magnetoresistance and spin-transfer torque in magnetic ... › r6 › scv › mag › mtgsum ›...
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S. Yuasa
Magnetoresistance and spin-transfer torque
in magnetic tunnel junctions
IEEE Distinguished Lecturer 2012
E-mail: [email protected]
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Toshiba Corp. (H. Yoda) (STT-MRAM)
Osaka University (Y. Suzuki) (rf & high-speed experiments)
Collaborations
Canon Anelva Corp. (sputtering deposition process)
CNRS/Thales (A.Fert, V.Cros, J.Grollier) (spin-torque oscillator)
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Outline
(1) Spintronics
(2) Tunnel magnetoresistance (TMR)
・Magnetoresistance
・Tunnel magnetoresistancein magnetic tunnel junction(MTJ)
・Giant TMR in MgO-based MTJ
・CoFeB/MgO/CoFeB structure for device applications
(3) Spin-transfer torque (STT)
・Physics of spin-transfer torque
・Spin-transfer torque MRAM (STT-RAM or Spin-RAM)
・Microwave applications
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SpintronicsBoth charge and spin of electrons are utilized for
new functions.
Electronics・power amplification・logic operation basically volatile
Transistor, LSI
Magnetics・magnetic recording
non-volatile
Hard Disk Drive (HDD)
Electron
Electric Charge -e Spin (a small magnet)
N
S
What is spintronics ?
TMR & STT
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-e
N
S
SpintronicsCoupling between charge and spin by quantum mechanical effects (e.g. tunnel magnetoresistance, spin-transfer torque)
Highly efficient !
Magnetics Coupling between charge and spin by induction coilMost of the energy is wasted.
Difference between conventional magnetics and spintronics ?
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Outline
(1) Spintronics
(2) Tunnel magnetoresistance (TMR)
・Magnetoresistance
・Tunnel magnetoresistancein magnetic tunnel junction(MTJ)
・Giant TMR in MgO-based MTJ
・CoFeB/MgO/CoFeB structure for device applications
(3) Spin-transfer torque (STT)
・Physics of spin-transfer torque
・Spin-transfer torque MRAM (STT-RAM or Spin-RAM)
・Microwave applications
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Change in electric resistance induced by magnetic field.
Res
ista
nce,
R
Magnetic field, H 0
Magnetic field Hrequired to induce MR
Magneto-resistance ratio(MR ratio)
MR ratio at RT & a low H (~1 mT) is important for device applications.
Magneto-Resistance (MR)
MR converts magnetic signals into electric signals.(cf. STT converts electric signals into magnetic signals.)
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Year
1995
2000
2005
2010
Magnetoresistance MR ratio @ RT& low H
1857
1985
1990
AMR effect MR = 1 - 2% Lord Kelvin
GMR effectMR = 5 - 15%
A. Fert, P. Grünberg (Nobel Prize 2007)
T. Miyazaki, J. Moodera TMR effect
(Al-O barrier)MR = 20 - 70%
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Outline
(1) Spintronics
(2) Tunnel magnetoresistance (TMR)
・Magnetoresistance
・Tunnel magnetoresistancein magnetic tunnel junction(MTJ)
・Giant TMR in MgO-based MTJ
・CoFeB/MgO/CoFeB structure for device applications
(3) Spin-transfer torque (STT)
・Physics of spin-transfer torque
・Spin-transfer torque MRAM (STT-RAM or Spin-RAM)
・Microwave applications
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Insulator (nm –thick)(tunnel barrier)
Ferromagnetic electrode
Resistance RP : low
MR ratio (RAP – RP) / RP×100% (performance index)
Ferromagnetic electrode
Tunnel MagnetoResistance(TMR) effect in magnetic tunnel junction (MTJ)
ee ee
Parallel (P) state
Resistance RAP : high
Antiparallel (AP) state
ee
3d ferromagnet
3d ferromagnetAmorphous Al-O MR ratios of 20 – 70% at RT
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Recording media
Read head (magnetic sensor)
Magnetic field signal
Sense current
Head Medium
GMRヘッドの出現
0.01
0.1
1
10
100
1000
■■
■
■
■ ■
■■
■■■■ ■■
■■
■
■
■
■ ■
■■
■■■■ ■■
AMR GMR TMR
■■
1990 1992 1994 1996 1998 2000 2002 2004 2006 20081990 1992 1994 1996 1998 2000 2002 2004 2006 2008Year
GMR head
■
TMR head (amorphous tunnel barrier)
■■■
Reco
rdin
g de
nsity
(G
bit/
in2 )
Higher MR ratiois required for
> 200 Gbit/inch2.
Read head of hard disk drive (HDD)
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Read out Writing
Review: Science 294, 1488 (2001).
Non-volatile Magnetoresistive Random Access Memory (MRAM)
MTJBit line
Digit line
n+ p n+
CMOS
Write line MTJ
Digit line
CMOS
Bit line
or Parallel : “0”
Antiparallel:“1”
Non-volatile magnetic memory
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<Advantages> Non-volatile, high speed, write endurance > 1016
<Disadvantage> High-density MRAM is difficult to develop.
Non-volatile Magnetoresistive Random Access Memory (MRAM)
Freescale (US)’s 4 Mbit – MRAM based on Al-O MTJs (volume production since 2006)
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Density (bit /chip)
PRAM
1 Mbit 1 Gbit
1
10
100
1000
Acc
ess
spee
d (n
sec)
FeRAM
Write endurance > 1016
(virtually unlimited)
1 Tbit
Write endurance <1012
Non-volatile
Volatile
Storage
Work memory SRAM
DRAMMRAM
NOR
NAND
HDD
Three important properties for memory device:speed, density, and write endurance
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Density (bit /chip)
PRAM
1 Mbit 1 Gbit
1
10
100
1000
Acc
ess
spee
d (n
sec)
FeRAM
Write endurance > 1016
(virtually unlimited)
1 Tbit
Write endurance <1012
Non-volatile
Volatile
Storage
Work memory SRAM
DRAMMRAM
NOR
NAND
HDD
Three important properties for memory device:speed, density, and write endurance
Gbit-scale MRAM
High-speed MRAM
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How can we develop Gbit-scale MRAM ?
Cap
acity
(bi
t)
・Large output voltageMR ratio >> 100%・Reduction of writing power spin-torque switching
Major requirement for Gbit-MRAM
MRAM
DRAM
Year
Capacity of MRAM cannot go beyond 64 Mbit.
2000 2002 2004 2006 2008
1 K
1 M
1 G
Breakthrough
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Year
1995
2000
2005
2010
1857
1985
1990
MR effects MR ratio (RT & low H)
Device applications
MR head
GMR head
TMR head
HDD head
Inductivehead
MRAM
Memory
Much higher MR ratio is required for next-generation devices.
AMR effect MR = 1 ~ 2 %
TMR effect(Al-O barrier)
MR = 20 ~ 70 %
GMR effectMR = 5 ~ 15 %
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Simple model for TMR effect : Julliere’s model
Spin Polarization, P
TunnelBarrierFM 1
e
FM 2
e
TunnelBarrierFM 1 FM 2
D1D1
DOS
D2 D2
DOS
EF EF
D1 D1
DOS
D2 D2
DOS
EF EF
P alignment AP alignment
≡21 , ↑ ↓
↑ ↓, 1,2
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How can we attain giant MR ratio ?
(1) Electrode material with full spin-polarization |P | = 1
“Half Metal”
(E.g.) some Heusler alloys, Fe3O4, CrO2, LaSrMnO3 perovskite
EF
Energy
Room-temperature MR ratios for half-metal electrodes have never exceeded those for simple 3d alloys such as Co-Fe.
(2) Crystalline tunnel barrier such as MgO(001)
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Outline
(1) Spintronics
(2) Tunnel magnetoresistance (TMR)
・Magnetoresistance
・Tunnel magnetoresistancein magnetic tunnel junction(MTJ)
・Giant TMR in MgO-based MTJ
・CoFeB/MgO/CoFeB structure for device applications
(3) Spin-transfer torque (STT)
・Physics of spin-transfer torque
・Spin-transfer torque MRAM (STT-RAM or Spin-RAM)
・Microwave applications
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Incoherent tunneling ofvarious Bloch states.
MR < 100% at RT MR >> 1000% (theory)
Fe(001)2 5
Amorphous Al-O
1
Amorphous Al-O barrier (conventional MTJ) Crystal MgO(001) barrier
Amorphous Al-O barrier vs. crystal MgO barrier (theory)
Butler et al. PRB 2001; Mathon ibid 2001.
Fe(001)
Fe(001)
2 51
1
MgO(001) 1
Dominant tunneling of fully spin-polarized 1 Bloch states
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What we learn about “tunneling effect” at an undergraduate course
Barrier height
Barrier width, t
Tunnel barrier
Electrode Electrode
EF
Free-electron wave exp( i k·z )
Potential barrier is assumed to be vacuum.
Exponential decay of DOS
Tunneling transmittance (T) decays exponentially as a function of t.
m: effective mass (WKB approx.) )/8exp( 2 tmT ×
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Realistic tunneling effect
Both Bloch states and evanescent states have (i) specific orbital symmetry & (ii) specific band dispersion.
(complex wave vector k =kr + i )
Bloch states and evanescent states couple at interface.
Barrier Electrode
EFBand gap
Conduction band
Evanescent states in the band gap
Bloch states
Valence band
Electrode
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1 (spd)
5 (pd)
2’ (d)
Fe FeMgO
Butler (2001).
Decay of evanescent state largely depends on orbital symmetry.
1 : s + pz + d 2z2 – x2 – y2
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MgO(001)
1
5
2’
1
5
2
Fe(001)
1
5
2
Fe(001)
Coupling between Bloch states and evanescent states
Ideal coherent tunneling for k// = 0 direction
k//
k
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Fully spin-polarized 1 band in bcc Fe(001)
Fully spin-polarized 1 bandGiant MR ratio is theoretically expected.
Not only bcc Fe but also many other bcc alloys based on Fe or Co have fully spin-polarized 1 band.
(e.g. bcc Fe1-xCox , some Heusler alloys)
minority spin
majority spin1
1.5
1.0
0.5
0.0
-0.5
E-E
F( e
V )
H
1
(001) direction
EF
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X.-G. Zhang, et al., PRB 68, 092402 (2003).
Ideal interface Oxidized interface
Fe- 1 states couple withMgO-1 states at k// .
Fe- 1 states do not couple with MgO-1 states at k// = 0.
LDOS of1 states
MR ratio > 1000% MR ratio < 100%
k//
k
ExcessO atom
Importance of interface (theory)
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Fully epitaxial Fe/MgO/Fe MTJ grown by MBE
Fe(001)(Pinned layer)
MgO(001)
Fe(001)(Free layer)
TEM image2 nm
Yuasa et al., Nature Mater. 3, 868 (2004).
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Experimental demonstrations of giant TMR
Yuasa et al., Nature Mater. 3, 868 (2004).
MR = 247%
MR = 180%
-200 -100 0 100 2000
100
200
300
T = 20 K
T = 293 K
MR
ratio
(%)
H ( Oe) -1000 -500 0
H ( Oe) 0
2040
6080
100120140160180
MR
ratio
(%)
Parkin (IBM), Nature Mater. 3, 862 (2004).
Single-crystal MgO(001) barrier Textured MgO(001) barrier
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1995 2000 2005
MR
ratio
at R
T (%
)
Year0
100
200
300
400
500
600
[1] Yuasa, Jpn.J.Appl.Phys.43,L558 (2004). [2] Yuasa, Nature Mater.3, 868 (2004).[3] Parkin, Nature Mater.3, 862 (2004).
Amorphous Al-O tunnel barrier
AIST [1]
AIST [2]IBM [3]
Crystal MgO(001) tunnel barrier
“Giant TMR effect”
Fe(001)MgO(001)
Fully epitaxialMTJ
Textured MTJFeCo(001)MgO(001)
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Fundamental problem on thin film growth
MgO(001) cannot be grown on fcc (111).4-fold symmetry 3-fold symmetry
Ru
Tunnel barrier
Free layer
Pinned layer
FM (Co-Fe)
AF layer (Pt-Mn or Ir-Mn)for exchange biasing
This structure is based on fcc (111).
or
MTJ structure for practical applications
MTJ
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1995 2000 20050
100
200
300
400
500
600
Crystal MgO(001) barrier: Single crystal MgO(001): Poly-crystal MgO(001)
: CoFeB/MgO/CoFeB
AIST [1]
AIST [2]IBM [3]
AmorphousAl-O tunnel barrier
MR
ratio
at R
T (%
)
Year
Canon-Anelva& AIST [4]
Fe(001)MgO(001)
Fully epitaxialMTJ
Textured MTJFeCo(001)MgO(001)
[1] Yuasa, Jpn.J.Appl.Phys.43,L558 (2004). [2] Yuasa, Nature Mater.3, 868 (2004).[3] Parkin, Nature Mater.3, 862 (2004). [4] Djayaprawira, SY, APL 86,092502 (2005).
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Outline
(1) Spintronics
(2) Tunnel magnetoresistance (TMR)
・Magnetoresistance
・Tunnel magnetoresistancein magnetic tunnel junction(MTJ)
・Giant TMR in MgO-based MTJ
・CoFeB/MgO/CoFeB structure for device applications
(3) Spin-transfer torque (STT)
・Physics of spin-transfer torque
・Spin-transfer torque MRAM (STT-RAM or Spin-RAM)
・Microwave applications
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Amorphous CoFeB
Poly-crystal MgO(001)
1 nm Amorphous
CoFeB
As-grown state
Crystal-lization
Annealing above 250ºC
Canon-Anelva, AIST
After annealing
Poly-crystal bcc CoFeB(001)
Poly-crystal MgO(001)
Poly-crystal bcc CoFeB(001) 1 nm
CoFeB/MgO/CoFeB structure for device applications
Core technology for device applications Practical bottom
structure:fcc(111)(3-fold symmetry)
MgO-MTJ(4-foldsymmetry)
Djayaprawira, SY, Appl. Phys. Lett. 86, 092502 (2005). Yuasa & Djayaprawira, J. Phys. D: Appl. Phys. 40, R337 (2007).
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All the HDD manufacturers use this type of sputtering machine for the production of HDD magnetic heads.
Canon-Anelva C-7100 sputtering system
Load lock
RF
RF
Etching Oxidation
Sputtering
Load lock
DC
DC
Sputtering
Sputtering Sputtering
200– 300 mm wafer
Mass-manufacturing technology for HDD industry
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Year
1990
1995
2000
2005
2010
MR head
GMR head
HDD head
MgO-TMR head
Inductivehead
Industrial applications
MRAM
Memory
STT-RAM(Spin-RAM)
Novel devices
Microwave
AMR effect MR = 1 - 2 %
TMR effectAl-O barrier
MR = 20 - 70 %
Giant TMR effectMgO(001) barrierMR = 150 - 600 %
1857
GMR effectMR = 5 - 15 %
1985
TMR head
MR effects MR ratio (RT & low H)
: commercialized
: R & D level
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◆Volume production since 2007.
◆700 Gbit/ inch2 achieved (5 increase).
◆Applicable up to 1 – 2 Tbit / inch2.
◆World market of HDD: 25 billion USD head: 5 billion USD TEM image
MgO-TMR head
20 nm
Top lead
MgO MTJ
Bottom lead
MgO-TMR head for ultrahigh-density HDD
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Ultrathin CoFeB electrode can have perpendicular magnetization.
S. Ikeda, H. Ohno et al., Nature Mater. 9, 721 (2010).Since Djayaprawira, SY, et al.,
APL 86, 092502 (2005).
MgO barrier
CoFeB
CoFeB
0H (T)
M(T
)H planeH // plane
tCoFeB = 1.3 nm
1.5 nm
1.5 nm or
< 1.5 nm
< 1.5 nmor
In-plane magnetization Perpendicular magnetization
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Outline
(1) Spintronics
(2) Tunnel magnetoresistance (TMR)
・Magnetoresistance
・Tunnel magnetoresistancein magnetic tunnel junction(MTJ)
・Giant TMR in MgO-based MTJ
・CoFeB/MgO/CoFeB structure for device applications
(3) Spin-transfer torque (STT)
・Physics of spin-transfer torque
・Spin-transfer torque MRAM (STT-RAM or Spin-RAM)
・Microwave applications
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Spin-transfer torque in magnetic nano-pillar
NM spacer layer
FM2 Free layer
NM
FM1 (pinned layer) S1
S2
Local spin
Spin momentum transfer
I
Conduction electron
Spin-transfer torque
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21222222 ˆ)ˆˆ(ˆˆ ssssSsHSS eFTeSTeff II
Theory of spin-transfer torque
S1
Heff
S2Spin-transfer
torque
Precession
Damping
2s
J. Slonczewski, J. Magn. Magn. Mater. 159, L1 (1996). L. Berger, Phys. Rev. B 54, 9353 (1996).
Current IS1 S2
Pinned Free
Damping Spin-transferPrecession
When spin torque>damping torque, the precession angle is amplified, and the free-layer moment (S2) switches.
S2
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Outline
(1) Spintronics
(2) Tunnel magnetoresistance (TMR)
・Magnetoresistance
・Tunnel magnetoresistancein magnetic tunnel junction(MTJ)
・Giant TMR in MgO-based MTJ
・CoFeB/MgO/CoFeB structure for device applications
(3) Spin-transfer torque (STT)
・Physics of spin-transfer torque
・Spin-transfer torque MRAM (STT-RAM or Spin-RAM)
・Microwave applications
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Gbit-MRAM
0
0.1
0.2
0.3
10 100 1000
Writ
ing
pow
er
Cell size (nm)
Ipulse
Switching by field
Ideal for high-density MRAM cells
Switching current densityJC0 = 5105 A/cm2
is required for application.
Writing (magnetization switching) by spin-transfer torque
Not scalable !
Ipulse
Switching by Spin torque
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In-plane magnetization vs. Perpendicular magnetization
In-planemagnetization
Perpendicularmagnetization
<Materials>・CoFeB・Co-Fe・Ni-Fe
<Materials>・L10-ordered alloy (e.g. FePt)・Multilayer, superlattice・RE-TM alloy (e.g. Tb-Co) ・HCP alloy (e.g. Co-Cr)・ultrathin CoFeB
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2005 Sony (IEDM 2005)- in-plane MTJ cells- 4 kb
2007 Hitachi/Tohoku U. (ISSCC 2007)- in-plane MTJ cells- 2 Mb
2010 Toshiba (ISSCC 2010)- p-MTJ cells- 64 Mb, 65 nm
2008 Toshiba, AIST etc. (IEDM 2008)- p-MTJ cells- 1 kb
Development of Spin-RAM
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LL LL8PVD ・RT – 250ºC ・Co-sputtering from 3 targets.
8PVD・RT – 350ºC ・Co-sputtering from 3 targets.
4PVD
Plasma oxidation/
Etching
DC
RF
Canon-Anelva C-7100 sputtering system installed at AIST
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fcc(111) or hcp-cbuffer
fcc(111)-based superlattice film cf. conventional magnetic multilayer
with thick Pt(Pd) layers
Co (2-3 ML)
Pt(Pd) (6-8 ML)
Co (~1 ML)Pt(Pd) (~1 ML)
New perpendicular magnetic material : superlattice film
Yakushiji, SY et al., Appl. Phys. Express3, 053003 (2010). Yakushiji, SY et al., Appl. Phys. Lett., 97, 232508 (2010).
Ru buffer
Ru cap
[Co/Pt]6 CoPt
TEM HAADF-STEM
3 nm
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Superlatticefilm
Conventional multilayer film
Origin of perp. magnetic anisotroy
Thickness of total stack
Structure
Ku
Annealing stability
Ultra-thin( < 1.2 nm possible)
Relatively thick(> 3 nm)
Artifical alloy Mutilayer
Up to 12 Merg/cc(tunable) ~ 5 Merg/cc
Very good> 370ºC
Poor~ 200ºC
Magneto-crystalline anisotropy
Interfacial anisotropy
Magnetic superlattice vs. conventional multilayer
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Basic requirements for Gbit-scale Spin-RAM
(1) / kBT > 60–80 for cell size < 50 nm
(2) MR ratio > 100 – 150% and low RA product
(3) Switching current density, JC0 = 5105 A/cm2
(4) Switching speed < 20 ns to replace DRAM< 1 – 3 ns to replace SRAM
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Thermal stability of MTJ, = KuV/kBT
HDD 500 Gbit/inch2
TEM image of HDD media
> 80 for the grain size < 10 nm
7nm
CoPtCrO
Perpendicular magnetic recording
When cell size is smaller than 50 nm, the uniaxial shape anisotropy cannot yield > 60.
MTJ with in-plane magnetization is hopeless !
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(1) / kBT > 60–80 for cell size < 50 nm
(2) MR ratio > 100 – 150% and low RA product
(3) Switching current density, JC0 = 5105 A/cm2
(4) Switching speed < 20 ns to replace DRAM< 1 – 3 ns to replace SRAM
Basic requirements for Gbit-scale Spin-RAM
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◆MR > 100 – 150% is required to attain a high read-out signal (voltage) with a small read-out current.
MRA ratio and RA product required for Gbit Spin-RAM
◆Low RA is required to satisfy the impedance matching with the pass transistor (CMOS).
The MTJ resistance should be about 10 k.
5 Gbit (F = 30 nm) RA < 7 m2, MR > 100%RA < 7 m2, MR > 100%
10 Gbit (F = 20 nm) RA < 3.5 m2, MR > 100%RA < 3.5 m2, MR > 100%
1 Gbit (F = 65 nm) RA < 30 m2, MR > 100%RA < 30 m2, MR > 100%
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How to achieve high MR with perpendicular electrodes ?
<Issues>(i) The 1 band of perpendicular materials are not fully spin-polarized.
(ii) Lattice matching between perp. materials and MgO(001) is not good.
Insertion of CoFeB between MgO and PMA layer
MgO(001)
PMA material
・Lattice mismatch ・Band mismatch
PMA material
MgO(001)
PMA material
CoFe/CoFeB
CoFe/CoFeB
PMA material
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Typical structure of p-MgO-MTJ
TbFeCo
Co/Pt
CoFe/CoFeB
CoFeB/CoFeMgO
5 nm
Yakushiji, SY et al., Appl. Phys. Express3, 053003 (2010). Yakushiji, SY et al., Appl. Phys. Lett., 97, 232508 (2010).
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RA product (m2)
MR
rati
o (%
)
10 Gbit
The p-MTJs basically satisfy the requirements for10 Gbit Spin-RAM (RA < 3.5 m2, MR > 100%).
Can we simultaneously attain high MR & low RA ? – Yes !
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0.1 1 100
50
100
150
200M
R ra
tio a
t RT
(%)
RA ( ·m2 )
w/o in-situannealing of
MgO layer (APL 2006)
MR = 102% & RA = 0.9 ·m2
Nagamine, SY et al., Appl. Phys. Lett. 89, 162507 (2006). Maehara, SY et al., Appl. Phys. Express 4, 033002 (2011).
with in-situannealing of
MgO layer (APEX 2011)
MR = 175% & RA = 1.0 ·m2
The best properties attained with in-plane magnetization
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(1) / kBT > 60–80 for cell size < 50 nm
(2) MR ratio > 100 – 150% and low RA product
(3) Switching current density, JC0 = 5105 A/cm2
(4) Switching speed < 20 ns to replace DRAM< 1 – 3 ns to replace SRAM
Basic requirements for Gbit-scale Spin-RAM
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In-planeIn-plane PerpendicularPerpendicular
Easy
Axi
s
TkBtherm22e damp g
Ic =
E
Easy Axis
2e damp g
2222 tFMTk SBtherm Ic =
E
Potential barrier for magnetization switching
therm
STT
STT ~ 30therm
60kBT 60kBT
STTtherm
STT ~ therm
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Our latest data (Courtesy of Toshiba)
NEDO – Spintronics Non-Volatile Devices Project(Toshiba, AIST, etc.)
30 nm MgO-MTJ with perp. magnetization
0
50
100
150
200
250
MR
ratio
(%)
Magnetic field (a.u.)
MR ratio = 200% at RT
MgOElectrode
Electrode
30 nm Jc0 = 5105 A/cm2
= 45
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(1) / kBT > 60–80 for cell size < 50 nm
(2) MR ratio > 100 – 150% and low RA product
(3) Switching current density, JC0 = 5105 A/cm2
(4) Switching speed < 20 ns to replace DRAM< 1 – 3 ns to replace SRAM
Basic requirements for Gbit-scale Spin-RAM
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CMOS-integrated MTJ array
TEM image
-1 -0.5 0 0.5 1Voltage (V)
R (a
. u.)
4 nsec10 nsec30 nsec
0 10 20 30 40 50time (nsec)
Volta
ge (a
. u.)
4 nsec
10 nsec
30 nsec MTJ 50 nm
Write pulses
Spin-torque writing
Kishi, SY et al. IEDM 2008, 12.6.(Toshiba, AIST, etc.)
Demonstration of high-speed switching
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WRITE (Ic) <drive current of CMOS
READ (MR & RA) MR ratio > 100–150%& low RA
STABILITY for MTJ size < 50 nm
> 60 – 80
SPEED < 20 ns writing
ENDURANCE > 1016 write cycles
Perp.MTJ
In-planeMTJ
Summary on Spin-RAM
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Toshiba – Hynix alliance to commercialize Spin-RAM
http://www.toshiba.co.jp/about/press/2011_07/pr1302.htm
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Outline
(1) Spintronics
(2) Tunnel magnetoresistance (TMR)
・Magnetoresistance
・Tunnel magnetoresistancein magnetic tunnel junction(MTJ)
・Giant TMR in MgO-based MTJ
・CoFeB/MgO/CoFeB structure for device applications
(3) Spin-transfer torque (STT)
・Physics of spin-transfer torque
・Spin-transfer torque MRAM (STT-RAM or Spin-RAM)
・Microwave applications
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~100 nm
Steady-state precession induced by spin torque
NM
FM1 (pinned layer)
FM2 (free layer) Spin
torque Steady-state precession can be induced by adjusting I and H.
(ferromag. resonance (FMR) )
DC current & voltage
AC current & voltage(FMR frequency)
Spin torque
Giant MR ratio
MgO-MTJ is expected to act as a microwave oscillator and detector.
Steady-stateprecession
Microwave power (MR ratio)2
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Power: 2.4 WLine width: 12 MHzQ factor: 350
2 4 6 8 100
20
40
60
80
100
120
PS
D (
W/G
Hz)
Frequency (GHz)
Microwave functions of MgO-based MTJs
Tulapurkar, SY, Nature 438, 339 (2005).Kubota, SY et al., Nature Phys. 4, 37 (2008). Deac, SY et al., Nature Physic 4, 803-809 (2008). Dussaux, SY et al.,Nature Comm. 1, 8 (2010). H. Maehara, SY et al., MMM 2010.
Frequency (GHz)
dc v
olta
ge (
V)
Spin-torque diode effect(microwave detection)
Spin-torque oscillator (STO)(microwave emission)
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Ferromagnetic resonance No resonance circuit is necessary.
Large !
~1 cm
Small (100 nm), cheap, easily integrated in Silicon LSI
CoFeBMgOCoFeB
100 nm
MgO-MTJ-based STO
MMIC: Monolithic Microwave IC
Klystron
~10 cm
Gunn diodeoscillator
スピントルク発振器の特徴Advantages of STO over conventional microwave oscillators
MMIC: low efficiency
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Year
1990
1995
2000
2005
2010
MR head
GMR head
HDD head
MgO-TMR head
Inductivehead
Industrial applications
MRAM
Memory
STT-RAM(Spin-RAM)
Novel devices
Microwave
AMR effect MR = 1 - 2 %
TMR effectAl-O barrier
MR = 20 - 70 %
Giant TMR effectMgO(001) barrierMR = 150 - 600 %
1857
GMR effectMR = 5 - 15 %
1985
TMR head
MR effects MR ratio (RT & low H)
: commercialized
: R & D level