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ChE 384T / 323 Lecture 15 Chemical Engineering for Micro/Nano Fabrication

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Page 1: Lecture 15 - University of Texas at Austinwillson.cm.utexas.edu/Teaching/LithoClass2017/Files/Lecture 15 2017.pdfLecture 15 Chemical Engineering for Micro/Nano Fabrication. ChE 384T

ChE 384T / 323

Lecture 15Chemical Engineering for Micro/Nano Fabrication

Page 2: Lecture 15 - University of Texas at Austinwillson.cm.utexas.edu/Teaching/LithoClass2017/Files/Lecture 15 2017.pdfLecture 15 Chemical Engineering for Micro/Nano Fabrication. ChE 384T

ChE 384T / 323 W. Hinsberg, IBM

Polymer Permability

Page 3: Lecture 15 - University of Texas at Austinwillson.cm.utexas.edu/Teaching/LithoClass2017/Files/Lecture 15 2017.pdfLecture 15 Chemical Engineering for Micro/Nano Fabrication. ChE 384T

ChE 384T / 323 W.D. Hinsberg, et.al. IBM, Almaden

Page 4: Lecture 15 - University of Texas at Austinwillson.cm.utexas.edu/Teaching/LithoClass2017/Files/Lecture 15 2017.pdfLecture 15 Chemical Engineering for Micro/Nano Fabrication. ChE 384T

ChE 384T / 323

Page 5: Lecture 15 - University of Texas at Austinwillson.cm.utexas.edu/Teaching/LithoClass2017/Files/Lecture 15 2017.pdfLecture 15 Chemical Engineering for Micro/Nano Fabrication. ChE 384T

ChE 384T / 323

Page 6: Lecture 15 - University of Texas at Austinwillson.cm.utexas.edu/Teaching/LithoClass2017/Files/Lecture 15 2017.pdfLecture 15 Chemical Engineering for Micro/Nano Fabrication. ChE 384T

ChE 384T / 323

Page 7: Lecture 15 - University of Texas at Austinwillson.cm.utexas.edu/Teaching/LithoClass2017/Files/Lecture 15 2017.pdfLecture 15 Chemical Engineering for Micro/Nano Fabrication. ChE 384T

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Page 8: Lecture 15 - University of Texas at Austinwillson.cm.utexas.edu/Teaching/LithoClass2017/Files/Lecture 15 2017.pdfLecture 15 Chemical Engineering for Micro/Nano Fabrication. ChE 384T

ChE 384T / 323 Hiroshi Ito, IBM

Thermogravimetric analysis

Page 9: Lecture 15 - University of Texas at Austinwillson.cm.utexas.edu/Teaching/LithoClass2017/Files/Lecture 15 2017.pdfLecture 15 Chemical Engineering for Micro/Nano Fabrication. ChE 384T

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Page 10: Lecture 15 - University of Texas at Austinwillson.cm.utexas.edu/Teaching/LithoClass2017/Files/Lecture 15 2017.pdfLecture 15 Chemical Engineering for Micro/Nano Fabrication. ChE 384T

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Effects of filtered air (top) and 10ppb NMP (bottom) on positive images printed in the meta- (left) and para- (right) P(HOST-co-BOCST) resists.

Page 11: Lecture 15 - University of Texas at Austinwillson.cm.utexas.edu/Teaching/LithoClass2017/Files/Lecture 15 2017.pdfLecture 15 Chemical Engineering for Micro/Nano Fabrication. ChE 384T

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Page 12: Lecture 15 - University of Texas at Austinwillson.cm.utexas.edu/Teaching/LithoClass2017/Files/Lecture 15 2017.pdfLecture 15 Chemical Engineering for Micro/Nano Fabrication. ChE 384T

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The “Family”

Page 13: Lecture 15 - University of Texas at Austinwillson.cm.utexas.edu/Teaching/LithoClass2017/Files/Lecture 15 2017.pdfLecture 15 Chemical Engineering for Micro/Nano Fabrication. ChE 384T

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ESCAP

• Acrylic reduces solubility of NMP

• Acrylic ester more thermally stable than the t-butyl carbonate

• Enables post apply bake Temp > Tg

• Bake > Tg decreases permeance

*

*

OO

Hiroshi Ito

Page 14: Lecture 15 - University of Texas at Austinwillson.cm.utexas.edu/Teaching/LithoClass2017/Files/Lecture 15 2017.pdfLecture 15 Chemical Engineering for Micro/Nano Fabrication. ChE 384T

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IBM Mainframe Circuit Board

one of 20 layers printed circuit board that contained nearly a

mile of wire interconnections used in IBM Mainframes.

Page 15: Lecture 15 - University of Texas at Austinwillson.cm.utexas.edu/Teaching/LithoClass2017/Files/Lecture 15 2017.pdfLecture 15 Chemical Engineering for Micro/Nano Fabrication. ChE 384T

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SU-8 Negative Resist

Page 16: Lecture 15 - University of Texas at Austinwillson.cm.utexas.edu/Teaching/LithoClass2017/Files/Lecture 15 2017.pdfLecture 15 Chemical Engineering for Micro/Nano Fabrication. ChE 384T

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IBM CGR Negative Resist

*

*

OH

PAG

Page 17: Lecture 15 - University of Texas at Austinwillson.cm.utexas.edu/Teaching/LithoClass2017/Files/Lecture 15 2017.pdfLecture 15 Chemical Engineering for Micro/Nano Fabrication. ChE 384T

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Page 18: Lecture 15 - University of Texas at Austinwillson.cm.utexas.edu/Teaching/LithoClass2017/Files/Lecture 15 2017.pdfLecture 15 Chemical Engineering for Micro/Nano Fabrication. ChE 384T

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Page 19: Lecture 15 - University of Texas at Austinwillson.cm.utexas.edu/Teaching/LithoClass2017/Files/Lecture 15 2017.pdfLecture 15 Chemical Engineering for Micro/Nano Fabrication. ChE 384T

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Entergris, Inc

Air purification system