spins.

D . The greater the principal quantum number, thegreater the energy of the electron shell.

6 . What is the standard enthalpy change, DH°, of thereaction below?

2CO(g) + O2(g) Æ 2CO2(g)

A . DHf(CO2) – [DHf(CO) + DHf(O2)]B . 2DHf(CO2) – 2DHf(CO)C . DHf(CO) – DHf(CO2)D . 2DHf(CO2) + 2DHf(CO)

7 . What is the molecular geometry of borontrifluoride (BF3)?

A . BentB . Trigonal planarC . Trigonal pyramidalD . Tetrahedral

8 . Which of the processes below is accompanied bythe greatest increase in entropy?

A . FreezingB . CondensationC . EvaporationD . Sublimation

9 . Which of the following elements is the mostelectronegative?

A . BrB . AsC . NaD . Cr

4 1

1 0 . 100 mL of an ideal gas is placed in a sealedcontainer at a pressure of 300 mmHg. If thepressure is increased to 450 mmHg, what is thefinal volume of the gas?

A . 67 mLB . 75 mLC . 100 mLD . 134 mL

1 1 . Which of the following electrochemical conditionswill result in the greatest amount of copper platedfrom a copper (II) sulfate solution?

A . A current of 10 amperes in 5 minutesB . A current of 10 amperes in 15 minutesC . A current of 5 amperes in 10 minutesD . A current of 5 amperes in 15 minutes

1 2 . Which of the following acids is the strongest?

Acid pKaA 1.7B 2.1C 5.0D 7.0

A . AB . BC . CD . D

1 3 . What is the concentration of Ag+ in a saturatedsolution of AgCl at 25°C? (Ksp of AgCl = 1.8¥ 10–10)

A . 1.34 ¥ 10–5 MB . 1.8 ¥ 10–10 MC . 3.2 ¥ 10–10 MD . 3.2 ¥ 10–20 M

1 4 . Which of the following decreases from left to rightacross a period?

A . ElectronegativityB . Atomic radiusC . Electron affinityD . Ionization energy

1 5 . What is the order of increasing intermolecularbond strength?

A . Hydrogen bonding < Dipole-dipole interaction< Dispersion forces

B . Dispersion forces < Dipole-dipole interaction< Hydrogen bonding

C . Dipole-dipole interaction < Dispersion forces< Hydrogen bonding

D . Dipole-dipole interaction < Hydrogen bonding< Dispersion forces

1 6 . The boiling-point elevation constant for water isapproximately 0.5°C/m. What is the boiling pointof a solution containing 0.5 moles of glucosedissolved in 500 g of water?

A . 99.5°CB . 100°CC . 100.5°CD . 101°C

1 7 . Which of the following is a Lewis acid?

A . OH–

B . PH3C . BF3D . Cl–

1 8 . How much 1 M NaOH is needed to neutralize 75mL of 2 M H2SO4?

A . 75 mLB . 100 mLC . 150 mLD . 300 mL

4 2

Questions 19 and 20 refer to the table below:

Trial [X] (mol/L) [Y] (mol/L) Initial rate offormation of Z(mol/L•sec)

1 0.05 0.02 0.062 0.05 0.04 0.243 0.1 0.02 0.12

[Note: This data was obtained at a temperature of 298 K.]

1 9 . What is the correct rate law for this reaction?

A . Rate of reaction = k[X]B . Rate of reaction = k[X][Y]C . Rate of reaction = k[X][Y]2

D . Rate of reaction = k

2 0 . If the same experiment were carried out at 300 K,what would happen to the initial rate of formationof Z?

A . It would increaseB . It would decreaseC . It would remain the sameD . Cannot be determined

2 1 . For the reaction below, DH°298 K = –114 kJ/moland DS°2 9 8 K = –0.15 kJ/mol•K. At 298 K,would this reaction be spontaneous?

2NO(g) + O2(g) Æ 2NO2(g)

A . Yes, because DG° is positiveB . Yes, because DG° is negativeC . No, because DG° is positiveD . No, because DG° is negative

2 2 . Electron affinity is defined as:

A . the amount of energy released when a gaseousatom or ion gains an electron.

B . the amount of energy required to remove anelectron from a gaseous atom or ion.

C . the energy required to convert a compoundinto its gaseous ions.

D . the energy change when a compound isformed from its elements in their standardstates.

2 3 . Which of the following is NOT a colligativeproperty?

A . Freezing-point depressionB . Osmotic pressureC . Electrical conductivityD . Vapor-pressure lowering

2 4 . Which of the following factors can change thenumerical value of an equilibrium constant Keq?

A . VolumeB . ConcentrationC . TemperatureD . Pressure

2 5 . Boyle’s Law states that:

A . at constant pressure, the volume of a gas isdirectly proportional to temperature.

B . at constant temperature, the volume of a gasis inversely proportional to pressure.

C . at constant temperature and pressure, thevolume of a gas is directly proportional thenumber of moles of gas.

D . the total pressure exerted by a gaseousmixture is equal to the sum of the partialpressures exerted by each individual gas.

2 6 . The mass number of a neutral element correspondsto the number of:

A . protons.B . protons and electrons.C . neutrons.D . protons and neutrons.

4 3

2 7 . According to the following standard reductionpotentials:

Zn2+(aq) + 2e– Æ Zn(s) E° = –0.76 VAg+(aq) + e– Æ Ag(s) E° = +0.8 V

What is the cell potential of the reaction below?

Zn(s) + 2Ag+(aq) Æ Zn2+(aq) + 2Ag(s)

A . –1.56 VB . –0.04 VC . +0.04 VD . +1.56 V

2 8 . What is the oxidation state of manganese inKMnO4?

A . –2B . +1C . +4D . +7

2 9 . Transition metal complexes are usually coloredbecause:

A . electrons escape from the valence shell of themetal.

B . d electrons relax from a higher energy orbitalto a lower energy orbital.

C . the ionic radii of the transition metals issmall.

D . d electrons jump from a lower energy orbitalto a higher energy orbital.

3 0 . What is the ground-state electron configuration ofFe (atomic number 26)?

A . 1s22s22p63s23p64s23d6

B . 1s22s22p63s23p64s13d7

C . 1s22s22p63s23p63d8

D . 1s22s22p63s23p64s33d5 GO ON TO THE NEXT PAGE.BEGIN GRIDDING AT SECTION 3.

4 4

Section 3: Organic Chemistry

1 . Which of the following carboxylic acid derivativesare most reactive towards nucleophilic acylsubstitution?

A . EstersB . Acid anhydridesC . Acyl halidesD . Amides

2 . The compound below is classed as a(n):

H2N CH2 C

O

NH CH2COOH

A . amino acid.B . dipeptide.C . monoglyceride.D . carbohydrate.

3 . Which compound(s) below is/are optically active?

CH3

CH3

I

C

C Cl

Cl

H

H

H3C

H3C

II

C

CH3

OHH

C HH

C HH

HIII

A . II onlyB . III onlyC . I and III onlyD . I, II, and III

4 . What would happen if valine (pI = 6.0) and lysine(pI = 9.8) were subjected to electrophoresis atpH 6?

A . Valine would migrate to the anode and lysinewould migrate to the cathode.

B . Valine would not move and lysine wouldmigrate to the anode.

C . Valine would not move and lysine wouldmigrate to the cathode.

D . Lysine would not move and valine wouldmigrate to the cathode.

5 . Which of the compounds below cannot be oxidizedto a carboxylic acid?

A . An aldehydeB . A tertiary alcoholC . A primary alcoholD . A terminal alkene

6 . What is the order of increasing boiling points inthe following compounds?

I II III

CH3CH2COOH CH3CH2CO

HCH3CH2CHOH

A . I < III < IIB . II < III < IC . III < II < ID . I < II < III

7 . An IR peak in the region 1680–1750 cm– 1 ischaracteristic of what type of bond stretch?

A . O–HB . C=OC . C–CD . C–H

8 . What is the order of stability in the free radicalsshown below?

I II III

CCH3CH3

CHCH2CH3

CHCHCH3CH3

A . III > I > IIB . II > III > IC . I > II > IIID . I > III > II

4 5

9 . Which of the structures below accuratelyrepresents a zwitterion? A.

B.

C.

D.

C

H

R

COO–H3N+

C

H

R

COO–H2N

C

H

R

COOHH3N+

C

H

R

COOHH2N

1 0 . Which of the following is a false statement aboutthe reaction below?

CH3CH2CH2Cl

NaOH

DMSOCH3CH2CH2OH

A . The reaction proceeds via the formation of acarbocation.

B . The rate of reaction is dependent upon theconcentration of both substrate andnucleophile.

C . The reaction proceeds via a concertedmechanism.

D . The reaction intermediate is neutral.

1 1 . Which of the structures below is NOT aromatic? A.

B.

C.

D.

NH H

N

H

N

+

1 2 . Why is the reaction below an inefficient method tosynthesize primary amines?

NH3 + CH3ClOH–

CH3NH2 + HCl

A . Hydroxide ions will hydrolyze the primaryamine.

B . Excess alkyl halide will react to form sideproducts.

C . Hydrochloric acid will hydrolyze the primaryamine.

D . Ammonia is a poor nucleophile and will notreact with chloromethane.

1 3 . The reaction below results in the formation of:

MgBr + O

H

H3O+

A . a secondary alcohol.B . a tertiary alcohol.C . an aldehyde.D . a carboxylic acid.

4 6

1 4 . The bond angle most associated with sp3

hybridized atoms is:

A . 104.5°.B . 120°.C . 109.5°.D . 180°.

1 5 . Which of following is an example of a chain-propagation step?

A . CH3CH2CH2• +CH3CH2CH2• Æ CH3(CH2)4CH3

B . CH3CH2CH3 + Cl• Æ CH3CH2CH2• + HClC . Cl2

huæ Æ æ 2Cl•

D . 2Cl• Æ Cl2

1 6 . Which of the following cannot be oxidized to forma carboxylic acid?

A . a primary alcoholB . an alkylbenzeneC . a ketoneD . an aldehyde

1 7 . Epimers are specific types of carbohydrates thatdiffer in the orientation of substituents aboutcarbon 2. Therefore, epimers are specific types of:

A . conformational isomer.B . structural isomer.C . enantiomer.D . diastereomer.

1 8 . Which of the following carboxylic acids will bethe most acidic?

A . CCl3CH2COOHB . CHF2CH2COOHC . CH3CFClCOOHD . CH3CF2COOH

1 9 . What is the IUPAC name of the compoundbelow?

O

OH

OH

A . b-Hydroxyhexanoic acidB . 5-hydroxyhexanoic acidC . 6-carboxy-2-hexanolD . 1-carboxy-5-hexanol

2 0 . A compound with the general formulaRCOOCOR (where R = –H or any alkyl group) isclassed as a(n):

A . ether.B . ester.C . acid anhydride.D . epoxide.

2 1 . In the reaction below, what is the function ofAlCl3?

Cl2AlCl3

Cl

A . It acts as a Lewis acid catalyst.B . It depolarizes the chlorine molecule.C . It withdraws electrons from the aromatic ring.D . It attacks and adds to the aromatic ring.

2 2 . Which of the following is a quaternary ammoniumsalt?

A . (CH3)4N+Cl–B . (CH3)3NH+Cl–C . (CH3)2NH2

+Cl–D . NH4

+Cl–

2 3 . Which reagent would be most suitable in theextraction of phenol from CCl4?

A . Sodium bicarbonateB . Hydrochloric acidC . Sodium hydroxideD . Sodium chloride

4 7

2 4 . Which of the following represents the most stableform of cyclohexane? A.

B.

C.

D.

2 5 . Which of the compounds below will NOT producean IR spectrum?

A . COB . Cl2C . HClD . CO2

2 6 . The reaction below is an example of:

OH

O+

O

OOH

+ H2O

H+

A . saponification.B . nucleophilic substitution.C . esterification.D . acid-catalyzed hydrolysis.

2 7 . Which of the following is the correct structure ofb-glucose? A.

B.

C.

D.

OCH2OH

HOHO

OHOH

OCH2OH

HOHO OH

OH

OCH2OH

HOHO

OH

OCH3

OCH2OH

HH

OH

OH

2 8 . Which of the following does NOT directlycontribute to the tertiary structure of a protein?

A . Disulfide bondsB . Electrostatic interactionsC . Hydrogen bondingD . Peptide bonds

2 9 . The reaction below is an example of: CH3CH CH2 + HBr CH3CHBrCH3

A . Markovnikov addition.B . anti-Markovnikov addition.C . electrophilic substitution.D . free-radical addition.

4 8

3 0 . What is/are the product(s) of the reaction below? CH3 CH

CH3

O–Na+ + CH3CH2Cl

A.

B.

C.

D.

CH3 CH

CH3

OCH2CH3 + NaCl

CH3 CH

CH3

O–Na+ + CH2CH2 + HCl

CH3 CH

CH3

CH2CH3 + NaOCl

CH3 CH CH2 + CH3CH2O–Na+ + Cl–

GO ON TO THE NEXT PAGE.BEGIN GRIDDING AT SECTION 4.

4 9

Section 4: Physics

1 . A person drives, starting from rest, from theBoston area to the New York area where theyagain come to rest. The total distance traveled is260 miles and the trip takes 4 hours to complete.Which of the following statements is necessarilytrue?

A . The person’s instantaneous velocity is always65 miles per hour.

B . The person’s instantaneous velocity is alwaysless than 65 miles per hour.

C . The person’s instantaneous velocity issometimes less than 65 miles per hour.

D . The person’s average velocity is always lessthan the instantaneous velocity.

2 . A projectile is launched with an initial angle of30° with respect to the horizontal and an initialspeed of 100 m/s. The velocity of the projectile atits highest point is:

A . 100 m/sB . 100 cos30° m/sC . 100 sin30° m/sD . 0 m/s

3 . An external force of 50 N is acting horizontally onan object that is on a horizontal surface. The forceof friction on the object is 50 N. The object is:

A . accelerating.B . decelerating.C . motionless.D . Not enough information to determine the state

of motion.

4 . An object is sliding down a frictionless inclinewhose angle of inclination is 20°. The normalforce on the object is:

A . equal to the object’s weight.B . equal to the component of the object’s weight

along the direction of the incline.C . less than the component of the object’s

weight along the direction of the incline.D . greater than the component of the object’s

weight along the direction of the incline.

5 . A spaceship is towing a satellite and exerts a forceof 5000 N on the cable that joins the two. Thereaction force of the satellite has a magnitude of5000 N and is directed opposite to the force on thesatellite. The magnitude of the net force on thesatellite is:

A . 5000 NB . 0 NC . –5000 ND . Cannot be determined from the information

given.

6 . A 10 kg object slides down an incline whosecoefficient of friction is 0.3. As the angle of theincline increases, the frictional force:

A . stays the sameB . increasesC . decreasesD . increases for inclinations below 45° and then

decreases for inclinations above 45°

7 . A horizontal steel bar of uniform mass density andmass 5 kg is supported by two vertical steel cablesattached to the ends of the bar. When a 75 kg masshangs from the center of the bar, the tension ineach cable is:

A . 75 NB . 375 NC . 400 ND . 800 N

8 . A satellite of mass m orbits the Earth in a circularorbit which is at distance of r from the center ofthe Earth. The speed of the satellite is constant andequal to v. Determine the amount of work done bygravity during one complete orbit of the satellite.

A . 0B . 2prm gC . 2pr GmMearth/r2

D . 2prmv2/r

5 0

9 . A projectile of mass 20 kg is shot at an angle of60° to the horizontal at a speed of 100 m/s. Whatis the energy of the projectile at its highest point?

A . 0 JoulesB . 2.5 ¥ 104 Joules.C . 7.5 ¥ 104 Joules.D . 1 ¥ 105 Joules.

1 0 . A lamp with a 100-Watt light bulb is turned on.How long does it take for the lamp to consume3.6 ¥ 105 Joules?

A . 3.6 ¥ 103 sB . 3.6 ¥ 107 sC . (1/3.6) ¥ 10– 3 sD . (1/3.6) ¥ 10–7 s

1 1 . An 80 kg ice skater, standing on an essentiallyfrictionless frozen pond, propels himself forwardby throwing a 5 kg mass in the opposite directionwith a speed of 1 m/s. The skater is then propelledforward at a speed of 1/16 m/s. The totalmomentum of the skater and mass when both aremoving is:

A . 10 kg m /sB . –10 kg m/sC . 0 kg m/sD . 5 kg m/s

1 2 . Suppose that the liquid used in a thermometer hasa thermal expansion coefficient which is less thanthat of the thermometer tube itself. Which of thefollowing best describes what happens with achange in temperature?

A . The liquid level rises when the temperaturerises.

B . The liquid level falls when the temperaturerises.

C . The liquid level remains the same when thetemperature rises.

D . The liquid level falls when the temperaturefalls.

1 3 . A large aluminum stock pot is filled with 2 quartsof tap water at an initial temperature of 20°C. Thewater is then brought to a boil in a time of 5minutes. An identical pot is filled with 3 quarts oftap water at an initial temperature of 20°C andplaced over an identical heat source. Determine theamount of time required to bring the 3 quarts ofwater to a boil.

A . 3.33 minutesB . 5 minutesC . 7.5 minutesD . Not enough information to determine the

required time.

1 4 . 500 calories of heat are applied to a 10 g cube ofice which is at an initial temperature of 0˚C. Whatis the change in temperature of the ice due to thisamount of heat? Note: the heat of fusion of wateris 80 cal/g and the specific heat of water is 1cal/gm°C.

A . 0°CB . 5/8°CC . 42°CD . 50°C

1 5 . An ideal gas undergoes a process in which it does20 Joules of work on a piston and ends up in afinal state with an increase in internal energy of 10Joules. The amount of heat gained or lost by thegas is:

A . 10 Joules lostB . 30 Joules gainedC . 10 Joules gainedD . 30 Joules lost

1 6 . A copper ball of density 8.9 ¥ 103 kg/m3 isdropped, first into a container filled with water,and then a container filled with oil. The density ofthe water is 1 ¥ 103 kg/m3 and the density of theoil is 700 kg/m3. Ignoring frictional effects,which of the following best describes the resultsof this experiment?

A . In each liquid, the ball falls with anacceleration equal to g.

B . The acceleration of the ball is less than g inboth liquids and the greatest in water.

C . The acceleration of the ball is less than g inboth liquids and the greatest in oil.

D . The acceleration of the ball in both liquids iszero, i.e., the ball falls with a constant speed.

5 1

1 7 . A long piece of pipe of varying cross section isfilled with a fluid of density 1.02 g/cm3 and fittedwith movable pistons on each end. The piston onthe left end has a cross sectional area of A1 and thepiston on the right end has a cross sectional areaof A2. If a pressure of po is applied to the pistonon the left end then the pressure experienced by thepiston at the right end is:

A . poA2B . (A2/A1)poC . (A1/A2)poD . po

1 8 . An airplane wing is constructed so as to minimizeturbulent flow over the wing and also ensure thatthe air flowing over the top surface of the wingtravels a greater distance in a given amount oftime than the air flowing over the bottom wingsurface. Such a design will generate a lift forcewhen air flows over the top and bottom wingsurfaces because:

A . The velocity of the air on the top surface isgreater than the velocity of the air onthebottom surface.

B . The velocity of the air on the top surface isless than the velocity of the air on the bottomsurface.

C . The density of the air on the top surface isless than the density of the air on the bottomsurface.

D . The density of the air on the top surface isgreater than the density of the air on thebottom surface.

1 9 . An electron with a speed of 3 ¥ 105 cm/s movesin a northerly direction through a region of spacecontaining a uniform electric field of strength 100V/m which is directed toward the east. Which ofthe following best describes the result of the fieldon the motion of the electron?

A . The electron is deflected to the east with nochange in velocity.

B . The electron is deflected to the west andexperiences an increase in velocity.

C . The electron is deflected to the east andexperiences an increase in velocity.

D . The electron is deflected to the west with nochange in velocity.

2 0 . A long straight wire carries a current directedtowards the top of the page. A proton moves withvelocity 2 ¥ 104 cm/s towards the bottom of thepage and to the left of the wire. The magneticforce on the proton is:

A . towards the top of the pageB . towards the leftC . towards the rightD . towards the bottom of the page

2 1 . A circuit consists of a 12 V battery and tworesistors of resistance 3 W and 4 W in parallelwith the battery. The ratio of the current in the 3W resistor to that in the 4 W resistor is:

A . 1:1B . 3:4C . 4:3D . 12:7

2 2 . A circuit consists of a 6 V battery attached to a 12mF parallel plate capacitor. While the capacitor ischarging, the voltage across the capacitor is:

A . increasing and less than 6 VB . decreasing and less than 6 VC . decreasing and greater than 6 VD . equal to 6 V

2 3 . The speed of sound in air is proportional to thesquare root of the absolute temperature of the air.An organ pipe of fixed length produces a tone offrequency 343 Hz and wavelength 1 meter at an airtemperature of 20°C. At a temperature of 25°C,the same pipe produces a tone with:

A . an increased frequency and a decreasedwavelength

B . an increased frequency and the samewavelength

C . an increased wavelength and the samefrequency

D . the same frequency and the same wavelength

5 2

2 4 . A mass attached to a horizontal spring rests on africtionless horizontal surface, and will undergosimple harmonic motion with period 2 s whendisplaced from equilibrium and released. If themass is released at t = 0, then determine the timeor times at which the spring has its minimumpotential energy.

A . 0.5 s onlyB . 1 s onlyC . 0.5 s and 1.5 s only.D . 1 s and 2 s only.

2 5 . A state trooper uses Doppler radar to track thespeed of traffic that moves away from him. If thefrequency of the outgoing radar, as measured bythe trooper, is 101 0 Hz, then the frequency of theradar that bounces off the car and returns to thetrooper is:

A . also equal to 101 0 HzB . sometimes greater than 101 0 Hz depending on

the way in which it reflects off of eachparticular car

C . always greater than 101 0 HzD . always less than 101 0 Hz

2 6 . A light ray of wavelength 600 nm enters a pieceof glass with index of refraction 1.5. Which of thefollowing best describes the path of the emergingray?

A.airglass

C.airglass

B.airglass

D.airglass

A . AB . BC . CD . D

2 7 . An object is placed in between the focal point andthe surface of a thin converging lens. The imageproduced is:

A . real and upright.B . real and inverted.C . virtual and upright.D . virtual and inverted.

2 8 . A plane mirror of height 1 m has the property thatit reflects light rays that are perpendicular to itssurface back in the same direction they came. Thefocal length of such a mirror is:

A . 0 m.B . 0.5 m.C . 1 m.D . infinity.

2 9 . The first four energy levels of a hypothetical atomare listed below. What is the frequency of lightemitted when the atom makes a transition fromthe n=4 to the n=2 level of this atom? (h = 4.1 ¥10–15 eV s)

n = 1

n = 2

n = 3

n = 4

–6.4 eV

–4.2 eV

–3.1 eV

–2.6 eV

A . 3.9 ¥ 101 4 HzB . 6.3 ¥ 101 4 HzC . 1.0 ¥ 1015 HzD . 1.7 ¥ 101 5 Hz

3 0 . The radioactive isotope of lead, Pb, decays to theradioactive isotope of bismuth, Bi. The decayprocess responsible for this decay is:

A . alpha decay.B . beta-minus decay.C . beta-plus decay.D . gamma decay.

Personal Profile

iii

Personal Profile Questions

Directions: Please answer these questions on the Science Diagnostic Input Form in the Personal Profile section.

ITEM 1No Input

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ITEM 7On which test date do you plan to take the MCAT? (Youmust put a valid date here.)

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ITEM 9Please fill in your approximate undergraduate GPA on a 4.0scale. If you have taken graduate or post-baccalaureatecourses, you may include them in your GPA estimate.

ITEM 101. Please indicate your undergraduate major(s). You

may check more than one, if necessary.(A) Biology(B) Chemistry(C) Physics(D) Mathematics / Computer Science(E) Psychology(F) History / Sociology / Social Science(G) English / Liberal Arts(H) Other

2. When you were in school, what was the mosteffective way for you to study for exams? (You maycheck more than one.)(A) Listening to a lecture by a good teacher(B) Working in a small study group(C) Studying heavily from books(D) Studying heavily from lecture notes(E) Working with computer programs(F) No preference

3. Which of the following concerns you about theMCAT? (You may check more than one.)(A) Weakness in basic science knowledge(B) Trouble understanding MCAT passages(C) Trouble with reading and Verbal Reasoning(D) Trouble with essay writing(E) Test anxiety(F) Test stamina(G) I'm just not good at standardized tests(H) I’m not concerned

4. Which of the following online services do you useregularly (once a week or more)? (You may checkmore than one.)(A) I don't use an online service(B) America Online(C) Compuserve(D) Prodigy(E) Internet (newsgroups, e-mail, etc.)(F) World Wide Web(G) Other

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5. In school, how did you prefer to study? Check allthat apply.(A) Alone in dorm room(B) Alone in Library Reading Room (large table)(C) Alone in Library book stacks (private desk)(D) Small group (4 or less people)(E) Large group (5 or more people)(F) Other

6. What are your perceived MCAT strengths? Checkall that apply.(A) Solid biology knowledge(B) Solid organic chemistry knowledge(C) Solid general chemistry knowledge(D) Solid physics knowledge(E) Strong analytical skills(F) Strong reading comprehension skills(G) Strong standardized testing skills(H) Familiarity with MCAT question style

7. What are your perceived MCAT weaknesses? Checkall that apply.(A) Weak biology knowledge(B) Weak organic chemistry knowledge(C) Weak general chemistry knowledge(D) Weak physics knowledge(E) Weak analytical skills(F) Weak reading comprehension skills(G) Weak standardized testing skills(H) Little familiarity with MCAT question style

8. Leave Blank9. Leave Blank

ITEM 11If you have taken the MCAT before, please indicate yourbest total score (3-45). Please mark your score in the lasttwo slots (e.g.: __24). If you have never taken the MCATpreviously, leave this item blank.

ITEM 12As realistically as you can, please tell us your total targetMCAT score (e.g., 30 (10s in each numerical section)).You must indicate a target score here.

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ITEM 181. In light of the fact that Kaplan MCAT preparation is

a serious commitment, what is your most realisticestimate of how many hours per week you plan tospend on MCAT practice? (including homeworkassignments)(A) Fewer than 2 hours(B) 2-5 hours(C) 5-10 hours(D) 10-15 hours(E) more than 15 hours

2. When was the last time you studied any form ofbiology (basic or advanced)?(A) more than 3 years ago(B) 3 years ago(C) 2 years ago(D) 1 year ago(E) less than 1 year ago(F) currently studying it(G) will study it in the near future (e.g., next

semester)

3. When was the last time you studied any form ofinorganic chemistry (basic or advanced)?(A) more than 3 years ago(B) 3 years ago(C) 2 years ago(D) 1 year ago(E) less than 1 year ago(F) currently studying it(G) will study it in the near future (e.g., next

semester)

4. When was the last time you studied any form oforganic chemistry (basic or advanced)?(A) more than 3 years ago(B) 3 years ago(C) 2 years ago(D) 1 year ago(E) less than 1 year ago(F) currently studying it(G) will study it in the near future (e.g., next

semester)

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5. When was the last time you studied any form ofphysics (basic or advanced)?(A) more than 3 years ago(B) 3 years ago(C) 2 years ago(D) 1 year ago(E) less than 1 year ago(F) currently studying it(G) will study it in the near future (e.g., next

semester)

6. Is English your native language?(A) Yes(B) No

7. How would you rate your proficiency in Englishwriting ?

(A) poor(B) fair(C) good(D) excellent

8. How would you rate your proficiency in Englishreading ?

(A) poor(B) fair(C) good(D) excellent

9. How long has it been since you last wrote brief,organized essays on a regular basis, whether inschool or in another context?(A) I currently do so on a regular basis(B) It's been less than one year(C) It's been one to two years(D) It's been two to three years(E) It's been more than three years

10. How close do you live to your nearest KaplanCenter?(A) Fewer than 5 miles(B) 5-10 miles(C) 10-15 miles(D) 15-25 miles(E) more than 25 miles

11–96. Leave these questions blank.

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