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LONGHORN ARMY AMMUNITION PLANT
KARNACK, TEXAS
ADMINISTRATIVE RECORD
Volume 17 of 19
2010
Bate Stamp Numbers 00096688 – 00097694
Prepared for
Department of the Army Longhorn Army Ammunition Plant
1976 – 2010
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LONGHORN ARMY AMMUNITION PLANT KARNACK, TEXAS
ADMINISTRATIVE RECORD – CHRONOLOGICAL INDEX
VOLUME 17 of 19 2010 A. Title: Report – (Continued) Final Feasibility Study, LHAAP-29, Former TNT Production Area, Group 2, Longhorn Army Ammunition Plant, Karnack, Texas, April 2010 Author(s): US Army Corps of Engineers Recipient: USEPA Date: April 30, 2010 Bate Stamp: 00096688 – 00097694
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Corporate Information:
Microbac Laboratories, Inc.
Franklin Corporate Center
2000 Corporate Drive, Suite 350
Wexford, PA 15090
Phone: (724) 934-5030
FAX: (724) 934-5088
www.microbac.com
President & CEO: J. Trevor Boyce
Federal Tax ID#: 25-1199-642
DUNS#: 048192892
Incorporated in the State of PA -- May 1, 1969
Employees Corporate-Wide: 467
Facilities Corporate –Wide: 18 Divisions, 28 locations across 15 states
Phone: 800-373-4071 Fax: 740-373-4835
Email: [email protected]
Microbac Laboratories Inc. Ohio Valley Division 158 Starlite Drive
Marietta, OH 45750
Please note these administrative changes for our Ohio Valley Division laboratory in Marietta, OH (formerly KEMRON Environmental Services, Inc.) , in particular the address, which is a revised routing of remittances on our invoices. All invoices dated April 1, 2008 or later will reflect this change, and will be highlighted with an attention-getting sticker during our transition. Please adjust your records to ensure proper routing of payments.
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Quick Facts
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00096688
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158 Starlite Drive, Marietta, OH 45750 • T:740-373-4071 • F:740-373-4835 • http://www.microbac.com
Laboratory Report Number: L08100667
Please find enclosed the analytical results for the samples you submitted to Microbac Laboratories.
Review and compilation of your report was completed by Microbac’s Sales and Service Team. If you have questions,comments or require further assistance regarding this report, please contact your team member noted in the reviewedbox bleow at 800-373-4071. Team member e-mail addresses also appear here for your convenience.
Kathy Albertson Team Chemist/Data Specialist [email protected] Mossburg Team Chemist/Data Specialist [email protected] Long Team Chemist/Data Specialist [email protected] Gregory Client Services Specialist [email protected] Fickiesen Client Services Specialist [email protected] Brown Client Services Specialist [email protected] Parsons Team Assistant [email protected]
This report was reviewed on November 03, 2008.
Stephanie Mossburg - Team Chemist/Data Specialist
I certify that all test results meet all of the requirements of the accrediting authority listed below. All results for soilsamples are reported on a ’dry-weight’ basis unless specified otherwise. Analytical results for water and wastes arereported on a ’as received’ basis unless specified otherwise. A statement of uncertainty for each analysis is availableupon request. This laboratory report shall not be reproduced, except in full, without the written approval of MicrobacLaboratories.
This report was certified on November 03, 2008.
David Vandenberg - Managing Director
State of origin: TexasAccrediting authority: Texas Commission on Environmental Quality ID:T104704252-07-TXQAPP: Microbac (OVD) LQAPThis report contains a total of 266 pages.
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Microbac REPORT L08100667PREPARED FOR Shaw E I, Inc.WORK ID:
1.0 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42.1 Metals Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21
2.1.1 Metals I C P Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 222.1.1.1 Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 232.1.1.2 QC Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48
2.1.2 Metals ICP-MS Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1532.1.2.1 Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1542.1.2.2 QC Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 167
2.1.3 Metals CVAA Data (Mercury) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2232.1.3.1 Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2242.1.3.2 QC Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 233
3.0 Attachments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 259
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00096690
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1.0 Introduction
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00096691
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ID: 84941
Microbac Laboratories Inc.REPORT NARRATIVE
Microbac Login No: L08100667
CHAIN OF CUSTODY: The chain of custody number was 5424.
SHIPMENT CONDITIONS: The chain of custody forms were received sealed in a cooler. The cooler temperaturewas 1 degrees C.
SAMPLE MANAGEMENT: All samples received were intact.
I certify that this data package is in compliance with the terms and conditions agreed to by the client and MicrobacLaboratories Inc., both technically and for completeness, except for the conditions noted above. Release of the datacontained in this hardcopy data package has been authorized by the Laboratory Manager or designated person, asverified by the following signature.
Approved: 28-OCT-08
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00096692
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Laboratory Data Package Cover PageThis data Package consists of:
This signature page, the laboratory review checklists, and the following reportable data:R1 Field chain-of-custody documentation;R2 sample identification cross-reference;R3 Test reports (analytical data sheets) for each enviornmental sample that includes:
a) Items consistant with NELAC 5.13 or ISO/IEC 17025 Section 5.10b) dilution factors,c) preparation methods,d) Cleanup methods, ande) If required for the project, tentatively identified compounds (TICs)
R4 Surrogate recovery data including:a) Calculated recovery (%R) for each analyte, andb) The laboratory’s surrogate QC limits.
R5 Test reports/summary forms for blank samples;R6 Test reports/summary forms FOR laboratory control samples (LCSs) including:
a) LCS spiking amount,b) Calculated %R for each analyte, andc) The laboratory”s LCS QC limits.
R7 Test reports for project matrix spike/matrix spike duplicates (MS/MSDs) including:a) Samples associated with the MS/MSD clearly identified,b) MS/MSD spiking amounts,c) Concentration of each MS/MSD analyte measured in the parent and spiked samples,d) Calculated %R and relative percent differences (RPDs), ande) The laboratory’s MS/MSD QC limits
R8 Laboratory analytical duplicate (if applicable) revocery and precision:a) the amount of analyte measured in the duplicate,b) the calculated RPD, andc) the laboratory’s QC limits for anlytical duplicates.
R9 List of method quantitation limits (MQLs) for each analyte for each method and matrix;R10 Other problems or anomalies.The exception Report for every ”No” or ”Not Reviewed (NR)” item in laboratory review checklist.
Release statement: I am responsible for the release of this laboratory data package. This data package has been reviewed by thelaboratory and is complete and technically compliant with the requirements of the methods used, except where noted by the laboratoryin the attached exceptions reports. By my signature below, I affirm to the best of my knowledge, all problems/anomalies, observed bythe laboratory as having the potential to affect the quality of the data, have been identified by the laboratoy in the Laboratory ReviewChecklist, and no information or data have been knowingly withheld that would affect the quality of the data.
Check, If applicable: [] This laboratory is an in-house laboratory controlled by the person repsonding to rule. The official signing thecover page of the rule-required report (for example, the APAR) in which these data are used is responsible for releasing this datapackage and is by signature affirming the above release statement is trus.
MAREN M. BEERY Metals Supervisor October 27, 2008
Name (Printed) Signature Official Title (printed) DATE
RG-366/TRRP-13 December 2002 A1
6
00096693
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Checklist ID: 33035
Microbac Laboratories Inc.Laboratory Review Checklist
Laboratory Name: Microbac Laboratories Inc.Laboratory Log Number: L08100667Project Name: 798-LONGHORNMethod: 6010Prep Batch Number(s): WG285777Reviewer Name: MAREN M. BEERYLRC Date: October 27, 2008
Description Yes No NA(1) NR(2) ER(3)
Chain-Of-Custody (C-O-C)Did samples meet the laboratory’s standard conditions of sample acceptability uponreceipt?
X
Were all departures from standard conditions described in an exception report? XSample and quality control (QC) identificationAre all field sample ID numbers cross-referenced to the laboratory ID numbers? XAre all laboratory ID numbers cross-referenced to the corresponding QC data? XTest reportsWere all samples prepared and analyzed within holding times? XOther than those results
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Description Yes No NA(1) NR(2) ER(3)
Were MS/MSD RPDs within laboratory QC limits? XAnalytical duplicate dataWere appropriate analytical duplicates analyzed for each matrix? XWere analytical duplicates analyzed at the appropriate frequency? XWere RPDs or relative standard deviations within the laboratory QC limits? XMethod quantitation limits (MQLs):Are the MQLs for each method analyte included in the laboratory data package? XDo the MQLs correspond to the concentration of the lowest non-zero calibration standard? XAre unadjusted MQLs included in the laboratory data package? XOther problems/anomaliesAre all known problems/anomalies/special conditions noted in this LRC and ER? XWere all necessary corrective actions performed for the reported data? XWas applicable and available technology used to lower the SQL minimize the matrixinterference affects on the sample results?
X ER3
ICALWere response factors and/or relative response factors for each analyte within QC limits? XWere percent RSDs or correlation coefficient criteria met? XWas the number of standards recommended in the method used for all analytes? XWere all points generated between the lowest and highest standard used to calculate thecurve?
X
Are ICAL data available for all instruments used? XHas the initial calibration curve been verified using an appropriate second source standard? XInitial and continuing calibration verification (ICV and CCV) and continuingcalibration blank (CCB):Was the CCV analyzed at the method-required frequency? XWere percent differences for each analyte within the method-required QC limits? X ER1Was the ICAL curve verified for each analyte? XWas the absolute value of the analyte concentration in the inorganic CCB
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Description Yes No NA(1) NR(2) ER(3)
Standards documentationAre all standards used in the analyses NIST-traceable or obtained from other appropriatesources?
X
Compound/analyte identification proceduresAre the procedures for compound/analyte identification documented? XDemonstration of analyst competency (DOC)Was DOC conducted consistent with NELAC Chapter 5C or ISO/IEC 4? XIs documentation of the analyst’s competency up-to-date and on file? XVerification/validation documentation for methods (NELAC Chap 5 or ISO/IEC17025 Section 5)Are all the methods used to generate the data documented, verified, and validated, whereapplicable?
X
Laboratory standard operating procedures (SOPs):Are laboratory SOPs current and on file for each method performed? X
9
00096696
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Checklist ID: 33035
Microbac Laboratories Inc.Laboratory Review Checklist
Laboratory Name: Microbac Laboratories Inc.Laboratory Log Number: L08100667Project Name: 798-LONGHORNMethod: 6010Prep Batch Number(s): WG285777Reviewer Name: MAREN M. BEERYLRC Date: October 27, 2008
EXCEPTIONS REPORTER#1 - Due to continuing calibration verification failure for calcium and iron on 25-OCT-2008 at 01:15, all batch QA/QC andclient samples were reanalyzed on a later calibration for calcium and iron.ER2 - Client samples 01 through 07 required dilution analysis in order to obtain results for sodium within the linear range.Client samples 03 and 04 required dilution analysis in order to obtain results for calcium within the linear range. ER3 - Due toresults that were noncompliant on the negative side upon initial analysis, vanadium for client samples 01, 02, 05, 06 and 07 wasreported from dilution analyses.Footnotes:(1) NA = Not applicable to method or project(2) NR = Not reviewed(3) ER# = Exception report number
10
00096697
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Laboratory Data Package Cover PageThis data Package consists of:
This signature page, the laboratory review checklists, and the following reportable data:R1 Field chain-of-custody documentation;R2 sample identification cross-reference;R3 Test reports (analytical data sheets) for each enviornmental sample that includes:
a) Items consistant with NELAC 5.13 or ISO/IEC 17025 Section 5.10b) dilution factors,c) preparation methods,d) Cleanup methods, ande) If required for the project, tentatively identified compounds (TICs)
R4 Surrogate recovery data including:a) Calculated recovery (%R) for each analyte, andb) The laboratory’s surrogate QC limits.
R5 Test reports/summary forms for blank samples;R6 Test reports/summary forms FOR laboratory control samples (LCSs) including:
a) LCS spiking amount,b) Calculated %R for each analyte, andc) The laboratory”s LCS QC limits.
R7 Test reports for project matrix spike/matrix spike duplicates (MS/MSDs) including:a) Samples associated with the MS/MSD clearly identified,b) MS/MSD spiking amounts,c) Concentration of each MS/MSD analyte measured in the parent and spiked samples,d) Calculated %R and relative percent differences (RPDs), ande) The laboratory’s MS/MSD QC limits
R8 Laboratory analytical duplicate (if applicable) revocery and precision:a) the amount of analyte measured in the duplicate,b) the calculated RPD, andc) the laboratory’s QC limits for anlytical duplicates.
R9 List of method quantitation limits (MQLs) for each analyte for each method and matrix;R10 Other problems or anomalies.The exception Report for every ”No” or ”Not Reviewed (NR)” item in laboratory review checklist.
Release statement: I am responsible for the release of this laboratory data package. This data package has been reviewed by thelaboratory and is complete and technically compliant with the requirements of the methods used, except where noted by the laboratoryin the attached exceptions reports. By my signature below, I affirm to the best of my knowledge, all problems/anomalies, observed bythe laboratory as having the potential to affect the quality of the data, have been identified by the laboratoy in the Laboratory ReviewChecklist, and no information or data have been knowingly withheld that would affect the quality of the data.
Check, If applicable: [] This laboratory is an in-house laboratory controlled by the person repsonding to rule. The official signing thecover page of the rule-required report (for example, the APAR) in which these data are used is responsible for releasing this datapackage and is by signature affirming the above release statement is trus.
MAREN M. BEERY Metals Supervisor October 31, 2008
Name (Printed) Signature Official Title (printed) DATE
RG-366/TRRP-13 December 2002 A1
11
00096698
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Checklist ID: 33198
Microbac Laboratories Inc.Laboratory Review Checklist
Laboratory Name: Microbac Laboratories Inc.Laboratory Log Number: L08100667Project Name: 798-LONGHORNMethod: 7471Prep Batch Number(s): WG285904Reviewer Name: MAREN M. BEERYLRC Date: October 31, 2008
Description Yes No NA(1) NR(2) ER(3)
Chain-Of-Custody (C-O-C)Did samples meet the laboratory’s standard conditions of sample acceptability uponreceipt?
X
Were all departures from standard conditions described in an exception report? XSample and quality control (QC) identificationAre all field sample ID numbers cross-referenced to the laboratory ID numbers? XAre all laboratory ID numbers cross-referenced to the corresponding QC data? XTest reportsWere all samples prepared and analyzed within holding times? XOther than those results
-
Description Yes No NA(1) NR(2) ER(3)
Were MS/MSD RPDs within laboratory QC limits? XAnalytical duplicate dataWere appropriate analytical duplicates analyzed for each matrix? XWere analytical duplicates analyzed at the appropriate frequency? XWere RPDs or relative standard deviations within the laboratory QC limits? XMethod quantitation limits (MQLs):Are the MQLs for each method analyte included in the laboratory data package? XDo the MQLs correspond to the concentration of the lowest non-zero calibration standard? XAre unadjusted MQLs included in the laboratory data package? XOther problems/anomaliesAre all known problems/anomalies/special conditions noted in this LRC and ER? XWere all necessary corrective actions performed for the reported data? XWas applicable and available technology used to lower the SQL minimize the matrixinterference affects on the sample results?
X
ICALWere response factors and/or relative response factors for each analyte within QC limits? XWere percent RSDs or correlation coefficient criteria met? XWas the number of standards recommended in the method used for all analytes? XWere all points generated between the lowest and highest standard used to calculate thecurve?
X
Are ICAL data available for all instruments used? XHas the initial calibration curve been verified using an appropriate second source standard? XInitial and continuing calibration verification (ICV and CCV) and continuingcalibration blank (CCB):Was the CCV analyzed at the method-required frequency? XWere percent differences for each analyte within the method-required QC limits? XWas the ICAL curve verified for each analyte? XWas the absolute value of the analyte concentration in the inorganic CCB
-
Description Yes No NA(1) NR(2) ER(3)
Standards documentationAre all standards used in the analyses NIST-traceable or obtained from other appropriatesources?
X
Compound/analyte identification proceduresAre the procedures for compound/analyte identification documented? XDemonstration of analyst competency (DOC)Was DOC conducted consistent with NELAC Chapter 5C or ISO/IEC 4? XIs documentation of the analyst’s competency up-to-date and on file? XVerification/validation documentation for methods (NELAC Chap 5 or ISO/IEC17025 Section 5)Are all the methods used to generate the data documented, verified, and validated, whereapplicable?
X
Laboratory standard operating procedures (SOPs):Are laboratory SOPs current and on file for each method performed? X
14
00096701
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Checklist ID: 33198
Microbac Laboratories Inc.Laboratory Review Checklist
Laboratory Name: Microbac Laboratories Inc.Laboratory Log Number: L08100667Project Name: 798-LONGHORNMethod: 7471Prep Batch Number(s): WG285904Reviewer Name: MAREN M. BEERYLRC Date: October 31, 2008
EXCEPTIONS REPORTER# - DescriptionFootnotes:(1) NA = Not applicable to method or project(2) NR = Not reviewed(3) ER# = Exception report number
15
00096702
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Laboratory Data Package Cover PageThis data Package consists of:
This signature page, the laboratory review checklists, and the following reportable data:R1 Field chain-of-custody documentation;R2 sample identification cross-reference;R3 Test reports (analytical data sheets) for each enviornmental sample that includes:
a) Items consistant with NELAC 5.13 or ISO/IEC 17025 Section 5.10b) dilution factors,c) preparation methods,d) Cleanup methods, ande) If required for the project, tentatively identified compounds (TICs)
R4 Surrogate recovery data including:a) Calculated recovery (%R) for each analyte, andb) The laboratory’s surrogate QC limits.
R5 Test reports/summary forms for blank samples;R6 Test reports/summary forms FOR laboratory control samples (LCSs) including:
a) LCS spiking amount,b) Calculated %R for each analyte, andc) The laboratory”s LCS QC limits.
R7 Test reports for project matrix spike/matrix spike duplicates (MS/MSDs) including:a) Samples associated with the MS/MSD clearly identified,b) MS/MSD spiking amounts,c) Concentration of each MS/MSD analyte measured in the parent and spiked samples,d) Calculated %R and relative percent differences (RPDs), ande) The laboratory’s MS/MSD QC limits
R8 Laboratory analytical duplicate (if applicable) revocery and precision:a) the amount of analyte measured in the duplicate,b) the calculated RPD, andc) the laboratory’s QC limits for anlytical duplicates.
R9 List of method quantitation limits (MQLs) for each analyte for each method and matrix;R10 Other problems or anomalies.The exception Report for every ”No” or ”Not Reviewed (NR)” item in laboratory review checklist.
Release statement: I am responsible for the release of this laboratory data package. This data package has been reviewed by thelaboratory and is complete and technically compliant with the requirements of the methods used, except where noted by the laboratoryin the attached exceptions reports. By my signature below, I affirm to the best of my knowledge, all problems/anomalies, observed bythe laboratory as having the potential to affect the quality of the data, have been identified by the laboratoy in the Laboratory ReviewChecklist, and no information or data have been knowingly withheld that would affect the quality of the data.
Check, If applicable: [] This laboratory is an in-house laboratory controlled by the person repsonding to rule. The official signing thecover page of the rule-required report (for example, the APAR) in which these data are used is responsible for releasing this datapackage and is by signature affirming the above release statement is trus.
MAREN M. BEERY Metals Supervisor October 27, 2008
Name (Printed) Signature Official Title (printed) DATE
RG-366/TRRP-13 December 2002 A1
16
00096703
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Checklist ID: 33046
Microbac Laboratories Inc.Laboratory Review Checklist
Laboratory Name: Microbac Laboratories Inc.Laboratory Log Number: L08100667Project Name: 798-LONGHORNMethod: 6020Prep Batch Number(s): WG285801Reviewer Name: MAREN M. BEERYLRC Date: October 27, 2008
Description Yes No NA(1) NR(2) ER(3)
Chain-Of-Custody (C-O-C)Did samples meet the laboratory’s standard conditions of sample acceptability uponreceipt?
X
Were all departures from standard conditions described in an exception report? XSample and quality control (QC) identificationAre all field sample ID numbers cross-referenced to the laboratory ID numbers? XAre all laboratory ID numbers cross-referenced to the corresponding QC data? XTest reportsWere all samples prepared and analyzed within holding times? XOther than those results
-
Description Yes No NA(1) NR(2) ER(3)
Were MS/MSD RPDs within laboratory QC limits? XAnalytical duplicate dataWere appropriate analytical duplicates analyzed for each matrix? XWere analytical duplicates analyzed at the appropriate frequency? XWere RPDs or relative standard deviations within the laboratory QC limits? XMethod quantitation limits (MQLs):Are the MQLs for each method analyte included in the laboratory data package? XDo the MQLs correspond to the concentration of the lowest non-zero calibration standard? XAre unadjusted MQLs included in the laboratory data package? XOther problems/anomaliesAre all known problems/anomalies/special conditions noted in this LRC and ER? XWere all necessary corrective actions performed for the reported data? XWas applicable and available technology used to lower the SQL minimize the matrixinterference affects on the sample results?
X ER3
ICALWere response factors and/or relative response factors for each analyte within QC limits? XWere percent RSDs or correlation coefficient criteria met? XWas the number of standards recommended in the method used for all analytes? XWere all points generated between the lowest and highest standard used to calculate thecurve?
X
Are ICAL data available for all instruments used? XHas the initial calibration curve been verified using an appropriate second source standard? XInitial and continuing calibration verification (ICV and CCV) and continuingcalibration blank (CCB):Was the CCV analyzed at the method-required frequency? XWere percent differences for each analyte within the method-required QC limits? XWas the ICAL curve verified for each analyte? XWas the absolute value of the analyte concentration in the inorganic CCB
-
Description Yes No NA(1) NR(2) ER(3)
Standards documentationAre all standards used in the analyses NIST-traceable or obtained from other appropriatesources?
X
Compound/analyte identification proceduresAre the procedures for compound/analyte identification documented? XDemonstration of analyst competency (DOC)Was DOC conducted consistent with NELAC Chapter 5C or ISO/IEC 4? XIs documentation of the analyst’s competency up-to-date and on file? XVerification/validation documentation for methods (NELAC Chap 5 or ISO/IEC17025 Section 5)Are all the methods used to generate the data documented, verified, and validated, whereapplicable?
X
Laboratory standard operating procedures (SOPs):Are laboratory SOPs current and on file for each method performed? X
19
00096706
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Checklist ID: 33046
Microbac Laboratories Inc.Laboratory Review Checklist
Laboratory Name: Microbac Laboratories Inc.Laboratory Log Number: L08100667Project Name: 798-LONGHORNMethod: 6020Prep Batch Number(s): WG285801Reviewer Name: MAREN M. BEERYLRC Date: October 27, 2008
EXCEPTIONS REPORTER#1 - Chromium for client sample 01 was reported from the two fold dilution where the two fold post digestion spike wascompliant.ER2 - Client samples 02 and 06 required dilution analyses in order to obtain results for manganese within the linear range.Client sample 05 required dilution analysis in order to obtain a result for nickel within the linear range.ER3 - Due to the dark color of the digestate, client sample 07 was analyzed at a dilution.Footnotes:(1) NA = Not applicable to method or project(2) NR = Not reviewed(3) ER# = Exception report number
20
00096707
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2.1 Metals Data
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2.1.1 Metals I C P Data
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2.1.1.1 Summary Data
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LABORATORY REPORT
11/03/08 17:20
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1 OFL1_A_PROD - Modified 03/06/2008
11/03/2008 17:20Report generated:1240187PDF File ID:
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Sample Analysis Summary
Date Received
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Attention: Larry Duty
Account Name: Shaw E & I, Inc.ABB Lummus Biulding3010 Briarpark Drive Suite 4NHouston, TX 77042
Project Number:
Site:
2773.025Longhorn AAP
P.O. Number: 389869/ 390836(GWTP)
Submitted By
For
Microbac Laboratories Inc.
158 Starlite Drive
Marietta OH 45750,740 373 4071)( -
Method
6010B
6010B
6010B
6010B
6010B
6010B
6010B
6010B
6010B
6010B
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6010B
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6010B
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6010B
6010B
6010B
6010B
LONGHORN AAP KARNACK TXProject:
24
00096711
-
L08100667
November 3, 2008
Report Number:
Report Date :
1 of
Microbac Laboratories Inc.
23
Sodium, TotalAnalyte Qual
1.252.50372ResultCAS. Number
7440-23-5
L08100667-01Sample Number: PE-ICP2Instrument:
P2.102808.114616File ID:10/28/2008Run Date:Analyst:10/28/2008 08:34Cal Date:
11:46Workgroup Number:Matrix: Analytical Method:Water
MW118-102008Client ID:
Sample Tag:DL01Dilution:
Units:
WG2858236010BJYH5mg/L
Collect Date:10/20/2008 15:15
Prep Method:3005A 10/23/2008 08:48Prep Date:
PQL SDL
NONEPrePrep Method:
25
00096712
-
L08100667
November 3, 2008
Report Number:
Report Date :
2 of
Microbac Laboratories Inc.
23
Calcium, Total Iron, Total Vanadium, Total
Analyte
UU
Qual0.1000.02500.00500
0.2000.1000.0100
347ResultCAS. Number
7440-70-27439-89-67440-62-2
L08100667-01Sample Number: PE-ICP2Instrument:
P2.102908.133751File ID:10/29/2008Run Date:Analyst:10/29/2008 09:26Cal Date:
13:37Workgroup Number:Matrix: Analytical Method:Water
MW118-102008Client ID:
Sample Tag:02Dilution:
Units:
WG2858236010BJYH1mg/L
Collect Date:10/20/2008 15:15
Prep Method:3005A 10/23/2008 08:48Prep Date:
U Not detected at or above adjusted sample detection limit
PQL SDL
NONEPrePrep Method:
26
00096713
-
L08100667
November 3, 2008
Report Number:
Report Date :
3 of
Microbac Laboratories Inc.
23
Aluminum, Total Beryllium, Total Cobalt, Total Magnesium, Total Potassium, Total Zinc, Total
AnalyteUUU
J
Qual0.0500
0.0005000.002500.2500.250
0.00500
0.1000.002000.005000.5001.00
0.0200
1871.99
0.0193
ResultCAS. Number7429-90-57440-41-77440-48-47439-95-47440-09-77440-66-6
L08100667-01Sample Number: PE-ICP2Instrument:
P2.102508.032154File ID:10/25/2008Run Date:Analyst:10/24/2008 14:46Cal Date:
03:21Workgroup Number:Matrix: Analytical Method:Water
MW118-102008Client ID:
Sample Tag:01Dilution:
Units:
WG2858236010BJYH1mg/L
Collect Date:10/20/2008 15:15
Prep Method:3005A 10/23/2008 08:48Prep Date:
U Not detected at or above adjusted sample detection limitJ The analyte was positively identified, but the quantitation was below the RL
PQL SDL
NONEPrePrep Method:
27
00096714
-
L08100667
November 3, 2008
Report Number:
Report Date :
4 of
Microbac Laboratories Inc.
23
Sodium, TotalAnalyte Qual
1.252.50207ResultCAS. Number
7440-23-5
L08100667-02Sample Number: PE-ICP2Instrument:
P2.102808.115241File ID:10/28/2008Run Date:Analyst:10/28/2008 08:34Cal Date:
11:52Workgroup Number:Matrix: Analytical Method:Water
MW114-102008Client ID:
Sample Tag:DL01Dilution:
Units:
WG2858236010BJYH5mg/L
Collect Date:10/20/2008 16:10
Prep Method:3005A 10/23/2008 08:48Prep Date:
PQL SDL
NONEPrePrep Method:
28
00096715
-
L08100667
November 3, 2008
Report Number:
Report Date :
5 of
Microbac Laboratories Inc.
23
Aluminum, Total Beryllium, Total Cobalt, Total Magnesium, Total Potassium, Total Zinc, Total
AnalyteJU
Qual0.0500
0.0005000.002500.2500.250
0.00500
0.1000.002000.005000.5001.00
0.0200
0.0846
0.006141603.26
0.0200
ResultCAS. Number7429-90-57440-41-77440-48-47439-95-47440-09-77440-66-6
L08100667-02Sample Number: PE-ICP2Instrument:
P2.102508.032814File ID:10/25/2008Run Date:Analyst:10/24/2008 14:46Cal Date:
03:28Workgroup Number:Matrix: Analytical Method:Water
MW114-102008Client ID:
Sample Tag:01Dilution:
Units:
WG2858236010BJYH1mg/L
Collect Date:10/20/2008 16:10
Prep Method:3005A 10/23/2008 08:48Prep Date:
J The analyte was positively identified, but the quantitation was below the RLU Not detected at or above adjusted sample detection limit
PQL SDL
NONEPrePrep Method:
29
00096716
-
L08100667
November 3, 2008
Report Number:
Report Date :
6 of
Microbac Laboratories Inc.
23
Calcium, Total Iron, Total Vanadium, Total
Analyte
U
Qual0.5000.1250.0250
1.000.5000.0500
1611.10
ResultCAS. Number7440-70-27439-89-67440-62-2
L08100667-02Sample Number: PE-ICP2Instrument:
P2.102908.135035File ID:10/29/2008Run Date:Analyst:10/29/2008 09:26Cal Date:
13:50Workgroup Number:Matrix: Analytical Method:Water
MW114-102008Client ID:
Sample Tag:DL02Dilution:
Units:
WG2858236010BJYH5mg/L
Collect Date:10/20/2008 16:10
Prep Method:3005A 10/23/2008 08:48Prep Date:
U Not detected at or above adjusted sample detection limit
PQL SDL
NONEPrePrep Method:
30
00096717
-
L08100667
November 3, 2008
Report Number:
Report Date :
7 of
Microbac Laboratories Inc.
23
Aluminum, Total Beryllium, Total Cobalt, Total Magnesium, Total Potassium, Total Vanadium, Total Zinc, Total
Analyte
UJ
U
Qual0.0500
0.0005000.002500.2500.250
0.005000.00500
0.1000.002000.005000.5001.00
0.01000.0200
0.439
0.004293555.85
0.0391
ResultCAS. Number7429-90-57440-41-77440-48-47439-95-47440-09-77440-62-27440-66-6
L08100667-03Sample Number: PE-ICP2Instrument:
P2.102508.033440File ID:10/25/2008Run Date:Analyst:10/24/2008 14:46Cal Date:
03:34Workgroup Number:Matrix: Analytical Method:Water
MW116-102108Client ID:
Sample Tag:01Dilution:
Units:
WG2858236010BJYH1mg/L
Collect Date:10/21/2008 11:05
Prep Method:3005A 10/23/2008 08:48Prep Date:
U Not detected at or above adjusted sample detection limitJ The analyte was positively identified, but the quantitation was below the RL
PQL SDL
NONEPrePrep Method:
31
00096718
-
L08100667
November 3, 2008
Report Number:
Report Date :
8 of
Microbac Laboratories Inc.
23
Calcium, Total Iron, Total
Analyte Qual0.5000.125
1.000.500
5091.66
ResultCAS. Number7440-70-27439-89-6
L08100667-03Sample Number: PE-ICP2Instrument:
P2.102908.140309File ID:10/29/2008Run Date:Analyst:10/29/2008 09:26Cal Date:
14:03Workgroup Number:Matrix: Analytical Method:Water
MW116-102108Client ID:
Sample Tag:DL01Dilution:
Units:
WG2858236010BJYH5mg/L
Collect Date:10/21/2008 11:05
Prep Method:3005A 10/23/2008 08:48Prep Date:
PQL SDL
NONEPrePrep Method:
32
00096719
-
L08100667
November 3, 2008
Report Number:
Report Date :
9 of
Microbac Laboratories Inc.
23
Sodium, TotalAnalyte Qual
1.252.50514ResultCAS. Number
7440-23-5
L08100667-03Sample Number: PE-ICP2Instrument:
P2.102808.115859File ID:10/28/2008Run Date:Analyst:10/28/2008 08:34Cal Date:
11:58Workgroup Number:Matrix: Analytical Method:Water
MW116-102108Client ID:
Sample Tag:02Dilution:
Units:
WG2858236010BJYH5mg/L
Collect Date:10/21/2008 11:05
Prep Method:3005A 10/23/2008 08:48Prep Date:
PQL SDL
NONEPrePrep Method:
33
00096720
-
L08100667
November 3, 2008
Report Number:
Report Date :
10 of
Microbac Laboratories Inc.
23
Sodium, TotalAnalyte Qual
1.252.50512ResultCAS. Number
7440-23-5
L08100667-04Sample Number: PE-ICP2Instrument:
P2.102808.120520File ID:10/28/2008Run Date:Analyst:10/28/2008 08:34Cal Date:
12:05Workgroup Number:Matrix: Analytical Method:Water
MW116-102108-QAClient ID:
Sample Tag:DL01Dilution:
Units:
WG2858236010BJYH5mg/L
Collect Date:10/21/2008 11:05
Prep Method:3005A 10/23/2008 08:48Prep Date:
PQL SDL
NONEPrePrep Method:
34
00096721
-
L08100667
November 3, 2008
Report Number:
Report Date :
11 of
Microbac Laboratories Inc.
23
Aluminum, Total Beryllium, Total Cobalt, Total Magnesium, Total Potassium, Total Vanadium, Total Zinc, Total
Analyte
UJ
U
Qual0.0500
0.0005000.002500.2500.250
0.005000.00500
0.1000.002000.005000.5001.00
0.01000.0200
0.445
0.004083545.74
0.0399
ResultCAS. Number7429-90-57440-41-77440-48-47439-95-47440-09-77440-62-27440-66-6
L08100667-04Sample Number: PE-ICP2Instrument:
P2.102508.034106File ID:10/25/2008Run Date:Analyst:10/24/2008 14:46Cal Date:
03:41Workgroup Number:Matrix: Analytical Method:Water
MW116-102108-QAClient ID:
Sample Tag:01Dilution:
Units:
WG2858236010BJYH1mg/L
Collect Date:10/21/2008 11:05
Prep Method:3005A 10/23/2008 08:48Prep Date:
U Not detected at or above adjusted sample detection limitJ The analyte was positively identified, but the quantitation was below the RL
PQL SDL
NONEPrePrep Method:
35
00096722
-
L08100667
November 3, 2008
Report Number:
Report Date :
12 of
Microbac Laboratories Inc.
23
Calcium, Total Iron, Total
Analyte Qual0.5000.125
1.000.500
4951.67
ResultCAS. Number7440-70-27439-89-6
L08100667-04Sample Number: PE-ICP2Instrument:
P2.102908.140934File ID:10/29/2008Run Date:Analyst:10/29/2008 09:26Cal Date:
14:09Workgroup Number:Matrix: Analytical Method:Water
MW116-102108-QAClient ID:
Sample Tag:DL02Dilution:
Units:
WG2858236010BJYH5mg/L
Collect Date:10/21/2008 11:05
Prep Method:3005A 10/23/2008 08:48Prep Date:
PQL SDL
NONEPrePrep Method:
36
00096723
-
L08100667
November 3, 2008
Report Number:
Report Date :
13 of
Microbac Laboratories Inc.
23
Calcium, Total Iron, Total
Analyte Qual0.2000.0500
0.4000.200
80.10.665
ResultCAS. Number7440-70-27439-89-6
L08100667-05Sample Number: PE-ICP2Instrument:
P2.102908.141552File ID:10/29/2008Run Date:Analyst:10/29/2008 09:26Cal Date:
14:15Workgroup Number:Matrix: Analytical Method:Water
29WW10-102108Client ID:
Sample Tag:DL03Dilution:
Units:
WG2858236010BJYH2mg/L
Collect Date:10/21/2008 10:00
Prep Method:3005A 10/23/2008 08:48Prep Date:
PQL SDL
NONEPrePrep Method:
37
00096724
-
L08100667
November 3, 2008
Report Number:
Report Date :
14 of
Microbac Laboratories Inc.
23
Aluminum, Total Beryllium, Total Cobalt, Total Magnesium, Total Potassium, Total Zinc, Total
AnalyteUUJ
JJ
Qual0.0500
0.0005000.002500.2500.250
0.00500
0.1000.002000.005000.5001.00
0.0200
0.0049462.20.5340.0151
ResultCAS. Number7429-90-57440-41-77440-48-47439-95-47440-09-77440-66-6
L08100667-05Sample Number: PE-ICP2Instrument:
P2.102508.040011File ID:10/25/2008Run Date:Analyst:10/24/2008 14:46Cal Date:
04:00Workgroup Number:Matrix: Analytical Method:Water
29WW10-102108Client ID:
Sample Tag:01Dilution:
Units:
WG2858236010BJYH1mg/L
Collect Date:10/21/2008 10:00
Prep Method:3005A 10/23/2008 08:48Prep Date:
U Not detected at or above adjusted sample detection limitJ The analyte was positively identified, but the quantitation was below the RL
PQL SDL
NONEPrePrep Method:
38
00096725
-
L08100667
November 3, 2008
Report Number:
Report Date :
15 of
Microbac Laboratories Inc.
23
Vanadium, TotalAnalyte
UQual
0.05000.100ResultCAS. Number
7440-62-2
L08100667-05Sample Number: PE-ICP2Instrument:
P2.102808.150941File ID:10/28/2008Run Date:Analyst:10/28/2008 08:34Cal Date:
15:09Workgroup Number:Matrix: Analytical Method:Water
29WW10-102108Client ID:
Sample Tag:DL02Dilution:
Units:
WG2858236010BJYH10mg/L
Collect Date:10/21/2008 10:00
Prep Method:3005A 10/23/2008 08:48Prep Date:
U Not detected at or above adjusted sample detection limit
PQL SDL
NONEPrePrep Method:
39
00096726
-
L08100667
November 3, 2008
Report Number:
Report Date :
16 of
Microbac Laboratories Inc.
23
Sodium, TotalAnalyte Qual
1.252.50206ResultCAS. Number
7440-23-5
L08100667-05Sample Number: PE-ICP2Instrument:
P2.102808.123044File ID:10/28/2008Run Date:Analyst:10/28/2008 08:34Cal Date:
12:30Workgroup Number:Matrix: Analytical Method:Water
29WW10-102108Client ID:
Sample Tag:DL01Dilution:
Units:
WG2858236010BJYH5mg/L
Collect Date:10/21/2008 10:00
Prep Method:3005A 10/23/2008 08:48Prep Date:
PQL SDL
NONEPrePrep Method:
40
00096727
-
L08100667
November 3, 2008
Report Number:
Report Date :
17 of
Microbac Laboratories Inc.
23
Vanadium, TotalAnalyte
UQual
0.02500.0500ResultCAS. Number
7440-62-2
L08100667-06Sample Number: PE-ICP2Instrument:
P2.103108.102354File ID:10/31/2008Run Date:Analyst:10/31/2008 09:37Cal Date:
10:23Workgroup Number:Matrix: Analytical Method:Water
29WW19-102108Client ID:
Sample Tag:DL03Dilution:
Units:
WG2858236010BED5mg/L
Collect Date:10/21/2008 12:20
Prep Method:3005A 10/23/2008 08:48Prep Date:
U Not detected at or above adjusted sample detection limit
PQL SDL
NONEPrePrep Method:
41
00096728
-
L08100667
November 3, 2008
Report Number:
Report Date :
18 of
Microbac Laboratories Inc.
23
Calcium, Total Iron, Total
Analyte Qual0.2000.0500
0.4000.200
3660.561
ResultCAS. Number7440-70-27439-89-6
L08100667-06Sample Number: PE-ICP2Instrument:
P2.102908.142212File ID:10/29/2008Run Date:Analyst:10/29/2008 09:26Cal Date:
14:22Workgroup Number:Matrix: Analytical Method:Water
29WW19-102108Client ID:
Sample Tag:DL02Dilution:
Units:
WG2858236010BJYH2mg/L
Collect Date:10/21/2008 12:20
Prep Method:3005A 10/23/2008 08:48Prep Date:
PQL SDL
NONEPrePrep Method:
42
00096729
-
L08100667
November 3, 2008
Report Number:
Report Date :
19 of
Microbac Laboratories Inc.
23
Sodium, TotalAnalyte Qual
1.252.50218ResultCAS. Number
7440-23-5
L08100667-06Sample Number: PE-ICP2Instrument:
P2.102808.124328File ID:10/28/2008Run Date:Analyst:10/28/2008 08:34Cal Date:
12:43Workgroup Number:Matrix: Analytical Method:Water
29WW19-102108Client ID:
Sample Tag:DL01Dilution:
Units:
WG2858236010BJYH5mg/L
Collect Date:10/21/2008 12:20
Prep Method:3005A 10/23/2008 08:48Prep Date:
PQL SDL
NONEPrePrep Method:
43
00096730
-
L08100667
November 3, 2008
Report Number:
Report Date :
20 of
Microbac Laboratories Inc.
23
Aluminum, Total Beryllium, Total Cobalt, Total Magnesium, Total Potassium, Total Zinc, Total
AnalyteUUU
J
Qual0.0500
0.0005000.002500.2500.250
0.00500
0.1000.002000.005000.5001.00
0.0200
2645.47
0.0180
ResultCAS. Number7429-90-57440-41-77440-48-47439-95-47440-09-77440-66-6
L08100667-06Sample Number: PE-ICP2Instrument:
P2.102508.040630File ID:10/25/2008Run Date:Analyst:10/24/2008 14:46Cal Date:
04:06Workgroup Number:Matrix: Analytical Method:Water
29WW19-102108Client ID:
Sample Tag:01Dilution:
Units:
WG2858236010BJYH1mg/L
Collect Date:10/21/2008 12:20
Prep Method:3005A 10/23/2008 08:48Prep Date:
U Not detected at or above adjusted sample detection limitJ The analyte was positively identified, but the quantitation was below the RL
PQL SDL
NONEPrePrep Method:
44
00096731
-
L08100667
November 3, 2008
Report Number:
Report Date :
21 of
Microbac Laboratories Inc.
23
Aluminum, Total Beryllium, Total Cobalt, Total Magnesium, Total Potassium, Total Zinc, Total
AnalyteUU
Qual0.0500
0.0005000.002500.2500.250
0.00500
0.1000.002000.005000.5001.00
0.0200
0.05721594.26
0.0311
ResultCAS. Number7429-90-57440-41-77440-48-47439-95-47440-09-77440-66-6
L08100667-07Sample Number: PE-ICP2Instrument:
P2.102508.041302File ID:10/25/2008Run Date:Analyst:10/24/2008 14:46Cal Date:
04:13Workgroup Number:Matrix: Analytical Method:Water
29WW25-102108Client ID:
Sample Tag:01Dilution:
Units:
WG2858236010BJYH1mg/L
Collect Date:10/21/2008 15:00
Prep Method:3005A 10/23/2008 08:48Prep Date:
U Not detected at or above adjusted sample detection limit
PQL SDL
NONEPrePrep Method:
45
00096732
-
L08100667
November 3, 2008
Report Number:
Report Date :
22 of
Microbac Laboratories Inc.
23
Calcium, Total Iron, Total Vanadium, Total
Analyte
U
Qual0.5000.1250.0250
1.000.5000.0500
25717.3
ResultCAS. Number7440-70-27439-89-67440-62-2
L08100667-07Sample Number: PE-ICP2Instrument:
P2.102908.144117File ID:10/29/2008Run Date:Analyst:10/29/2008 09:26Cal Date:
14:41Workgroup Number:Matrix: Analytical Method:Water
29WW25-102108Client ID:
Sample Tag:DL02Dilution:
Units:
WG2858236010BJYH5mg/L
Collect Date:10/21/2008 15:00
Prep Method:3005A 10/23/2008 08:48Prep Date:
U Not detected at or above adjusted sample detection limit
PQL SDL
NONEPrePrep Method:
46
00096733
-
L08100667
November 3, 2008
Report Number:
Report Date :
23 of
Microbac Laboratories Inc.
23
Sodium, TotalAnalyte Qual
1.252.50210ResultCAS. Number
7440-23-5
L08100667-07Sample Number: PE-ICP2Instrument:
P2.102808.124953File ID:10/28/2008Run Date:Analyst:10/28/2008 08:34Cal Date:
12:49Workgroup Number:Matrix: Analytical Method:Water
29WW25-102108Client ID:
Sample Tag:DL01Dilution:
Units:
WG2858236010BJYH5mg/L
Collect Date:10/21/2008 15:00
Prep Method:3005A 10/23/2008 08:48Prep Date:
PQL SDL
NONEPrePrep Method:
47
00096734
-
2.1.1.2 QC Summary Data
48
00096735
-
Example 6010 CalculationsPerkin Elmer Optima 4300 DV
1.0 Initial Calibration (ICAL) ParametersThe system performs linear regression from data consisting of a blank and three standards.
2.0 Calculating the concentration (C) of an element in water using data from prep log, run log, andquantitation report (note:the data system performs this calculation automatically when correction factorshave been entered):
Cx = Cs× V fV i
×D
Where: Example:Cs = Concentration computed by the data system in ug/mL (ppm) 0.1V f = Final volume (mL) 50V i = Initial volume (mL) 50D = Dilution factor as a multiplier (10X = 10) 1
Cx = Concentration of element in ug/mL (mg/L) 0.1
3.0 Calculating the concentration (C) of an element in soil using data from prep log, run log, and quantitationreport (note: the data system performs this calculation automatically when correction factors have beenentered):
Cx = Cs× V fV i
×D
Where: Example:Cs = Concentration computed by the data system (mg/L) (ppm) 0.1V f = Final volume (mL) 50V i = Initial weight (g) 1D = Dilution factor as a multiplier (10X = 10) 1
Cx = Concentration of element in ug/g (mg/kg) 5
4.0 Adjusting the concentration to dry weight:
Cdry =Cx× 100
Px
Where: Example:Cx = Concentration calculated as received (wet basis) 5Px = Percent solids of sample (%wt) 80
Cdry = Concentration calculated as dry weight (mg/kg) 6.25
49
00096736
-
Example 6010 CalculationsThermo Scientific IRIS Advantage
1.0 Initial Calibration (ICAL) ParametersThe system performs linear regression from data consisting of a blank and three standards.
2.0 Calculating the concentration (C) of an element in water using data from prep log, run log, andquantitation report (note:the data system performs this calculation automatically when correction factorshave been entered):
Cx = Cs× V fV i
×D
Where: Example:Cs = Concentration computed by the data system in ug/mL (ppm) 0.1V f = Final volume (mL) 50V i = Initial volume (mL) 50D = Dilution factor as a multiplier (10X = 10) 1
Cx = Concentration of element in ug/mL (mg/L) 0.1
3.0 Calculating the concentration (C) of an element in soil using data from prep log, run log, and quantitationreport (note: the data system performs this calculation automatically when correction factors have beenentered):
Cx = Cs× V fV i
×D
Where: Example:Cs = Concentration computed by the data system (mg/L) (ppm) 0.1V f = Final volume (mL) 50V i = Initial weight (g) 1D = Dilution factor as a multiplier (10X = 10) 1
Cx = Concentration of element in ug/g (mg/kg) 5
4.0 Adjusting the concentration to dry weight:
Cdry =Cx× 100
Px
Where: Example:Cx = Concentration calculated as received (wet basis) 5Px = Percent solids of sample (%wt) 80
Cdry = Concentration calculated as dry weight (mg/kg) 6.25
50
00096737
-
Example 6010 CalculationsThermo Scientific iCAP 6500
1.0 Initial Calibration (ICAL) ParametersThe system performs linear regression from data consisting of a blank and four standards.
2.0 Calculating the concentration (C) of an element in water using data from prep log, run log, andquantitation report (note:the data system performs this calculation automatically when correction factorshave been entered):
Cx = Cs× V fV i
×D
Where: Example:Cs = Concentration computed by the data system in ug/mL (ppm) 0.1V f = Final volume (mL) 50V i = Initial volume (mL) 50D = Dilution factor as a multiplier (10X = 10) 1
Cx = Concentration of element in ug/mL (mg/L) 0.1
3.0 Calculating the concentration (C) of an element in soil using data from prep log, run log, and quantitationreport (note: the data system performs this calculation automatically when correction factors have beenentered):
Cx = Cs× V fV i
×D
Where: Example:Cs = Concentration computed by the data system (mg/L) (ppm) 0.1V f = Final volume (mL) 50V i = Initial weight (g) 1D = Dilution factor as a multiplier (10X = 10) 1
Cx = Concentration of element in ug/g (mg/kg) 5
4.0 Adjusting the concentration to dry weight:
Cdry =Cx× 100
Px
Where: Example:Cx = Concentration calculated as received (wet basis) 5Px = Percent solids of sample (%wt) 80
Cdry = Concentration calculated as dry weight (mg/kg) 6.25
51
00096738
-
Metals Digest Log
BLOCK_DIG - Modified 07/22/2008 PDF ID:Report generated: 10/23/2008 11:02
Microbac Laboratories Inc.
1230326
Reviewer:Analyst:
WG285777-02
WG285777-03
L08100621-01
L08100621-02
L08100621-03
L08100632-01
WG285777-01
L08100633-01
WG285777-04
L08100633-02
WG285777-05
L08100633-03
L08100633-04
L08100633-05
L08100633-06
L08100641-03
L08100641-04
L08100667-01
L08100667-02
L08100667-03
L08100667-04
L08100667-05
L08100667-06
L08100667-07
SAMPLE #
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
Initial Amount
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
50 mL
Final Volume Due Date
10/31/08
10/31/08
10/31/08
10/31/08
11/05/08
11/05/08
11/05/08
11/05/08
11/05/08
11/05/08
10/29/08
10/29/08
10/31/08
10/31/08
10/31/08
10/31/08
10/31/08
10/31/08
10/31/08
Type
BLANK
LCS
SAMP
SAMP
SAMP
SAMP
REF
RS01
MS
MS01
MSD
SD01
SAMP
SAMP
SAMP
SAMP
SAMP
SAMP
SAMP
SAMP
SAMP
SAMP
SAMP
SAMP
WG285777
Method:3005A
Analyst:REK
Workgroup:
Run Date:10/23/2008 08:48
ME401 Revison 13SOP:
Spike Solution:
Spike Witness:
STD27613
SDL
COA13347
COA13324
COA13407
HNO3 Lot #:
hcl Lot #:
Digest tubes Lot #:
95 @ 06:45
95 @ 10:45
Hotblock Start Temp:Hotblock End Temp:
Matrix
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
Spike Amount
5 mL
5 mL
5 mL
5 mL
5 mL
52
00096739
-
Instrument Run Log
Run Log ID: 24892
Page: 1 Approved: October 28, 2008
Microbac Laboratories Inc.
Instrument:
Analyst1:
Method:
Dataset:
Analyst2:
SOP: Rev:
PE-ICP2
ED
6010B
102408H3R.CSV
N/A
ME600E 8
Calibration Std:
ICSA:
ICV/CCV Std:
ICSAB:
Post Spike:
Workgroups:
STD29127
STD29188
STD29410
STD29411
STD27612
285957,285645,285632,285641,285823,285136
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
P2.102408.142122
P2.102408.142737
P2.102408.143351
P2.102408.144008
P2.102408.144624
P2.102408.145157
P2.102408.145815
P2.102408.150432
P2.102408.150952
P2.102408.151514
P2.102408.152134
P2.102408.153243
P2.102408.153856
P2.102408.154516
P2.102408.155141
P2.102408.155759
P2.102408.160424
P2.102408.161045
P2.102408.161710
P2.102408.162328
P2.102408.162955
P2.102408.163620
P2.102408.164240
P2.102408.164858
P2.102408.165516
P2.102408.170138
P2.102408.170702
P2.102408.171323
P2.102408.171937
P2.102408.172555
P2.102408.173216
P2.102408.173830
P2.102408.174449
P2.102408.175014
P2.102408.175632
P2.102408.180249
P2.102408.180913
WG286114-01
WG286114-02
WG286114-03
WG286114-04
WG286114-05
WG286114-06
WG286114-07
WG286114-08
WG286114-09
WG286114-10
WG286114-11
WG285892-02
WG285892-03
L08100661-04
WG285892-01
WG285957-01
WG285957-02
WG285892-04
WG285892-05
L08100696-04
L08100696-06
WG286114-12
WG286114-13
L08100697-01
WG285422-01
WG285645-01
WG285645-02
WG285422-04
WG285422-05
L08100521-09
L08100521-10
L08100542-01
L08100534-01
WG286114-14
WG286114-15
L08100534-01
L08100534-02
Calibration Point
Calibration Point
Calibration Point
Calibration Point
Calibration Point
Initial Calibration Verification
Initial Calib Blank
Interference Check
Interference Check
CCV
CCB
Method/Prep Blank
Laboratory Control S
EFFLUENT
Reference Sample
Post Digestion Spike
Serial Dilution
Matrix Spike
Matrix Spike Duplica
OUTFALL 003/COMP
OUTFALL 800/COMP
CCV
CCB
OUTFALL 002/COMP
Reference Sample
Post Digestion Spike
Serial Dilution
Matrix Spike
Matrix Spike Duplica
SPE-G-MW-3-DUP
SPE-G-MW-3-DIS-DUP
001
PZ03-101608
CCV
CCB
PZ03-101608
PZ01-101608
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
5
1
1
1
1
1
1
1
200
200
1000
200
200
200
200
1
5
1
1
100
2
L08100683-01
L08100683-01
L08100683-01
L08100683-01
L08100683-01
L08100521-01
L08100521-01
L08100521-01
L08100521-01
L08100521-01
10/24/08 14:21
10/24/08 14:27
10/24/08 14:33
10/24/08 14:40
10/24/08 14:46
10/24/08 14:51
10/24/08 14:58
10/24/08 15:04
10/24/08 15:09
10/24/08 15:15
10/24/08 15:21
10/24/08 15:32
10/24/08 15:38
10/24/08 15:45
10/24/08 15:51
10/24/08 15:57
10/24/08 16:04
10/24/08 16:10
10/24/08 16:17
10/24/08 16:23
10/24/08 16:29
10/24/08 16:36
10/24/08 16:42
10/24/08 16:48
10/24/08 16:55
10/24/08 17:01
10/24/08 17:07
10/24/08 17:13
10/24/08 17:19
10/24/08 17:25
10/24/08 17:32
10/24/08 17:38
10/24/08 17:44
10/24/08 17:50
10/24/08 17:56
10/24/08 18:02
10/24/08 18:09
Seq. File ID Sample ID Prep Dil Reference Date/Time
Comments:
Maintenance Log ID: 286114
53
00096740
-
Instrument Run Log
Run Log ID: 24892
Page: 2 Approved: October 28, 2008
Microbac Laboratories Inc.
Instrument:
Analyst1:
Method:
Dataset:
Analyst2:
SOP: Rev:
PE-ICP2
ED
6010B
102408H3R.CSV
N/A
ME600E 8
Calibration Std:
ICSA:
ICV/CCV Std:
ICSAB:
Post Spike:
Workgroups:
STD29127
STD29188
STD29410
STD29411
STD27612
285957,285645,285632,285641,285823,285136
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
P2.102408.181431
P2.102408.182048
P2.102408.182713
P2.102408.183329
P2.102408.183952
P2.102408.184622
P2.102408.185239
P2.102408.185804
P2.102408.190425
P2.102408.191038
P2.102408.191702
P2.102408.192327
P2.102408.192941
P2.102408.193558
P2.102408.194220
P2.102408.194834
P2.102408.195454
P2.102408.200117
P2.102408.200731
P2.102408.201354
P2.102408.202015
P2.102408.202533
P2.102408.203201
P2.102408.203817
P2.102408.204430
P2.102408.205050
P2.102408.205710
P2.102408.210324
P2.102408.210905
P2.102408.211437
P2.102408.211955
P2.102408.212524
P2.102408.213050
P2.102408.213608
P2.102408.214237
P2.102408.214853
P2.102408.215510
L08100534-03
L08100534-04
L08100534-05
L08100534-06
L08100534-08
L08100534-10
L08100544-01
L08100544-01
WG285522-03
WG286114-16
WG286114-17
WG285522-04
WG285522-01
WG285632-01
WG285632-02
WG285522-05
WG285522-06
L08100533-11
L08100533-14
L08100533-16
L08100533-19
WG286114-18
WG286114-19
L08100533-22
L08100533-25
L08100533-27
L08100533-30
L08100547-01
L08100547-02
WG285522-02
WG285522-07
WG285522-08
L08100547-06
WG286114-20
WG286114-21
L08100547-07
L08100547-08
MW10-101608
MW03-101608
MW19-101608
MW05S-101508
BLDG4PITSSP-101608
PZ01-101608
6278
6278
Method/Prep Blank
CCV
CCB
Laboratory Control S
Reference Sample
Post Digestion Spike
Serial Dilution
Matrix Spike
Matrix Spike Duplica
MW2D-230-14
MW4A-230-14
MW4C-230-14
MW4C2-230-14
CCV
CCB
MW5A-230-14
OW1A-230-14
OW2A-230-14
OW3A-230-14
MW01S-GW-101408
MW01S-GW-101408D
Reference Sample
Matrix Spike
Matrix Spike Duplica
MW04D-GW-101508
CCV
CCB
MW06D-GW-101508
MW07D-GW-101608
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
5
5
1
5
5
5
1
10
1
1
1
1
1
1
5
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
L08100533-02
L08100533-02
L08100533-02
L08100533-02
L08100533-02
L08100547-03
L08100547-03
L08100547-03
10/24/08 18:14
10/24/08 18:20
10/24/08 18:27
10/24/08 18:33
10/24/08 18:39
10/24/08 18:46
10/24/08 18:52
10/24/08 18:58
10/24/08 19:04
10/24/08 19:10
10/24/08 19:17
10/24/08 19:23
10/24/08 19:29
10/24/08 19:35
10/24/08 19:42
10/24/08 19:48
10/24/08 19:54
10/24/08 20:01
10/24/08 20:07
10/24/08 20:13
10/24/08 20:20
10/24/08 20:25
10/24/08 20:32
10/24/08 20:38
10/24/08 20:44
10/24/08 20:50
10/24/08 20:57
10/24/08 21:03
10/24/08 21:09
10/24/08 21:14
10/24/08 21:19
10/24/08 21:25
10/24/08 21:30
10/24/08 21:36
10/24/08 21:42
10/24/08 21:48
10/24/08 21:55
Seq. File ID Sample ID Prep Dil Reference Date/Time
Comments:
Maintenance Log ID: 286114
54
00096741
-
Instrument Run Log
Run Log ID: 24892
Page: 3 Approved: October 28, 2008
Microbac Laboratories Inc.
Instrument:
Analyst1:
Method:
Dataset:
Analyst2:
SOP: Rev:
PE-ICP2
ED
6010B
102408H3R.CSV
N/A
ME600E 8
Calibration Std:
ICSA:
ICV/CCV Std:
ICSAB:
Post Spike:
Workgroups:
STD29127
STD29188
STD29410
STD29411
STD27612
285957,285645,285632,285641,285823,285136
75
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
98
99
100
101
102
103
104
105
106
107
108
109
110
111
P2.102408.220035
P2.102408.220600
P2.102408.221118
P2.102408.221647
P2.102408.222306
P2.102408.222921
P2.102408.223446
P2.102408.224107
P2.102408.224722
P2.102408.225345
P2.102408.230005
P2.102408.230627
P2.102408.231242
P2.102408.231902
P2.102408.232523
P2.102408.233042
P2.102408.233700
P2.102408.234324
P2.102408.234940
P2.102408.235604
P2.102508.000226
P2.102508.000842
P2.102508.001506
P2.102508.002128
P2.102508.002744
P2.102508.003309
P2.102508.003934
P2.102508.004556
P2.102508.005211
P2.102508.005832
P2.102508.010454
P2.102508.011013
P2.102508.011538
P2.102508.012200
P2.102508.012814
P2.102508.013435
P2.102508.014057
L08100547-09
L08100547-10
L08100547-11
WG285526-03
WG285526-04
L08100572-01
WG285526-01
WG285641-01
WG286114-22
WG286114-23
WG285641-02
L08100572-03
L08100572-04
L08100572-05
L08100572-06
L08100572-07
WG285526-05
WG285526-06
WG285526-02
WG285526-07
WG286114-24
WG286114-25
WG285526-08
L08100573-16
L08100575-01
L08100575-02
L08100575-03
L08100575-04
L08100575-05
L08100575-06
L08100575-07
L08100575-08
WG286114-26
WG286114-27
WG285777-02
WG285777-03
L08100621-01
MW07S-GW-101608
MW03D-GW-101608
MW02S-GW-101608
Method/Prep Blank
Laboratory Control S
MW-2A
Reference Sample
Post Digestion Spike
CCV
CCB
Serial Dilution
MW-2C
MW-8A
MW-8B
MW-7A
MW-7B
Matrix Spike
Matrix Spike Duplica
Reference Sample
Matrix Spike
CCV
CCB
Matrix Spike Duplica
MAIN DISCHARGE-IS-5-DUP
MW02D-GW-101708
MW03S-GW-101708
0051-SW-101808
0052-SW-101808
0053-SW-101808
0054-SW-101808
0055-SW-101808
0056-SW-101808
CCV
CCB
Method/Prep Blank
Laboratory Control S
6282
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
1
1
1
1
1
1
1
1
1
1
5
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
L08100572-02
L08100572-02
L08100572-02
WG285931-04
L08100572-02
L08100572-02
L08100573-13
L08100573-13
L08100573-13
WG285634-01
10/24/08 22:00
10/24/08 22:06
10/24/08 22:11
10/24/08 22:16
10/24/08 22:23
10/24/08 22:29
10/24/08 22:34
10/24/08 22:41
10/24/08 22:47
10/24/08 22:53
10/24/08 23:00
10/24/08 23:06
10/24/08 23:12
10/24/08 23:19
10/24/08 23:25
10/24/08 23:30
10/24/08 23:37
10/24/08 23:43
10/24/08 23:49
10/24/08 23:56
10/25/08 00:02
10/25/08 00:08
10/25/08 00:15
10/25/08 00:21
10/25/08 00:27
10/25/08 00:33
10/25/08 00:39
10/25/08 00:45
10/25/08 00:52
10/25/08 00:58
10/25/08 01:04
10/25/08 01:10
10/25/08 01:15
10/25/08 01:22
10/25/08 01:28
10/25/08 01:34
10/25/08 01:40
Seq. File ID Sample ID Prep Dil Reference Date/Time
Comments:
Maintenance Log ID: 286114
55
00096742
-
Instrument Run Log
Run Log ID: 24892
Page: 4 Approved: October 28, 2008
Microbac Laboratories Inc.
Instrument:
Analyst1:
Method:
Dataset:
Analyst2:
SOP: Rev:
PE-ICP2
ED
6010B
102408H3R.CSV
N/A
ME600E 8
Calibration Std:
ICSA:
ICV/CCV Std:
ICSAB:
Post Spike:
Workgroups:
STD29127
STD29188
STD29410
STD29411
STD27612
285957,285645,285632,285641,285823,285136
112
113
114
115
116
117
118
119
120
121
122
123
124
125
126
127
128
129
130
131
132
133
134
135
136
137
138
139
140
141
142
143
144
145
146
147
148
P2.102508.014717
P2.102508.015339
P2.102508.020005
P2.102508.020625
P2.102508.021251
P2.102508.021914
P2.102508.022529
P2.102508.023153
P2.102508.023815
P2.102508.024436
P2.102508.025054
P2.102508.025721
P2.102508.030343
P2.102508.030958
P2.102508.031528
P2.102508.032154
P2.102508.032814
P2.102508.033440
P2.102508.034106
P2.102508.034725
P2.102508.035350
P2.102508.040011
P2.102508.040630
P2.102508.041302
P2.102508.041831
P2.102508.042447
P2.102508.043111
P2.102508.043640
P2.102508.044305
P2.102508.044827
P2.102508.045453
P2.102508.050115
P2.102508.050731
P2.102508.051351
P2.102508.051913
P2.102508.052433
P2.102508.052954
L08100621-02
L08100621-03
L08100632-01
WG285777-01
WG285823-01
WG285823-02
WG285777-04
WG286114-28
WG286114-29
WG285777-05
L08100633-04
L08100633-05
L08100633-06
L08100641-03
L08100641-04
L08100667-01
L08100667-02
L08100667-03
L08100667-04
WG286114-30
WG286114-31
L08100667-05
L08100667-06
L08100667-07
L08100440-01
L08100440-02
L08100440-09
L08100440-13
L08100440-14
L08100440-16
L08100440-17
WG286114-32
WG286114-33
WG286114-34
WG286114-35
WG286114-36
WG286114-37
6279
6280
6518
Reference Sample
Post Digestion Spike
Serial Dilution
Matrix Spike
CCV
CCB
Matrix Spike Duplica
C-23-MWDM003 (102108)
EB001 (102108)
FB002 (102108)
LH18/24-SP140-7116-GRAB
LH18/24-SP140-7116-GRAB
MW118-102008
MW114-102008
MW116-102108
MW116-102108-QA
CCV
CCB
29WW10-102108
29WW19-102108
29WW25-102108
CRP 3051
CRP 3043
CRP 3046
CRP 3045
CRP 3044
CRP 3048
CRP 3041
CCV
CCB
Interference Check
Interference Check
CCV
CCB
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
1
1
1
1
1
5
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
100
5
5
10
5
5
100
1
1
1
1
1
1
WG285782-01
L08100633-01
L08100633-01
L08100633-01
L08100633-01
L08100633-01
10/25/08 01:47
10/25/08 01:53
10/25/08 02:00
10/25/08 02:06
10/25/08 02:12
10/25/08 02:19
10/25/08 02:25
10/25/08 02:31
10/25/08 02:38
10/25/08 02:44
10/25/08 02:50
10/25/08 02:57
10/25/08 03:03
10/25/08 03:09
10/25/08 03:15
10/25/08 03:21
10/25/08 03:28
10/25/08 03:34
10/25/08 03:41
10/25/08 03:47
10/25/08 03:53
10/25/08 04:00
10/25/08 04:06
10/25/08 04:13
10/25/08 04:18
10/25/08 04:24
10/25/08 04:31
10/25/08 04:36
10/25/08 04:43
10/25/08 04:48
10/25/08 04:54
10/25/08 05:01
10/25/08 05:07
10/25/08 05:13
10/25/08 05:19
10/25/08 05:24
10/25/08 05:29
Seq. File ID Sample ID Prep Dil Reference Date/Time
Comments:
Maintenance Log ID: 286114
56
00096743
-
Instrument Run Log
Run Log ID: 24931
Page: 1 Approved: October 30, 2008
Microbac Laboratories Inc.
Instrument:
Analyst1:
Method:
Dataset:
Analyst2:
SOP: Rev:
PE-ICP2
JYH
6010B
102808HR3.CSV
ED
ME600E 8
Calibration Std:
ICSA:
ICV/CCV Std:
ICSAB:
Post Spike:
Workgroups:
STD29127
STD29188
STD29409
STD29411
STD27612
285632,285641,285645,285628,285823,285957,286235,285127
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
P2.102808.080954
P2.102808.081608
P2.102808.082223
P2.102808.082838
P2.102808.083454
P2.102808.084020
P2.102808.084639
P2.102808.085255
P2.102808.085814
P2.102808.090335
P2.102808.090953
P2.102808.092411
P2.102808.092929
P2.102808.093758
P2.102808.094316
P2.102808.094840
P2.102808.095407
P2.102808.100024
P2.102808.101749
P2.102808.102406
P2.102808.103027
P2.102808.103648
P2.102808.105543
P2.102808.110202
P2.102808.110818
P2.102808.111437
P2.102808.112049
P2.102808.112713
P2.102808.113337
P2.102808.113954
P2.102808.114616
P2.102808.115241
P2.102808.115859
P2.102808.120520
P2.102808.121144
P2.102808.121805
P2.102808.122422
WG286259-01
WG286259-02
WG286259-03
WG286259-04
WG286259-05
WG286259-06
WG286259-07
WG286259-08
WG286259-09
WG286259-10
WG286259-11
L08100547-06
L08100575-01
L08100547-06
WG286259-12
WG286259-13
WG286259-14
WG286259-15
L08100534-10
L08100534-10
WG286259-16
WG286259-17
WG286259-18
WG286259-19
L08100573-15
L08100573-16
L08100621-02
L08100621-03
L08100641-04
L08100667-01
L08100667-01
L08100667-02
L08100667-03
L08100667-04
WG286259-20
WG286259-21
L08100667-05
Calibration Point
Calibration Point
Calibration Point
Calibration Point
Calibration Point
Initial Calibration Verification
Initial Calib Blank
Interference Check
Interference Check
CCV
CCB
MW04D-GW-101508
MW02D-GW-101708
MW04D-GW-101508
Interference Check
Interference Check
CCV
CCB
PZ01-101608
PZ01-101608
CCV
CCB
CCV
CCB
MAIN DISCHARGE-IS-5-MSD
MAIN DISCHARGE-IS-5-DUP
6279
6280
LH18/24-SP140-7116-GRAB
MW118-102008
MW118-102008
MW114-102008
MW116-102108
MW116-102108-QA
CCV
CCB
29WW10-102108
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
1
1
1
1
1
1
1
1
1
1
1
2
5
5
1
1
1
1
10
25
1
1
1
1
1
1
5
5
5
1
5
5
1
5
1
1
1
WG285526-08
10/28/08 08:09
10/28/08 08:16
10/28/08 08:22
10/28/08 08:28
10/28/08 08:34
10/28/08 08:40
10/28/08 08:46
10/28/08 08:52
10/28/08 08:58
10/28/08 09:03
10/28/08 09:09
10/28/08 09:24
10/28/08 09:29
10/28/08 09:37
10/28/08 09:43
10/28/08 09:48
10/28/08 09:54
10/28/08 10:00
10/28/08 10:17
10/28/08 10:24
10/28/08 10:30
10/28/08 10:36
10/28/08 10:55
10/28/08 11:02
10/28/08 11:08
10/28/08 11:14
10/28/08 11:20
10/28/08 11:27
10/28/08 11:33
10/28/08 11:39
10/28/08 11:46
10/28/08 11:52
10/28/08 11:58
10/28/08 12:05
10/28/08 12:11
10/28/08 12:18
10/28/08 12:24
Seq. File ID Sample ID Prep Dil Reference Date/Time
285955,286255,285817Comments:
Maintenance Log ID: 26352
57
00096744
-
Instrument Run Log
Run Log ID: 24931
Page: 2 Approved: October 30, 2008
Microbac Laboratories Inc.
Instrument:
Analyst1:
Method:
Dataset:
Analyst2:
SOP: Rev:
PE-ICP2
JYH
6010B
102808HR3.CSV
ED
ME600E 8
Calibration Std:
ICSA:
ICV/CCV Std:
ICSAB:
Post Spike:
Workgroups:
STD29127
STD29188
STD29409
STD29411
STD27612
285632,285641,285645,285628,285823,285957,286235,285127
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
P2.102808.123044
P2.102808.123701
P2.102808.124328
P2.102808.124953
P2.102808.125607
P2.102808.130234
P2.102808.130853
P2.102808.133447
P2.102808.134113
P2.102808.134729
P2.102808.135347
P2.102808.140002
P2.102808.140624
P2.102808.141248
P2.102808.141901
P2.102808.142525
P2.102808.143143
P2.102808.143756
P2.102808.144410
P2.102808.145021
P2.102808.145652
P2.102808.150317
P2.102808.150941
P2.102808.151553
P2.102808.152701
P2.102808.153322
P2.102808.153944
P2.102808.154609
P2.102808.155221
P2.102808.155841
P2.102808.160502
P2.102808.161115
P2.102808.161741
P2.102808.162403
P2.102808.163019
P2.102808.163638
P2.102808.164256
L08100667-05
L08100667-06
L08100667-06
L08100667-07
L08100696-04
WG286259-22
WG286259-23
WG286259-24
WG286259-25
WG285513-02
WG285513-03
WG285513-01
WG285628-01
WG285628-02
WG285513-04
WG285513-05
L08100580-16
WG286259-26
WG286259-27
L08100641-04
L08100667-01
L08100667-02
L08100667-05
L08100667-06
WG285522-03
WG286259-28
WG286259-29
L08100667-07
L08100696-04
L08100521-33
L08100521-34
L08100521-36
WG286259-30
WG286259-31
L08100521-37
L08100521-38
L08100521-39
29WW10-102108
29WW19-102108
29WW19-102108
29WW25-102108
OUTFALL 003/COMP
CCV
CCB
CCV
CCB
Method/Prep Blank
Laboratory Control S
Reference Sample
Post Digestion Spike
Serial Dilution
Matrix Spike
Matrix Spike Duplica
EBGS.1015
CCV
CCB
LH18/24-SP140-7116-GRAB
MW118-102008
MW114-102008
29WW10-102108
29WW19-102108
Method/Prep Blank
CCV
CCB
29WW25-102108
OUTFALL 003/COMP
SPE-G-MW-58
SPE-G-MW-58-DIS
SPE-G-MW-60-DIS
CCV
CCB
SPE-K-FB-1
SPE-K-FB-2
SPE-K-FB-2-DIS
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
5
1
5
5
10
1
1
1
1
1
1
10
10
50
10
10
1
1
1
10
10
10
10
10
1
1
1
10
20
10
10
10
1
1
10
10
10
L08100521-35
L08100521-35
L08100521-35
L08100521-35
L08100521-35
10/28/08 12:30
10/28/08 12:37
10/28/08 12:43
10/28/08 12:49
10/28/08 12:56
10/28/08 13:02
10/28/08 13:08
10/28/08 13:34
10/28/08 13:41
10/28/08 13:47
10/28/08 13:53
10/28/08 14:00
10/28/08 14:06
10/28/08 14:12
10/28/08 14:19
10/28/08 14:25
10/28/08 14:31
10/28/08 14:37
10/28/08 14:44
10/28/08 14:50
10/28/08 14:56
10/28/08 15:03
10/28/08 15:09
10/28/08 15:15
10/28/08 15:27
10/28/08 15:33
10/28/08 15:39
10/28/08 15:46
10/28/08 15:52
10/28/08 15:58
10/28/08 16:05
10/28/08 16:11
10/28/08 16:17
10/28/08 16:24
10/28/08 16:30
10/28/08 16:36
10/28/08 16:42
Seq. File ID Sample ID Prep Dil Reference Date/Time
285955,286255,285817Comments:
Maintenance Log ID: 26352
58
00096745
-
Instrument Run Log
Run Log ID: 24931
Page: 3 Approved: October 30, 2008
Microbac Laboratories Inc.
Instrument:
Analyst1:
Method:
Dataset:
Analyst2:
SOP: Rev:
PE-ICP2
JYH
6010B
102808HR3.CSV
ED
ME600E 8
Calibration Std:
ICSA:
ICV/CCV Std:
ICSAB:
Post Spike:
Workgroups:
STD29127
STD29188
STD29409
STD29411
STD27612
285632,285641,285645,285628,285823,285957,286235,285127
75
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
98
99
100
101
102
103
104
105
106
107
108
109
110
111
P2.102808.164910
P2.102808.165530
P2.102808.170236
P2.102808.170850
P2.102808.171510
P2.102808.172131
P2.102808.172744
P2.102808.173403
P2.102808.174022
P2.102808.174637
P2.102808.175256
P2.102808.175917
P2.102808.180531
P2.102808.181151
P2.102808.181812
P2.102808.182426
P2.102808.183047
P2.102808.183707
P2.102808.184320
P2.102808.184943
P2.102808.185604
P2.102808.190220
P2.102808.190839
P2.102808.191500
P2.102808.192114
P2.102808.192734
P2.102808.193357
P2.102808.194012
P2.102808.194635
P2.102808.195256
P2.102808.195909
P2.102808.200530
P2.102808.201149
P2.102808.201805
P2.102808.202424
P2.102808.203045
P2.102808.203701
L08100560-10
L08100560-35
L08100560-54
L08100561-36
L08100562-06
L08100562-24
L08100577-54
WG286259-32
WG286259-33
L08100578-19
L08100579-01
L08100579-27
L08100579-41
WG286025-02
WG286025-03
L08100677-20
L08100678-14
L08100680-07
L08100680-19
WG286259-34
WG286259-35
WG286025-01
WG286235-01
WG286235-02
WG286025-04
WG286025-05
L08100712-01
L08100724-11
L08100724-31
L08100725-11
L08100729-05
WG286259-36
WG286259-37
L08100738-09
WG285077-02
WG285077-03
L08100439-01
10144-W0002
10556-W0003
10569-W0004
10581-W0005
10586-W0006
10592-W0007
10101-W0002
CCV
CCB
10212-W0003
10231-W0004
10268-W0005
10286-W0006
Method/Prep Blank
Laboratory Control S
865-W0001
901-W0001
905-W0001
962-W0001
CCV
CCB
Reference Sample
Post Digestion Spike
Serial Dilution
Matrix Spike
Matrix Spike Duplica
SE-3037P
2556-W0001
2626-W0002
2509-W0003
2567-W0004
CCV
CCB
2654-W0005
Method/Prep Blank
Laboratory Control S
OW-103
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
50/50
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
5
1
1
1
1
1
1
1
1
1
1
1
1
1
L08100710-01
L08100710-01
L08100710-01