lake manitou 2018 report attachments 1-4...lake manitou 2018 monitoring qa/qc lake manitou 2018...

Attachment 1

Lake Manitou 2018 Monitoring QA/QC

Lake Manitou 2018 Monitoring Report Attachment 1

Quality-Assurance/Quality-Control (QA/QC) Sampling equipment was adequately cleaned prior to use during each sampling event. New,

clean collection bottles were provided by the analytical laboratory for all water quality chemistry

parameters. For both in-lake and drain sampling efforts, K&A field staff used clean, adequately

calibrated meters for measuring profiles and field parameters. Dissolved oxygen and temperature

were measured using a YSI ProODO Meter, specific conductivity was measured using a YSI

Pro30 Meter, and pH was measured using an Oakton pH450 Meter.

At each in-lake station, K&A field staff collected water samples using a WildCo Van Dorn

Sampler. Each depth-integrated composite chlorophyll a sample was collected in a clean opaque

plastic bottle and transferred to clean opaque bottles to prevent light exposure. Sediment samples

were collected using a Petite Ponar Dredge and composited in a clean stainless-steel bowl before

being transferred into sample jars and transported to the analytical laboratory.

At each drain monitoring station, K&A field staff collected samples by wading or reaching into

the center of the stream, upstream of any sediment stirred up during the collection process. Depth

of water was then recorded at the in-stream point where flow would be measured. Where

applicable, a staff gauge reading, width of flowing water, and/or depth of water overtopping the

flow control structure (weir), were also recorded. Where no flow control structure exists, average

velocities were measured using a Marsh McBirney Flo-Mate 2000 Flow Meter at the point of

fixed geometry (culvert) within the drain. Field parameters were measured in a clean, open faced

collection vessel containing water captured from the stream.

The following Table A1-1 outlines water chemistry parameters collected at each sampling

station, including in-lake and drain stations, during each sampling event.

Table A1-1. Lake/Water Chemistry Parameters Collected at All Sampling Stations

Parameter Collection

Station(s)

Collection

Method

Preservative or

Filtration Method

Volume

Collected (mL)

Temperature All YSI ProODO N/A N/A

Dissolved Oxygen All YSI ProODO N/A N/A

pH All Oakton pH450 N/A N/A

Specific

Conductance All YSI Pro30 N/A N/A

Total Phosphorus All Van Dorn,

In-stream Grab

H2SO4

(10 drops/500 mL) 250

Nitrate-N (NO3) Drain Stations Van Dorn,

In-stream Grab None 500

Total Suspended

Solids Drain Stations

Van Dorn,

In-stream Grab None 500

Alkalinity In-Lake Stations Van Dorn None 500

Chloride In-Lake Stations Van Dorn None 500

Total Nitrogen In-Lake Stations Van Dorn None 500


Chlorophyll a In-Lake Stations

Depth-integrated

Composite

Sampler

Filtered using

0.45 µm filters,

preserved with 1

drop of magnesium

carbonate

150

(filtered volume)

Total Iron In-Lake Sediment Ponar Dredge None 250

Percent Solids In-Lake Sediment Ponar Dredge None 250

Merit Laboratories was used for analysis of water quality and sediment chemistry parameters for

all sample events with the exception of the 10 May event, which was analyzed by Pace

Analytical Laboratories. Upstate Freshwater Institute (UFI) was used for analysis of all

chlorophyll a for all in-lake samples.

Table A1-2 below summarizes the standard methods used for processing and analyzing

analytical parameters in water samples collected during the 2018 monitoring.

Table A1-2. Summary of Standard Methods for Processing and Analyzing Samples.

Parameter Units Analytical

Laboratory

Analytical

Method

Analytical

Method

Technique

Method

Detection

Level

Sample

Holding Time

Temperature °C N/A Data sonde Measured with

Field Instrument 0.012 N/A

Dissolved

Oxygen mg/l N/A Data sonde

Measured with


pH pH units N/A Data sonde Measured with


Specific

Conductance

mS/cm

at 25°C N/A Data sonde

Measured with


Total

Phosphorus mg/l Pace1, Merit

SM2540D,

SM4500-PE

SM 2540 D

2011, SM 4500

P E 2011

0.004 mg/l 28 days, cool to

<4°C, pH <23

Nitrate-N mg/l Pace1, Merit E300.0

EPA Method

300.0 Revision

2.1

0.04 mg/l 48hrs, cool to

<6°C

Total

Suspended

Solids

mg/l Pace1, Merit SM2540D SM 2540 D

2011 3 mg/l

7 days, cool to

<6°C

Alkalinity mg/l Pace1, Merit SM2320B SM 2320 B

2011 2 mg/l

14 days, cool to

<6°C

Chloride mg/l Pace1, Merit E300.0

EPA Method

300.0 Revision

2.1

0.26 mg/l 28 days, cool to

<6°C


Total

Nitrogen mg/l Pace1, Merit

Calculation,

E300.0 and

SM4500-

N(org)/NH

Calculation,

EPA Method

300.0 Revision

2.1, SM 4500

N(org)B /

NH3D 2011

0.5 mg/l 48hrs, cool to

<6°C

Chlorophyll a µg/l UFI

USEPA

445.0 Rev.

1.2

USEPA 445.0

Rev. 1.2 0.1 μgChl/L

21 days, filtered

and frozen

Total

Phosphorus

(sediments)

mg/kg Pace1, Merit SM4500-PE

Standard

Method 4500 P

E 2011

1 mg/kg 6 months, cool

to <6°C

Total Iron

(sediments) mg/kg Pace1, Merit SW6020A

SW 846 Method

6020A Revision

1 February 2007

1 mg/kg 6 months, cool

to <6°C

Percent Solids

(sediments) % Pace1, Merit SM2540B

SW 846 Method

3050B Revision

2 December

1996

1% 28 days, cool to

<6°C

1 Pace Analytical was used for the 10-May-18 sampling event only. Merit Laboratories were used for water

chemistry analyses on all other sampling event dates. 2 Performance resolution. 3 Samples preserved to pH <2 using sulfuric acid (10 drops/500mL).

Attachment 2

Lake Manitou 2018 Flow and Pollutant Load Calculations

Lake Manitou 2018 Monitoring Report

Attachment 2

Hardy-Jennings Drain-In: 2018 Flows and Pollutant Loads

TP TSS NO3 TP TSS NO3

ft mg/L mg/L mg/L cfs mg/s mg/s mg/s

05/10/18 8:40 DRY 0.088 9.2 0.39 1.357 3.382 353.546 14.987

05/17/18 11:23 DRY 1.51 0.38 5 1.4 1.287 13.846 182.187 51.012

05/21/18 15:20 DRY 1.43 1.182

05/26/18 9:40 DRY 1.5 1.276

05/29/18 8:00 DRY 1.56 1.330

05/31/18 7:00 WET 1.4 0.1 1.132 3.205

05/31/18 7:18 WET 1.63 0.22 6 0.7 1.363 8.492 231.592 27.019

06/06/18 10:00 DRY 1.52 0.04 1.297 1.469

06/08/18 6:35 DRY 1.54 0.07 1.315 2.606

06/09/18 7:10 WET 1.54 0.07 1.315 2.606

06/09/18 9:35 WET 1.60 0.08 1.353 3.065

06/09/18 12:40 WET 1.62 1.360

06/09/18 16:25 WET 1.63 0.09 1.363 3.474

06/12/18 6:30 DRY 1.72 0.07 1.357 2.689

06/20/18 14:40 DRY 1.50 1.276

06/24/18 11:15 DRY 1.48 1.252

06/28/18 9:05 WET 1.56 1.330

07/02/18 14:00 DRY 1.58 1.343

07/07/18 15:40 DRY 1.50 1.276

07/14/18 10:40 DRY 1.36 1.055

07/20/18 6:45 DRY 1.26 0.817

07/20/18 22:50 DRY 1.26 0.817

07/21/18 15:20 DRY 1.24 0.761

07/22/18 9:45 WET 1.24 0.761

07/23/18 15:40 WET 1.24 0.761

07/27/18 17:10 DRY 1.19 0.610

08/01/18 17:20 DRY 1.12 0.370

08/06/18 9:30 WET 1.00 0.04 1.5 -0.118 0.000 0.000 0.000

08/06/18 11:30 WET 1.00 -0.118

08/06/18 16:52 WET 1.11 0.3 5 1.2 0.333 2.828 47.138 11.313

08/06/18 21:30 WET 1.13 0.406

08/07/18 11:00 DRY 1.13 0.406

08/08/18 10:15 Wet 1.18 0.07 0.577 1.145

08/10/18 12:00 DRY 1.20 0.641

08/19/18 11:40 DRY 1.08 0.218

08/21/18 19:30 DRY 1.1 0.295

08/25/18 13:40 DRY 1.03 0.013

08/27/18 15:00 DRY 1.1 0.295

08/28/18 11:30 DRY 1.6 1.353

08/29/18 8:15 WET 1.19 0.610

08/29/18 9:35 WET 1.21 0.13 9 1 0.672 2.475 171.329 19.037

09/01/18 20:00 WET 1.22 0.02 1.5 0.702 0.398 29.839

09/02/18 5:30 WET 1.22 0.02 4 0.702 0.398 79.571

Instantaneous Pollutant Load

Date TimeEvent

Type

Staff

Gauge

Pollutant Concentration Instantaneous

Flow


Attachment 2

09/02/18 7:30 WET 1.24 0.05 3 0.761 1.077 64.644

09/02/18 9:45 WET 1.25 0.05 3 0.789 1.117 67.041

09/04/18 8:00 DRY 1.27 0.04 5 0.843 0.956 119.439

09/07/18 12:30 DRY 1.25 0.789

09/09/18 22:30 WET 1.22 0.702

09/11/18 14:30 DRY 1.2 0.641

09/16/18 12:30 DRY 1.18 0.577

09/18/18 13:30 DRY 1.16 0.511

09/25/18 17:15 DRY 1.22 0.702

09/30/18 21:30 WET 1.26 0.05 1.5 1.1 0.817 1.156 34.690

10/01/18 7:15 WET 1.30 0.09 5 1.1 0.920 2.345 130.282 28.662

10/01/18 9:45 WET 1.35 0.1 6 1.2 1.034 2.929 175.739 35.148

10/03/18 14:45 DRY 1.52 1.297

10/06/18 9:00 WET 1.56 1.330

10/08/18 15:15 DRY 1.39 1.113

10/21/18 16:40 DRY 1.26 0.817

10/30/18 12:40 DRY 1.1 0.295

10/30/18 20:00 DRY 0.92 -0.497

10/31/18 5:30 WET 1.11 0.333

10/31/18 6:15 WET 1.12 0.05 13 1 0.370 0.524 136.165 10.474

10/31/18 8:30 WET 1.13 0.406

10/31/18 15:15 WET 1.15 0.477

* Italicized values were below the laboratory reporting limit and are entered here as half the reporting limit value

Mirror Lake-In: 2018 Flows and Pollutant Loads



05/10/18 10:20 DRY 0.019 3.3 0.05 0.131 0.071 12.264 0.186

05/17/18 13:06 DRY 1.15 0.02 1.5 0.25 0.174 0.098 7.385 1.231

05/21/18 15:20 DRY 0.92 0.095

05/26/18 9:40 DRY 0.87 0.072

05/29/18 8:00 DRY 0.92 0.095

05/31/18 7:00 WET 1.02 0.130

05/31/18 8:18 WET 1.03 0.03 1.5 0.25 0.133 0.113 5.647 0.941

06/06/18 10:00 DRY 0.92 0.095

06/09/18 9:35 WET 1.00 0.123

06/09/18 12:40 WET 1.02 0.130

06/09/18 16:25 WET 1.02 0.130

06/12/18 6:30 DRY 1.02 0.130

06/20/18 14:40 DRY 0.88 0.082

06/24/18 11:15 DRY 0.87 0.078

06/28/18 9:05 WET 0.94 0.102

07/02/18 14:00 DRY 0.95 0.106

07/07/18 15:40 DRY 0.87 0.078

Date TimeEvent

Type

Staff

Gauge


Flow



Attachment 2

07/14/18 10:40 DRY 0.76 0.041

07/20/18 6:45 DRY 0.68 0.014

07/21/18 15:20 DRY 0.70 0.020

07/23/18 15:40 WET 0.66 0.007

07/27/18 17:10 DRY 0.64 0.000

08/01/18 17:20 DRY 0.61 0.000

08/06/18 9:30 WET 0.57 0.000

08/06/18 16:00 WET 0.57 0.05 14 0.25 0.000 0.000 0.000 0.000

08/07/18 11:00 DRY 0.60 0.000

08/08/18 10:15 Wet 0.65 0.000

08/10/18 12:00 DRY 0.66 0.007

08/19/18 11:40 DRY 0.76 0.041

08/21/18 19:30 WET 0.56 0.000

08/25/18 13:40 DRY 0.53 0.000

08/27/18 15:00 DRY 0.6 0.000

08/29/18 8:15 WET 0.7 0.020

08/29/18 10:00 WET 0.70 0.020

09/02/18 5:30 WET 0.72 0.027

09/02/18 7:30 WET 0.74 0.034

09/02/18 9:45 WET 0.74 0.034

09/04/18 8:00 DRY 0.77 0.044

09/07/18 12:30 DRY 0.73 0.031

09/09/18 22:30 WET 0.7 0.020

09/11/18 14:30 DRY 0.68 0.014

09/16/18 12:30 DRY 0.66 0.007

09/18/18 13:30 DRY 0.66 0.007

09/25/18 17:15 DRY 0.73 0.031

09/30/18 21:30 WET 0.76 0.041

10/01/18 7:05 WET 0.85 0.072

10/01/18 8:05 WET 0.90 0.04 3 0.25 0.089 0.100 7.528 0.627

10/01/18 9:35 WET 0.91 0.092

10/03/18 14:45 DRY 0.95 0.106

10/06/18 9:00 WET 0.94 0.102

10/08/18 15:15 DRY 0.88 0.082

10/21/18 16:40 DRY 0.85 0.072

10/30/18 12:40 DRY 0.82 0.061

10/31/18 5:14 WET 0.85 0.072

10/31/18 6:00 WET 0.86 0.02 1.5 0.25 0.075 0.042 3.185 0.531



Attachment 2

Forest Lake-In: 2018 Flows and Pollutant Loads



05/10/18 9:45 DRY 0.019 1.65 0.05 0.659 0.355 30.802 0.933

05/17/18 12:18 DRY 1.07 0.02 1.5 0.25 1.435 0.813 60.947 10.158

05/21/18 15:20 DRY 0.95 0.599

05/26/18 9:40 DRY 0.92 0.429

05/31/18 7:00 WET 0.96 0.659

05/31/18 8:08 WET 0.96 0.03 4 0.25 0.659 0.560 74.672 4.667

06/06/18 10:00 DRY 0.89 0.279

06/09/18 9:35 WET 0.90 0.327

06/09/18 12:40 WET 0.92 0.429

06/09/18 16:25 WET 0.93 0.484

06/12/18 6:30 DRY 0.91 0.377

06/20/18 14:40 DRY 0.86 0.152

06/24/18 11:15 DRY 0.83 0.054

06/28/18 9:05 WET 0.88 0.234

07/02/18 14:00 DRY 0.82 0.029

07/07/18 15:40 DRY 0.76 0.000

07/14/18 10:40 DRY 0.73 0.000

07/20/18 6:45 DRY 0.69 0.000

07/21/18 15:20 DRY 0.68 0.000

07/23/18 15:40 WET 0.69 0.000

07/27/18 17:10 DRY 0.68 0.000

08/01/18 17:20 DRY 0.68 0.000

08/06/18 9:30 WET 0.68 0.000

08/06/18 16:18 WET 0.69 0.06 3 0.25 0.000 0.000 0.000 0.000

08/07/18 11:00 DRY 0.71 0.000

08/08/18 10:15 Wet 0.81 0.010

08/10/18 12:00 DRY 0.81 0.010

08/19/18 11:40 DRY 0.59 0.000

08/21/18 19:30 WET 0.79 0.000

08/25/18 13:40 DRY 0.76 0.000

08/27/18 15:00 DRY 0.84 0.083

08/28/18 11:30 DRY 0.85 0.116

08/29/18 8:15 WET 0.9 0.327

08/29/18 9:50 WET 0.91 0.377

09/02/18 5:30 WET 0.87 0.192

09/02/18 7:30 WET 0.89 0.279

09/02/18 9:45 WET 0.88 0.234

09/04/18 8:00 DRY 0.87 0.192

09/07/18 12:30 DRY 0.82 0.029

09/09/18 22:30 WET 0.81 0.010

09/11/18 14:30 DRY 0.81 0.010

09/16/18 12:30 DRY 0.82 0.029

09/18/18 13:30 DRY 0.78 0.000


Date TimeEvent

Type

Staff

Gauge


Flow


Attachment 2

09/25/18 17:15 DRY 0.82 0.029

09/30/18 21:30 WET 0.87 0.192

10/01/18 7:10 WET 0.95 0.599

10/01/18 7:55 WET 0.95 0.02 1.5 0.25 0.599 0.339 25.435 4.239

10/01/18 9:40 WET 0.98 0.786

10/03/18 14:45 DRY 0.93 0.484

10/06/18 9:00 WET 0.92 0.429

10/08/18 15:15 DRY 0.9 0.327

10/21/18 16:40 DRY 0.84 0.083

10/30/18 12:40 DRY 0.86 0.152

10/31/18 5:20 WET 0.87 0.192

10/31/18 6:05 WET 0.87 0.02 1.5 0.25 0.192 0.109 8.150 1.358


Lake Manitou Outlet: 2018 Flows and Pollutant Loads



05/10/18 13:15 DRY 1.24 0.013 1.65 0.29 0.266 0.098 12.438 2.186

05/17/18 14:27 DRY 1.30 0.02 1.5 0.25 1.051 0.595 44.644 7.441

05/21/18 15:20 DRY 1.21 0.033

05/26/18 9:40 DRY 1.27 0.616

05/29/18 8:00 DRY 1.33 1.557

05/31/18 7:00 WET 1.41 3.191

05/31/18 7:57 WET 1.44 0.01 3 0.25 3.896 1.103 331.044 27.587

06/06/18 10:00 DRY 1.33 1.557

06/09/18 12:40 WET 1.38 2.534

06/09/18 16:25 WET 1.53 6.271

06/12/18 6:30 DRY 1.53 6.271

06/20/18 14:40 DRY 1.28 0.752

06/24/18 11:15 DRY 1.27 0.616

06/28/18 9:05 WET 1.35 1.929

07/02/18 14:00 DRY 1.60 8.357

07/07/18 15:40 DRY 1.26 0.489

07/14/18 10:40 DRY 1.17 0.000

07/20/18 6:45 DRY 1.06 0.000

07/23/18 15:40 WET 1.24 0.266

07/27/18 17:10 DRY 1.02 0.000

08/01/18 17:20 DRY 0.95 0.000

08/06/18 9:30 WET 0.90 0.000

08/06/18 17:02 WET 0.94 0.02 1.5 0.25 0.000 0.000 0.000 0.000

08/07/18 11:00 DRY 0.94 0.000

08/08/18 10:15 Wet 0.99 0.000

08/10/18 12:00 DRY 0.99 0.000

08/19/18 11:40 DRY 0.89 0.000

Date TimeEvent

Type

Staff

Gauge


Flow



Attachment 2

08/25/18 13:40 DRY 0.84 0.000

08/28/18 11:30 DRY 0.91 0.000

08/29/18 8:15 WET 0.97 0.000

08/29/18 11:20 WET 1.00 0.000

08/30/18 8:00 DRY 0.97 0.000

09/02/18 9:45 WET 1.05 0.000

09/04/18 8:00 DRY 1.05 0.000

09/07/18 12:30 DRY 1.06 0.000

09/11/18 14:30 DRY 1.00 0.000

09/16/18 12:30 DRY 0.7 0.000

09/18/18 13:30 DRY 0.96 0.000

09/25/18 17:15 DRY 1.01 0.000

09/30/18 21:30 WET 1.06 0.000

10/01/18 8:40 WET 1.14 0.04 5 0.25 0.000 0.000 0.000 0.000

10/03/18 14:45 DRY 1.33 1.557

10/06/18 9:00 WET 1.36 2.124

10/21/18 16:40 DRY 1.05 0.000

10/30/18 12:40 DRY 0.92 0.000

10/31/18 6:30 WET 0.92 0.02 1.5 0.25 0.000 0.000 0.000 0.000


Attachment 3

Lake Manitou 2018 Raw Field Data Tables


Attachment 3. Raw Data Tables

K&A In-Lake Monitoring Data

Secchi

Depth Depth Temp DO COND pH TP TN Chloride Alkalinity Chl. a

ft ft ⁰C mg/L µS/cm mg/L mg/L mg/L mg/L µg/L

0 18.50 10.77 403.4

3 18.50 10.80 403.5 8.93 0.7501 0.32 13.6 185 4.1

6 18.50 10.81 403.1

9 18.40 10.76 403.4

12 14.70 10.57 413.1

15 9.40 9.88 416.0

18 7.50 1.20 428.0 8.52 0.069 0.73 13.3 195

19 7.50 0.23 436.5

0 18.40 10.52 387.7

3 18.40 10.51 389.2 8.89 0.025 0.32 13.5 183 0.9

6 18.20 10.41 389.2

9 17.60 9.93 404.5

12 14.20 8.53 411.0 8.72 0.023 0.37 13.5 187

12.5 12.00 0.41 421.3

0 25.20 10.13 369.7

3 25.20 9.80 370.1 8.22 0.040 0.70 17.0 152 12.4

6 25.10 8.84 371.3

9 24.70 7.38 377.9

12 24.20 2.83 387.9

15 23.80 0.48 394.1 8.16 0.120 1.20 18.0 166

17.9 20.90 0.20 511.0

0 25.00 9.95 366.0

3 24.90 9.92 365.5 8.38 0.040 0.60 17.0 144 11.0

6 24.80 9.54 364.6

9 24.50 6.06 376.6

12 24.10 0.50 386.8 8.3 0.050 0.70 17.0 160

12.2 23.90 0.25 479.01

Reported result from Pace Analytical lab was suspected to be erroneous. K&A contested result with no resolution from the analytical lab. See Attachment 4.

K&A In-Lake Sediment Monitoring Data

TP Fe Solids

mg/kg mg/kg %

05/10/18 Deep 1090 28800 16.8

05/10/18 Mid 592 21500 20.2

10/01/18 Deep 569 19700 21.0

10/01/18 Mid 454 20000 29.0

Date

05/10/18

05/10/18

08/29/18

08/29/18

DateSample

ID

4

Deep

(S10)

Mid (S3)

Deep

(S10)

Mid (S3)

Sample

ID

7.5

6

4



K&A Drain Monitoring Data

Avg.

Velocity

Water

Depth

Water

Over

Weir

Staff

GaugepH Temp DO COND TP TSS NO3

ft/s ft ft ft ⁰C mg/L µS/cm mg/L mg/L mg/L

13:15 Lake Out 1 2.163 1.24 9.02 19 10.77 420 0.013 <3.3 0.29

1 1.420 0.375

2 0.387 0.292

8:55 HJ Up 1 1.790 0.083 8.56 13.8 10.51 680 0.019 4.4 0.82

1 0.160 2.300

2 0.143 1.930

9:45 FL In 1 0.2 8.66 18.9 9.33 350 0.019 <3.3 <0.10

10:20 ML In 1 0.467 0.250 8.91 18.9 10.48 340 0.019 3.3 <0.10

14:27 Lake Out 0 0.5 1.3 8.23 21.7 10.41 420 0.02 <3 <0.5

13:06 ML In 1 2.243 0.375 1.15 8.33 22.3 12.33 310 0.02 <3 <0.5

12:17 FL In 0 0.318 1.07 8.04 21.9 9.75 320 0.02 <3 <0.5

1 1.407 0.420

2 0.567 0.330

11:08 HJ Up 1 1.827 0.208 8.04 15.9 12.91 620 0.06 4 1.3

1 0.100 2.208

2 0.167 1.833

7:57 Lake Out 0 0.25 1.44 8.06 24.7 9.66 420 0.01 3 <0.5

8:18 ML In 1 0.277 0.375 1.03 7.89 25.9 6.76 340 0.03 <3 <0.5

8:08 FL In 0 0.208 0.96 7.82 25.9 7.49 330 0.03 4 <0.5

1 0.310 2.500

2 1.033 4.000

7:41 HJ Up 1 1.480 1.000 7.71 18.5 7.09 650 0.09 9 1.9

1 0.100 2.250

2 0.100 2.000

17:02 Lake Out 0 -0.83 0.94 8.23 23.6 10.81 410 0.02 <3 <0.5

16:10 ML In 1 0.000 -0.187 0.57 8.25 25.7 11.67 330 0.05 14 <0.5

16:20 FL In 0 -0.07 0.69 7.7 25.6 5.67 390 0.06 3 <0.5

1 0.543 0.250

2 0.040 0.250

16:30 HJ Up 1 0.847 0.042 7.87 21.2 7.51 670 0.14 22 <0.5

1 0.057 1.542

2 0.023 1.333

9:41 HJ In 1 0.08 1.58

9:41 HJ In 2 0.08 1.33

9:50 ML In 1 -0.06 0.7

10:00 FL In 0 0.08 0.91

11:10 Lake Out 0 1

7:18 HJ In

7:31 HJ Down

08/06/18

HJ In

HJ Down8:38

9:11

11:25 HJ In

HJ Down10:52

05/10/18

05/17/18

05/31/18

08/29/18

HJ In

HJ Down

16:54

16:43

DateSample

ID

XS

#Time

0.13 9 1

1.11 7.92 19.3 9.2 610 0.3

1.21

7.9 19.7 7 670 0.09 8 <0.5

5 1.2

650 0.14 7 1.5

1.63 7.59 19.8 6.13 600 0.22

7.64 18.8 6.06

6 0.7

13.85 640 0.38 5 1.4

7.99 16.4 10.39 620 0.08

17.1 12.25 490 0.088 9.2 0.39

8.47 14.1 8.71 670 0.065 3.6 0.78

8.74

3 1.1

1.51 8.15 15.4



K&A Drain Monitoring Data

Avg.

Velocity

Water

Depth

Water

Over

Weir

Staff

GaugepH Temp DO COND TP TSS NO3

ft/s ft ft ft ⁰C mg/L µS/cm mg/L mg/L mg/L

1 0.1 1.75

2 0.087 1.58

1 0.23 1.79

2 0.097 1.58

1 0.203 0.5

2 0.48 0.5

1 0.21 0.58

2 0.517 0.58

7:42 HJ Up 1 1.957 0.25 8.34 11.5 9.53 490 0.32 92 0.6

10:10 HJ Up 1 1.863 0.25 8.3 11.3 9.72 490 0.29 33 1.3

7:05 ML In 1 0.096 0.85

8:05 ML In 1 0.873 0.146 0.9 7.61 14.1 7.47 360 0.04 3 <0.5

9:35 ML In 1 0.883 0.146 0.91

7:10 FL In 0 0.125 0.95

7:55 FL In 0 0.125 0.95 7.25 14.6 14.6 440 0.02 <3 <0.5

9:40 FL In 0 0.158 0.98

8:40 Lake Out 0 -0.46 1.14 7.81 15.8 7.76 410 0.04 5 <0.5

6:30 Lake Out 0 0.083 0.92 8.61 10.5 10.99 390 0.02 <3 <0.5

5:14 ML In 1 0.023 0.083 0.85

6:00 ML In 1 0.063 0.104 0.86 8.82 10.2 12.22 320 0.02 <3 <0.5

5:20 FL In 0 0.167 0.87

6:05 FL In 0 0.167 0.87 8.33 9.8 10.01 390 0.02 <3 <0.5

1 0.153 0.333

2 0.577 0.333

5:40 HJ Up 1 1.970 0.250 8.19 11.3 9.19 600 0.18 30 0.9

1 0.143 1.583

2 0.100 1.333

1 0.133 1.583

2 0.100 1.333HJ In6:15

5:30 HJ In

HJ Down5:50

9:45

7:15

HJ Down

10/31/18

10/01/18

HJ Down

HJ In

HJ In

10:00

7:30

13 1

Date TimeSample

ID

XS

#

1.12 8.03 10.4 7.99 700 0.05

20 0.6

1.11

8.12 10.9 8.38 630 0.14

23 1.4

8.51 11.2 9.48 520 0.41 24 2

8.61 11.7 9.48 520 0.28

5 1.1

1.35 7.95 11 10.02 6100.1 6 1.2

1.3 7.95 11 10.02 6100.09



Staff Gauge Readings (All)

HJ In FL In ML In Lk Out HJ Down HJ Up

5/10/18 8:40 0.375 1.420 K&A R Side

5/10/18 8:40 0.291 0.387 K&A L Side

5/10/18 8:55 0.250 1.790 K&A Center

5/10/18 13:15 1.24 K&A Odd Boards

5/17/18 10:52 0.33 0.567 K&A L side

5/17/18 10:52 0.42 1.407 K&A R Side

5/17/18 11:10 0.208 1.827 K&A Center

5/17/18 11:23 1.51 2.208 0.100 K&A L side

5/17/18 11:23 1.51 1.833 0.167 K&A R side

5/17/18 12:18 1.07 K&A Level Over Weir

5/17/18 13:06 1.15 0.375 2.243 K&A Level In-culvert

5/17/18 14:27 1.30 K&A Odd Boards

5/21/18 15:20 1.43 FF Dry Event. Low flow into LM.

5/21/18 15:20 1.21 FF Dry. Mod flow, 2 c boards, 1 board out

5/21/18 15:20 0.95 FF Dry event. Low to Mod Flow into LM

5/21/18 15:20 0.92 FF Dry event. Low Flow into LM

5/26/18 9:40 1.5 FF Dry Event. Low to mod flow into LM.

5/26/18 9:40 1.27 FF Dry. Low outflow. 1 center board out

5/26/18 9:40 0.92 FF Dry event.


5/29/18 8:00 1.56 FF Dry Event. Low flow into LM.

5/29/18 8:00 1.33 FF Dry. Low outflow. 1 center board out


5/31/18 7:00 1.4 FF .3 inches of rain / Rain 12 hrs prior

5/31/18 7:00 1.41 FF All boards were put in on 5-30-18

5/31/18 7:00 0.96 FF Wet Event. 0.37in Rain 12hrs prior

5/31/18 7:00 1.02 FF Wet Event. 0.37in Rain 12hrs prior

5/31/18 7:18 1.63 2.250 0.100 K&A L Side

5/31/18 7:18 1.63 2.000 0.100 K&A R Side

5/31/18 7:31 0.208 0.310 K&A L Side

5/31/18 7:31 0.333 1.033 K&A R Side

5/31/18 7:41 0.083 1.480 K&A Center

5/31/18 7:57 1.44 0.25 K&A Level Over Weir


5/31/18 8:18 1.03 0.375 0.277 K&A Level Before Culvert

6/6/18 10:00 1.52 FF

6/6/18 10:00 0.89 FF

6/6/18 10:00 0.92 FF

6/6/18 10:00 1.33 FF

6/8/18 6:35 1.54 FF TP Taken, Pre-rain DRY

NotesDate / TimeStaff Gauge Level Readings (ft)

Water

Level

(ft)

Water Level (ft)Avg.

Velocity

(fps)

SG

Read

by





6/9/18 7:10 1.54 FF TP, TSS Taken, Wet Event (0.1" at 6AM)

6/9/18 9:35 1.60 FF TP, TSS Taken, Intermittent rain WET

6/9/18 9:35 0.90 FF Intermittent light to moderate rain





6/9/18 12:40 1.38 FF Intermittent rain. All boards in place

6/9/18 16:25 1.63 FF TP, TSS Taken, Overcast, (end of event)

6/9/18 16:25 0.93 FF Overcast, stopped raining (end of event)



6/12/18 6:30 1.72 FF Dry, no rain since 6-9-18




6/20/18 14:40 1.50 FF DRY

6/20/18 14:40 0.86 FF DRY Low Flow

6/20/18 14:40 0.88 FF DRY Low Flow

6/20/18 14:40 1.28 FF DRY All boards in

6/24/18 11:15 1.48 FF DRY

6/24/18 11:15 0.83 FF DRY

6/24/18 11:15 0.87 FF DRY

6/24/18 11:15 1.27 FF DRY

6/28/18 9:05 1.56 FF WET (Intermittent Rain 11a-5p)




7/2/18 14:00 1.58 FF Dry

7/2/18 14:00 0.82 FF Dry

7/2/18 14:00 0.95 FF Dry

7/2/18 14:00 1.60 FF Dry

7/7/18 15:40 1.50 FF Dry

7/7/18 15:40 0.76 FF Dry

7/7/18 15:40 0.87 FF Dry

7/7/18 15:40 1.26 FF Dry

7/14/18 10:40 1.36 FF Dry

7/14/18 10:40 0.73 FF Dry

7/14/18 10:40 0.76 FF Dry

7/14/18 10:40 1.17 FF Dry

7/20/18 6:45 1.26 FF Dry

7/20/18 6:45 0.69 FF Dry

Date / TimeStaff Gauge Level Readings (ft)

Water

Level

(ft)


Velocity

(fps)

SG

Read

by

Notes





7/20/18 6:45 0.68 FF Dry

7/20/18 6:45 1.06 FF Dry

7/20/18 22:50 1.26 FF Dry

7/21/18 15:20 1.24 FF Dry

7/21/18 15:20 0.68 FF Dry

7/21/18 15:20 0.70 FF Dry

7/22/18 9:45 1.24 FF Wet

7/23/18 15:40 1.24 FF Wet (Drizzle)

7/23/18 15:40 0.69 FF Wet (Drizzle)

7/23/18 15:40 0.66 FF Wet (Drizzle)

7/23/18 15:40 1.24 FF Wet (Drizzle)

7/27/18 17:10 1.19 FF Dry

7/27/18 17:10 0.68 FF Dry

7/27/18 17:10 0.64 FF Dry

7/27/18 17:10 1.02 FF Dry

8/1/18 17:20 1.12 FF Dry

8/1/18 17:20 0.68 FF Dry

8/1/18 17:20 0.61 FF Dry

8/1/18 17:20 0.95 FF Dry

8/6/18 9:30 1.00 FF Wet

8/6/18 9:30 0.68 FF Wet

8/6/18 9:30 0.57 FF Wet

8/6/18 9:30 0.90 FF Wet

8/6/18 11:30 1.00 FF Wet (Drizzle)

8/6/18 16:00 0.57 0 K&A Level below culvert (no flow)

8/6/18 16:18 0.69 -0.073 K&A Level below weir (no flow)

8/6/18 16:30 0.042 0.847 K&A Center

8/6/18 16:40 0.250 0.543 K&A L Side

8/6/18 16:40 0.250 0.040 K&A R Side

8/6/18 16:52 1.11 1.542 0.057 K&A L Side

8/6/18 16:52 1.11 1.333 0.023 K&A R Side


8/6/18 21:30 1.13 FF Stopped Raining

8/7/18 11:00 1.13 FF Dry

8/7/18 11:00 0.71 FF Dry

8/7/18 11:00 0.60 FF Dry

8/7/18 11:00 0.94 FF Dry

8/8/18 10:15 1.18 FF Wet

8/8/18 10:15 0.81 FF Wet

8/8/18 10:15 0.65 FF Wet

8/8/18 10:15 0.99 FF Wet

8/10/18 12:00 1.20 FF Dry


Water

Level

(ft)


Velocity

(fps)

SG

Read

by

Notes





8/10/18 12:00 0.81 FF Dry

8/10/18 12:00 0.66 FF Dry

8/10/18 12:00 0.99 FF Dry

8/19/18 11:40 1.08 FF Dry

8/19/18 11:40 0.59 FF Dry

8/19/18 11:40 0.76 FF Dry

8/19/18 11:40 0.89 FF Dry

8/21/18 19:30 1.1 FF Dry event.

8/21/18 19:30 0.79 FF Trickle outflow

8/21/18 19:30 0.56 FF No outflow

8/25/18 13:40 1.03 FF Dry event.

8/25/18 13:40 0.84 FF Dry event.

8/25/18 13:40 0.76 FF Trickle outflow

8/25/18 13:40 0.53 FF No outflow

8/27/18 15:00 1.1 FF Dry event.

8/27/18 15:00 0.84 FF Light outflow

8/27/18 15:00 0.6 FF No outflow

8/28/18 11:30 1.6 FF Dry event.

8/28/18 11:30 0.91 FF Dry event. All spillboards in place.

8/28/18 11:30 0.85 FF Light outflow

8/29/18 8:15 1.19 FF Rain during early morning hours

8/29/18 8:15 0.97 FF Dry event. All spillboards in place.

8/29/18 8:15 0.9 FF Moderate outflow

8/29/18 8:15 0.7 FF No outflow

8/29/18 9:35 1.21 1.58 0.08 K&A L Side

8/29/18 9:35 1.21 1.33 0.08 K&A R Side


8/29/18 10:00 0.70 K&A Level below culvert (no flow)


8/30/18 8:00 0.97 FF Dry Event.

9/1/18 20:00 1.22 FF Wet. 15min downpour 20min prior.

9/2/18 5:30 1.22 FF Wet. Downpour 1hr prior.

9/2/18 5:30 0.87 FF Wet. Mod flow. Downpour 1hr prior.

9/2/18 5:30 0.72 FF Wet. Barely flow. Downpour 1hr prior.

9/2/18 7:30 1.24 FF Wet. Heavy rain 10min prior.



9/2/18 9:45 1.25 FF Wet/Dry. Stopped raining 2hrs prior.




9/4/18 8:00 1.27 FF Dry event.


Water

Level

(ft)


Velocity

(fps)

SG

Read

by

Notes





9/4/18 8:00 1.05 FF Dry event. All spillway boards in place.

9/4/18 8:00 0.87 FF Dry event.

9/4/18 8:00 0.77 FF Dry event.

9/7/18 12:30 1.25 FF Dry event. 12:30PM

9/7/18 12:30 1.06 FF Dry event. All spillway boards in place.

9/7/18 12:30 0.82 FF Dry event. 12:30PM. Mod Outflow.

9/7/18 12:30 0.73 FF Dry event. 12:30PM. Trickle Outflow

9/9/18 22:30 1.22 FF Wet Event. 10:30PM

9/9/18 22:30 0.81 FF Wet Event. 10:30PM. Light Outflow.

9/9/18 22:30 0.7 FF Wet Event. 10:30PM. No Outflow

9/11/18 14:30 1.2 FF Dry Event. 2:30PM.

9/11/18 14:30 1.00 FF Dry Event. All spillway boards in place.

9/11/18 14:30 0.81 FF Dry Event. 2:30PM. Light Outflow.

9/11/18 14:30 0.68 FF Dry Event. 2:30PM. No Outflow

9/16/18 12:30 1.18 FF Dry Event. 12:30PM.


9/16/18 12:30 0.82 FF Dry event. Mod Outflow.

9/16/18 12:30 0.66 FF Dry Event. No Outflow

9/18/18 13:30 1.16 FF Dry Event.


9/18/18 13:30 0.78 FF Dry Event. Trickle Outflow.

9/18/18 13:30 0.66 FF Dry Event. No Outflow

9/25/18 17:15 1.22 FF Dry Event.PM

9/25/18 17:15 1.01 FF Dry Event.All spillway boards in place.

9/25/18 17:15 0.82 FF Dry Event. Mod Outflow.

9/25/18 17:15 0.73 FF Dry Event. Trickle Outflow

9/30/18 21:30 1.26 FF Wet Event (beginning of rain)

9/30/18 21:30 1.06 FF Wet (beginning). All boards in. No flow.

9/30/18 21:30 0.87 FF Wet (beginning of rain). Mod Outflow.

9/30/18 21:30 0.76 FF Wet (beginning of rain). Low Outflow.

10/1/18 7:05 0.85 K&A

10/1/18 7:10 0.95 K&A

10/1/18 7:15 1.30 1.75 0.1 K&A L Side

10/1/18 7:15 1.30 1.58 0.087 K&A R Side

10/1/18 7:30 0.5 0.203 K&A L Side

10/1/18 7:30 0.5 0.48 K&A R Side

10/1/18 7:42 0.25 1.957 K&A Center

10/1/18 7:55 0.95 0.125 K&A Level over weir





10/1/18 9:45 1.35 1.79 0.23 K&A L Side


Water

Level

(ft)


Velocity

(fps)

SG

Read

by

Notes





10/1/18 9:45 1.35 1.58 0.097 K&A R Side

10/1/18 10:00 0.58 0.21 K&A L Side

10/1/18 10:00 0.58 0.517 K&A R Side

10/1/18 10:10 0.25 1.863 K&A Center

10/3/18 14:45 1.52 FF 2:45PM, Dry

10/3/18 14:45 1.33 FF Dry. Top 3 boards removed.

10/3/18 14:45 0.93 FF 2:45PM, Dry

10/3/18 14:45 0.95 FF 2:45PM, Dry. Light Outflow

10/6/18 9:00 1.56 FF 9:00 AM, Wet

10/6/18 9:00 1.36 FF Wet. 2 Additional boards out (5 total)

10/6/18 9:00 0.92 FF 9:00 AM. Wet. Moderate Outflow.

10/6/18 9:00 0.94 FF 9:00 AM. Wet. Moderate Outflow.

10/8/18 15:15 1.39 FF 3:15 PM, Dry

10/8/18 15:15 0.9 FF 3:15 PM. Dry.

10/8/18 15:15 0.88 FF 3:15 PM. Dry

10/21/18 16:40 1.26 FF 4:40 PM, Dry

10/21/18 16:40 1.05 FF Dry. 5 Boards Out

10/21/18 16:40 0.84 FF 4:40 PM, Dry. Moderate Outflow.

10/21/18 16:40 0.85 FF 4:40 PM, Dry. Slight Outflow.

10/30/18 12:40 1.1 FF 12:40 PM

10/30/18 12:40 0.92 FF Five boards out for winter months.

10/30/18 12:40 0.86 FF 12:40:00 PM. Moderate Outflow.

10/30/18 12:40 0.82 FF 12:40:00 PM. Light Outflow.

10/30/18 20:00 0.92 FF 8:00 PM

10/31/18 6:30 0.92 0.083 K&A Level over weir. Odd boards.

10/31/18 5:14 0.85 0.083 0.023 K&A Level in culvert

10/31/18 6:00 0.86 0.104 0.063 K&A Level in culvert



10/31/18 5:50 0.333 0.153 K&A Left side.

10/31/18 5:50 0.333 0.577 K&A Right Side

10/31/18 5:40 0.25 1.970 K&A

10/31/18 5:30 1.11 1.583 0.143 K&A L side

10/31/18 5:30 1.11 1.333 0.100 K&A R side

10/31/18 6:15 1.12 1.583 0.133 K&A L side

10/31/18 6:15 1.12 1.333 0.100 K&A R side

10/31/18 8:30 1.13 FF 8:30AM, End of Rain.

10/31/18 15:15 1.15 FF 3:15PM, ~10hrs After rain event.


Water

Level

(ft)


Velocity

(fps)

SG

Read

by

Notes



Water Quality Samples Collected by Fred Farkas

Staff

GaugeTP TSS E. Coli

ft µg/L mg/L MPN/100ml

04/03/18 HJ Down 80 10

04/03/18 ML In 20 10

05/16/18 HJ Down 410 Day after yellow water and floating semisolids

05/16/18 HJ In 350 Day after yellow water and floating semisolids

05/31/18 HJ In 1.4 100 .3 inches rain / Rain 12 hrs prior to SG reading

06/06/18 HJ In 40

06/08/18 HJ In 70 6:35a pre rain event #1

06/09/18 HJ In 70 7:10a start of rain event

06/09/18 HJ In 80 9:35a rain event

06/09/18 HJ In 90 4:25p rain event

06/12/18 HJ In 70 post rain event #1

07/11/18 ML In 40

08/02/18 In-Lake* 10 *4930 Ottawa Ct. - Gagnier

08/02/18 In-Lake* 30 *4893 Mohican - Griffin

08/06/18 HJ In 40 9:30a pre rain event #2

08/08/18 HJ In 70 post rain event #2

09/01/18 HJ In 1.22 20 < 3 Wet event. 15min downpour 20min prior

09/02/18 HJ In 1.22 20 4 Wet event. Downpour 1hr prior, steady rain

09/02/18 HJ In 1.24 50 3 Wet event. 7:30AM. Heavy rain 10min prior

09/02/18 HJ In 1.25 50 3 Wet/Dry. 9:45AM. Stopped raining 2hrs prior

09/04/18 HJ In 1.27 40 5 Dry event.

09/04/18 In-Lake* 210 *In-lake Channel 150ft from HJ-In culverts

09/30/18 HJ In 1.26 50 < 3 NO3: 1.1 mg/L. 9:45PM Wet Event (beginning)

10/02/18 HJ Down >1,000,000 8:30AM

10/02/18 HJ E. Fork* >1,000,000 *Dairy Drain at Morrice Rd. 8:55AM

10/02/18 HJ Up 10,000 8:40AM

10/02/18 HJ In >1,000,000

10/31/18 HJ E. Fork* 21,000 *Dairy Drain at Morrice Rd. 8:50AM

10/31/18 HJ Up 740 8:55AM

NOTESSample IDDate

Attachment 4

Lake Manitou 2018 Analytical Laboratory Reports

#=CL#

June 06, 2018

LIMS USE: FR - PATTYLIMS OBJECT ID: 4612093

4612093Project:Pace Project No.:

RE:

Patty Hoch-MelluishKieser & Associates536 E. Michigan Ave.Kalamazoo, MI 49007

Manitou Lake

Dear Patty Hoch-Melluish:Enclosed are the analytical results for sample(s) received by the laboratory on May 11, 2018. Theresults relate only to the samples included in this report. Results reported herein conform to the mostcurrent, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, whereapplicable, unless otherwise noted in the body of the report.

Unreported: Added phosphorus per client request

If you have any questions concerning this report, please feel free to contact me.

Sincerely,

Andrea [email protected]

Project Manager269-381-9666

Enclosures

cc: Josh Kieser, Kieser & Associates

REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,

without the written consent of Pace Analytical Services, LLC.

Pace Analytical Services, LLC4425 Manchester Road

Kalamazoo, MI 49001269-381-9666

Page 1 of 39

#=CP#

CERTIFICATIONS

Pace Project No.:Project:

4612093Manitou Lake

Grand Rapids Certification ID's5560 Corporate Exchange Ct SE, Grand Rapids, MI 49512Minnesota Department of Health, Certificate #1385941Arkansas Department of Environmental Quality, Certificate#17-046-0Georgia Environmental Protection Division, StipulationIllinois Environmental Protection Agency, Certificate#004325Michigan Department of Environmental Quality, Laboratory#0034

New York State Department of Health, Serial #57971 and57972North Carolina Division of Water Resources, Certificate#659Virginia Department of General Services, Certificate #9028Wisconsin Department of Natural Resources, Laboratory#999472650U.S. Department of Agriculture Permit to Receive Soil,Permit #P330-17-00278




Kalamazoo, MI 49001269-381-9666

Page 2 of 39

#=SS#

SAMPLE SUMMARY


4612093Manitou Lake

Lab ID Sample ID Matrix Date Collected Date Received

4612093001 Lake Deep S Water 05/10/18 13:57 05/11/18 09:50

4612093002 Lake Deep B Water 05/10/18 13:54 05/11/18 09:50

4612093003 Lake Mid S Water 05/10/18 12:15 05/11/18 09:50

4612093004 Lake Mid B Water 05/10/18 12:05 05/11/18 09:50

4612093005 Lake out Water 05/10/18 13:15 05/11/18 09:50

4612093006 FLIN Water 05/10/18 09:45 05/11/18 09:50

4612093007 HJIN Water 05/10/18 09:11 05/11/18 09:50

4612093008 MLIN Water 05/10/18 10:20 05/11/18 09:50

4612093009 HJDOWN Water 05/10/18 08:38 05/11/18 09:50

4612093010 HJUP Water 05/10/18 08:55 05/11/18 09:50

4612093011 Lake Deep Solid 05/10/18 14:05 05/11/18 09:50

4612093012 Lake Mid Solid 05/10/18 12:40 05/11/18 09:50




Kalamazoo, MI 49001269-381-9666

Page 3 of 39

#=SA#

SAMPLE ANALYTE COUNT


4612093Manitou Lake

Lab ID Sample ID MethodAnalytesReportedAnalysts

4612093001 Lake Deep S EPA 300.0 1JLB1

SM 2320B-11 1NS1

NO2+NO3+NH3 Calculation 1JTW

SM 4500-NH3 G-11 1EB1

SM 4500-NO3 F-11 1NRC

SM 4500-P E-11 1NRC

4612093002 Lake Deep B EPA 300.0 1JLB1

SM 2320B-11 1NS1


SM 4500-NH3 G-11 1EB1

SM 4500-NO3 F-11 1NRC

SM 4500-P E-11 1NRC

4612093003 Lake Mid S EPA 300.0 1JLB1

SM 2320B-11 1NS1


SM 4500-NH3 G-11 1EB1

SM 4500-NO3 F-11 1NRC

SM 4500-P E-11 1NRC

4612093004 Lake Mid B EPA 300.0 1JLB1

SM 2320B-11 1NS1


SM 4500-NH3 G-11 1EB1

SM 4500-NO3 F-11 1NRC

SM 4500-P E-11 1NRC

4612093005 Lake out EPA 300.0 1JLB1

SM 2540D-11 1MAD

SM 4500-P E-11 1AS

4612093006 FLIN EPA 300.0 1JLB1

SM 2540D-11 1MAD

SM 4500-P E-11 1AS

4612093007 HJIN EPA 300.0 1JLB1

SM 2540D-11 1MAD

SM 4500-P E-11 1AS

4612093008 MLIN EPA 300.0 1JLB1

SM 2540D-11 1MAD

SM 4500-P E-11 1AS

4612093009 HJDOWN EPA 300.0 1JLB1




Kalamazoo, MI 49001269-381-9666

Page 4 of 39

#=SA#

SAMPLE ANALYTE COUNT


4612093Manitou Lake

Lab ID Sample ID MethodAnalytesReportedAnalysts

SM 2540D-11 1MAD

SM 4500-P E-11 1AS

4612093010 HJUP EPA 300.0 1JLB1

SM 2540D-11 1MAD

SM 4500-P E-11 1AS

4612093011 Lake Deep EPA 6010C 1KLV

SM 2540 G-11/3550 1NS1

SM 2540G 1NS1

SM 4500-P E-11 1AS

4612093012 Lake Mid EPA 6010C 1KLV

SM 2540 G-11/3550 1NS1

SM 2540G 1NS1

SM 4500-P E-11 1AS




Kalamazoo, MI 49001269-381-9666

Page 5 of 39

#=HO#

SUMMARY OF DETECTION


4612093Manitou Lake

Parameters AnalyzedResultLab Sample ID

Report Limit QualifiersUnitsMethodClient Sample ID

4612093001 Lake Deep SChloride 13.6 mg/L 05/17/18 12:032.0EPA 300.0Alkalinity, Total as CaCO3 185 mg/L 05/22/18 12:2720.0SM 2320B-11Total Inorganic Nitrogen 0.32 mg/L 05/25/18 16:59 N20.050NO2+NO3+NH3 CalculationNitrogen, Ammonia 0.033 mg/L 05/25/18 12:320.010SM 4500-NH3 G-11Nitrogen, NO2 plus NO3 0.29 mg/L 05/19/18 11:390.050SM 4500-NO3 F-11Phosphorus 0.75 mg/L 05/18/18 13:150.010SM 4500-P E-11

4612093002 Lake Deep BChloride 13.3 mg/L 05/16/18 21:172.0EPA 300.0Alkalinity, Total as CaCO3 195 mg/L 05/22/18 12:3020.0SM 2320B-11Total Inorganic Nitrogen 0.73 mg/L 05/25/18 16:59 N20.050NO2+NO3+NH3 CalculationNitrogen, Ammonia 0.43 mg/L 05/25/18 12:340.010SM 4500-NH3 G-11Nitrogen, NO2 plus NO3 0.30 mg/L 05/19/18 11:400.050SM 4500-NO3 F-11Phosphorus 0.069 mg/L 05/18/18 13:150.010SM 4500-P E-11

4612093003 Lake Mid SChloride 13.5 mg/L 05/16/18 21:362.0EPA 300.0Alkalinity, Total as CaCO3 183 mg/L 05/22/18 12:3320.0SM 2320B-11Total Inorganic Nitrogen 0.32 mg/L 05/25/18 16:59 N20.050NO2+NO3+NH3 CalculationNitrogen, Ammonia 0.037 mg/L 05/25/18 12:360.010SM 4500-NH3 G-11Nitrogen, NO2 plus NO3 0.28 mg/L 05/19/18 11:410.050SM 4500-NO3 F-11Phosphorus 0.025 mg/L 05/18/18 13:150.010SM 4500-P E-11

4612093004 Lake Mid BChloride 13.5 mg/L 05/16/18 21:552.0EPA 300.0Alkalinity, Total as CaCO3 187 mg/L 05/22/18 12:3620.0SM 2320B-11Total Inorganic Nitrogen 0.37 mg/L 05/25/18 16:59 N20.050NO2+NO3+NH3 CalculationNitrogen, Ammonia 0.072 mg/L 05/25/18 12:380.010SM 4500-NH3 G-11Nitrogen, NO2 plus NO3 0.29 mg/L 05/19/18 11:480.050SM 4500-NO3 F-11Phosphorus 0.023 mg/L 05/18/18 13:150.010SM 4500-P E-11

4612093005 Lake outNitrate as N 0.29 mg/L 05/11/18 23:050.10EPA 300.0Phosphorus 0.013 mg/L 06/05/18 13:060.010SM 4500-P E-11

4612093006 FLINPhosphorus 0.019 mg/L 06/05/18 13:060.010SM 4500-P E-11

4612093007 HJINNitrate as N 0.39 mg/L 05/11/18 20:350.10EPA 300.0Total Suspended Solids 9.2 mg/L 05/15/18 10:243.3SM 2540D-11Phosphorus 0.088 mg/L 06/05/18 13:060.010SM 4500-P E-11

4612093008 MLINTotal Suspended Solids 3.3 mg/L 05/15/18 10:243.3SM 2540D-11Phosphorus 0.019 mg/L 06/05/18 13:060.010SM 4500-P E-11

4612093009 HJDOWNNitrate as N 0.78 mg/L 05/11/18 19:570.10EPA 300.0Total Suspended Solids 3.6 mg/L 05/15/18 10:243.3SM 2540D-11




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#=HO#

SUMMARY OF DETECTION


4612093Manitou Lake

Parameters AnalyzedResultLab Sample ID

Report Limit QualifiersUnitsMethodClient Sample ID

4612093009 HJDOWNPhosphorus 0.065 mg/L 06/05/18 13:060.010SM 4500-P E-11

4612093010 HJUPNitrate as N 0.82 mg/L 05/11/18 20:160.10EPA 300.0Total Suspended Solids 4.4 mg/L 05/15/18 10:243.3SM 2540D-11Phosphorus 0.019 mg/L 06/05/18 13:300.010SM 4500-P E-11

4612093011 Lake DeepIron 28800 mg/kg 05/20/18 13:0729.3EPA 6010CPercent Moisture 83.2 % 05/16/18 12:130.10SM 2540 G-11/3550Total Solids 16.8 % 05/14/18 15:32 N20.10SM 2540GPhosphorus 1090 mg/kg 06/05/18 11:1258.5SM 4500-P E-11

4612093012 Lake MidIron 21500 mg/kg 05/20/18 13:1122.6EPA 6010CPercent Moisture 79.8 % 05/16/18 12:130.10SM 2540 G-11/3550Total Solids 20.2 % 05/14/18 15:33 N20.10SM 2540GPhosphorus 592 mg/kg 06/05/18 11:1248.9SM 4500-P E-11




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#=AR#

ANALYTICAL RESULTS


4612093Manitou Lake

Sample: Lake Deep S Lab ID: 4612093001 Collected: 05/10/18 13:57 Received: 05/11/18 09:50 Matrix: Water

Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit

Analytical Method: EPA 300.0300.0 IC Anions 28 Days

Chloride 13.6 mg/L 05/17/18 12:03 16887-00-62.0 1

Analytical Method: SM 2320B-112320B Alkalinity

Alkalinity, Total as CaCO3 185 mg/L 05/22/18 12:2720.0 1

Analytical Method: NO2+NO3+NH3 CalculationTotal Inorganic Nitrogen

Total Inorganic Nitrogen 0.32 mg/L 05/25/18 16:59 N20.050 1

Analytical Method: SM 4500-NH3 G-114500 Ammonia Water

Nitrogen, Ammonia 0.033 mg/L 05/25/18 12:32 7664-41-70.010 1

Analytical Method: SM 4500-NO3 F-114500NO3-F, NO2/NO3 pres.

Nitrogen, NO2 plus NO3 0.29 mg/L 05/19/18 11:390.050 1

Analytical Method: SM 4500-P E-11 Preparation Method: SM 4500-P B-114500PE Total Phosphorus

Phosphorus 0.75 mg/L 05/18/18 13:15 7723-14-005/17/18 14:460.010 1


without the written consent of Pace Analytical Services, LLC.Date: 06/06/2018 02:11 PM


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#=AR#

ANALYTICAL RESULTS


4612093Manitou Lake

Sample: Lake Deep B Lab ID: 4612093002 Collected: 05/10/18 13:54 Received: 05/11/18 09:50 Matrix: Water



Chloride 13.3 mg/L 05/16/18 21:17 16887-00-62.0 1










Phosphorus 0.069 mg/L 05/18/18 13:15 7723-14-005/17/18 14:460.010 1




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#=AR#

ANALYTICAL RESULTS


4612093Manitou Lake

Sample: Lake Mid S Lab ID: 4612093003 Collected: 05/10/18 12:15 Received: 05/11/18 09:50 Matrix: Water



Chloride 13.5 mg/L 05/16/18 21:36 16887-00-62.0 1










Phosphorus 0.025 mg/L 05/18/18 13:15 7723-14-005/17/18 14:460.010 1




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#=AR#

ANALYTICAL RESULTS


4612093Manitou Lake

Sample: Lake Mid B Lab ID: 4612093004 Collected: 05/10/18 12:05 Received: 05/11/18 09:50 Matrix: Water



Chloride 13.5 mg/L 05/16/18 21:55 16887-00-62.0 1










Phosphorus 0.023 mg/L 05/18/18 13:15 7723-14-005/17/18 14:460.010 1




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#=AR#

ANALYTICAL RESULTS


4612093Manitou Lake

Sample: Lake out Lab ID: 4612093005 Collected: 05/10/18 13:15 Received: 05/11/18 09:50 Matrix: Water


Analytical Method: EPA 300.0300.0 IC Anions

Nitrate as N 0.29 mg/L 05/11/18 23:05 14797-55-80.10 1

Analytical Method: SM 2540D-112540D Total Suspended Solids

Total Suspended Solids <3.3 mg/L 05/15/18 10:243.3 1


Phosphorus 0.013 mg/L 06/05/18 13:06 7723-14-006/04/18 12:540.010 1




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#=AR#

ANALYTICAL RESULTS


4612093Manitou Lake

Sample: FLIN Lab ID: 4612093006 Collected: 05/10/18 09:45 Received: 05/11/18 09:50 Matrix: Water



Nitrate as N <0.10 mg/L 05/11/18 20:53 14797-55-80.10 1


Total Suspended Solids <3.3 mg/L 05/15/18 10:243.3 1


Phosphorus 0.019 mg/L 06/05/18 13:06 7723-14-006/04/18 12:540.010 1




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#=AR#

ANALYTICAL RESULTS


4612093Manitou Lake

Sample: HJIN Lab ID: 4612093007 Collected: 05/10/18 09:11 Received: 05/11/18 09:50 Matrix: Water



Nitrate as N 0.39 mg/L 05/11/18 20:35 14797-55-80.10 1


Total Suspended Solids 9.2 mg/L 05/15/18 10:243.3 1


Phosphorus 0.088 mg/L 06/05/18 13:06 7723-14-006/04/18 12:540.010 1




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#=AR#

ANALYTICAL RESULTS


4612093Manitou Lake

Sample: MLIN Lab ID: 4612093008 Collected: 05/10/18 10:20 Received: 05/11/18 09:50 Matrix: Water



Nitrate as N <0.10 mg/L 05/11/18 21:12 14797-55-80.10 1




Phosphorus 0.019 mg/L 06/05/18 13:06 7723-14-006/04/18 12:540.010 1




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#=AR#

ANALYTICAL RESULTS


4612093Manitou Lake

Sample: HJDOWN Lab ID: 4612093009 Collected: 05/10/18 08:38 Received: 05/11/18 09:50 Matrix: Water



Nitrate as N 0.78 mg/L 05/11/18 19:57 14797-55-80.10 1




Phosphorus 0.065 mg/L 06/05/18 13:06 7723-14-006/04/18 12:540.010 1




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#=AR#

ANALYTICAL RESULTS


4612093Manitou Lake

Sample: HJUP Lab ID: 4612093010 Collected: 05/10/18 08:55 Received: 05/11/18 09:50 Matrix: Water



Nitrate as N 0.82 mg/L 05/11/18 20:16 14797-55-80.10 1




Phosphorus 0.019 mg/L 06/05/18 13:30 7723-14-006/04/18 12:540.010 1




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#=AR#

ANALYTICAL RESULTS


4612093Manitou Lake

Sample: Lake Deep Lab ID: 4612093011 Collected: 05/10/18 14:05 Received: 05/11/18 09:50 Matrix: SolidResults reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.


Analytical Method: EPA 6010C Preparation Method: EPA 3050B6010C MET ICP

Iron 28800 mg/kg 05/20/18 13:07 7439-89-605/17/18 12:5129.3 1

Analytical Method: SM 2540 G-11/3550Percent Moisture

Percent Moisture 83.2 % 05/16/18 12:130.10 1

Analytical Method: SM 2540G2540G Total Percent Solids

Total Solids 16.8 % 05/14/18 15:32 N20.10 1


Phosphorus 1090 mg/kg 06/05/18 11:12 7723-14-006/04/18 13:3658.5 1




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#=AR#

ANALYTICAL RESULTS


4612093Manitou Lake

Sample: Lake Mid Lab ID: 4612093012 Collected: 05/10/18 12:40 Received: 05/11/18 09:50 Matrix: SolidResults reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.


Analytical Method: EPA 6010C Preparation Method: EPA 3050B6010C MET ICP

Iron 21500 mg/kg 05/20/18 13:11 7439-89-605/17/18 12:5122.6 1

Analytical Method: SM 2540 G-11/3550Percent Moisture

Percent Moisture 79.8 % 05/16/18 12:130.10 1

Analytical Method: SM 2540G2540G Total Percent Solids

Total Solids 20.2 % 05/14/18 15:33 N20.10 1


Phosphorus 592 mg/kg 06/05/18 11:12 7723-14-006/04/18 13:3648.9 1




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#=QC#

QUALITY CONTROL DATA


4612093Manitou Lake

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:QC Batch Method:

Analysis Method:Analysis Description:

22751EPA 300.0

EPA 300.0300.0 IC Anions

Associated Lab Samples: 4612093005, 4612093006, 4612093007, 4612093008, 4612093009, 4612093010

Parameter UnitsBlankResult

ReportingLimit Qualifiers

METHOD BLANK: 91268Associated Lab Samples: 4612093005, 4612093006, 4612093007, 4612093008, 4612093009, 4612093010

Matrix: Water

Analyzed

Nitrate as N mg/L <0.10 0.10 05/11/18 19:19

Parameter UnitsLCS

Result% RecLimits Qualifiers% RecConc.

91269LABORATORY CONTROL SAMPLE:LCSSpike

Nitrate as N mg/L 3.03 101 90-110

Parameter UnitsMS

Result% RecLimits Qual% RecConc.

91270MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

MSSpikeResult

4612093008

91271

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Nitrate as N mg/L 3 102 90-110102 0 203<0.10 3.1 3.1

Parameter UnitsDup

ResultMaxRPD QualifiersRPDResult

461209300891272SAMPLE DUPLICATE:

Nitrate as N mg/L <0.10 20<0.10

Parameter UnitsDup



Nitrate as N mg/L 0.28 3 200.29




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#=QC#



4612093Manitou Lake




23132EPA 300.0


Associated Lab Samples: 4612093001



METHOD BLANK: 92762Associated Lab Samples: 4612093001

Matrix: Water

Analyzed

Chloride mg/L <2.0 2.0 05/17/18 02:56

Parameter UnitsLCS



Chloride mg/L 47.450 95 90-110

Parameter UnitsMS



MSSpikeResult

4612137001

92765

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Chloride mg/L E,M1250 82 90-11080 1 20250389 593 588

Parameter UnitsDup



Chloride mg/L 373 4 20389

Parameter UnitsDup



Chloride mg/L <2.0 20<2.0




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#=QC#



4612093Manitou Lake




23133EPA 300.0


Associated Lab Samples: 4612093002, 4612093003, 4612093004



METHOD BLANK: 92768Associated Lab Samples: 4612093002, 4612093003, 4612093004

Matrix: Water

Analyzed

Chloride mg/L <2.0 2.0 05/17/18 02:37

Parameter UnitsLCS



Chloride mg/L 47.250 94 90-110

Parameter UnitsMS



MSSpikeResult

4612234009

93593

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Chloride mg/L M150 86 90-11086 0 2050<2.0 44.4 44.5

Parameter UnitsDup



Chloride mg/L 83.1 0 2083.0

Parameter UnitsDup



Chloride mg/L <2.0 20<2.0




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#=QC#



4612093Manitou Lake




23231EPA 3050B

EPA 6010C6010 MET

Associated Lab Samples: 4612093011, 4612093012



METHOD BLANK: 93248Associated Lab Samples: 4612093011, 4612093012

Matrix: Solid

Analyzed

Iron mg/kg <4.9 4.9 05/20/18 13:01

Parameter UnitsLCS



Iron mg/kg 18.719.3 97 80-120

Parameter UnitsMS



MSSpikeResult

4612194001

93373

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Iron mg/kg M119.5 270 75-125181 18 2019.155.5 108 90.1




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#=QC#



4612093Manitou Lake




23070SM 2540 G-11/3550

SM 2540 G-11/3550Dry Weight/Percent Moisture


Parameter UnitsDup



Percent Moisture % 6.4 1 206.4

Parameter UnitsDup



Percent Moisture % 12.1 7 2011.3




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#=QC#



4612093Manitou Lake




23677SM 2320B-11

SM 2320B-112320B Alkalinity

Associated Lab Samples: 4612093001, 4612093002, 4612093003, 4612093004



METHOD BLANK: 95099Associated Lab Samples: 4612093001, 4612093002, 4612093003, 4612093004

Matrix: Water

Analyzed

Alkalinity, Total as CaCO3 mg/L <20.0 20.0 05/22/18 10:06

Parameter UnitsLCS



Alkalinity, Total as CaCO3 mg/L 249238 105 91-110

Parameter UnitsMS


95102MATRIX SPIKE SAMPLE:MSSpike

Result4612437001

Alkalinity, Total as CaCO3 mg/L 732238 101 82-121491

Parameter UnitsMS


95286MATRIX SPIKE SAMPLE:MSSpike

Result4612058001

Alkalinity, Total as CaCO3 mg/L 374238 98 82-121140000 ug/L

Parameter UnitsDup



Alkalinity, Total as CaCO3 mg/L 491 0 20491

Parameter UnitsDup



Alkalinity, Total as CaCO3 mg/L 139 1 20140000 ug/L




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#=QC#



4612093Manitou Lake




22936SM 2540D-11

SM 2540D-112540D Total Suspended Solids





Matrix: Water

Analyzed

Total Suspended Solids mg/L <3.3 3.3 05/15/18 10:23

Parameter UnitsLCS



Total Suspended Solids mg/L 191200 96 80-120

Parameter UnitsDup



Total Suspended Solids mg/L 34.9 2 535.7

Parameter UnitsDup



Total Suspended Solids mg/L 145 0 5145




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#=QC#



4612093Manitou Lake




22709SM 2540G

SM 2540G2540G Total Solids


Parameter UnitsDup



Total Solids % 7.4 N21 57.4




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#=QC#



4612093Manitou Lake




24119SM 4500-NH3 G-11

SM 4500-NH3 G-114500 Ammonia





Matrix: Water

Analyzed

Nitrogen, Ammonia mg/L <0.010 0.010 05/25/18 12:00

Parameter UnitsLCS



Nitrogen, Ammonia mg/L 2.52.5 100 90-110

Parameter UnitsMS



MSSpikeResult

4611898001

96936

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Nitrogen, Ammonia mg/L 2.5 104 90-110104 0 202.50.051 2.6 2.6




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#=QC#



4612093Manitou Lake




23456SM 4500-NO3 F-11

SM 4500-NO3 F-114500NO3-F Nitrate + Nitrite, preserved





Matrix: Water

Analyzed

Nitrogen, NO2 plus NO3 mg/L <0.050 0.050 05/19/18 11:18

Parameter UnitsLCS



Nitrogen, NO2 plus NO3 mg/L 0.46.5 93 90-110

Parameter UnitsMS



MSSpikeResult

4612115004

94432

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Nitrogen, NO2 plus NO3 mg/L .5 105 90-110103 1 20.5233 ug/L 0.76 0.75




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#=QC#



4612093Manitou Lake




24753SM 4500-P B-11

SM 4500-P E-114500PE Soil Phosphorus




METHOD BLANK: 99467Associated Lab Samples: 4612093011, 4612093012

Matrix: Solid

Analyzed

Phosphorus mg/kg <10.0 10.0 06/05/18 11:12

Parameter UnitsLCS



Phosphorus mg/kg 109100 109 90-110

Parameter UnitsMS



MSSpikeResult

4612634016

99470

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Phosphorus mg/kg M1103 84 90-11062 10 20103160 246 224

Parameter UnitsMS



MSSpikeResult

4612872016

99472

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Phosphorus mg/kg M1101 109 90-110111 7 201079.4J 119 128




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#=QC#



4612093Manitou Lake




23262SM 4500-P B-11

SM 4500-P E-114500PE Total Phosphorus





Matrix: Water

Analyzed

Phosphorus mg/L <0.010 0.010 05/18/18 12:09

Parameter UnitsLCS



Phosphorus mg/L 0.42.4 106 90-110

Parameter UnitsMS



MSSpikeResult

4612058002

93336

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Phosphorus mg/L M1.4 95 90-11087 7 20.492.6 ug/L 0.47 0.44




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#=QC#



4612093Manitou Lake




24755SM 4500-P B-11

SM 4500-P E-114500PE Total Phosphorus





Matrix: Water

Analyzed

Phosphorus mg/L <0.010 0.010 06/05/18 13:30

Parameter UnitsLCS



Phosphorus mg/L 0.42.4 104 90-110

Parameter UnitsMS



MSSpikeResult

4612800002

99476

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Phosphorus mg/L M1.4 111 90-110111 0 20.40.46 0.90 0.90




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#=QL#

QUALIFIERS


4612093Manitou Lake

DEFINITIONS

DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.ND - Not Detected at or above adjusted reporting limit.TNTC - Too Numerous To CountJ - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.MDL - Adjusted Method Detection Limit.PQL - Practical Quantitation Limit.RL - Reporting Limit.S - Surrogate1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.LCS(D) - Laboratory Control Sample (Duplicate)MS(D) - Matrix Spike (Duplicate)DUP - Sample DuplicateRPD - Relative Percent DifferenceNC - Not Calculable.SG - Silica Gel - Clean-UpU - Indicates the compound was analyzed for, but not detected.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.TNI - The NELAC Institute.

ANALYTE QUALIFIERS

Analyte concentration exceeded the calibration range. The reported result is estimated.EMatrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1The lab does not hold NELAC/TNI accreditation for this parameter.N2




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#=CR#

QUALITY CONTROL DATA CROSS REFERENCE TABLE


4612093Manitou Lake

Lab ID Sample ID QC Batch Method QC Batch Analytical MethodAnalyticalBatch

4612093005 22751Lake out EPA 300.04612093006 22751FLIN EPA 300.04612093007 22751HJIN EPA 300.04612093008 22751MLIN EPA 300.04612093009 22751HJDOWN EPA 300.04612093010 22751HJUP EPA 300.0

4612093001 23132Lake Deep S EPA 300.0

4612093002 23133Lake Deep B EPA 300.04612093003 23133Lake Mid S EPA 300.04612093004 23133Lake Mid B EPA 300.0

4612093011 23231 23516Lake Deep EPA 3050B EPA 6010C4612093012 23231 23516Lake Mid EPA 3050B EPA 6010C

4612093011 23070Lake Deep SM 2540 G-11/35504612093012 23070Lake Mid SM 2540 G-11/3550

4612093001 23677Lake Deep S SM 2320B-114612093002 23677Lake Deep B SM 2320B-114612093003 23677Lake Mid S SM 2320B-114612093004 23677Lake Mid B SM 2320B-11

4612093005 22936Lake out SM 2540D-114612093006 22936FLIN SM 2540D-114612093007 22936HJIN SM 2540D-114612093008 22936MLIN SM 2540D-114612093009 22936HJDOWN SM 2540D-114612093010 22936HJUP SM 2540D-11

4612093011 22709Lake Deep SM 2540G4612093012 22709Lake Mid SM 2540G

4612093001 24176Lake Deep S NO2+NO3+NH3Calculation

4612093002 24176Lake Deep B NO2+NO3+NH3Calculation

4612093003 24176Lake Mid S NO2+NO3+NH3Calculation

4612093004 24176Lake Mid B NO2+NO3+NH3Calculation

4612093001 24119Lake Deep S SM 4500-NH3 G-114612093002 24119Lake Deep B SM 4500-NH3 G-114612093003 24119Lake Mid S SM 4500-NH3 G-114612093004 24119Lake Mid B SM 4500-NH3 G-11

4612093001 23456Lake Deep S SM 4500-NO3 F-114612093002 23456Lake Deep B SM 4500-NO3 F-114612093003 23456Lake Mid S SM 4500-NO3 F-114612093004 23456Lake Mid B SM 4500-NO3 F-11

4612093011 24753 24958Lake Deep SM 4500-P B-11 SM 4500-P E-114612093012 24753 24958Lake Mid SM 4500-P B-11 SM 4500-P E-11




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#=CR#

QUALITY CONTROL DATA CROSS REFERENCE TABLE


4612093Manitou Lake

Lab ID Sample ID QC Batch Method QC Batch Analytical MethodAnalyticalBatch

4612093001 23262 23439Lake Deep S SM 4500-P B-11 SM 4500-P E-114612093002 23262 23439Lake Deep B SM 4500-P B-11 SM 4500-P E-114612093003 23262 23439Lake Mid S SM 4500-P B-11 SM 4500-P E-114612093004 23262 23439Lake Mid B SM 4500-P B-11 SM 4500-P E-11

4612093005 24755 24954Lake out SM 4500-P B-11 SM 4500-P E-114612093006 24755 24954FLIN SM 4500-P B-11 SM 4500-P E-114612093007 24755 24954HJIN SM 4500-P B-11 SM 4500-P E-114612093008 24755 24954MLIN SM 4500-P B-11 SM 4500-P E-114612093009 24755 24954HJDOWN SM 4500-P B-11 SM 4500-P E-114612093010 24755 24954HJUP SM 4500-P B-11 SM 4500-P E-11




Kalamazoo, MI 49001269-381-9666

Page 35 of 39

Analytical Laboratory Report

Report ID: S89936.01(01)Generated on 05/25/2018

Report to Report produced byAttention: Josh Kieser Merit Laboratories, Inc.Kieser & Associates 2680 East Lansing Drive536 E. Michigan Ave. Ste 300 East Lansing, MI 48823Kalamazoo, MI 49007

Phone: (517) 332-0167 FAX: (517) 332-6333Phone: 269-344-7117 FAX:Email: [email protected] Contacts for report questions:

John Laverty ([email protected])Barbara Ball ([email protected])

Addtional Contacts: Doug Ervin, Becky Hough

Report SummaryLab Sample ID(s): S89936.01-S89936.06Project: Lake ManitouCollected Date: 05/17/2018Submitted Date/Time: 05/17/2018 15:30Sampled by: Josh Kieser / Gabby MetznerP.O. #:

Table of ContentsCover Page (Page 1)General Report Notes (Page 2)Report Narrative (Page 2)Laboratory Certifications (Page 3)Qualifier Descriptions (Page 3)Glossary of Abbreviations (Page 3)Method Summary (Page 4)Sample Summary (Page 5)

Maya MurshakTechnical Director

Report to Kieser & AssociatesProject: Lake Manitou

Page 1 of 11Report ID: S89936.01(01)Generated on 05/25/2018


General Report NotesAnalytical results relate only to the samples tested, in the condition received by the laboratory.Methods may be modified for improved performance.Results reported on a dry weight basis where applicable.'Not detected' indicates that parameter was not found at a level equal to or greater than the reporting limit (RL).40 CFR Part 136 Table II Required Containers, Preservation Techniques and Holding Times for the Clean Water Act specify that samplesfor acrolein and acrylonitrile need to be preserved at a pH in the range of 4 to 5 or if not preserved, analyzed within 3 days of sampling.QA/QC corresponding to this analytical report is a separate document with the same Merit ID reference and is available upon request.Full accreditation certificates are available upon request. Starred (*) analytes are not NELAP accredited.Samples are held by the lab for 30 days from the final report date unless a written request to hold longer is provided by the client.Report shall not be reproduced except in full, without the written approval of Merit Laboratories, Inc.Limits for drinking water samples, are listed as the MCL Limits (Maximum Contaminant Level Concentrations)

Report NarrativeThere is no additional narrative for this analytical report




Laboratory CertificationsAuthority Certification IDMichigan DEQ #9956DOD ELAP/ISO 17025 #69699WBENC #2005110032Ohio VAP #CL0002Indiana DOH #C-MI-07New York NELAC #11814North Carolina DENR #680North Carolina DOH #26702Alaska CSLAP #17-001

Qualifier DescriptionsQualifier Description! Result is outside of stated limit criteriaB Compound also found in associated method blankE Concentration exceeds calibration rangeF Analysis run outside of holding timeG Estimated result due to extraction run outside of holding timeH Sample submitted and run outside of holding timeI Matrix interference with internal standardJ Estimated value less than reporting limit, but greater than MDLL Elevated reporting limit due to low sample amountM Result reported to MDL not RDLO Analysis performed by outside laboratory. See attached report.R Preliminary resultS Surrogate recovery outside of control limitsT No correction for total solidsX Elevated reporting limit due to matrix interferenceY Elevated reporting limit due to high target concentrationb Value detected less than reporting limit, but greater than MDLe Reported value estimated due to interferencej Analyte also found in associated method blankp Benzo(b)Fluoranthene and Benzo(k)Fluoranthene integrated as one peak.x Preserved from bulk sample

Glossary of AbbreviationsAbbreviation DescriptionRL/RDL Reporting LimitMDL Method Detection LimitMS Matrix SpikeMSD Matrix Spike DuplicateSW EPA SW 846 (Soil and Wastewater) MethodsE EPA MethodsSM Standard MethodsLN LinearBR Branched




Method SummaryMethod VersionE300.0 EPA Method 300.0 Revision 2.1SM2540D Standard Method 2540 D 2011SM4500-PE Standard Method 4500 P E 2011




Sample Summary (6 samples)Sample ID Sample Tag Matrix Collected Date/TimeS89936.01 Lake Out Liquid 05/17/18 14:27S89936.02 ML In Liquid 05/17/18 13:06S89936.03 FL In Liquid 05/17/18 12:17S89936.04 HJ Down Liquid 05/17/18 10:52S89936.05 HJ In Liquid 05/17/18 11:25S89936.06 HJ Up Liquid 05/17/18 11:08




Lab Sample ID: S89936.01Sample Tag: Lake OutCollected Date/Time: 05/17/2018 14:27Matrix: LiquidCOC Reference: 110531

Sample Containers# Type Preservative(s) Refrigerated? Arrival Temp. (C) Thermometer #2 500ml Plastic None Yes 12.3 IR1 250ml Plastic H2SO4 Yes 12.3 IR

Analysis Results Units RL Method Run Date/Time Tech CAS # FlagsInorganicsNitrate-N Not detected mg/L 0.5 E300.0 05/18/18 11:55 JDP 14797-55-8Total Phosphorus 0.02 mg/L 0.01 SM4500-PE 05/24/18 13:57 MJC 7723-14-0Total Suspended Solids Not detected mg/L 3 SM2540D 05/22/18 17:15 ASB




Lab Sample ID: S89936.02Sample Tag: ML InCollected Date/Time: 05/17/2018 13:06Matrix: LiquidCOC Reference: 110531






Lab Sample ID: S89936.03Sample Tag: FL InCollected Date/Time: 05/17/2018 12:17Matrix: LiquidCOC Reference: 110531






Lab Sample ID: S89936.04Sample Tag: HJ DownCollected Date/Time: 05/17/2018 10:52Matrix: LiquidCOC Reference: 110531


Analysis Results Units RL Method Run Date/Time Tech CAS # FlagsInorganicsNitrate-N 1.1 mg/L 0.5 E300.0 05/18/18 12:33 JDP 14797-55-8Total Phosphorus 0.08 mg/L 0.01 SM4500-PE 05/24/18 14:10 MJC 7723-14-0Total Suspended Solids 3 mg/L 3 SM2540D 05/22/18 17:15 ASB




Lab Sample ID: S89936.05Sample Tag: HJ InCollected Date/Time: 05/17/2018 11:25Matrix: LiquidCOC Reference: 110531






Lab Sample ID: S89936.06Sample Tag: HJ UpCollected Date/Time: 05/17/2018 11:08Matrix: LiquidCOC Reference: 110531






Report ID: S90277.01(01)

Generated on 06/07/2018

Report to Report produced by

Attention: Josh Kieser Merit Laboratories, Inc.

Kieser & Associates 2680 East Lansing Drive

536 E. Michigan Ave. Ste 300 East Lansing, MI 48823

Kalamazoo, MI 49007

Phone: (517) 332-0167 FAX: (517) 332-6333

Phone: 269-344-7117 FAX:

Email: [email protected] Contacts for report questions:

John Laverty ([email protected])

Barbara Ball ([email protected])


Report Summary

Lab Sample ID(s): S90277.01-S90277.06

Project: Lake Manitou

Collected Date: 05/31/2018

Submitted Date/Time: 05/31/2018 09:37

Sampled by: Josh Kieser / Gabby Metzner

P.O. #:

Table of Contents

Cover Page (Page 1)

General Report Notes (Page 2)

Report Narrative (Page 2)

Laboratory Certifications (Page 3)

Qualifier Descriptions (Page 3)

Glossary of Abbreviations (Page 3)

Method Summary (Page 4)

Sample Summary (Page 5)

Maya Murshak

Technical Director




General Report Notes

Analytical results relate only to the samples tested, in the condition received by the laboratory.

Methods may be modified for improved performance.

Results reported on a dry weight basis where applicable.

'Not detected' indicates that parameter was not found at a level equal to or greater than the reporting limit (RL).

40 CFR Part 136 Table II Required Containers, Preservation Techniques and Holding Times for the Clean Water Act specify that samples

for acrolein and acrylonitrile need to be preserved at a pH in the range of 4 to 5 or if not preserved, analyzed within 3 days of sampling.

QA/QC corresponding to this analytical report is a separate document with the same Merit ID reference and is available upon request.

Full accreditation certificates are available upon request. Starred (*) analytes are not NELAP accredited.

Samples are held by the lab for 30 days from the final report date unless a written request to hold longer is provided by the client.

Report shall not be reproduced except in full, without the written approval of Merit Laboratories, Inc.

Limits for drinking water samples, are listed as the MCL Limits (Maximum Contaminant Level Concentrations)

Report Narrative

There is no additional narrative for this analytical report




Laboratory Certifications

Authority Certification ID

Michigan DEQ #9956

DOD ELAP/ISO 17025 #69699

WBENC #2005110032

Ohio VAP #CL0002

Indiana DOH #C-MI-07

New York NELAC #11814

North Carolina DENR #680

North Carolina DOH #26702

Alaska CSLAP #17-001

Qualifier Descriptions

Qualifier Description

! Result is outside of stated limit criteria

B Compound also found in associated method blank

E Concentration exceeds calibration range

F Analysis run outside of holding time

G Estimated result due to extraction run outside of holding time

H Sample submitted and run outside of holding time

I Matrix interference with internal standard

J Estimated value less than reporting limit, but greater than MDL

L Elevated reporting limit due to low sample amount

M Result reported to MDL not RDL

O Analysis performed by outside laboratory. See attached report.

R Preliminary result

S Surrogate recovery outside of control limits

T No correction for total solids

X Elevated reporting limit due to matrix interference

Y Elevated reporting limit due to high target concentration

b Value detected less than reporting limit, but greater than MDL

e Reported value estimated due to interference

j Analyte also found in associated method blank

p Benzo(b)Fluoranthene and Benzo(k)Fluoranthene integrated as one peak.

x Preserved from bulk sample

Glossary of Abbreviations

Abbreviation Description

RL/RDL Reporting Limit

MDL Method Detection Limit

MS Matrix Spike

MSD Matrix Spike Duplicate

SW EPA SW 846 (Soil and Wastewater) Methods

E EPA Methods

SM Standard Methods

LN Linear

BR Branched




Method Summary

Method Version

E300.0 EPA Method 300.0 Revision 2.1

SM2540D Standard Method 2540 D 2011

SM4500-PE Standard Method 4500 P E 2011




Sample Summary (6 samples)

Sample ID Sample Tag Matrix Collected Date/Time

S90277.01 ML In Liquid 05/31/18 08:18

S90277.02 FL In Liquid 05/31/18 08:08

S90277.03 Lake Out Liquid 05/31/18 07:57

S90277.04 HJ Up Liquid 05/31/18 07:41

S90277.05 HJ Down Liquid 05/31/18 07:31

S90277.06 HJ In Liquid 05/31/18 07:18




Lab Sample ID: S90277.01

Sample Tag: ML In

Collected Date/Time: 05/31/2018 08:18

Matrix: Liquid

COC Reference: 110540

Sample Containers

# Type Preservative(s) Refrigerated? Arrival Temp. (C) Thermometer #

2 500ml Plastic None Yes 14.6 IR

1 250ml Plastic H2SO4 Yes 14.6 IR

Analysis Results Units RL Method Run Date/Time Tech CAS # Flags

Inorganics

Nitrate-N Not detected mg/L 0.5 E300.0 05/31/18 12:11 JDP 14797-55-8

Total Phosphorus 0.03 mg/L 0.01 SM4500-PE 06/07/18 13:18 MJC 7723-14-0

Total Suspended Solids Not detected mg/L 3 SM2540D 06/01/18 18:30 ASB





Sample Tag: FL In


Matrix: Liquid


Sample Containers





Inorganics



Total Suspended Solids 4 mg/L 3 SM2540D 06/01/18 18:30 ASB





Sample Tag: Lake Out


Matrix: Liquid


Sample Containers





Inorganics








Sample Tag: HJ Up


Matrix: Liquid


Sample Containers





Inorganics

Nitrate-N 1.9 mg/L 0.5 E300.0 05/31/18 12:50 JDP 14797-55-8







Sample Tag: HJ Down


Matrix: Liquid


Sample Containers





Inorganics








Sample Tag: HJ In


Matrix: Liquid


Sample Containers





Inorganics







Report ID: S92695.01(01)






Kalamazoo, MI 49007

Phone: (517) 332-0167 FAX: (517) 332-6333

Phone: 269-344-7117 FAX:





Report Summary

Lab Sample ID(s): S92695.01-S92695.07

Project: Manitou Lake



Sampled by: John Kieser

P.O. #:

Table of Contents

Cover Page (Page 1)








Maya Murshak

Technical Director

Report to Kieser & AssociatesProject: Manitou Lake















Report Narrative







Michigan DEQ #9956


WBENC #2005110032

Ohio VAP #CL0002

































MS Matrix Spike



E EPA Methods

SM Standard Methods

LN Linear

BR Branched




Method Summary

Method Version









S92695.01 HJ Up Liquid 08/06/18 16:30

S92695.02 HJ Down Liquid 08/06/18 16:43

S92695.03 HJ In Liquid 08/06/18 16:54

S92695.04 Lake Out Liquid 08/06/18 17:02

S92695.05 ML In Liquid 08/06/18 16:10

S92695.06 FL In Liquid 08/06/18 16:20

S92695.07 HJ In-1F Liquid 08/06/18 11:30





Sample Tag: HJ Up


Matrix: Liquid


Sample Containers




Inorganics

Method: E300.0, Run Date: 08/08/18 11:15, Analyst: JDP

Parameter Result RL MDL Units Dilution CAS# Flags

Nitrate-N Not detected 0.5 0.04 mg/L 5 14797-55-8

Method: SM2540D, Run Date: 08/08/18 14:15, Analyst: DEP


Total Suspended Solids 22 3 mg/L 1

Method: SM4500-PE, Run Date: 08/10/18 12:57, Analyst: MJC


Total Phosphorus 0.14 0.01 0.004 mg/L 1 7723-14-0





Sample Tag: HJ Down


Matrix: Liquid


Sample Containers




Inorganics














Sample Tag: HJ In


Matrix: Liquid


Sample Containers




Inorganics



Nitrate-N 1.2 0.5 0.04 mg/L 5 14797-55-8













Matrix: Liquid


Sample Containers




Inorganics






Total Suspended Solids Not detected 3 mg/L 1








Sample Tag: ML In


Matrix: Liquid


Sample Containers




Inorganics














Sample Tag: FL In


Matrix: Liquid


Sample Containers




Inorganics














Sample Tag: HJ In-1F


Matrix: Liquid


Sample Containers




Inorganics









Merit Laboratories Login Checklist

Login User:

Lab Set ID:

Project:

S92695

Manitou Lake

SRS

Attention: Josh KieserAddress: Kieser & Associates

536 E. Michigan Ave. Ste 300Kalamazoo, MI 49007

Phone: 269-344-7117 FAX:Email:[email protected]

NoteDescription

Client:KIESER (Kieser & Associates)

Selection

Submitted:08/07/2018 16:10

Sample Receiving

Samples are received at 4C +/- 2C Thermometer # IR 4.9Yes No N/AX01.

Received on ice/ cooling process begunYes No N/AX02.

Samples shippedYes No N/AX03.

Samples left in 24 hr. drop boxYes No N/AX04.

Are there custody seals/tape or is the drop box lockedYes No N/AX05.

Chain of Custody

COC adequately filled outYes No N/AX06.

COC signed and relinquished to the labYes No N/AX07.

Sample tag on bottles match COCYes No N/AX08.

Subcontracting needed? Subcontacted to:Yes No N/AX09.

Preservation

Do sample have correct chemical preservationYes No N/AX10.

Completed pH checks on preserved samples? (no VOAs)Yes No N/AX11.

Did any samples need to be preserved in the lab?Yes No N/AX12.

Bottle Conditions

All bottles intactYes No N/AX13.

Appropriate analytical bottles are usedYes No N/AX14.

Merit bottles usedYes No N/AX15.

Sufficient sample volume receivedYes No N/AX16.

Samples require laboratory filtrationYes No N/AX17.

Samples submitted within holding timeYes No N/AX18.

Do water VOC or TOX bottles contain headspaceYes No N/AX19.

Corrective action for all exceptions is to call the client and to notify the project manager.

Client Review By: Date:

Page 1 of 1 Prepared by Merit Laboratories

Merit Laboratories Bottle Preservation Check

Lab ID

pH

<2 >12 otherml

pH Notesnew

add

125 ml

HNO

Plastic

3

125 ml

NaOH

Plastic

125 ml

Amber

250 ml

Plastic

32 oz

HCl

Glass

SOH2 4SOH2 4

250 ml

Plastic

125 ml

PbCOAmber

3NaOH

Lab Set ID:

Project:

S92695

Manitou Lake




Client: KIESER (Kieser & Associates)

Login User:Submitted: 08/07/2018 16:10

Initials:

HNO3

1 L

Plastic

HNO3

SRS

S92695.01 X X

S92695.02 X X

S92695.03 X X

S92695.04 X X

S92695.05 X X

S92695.06 X X

S92695.07 X X



Report ID: S92774.01(01)



Attention: Fred Farkas Merit Laboratories, Inc.

Lake Manitou Association 2680 East Lansing Drive

PO Box 61 East Lansing, MI 48823

Owosso, MI 48867

Phone: (517) 332-0167 FAX: (517) 332-6333

Phone: 734-417-1276 FAX:




Report Summary

Lab Sample ID(s): S92774.01-S92774.04


Collected Date: 08/06/2018 - 08/08/2018


Sampled by: Fred Farkas

P.O. #:

Table of Contents

Cover Page (Page 1)








Maya Murshak

Technical Director

Report to Lake Manitou AssociationProject: Lake Manitou















Report Narrative







Michigan DEQ #9956


WBENC #2005110032

Ohio VAP #CL0002

































MS Matrix Spike



E EPA Methods

SM Standard Methods

LN Linear

BR Branched




Method Summary

Method Version








S92774.01 Hardy Jennings Drain Inlet to Lake Manitou #1 Liquid 08/06/18 09:30








Sample Tag: Hardy Jennings Drain Inlet to Lake Manitou #1


Matrix: Liquid


Sample Containers



Inorganics










Matrix: Liquid


Sample Containers



Inorganics







Login User:

Lab Set ID:

Project:

S92774

Lake Manitou

SRS

Attention: Fred FarkasAddress: Lake Manitou Association

PO Box 61Owosso, MI 48867

Phone: 734-417-1276 FAX:Email: [email protected]

NoteDescription

Client:LAKEMANITOU (Lake Manitou Association)

Selection

Submitted:08/09/2018 13:17

Sample Receiving






Chain of Custody





Preservation




Bottle Conditions












Lab ID

pH

<2 >12 otherml

pH Notesnew

add

125 ml

HNO

Plastic

3

125 ml

NaOH

Plastic

125 ml

Amber

250 ml

Plastic

32 oz

HCl

Glass

SOH2 4SOH2 4

250 ml

Plastic

125 ml

PbCOAmber

3NaOH

Lab Set ID:

Project:

S92774

Lake Manitou

Attention: Fred FarkasAddress: Lake Manitou Association

PO Box 61Owosso, MI 48867

Phone: 734-417-1276 FAX:Email: [email protected]

Client: LAKEMANITOU (Lake Manitou Association)


Initials:

HNO3

1 L

Plastic

HNO3

SRS

S92774.01 X X

S92774.03 X X



Report ID: S93711.01(01)






Kalamazoo, MI 49007

Phone: (517) 332-0167 FAX: (517) 332-6333

Phone: 269-344-7117 FAX:





Report Summary

Lab Sample ID(s): S93711.01-S93711.05

Project: Manitou



Sampled by: John Kieser

P.O. #:

Table of Contents

Cover Page (Page 1)








Maya Murshak

Technical Director

Report to Kieser & AssociatesProject: Manitou















Report Narrative







Michigan DEQ #9956


WBENC #2005110032

Ohio VAP #CL0002

































MS Matrix Spike



E EPA Methods

SM Standard Methods

LN Linear

BR Branched




Method Summary

Method Version

Calculation Calculation


SM2320B Standard Method 2320 B 2011


SM4500-N(org)/NH Standard Method 4500 N(org)B / NH3D 2011







S93711.01 HJ - In Liquid 08/29/18 09:40

S93711.02 MID (S) Liquid 08/29/18 11:05

S93711.03 MID (B) Liquid 08/29/18 11:08

S93711.04 DEEP (S) Liquid 08/29/18 11:40

S93711.05 DEEP (B) Liquid 08/29/18 11:45





Sample Tag: HJ - In


Matrix: Liquid


Sample Containers




Inorganics



Nitrate-N 1.0 0.5 0.04 mg/L 5 14797-55-8

Method: SM2540D, Run Date: 08/31/18 15:30, Analyst: ASB










Sample Tag: MID (S)


Matrix: Liquid


Sample Containers




Inorganics

Method: Calculation, Run Date: 08/30/18 10:26, Analyst: MJC


Total Nitrogen* 0.6 mg/L 1



Chloride 17 5 0.26 mg/L 5 16887-00-6


Nitrite-N Not detected 0.5 0.03 mg/L 5 14797-65-0

Method: SM2320B, Run Date: 08/29/18 14:22, Analyst: JKB


Alkalinity as CaCO3 144 2 mg/L 2

Method: SM4500-N(org)/NH, Run Date: 08/29/18 22:49, Analyst: MJC


Total Kjeldahl Nitrogen 0.6 0.1 mg/L 1








Sample Tag: MID (B)


Matrix: Liquid


Sample Containers




Inorganics






Chloride 17 5 0.26 mg/L 5 16887-00-6
















Sample Tag: DEEP (S)


Matrix: Liquid


Sample Containers




Inorganics






Chloride 17 5 0.26 mg/L 5 16887-00-6
















Sample Tag: DEEP (B)


Matrix: Liquid


Sample Containers




Inorganics






Chloride 18 5 0.26 mg/L 5 16887-00-6















Login User:

Lab Set ID:

Project:

S93711

Manitou

MMC




NoteDescription


Selection

Submitted:08/29/2018 13:30

Sample Receiving






Chain of Custody





Preservation




Bottle Conditions












Lab ID

pH

<2 >12 otherml

pH Notesnew

add

125 ml

HNO

Plastic

3

125 ml

NaOH

Plastic

125 ml

Amber

250 ml

Plastic

32 oz

HCl

Glass

SOH2 4SOH2 4

250 ml

Plastic

125 ml

PbCOAmber

3NaOH

Lab Set ID:

Project:

S93711

Manitou






Initials:

HNO3

1 L

Plastic

HNO3

MMC

S93711.01 X X

S93711.02 X X

S93711.03 X X

S93711.04 X X

S93711.05 X X



Report ID: S94943.01(01)






Kalamazoo, MI 49007

Phone: (517) 332-0167 FAX: (517) 332-6333

Phone: 269-344-7117 FAX:





Report Summary

Lab Sample ID(s): S94943.01-S94943.12


Collected Date: 09/30/2018 - 10/01/2018


Sampled by: Unknown

P.O. #:

Table of Contents

Cover Page (Page 1)








Maya Murshak

Technical Director
















Report Narrative







Michigan DEQ #9956


WBENC #2005110032

Ohio VAP #CL0002

































MS Matrix Spike



E EPA Methods

SM Standard Methods

LN Linear

BR Branched




Method Summary

Method Version





SW3050B SW 846 Method 3050B Revision 2 December 1996

SW6020A SW 846 Method 6020A Revision 1 February 2007






S94943.01 HJ-IN 0 Liquid 09/30/18 09:45

S94943.02 HJ-IN Liquid 10/01/18 07:15

S94943.03 HJ-IN 2 Liquid 10/01/18 09:50

S94943.04 HJ-Up Liquid 10/01/18 07:42

S94943.05 HJ-Up 2 Liquid 10/01/18 10:10

S94943.06 HJ-Down Liquid 10/01/18 07:30

S94943.07 HJ-Down 2 Liquid 10/01/18 10:00

S94943.08 ML-IN Liquid 10/01/18 08:05

S94943.09 FL-IN Liquid 10/01/18 07:55

S94943.10 Lake Out Liquid 10/01/18 08:40

S94943.11 Deep Solid 10/01/18 08:50

S94943.12 MID Solid 10/01/18 09:00





Sample Tag: HJ-IN 0


Matrix: Liquid


Sample Containers




Inorganics



Nitrate-N 1.1 0.5 0.04 mg/L 5 14797-55-8











Sample Tag: HJ-IN


Matrix: Liquid


Sample Containers




Inorganics



Nitrate-N 1.1 0.5 0.04 mg/L 5 14797-55-8











Sample Tag: HJ-IN 2


Matrix: Liquid


Sample Containers




Inorganics



Nitrate-N 1.2 0.5 0.04 mg/L 5 14797-55-8











Sample Tag: HJ-Up


Matrix: Liquid


Sample Containers




Inorganics



Nitrate-N 0.6 0.5 0.04 mg/L 5 14797-55-8











Sample Tag: HJ-Up 2


Matrix: Liquid


Sample Containers




Inorganics



Nitrate-N 1.3 0.5 0.04 mg/L 5 14797-55-8











Sample Tag: HJ-Down


Matrix: Liquid


Sample Containers




Inorganics



Nitrate-N 1.4 0.5 0.04 mg/L 5 14797-55-8











Sample Tag: HJ-Down 2


Matrix: Liquid


Sample Containers




Inorganics



Nitrate-N 2.0 0.5 0.04 mg/L 5 14797-55-8











Sample Tag: ML-IN


Matrix: Liquid


Sample Containers




Inorganics














Sample Tag: FL-IN


Matrix: Liquid


Sample Containers




Inorganics
















Matrix: Liquid


Sample Containers




Inorganics














Sample Tag: Deep


Matrix: Solid


Sample Containers


1 8oz Glass None Yes 5.8 IR

Extraction / Prep.

Parameter Result Method Run Date Analyst Flags

Metal Digestion Completed SW3050B 10/05/18 09:30 JRH

Inorganics

Method: SM2540B, Run Date: 10/01/18 16:30, Analyst: JBL


Total Solids* 21 1 1 % 1



Total Phosphorus* 569 1 mg/kg 1 7723-14-0

Metals

Method: SW6020A, Run Date: 10/05/18 13:50, Analyst: JRH


Iron 19,700 1.0 mg/kg 912 7439-89-6





Sample Tag: MID


Matrix: Solid


Sample Containers



Extraction / Prep.



Inorganics







Metals



Iron 20,000 1.0 mg/kg 950 7439-89-6




Login User:

Lab Set ID:

Project:

S94943

Lake Manitou

SRS




NoteDescription


Selection

Submitted:10/01/2018 11:15

Sample Receiving






Chain of Custody





Preservation




Bottle Conditions












Lab ID

pH

<2 >12 otherml

pH Notesnew

add

125 ml

HNO

Plastic

3

125 ml

NaOH

Plastic

125 ml

Amber

250 ml

Plastic

32 oz

HCl

Glass

SOH2 4SOH2 4

250 ml

Plastic

125 ml

PbCOAmber

3NaOH

Lab Set ID:

Project:

S94943

Lake Manitou






Initials:

HNO3

1 L

Plastic

HNO3

SRS

S94943.01 X X

S94943.02 X X

S94943.03 X X

S94943.04 X X

S94943.05 X X

S94943.06 X X

S94943.07 X X

S94943.08 X X

S94943.09 X X

S94943.10 X X
