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LONGHORN ARMY AMMUNITION PLANT KARNACK, TEXAS ADMINISTRATIVE RECORD Volume 17 of 19 2010 Bate Stamp Numbers 00096688 – 00097694 Prepared for Department of the Army Longhorn Army Ammunition Plant 1976 – 2010

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  • LONGHORN ARMY AMMUNITION PLANT

    KARNACK, TEXAS

    ADMINISTRATIVE RECORD

    Volume 17 of 19

    2010

    Bate Stamp Numbers 00096688 – 00097694

    Prepared for

    Department of the Army Longhorn Army Ammunition Plant

    1976 – 2010

  • LONGHORN ARMY AMMUNITION PLANT KARNACK, TEXAS

    ADMINISTRATIVE RECORD – CHRONOLOGICAL INDEX

    VOLUME 17 of 19 2010 A. Title: Report – (Continued) Final Feasibility Study, LHAAP-29, Former TNT Production Area, Group 2, Longhorn Army Ammunition Plant, Karnack, Texas, April 2010 Author(s): US Army Corps of Engineers Recipient: USEPA Date: April 30, 2010 Bate Stamp: 00096688 – 00097694

  • Corporate Information:

    Microbac Laboratories, Inc.

    Franklin Corporate Center

    2000 Corporate Drive, Suite 350

    Wexford, PA 15090

    Phone: (724) 934-5030

    FAX: (724) 934-5088

    www.microbac.com

    President & CEO: J. Trevor Boyce

    Federal Tax ID#: 25-1199-642

    DUNS#: 048192892

    Incorporated in the State of PA -- May 1, 1969

    Employees Corporate-Wide: 467

    Facilities Corporate –Wide: 18 Divisions, 28 locations across 15 states

    Phone: 800-373-4071 Fax: 740-373-4835

    Email: [email protected]

    Microbac Laboratories Inc. Ohio Valley Division 158 Starlite Drive

    Marietta, OH 45750

    Please note these administrative changes for our Ohio Valley Division laboratory in Marietta, OH (formerly KEMRON Environmental Services, Inc.) , in particular the address, which is a revised routing of remittances on our invoices. All invoices dated April 1, 2008 or later will reflect this change, and will be highlighted with an attention-getting sticker during our transition. Please adjust your records to ensure proper routing of payments.

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    Quick Facts

    1

    00096688

  • 158 Starlite Drive, Marietta, OH 45750 • T:740-373-4071 • F:740-373-4835 • http://www.microbac.com

    Laboratory Report Number: L08100667

    Please find enclosed the analytical results for the samples you submitted to Microbac Laboratories.

    Review and compilation of your report was completed by Microbac’s Sales and Service Team. If you have questions,comments or require further assistance regarding this report, please contact your team member noted in the reviewedbox bleow at 800-373-4071. Team member e-mail addresses also appear here for your convenience.

    Kathy Albertson Team Chemist/Data Specialist [email protected] Mossburg Team Chemist/Data Specialist [email protected] Long Team Chemist/Data Specialist [email protected] Gregory Client Services Specialist [email protected] Fickiesen Client Services Specialist [email protected] Brown Client Services Specialist [email protected] Parsons Team Assistant [email protected]

    This report was reviewed on November 03, 2008.

    Stephanie Mossburg - Team Chemist/Data Specialist

    I certify that all test results meet all of the requirements of the accrediting authority listed below. All results for soilsamples are reported on a ’dry-weight’ basis unless specified otherwise. Analytical results for water and wastes arereported on a ’as received’ basis unless specified otherwise. A statement of uncertainty for each analysis is availableupon request. This laboratory report shall not be reproduced, except in full, without the written approval of MicrobacLaboratories.

    This report was certified on November 03, 2008.

    David Vandenberg - Managing Director

    State of origin: TexasAccrediting authority: Texas Commission on Environmental Quality ID:T104704252-07-TXQAPP: Microbac (OVD) LQAPThis report contains a total of 266 pages.

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    2

    00096689

  • Microbac REPORT L08100667PREPARED FOR Shaw E I, Inc.WORK ID:

    1.0 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42.1 Metals Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21

    2.1.1 Metals I C P Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 222.1.1.1 Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 232.1.1.2 QC Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48

    2.1.2 Metals ICP-MS Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1532.1.2.1 Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1542.1.2.2 QC Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 167

    2.1.3 Metals CVAA Data (Mercury) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2232.1.3.1 Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2242.1.3.2 QC Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 233

    3.0 Attachments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 259

    3

    00096690

  • 1.0 Introduction

    4

    00096691

  • ID: 84941

    Microbac Laboratories Inc.REPORT NARRATIVE

    Microbac Login No: L08100667

    CHAIN OF CUSTODY: The chain of custody number was 5424.

    SHIPMENT CONDITIONS: The chain of custody forms were received sealed in a cooler. The cooler temperaturewas 1 degrees C.

    SAMPLE MANAGEMENT: All samples received were intact.

    I certify that this data package is in compliance with the terms and conditions agreed to by the client and MicrobacLaboratories Inc., both technically and for completeness, except for the conditions noted above. Release of the datacontained in this hardcopy data package has been authorized by the Laboratory Manager or designated person, asverified by the following signature.

    Approved: 28-OCT-08

    5

    00096692

  • Laboratory Data Package Cover PageThis data Package consists of:

    This signature page, the laboratory review checklists, and the following reportable data:R1 Field chain-of-custody documentation;R2 sample identification cross-reference;R3 Test reports (analytical data sheets) for each enviornmental sample that includes:

    a) Items consistant with NELAC 5.13 or ISO/IEC 17025 Section 5.10b) dilution factors,c) preparation methods,d) Cleanup methods, ande) If required for the project, tentatively identified compounds (TICs)

    R4 Surrogate recovery data including:a) Calculated recovery (%R) for each analyte, andb) The laboratory’s surrogate QC limits.

    R5 Test reports/summary forms for blank samples;R6 Test reports/summary forms FOR laboratory control samples (LCSs) including:

    a) LCS spiking amount,b) Calculated %R for each analyte, andc) The laboratory”s LCS QC limits.

    R7 Test reports for project matrix spike/matrix spike duplicates (MS/MSDs) including:a) Samples associated with the MS/MSD clearly identified,b) MS/MSD spiking amounts,c) Concentration of each MS/MSD analyte measured in the parent and spiked samples,d) Calculated %R and relative percent differences (RPDs), ande) The laboratory’s MS/MSD QC limits

    R8 Laboratory analytical duplicate (if applicable) revocery and precision:a) the amount of analyte measured in the duplicate,b) the calculated RPD, andc) the laboratory’s QC limits for anlytical duplicates.

    R9 List of method quantitation limits (MQLs) for each analyte for each method and matrix;R10 Other problems or anomalies.The exception Report for every ”No” or ”Not Reviewed (NR)” item in laboratory review checklist.

    Release statement: I am responsible for the release of this laboratory data package. This data package has been reviewed by thelaboratory and is complete and technically compliant with the requirements of the methods used, except where noted by the laboratoryin the attached exceptions reports. By my signature below, I affirm to the best of my knowledge, all problems/anomalies, observed bythe laboratory as having the potential to affect the quality of the data, have been identified by the laboratoy in the Laboratory ReviewChecklist, and no information or data have been knowingly withheld that would affect the quality of the data.

    Check, If applicable: [] This laboratory is an in-house laboratory controlled by the person repsonding to rule. The official signing thecover page of the rule-required report (for example, the APAR) in which these data are used is responsible for releasing this datapackage and is by signature affirming the above release statement is trus.

    MAREN M. BEERY Metals Supervisor October 27, 2008

    Name (Printed) Signature Official Title (printed) DATE

    RG-366/TRRP-13 December 2002 A1

    6

    00096693

  • Checklist ID: 33035

    Microbac Laboratories Inc.Laboratory Review Checklist

    Laboratory Name: Microbac Laboratories Inc.Laboratory Log Number: L08100667Project Name: 798-LONGHORNMethod: 6010Prep Batch Number(s): WG285777Reviewer Name: MAREN M. BEERYLRC Date: October 27, 2008

    Description Yes No NA(1) NR(2) ER(3)

    Chain-Of-Custody (C-O-C)Did samples meet the laboratory’s standard conditions of sample acceptability uponreceipt?

    X

    Were all departures from standard conditions described in an exception report? XSample and quality control (QC) identificationAre all field sample ID numbers cross-referenced to the laboratory ID numbers? XAre all laboratory ID numbers cross-referenced to the corresponding QC data? XTest reportsWere all samples prepared and analyzed within holding times? XOther than those results

  • Description Yes No NA(1) NR(2) ER(3)

    Were MS/MSD RPDs within laboratory QC limits? XAnalytical duplicate dataWere appropriate analytical duplicates analyzed for each matrix? XWere analytical duplicates analyzed at the appropriate frequency? XWere RPDs or relative standard deviations within the laboratory QC limits? XMethod quantitation limits (MQLs):Are the MQLs for each method analyte included in the laboratory data package? XDo the MQLs correspond to the concentration of the lowest non-zero calibration standard? XAre unadjusted MQLs included in the laboratory data package? XOther problems/anomaliesAre all known problems/anomalies/special conditions noted in this LRC and ER? XWere all necessary corrective actions performed for the reported data? XWas applicable and available technology used to lower the SQL minimize the matrixinterference affects on the sample results?

    X ER3

    ICALWere response factors and/or relative response factors for each analyte within QC limits? XWere percent RSDs or correlation coefficient criteria met? XWas the number of standards recommended in the method used for all analytes? XWere all points generated between the lowest and highest standard used to calculate thecurve?

    X

    Are ICAL data available for all instruments used? XHas the initial calibration curve been verified using an appropriate second source standard? XInitial and continuing calibration verification (ICV and CCV) and continuingcalibration blank (CCB):Was the CCV analyzed at the method-required frequency? XWere percent differences for each analyte within the method-required QC limits? X ER1Was the ICAL curve verified for each analyte? XWas the absolute value of the analyte concentration in the inorganic CCB

  • Description Yes No NA(1) NR(2) ER(3)

    Standards documentationAre all standards used in the analyses NIST-traceable or obtained from other appropriatesources?

    X

    Compound/analyte identification proceduresAre the procedures for compound/analyte identification documented? XDemonstration of analyst competency (DOC)Was DOC conducted consistent with NELAC Chapter 5C or ISO/IEC 4? XIs documentation of the analyst’s competency up-to-date and on file? XVerification/validation documentation for methods (NELAC Chap 5 or ISO/IEC17025 Section 5)Are all the methods used to generate the data documented, verified, and validated, whereapplicable?

    X

    Laboratory standard operating procedures (SOPs):Are laboratory SOPs current and on file for each method performed? X

    9

    00096696

  • Checklist ID: 33035

    Microbac Laboratories Inc.Laboratory Review Checklist

    Laboratory Name: Microbac Laboratories Inc.Laboratory Log Number: L08100667Project Name: 798-LONGHORNMethod: 6010Prep Batch Number(s): WG285777Reviewer Name: MAREN M. BEERYLRC Date: October 27, 2008

    EXCEPTIONS REPORTER#1 - Due to continuing calibration verification failure for calcium and iron on 25-OCT-2008 at 01:15, all batch QA/QC andclient samples were reanalyzed on a later calibration for calcium and iron.ER2 - Client samples 01 through 07 required dilution analysis in order to obtain results for sodium within the linear range.Client samples 03 and 04 required dilution analysis in order to obtain results for calcium within the linear range. ER3 - Due toresults that were noncompliant on the negative side upon initial analysis, vanadium for client samples 01, 02, 05, 06 and 07 wasreported from dilution analyses.Footnotes:(1) NA = Not applicable to method or project(2) NR = Not reviewed(3) ER# = Exception report number

    10

    00096697

  • Laboratory Data Package Cover PageThis data Package consists of:

    This signature page, the laboratory review checklists, and the following reportable data:R1 Field chain-of-custody documentation;R2 sample identification cross-reference;R3 Test reports (analytical data sheets) for each enviornmental sample that includes:

    a) Items consistant with NELAC 5.13 or ISO/IEC 17025 Section 5.10b) dilution factors,c) preparation methods,d) Cleanup methods, ande) If required for the project, tentatively identified compounds (TICs)

    R4 Surrogate recovery data including:a) Calculated recovery (%R) for each analyte, andb) The laboratory’s surrogate QC limits.

    R5 Test reports/summary forms for blank samples;R6 Test reports/summary forms FOR laboratory control samples (LCSs) including:

    a) LCS spiking amount,b) Calculated %R for each analyte, andc) The laboratory”s LCS QC limits.

    R7 Test reports for project matrix spike/matrix spike duplicates (MS/MSDs) including:a) Samples associated with the MS/MSD clearly identified,b) MS/MSD spiking amounts,c) Concentration of each MS/MSD analyte measured in the parent and spiked samples,d) Calculated %R and relative percent differences (RPDs), ande) The laboratory’s MS/MSD QC limits

    R8 Laboratory analytical duplicate (if applicable) revocery and precision:a) the amount of analyte measured in the duplicate,b) the calculated RPD, andc) the laboratory’s QC limits for anlytical duplicates.

    R9 List of method quantitation limits (MQLs) for each analyte for each method and matrix;R10 Other problems or anomalies.The exception Report for every ”No” or ”Not Reviewed (NR)” item in laboratory review checklist.

    Release statement: I am responsible for the release of this laboratory data package. This data package has been reviewed by thelaboratory and is complete and technically compliant with the requirements of the methods used, except where noted by the laboratoryin the attached exceptions reports. By my signature below, I affirm to the best of my knowledge, all problems/anomalies, observed bythe laboratory as having the potential to affect the quality of the data, have been identified by the laboratoy in the Laboratory ReviewChecklist, and no information or data have been knowingly withheld that would affect the quality of the data.

    Check, If applicable: [] This laboratory is an in-house laboratory controlled by the person repsonding to rule. The official signing thecover page of the rule-required report (for example, the APAR) in which these data are used is responsible for releasing this datapackage and is by signature affirming the above release statement is trus.

    MAREN M. BEERY Metals Supervisor October 31, 2008

    Name (Printed) Signature Official Title (printed) DATE

    RG-366/TRRP-13 December 2002 A1

    11

    00096698

  • Checklist ID: 33198

    Microbac Laboratories Inc.Laboratory Review Checklist

    Laboratory Name: Microbac Laboratories Inc.Laboratory Log Number: L08100667Project Name: 798-LONGHORNMethod: 7471Prep Batch Number(s): WG285904Reviewer Name: MAREN M. BEERYLRC Date: October 31, 2008

    Description Yes No NA(1) NR(2) ER(3)

    Chain-Of-Custody (C-O-C)Did samples meet the laboratory’s standard conditions of sample acceptability uponreceipt?

    X

    Were all departures from standard conditions described in an exception report? XSample and quality control (QC) identificationAre all field sample ID numbers cross-referenced to the laboratory ID numbers? XAre all laboratory ID numbers cross-referenced to the corresponding QC data? XTest reportsWere all samples prepared and analyzed within holding times? XOther than those results

  • Description Yes No NA(1) NR(2) ER(3)

    Were MS/MSD RPDs within laboratory QC limits? XAnalytical duplicate dataWere appropriate analytical duplicates analyzed for each matrix? XWere analytical duplicates analyzed at the appropriate frequency? XWere RPDs or relative standard deviations within the laboratory QC limits? XMethod quantitation limits (MQLs):Are the MQLs for each method analyte included in the laboratory data package? XDo the MQLs correspond to the concentration of the lowest non-zero calibration standard? XAre unadjusted MQLs included in the laboratory data package? XOther problems/anomaliesAre all known problems/anomalies/special conditions noted in this LRC and ER? XWere all necessary corrective actions performed for the reported data? XWas applicable and available technology used to lower the SQL minimize the matrixinterference affects on the sample results?

    X

    ICALWere response factors and/or relative response factors for each analyte within QC limits? XWere percent RSDs or correlation coefficient criteria met? XWas the number of standards recommended in the method used for all analytes? XWere all points generated between the lowest and highest standard used to calculate thecurve?

    X

    Are ICAL data available for all instruments used? XHas the initial calibration curve been verified using an appropriate second source standard? XInitial and continuing calibration verification (ICV and CCV) and continuingcalibration blank (CCB):Was the CCV analyzed at the method-required frequency? XWere percent differences for each analyte within the method-required QC limits? XWas the ICAL curve verified for each analyte? XWas the absolute value of the analyte concentration in the inorganic CCB

  • Description Yes No NA(1) NR(2) ER(3)

    Standards documentationAre all standards used in the analyses NIST-traceable or obtained from other appropriatesources?

    X

    Compound/analyte identification proceduresAre the procedures for compound/analyte identification documented? XDemonstration of analyst competency (DOC)Was DOC conducted consistent with NELAC Chapter 5C or ISO/IEC 4? XIs documentation of the analyst’s competency up-to-date and on file? XVerification/validation documentation for methods (NELAC Chap 5 or ISO/IEC17025 Section 5)Are all the methods used to generate the data documented, verified, and validated, whereapplicable?

    X

    Laboratory standard operating procedures (SOPs):Are laboratory SOPs current and on file for each method performed? X

    14

    00096701

  • Checklist ID: 33198

    Microbac Laboratories Inc.Laboratory Review Checklist

    Laboratory Name: Microbac Laboratories Inc.Laboratory Log Number: L08100667Project Name: 798-LONGHORNMethod: 7471Prep Batch Number(s): WG285904Reviewer Name: MAREN M. BEERYLRC Date: October 31, 2008

    EXCEPTIONS REPORTER# - DescriptionFootnotes:(1) NA = Not applicable to method or project(2) NR = Not reviewed(3) ER# = Exception report number

    15

    00096702

  • Laboratory Data Package Cover PageThis data Package consists of:

    This signature page, the laboratory review checklists, and the following reportable data:R1 Field chain-of-custody documentation;R2 sample identification cross-reference;R3 Test reports (analytical data sheets) for each enviornmental sample that includes:

    a) Items consistant with NELAC 5.13 or ISO/IEC 17025 Section 5.10b) dilution factors,c) preparation methods,d) Cleanup methods, ande) If required for the project, tentatively identified compounds (TICs)

    R4 Surrogate recovery data including:a) Calculated recovery (%R) for each analyte, andb) The laboratory’s surrogate QC limits.

    R5 Test reports/summary forms for blank samples;R6 Test reports/summary forms FOR laboratory control samples (LCSs) including:

    a) LCS spiking amount,b) Calculated %R for each analyte, andc) The laboratory”s LCS QC limits.

    R7 Test reports for project matrix spike/matrix spike duplicates (MS/MSDs) including:a) Samples associated with the MS/MSD clearly identified,b) MS/MSD spiking amounts,c) Concentration of each MS/MSD analyte measured in the parent and spiked samples,d) Calculated %R and relative percent differences (RPDs), ande) The laboratory’s MS/MSD QC limits

    R8 Laboratory analytical duplicate (if applicable) revocery and precision:a) the amount of analyte measured in the duplicate,b) the calculated RPD, andc) the laboratory’s QC limits for anlytical duplicates.

    R9 List of method quantitation limits (MQLs) for each analyte for each method and matrix;R10 Other problems or anomalies.The exception Report for every ”No” or ”Not Reviewed (NR)” item in laboratory review checklist.

    Release statement: I am responsible for the release of this laboratory data package. This data package has been reviewed by thelaboratory and is complete and technically compliant with the requirements of the methods used, except where noted by the laboratoryin the attached exceptions reports. By my signature below, I affirm to the best of my knowledge, all problems/anomalies, observed bythe laboratory as having the potential to affect the quality of the data, have been identified by the laboratoy in the Laboratory ReviewChecklist, and no information or data have been knowingly withheld that would affect the quality of the data.

    Check, If applicable: [] This laboratory is an in-house laboratory controlled by the person repsonding to rule. The official signing thecover page of the rule-required report (for example, the APAR) in which these data are used is responsible for releasing this datapackage and is by signature affirming the above release statement is trus.

    MAREN M. BEERY Metals Supervisor October 27, 2008

    Name (Printed) Signature Official Title (printed) DATE

    RG-366/TRRP-13 December 2002 A1

    16

    00096703

  • Checklist ID: 33046

    Microbac Laboratories Inc.Laboratory Review Checklist

    Laboratory Name: Microbac Laboratories Inc.Laboratory Log Number: L08100667Project Name: 798-LONGHORNMethod: 6020Prep Batch Number(s): WG285801Reviewer Name: MAREN M. BEERYLRC Date: October 27, 2008

    Description Yes No NA(1) NR(2) ER(3)

    Chain-Of-Custody (C-O-C)Did samples meet the laboratory’s standard conditions of sample acceptability uponreceipt?

    X

    Were all departures from standard conditions described in an exception report? XSample and quality control (QC) identificationAre all field sample ID numbers cross-referenced to the laboratory ID numbers? XAre all laboratory ID numbers cross-referenced to the corresponding QC data? XTest reportsWere all samples prepared and analyzed within holding times? XOther than those results

  • Description Yes No NA(1) NR(2) ER(3)

    Were MS/MSD RPDs within laboratory QC limits? XAnalytical duplicate dataWere appropriate analytical duplicates analyzed for each matrix? XWere analytical duplicates analyzed at the appropriate frequency? XWere RPDs or relative standard deviations within the laboratory QC limits? XMethod quantitation limits (MQLs):Are the MQLs for each method analyte included in the laboratory data package? XDo the MQLs correspond to the concentration of the lowest non-zero calibration standard? XAre unadjusted MQLs included in the laboratory data package? XOther problems/anomaliesAre all known problems/anomalies/special conditions noted in this LRC and ER? XWere all necessary corrective actions performed for the reported data? XWas applicable and available technology used to lower the SQL minimize the matrixinterference affects on the sample results?

    X ER3

    ICALWere response factors and/or relative response factors for each analyte within QC limits? XWere percent RSDs or correlation coefficient criteria met? XWas the number of standards recommended in the method used for all analytes? XWere all points generated between the lowest and highest standard used to calculate thecurve?

    X

    Are ICAL data available for all instruments used? XHas the initial calibration curve been verified using an appropriate second source standard? XInitial and continuing calibration verification (ICV and CCV) and continuingcalibration blank (CCB):Was the CCV analyzed at the method-required frequency? XWere percent differences for each analyte within the method-required QC limits? XWas the ICAL curve verified for each analyte? XWas the absolute value of the analyte concentration in the inorganic CCB

  • Description Yes No NA(1) NR(2) ER(3)

    Standards documentationAre all standards used in the analyses NIST-traceable or obtained from other appropriatesources?

    X

    Compound/analyte identification proceduresAre the procedures for compound/analyte identification documented? XDemonstration of analyst competency (DOC)Was DOC conducted consistent with NELAC Chapter 5C or ISO/IEC 4? XIs documentation of the analyst’s competency up-to-date and on file? XVerification/validation documentation for methods (NELAC Chap 5 or ISO/IEC17025 Section 5)Are all the methods used to generate the data documented, verified, and validated, whereapplicable?

    X

    Laboratory standard operating procedures (SOPs):Are laboratory SOPs current and on file for each method performed? X

    19

    00096706

  • Checklist ID: 33046

    Microbac Laboratories Inc.Laboratory Review Checklist

    Laboratory Name: Microbac Laboratories Inc.Laboratory Log Number: L08100667Project Name: 798-LONGHORNMethod: 6020Prep Batch Number(s): WG285801Reviewer Name: MAREN M. BEERYLRC Date: October 27, 2008

    EXCEPTIONS REPORTER#1 - Chromium for client sample 01 was reported from the two fold dilution where the two fold post digestion spike wascompliant.ER2 - Client samples 02 and 06 required dilution analyses in order to obtain results for manganese within the linear range.Client sample 05 required dilution analysis in order to obtain a result for nickel within the linear range.ER3 - Due to the dark color of the digestate, client sample 07 was analyzed at a dilution.Footnotes:(1) NA = Not applicable to method or project(2) NR = Not reviewed(3) ER# = Exception report number

    20

    00096707

  • 2.1 Metals Data

    21

    00096708

  • 2.1.1 Metals I C P Data

    22

    00096709

  • 2.1.1.1 Summary Data

    23

    00096710

  • LABORATORY REPORT

    11/03/08 17:20

    L08100667

    1 OFL1_A_PROD - Modified 03/06/2008

    11/03/2008 17:20Report generated:1240187PDF File ID:

    1

    L08100667-01

    L08100667-01

    L08100667-01

    L08100667-02

    L08100667-02

    L08100667-02

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    L08100667-03

    L08100667-03

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    L08100667-05

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    L08100667-06

    L08100667-07

    L08100667-07

    L08100667-07

    MW118-102008

    MW118-102008

    MW118-102008

    MW114-102008

    MW114-102008

    MW114-102008

    MW116-102108

    MW116-102108

    MW116-102108

    MW116-102108-QA

    MW116-102108-QA

    MW116-102108-QA

    29WW10-102108

    29WW10-102108

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    29WW10-102108

    29WW19-102108

    29WW19-102108

    29WW19-102108

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    29WW25-102108

    29WW25-102108

    29WW25-102108

    Client ID Lab ID Dilution

    5

    1

    1

    5

    1

    5

    1

    5

    5

    5

    1

    5

    2

    1

    10

    5

    5

    2

    5

    1

    1

    5

    5

    Sample Analysis Summary

    Date Received

    22-OCT-08

    22-OCT-08

    22-OCT-08

    22-OCT-08

    22-OCT-08

    22-OCT-08

    22-OCT-08

    22-OCT-08

    22-OCT-08

    22-OCT-08

    22-OCT-08

    22-OCT-08

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    22-OCT-08

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    22-OCT-08

    Attention: Larry Duty

    Account Name: Shaw E & I, Inc.ABB Lummus Biulding3010 Briarpark Drive Suite 4NHouston, TX 77042

    Project Number:

    Site:

    2773.025Longhorn AAP

    P.O. Number: 389869/ 390836(GWTP)

    Submitted By

    For

    Microbac Laboratories Inc.

    158 Starlite Drive

    Marietta OH 45750,740 373 4071)( -

    Method

    6010B

    6010B

    6010B

    6010B

    6010B

    6010B

    6010B

    6010B

    6010B

    6010B

    6010B

    6010B

    6010B

    6010B

    6010B

    6010B

    6010B

    6010B

    6010B

    6010B

    6010B

    6010B

    6010B

    LONGHORN AAP KARNACK TXProject:

    24

    00096711

  • L08100667

    November 3, 2008

    Report Number:

    Report Date :

    1 of

    Microbac Laboratories Inc.

    23

    Sodium, TotalAnalyte Qual

    1.252.50372ResultCAS. Number

    7440-23-5

    L08100667-01Sample Number: PE-ICP2Instrument:

    P2.102808.114616File ID:10/28/2008Run Date:Analyst:10/28/2008 08:34Cal Date:

    11:46Workgroup Number:Matrix: Analytical Method:Water

    MW118-102008Client ID:

    Sample Tag:DL01Dilution:

    Units:

    WG2858236010BJYH5mg/L

    Collect Date:10/20/2008 15:15

    Prep Method:3005A 10/23/2008 08:48Prep Date:

    PQL SDL

    NONEPrePrep Method:

    25

    00096712

  • L08100667

    November 3, 2008

    Report Number:

    Report Date :

    2 of

    Microbac Laboratories Inc.

    23

    Calcium, Total Iron, Total Vanadium, Total

    Analyte

    UU

    Qual0.1000.02500.00500

    0.2000.1000.0100

    347ResultCAS. Number

    7440-70-27439-89-67440-62-2

    L08100667-01Sample Number: PE-ICP2Instrument:

    P2.102908.133751File ID:10/29/2008Run Date:Analyst:10/29/2008 09:26Cal Date:

    13:37Workgroup Number:Matrix: Analytical Method:Water

    MW118-102008Client ID:

    Sample Tag:02Dilution:

    Units:

    WG2858236010BJYH1mg/L

    Collect Date:10/20/2008 15:15

    Prep Method:3005A 10/23/2008 08:48Prep Date:

    U Not detected at or above adjusted sample detection limit

    PQL SDL

    NONEPrePrep Method:

    26

    00096713

  • L08100667

    November 3, 2008

    Report Number:

    Report Date :

    3 of

    Microbac Laboratories Inc.

    23

    Aluminum, Total Beryllium, Total Cobalt, Total Magnesium, Total Potassium, Total Zinc, Total

    AnalyteUUU

    J

    Qual0.0500

    0.0005000.002500.2500.250

    0.00500

    0.1000.002000.005000.5001.00

    0.0200

    1871.99

    0.0193

    ResultCAS. Number7429-90-57440-41-77440-48-47439-95-47440-09-77440-66-6

    L08100667-01Sample Number: PE-ICP2Instrument:

    P2.102508.032154File ID:10/25/2008Run Date:Analyst:10/24/2008 14:46Cal Date:

    03:21Workgroup Number:Matrix: Analytical Method:Water

    MW118-102008Client ID:

    Sample Tag:01Dilution:

    Units:

    WG2858236010BJYH1mg/L

    Collect Date:10/20/2008 15:15

    Prep Method:3005A 10/23/2008 08:48Prep Date:

    U Not detected at or above adjusted sample detection limitJ The analyte was positively identified, but the quantitation was below the RL

    PQL SDL

    NONEPrePrep Method:

    27

    00096714

  • L08100667

    November 3, 2008

    Report Number:

    Report Date :

    4 of

    Microbac Laboratories Inc.

    23

    Sodium, TotalAnalyte Qual

    1.252.50207ResultCAS. Number

    7440-23-5

    L08100667-02Sample Number: PE-ICP2Instrument:

    P2.102808.115241File ID:10/28/2008Run Date:Analyst:10/28/2008 08:34Cal Date:

    11:52Workgroup Number:Matrix: Analytical Method:Water

    MW114-102008Client ID:

    Sample Tag:DL01Dilution:

    Units:

    WG2858236010BJYH5mg/L

    Collect Date:10/20/2008 16:10

    Prep Method:3005A 10/23/2008 08:48Prep Date:

    PQL SDL

    NONEPrePrep Method:

    28

    00096715

  • L08100667

    November 3, 2008

    Report Number:

    Report Date :

    5 of

    Microbac Laboratories Inc.

    23

    Aluminum, Total Beryllium, Total Cobalt, Total Magnesium, Total Potassium, Total Zinc, Total

    AnalyteJU

    Qual0.0500

    0.0005000.002500.2500.250

    0.00500

    0.1000.002000.005000.5001.00

    0.0200

    0.0846

    0.006141603.26

    0.0200

    ResultCAS. Number7429-90-57440-41-77440-48-47439-95-47440-09-77440-66-6

    L08100667-02Sample Number: PE-ICP2Instrument:

    P2.102508.032814File ID:10/25/2008Run Date:Analyst:10/24/2008 14:46Cal Date:

    03:28Workgroup Number:Matrix: Analytical Method:Water

    MW114-102008Client ID:

    Sample Tag:01Dilution:

    Units:

    WG2858236010BJYH1mg/L

    Collect Date:10/20/2008 16:10

    Prep Method:3005A 10/23/2008 08:48Prep Date:

    J The analyte was positively identified, but the quantitation was below the RLU Not detected at or above adjusted sample detection limit

    PQL SDL

    NONEPrePrep Method:

    29

    00096716

  • L08100667

    November 3, 2008

    Report Number:

    Report Date :

    6 of

    Microbac Laboratories Inc.

    23

    Calcium, Total Iron, Total Vanadium, Total

    Analyte

    U

    Qual0.5000.1250.0250

    1.000.5000.0500

    1611.10

    ResultCAS. Number7440-70-27439-89-67440-62-2

    L08100667-02Sample Number: PE-ICP2Instrument:

    P2.102908.135035File ID:10/29/2008Run Date:Analyst:10/29/2008 09:26Cal Date:

    13:50Workgroup Number:Matrix: Analytical Method:Water

    MW114-102008Client ID:

    Sample Tag:DL02Dilution:

    Units:

    WG2858236010BJYH5mg/L

    Collect Date:10/20/2008 16:10

    Prep Method:3005A 10/23/2008 08:48Prep Date:

    U Not detected at or above adjusted sample detection limit

    PQL SDL

    NONEPrePrep Method:

    30

    00096717

  • L08100667

    November 3, 2008

    Report Number:

    Report Date :

    7 of

    Microbac Laboratories Inc.

    23

    Aluminum, Total Beryllium, Total Cobalt, Total Magnesium, Total Potassium, Total Vanadium, Total Zinc, Total

    Analyte

    UJ

    U

    Qual0.0500

    0.0005000.002500.2500.250

    0.005000.00500

    0.1000.002000.005000.5001.00

    0.01000.0200

    0.439

    0.004293555.85

    0.0391

    ResultCAS. Number7429-90-57440-41-77440-48-47439-95-47440-09-77440-62-27440-66-6

    L08100667-03Sample Number: PE-ICP2Instrument:

    P2.102508.033440File ID:10/25/2008Run Date:Analyst:10/24/2008 14:46Cal Date:

    03:34Workgroup Number:Matrix: Analytical Method:Water

    MW116-102108Client ID:

    Sample Tag:01Dilution:

    Units:

    WG2858236010BJYH1mg/L

    Collect Date:10/21/2008 11:05

    Prep Method:3005A 10/23/2008 08:48Prep Date:

    U Not detected at or above adjusted sample detection limitJ The analyte was positively identified, but the quantitation was below the RL

    PQL SDL

    NONEPrePrep Method:

    31

    00096718

  • L08100667

    November 3, 2008

    Report Number:

    Report Date :

    8 of

    Microbac Laboratories Inc.

    23

    Calcium, Total Iron, Total

    Analyte Qual0.5000.125

    1.000.500

    5091.66

    ResultCAS. Number7440-70-27439-89-6

    L08100667-03Sample Number: PE-ICP2Instrument:

    P2.102908.140309File ID:10/29/2008Run Date:Analyst:10/29/2008 09:26Cal Date:

    14:03Workgroup Number:Matrix: Analytical Method:Water

    MW116-102108Client ID:

    Sample Tag:DL01Dilution:

    Units:

    WG2858236010BJYH5mg/L

    Collect Date:10/21/2008 11:05

    Prep Method:3005A 10/23/2008 08:48Prep Date:

    PQL SDL

    NONEPrePrep Method:

    32

    00096719

  • L08100667

    November 3, 2008

    Report Number:

    Report Date :

    9 of

    Microbac Laboratories Inc.

    23

    Sodium, TotalAnalyte Qual

    1.252.50514ResultCAS. Number

    7440-23-5

    L08100667-03Sample Number: PE-ICP2Instrument:

    P2.102808.115859File ID:10/28/2008Run Date:Analyst:10/28/2008 08:34Cal Date:

    11:58Workgroup Number:Matrix: Analytical Method:Water

    MW116-102108Client ID:

    Sample Tag:02Dilution:

    Units:

    WG2858236010BJYH5mg/L

    Collect Date:10/21/2008 11:05

    Prep Method:3005A 10/23/2008 08:48Prep Date:

    PQL SDL

    NONEPrePrep Method:

    33

    00096720

  • L08100667

    November 3, 2008

    Report Number:

    Report Date :

    10 of

    Microbac Laboratories Inc.

    23

    Sodium, TotalAnalyte Qual

    1.252.50512ResultCAS. Number

    7440-23-5

    L08100667-04Sample Number: PE-ICP2Instrument:

    P2.102808.120520File ID:10/28/2008Run Date:Analyst:10/28/2008 08:34Cal Date:

    12:05Workgroup Number:Matrix: Analytical Method:Water

    MW116-102108-QAClient ID:

    Sample Tag:DL01Dilution:

    Units:

    WG2858236010BJYH5mg/L

    Collect Date:10/21/2008 11:05

    Prep Method:3005A 10/23/2008 08:48Prep Date:

    PQL SDL

    NONEPrePrep Method:

    34

    00096721

  • L08100667

    November 3, 2008

    Report Number:

    Report Date :

    11 of

    Microbac Laboratories Inc.

    23

    Aluminum, Total Beryllium, Total Cobalt, Total Magnesium, Total Potassium, Total Vanadium, Total Zinc, Total

    Analyte

    UJ

    U

    Qual0.0500

    0.0005000.002500.2500.250

    0.005000.00500

    0.1000.002000.005000.5001.00

    0.01000.0200

    0.445

    0.004083545.74

    0.0399

    ResultCAS. Number7429-90-57440-41-77440-48-47439-95-47440-09-77440-62-27440-66-6

    L08100667-04Sample Number: PE-ICP2Instrument:

    P2.102508.034106File ID:10/25/2008Run Date:Analyst:10/24/2008 14:46Cal Date:

    03:41Workgroup Number:Matrix: Analytical Method:Water

    MW116-102108-QAClient ID:

    Sample Tag:01Dilution:

    Units:

    WG2858236010BJYH1mg/L

    Collect Date:10/21/2008 11:05

    Prep Method:3005A 10/23/2008 08:48Prep Date:

    U Not detected at or above adjusted sample detection limitJ The analyte was positively identified, but the quantitation was below the RL

    PQL SDL

    NONEPrePrep Method:

    35

    00096722

  • L08100667

    November 3, 2008

    Report Number:

    Report Date :

    12 of

    Microbac Laboratories Inc.

    23

    Calcium, Total Iron, Total

    Analyte Qual0.5000.125

    1.000.500

    4951.67

    ResultCAS. Number7440-70-27439-89-6

    L08100667-04Sample Number: PE-ICP2Instrument:

    P2.102908.140934File ID:10/29/2008Run Date:Analyst:10/29/2008 09:26Cal Date:

    14:09Workgroup Number:Matrix: Analytical Method:Water

    MW116-102108-QAClient ID:

    Sample Tag:DL02Dilution:

    Units:

    WG2858236010BJYH5mg/L

    Collect Date:10/21/2008 11:05

    Prep Method:3005A 10/23/2008 08:48Prep Date:

    PQL SDL

    NONEPrePrep Method:

    36

    00096723

  • L08100667

    November 3, 2008

    Report Number:

    Report Date :

    13 of

    Microbac Laboratories Inc.

    23

    Calcium, Total Iron, Total

    Analyte Qual0.2000.0500

    0.4000.200

    80.10.665

    ResultCAS. Number7440-70-27439-89-6

    L08100667-05Sample Number: PE-ICP2Instrument:

    P2.102908.141552File ID:10/29/2008Run Date:Analyst:10/29/2008 09:26Cal Date:

    14:15Workgroup Number:Matrix: Analytical Method:Water

    29WW10-102108Client ID:

    Sample Tag:DL03Dilution:

    Units:

    WG2858236010BJYH2mg/L

    Collect Date:10/21/2008 10:00

    Prep Method:3005A 10/23/2008 08:48Prep Date:

    PQL SDL

    NONEPrePrep Method:

    37

    00096724

  • L08100667

    November 3, 2008

    Report Number:

    Report Date :

    14 of

    Microbac Laboratories Inc.

    23

    Aluminum, Total Beryllium, Total Cobalt, Total Magnesium, Total Potassium, Total Zinc, Total

    AnalyteUUJ

    JJ

    Qual0.0500

    0.0005000.002500.2500.250

    0.00500

    0.1000.002000.005000.5001.00

    0.0200

    0.0049462.20.5340.0151

    ResultCAS. Number7429-90-57440-41-77440-48-47439-95-47440-09-77440-66-6

    L08100667-05Sample Number: PE-ICP2Instrument:

    P2.102508.040011File ID:10/25/2008Run Date:Analyst:10/24/2008 14:46Cal Date:

    04:00Workgroup Number:Matrix: Analytical Method:Water

    29WW10-102108Client ID:

    Sample Tag:01Dilution:

    Units:

    WG2858236010BJYH1mg/L

    Collect Date:10/21/2008 10:00

    Prep Method:3005A 10/23/2008 08:48Prep Date:

    U Not detected at or above adjusted sample detection limitJ The analyte was positively identified, but the quantitation was below the RL

    PQL SDL

    NONEPrePrep Method:

    38

    00096725

  • L08100667

    November 3, 2008

    Report Number:

    Report Date :

    15 of

    Microbac Laboratories Inc.

    23

    Vanadium, TotalAnalyte

    UQual

    0.05000.100ResultCAS. Number

    7440-62-2

    L08100667-05Sample Number: PE-ICP2Instrument:

    P2.102808.150941File ID:10/28/2008Run Date:Analyst:10/28/2008 08:34Cal Date:

    15:09Workgroup Number:Matrix: Analytical Method:Water

    29WW10-102108Client ID:

    Sample Tag:DL02Dilution:

    Units:

    WG2858236010BJYH10mg/L

    Collect Date:10/21/2008 10:00

    Prep Method:3005A 10/23/2008 08:48Prep Date:

    U Not detected at or above adjusted sample detection limit

    PQL SDL

    NONEPrePrep Method:

    39

    00096726

  • L08100667

    November 3, 2008

    Report Number:

    Report Date :

    16 of

    Microbac Laboratories Inc.

    23

    Sodium, TotalAnalyte Qual

    1.252.50206ResultCAS. Number

    7440-23-5

    L08100667-05Sample Number: PE-ICP2Instrument:

    P2.102808.123044File ID:10/28/2008Run Date:Analyst:10/28/2008 08:34Cal Date:

    12:30Workgroup Number:Matrix: Analytical Method:Water

    29WW10-102108Client ID:

    Sample Tag:DL01Dilution:

    Units:

    WG2858236010BJYH5mg/L

    Collect Date:10/21/2008 10:00

    Prep Method:3005A 10/23/2008 08:48Prep Date:

    PQL SDL

    NONEPrePrep Method:

    40

    00096727

  • L08100667

    November 3, 2008

    Report Number:

    Report Date :

    17 of

    Microbac Laboratories Inc.

    23

    Vanadium, TotalAnalyte

    UQual

    0.02500.0500ResultCAS. Number

    7440-62-2

    L08100667-06Sample Number: PE-ICP2Instrument:

    P2.103108.102354File ID:10/31/2008Run Date:Analyst:10/31/2008 09:37Cal Date:

    10:23Workgroup Number:Matrix: Analytical Method:Water

    29WW19-102108Client ID:

    Sample Tag:DL03Dilution:

    Units:

    WG2858236010BED5mg/L

    Collect Date:10/21/2008 12:20

    Prep Method:3005A 10/23/2008 08:48Prep Date:

    U Not detected at or above adjusted sample detection limit

    PQL SDL

    NONEPrePrep Method:

    41

    00096728

  • L08100667

    November 3, 2008

    Report Number:

    Report Date :

    18 of

    Microbac Laboratories Inc.

    23

    Calcium, Total Iron, Total

    Analyte Qual0.2000.0500

    0.4000.200

    3660.561

    ResultCAS. Number7440-70-27439-89-6

    L08100667-06Sample Number: PE-ICP2Instrument:

    P2.102908.142212File ID:10/29/2008Run Date:Analyst:10/29/2008 09:26Cal Date:

    14:22Workgroup Number:Matrix: Analytical Method:Water

    29WW19-102108Client ID:

    Sample Tag:DL02Dilution:

    Units:

    WG2858236010BJYH2mg/L

    Collect Date:10/21/2008 12:20

    Prep Method:3005A 10/23/2008 08:48Prep Date:

    PQL SDL

    NONEPrePrep Method:

    42

    00096729

  • L08100667

    November 3, 2008

    Report Number:

    Report Date :

    19 of

    Microbac Laboratories Inc.

    23

    Sodium, TotalAnalyte Qual

    1.252.50218ResultCAS. Number

    7440-23-5

    L08100667-06Sample Number: PE-ICP2Instrument:

    P2.102808.124328File ID:10/28/2008Run Date:Analyst:10/28/2008 08:34Cal Date:

    12:43Workgroup Number:Matrix: Analytical Method:Water

    29WW19-102108Client ID:

    Sample Tag:DL01Dilution:

    Units:

    WG2858236010BJYH5mg/L

    Collect Date:10/21/2008 12:20

    Prep Method:3005A 10/23/2008 08:48Prep Date:

    PQL SDL

    NONEPrePrep Method:

    43

    00096730

  • L08100667

    November 3, 2008

    Report Number:

    Report Date :

    20 of

    Microbac Laboratories Inc.

    23

    Aluminum, Total Beryllium, Total Cobalt, Total Magnesium, Total Potassium, Total Zinc, Total

    AnalyteUUU

    J

    Qual0.0500

    0.0005000.002500.2500.250

    0.00500

    0.1000.002000.005000.5001.00

    0.0200

    2645.47

    0.0180

    ResultCAS. Number7429-90-57440-41-77440-48-47439-95-47440-09-77440-66-6

    L08100667-06Sample Number: PE-ICP2Instrument:

    P2.102508.040630File ID:10/25/2008Run Date:Analyst:10/24/2008 14:46Cal Date:

    04:06Workgroup Number:Matrix: Analytical Method:Water

    29WW19-102108Client ID:

    Sample Tag:01Dilution:

    Units:

    WG2858236010BJYH1mg/L

    Collect Date:10/21/2008 12:20

    Prep Method:3005A 10/23/2008 08:48Prep Date:

    U Not detected at or above adjusted sample detection limitJ The analyte was positively identified, but the quantitation was below the RL

    PQL SDL

    NONEPrePrep Method:

    44

    00096731

  • L08100667

    November 3, 2008

    Report Number:

    Report Date :

    21 of

    Microbac Laboratories Inc.

    23

    Aluminum, Total Beryllium, Total Cobalt, Total Magnesium, Total Potassium, Total Zinc, Total

    AnalyteUU

    Qual0.0500

    0.0005000.002500.2500.250

    0.00500

    0.1000.002000.005000.5001.00

    0.0200

    0.05721594.26

    0.0311

    ResultCAS. Number7429-90-57440-41-77440-48-47439-95-47440-09-77440-66-6

    L08100667-07Sample Number: PE-ICP2Instrument:

    P2.102508.041302File ID:10/25/2008Run Date:Analyst:10/24/2008 14:46Cal Date:

    04:13Workgroup Number:Matrix: Analytical Method:Water

    29WW25-102108Client ID:

    Sample Tag:01Dilution:

    Units:

    WG2858236010BJYH1mg/L

    Collect Date:10/21/2008 15:00

    Prep Method:3005A 10/23/2008 08:48Prep Date:

    U Not detected at or above adjusted sample detection limit

    PQL SDL

    NONEPrePrep Method:

    45

    00096732

  • L08100667

    November 3, 2008

    Report Number:

    Report Date :

    22 of

    Microbac Laboratories Inc.

    23

    Calcium, Total Iron, Total Vanadium, Total

    Analyte

    U

    Qual0.5000.1250.0250

    1.000.5000.0500

    25717.3

    ResultCAS. Number7440-70-27439-89-67440-62-2

    L08100667-07Sample Number: PE-ICP2Instrument:

    P2.102908.144117File ID:10/29/2008Run Date:Analyst:10/29/2008 09:26Cal Date:

    14:41Workgroup Number:Matrix: Analytical Method:Water

    29WW25-102108Client ID:

    Sample Tag:DL02Dilution:

    Units:

    WG2858236010BJYH5mg/L

    Collect Date:10/21/2008 15:00

    Prep Method:3005A 10/23/2008 08:48Prep Date:

    U Not detected at or above adjusted sample detection limit

    PQL SDL

    NONEPrePrep Method:

    46

    00096733

  • L08100667

    November 3, 2008

    Report Number:

    Report Date :

    23 of

    Microbac Laboratories Inc.

    23

    Sodium, TotalAnalyte Qual

    1.252.50210ResultCAS. Number

    7440-23-5

    L08100667-07Sample Number: PE-ICP2Instrument:

    P2.102808.124953File ID:10/28/2008Run Date:Analyst:10/28/2008 08:34Cal Date:

    12:49Workgroup Number:Matrix: Analytical Method:Water

    29WW25-102108Client ID:

    Sample Tag:DL01Dilution:

    Units:

    WG2858236010BJYH5mg/L

    Collect Date:10/21/2008 15:00

    Prep Method:3005A 10/23/2008 08:48Prep Date:

    PQL SDL

    NONEPrePrep Method:

    47

    00096734

  • 2.1.1.2 QC Summary Data

    48

    00096735

  • Example 6010 CalculationsPerkin Elmer Optima 4300 DV

    1.0 Initial Calibration (ICAL) ParametersThe system performs linear regression from data consisting of a blank and three standards.

    2.0 Calculating the concentration (C) of an element in water using data from prep log, run log, andquantitation report (note:the data system performs this calculation automatically when correction factorshave been entered):

    Cx = Cs× V fV i

    ×D

    Where: Example:Cs = Concentration computed by the data system in ug/mL (ppm) 0.1V f = Final volume (mL) 50V i = Initial volume (mL) 50D = Dilution factor as a multiplier (10X = 10) 1

    Cx = Concentration of element in ug/mL (mg/L) 0.1

    3.0 Calculating the concentration (C) of an element in soil using data from prep log, run log, and quantitationreport (note: the data system performs this calculation automatically when correction factors have beenentered):

    Cx = Cs× V fV i

    ×D

    Where: Example:Cs = Concentration computed by the data system (mg/L) (ppm) 0.1V f = Final volume (mL) 50V i = Initial weight (g) 1D = Dilution factor as a multiplier (10X = 10) 1

    Cx = Concentration of element in ug/g (mg/kg) 5

    4.0 Adjusting the concentration to dry weight:

    Cdry =Cx× 100

    Px

    Where: Example:Cx = Concentration calculated as received (wet basis) 5Px = Percent solids of sample (%wt) 80

    Cdry = Concentration calculated as dry weight (mg/kg) 6.25

    49

    00096736

  • Example 6010 CalculationsThermo Scientific IRIS Advantage

    1.0 Initial Calibration (ICAL) ParametersThe system performs linear regression from data consisting of a blank and three standards.

    2.0 Calculating the concentration (C) of an element in water using data from prep log, run log, andquantitation report (note:the data system performs this calculation automatically when correction factorshave been entered):

    Cx = Cs× V fV i

    ×D

    Where: Example:Cs = Concentration computed by the data system in ug/mL (ppm) 0.1V f = Final volume (mL) 50V i = Initial volume (mL) 50D = Dilution factor as a multiplier (10X = 10) 1

    Cx = Concentration of element in ug/mL (mg/L) 0.1

    3.0 Calculating the concentration (C) of an element in soil using data from prep log, run log, and quantitationreport (note: the data system performs this calculation automatically when correction factors have beenentered):

    Cx = Cs× V fV i

    ×D

    Where: Example:Cs = Concentration computed by the data system (mg/L) (ppm) 0.1V f = Final volume (mL) 50V i = Initial weight (g) 1D = Dilution factor as a multiplier (10X = 10) 1

    Cx = Concentration of element in ug/g (mg/kg) 5

    4.0 Adjusting the concentration to dry weight:

    Cdry =Cx× 100

    Px

    Where: Example:Cx = Concentration calculated as received (wet basis) 5Px = Percent solids of sample (%wt) 80

    Cdry = Concentration calculated as dry weight (mg/kg) 6.25

    50

    00096737

  • Example 6010 CalculationsThermo Scientific iCAP 6500

    1.0 Initial Calibration (ICAL) ParametersThe system performs linear regression from data consisting of a blank and four standards.

    2.0 Calculating the concentration (C) of an element in water using data from prep log, run log, andquantitation report (note:the data system performs this calculation automatically when correction factorshave been entered):

    Cx = Cs× V fV i

    ×D

    Where: Example:Cs = Concentration computed by the data system in ug/mL (ppm) 0.1V f = Final volume (mL) 50V i = Initial volume (mL) 50D = Dilution factor as a multiplier (10X = 10) 1

    Cx = Concentration of element in ug/mL (mg/L) 0.1

    3.0 Calculating the concentration (C) of an element in soil using data from prep log, run log, and quantitationreport (note: the data system performs this calculation automatically when correction factors have beenentered):

    Cx = Cs× V fV i

    ×D

    Where: Example:Cs = Concentration computed by the data system (mg/L) (ppm) 0.1V f = Final volume (mL) 50V i = Initial weight (g) 1D = Dilution factor as a multiplier (10X = 10) 1

    Cx = Concentration of element in ug/g (mg/kg) 5

    4.0 Adjusting the concentration to dry weight:

    Cdry =Cx× 100

    Px

    Where: Example:Cx = Concentration calculated as received (wet basis) 5Px = Percent solids of sample (%wt) 80

    Cdry = Concentration calculated as dry weight (mg/kg) 6.25

    51

    00096738

  • Metals Digest Log

    BLOCK_DIG - Modified 07/22/2008 PDF ID:Report generated: 10/23/2008 11:02

    Microbac Laboratories Inc.

    1230326

    Reviewer:Analyst:

    WG285777-02

    WG285777-03

    L08100621-01

    L08100621-02

    L08100621-03

    L08100632-01

    WG285777-01

    L08100633-01

    WG285777-04

    L08100633-02

    WG285777-05

    L08100633-03

    L08100633-04

    L08100633-05

    L08100633-06

    L08100641-03

    L08100641-04

    L08100667-01

    L08100667-02

    L08100667-03

    L08100667-04

    L08100667-05

    L08100667-06

    L08100667-07

    SAMPLE #

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    Initial Amount

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    50 mL

    Final Volume Due Date

    10/31/08

    10/31/08

    10/31/08

    10/31/08

    11/05/08

    11/05/08

    11/05/08

    11/05/08

    11/05/08

    11/05/08

    10/29/08

    10/29/08

    10/31/08

    10/31/08

    10/31/08

    10/31/08

    10/31/08

    10/31/08

    10/31/08

    Type

    BLANK

    LCS

    SAMP

    SAMP

    SAMP

    SAMP

    REF

    RS01

    MS

    MS01

    MSD

    SD01

    SAMP

    SAMP

    SAMP

    SAMP

    SAMP

    SAMP

    SAMP

    SAMP

    SAMP

    SAMP

    SAMP

    SAMP

    WG285777

    Method:3005A

    Analyst:REK

    Workgroup:

    Run Date:10/23/2008 08:48

    ME401 Revison 13SOP:

    Spike Solution:

    Spike Witness:

    STD27613

    SDL

    COA13347

    COA13324

    COA13407

    HNO3 Lot #:

    hcl Lot #:

    Digest tubes Lot #:

    95 @ 06:45

    95 @ 10:45

    Hotblock Start Temp:Hotblock End Temp:

    Matrix

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    2

    3

    4

    5

    6

    7

    8

    9

    10

    11

    12

    13

    14

    15

    16

    17

    18

    19

    20

    21

    22

    23

    24

    Spike Amount

    5 mL

    5 mL

    5 mL

    5 mL

    5 mL

    52

    00096739

  • Instrument Run Log

    Run Log ID: 24892

    Page: 1 Approved: October 28, 2008

    Microbac Laboratories Inc.

    Instrument:

    Analyst1:

    Method:

    Dataset:

    Analyst2:

    SOP: Rev:

    PE-ICP2

    ED

    6010B

    102408H3R.CSV

    N/A

    ME600E 8

    Calibration Std:

    ICSA:

    ICV/CCV Std:

    ICSAB:

    Post Spike:

    Workgroups:

    STD29127

    STD29188

    STD29410

    STD29411

    STD27612

    285957,285645,285632,285641,285823,285136

    1

    2

    3

    4

    5

    6

    7

    8

    9

    10

    11

    12

    13

    14

    15

    16

    17

    18

    19

    20

    21

    22

    23

    24

    25

    26

    27

    28

    29

    30

    31

    32

    33

    34

    35

    36

    37

    P2.102408.142122

    P2.102408.142737

    P2.102408.143351

    P2.102408.144008

    P2.102408.144624

    P2.102408.145157

    P2.102408.145815

    P2.102408.150432

    P2.102408.150952

    P2.102408.151514

    P2.102408.152134

    P2.102408.153243

    P2.102408.153856

    P2.102408.154516

    P2.102408.155141

    P2.102408.155759

    P2.102408.160424

    P2.102408.161045

    P2.102408.161710

    P2.102408.162328

    P2.102408.162955

    P2.102408.163620

    P2.102408.164240

    P2.102408.164858

    P2.102408.165516

    P2.102408.170138

    P2.102408.170702

    P2.102408.171323

    P2.102408.171937

    P2.102408.172555

    P2.102408.173216

    P2.102408.173830

    P2.102408.174449

    P2.102408.175014

    P2.102408.175632

    P2.102408.180249

    P2.102408.180913

    WG286114-01

    WG286114-02

    WG286114-03

    WG286114-04

    WG286114-05

    WG286114-06

    WG286114-07

    WG286114-08

    WG286114-09

    WG286114-10

    WG286114-11

    WG285892-02

    WG285892-03

    L08100661-04

    WG285892-01

    WG285957-01

    WG285957-02

    WG285892-04

    WG285892-05

    L08100696-04

    L08100696-06

    WG286114-12

    WG286114-13

    L08100697-01

    WG285422-01

    WG285645-01

    WG285645-02

    WG285422-04

    WG285422-05

    L08100521-09

    L08100521-10

    L08100542-01

    L08100534-01

    WG286114-14

    WG286114-15

    L08100534-01

    L08100534-02

    Calibration Point

    Calibration Point

    Calibration Point

    Calibration Point

    Calibration Point

    Initial Calibration Verification

    Initial Calib Blank

    Interference Check

    Interference Check

    CCV

    CCB

    Method/Prep Blank

    Laboratory Control S

    EFFLUENT

    Reference Sample

    Post Digestion Spike

    Serial Dilution

    Matrix Spike

    Matrix Spike Duplica

    OUTFALL 003/COMP

    OUTFALL 800/COMP

    CCV

    CCB

    OUTFALL 002/COMP

    Reference Sample

    Post Digestion Spike

    Serial Dilution

    Matrix Spike

    Matrix Spike Duplica

    SPE-G-MW-3-DUP

    SPE-G-MW-3-DIS-DUP

    001

    PZ03-101608

    CCV

    CCB

    PZ03-101608

    PZ01-101608

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    5

    1

    1

    1

    1

    1

    1

    1

    200

    200

    1000

    200

    200

    200

    200

    1

    5

    1

    1

    100

    2

    L08100683-01

    L08100683-01

    L08100683-01

    L08100683-01

    L08100683-01

    L08100521-01

    L08100521-01

    L08100521-01

    L08100521-01

    L08100521-01

    10/24/08 14:21

    10/24/08 14:27

    10/24/08 14:33

    10/24/08 14:40

    10/24/08 14:46

    10/24/08 14:51

    10/24/08 14:58

    10/24/08 15:04

    10/24/08 15:09

    10/24/08 15:15

    10/24/08 15:21

    10/24/08 15:32

    10/24/08 15:38

    10/24/08 15:45

    10/24/08 15:51

    10/24/08 15:57

    10/24/08 16:04

    10/24/08 16:10

    10/24/08 16:17

    10/24/08 16:23

    10/24/08 16:29

    10/24/08 16:36

    10/24/08 16:42

    10/24/08 16:48

    10/24/08 16:55

    10/24/08 17:01

    10/24/08 17:07

    10/24/08 17:13

    10/24/08 17:19

    10/24/08 17:25

    10/24/08 17:32

    10/24/08 17:38

    10/24/08 17:44

    10/24/08 17:50

    10/24/08 17:56

    10/24/08 18:02

    10/24/08 18:09

    Seq. File ID Sample ID Prep Dil Reference Date/Time

    Comments:

    Maintenance Log ID: 286114

    53

    00096740

  • Instrument Run Log

    Run Log ID: 24892

    Page: 2 Approved: October 28, 2008

    Microbac Laboratories Inc.

    Instrument:

    Analyst1:

    Method:

    Dataset:

    Analyst2:

    SOP: Rev:

    PE-ICP2

    ED

    6010B

    102408H3R.CSV

    N/A

    ME600E 8

    Calibration Std:

    ICSA:

    ICV/CCV Std:

    ICSAB:

    Post Spike:

    Workgroups:

    STD29127

    STD29188

    STD29410

    STD29411

    STD27612

    285957,285645,285632,285641,285823,285136

    38

    39

    40

    41

    42

    43

    44

    45

    46

    47

    48

    49

    50

    51

    52

    53

    54

    55

    56

    57

    58

    59

    60

    61

    62

    63

    64

    65

    66

    67

    68

    69

    70

    71

    72

    73

    74

    P2.102408.181431

    P2.102408.182048

    P2.102408.182713

    P2.102408.183329

    P2.102408.183952

    P2.102408.184622

    P2.102408.185239

    P2.102408.185804

    P2.102408.190425

    P2.102408.191038

    P2.102408.191702

    P2.102408.192327

    P2.102408.192941

    P2.102408.193558

    P2.102408.194220

    P2.102408.194834

    P2.102408.195454

    P2.102408.200117

    P2.102408.200731

    P2.102408.201354

    P2.102408.202015

    P2.102408.202533

    P2.102408.203201

    P2.102408.203817

    P2.102408.204430

    P2.102408.205050

    P2.102408.205710

    P2.102408.210324

    P2.102408.210905

    P2.102408.211437

    P2.102408.211955

    P2.102408.212524

    P2.102408.213050

    P2.102408.213608

    P2.102408.214237

    P2.102408.214853

    P2.102408.215510

    L08100534-03

    L08100534-04

    L08100534-05

    L08100534-06

    L08100534-08

    L08100534-10

    L08100544-01

    L08100544-01

    WG285522-03

    WG286114-16

    WG286114-17

    WG285522-04

    WG285522-01

    WG285632-01

    WG285632-02

    WG285522-05

    WG285522-06

    L08100533-11

    L08100533-14

    L08100533-16

    L08100533-19

    WG286114-18

    WG286114-19

    L08100533-22

    L08100533-25

    L08100533-27

    L08100533-30

    L08100547-01

    L08100547-02

    WG285522-02

    WG285522-07

    WG285522-08

    L08100547-06

    WG286114-20

    WG286114-21

    L08100547-07

    L08100547-08

    MW10-101608

    MW03-101608

    MW19-101608

    MW05S-101508

    BLDG4PITSSP-101608

    PZ01-101608

    6278

    6278

    Method/Prep Blank

    CCV

    CCB

    Laboratory Control S

    Reference Sample

    Post Digestion Spike

    Serial Dilution

    Matrix Spike

    Matrix Spike Duplica

    MW2D-230-14

    MW4A-230-14

    MW4C-230-14

    MW4C2-230-14

    CCV

    CCB

    MW5A-230-14

    OW1A-230-14

    OW2A-230-14

    OW3A-230-14

    MW01S-GW-101408

    MW01S-GW-101408D

    Reference Sample

    Matrix Spike

    Matrix Spike Duplica

    MW04D-GW-101508

    CCV

    CCB

    MW06D-GW-101508

    MW07D-GW-101608

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    5

    5

    1

    5

    5

    5

    1

    10

    1

    1

    1

    1

    1

    1

    5

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    L08100533-02

    L08100533-02

    L08100533-02

    L08100533-02

    L08100533-02

    L08100547-03

    L08100547-03

    L08100547-03

    10/24/08 18:14

    10/24/08 18:20

    10/24/08 18:27

    10/24/08 18:33

    10/24/08 18:39

    10/24/08 18:46

    10/24/08 18:52

    10/24/08 18:58

    10/24/08 19:04

    10/24/08 19:10

    10/24/08 19:17

    10/24/08 19:23

    10/24/08 19:29

    10/24/08 19:35

    10/24/08 19:42

    10/24/08 19:48

    10/24/08 19:54

    10/24/08 20:01

    10/24/08 20:07

    10/24/08 20:13

    10/24/08 20:20

    10/24/08 20:25

    10/24/08 20:32

    10/24/08 20:38

    10/24/08 20:44

    10/24/08 20:50

    10/24/08 20:57

    10/24/08 21:03

    10/24/08 21:09

    10/24/08 21:14

    10/24/08 21:19

    10/24/08 21:25

    10/24/08 21:30

    10/24/08 21:36

    10/24/08 21:42

    10/24/08 21:48

    10/24/08 21:55

    Seq. File ID Sample ID Prep Dil Reference Date/Time

    Comments:

    Maintenance Log ID: 286114

    54

    00096741

  • Instrument Run Log

    Run Log ID: 24892

    Page: 3 Approved: October 28, 2008

    Microbac Laboratories Inc.

    Instrument:

    Analyst1:

    Method:

    Dataset:

    Analyst2:

    SOP: Rev:

    PE-ICP2

    ED

    6010B

    102408H3R.CSV

    N/A

    ME600E 8

    Calibration Std:

    ICSA:

    ICV/CCV Std:

    ICSAB:

    Post Spike:

    Workgroups:

    STD29127

    STD29188

    STD29410

    STD29411

    STD27612

    285957,285645,285632,285641,285823,285136

    75

    76

    77

    78

    79

    80

    81

    82

    83

    84

    85

    86

    87

    88

    89

    90

    91

    92

    93

    94

    95

    96

    97

    98

    99

    100

    101

    102

    103

    104

    105

    106

    107

    108

    109

    110

    111

    P2.102408.220035

    P2.102408.220600

    P2.102408.221118

    P2.102408.221647

    P2.102408.222306

    P2.102408.222921

    P2.102408.223446

    P2.102408.224107

    P2.102408.224722

    P2.102408.225345

    P2.102408.230005

    P2.102408.230627

    P2.102408.231242

    P2.102408.231902

    P2.102408.232523

    P2.102408.233042

    P2.102408.233700

    P2.102408.234324

    P2.102408.234940

    P2.102408.235604

    P2.102508.000226

    P2.102508.000842

    P2.102508.001506

    P2.102508.002128

    P2.102508.002744

    P2.102508.003309

    P2.102508.003934

    P2.102508.004556

    P2.102508.005211

    P2.102508.005832

    P2.102508.010454

    P2.102508.011013

    P2.102508.011538

    P2.102508.012200

    P2.102508.012814

    P2.102508.013435

    P2.102508.014057

    L08100547-09

    L08100547-10

    L08100547-11

    WG285526-03

    WG285526-04

    L08100572-01

    WG285526-01

    WG285641-01

    WG286114-22

    WG286114-23

    WG285641-02

    L08100572-03

    L08100572-04

    L08100572-05

    L08100572-06

    L08100572-07

    WG285526-05

    WG285526-06

    WG285526-02

    WG285526-07

    WG286114-24

    WG286114-25

    WG285526-08

    L08100573-16

    L08100575-01

    L08100575-02

    L08100575-03

    L08100575-04

    L08100575-05

    L08100575-06

    L08100575-07

    L08100575-08

    WG286114-26

    WG286114-27

    WG285777-02

    WG285777-03

    L08100621-01

    MW07S-GW-101608

    MW03D-GW-101608

    MW02S-GW-101608

    Method/Prep Blank

    Laboratory Control S

    MW-2A

    Reference Sample

    Post Digestion Spike

    CCV

    CCB

    Serial Dilution

    MW-2C

    MW-8A

    MW-8B

    MW-7A

    MW-7B

    Matrix Spike

    Matrix Spike Duplica

    Reference Sample

    Matrix Spike

    CCV

    CCB

    Matrix Spike Duplica

    MAIN DISCHARGE-IS-5-DUP

    MW02D-GW-101708

    MW03S-GW-101708

    0051-SW-101808

    0052-SW-101808

    0053-SW-101808

    0054-SW-101808

    0055-SW-101808

    0056-SW-101808

    CCV

    CCB

    Method/Prep Blank

    Laboratory Control S

    6282

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    5

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    L08100572-02

    L08100572-02

    L08100572-02

    WG285931-04

    L08100572-02

    L08100572-02

    L08100573-13

    L08100573-13

    L08100573-13

    WG285634-01

    10/24/08 22:00

    10/24/08 22:06

    10/24/08 22:11

    10/24/08 22:16

    10/24/08 22:23

    10/24/08 22:29

    10/24/08 22:34

    10/24/08 22:41

    10/24/08 22:47

    10/24/08 22:53

    10/24/08 23:00

    10/24/08 23:06

    10/24/08 23:12

    10/24/08 23:19

    10/24/08 23:25

    10/24/08 23:30

    10/24/08 23:37

    10/24/08 23:43

    10/24/08 23:49

    10/24/08 23:56

    10/25/08 00:02

    10/25/08 00:08

    10/25/08 00:15

    10/25/08 00:21

    10/25/08 00:27

    10/25/08 00:33

    10/25/08 00:39

    10/25/08 00:45

    10/25/08 00:52

    10/25/08 00:58

    10/25/08 01:04

    10/25/08 01:10

    10/25/08 01:15

    10/25/08 01:22

    10/25/08 01:28

    10/25/08 01:34

    10/25/08 01:40

    Seq. File ID Sample ID Prep Dil Reference Date/Time

    Comments:

    Maintenance Log ID: 286114

    55

    00096742

  • Instrument Run Log

    Run Log ID: 24892

    Page: 4 Approved: October 28, 2008

    Microbac Laboratories Inc.

    Instrument:

    Analyst1:

    Method:

    Dataset:

    Analyst2:

    SOP: Rev:

    PE-ICP2

    ED

    6010B

    102408H3R.CSV

    N/A

    ME600E 8

    Calibration Std:

    ICSA:

    ICV/CCV Std:

    ICSAB:

    Post Spike:

    Workgroups:

    STD29127

    STD29188

    STD29410

    STD29411

    STD27612

    285957,285645,285632,285641,285823,285136

    112

    113

    114

    115

    116

    117

    118

    119

    120

    121

    122

    123

    124

    125

    126

    127

    128

    129

    130

    131

    132

    133

    134

    135

    136

    137

    138

    139

    140

    141

    142

    143

    144

    145

    146

    147

    148

    P2.102508.014717

    P2.102508.015339

    P2.102508.020005

    P2.102508.020625

    P2.102508.021251

    P2.102508.021914

    P2.102508.022529

    P2.102508.023153

    P2.102508.023815

    P2.102508.024436

    P2.102508.025054

    P2.102508.025721

    P2.102508.030343

    P2.102508.030958

    P2.102508.031528

    P2.102508.032154

    P2.102508.032814

    P2.102508.033440

    P2.102508.034106

    P2.102508.034725

    P2.102508.035350

    P2.102508.040011

    P2.102508.040630

    P2.102508.041302

    P2.102508.041831

    P2.102508.042447

    P2.102508.043111

    P2.102508.043640

    P2.102508.044305

    P2.102508.044827

    P2.102508.045453

    P2.102508.050115

    P2.102508.050731

    P2.102508.051351

    P2.102508.051913

    P2.102508.052433

    P2.102508.052954

    L08100621-02

    L08100621-03

    L08100632-01

    WG285777-01

    WG285823-01

    WG285823-02

    WG285777-04

    WG286114-28

    WG286114-29

    WG285777-05

    L08100633-04

    L08100633-05

    L08100633-06

    L08100641-03

    L08100641-04

    L08100667-01

    L08100667-02

    L08100667-03

    L08100667-04

    WG286114-30

    WG286114-31

    L08100667-05

    L08100667-06

    L08100667-07

    L08100440-01

    L08100440-02

    L08100440-09

    L08100440-13

    L08100440-14

    L08100440-16

    L08100440-17

    WG286114-32

    WG286114-33

    WG286114-34

    WG286114-35

    WG286114-36

    WG286114-37

    6279

    6280

    6518

    Reference Sample

    Post Digestion Spike

    Serial Dilution

    Matrix Spike

    CCV

    CCB

    Matrix Spike Duplica

    C-23-MWDM003 (102108)

    EB001 (102108)

    FB002 (102108)

    LH18/24-SP140-7116-GRAB

    LH18/24-SP140-7116-GRAB

    MW118-102008

    MW114-102008

    MW116-102108

    MW116-102108-QA

    CCV

    CCB

    29WW10-102108

    29WW19-102108

    29WW25-102108

    CRP 3051

    CRP 3043

    CRP 3046

    CRP 3045

    CRP 3044

    CRP 3048

    CRP 3041

    CCV

    CCB

    Interference Check

    Interference Check

    CCV

    CCB

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    1

    1

    1

    1

    1

    5

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    100

    5

    5

    10

    5

    5

    100

    1

    1

    1

    1

    1

    1

    WG285782-01

    L08100633-01

    L08100633-01

    L08100633-01

    L08100633-01

    L08100633-01

    10/25/08 01:47

    10/25/08 01:53

    10/25/08 02:00

    10/25/08 02:06

    10/25/08 02:12

    10/25/08 02:19

    10/25/08 02:25

    10/25/08 02:31

    10/25/08 02:38

    10/25/08 02:44

    10/25/08 02:50

    10/25/08 02:57

    10/25/08 03:03

    10/25/08 03:09

    10/25/08 03:15

    10/25/08 03:21

    10/25/08 03:28

    10/25/08 03:34

    10/25/08 03:41

    10/25/08 03:47

    10/25/08 03:53

    10/25/08 04:00

    10/25/08 04:06

    10/25/08 04:13

    10/25/08 04:18

    10/25/08 04:24

    10/25/08 04:31

    10/25/08 04:36

    10/25/08 04:43

    10/25/08 04:48

    10/25/08 04:54

    10/25/08 05:01

    10/25/08 05:07

    10/25/08 05:13

    10/25/08 05:19

    10/25/08 05:24

    10/25/08 05:29

    Seq. File ID Sample ID Prep Dil Reference Date/Time

    Comments:

    Maintenance Log ID: 286114

    56

    00096743

  • Instrument Run Log

    Run Log ID: 24931

    Page: 1 Approved: October 30, 2008

    Microbac Laboratories Inc.

    Instrument:

    Analyst1:

    Method:

    Dataset:

    Analyst2:

    SOP: Rev:

    PE-ICP2

    JYH

    6010B

    102808HR3.CSV

    ED

    ME600E 8

    Calibration Std:

    ICSA:

    ICV/CCV Std:

    ICSAB:

    Post Spike:

    Workgroups:

    STD29127

    STD29188

    STD29409

    STD29411

    STD27612

    285632,285641,285645,285628,285823,285957,286235,285127

    1

    2

    3

    4

    5

    6

    7

    8

    9

    10

    11

    12

    13

    14

    15

    16

    17

    18

    19

    20

    21

    22

    23

    24

    25

    26

    27

    28

    29

    30

    31

    32

    33

    34

    35

    36

    37

    P2.102808.080954

    P2.102808.081608

    P2.102808.082223

    P2.102808.082838

    P2.102808.083454

    P2.102808.084020

    P2.102808.084639

    P2.102808.085255

    P2.102808.085814

    P2.102808.090335

    P2.102808.090953

    P2.102808.092411

    P2.102808.092929

    P2.102808.093758

    P2.102808.094316

    P2.102808.094840

    P2.102808.095407

    P2.102808.100024

    P2.102808.101749

    P2.102808.102406

    P2.102808.103027

    P2.102808.103648

    P2.102808.105543

    P2.102808.110202

    P2.102808.110818

    P2.102808.111437

    P2.102808.112049

    P2.102808.112713

    P2.102808.113337

    P2.102808.113954

    P2.102808.114616

    P2.102808.115241

    P2.102808.115859

    P2.102808.120520

    P2.102808.121144

    P2.102808.121805

    P2.102808.122422

    WG286259-01

    WG286259-02

    WG286259-03

    WG286259-04

    WG286259-05

    WG286259-06

    WG286259-07

    WG286259-08

    WG286259-09

    WG286259-10

    WG286259-11

    L08100547-06

    L08100575-01

    L08100547-06

    WG286259-12

    WG286259-13

    WG286259-14

    WG286259-15

    L08100534-10

    L08100534-10

    WG286259-16

    WG286259-17

    WG286259-18

    WG286259-19

    L08100573-15

    L08100573-16

    L08100621-02

    L08100621-03

    L08100641-04

    L08100667-01

    L08100667-01

    L08100667-02

    L08100667-03

    L08100667-04

    WG286259-20

    WG286259-21

    L08100667-05

    Calibration Point

    Calibration Point

    Calibration Point

    Calibration Point

    Calibration Point

    Initial Calibration Verification

    Initial Calib Blank

    Interference Check

    Interference Check

    CCV

    CCB

    MW04D-GW-101508

    MW02D-GW-101708

    MW04D-GW-101508

    Interference Check

    Interference Check

    CCV

    CCB

    PZ01-101608

    PZ01-101608

    CCV

    CCB

    CCV

    CCB

    MAIN DISCHARGE-IS-5-MSD

    MAIN DISCHARGE-IS-5-DUP

    6279

    6280

    LH18/24-SP140-7116-GRAB

    MW118-102008

    MW118-102008

    MW114-102008

    MW116-102108

    MW116-102108-QA

    CCV

    CCB

    29WW10-102108

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    2

    5

    5

    1

    1

    1

    1

    10

    25

    1

    1

    1

    1

    1

    1

    5

    5

    5

    1

    5

    5

    1

    5

    1

    1

    1

    WG285526-08

    10/28/08 08:09

    10/28/08 08:16

    10/28/08 08:22

    10/28/08 08:28

    10/28/08 08:34

    10/28/08 08:40

    10/28/08 08:46

    10/28/08 08:52

    10/28/08 08:58

    10/28/08 09:03

    10/28/08 09:09

    10/28/08 09:24

    10/28/08 09:29

    10/28/08 09:37

    10/28/08 09:43

    10/28/08 09:48

    10/28/08 09:54

    10/28/08 10:00

    10/28/08 10:17

    10/28/08 10:24

    10/28/08 10:30

    10/28/08 10:36

    10/28/08 10:55

    10/28/08 11:02

    10/28/08 11:08

    10/28/08 11:14

    10/28/08 11:20

    10/28/08 11:27

    10/28/08 11:33

    10/28/08 11:39

    10/28/08 11:46

    10/28/08 11:52

    10/28/08 11:58

    10/28/08 12:05

    10/28/08 12:11

    10/28/08 12:18

    10/28/08 12:24

    Seq. File ID Sample ID Prep Dil Reference Date/Time

    285955,286255,285817Comments:

    Maintenance Log ID: 26352

    57

    00096744

  • Instrument Run Log

    Run Log ID: 24931

    Page: 2 Approved: October 30, 2008

    Microbac Laboratories Inc.

    Instrument:

    Analyst1:

    Method:

    Dataset:

    Analyst2:

    SOP: Rev:

    PE-ICP2

    JYH

    6010B

    102808HR3.CSV

    ED

    ME600E 8

    Calibration Std:

    ICSA:

    ICV/CCV Std:

    ICSAB:

    Post Spike:

    Workgroups:

    STD29127

    STD29188

    STD29409

    STD29411

    STD27612

    285632,285641,285645,285628,285823,285957,286235,285127

    38

    39

    40

    41

    42

    43

    44

    45

    46

    47

    48

    49

    50

    51

    52

    53

    54

    55

    56

    57

    58

    59

    60

    61

    62

    63

    64

    65

    66

    67

    68

    69

    70

    71

    72

    73

    74

    P2.102808.123044

    P2.102808.123701

    P2.102808.124328

    P2.102808.124953

    P2.102808.125607

    P2.102808.130234

    P2.102808.130853

    P2.102808.133447

    P2.102808.134113

    P2.102808.134729

    P2.102808.135347

    P2.102808.140002

    P2.102808.140624

    P2.102808.141248

    P2.102808.141901

    P2.102808.142525

    P2.102808.143143

    P2.102808.143756

    P2.102808.144410

    P2.102808.145021

    P2.102808.145652

    P2.102808.150317

    P2.102808.150941

    P2.102808.151553

    P2.102808.152701

    P2.102808.153322

    P2.102808.153944

    P2.102808.154609

    P2.102808.155221

    P2.102808.155841

    P2.102808.160502

    P2.102808.161115

    P2.102808.161741

    P2.102808.162403

    P2.102808.163019

    P2.102808.163638

    P2.102808.164256

    L08100667-05

    L08100667-06

    L08100667-06

    L08100667-07

    L08100696-04

    WG286259-22

    WG286259-23

    WG286259-24

    WG286259-25

    WG285513-02

    WG285513-03

    WG285513-01

    WG285628-01

    WG285628-02

    WG285513-04

    WG285513-05

    L08100580-16

    WG286259-26

    WG286259-27

    L08100641-04

    L08100667-01

    L08100667-02

    L08100667-05

    L08100667-06

    WG285522-03

    WG286259-28

    WG286259-29

    L08100667-07

    L08100696-04

    L08100521-33

    L08100521-34

    L08100521-36

    WG286259-30

    WG286259-31

    L08100521-37

    L08100521-38

    L08100521-39

    29WW10-102108

    29WW19-102108

    29WW19-102108

    29WW25-102108

    OUTFALL 003/COMP

    CCV

    CCB

    CCV

    CCB

    Method/Prep Blank

    Laboratory Control S

    Reference Sample

    Post Digestion Spike

    Serial Dilution

    Matrix Spike

    Matrix Spike Duplica

    EBGS.1015

    CCV

    CCB

    LH18/24-SP140-7116-GRAB

    MW118-102008

    MW114-102008

    29WW10-102108

    29WW19-102108

    Method/Prep Blank

    CCV

    CCB

    29WW25-102108

    OUTFALL 003/COMP

    SPE-G-MW-58

    SPE-G-MW-58-DIS

    SPE-G-MW-60-DIS

    CCV

    CCB

    SPE-K-FB-1

    SPE-K-FB-2

    SPE-K-FB-2-DIS

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    5

    1

    5

    5

    10

    1

    1

    1

    1

    1

    1

    10

    10

    50

    10

    10

    1

    1

    1

    10

    10

    10

    10

    10

    1

    1

    1

    10

    20

    10

    10

    10

    1

    1

    10

    10

    10

    L08100521-35

    L08100521-35

    L08100521-35

    L08100521-35

    L08100521-35

    10/28/08 12:30

    10/28/08 12:37

    10/28/08 12:43

    10/28/08 12:49

    10/28/08 12:56

    10/28/08 13:02

    10/28/08 13:08

    10/28/08 13:34

    10/28/08 13:41

    10/28/08 13:47

    10/28/08 13:53

    10/28/08 14:00

    10/28/08 14:06

    10/28/08 14:12

    10/28/08 14:19

    10/28/08 14:25

    10/28/08 14:31

    10/28/08 14:37

    10/28/08 14:44

    10/28/08 14:50

    10/28/08 14:56

    10/28/08 15:03

    10/28/08 15:09

    10/28/08 15:15

    10/28/08 15:27

    10/28/08 15:33

    10/28/08 15:39

    10/28/08 15:46

    10/28/08 15:52

    10/28/08 15:58

    10/28/08 16:05

    10/28/08 16:11

    10/28/08 16:17

    10/28/08 16:24

    10/28/08 16:30

    10/28/08 16:36

    10/28/08 16:42

    Seq. File ID Sample ID Prep Dil Reference Date/Time

    285955,286255,285817Comments:

    Maintenance Log ID: 26352

    58

    00096745

  • Instrument Run Log

    Run Log ID: 24931

    Page: 3 Approved: October 30, 2008

    Microbac Laboratories Inc.

    Instrument:

    Analyst1:

    Method:

    Dataset:

    Analyst2:

    SOP: Rev:

    PE-ICP2

    JYH

    6010B

    102808HR3.CSV

    ED

    ME600E 8

    Calibration Std:

    ICSA:

    ICV/CCV Std:

    ICSAB:

    Post Spike:

    Workgroups:

    STD29127

    STD29188

    STD29409

    STD29411

    STD27612

    285632,285641,285645,285628,285823,285957,286235,285127

    75

    76

    77

    78

    79

    80

    81

    82

    83

    84

    85

    86

    87

    88

    89

    90

    91

    92

    93

    94

    95

    96

    97

    98

    99

    100

    101

    102

    103

    104

    105

    106

    107

    108

    109

    110

    111

    P2.102808.164910

    P2.102808.165530

    P2.102808.170236

    P2.102808.170850

    P2.102808.171510

    P2.102808.172131

    P2.102808.172744

    P2.102808.173403

    P2.102808.174022

    P2.102808.174637

    P2.102808.175256

    P2.102808.175917

    P2.102808.180531

    P2.102808.181151

    P2.102808.181812

    P2.102808.182426

    P2.102808.183047

    P2.102808.183707

    P2.102808.184320

    P2.102808.184943

    P2.102808.185604

    P2.102808.190220

    P2.102808.190839

    P2.102808.191500

    P2.102808.192114

    P2.102808.192734

    P2.102808.193357

    P2.102808.194012

    P2.102808.194635

    P2.102808.195256

    P2.102808.195909

    P2.102808.200530

    P2.102808.201149

    P2.102808.201805

    P2.102808.202424

    P2.102808.203045

    P2.102808.203701

    L08100560-10

    L08100560-35

    L08100560-54

    L08100561-36

    L08100562-06

    L08100562-24

    L08100577-54

    WG286259-32

    WG286259-33

    L08100578-19

    L08100579-01

    L08100579-27

    L08100579-41

    WG286025-02

    WG286025-03

    L08100677-20

    L08100678-14

    L08100680-07

    L08100680-19

    WG286259-34

    WG286259-35

    WG286025-01

    WG286235-01

    WG286235-02

    WG286025-04

    WG286025-05

    L08100712-01

    L08100724-11

    L08100724-31

    L08100725-11

    L08100729-05

    WG286259-36

    WG286259-37

    L08100738-09

    WG285077-02

    WG285077-03

    L08100439-01

    10144-W0002

    10556-W0003

    10569-W0004

    10581-W0005

    10586-W0006

    10592-W0007

    10101-W0002

    CCV

    CCB

    10212-W0003

    10231-W0004

    10268-W0005

    10286-W0006

    Method/Prep Blank

    Laboratory Control S

    865-W0001

    901-W0001

    905-W0001

    962-W0001

    CCV

    CCB

    Reference Sample

    Post Digestion Spike

    Serial Dilution

    Matrix Spike

    Matrix Spike Duplica

    SE-3037P

    2556-W0001

    2626-W0002

    2509-W0003

    2567-W0004

    CCV

    CCB

    2654-W0005

    Method/Prep Blank

    Laboratory Control S

    OW-103

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    50/50

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    5

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    1

    L08100710-01

    L08100710-01

    L08100710-01