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PtmiddotUNITED STATES ENVIRONMENTAL PROTECTION AGENCY ) middot
lGIONI middot1middotmiddot-JJ XINNIOY ftOliiAL IUIL DING IOITON MAIIACHUHnl a203-zt11 ~middotlt-
March 8 1989
Mr ancS Mra Roqer Pinette Gardner Creek Road (aka Wade Road) Washburn HE 04786
Dear Mr and Hra Pinette
Aa you are aware the us Environmental Protection Agency (EPA) in concert with the Maine Department of Environmental Protection (DEP) collected drinking water aamplea froa your residence on January 11 1989 Theae samples were returned to a certitied EPA laboratory and analyzed tor volatile organic pri ority pollutants especially including the capound t e trachloroethane which waa detected at 7 parts per billion (ppb) in your vall back in June 1988
Baaed upon the reaulta received froa thb aore recent analyaia we are able to r eport that none of theae cobullpounda ( inclucUncJ tetrachloroethane) we re detected in your drinking water [aa denoted by the blank (--) apacea throughout the coluana on the enclobulled data _eetbull1middot
I have enclobulled a copy of the analytical data aheetbull generated by our laboratory on your drinking water If you have any quea tiona regarding this letter or the enclobulled analytical data feel free to call bulle at (617) 573-5786
Sincerely
rJi~ middot Pinettebullbull Site Remedial Projec t Manager
ENCLOSURE
cc cynthia Kuhns Rebecca Hewitt State of Maine (with enclosure)
---------- t bullLl ltshy
MgtV f WlSTONINC tAHOMAAKONE ONl VAA DE GRMff DRIVE IURLWGTOH MA-011103 11171221middot2050 February 3 1989
Mr Dennia GagneRegional sample Control cuatodian u s Environmental Protection Agency 90 canal street Beaton ~aaaachuaetta 02114
Re TID No 01-88-1202 site Pinettebull Salvage Yard SAS No 4385A Laboratory Reaource Analyat Inc Method tjwater52 4 1
Dear Mr Gagne
A validation waa perforaed on the organic analytical data for BAS No 4385A drinking water analya ia collected for Michael Jaainaky of the Environmental Protection Agency at the Pinettebull Salvage Yard aite The data waa evaluated baaed on the following paraaetera
o data completeneaa o holding tiaea o GCMS tuning o calibration o blanka o aurrogate recoverbullbull o matrix apike r ecove rbullbull o field duplicate r eaulta o i nternal atandard perforance o compound identification o compound quantitation
- All criteria were met f or thia parameter
Table I augorizea the yalidation recommendations which were based on the following intornotion
pata compltteneal
The laboratory did not initially aubmit all the raw data necesaary to perform the validation The laboratory was contacted and some raw data was submitted The laboratory did not submit the data pertaining to the laboratory method detection limit study They were contacted to verify one had been done but they were not requested to submit one at this time
Mr Gagne February 3 1~89 Page TWo
OC MI 2Upln q
The aasbull libullting wabull not provided for the bromotluorobenzene tune The instrumental printout ot the EPA Forw V with the 11aaa apectrw1 waa provided thia wabull bullutticient to verity the tuning criteriamiddot were 11et
Cal i bratiop
Chloro11ethane vinyl Chloride 1 2-Dibroa o-3-chloropropane 1 2 3-Trichlorobenzene
OM
~~ ~ _ IC cc Mr ltltl=ll=ll l=ll=ll
X 0-lt X + X Olgt
00 X
All 4385A-Ol - 4385A-04
x - Percent RSD gt30 Perce nt D gt25 Estimate (J) all poaitive reaulta
+ -iF RF lt0051 Eatiaate (J) all pobullitive reaulta and reject (R) all non-detecta
There waa anothe r problea which waa noted tor the initial curve which waa aubbull itted The 5ppb standard waa not analyzed on 1-16-89 the day the r est of the curve waa analyzed It was analyzed 1-17-89 a fte r the daily continuing calibration standard was analyzed Thia ia not the correct sequence t or an initi al cal ibration but the data will be ac cepted a bull it ia The raw data wabull not s ubmi tted tor each i nitial c a libr ation bull tandar d Tha raw data vaa aub11ittad t or the ~ontinuinq calibrati on atandard on l -17-89 The calculation of the r e lative r esponse f act ors a nd the report i ng of the factors with t ha percent differences were ver ified t or t he cont inuing cal ibration a nd were correctly r eport ed
Mr Gaqne February 3 J989 Page Three
coapound Jdtptificatiop
The apectra were not provided for the poaitive reaulte found in the method blankbull There were no compound a reported in the aamplee The data wae accepted 111 it waa preaented
MaximWl Concentration Action Level uq1
Methylene Chloride Chloroforw
2 8 bull 39
14 2 0
Blank Actione
o value lt action level J report value followed by a U
o value gt action level I report the value unqualified
very truly youre
ROY 1 WESTON INC
middot~ Vic1ti Howe ll Environaental Chebullibullt
Q_ yj77a~ Joeeph D Maatone
ESAT Team Manaqer Reqion I
VHVh Encloauree ec D szaro
Pinettebullbull Salvage Yard SAS No 4J85A
Table I - Recommendation summary
SAS No 5241
4385A-Ol A
4385A-02 A
4385A-03 A
4385A-04 A
A - Accept all data
OM ltZ Ml1 Z-lt M-lt Mr ltlt
Gl n-lt Olgt
00
A - Acceptable data
J - The aaaociated nuaerical value h an eatiaated quantit7
R - Reject data due to quality control criteria The data are unuaable (coapound bullbullY or aay not be preaent) Reaaaplinamp and reanalyaia ia neceaaary tor verification
U - The eoapound waa analyzed tor but waa not de tected The aaaociated nuaerica l value h the aaaple quantitati on Uait
UJ - The coapound waa analysed tor but waa not detected The aaaple quantitation Uait ia an eatiaated quantity
- The eoapound waa analysed tor but waa not detected The aaaple quant1tat1on liait ia the aaae aa the CRQL preaented
i 8 N
--
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REGION I Site Name f~ tJ middot~ $1 VdData Review Workaheeta Reference Number
REGION I REVIEW OP ORGANIC CONTRACT lABORATORY DATA PACJtAGB
rbullbull The hardeopied (laboratory name) eM bull u~ftmiddotLi data package received at Region I haa been reviewed and the qual ty aaurance and performancedata ampWIIlllarhed The data review included1
Caae No ~ SU No~ Saaplinq Date(a) l middot tlmiddottbull SDG No -btUeL Matrix ~ Shippinq Date(a) l middot u middotbulls No of Samp~ea__l_ ~d ~l~ 1 Date Recd by Lab ------ -- shy
Traffic Report Noa j~1SA- ol MSA -oa 01 1UU-oot
Trip Blank No Equipbullent Blank lfot Pield Dup Noe l
sow No requirebull that apecific analytical work be done and that aaaoclated reportbull be provided by the laboratory to the Reqiona EMSL-LV and ampMO The qeneral criteria uaed to deterwine the perfonance were baaed on an exabullination ofa
-Data Cobullpleteneaa -Matrix SpikeMatrix Spike Dup-HoldiiiCJ TiHe -Pield Duplicatebull -GCMS Tuni119 -Internal Standard Perfo1111ance -calibrationa -Peaticide Inat Perforaance -BlanJta -compound Identification -surroqate Recoveriea -co11pound Quantitation
OVerall couenta shyIIIMJ dW k b ~ bull8
Definitionbull and Qualifiera ~ A - Acceptable data J - Approximate data due to quality control criteria R - Reject data due to quality control criteria V - Compound not detected middotmiddot
u middot ff
Reviewerbull _____v_-~=J4==lt----- Date _ __1_-_~___r____ middot
REGION I Data Revev Workahebulltbull
I DATA COMPLETENESS
MISSING INFORMATION DATE LlB CONTAkiED DATE RECbullp
11 pound100lt db sJ_ rnA A t1tz -6_ iJiiuob J 41 rIbull-Jb bY- bull 1 ltbull+W Je cJw NAP emzht1i-rJ ~ 6YcfplciJl s9bW middot ttryy cJp -1 middot1middot
--- ------------
______
----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- ------- ----- ----- ------ ------ --------- ------- ----- ----- ------ ----- ------
REGION I Data Review Workaheeta
II HOLDING TIMES Complete table for all aa1r1plea and circle the fract ionbull which are not within criteria middot
VOA BNA PEST SAMPLE DATE DATE DATE
ID SAMPLED ANAL EXTR
~~AmiddotDI ~~---
~~UA middot6bull plusmn ~ NA
~~1-A middotCS l-11middottbull NA
~nsH~ ________ I-IH1 ~
DATE DATE ANAL EXTR
DATE ANAL
~ ~
-
~
VOA - Unpreaervedt Aromatic within 7 daya non-aromatic within 14 daya of aample collection Preaerved t Both within 14 daya of aample collection Soila t Both within 14 daya of bullbullbullple collection
BNA PEST - Extracted within 7 daya analyzed within 40 daya aoih ancS water
ACTION t 1 If holding timea are exceeded all poaitive results are eatimate
(J) and non-detecta are eatimated (UJ) 2 middotIf holding timea are groaaly exceeded the reviewer may
determine that non-detecta are unusable(bull)
-bull8 N
REGION 1 Data Review Workaheeta
111 CCfMS IUMINC
The DFTPP pertor111ance reaulta were reviewed and found to be within the apecifia4 criteria
If no lgtllOMSabullplaa affected____________________ ltZ ~ z-o ~ -oltlTha BFB performance raaulta ware raviawad and found to be within
the apacifiad criteria ~rIr no ltlt Sabullplaa affactacl____________________ 0-lt Olgt
00If aaaa calibration ia in error refer to tha Raion quidalinaa for expanded criteria If nacaaaary all aaaociatad data bullbull unuaabla (R)
cw ~ v-h H ~ ~ -+- W-4
fv H -t ~ ~middottp tJJ-- -6-- JAl s-IJ~ li lthi
o 1-n-H -Ht L~S s+-JJ ~1f- ~ ltIL __ -14 ltkgt c--1 11-Lf vltuv-1 ~ ~ -n ~ ~t-1~ ~ ~ -6v -~middotc_d ~ dG lwiW ~ -~-
fv-u middot~ _t~~~ ~
~ b jlu e I -1shymiddotmiddotmiddotmiddot middot middot~ w- -Hulmiddot11middot fl ~ -u ~ ~-tgt REGIOH I Data Review Worksheetbull ZV A VOLATILE CALIBRATION VERIPICATlOII
~
Data of Initial Calibration bulltmiddot~middot~middot~middotf~B~middotmiddotDatea of ContinuinCjJ Calibrationbull r- y1 Instrument ID 1 MatrixLevel 1 f of f llvJ
CRITERIA OUT ~ YWW RFtRSDRFtD middot eigtD cJb Ky ( )
Saaplaa Affected
ollSIgt --l dQJoL1botngtJngtbullcmiddot~3i~bullJdolkOCltJbullIjwlgtllflopound4tNL-j~yeni~Cl1Lmiddot middot ~middotlliJ)LSamplebull Affected -- - bull
Rf -~~~l~-D~kwmd~~~3~middot~Yl+n~~~~~~~L_~r~~~~~middot~)L_____Samplaa Affected
s bullbull~~ Atfected-liJlJlmiddot--rubullCLocltcUnllbulllpllth~~r~-+(~middot~__)J~----
Saaplaa Affactad------------------- shy
saaplaa Affactadlmiddot-------------------
Samplaa Affactach
Samplebull Affected IISmiddotDmiddot ckJnbull~
1 All iFbulla and RF 1a muat be gt005 ~~~~ ~ bull 333 2 All RSD 1a bulluat belt30 3 All D 1 a bulluat be lt25 gt+gt~
11~111 _lg_a zDSI ACTIOMI ~ If 10 1 If any compound haa an initial RF or a continuing RF of lt005
a Flag podtive r eaulta for that compound aa eatimated (J) bFlag non-detectbull for that compound as unusable (R) bull
2 If any compound has a RSD gt30 or a D gt25 aFlag positive results for that cornpound as estimated (J) b Flag non-detecta for that compound as estimated (UJ) if the RSO
or D ia gt50
A separate worksheet should be filled out for each initial curve
I I I I
REGION J Data Review Worksheets
JV I SEMIVOITILE CALIBRATION VERIFICATION
Date of Initial Calibration -====== Dataa of Continuin9 Calibrations~ tnatruaant ID ______
llW C2lli2l1llllCRITERIA OUT RFRSDRF0
Saaplaa Affected
Samples Affected
Saaplaa Affected
Saaplaa Affected
Saaplaa Affected
Saaplaa Affectach
Sabull plaa Affected
Saaplaa AffeCted
samples Affected
Saaplaa Affacta4
Samplaa Affactada
bull-8 N
Saaplea Affactadt
samples Afflctach
Samples Affected
Sea worksheet IV-A for criteria and actions
A new worksheet should be filled out for each initial curve
iluHot CAhv~ Z~H) bull ~~ bull z f o 1~1 t1C
REGION I Data Jteviev Worksheet
V A 111NK ANALYSIS RESULTS (Soctiono 1 2)
Liat the contamination in the blanka belov
1 Laboratory Bllnka
CONCENTftATIOM
lll1Ii
middota 1lt
2 Equipment and Trip Blanka CONCENTRAT ION[
lll1Ii shybull8 N
A separate worksheet should be used for low and media level blanks
REGION I DAtA Review Worksheets
V I BIAHJt ANALYSIS RESULTS (Section 3)
l BlAnk Actionbull
Action levelbull ahould be baeed upon the higheet concentration of contAIIinant determined in Any bhnk The Action level for aamplea vhich have been concentrAted or diluted ahould be bullultipUed by the concentrationdilution fActor No poaitive aample result ahould be reported unlaas the concentrAtion of the compound in the sAmple axceede the Action laval of 10 x a the Amount in the blAnk for the couon contAainAnta or 5 x a the aaount for any other compound Specific act i ona are bullbull follovaz
1 The c oncentr ation is l esa t han the CRQL repor t the CRQL
2 The concent r at i on i s 9reater than the CRQL but l eea than the act i on level r eport the c oncentration found u
3 The concentration Ja greater than the action level r eport the concentration unqualified
For exaaplea refer to the Regional Cuidelinea
Couon contaa inanta bull aethylene chloride acetone 2-butanone tolueneand phthalatea
MbX CONC ACTION LEVEL l1liUI l1liUI
bull middot )IQ
A aeparat~ vorksheet should be used for low and medium level blanka
-bull8 N
REGION I Data Review Workaheata
VI SURROGATE SPIKB RECOVERIU
Liat the percent racovariaa which do not bullbullbullt the criteria for aurrogata recovery
Au _-u ~ q-- 110 bull bullbull middot Matrixbull~
mJI_ TOL JIFB pep HBZ FBP TPH fHL 2PP TBP
to to to to to to to to to to
Surrogate Actiona PERCENT RECOVERY
~ ~ ~ Positive sample raaulta J J J Non-detected results R UJ A
CRR bull Contract Required Recovery Range Surrogate action should be applied
1 bull If at least two aurroatea in a BN or A fraction or one surrogate in the VOA fraction are out of specification but have recoveries of gt10
2 If any one surrogate in a fraction ahova lt10 recovery
REGION I Data Review Worksheets
fgt-100
VII A MATRIX SPIKEMATRIX SPIJa DUPLICATE
1 Matrix SpikeHatrix Spike Duplicate Recoveriea and Precision
lR )loa___ ___ lAveli~ Matrix1
List the tgtbullrcent recovariea and RPDa of coapounda whi ch do not aeet the criteriamiddot atated on Fotll J
bull-8
QUALIFICATION IS LIMITED TO THE UNSPIXED SAMPLE ONLY N 1 If any compound doea not aeet the Contraet Required Recovery range
(CRR) follow the actions stated belovt
PERCENT RECOVERY
~ ~ Poaitiva Sample Reaulta J J Non-detected Results R A
2 If any compound does not meet the RPD criteria flag positive reaulta tor that compound a a estimated (J)
A aeparate worksheet should be used for each MSMSD pair
REGION I Data Review Workaheeta Vll B MATRIX SPliCEMATRIX SPliCE DUPLICATE (Section 2)
3 Matrix Spike Duplicate - UnapUted compoundbull
TR Nos ___ ---
Liat the concentrations of the unspiked compounds and determine the percent RSDbull of the unapiked aample Jiatrix spike and matrix spike duplicate No Uaita have been developed for the RSD valuea of the unapUced compounda
SN1PLpound MS MSp CQNC
8 N
The reviewer auat uaa profeaaional judgement to datenina if there ia a need to qualify any of the unspiked compounds in the sample
REGION I Data Review Workaheeta
VIII PIELD DUPLICATE PRECISION
TR Noa___ --- Matrixamp___
Liat the concentrationbull of the compounda which do not bullbullbullt the followinc RPD criteriat middot
1 middot An RPD of lt30 for water duplicatea 2 An RPD of lt50 for aoil duplicatea
SAJ1PL CONC pup SAMPLE CONC
ACTIONS I
1 If the reaulta for any co111ponda do not bullbullbullt the RPD criteria flag the poaitive reaulta for that compound aa eatbnated
2 If one value ibull non-detected and one ia above the CRQLt a Flag the positive result aa estimated (J) b Flag the non-detected result bullbull estimated (UJ) bull
~~T=~l ~~~bull ~~Y~~lx~middot utilized to apply duplicate actionbull
A separate worksheet should be filled out for each field duplicate pair
REGIOII X Data Review Workaheeta
D DITERHAL STAJIDAIU) PERFORMAIICII tgt1 ~ -h-J-J ~ ~
Liat the internal atandard areaa of aaaplea which do not aaat the criteria of +lOOt or -50 of the internal atandard area in the aaaochtad continuing calibration atandard
OH ltZ
Hr ltlt 0-lt OJgt
00
bull-ACIIOIII
1 If an IS area count ia outaida the criteria -sot or +lOOt of the aaaociatac1 atandarch
a Poaitive reaulta for ~ompounda quantitated uaing that IS are 8flagged aa aatlmatad (J) for that aampla fraction
b Non-datacta for compound a quanti tatad uaing that IS are tlaggad ~ aa estimated (UJ) for that aampla fraction
c If extremely lov area counta ara reported or if perforanceaxhiblta a aajor drop-off than a aavara loaa of aenaitivlty ia indicated Non-detectbull ahould then be flagged aa unusable (R)
2 If an IS retention time varies more than 30 aeconda the chromatoqraphic profile tor that sample aust be examined to determine if any false positives or negatives exiat For ehifta of a large magnitucSe the reviewer may consider partial or total rejection of the cSata for that sample traction
IS OUT H ~~
Data Buaaar IbullT
A bull Acceptable data
J - The a ociated nuaerical value ia an eatibullated quantit
R - ReJect data due to qualitT control criteria Tba data are unuaable (cobullpound bullay or bullay not be preaent) Reaplinamp and reanal7aia h neceaaary for verification
U bull The coapound waa anal7aed for but waa not detected The aaaociated nuaerical value h the aaaple quantitation liait
UJ - The coapound waa anamplJamped for but waa not detected The aaaple quantitation liait h an eatiaated quantitTbull
- The coapound waa analJamped for but waa not detected Tba auple quantltation Uait ia the aua bullbull tba CRQL preaented
- barcode 581461
- barcodetext SDMS Doc ID 581461
MgtV f WlSTONINC tAHOMAAKONE ONl VAA DE GRMff DRIVE IURLWGTOH MA-011103 11171221middot2050 February 3 1989
Mr Dennia GagneRegional sample Control cuatodian u s Environmental Protection Agency 90 canal street Beaton ~aaaachuaetta 02114
Re TID No 01-88-1202 site Pinettebull Salvage Yard SAS No 4385A Laboratory Reaource Analyat Inc Method tjwater52 4 1
Dear Mr Gagne
A validation waa perforaed on the organic analytical data for BAS No 4385A drinking water analya ia collected for Michael Jaainaky of the Environmental Protection Agency at the Pinettebull Salvage Yard aite The data waa evaluated baaed on the following paraaetera
o data completeneaa o holding tiaea o GCMS tuning o calibration o blanka o aurrogate recoverbullbull o matrix apike r ecove rbullbull o field duplicate r eaulta o i nternal atandard perforance o compound identification o compound quantitation
- All criteria were met f or thia parameter
Table I augorizea the yalidation recommendations which were based on the following intornotion
pata compltteneal
The laboratory did not initially aubmit all the raw data necesaary to perform the validation The laboratory was contacted and some raw data was submitted The laboratory did not submit the data pertaining to the laboratory method detection limit study They were contacted to verify one had been done but they were not requested to submit one at this time
Mr Gagne February 3 1~89 Page TWo
OC MI 2Upln q
The aasbull libullting wabull not provided for the bromotluorobenzene tune The instrumental printout ot the EPA Forw V with the 11aaa apectrw1 waa provided thia wabull bullutticient to verity the tuning criteriamiddot were 11et
Cal i bratiop
Chloro11ethane vinyl Chloride 1 2-Dibroa o-3-chloropropane 1 2 3-Trichlorobenzene
OM
~~ ~ _ IC cc Mr ltltl=ll=ll l=ll=ll
X 0-lt X + X Olgt
00 X
All 4385A-Ol - 4385A-04
x - Percent RSD gt30 Perce nt D gt25 Estimate (J) all poaitive reaulta
+ -iF RF lt0051 Eatiaate (J) all pobullitive reaulta and reject (R) all non-detecta
There waa anothe r problea which waa noted tor the initial curve which waa aubbull itted The 5ppb standard waa not analyzed on 1-16-89 the day the r est of the curve waa analyzed It was analyzed 1-17-89 a fte r the daily continuing calibration standard was analyzed Thia ia not the correct sequence t or an initi al cal ibration but the data will be ac cepted a bull it ia The raw data wabull not s ubmi tted tor each i nitial c a libr ation bull tandar d Tha raw data vaa aub11ittad t or the ~ontinuinq calibrati on atandard on l -17-89 The calculation of the r e lative r esponse f act ors a nd the report i ng of the factors with t ha percent differences were ver ified t or t he cont inuing cal ibration a nd were correctly r eport ed
Mr Gaqne February 3 J989 Page Three
coapound Jdtptificatiop
The apectra were not provided for the poaitive reaulte found in the method blankbull There were no compound a reported in the aamplee The data wae accepted 111 it waa preaented
MaximWl Concentration Action Level uq1
Methylene Chloride Chloroforw
2 8 bull 39
14 2 0
Blank Actione
o value lt action level J report value followed by a U
o value gt action level I report the value unqualified
very truly youre
ROY 1 WESTON INC
middot~ Vic1ti Howe ll Environaental Chebullibullt
Q_ yj77a~ Joeeph D Maatone
ESAT Team Manaqer Reqion I
VHVh Encloauree ec D szaro
Pinettebullbull Salvage Yard SAS No 4J85A
Table I - Recommendation summary
SAS No 5241
4385A-Ol A
4385A-02 A
4385A-03 A
4385A-04 A
A - Accept all data
OM ltZ Ml1 Z-lt M-lt Mr ltlt
Gl n-lt Olgt
00
A - Acceptable data
J - The aaaociated nuaerical value h an eatiaated quantit7
R - Reject data due to quality control criteria The data are unuaable (coapound bullbullY or aay not be preaent) Reaaaplinamp and reanalyaia ia neceaaary tor verification
U - The eoapound waa analyzed tor but waa not de tected The aaaociated nuaerica l value h the aaaple quantitati on Uait
UJ - The coapound waa analysed tor but waa not detected The aaaple quantitation Uait ia an eatiaated quantity
- The eoapound waa analysed tor but waa not detected The aaaple quant1tat1on liait ia the aaae aa the CRQL preaented
i 8 N
--
aw-n-shy-middot -~~~ PINETTE$ SALVAGE YARD ootlco It lo 4oo to tho ADMINISTRATIVE RECORD
of tiM t
( ()
ftmiddottU Zllll IOmiddotSOLIl bullmiddotZOLIl ~ bull _ ZOmiddotISKt LObullWSKt
lO __
) _ -1MqAdD-Iosl
_nAiiJil _ _ _PI~I
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~IPIIJmiddotSZL ~~~JM1middotZZLL
~Jiipela-1-ZLLL
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-pMMJipttt-ZL1 ~_
_UINOIIIPIIJ _IIIPIIbullLL IIIPII-Zl -liPI~ _J-J
PJJllpJIJ-1
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bulltIOJIIO lAYJA
_ - ~
=middot---~ =IIOIlwJOlJWflfl
wsesmiddot swsan _ l olllall4 11111
nUrn-shymiddot---tlllo
It lo M to tho PINETTES SALVAGE YARD ADMINISTRATIVE RECORD
tiiiHcunt
c u
bull middot11middot1 61bull11 bull1 dlbulllH IOJZAJlfG bull middotn middotl bull u-a bull middotUmiddotI bullmiddotu-a =Gi1oMS Jlyen0
zmm~ ICIIUTIIO
--zutqAit~JJJbullStl
-qiAitlbullfIJmiddottll -~IPIJ1bulltZl
-~IIPfJJbull[l l
_)AIIu
-IIIOAIPtomiddottl -~lfllmiddotll -1Wq1Alftl-shy
JO)OJOIIO-t -10)010110-Z
~IAvllbull-)
-)AJIdo
ft-fUtl lltl bull-so 110-anw - shy n~~n~nbullrs 11)1JrJ01J~
amiddotm VW[t middotowns lftV3 _bullubull ~essou8Utbull bullJus
REGION I Site Name f~ tJ middot~ $1 VdData Review Workaheeta Reference Number
REGION I REVIEW OP ORGANIC CONTRACT lABORATORY DATA PACJtAGB
rbullbull The hardeopied (laboratory name) eM bull u~ftmiddotLi data package received at Region I haa been reviewed and the qual ty aaurance and performancedata ampWIIlllarhed The data review included1
Caae No ~ SU No~ Saaplinq Date(a) l middot tlmiddottbull SDG No -btUeL Matrix ~ Shippinq Date(a) l middot u middotbulls No of Samp~ea__l_ ~d ~l~ 1 Date Recd by Lab ------ -- shy
Traffic Report Noa j~1SA- ol MSA -oa 01 1UU-oot
Trip Blank No Equipbullent Blank lfot Pield Dup Noe l
sow No requirebull that apecific analytical work be done and that aaaoclated reportbull be provided by the laboratory to the Reqiona EMSL-LV and ampMO The qeneral criteria uaed to deterwine the perfonance were baaed on an exabullination ofa
-Data Cobullpleteneaa -Matrix SpikeMatrix Spike Dup-HoldiiiCJ TiHe -Pield Duplicatebull -GCMS Tuni119 -Internal Standard Perfo1111ance -calibrationa -Peaticide Inat Perforaance -BlanJta -compound Identification -surroqate Recoveriea -co11pound Quantitation
OVerall couenta shyIIIMJ dW k b ~ bull8
Definitionbull and Qualifiera ~ A - Acceptable data J - Approximate data due to quality control criteria R - Reject data due to quality control criteria V - Compound not detected middotmiddot
u middot ff
Reviewerbull _____v_-~=J4==lt----- Date _ __1_-_~___r____ middot
REGION I Data Revev Workahebulltbull
I DATA COMPLETENESS
MISSING INFORMATION DATE LlB CONTAkiED DATE RECbullp
11 pound100lt db sJ_ rnA A t1tz -6_ iJiiuob J 41 rIbull-Jb bY- bull 1 ltbull+W Je cJw NAP emzht1i-rJ ~ 6YcfplciJl s9bW middot ttryy cJp -1 middot1middot
--- ------------
______
----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- ------- ----- ----- ------ ------ --------- ------- ----- ----- ------ ----- ------
REGION I Data Review Workaheeta
II HOLDING TIMES Complete table for all aa1r1plea and circle the fract ionbull which are not within criteria middot
VOA BNA PEST SAMPLE DATE DATE DATE
ID SAMPLED ANAL EXTR
~~AmiddotDI ~~---
~~UA middot6bull plusmn ~ NA
~~1-A middotCS l-11middottbull NA
~nsH~ ________ I-IH1 ~
DATE DATE ANAL EXTR
DATE ANAL
~ ~
-
~
VOA - Unpreaervedt Aromatic within 7 daya non-aromatic within 14 daya of aample collection Preaerved t Both within 14 daya of aample collection Soila t Both within 14 daya of bullbullbullple collection
BNA PEST - Extracted within 7 daya analyzed within 40 daya aoih ancS water
ACTION t 1 If holding timea are exceeded all poaitive results are eatimate
(J) and non-detecta are eatimated (UJ) 2 middotIf holding timea are groaaly exceeded the reviewer may
determine that non-detecta are unusable(bull)
-bull8 N
REGION 1 Data Review Workaheeta
111 CCfMS IUMINC
The DFTPP pertor111ance reaulta were reviewed and found to be within the apecifia4 criteria
If no lgtllOMSabullplaa affected____________________ ltZ ~ z-o ~ -oltlTha BFB performance raaulta ware raviawad and found to be within
the apacifiad criteria ~rIr no ltlt Sabullplaa affactacl____________________ 0-lt Olgt
00If aaaa calibration ia in error refer to tha Raion quidalinaa for expanded criteria If nacaaaary all aaaociatad data bullbull unuaabla (R)
cw ~ v-h H ~ ~ -+- W-4
fv H -t ~ ~middottp tJJ-- -6-- JAl s-IJ~ li lthi
o 1-n-H -Ht L~S s+-JJ ~1f- ~ ltIL __ -14 ltkgt c--1 11-Lf vltuv-1 ~ ~ -n ~ ~t-1~ ~ ~ -6v -~middotc_d ~ dG lwiW ~ -~-
fv-u middot~ _t~~~ ~
~ b jlu e I -1shymiddotmiddotmiddotmiddot middot middot~ w- -Hulmiddot11middot fl ~ -u ~ ~-tgt REGIOH I Data Review Worksheetbull ZV A VOLATILE CALIBRATION VERIPICATlOII
~
Data of Initial Calibration bulltmiddot~middot~middot~middotf~B~middotmiddotDatea of ContinuinCjJ Calibrationbull r- y1 Instrument ID 1 MatrixLevel 1 f of f llvJ
CRITERIA OUT ~ YWW RFtRSDRFtD middot eigtD cJb Ky ( )
Saaplaa Affected
ollSIgt --l dQJoL1botngtJngtbullcmiddot~3i~bullJdolkOCltJbullIjwlgtllflopound4tNL-j~yeni~Cl1Lmiddot middot ~middotlliJ)LSamplebull Affected -- - bull
Rf -~~~l~-D~kwmd~~~3~middot~Yl+n~~~~~~~L_~r~~~~~middot~)L_____Samplaa Affected
s bullbull~~ Atfected-liJlJlmiddot--rubullCLocltcUnllbulllpllth~~r~-+(~middot~__)J~----
Saaplaa Affactad------------------- shy
saaplaa Affactadlmiddot-------------------
Samplaa Affactach
Samplebull Affected IISmiddotDmiddot ckJnbull~
1 All iFbulla and RF 1a muat be gt005 ~~~~ ~ bull 333 2 All RSD 1a bulluat belt30 3 All D 1 a bulluat be lt25 gt+gt~
11~111 _lg_a zDSI ACTIOMI ~ If 10 1 If any compound haa an initial RF or a continuing RF of lt005
a Flag podtive r eaulta for that compound aa eatimated (J) bFlag non-detectbull for that compound as unusable (R) bull
2 If any compound has a RSD gt30 or a D gt25 aFlag positive results for that cornpound as estimated (J) b Flag non-detecta for that compound as estimated (UJ) if the RSO
or D ia gt50
A separate worksheet should be filled out for each initial curve
I I I I
REGION J Data Review Worksheets
JV I SEMIVOITILE CALIBRATION VERIFICATION
Date of Initial Calibration -====== Dataa of Continuin9 Calibrations~ tnatruaant ID ______
llW C2lli2l1llllCRITERIA OUT RFRSDRF0
Saaplaa Affected
Samples Affected
Saaplaa Affected
Saaplaa Affected
Saaplaa Affected
Saaplaa Affectach
Sabull plaa Affected
Saaplaa AffeCted
samples Affected
Saaplaa Affacta4
Samplaa Affactada
bull-8 N
Saaplea Affactadt
samples Afflctach
Samples Affected
Sea worksheet IV-A for criteria and actions
A new worksheet should be filled out for each initial curve
iluHot CAhv~ Z~H) bull ~~ bull z f o 1~1 t1C
REGION I Data Jteviev Worksheet
V A 111NK ANALYSIS RESULTS (Soctiono 1 2)
Liat the contamination in the blanka belov
1 Laboratory Bllnka
CONCENTftATIOM
lll1Ii
middota 1lt
2 Equipment and Trip Blanka CONCENTRAT ION[
lll1Ii shybull8 N
A separate worksheet should be used for low and media level blanks
REGION I DAtA Review Worksheets
V I BIAHJt ANALYSIS RESULTS (Section 3)
l BlAnk Actionbull
Action levelbull ahould be baeed upon the higheet concentration of contAIIinant determined in Any bhnk The Action level for aamplea vhich have been concentrAted or diluted ahould be bullultipUed by the concentrationdilution fActor No poaitive aample result ahould be reported unlaas the concentrAtion of the compound in the sAmple axceede the Action laval of 10 x a the Amount in the blAnk for the couon contAainAnta or 5 x a the aaount for any other compound Specific act i ona are bullbull follovaz
1 The c oncentr ation is l esa t han the CRQL repor t the CRQL
2 The concent r at i on i s 9reater than the CRQL but l eea than the act i on level r eport the c oncentration found u
3 The concentration Ja greater than the action level r eport the concentration unqualified
For exaaplea refer to the Regional Cuidelinea
Couon contaa inanta bull aethylene chloride acetone 2-butanone tolueneand phthalatea
MbX CONC ACTION LEVEL l1liUI l1liUI
bull middot )IQ
A aeparat~ vorksheet should be used for low and medium level blanka
-bull8 N
REGION I Data Review Workaheata
VI SURROGATE SPIKB RECOVERIU
Liat the percent racovariaa which do not bullbullbullt the criteria for aurrogata recovery
Au _-u ~ q-- 110 bull bullbull middot Matrixbull~
mJI_ TOL JIFB pep HBZ FBP TPH fHL 2PP TBP
to to to to to to to to to to
Surrogate Actiona PERCENT RECOVERY
~ ~ ~ Positive sample raaulta J J J Non-detected results R UJ A
CRR bull Contract Required Recovery Range Surrogate action should be applied
1 bull If at least two aurroatea in a BN or A fraction or one surrogate in the VOA fraction are out of specification but have recoveries of gt10
2 If any one surrogate in a fraction ahova lt10 recovery
REGION I Data Review Worksheets
fgt-100
VII A MATRIX SPIKEMATRIX SPIJa DUPLICATE
1 Matrix SpikeHatrix Spike Duplicate Recoveriea and Precision
lR )loa___ ___ lAveli~ Matrix1
List the tgtbullrcent recovariea and RPDa of coapounda whi ch do not aeet the criteriamiddot atated on Fotll J
bull-8
QUALIFICATION IS LIMITED TO THE UNSPIXED SAMPLE ONLY N 1 If any compound doea not aeet the Contraet Required Recovery range
(CRR) follow the actions stated belovt
PERCENT RECOVERY
~ ~ Poaitiva Sample Reaulta J J Non-detected Results R A
2 If any compound does not meet the RPD criteria flag positive reaulta tor that compound a a estimated (J)
A aeparate worksheet should be used for each MSMSD pair
REGION I Data Review Workaheeta Vll B MATRIX SPliCEMATRIX SPliCE DUPLICATE (Section 2)
3 Matrix Spike Duplicate - UnapUted compoundbull
TR Nos ___ ---
Liat the concentrations of the unspiked compounds and determine the percent RSDbull of the unapiked aample Jiatrix spike and matrix spike duplicate No Uaita have been developed for the RSD valuea of the unapUced compounda
SN1PLpound MS MSp CQNC
8 N
The reviewer auat uaa profeaaional judgement to datenina if there ia a need to qualify any of the unspiked compounds in the sample
REGION I Data Review Workaheeta
VIII PIELD DUPLICATE PRECISION
TR Noa___ --- Matrixamp___
Liat the concentrationbull of the compounda which do not bullbullbullt the followinc RPD criteriat middot
1 middot An RPD of lt30 for water duplicatea 2 An RPD of lt50 for aoil duplicatea
SAJ1PL CONC pup SAMPLE CONC
ACTIONS I
1 If the reaulta for any co111ponda do not bullbullbullt the RPD criteria flag the poaitive reaulta for that compound aa eatbnated
2 If one value ibull non-detected and one ia above the CRQLt a Flag the positive result aa estimated (J) b Flag the non-detected result bullbull estimated (UJ) bull
~~T=~l ~~~bull ~~Y~~lx~middot utilized to apply duplicate actionbull
A separate worksheet should be filled out for each field duplicate pair
REGIOII X Data Review Workaheeta
D DITERHAL STAJIDAIU) PERFORMAIICII tgt1 ~ -h-J-J ~ ~
Liat the internal atandard areaa of aaaplea which do not aaat the criteria of +lOOt or -50 of the internal atandard area in the aaaochtad continuing calibration atandard
OH ltZ
Hr ltlt 0-lt OJgt
00
bull-ACIIOIII
1 If an IS area count ia outaida the criteria -sot or +lOOt of the aaaociatac1 atandarch
a Poaitive reaulta for ~ompounda quantitated uaing that IS are 8flagged aa aatlmatad (J) for that aampla fraction
b Non-datacta for compound a quanti tatad uaing that IS are tlaggad ~ aa estimated (UJ) for that aampla fraction
c If extremely lov area counta ara reported or if perforanceaxhiblta a aajor drop-off than a aavara loaa of aenaitivlty ia indicated Non-detectbull ahould then be flagged aa unusable (R)
2 If an IS retention time varies more than 30 aeconda the chromatoqraphic profile tor that sample aust be examined to determine if any false positives or negatives exiat For ehifta of a large magnitucSe the reviewer may consider partial or total rejection of the cSata for that sample traction
IS OUT H ~~
Data Buaaar IbullT
A bull Acceptable data
J - The a ociated nuaerical value ia an eatibullated quantit
R - ReJect data due to qualitT control criteria Tba data are unuaable (cobullpound bullay or bullay not be preaent) Reaplinamp and reanal7aia h neceaaary for verification
U bull The coapound waa anal7aed for but waa not detected The aaaociated nuaerical value h the aaaple quantitation liait
UJ - The coapound waa anamplJamped for but waa not detected The aaaple quantitation liait h an eatiaated quantitTbull
- The coapound waa analJamped for but waa not detected Tba auple quantltation Uait ia the aua bullbull tba CRQL preaented
- barcode 581461
- barcodetext SDMS Doc ID 581461
Mr Gagne February 3 1~89 Page TWo
OC MI 2Upln q
The aasbull libullting wabull not provided for the bromotluorobenzene tune The instrumental printout ot the EPA Forw V with the 11aaa apectrw1 waa provided thia wabull bullutticient to verity the tuning criteriamiddot were 11et
Cal i bratiop
Chloro11ethane vinyl Chloride 1 2-Dibroa o-3-chloropropane 1 2 3-Trichlorobenzene
OM
~~ ~ _ IC cc Mr ltltl=ll=ll l=ll=ll
X 0-lt X + X Olgt
00 X
All 4385A-Ol - 4385A-04
x - Percent RSD gt30 Perce nt D gt25 Estimate (J) all poaitive reaulta
+ -iF RF lt0051 Eatiaate (J) all pobullitive reaulta and reject (R) all non-detecta
There waa anothe r problea which waa noted tor the initial curve which waa aubbull itted The 5ppb standard waa not analyzed on 1-16-89 the day the r est of the curve waa analyzed It was analyzed 1-17-89 a fte r the daily continuing calibration standard was analyzed Thia ia not the correct sequence t or an initi al cal ibration but the data will be ac cepted a bull it ia The raw data wabull not s ubmi tted tor each i nitial c a libr ation bull tandar d Tha raw data vaa aub11ittad t or the ~ontinuinq calibrati on atandard on l -17-89 The calculation of the r e lative r esponse f act ors a nd the report i ng of the factors with t ha percent differences were ver ified t or t he cont inuing cal ibration a nd were correctly r eport ed
Mr Gaqne February 3 J989 Page Three
coapound Jdtptificatiop
The apectra were not provided for the poaitive reaulte found in the method blankbull There were no compound a reported in the aamplee The data wae accepted 111 it waa preaented
MaximWl Concentration Action Level uq1
Methylene Chloride Chloroforw
2 8 bull 39
14 2 0
Blank Actione
o value lt action level J report value followed by a U
o value gt action level I report the value unqualified
very truly youre
ROY 1 WESTON INC
middot~ Vic1ti Howe ll Environaental Chebullibullt
Q_ yj77a~ Joeeph D Maatone
ESAT Team Manaqer Reqion I
VHVh Encloauree ec D szaro
Pinettebullbull Salvage Yard SAS No 4J85A
Table I - Recommendation summary
SAS No 5241
4385A-Ol A
4385A-02 A
4385A-03 A
4385A-04 A
A - Accept all data
OM ltZ Ml1 Z-lt M-lt Mr ltlt
Gl n-lt Olgt
00
A - Acceptable data
J - The aaaociated nuaerical value h an eatiaated quantit7
R - Reject data due to quality control criteria The data are unuaable (coapound bullbullY or aay not be preaent) Reaaaplinamp and reanalyaia ia neceaaary tor verification
U - The eoapound waa analyzed tor but waa not de tected The aaaociated nuaerica l value h the aaaple quantitati on Uait
UJ - The coapound waa analysed tor but waa not detected The aaaple quantitation Uait ia an eatiaated quantity
- The eoapound waa analysed tor but waa not detected The aaaple quant1tat1on liait ia the aaae aa the CRQL preaented
i 8 N
--
aw-n-shy-middot -~~~ PINETTE$ SALVAGE YARD ootlco It lo 4oo to tho ADMINISTRATIVE RECORD
of tiM t
( ()
ftmiddottU Zllll IOmiddotSOLIl bullmiddotZOLIl ~ bull _ ZOmiddotISKt LObullWSKt
lO __
) _ -1MqAdD-Iosl
_nAiiJil _ _ _PI~I
-shy IPmiddot(-qJGbullZL 1-ltpeIPl
~IPIIJmiddotSZL ~~~JM1middotZZLL
~Jiipela-1-ZLLL
--n-qta-zL IPIImiddotSL
-pMMJipttt-ZL1 ~_
_UINOIIIPIIJ _IIIPIIbullLL IIIPII-Zl -liPI~ _J-J
PJJllpJIJ-1
lPIImiddotZZ ~-IPII-ZL___
(IHelP-IIPio-Zl --p-lPII-11
-p-middot~ ~-IIPIOLl
~ __ middotmiddotmiddotmiddot1(1-~
bulltIOJIIO lAYJA
_ - ~
=middot---~ =IIOIlwJOlJWflfl
wsesmiddot swsan _ l olllall4 11111
nUrn-shymiddot---tlllo
It lo M to tho PINETTES SALVAGE YARD ADMINISTRATIVE RECORD
tiiiHcunt
c u
bull middot11middot1 61bull11 bull1 dlbulllH IOJZAJlfG bull middotn middotl bull u-a bull middotUmiddotI bullmiddotu-a =Gi1oMS Jlyen0
zmm~ ICIIUTIIO
--zutqAit~JJJbullStl
-qiAitlbullfIJmiddottll -~IPIJ1bulltZl
-~IIPfJJbull[l l
_)AIIu
-IIIOAIPtomiddottl -~lfllmiddotll -1Wq1Alftl-shy
JO)OJOIIO-t -10)010110-Z
~IAvllbull-)
-)AJIdo
ft-fUtl lltl bull-so 110-anw - shy n~~n~nbullrs 11)1JrJ01J~
amiddotm VW[t middotowns lftV3 _bullubull ~essou8Utbull bullJus
REGION I Site Name f~ tJ middot~ $1 VdData Review Workaheeta Reference Number
REGION I REVIEW OP ORGANIC CONTRACT lABORATORY DATA PACJtAGB
rbullbull The hardeopied (laboratory name) eM bull u~ftmiddotLi data package received at Region I haa been reviewed and the qual ty aaurance and performancedata ampWIIlllarhed The data review included1
Caae No ~ SU No~ Saaplinq Date(a) l middot tlmiddottbull SDG No -btUeL Matrix ~ Shippinq Date(a) l middot u middotbulls No of Samp~ea__l_ ~d ~l~ 1 Date Recd by Lab ------ -- shy
Traffic Report Noa j~1SA- ol MSA -oa 01 1UU-oot
Trip Blank No Equipbullent Blank lfot Pield Dup Noe l
sow No requirebull that apecific analytical work be done and that aaaoclated reportbull be provided by the laboratory to the Reqiona EMSL-LV and ampMO The qeneral criteria uaed to deterwine the perfonance were baaed on an exabullination ofa
-Data Cobullpleteneaa -Matrix SpikeMatrix Spike Dup-HoldiiiCJ TiHe -Pield Duplicatebull -GCMS Tuni119 -Internal Standard Perfo1111ance -calibrationa -Peaticide Inat Perforaance -BlanJta -compound Identification -surroqate Recoveriea -co11pound Quantitation
OVerall couenta shyIIIMJ dW k b ~ bull8
Definitionbull and Qualifiera ~ A - Acceptable data J - Approximate data due to quality control criteria R - Reject data due to quality control criteria V - Compound not detected middotmiddot
u middot ff
Reviewerbull _____v_-~=J4==lt----- Date _ __1_-_~___r____ middot
REGION I Data Revev Workahebulltbull
I DATA COMPLETENESS
MISSING INFORMATION DATE LlB CONTAkiED DATE RECbullp
11 pound100lt db sJ_ rnA A t1tz -6_ iJiiuob J 41 rIbull-Jb bY- bull 1 ltbull+W Je cJw NAP emzht1i-rJ ~ 6YcfplciJl s9bW middot ttryy cJp -1 middot1middot
--- ------------
______
----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- ------- ----- ----- ------ ------ --------- ------- ----- ----- ------ ----- ------
REGION I Data Review Workaheeta
II HOLDING TIMES Complete table for all aa1r1plea and circle the fract ionbull which are not within criteria middot
VOA BNA PEST SAMPLE DATE DATE DATE
ID SAMPLED ANAL EXTR
~~AmiddotDI ~~---
~~UA middot6bull plusmn ~ NA
~~1-A middotCS l-11middottbull NA
~nsH~ ________ I-IH1 ~
DATE DATE ANAL EXTR
DATE ANAL
~ ~
-
~
VOA - Unpreaervedt Aromatic within 7 daya non-aromatic within 14 daya of aample collection Preaerved t Both within 14 daya of aample collection Soila t Both within 14 daya of bullbullbullple collection
BNA PEST - Extracted within 7 daya analyzed within 40 daya aoih ancS water
ACTION t 1 If holding timea are exceeded all poaitive results are eatimate
(J) and non-detecta are eatimated (UJ) 2 middotIf holding timea are groaaly exceeded the reviewer may
determine that non-detecta are unusable(bull)
-bull8 N
REGION 1 Data Review Workaheeta
111 CCfMS IUMINC
The DFTPP pertor111ance reaulta were reviewed and found to be within the apecifia4 criteria
If no lgtllOMSabullplaa affected____________________ ltZ ~ z-o ~ -oltlTha BFB performance raaulta ware raviawad and found to be within
the apacifiad criteria ~rIr no ltlt Sabullplaa affactacl____________________ 0-lt Olgt
00If aaaa calibration ia in error refer to tha Raion quidalinaa for expanded criteria If nacaaaary all aaaociatad data bullbull unuaabla (R)
cw ~ v-h H ~ ~ -+- W-4
fv H -t ~ ~middottp tJJ-- -6-- JAl s-IJ~ li lthi
o 1-n-H -Ht L~S s+-JJ ~1f- ~ ltIL __ -14 ltkgt c--1 11-Lf vltuv-1 ~ ~ -n ~ ~t-1~ ~ ~ -6v -~middotc_d ~ dG lwiW ~ -~-
fv-u middot~ _t~~~ ~
~ b jlu e I -1shymiddotmiddotmiddotmiddot middot middot~ w- -Hulmiddot11middot fl ~ -u ~ ~-tgt REGIOH I Data Review Worksheetbull ZV A VOLATILE CALIBRATION VERIPICATlOII
~
Data of Initial Calibration bulltmiddot~middot~middot~middotf~B~middotmiddotDatea of ContinuinCjJ Calibrationbull r- y1 Instrument ID 1 MatrixLevel 1 f of f llvJ
CRITERIA OUT ~ YWW RFtRSDRFtD middot eigtD cJb Ky ( )
Saaplaa Affected
ollSIgt --l dQJoL1botngtJngtbullcmiddot~3i~bullJdolkOCltJbullIjwlgtllflopound4tNL-j~yeni~Cl1Lmiddot middot ~middotlliJ)LSamplebull Affected -- - bull
Rf -~~~l~-D~kwmd~~~3~middot~Yl+n~~~~~~~L_~r~~~~~middot~)L_____Samplaa Affected
s bullbull~~ Atfected-liJlJlmiddot--rubullCLocltcUnllbulllpllth~~r~-+(~middot~__)J~----
Saaplaa Affactad------------------- shy
saaplaa Affactadlmiddot-------------------
Samplaa Affactach
Samplebull Affected IISmiddotDmiddot ckJnbull~
1 All iFbulla and RF 1a muat be gt005 ~~~~ ~ bull 333 2 All RSD 1a bulluat belt30 3 All D 1 a bulluat be lt25 gt+gt~
11~111 _lg_a zDSI ACTIOMI ~ If 10 1 If any compound haa an initial RF or a continuing RF of lt005
a Flag podtive r eaulta for that compound aa eatimated (J) bFlag non-detectbull for that compound as unusable (R) bull
2 If any compound has a RSD gt30 or a D gt25 aFlag positive results for that cornpound as estimated (J) b Flag non-detecta for that compound as estimated (UJ) if the RSO
or D ia gt50
A separate worksheet should be filled out for each initial curve
I I I I
REGION J Data Review Worksheets
JV I SEMIVOITILE CALIBRATION VERIFICATION
Date of Initial Calibration -====== Dataa of Continuin9 Calibrations~ tnatruaant ID ______
llW C2lli2l1llllCRITERIA OUT RFRSDRF0
Saaplaa Affected
Samples Affected
Saaplaa Affected
Saaplaa Affected
Saaplaa Affected
Saaplaa Affectach
Sabull plaa Affected
Saaplaa AffeCted
samples Affected
Saaplaa Affacta4
Samplaa Affactada
bull-8 N
Saaplea Affactadt
samples Afflctach
Samples Affected
Sea worksheet IV-A for criteria and actions
A new worksheet should be filled out for each initial curve
iluHot CAhv~ Z~H) bull ~~ bull z f o 1~1 t1C
REGION I Data Jteviev Worksheet
V A 111NK ANALYSIS RESULTS (Soctiono 1 2)
Liat the contamination in the blanka belov
1 Laboratory Bllnka
CONCENTftATIOM
lll1Ii
middota 1lt
2 Equipment and Trip Blanka CONCENTRAT ION[
lll1Ii shybull8 N
A separate worksheet should be used for low and media level blanks
REGION I DAtA Review Worksheets
V I BIAHJt ANALYSIS RESULTS (Section 3)
l BlAnk Actionbull
Action levelbull ahould be baeed upon the higheet concentration of contAIIinant determined in Any bhnk The Action level for aamplea vhich have been concentrAted or diluted ahould be bullultipUed by the concentrationdilution fActor No poaitive aample result ahould be reported unlaas the concentrAtion of the compound in the sAmple axceede the Action laval of 10 x a the Amount in the blAnk for the couon contAainAnta or 5 x a the aaount for any other compound Specific act i ona are bullbull follovaz
1 The c oncentr ation is l esa t han the CRQL repor t the CRQL
2 The concent r at i on i s 9reater than the CRQL but l eea than the act i on level r eport the c oncentration found u
3 The concentration Ja greater than the action level r eport the concentration unqualified
For exaaplea refer to the Regional Cuidelinea
Couon contaa inanta bull aethylene chloride acetone 2-butanone tolueneand phthalatea
MbX CONC ACTION LEVEL l1liUI l1liUI
bull middot )IQ
A aeparat~ vorksheet should be used for low and medium level blanka
-bull8 N
REGION I Data Review Workaheata
VI SURROGATE SPIKB RECOVERIU
Liat the percent racovariaa which do not bullbullbullt the criteria for aurrogata recovery
Au _-u ~ q-- 110 bull bullbull middot Matrixbull~
mJI_ TOL JIFB pep HBZ FBP TPH fHL 2PP TBP
to to to to to to to to to to
Surrogate Actiona PERCENT RECOVERY
~ ~ ~ Positive sample raaulta J J J Non-detected results R UJ A
CRR bull Contract Required Recovery Range Surrogate action should be applied
1 bull If at least two aurroatea in a BN or A fraction or one surrogate in the VOA fraction are out of specification but have recoveries of gt10
2 If any one surrogate in a fraction ahova lt10 recovery
REGION I Data Review Worksheets
fgt-100
VII A MATRIX SPIKEMATRIX SPIJa DUPLICATE
1 Matrix SpikeHatrix Spike Duplicate Recoveriea and Precision
lR )loa___ ___ lAveli~ Matrix1
List the tgtbullrcent recovariea and RPDa of coapounda whi ch do not aeet the criteriamiddot atated on Fotll J
bull-8
QUALIFICATION IS LIMITED TO THE UNSPIXED SAMPLE ONLY N 1 If any compound doea not aeet the Contraet Required Recovery range
(CRR) follow the actions stated belovt
PERCENT RECOVERY
~ ~ Poaitiva Sample Reaulta J J Non-detected Results R A
2 If any compound does not meet the RPD criteria flag positive reaulta tor that compound a a estimated (J)
A aeparate worksheet should be used for each MSMSD pair
REGION I Data Review Workaheeta Vll B MATRIX SPliCEMATRIX SPliCE DUPLICATE (Section 2)
3 Matrix Spike Duplicate - UnapUted compoundbull
TR Nos ___ ---
Liat the concentrations of the unspiked compounds and determine the percent RSDbull of the unapiked aample Jiatrix spike and matrix spike duplicate No Uaita have been developed for the RSD valuea of the unapUced compounda
SN1PLpound MS MSp CQNC
8 N
The reviewer auat uaa profeaaional judgement to datenina if there ia a need to qualify any of the unspiked compounds in the sample
REGION I Data Review Workaheeta
VIII PIELD DUPLICATE PRECISION
TR Noa___ --- Matrixamp___
Liat the concentrationbull of the compounda which do not bullbullbullt the followinc RPD criteriat middot
1 middot An RPD of lt30 for water duplicatea 2 An RPD of lt50 for aoil duplicatea
SAJ1PL CONC pup SAMPLE CONC
ACTIONS I
1 If the reaulta for any co111ponda do not bullbullbullt the RPD criteria flag the poaitive reaulta for that compound aa eatbnated
2 If one value ibull non-detected and one ia above the CRQLt a Flag the positive result aa estimated (J) b Flag the non-detected result bullbull estimated (UJ) bull
~~T=~l ~~~bull ~~Y~~lx~middot utilized to apply duplicate actionbull
A separate worksheet should be filled out for each field duplicate pair
REGIOII X Data Review Workaheeta
D DITERHAL STAJIDAIU) PERFORMAIICII tgt1 ~ -h-J-J ~ ~
Liat the internal atandard areaa of aaaplea which do not aaat the criteria of +lOOt or -50 of the internal atandard area in the aaaochtad continuing calibration atandard
OH ltZ
Hr ltlt 0-lt OJgt
00
bull-ACIIOIII
1 If an IS area count ia outaida the criteria -sot or +lOOt of the aaaociatac1 atandarch
a Poaitive reaulta for ~ompounda quantitated uaing that IS are 8flagged aa aatlmatad (J) for that aampla fraction
b Non-datacta for compound a quanti tatad uaing that IS are tlaggad ~ aa estimated (UJ) for that aampla fraction
c If extremely lov area counta ara reported or if perforanceaxhiblta a aajor drop-off than a aavara loaa of aenaitivlty ia indicated Non-detectbull ahould then be flagged aa unusable (R)
2 If an IS retention time varies more than 30 aeconda the chromatoqraphic profile tor that sample aust be examined to determine if any false positives or negatives exiat For ehifta of a large magnitucSe the reviewer may consider partial or total rejection of the cSata for that sample traction
IS OUT H ~~
Data Buaaar IbullT
A bull Acceptable data
J - The a ociated nuaerical value ia an eatibullated quantit
R - ReJect data due to qualitT control criteria Tba data are unuaable (cobullpound bullay or bullay not be preaent) Reaplinamp and reanal7aia h neceaaary for verification
U bull The coapound waa anal7aed for but waa not detected The aaaociated nuaerical value h the aaaple quantitation liait
UJ - The coapound waa anamplJamped for but waa not detected The aaaple quantitation liait h an eatiaated quantitTbull
- The coapound waa analJamped for but waa not detected Tba auple quantltation Uait ia the aua bullbull tba CRQL preaented
- barcode 581461
- barcodetext SDMS Doc ID 581461
Mr Gaqne February 3 J989 Page Three
coapound Jdtptificatiop
The apectra were not provided for the poaitive reaulte found in the method blankbull There were no compound a reported in the aamplee The data wae accepted 111 it waa preaented
MaximWl Concentration Action Level uq1
Methylene Chloride Chloroforw
2 8 bull 39
14 2 0
Blank Actione
o value lt action level J report value followed by a U
o value gt action level I report the value unqualified
very truly youre
ROY 1 WESTON INC
middot~ Vic1ti Howe ll Environaental Chebullibullt
Q_ yj77a~ Joeeph D Maatone
ESAT Team Manaqer Reqion I
VHVh Encloauree ec D szaro
Pinettebullbull Salvage Yard SAS No 4J85A
Table I - Recommendation summary
SAS No 5241
4385A-Ol A
4385A-02 A
4385A-03 A
4385A-04 A
A - Accept all data
OM ltZ Ml1 Z-lt M-lt Mr ltlt
Gl n-lt Olgt
00
A - Acceptable data
J - The aaaociated nuaerical value h an eatiaated quantit7
R - Reject data due to quality control criteria The data are unuaable (coapound bullbullY or aay not be preaent) Reaaaplinamp and reanalyaia ia neceaaary tor verification
U - The eoapound waa analyzed tor but waa not de tected The aaaociated nuaerica l value h the aaaple quantitati on Uait
UJ - The coapound waa analysed tor but waa not detected The aaaple quantitation Uait ia an eatiaated quantity
- The eoapound waa analysed tor but waa not detected The aaaple quant1tat1on liait ia the aaae aa the CRQL preaented
i 8 N
--
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of tiM t
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_UINOIIIPIIJ _IIIPIIbullLL IIIPII-Zl -liPI~ _J-J
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bulltIOJIIO lAYJA
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tiiiHcunt
c u
bull middot11middot1 61bull11 bull1 dlbulllH IOJZAJlfG bull middotn middotl bull u-a bull middotUmiddotI bullmiddotu-a =Gi1oMS Jlyen0
zmm~ ICIIUTIIO
--zutqAit~JJJbullStl
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ft-fUtl lltl bull-so 110-anw - shy n~~n~nbullrs 11)1JrJ01J~
amiddotm VW[t middotowns lftV3 _bullubull ~essou8Utbull bullJus
REGION I Site Name f~ tJ middot~ $1 VdData Review Workaheeta Reference Number
REGION I REVIEW OP ORGANIC CONTRACT lABORATORY DATA PACJtAGB
rbullbull The hardeopied (laboratory name) eM bull u~ftmiddotLi data package received at Region I haa been reviewed and the qual ty aaurance and performancedata ampWIIlllarhed The data review included1
Caae No ~ SU No~ Saaplinq Date(a) l middot tlmiddottbull SDG No -btUeL Matrix ~ Shippinq Date(a) l middot u middotbulls No of Samp~ea__l_ ~d ~l~ 1 Date Recd by Lab ------ -- shy
Traffic Report Noa j~1SA- ol MSA -oa 01 1UU-oot
Trip Blank No Equipbullent Blank lfot Pield Dup Noe l
sow No requirebull that apecific analytical work be done and that aaaoclated reportbull be provided by the laboratory to the Reqiona EMSL-LV and ampMO The qeneral criteria uaed to deterwine the perfonance were baaed on an exabullination ofa
-Data Cobullpleteneaa -Matrix SpikeMatrix Spike Dup-HoldiiiCJ TiHe -Pield Duplicatebull -GCMS Tuni119 -Internal Standard Perfo1111ance -calibrationa -Peaticide Inat Perforaance -BlanJta -compound Identification -surroqate Recoveriea -co11pound Quantitation
OVerall couenta shyIIIMJ dW k b ~ bull8
Definitionbull and Qualifiera ~ A - Acceptable data J - Approximate data due to quality control criteria R - Reject data due to quality control criteria V - Compound not detected middotmiddot
u middot ff
Reviewerbull _____v_-~=J4==lt----- Date _ __1_-_~___r____ middot
REGION I Data Revev Workahebulltbull
I DATA COMPLETENESS
MISSING INFORMATION DATE LlB CONTAkiED DATE RECbullp
11 pound100lt db sJ_ rnA A t1tz -6_ iJiiuob J 41 rIbull-Jb bY- bull 1 ltbull+W Je cJw NAP emzht1i-rJ ~ 6YcfplciJl s9bW middot ttryy cJp -1 middot1middot
--- ------------
______
----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- ------- ----- ----- ------ ------ --------- ------- ----- ----- ------ ----- ------
REGION I Data Review Workaheeta
II HOLDING TIMES Complete table for all aa1r1plea and circle the fract ionbull which are not within criteria middot
VOA BNA PEST SAMPLE DATE DATE DATE
ID SAMPLED ANAL EXTR
~~AmiddotDI ~~---
~~UA middot6bull plusmn ~ NA
~~1-A middotCS l-11middottbull NA
~nsH~ ________ I-IH1 ~
DATE DATE ANAL EXTR
DATE ANAL
~ ~
-
~
VOA - Unpreaervedt Aromatic within 7 daya non-aromatic within 14 daya of aample collection Preaerved t Both within 14 daya of aample collection Soila t Both within 14 daya of bullbullbullple collection
BNA PEST - Extracted within 7 daya analyzed within 40 daya aoih ancS water
ACTION t 1 If holding timea are exceeded all poaitive results are eatimate
(J) and non-detecta are eatimated (UJ) 2 middotIf holding timea are groaaly exceeded the reviewer may
determine that non-detecta are unusable(bull)
-bull8 N
REGION 1 Data Review Workaheeta
111 CCfMS IUMINC
The DFTPP pertor111ance reaulta were reviewed and found to be within the apecifia4 criteria
If no lgtllOMSabullplaa affected____________________ ltZ ~ z-o ~ -oltlTha BFB performance raaulta ware raviawad and found to be within
the apacifiad criteria ~rIr no ltlt Sabullplaa affactacl____________________ 0-lt Olgt
00If aaaa calibration ia in error refer to tha Raion quidalinaa for expanded criteria If nacaaaary all aaaociatad data bullbull unuaabla (R)
cw ~ v-h H ~ ~ -+- W-4
fv H -t ~ ~middottp tJJ-- -6-- JAl s-IJ~ li lthi
o 1-n-H -Ht L~S s+-JJ ~1f- ~ ltIL __ -14 ltkgt c--1 11-Lf vltuv-1 ~ ~ -n ~ ~t-1~ ~ ~ -6v -~middotc_d ~ dG lwiW ~ -~-
fv-u middot~ _t~~~ ~
~ b jlu e I -1shymiddotmiddotmiddotmiddot middot middot~ w- -Hulmiddot11middot fl ~ -u ~ ~-tgt REGIOH I Data Review Worksheetbull ZV A VOLATILE CALIBRATION VERIPICATlOII
~
Data of Initial Calibration bulltmiddot~middot~middot~middotf~B~middotmiddotDatea of ContinuinCjJ Calibrationbull r- y1 Instrument ID 1 MatrixLevel 1 f of f llvJ
CRITERIA OUT ~ YWW RFtRSDRFtD middot eigtD cJb Ky ( )
Saaplaa Affected
ollSIgt --l dQJoL1botngtJngtbullcmiddot~3i~bullJdolkOCltJbullIjwlgtllflopound4tNL-j~yeni~Cl1Lmiddot middot ~middotlliJ)LSamplebull Affected -- - bull
Rf -~~~l~-D~kwmd~~~3~middot~Yl+n~~~~~~~L_~r~~~~~middot~)L_____Samplaa Affected
s bullbull~~ Atfected-liJlJlmiddot--rubullCLocltcUnllbulllpllth~~r~-+(~middot~__)J~----
Saaplaa Affactad------------------- shy
saaplaa Affactadlmiddot-------------------
Samplaa Affactach
Samplebull Affected IISmiddotDmiddot ckJnbull~
1 All iFbulla and RF 1a muat be gt005 ~~~~ ~ bull 333 2 All RSD 1a bulluat belt30 3 All D 1 a bulluat be lt25 gt+gt~
11~111 _lg_a zDSI ACTIOMI ~ If 10 1 If any compound haa an initial RF or a continuing RF of lt005
a Flag podtive r eaulta for that compound aa eatimated (J) bFlag non-detectbull for that compound as unusable (R) bull
2 If any compound has a RSD gt30 or a D gt25 aFlag positive results for that cornpound as estimated (J) b Flag non-detecta for that compound as estimated (UJ) if the RSO
or D ia gt50
A separate worksheet should be filled out for each initial curve
I I I I
REGION J Data Review Worksheets
JV I SEMIVOITILE CALIBRATION VERIFICATION
Date of Initial Calibration -====== Dataa of Continuin9 Calibrations~ tnatruaant ID ______
llW C2lli2l1llllCRITERIA OUT RFRSDRF0
Saaplaa Affected
Samples Affected
Saaplaa Affected
Saaplaa Affected
Saaplaa Affected
Saaplaa Affectach
Sabull plaa Affected
Saaplaa AffeCted
samples Affected
Saaplaa Affacta4
Samplaa Affactada
bull-8 N
Saaplea Affactadt
samples Afflctach
Samples Affected
Sea worksheet IV-A for criteria and actions
A new worksheet should be filled out for each initial curve
iluHot CAhv~ Z~H) bull ~~ bull z f o 1~1 t1C
REGION I Data Jteviev Worksheet
V A 111NK ANALYSIS RESULTS (Soctiono 1 2)
Liat the contamination in the blanka belov
1 Laboratory Bllnka
CONCENTftATIOM
lll1Ii
middota 1lt
2 Equipment and Trip Blanka CONCENTRAT ION[
lll1Ii shybull8 N
A separate worksheet should be used for low and media level blanks
REGION I DAtA Review Worksheets
V I BIAHJt ANALYSIS RESULTS (Section 3)
l BlAnk Actionbull
Action levelbull ahould be baeed upon the higheet concentration of contAIIinant determined in Any bhnk The Action level for aamplea vhich have been concentrAted or diluted ahould be bullultipUed by the concentrationdilution fActor No poaitive aample result ahould be reported unlaas the concentrAtion of the compound in the sAmple axceede the Action laval of 10 x a the Amount in the blAnk for the couon contAainAnta or 5 x a the aaount for any other compound Specific act i ona are bullbull follovaz
1 The c oncentr ation is l esa t han the CRQL repor t the CRQL
2 The concent r at i on i s 9reater than the CRQL but l eea than the act i on level r eport the c oncentration found u
3 The concentration Ja greater than the action level r eport the concentration unqualified
For exaaplea refer to the Regional Cuidelinea
Couon contaa inanta bull aethylene chloride acetone 2-butanone tolueneand phthalatea
MbX CONC ACTION LEVEL l1liUI l1liUI
bull middot )IQ
A aeparat~ vorksheet should be used for low and medium level blanka
-bull8 N
REGION I Data Review Workaheata
VI SURROGATE SPIKB RECOVERIU
Liat the percent racovariaa which do not bullbullbullt the criteria for aurrogata recovery
Au _-u ~ q-- 110 bull bullbull middot Matrixbull~
mJI_ TOL JIFB pep HBZ FBP TPH fHL 2PP TBP
to to to to to to to to to to
Surrogate Actiona PERCENT RECOVERY
~ ~ ~ Positive sample raaulta J J J Non-detected results R UJ A
CRR bull Contract Required Recovery Range Surrogate action should be applied
1 bull If at least two aurroatea in a BN or A fraction or one surrogate in the VOA fraction are out of specification but have recoveries of gt10
2 If any one surrogate in a fraction ahova lt10 recovery
REGION I Data Review Worksheets
fgt-100
VII A MATRIX SPIKEMATRIX SPIJa DUPLICATE
1 Matrix SpikeHatrix Spike Duplicate Recoveriea and Precision
lR )loa___ ___ lAveli~ Matrix1
List the tgtbullrcent recovariea and RPDa of coapounda whi ch do not aeet the criteriamiddot atated on Fotll J
bull-8
QUALIFICATION IS LIMITED TO THE UNSPIXED SAMPLE ONLY N 1 If any compound doea not aeet the Contraet Required Recovery range
(CRR) follow the actions stated belovt
PERCENT RECOVERY
~ ~ Poaitiva Sample Reaulta J J Non-detected Results R A
2 If any compound does not meet the RPD criteria flag positive reaulta tor that compound a a estimated (J)
A aeparate worksheet should be used for each MSMSD pair
REGION I Data Review Workaheeta Vll B MATRIX SPliCEMATRIX SPliCE DUPLICATE (Section 2)
3 Matrix Spike Duplicate - UnapUted compoundbull
TR Nos ___ ---
Liat the concentrations of the unspiked compounds and determine the percent RSDbull of the unapiked aample Jiatrix spike and matrix spike duplicate No Uaita have been developed for the RSD valuea of the unapUced compounda
SN1PLpound MS MSp CQNC
8 N
The reviewer auat uaa profeaaional judgement to datenina if there ia a need to qualify any of the unspiked compounds in the sample
REGION I Data Review Workaheeta
VIII PIELD DUPLICATE PRECISION
TR Noa___ --- Matrixamp___
Liat the concentrationbull of the compounda which do not bullbullbullt the followinc RPD criteriat middot
1 middot An RPD of lt30 for water duplicatea 2 An RPD of lt50 for aoil duplicatea
SAJ1PL CONC pup SAMPLE CONC
ACTIONS I
1 If the reaulta for any co111ponda do not bullbullbullt the RPD criteria flag the poaitive reaulta for that compound aa eatbnated
2 If one value ibull non-detected and one ia above the CRQLt a Flag the positive result aa estimated (J) b Flag the non-detected result bullbull estimated (UJ) bull
~~T=~l ~~~bull ~~Y~~lx~middot utilized to apply duplicate actionbull
A separate worksheet should be filled out for each field duplicate pair
REGIOII X Data Review Workaheeta
D DITERHAL STAJIDAIU) PERFORMAIICII tgt1 ~ -h-J-J ~ ~
Liat the internal atandard areaa of aaaplea which do not aaat the criteria of +lOOt or -50 of the internal atandard area in the aaaochtad continuing calibration atandard
OH ltZ
Hr ltlt 0-lt OJgt
00
bull-ACIIOIII
1 If an IS area count ia outaida the criteria -sot or +lOOt of the aaaociatac1 atandarch
a Poaitive reaulta for ~ompounda quantitated uaing that IS are 8flagged aa aatlmatad (J) for that aampla fraction
b Non-datacta for compound a quanti tatad uaing that IS are tlaggad ~ aa estimated (UJ) for that aampla fraction
c If extremely lov area counta ara reported or if perforanceaxhiblta a aajor drop-off than a aavara loaa of aenaitivlty ia indicated Non-detectbull ahould then be flagged aa unusable (R)
2 If an IS retention time varies more than 30 aeconda the chromatoqraphic profile tor that sample aust be examined to determine if any false positives or negatives exiat For ehifta of a large magnitucSe the reviewer may consider partial or total rejection of the cSata for that sample traction
IS OUT H ~~
Data Buaaar IbullT
A bull Acceptable data
J - The a ociated nuaerical value ia an eatibullated quantit
R - ReJect data due to qualitT control criteria Tba data are unuaable (cobullpound bullay or bullay not be preaent) Reaplinamp and reanal7aia h neceaaary for verification
U bull The coapound waa anal7aed for but waa not detected The aaaociated nuaerical value h the aaaple quantitation liait
UJ - The coapound waa anamplJamped for but waa not detected The aaaple quantitation liait h an eatiaated quantitTbull
- The coapound waa analJamped for but waa not detected Tba auple quantltation Uait ia the aua bullbull tba CRQL preaented
- barcode 581461
- barcodetext SDMS Doc ID 581461
Pinettebullbull Salvage Yard SAS No 4J85A
Table I - Recommendation summary
SAS No 5241
4385A-Ol A
4385A-02 A
4385A-03 A
4385A-04 A
A - Accept all data
OM ltZ Ml1 Z-lt M-lt Mr ltlt
Gl n-lt Olgt
00
A - Acceptable data
J - The aaaociated nuaerical value h an eatiaated quantit7
R - Reject data due to quality control criteria The data are unuaable (coapound bullbullY or aay not be preaent) Reaaaplinamp and reanalyaia ia neceaaary tor verification
U - The eoapound waa analyzed tor but waa not de tected The aaaociated nuaerica l value h the aaaple quantitati on Uait
UJ - The coapound waa analysed tor but waa not detected The aaaple quantitation Uait ia an eatiaated quantity
- The eoapound waa analysed tor but waa not detected The aaaple quant1tat1on liait ia the aaae aa the CRQL preaented
i 8 N
--
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of tiM t
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tiiiHcunt
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REGION I Site Name f~ tJ middot~ $1 VdData Review Workaheeta Reference Number
REGION I REVIEW OP ORGANIC CONTRACT lABORATORY DATA PACJtAGB
rbullbull The hardeopied (laboratory name) eM bull u~ftmiddotLi data package received at Region I haa been reviewed and the qual ty aaurance and performancedata ampWIIlllarhed The data review included1
Caae No ~ SU No~ Saaplinq Date(a) l middot tlmiddottbull SDG No -btUeL Matrix ~ Shippinq Date(a) l middot u middotbulls No of Samp~ea__l_ ~d ~l~ 1 Date Recd by Lab ------ -- shy
Traffic Report Noa j~1SA- ol MSA -oa 01 1UU-oot
Trip Blank No Equipbullent Blank lfot Pield Dup Noe l
sow No requirebull that apecific analytical work be done and that aaaoclated reportbull be provided by the laboratory to the Reqiona EMSL-LV and ampMO The qeneral criteria uaed to deterwine the perfonance were baaed on an exabullination ofa
-Data Cobullpleteneaa -Matrix SpikeMatrix Spike Dup-HoldiiiCJ TiHe -Pield Duplicatebull -GCMS Tuni119 -Internal Standard Perfo1111ance -calibrationa -Peaticide Inat Perforaance -BlanJta -compound Identification -surroqate Recoveriea -co11pound Quantitation
OVerall couenta shyIIIMJ dW k b ~ bull8
Definitionbull and Qualifiera ~ A - Acceptable data J - Approximate data due to quality control criteria R - Reject data due to quality control criteria V - Compound not detected middotmiddot
u middot ff
Reviewerbull _____v_-~=J4==lt----- Date _ __1_-_~___r____ middot
REGION I Data Revev Workahebulltbull
I DATA COMPLETENESS
MISSING INFORMATION DATE LlB CONTAkiED DATE RECbullp
11 pound100lt db sJ_ rnA A t1tz -6_ iJiiuob J 41 rIbull-Jb bY- bull 1 ltbull+W Je cJw NAP emzht1i-rJ ~ 6YcfplciJl s9bW middot ttryy cJp -1 middot1middot
--- ------------
______
----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- ------- ----- ----- ------ ------ --------- ------- ----- ----- ------ ----- ------
REGION I Data Review Workaheeta
II HOLDING TIMES Complete table for all aa1r1plea and circle the fract ionbull which are not within criteria middot
VOA BNA PEST SAMPLE DATE DATE DATE
ID SAMPLED ANAL EXTR
~~AmiddotDI ~~---
~~UA middot6bull plusmn ~ NA
~~1-A middotCS l-11middottbull NA
~nsH~ ________ I-IH1 ~
DATE DATE ANAL EXTR
DATE ANAL
~ ~
-
~
VOA - Unpreaervedt Aromatic within 7 daya non-aromatic within 14 daya of aample collection Preaerved t Both within 14 daya of aample collection Soila t Both within 14 daya of bullbullbullple collection
BNA PEST - Extracted within 7 daya analyzed within 40 daya aoih ancS water
ACTION t 1 If holding timea are exceeded all poaitive results are eatimate
(J) and non-detecta are eatimated (UJ) 2 middotIf holding timea are groaaly exceeded the reviewer may
determine that non-detecta are unusable(bull)
-bull8 N
REGION 1 Data Review Workaheeta
111 CCfMS IUMINC
The DFTPP pertor111ance reaulta were reviewed and found to be within the apecifia4 criteria
If no lgtllOMSabullplaa affected____________________ ltZ ~ z-o ~ -oltlTha BFB performance raaulta ware raviawad and found to be within
the apacifiad criteria ~rIr no ltlt Sabullplaa affactacl____________________ 0-lt Olgt
00If aaaa calibration ia in error refer to tha Raion quidalinaa for expanded criteria If nacaaaary all aaaociatad data bullbull unuaabla (R)
cw ~ v-h H ~ ~ -+- W-4
fv H -t ~ ~middottp tJJ-- -6-- JAl s-IJ~ li lthi
o 1-n-H -Ht L~S s+-JJ ~1f- ~ ltIL __ -14 ltkgt c--1 11-Lf vltuv-1 ~ ~ -n ~ ~t-1~ ~ ~ -6v -~middotc_d ~ dG lwiW ~ -~-
fv-u middot~ _t~~~ ~
~ b jlu e I -1shymiddotmiddotmiddotmiddot middot middot~ w- -Hulmiddot11middot fl ~ -u ~ ~-tgt REGIOH I Data Review Worksheetbull ZV A VOLATILE CALIBRATION VERIPICATlOII
~
Data of Initial Calibration bulltmiddot~middot~middot~middotf~B~middotmiddotDatea of ContinuinCjJ Calibrationbull r- y1 Instrument ID 1 MatrixLevel 1 f of f llvJ
CRITERIA OUT ~ YWW RFtRSDRFtD middot eigtD cJb Ky ( )
Saaplaa Affected
ollSIgt --l dQJoL1botngtJngtbullcmiddot~3i~bullJdolkOCltJbullIjwlgtllflopound4tNL-j~yeni~Cl1Lmiddot middot ~middotlliJ)LSamplebull Affected -- - bull
Rf -~~~l~-D~kwmd~~~3~middot~Yl+n~~~~~~~L_~r~~~~~middot~)L_____Samplaa Affected
s bullbull~~ Atfected-liJlJlmiddot--rubullCLocltcUnllbulllpllth~~r~-+(~middot~__)J~----
Saaplaa Affactad------------------- shy
saaplaa Affactadlmiddot-------------------
Samplaa Affactach
Samplebull Affected IISmiddotDmiddot ckJnbull~
1 All iFbulla and RF 1a muat be gt005 ~~~~ ~ bull 333 2 All RSD 1a bulluat belt30 3 All D 1 a bulluat be lt25 gt+gt~
11~111 _lg_a zDSI ACTIOMI ~ If 10 1 If any compound haa an initial RF or a continuing RF of lt005
a Flag podtive r eaulta for that compound aa eatimated (J) bFlag non-detectbull for that compound as unusable (R) bull
2 If any compound has a RSD gt30 or a D gt25 aFlag positive results for that cornpound as estimated (J) b Flag non-detecta for that compound as estimated (UJ) if the RSO
or D ia gt50
A separate worksheet should be filled out for each initial curve
I I I I
REGION J Data Review Worksheets
JV I SEMIVOITILE CALIBRATION VERIFICATION
Date of Initial Calibration -====== Dataa of Continuin9 Calibrations~ tnatruaant ID ______
llW C2lli2l1llllCRITERIA OUT RFRSDRF0
Saaplaa Affected
Samples Affected
Saaplaa Affected
Saaplaa Affected
Saaplaa Affected
Saaplaa Affectach
Sabull plaa Affected
Saaplaa AffeCted
samples Affected
Saaplaa Affacta4
Samplaa Affactada
bull-8 N
Saaplea Affactadt
samples Afflctach
Samples Affected
Sea worksheet IV-A for criteria and actions
A new worksheet should be filled out for each initial curve
iluHot CAhv~ Z~H) bull ~~ bull z f o 1~1 t1C
REGION I Data Jteviev Worksheet
V A 111NK ANALYSIS RESULTS (Soctiono 1 2)
Liat the contamination in the blanka belov
1 Laboratory Bllnka
CONCENTftATIOM
lll1Ii
middota 1lt
2 Equipment and Trip Blanka CONCENTRAT ION[
lll1Ii shybull8 N
A separate worksheet should be used for low and media level blanks
REGION I DAtA Review Worksheets
V I BIAHJt ANALYSIS RESULTS (Section 3)
l BlAnk Actionbull
Action levelbull ahould be baeed upon the higheet concentration of contAIIinant determined in Any bhnk The Action level for aamplea vhich have been concentrAted or diluted ahould be bullultipUed by the concentrationdilution fActor No poaitive aample result ahould be reported unlaas the concentrAtion of the compound in the sAmple axceede the Action laval of 10 x a the Amount in the blAnk for the couon contAainAnta or 5 x a the aaount for any other compound Specific act i ona are bullbull follovaz
1 The c oncentr ation is l esa t han the CRQL repor t the CRQL
2 The concent r at i on i s 9reater than the CRQL but l eea than the act i on level r eport the c oncentration found u
3 The concentration Ja greater than the action level r eport the concentration unqualified
For exaaplea refer to the Regional Cuidelinea
Couon contaa inanta bull aethylene chloride acetone 2-butanone tolueneand phthalatea
MbX CONC ACTION LEVEL l1liUI l1liUI
bull middot )IQ
A aeparat~ vorksheet should be used for low and medium level blanka
-bull8 N
REGION I Data Review Workaheata
VI SURROGATE SPIKB RECOVERIU
Liat the percent racovariaa which do not bullbullbullt the criteria for aurrogata recovery
Au _-u ~ q-- 110 bull bullbull middot Matrixbull~
mJI_ TOL JIFB pep HBZ FBP TPH fHL 2PP TBP
to to to to to to to to to to
Surrogate Actiona PERCENT RECOVERY
~ ~ ~ Positive sample raaulta J J J Non-detected results R UJ A
CRR bull Contract Required Recovery Range Surrogate action should be applied
1 bull If at least two aurroatea in a BN or A fraction or one surrogate in the VOA fraction are out of specification but have recoveries of gt10
2 If any one surrogate in a fraction ahova lt10 recovery
REGION I Data Review Worksheets
fgt-100
VII A MATRIX SPIKEMATRIX SPIJa DUPLICATE
1 Matrix SpikeHatrix Spike Duplicate Recoveriea and Precision
lR )loa___ ___ lAveli~ Matrix1
List the tgtbullrcent recovariea and RPDa of coapounda whi ch do not aeet the criteriamiddot atated on Fotll J
bull-8
QUALIFICATION IS LIMITED TO THE UNSPIXED SAMPLE ONLY N 1 If any compound doea not aeet the Contraet Required Recovery range
(CRR) follow the actions stated belovt
PERCENT RECOVERY
~ ~ Poaitiva Sample Reaulta J J Non-detected Results R A
2 If any compound does not meet the RPD criteria flag positive reaulta tor that compound a a estimated (J)
A aeparate worksheet should be used for each MSMSD pair
REGION I Data Review Workaheeta Vll B MATRIX SPliCEMATRIX SPliCE DUPLICATE (Section 2)
3 Matrix Spike Duplicate - UnapUted compoundbull
TR Nos ___ ---
Liat the concentrations of the unspiked compounds and determine the percent RSDbull of the unapiked aample Jiatrix spike and matrix spike duplicate No Uaita have been developed for the RSD valuea of the unapUced compounda
SN1PLpound MS MSp CQNC
8 N
The reviewer auat uaa profeaaional judgement to datenina if there ia a need to qualify any of the unspiked compounds in the sample
REGION I Data Review Workaheeta
VIII PIELD DUPLICATE PRECISION
TR Noa___ --- Matrixamp___
Liat the concentrationbull of the compounda which do not bullbullbullt the followinc RPD criteriat middot
1 middot An RPD of lt30 for water duplicatea 2 An RPD of lt50 for aoil duplicatea
SAJ1PL CONC pup SAMPLE CONC
ACTIONS I
1 If the reaulta for any co111ponda do not bullbullbullt the RPD criteria flag the poaitive reaulta for that compound aa eatbnated
2 If one value ibull non-detected and one ia above the CRQLt a Flag the positive result aa estimated (J) b Flag the non-detected result bullbull estimated (UJ) bull
~~T=~l ~~~bull ~~Y~~lx~middot utilized to apply duplicate actionbull
A separate worksheet should be filled out for each field duplicate pair
REGIOII X Data Review Workaheeta
D DITERHAL STAJIDAIU) PERFORMAIICII tgt1 ~ -h-J-J ~ ~
Liat the internal atandard areaa of aaaplea which do not aaat the criteria of +lOOt or -50 of the internal atandard area in the aaaochtad continuing calibration atandard
OH ltZ
Hr ltlt 0-lt OJgt
00
bull-ACIIOIII
1 If an IS area count ia outaida the criteria -sot or +lOOt of the aaaociatac1 atandarch
a Poaitive reaulta for ~ompounda quantitated uaing that IS are 8flagged aa aatlmatad (J) for that aampla fraction
b Non-datacta for compound a quanti tatad uaing that IS are tlaggad ~ aa estimated (UJ) for that aampla fraction
c If extremely lov area counta ara reported or if perforanceaxhiblta a aajor drop-off than a aavara loaa of aenaitivlty ia indicated Non-detectbull ahould then be flagged aa unusable (R)
2 If an IS retention time varies more than 30 aeconda the chromatoqraphic profile tor that sample aust be examined to determine if any false positives or negatives exiat For ehifta of a large magnitucSe the reviewer may consider partial or total rejection of the cSata for that sample traction
IS OUT H ~~
Data Buaaar IbullT
A bull Acceptable data
J - The a ociated nuaerical value ia an eatibullated quantit
R - ReJect data due to qualitT control criteria Tba data are unuaable (cobullpound bullay or bullay not be preaent) Reaplinamp and reanal7aia h neceaaary for verification
U bull The coapound waa anal7aed for but waa not detected The aaaociated nuaerical value h the aaaple quantitation liait
UJ - The coapound waa anamplJamped for but waa not detected The aaaple quantitation liait h an eatiaated quantitTbull
- The coapound waa analJamped for but waa not detected Tba auple quantltation Uait ia the aua bullbull tba CRQL preaented
- barcode 581461
- barcodetext SDMS Doc ID 581461
A - Acceptable data
J - The aaaociated nuaerical value h an eatiaated quantit7
R - Reject data due to quality control criteria The data are unuaable (coapound bullbullY or aay not be preaent) Reaaaplinamp and reanalyaia ia neceaaary tor verification
U - The eoapound waa analyzed tor but waa not de tected The aaaociated nuaerica l value h the aaaple quantitati on Uait
UJ - The coapound waa analysed tor but waa not detected The aaaple quantitation Uait ia an eatiaated quantity
- The eoapound waa analysed tor but waa not detected The aaaple quant1tat1on liait ia the aaae aa the CRQL preaented
i 8 N
--
aw-n-shy-middot -~~~ PINETTE$ SALVAGE YARD ootlco It lo 4oo to tho ADMINISTRATIVE RECORD
of tiM t
( ()
ftmiddottU Zllll IOmiddotSOLIl bullmiddotZOLIl ~ bull _ ZOmiddotISKt LObullWSKt
lO __
) _ -1MqAdD-Iosl
_nAiiJil _ _ _PI~I
-shy IPmiddot(-qJGbullZL 1-ltpeIPl
~IPIIJmiddotSZL ~~~JM1middotZZLL
~Jiipela-1-ZLLL
--n-qta-zL IPIImiddotSL
-pMMJipttt-ZL1 ~_
_UINOIIIPIIJ _IIIPIIbullLL IIIPII-Zl -liPI~ _J-J
PJJllpJIJ-1
lPIImiddotZZ ~-IPII-ZL___
(IHelP-IIPio-Zl --p-lPII-11
-p-middot~ ~-IIPIOLl
~ __ middotmiddotmiddotmiddot1(1-~
bulltIOJIIO lAYJA
_ - ~
=middot---~ =IIOIlwJOlJWflfl
wsesmiddot swsan _ l olllall4 11111
nUrn-shymiddot---tlllo
It lo M to tho PINETTES SALVAGE YARD ADMINISTRATIVE RECORD
tiiiHcunt
c u
bull middot11middot1 61bull11 bull1 dlbulllH IOJZAJlfG bull middotn middotl bull u-a bull middotUmiddotI bullmiddotu-a =Gi1oMS Jlyen0
zmm~ ICIIUTIIO
--zutqAit~JJJbullStl
-qiAitlbullfIJmiddottll -~IPIJ1bulltZl
-~IIPfJJbull[l l
_)AIIu
-IIIOAIPtomiddottl -~lfllmiddotll -1Wq1Alftl-shy
JO)OJOIIO-t -10)010110-Z
~IAvllbull-)
-)AJIdo
ft-fUtl lltl bull-so 110-anw - shy n~~n~nbullrs 11)1JrJ01J~
amiddotm VW[t middotowns lftV3 _bullubull ~essou8Utbull bullJus
REGION I Site Name f~ tJ middot~ $1 VdData Review Workaheeta Reference Number
REGION I REVIEW OP ORGANIC CONTRACT lABORATORY DATA PACJtAGB
rbullbull The hardeopied (laboratory name) eM bull u~ftmiddotLi data package received at Region I haa been reviewed and the qual ty aaurance and performancedata ampWIIlllarhed The data review included1
Caae No ~ SU No~ Saaplinq Date(a) l middot tlmiddottbull SDG No -btUeL Matrix ~ Shippinq Date(a) l middot u middotbulls No of Samp~ea__l_ ~d ~l~ 1 Date Recd by Lab ------ -- shy
Traffic Report Noa j~1SA- ol MSA -oa 01 1UU-oot
Trip Blank No Equipbullent Blank lfot Pield Dup Noe l
sow No requirebull that apecific analytical work be done and that aaaoclated reportbull be provided by the laboratory to the Reqiona EMSL-LV and ampMO The qeneral criteria uaed to deterwine the perfonance were baaed on an exabullination ofa
-Data Cobullpleteneaa -Matrix SpikeMatrix Spike Dup-HoldiiiCJ TiHe -Pield Duplicatebull -GCMS Tuni119 -Internal Standard Perfo1111ance -calibrationa -Peaticide Inat Perforaance -BlanJta -compound Identification -surroqate Recoveriea -co11pound Quantitation
OVerall couenta shyIIIMJ dW k b ~ bull8
Definitionbull and Qualifiera ~ A - Acceptable data J - Approximate data due to quality control criteria R - Reject data due to quality control criteria V - Compound not detected middotmiddot
u middot ff
Reviewerbull _____v_-~=J4==lt----- Date _ __1_-_~___r____ middot
REGION I Data Revev Workahebulltbull
I DATA COMPLETENESS
MISSING INFORMATION DATE LlB CONTAkiED DATE RECbullp
11 pound100lt db sJ_ rnA A t1tz -6_ iJiiuob J 41 rIbull-Jb bY- bull 1 ltbull+W Je cJw NAP emzht1i-rJ ~ 6YcfplciJl s9bW middot ttryy cJp -1 middot1middot
--- ------------
______
----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- ------- ----- ----- ------ ------ --------- ------- ----- ----- ------ ----- ------
REGION I Data Review Workaheeta
II HOLDING TIMES Complete table for all aa1r1plea and circle the fract ionbull which are not within criteria middot
VOA BNA PEST SAMPLE DATE DATE DATE
ID SAMPLED ANAL EXTR
~~AmiddotDI ~~---
~~UA middot6bull plusmn ~ NA
~~1-A middotCS l-11middottbull NA
~nsH~ ________ I-IH1 ~
DATE DATE ANAL EXTR
DATE ANAL
~ ~
-
~
VOA - Unpreaervedt Aromatic within 7 daya non-aromatic within 14 daya of aample collection Preaerved t Both within 14 daya of aample collection Soila t Both within 14 daya of bullbullbullple collection
BNA PEST - Extracted within 7 daya analyzed within 40 daya aoih ancS water
ACTION t 1 If holding timea are exceeded all poaitive results are eatimate
(J) and non-detecta are eatimated (UJ) 2 middotIf holding timea are groaaly exceeded the reviewer may
determine that non-detecta are unusable(bull)
-bull8 N
REGION 1 Data Review Workaheeta
111 CCfMS IUMINC
The DFTPP pertor111ance reaulta were reviewed and found to be within the apecifia4 criteria
If no lgtllOMSabullplaa affected____________________ ltZ ~ z-o ~ -oltlTha BFB performance raaulta ware raviawad and found to be within
the apacifiad criteria ~rIr no ltlt Sabullplaa affactacl____________________ 0-lt Olgt
00If aaaa calibration ia in error refer to tha Raion quidalinaa for expanded criteria If nacaaaary all aaaociatad data bullbull unuaabla (R)
cw ~ v-h H ~ ~ -+- W-4
fv H -t ~ ~middottp tJJ-- -6-- JAl s-IJ~ li lthi
o 1-n-H -Ht L~S s+-JJ ~1f- ~ ltIL __ -14 ltkgt c--1 11-Lf vltuv-1 ~ ~ -n ~ ~t-1~ ~ ~ -6v -~middotc_d ~ dG lwiW ~ -~-
fv-u middot~ _t~~~ ~
~ b jlu e I -1shymiddotmiddotmiddotmiddot middot middot~ w- -Hulmiddot11middot fl ~ -u ~ ~-tgt REGIOH I Data Review Worksheetbull ZV A VOLATILE CALIBRATION VERIPICATlOII
~
Data of Initial Calibration bulltmiddot~middot~middot~middotf~B~middotmiddotDatea of ContinuinCjJ Calibrationbull r- y1 Instrument ID 1 MatrixLevel 1 f of f llvJ
CRITERIA OUT ~ YWW RFtRSDRFtD middot eigtD cJb Ky ( )
Saaplaa Affected
ollSIgt --l dQJoL1botngtJngtbullcmiddot~3i~bullJdolkOCltJbullIjwlgtllflopound4tNL-j~yeni~Cl1Lmiddot middot ~middotlliJ)LSamplebull Affected -- - bull
Rf -~~~l~-D~kwmd~~~3~middot~Yl+n~~~~~~~L_~r~~~~~middot~)L_____Samplaa Affected
s bullbull~~ Atfected-liJlJlmiddot--rubullCLocltcUnllbulllpllth~~r~-+(~middot~__)J~----
Saaplaa Affactad------------------- shy
saaplaa Affactadlmiddot-------------------
Samplaa Affactach
Samplebull Affected IISmiddotDmiddot ckJnbull~
1 All iFbulla and RF 1a muat be gt005 ~~~~ ~ bull 333 2 All RSD 1a bulluat belt30 3 All D 1 a bulluat be lt25 gt+gt~
11~111 _lg_a zDSI ACTIOMI ~ If 10 1 If any compound haa an initial RF or a continuing RF of lt005
a Flag podtive r eaulta for that compound aa eatimated (J) bFlag non-detectbull for that compound as unusable (R) bull
2 If any compound has a RSD gt30 or a D gt25 aFlag positive results for that cornpound as estimated (J) b Flag non-detecta for that compound as estimated (UJ) if the RSO
or D ia gt50
A separate worksheet should be filled out for each initial curve
I I I I
REGION J Data Review Worksheets
JV I SEMIVOITILE CALIBRATION VERIFICATION
Date of Initial Calibration -====== Dataa of Continuin9 Calibrations~ tnatruaant ID ______
llW C2lli2l1llllCRITERIA OUT RFRSDRF0
Saaplaa Affected
Samples Affected
Saaplaa Affected
Saaplaa Affected
Saaplaa Affected
Saaplaa Affectach
Sabull plaa Affected
Saaplaa AffeCted
samples Affected
Saaplaa Affacta4
Samplaa Affactada
bull-8 N
Saaplea Affactadt
samples Afflctach
Samples Affected
Sea worksheet IV-A for criteria and actions
A new worksheet should be filled out for each initial curve
iluHot CAhv~ Z~H) bull ~~ bull z f o 1~1 t1C
REGION I Data Jteviev Worksheet
V A 111NK ANALYSIS RESULTS (Soctiono 1 2)
Liat the contamination in the blanka belov
1 Laboratory Bllnka
CONCENTftATIOM
lll1Ii
middota 1lt
2 Equipment and Trip Blanka CONCENTRAT ION[
lll1Ii shybull8 N
A separate worksheet should be used for low and media level blanks
REGION I DAtA Review Worksheets
V I BIAHJt ANALYSIS RESULTS (Section 3)
l BlAnk Actionbull
Action levelbull ahould be baeed upon the higheet concentration of contAIIinant determined in Any bhnk The Action level for aamplea vhich have been concentrAted or diluted ahould be bullultipUed by the concentrationdilution fActor No poaitive aample result ahould be reported unlaas the concentrAtion of the compound in the sAmple axceede the Action laval of 10 x a the Amount in the blAnk for the couon contAainAnta or 5 x a the aaount for any other compound Specific act i ona are bullbull follovaz
1 The c oncentr ation is l esa t han the CRQL repor t the CRQL
2 The concent r at i on i s 9reater than the CRQL but l eea than the act i on level r eport the c oncentration found u
3 The concentration Ja greater than the action level r eport the concentration unqualified
For exaaplea refer to the Regional Cuidelinea
Couon contaa inanta bull aethylene chloride acetone 2-butanone tolueneand phthalatea
MbX CONC ACTION LEVEL l1liUI l1liUI
bull middot )IQ
A aeparat~ vorksheet should be used for low and medium level blanka
-bull8 N
REGION I Data Review Workaheata
VI SURROGATE SPIKB RECOVERIU
Liat the percent racovariaa which do not bullbullbullt the criteria for aurrogata recovery
Au _-u ~ q-- 110 bull bullbull middot Matrixbull~
mJI_ TOL JIFB pep HBZ FBP TPH fHL 2PP TBP
to to to to to to to to to to
Surrogate Actiona PERCENT RECOVERY
~ ~ ~ Positive sample raaulta J J J Non-detected results R UJ A
CRR bull Contract Required Recovery Range Surrogate action should be applied
1 bull If at least two aurroatea in a BN or A fraction or one surrogate in the VOA fraction are out of specification but have recoveries of gt10
2 If any one surrogate in a fraction ahova lt10 recovery
REGION I Data Review Worksheets
fgt-100
VII A MATRIX SPIKEMATRIX SPIJa DUPLICATE
1 Matrix SpikeHatrix Spike Duplicate Recoveriea and Precision
lR )loa___ ___ lAveli~ Matrix1
List the tgtbullrcent recovariea and RPDa of coapounda whi ch do not aeet the criteriamiddot atated on Fotll J
bull-8
QUALIFICATION IS LIMITED TO THE UNSPIXED SAMPLE ONLY N 1 If any compound doea not aeet the Contraet Required Recovery range
(CRR) follow the actions stated belovt
PERCENT RECOVERY
~ ~ Poaitiva Sample Reaulta J J Non-detected Results R A
2 If any compound does not meet the RPD criteria flag positive reaulta tor that compound a a estimated (J)
A aeparate worksheet should be used for each MSMSD pair
REGION I Data Review Workaheeta Vll B MATRIX SPliCEMATRIX SPliCE DUPLICATE (Section 2)
3 Matrix Spike Duplicate - UnapUted compoundbull
TR Nos ___ ---
Liat the concentrations of the unspiked compounds and determine the percent RSDbull of the unapiked aample Jiatrix spike and matrix spike duplicate No Uaita have been developed for the RSD valuea of the unapUced compounda
SN1PLpound MS MSp CQNC
8 N
The reviewer auat uaa profeaaional judgement to datenina if there ia a need to qualify any of the unspiked compounds in the sample
REGION I Data Review Workaheeta
VIII PIELD DUPLICATE PRECISION
TR Noa___ --- Matrixamp___
Liat the concentrationbull of the compounda which do not bullbullbullt the followinc RPD criteriat middot
1 middot An RPD of lt30 for water duplicatea 2 An RPD of lt50 for aoil duplicatea
SAJ1PL CONC pup SAMPLE CONC
ACTIONS I
1 If the reaulta for any co111ponda do not bullbullbullt the RPD criteria flag the poaitive reaulta for that compound aa eatbnated
2 If one value ibull non-detected and one ia above the CRQLt a Flag the positive result aa estimated (J) b Flag the non-detected result bullbull estimated (UJ) bull
~~T=~l ~~~bull ~~Y~~lx~middot utilized to apply duplicate actionbull
A separate worksheet should be filled out for each field duplicate pair
REGIOII X Data Review Workaheeta
D DITERHAL STAJIDAIU) PERFORMAIICII tgt1 ~ -h-J-J ~ ~
Liat the internal atandard areaa of aaaplea which do not aaat the criteria of +lOOt or -50 of the internal atandard area in the aaaochtad continuing calibration atandard
OH ltZ
Hr ltlt 0-lt OJgt
00
bull-ACIIOIII
1 If an IS area count ia outaida the criteria -sot or +lOOt of the aaaociatac1 atandarch
a Poaitive reaulta for ~ompounda quantitated uaing that IS are 8flagged aa aatlmatad (J) for that aampla fraction
b Non-datacta for compound a quanti tatad uaing that IS are tlaggad ~ aa estimated (UJ) for that aampla fraction
c If extremely lov area counta ara reported or if perforanceaxhiblta a aajor drop-off than a aavara loaa of aenaitivlty ia indicated Non-detectbull ahould then be flagged aa unusable (R)
2 If an IS retention time varies more than 30 aeconda the chromatoqraphic profile tor that sample aust be examined to determine if any false positives or negatives exiat For ehifta of a large magnitucSe the reviewer may consider partial or total rejection of the cSata for that sample traction
IS OUT H ~~
Data Buaaar IbullT
A bull Acceptable data
J - The a ociated nuaerical value ia an eatibullated quantit
R - ReJect data due to qualitT control criteria Tba data are unuaable (cobullpound bullay or bullay not be preaent) Reaplinamp and reanal7aia h neceaaary for verification
U bull The coapound waa anal7aed for but waa not detected The aaaociated nuaerical value h the aaaple quantitation liait
UJ - The coapound waa anamplJamped for but waa not detected The aaaple quantitation liait h an eatiaated quantitTbull
- The coapound waa analJamped for but waa not detected Tba auple quantltation Uait ia the aua bullbull tba CRQL preaented
- barcode 581461
- barcodetext SDMS Doc ID 581461
--
aw-n-shy-middot -~~~ PINETTE$ SALVAGE YARD ootlco It lo 4oo to tho ADMINISTRATIVE RECORD
of tiM t
( ()
ftmiddottU Zllll IOmiddotSOLIl bullmiddotZOLIl ~ bull _ ZOmiddotISKt LObullWSKt
lO __
) _ -1MqAdD-Iosl
_nAiiJil _ _ _PI~I
-shy IPmiddot(-qJGbullZL 1-ltpeIPl
~IPIIJmiddotSZL ~~~JM1middotZZLL
~Jiipela-1-ZLLL
--n-qta-zL IPIImiddotSL
-pMMJipttt-ZL1 ~_
_UINOIIIPIIJ _IIIPIIbullLL IIIPII-Zl -liPI~ _J-J
PJJllpJIJ-1
lPIImiddotZZ ~-IPII-ZL___
(IHelP-IIPio-Zl --p-lPII-11
-p-middot~ ~-IIPIOLl
~ __ middotmiddotmiddotmiddot1(1-~
bulltIOJIIO lAYJA
_ - ~
=middot---~ =IIOIlwJOlJWflfl
wsesmiddot swsan _ l olllall4 11111
nUrn-shymiddot---tlllo
It lo M to tho PINETTES SALVAGE YARD ADMINISTRATIVE RECORD
tiiiHcunt
c u
bull middot11middot1 61bull11 bull1 dlbulllH IOJZAJlfG bull middotn middotl bull u-a bull middotUmiddotI bullmiddotu-a =Gi1oMS Jlyen0
zmm~ ICIIUTIIO
--zutqAit~JJJbullStl
-qiAitlbullfIJmiddottll -~IPIJ1bulltZl
-~IIPfJJbull[l l
_)AIIu
-IIIOAIPtomiddottl -~lfllmiddotll -1Wq1Alftl-shy
JO)OJOIIO-t -10)010110-Z
~IAvllbull-)
-)AJIdo
ft-fUtl lltl bull-so 110-anw - shy n~~n~nbullrs 11)1JrJ01J~
amiddotm VW[t middotowns lftV3 _bullubull ~essou8Utbull bullJus
REGION I Site Name f~ tJ middot~ $1 VdData Review Workaheeta Reference Number
REGION I REVIEW OP ORGANIC CONTRACT lABORATORY DATA PACJtAGB
rbullbull The hardeopied (laboratory name) eM bull u~ftmiddotLi data package received at Region I haa been reviewed and the qual ty aaurance and performancedata ampWIIlllarhed The data review included1
Caae No ~ SU No~ Saaplinq Date(a) l middot tlmiddottbull SDG No -btUeL Matrix ~ Shippinq Date(a) l middot u middotbulls No of Samp~ea__l_ ~d ~l~ 1 Date Recd by Lab ------ -- shy
Traffic Report Noa j~1SA- ol MSA -oa 01 1UU-oot
Trip Blank No Equipbullent Blank lfot Pield Dup Noe l
sow No requirebull that apecific analytical work be done and that aaaoclated reportbull be provided by the laboratory to the Reqiona EMSL-LV and ampMO The qeneral criteria uaed to deterwine the perfonance were baaed on an exabullination ofa
-Data Cobullpleteneaa -Matrix SpikeMatrix Spike Dup-HoldiiiCJ TiHe -Pield Duplicatebull -GCMS Tuni119 -Internal Standard Perfo1111ance -calibrationa -Peaticide Inat Perforaance -BlanJta -compound Identification -surroqate Recoveriea -co11pound Quantitation
OVerall couenta shyIIIMJ dW k b ~ bull8
Definitionbull and Qualifiera ~ A - Acceptable data J - Approximate data due to quality control criteria R - Reject data due to quality control criteria V - Compound not detected middotmiddot
u middot ff
Reviewerbull _____v_-~=J4==lt----- Date _ __1_-_~___r____ middot
REGION I Data Revev Workahebulltbull
I DATA COMPLETENESS
MISSING INFORMATION DATE LlB CONTAkiED DATE RECbullp
11 pound100lt db sJ_ rnA A t1tz -6_ iJiiuob J 41 rIbull-Jb bY- bull 1 ltbull+W Je cJw NAP emzht1i-rJ ~ 6YcfplciJl s9bW middot ttryy cJp -1 middot1middot
--- ------------
______
----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- ------- ----- ----- ------ ------ --------- ------- ----- ----- ------ ----- ------
REGION I Data Review Workaheeta
II HOLDING TIMES Complete table for all aa1r1plea and circle the fract ionbull which are not within criteria middot
VOA BNA PEST SAMPLE DATE DATE DATE
ID SAMPLED ANAL EXTR
~~AmiddotDI ~~---
~~UA middot6bull plusmn ~ NA
~~1-A middotCS l-11middottbull NA
~nsH~ ________ I-IH1 ~
DATE DATE ANAL EXTR
DATE ANAL
~ ~
-
~
VOA - Unpreaervedt Aromatic within 7 daya non-aromatic within 14 daya of aample collection Preaerved t Both within 14 daya of aample collection Soila t Both within 14 daya of bullbullbullple collection
BNA PEST - Extracted within 7 daya analyzed within 40 daya aoih ancS water
ACTION t 1 If holding timea are exceeded all poaitive results are eatimate
(J) and non-detecta are eatimated (UJ) 2 middotIf holding timea are groaaly exceeded the reviewer may
determine that non-detecta are unusable(bull)
-bull8 N
REGION 1 Data Review Workaheeta
111 CCfMS IUMINC
The DFTPP pertor111ance reaulta were reviewed and found to be within the apecifia4 criteria
If no lgtllOMSabullplaa affected____________________ ltZ ~ z-o ~ -oltlTha BFB performance raaulta ware raviawad and found to be within
the apacifiad criteria ~rIr no ltlt Sabullplaa affactacl____________________ 0-lt Olgt
00If aaaa calibration ia in error refer to tha Raion quidalinaa for expanded criteria If nacaaaary all aaaociatad data bullbull unuaabla (R)
cw ~ v-h H ~ ~ -+- W-4
fv H -t ~ ~middottp tJJ-- -6-- JAl s-IJ~ li lthi
o 1-n-H -Ht L~S s+-JJ ~1f- ~ ltIL __ -14 ltkgt c--1 11-Lf vltuv-1 ~ ~ -n ~ ~t-1~ ~ ~ -6v -~middotc_d ~ dG lwiW ~ -~-
fv-u middot~ _t~~~ ~
~ b jlu e I -1shymiddotmiddotmiddotmiddot middot middot~ w- -Hulmiddot11middot fl ~ -u ~ ~-tgt REGIOH I Data Review Worksheetbull ZV A VOLATILE CALIBRATION VERIPICATlOII
~
Data of Initial Calibration bulltmiddot~middot~middot~middotf~B~middotmiddotDatea of ContinuinCjJ Calibrationbull r- y1 Instrument ID 1 MatrixLevel 1 f of f llvJ
CRITERIA OUT ~ YWW RFtRSDRFtD middot eigtD cJb Ky ( )
Saaplaa Affected
ollSIgt --l dQJoL1botngtJngtbullcmiddot~3i~bullJdolkOCltJbullIjwlgtllflopound4tNL-j~yeni~Cl1Lmiddot middot ~middotlliJ)LSamplebull Affected -- - bull
Rf -~~~l~-D~kwmd~~~3~middot~Yl+n~~~~~~~L_~r~~~~~middot~)L_____Samplaa Affected
s bullbull~~ Atfected-liJlJlmiddot--rubullCLocltcUnllbulllpllth~~r~-+(~middot~__)J~----
Saaplaa Affactad------------------- shy
saaplaa Affactadlmiddot-------------------
Samplaa Affactach
Samplebull Affected IISmiddotDmiddot ckJnbull~
1 All iFbulla and RF 1a muat be gt005 ~~~~ ~ bull 333 2 All RSD 1a bulluat belt30 3 All D 1 a bulluat be lt25 gt+gt~
11~111 _lg_a zDSI ACTIOMI ~ If 10 1 If any compound haa an initial RF or a continuing RF of lt005
a Flag podtive r eaulta for that compound aa eatimated (J) bFlag non-detectbull for that compound as unusable (R) bull
2 If any compound has a RSD gt30 or a D gt25 aFlag positive results for that cornpound as estimated (J) b Flag non-detecta for that compound as estimated (UJ) if the RSO
or D ia gt50
A separate worksheet should be filled out for each initial curve
I I I I
REGION J Data Review Worksheets
JV I SEMIVOITILE CALIBRATION VERIFICATION
Date of Initial Calibration -====== Dataa of Continuin9 Calibrations~ tnatruaant ID ______
llW C2lli2l1llllCRITERIA OUT RFRSDRF0
Saaplaa Affected
Samples Affected
Saaplaa Affected
Saaplaa Affected
Saaplaa Affected
Saaplaa Affectach
Sabull plaa Affected
Saaplaa AffeCted
samples Affected
Saaplaa Affacta4
Samplaa Affactada
bull-8 N
Saaplea Affactadt
samples Afflctach
Samples Affected
Sea worksheet IV-A for criteria and actions
A new worksheet should be filled out for each initial curve
iluHot CAhv~ Z~H) bull ~~ bull z f o 1~1 t1C
REGION I Data Jteviev Worksheet
V A 111NK ANALYSIS RESULTS (Soctiono 1 2)
Liat the contamination in the blanka belov
1 Laboratory Bllnka
CONCENTftATIOM
lll1Ii
middota 1lt
2 Equipment and Trip Blanka CONCENTRAT ION[
lll1Ii shybull8 N
A separate worksheet should be used for low and media level blanks
REGION I DAtA Review Worksheets
V I BIAHJt ANALYSIS RESULTS (Section 3)
l BlAnk Actionbull
Action levelbull ahould be baeed upon the higheet concentration of contAIIinant determined in Any bhnk The Action level for aamplea vhich have been concentrAted or diluted ahould be bullultipUed by the concentrationdilution fActor No poaitive aample result ahould be reported unlaas the concentrAtion of the compound in the sAmple axceede the Action laval of 10 x a the Amount in the blAnk for the couon contAainAnta or 5 x a the aaount for any other compound Specific act i ona are bullbull follovaz
1 The c oncentr ation is l esa t han the CRQL repor t the CRQL
2 The concent r at i on i s 9reater than the CRQL but l eea than the act i on level r eport the c oncentration found u
3 The concentration Ja greater than the action level r eport the concentration unqualified
For exaaplea refer to the Regional Cuidelinea
Couon contaa inanta bull aethylene chloride acetone 2-butanone tolueneand phthalatea
MbX CONC ACTION LEVEL l1liUI l1liUI
bull middot )IQ
A aeparat~ vorksheet should be used for low and medium level blanka
-bull8 N
REGION I Data Review Workaheata
VI SURROGATE SPIKB RECOVERIU
Liat the percent racovariaa which do not bullbullbullt the criteria for aurrogata recovery
Au _-u ~ q-- 110 bull bullbull middot Matrixbull~
mJI_ TOL JIFB pep HBZ FBP TPH fHL 2PP TBP
to to to to to to to to to to
Surrogate Actiona PERCENT RECOVERY
~ ~ ~ Positive sample raaulta J J J Non-detected results R UJ A
CRR bull Contract Required Recovery Range Surrogate action should be applied
1 bull If at least two aurroatea in a BN or A fraction or one surrogate in the VOA fraction are out of specification but have recoveries of gt10
2 If any one surrogate in a fraction ahova lt10 recovery
REGION I Data Review Worksheets
fgt-100
VII A MATRIX SPIKEMATRIX SPIJa DUPLICATE
1 Matrix SpikeHatrix Spike Duplicate Recoveriea and Precision
lR )loa___ ___ lAveli~ Matrix1
List the tgtbullrcent recovariea and RPDa of coapounda whi ch do not aeet the criteriamiddot atated on Fotll J
bull-8
QUALIFICATION IS LIMITED TO THE UNSPIXED SAMPLE ONLY N 1 If any compound doea not aeet the Contraet Required Recovery range
(CRR) follow the actions stated belovt
PERCENT RECOVERY
~ ~ Poaitiva Sample Reaulta J J Non-detected Results R A
2 If any compound does not meet the RPD criteria flag positive reaulta tor that compound a a estimated (J)
A aeparate worksheet should be used for each MSMSD pair
REGION I Data Review Workaheeta Vll B MATRIX SPliCEMATRIX SPliCE DUPLICATE (Section 2)
3 Matrix Spike Duplicate - UnapUted compoundbull
TR Nos ___ ---
Liat the concentrations of the unspiked compounds and determine the percent RSDbull of the unapiked aample Jiatrix spike and matrix spike duplicate No Uaita have been developed for the RSD valuea of the unapUced compounda
SN1PLpound MS MSp CQNC
8 N
The reviewer auat uaa profeaaional judgement to datenina if there ia a need to qualify any of the unspiked compounds in the sample
REGION I Data Review Workaheeta
VIII PIELD DUPLICATE PRECISION
TR Noa___ --- Matrixamp___
Liat the concentrationbull of the compounda which do not bullbullbullt the followinc RPD criteriat middot
1 middot An RPD of lt30 for water duplicatea 2 An RPD of lt50 for aoil duplicatea
SAJ1PL CONC pup SAMPLE CONC
ACTIONS I
1 If the reaulta for any co111ponda do not bullbullbullt the RPD criteria flag the poaitive reaulta for that compound aa eatbnated
2 If one value ibull non-detected and one ia above the CRQLt a Flag the positive result aa estimated (J) b Flag the non-detected result bullbull estimated (UJ) bull
~~T=~l ~~~bull ~~Y~~lx~middot utilized to apply duplicate actionbull
A separate worksheet should be filled out for each field duplicate pair
REGIOII X Data Review Workaheeta
D DITERHAL STAJIDAIU) PERFORMAIICII tgt1 ~ -h-J-J ~ ~
Liat the internal atandard areaa of aaaplea which do not aaat the criteria of +lOOt or -50 of the internal atandard area in the aaaochtad continuing calibration atandard
OH ltZ
Hr ltlt 0-lt OJgt
00
bull-ACIIOIII
1 If an IS area count ia outaida the criteria -sot or +lOOt of the aaaociatac1 atandarch
a Poaitive reaulta for ~ompounda quantitated uaing that IS are 8flagged aa aatlmatad (J) for that aampla fraction
b Non-datacta for compound a quanti tatad uaing that IS are tlaggad ~ aa estimated (UJ) for that aampla fraction
c If extremely lov area counta ara reported or if perforanceaxhiblta a aajor drop-off than a aavara loaa of aenaitivlty ia indicated Non-detectbull ahould then be flagged aa unusable (R)
2 If an IS retention time varies more than 30 aeconda the chromatoqraphic profile tor that sample aust be examined to determine if any false positives or negatives exiat For ehifta of a large magnitucSe the reviewer may consider partial or total rejection of the cSata for that sample traction
IS OUT H ~~
Data Buaaar IbullT
A bull Acceptable data
J - The a ociated nuaerical value ia an eatibullated quantit
R - ReJect data due to qualitT control criteria Tba data are unuaable (cobullpound bullay or bullay not be preaent) Reaplinamp and reanal7aia h neceaaary for verification
U bull The coapound waa anal7aed for but waa not detected The aaaociated nuaerical value h the aaaple quantitation liait
UJ - The coapound waa anamplJamped for but waa not detected The aaaple quantitation liait h an eatiaated quantitTbull
- The coapound waa analJamped for but waa not detected Tba auple quantltation Uait ia the aua bullbull tba CRQL preaented
- barcode 581461
- barcodetext SDMS Doc ID 581461
nUrn-shymiddot---tlllo
It lo M to tho PINETTES SALVAGE YARD ADMINISTRATIVE RECORD
tiiiHcunt
c u
bull middot11middot1 61bull11 bull1 dlbulllH IOJZAJlfG bull middotn middotl bull u-a bull middotUmiddotI bullmiddotu-a =Gi1oMS Jlyen0
zmm~ ICIIUTIIO
--zutqAit~JJJbullStl
-qiAitlbullfIJmiddottll -~IPIJ1bulltZl
-~IIPfJJbull[l l
_)AIIu
-IIIOAIPtomiddottl -~lfllmiddotll -1Wq1Alftl-shy
JO)OJOIIO-t -10)010110-Z
~IAvllbull-)
-)AJIdo
ft-fUtl lltl bull-so 110-anw - shy n~~n~nbullrs 11)1JrJ01J~
amiddotm VW[t middotowns lftV3 _bullubull ~essou8Utbull bullJus
REGION I Site Name f~ tJ middot~ $1 VdData Review Workaheeta Reference Number
REGION I REVIEW OP ORGANIC CONTRACT lABORATORY DATA PACJtAGB
rbullbull The hardeopied (laboratory name) eM bull u~ftmiddotLi data package received at Region I haa been reviewed and the qual ty aaurance and performancedata ampWIIlllarhed The data review included1
Caae No ~ SU No~ Saaplinq Date(a) l middot tlmiddottbull SDG No -btUeL Matrix ~ Shippinq Date(a) l middot u middotbulls No of Samp~ea__l_ ~d ~l~ 1 Date Recd by Lab ------ -- shy
Traffic Report Noa j~1SA- ol MSA -oa 01 1UU-oot
Trip Blank No Equipbullent Blank lfot Pield Dup Noe l
sow No requirebull that apecific analytical work be done and that aaaoclated reportbull be provided by the laboratory to the Reqiona EMSL-LV and ampMO The qeneral criteria uaed to deterwine the perfonance were baaed on an exabullination ofa
-Data Cobullpleteneaa -Matrix SpikeMatrix Spike Dup-HoldiiiCJ TiHe -Pield Duplicatebull -GCMS Tuni119 -Internal Standard Perfo1111ance -calibrationa -Peaticide Inat Perforaance -BlanJta -compound Identification -surroqate Recoveriea -co11pound Quantitation
OVerall couenta shyIIIMJ dW k b ~ bull8
Definitionbull and Qualifiera ~ A - Acceptable data J - Approximate data due to quality control criteria R - Reject data due to quality control criteria V - Compound not detected middotmiddot
u middot ff
Reviewerbull _____v_-~=J4==lt----- Date _ __1_-_~___r____ middot
REGION I Data Revev Workahebulltbull
I DATA COMPLETENESS
MISSING INFORMATION DATE LlB CONTAkiED DATE RECbullp
11 pound100lt db sJ_ rnA A t1tz -6_ iJiiuob J 41 rIbull-Jb bY- bull 1 ltbull+W Je cJw NAP emzht1i-rJ ~ 6YcfplciJl s9bW middot ttryy cJp -1 middot1middot
--- ------------
______
----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- ------- ----- ----- ------ ------ --------- ------- ----- ----- ------ ----- ------
REGION I Data Review Workaheeta
II HOLDING TIMES Complete table for all aa1r1plea and circle the fract ionbull which are not within criteria middot
VOA BNA PEST SAMPLE DATE DATE DATE
ID SAMPLED ANAL EXTR
~~AmiddotDI ~~---
~~UA middot6bull plusmn ~ NA
~~1-A middotCS l-11middottbull NA
~nsH~ ________ I-IH1 ~
DATE DATE ANAL EXTR
DATE ANAL
~ ~
-
~
VOA - Unpreaervedt Aromatic within 7 daya non-aromatic within 14 daya of aample collection Preaerved t Both within 14 daya of aample collection Soila t Both within 14 daya of bullbullbullple collection
BNA PEST - Extracted within 7 daya analyzed within 40 daya aoih ancS water
ACTION t 1 If holding timea are exceeded all poaitive results are eatimate
(J) and non-detecta are eatimated (UJ) 2 middotIf holding timea are groaaly exceeded the reviewer may
determine that non-detecta are unusable(bull)
-bull8 N
REGION 1 Data Review Workaheeta
111 CCfMS IUMINC
The DFTPP pertor111ance reaulta were reviewed and found to be within the apecifia4 criteria
If no lgtllOMSabullplaa affected____________________ ltZ ~ z-o ~ -oltlTha BFB performance raaulta ware raviawad and found to be within
the apacifiad criteria ~rIr no ltlt Sabullplaa affactacl____________________ 0-lt Olgt
00If aaaa calibration ia in error refer to tha Raion quidalinaa for expanded criteria If nacaaaary all aaaociatad data bullbull unuaabla (R)
cw ~ v-h H ~ ~ -+- W-4
fv H -t ~ ~middottp tJJ-- -6-- JAl s-IJ~ li lthi
o 1-n-H -Ht L~S s+-JJ ~1f- ~ ltIL __ -14 ltkgt c--1 11-Lf vltuv-1 ~ ~ -n ~ ~t-1~ ~ ~ -6v -~middotc_d ~ dG lwiW ~ -~-
fv-u middot~ _t~~~ ~
~ b jlu e I -1shymiddotmiddotmiddotmiddot middot middot~ w- -Hulmiddot11middot fl ~ -u ~ ~-tgt REGIOH I Data Review Worksheetbull ZV A VOLATILE CALIBRATION VERIPICATlOII
~
Data of Initial Calibration bulltmiddot~middot~middot~middotf~B~middotmiddotDatea of ContinuinCjJ Calibrationbull r- y1 Instrument ID 1 MatrixLevel 1 f of f llvJ
CRITERIA OUT ~ YWW RFtRSDRFtD middot eigtD cJb Ky ( )
Saaplaa Affected
ollSIgt --l dQJoL1botngtJngtbullcmiddot~3i~bullJdolkOCltJbullIjwlgtllflopound4tNL-j~yeni~Cl1Lmiddot middot ~middotlliJ)LSamplebull Affected -- - bull
Rf -~~~l~-D~kwmd~~~3~middot~Yl+n~~~~~~~L_~r~~~~~middot~)L_____Samplaa Affected
s bullbull~~ Atfected-liJlJlmiddot--rubullCLocltcUnllbulllpllth~~r~-+(~middot~__)J~----
Saaplaa Affactad------------------- shy
saaplaa Affactadlmiddot-------------------
Samplaa Affactach
Samplebull Affected IISmiddotDmiddot ckJnbull~
1 All iFbulla and RF 1a muat be gt005 ~~~~ ~ bull 333 2 All RSD 1a bulluat belt30 3 All D 1 a bulluat be lt25 gt+gt~
11~111 _lg_a zDSI ACTIOMI ~ If 10 1 If any compound haa an initial RF or a continuing RF of lt005
a Flag podtive r eaulta for that compound aa eatimated (J) bFlag non-detectbull for that compound as unusable (R) bull
2 If any compound has a RSD gt30 or a D gt25 aFlag positive results for that cornpound as estimated (J) b Flag non-detecta for that compound as estimated (UJ) if the RSO
or D ia gt50
A separate worksheet should be filled out for each initial curve
I I I I
REGION J Data Review Worksheets
JV I SEMIVOITILE CALIBRATION VERIFICATION
Date of Initial Calibration -====== Dataa of Continuin9 Calibrations~ tnatruaant ID ______
llW C2lli2l1llllCRITERIA OUT RFRSDRF0
Saaplaa Affected
Samples Affected
Saaplaa Affected
Saaplaa Affected
Saaplaa Affected
Saaplaa Affectach
Sabull plaa Affected
Saaplaa AffeCted
samples Affected
Saaplaa Affacta4
Samplaa Affactada
bull-8 N
Saaplea Affactadt
samples Afflctach
Samples Affected
Sea worksheet IV-A for criteria and actions
A new worksheet should be filled out for each initial curve
iluHot CAhv~ Z~H) bull ~~ bull z f o 1~1 t1C
REGION I Data Jteviev Worksheet
V A 111NK ANALYSIS RESULTS (Soctiono 1 2)
Liat the contamination in the blanka belov
1 Laboratory Bllnka
CONCENTftATIOM
lll1Ii
middota 1lt
2 Equipment and Trip Blanka CONCENTRAT ION[
lll1Ii shybull8 N
A separate worksheet should be used for low and media level blanks
REGION I DAtA Review Worksheets
V I BIAHJt ANALYSIS RESULTS (Section 3)
l BlAnk Actionbull
Action levelbull ahould be baeed upon the higheet concentration of contAIIinant determined in Any bhnk The Action level for aamplea vhich have been concentrAted or diluted ahould be bullultipUed by the concentrationdilution fActor No poaitive aample result ahould be reported unlaas the concentrAtion of the compound in the sAmple axceede the Action laval of 10 x a the Amount in the blAnk for the couon contAainAnta or 5 x a the aaount for any other compound Specific act i ona are bullbull follovaz
1 The c oncentr ation is l esa t han the CRQL repor t the CRQL
2 The concent r at i on i s 9reater than the CRQL but l eea than the act i on level r eport the c oncentration found u
3 The concentration Ja greater than the action level r eport the concentration unqualified
For exaaplea refer to the Regional Cuidelinea
Couon contaa inanta bull aethylene chloride acetone 2-butanone tolueneand phthalatea
MbX CONC ACTION LEVEL l1liUI l1liUI
bull middot )IQ
A aeparat~ vorksheet should be used for low and medium level blanka
-bull8 N
REGION I Data Review Workaheata
VI SURROGATE SPIKB RECOVERIU
Liat the percent racovariaa which do not bullbullbullt the criteria for aurrogata recovery
Au _-u ~ q-- 110 bull bullbull middot Matrixbull~
mJI_ TOL JIFB pep HBZ FBP TPH fHL 2PP TBP
to to to to to to to to to to
Surrogate Actiona PERCENT RECOVERY
~ ~ ~ Positive sample raaulta J J J Non-detected results R UJ A
CRR bull Contract Required Recovery Range Surrogate action should be applied
1 bull If at least two aurroatea in a BN or A fraction or one surrogate in the VOA fraction are out of specification but have recoveries of gt10
2 If any one surrogate in a fraction ahova lt10 recovery
REGION I Data Review Worksheets
fgt-100
VII A MATRIX SPIKEMATRIX SPIJa DUPLICATE
1 Matrix SpikeHatrix Spike Duplicate Recoveriea and Precision
lR )loa___ ___ lAveli~ Matrix1
List the tgtbullrcent recovariea and RPDa of coapounda whi ch do not aeet the criteriamiddot atated on Fotll J
bull-8
QUALIFICATION IS LIMITED TO THE UNSPIXED SAMPLE ONLY N 1 If any compound doea not aeet the Contraet Required Recovery range
(CRR) follow the actions stated belovt
PERCENT RECOVERY
~ ~ Poaitiva Sample Reaulta J J Non-detected Results R A
2 If any compound does not meet the RPD criteria flag positive reaulta tor that compound a a estimated (J)
A aeparate worksheet should be used for each MSMSD pair
REGION I Data Review Workaheeta Vll B MATRIX SPliCEMATRIX SPliCE DUPLICATE (Section 2)
3 Matrix Spike Duplicate - UnapUted compoundbull
TR Nos ___ ---
Liat the concentrations of the unspiked compounds and determine the percent RSDbull of the unapiked aample Jiatrix spike and matrix spike duplicate No Uaita have been developed for the RSD valuea of the unapUced compounda
SN1PLpound MS MSp CQNC
8 N
The reviewer auat uaa profeaaional judgement to datenina if there ia a need to qualify any of the unspiked compounds in the sample
REGION I Data Review Workaheeta
VIII PIELD DUPLICATE PRECISION
TR Noa___ --- Matrixamp___
Liat the concentrationbull of the compounda which do not bullbullbullt the followinc RPD criteriat middot
1 middot An RPD of lt30 for water duplicatea 2 An RPD of lt50 for aoil duplicatea
SAJ1PL CONC pup SAMPLE CONC
ACTIONS I
1 If the reaulta for any co111ponda do not bullbullbullt the RPD criteria flag the poaitive reaulta for that compound aa eatbnated
2 If one value ibull non-detected and one ia above the CRQLt a Flag the positive result aa estimated (J) b Flag the non-detected result bullbull estimated (UJ) bull
~~T=~l ~~~bull ~~Y~~lx~middot utilized to apply duplicate actionbull
A separate worksheet should be filled out for each field duplicate pair
REGIOII X Data Review Workaheeta
D DITERHAL STAJIDAIU) PERFORMAIICII tgt1 ~ -h-J-J ~ ~
Liat the internal atandard areaa of aaaplea which do not aaat the criteria of +lOOt or -50 of the internal atandard area in the aaaochtad continuing calibration atandard
OH ltZ
Hr ltlt 0-lt OJgt
00
bull-ACIIOIII
1 If an IS area count ia outaida the criteria -sot or +lOOt of the aaaociatac1 atandarch
a Poaitive reaulta for ~ompounda quantitated uaing that IS are 8flagged aa aatlmatad (J) for that aampla fraction
b Non-datacta for compound a quanti tatad uaing that IS are tlaggad ~ aa estimated (UJ) for that aampla fraction
c If extremely lov area counta ara reported or if perforanceaxhiblta a aajor drop-off than a aavara loaa of aenaitivlty ia indicated Non-detectbull ahould then be flagged aa unusable (R)
2 If an IS retention time varies more than 30 aeconda the chromatoqraphic profile tor that sample aust be examined to determine if any false positives or negatives exiat For ehifta of a large magnitucSe the reviewer may consider partial or total rejection of the cSata for that sample traction
IS OUT H ~~
Data Buaaar IbullT
A bull Acceptable data
J - The a ociated nuaerical value ia an eatibullated quantit
R - ReJect data due to qualitT control criteria Tba data are unuaable (cobullpound bullay or bullay not be preaent) Reaplinamp and reanal7aia h neceaaary for verification
U bull The coapound waa anal7aed for but waa not detected The aaaociated nuaerical value h the aaaple quantitation liait
UJ - The coapound waa anamplJamped for but waa not detected The aaaple quantitation liait h an eatiaated quantitTbull
- The coapound waa analJamped for but waa not detected Tba auple quantltation Uait ia the aua bullbull tba CRQL preaented
- barcode 581461
- barcodetext SDMS Doc ID 581461
REGION I Site Name f~ tJ middot~ $1 VdData Review Workaheeta Reference Number
REGION I REVIEW OP ORGANIC CONTRACT lABORATORY DATA PACJtAGB
rbullbull The hardeopied (laboratory name) eM bull u~ftmiddotLi data package received at Region I haa been reviewed and the qual ty aaurance and performancedata ampWIIlllarhed The data review included1
Caae No ~ SU No~ Saaplinq Date(a) l middot tlmiddottbull SDG No -btUeL Matrix ~ Shippinq Date(a) l middot u middotbulls No of Samp~ea__l_ ~d ~l~ 1 Date Recd by Lab ------ -- shy
Traffic Report Noa j~1SA- ol MSA -oa 01 1UU-oot
Trip Blank No Equipbullent Blank lfot Pield Dup Noe l
sow No requirebull that apecific analytical work be done and that aaaoclated reportbull be provided by the laboratory to the Reqiona EMSL-LV and ampMO The qeneral criteria uaed to deterwine the perfonance were baaed on an exabullination ofa
-Data Cobullpleteneaa -Matrix SpikeMatrix Spike Dup-HoldiiiCJ TiHe -Pield Duplicatebull -GCMS Tuni119 -Internal Standard Perfo1111ance -calibrationa -Peaticide Inat Perforaance -BlanJta -compound Identification -surroqate Recoveriea -co11pound Quantitation
OVerall couenta shyIIIMJ dW k b ~ bull8
Definitionbull and Qualifiera ~ A - Acceptable data J - Approximate data due to quality control criteria R - Reject data due to quality control criteria V - Compound not detected middotmiddot
u middot ff
Reviewerbull _____v_-~=J4==lt----- Date _ __1_-_~___r____ middot
REGION I Data Revev Workahebulltbull
I DATA COMPLETENESS
MISSING INFORMATION DATE LlB CONTAkiED DATE RECbullp
11 pound100lt db sJ_ rnA A t1tz -6_ iJiiuob J 41 rIbull-Jb bY- bull 1 ltbull+W Je cJw NAP emzht1i-rJ ~ 6YcfplciJl s9bW middot ttryy cJp -1 middot1middot
--- ------------
______
----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- ------- ----- ----- ------ ------ --------- ------- ----- ----- ------ ----- ------
REGION I Data Review Workaheeta
II HOLDING TIMES Complete table for all aa1r1plea and circle the fract ionbull which are not within criteria middot
VOA BNA PEST SAMPLE DATE DATE DATE
ID SAMPLED ANAL EXTR
~~AmiddotDI ~~---
~~UA middot6bull plusmn ~ NA
~~1-A middotCS l-11middottbull NA
~nsH~ ________ I-IH1 ~
DATE DATE ANAL EXTR
DATE ANAL
~ ~
-
~
VOA - Unpreaervedt Aromatic within 7 daya non-aromatic within 14 daya of aample collection Preaerved t Both within 14 daya of aample collection Soila t Both within 14 daya of bullbullbullple collection
BNA PEST - Extracted within 7 daya analyzed within 40 daya aoih ancS water
ACTION t 1 If holding timea are exceeded all poaitive results are eatimate
(J) and non-detecta are eatimated (UJ) 2 middotIf holding timea are groaaly exceeded the reviewer may
determine that non-detecta are unusable(bull)
-bull8 N
REGION 1 Data Review Workaheeta
111 CCfMS IUMINC
The DFTPP pertor111ance reaulta were reviewed and found to be within the apecifia4 criteria
If no lgtllOMSabullplaa affected____________________ ltZ ~ z-o ~ -oltlTha BFB performance raaulta ware raviawad and found to be within
the apacifiad criteria ~rIr no ltlt Sabullplaa affactacl____________________ 0-lt Olgt
00If aaaa calibration ia in error refer to tha Raion quidalinaa for expanded criteria If nacaaaary all aaaociatad data bullbull unuaabla (R)
cw ~ v-h H ~ ~ -+- W-4
fv H -t ~ ~middottp tJJ-- -6-- JAl s-IJ~ li lthi
o 1-n-H -Ht L~S s+-JJ ~1f- ~ ltIL __ -14 ltkgt c--1 11-Lf vltuv-1 ~ ~ -n ~ ~t-1~ ~ ~ -6v -~middotc_d ~ dG lwiW ~ -~-
fv-u middot~ _t~~~ ~
~ b jlu e I -1shymiddotmiddotmiddotmiddot middot middot~ w- -Hulmiddot11middot fl ~ -u ~ ~-tgt REGIOH I Data Review Worksheetbull ZV A VOLATILE CALIBRATION VERIPICATlOII
~
Data of Initial Calibration bulltmiddot~middot~middot~middotf~B~middotmiddotDatea of ContinuinCjJ Calibrationbull r- y1 Instrument ID 1 MatrixLevel 1 f of f llvJ
CRITERIA OUT ~ YWW RFtRSDRFtD middot eigtD cJb Ky ( )
Saaplaa Affected
ollSIgt --l dQJoL1botngtJngtbullcmiddot~3i~bullJdolkOCltJbullIjwlgtllflopound4tNL-j~yeni~Cl1Lmiddot middot ~middotlliJ)LSamplebull Affected -- - bull
Rf -~~~l~-D~kwmd~~~3~middot~Yl+n~~~~~~~L_~r~~~~~middot~)L_____Samplaa Affected
s bullbull~~ Atfected-liJlJlmiddot--rubullCLocltcUnllbulllpllth~~r~-+(~middot~__)J~----
Saaplaa Affactad------------------- shy
saaplaa Affactadlmiddot-------------------
Samplaa Affactach
Samplebull Affected IISmiddotDmiddot ckJnbull~
1 All iFbulla and RF 1a muat be gt005 ~~~~ ~ bull 333 2 All RSD 1a bulluat belt30 3 All D 1 a bulluat be lt25 gt+gt~
11~111 _lg_a zDSI ACTIOMI ~ If 10 1 If any compound haa an initial RF or a continuing RF of lt005
a Flag podtive r eaulta for that compound aa eatimated (J) bFlag non-detectbull for that compound as unusable (R) bull
2 If any compound has a RSD gt30 or a D gt25 aFlag positive results for that cornpound as estimated (J) b Flag non-detecta for that compound as estimated (UJ) if the RSO
or D ia gt50
A separate worksheet should be filled out for each initial curve
I I I I
REGION J Data Review Worksheets
JV I SEMIVOITILE CALIBRATION VERIFICATION
Date of Initial Calibration -====== Dataa of Continuin9 Calibrations~ tnatruaant ID ______
llW C2lli2l1llllCRITERIA OUT RFRSDRF0
Saaplaa Affected
Samples Affected
Saaplaa Affected
Saaplaa Affected
Saaplaa Affected
Saaplaa Affectach
Sabull plaa Affected
Saaplaa AffeCted
samples Affected
Saaplaa Affacta4
Samplaa Affactada
bull-8 N
Saaplea Affactadt
samples Afflctach
Samples Affected
Sea worksheet IV-A for criteria and actions
A new worksheet should be filled out for each initial curve
iluHot CAhv~ Z~H) bull ~~ bull z f o 1~1 t1C
REGION I Data Jteviev Worksheet
V A 111NK ANALYSIS RESULTS (Soctiono 1 2)
Liat the contamination in the blanka belov
1 Laboratory Bllnka
CONCENTftATIOM
lll1Ii
middota 1lt
2 Equipment and Trip Blanka CONCENTRAT ION[
lll1Ii shybull8 N
A separate worksheet should be used for low and media level blanks
REGION I DAtA Review Worksheets
V I BIAHJt ANALYSIS RESULTS (Section 3)
l BlAnk Actionbull
Action levelbull ahould be baeed upon the higheet concentration of contAIIinant determined in Any bhnk The Action level for aamplea vhich have been concentrAted or diluted ahould be bullultipUed by the concentrationdilution fActor No poaitive aample result ahould be reported unlaas the concentrAtion of the compound in the sAmple axceede the Action laval of 10 x a the Amount in the blAnk for the couon contAainAnta or 5 x a the aaount for any other compound Specific act i ona are bullbull follovaz
1 The c oncentr ation is l esa t han the CRQL repor t the CRQL
2 The concent r at i on i s 9reater than the CRQL but l eea than the act i on level r eport the c oncentration found u
3 The concentration Ja greater than the action level r eport the concentration unqualified
For exaaplea refer to the Regional Cuidelinea
Couon contaa inanta bull aethylene chloride acetone 2-butanone tolueneand phthalatea
MbX CONC ACTION LEVEL l1liUI l1liUI
bull middot )IQ
A aeparat~ vorksheet should be used for low and medium level blanka
-bull8 N
REGION I Data Review Workaheata
VI SURROGATE SPIKB RECOVERIU
Liat the percent racovariaa which do not bullbullbullt the criteria for aurrogata recovery
Au _-u ~ q-- 110 bull bullbull middot Matrixbull~
mJI_ TOL JIFB pep HBZ FBP TPH fHL 2PP TBP
to to to to to to to to to to
Surrogate Actiona PERCENT RECOVERY
~ ~ ~ Positive sample raaulta J J J Non-detected results R UJ A
CRR bull Contract Required Recovery Range Surrogate action should be applied
1 bull If at least two aurroatea in a BN or A fraction or one surrogate in the VOA fraction are out of specification but have recoveries of gt10
2 If any one surrogate in a fraction ahova lt10 recovery
REGION I Data Review Worksheets
fgt-100
VII A MATRIX SPIKEMATRIX SPIJa DUPLICATE
1 Matrix SpikeHatrix Spike Duplicate Recoveriea and Precision
lR )loa___ ___ lAveli~ Matrix1
List the tgtbullrcent recovariea and RPDa of coapounda whi ch do not aeet the criteriamiddot atated on Fotll J
bull-8
QUALIFICATION IS LIMITED TO THE UNSPIXED SAMPLE ONLY N 1 If any compound doea not aeet the Contraet Required Recovery range
(CRR) follow the actions stated belovt
PERCENT RECOVERY
~ ~ Poaitiva Sample Reaulta J J Non-detected Results R A
2 If any compound does not meet the RPD criteria flag positive reaulta tor that compound a a estimated (J)
A aeparate worksheet should be used for each MSMSD pair
REGION I Data Review Workaheeta Vll B MATRIX SPliCEMATRIX SPliCE DUPLICATE (Section 2)
3 Matrix Spike Duplicate - UnapUted compoundbull
TR Nos ___ ---
Liat the concentrations of the unspiked compounds and determine the percent RSDbull of the unapiked aample Jiatrix spike and matrix spike duplicate No Uaita have been developed for the RSD valuea of the unapUced compounda
SN1PLpound MS MSp CQNC
8 N
The reviewer auat uaa profeaaional judgement to datenina if there ia a need to qualify any of the unspiked compounds in the sample
REGION I Data Review Workaheeta
VIII PIELD DUPLICATE PRECISION
TR Noa___ --- Matrixamp___
Liat the concentrationbull of the compounda which do not bullbullbullt the followinc RPD criteriat middot
1 middot An RPD of lt30 for water duplicatea 2 An RPD of lt50 for aoil duplicatea
SAJ1PL CONC pup SAMPLE CONC
ACTIONS I
1 If the reaulta for any co111ponda do not bullbullbullt the RPD criteria flag the poaitive reaulta for that compound aa eatbnated
2 If one value ibull non-detected and one ia above the CRQLt a Flag the positive result aa estimated (J) b Flag the non-detected result bullbull estimated (UJ) bull
~~T=~l ~~~bull ~~Y~~lx~middot utilized to apply duplicate actionbull
A separate worksheet should be filled out for each field duplicate pair
REGIOII X Data Review Workaheeta
D DITERHAL STAJIDAIU) PERFORMAIICII tgt1 ~ -h-J-J ~ ~
Liat the internal atandard areaa of aaaplea which do not aaat the criteria of +lOOt or -50 of the internal atandard area in the aaaochtad continuing calibration atandard
OH ltZ
Hr ltlt 0-lt OJgt
00
bull-ACIIOIII
1 If an IS area count ia outaida the criteria -sot or +lOOt of the aaaociatac1 atandarch
a Poaitive reaulta for ~ompounda quantitated uaing that IS are 8flagged aa aatlmatad (J) for that aampla fraction
b Non-datacta for compound a quanti tatad uaing that IS are tlaggad ~ aa estimated (UJ) for that aampla fraction
c If extremely lov area counta ara reported or if perforanceaxhiblta a aajor drop-off than a aavara loaa of aenaitivlty ia indicated Non-detectbull ahould then be flagged aa unusable (R)
2 If an IS retention time varies more than 30 aeconda the chromatoqraphic profile tor that sample aust be examined to determine if any false positives or negatives exiat For ehifta of a large magnitucSe the reviewer may consider partial or total rejection of the cSata for that sample traction
IS OUT H ~~
Data Buaaar IbullT
A bull Acceptable data
J - The a ociated nuaerical value ia an eatibullated quantit
R - ReJect data due to qualitT control criteria Tba data are unuaable (cobullpound bullay or bullay not be preaent) Reaplinamp and reanal7aia h neceaaary for verification
U bull The coapound waa anal7aed for but waa not detected The aaaociated nuaerical value h the aaaple quantitation liait
UJ - The coapound waa anamplJamped for but waa not detected The aaaple quantitation liait h an eatiaated quantitTbull
- The coapound waa analJamped for but waa not detected Tba auple quantltation Uait ia the aua bullbull tba CRQL preaented
- barcode 581461
- barcodetext SDMS Doc ID 581461
REGION I Data Revev Workahebulltbull
I DATA COMPLETENESS
MISSING INFORMATION DATE LlB CONTAkiED DATE RECbullp
11 pound100lt db sJ_ rnA A t1tz -6_ iJiiuob J 41 rIbull-Jb bY- bull 1 ltbull+W Je cJw NAP emzht1i-rJ ~ 6YcfplciJl s9bW middot ttryy cJp -1 middot1middot
--- ------------
______
----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- ------- ----- ----- ------ ------ --------- ------- ----- ----- ------ ----- ------
REGION I Data Review Workaheeta
II HOLDING TIMES Complete table for all aa1r1plea and circle the fract ionbull which are not within criteria middot
VOA BNA PEST SAMPLE DATE DATE DATE
ID SAMPLED ANAL EXTR
~~AmiddotDI ~~---
~~UA middot6bull plusmn ~ NA
~~1-A middotCS l-11middottbull NA
~nsH~ ________ I-IH1 ~
DATE DATE ANAL EXTR
DATE ANAL
~ ~
-
~
VOA - Unpreaervedt Aromatic within 7 daya non-aromatic within 14 daya of aample collection Preaerved t Both within 14 daya of aample collection Soila t Both within 14 daya of bullbullbullple collection
BNA PEST - Extracted within 7 daya analyzed within 40 daya aoih ancS water
ACTION t 1 If holding timea are exceeded all poaitive results are eatimate
(J) and non-detecta are eatimated (UJ) 2 middotIf holding timea are groaaly exceeded the reviewer may
determine that non-detecta are unusable(bull)
-bull8 N
REGION 1 Data Review Workaheeta
111 CCfMS IUMINC
The DFTPP pertor111ance reaulta were reviewed and found to be within the apecifia4 criteria
If no lgtllOMSabullplaa affected____________________ ltZ ~ z-o ~ -oltlTha BFB performance raaulta ware raviawad and found to be within
the apacifiad criteria ~rIr no ltlt Sabullplaa affactacl____________________ 0-lt Olgt
00If aaaa calibration ia in error refer to tha Raion quidalinaa for expanded criteria If nacaaaary all aaaociatad data bullbull unuaabla (R)
cw ~ v-h H ~ ~ -+- W-4
fv H -t ~ ~middottp tJJ-- -6-- JAl s-IJ~ li lthi
o 1-n-H -Ht L~S s+-JJ ~1f- ~ ltIL __ -14 ltkgt c--1 11-Lf vltuv-1 ~ ~ -n ~ ~t-1~ ~ ~ -6v -~middotc_d ~ dG lwiW ~ -~-
fv-u middot~ _t~~~ ~
~ b jlu e I -1shymiddotmiddotmiddotmiddot middot middot~ w- -Hulmiddot11middot fl ~ -u ~ ~-tgt REGIOH I Data Review Worksheetbull ZV A VOLATILE CALIBRATION VERIPICATlOII
~
Data of Initial Calibration bulltmiddot~middot~middot~middotf~B~middotmiddotDatea of ContinuinCjJ Calibrationbull r- y1 Instrument ID 1 MatrixLevel 1 f of f llvJ
CRITERIA OUT ~ YWW RFtRSDRFtD middot eigtD cJb Ky ( )
Saaplaa Affected
ollSIgt --l dQJoL1botngtJngtbullcmiddot~3i~bullJdolkOCltJbullIjwlgtllflopound4tNL-j~yeni~Cl1Lmiddot middot ~middotlliJ)LSamplebull Affected -- - bull
Rf -~~~l~-D~kwmd~~~3~middot~Yl+n~~~~~~~L_~r~~~~~middot~)L_____Samplaa Affected
s bullbull~~ Atfected-liJlJlmiddot--rubullCLocltcUnllbulllpllth~~r~-+(~middot~__)J~----
Saaplaa Affactad------------------- shy
saaplaa Affactadlmiddot-------------------
Samplaa Affactach
Samplebull Affected IISmiddotDmiddot ckJnbull~
1 All iFbulla and RF 1a muat be gt005 ~~~~ ~ bull 333 2 All RSD 1a bulluat belt30 3 All D 1 a bulluat be lt25 gt+gt~
11~111 _lg_a zDSI ACTIOMI ~ If 10 1 If any compound haa an initial RF or a continuing RF of lt005
a Flag podtive r eaulta for that compound aa eatimated (J) bFlag non-detectbull for that compound as unusable (R) bull
2 If any compound has a RSD gt30 or a D gt25 aFlag positive results for that cornpound as estimated (J) b Flag non-detecta for that compound as estimated (UJ) if the RSO
or D ia gt50
A separate worksheet should be filled out for each initial curve
I I I I
REGION J Data Review Worksheets
JV I SEMIVOITILE CALIBRATION VERIFICATION
Date of Initial Calibration -====== Dataa of Continuin9 Calibrations~ tnatruaant ID ______
llW C2lli2l1llllCRITERIA OUT RFRSDRF0
Saaplaa Affected
Samples Affected
Saaplaa Affected
Saaplaa Affected
Saaplaa Affected
Saaplaa Affectach
Sabull plaa Affected
Saaplaa AffeCted
samples Affected
Saaplaa Affacta4
Samplaa Affactada
bull-8 N
Saaplea Affactadt
samples Afflctach
Samples Affected
Sea worksheet IV-A for criteria and actions
A new worksheet should be filled out for each initial curve
iluHot CAhv~ Z~H) bull ~~ bull z f o 1~1 t1C
REGION I Data Jteviev Worksheet
V A 111NK ANALYSIS RESULTS (Soctiono 1 2)
Liat the contamination in the blanka belov
1 Laboratory Bllnka
CONCENTftATIOM
lll1Ii
middota 1lt
2 Equipment and Trip Blanka CONCENTRAT ION[
lll1Ii shybull8 N
A separate worksheet should be used for low and media level blanks
REGION I DAtA Review Worksheets
V I BIAHJt ANALYSIS RESULTS (Section 3)
l BlAnk Actionbull
Action levelbull ahould be baeed upon the higheet concentration of contAIIinant determined in Any bhnk The Action level for aamplea vhich have been concentrAted or diluted ahould be bullultipUed by the concentrationdilution fActor No poaitive aample result ahould be reported unlaas the concentrAtion of the compound in the sAmple axceede the Action laval of 10 x a the Amount in the blAnk for the couon contAainAnta or 5 x a the aaount for any other compound Specific act i ona are bullbull follovaz
1 The c oncentr ation is l esa t han the CRQL repor t the CRQL
2 The concent r at i on i s 9reater than the CRQL but l eea than the act i on level r eport the c oncentration found u
3 The concentration Ja greater than the action level r eport the concentration unqualified
For exaaplea refer to the Regional Cuidelinea
Couon contaa inanta bull aethylene chloride acetone 2-butanone tolueneand phthalatea
MbX CONC ACTION LEVEL l1liUI l1liUI
bull middot )IQ
A aeparat~ vorksheet should be used for low and medium level blanka
-bull8 N
REGION I Data Review Workaheata
VI SURROGATE SPIKB RECOVERIU
Liat the percent racovariaa which do not bullbullbullt the criteria for aurrogata recovery
Au _-u ~ q-- 110 bull bullbull middot Matrixbull~
mJI_ TOL JIFB pep HBZ FBP TPH fHL 2PP TBP
to to to to to to to to to to
Surrogate Actiona PERCENT RECOVERY
~ ~ ~ Positive sample raaulta J J J Non-detected results R UJ A
CRR bull Contract Required Recovery Range Surrogate action should be applied
1 bull If at least two aurroatea in a BN or A fraction or one surrogate in the VOA fraction are out of specification but have recoveries of gt10
2 If any one surrogate in a fraction ahova lt10 recovery
REGION I Data Review Worksheets
fgt-100
VII A MATRIX SPIKEMATRIX SPIJa DUPLICATE
1 Matrix SpikeHatrix Spike Duplicate Recoveriea and Precision
lR )loa___ ___ lAveli~ Matrix1
List the tgtbullrcent recovariea and RPDa of coapounda whi ch do not aeet the criteriamiddot atated on Fotll J
bull-8
QUALIFICATION IS LIMITED TO THE UNSPIXED SAMPLE ONLY N 1 If any compound doea not aeet the Contraet Required Recovery range
(CRR) follow the actions stated belovt
PERCENT RECOVERY
~ ~ Poaitiva Sample Reaulta J J Non-detected Results R A
2 If any compound does not meet the RPD criteria flag positive reaulta tor that compound a a estimated (J)
A aeparate worksheet should be used for each MSMSD pair
REGION I Data Review Workaheeta Vll B MATRIX SPliCEMATRIX SPliCE DUPLICATE (Section 2)
3 Matrix Spike Duplicate - UnapUted compoundbull
TR Nos ___ ---
Liat the concentrations of the unspiked compounds and determine the percent RSDbull of the unapiked aample Jiatrix spike and matrix spike duplicate No Uaita have been developed for the RSD valuea of the unapUced compounda
SN1PLpound MS MSp CQNC
8 N
The reviewer auat uaa profeaaional judgement to datenina if there ia a need to qualify any of the unspiked compounds in the sample
REGION I Data Review Workaheeta
VIII PIELD DUPLICATE PRECISION
TR Noa___ --- Matrixamp___
Liat the concentrationbull of the compounda which do not bullbullbullt the followinc RPD criteriat middot
1 middot An RPD of lt30 for water duplicatea 2 An RPD of lt50 for aoil duplicatea
SAJ1PL CONC pup SAMPLE CONC
ACTIONS I
1 If the reaulta for any co111ponda do not bullbullbullt the RPD criteria flag the poaitive reaulta for that compound aa eatbnated
2 If one value ibull non-detected and one ia above the CRQLt a Flag the positive result aa estimated (J) b Flag the non-detected result bullbull estimated (UJ) bull
~~T=~l ~~~bull ~~Y~~lx~middot utilized to apply duplicate actionbull
A separate worksheet should be filled out for each field duplicate pair
REGIOII X Data Review Workaheeta
D DITERHAL STAJIDAIU) PERFORMAIICII tgt1 ~ -h-J-J ~ ~
Liat the internal atandard areaa of aaaplea which do not aaat the criteria of +lOOt or -50 of the internal atandard area in the aaaochtad continuing calibration atandard
OH ltZ
Hr ltlt 0-lt OJgt
00
bull-ACIIOIII
1 If an IS area count ia outaida the criteria -sot or +lOOt of the aaaociatac1 atandarch
a Poaitive reaulta for ~ompounda quantitated uaing that IS are 8flagged aa aatlmatad (J) for that aampla fraction
b Non-datacta for compound a quanti tatad uaing that IS are tlaggad ~ aa estimated (UJ) for that aampla fraction
c If extremely lov area counta ara reported or if perforanceaxhiblta a aajor drop-off than a aavara loaa of aenaitivlty ia indicated Non-detectbull ahould then be flagged aa unusable (R)
2 If an IS retention time varies more than 30 aeconda the chromatoqraphic profile tor that sample aust be examined to determine if any false positives or negatives exiat For ehifta of a large magnitucSe the reviewer may consider partial or total rejection of the cSata for that sample traction
IS OUT H ~~
Data Buaaar IbullT
A bull Acceptable data
J - The a ociated nuaerical value ia an eatibullated quantit
R - ReJect data due to qualitT control criteria Tba data are unuaable (cobullpound bullay or bullay not be preaent) Reaplinamp and reanal7aia h neceaaary for verification
U bull The coapound waa anal7aed for but waa not detected The aaaociated nuaerical value h the aaaple quantitation liait
UJ - The coapound waa anamplJamped for but waa not detected The aaaple quantitation liait h an eatiaated quantitTbull
- The coapound waa analJamped for but waa not detected Tba auple quantltation Uait ia the aua bullbull tba CRQL preaented
- barcode 581461
- barcodetext SDMS Doc ID 581461
--- ------------
______
----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- ------- ----- ----- ------ ------ --------- ------- ----- ----- ------ ----- ------
REGION I Data Review Workaheeta
II HOLDING TIMES Complete table for all aa1r1plea and circle the fract ionbull which are not within criteria middot
VOA BNA PEST SAMPLE DATE DATE DATE
ID SAMPLED ANAL EXTR
~~AmiddotDI ~~---
~~UA middot6bull plusmn ~ NA
~~1-A middotCS l-11middottbull NA
~nsH~ ________ I-IH1 ~
DATE DATE ANAL EXTR
DATE ANAL
~ ~
-
~
VOA - Unpreaervedt Aromatic within 7 daya non-aromatic within 14 daya of aample collection Preaerved t Both within 14 daya of aample collection Soila t Both within 14 daya of bullbullbullple collection
BNA PEST - Extracted within 7 daya analyzed within 40 daya aoih ancS water
ACTION t 1 If holding timea are exceeded all poaitive results are eatimate
(J) and non-detecta are eatimated (UJ) 2 middotIf holding timea are groaaly exceeded the reviewer may
determine that non-detecta are unusable(bull)
-bull8 N
REGION 1 Data Review Workaheeta
111 CCfMS IUMINC
The DFTPP pertor111ance reaulta were reviewed and found to be within the apecifia4 criteria
If no lgtllOMSabullplaa affected____________________ ltZ ~ z-o ~ -oltlTha BFB performance raaulta ware raviawad and found to be within
the apacifiad criteria ~rIr no ltlt Sabullplaa affactacl____________________ 0-lt Olgt
00If aaaa calibration ia in error refer to tha Raion quidalinaa for expanded criteria If nacaaaary all aaaociatad data bullbull unuaabla (R)
cw ~ v-h H ~ ~ -+- W-4
fv H -t ~ ~middottp tJJ-- -6-- JAl s-IJ~ li lthi
o 1-n-H -Ht L~S s+-JJ ~1f- ~ ltIL __ -14 ltkgt c--1 11-Lf vltuv-1 ~ ~ -n ~ ~t-1~ ~ ~ -6v -~middotc_d ~ dG lwiW ~ -~-
fv-u middot~ _t~~~ ~
~ b jlu e I -1shymiddotmiddotmiddotmiddot middot middot~ w- -Hulmiddot11middot fl ~ -u ~ ~-tgt REGIOH I Data Review Worksheetbull ZV A VOLATILE CALIBRATION VERIPICATlOII
~
Data of Initial Calibration bulltmiddot~middot~middot~middotf~B~middotmiddotDatea of ContinuinCjJ Calibrationbull r- y1 Instrument ID 1 MatrixLevel 1 f of f llvJ
CRITERIA OUT ~ YWW RFtRSDRFtD middot eigtD cJb Ky ( )
Saaplaa Affected
ollSIgt --l dQJoL1botngtJngtbullcmiddot~3i~bullJdolkOCltJbullIjwlgtllflopound4tNL-j~yeni~Cl1Lmiddot middot ~middotlliJ)LSamplebull Affected -- - bull
Rf -~~~l~-D~kwmd~~~3~middot~Yl+n~~~~~~~L_~r~~~~~middot~)L_____Samplaa Affected
s bullbull~~ Atfected-liJlJlmiddot--rubullCLocltcUnllbulllpllth~~r~-+(~middot~__)J~----
Saaplaa Affactad------------------- shy
saaplaa Affactadlmiddot-------------------
Samplaa Affactach
Samplebull Affected IISmiddotDmiddot ckJnbull~
1 All iFbulla and RF 1a muat be gt005 ~~~~ ~ bull 333 2 All RSD 1a bulluat belt30 3 All D 1 a bulluat be lt25 gt+gt~
11~111 _lg_a zDSI ACTIOMI ~ If 10 1 If any compound haa an initial RF or a continuing RF of lt005
a Flag podtive r eaulta for that compound aa eatimated (J) bFlag non-detectbull for that compound as unusable (R) bull
2 If any compound has a RSD gt30 or a D gt25 aFlag positive results for that cornpound as estimated (J) b Flag non-detecta for that compound as estimated (UJ) if the RSO
or D ia gt50
A separate worksheet should be filled out for each initial curve
I I I I
REGION J Data Review Worksheets
JV I SEMIVOITILE CALIBRATION VERIFICATION
Date of Initial Calibration -====== Dataa of Continuin9 Calibrations~ tnatruaant ID ______
llW C2lli2l1llllCRITERIA OUT RFRSDRF0
Saaplaa Affected
Samples Affected
Saaplaa Affected
Saaplaa Affected
Saaplaa Affected
Saaplaa Affectach
Sabull plaa Affected
Saaplaa AffeCted
samples Affected
Saaplaa Affacta4
Samplaa Affactada
bull-8 N
Saaplea Affactadt
samples Afflctach
Samples Affected
Sea worksheet IV-A for criteria and actions
A new worksheet should be filled out for each initial curve
iluHot CAhv~ Z~H) bull ~~ bull z f o 1~1 t1C
REGION I Data Jteviev Worksheet
V A 111NK ANALYSIS RESULTS (Soctiono 1 2)
Liat the contamination in the blanka belov
1 Laboratory Bllnka
CONCENTftATIOM
lll1Ii
middota 1lt
2 Equipment and Trip Blanka CONCENTRAT ION[
lll1Ii shybull8 N
A separate worksheet should be used for low and media level blanks
REGION I DAtA Review Worksheets
V I BIAHJt ANALYSIS RESULTS (Section 3)
l BlAnk Actionbull
Action levelbull ahould be baeed upon the higheet concentration of contAIIinant determined in Any bhnk The Action level for aamplea vhich have been concentrAted or diluted ahould be bullultipUed by the concentrationdilution fActor No poaitive aample result ahould be reported unlaas the concentrAtion of the compound in the sAmple axceede the Action laval of 10 x a the Amount in the blAnk for the couon contAainAnta or 5 x a the aaount for any other compound Specific act i ona are bullbull follovaz
1 The c oncentr ation is l esa t han the CRQL repor t the CRQL
2 The concent r at i on i s 9reater than the CRQL but l eea than the act i on level r eport the c oncentration found u
3 The concentration Ja greater than the action level r eport the concentration unqualified
For exaaplea refer to the Regional Cuidelinea
Couon contaa inanta bull aethylene chloride acetone 2-butanone tolueneand phthalatea
MbX CONC ACTION LEVEL l1liUI l1liUI
bull middot )IQ
A aeparat~ vorksheet should be used for low and medium level blanka
-bull8 N
REGION I Data Review Workaheata
VI SURROGATE SPIKB RECOVERIU
Liat the percent racovariaa which do not bullbullbullt the criteria for aurrogata recovery
Au _-u ~ q-- 110 bull bullbull middot Matrixbull~
mJI_ TOL JIFB pep HBZ FBP TPH fHL 2PP TBP
to to to to to to to to to to
Surrogate Actiona PERCENT RECOVERY
~ ~ ~ Positive sample raaulta J J J Non-detected results R UJ A
CRR bull Contract Required Recovery Range Surrogate action should be applied
1 bull If at least two aurroatea in a BN or A fraction or one surrogate in the VOA fraction are out of specification but have recoveries of gt10
2 If any one surrogate in a fraction ahova lt10 recovery
REGION I Data Review Worksheets
fgt-100
VII A MATRIX SPIKEMATRIX SPIJa DUPLICATE
1 Matrix SpikeHatrix Spike Duplicate Recoveriea and Precision
lR )loa___ ___ lAveli~ Matrix1
List the tgtbullrcent recovariea and RPDa of coapounda whi ch do not aeet the criteriamiddot atated on Fotll J
bull-8
QUALIFICATION IS LIMITED TO THE UNSPIXED SAMPLE ONLY N 1 If any compound doea not aeet the Contraet Required Recovery range
(CRR) follow the actions stated belovt
PERCENT RECOVERY
~ ~ Poaitiva Sample Reaulta J J Non-detected Results R A
2 If any compound does not meet the RPD criteria flag positive reaulta tor that compound a a estimated (J)
A aeparate worksheet should be used for each MSMSD pair
REGION I Data Review Workaheeta Vll B MATRIX SPliCEMATRIX SPliCE DUPLICATE (Section 2)
3 Matrix Spike Duplicate - UnapUted compoundbull
TR Nos ___ ---
Liat the concentrations of the unspiked compounds and determine the percent RSDbull of the unapiked aample Jiatrix spike and matrix spike duplicate No Uaita have been developed for the RSD valuea of the unapUced compounda
SN1PLpound MS MSp CQNC
8 N
The reviewer auat uaa profeaaional judgement to datenina if there ia a need to qualify any of the unspiked compounds in the sample
REGION I Data Review Workaheeta
VIII PIELD DUPLICATE PRECISION
TR Noa___ --- Matrixamp___
Liat the concentrationbull of the compounda which do not bullbullbullt the followinc RPD criteriat middot
1 middot An RPD of lt30 for water duplicatea 2 An RPD of lt50 for aoil duplicatea
SAJ1PL CONC pup SAMPLE CONC
ACTIONS I
1 If the reaulta for any co111ponda do not bullbullbullt the RPD criteria flag the poaitive reaulta for that compound aa eatbnated
2 If one value ibull non-detected and one ia above the CRQLt a Flag the positive result aa estimated (J) b Flag the non-detected result bullbull estimated (UJ) bull
~~T=~l ~~~bull ~~Y~~lx~middot utilized to apply duplicate actionbull
A separate worksheet should be filled out for each field duplicate pair
REGIOII X Data Review Workaheeta
D DITERHAL STAJIDAIU) PERFORMAIICII tgt1 ~ -h-J-J ~ ~
Liat the internal atandard areaa of aaaplea which do not aaat the criteria of +lOOt or -50 of the internal atandard area in the aaaochtad continuing calibration atandard
OH ltZ
Hr ltlt 0-lt OJgt
00
bull-ACIIOIII
1 If an IS area count ia outaida the criteria -sot or +lOOt of the aaaociatac1 atandarch
a Poaitive reaulta for ~ompounda quantitated uaing that IS are 8flagged aa aatlmatad (J) for that aampla fraction
b Non-datacta for compound a quanti tatad uaing that IS are tlaggad ~ aa estimated (UJ) for that aampla fraction
c If extremely lov area counta ara reported or if perforanceaxhiblta a aajor drop-off than a aavara loaa of aenaitivlty ia indicated Non-detectbull ahould then be flagged aa unusable (R)
2 If an IS retention time varies more than 30 aeconda the chromatoqraphic profile tor that sample aust be examined to determine if any false positives or negatives exiat For ehifta of a large magnitucSe the reviewer may consider partial or total rejection of the cSata for that sample traction
IS OUT H ~~
Data Buaaar IbullT
A bull Acceptable data
J - The a ociated nuaerical value ia an eatibullated quantit
R - ReJect data due to qualitT control criteria Tba data are unuaable (cobullpound bullay or bullay not be preaent) Reaplinamp and reanal7aia h neceaaary for verification
U bull The coapound waa anal7aed for but waa not detected The aaaociated nuaerical value h the aaaple quantitation liait
UJ - The coapound waa anamplJamped for but waa not detected The aaaple quantitation liait h an eatiaated quantitTbull
- The coapound waa analJamped for but waa not detected Tba auple quantltation Uait ia the aua bullbull tba CRQL preaented
- barcode 581461
- barcodetext SDMS Doc ID 581461
REGION 1 Data Review Workaheeta
111 CCfMS IUMINC
The DFTPP pertor111ance reaulta were reviewed and found to be within the apecifia4 criteria
If no lgtllOMSabullplaa affected____________________ ltZ ~ z-o ~ -oltlTha BFB performance raaulta ware raviawad and found to be within
the apacifiad criteria ~rIr no ltlt Sabullplaa affactacl____________________ 0-lt Olgt
00If aaaa calibration ia in error refer to tha Raion quidalinaa for expanded criteria If nacaaaary all aaaociatad data bullbull unuaabla (R)
cw ~ v-h H ~ ~ -+- W-4
fv H -t ~ ~middottp tJJ-- -6-- JAl s-IJ~ li lthi
o 1-n-H -Ht L~S s+-JJ ~1f- ~ ltIL __ -14 ltkgt c--1 11-Lf vltuv-1 ~ ~ -n ~ ~t-1~ ~ ~ -6v -~middotc_d ~ dG lwiW ~ -~-
fv-u middot~ _t~~~ ~
~ b jlu e I -1shymiddotmiddotmiddotmiddot middot middot~ w- -Hulmiddot11middot fl ~ -u ~ ~-tgt REGIOH I Data Review Worksheetbull ZV A VOLATILE CALIBRATION VERIPICATlOII
~
Data of Initial Calibration bulltmiddot~middot~middot~middotf~B~middotmiddotDatea of ContinuinCjJ Calibrationbull r- y1 Instrument ID 1 MatrixLevel 1 f of f llvJ
CRITERIA OUT ~ YWW RFtRSDRFtD middot eigtD cJb Ky ( )
Saaplaa Affected
ollSIgt --l dQJoL1botngtJngtbullcmiddot~3i~bullJdolkOCltJbullIjwlgtllflopound4tNL-j~yeni~Cl1Lmiddot middot ~middotlliJ)LSamplebull Affected -- - bull
Rf -~~~l~-D~kwmd~~~3~middot~Yl+n~~~~~~~L_~r~~~~~middot~)L_____Samplaa Affected
s bullbull~~ Atfected-liJlJlmiddot--rubullCLocltcUnllbulllpllth~~r~-+(~middot~__)J~----
Saaplaa Affactad------------------- shy
saaplaa Affactadlmiddot-------------------
Samplaa Affactach
Samplebull Affected IISmiddotDmiddot ckJnbull~
1 All iFbulla and RF 1a muat be gt005 ~~~~ ~ bull 333 2 All RSD 1a bulluat belt30 3 All D 1 a bulluat be lt25 gt+gt~
11~111 _lg_a zDSI ACTIOMI ~ If 10 1 If any compound haa an initial RF or a continuing RF of lt005
a Flag podtive r eaulta for that compound aa eatimated (J) bFlag non-detectbull for that compound as unusable (R) bull
2 If any compound has a RSD gt30 or a D gt25 aFlag positive results for that cornpound as estimated (J) b Flag non-detecta for that compound as estimated (UJ) if the RSO
or D ia gt50
A separate worksheet should be filled out for each initial curve
I I I I
REGION J Data Review Worksheets
JV I SEMIVOITILE CALIBRATION VERIFICATION
Date of Initial Calibration -====== Dataa of Continuin9 Calibrations~ tnatruaant ID ______
llW C2lli2l1llllCRITERIA OUT RFRSDRF0
Saaplaa Affected
Samples Affected
Saaplaa Affected
Saaplaa Affected
Saaplaa Affected
Saaplaa Affectach
Sabull plaa Affected
Saaplaa AffeCted
samples Affected
Saaplaa Affacta4
Samplaa Affactada
bull-8 N
Saaplea Affactadt
samples Afflctach
Samples Affected
Sea worksheet IV-A for criteria and actions
A new worksheet should be filled out for each initial curve
iluHot CAhv~ Z~H) bull ~~ bull z f o 1~1 t1C
REGION I Data Jteviev Worksheet
V A 111NK ANALYSIS RESULTS (Soctiono 1 2)
Liat the contamination in the blanka belov
1 Laboratory Bllnka
CONCENTftATIOM
lll1Ii
middota 1lt
2 Equipment and Trip Blanka CONCENTRAT ION[
lll1Ii shybull8 N
A separate worksheet should be used for low and media level blanks
REGION I DAtA Review Worksheets
V I BIAHJt ANALYSIS RESULTS (Section 3)
l BlAnk Actionbull
Action levelbull ahould be baeed upon the higheet concentration of contAIIinant determined in Any bhnk The Action level for aamplea vhich have been concentrAted or diluted ahould be bullultipUed by the concentrationdilution fActor No poaitive aample result ahould be reported unlaas the concentrAtion of the compound in the sAmple axceede the Action laval of 10 x a the Amount in the blAnk for the couon contAainAnta or 5 x a the aaount for any other compound Specific act i ona are bullbull follovaz
1 The c oncentr ation is l esa t han the CRQL repor t the CRQL
2 The concent r at i on i s 9reater than the CRQL but l eea than the act i on level r eport the c oncentration found u
3 The concentration Ja greater than the action level r eport the concentration unqualified
For exaaplea refer to the Regional Cuidelinea
Couon contaa inanta bull aethylene chloride acetone 2-butanone tolueneand phthalatea
MbX CONC ACTION LEVEL l1liUI l1liUI
bull middot )IQ
A aeparat~ vorksheet should be used for low and medium level blanka
-bull8 N
REGION I Data Review Workaheata
VI SURROGATE SPIKB RECOVERIU
Liat the percent racovariaa which do not bullbullbullt the criteria for aurrogata recovery
Au _-u ~ q-- 110 bull bullbull middot Matrixbull~
mJI_ TOL JIFB pep HBZ FBP TPH fHL 2PP TBP
to to to to to to to to to to
Surrogate Actiona PERCENT RECOVERY
~ ~ ~ Positive sample raaulta J J J Non-detected results R UJ A
CRR bull Contract Required Recovery Range Surrogate action should be applied
1 bull If at least two aurroatea in a BN or A fraction or one surrogate in the VOA fraction are out of specification but have recoveries of gt10
2 If any one surrogate in a fraction ahova lt10 recovery
REGION I Data Review Worksheets
fgt-100
VII A MATRIX SPIKEMATRIX SPIJa DUPLICATE
1 Matrix SpikeHatrix Spike Duplicate Recoveriea and Precision
lR )loa___ ___ lAveli~ Matrix1
List the tgtbullrcent recovariea and RPDa of coapounda whi ch do not aeet the criteriamiddot atated on Fotll J
bull-8
QUALIFICATION IS LIMITED TO THE UNSPIXED SAMPLE ONLY N 1 If any compound doea not aeet the Contraet Required Recovery range
(CRR) follow the actions stated belovt
PERCENT RECOVERY
~ ~ Poaitiva Sample Reaulta J J Non-detected Results R A
2 If any compound does not meet the RPD criteria flag positive reaulta tor that compound a a estimated (J)
A aeparate worksheet should be used for each MSMSD pair
REGION I Data Review Workaheeta Vll B MATRIX SPliCEMATRIX SPliCE DUPLICATE (Section 2)
3 Matrix Spike Duplicate - UnapUted compoundbull
TR Nos ___ ---
Liat the concentrations of the unspiked compounds and determine the percent RSDbull of the unapiked aample Jiatrix spike and matrix spike duplicate No Uaita have been developed for the RSD valuea of the unapUced compounda
SN1PLpound MS MSp CQNC
8 N
The reviewer auat uaa profeaaional judgement to datenina if there ia a need to qualify any of the unspiked compounds in the sample
REGION I Data Review Workaheeta
VIII PIELD DUPLICATE PRECISION
TR Noa___ --- Matrixamp___
Liat the concentrationbull of the compounda which do not bullbullbullt the followinc RPD criteriat middot
1 middot An RPD of lt30 for water duplicatea 2 An RPD of lt50 for aoil duplicatea
SAJ1PL CONC pup SAMPLE CONC
ACTIONS I
1 If the reaulta for any co111ponda do not bullbullbullt the RPD criteria flag the poaitive reaulta for that compound aa eatbnated
2 If one value ibull non-detected and one ia above the CRQLt a Flag the positive result aa estimated (J) b Flag the non-detected result bullbull estimated (UJ) bull
~~T=~l ~~~bull ~~Y~~lx~middot utilized to apply duplicate actionbull
A separate worksheet should be filled out for each field duplicate pair
REGIOII X Data Review Workaheeta
D DITERHAL STAJIDAIU) PERFORMAIICII tgt1 ~ -h-J-J ~ ~
Liat the internal atandard areaa of aaaplea which do not aaat the criteria of +lOOt or -50 of the internal atandard area in the aaaochtad continuing calibration atandard
OH ltZ
Hr ltlt 0-lt OJgt
00
bull-ACIIOIII
1 If an IS area count ia outaida the criteria -sot or +lOOt of the aaaociatac1 atandarch
a Poaitive reaulta for ~ompounda quantitated uaing that IS are 8flagged aa aatlmatad (J) for that aampla fraction
b Non-datacta for compound a quanti tatad uaing that IS are tlaggad ~ aa estimated (UJ) for that aampla fraction
c If extremely lov area counta ara reported or if perforanceaxhiblta a aajor drop-off than a aavara loaa of aenaitivlty ia indicated Non-detectbull ahould then be flagged aa unusable (R)
2 If an IS retention time varies more than 30 aeconda the chromatoqraphic profile tor that sample aust be examined to determine if any false positives or negatives exiat For ehifta of a large magnitucSe the reviewer may consider partial or total rejection of the cSata for that sample traction
IS OUT H ~~
Data Buaaar IbullT
A bull Acceptable data
J - The a ociated nuaerical value ia an eatibullated quantit
R - ReJect data due to qualitT control criteria Tba data are unuaable (cobullpound bullay or bullay not be preaent) Reaplinamp and reanal7aia h neceaaary for verification
U bull The coapound waa anal7aed for but waa not detected The aaaociated nuaerical value h the aaaple quantitation liait
UJ - The coapound waa anamplJamped for but waa not detected The aaaple quantitation liait h an eatiaated quantitTbull
- The coapound waa analJamped for but waa not detected Tba auple quantltation Uait ia the aua bullbull tba CRQL preaented
- barcode 581461
- barcodetext SDMS Doc ID 581461
fv-u middot~ _t~~~ ~
~ b jlu e I -1shymiddotmiddotmiddotmiddot middot middot~ w- -Hulmiddot11middot fl ~ -u ~ ~-tgt REGIOH I Data Review Worksheetbull ZV A VOLATILE CALIBRATION VERIPICATlOII
~
Data of Initial Calibration bulltmiddot~middot~middot~middotf~B~middotmiddotDatea of ContinuinCjJ Calibrationbull r- y1 Instrument ID 1 MatrixLevel 1 f of f llvJ
CRITERIA OUT ~ YWW RFtRSDRFtD middot eigtD cJb Ky ( )
Saaplaa Affected
ollSIgt --l dQJoL1botngtJngtbullcmiddot~3i~bullJdolkOCltJbullIjwlgtllflopound4tNL-j~yeni~Cl1Lmiddot middot ~middotlliJ)LSamplebull Affected -- - bull
Rf -~~~l~-D~kwmd~~~3~middot~Yl+n~~~~~~~L_~r~~~~~middot~)L_____Samplaa Affected
s bullbull~~ Atfected-liJlJlmiddot--rubullCLocltcUnllbulllpllth~~r~-+(~middot~__)J~----
Saaplaa Affactad------------------- shy
saaplaa Affactadlmiddot-------------------
Samplaa Affactach
Samplebull Affected IISmiddotDmiddot ckJnbull~
1 All iFbulla and RF 1a muat be gt005 ~~~~ ~ bull 333 2 All RSD 1a bulluat belt30 3 All D 1 a bulluat be lt25 gt+gt~
11~111 _lg_a zDSI ACTIOMI ~ If 10 1 If any compound haa an initial RF or a continuing RF of lt005
a Flag podtive r eaulta for that compound aa eatimated (J) bFlag non-detectbull for that compound as unusable (R) bull
2 If any compound has a RSD gt30 or a D gt25 aFlag positive results for that cornpound as estimated (J) b Flag non-detecta for that compound as estimated (UJ) if the RSO
or D ia gt50
A separate worksheet should be filled out for each initial curve
I I I I
REGION J Data Review Worksheets
JV I SEMIVOITILE CALIBRATION VERIFICATION
Date of Initial Calibration -====== Dataa of Continuin9 Calibrations~ tnatruaant ID ______
llW C2lli2l1llllCRITERIA OUT RFRSDRF0
Saaplaa Affected
Samples Affected
Saaplaa Affected
Saaplaa Affected
Saaplaa Affected
Saaplaa Affectach
Sabull plaa Affected
Saaplaa AffeCted
samples Affected
Saaplaa Affacta4
Samplaa Affactada
bull-8 N
Saaplea Affactadt
samples Afflctach
Samples Affected
Sea worksheet IV-A for criteria and actions
A new worksheet should be filled out for each initial curve
iluHot CAhv~ Z~H) bull ~~ bull z f o 1~1 t1C
REGION I Data Jteviev Worksheet
V A 111NK ANALYSIS RESULTS (Soctiono 1 2)
Liat the contamination in the blanka belov
1 Laboratory Bllnka
CONCENTftATIOM
lll1Ii
middota 1lt
2 Equipment and Trip Blanka CONCENTRAT ION[
lll1Ii shybull8 N
A separate worksheet should be used for low and media level blanks
REGION I DAtA Review Worksheets
V I BIAHJt ANALYSIS RESULTS (Section 3)
l BlAnk Actionbull
Action levelbull ahould be baeed upon the higheet concentration of contAIIinant determined in Any bhnk The Action level for aamplea vhich have been concentrAted or diluted ahould be bullultipUed by the concentrationdilution fActor No poaitive aample result ahould be reported unlaas the concentrAtion of the compound in the sAmple axceede the Action laval of 10 x a the Amount in the blAnk for the couon contAainAnta or 5 x a the aaount for any other compound Specific act i ona are bullbull follovaz
1 The c oncentr ation is l esa t han the CRQL repor t the CRQL
2 The concent r at i on i s 9reater than the CRQL but l eea than the act i on level r eport the c oncentration found u
3 The concentration Ja greater than the action level r eport the concentration unqualified
For exaaplea refer to the Regional Cuidelinea
Couon contaa inanta bull aethylene chloride acetone 2-butanone tolueneand phthalatea
MbX CONC ACTION LEVEL l1liUI l1liUI
bull middot )IQ
A aeparat~ vorksheet should be used for low and medium level blanka
-bull8 N
REGION I Data Review Workaheata
VI SURROGATE SPIKB RECOVERIU
Liat the percent racovariaa which do not bullbullbullt the criteria for aurrogata recovery
Au _-u ~ q-- 110 bull bullbull middot Matrixbull~
mJI_ TOL JIFB pep HBZ FBP TPH fHL 2PP TBP
to to to to to to to to to to
Surrogate Actiona PERCENT RECOVERY
~ ~ ~ Positive sample raaulta J J J Non-detected results R UJ A
CRR bull Contract Required Recovery Range Surrogate action should be applied
1 bull If at least two aurroatea in a BN or A fraction or one surrogate in the VOA fraction are out of specification but have recoveries of gt10
2 If any one surrogate in a fraction ahova lt10 recovery
REGION I Data Review Worksheets
fgt-100
VII A MATRIX SPIKEMATRIX SPIJa DUPLICATE
1 Matrix SpikeHatrix Spike Duplicate Recoveriea and Precision
lR )loa___ ___ lAveli~ Matrix1
List the tgtbullrcent recovariea and RPDa of coapounda whi ch do not aeet the criteriamiddot atated on Fotll J
bull-8
QUALIFICATION IS LIMITED TO THE UNSPIXED SAMPLE ONLY N 1 If any compound doea not aeet the Contraet Required Recovery range
(CRR) follow the actions stated belovt
PERCENT RECOVERY
~ ~ Poaitiva Sample Reaulta J J Non-detected Results R A
2 If any compound does not meet the RPD criteria flag positive reaulta tor that compound a a estimated (J)
A aeparate worksheet should be used for each MSMSD pair
REGION I Data Review Workaheeta Vll B MATRIX SPliCEMATRIX SPliCE DUPLICATE (Section 2)
3 Matrix Spike Duplicate - UnapUted compoundbull
TR Nos ___ ---
Liat the concentrations of the unspiked compounds and determine the percent RSDbull of the unapiked aample Jiatrix spike and matrix spike duplicate No Uaita have been developed for the RSD valuea of the unapUced compounda
SN1PLpound MS MSp CQNC
8 N
The reviewer auat uaa profeaaional judgement to datenina if there ia a need to qualify any of the unspiked compounds in the sample
REGION I Data Review Workaheeta
VIII PIELD DUPLICATE PRECISION
TR Noa___ --- Matrixamp___
Liat the concentrationbull of the compounda which do not bullbullbullt the followinc RPD criteriat middot
1 middot An RPD of lt30 for water duplicatea 2 An RPD of lt50 for aoil duplicatea
SAJ1PL CONC pup SAMPLE CONC
ACTIONS I
1 If the reaulta for any co111ponda do not bullbullbullt the RPD criteria flag the poaitive reaulta for that compound aa eatbnated
2 If one value ibull non-detected and one ia above the CRQLt a Flag the positive result aa estimated (J) b Flag the non-detected result bullbull estimated (UJ) bull
~~T=~l ~~~bull ~~Y~~lx~middot utilized to apply duplicate actionbull
A separate worksheet should be filled out for each field duplicate pair
REGIOII X Data Review Workaheeta
D DITERHAL STAJIDAIU) PERFORMAIICII tgt1 ~ -h-J-J ~ ~
Liat the internal atandard areaa of aaaplea which do not aaat the criteria of +lOOt or -50 of the internal atandard area in the aaaochtad continuing calibration atandard
OH ltZ
Hr ltlt 0-lt OJgt
00
bull-ACIIOIII
1 If an IS area count ia outaida the criteria -sot or +lOOt of the aaaociatac1 atandarch
a Poaitive reaulta for ~ompounda quantitated uaing that IS are 8flagged aa aatlmatad (J) for that aampla fraction
b Non-datacta for compound a quanti tatad uaing that IS are tlaggad ~ aa estimated (UJ) for that aampla fraction
c If extremely lov area counta ara reported or if perforanceaxhiblta a aajor drop-off than a aavara loaa of aenaitivlty ia indicated Non-detectbull ahould then be flagged aa unusable (R)
2 If an IS retention time varies more than 30 aeconda the chromatoqraphic profile tor that sample aust be examined to determine if any false positives or negatives exiat For ehifta of a large magnitucSe the reviewer may consider partial or total rejection of the cSata for that sample traction
IS OUT H ~~
Data Buaaar IbullT
A bull Acceptable data
J - The a ociated nuaerical value ia an eatibullated quantit
R - ReJect data due to qualitT control criteria Tba data are unuaable (cobullpound bullay or bullay not be preaent) Reaplinamp and reanal7aia h neceaaary for verification
U bull The coapound waa anal7aed for but waa not detected The aaaociated nuaerical value h the aaaple quantitation liait
UJ - The coapound waa anamplJamped for but waa not detected The aaaple quantitation liait h an eatiaated quantitTbull
- The coapound waa analJamped for but waa not detected Tba auple quantltation Uait ia the aua bullbull tba CRQL preaented
- barcode 581461
- barcodetext SDMS Doc ID 581461
I I I I
REGION J Data Review Worksheets
JV I SEMIVOITILE CALIBRATION VERIFICATION
Date of Initial Calibration -====== Dataa of Continuin9 Calibrations~ tnatruaant ID ______
llW C2lli2l1llllCRITERIA OUT RFRSDRF0
Saaplaa Affected
Samples Affected
Saaplaa Affected
Saaplaa Affected
Saaplaa Affected
Saaplaa Affectach
Sabull plaa Affected
Saaplaa AffeCted
samples Affected
Saaplaa Affacta4
Samplaa Affactada
bull-8 N
Saaplea Affactadt
samples Afflctach
Samples Affected
Sea worksheet IV-A for criteria and actions
A new worksheet should be filled out for each initial curve
iluHot CAhv~ Z~H) bull ~~ bull z f o 1~1 t1C
REGION I Data Jteviev Worksheet
V A 111NK ANALYSIS RESULTS (Soctiono 1 2)
Liat the contamination in the blanka belov
1 Laboratory Bllnka
CONCENTftATIOM
lll1Ii
middota 1lt
2 Equipment and Trip Blanka CONCENTRAT ION[
lll1Ii shybull8 N
A separate worksheet should be used for low and media level blanks
REGION I DAtA Review Worksheets
V I BIAHJt ANALYSIS RESULTS (Section 3)
l BlAnk Actionbull
Action levelbull ahould be baeed upon the higheet concentration of contAIIinant determined in Any bhnk The Action level for aamplea vhich have been concentrAted or diluted ahould be bullultipUed by the concentrationdilution fActor No poaitive aample result ahould be reported unlaas the concentrAtion of the compound in the sAmple axceede the Action laval of 10 x a the Amount in the blAnk for the couon contAainAnta or 5 x a the aaount for any other compound Specific act i ona are bullbull follovaz
1 The c oncentr ation is l esa t han the CRQL repor t the CRQL
2 The concent r at i on i s 9reater than the CRQL but l eea than the act i on level r eport the c oncentration found u
3 The concentration Ja greater than the action level r eport the concentration unqualified
For exaaplea refer to the Regional Cuidelinea
Couon contaa inanta bull aethylene chloride acetone 2-butanone tolueneand phthalatea
MbX CONC ACTION LEVEL l1liUI l1liUI
bull middot )IQ
A aeparat~ vorksheet should be used for low and medium level blanka
-bull8 N
REGION I Data Review Workaheata
VI SURROGATE SPIKB RECOVERIU
Liat the percent racovariaa which do not bullbullbullt the criteria for aurrogata recovery
Au _-u ~ q-- 110 bull bullbull middot Matrixbull~
mJI_ TOL JIFB pep HBZ FBP TPH fHL 2PP TBP
to to to to to to to to to to
Surrogate Actiona PERCENT RECOVERY
~ ~ ~ Positive sample raaulta J J J Non-detected results R UJ A
CRR bull Contract Required Recovery Range Surrogate action should be applied
1 bull If at least two aurroatea in a BN or A fraction or one surrogate in the VOA fraction are out of specification but have recoveries of gt10
2 If any one surrogate in a fraction ahova lt10 recovery
REGION I Data Review Worksheets
fgt-100
VII A MATRIX SPIKEMATRIX SPIJa DUPLICATE
1 Matrix SpikeHatrix Spike Duplicate Recoveriea and Precision
lR )loa___ ___ lAveli~ Matrix1
List the tgtbullrcent recovariea and RPDa of coapounda whi ch do not aeet the criteriamiddot atated on Fotll J
bull-8
QUALIFICATION IS LIMITED TO THE UNSPIXED SAMPLE ONLY N 1 If any compound doea not aeet the Contraet Required Recovery range
(CRR) follow the actions stated belovt
PERCENT RECOVERY
~ ~ Poaitiva Sample Reaulta J J Non-detected Results R A
2 If any compound does not meet the RPD criteria flag positive reaulta tor that compound a a estimated (J)
A aeparate worksheet should be used for each MSMSD pair
REGION I Data Review Workaheeta Vll B MATRIX SPliCEMATRIX SPliCE DUPLICATE (Section 2)
3 Matrix Spike Duplicate - UnapUted compoundbull
TR Nos ___ ---
Liat the concentrations of the unspiked compounds and determine the percent RSDbull of the unapiked aample Jiatrix spike and matrix spike duplicate No Uaita have been developed for the RSD valuea of the unapUced compounda
SN1PLpound MS MSp CQNC
8 N
The reviewer auat uaa profeaaional judgement to datenina if there ia a need to qualify any of the unspiked compounds in the sample
REGION I Data Review Workaheeta
VIII PIELD DUPLICATE PRECISION
TR Noa___ --- Matrixamp___
Liat the concentrationbull of the compounda which do not bullbullbullt the followinc RPD criteriat middot
1 middot An RPD of lt30 for water duplicatea 2 An RPD of lt50 for aoil duplicatea
SAJ1PL CONC pup SAMPLE CONC
ACTIONS I
1 If the reaulta for any co111ponda do not bullbullbullt the RPD criteria flag the poaitive reaulta for that compound aa eatbnated
2 If one value ibull non-detected and one ia above the CRQLt a Flag the positive result aa estimated (J) b Flag the non-detected result bullbull estimated (UJ) bull
~~T=~l ~~~bull ~~Y~~lx~middot utilized to apply duplicate actionbull
A separate worksheet should be filled out for each field duplicate pair
REGIOII X Data Review Workaheeta
D DITERHAL STAJIDAIU) PERFORMAIICII tgt1 ~ -h-J-J ~ ~
Liat the internal atandard areaa of aaaplea which do not aaat the criteria of +lOOt or -50 of the internal atandard area in the aaaochtad continuing calibration atandard
OH ltZ
Hr ltlt 0-lt OJgt
00
bull-ACIIOIII
1 If an IS area count ia outaida the criteria -sot or +lOOt of the aaaociatac1 atandarch
a Poaitive reaulta for ~ompounda quantitated uaing that IS are 8flagged aa aatlmatad (J) for that aampla fraction
b Non-datacta for compound a quanti tatad uaing that IS are tlaggad ~ aa estimated (UJ) for that aampla fraction
c If extremely lov area counta ara reported or if perforanceaxhiblta a aajor drop-off than a aavara loaa of aenaitivlty ia indicated Non-detectbull ahould then be flagged aa unusable (R)
2 If an IS retention time varies more than 30 aeconda the chromatoqraphic profile tor that sample aust be examined to determine if any false positives or negatives exiat For ehifta of a large magnitucSe the reviewer may consider partial or total rejection of the cSata for that sample traction
IS OUT H ~~
Data Buaaar IbullT
A bull Acceptable data
J - The a ociated nuaerical value ia an eatibullated quantit
R - ReJect data due to qualitT control criteria Tba data are unuaable (cobullpound bullay or bullay not be preaent) Reaplinamp and reanal7aia h neceaaary for verification
U bull The coapound waa anal7aed for but waa not detected The aaaociated nuaerical value h the aaaple quantitation liait
UJ - The coapound waa anamplJamped for but waa not detected The aaaple quantitation liait h an eatiaated quantitTbull
- The coapound waa analJamped for but waa not detected Tba auple quantltation Uait ia the aua bullbull tba CRQL preaented
- barcode 581461
- barcodetext SDMS Doc ID 581461
iluHot CAhv~ Z~H) bull ~~ bull z f o 1~1 t1C
REGION I Data Jteviev Worksheet
V A 111NK ANALYSIS RESULTS (Soctiono 1 2)
Liat the contamination in the blanka belov
1 Laboratory Bllnka
CONCENTftATIOM
lll1Ii
middota 1lt
2 Equipment and Trip Blanka CONCENTRAT ION[
lll1Ii shybull8 N
A separate worksheet should be used for low and media level blanks
REGION I DAtA Review Worksheets
V I BIAHJt ANALYSIS RESULTS (Section 3)
l BlAnk Actionbull
Action levelbull ahould be baeed upon the higheet concentration of contAIIinant determined in Any bhnk The Action level for aamplea vhich have been concentrAted or diluted ahould be bullultipUed by the concentrationdilution fActor No poaitive aample result ahould be reported unlaas the concentrAtion of the compound in the sAmple axceede the Action laval of 10 x a the Amount in the blAnk for the couon contAainAnta or 5 x a the aaount for any other compound Specific act i ona are bullbull follovaz
1 The c oncentr ation is l esa t han the CRQL repor t the CRQL
2 The concent r at i on i s 9reater than the CRQL but l eea than the act i on level r eport the c oncentration found u
3 The concentration Ja greater than the action level r eport the concentration unqualified
For exaaplea refer to the Regional Cuidelinea
Couon contaa inanta bull aethylene chloride acetone 2-butanone tolueneand phthalatea
MbX CONC ACTION LEVEL l1liUI l1liUI
bull middot )IQ
A aeparat~ vorksheet should be used for low and medium level blanka
-bull8 N
REGION I Data Review Workaheata
VI SURROGATE SPIKB RECOVERIU
Liat the percent racovariaa which do not bullbullbullt the criteria for aurrogata recovery
Au _-u ~ q-- 110 bull bullbull middot Matrixbull~
mJI_ TOL JIFB pep HBZ FBP TPH fHL 2PP TBP
to to to to to to to to to to
Surrogate Actiona PERCENT RECOVERY
~ ~ ~ Positive sample raaulta J J J Non-detected results R UJ A
CRR bull Contract Required Recovery Range Surrogate action should be applied
1 bull If at least two aurroatea in a BN or A fraction or one surrogate in the VOA fraction are out of specification but have recoveries of gt10
2 If any one surrogate in a fraction ahova lt10 recovery
REGION I Data Review Worksheets
fgt-100
VII A MATRIX SPIKEMATRIX SPIJa DUPLICATE
1 Matrix SpikeHatrix Spike Duplicate Recoveriea and Precision
lR )loa___ ___ lAveli~ Matrix1
List the tgtbullrcent recovariea and RPDa of coapounda whi ch do not aeet the criteriamiddot atated on Fotll J
bull-8
QUALIFICATION IS LIMITED TO THE UNSPIXED SAMPLE ONLY N 1 If any compound doea not aeet the Contraet Required Recovery range
(CRR) follow the actions stated belovt
PERCENT RECOVERY
~ ~ Poaitiva Sample Reaulta J J Non-detected Results R A
2 If any compound does not meet the RPD criteria flag positive reaulta tor that compound a a estimated (J)
A aeparate worksheet should be used for each MSMSD pair
REGION I Data Review Workaheeta Vll B MATRIX SPliCEMATRIX SPliCE DUPLICATE (Section 2)
3 Matrix Spike Duplicate - UnapUted compoundbull
TR Nos ___ ---
Liat the concentrations of the unspiked compounds and determine the percent RSDbull of the unapiked aample Jiatrix spike and matrix spike duplicate No Uaita have been developed for the RSD valuea of the unapUced compounda
SN1PLpound MS MSp CQNC
8 N
The reviewer auat uaa profeaaional judgement to datenina if there ia a need to qualify any of the unspiked compounds in the sample
REGION I Data Review Workaheeta
VIII PIELD DUPLICATE PRECISION
TR Noa___ --- Matrixamp___
Liat the concentrationbull of the compounda which do not bullbullbullt the followinc RPD criteriat middot
1 middot An RPD of lt30 for water duplicatea 2 An RPD of lt50 for aoil duplicatea
SAJ1PL CONC pup SAMPLE CONC
ACTIONS I
1 If the reaulta for any co111ponda do not bullbullbullt the RPD criteria flag the poaitive reaulta for that compound aa eatbnated
2 If one value ibull non-detected and one ia above the CRQLt a Flag the positive result aa estimated (J) b Flag the non-detected result bullbull estimated (UJ) bull
~~T=~l ~~~bull ~~Y~~lx~middot utilized to apply duplicate actionbull
A separate worksheet should be filled out for each field duplicate pair
REGIOII X Data Review Workaheeta
D DITERHAL STAJIDAIU) PERFORMAIICII tgt1 ~ -h-J-J ~ ~
Liat the internal atandard areaa of aaaplea which do not aaat the criteria of +lOOt or -50 of the internal atandard area in the aaaochtad continuing calibration atandard
OH ltZ
Hr ltlt 0-lt OJgt
00
bull-ACIIOIII
1 If an IS area count ia outaida the criteria -sot or +lOOt of the aaaociatac1 atandarch
a Poaitive reaulta for ~ompounda quantitated uaing that IS are 8flagged aa aatlmatad (J) for that aampla fraction
b Non-datacta for compound a quanti tatad uaing that IS are tlaggad ~ aa estimated (UJ) for that aampla fraction
c If extremely lov area counta ara reported or if perforanceaxhiblta a aajor drop-off than a aavara loaa of aenaitivlty ia indicated Non-detectbull ahould then be flagged aa unusable (R)
2 If an IS retention time varies more than 30 aeconda the chromatoqraphic profile tor that sample aust be examined to determine if any false positives or negatives exiat For ehifta of a large magnitucSe the reviewer may consider partial or total rejection of the cSata for that sample traction
IS OUT H ~~
Data Buaaar IbullT
A bull Acceptable data
J - The a ociated nuaerical value ia an eatibullated quantit
R - ReJect data due to qualitT control criteria Tba data are unuaable (cobullpound bullay or bullay not be preaent) Reaplinamp and reanal7aia h neceaaary for verification
U bull The coapound waa anal7aed for but waa not detected The aaaociated nuaerical value h the aaaple quantitation liait
UJ - The coapound waa anamplJamped for but waa not detected The aaaple quantitation liait h an eatiaated quantitTbull
- The coapound waa analJamped for but waa not detected Tba auple quantltation Uait ia the aua bullbull tba CRQL preaented
- barcode 581461
- barcodetext SDMS Doc ID 581461
REGION I DAtA Review Worksheets
V I BIAHJt ANALYSIS RESULTS (Section 3)
l BlAnk Actionbull
Action levelbull ahould be baeed upon the higheet concentration of contAIIinant determined in Any bhnk The Action level for aamplea vhich have been concentrAted or diluted ahould be bullultipUed by the concentrationdilution fActor No poaitive aample result ahould be reported unlaas the concentrAtion of the compound in the sAmple axceede the Action laval of 10 x a the Amount in the blAnk for the couon contAainAnta or 5 x a the aaount for any other compound Specific act i ona are bullbull follovaz
1 The c oncentr ation is l esa t han the CRQL repor t the CRQL
2 The concent r at i on i s 9reater than the CRQL but l eea than the act i on level r eport the c oncentration found u
3 The concentration Ja greater than the action level r eport the concentration unqualified
For exaaplea refer to the Regional Cuidelinea
Couon contaa inanta bull aethylene chloride acetone 2-butanone tolueneand phthalatea
MbX CONC ACTION LEVEL l1liUI l1liUI
bull middot )IQ
A aeparat~ vorksheet should be used for low and medium level blanka
-bull8 N
REGION I Data Review Workaheata
VI SURROGATE SPIKB RECOVERIU
Liat the percent racovariaa which do not bullbullbullt the criteria for aurrogata recovery
Au _-u ~ q-- 110 bull bullbull middot Matrixbull~
mJI_ TOL JIFB pep HBZ FBP TPH fHL 2PP TBP
to to to to to to to to to to
Surrogate Actiona PERCENT RECOVERY
~ ~ ~ Positive sample raaulta J J J Non-detected results R UJ A
CRR bull Contract Required Recovery Range Surrogate action should be applied
1 bull If at least two aurroatea in a BN or A fraction or one surrogate in the VOA fraction are out of specification but have recoveries of gt10
2 If any one surrogate in a fraction ahova lt10 recovery
REGION I Data Review Worksheets
fgt-100
VII A MATRIX SPIKEMATRIX SPIJa DUPLICATE
1 Matrix SpikeHatrix Spike Duplicate Recoveriea and Precision
lR )loa___ ___ lAveli~ Matrix1
List the tgtbullrcent recovariea and RPDa of coapounda whi ch do not aeet the criteriamiddot atated on Fotll J
bull-8
QUALIFICATION IS LIMITED TO THE UNSPIXED SAMPLE ONLY N 1 If any compound doea not aeet the Contraet Required Recovery range
(CRR) follow the actions stated belovt
PERCENT RECOVERY
~ ~ Poaitiva Sample Reaulta J J Non-detected Results R A
2 If any compound does not meet the RPD criteria flag positive reaulta tor that compound a a estimated (J)
A aeparate worksheet should be used for each MSMSD pair
REGION I Data Review Workaheeta Vll B MATRIX SPliCEMATRIX SPliCE DUPLICATE (Section 2)
3 Matrix Spike Duplicate - UnapUted compoundbull
TR Nos ___ ---
Liat the concentrations of the unspiked compounds and determine the percent RSDbull of the unapiked aample Jiatrix spike and matrix spike duplicate No Uaita have been developed for the RSD valuea of the unapUced compounda
SN1PLpound MS MSp CQNC
8 N
The reviewer auat uaa profeaaional judgement to datenina if there ia a need to qualify any of the unspiked compounds in the sample
REGION I Data Review Workaheeta
VIII PIELD DUPLICATE PRECISION
TR Noa___ --- Matrixamp___
Liat the concentrationbull of the compounda which do not bullbullbullt the followinc RPD criteriat middot
1 middot An RPD of lt30 for water duplicatea 2 An RPD of lt50 for aoil duplicatea
SAJ1PL CONC pup SAMPLE CONC
ACTIONS I
1 If the reaulta for any co111ponda do not bullbullbullt the RPD criteria flag the poaitive reaulta for that compound aa eatbnated
2 If one value ibull non-detected and one ia above the CRQLt a Flag the positive result aa estimated (J) b Flag the non-detected result bullbull estimated (UJ) bull
~~T=~l ~~~bull ~~Y~~lx~middot utilized to apply duplicate actionbull
A separate worksheet should be filled out for each field duplicate pair
REGIOII X Data Review Workaheeta
D DITERHAL STAJIDAIU) PERFORMAIICII tgt1 ~ -h-J-J ~ ~
Liat the internal atandard areaa of aaaplea which do not aaat the criteria of +lOOt or -50 of the internal atandard area in the aaaochtad continuing calibration atandard
OH ltZ
Hr ltlt 0-lt OJgt
00
bull-ACIIOIII
1 If an IS area count ia outaida the criteria -sot or +lOOt of the aaaociatac1 atandarch
a Poaitive reaulta for ~ompounda quantitated uaing that IS are 8flagged aa aatlmatad (J) for that aampla fraction
b Non-datacta for compound a quanti tatad uaing that IS are tlaggad ~ aa estimated (UJ) for that aampla fraction
c If extremely lov area counta ara reported or if perforanceaxhiblta a aajor drop-off than a aavara loaa of aenaitivlty ia indicated Non-detectbull ahould then be flagged aa unusable (R)
2 If an IS retention time varies more than 30 aeconda the chromatoqraphic profile tor that sample aust be examined to determine if any false positives or negatives exiat For ehifta of a large magnitucSe the reviewer may consider partial or total rejection of the cSata for that sample traction
IS OUT H ~~
Data Buaaar IbullT
A bull Acceptable data
J - The a ociated nuaerical value ia an eatibullated quantit
R - ReJect data due to qualitT control criteria Tba data are unuaable (cobullpound bullay or bullay not be preaent) Reaplinamp and reanal7aia h neceaaary for verification
U bull The coapound waa anal7aed for but waa not detected The aaaociated nuaerical value h the aaaple quantitation liait
UJ - The coapound waa anamplJamped for but waa not detected The aaaple quantitation liait h an eatiaated quantitTbull
- The coapound waa analJamped for but waa not detected Tba auple quantltation Uait ia the aua bullbull tba CRQL preaented
- barcode 581461
- barcodetext SDMS Doc ID 581461
REGION I Data Review Workaheata
VI SURROGATE SPIKB RECOVERIU
Liat the percent racovariaa which do not bullbullbullt the criteria for aurrogata recovery
Au _-u ~ q-- 110 bull bullbull middot Matrixbull~
mJI_ TOL JIFB pep HBZ FBP TPH fHL 2PP TBP
to to to to to to to to to to
Surrogate Actiona PERCENT RECOVERY
~ ~ ~ Positive sample raaulta J J J Non-detected results R UJ A
CRR bull Contract Required Recovery Range Surrogate action should be applied
1 bull If at least two aurroatea in a BN or A fraction or one surrogate in the VOA fraction are out of specification but have recoveries of gt10
2 If any one surrogate in a fraction ahova lt10 recovery
REGION I Data Review Worksheets
fgt-100
VII A MATRIX SPIKEMATRIX SPIJa DUPLICATE
1 Matrix SpikeHatrix Spike Duplicate Recoveriea and Precision
lR )loa___ ___ lAveli~ Matrix1
List the tgtbullrcent recovariea and RPDa of coapounda whi ch do not aeet the criteriamiddot atated on Fotll J
bull-8
QUALIFICATION IS LIMITED TO THE UNSPIXED SAMPLE ONLY N 1 If any compound doea not aeet the Contraet Required Recovery range
(CRR) follow the actions stated belovt
PERCENT RECOVERY
~ ~ Poaitiva Sample Reaulta J J Non-detected Results R A
2 If any compound does not meet the RPD criteria flag positive reaulta tor that compound a a estimated (J)
A aeparate worksheet should be used for each MSMSD pair
REGION I Data Review Workaheeta Vll B MATRIX SPliCEMATRIX SPliCE DUPLICATE (Section 2)
3 Matrix Spike Duplicate - UnapUted compoundbull
TR Nos ___ ---
Liat the concentrations of the unspiked compounds and determine the percent RSDbull of the unapiked aample Jiatrix spike and matrix spike duplicate No Uaita have been developed for the RSD valuea of the unapUced compounda
SN1PLpound MS MSp CQNC
8 N
The reviewer auat uaa profeaaional judgement to datenina if there ia a need to qualify any of the unspiked compounds in the sample
REGION I Data Review Workaheeta
VIII PIELD DUPLICATE PRECISION
TR Noa___ --- Matrixamp___
Liat the concentrationbull of the compounda which do not bullbullbullt the followinc RPD criteriat middot
1 middot An RPD of lt30 for water duplicatea 2 An RPD of lt50 for aoil duplicatea
SAJ1PL CONC pup SAMPLE CONC
ACTIONS I
1 If the reaulta for any co111ponda do not bullbullbullt the RPD criteria flag the poaitive reaulta for that compound aa eatbnated
2 If one value ibull non-detected and one ia above the CRQLt a Flag the positive result aa estimated (J) b Flag the non-detected result bullbull estimated (UJ) bull
~~T=~l ~~~bull ~~Y~~lx~middot utilized to apply duplicate actionbull
A separate worksheet should be filled out for each field duplicate pair
REGIOII X Data Review Workaheeta
D DITERHAL STAJIDAIU) PERFORMAIICII tgt1 ~ -h-J-J ~ ~
Liat the internal atandard areaa of aaaplea which do not aaat the criteria of +lOOt or -50 of the internal atandard area in the aaaochtad continuing calibration atandard
OH ltZ
Hr ltlt 0-lt OJgt
00
bull-ACIIOIII
1 If an IS area count ia outaida the criteria -sot or +lOOt of the aaaociatac1 atandarch
a Poaitive reaulta for ~ompounda quantitated uaing that IS are 8flagged aa aatlmatad (J) for that aampla fraction
b Non-datacta for compound a quanti tatad uaing that IS are tlaggad ~ aa estimated (UJ) for that aampla fraction
c If extremely lov area counta ara reported or if perforanceaxhiblta a aajor drop-off than a aavara loaa of aenaitivlty ia indicated Non-detectbull ahould then be flagged aa unusable (R)
2 If an IS retention time varies more than 30 aeconda the chromatoqraphic profile tor that sample aust be examined to determine if any false positives or negatives exiat For ehifta of a large magnitucSe the reviewer may consider partial or total rejection of the cSata for that sample traction
IS OUT H ~~
Data Buaaar IbullT
A bull Acceptable data
J - The a ociated nuaerical value ia an eatibullated quantit
R - ReJect data due to qualitT control criteria Tba data are unuaable (cobullpound bullay or bullay not be preaent) Reaplinamp and reanal7aia h neceaaary for verification
U bull The coapound waa anal7aed for but waa not detected The aaaociated nuaerical value h the aaaple quantitation liait
UJ - The coapound waa anamplJamped for but waa not detected The aaaple quantitation liait h an eatiaated quantitTbull
- The coapound waa analJamped for but waa not detected Tba auple quantltation Uait ia the aua bullbull tba CRQL preaented
- barcode 581461
- barcodetext SDMS Doc ID 581461
REGION I Data Review Worksheets
fgt-100
VII A MATRIX SPIKEMATRIX SPIJa DUPLICATE
1 Matrix SpikeHatrix Spike Duplicate Recoveriea and Precision
lR )loa___ ___ lAveli~ Matrix1
List the tgtbullrcent recovariea and RPDa of coapounda whi ch do not aeet the criteriamiddot atated on Fotll J
bull-8
QUALIFICATION IS LIMITED TO THE UNSPIXED SAMPLE ONLY N 1 If any compound doea not aeet the Contraet Required Recovery range
(CRR) follow the actions stated belovt
PERCENT RECOVERY
~ ~ Poaitiva Sample Reaulta J J Non-detected Results R A
2 If any compound does not meet the RPD criteria flag positive reaulta tor that compound a a estimated (J)
A aeparate worksheet should be used for each MSMSD pair
REGION I Data Review Workaheeta Vll B MATRIX SPliCEMATRIX SPliCE DUPLICATE (Section 2)
3 Matrix Spike Duplicate - UnapUted compoundbull
TR Nos ___ ---
Liat the concentrations of the unspiked compounds and determine the percent RSDbull of the unapiked aample Jiatrix spike and matrix spike duplicate No Uaita have been developed for the RSD valuea of the unapUced compounda
SN1PLpound MS MSp CQNC
8 N
The reviewer auat uaa profeaaional judgement to datenina if there ia a need to qualify any of the unspiked compounds in the sample
REGION I Data Review Workaheeta
VIII PIELD DUPLICATE PRECISION
TR Noa___ --- Matrixamp___
Liat the concentrationbull of the compounda which do not bullbullbullt the followinc RPD criteriat middot
1 middot An RPD of lt30 for water duplicatea 2 An RPD of lt50 for aoil duplicatea
SAJ1PL CONC pup SAMPLE CONC
ACTIONS I
1 If the reaulta for any co111ponda do not bullbullbullt the RPD criteria flag the poaitive reaulta for that compound aa eatbnated
2 If one value ibull non-detected and one ia above the CRQLt a Flag the positive result aa estimated (J) b Flag the non-detected result bullbull estimated (UJ) bull
~~T=~l ~~~bull ~~Y~~lx~middot utilized to apply duplicate actionbull
A separate worksheet should be filled out for each field duplicate pair
REGIOII X Data Review Workaheeta
D DITERHAL STAJIDAIU) PERFORMAIICII tgt1 ~ -h-J-J ~ ~
Liat the internal atandard areaa of aaaplea which do not aaat the criteria of +lOOt or -50 of the internal atandard area in the aaaochtad continuing calibration atandard
OH ltZ
Hr ltlt 0-lt OJgt
00
bull-ACIIOIII
1 If an IS area count ia outaida the criteria -sot or +lOOt of the aaaociatac1 atandarch
a Poaitive reaulta for ~ompounda quantitated uaing that IS are 8flagged aa aatlmatad (J) for that aampla fraction
b Non-datacta for compound a quanti tatad uaing that IS are tlaggad ~ aa estimated (UJ) for that aampla fraction
c If extremely lov area counta ara reported or if perforanceaxhiblta a aajor drop-off than a aavara loaa of aenaitivlty ia indicated Non-detectbull ahould then be flagged aa unusable (R)
2 If an IS retention time varies more than 30 aeconda the chromatoqraphic profile tor that sample aust be examined to determine if any false positives or negatives exiat For ehifta of a large magnitucSe the reviewer may consider partial or total rejection of the cSata for that sample traction
IS OUT H ~~
Data Buaaar IbullT
A bull Acceptable data
J - The a ociated nuaerical value ia an eatibullated quantit
R - ReJect data due to qualitT control criteria Tba data are unuaable (cobullpound bullay or bullay not be preaent) Reaplinamp and reanal7aia h neceaaary for verification
U bull The coapound waa anal7aed for but waa not detected The aaaociated nuaerical value h the aaaple quantitation liait
UJ - The coapound waa anamplJamped for but waa not detected The aaaple quantitation liait h an eatiaated quantitTbull
- The coapound waa analJamped for but waa not detected Tba auple quantltation Uait ia the aua bullbull tba CRQL preaented
- barcode 581461
- barcodetext SDMS Doc ID 581461
REGION I Data Review Workaheeta Vll B MATRIX SPliCEMATRIX SPliCE DUPLICATE (Section 2)
3 Matrix Spike Duplicate - UnapUted compoundbull
TR Nos ___ ---
Liat the concentrations of the unspiked compounds and determine the percent RSDbull of the unapiked aample Jiatrix spike and matrix spike duplicate No Uaita have been developed for the RSD valuea of the unapUced compounda
SN1PLpound MS MSp CQNC
8 N
The reviewer auat uaa profeaaional judgement to datenina if there ia a need to qualify any of the unspiked compounds in the sample
REGION I Data Review Workaheeta
VIII PIELD DUPLICATE PRECISION
TR Noa___ --- Matrixamp___
Liat the concentrationbull of the compounda which do not bullbullbullt the followinc RPD criteriat middot
1 middot An RPD of lt30 for water duplicatea 2 An RPD of lt50 for aoil duplicatea
SAJ1PL CONC pup SAMPLE CONC
ACTIONS I
1 If the reaulta for any co111ponda do not bullbullbullt the RPD criteria flag the poaitive reaulta for that compound aa eatbnated
2 If one value ibull non-detected and one ia above the CRQLt a Flag the positive result aa estimated (J) b Flag the non-detected result bullbull estimated (UJ) bull
~~T=~l ~~~bull ~~Y~~lx~middot utilized to apply duplicate actionbull
A separate worksheet should be filled out for each field duplicate pair
REGIOII X Data Review Workaheeta
D DITERHAL STAJIDAIU) PERFORMAIICII tgt1 ~ -h-J-J ~ ~
Liat the internal atandard areaa of aaaplea which do not aaat the criteria of +lOOt or -50 of the internal atandard area in the aaaochtad continuing calibration atandard
OH ltZ
Hr ltlt 0-lt OJgt
00
bull-ACIIOIII
1 If an IS area count ia outaida the criteria -sot or +lOOt of the aaaociatac1 atandarch
a Poaitive reaulta for ~ompounda quantitated uaing that IS are 8flagged aa aatlmatad (J) for that aampla fraction
b Non-datacta for compound a quanti tatad uaing that IS are tlaggad ~ aa estimated (UJ) for that aampla fraction
c If extremely lov area counta ara reported or if perforanceaxhiblta a aajor drop-off than a aavara loaa of aenaitivlty ia indicated Non-detectbull ahould then be flagged aa unusable (R)
2 If an IS retention time varies more than 30 aeconda the chromatoqraphic profile tor that sample aust be examined to determine if any false positives or negatives exiat For ehifta of a large magnitucSe the reviewer may consider partial or total rejection of the cSata for that sample traction
IS OUT H ~~
Data Buaaar IbullT
A bull Acceptable data
J - The a ociated nuaerical value ia an eatibullated quantit
R - ReJect data due to qualitT control criteria Tba data are unuaable (cobullpound bullay or bullay not be preaent) Reaplinamp and reanal7aia h neceaaary for verification
U bull The coapound waa anal7aed for but waa not detected The aaaociated nuaerical value h the aaaple quantitation liait
UJ - The coapound waa anamplJamped for but waa not detected The aaaple quantitation liait h an eatiaated quantitTbull
- The coapound waa analJamped for but waa not detected Tba auple quantltation Uait ia the aua bullbull tba CRQL preaented
- barcode 581461
- barcodetext SDMS Doc ID 581461
REGION I Data Review Workaheeta
VIII PIELD DUPLICATE PRECISION
TR Noa___ --- Matrixamp___
Liat the concentrationbull of the compounda which do not bullbullbullt the followinc RPD criteriat middot
1 middot An RPD of lt30 for water duplicatea 2 An RPD of lt50 for aoil duplicatea
SAJ1PL CONC pup SAMPLE CONC
ACTIONS I
1 If the reaulta for any co111ponda do not bullbullbullt the RPD criteria flag the poaitive reaulta for that compound aa eatbnated
2 If one value ibull non-detected and one ia above the CRQLt a Flag the positive result aa estimated (J) b Flag the non-detected result bullbull estimated (UJ) bull
~~T=~l ~~~bull ~~Y~~lx~middot utilized to apply duplicate actionbull
A separate worksheet should be filled out for each field duplicate pair
REGIOII X Data Review Workaheeta
D DITERHAL STAJIDAIU) PERFORMAIICII tgt1 ~ -h-J-J ~ ~
Liat the internal atandard areaa of aaaplea which do not aaat the criteria of +lOOt or -50 of the internal atandard area in the aaaochtad continuing calibration atandard
OH ltZ
Hr ltlt 0-lt OJgt
00
bull-ACIIOIII
1 If an IS area count ia outaida the criteria -sot or +lOOt of the aaaociatac1 atandarch
a Poaitive reaulta for ~ompounda quantitated uaing that IS are 8flagged aa aatlmatad (J) for that aampla fraction
b Non-datacta for compound a quanti tatad uaing that IS are tlaggad ~ aa estimated (UJ) for that aampla fraction
c If extremely lov area counta ara reported or if perforanceaxhiblta a aajor drop-off than a aavara loaa of aenaitivlty ia indicated Non-detectbull ahould then be flagged aa unusable (R)
2 If an IS retention time varies more than 30 aeconda the chromatoqraphic profile tor that sample aust be examined to determine if any false positives or negatives exiat For ehifta of a large magnitucSe the reviewer may consider partial or total rejection of the cSata for that sample traction
IS OUT H ~~
Data Buaaar IbullT
A bull Acceptable data
J - The a ociated nuaerical value ia an eatibullated quantit
R - ReJect data due to qualitT control criteria Tba data are unuaable (cobullpound bullay or bullay not be preaent) Reaplinamp and reanal7aia h neceaaary for verification
U bull The coapound waa anal7aed for but waa not detected The aaaociated nuaerical value h the aaaple quantitation liait
UJ - The coapound waa anamplJamped for but waa not detected The aaaple quantitation liait h an eatiaated quantitTbull
- The coapound waa analJamped for but waa not detected Tba auple quantltation Uait ia the aua bullbull tba CRQL preaented
- barcode 581461
- barcodetext SDMS Doc ID 581461
REGIOII X Data Review Workaheeta
D DITERHAL STAJIDAIU) PERFORMAIICII tgt1 ~ -h-J-J ~ ~
Liat the internal atandard areaa of aaaplea which do not aaat the criteria of +lOOt or -50 of the internal atandard area in the aaaochtad continuing calibration atandard
OH ltZ
Hr ltlt 0-lt OJgt
00
bull-ACIIOIII
1 If an IS area count ia outaida the criteria -sot or +lOOt of the aaaociatac1 atandarch
a Poaitive reaulta for ~ompounda quantitated uaing that IS are 8flagged aa aatlmatad (J) for that aampla fraction
b Non-datacta for compound a quanti tatad uaing that IS are tlaggad ~ aa estimated (UJ) for that aampla fraction
c If extremely lov area counta ara reported or if perforanceaxhiblta a aajor drop-off than a aavara loaa of aenaitivlty ia indicated Non-detectbull ahould then be flagged aa unusable (R)
2 If an IS retention time varies more than 30 aeconda the chromatoqraphic profile tor that sample aust be examined to determine if any false positives or negatives exiat For ehifta of a large magnitucSe the reviewer may consider partial or total rejection of the cSata for that sample traction
IS OUT H ~~
Data Buaaar IbullT
A bull Acceptable data
J - The a ociated nuaerical value ia an eatibullated quantit
R - ReJect data due to qualitT control criteria Tba data are unuaable (cobullpound bullay or bullay not be preaent) Reaplinamp and reanal7aia h neceaaary for verification
U bull The coapound waa anal7aed for but waa not detected The aaaociated nuaerical value h the aaaple quantitation liait
UJ - The coapound waa anamplJamped for but waa not detected The aaaple quantitation liait h an eatiaated quantitTbull
- The coapound waa analJamped for but waa not detected Tba auple quantltation Uait ia the aua bullbull tba CRQL preaented
- barcode 581461
- barcodetext SDMS Doc ID 581461
Data Buaaar IbullT
A bull Acceptable data
J - The a ociated nuaerical value ia an eatibullated quantit
R - ReJect data due to qualitT control criteria Tba data are unuaable (cobullpound bullay or bullay not be preaent) Reaplinamp and reanal7aia h neceaaary for verification
U bull The coapound waa anal7aed for but waa not detected The aaaociated nuaerical value h the aaaple quantitation liait
UJ - The coapound waa anamplJamped for but waa not detected The aaaple quantitation liait h an eatiaated quantitTbull
- The coapound waa analJamped for but waa not detected Tba auple quantltation Uait ia the aua bullbull tba CRQL preaented
- barcode 581461
- barcodetext SDMS Doc ID 581461