material safety data sheet 2001/58/ec … msds compl… · material safety data sheet 2001/58/ec...

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 01.06.04 A80 Page: 1/6

SDS-315/EN 1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: A80 Code: 51453 1.2 Use of the preparation: Bodywork repair polyester filler. 1.3Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) 2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 10-25 % Styrene R10 R20 R36/38 Xn CAS: 100-42-5

EC No. 202-851-5 SAX: SMQ000 No. 601-026-00-0

2,5-10 % Ethyl acetate R11 R36 R66 R67 F Xi CAS: 141-78-6 EC No. 205-500-4 SAX: EFR000 No. 607-022-00-5

For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Highly flammable. Harmful by inhalation. Irritating to eyes. Irritating to skin. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.3 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: In case of fire, use alcohol-resistant foam, dry chemical powder, carbon dioxide, AFFF. Do not use for extinguishing: direct water jet.


SDS-315/EN 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sewages, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Clean preferably with a detergent. Avoid use of solvents. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed. Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. Recommendations for the prevention of toxicological risks: Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Class B1. According to ITC MIE APQ-1, RD 379/2001. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 32ºC. 7.3 Incompatible materials: Keep away from oxidizing agents, from strongly alkaline and strongly acid materials. 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions.


SDS-315/EN 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC 8.1 Occupational Exposure Limits (TLV) AGCIH 2001

TWA STEL Year ppm mg/m3 ppm mg/m3

Styrene 20 85 40 170 A4 1997 Ethyl acetate 400 1440 1996 A4 - Non classified as carcinogenic in humans. 8.2 Ocupational exposure controls in accordance with Guideline 89/686/EEC:: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particles and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. Vapour density: 3.13 Air=1 at 20ºC Relative Lower explosive limit: 2.3 % Volume Ventilation requirement: 65 m3/l Air/Preparation to keep below 1/10 of the Lower Explosive Limit. 8.3 Protection of respiratory system: Avoid the inhalation of vapours. When operators, whether spraying or not, are inside the spraybooth, and ventilation is unlikely to be sufficient to constantly control particles and solvent vapour in all cases, in such circumstances they should wear a compressed air-fed respirator during the spraying process and until such a time as the particles and solvent vapour concentration has fallen below the exposure limits. Mask: Filter mask. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles designed to protect against liquid splashes. Face shield: No. 8.5 Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Personnel should wear antistatic clothing made of natural fibre or of high temperature resistant synthetic fibre. Wash contaminated work clothes before wearing them again. 9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Liquid - Colour: Grey - Odour: Characteristic - Viscosity: 1.9*105 cps 20ºC Brookfield - Specific gravity: 1.54 g/cc at 20ºC - Boiling point: 77.1ºC at 760 mmHg - Flash point: 12ºC Setaflash - Autoignition temperature: 471.5ºC - Vapour pressure: 26.7 mmHg at 20ºC 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents, acids, alkalis, peroxides.


SDS-315/EN 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced. 11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. 11.2 Dose and lethal concentrations for individual ingredients:

DL50 Oral DL50 Cutaneous CL50 Inhalation mg/kg mg/kg mg/l.4hours

Styrene 2650 Rat 12 Rat Ethyl acetate 5620 Rat 20000 Rabbit 200 Rat For more information about ingredients dangerous to health, see sections 2 and 8. *12. ECOLOGICAL INFORMATION No experimental ecotoxicological data on the preparation as such is available. 12.1 Spills on the soil: Prevent contamination of soil. 12.2 Spills in water: Do not allow to escape into drains, sewers or water courses. 12.3 Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - VOC: 191 g/l ASTM D-3960 - Aliphatic hydrocarbons: 0.2% Weight - Aromatic hydrocarbons: 22% Weight 12.4 Ecotoxicological data for individual ingredients: CL50 CE50 CI50

mg/l.96hours mg/l.48hours mg/l.72hours Styrene 255 Dafnia 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations.


SDS-315/EN 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. 14. TRANSPORT INFORMATION PAINTS (FP<23ºC, viscous according to 2.2.3.1.4, VP<110 kPa50ºC) 14.1 Land: Transport by road: ADR 2003 Transport by rail: RID Class: 3 Packaging group: III UN no. 1263 Transport document: Consignment paper Written instructions. 14.2 Sea: Transport by ship: IMDG 30-00 Class: 3 Packaging group: III UN no. 1263 Emergency Sheet (EmS): 3-05, 07 First Aid Guide (MFAG): 310, 313 Marine pollutant: No Transport document: Shipping Bill of lading 14.3 Air: Transport by plane: IATA/ICAO Class: 3 Packaging group: III UN no. 1263 Transport document: Air Bill of lading 15. INFORMATION ON REGULATIONS 15.1 EC Labelling F, Xn This product is HIGHLY FLAMMABLE and HARMFUL in accordance with Guideline 67/548/EEC - 2001/59/EC and 1999/45/EC - 2001/60/EC. R20 Harmful by inhalation. R36/38 Irritating to eyes and skin. S16 Keep away from sources of ignition – No smoking. S23 Do not breathe vapour/spray. S51 Use only in well-ventilated areas. Dangerous ingredients: Styrene 15.2 Type of packaging: According to current legislation. 16. OTHER INFORMATION Intended use: Only for professional use. Text of R-phrases listed in section 2: R10 Flammable. R11 Highly flammable. R20 Harmful by inhalation.


SDS-315/EN R36 Irritating to eyes. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. R36/38 Irritating to eyes and skin. Labelling regulations: The information provided in this Material Safety Data Sheet has been written in accordance with Guideline 67/548/EEC (Substances), 88/379/EEC (Preparations) and 91/155/EEC (Material Safety Data Sheet). It has been updated to Guideline 2001/59/EC (Substances), 2001/60/EC (Preparations) and 2001/58/EC (Material Safety Data Sheet). The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 10.12.02 AIRCOLOR ANTIGRAVILLA HS Page: 1/6

SDS-816/EN *1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: AIRCOLOR ANTIGRAVILLA HS GREY Code: 61435 AIRCOLOR ANTIGRAVILLA HS BLACK Code: 61436 1.2 Use of the preparation: Bodywork plastics treatment in aerosol. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia)

2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 25-50 % Toluene R11 R20 F Xn CAS: 108-88-3 EC No. 203-625-9 SAX: TGK750 No.601-021-00-3 For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Extremely flammable. Harmful by inhalation. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.3 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. In the case of skin reddening or rashes, contact a doctor immediately. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: In case of fire, alcohol-resistant foam, dry chemical powder, carbon dioxide. Do not use for extinguishing: direct water jet.


SDS-816/EN 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sews, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Clean preferably with a detergent. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. - Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. Pressurised container. Protect from sunlight and do not expose to temperatures exceeding 50º C. Do not pierce or burn aerosol even after use. Do not spray on a naked flame or any incandescent material. - Recommendations for the prevention of toxicological risks: Avoid applying the product directly to people, animals, plants or foodstuffs. Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. Class of store: According to current legislation. Maximum storage period: 12. months. Temperature interval: min: 5ºC, max: 35ºC. 7.3 Incompatible materials: Keep away from oxidizing agents, acids, alkalis. 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions.


SDS-816/EN 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC 8.1 Occupational Exposure Limits (TLV) AGCIH 2001 TWA STEL Year

ppm mg/m3 ppm mg/m3 Toluene 50 188 A4 Dermal 1996 A4 - Non classified as carcinogenic in humans. 8.2 Engineering measures: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particles and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. AIRCOLOR ANTIGRAVILLA HS BLACK - Ventilation requirement: 1736 m3/l (maximum) Air/Preparation to keep below the Occupational Exposure Limit of the product. Special ventilation is required. AIRCOLOR ANTIGRAVILLA HS GREY - Ventilation requirement: 1787 m3/l (maximum) Air/Preparation to keep below the Occupational Exposure Limit of the product. Special ventilation is required. 8.3 Protection of respiratory system: Avoid the inhalation of vapours. Mask: Filter mask. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles designed to protect against liquid splashes. Face shield: No. 8.5 Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Suitable work clothes which avoid contact with the product should be worn. 9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Aerosol - Colour: Black/Grey - Odour: Characteristic - Specific gravity: 0.94 g/cc at 20ºC (Grey) 0.92 g/cc at 20ºC (Black) - Flash point: -41ºC Setaflash - Autoignition temperature: 441ºC (Grey) 438ºC (Black) - Descomposition temperature: 350ºC 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents and acids. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced. 11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available.


SDS-816/EN 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. 11.2 Dose and lethal concentrations for individual ingredients:


Toluene 5000 Rat 12124 Rabbit 15 Rat For more information about ingredients dangerous to health, see sections 2 and 8. 12. ECOLOGICAL INFORMATION Prevent contamination of soil. Do not allow to escape into drains, sewers or water courses. Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - VOC: 604 g/l ASTM D-3960 (Grey) 602 g/l ASTM D-3960 (Black) - Aromatic hydrocarbons: 36 % Weight 12.1 Ecotoxicity: No experimental ecotoxicological data on the preparation as such is available. Ecotoxicological data for individual ingredients:

CL50 CE50 CI50 mg/l.96hours mg/l.48hours mg/l.72hours

Toluene 24 Fishes 12 Daphnia 400 Algae 12.2 Mobility: N/A 12.3 Persistence and degradability: In water: t ½ life= 2.9 - 5.7 hours (Toluene) In air: t ½ life= 3 hours - 1 day (Toluene) 12.4 Bioaccumulative potential: log Pow = 2 .6 (Toluene) N/A: Not available. 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. Ensure the container is completely empty before throwing it away.


SDS-816/EN 13.3 Procedures for neutralising or destroying the product: In accordance with local regulations. Do not incinerate closed containers. 14. TRANSPORT INFORMATION AEROSOLS 14.1 Land: Transport by road: ADR-2001

Transport by rail: RID/TPF Class: 2 Classification code: 5F UN nº1950

Transport document: Consignment paper Written instructions.

14.2 Sea: Transport by ship: IMDG

Class: 2 UN nº1950 Marine pollutant: no Packaging group: II Emergency Sheet (EmS): 2-13 First Aid Guide (MFAG): 620 Transport document: Shipping Bill of Lading

14.3 Air: Transport by plane: IATA/ICAO

Class: 2 UN nº1950 Packaging group: II Transport document: Air Bill of Lading

15. INFORMATION ON REGULATIONS 15.1 EC Labelling F+, Xn This product is extremely flammable and harmful in accordance with 67/548/EEC - 2001/59/EC and 1999/45/EC - 2001/60/EC directives. R20 Harmful by inhalation. S16 Keep away from sources of ignition- No smoking. S23 Do not breathe vapour/spray. S51 Use only in well-ventilated areas. Pressurised container. Protect from sunlight and do not expose to temperatures exceeding 50ºC. Do not pierce or burn aerosol even after use. Do not spray on a naked flame or any incandescent material. Dangerous ingredients: Toluene. 15.2 Type of packaging: According to current legislation. 16. OTHER INFORMATION Intended use Only for professional use. Text of R-phrases listed in section 2: R11 Highly flammable.


SDS-816/EN R20 Harmful by inhalation. Labelling regulations: The information provided in this Material Safety Data Sheet has been written in accordance with 67/548/EEC (Substances), 88/379/EEC (Preparations) and 91/155/EEC (Material Safety Data Sheet) directives. It has been updated to 2001/59/EC (Substances), 2001/60/EC (Preparations) and 2001/58/EC (Material Safety Data Sheet) directives. The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 18.02.04 AIRCOLOR BUMPER Page: 1/6

SDS-819/EN *1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: AIRCOLOR BUMPER BLACK Code: 51222 AIRCOLOR BUMPER GREY ANTHRACITE Code: 51223 1.2 Use of the preparation: Paint for automotive plastics in aerosol. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) *2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 25-50 % Dimethyl ether R12 F+ EC No. 204-065-8 CAS: 115-10-6 SAX: MJW500 No. 603-019-00-8 10-25 % n-butyl acetate R10 R66 R67 EC No. 204-658-1 CAS: 123-86-4 SAX: BPU750 No. 607-025-00-1 10-25 % Toluene R11 R20 F Xn EC No. 203-625-9 CAS: 108-88-3 SAX: TGK750 No. 601-021-00-3 2,5-10 % Ethyl acetate R11 R36 R66 R67 F Xi EC No. 205-500-4 CAS: 141-78-6 SAX: EFR000 No. 607-022-00-5 2,5-10 % Acetone R11 R36 R66 R67 F Xi EC No. 200-662-2 CAS: 67-64-1 SAX: ABC750 No. 606-001-00-8 < 2,5 % Xylene (mixture of isomers) R10 R38 R20/21 Xn EC No. 215-535-7 CAS: 1330-20-7 SAX: XGS000 No. 601-022-00-9 For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Extremely flammable. Vapours may cause drowsiness and dizziness. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person.


SDS-819/EN 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.3 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. *5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: In case of fire, alcohol-resistant foam, dry chemical powder, carbon dioxide, AFFF. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sews, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Avoid use of solvents. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. Pressurised container. Protect from sunlight and do not expose to temperature exceeding


SDS-819/EN 50ºC. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Recommendations for the prevention of toxicological risks: Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. Class of store: According to current legislation. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 35ºC. 7.3 Incompatible materials: Keep away from oxidizing agents, from strongly alkaline and strongly acid materials. 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions. *8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC 8.1 Occupational Exposure Limits (TLV) AGCIH 2001 TWA STEL Year ppm mg/m3 ppm mg/m3 Dimethyl ether 1000 1920 Recommended n-butyl acetate 150 713 200 950 1998 Toluene 50 188 A4 Dermal 1996 Ethyl acetate 400 1440 1996 Acetone 500 1188 750 1782 A4 1997 Xylene (mixture of isomers) 100 434 150 651 A4 1996 A4 - Non classified as carcinogenic in humans. 8.2 Engineering measures: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficent to maintain concentrations of particulates and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. 8.3 Protection of respiratory system: Avoid the inhalation of vapours. Mask: Filter mask. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Suitable safety goggles. Face shield: No. 8.5 Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Suitable work clothes which avoid contact with the product should be worn. Wash contaminated work clothes before wearing them again. *9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Aerosol - Odour: Characteristic - Colour: Black / Grey anthracite - Specific gravity: 0.92 g/cc at 20ºC - Flash point: -41ºC - Autoignition temperature: 398ºC - Decomposition temperature: 350ºC


SDS-819/EN 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents, acids, alkalis, peroxides. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced. *11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. 11.2 Dose and lethal concentrations for individual ingredients: DL50 Oral DL50 Cutaneous CL50 Inhalation mg/kg mg/kg mg/l.4hours n-butyl acetate 10768 Rat 17600 Rabbit 9.7 Rat Toluene 636 Rat 12124 Rabbit 49 Rat Ethyl acetate 5620 Rat 20000 Rabbit 200 Rat Acetone 5800 Rat 20000 Rabbit 100 Rat Xylene (mixture of isomers) 4300 Rat 1700 Rabbit 22 Rat For more information about ingredients dangerous to health, see sections 2 and 8. *12. ECOLOGICAL INFORMATION No experimental ecotoxicological data on the preparation as such is available. 12.1 Spills on the soil: Prevent contamination of soil. 12.2 Spills in water: Do not allow to escape into drains, sewers or water courses. 12.3 Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - COV: 634 g/l Black ASTM D-3960 636 g/l Grey anthracite ASTM D-3960 - Aromatic hydrocarbons: 14.3 % Weight 12.4 Ecotoxicological data for individual ingredients: CL50 CE50 CI50 mg/l.96hours mg/l.48hours mg/l.72hours Dimethyl ether 4000 Fishes 4000 Daphnia n-butyl acetate 18 Fishes Toluene 24 Fishes 12 Daphnia 400 Algae Acetone 2000 Fishes 12100 Daphnia Xylene (mixture of isomers) 75 Fishes 16 Daphnia


SDS-819/EN 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. Ensure the container is completely empty before throwing it away. 13.3 Procedures for neutralising or destroying the product: In accordance with local regulations. Do not incinerarate closed containers. *14. TRANSPORT INFORMATION AEROSOLS 14.1 Land: Transport by road: ADR-2003



14.2 Sea: Transport by ship: IMDG 30-00

Class: 2 UN nº1950 Marine pollutant: no Packaging group: II Emergency Sheet (EmS): 2-13 First Aid Guide (MFAG): 620* Transport document: Shipping Bill of Lading



*15. INFORMATION ON REGULATIONS 15.1 EC Labelling F+, Xn This product is EXTREMELY FLAMMABLE and HARMFUL in accordance with Guideline 67/548/EEC - 2001/59/EC and 1999/45/EC - 2001/60/EC. R20 Harmful by inhalation. R66 Repeated exposure may cause skin dryness or cracking. S16 Keep away from sources of ignition- No smoking. S23 Do not breathe vapor/spray. S51 Use only in well-ventilated areas. P96 Pressurized container. Protect from sunlight and do not expose to temperature exceeding 50ºC. Do not pierce or burn, even after use. P97 Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No smoking. Keep out of reach of children. Dangerous ingredients: None in a percentage equal to or higher than the limit for the name.


SDS-819/EN 15.2 Type of packaging: According to current legislation. *16. OTHER INFORMATION Intended use Only for professional use. Text of R-phrases listed in section 2: R10 Flammable. R11 Highly flammable. R12 Extremely flammable. R20 Harmful by inhalation. R36 Irritating to eyes. R38 Irritating to skin. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. R20/21 Harmful by inhalation and in contact with skin. Labelling regulations: The information provided in this Material Safety Data Sheet has been written in accordance with 67/548/EEC (Substances), 88/379/EEC (Preparations) and 91/155/EEC (Material Safety Data Sheet) directives. It has been updated to Guideline 2001/59/EC (Substances), 2001/60/EC (Preparations) and 2001/58/EC (Material Safety Data Sheet). The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 15.10.02 AIRCOLOR CAVITEX Página: 1/6

SDS-828/EN *1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: AIRCOLOR CAVITEX Code: 61440 1.2 Use of the preparation: Cavities wax in aerosol. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia)

2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 25-50 % Naphtha (oil), heavy hydrodesulfurized

R10 R65 R66 R67 R51/53 Xn N CAS: 64742-82-1 EC No. 265-185-4 No. 649-330-00-2 (Note P)

10-25 % n-butyl acetate R10 R66 R67 CAS: 123-86-4

EC No. 204-658-1 SAX: BPU750 No. 607-025-00-1

For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Extremely flammable. Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and dizziness. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.3 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest.


SDS-828/EN 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: Extinguishing powder or CO2. In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sewages, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Clean preferably with a detergent. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. - Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. Pressurised container. Protect from sunlight and do not expose to temperatures exceeding 50º C. Do not pierce or burn aerosol even after use. Do not spray on a naked flame or any incandescent material. - Recommendations for the prevention of toxicological risks: Avoid applying the product directly to people, animals, plants or foodstuffs. Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. Class of store: According to current legislation. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 35ºC. 7.3 Incompatible materials: Keep away from oxidizing agents, acids, alkalis, peroxides.


SDS-828/EN 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/CE 8.1 Occupational Exposure Limits (TLV) AGCIH 2001 TWA STEL Year

ppm mg/m3 ppm mg/m3 Naphtha (oil), heavy hydrodesulfurized 100 525 Internal value n-butyl acetate 150 713 200 950 1998 A4 - Non classified as carcinogenic in humans. 8.2 Engineering measures: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particles and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. Ventilation requirement: 403 m3/l (maximum) Air/Preparation to keep below the Occupational Exposure Limit of the product. 8.3 Protection of respiratory system: Avoid the inhalation of vapours. Mask: Filter mask. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Suitable safety goggles. Face shield: No. 8.5 Protection of hands and skin: Install emergency showers close to the working area. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Advisable. 9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Aerosol - Colour: White - Odour: Characteristic - Specific gravity: 0.79 g/cc at 20ºC - Flash point: -41 ºC Setaflash - Autoignition temperature: 322.6ºC 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents, acids, alkalis, peroxides. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced. 11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane


SDS-828/EN and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. 11.2 Dose and lethal concentrations for individual ingredients:


Naphtha (oil), heavy hydrodesulfurized 6000 Rat 3000 Rat 31 Rat n-butyl acetate 13100 Rat 5000 Rabbit 9.7 Rat For more information about ingredients dangerous to health, see sections 2 and 8. 12. ECOLOGICAL INFORMATION Prevent contamination of soil. Do not allow to escape into drains, sewers or water courses. Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - VOC: 586 g/l ASTM D-3960 - Aliphatic hydrocarbons: 21.2 % Weight - Aromatic hydrocarbons: 5.3 % Weight 12.1 Ecotoxicity: No experimental ecotoxicological data on the preparation as such is available. Ecotoxicological data for individual ingredients:


Naphtha (oil), heavy hydrodesulfurized 800 Fishes 100 Daphnia 450 Algae n-butyl acetate 18 Fishes 10 Daphnia 21 Algae 12.2 Mobility : N/A 12.3 Persistence and degradability: N/A 12.4 Bioaccumulative potential : log Pow = 3 - 6 estimated (Naphtha (oil), heavy hydrodesulfurized) log Pow = 1.82 (n-butyl acetate) BCF = 112 -159 (Naphtha (oil), heavy hydrodesulfurized) BCF = 14 (n-butyl acetate) N/A: Not available. 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. Ensure the container is completely empty before throwing it away.


SDS-828/EN 13.3 Procedures for neutralising or destroying the product: In accordance with local regulations. Do not incinerate closed containers. 14. TRANSPORT INFORMATION AEROSOL 14.1 Land: Transport by road: ADR-2001

Transport by rail: RID/TPF Class: 2 UN nº1950 Packaging group: II Transport document: Consignment paper Written instructions.

14.2 Sea: Transport by ship: IMDG Class: 2 UN nº1950 Marine pollutant: no Packaging group: II Emergency Sheet (EmS): 2-13 First Aid Guide (MFAG): 620 Transport document: Shipping Bill of Lading



15. INFORMATION ON REGULATIONS 15.1 EC Labelling F+, N This product is extremely flammable and dangerous for the environment in accordance with 67/548/EEC – 2001/59/EC and 1999/45/EC – 2001/60/EC directives. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic

environment. S16 Keep away from sources of ignition- No smoking. S23 Do not breathe vapour/spray. S29/56 Do not empty into drains, dispose of this material and its container to hazardous or

special waste collection point. S51 Use only in well-ventilated areas. Pressurised container. Protect from sunlight and do not expose to temperatures exceeding 50ºC. Do not pierce or burn aerosol even after use. Do not spray on a naked flame or any incandescent material. Dangerous ingredients: None in a percentage equal to or higher than the limit for the name. 15.2 Type of packaging: According to current legislation. 16. OTHER INFORMATION Intended use


SDS-828/EN Only for professional use. Text of R-phrases listed in section 2: R10 Flammable. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic

environment. Note P : It is unnecessary to apply the classification as carcinogenic if it can be proved that the substance contains less than 0.1% benzene (EC No. 200-753-7) in weight. Labelling regulations: The information provided in this Material Safety Data Sheet has been written in accordance wit 67/548/EEC (Substances), 88/379/EEC (Preparations) and 91/155/EEC (Material Safety Data Sheet) directives. It has been updated to 2001/59/EC (Substances), 2001/60/EC (Preparations) and 2001/58/EC (Material Safety Data Sheet) directives. The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

* MATERIAL SAFETY DATA SHEET 2001/58 /EC Revision date: 11.11.02 AIRCOLOR COBRE Page: 1/6

SDS-813/EN *1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: AIRCOLOR COBRE Code: 61441 1.2 Use of the preparation: Copper paint in aerosol. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia)

2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 25-50 % Toluene R11 R20 F Xn CAS: 108-88-3 EC No. 203-625-9 SAX: TGK750 No.601-021-00-3 10-25 % Butane R12 F+ CAS: 106-97-8

EC No. 203-448-7 SAX:BOR500 No.601-004-00-0

10-25 % Propane R12 F+ CAS: 74-98-6 EC No. 200-827-9 SAX: PMJ750 No.601-003-00-5

2.5-10 % Copper R20/22 Xn CAS: 7440-50-8 EC No. 231-159-6 SAX: CNI000

For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Extremely flammable. Harmful by inhalation. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.3 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. In the case of skin reddening or rashes, contact a doctor immediately.


SDS-813/EN 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: In case of fire, alcohol-resistant foam, dry chemical powder, carbon dioxide, sand. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sews, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Clean preferably with a detergent. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. - Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. Pressurised container. Protect from sunlight and do not expose to temperatures exceeding 50º C. Do not pierce or burn aerosol even after use. Do not spray on a naked flame or any incandescent material. - Recommendations for the prevention of toxicological risks: Avoid applying the product directly to people, animals, plants or foodstuffs. Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8.


SDS-813/EN 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. Class of store: According to current legislation. Maximum storage period: 12. months. Temperature interval: min:5ºC, max: 35ºC. 7.3 Incompatible materials: Keep away from oxidizing agents, acids, alkalis. 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/CE 8.1 Occupational Exposure Limits (TLV) AGCIH 2001 TWA STEL Year

ppm mg/m3 ppm mg/m3 Toluene 50 188 A4 Dermal 1996 Butane 800 1900 1981 Propane 2500 4508 Suffocating gas 1998 Copper 1.0 Powder and mist 1986 A4 - Non classified as carcinogenic in humans. 8.2 Engineering measures: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particles and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. Ventilation requirement: 1424 m3/l (maximum) Air/Preparation to keep below the Occupational Exposure Limit of the product. Special ventilation is required. 8.3 Protection of respiratory system: Avoid the inhalation of vapours. Mask: Filter mask. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles designed to protect against liquid splashes. Face shield: No. 8.5 Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Suitable work clothes which avoid contact with the product should be worn. 9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Aerosol - Colour: Copper - Odour: Characteristic. - Specific gravity: 0.84 g/cc at 20ºC - Flash point: -104ºC Setaflash - Autoignition temperature: 460ºC 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with water, oxidizing agents and acids.




Toluene 5000 Rat 12124 Rabbit 15 Rat Butane 1.6 Rat For more information about ingredients dangerous to health, see sections 2 and 8. 12. ECOLOGICAL INFORMATION Prevent contamination of soil. Do not allow to escape into drains, sewers or water courses. Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - VOC: 572 g/l ASTM D-3960 - Aliphatic hydrocarbons: 36.2 % Weight - Aromatic hydrocarbons: 31.9 % Weight 12.1 Ecotoxicity: No experimental ecotoxicological data on the preparation as such is available. Ecotoxicological data for individual ingredients:


Toluene 24 Fishes 12 Daphnia 400 Algae 12.2 Mobility : N/A 12.3 Persistence and degradability : In water : : t ½ life= 2.9 - 5.7 hours (Toluene) In air: t ½ life= 3 hours - 1 day (Toluene) 12.4 Bioaccumulative potential : log Pow = 2 .6 (Toluene) N/A: Not available. 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into


SDS-813/EN drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. Ensure the container is completely empty before throwing it away. 13.3 Procedures for neutralising or destroying the product: In accordance with local regulations. Do not incinerate closed containers. 14. TRANSPORT INFORMATION AEROSOLS 14.1 Land: Transport by road: ADR-2001







15. INFORMATION ON REGULATIONS 15.1 EC Labelling F+, Xn This product is extremely flammable and harmful in accordance with 67/548/EEC - 2001/59/EC and 1999/45/EC - 2001/60/EC directives. R20 Harmful by inhalation. S16 Keep away from sources of ignition- No smoking. S23 Do not breathe vapour/spray. S51 Use only in well-ventilated areas. Pressurised container. Protect from sunlight and do not expose to temperatures exceeding 50ºC. Do not pierce or burn aerosol even after use. Do not spray on a naked flame or any incandescent material. Dangerous ingredients: Toluene. 15.2 Type of packaging: According to current legislation. 16. OTHER INFORMATION Intended use


SDS-813/EN Only for professional use. Text of R-phrases listed in section 2: R11 Highly flammable. R12 Extremely flammable. R20 Harmful by inhalation. R20/22 Harmful by inhalation and if swallowed. Labelling regulations: The information provided in this Material Safety Data Sheet has been written in accordance with 67/548/EEC (Substances), 88/379/EEC (Preparations) and 91/155/EEC (Material Safety Data Sheet) directives. It has been updated to 2001/59/EC (Substances), 2001/60/EC (Preparations) and 2001/58/EC (Material Safety Data Sheet) directives. The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 12.02.03 AIRCOLOR CONTAC Page: 1/6

SDS-818/EN *1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: AIRCOLOR CONTAC Code: 61442 1.2 Use of the preparation: Generic glue. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia)

*2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 25-50 % Hexane (mixture of isomers) R11 R38 R65 R67 R51/53 F Xn N No. 601-007-00-7 10-25 % Cyclohexane R11 R38 R65 R67 R50/53 F Xn N CAS: 110-82-7 EC No. 203-806-2 SAX: CPB000 No. 601-017-00-1 2,5-10 % Butane R12 F+ CAS: 106-97-8 EC No. 203-448-7 SAX: BOR500 No. 601-004-00-0 For more information on dangerous ingredients, see sections 8, 11, 12 and 16. *3. IDENTIFICATION OF HAZARDS Extremely flammable. Irritating to skin. Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Vapours may cause drowsiness and dizziness. *4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.3 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners.


SDS-818/EN 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. *5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: Extinguishing powder or CO2. In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. *6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sewages, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Clean preferably with a detergent. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. *7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. - Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. Pressurised container. Protect from sunlight and do not expose to temperatures exceeding 50º C. Do not pierce or burn aerosol even after use. Do not spray on a naked flame or any incandescent material. -Recommendations for the prevention of toxicological risks: Avoid applying the product directly to people, animals, plants or foodstuffs. Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8.


SDS-818/EN - Recommendations for the prevention of environmental contamination: Product dangerous to the environment. Avoid any spillage in the environment. Pay special attention to the cleaning water. In the case of accidental spillage, follow the instructions indicated in section 6. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. Class of store: According to current legislation. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 35ºC. 7.3 Incompatible materials: Keep away from oxidizing agents. 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions. *8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/CE 8.1 Occupational Exposure Limits (TLV) AGCIH 2001 TWA STEL Year

ppm mg/m3 ppm mg/m3 Hexane (mixture of isomers) 500 1760 1000 3500 1982 Cyclohexane 300 1030 1987 Butane 800 1900 1981 8.2 Engineering measures: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particles and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. Ventilation requirement: 145 m3/l (maximum) Air/Preparation to keep below the Occupational Exposure Limit of the product. 8.3 Protection of respiratory system: Avoid the inhalation of vapours. Mask: Filter mask. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Suitable safety goggles. Face shield: No. 8.5 Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier cream should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Suitable work clothes which avoid contact with the product should be worn. *9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Aerosol - Colour: Light Yellow - Odour: Characteristic - Specific gravity: 0.832 g/cc at 20ºC - Flash point: -1ºC Setaflash - Autoignition temperature: 263.8ºC *10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents.


SDS-818/EN 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced. *11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. 11.2 Dose and lethal concentrations for individual ingredients:


Hexane (mixture of isomers) 28710 Rat Ciclohexane 12705 Rat Butane 1.6 Rat For more information about ingredients dangerous to health, see sections 2 and 8. *12. ECOLOGICAL INFORMATION Prevent contamination of soil. Toxic to aquatic organisms. May cause long-term adverse effects on the aquatic environment. Do not allow to escape into drains, sewers or water courses. Do not allow to escape into drains, sewers or water courses. Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - VOC : 457.5 g/l ASTM D-3960 - Aliphatic hydrocarbons : 55 % Weight 12.1 Ecotoxicity: No experimental ecotoxicological data on the preparation as such is available. Ecotoxicological data for individual ingredients: Not available 12.2 Mobility : N/A 12.3 Persistence and degradability: N/A 12.4 Bioaccumulative potential : N/A N A: Not available. *13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8.


SDS-818/EN 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. Ensure the container is completely empty before throwing it away. 13.3 Procedures for neutralising or destroying the product: In accordance with local regulations. Do not incinerate closed containers. *14. TRANSPORT INFORMATION AEROSOLS 14.1 Land: Transport by road: ADR-2001

Transport by rail: RID/TPF Class: 2 Classification code: 5F UN nº1950 Transport document: Consignment paper Written instructions.

14.2 Sea: Transport by ship: IMDG Class: 2 UN nº1950 Marine pollutant: no Packaging group: II Emergency Sheet (EmS): 2-13 First Aid Guide (MFAG): 620* Transport document: Shipping Bill of Lading



*15. INFORMATION ON REGULATIONS 15.1 EC Labelling F+, Xi, N This product is extremely flammable, irritant and dangerous for the environment in accordance with 67/548/EEC - 2001/59/EC and 1999/45/EC - 2001/60/EC directives. R38 Irritating to skin. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R67 Vapours may cause drowsiness and dizziness. S23 Do not breathe vapour/spray. S29/56 Do not empty into drains, dispose of this material and its container to hazardous or

special waste collection point. S51 Use only in well-ventilated areas. Pressurised container. Protect from sunlight and do not expose to temperatures exceeding 50ºC. Do not pierce or burn aerosol even after use. Do not spray on a naked flame or any incandescent material. Dangerous ingredients: None in a percentage equal to or higher than the limit for the name. 15.2 Type of packaging: According to current legislation.


SDS-818/EN *16. OTHER INFORMATION Intended use Only for professional use. Text of R-phrases listed in section 2: R11 Highly flammable. R12 Extremely flammable. R38 Irritating to skin. R65 Harmful: may cause lung damage if swallowed. R67 Vapours may cause drowsiness and dizziness. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic

environment. Labelling regulations: The information provided in this Material Safety Data Sheet has been written in accordance wit 67/548/EEC (Substances), 88/379/EEC (Preparations) and 91/155/EEC (Material Safety Data Sheet) directives. It has been updated to 2001/59/EC (Substances), 2001/60/EC (Preparations) and 2001/58/EC (Material Safety Data Sheet) directives. The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 21.12.05 AIRCOLOR GUIDEX Page: 1/6

SDS-820/EN 1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: AIRCOLOR GUIDEX Code: 61444 1.2 Use of the preparation: Black paint in aerosol. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) 2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health and/or environment hazard, and/or with a Communitary workplace exposure limit: 25-50 % Dimethyl ether EC: 204-065-8 F+; R12 CAS: 115-10-6 No. 603-019-00-8 10-25 % Isobutylmethylketone EC 203-550-1 F:R11 | Xn:R20 | Xi:R36/37 | R66 Index No. 606-004-00-4 CAS 108-10-1 10-25 % Ethyl acetate EC 205-500-4 F:R11 | Xi:R36 | R66-R67 Index No. 607-022-00-5 CAS 141-78-6 2,5-10 % Toluene EC 203-625-9 F:R11 | Repr.Cat.3:R63 | Xn:R48/20-65 | Xi:R38 | R67 Index No. 601-021-00-3 CAS 108-88-3 For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Extremely flammable. Possible risk of harm to the unborn child. Irritating to eyes. Irritating to respiratory system. Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and dizziness. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. 4.3 By contact with eyes: Remove contact lenses. Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately.


SDS-820/EN 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: In case of fire, use alcohol-resistant foam, dry chemical powder, carbon dioxide, AFFF. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous products may be produced: carbon monoxide, carbon dioxide, nitrogen oxides. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sews, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. - Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. Pressurised container. Protect from sunlight and do not expose to temperature exceeding 50ºC. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. - Flash point: -41ºC - Autoignition temperature: 170ºC - Flammability range: 2,8-15,2 % Volume 25ºC - Recommendations for the prevention of toxicological risks: Avoid applying the product directly to people, animals, plants or foodstuffs. Do not eat, drink or smoke while handling. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8.


SDS-820/EN 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. Class of store: According to current legislation. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 30ºC. - Incompatible materials: Keep away from oxidising agents, from strongly alkaline and strongly acid materials. - Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions. - Type of packaging: According to current legislation. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC 8.1 Occupational Exposure Limits (TLV) AGGIH 2004 TWA STEL Year ppm mg/m3 ppm mg/m3 Dimethyl ether 1000 1920 Recommended Isobutylmethylketone 50 205 75 307 1981 Ethyl acetate 400 1440 1996 Toluene 50 188 A4 Dermal 1996 8.2 Occupational exposure controls, Directive 89/686/EEC: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particulates and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. - Protection of respiratory system: Avoid the inhalation of solvents. Mask: Suitable combined filter mask for gases, vapours and particles (EN141/EN143). In order to obtain a suitable protection level, the filter class must be selected depending on the type and concentration of the contaminating agents present, in accordance with the specifications supplied by the filter producers. The respiratory equipment with filters does not work satisfactorily when the air contains high concentrations of vapour. - Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles with suitable lateral protection (EN166). Face shield: No. - Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Gloves resistant against chemicals (EN374). The gloves should be immediately replaced when any sign of degradation is noted. Boots: No. Apron: No. Clothing: Suitable work clothes which avoid contact with the product should be worn. 8.3 Environmental exposure controls: Avoid any spillage in the environment of the product, wastes, packages or spraybooth sewages. Avoid any release into the atmosphere above the legal limits allowed. 9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Aerosol - Colour: Black - Odour: Characteristic - Specific gravity: 0,83 g/cc at 20ºC - Flash point: -41ºC - Decomposition temperature: 80ºC


SDS-820/EN 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with reducing agents, oxidizing agents, acids, alkalis, amines. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced: nitrogen oxides. 11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. - Toxicity for reproduction: This preparation contains the following ingredients which can toxic for human reproduction: Toluene (cat.3). 11.2 Dose and lethal concentrations for individual ingredients: DL50 Oral DL50 Cutaneous CL50 Inhalation mg/kg mg/kg mg/l.4hours Isobutylmethylketone 2080 Rat 20000 Rabbit Ethyl acetate 5620 Rat 20000 Rabbit 200 Rat Toluene 636 Rat 12124 Rabbit 49 Rat For more information about ingredients dangerous to health, see sections 2 and 8. 12. ECOLOGICAL INFORMATION No experimental ecotoxicological data on the preparation as such is available. 12.1 Spills on the soil: Prevent contamination of soil. 12.2 Spills in water: Do not allow to escape into drains, sewers or water courses. 12.3 Emissions to the atmosphere: Avoid any release into the atmosphere. - VOC: 717 g/l ASTM D-3960 12.4 Ecotoxicological data for individual ingredients: CL50 CE50 CI50 mg/l.96hours mg/l.48hours mg/l.72hours Eter dimetílico 4000 Fishes 4000 Daphnia Toluene 24 Fishes 12 Daphnia 400 Algae 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste, Directive 75/442/EEC~91/156/EC: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current


SDS-820/EN local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers, Directive 94/62/EC: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. Ensure the container is completely empty before throwing it away. 13.3 Procedures for neutralising or destroying the product: In accordance with local regulations. Do not incinerate closed containers. 14. TRANSPORT INFORMATION AEROSOLS 14.1 Transport by road, Directive 94/55/EC (ADR 2005): Transport by rail, Directive 96/49/EC (RID 2005): Class: 2 Classification code: 5F UN nº1950


14.2 Transport by sea (IMDG 32-04):

Class: 2 UN nº1950 Marine pollutant: no Packaging group: - Emergency Sheet (EmS): F-D,S-U First Aid Guide (MFAG): 620* Transport document: Shipping Bill of Lading

14.3 Transport by air (ICAO/IATA):

Class: 2 UN nº1950 Packaging group: - Transport document: Air Bill of Lading

15. INFORMATION ON REGULATIONS 15.1 EC Labelling F+, Xn This product is EXTREMELY FLAMMABLE and HARMFUL in accordance with Directive 67/548/EEC - 2004/73/EC and 1999/45/EC - 2001/60/EC. R36/37 Irritating to eyes and respitatory system. R63 Possible risk of harm to the unborn child. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. S23 Do not breathe vapour, spray. S37 Wear suitable gloves. S51 Use only in well-ventilated areas. P96 Pressurised container. Protect from sunlight and do not expose to temperature exceeding 50ºC. Do not pierce or burn, even after use. P97 Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No smoking. Keep out of reach of children. - Dangerous ingredients: Toluene 15.2 Restrictions to the marketing and use in accordance with Directive 76/769/EEC: For professional users only. 15.3 Other regulations: It is applicable the Directive 75/324/EEC~94/1/EC, relating to aerosol dispensers and the Directive 87/404/EEC, concerning simple pressure packages.


SDS-820/EN 16. OTHER INFORMATION Text of R-phrases listed in section 2: R11 Highly flammable. R12 Extremely flammable. R20 Harmful by inhalation. R36 Irritating to eyes. R38 Irritating to skin. R63 Possible risk of harm to the unborn child. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. R36/37 Irritating to eyes and respitatory system. R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. Material Safety Data Sheet regulations: Material Safety Data Sheet in accordance with Directive 91/155/EEC~2001/58/EC. The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 23.09.04 AIRCOLOR ISOSPRAY - AIRCOLOR ISOFAST Page: 1/6

SDS-821/EN *1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: AIRCOLOR ISOSPRAY Code: 61446 AIRCOLOR ISOFAST Code: 61445 1.2 Use of the preparation: Bodywork nytrosynthetic base in aerosol. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) *2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 25-50 % Dimethyl ether R12 F+ EC No. 204-065-8

CAS: 115-10-6 SAX: MJW500

No. 603-019-00-8 10-25 % n-butyl acetate R10 R66 R67 EC No. 204-658-1 CAS: 123-86-4 SAX: BPU750 No. 607-025-00-1 2,5-10 % Ethyl acetate R11 R36 R66 R67 F Xi EC No. 205-500-4 CAS: 141-78-6 SAX: EFR000 No. 607-022-00-5 2,5-10 % Toluene R11 R20 F Xn EC No. 203-625-9

CAS: 108-88-3 SAX: TGK750

No. 601-021-00-3 2,5-10 % Xylene (mixture of isomers) R10 R38 R20/21 Xn EC No. 215-535-7 CAS: 1330-20-7 SAX: XGS000 No. 601-022-00-9 < 2,5 % Isopropyl alcohol R11 R36 R67 F Xi EC No. 200-661-7 CAS: 67-63-0 SAX: INJ000 No. 603-117-00-0 < 2,5 % Ethylbenzene R11 R20 F Xn EC No. 202-849-4 CAS: 100-41-4 SAX: EGP500 No. 601-023-00-4 For more information on dangerous ingredients, see sections 8, 11, 12 and 16. *3. IDENTIFICATION OF HAZARDS Extremely flammable. Vapours may cause drowsiness and dizziness. Repeated exposure may cause skin dryness or cracking.


SDS-821/EN *4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. 4.3 By contact with eyes: Remove contact lenses. Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: In case of fire, use alcohol-resistant foam, dry chemical powder, carbon dioxide, AFFF. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sews, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Avoid use of solvents. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. - Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other


SDS-821/EN sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. Pressurised container. Protect from sunlight and do not expose to temperature exceeding 50ºC. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. - Recommendations for the prevention of toxicological risks: Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. Class of store: According to current legislation. According to. ITC MIE APQ-1, RD 379/2001. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 30ºC. 7.3 Incompatible materials: Keep away from oxidizing agents, from strongly alkaline and strongly acid materials. 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions. *8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC 8.1 Occupational Exposure Limits (TLV) AGCIH 2002


Dimethyl ether 1000 1920 Recommended n-butyl acetate 150 713 200 950 1998 Ethyl acetate 400 1440 1996 Toluene 50 188 A4 Dermal 1996 Xylene (mixture of isomers) 100 434 150 651 A4 1996 Isopropyl alcohol 400 983 500 1230 1976 Ethylbenzene 100 434 125 543 1976 A4 - Non classified as carcinogenic in humans. 8.2 Engineering measures: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficent to maintain concentrations of particulates and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. 8.3 Protection of respiratory system: Avoid the inhalation of vapours. Mask: Filter mask. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Suitable safety goggles. Face shield: No. 8.5 Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Advisable. 9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Aerosol - Colour: Green / Grey - Odour: Characteristic - Specific gravity: 0,92 g/cc at 20ºC (Isospray) 0,85 g/cc at 20ºC (Isofast) - Solubility in water: 328 g/l - Flash point: -41ºC


SDS-821/EN - Autoignition temperature: 170ºC - Decomposition temperature: 170ºC 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents, acids, alkalis, amines, peroxides. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced: nitrogen oxides. 11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. 11.2 Dose and lethal concentrations for individual ingredients:


n-butyl acetate 10768 Rat 17600 Rabbit 9,7 Rat Ethyl acetate 5620 Rat 20000 Rabbit 200 Rat Toluene 636 Rat 12124 Rabbit 49 Rat Xylene (mixture of isomers) 4300 Rat 1700 Rabbit 22 Rat Isopropyl alcohol 5045 Rat 12800 Rabbit Ethylbenzene 3500 Rat 17800 Rabbit For more information about ingredients dangerous to health, see sections 2 and 8. *12. ECOLOGICAL INFORMATION No experimental ecotoxicological data on the preparation as such is available. 12.1 Spills on the soil: Prevent contamination of soil. 12.2 Spills in water: Do not allow to escape into drains, sewers or water courses. 12.3 Emissions to the atmosphere: When possible, avoid solvent release to the atmosphere; do not pulverize more than is strictly necessary. - VOC: 678 g/l ASTM D-3960 (Isospray) 692 g/l ASTM D-3960 (Isofast) - Aromatic hydrocarbons: 12,5 % Weight (Isospray) 12,3 % Weight (Isofast) 12.4 Ecotoxicological data for individual ingredients:


Dimethyl ether 4000 Fishes 4000 Daphnia


SDS-821/EN


n-butyl acetate 18 Fishes Toluene 24 Fishes 12 Daphnia 400 Algae Xylene (mixture of isomers) 75 Fishes 16 Daphnia Ethylbenzene 12 Fishes 33 Algae 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. Ensure the container is completely empty before throwing it away. 13.3 Procedures for neutralising or destroying the product: In accordance with local regulations. Do not incinerarate closed containers. 14. TRANSPORT INFORMATION AEROSOLS 14.1 Land: Transport by road: ADR

Transport by rail: RID Class: 2 Classification code: 5F UN nº1950






*15. INFORMATION ON REGULATIONS 15.1 EC Labelling F+ This product is EXTREMELY FLAMMABLE in accordance with Guideline 67/548/EEC - 2001/59/EC and 1999/45/EC - 2001/60/EC. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. S23 Do not breathe vapour, spray. S24/25 Avoid contact with skin and eyes.


SDS-821/EN S51 Use only in well-ventilated areas. P96 Pressurised container. Protect from sunlight and do not expose to temperature

exceeding 50ºC. Do not pierce or burn, even after use. P97 Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No smoking. Keep out of reach of children. Dangerous ingredients: None in a percentage equal to or higher than the limit for the name. 15.2 Type of packaging: According to current legislation. *16. OTHER INFORMATION Intended use Only for professional use. Text of R-phrases listed in section 2: R10 Flammable. R11 Highly flammable. R12 Extremely flammable. R20 Harmful by inhalation. R36 Irritating to eyes. R38 Irritating to skin. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. R20/21 Harmful by inhalation and in contact with skin. Labelling regulations: The information provided in this Material Safety Data Sheet has been written in accordance with Guideline 67/548/EEC (Substances), 88/379/EEC (Preparations) and 91/155/EEC (Material Safety Data Sheet). It has been updated to Guideline 2001/59/EC (Substances), 2001/60/EC (Preparations) and 2001/58/EC (Material Safety Data Sheet). The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 10.12.02 AIRCOLOR MATT BLACK Page: 1/6 AIRCOLOR SATIN BLACK SDS-815/EN *1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: AIRCOLOR MATT BLACK Code: 61447 AIRCOLOR SATIN BLACK Code: 61448 1.2 Use of the preparation: Black paint in aerosol. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) 2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 2,5-10 % n-butyl acetate R10 R66 R67 CAS: 123-86-4 EC No. 204-658-1 SAX: BPU750 No. 607-025-00-1 10-25 % Xylene (mixture of isomers) R10 R38 R20/21 Xn CAS: 1330-20-7 EC No. 215-535-7 SAX: XGS000 No. 601-022-00-9 2,5-10 % Ethylbenzene R11 R20 F Xn CAS: 100-41-4 EC No. 202-849-4 SAX: EGP500 No. 601-023-00-4 For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Extremely flammable. Harmful by inhalation. Harmful in contact with skin. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.3 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. In the case of skin reddening or rashes, contact a doctor immediately.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 10.12.02 AIRCOLOR MATT BLACK Page: 2/6 AIRCOLOR SATIN BLACK SDS-815/EN 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: In case of fire, alcohol-resistant foam, dry chemical powder, carbon dioxide, AFFF. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sewages, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Clean preferably with a detergent. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. - Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. Pressurised container. Protect from sunlight and do not expose to temperatures exceeding 50º C. Do not pierce or burn aerosol even after use. Do not spray on a naked flame or any incandescent material. - Recommendations for the prevention of toxicological risks: Avoid applying the product directly to people, animals, plants or foodstuffs. Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 10.12.02 AIRCOLOR MATT BLACK Page: 3/6 AIRCOLOR SATIN BLACK SDS-815/EN 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. Class of store: According to current legislation. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 35ºC. 7.3 Incompatible materials: Keep away from oxidizing agents, from strongly alkaline and strongly acid materials. 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC 8.1 Occupational Exposure Limits (TLV) AGCIH 2001 TWA STEL Year

ppm mg/m3 ppm mg/m3 n-butyl acetate 150 713 200 950 1998 Xylene (mixture of isomers) 100 434 150 651 A4 1996 Ethylbenzene 100 434 125 543 1976 A4 - Non classified as carcinogenic in humans. 8.2 Engineering measures: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particles and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. Ventilation requirement: 236 m3/l (maximum) Air/Preparation (MATT BLACK) 253 m3/l m3/l (maximum) Air/Preparation (SATIN BLACK) to keep below the Occupational Exposure Limit of the product. 8.3 Protection of respiratory system: Avoid the inhalation of vapours. Mask: Filter mask. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Suitable safety goggles. Face shield: No. 8.5 Protection of hands and skin: Install emergency showers close to the working area. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Suitable work clothes which avoid contact with the product should be worn. 9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Aerosol - Colour: Matt Satin / Satin Black - Odour: Characteristic - Specific gravity: 0.78 g/cc at 20ºC (MATT BLACK)

0.77 g/cc at 20ºC (SATIN BLACK) - Flash point: -41ºC Setaflash - Autoignition temperature: 368ºC (MATT BLACK)

370ºC (SATIN BLACK) 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 10.12.02 AIRCOLOR MATT BLACK Page: 4/6 AIRCOLOR SATIN BLACK SDS-815/EN 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents, acids, alkalis, peroxides. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced. 11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. 11.2 Dose and lethal concentrations for individual ingredients:


n-butyl acetate 13100 Rat 5000 Rabbit 9.7 Rat Xylene (mixture of isomers) 4300 Rat 1700 Rabbit 22 Rat Ethylbenzene 3500 Rat 17800 Rabbit For more information about ingredients dangerous to health, see sections 2 and 8. 12. ECOLOGICAL INFORMATION Prevent contamination of soil. Do not allow to escape into drains, sewers or water courses. Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - VOC: 648 g/l ASTM D-3960 (MATT BLACK) - VOC: 653 g/l ASTM D-3960 (SATIN BLACK) - Aliphatic hydrocarbons: 0.1 % Weight - Aromatic hydrocarbons: 16 % Weight (MATT BLACK) 17 % Weight (SATIN BLACK) 12.1 Ecotoxicity: No experimental ecotoxicological data on the preparation as such is available. Ecotoxicological data for individual ingredients:


n-butyl acetate 18 Fishes 10 Daphnia 21 Algae Xylene (mixture of isomers) 75 Fishes 16 Daphnia Ethylbenzene 12 Fishes 33 Algae 12.2 Mobility: N/A 12.3 Persistence and degradability: In water: t ½ life = 29 - 144 hours (Xylene) In air: t ½ life = 1 - 18 hours (Xylene) 12.4 Bioaccumulative potential: log Pow = 1.82 (n-butyl acetate) log Pow = 3.12 - 3.20 (Xylene) BCF = 14 (n-butyl acetate)

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 10.12.02 AIRCOLOR MATT BLACK Page: 5/6 AIRCOLOR SATIN BLACK SDS-815/EN N/A: Not available. 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. Ensure the container is completely empty before throwing it away. 13.3 Procedures for neutralising or destroying the product: In accordance with local regulations. Do not incinerate closed containers. 14. TRANSPORT INFORMATION AEROSOLS 14.1 Land: Transport by road: ADR-2001







15. INFORMATION ON REGULATIONS 15.1 EC Labelling F+, Xn This product is extremely flammable and harmful in accordance with 67/548/EEC - 2001/59/EC and 1999/45/EC - 2001/60/EC directives. R20/21 Harmful by inhalation and in contact with skin. S16 Keep away from sources of ignition- No smoking. S23 Do not breathe vapour/spray. S51 Use only in well-ventilated areas. Pressurised container. Protect from sunlight and do not expose to temperatures exceeding 50ºC. Do not pierce or burn aerosol even after use. Do not spray on a naked flame or any incandescent material.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 10.12.02 AIRCOLOR MATT BLACK Page: 6/6 AIRCOLOR SATIN BLACK SDS-815/EN Dangerous ingredients: None in a percentage equal to or higher than the limit for the name. 15.2 Type of packaging: According to current legislation. 16. OTHER INFORMATION Intended use Only for professional use. Text of R-phrases listed in section 2: R10 Flammable. R11 Highly flammable R20 Harmful by inhalation. R38 Irritating to skin. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. R20/21 Harmful by inhalation and in contact with skin. Labelling regulations: The information provided in this Material Safety Data Sheet has been written in accordance with 67/548/EEC (Substances), 88/379/EEC (Preparations) and 91/155/EEC (Material Safety Data Sheet) directives. It has been updated to 2001/59/EC (Substances), 2001/60/EC (Preparations) and 2001/58/EC (Material Safety Data Sheet) directives. The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 03.04.03 AIRCOLOR PAINT BLACK - WHITE Page: 1/6

SDS-825/EN *1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: AIRCOLOR PAINT BLACK Code: 61449 AIRCOLOR PAINT WHITE Code: 61450 1.2 Use of the preparation: Paint for the covering of different surfaces. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia)

*2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 25-50 % Dimethyl ether R12 F+ CAS: 115-10-6 EC No. 204-065-8 SAX: MJW500 No. 603-019-00-8 2,5-10 % Isobutylmethylketone R11 R20 R66 R36/37 F Xn CAS: 108-10-1 EC No. 203-550-1 SAX: HFG500 No. 606-004-00-4 2,5-10 % Xylene R10 R38 R20/21 Xn CAS:1330-20-7 (mixture of isomers) EC No. 215-535-7

SAX:XGS000 No.601-022-00-9

2,5-10% 1-methoxypropyl acetate R10 R36 Xi CAS: 108-65-6 EC No. 203-603-9 No. 607-195-00-7 < 2,5 % Ethylbenzene R11 R20 F Xn CAS: 100-41-4

EC No. 202-849-4 SAX:EGP500 No.601-023-00-4 For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Extremely flammable. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives.


SDS-825/EN 4.2 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.3 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. In the case of skin reddening or rashes. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: In case of fire, alcohol-resistant foam, dry chemical powder, carbon dioxide, AFFF. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sewages, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. - Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. Pressurised container. Protect from sunlight and do not expose to temperatures exceeding 50ºC. Do not pierce or burn aerosol even after use. Do not spray on a naked flame or any incandescent material.


SDS-825/EN - Recommendations for the prevention of toxicological risks: Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. Class of store: According to current legislation. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 35ºC. 7.3 Incompatible materials: Keep away from reducing agents, oxidizing agents, acids. 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions. *8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC 8.1 Occupational Exposure Limits (TLV) AGCIH 2001 TWA STEL Year AGCIH 2001 ppm mg/m3 ppm mg/m3 Dimethyl ether 1000 1910 2000 3830 1999 Isobutylmethylketone 20 83 50 208 2000 Xylene (mixture of isomers) 100 442 150 663 Dermal 1999 1-methoxypropyl acetate 50 275 100 550 Dermal 1999 Ethylbenzene 100 441 125 551 Dermal 2000 8.2 Engineering measures: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particles and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. Ventilation requirement 320 m3/l (maximum) Air/Preparation to keep below the Occupational Exposure Limit of the product. 8.3 Protection of respiratory system: Avoid the inhalation of vapours. Mask: Filter mask. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Suitable safety goggles. Face shield: No. 8.5 Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Suitable Advisable. 9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Aerosol - Colour: Black/white - Odour: Characteristic - Specific gravity: 0.82 g/cc at 20ºC - Flash point: -41ºC Setaflash - Autoignition temperature: 371.9ºC 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with reducing agents, oxidizing agents, acids.




Isobutylmethylketone 2080 Rat 20000 Rabbit Xylene (mixture of isomers) 4300 Rat 1700 Rabbit 22 Rat 1-methoxypropyl acetate 8532 Rat Ethylbenzene 3500 Rat 17800 Rabbit For more information about ingredients dangerous to health, see sections 2 and 8. *12. ECOLOGICAL INFORMATION Prevent contamination of soil. Do not allow to escape into drains, sewers or water courses. Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - VOC: 536 g/l ASTM D-3960 - Aromatic hydrocarbons: 8.5 % Weight 12.1 Ecotoxicity: No experimental ecotoxicological data on the preparation as such is available. Ecotoxicological data for individual ingredients:


Xylene (mixture of isomers) 75 Fishes 16 Daphnia Ethylbenzene 12 Fishes 33 Algae Dimethyl ether 4000 Fishes 4000 Daphnia 12.2 Mobility : N/A 12.3 Persistence and degradability: In water : t ½ life = 29 - 144 hours (Xylene) In air: t ½ life = 1 - 18 hours (Xylene) 12.4 Bioaccumulative potential : log Pow = 3.12 - 3.20 (Xylene) N/A: Not available.


SDS-825/EN 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. Ensure the container is completely empty before throwing it away. 13.3 Procedures for neutralising or destroying the product: In accordance with local regulations. Do not incinerate closed containers. *14. TRANSPORT INFORMATION AEROSOLS 14.1 Land: Transport by road: ADR-2003







*15. INFORMATION ON REGULATIONS 15.1 EC Labelling F+ This product is extremely flammable in accordance with 67/548/EEC - 2001/59/EC and 1999/45/EC - 2001/60/EC directives. S16 Keep away from sources of ignition- No smoking. S23 Do not breathe vapour/spray. S51 Use only in well-ventilated areas. P96 Pressurised container. Protect from sunlight and do not expose to temperature exceeding 50ºC. Do not pierce or burn, even after use. P97 Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No smoking. Keep out of reach of children. Dangerous ingredients: None in a percentage equal to or higher than the limit for the name.


SDS-825/EN 15.2 Type of packaging: According to current legislation. 16. OTHER INFORMATION Intended use Only for professional use. Text of R-phrases listed in section 2: R10 Flammable. R11 Highly flammable. R20 Harmful by inhalation. R36 Irritating to eyes R38 Irritating to skin. R66 Repeated exposure may cause skin dryness or cracking. R20/21 Harmful by inhalation and in contact with skin. R36/37 Irritating to eyes and respitatory system. Labelling regulations: The information provided in this Material Safety Data Sheet has been written in accordance with 67/548/EEC (Substances), 88/379/EEC (Preparations) and 91/155/EEC (Material Safety Data Sheet) directives. It has been updated to 2001/59/EC (Substances), 2001/60/EC (Preparations) and 2001/58/EC (Material Safety Data Sheet) directives. The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 27.02.04 AIRCOLOR THERMO-ALU Page: 1/6

SDS-823/EN 1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: AIRCOLOR THERMO-ALU Code: 61453 1.2 Use of the preparation: Paint for the covering of different surfaces. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia)

2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 25-50 % Toluene R11 R20 F Xn CAS: 108-88-3 EC No. 203-625-9 SAX: TGK750 No.601-021-00-3 10-25 % Butane R12 F+ CAS: 106-97-8

EC No. 203-448-7 SAX:BOR500 No.601-004-00-0

10-25 % Propane R12 F+ CAS: 74-98-6 EC No. 200-827-9 SAX: PMJ750 No.601-003-00-5

2.5-10 % Aluminium powder (stabilised) R10 R15 F EC No.7429-90-5 10 -25 % Titanium polybutyle R36/38 Xi EC No. 162303-51-7 For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Extremely flammable. Harmful by inhalation. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.3 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. In the case of skin reddening or rashes, contact a doctor immediately. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest.


SDS-823/EN 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: Extinguishing powder or CO2. In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use never water. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide, formaldehyde. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sews, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Clean preferably with a detergent. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. - Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. Pressurised container. Protect from sunlight and do not expose to temperatures exceeding 50º C. Do not pierce or burn aerosol even after use. Do not spray on a naked flame or any incandescent material. - Recommendations for the prevention of toxicological risks: Avoid applying the product directly to people, animals, plants or foodstuffs. Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. Class of store: According to current legislation. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 35ºC. Combustion heat: 9851 Kcal/kg. 7.3 Incompatible materials: Keep away from oxidizing agents, acids, alkalis.


SDS-823/EN 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/CE 8.1 Occupational Exposure Limits (TLV) AGCIH 2001 TWA STEL Year

ppm mg/m3 ppm mg/m3 Toluene 50 188 A4 Dermal 1996 Butane 800 1900 1981 Propane 2500 4508 Suffocating gas 1998 Aluminium powder (stabilised) 10 A4 - Non classified as carcinogenic in humans. 8.2 Engineering measures: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particles and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. Ventilation requirement: 1075 m3/l (maximum) Air/Preparation to keep below the Occupational Exposure Limit of the product. Special ventilation is required. 8.3 Protection of respiratory system: Avoid the inhalation of vapours. Mask: Filter mask. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Suitable safety goggles. Face shield: No. 8.5 Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Suitable work clothes which avoid contact with the product should be worn. *9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Aerosol - Colour: Aluminium - Odour: Characteristic. - Specific gravity: 0.78 g/cc at 20ºC - Flash point: -83ºC Setaflash - Autoignition temperature: 447ºC - Decomposition temperature: 150ºC 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with reducing agents, oxidizing agents, acids. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced: Formaldehyde.


SDS-823/EN 11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. 11.2 Dose and lethal concentrations for individual ingredients:


Toluene 636 Rat 12124 Rabbit 49 Rat Butane 658 Rat For more information about ingredients dangerous to health, see sections 2 and 8. *12. ECOLOGICAL INFORMATION Prevent contamination of soil. Do not allow to escape into drains, sewers or water courses. Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - VOC: 637 g/l ASTM D-3960 - Aliphatic hydrocarbons: 46 % Weight - Aromatic hydrocarbons: 26 % Weight 12.1 Ecotoxicity: No experimental ecotoxicological data on the preparation as such is available. Ecotoxicological data for individual ingredients:


Toluene 24 Fishes 12 Daphnia 400 Algae 12.2 Mobility : N/A 12.3 Persistence and degradability : In water : : t ½ life= 2.9 - 5.7 hours (Toluene) In air: t ½ life= 3 hours - 1 day (Toluene) 12.4 Bioaccumulative potential : log Pow = 2 .6 (Toluene) N/A: Not available. 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8.


SDS-823/EN 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. Ensure the container is completely empty before throwing it away. 13.3 Procedures for neutralising or destroying the product: In accordance with local regulations. Do not incinerate closed containers. *14. TRANSPORT INFORMATION AEROSOLS 14.1 Land: Transport by road: ADR-2003

Transport by rail: RID Class: 2 Classification code: 5F UN nº1950 Transport document: Consignment paper Written instructions.





15. INFORMATION ON REGULATIONS 15.1 EC Labelling F+, Xn This product is EXTREMELY FLAMMABLE and HARMFUL in accordance with 67/548/EEC - 2001/59/EC and 1999/45/EC - 2001/60/EC directives. R20 Harmful by inhalation. S16 Keep away from sources of ignition- No smoking. S23 Do not breathe vapour/spray. S51 Use only in well-ventilated areas. P96 Pressurised container. Protect from sunlight and do not expose to temperature exceeding 50ºC. Do not pierce or burn, even after use. P97 Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No smoking. Keep out of reach of children. Dangerous ingredients: Toluene. 15.2 Type of packaging: According to current legislation.


SDS-823/EN 16. OTHER INFORMATION Intended use Only for professional use. Text of R-phrases listed in section 2: R10 Flammable. R11 Highly flammable. R12 Extremely flammable. R15 Contact with water liberates extremely flammable gases. R20 Harmful by inhalation. R36/38 Irritating to eyes and skin. Labelling regulations: The information provided in this Material Safety Data Sheet has been written in accordance with 67/548/EEC (Substances), 88/379/EEC (Preparations) and 91/155/EEC (Material Safety Data Sheet) directives. It has been updated to 2001/59/EC (Substances), 2001/60/EC (Preparations) and 2001/58/EC (Material Safety Data Sheet) directives. The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 10.12.02 AIRCOLOR ZINC Page: 1/6

SDS-812/EN *1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: AIRCOLOR ZINC Code: 61455 1.2 Use of the preparation: Anticorrosion primer in aerosol. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia)

2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value:

10-25 % n-butyl acetate R10 R66 R67 CAS: 123-86-4

EC No. 204-658-1 SAX: BPU750 No. 607-025-00-1

2.5-10 % Toluene R11 R20 F,Xn CAS :108-88-3

EC No. 205-500-4 SAX : EFR000 No.607-022-00-5

For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Extremely flammable. Vapours may cause drowsiness and dizziness. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.3 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. In the case of skin reddening or rashes, contact a doctor immediately. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest.


SDS-812/EN 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: In case of fire, alcohol-resistant foam, dry chemical powder, carbon dioxide, AFFF. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sewages, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Clean preferably with a detergent. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. - Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. Pressurised container. Protect from sunlight and do not expose to temperatures exceeding 50º C. Do not pierce or burn aerosol even after use. Do not spray on a naked flame or any incandescent material. - Recommendations for the prevention of toxicological risks: Avoid applying the product directly to people, animals, plants or foodstuffs. Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. Class of store: According to current legislation. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 35ºC. 7.3 Incompatible materials: Keep away from oxidizing agents, acids, alkalis.


SDS-812/EN 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC 8.1 Occupational Exposure Limits (TLV) AGCIH 2001 TWA STEL Year

ppm mg/m3 ppm mg/m3 n-butyl acetate 150 713 200 950 1998 Toluene 50 188 A4 Derm. 1996 A4 - Non classified as carcinogenic in humans. 8.2 Engineering measures: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particles and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. Ventilation requirement: 250 m3/l (maximum) Air/Preparation to keep below the Occupational Exposure Limit of the product. 8.3 Protection of respiratory system: Avoid the inhalation of vapours. Mask: Filter mask. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Suitable safety goggles. Face shield: No. 8.5 Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Advisable. 9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Aerosol - Odour: Characteristic - Specific gravity: 1.1 g/cc at 20ºC - Solubility in water: 328 g/l - Flash point: -41ºC Setaflash - Autoignition temperature: 363ºC - Descomposition temperature: > 500ºC 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with water, oxidizing agents, acids, alkalis, peroxides. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced. 11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available.


SDS-812/EN 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. 11.2 Dose and lethal concentrations for individual ingredients:


n-butyl acetate 13100 Rat 5000 Rabbit 9.7 Rat Toluene 5000 Rat 12124 Rabbit 15 Rat For more information about ingredients dangerous to health, see sections 2 and 8. 12. ECOLOGICAL INFORMATION Prevent contamination of soil. Do not allow to escape into drains, sewers or water courses. Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - VOC: 653 g/l ASTM D-3960 - Aromatic hydrocarbons: 4.5 % Weight 12.1 Ecotoxicity: No experimental ecotoxicological data on the preparation as such is available. Ecotoxicological data for individual ingredients:


n-butyl acetate 18 Fishes 10 Daphnia 21 Algae Toluene 24 Fishes 12 Daphnia 400 Algae 12.2 Mobility: N/A 12.3 Persistence and degradability: In water: t ½ life = 2.9 - 5.7 hours (Toluene) In air: t ½ life = 3 hours - 1 day (Toluene) 12.4 Bioaccumulative potential: log Pow = 1.82 (n-butyl acetate) log Pow = 2 .6 (Toluene) BCF = 14 (n-butyl acetate) N/A: Not available. 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. 13.3 Procedures for neutralising or destroying the product: In accordance with local regulations. Do not incinerate closed containers.


SDS-812/EN 14. TRANSPORT INFORMATION AEROSOLS 14.1 Land: Transport by road: ADR-2001







15. INFORMATION ON REGULATIONS 15.1 EC Labelling F+ This product is extremely flammable in accordance with 67/548/EEC - 2001/59/EC and 1999/45/EC - 2001/60/EC directives. R67 Vapours may cause drowsiness and dizziness. S16 Keep away from sources of ignition- No smoking. S23 Do not breathe vapour/spray. S51 Use only in well-ventilated areas. Pressurised container. Protect from sunlight and do not expose to temperatures exceeding 50ºC. Do not pierce or burn aerosol even after use. Do not spray on a naked flame or any incandescent material. Dangerous ingredients: None in a percentage equal to or higher than the limit for the name. 15.2 Type of packaging: According to current legislation. 16. OTHER INFORMATION Intended use Only for professional use. Text of R-phrases listed in section 2: R10 Flammable. R11 Highly flammable. R20 Harmful by inhalation. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness.


SDS-812/EN Labelling regulations: The information provided in this Material Safety Data Sheet has been written in accordance with 67/548/EEC (Substances), 88/379/EEC (Preparations) and 91/155/EEC (Material Safety Data Sheet) directives. It has been updated to 2001/59/EC (Substances), 2001/60/EC (Preparations) and 2001/58/EC (Material Safety Data Sheet) directives. The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 19.12.02 BUMPER COLOR Page: 1/6

SDS-808/EN *1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: BUMPER COLOR BLACK Code: 51270 GREY Code: 51271 WHITE Code: 51273 1.2 Use of the preparation: Bodywork plastics treatment. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia)

2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 10-25 % Toluene R11 R20 F Xn CAS: 108-88-3 EC No. 203-625-9 SAX: TGK750 No.601-021-00-3 10-25 % Ethyl acetate R11 R36 R66 R67 F Xi CAS: 141-78-6 EC No. 205-500-4 SAX: EFR000 No.607-022-00-5 2,5-10% Acetone R11 R36 R66 R67 F Xi CAS: 67-64-1 EC No. 200-662-2 SAX: ABC750 No.606-001-00-8 2,5-10 % Xylene R10 R38 R20/21 Xn CAS: 1330-20-7

(mixture of isomers) EC No. 215-535-7 SAX: XGS000 No.601-022-00-9

< 2,5 % Ethylbencene R11 R20 F Xn CAS: 100-41-4 EC No. 202-849-4 SAX:EGP500 No.601-023-00-4 For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Highly flammable. Harmful by inhalation. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately.


SDS-808/EN 4.3 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. In the case of skin reddening or rashes, contact a doctor immediately. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: In case of fire use water spray, alcohol-resistant foam, dry chemical powder, carbon dioxide, AFFF. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sewages, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Clean preferably with a detergent. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed. Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. Recommendations for the prevention of toxicological risks: Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8.


SDS-808/EN 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. Keep away from living quarters. Keep away from food, drink and animal foodstuffs. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Class B1. According to ITC MIE APQ-1, RD.379/2001. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 35ºC. 7.3 Incompatible materials: Keep away from oxidizing agents, acids, alkalis. 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/CE 8.1 Occupational Exposure Limits (TLV) AGCIH 2001 TWA STEL Year

ppm mg/m3 ppm mg/m3 Toluene 50 188 A4Dermal 1996 Ethyl acetate 400 1440 1996 Acetone 500 1188 750 1782 1997 Xylene (mixture of isomers) 100 434 150 651 1996 Ethylbencene 100 434 125 543 1976 A4 - Non classified as carcinogenic in humans. 8.2 Engineering measures: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particles and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. Vapour density: 2.47 Air = 1 at 20ºC Relative Lower explosive limit: 2.6 % Volume Ventilation requirement: 76 m3/l Air/Preparation to keep below 1/10 of the Lower Explosive Limit. Ventilation requirement: 1222 m3/l (maximum) Air/Preparation to keep below the Occupational Exposure Limit of the product. Special ventilation is required. 8.3 Protection of respiratory system: Avoid the inhalation of vapours. Mask: Filter mask. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles designed to protect against liquid splashes. Face shield: No. 8.5 Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Personnel should wear antistatic clothing made of natural fibre or of high temperature resistant synthetic fibre. Wash contaminated work clothes before wearing them again. 9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Liquid - Colour: Black/Grey/White - Odour: Characteristic - Viscosity: 150000 cps at 20ºC Brookfield - Specific gravity: Black / Grey 1.15 g/cc at 20ºC

White 1.21 g/cc at 20ºC - Boiling point: 56.2ºC at 760 mmHg - Flash point: -4ºC Setaflash


SDS-808/EN - Autoignition temperature: 493ºC - Vapour pressure: 68.5 mmHg at 20ºC 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents, acids, alkalis, peroxides. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced. 11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. 11.2 Dose and lethal concentrations for individual ingredients:


Toluene 5000 Rat 12124 Rabbit 15 Rat Ethyl acetate 5620 Rat 20000 Rabbit Acetone 5800 Rat 20000 Rabbit Xylene (mixture of isomers) 4300 Rat 1700 Rabbit 22 Rat Ethylbenzene 3500 Rat 17800 Rabbit For more information about ingredients dangerous to health, see sections 2 and 8. 12. ECOLOGICAL INFORMATION Prevent contamination of soil. Do not allow to escape into drains, sewers or water courses. Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - VOC: 496 g/l BUMPER COLOR WHITE ASTM D-3960 506 g/l BUMPER COLOR BLACK ASTM D-3960 506 g/l BUMPER COLOR GREY ASTM D-3960 - Aromatic hydrocarbons: 25.7% Weight 12.1 Ecotoxicity: No experimental ecotoxicological data on the preparation as such is available. Ecotoxicological data for individual ingredients:


SDS-808/EN


Toluene 24 Fishes 12 Daphnia 400 Algae Acetone 2000 Fishes 12100 Daphnia Xylene(mixture of isomers) 75 Fishes 16 Daphnia Ethylbenzene 12 Fishes 33 Algae 12.2 Mobility : N/A 12.3 Persistence and degradability: In water : t ½ life = 2.9 - 5.7 hours (Toluene) t ½ life = 29 - 144 hours (Xylene) In air: t ½ life = 3 hours - 1 day (Toluene) t ½ life = 1 - 18 hours (Xylene) 12.4 Bioaccumulative potential : log Pow = 2 .6 (Toluene) log Pow = 3.12 - 3.20 (Xylene) N/A: Not available. 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. 14. TRANSPORT INFORMATION PAINTS (FP<23ºC, viscous according to 2.2.3.1.4, VP<110 kPa50ºC) 14.1 Land: Transport by road: ADR 2001 Transport by rail: RID/TPF Class: 3 Packaging group: III UN no. 1263 Transport document: Consignment paper Written instructions. 14.2 Sea: Transport by ship: IMDG 30-00 Class: 3 Packaging group: III UN no. 1263 Emergency Sheet (EmS): 3-05 First Aid Guide (MFAG): 310, 313 Marine pollutant: No Transport document: Shipping Bill of lading 14.3 Air: Transport by plane: IATA/ICAO Class: 3 Packaging group: III UN no. 1263 Transport document: Air Bill of lading


SDS-808/EN 15. INFORMATION ON REGULATIONS 15.1 EC Labelling F, Xn This product is highly flammable and harmful in accordance with 67/548/EEC - 2001/59/EC and 1999/45/EC - 2001/60/EC directives. R20 Harmful by inhalation. S16 Keep away from sources of ignition- No smoking. S23 Do not breathe vapour/spray. S51 Use only in well-ventilated areas. Dangerous ingredients: Toluene. 15.2 Type of packaging: According to current legislation. 16. OTHER INFORMATION Intended use Only for professional use. Text of R-phrases listed in section 2: R10 Flammable R11 Highly flammable R20 Harmful by inhalation. R20/21 Harmful by inhalation and in contact with skin. R36 Irritating to eyes. R38 Irritating to skin. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. Labelling regulations: The information provided in this Material Safety Data Sheet has been written in accordance with 67/548/EEC (Substances), 88/379/EEC (Preparations) and 91/155/EEC (Material Safety Data Sheet) directives. It has been updated to 2001/59/EC (Substances), 2001/60/EC (Preparations) and 2001/58/EC (Material Safety Data Sheet) directives. The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 22.11.02 CAVITEX Page: 1/6

SDS-806/EN *1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: CAVITEX Code: 61418 1.2 Use of the preparation: Anticorrosive protector. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia)

2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 25-50 % Naphtha (oil), heavy hydrodesulfurized

R10 R65 R66 R67 R51/53 Xn N CAS: 64742-82-1 EC No. 265-185-4 No. 649-330-00-2 (Note P)

For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Flammable. Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and dizziness. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.3 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: In case of fire, use water spray, alcohol-resistant foam, dry chemical powder, carbon dioxide. Do not use for extinguishing: direct water jet.


SDS-806/EN 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sewages, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Clean preferably with a detergent. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. - Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. - Recommendations for the prevention of toxicological risks: Avoid applying the product directly to people, animals, plants or foodstuffs. Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. - Recommendations for the prevention of environmental contamination: Product dangerous to the environment. Avoid any spillage in the environment. Pay special attention to the cleaning water. In the case of accidental spillage, follow the instructions indicated in section 6. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. Class of store: Class B2. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 35ºC. 7.3 Incompatible materials: Keep away from oxidizing agents, acids. 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions.


SDS-806/EN 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/CE 8.1 Occupational Exposure Limits (TLV) AGCIH 2001 TWA STEL Year

ppm mg/m3 ppm mg/m3 Naphtha (oil), heavy hydrodesulfurized 100 525 Internal value 8.2 Engineering measures: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particles and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. Vapour density: 5.18 Air = 1 at 20ºC Relative - Lower explosive limit: 0.8 % Volume - Ventilation requirement: 107 m3/l Air/Preparation to keep below 1/10 of the Lower Explosive Limit. -Ventilation requirement: 819 m3/l (maximum) Air/Preparation to keep below the Occupational Exposure Limit of the product. 8.3 Protection of respiratory system: Avoid the inhalation of vapours. Mask: Filter mask. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles designed to protect against liquid splashes. Face shield: No. 8.5 Protection of hands and skin: Install emergency showers close to the working area. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Personnel should wear antistatic clothing made of natural fibre or of high temperature resistant synthetic fibre. 9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Liquid - Colour: White - Odour: Characteristic - Viscosity: 26 sec. FC/4 20ºC - Specific gravity: 0.86 g/cc at 20ºC - Boiling point: 150ºC at 760 mmHg - Flash point: 41ºC Setaflash - Autoignition temperature: 275ºC - Vapour pressure: 1.5 mmHg a 20ºC 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents and acids. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced. 11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following


SDS-806/EN effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. 11.2 Dose and lethal concentrations for individual ingredients:


Naphtha (oil), heavy hydrodesulfurized 6000 Rat 3000 Rat 31 Rat For more information about ingredients dangerous to health, see sections 2 and 8. 12. ECOLOGICAL INFORMATION Prevent contamination of soil. Toxic to aquatic organisms. May cause long-term adverse effects on the aquatic environment. Do not allow to escape into drains, sewers or water courses. Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - VOC: 430 g/l ASTM D-3960 - Aliphatic hydrocarbons: 40 % Weight - Aromatic hydrocarbons: 10 % Weight 12.1 Ecotoxicity: No experimental ecotoxicological data on the preparation as such is available. Ecotoxicological data for individual ingredients:


Naphtha (oil), heavy hydrodesulfurized 800 Fishes 100 Daphnia 450 Algae 12.2 Mobility : N/A 12.3 Persistence and degradability: N/A 12.4 Bioaccumulative potential : log Pow = 3 - 6 estimated (Naphtha (oil), heavy hydrodesulfurized) BCF = 112 -159 (Naphtha (oil), heavy hydrodesulfurized) N/A: Not available. 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. Ensure the container is completely empty before throwing it away. 13.3 Procedures for neutralising or destroying the product: In accordance with local regulations. *14. TRANSPORT INFORMATION COATING SOLUTION, non viscous


SDS-806/EN 14.1 Land: Transport by road: ADR-2001

Transport by rail: RID/TPF Class: 3 UN nº1139 Packaging group: III Transport document: Consignment paper Written instructions.

14.2 Sea: Transport by ship: IMDG Class: 3 UN nº1139 Marine pollutant: yes Packaging group: III

Emergency Sheet (EmS): 3-07 First Aid Guide (MFAG): 311

Transport document: Shipping Bill of Lading 14.3 Air: Transport by plane: IATA/ICAO

Class: 3 UN nº1139 Packaging group: III Transport document: Air Bill of Lading

15. INFORMATION ON REGULATIONS 15.1 EC Labelling N This product is flammable and dangerous for the environment in accordance with 67/548/EEC - 2001/59/EC and 1999/45/EC - 2001/60/EC directives. R10 Flammable. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic

environment. S23 Do not breathe vapour/spray. S24 Avoid contact with skin. S29/56 Do not empty into drains, dispose of this material and its container to hazardous or

special waste collection point. S51 Use only in well-ventilated areas. Dangerous ingredients: None in a percentage equal to or higher than the limit for the name. 15.2 Type of packaging: According to current legislation. 16. OTHER INFORMATION Intended use Only for professional use. Text of R-phrases listed in section 2: R10 Flammable. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic

environment. Note P : It is unnecessary to apply the classification as carcinogenic if it can be proved that the substance contains less than 0.1% benzene (EC No. 200-753-7) in weight.


SDS-806/EN Labelling regulations: The information provided in this Material Safety Data Sheet has been written in accordance with 67/548/EEC (Substances), 88/379/EEC (Preparations) and 91/155/EEC (Material Safety Data Sheet) directives. It has been updated to 2001/59/EC (Substances), 2001/60/EC (Preparations) and 2001/58/EC (Material Safety Data Sheet) directives. The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 03.09.03 250 MS Page: 1/7

SDS-721/EN 1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: 250 MS Code: 51462 1.2 Use of the preparation: Bodywork repair acrylic varnish. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) 2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 25-50 % n-butyl acetate R10 R66 R67 CAS: 123-86-4

EC No. 204-658-1 SAX: BPU750 No. 607-025-00-1

10-25 % Xylene R10 R38 R20/21 Xn CAS: 1330-20-7 (mixture of isomers) EC No. 215-535-7

SAX: XGS000 No. 601-022-00-9

2,5-10 % 1-methoxypropyl acetate R10 R36 Xi CAS: 108-65-6 EC No. 203-603-9 No. 607-195-00-7 2,5-10 % Butylglycol acetate R20/21 Xn CAS: 112-07-2 EC No. 203-933-3 SAX:BPM000 No. 607-038-00-2 < 2,5 % Ethylbenzene R11 R20 F Xn CAS: 100-41-4

EC No. 202-849-4 SAX: EGP500 No. 601-023-00-4

< 0,5 % Bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate Xi N CAS: 41556-26-7 R43 R51/53 EC No. 255-437-1 < 0,5 % Bis(hydroxiphenylbenzotriazole) derivative Xn N CAS: 104810-48-2 R43 R48/22 R51/53 EC No. 400-830-7 < 0,5 % Naphtha solvent (oil), Xn N CAS: 64742-95-6 light aromatic R10 R65 R66 R67 R51/53 EC No. 265-199-0

No. 649-356-00-4 (Note P)

For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Flammable. Harmful by inhalation. Harmful in contact with skin.


SDS-721/EN 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.3 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: Extinguishing powder or CO2. In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sewages, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Clean preferably with a detergent. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed. Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures


SDS-721/EN with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. Recommendations for the prevention of toxicological risks: Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. Keep away from living quarters. Keep away from food, drink and animal foodstuffs. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Class B1. According to ITC MIE APQ-1, RD.379/2001. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 35ºC. 7.3 Incompatible materials: Keep away from oxidizing agents, acids, alkalis, peroxides. 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC 8.1 Occupational Exposure Limits (TLV) TWA STEL Year AGCIH 2001 ppm mg/m3 ppm mg/m3 n-butyl acetate 150 713 200 950 1998 Xylene (mixture of isomers) 100 434 150 651 A4 1996 1-methoxypropyl acetate 50 275 100 550 Recommended Dermal Butylglycol acetate 20 133 50 333 Recommended Dermal Ethylbenzene 100 434 125 543 1976 Bis(hydroxiphenylbenzotriazole) derivative 1.0 Internal value bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate 1.0 Internal value Naphtha solvent (oil), light aromatic 50 260 Internal value A4 - Non classified as carcinogenic in humans. 8.2 Engineering measures: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particles and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. Vapour density: 3.95 Air = 1 at 20ºC Relative Lower explosive limit: 1.4 % Volume Ventilation requirement: 56 m3/l Air/Preparation to keep below 1/10 of the Lower Explosive Limit. 8.3 Protection of respiratory system: Avoid the inhalation of vapours. Mask: Filter mask. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles designed to protect against liquid splashes. Face shield: No. 8.5 Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Personnel should wear antistatic clothing made of natural fibre or of high temperature resistant synthetic fibre. Wash contaminated work clothes before wearing them again.


SDS-721/EN 9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Liquid - Colour: Colourless - Odour: Characteristic - Viscosity: 36 sec. CF/4 at 20ºC ASTM D 1200-88 - Specific gravity: 0.993 g/cc at 20ºC - Boiling point : 126.3ºC at 760 mmHg - Flash point: 28ºC Setaflash - Autoignition temperature: 375ºC - Vapour pressure: 7 mmHg at 20ºC 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents, acids, alkalis, peroxides. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced. 11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. This preparation contains glycols that are readily absorbed through the skin and may cause harmful effects on the blood. Contains sensitising substances. May produce an allergic reaction. 11.2 Dose and lethal concentrations for individual ingredients:

DL50 Oral DL50 Cutaneous CL50 Inhalation mg/kg mg/kg mg/l.4hours n-butyl acetate 10768 Rat 17600 Rabbit 9.7 Rat Xylene (mixture of isomers) 4300 Rat 1700 Rabbit 22 Rat 1-methoxypropyl acetate 8532 Rat Butylglycol acetate 2400 Rat 1500 Rabbit Ethylbenzene 3500 Rat 17800 Rabbit Bis(hydroxiphenylbenzotriazole) derivative 2000 Rat bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate 2000 Rat Naphtha solvent (oil), light aromatic 3900 Rat 3160 Rabbit Methyl(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate 2000 Rat


SDS-721/EN For more information about ingredients dangerous to health, see sections 2 and 8. 12. ECOLOGICAL INFORMATION Prevent contamination of soil. Do not allow to escape into drains, sewers or water courses. Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - VOC: 519 g/l ASTM D-3960 - Aromatic hydrocarbons: 13.9% Weight 12.1 Ecotoxicity: No experimental ecotoxicological data on the preparation as such is available. Ecotoxicological data for individual ingredients:


n-butyl acetate 18 Fishes 10 Daphnia 21 Algae Xylene (mixture of isomers) 75 Fishes 16 Daphnia Ethylbenzene 12 Fishes 33 Algae Derivative of 2.8 Fishes 3.8 Daphnia 9.0 Algae hydroxiphenylbenzotriazole bis(1,2,2,6,6-pentamethyl-4- 7.9 Fishes 20 Daphnia piperidyl) sebacate Naphtha solvent (oil), 9.2 Fishes 6.1 Daphnia light aromatic Methyl(1,2,2,6,6-pentamethyl-4- 7.9 Fishes 20 Daphnia piperidyl) sebacate 12.2 Mobility : N/A 12.3 Persistence and degradability: In water : t ½ life = 29 - 144 hours (Xylene) In air: t ½ life = 1 - 18 hours (Xylene) 12.4 Bioaccumulative potential : log Pow = 1.82 (n-butyl acetate) log Pow = 3.12 - 3.20 (Xylene) BCF = 14 (n-butyl acetate) N/A: Not available. 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. 14. TRANSPORT INFORMATION PAINTS (FP>23ºC)


SDS-721/EN 14.1 Land: Transport by road: ADR 2003 Transport by rail: RID Class: 3 Packaging group: III UN no. 1263 Transport document: Consignment paper Written instructions. 14.2 Sea: Transport by ship: IMDG 30-00 Class: 3 Packaging group: III UN no. 1263 Emergency Sheet (EmS): 3-05-07 First Aid Guide (MFAG): 310, 313 Marine pollutant: No Transport document: Shipping Bill of lading 14.3 Air: Transport by plane: IATA/ICAO Class: 3 Packaging group: III UN no. 1263 Transport document: Air Bill of lading

15. INFORMATION ON REGULATIONS 15.1 EC Labelling Xn This product is FLAMMABLE and HARMFUL in accordance with Guideline 67/548/EEC~2001/59/EC and 1999/45/EC~2001/60/EC R10 Flammable. R20/21 Harmful by inhalation and in contact with skin. S23 Do not breathe vapour, spray. S36/37 Wear suitable protective clothing and gloves. S51 Use only in well-ventilated areas. P99 Contains bis(hydroxiphenylbenzotriazole) derivative, bis(1,2,2,6,6-pentamethyl-4- piperidyl) sebacate. May produce an allergic reaction. - Dangerous ingredients: None in a percentage equal to or higher than the limit for the name. 15.2 Type of packaging: According to current legislation. 16. OTHER INFORMATION Intended use Only for professional use. Text of R-phrases listed in section 2: R10 Flammable. R11 Highly flammable. R20 Harmful by inhalation. R36 Irritating to eyes. R38 Irritating to skin. R43 May cause sensitization by skin contact. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. R20/21 Harmful by inhalation and in contact with skin.


SDS-721/EN R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic


MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 03.09.03 350 HS Page: 1/7

SDS-722/EN 1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: 350 HS Code: 51441 1.2 Use of the preparation: Bodywork repair acrylic varnish. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) 2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 10-25 % n-butyl acetate R10 R66 R67 CAS: 123-86-4

EC No. 204-658-1 SAX: BPU750 No. 607-025-00-1

10-25 % 1-methoxypropyl acetate R10 R36 Xi CAS: 108-65-6 EC No. 203-603-9 No. 607-195-00-7 2,5-10 % Xylene R10 R38 R20/21 Xn CAS: 1330-20-7 (mixture of isomers) EC No. 215-535-7

SAX: XGS000 No. 601-022-00-9

2,5-10 % Butylglycol acetate R20/21 Xn CAS: 112-07-2 EC No. 203-933-3 SAX: BPM000 No. 607-038-00-2 < 2,5 % Ethylbenzene R11 R20 F Xn CAS: 100-41-4

EC No. 202-849-4 SAX: EGP500 No. 601-023-00-4

< 2,5 % Bis(hydroxiphenylbenzotriazole) derivative Xn N CAS: 104810-48-2 R43 R48/22 R51/53 EC No. 400-830-7 < 0,5 % Bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate Xi N CAS: 41556-26-7 R43 R51/53 EC No. 255-437-1 < 0,5 % Naphtha solvent (oil), Xn N CAS: 64742-95-6 light aromatic R10 R65 R66 R67 R51/53 EC No. 265-199-0

No. 649-356-00-4 (Note P)

< 0,2 % Methyl(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate Xi N CAS: 82919-37-7 R43 R51/53 EC No. 280-060-4 For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Flammable. May cause sensitization by skin contact. Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and dizziness.


SDS-722/EN 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.3 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. In the case of skin reddening or rashes, contact a doctor immediately. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: Extinguishing powder or CO2. In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide, nitrogen oxides. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sewages, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Clean preferably with a detergent. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed. Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures


SDS-722/EN with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. Recommendations for the prevention of toxicological risks: Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. Keep away from living quarters. Keep away from food, drink and animal foodstuffs. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Class B1. According to ITC MIE APQ-1, RD.379/2001. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 35ºC. 7.3 Incompatible materials: Keep away from oxidizing agents, acids, alkalis, peroxides. 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC 8.1 Occupational Exposure Limits (TLV) AGCIH 2001 TWA STEL Year ppm mg/m3 ppm mg/m3 n-butyl acetate 150 713 200 950 1998 1-methoxypropyl acetate 50 275 100 550 Recommended Dermal Xylene (mixture of isomers) 100 434 150 651 A4 1996 Butylglycol acetate 20 133 50 333 Recommended Dermal Ethylbenzene 100 434 125 543 1976 Bis(hydroxiphenylbenzotriazole) derivative 1.0 Internal value bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate 1.0 Internal value Naphtha solvent (oil), light aromatic 50 260 Internal value Methyl(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate 1.0 Internal value A4 - Non classified as carcinogenic in humans. 8.2 Engineering measures: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particles and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. Vapour density: 3.99 Air = 1 at 20ºC Relative Lower explosive limit: 1.5 % Volume Ventilation requirement: 54 m3/l Air/Preparation to keep below 1/10 of the Lower Explosive Limit. 8.3 Protection of respiratory system: Avoid the inhalation of vapours. When operators, whether spraying or not, are inside the spraybooth, and ventilation is unlikely to be sufficient to constantly control particles and solvent vapour in all cases, in such circumstances they should wear a compressed air-fed respirator during the spraying process and until such a time as the particles and solvent vapour concentration has fallen below the exposure limits. Mask: Filter mask. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles designed to protect against liquid splashes. Face shield: No.


SDS-722/EN 8.5 Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Personnel should wear antistatic clothing made of natural fibre or of high temperature resistant synthetic fibre. Wash contaminated work clothes before wearing them again. 9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Liquid - Colour: Colourless - Odour: Characteristic - Viscosity: 45 sec. CF/4 at 20ºC ASTM D 1200-88 - Specific gravity: 0.995 g/cc at 20ºC - Flash point: 29ºC Setaflash - Autoignition temperature: 369ºC - Decomposition temperature 250ºC - Vapour pressure: 6.8 mmHg at 20ºC 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents, acids, alkalis, peroxides. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced. 11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. This preparation contains glycols that are readily absorbed through the skin and may cause harmful effects on the blood. 11.2 Dose and lethal concentrations for individual ingredients:

DL50 Oral DL50 Cutaneous CL50 Inhalation mg/kg mg/kg mg/l.4hours n-butyl acetate 10768 Rat 17600 Rabbit 9.7 Rat 1-methoxypropyl acetate 8532 Rat Xylene (mixture of isomers) 4300 Rat 1700 Rabbit 22 Rat Butylglycol acetate 2400 Rat 1500 Rabbit Ethylbenzene 3500 Rat 17800 Rabbit


SDS-722/EN

DL50 Oral DL50 Cutaneous CL50 Inhalation mg/kg mg/kg mg/l.4hours Bis(hydroxiphenylbenzotriazole) derivative 2000 Rat bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate 2000 Rat Naphtha solvent (oil), light aromatic 3900 Rat 3160 Rabbit Methyl(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate 2000 Rat For more information about ingredients dangerous to health, see sections 2 and 8. 12. ECOLOGICAL INFORMATION Prevent contamination of soil. Do not allow to escape into drains, sewers or water courses. Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - VOC: 481 g/l ASTM D-3960 - Aromatic hydrocarbons: 11.1% Weight 12.1 Ecotoxicity: No experimental ecotoxicological data on the preparation as such is available. Ecotoxicological data for individual ingredients:


Xylene (mixture of isomers), 75 Fishes 16 Daphnia n-butyl acetate 18 Fishes 10 Daphnia 21 Algae Naphtha solvent (oil), 9.2 Fishes 6.1 Daphnia light aromatic Ethylbenzene 12 Fishes 33 Algae bis(1,2,2,6,6-pentamethyl-4- 7.9 Fishes 20 Daphnia piperidyl) sebacate Derivative of 2.8 Fishes 3.8 Daphnia 9.0 Algae hydroxiphenylbenzotriazole Methyl(1,2,2,6,6-pentamethyl-4- 7.9 Fishes 20 Daphnia piperidyl) sebacate 12.2 Mobility : N/A 12.3 Persistence and degradability: In water : t ½ life = 29 - 144 hours (Xylene) In air: t ½ life = 1 - 18 hours (Xylene) 12.4 Bioaccumulative potential : log Pow = 1.82 (n-butyl acetate) log Pow = 3.12 - 3.20 (Xylene) BCF = 14 (n-butyl acetate) N/A: Not available. 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8.


SDS-722/EN 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. 14. TRANSPORT INFORMATION PAINTS (FP>23ºC) 14.1 Land: Transport by road: ADR 2003 Transport by rail: RID Class: 3 Packaging group: III UN no. 1263 Transport document: Consignment paper Written instructions. 14.2 Sea: Transport by ship: IMDG 30-00 Class: 3 Packaging group: III UN no. 1263 Emergency Sheet (EmS): 3-05-07 First Aid Guide (MFAG): 310, 313 Marine pollutant: No Transport document: Shipping Bill of lading 14.3 Air: Transport by plane: IATA/ICAO Class: 3 Packaging group: III UN no. 1263 Transport document: Air Bill of lading

15. INFORMATION ON REGULATIONS 15.1 EC Labelling Xi This product is FLAMMABLE AND IRRITANT in accordance with Guideline 67/548/EEC - 2001/59/EC and 1999/45/EC - 2001/60/EC. R10 Flammable. R43 May cause sensitization by skin contact. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. S23 Do not breathe gases. S24/25 Avoid contact with skin and eyes. S51 Use only in well-ventilated areas. - Dangerous ingredients: Bis(hydroxiphenylbenzotriazole) derivative 15.2 Type of packaging: According to current legislation. 16. OTHER INFORMATION Intended use: Only for professional use.


SDS-722/EN Text of R-phrases listed in section 2: R10 Flammable. R11 Highly flammable. R20 Harmful by inhalation. R36 Irritating to eyes. R38 Irritating to skin. R43 May cause sensitization by skin contact. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. R20/21 Harmful by inhalation and in contact with skin. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic


MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 03.09.03 450 UHS Page: 1/7

SDS-723/EN 1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: 450 UHS Code: 51401 1.2 Use of the preparation: Bodywork repair acrylic varnish. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) 2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 25-50 % n-butyl acetate R10 R66 R67 EC No. 204-658-1 CAS: 123-86-4 SAX: BPU750 No. 607-025-00-1 10-25 % 1-methoxypropyl acetate R10 R36 Xi EC No. 203-603-9 CAS: 108-65-6 No. 607-195-00-7 < 2,5 % Bis(hydroxiphenylbenzotriazole) derivative R43 R51/53 Xn N EC No. 400-830-7 CAS: 104810-48-2 < 0,5 % bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate R43 R51/53 Xi N EC No. 255-437-1 CAS: 41556-26-7 < 0,5 % Naphtha solvent (oil), light aromatic R10 R65 R66 R67 R51/53 Xn N EC No. 265-199-0 CAS: 64742-95-6 No. 649-356-00-4 (Note P) < 0,2 % Methyl(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate R43 R51/53 Xi N EC No. 280-060-4 CAS: 82919-37-7

For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Flammable. May cause sensitization by skin contact. Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and dizziness. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious,


SDS-723/EN place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.3 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. In the case of skin reddening or rashes, contact a doctor immediately. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: Extinguishing powder or CO2. In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide, nitrogen oxides. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sewages, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Clean preferably with a detergent. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed. - Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off.


SDS-723/EN - Recommendations for the prevention of toxicological risks: Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. Keep away from living quarters. Keep away from food, drink and animal foodstuffs. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Class B1. According to ITC MIE APQ-1, RD.379/2001. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 35ºC. 7.3 Incompatible materials: Keep away from oxidizing agents, acids, alkalis, peroxides. 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC 8.1 Occupational Exposure Limits (TLV) AGCIH 2001


n-butyl acetate 150 713 200 950 1998 1-methoxypropyl acetate 50 275 100 550 Recommended Dermal Bis(hydroxiphenylbenzotriazole) 1.0 Internal value derivative bis(1,2,2,6,6-pentamethyl-4-piperidyl) 1.0 Internal value sebacate Naphtha solvent (oil) 50 260 Internal value light aromatic Methyl(1,2,2,6,6-pentamethyl-4-piperidyl) 1.0 Internal value Sebacate 8.2 Engineering measures: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particles and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. Vapour density: 4.08 Air = 1 at 20ºC Relative Lower explosive limit: 1.7 % Volume Ventilation requirement: 43 m3/l Air/Preparation to keep below 1/10 of the Lower Explosive Limit. 8.3 Protection of respiratory system: Avoid the inhalation of vapours. When operators, whether spraying or not, are inside the spraybooth, and ventilation is unlikely to be sufficient to constantly control particles and solvent vapour in all cases, in such circumstances they should wear a compressed air-fed respirator during the spraying process and until such a time as the particles and solvent vapour concentration has fallen below the exposure limits. Mask: Filter mask. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles designed to protect against liquid splashes. Face shield: No. 8.5 Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Personnel should wear antistatic clothing made of natural fibre or of high temperature resistant synthetic fibre. Wash contaminated work clothes before wearing them again.


SDS-723/EN 9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Liquid - Colour: Colourless - Odour: Characteristic - Viscosity: 32 sec CF/4 at 20ºC ASTM D 1200-88 - Specific gravity: 1.015 g/cc at 20ºC - Flash point: 29ºC Setaflash - Decomposition temperature: 250ºC - Vapour pressure: 7.3 mmHg at 20ºC 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents, acids, alkalis, peroxides. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced: nitrogen oxides. 11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. 11.2 Dose and lethal concentrations for individual ingredients:


n-butyl acetate 10768 Rat 17600 Rabbit 9.7 Rat 1-methoxypropyl acetate 8532 Rat Bis(hydroxiphenylbenzotriazole) Derivative 2000 Rat bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate 2000 Rat Naphtha solvent (oil), 3900 Rat 3160 Rabbit (light aromatic Methyl(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate 2000 Rat For more information about ingredients dangerous to health, see sections 2 and 8.


SDS-723/EN 12. ECOLOGICAL INFORMATION Prevent contamination of soil. Do not allow to escape into drains, sewers or water courses. Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - VOC: 431 g/l ASTM D-3960 - Aromatic hydrocarbons: 0.4 % Weight 12.1 Ecotoxicity: No experimental ecotoxicological data on the preparation as such is available. Ecotoxicological data for individual ingredients:

CL50 CE50 CI50 mg/l.96hours mg/l.48 hours mg/l.72 hours

n-butyl acetate 18 Fishes Bis(hydroxiphenylbenzotriazole) Derivative 2.8 Fishes 3.8 Daphnia 9.0 Algae bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate 7.9 Fishes 20 Daphnia Naphtha solvent (oil), light aromatic 9.2 Fishes 6.1 Daphnia Methyl(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate 7.9 Fishes 20 Daphnia 12.2 Mobility : N/A 12.3 Persistence and degradability: N/A 12.4 Bioaccumulative potential : log Pow = 1.82 (n-butyl acetate) BCF = 14 (n-butyl acetate) N/A: Not available. 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. 14. TRANSPORT INFORMATION PAINTS (FP>23ºC) 14.1 Land: Transport by road: ADR 2003 Transport by rail: RID Class: 3 Packaging group: III UN no. 1263 Transport document: Consignment paper Written instructions. 14.2 Sea: Transport by ship: IMDG 30-00 Class: 3 Packaging group: III UN no. 1263 Emergency Sheet (EmS): 3-05-07 First Aid Guide (MFAG): 310, 313


SDS-723/EN Marine pollutant: No Transport document: Shipping Bill of lading 14.3 Air: Transport by plane: IATA/ICAO Class: 3 Packaging group: III UN no. 1263 Transport document: Air Bill of lading

15. INFORMATION ON REGULATIONS 15.1 EC Labelling Xi This product is FLAMMABLE AND IRRITANT in accordance with Guideline 67/548/EEC - 2001/59/EC and 1999/45/EC - 2001/60/EC. R10 Flammable. R43 May cause sensitization by skin contact. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. S23 Do not breathe gases. S24/25 Avoid contact with skin and eyes. S51 Use only in well-ventilated areas. - Dangerous ingredients: Bis(hydroxiphenylbenzotriazole) derivative 15.2 Type of packaging: According to current legislation. 16. OTHER INFORMATION Intended use: Only for professional use. Text of R-phrases listed in section 2: R10 Flammable. R36 Irritating to eyes. R43 May cause sensitization by skin contact. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic

environment. Note P : It is unnecessary to apply the classification as carcinogenic if it can be proved that the substance contains less than 0.1% benzene (EC No. 200-753-7) in weight. Labelling regulations: The information provided in this Material Safety Data Sheet has been written in accordance wit 67/548/EEC (Substances), 88/379/EEC (Preparations) and 91/155/EEC (Material Safety Data Sheet) directives. It has been updated to 2001/59/EC (Substances), 2001/60/EC (Preparations) and 2001/58/EC (Material Safety Data Sheet) directives. The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our


SDS-723/EN knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 06.10.05 EXPRESS 350 Page: 1/7

SDS-725/EN 1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: EXPRESS 350 Code: 51663 1.2 Use of the preparation: Bodywork repair acrylic varnish. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) 2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 25-50 % n-butyl acetate EC: 204-658-1 R10 R66-R67 CAS: 123-86-4 No. 607-025-00-1 10-25 % 2-methoxy-1-methylethyl acetate EC: 203-603-9 R10 Xi; R36 CAS: 108-65-6 No. 607-195-00-7 2,5-10 % Xylene (mixture of isomers) EC: 215-535-7 R10 Xn; R20/21 Xi; R38 CAS: 1330-20-7 No. 601-022-00-9 2,5-10 % Butylglycol acetate EC: 203-933-3 Xn; R20/21 CAS: 112-07-2 No. 607-038-00-2 < 2,5 % Ethylbenzene EC: 202-849-4 F; R11 Xn; R20 CAS: 100-41-4 No. 601-023-00-4 < 2,5 % Bis(hydroxiphenylbenzotriazole) derivative EC: 400-830-7 R43 N; R51-53 CAS: 104810-48-2 < 0,5 % Bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate EC: 255-437-1 R43 N; R51-53 CAS: 41556-26-7 < 0,5 % Naphtha solvent (oil), light aromatic EC: 265-199-0 R10 Xn; R65 R66-R67 N; R51-53 CAS: 64742-95-6 No. 649-356-00-4 (Note P) < 0,2 % Methyl 1,2,2,6,6-pentamethyl-4-piperidyl sebacate EC: 280-060-4 R43 N; R51-53 CAS: 82919-37-7 For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Flammable. May cause sensitization by skin contact. Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and dizziness. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person.


SDS-725/EN 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. In the case of skin reddening or rashes, contact a doctor immediately. 4.3 By contact with eyes: Remove contact lenses. Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: Extinguishing powder or CO2. In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use for extinguishing: direct water jet. 5.2 Specific risks: As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide, nitrogen oxides. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sewages, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Clean preferably with a detergent. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed. - Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a


SDS-725/EN potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. - Flash point: 29ºC Setaflash - Autoignition temperature: 366,8ºC - Recommendations for the prevention of toxicological risks: Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. Keep away from living quarters. Keep away from food, drink and animal foodstuffs. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Class B1. According to ITC MIE APQ-1, RD.379/2001. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 35ºC. - Incompatible materials: Keep away from oxidizing agents, acids, alkalis, peroxides. - Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions. - Type of packaging: According to current legislation. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC 8.1 Occupational Exposure Limits (TLV) AGCIH 2004 TWA STEL Year ppm mg/m3 ppm mg/m3 n-butyl acetate 150 713 200 950 1998 Xylene (mixture of isomers) 100 434 150 651 A4 1996 2-methoxy-1-methylethyl acetate 50 275 100 550 Recommended Dermal Butylglycol acetate 20 133 50 333 A3 2003 Ethylbenzene 100 434 125 543 A3 2002 Bis(hydroxiphenylbenzotriazole) derivative 1,0 Internal value Bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate 1,0 Internal value Naphtha solvent (oil), light aromatic 50 290 Internal value Methyl 1,2,2,6,6-pentamethyl-4-piperidyl sebacate 1,0 Internal value A3 - Carcinogenic in animals. A4 - Non classified as carcinogenic in humans. 8.2 Occupational exposure controls, Directive 89/686/EEC: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particles and vapors below the Occupational Exposure Limits, suitable respiratory protection must be worn. - Protection of respiratory system: Avoid the inhalation of vapours. Avoid the inhalation of particles or spray mist arising from the application of this preparation. Mask: Suitable combined filter mask for gases, vapours and particles (EN141/EN143). In order to obtain a suitable protection level, the filter class must be selected depending on the type and concentration of the contaminating agents present, in accordance with the specifications supplied by the filter producers. The respiratory equipment with filters does not work satisfactorily when the air contains high concentrations of vapour. If mask use is not sufficient, when operators, whether spraying or not, are inside the spraybooth, and ventilation is unlikely to be sufficient to constantly control particulates and solvent vapour in all cases, in such circumstances they should wear a compressed air-fed respiratory protective equipment (EN137) during the spraying


SDS-725/EN process and until such a time as the particulates and solvent vapour concentration has fallen below the exposure limits. - Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles designed to protect against liquid splashes, with suitable lateral protection (EN166). Face shield: No. - Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Gloves resistant against chemicals (EN374). Boots: No. Apron: No. Clothing: It is advisable personnel wear antistatic clothing made of natural fibre or of high temperature resistant synthetic fibre. Wash contaminated work clothes before wearing them again. 8.3 Environmental exposure controls: Avoid any spillage in the environment of the product, wastes, packages or spraybooth sewages. Avoid any release into the atmosphere above the legal limits allowed. 9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Liquid - Colour: Colourless - Odour: Characteristic - Viscosity: 31 sec. CF/4 at 20ºC ASTM D 1200-88 - Specific gravity: 0,995 g/cc at 20ºC - Flash point: 29ºC Setaflash - Decomposition temperature 250ºC - Vapour pressure: 6,5 mmHg at 20ºC 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents, acids, alkalis, peroxides. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced. 11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. · This preparation contains glycols that are readily absorbed through the skin and may cause harmful effects on the blood.


SDS-725/EN 11.2 Dose and lethal concentrations for individual ingredients:

DL50 Oral DL50 Cutaneous CL50 Inhalation mg/kg mg/kg mg/l.4hours n-butyl acetate 10768 Rat 17600 Rabbit 9,7 Rat Xylene (mixture of isomers) 4300 Rat 1700 Rabbit 22 Rat 2-methoxy-1-methylethyl acetate 8532 Rat Butylglycol acetate 2400 Rat 1500 Rabbit Ethylbenzene 3500 Rat 17800 Rabbit Bis(hydroxiphenylbenzotriazole) derivative 2000 Rat Bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate 2000 Rat Naphtha solvent (oil), light aromatic 3900 Rat 3160 Rabbit Methyl 1,2,2,6,6-pentamethyl- 4-piperidyl sebacate 2000 Rat For more information about ingredients dangerous to health, see sections 2 and 8. 12. ECOLOGICAL INFORMATION No experimental ecotoxicological data on the preparation as such is available. 12.1 Spills on the soil: Prevent contamination of soil. 12.2 Spills in water: Do not allow to escape into drains, sewers or water courses. 12.3 Emissions to the atmosphere: Avoid any release into the atmosphere. - COV: 481 g/l Express 350 ASTM D-3960 - Mixing application VOC: 478 g/l Express 350 - C355 (100:50 vol) ASTM D-3960 - Aromatic hydrocarbons: 11,6 % Weight 12.4 Ecotoxicological data for individual ingredients:


n-butyl acetate 18 Fishes Xylene (mixture of isomers), 75 Fishes 16 Daphnia Ethylbenzene 12 Fishes 33 Algae bis(1,2,2,6,6-pentamethyl-4- 7,9 Fishes 20 Daphnia piperidyl) sebacate Derivative of 2,8 Fishes 3,8 Daphnia 9,0 Algae hydroxiphenylbenzotriazole Naphtha solvent (oil), 9,2 Fishes 6,1 Daphnia light aromatic Methyl 1,2,2,6,6-pentamethyl-4- 7,9 Fishes 20 Daphnia piperidyl sebacate 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste, Directive 75/442/EEC~91/156/EC: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers, Directive 94/62/EC: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations.


SDS-725/EN 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. 14. TRANSPORT INFORMATION PAINTS (FP>23ºC) 14.1 Land: Transport by road: ADR 2003 Transport by rail: RID Class: 3 Packaging group: III UN no. 1263 Transport document: Consignment paper Written instructions. 14.2 Sea: Transport by ship: IMDG 30-00 Class: 3 Packaging group: III UN no. 1263 Emergency Sheet (EmS): 3-05-07 First Aid Guide (MFAG): 310, 313 Marine pollutant: No Transport document: Shipping Bill of lading 14.3 Air: Transport by plane: IATA/ICAO Class: 3 Packaging group: III UN no. 1263 Transport document: Air Bill of lading

15. INFORMATION ON REGULATIONS 15.1 EC Labelling Xi This product is FLAMMABLE AND IRRITANT in accordance with Guideline 67/548/EEC - 2004/73/EC and 1999/45/EC - 2001/60/EC. R10 Flammable. R43 May cause sensitization by skin contact. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. S23 Do not breathe gases. S24/25 Avoid contact with skin and eyes. S51 Use only in well-ventilated areas. - Dangerous ingredients: Bis(hydroxiphenylbenzotriazole) derivative 15.2 Restrictions to the marketing and use in accordance with Directive 76/769/EEC: Not applicable. 15.3 Other regulations: Not applicable. 16. OTHER INFORMATION Intended use: Only for professional use. Text of R-phrases listed in section 2: R10 Flammable. R11 Highly flammable. R20 Harmful by inhalation.


SDS-725/EN R36 Irritating to eyes. R38 Irritating to skin. R43 May cause sensitization by skin contact. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. R20/21 Harmful by inhalation and in contact with skin. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic

environment. Note P: It is unnecessary to apply the classification as carcinogenic if it can be proved that the substance contains less than 0.1% benzene (EC No. 200-753-7) in weight. Material Safety Data Sheet regulations: Material Safety Data Sheet in accordance with Directive 91/155/EEC~2001/58/EC. The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 22.07.04 MS303 Page: 1/7

SDS-716/EN *1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: MS303 Code: 51242 1.2 Use of the preparation: Bodywork repair acrylic varnish. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) 2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 10-25 % Xylene R10 R38 R20/21 Xn CAS: 1330-20-7 (mixture of isomers) EC No. 215-535-7

SAX: XGS000 No. 601-022-00-9

10-25 % n-butyl acetate R10 R66 R67 CAS: 123-86-4 EC No. 204-658-1 SAX: BPU750 No. 607-025-00-1

2,5-10 % 1-methoxypropyl acetate R10 R36 Xi CAS: 108-65-6 EC No. 203-603-9 No. 607-195-00-7 2,5-10 % Naphtha solvent (oil), Xn N CAS: 64742-95-6 light aromatic R10 R65 R66 R67 R51/53 EC No. 265-199-0

No. 649-356-00-4 (Note P)

<2,5 % Ethylbenzene R11 R20 F Xn CAS: 100-41-4 EC No. 202-849-4 SAX: EGP500 No. 601-023-00-4

< 0,5 % Bis(hydroxiphenylbenzotriazole) derivative Xn N CAS: 104810-48-2 R43 R51/53 EC No. 400-830-7 < 0,2 % Bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate Xi N CAS: 41556-26-7 R43 R51/53 EC No. 255-437-1

For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Flammable. Harmful by inhalation. Harmful in contact with skin. Irritating to skin. Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person.


SDS-716/EN 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. 4.3 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: Extinguishing powder or CO2. In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sewages, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Clean preferably with a detergent. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed. Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a


SDS-716/EN potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. Recommendations for the prevention of toxicological risks: Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. Keep away from living quarters. Keep away from food, drink and animal foodstuffs. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Class B1. According to ITC MIE APQ-1, RD.379/2001. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 35ºC. 7.3 Incompatible materials: Keep away from oxidizing agents, acids, alkalis, peroxides. 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC 8.1 Occupational Exposure Limits (TLV) AGCIH 2002


Xylene (mixture of isomers) 100 442 150 663 Recommended 1999 Dermal n-butyl acetate 150 724 200 965 1999 1-methoxypropyl acetate 50 275 100 550 Recommended 1999 Dermal Naphtha solvent (oil) 50 260 Internal value light aromatic Ethylbenzene 100 441 125 551 Recommended 2000 Dermal Bis(hydroxiphenylbenzotriazole) derivative 1,0 Internal value bis(1,2,2,6,6-pentamethyl-4-piperidyl) 1,0 Internal value sebacate 8.2 Engineering measures: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particles and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. Vapour density: 3,88 Air = 1 at 20ºC Relative Lower explosive limit: 1,4 % Volume Ventilation requirement: 73 m3/l Air/Preparation to keep below 1/10 of the Lower Explosive Limit. 8.3 Protection of respiratory system: Avoid the inhalation of vapours. When operators, whether spraying or not, are inside the spraybooth, and ventilation is unlikely to be sufficient to constantly control particles and solvent vapour in all cases, in such circumstances they should wear a compressed air-fed respirator during the spraying process and until such a time as the particles and solvent vapour concentration has fallen below the exposure limits. Mask: Filter mask. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles designed to protect against liquid splashes. Face shield: No. 8.5 Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Personnel should wear antistatic clothing made of natural fibre or of high


SDS-716/EN temperature resistant synthetic fibre. Wash contaminated work clothes before wearing them again. *9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Liquid - Colour: Colourless - Odour: Characteristic - Viscosity: 19 sec CF/4 at 20ºC ASTM D 1200-88 - Specific gravity: 0,985 g/cc at 20ºC - Boiling point: 126,3ºC at 760 mmHg - Flash point: 29ºC Setaflash - Autoignition temperature: 403,4ºC - Vapour pressure: 6,4 mmHg at 20ºC 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents, acids, alkalis, peroxides. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced. 11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. · Contains sensitising substances. May produce an allergic reaction. 11.2 Dose and lethal concentrations for individual ingredients:


Xylene (mixture of isomers) 4300 Rat 1700 Rabbit 22 Rat n-butyl acetate 10768 Rat 17600 Rabbit 9,7 Rat 1-methoxypropyl acetate 8532 Rat Naphtha solvent (oil), light aromatic 3900 Rat 3160 Rabbit Ethylbenzene 3500 Rat 17800 Rabbit Derivative of 2000 Rat Hydroxiphenylbenzotriazole bis(1,2,2,6,6-pentamethyl-4- 2000 Rat piperidyl) sebacate


SDS-716/EN For more information about ingredients dangerous to health, see sections 2 and 8. *12. ECOLOGICAL INFORMATION No experimental ecotoxicological data on the preparation as such is available. 12.1 Spills on the soil: Prevent contamination of soil. 12.2 Spills in water: Do not allow to escape into drains, sewers or water courses. 12.3 Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - VOC: 508 g/l ASTM D-3960 - Aromatic hydrocarbons: 30,7 % Weight 12.4 Ecotoxicity: Ecotoxicological data for individual ingredients:


Xylene (mixture of isomers) 75 Fishes 16 Daphnia n-butyl acetate 18 Fishes 10 Daphnia 21 Algae Naphtha solvent (oil), 9,2 Fishes 6,1 Daphnia light aromatic Ethylbenzene 12 Fishes 33 Algae Derivative of 2,8 Fishes 3,8 Daphnia 9,0 Algae hydroxiphenylbenzotriazole bis(1,2,2,6,6-pentamethyl-4- 7,9 Fishes 20 Daphnia piperidyl) sebacate 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. 14. TRANSPORT INFORMATION PAINTS (FP>23ºC) 14.1 Land: Transport by road: ADR 2003 Transport by rail: RID Class: 3 Packaging group: III UN no. 1263 Transport document: Consignment paper Written instructions. 14.2 Sea: Transport by ship: IMDG 30-00 Class: 3 Packaging group: III UN no. 1263 Emergency Sheet (EmS): 3-05-07 First Aid Guide (MFAG): 310, 313 Marine pollutant: No Transport document: Shipping Bill of lading


SDS-716/EN 14.3 Air: Transport by plane: IATA/ICAO Class: 3 Packaging group: III UN no. 1263 Transport document: Air Bill of lading

15. INFORMATION ON REGULATIONS 15.1 EC Labelling Xn This product is FLAMMABLE AND HARMFUL in accordance with Guideline 67/548/EEC - 2001/59/EC and 1999/45/EC - 2001/60/EC. R10 Flammable. R20/21 Harmful by inhalation and in contact with skin. R38 Irritating to skin. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S23 Do not breathe vapour/spray. S36/37 Wear suitable protective clothing and gloves. S51 Use only in well-ventilated areas. P99 Contains bis(hydroxiphenylbenzotriazole) derivative, bis(1,2,2,6,6-pentamethyl-4- piperidyl) sebacate. May produce an allergic reaction. Dangerous ingredients: Xylene (mixture of isomers) 15.2 Type of packaging: According to current legislation. 16. OTHER INFORMATION Intended use: Only for professional use. Text of R-phrases listed in section 2: R10 Flammable. R11 Highly flammable. R20 Harmful by inhalation. R36 Irritating to eyes. R38 Irritating to skin. R43 May cause sensitization by skin contact. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. R20/21 Harmful by inhalation and in contact with skin. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic

environment. Note P : It is unnecessary to apply the classification as carcinogenic if it can be proved that the substance contains less than 0.1% benzene (EC No. 200-753-7) in weight. Labelling regulations: The information provided in this Material Safety Data Sheet has been written in accordance with Guideline 67/548/EEC (Substances), 88/379/EEC (Preparations) and


SDS-716/EN 91/155/EEC (Material Safety Data Sheet). It has been updated to Guideline 2001/59/EC (Substances), 2001/60/EC (Preparations) and 2001/58/EC (Material Safety Data Sheet). The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 21.09.05 DUPLA Page: 1/5

SDS-011/EN 1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: DUPLA Code: 51570 1.2 Use of the preparation: Bodywork repair unsaturated polyester paste. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) 2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 10-25 % Styrene R10 R20 R36/38 Xn EC No. 202-851-5 CAS: 100-42-5

SAX: SMQ000 No. 601-026-00-0

< 2,5 % Ethyl Acetate R11 R36 R66 R67 F Xi EC No. 205-500-4 CAS: 141-78-6 SAX: EFR000 No. 607-022-00-5 For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Flammable. Harmful by inhalation. Irritating to eyes. Irritating to skin. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. 4.3 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest.


SDS-011/EN 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: Extinguishing powder or CO2. In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sews, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Avoid use of solvents. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed. Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. Recommendations for the prevention of toxicological risks: Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Class B1. According to. ITC MIE APQ-1, RD 379/2001. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 32ºC. 7.3 Incompatible materials: Keep away from oxidizing agents, from strongly alkaline and strongly acid materials. 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions.


SDS-011/EN *8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC 8.1 Occupational Exposure Limits (TLV) AGCIH 2004


Styrene 20 85 40 170 A4 1997 Ethyl acetate 400 1440 1996 A4 - Non classified as carcinogenic in humans. 8.2 Engineering measures: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. Vapour density: 3,27 Air=1 at 20ºC Relative Lower explosive limit: 1,9 % Volume 8.3 Protection of respiratory system: Avoid the inhalation of vapours. Mask: Filter mask. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Suitable safety goggles. Face shield: No. 8.5 Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Suitable work clothes which avoid contact with the product should be worn. *9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Paste - Colour: Light yellow - Odour: Characteristic - Viscosity: 6 x 106cps 20ºC Brookfield - Specific gravity: 2,0 g/cc a 20ºC - Solubility in water (styrene): 310 mg/l - Boiling point: 77,1ºC at 760 mmHg - Flash point: 32ºC Setaflash - Vapour pressure: 12,6 mmHg at 20ºC 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents, acids, alkalis, peroxides. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced. 11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects


SDS-011/EN may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. 11.2 Dose and lethal concentrations for individual ingredients:


Styrene 2650 Rat 12 Rat Ethyl acetate 5620 Rat 20000 Rabbit 200 Rat For more information about ingredients dangerous to health, see sections 2 and 8. *12. ECOLOGICAL INFORMATION No experimental ecotoxicological data on the preparation as such is available. 12.1 Spills on the soil: Prevent contamination of soil. 12.2 Spills in water: Do not allow to escape into drains, sewers or water courses. 12.3 Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - Mixing application VOC: 8 g/l ASTM D-3960 - Aromatic hydrocarbons: 12,2 % Weight 12.4 Ecotoxicological data for individual ingredients: CL50 CE50 CI50

mg/l.96hours mg/l.48hours mg/l.72hours Styrene 255 Dafnia 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. 13.3 Procedures for neutralizing or destroying the product: Authorized landfill in accordance with local regulations. *14. TRANSPORT INFORMATION 14.1 Transport by road, Directive 94/55/EC (ADR 2005):: Free Transport by rail, Directive 96/49/EC (RID 2005): Free 14.2 Transport by sea (IMDG 32-04): Free 14.3 Transport by air (ICAO/IATA): Free *15. INFORMATION ON REGULATIONS 15.1 EC Labelling Xn


SDS-011/EN This product is FLAMMABLE and HARMFUL in accordance with Guideline 67/548/EEC - 2004/73/EC and 1999/45/EC - 2001/60/EC. R10 Flammable. R20 Harmful by inhalation. R36/38 Irritating to eyes and skin. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S51 Use only in well-ventilated areas. Dangerous ingredients: Styrene 15.2 Type of packaging: According to current legislation. *16. OTHER INFORMATION Intended use Only for professional use. Text of R-phrases listed in section 2: R10 Flammable. R11 Highly flammable. R20 Harmful by inhalation. R36 Irritating to eyes. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. R36/38 Irritating to eyes and skin. Material Safety Data Sheet regulations: Material Safety Data Sheet in accordance with Directive 91/155/EEC~2001/58/EC. The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 20.11.02 ECOSIL Page: 1/5

SDS-504/EN *1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: ECOSIL BEIGE Code: 51219 1.2 Use of the preparation: Stone chip protector for bodywork. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) *2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit. 2,5-10 % Butylglycol R20/21/22 R36/38 Xn CAS: 111-76-2 EC No. 203-905-0 SAX: BPJ850 No. 603-014-00-0 For more information on dangerous ingredients, see sections 8, 11, 12 and 16. *3. IDENTIFICATION OF HAZARDS This product is not considered dangerous in accordance with 67/548/EEC - 2001/59/EC and 1999/45/EC - 2001/60/EC directives. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.3 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: Extinguishing powder or CO2. In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use for extinguishing: direct water jet.


SDS-504/EN 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sews, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Clean preferably with a detergent. Avoid use of solvents. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. *7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed. Recommendations for the prevention of toxicological risks: Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Class C. According to. ITC MIE APQ-1, RD 379/2001. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 35ºC. 7.3 Incompatible materials: Keep away from oxidizing agents, from strongly alkaline and strongly acid materials. 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. *8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC 8.1 Occupational Exposure Limits (TLV) AGCIH 2001


Butylglycol 20 100 Dermal 1999 8.2 Engineering measures: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction.


SDS-504/EN 8.3 Protection of respiratory system: Avoid the inhalation of vapours. When operators, whether spraying or not, are inside the spraybooth, and ventilation is unlikely to be sufficient to constantly control particles and solvent vapour in all cases, in such circumstances they should wear a compressed air-fed respirator during the spraying process and until such a time as the particles and solvent vapour concentration has fallen below the exposure limits. Mask: Filter mask. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles designed to protect against liquid splashes. Face shield: No. 8.5 Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Advisable. *9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Liquid - Colour: Beige - Viscosity: 1,6*106 cps 20ºC Brookfield - Specific gravity: 1.32 g/cc at 20ºC - Boiling point: >100ºC at 760 mmHg - Flash point: -- - Vapour pressure: 17.3 mmHg at 20ºC 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced. 11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. This preparation contains glycols that are readily absorbed through the skin and may cause harmful effects on the blood. 11.2 Dose and lethal concentrations for individual ingredients:


Butylglycol 470 Rat 220 Rabbit


SDS-504/EN For more information about ingredients dangerous to health, see sections 2 and 8. *12. ECOLOGICAL INFORMATION Prevent contamination of soil. Do not allow to escape into drains, sewers or water courses. Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - VOC: 40 g/l ASTM D-3960 - Aliphatic hydrocarbons: -- 12.1 Ecotoxicity: No experimental ecotoxicological data on the preparation as such is available. Ecotoxicological data for individual ingredients: CL50 CE50 CI50

mg/l.96hours mg/l.48hours mg/l.72hours Butylglycol 1395 Fishes 1815 Daphnia 500 Algae 12.2 Mobility : N/A 12.3 Persistence and degradability : - 88% THOD (Theoretical oxygen demand) (test BOD (Biological oxygen demand) 20 days) - THOD (Theoretical oxygen demand) (mg/mg ) : 2.25 - QOD (Chemical oxygen demand) (mg/mg ) : 2.30 12.4 Bioaccumulative potential : log Pow = 0.83 N/A: Not available. 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. 13.3 Procedures for neutralising or destroying the product: Authorised landfill in accordance with local regulations. *14. TRANSPORT INFORMATION 14.1 Land: Transport by road: ADR-2001/Transport by rail: RID/TPF: Free 14.2 Sea: Transport by ship: IMDG 30-00: Free 14.3 Air: Transport by plane: IATA/ICAO: Free *15. INFORMATION ON REGULATIONS 15.1 EC Labelling This product does not require pictograms in accordance with 67/548/EEC - 2001/59/EC and 1999/45/EC - 2001/60/EC directives.


SDS-504/EN S29 Do not empty into drains. S51 Use only in well-ventilated areas. Safety data sheet available for professional user on request. Dangerous ingredients: None in a percentage equal to or higher than the limit for the name. 15.2 Type of packaging: According to current legislation. *16. OTHER INFORMATION Intended use Only for professional use. Text of R-phrases listed in section 2: R20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R36/38 Irritating to eyes and skin. Labelling regulations: The information provided in this Material Safety Data Sheet has been written in accordance with 67/548/EEC (Substances), 88/379/EEC (Preparations) and 91/155/EEC (Material Safety Data Sheet) directives. It has been updated to 2001/59/EC (Substances), 2001/60/EC (Preparations) and 2001/58/EC (Material Safety Data Sheet) directives. The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

FICHA DE DATOS DE SEGURIDAD 2001/58/CE Fecha revisión: 27.10.03 FILMAR 470 - FILMAR 480 Página: 1/7

SDS-317/ES 1. DATOS IDENTIFICATIVOS DEL PRODUCTO Y DE LA EMPRESA 1.1 Identificación del preparado: FILMAR 470 Código: 51063 FILMAR 480 Código: 51188 1.2 Uso del preparado: Fondo para náutica. 1.3 Empresa: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - ESPAÑA Teléfono: 972 478 060 - Fax: 972 477 394 - [email protected] - www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) 2. COMPOSICION/INFORMACION SOBRE LOS COMPONENTES Sustancias que intervienen en un porcentaje superior al límite de exención y presentan un peligro para la salud o para el medio ambiente, y/o con un valor límite de exposición reconocido: 10-25 % Xileno R10 R38 R20/21 Xn CAS: 1330-20-7

(mezcla de isómeros) EC No. 215-535-7 SAX: XGS000 No. 601-022-00-9

2,5-10% Acetato de butilo R10 R66 R67 CAS: 123-86-4 EC No. 204-658-1 SAX: BPU750 No. 607-025-00-1

2,5-10% Acetato de 1-metoxipropilo R10 R36 Xi CAS: 108-65-6 EC No. 203-603-9 No. 607-195-00-7 <2,5 % Nafta disolvente (petróleo), aromático ligero R10 R65 R66 R67 R51/53 Xn N CAS: 64742-95-6 EC No. 265-199-0 No. 649-356-00-4 (Nota P) <2,5 % Etilbenceno R11 R20 F Xn CAS: 100-41-4

EC No. 202-849-4 SAX: EGP500 No. 601-023-00-4

Para mayor información sobre componentes peligrosos, ver epígrafes 8, 11, 12 y 16. 3. IDENTIFICACION DE LOS PELIGROS Inflamable. 4. PRIMEROS AUXILIOS En los casos de duda, o cuando persistan los síntomas de malestar, solicitar atención médica. No administrar nunca nada por vía oral a personas que se encuentren inconscientes. 4.1 Por inhalación: Sacar al afectado de la zona contaminada y trasladarlo al aire libre. Si la respiración es irregular o se detiene, practicar la respiración artificial. Si está inconsciente,


SDS-317/ES colocarlo en posición de recuperación apropiada. Mantenerlo cubierto con ropa de abrigo mientras se procura atención médica. 4.2 Por contacto con los ojos: Lavar por irrigación los ojos con abundante agua limpia y fresca durante al menos 15 minutos, hasta que descienda la irritación. Solicitar de inmediato asistencia médica especializada. 4.3 Por contacto con la piel: Despojarse de la ropa contaminada. Lavar a fondo las zonas afectadas con abundante agua fría o templada y jabón neutro, o bien con otro producto adecuado para la limpieza de la piel. No emplear disolventes. 4.4 Por ingestión: En caso de ingestión accidental, requerir asistencia médica inmediata. No provocar el vómito, debido al riesgo de aspiración. Mantener al afectado en reposo. 5. MEDIDAS DE LUCHA CONTRA INCENDIOS 5.1 Medios de extinción: En caso de incendios mas graves también espuma resistente al alcohol y agua pulverizada. No usar para la extinción: chorro directo de agua. 5.2 Riesgos específicos: El fuego puede producir un espeso humo negro. Como consecuencia de la combustión o de la descomposición térmica, pueden formarse productos peligrosos: monóxido de carbono, dióxido de carbono. La exposición a los productos de combustión o descomposición puede ser perjudicial para la salud. 5.3 Equipo de protección antiincendios: Según la magnitud del incendio, puede ser necesario el uso de trajes de protección contra el calor, equipo respiratorio autónomo, guantes, gafas protectoras o máscaras faciales y botas. 5.4 Otras recomendaciones: Refrigerar con agua los tanques, cisternas o recipientes próximos a la fuente de calor o fuego. Tener en cuenta la dirección del viento. Evitar que los productos utilizados en la lucha contra incendio, pasen a desagües, alcantarillas o a cursos de agua. 6. MEDIDAS A TOMAR EN CASO DE VERTIDO ACCIDENTAL 6.1 Precauciones individuales: Eliminar los posibles puntos de ignición y si procede, ventilar la zona. No fumar. Evitar el contacto directo con el producto. Evitar respirar los vapores. Para control de exposición y medidas de protección individual, ver epígrafe 8. 6.2 Precauciones para la protección del medio ambiente: Evitar la contaminación de desagües, aguas superficiales o subterráneas, así como del suelo. En caso de producirse grandes vertidos o si el producto contamina lagos, ríos o alcantarillas, informar a las autoridades competentes, según la legislación local. 6.3 Métodos de limpieza: Recoger el vertido con materiales absorbentes no combustibles (tierra, arena, vermiculita, tierra de diatomeas, etc..). Limpiar, preferiblemente, con detergente. Evitar el empleo de disolventes. Guardar los restos en un contenedor cerrado. Para la posterior eliminación de los residuos, seguir las recomendaciones del epígrafe 13. 7. MANIPULACION Y ALMACENAMIENTO 7.1 Precauciones en la manipulación: Cumplir con la legislación vigente sobre seguridad e higiene en el trabajo. - Recomendaciones generales: Evitar todo tipo de derrame o fuga. No dejar los recipientes abiertos. - Recomendaciones para prevenir riesgos de incendio y explosión: Los vapores son mas pesados que el aire y pueden desplazarse por el suelo a distancias considerables. Los vapores pueden formar con el aire mezclas que al alcanzar fuentes de ignición lejanas pueden inflamarse o explosionar. Debido a la inflamabilidad, este material sólo puede ser utilizado en zonas libres de puntos de ignición y alejado de fuentes de calor o eléctricas. No fumar. El


SDS-317/ES equipo eléctrico debe estar protegido de forma adecuada. No utilizar herramientas que puedan producir chispas. Utilizar equipos protegidos contra explosión. Apagar los teléfonos móviles. - Recomendaciones para prevenir riesgos toxicológicos: No comer, beber ni fumar en las zonas de aplicación y secado. Después de la manipulación, lavar las manos con agua y jabón. Para control de exposición y medidas de protección individual, ver epígrafe 8. 7.2 Condiciones de almacenamiento: Prohibir la entrada a personas no autorizadas. Mantener fuera del alcance de los niños. El producto debe almacenarse aislado de fuentes de calor y eléctricas. No fumar en el área de almacenamiento. Para evitar derrames, los envases, una vez abiertos, se deberán volver a cerrar cuidadosamente y a colocar en posición vertical. Clase de almacén: Clase B1. Según ITC MIE APQ-1, RD.379/2001.Tiempo máximo de stock: 12 meses. Intervalo de temperaturas: min: 5ºC, max: 35ºC. 7.3 Materias incompatibles: Consérvese lejos de agentes oxidantes y de materiales altamente alcalinos o ácidos fuertes 7.4 Condiciones que deben evitarse: Calor: Mantener alejado de fuentes de calor. Luz: Evitar la incidencia directa de radiación solar. Humedad: Evitar condiciones de humedad extremas. 8. CONTROLES DE EXPOSICION/PROTECCION PERSONAL 98/24/CE (RD.374/2001) 8.1 Límites de exposición (TLV) AGCIH 2001 TWA STEL Año

ppm mg/m3 ppm mg/m3 Xileno (mezcla de isómeros) 100 434 150 651 A4 1996 Acetato de butilo 150 713 200 950 1998 Acetato de 1-metoxipropilo 50 275 100 550 Recomendado Nafta disolvente (petróleo), 50 260 Valor interno aromático ligero Etilbenceno 100 434 125 543 1976 A4 - No clasificado como carcinógeno en humanos. 8.2 Medidas de orden técnico: Proveer una ventilación adecuada. Para ello, se debe realizar una buena ventilación local y se debe disponer de un buen sistema de extracción general. Si estas medidas no bastan para mantener la concentración de partículas y vapores por debajo de los límites de exposición durante el trabajo, deberá utilizarse un equipo respiratorio apropiado. - Densidad del vapor: 3.87 Aire = 1 a 20ºC Relativa - Limite explosividad inferior: 1.4 % Volumen - Requerimiento de ventilación: 41 m3/l Aire/Preparado FILMAR 470 42 m3/l Aire/Preparado FILMAR 480 para mantenerse por debajo de 1/10 del límite de explosividad inferior. - Requerimiento de ventilación: 16907 m3/l (máximo) Aire/Preparado para mantenerse por debajo del valor TLV del producto (aplicación por pulverización y suponiendo una eficacia de transferencia del 80%). Se requiere ventilación especial. 8.3 Protección del sistema respiratorio: Evitar la inhalación de vapores. Cuando los operarios se encuentren dentro de la cabina de aplicación, estén aplicando o no, y la ventilación no sea suficiente para controlar continuamente la concentración de partículas y vapor de disolvente, se debe usar un equipo respiratorio con suministro de aire durante el proceso de aplicación, hasta que la concentración de partículas y vapor de disolvente estén por debajo de los límites de exposición. Mascarilla: Mascarilla de carbón activo. 8.4 Protección de los ojos y la cara: Instalar fuentes oculares de emergencia en las proximidades de la zona de utilización. Gafas: Gafas de seguridad contra salpicaduras de líquidos. Escudo facial: No. 8.5 Protección de las manos y la piel: Instalar duchas de emergencia en las proximidades de la zona de utilización. El uso de cremas protectoras puede ayudar a proteger las áreas expuestas


SDS-317/ES de la piel. No deberán aplicarse cremas protectoras una vez se ha producido la exposición. Guantes: Guantes protectores de material adecuado. Botas: No. Delantal: No. Mono: Se deberá usar ropa antiestática hecha de fibra natural o de fibra sintética resistente a altas temperaturas. 9. PROPIEDADES FISICAS Y QUIMICAS - Forma física: Líquido viscoso - Color: Blanco/Negro - Olor: Característico - Viscosidad: 50000 cps a 20ºC Brookfield - Peso específico: 1.61 g/cc a 20ºC FILMAR 470 - 1.51 g/cc a 20ºC FILMAR 480 - Temperatura de ebullición: 126.3ºC a 760 mmHg - Temperatura de inflamación: 27ºC Setaflash - Temperatura autoignición: 402.2ºC - Temperatura descomposición: 350ºC - Presión de vapor: 6.9 mmHg a 20ºC 10. ESTABILIDAD Y REACTIVIDAD 10.1 Estabilidad: Estable bajo las condiciones recomendadas de almacenamiento y manipulación. 10.2 Reacciones peligrosas: Posible reacción peligrosa con agentes oxidantes, ácidos, álcalis, peróxidos. 10.3 Descomposición térmica: Como consecuencia de la descomposición térmica, pueden formarse productos peligrosos. 11. INFORMACIONES TOXICOLOGICAS No se dispone de datos toxicológicos experimentales del preparado como tal. 11.1 Efectos toxicológicos: La exposición a concentraciones de vapores de disolvente por encima del límite de exposición ocupacional establecido, puede producir efectos adversos para la salud, tales como irritación de la mucosa o aparato respiratorio, así como efectos adversos en los riñones, hígado y sistema nervioso central. Entre los síntomas cabe citar: dolor de cabeza, vértigo, fatiga, debilidad muscular, somnolencia y en casos extremos, pérdida de consciencia. Su ingestión puede producir los siguientes efectos: irritación de garganta, dolor abdominal, somnolencia, náuseas, vómitos y diarrea; otros efectos pueden ser iguales a los descritos en la exposición a los vapores. El contacto repetido o prolongado con los disolventes del preparado, puede provocar la eliminación de la grasa natural de la piel, dando como resultado dermatitis de contacto no alérgica y absorción a través de la piel. Las salpicaduras en los ojos pueden causar irritación y daños reversibles. 11.2 Dosis y concentraciones letales de componentes individuales :

DL50 Oral DL50 Cutánea CL50 Inhalación mg/kg mg/kg mg/l.4horas

Xileno (mezcla de isómeros) 4300 Rata 1700 Conejo 22 Rata Acetato de butilo 13100Rata 5000 Conejo 9.7 Rata Acetato de 1-metoxipropilo 8532 Rata Nafta disolvente (petróleo), 3900 Rata 3160 Conejo 14 Rata aromático ligero Etilbenceno 3500 Rata 17800 Conejo


SDS-317/ES Para mayor información sobre componentes peligrosos para la salud, ver epígrafes 2 y 8. 12. INFORMACIONES ECOLOGICAS Evitar la penetración en el terreno. No se debe permitir que el producto pase a desagües, alcantarillas ni a cursos de agua. Emisiones a la atmósfera: Evitar la emisión de disolventes a la atmósfera. - COV: 390 g/l FILMAR 470 ASTM D-3960 402 g/l FILMAR 480 - Hidrocarburos aromáticos: 14% Peso 12.1 Ecotoxicidad. No se dispone de datos ecotoxicológicos experimentales del preparado como tal. Datos ecotoxicológicos de componentes individuales :

CL50 CE50 CI50 mg/l.96horas mg/l.48horas mg/l.72horas

Xileno (mezcla de isómeros) 75 Peces 16 Dafnia Acetato de butilo 18 Peces 10 Dafnia 21 Algas Nafta disolvente (petróleo), 9.2 Peces 6.1 Dafnia aromático ligero Etilbenceno 12 Peces 33 Algas 12.2 Mobilidad : N/D 12.3 Persistencia y degradabilidad: En el agua: t ½ vida = 29 - 144 horas (Xileno) En el aire: t ½ vida = 1 - 18 horas (Xileno) 12.4 Potencial de bioacumulación : log Pow = 1.82 (Acetato de butilo ) log Pow = 3.12 - 3.20 (Xileno) FBC = 14 (Acetato de butilo ) N/D: No disponible. 13. CONSIDERACIONES SOBRE LA ELIMINACION 13.1 Manipulación de residuos: Tomar todas las medidas que sean necesarias para evitar al máximo la producción de residuos. Analizar posibles métodos de revalorización o reciclado. No verter en desagües o en el medio ambiente. Elimínese en un punto autorizado de recogida de residuos. Los residuos deben manipularse y eliminarse de acuerdo con las legislaciones local/nacional vigentes. Para control de exposición y medidas de protección individual, ver epígrafe 8. 13.2 Eliminación de envases vacíos: Los envases vacíos y embalajes deben eliminarse de acuerdo con las legislaciones local/nacional vigentes. 13.3 Procedimientos de neutralización o destrucción del producto: Incineración controlada en plantas especiales de residuos químicos, pero de acuerdo con las reglamentaciones locales. 14. INFORMACIONES RELATIVAS AL TRANSPORTE PINTURAS (Ti>23ºC, viscoso según 2.2.3.1.5 ) 14.1 Tierra: Transporte por carretera: ADR-2003

Transporte en ferrocarril: RID Mercancía no sometida a la Clase 3.¹


SDS-317/ES

¹ Transporte según 2.2.3.1.5 para líquidos viscosos en embalajes con capacidad inferior a 450 L

Documento de transporte: Carta de Porte

Instrucciones escritas 14.2 Mar: Transporte en barco: IMDG

Clase: 3 ONU nº1263 Contaminante marino: no Grupo de embalaje: III Ficha de Emergencia (FEm): 3-05,07 Guía de Primeros Auxilios (GPA): 310, 313 Documento de transporte: Conocimiento de embarque

14.3 Aire: Transporte en avión: IATA/ICAO Clase: 3 ONU nº1263 Grupo de embalaje: III Documento de transporte: Conocimiento aéreo.

15. INFORMACIONES REGLAMENTARIAS 15.1 Etiquetado CE: El producto es INFLAMABLE según la Directiva 67/548/CEE - 2001/59/CE y 1999/45/CE - 2001/60/CE. R10 Inflamable. S23 No respirar los vapores, aerosoles. S36/37 Úsense indumentaria y guantes de protección adecuados. S51 Úsese únicamente en lugares bien ventilados. Componentes peligrosos: Ninguno en porcentaje igual o superior al límite para el nombre. 15.2 Tipo de envase: Según las disposiciones vigentes. 16. OTRAS INFORMACIONES Utilizaciones Unicamente para uso profesional. Texto de las Frases R referenciadas en el epígrafe 2: R10 Inflamable. R11 Fácilmente inflamable. R20 Nocivo por inhalación. R36 Irrita los ojos. R38 Irrita la piel. R65 Nocivo: si se ingiere puede causar daño pulmonar. R66 La exposición repetida puede provocar sequedad o formación de grietas en la piel. R67 La inhalación de vapores puede provocar somnolencia y vértigo. R20/21 Nocivo por inhalación y en contacto con la piel. R51/53 Tóxico para los organismos acuáticos, puede provocar a largo plazo efectos negativos

en el medio ambiente acuático. Nota P: No es necesario aplicar la clasificación como carcinógeno si puede demostrarse que la sustancia contiene menos del 0.1% en peso de benceno (EC No.200-753-7).


SDS-317/ES Legislaciones sobre etiquetado: La información facilitada en esta Ficha de Datos de Seguridad ha sido redactada de acuerdo con las directivas 67/548/CEE (Sustancias), 88/379/CEE (Preparados) y 91/155/CEE (Ficha de Datos de Seguridad). Ha sido actualizada hasta las directivas 2001/59/CE (Sustancias), 2001/60/CE (Preparados) y 2001/58/CE (Ficha de Datos de Seguridad). La información de esta Ficha de Datos de Seguridad, está basada en los conocimientos actuales y en las leyes vigentes de la UE y nacionales, en cuanto que las condiciones de trabajo de los usuarios están fuera de nuestro conocimiento y control. El producto no debe utilizarse para fines distintos a aquellos que se especifican, sin tener primero una instrucción por escrito, de su manejo. Es siempre responsabilidad del usuario tomar las medidas oportunas con el fin de cumplir con las exigencias establecidas en las legislaciones vigentes. La información contenida en esta Ficha de Seguridad sólo significa una descripción de las exigencias de seguridad del preparado y no hay que considerarla como una garantía de sus propiedades.

* MATERIAL SAFETY DATA SHEET 91/155/EEC Revision date: 26.03.02 FLEXILAC Page: 1/6

SDS-715/EN *1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: FLEXILAC Code: 51243 1.2 Use of the preparation: Plasticiser for 2K products. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) 2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 10-25 % n-butyl acetate R10 R66 R67 CAS: 123-86-4

EC No. 204-658-1 SAX: BPU750 No. 607-025-00-1

2,5-10 % 1-methoxypropyl acetate R10 R36 Xi CAS: 108-65-6 EC No. 203-603-9 No. 607-195-00-7

2,5-10 % Xylene (mixture of isomers) R10 R38 R20/21 Xn CAS: 1330-20-7 EC No. 215-535-7 SAX: XGS000 No. 601-022-00-9

2,5-10 % Ethylbenzene R11 R20 F Xn CAS: 100-41-4 EC No. 202-849-4 SAX: EGP500 No. 601-023-00-4

For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Flammable. Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and dizziness. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately.


SDS-715/EN 4.3 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. In the case of skin reddening or rashes, contact a doctor immediately. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: In case of fire, use water spray, alcohol-resistant foam, dry chemical powder, carbon dioxide, AFFF. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sewages, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Clean preferably with a detergent. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed. Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. Recommendations for the prevention of toxicological risks: Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8.


SDS-715/EN 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. Keep away from living quarters. Keep away from food, drink and animal foodstuffs. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Class B1. According to ITC MIE APQ-1, RD.379/2001. Maximum storage period: 12 months. Temperature interval: min:5ºC, max: 35ºC. 7.3 Materials to avoid: Keep away from oxidizing agents, acids, alkalis, peroxides. 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION (98/24/CE) 8.1 Occupational Exposure Limits (TLV) AGCIH 2000


n-butyl acetate 150 713 200 950 1998 Xylene (mixture of isomers) 100 434 150 651 A4 1996 Ethylbenzene 100 434 125 543 1976 A4 - Non classified as carcinogenic in humans. 8.2 Engineering measures: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particulates and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. - Vapour density: 3.97 Air = 1 at 20ºC Relative - Lower explosive limit: 1.4% Volume - Ventilation requirement: 34 m3/l Air/Preparation to keep below 1/10 of the Lower Explosive Limit. - Ventilation requirement: 5897 m3/l (maximum) Air/Preparation to keep below the Occupational Exposure Limit of the product. Special ventilation is required. 8.3 Protection of respiratory system: Avoid the inhalation of vapours. Mask: Filter mask. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles designed to protect against liquid splashes. Face shield: No. 8.5 Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Personnel should wear antistatic clothing made of natural fibre or of high temperature resistant synthetic fibre. 9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Liquid - Colour: Colourless - Odour: Characteristic - Viscosity: 33 sec.FC4 20ºC - Specific gravity: 1.03 g/cc at 20ºC - Boiling point: 126.3ºC at 760 mmHg - Flash point: 26.8ºC Setaflash - Autoignition temperature: 371.7ºC - Vapour pressure: 7.3 mmHg at 20ºC


SDS-715/EN 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents, acids, alkalis, peroxides. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced. 11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. 11.2 Dose and lethal concentrations for individual ingredients:


n-butyl acetate 13100Rat 5000 Rabbit 9.7 Rat 1-methoxypropyl acetate 8532 Rat Xylene (mixture of isomers) 4300 Rat 1700 Rabbit 22 Rat Ethylbenzene 3500 Rat 17800Rabbit For more information about ingredients dangerous to health, see sections 2 and 8. 12. ECOLOGICAL INFORMATION No experimental ecotoxicological data on the preparation as such is available. 12.1 Spills on the soil: Prevent contamination of soil. 12.2 Spills in water: Do not allow to escape into drains, sewers or water courses. 12.3 Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - VOC: 473.8 g/l ASTM D-3960 - Aromatic hydrocarbons: 11.6% Weight 12.4 Ecotoxicological data for individual ingredients:


n-butyl acetate 18 Fishes Xylene (mixture of isomers) 75 Fishes 16 Daphnia Ethylbenzene 12 Fishes 33 Algae 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into


SDS-715/EN drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. 14. TRANSPORT INFORMATION PAINT 14.1 Land: Transport by road: ADR-1999

Transport by rail: RID/TPF Class: 3 Item: 31c UN nº1263 Packaging group: III Transport document: Consignment paper

14.2 Sea: Transport by ship: IMDG Class: 3.3 UN nº1263 Marine pollutant: no Packaging group: III IMDG Code Page: 3372 Emergency Sheet (EmS): 3-05 First Aid Guide (MFAG): 310, 313 Transport document: Shipping Bill of Lading



15. INFORMATION ON REGULATIONS CONCERNING PACKAGING AND LABELLING 15.1 EC Labelling: This product is flammable in accordance with RD.363/1995 (67/548/CEE) and RD.1078/1993 (88/379/CEE). R10 Flammable. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. S24/25 Avoid contact with skin and eyes. S51 Use only in well-ventilated areas. Dangerous ingredients: None in a percentage equal to or higher than the limit for the name.

15.2 Type of packaging: According to current legislation. 16. OTHER INFORMATION Intended use Liquid paint. Only for professional use.


SDS-715/EN Text of R-phrases listed in section 2: R10 Flammable. R11 Highly flammable. R20 Harmful by inhalation. R36 Irritating to eyes. R38 Irritating to skin. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. R20/21 Harmful by inhalation and in contact with skin. Labelling regulations: The information provided in this Material Safety Data Sheet has been written in accordance with annex III of RD.1078/1993 (88/379/EEC and 91/155/EEC) dated on July 2, published in the BOE on September 9, 1993 updated to the RD.1425/1998 (96/65/EC and 93/112/EEC) dated on July 3, published in the BOE on July 4, 1998, and also with RD.363/1995 (67/548/EEC) dated on March 10, published in the BOE on June 5, 1995, which approves the Regulations on Notification of New Substances and Classification, Packaging and Labelling of Dangerous Substances, whose technical annexes have been updated to the Order of April 5, 2001 (2000/32/EC and 2000/33/EC), published in the BOE on April 19, 2001. The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 28.10.05 FUTURA GLASS Page: 1/6

SDS-112/EN 1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: FUTURA GLASS Code: 51572 1.2 Use of the preparation: Bodywork repair unsaturated polyester paste. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) *2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health and/or environment hazard, and/or with a Communitary workplace exposure limit: 10-25 % Styrene EC: 202-851-5 R10 Xn; R20 Xi; R36/38 CAS: 100-42-5 No. 601-026-00-0 For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Flammable. Harmful by inhalation. Irritating to eyes. Irritating to skin. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. 4.3 By contact with eyes: Remove contact lenses. Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: Extinguishing powder or CO2. In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon


SDS-112/EN monoxide, carbon dioxide. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sews, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Avoid use of solvents. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. *7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed. - Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. - Flash point: 32ºC Setaflash - Autoignition temperature: 490ºC - Flammability range: 1,1 – 6,4 % Volume 25ºC - Flammability range: 0,8 – 9,0 % Volume 300ºC - Recommendations for the prevention of toxicological risks: Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Class B1. According to. ITC MIE APQ-1, RD 379/2001. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 32ºC. - Combustion heat: 3898 Kcal/kg - ncompatible materials: Keep away from oxidizing agents, from strongly alkaline and strongly acid materials. - Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions. - Type of packaging: According to current legislation.


SDS-112/EN *8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC 8.1 Occupational Exposure Limits: INSHT 2005: Spain VLA-ED-

ppm: VLA-ED-mg/m3:

VLA-EC -ppm:

VLA-EC -mg/m3: Notes:

100-42-5 20 86 40 172 VLB, ae INRS ND 2098, 02/2005:

France VME-ppm VME-mg/m3 VLE-ppm VLE-

mg/m3 Notes: TMP N°

100-42-5 50 215 - - - 84 DFG 2004:

Germany MAK-ppm: MAK-mg/m3: Note:

100-42-5 20 86 DFG, Y ACGIH 2004:

ACGIH(TLV) TWA-ppm: TWA-mg/m3:

STEL-ppm:

STEL-mg/m3: Note:

100-42-5 20 85 40 170 A4 2000/39/EC and 98/24/EC:

EC TWA-ppm: TWA-mg/m3: STEL-ppm: STEL-

mg/m3: Notes:

- - - - - - 8.2 Occupational exposure controls, Directive 89/686/EEC: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particulates and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. - Protection of respiratory system: Avoid the inhalation of vapours. Mask: Mask for gases and vapours (EN141). In order to obtain a suitable protection level, the filter class must be selected depending on the type and concentration of the contaminating agents present, in accordance with the specifications supplied by the filter producers. The respiratory equipment with filters does not work satisfactorily when the air contains high concentrations of vapour. - Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles with suitable lateral protection (EN166). Face shield: No. - Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Gloves resistant against chemicals (EN374). The breakthrough time of the selected glove material should be superior to the pretended period of use. The gloves should be immediately replaced when any sign of degradation is noted. Boots: No. Apron: No. Clothing: Suitable work clothes which avoid contact with the product should be worn. 8.3 Environmental exposure controls: Avoid any spillage in the environment of the product, wastes, packages or spraybooth sewages. Avoid any release into the atmosphere above the legal limits allowed. *9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Paste - Colour: Blue - Odour: Characteristic - Viscosity: 13 x 106 cps 20ºC Brookfield


SDS-112/EN - Specific gravity: 1,22 g/cc a 20ºC - Solubility in water (styrene): 310 mg/l - Boiling point: 145,2ºC at 760 mmHg - Flash point: 32ºC Setaflash - Vapour pressure: 4,5 mmHg at 20ºC 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents, acids, alkalis, peroxides. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced. 11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. 11.2 Dose and lethal concentrations for individual ingredients:


Styrene 2650 Rat 12 Rat For more information about ingredients dangerous to health, see sections 2 and 8. *12. ECOLOGICAL INFORMATION No experimental ecotoxicological data on the preparation as such is available. 12.1 Spills on the soil: Prevent contamination of soil. 12.2 Spills in water: Do not allow to escape into drains, sewers or water courses. 12.3 Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - Mixing application VOC: 6 g/l ASTM D-3960 - Aromatic hydrocarbons: 18,7 % Weight 12.4 Ecotoxicological data for individual ingredients: CL50 CE50 CI50

mg/l.96hours mg/l.48hours mg/l.72hours Styrene 255 Dafnia


SDS-112/EN *13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste, Directive 75/442/EEC~91/156/EC: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers, Directive 94/62/EC: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. *14. TRANSPORT INFORMATION 14.1 Transport by road, Directive 94/55/EC (ADR 2005): Free Transport by rail, Directive 96/49/EC (RID 2005): Free 14.2 Transport by sea (IMDG 32-04): Free 14.3 Transport by air (ICAO/IATA): Free *15. INFORMATION ON REGULATIONS 15.1 EC Labelling Xn This product is FLAMMABLE and HARMFUL in accordance with Guideline 67/548/EEC - 2004/73/EC and 1999/45/EC - 2001/60/EC. R10 Flammable. R20 Harmful by inhalation. R36/38 Irritating to eyes and skin. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S51 Use only in well-ventilated areas. Dangerous ingredients: Styrene · It is applicable the Directive 2004/42/EC, Annex I.2): Emission subcategory B). VOC (product ready for use): 6 g/l, VOC max: 250 g/l starting from 01.01.2007 15.2 Restrictions to the marketing and use in accordance with Directive 76/769/EEC: Not applicable. 15.3 Other regulations: Not available. *16. OTHER INFORMATION Intended use: Only for professional use. Text of R-phrases listed in section 2: R10 Flammable. R20 Harmful by inhalation. R36/38 Irritating to eyes and skin. Material Safety Data Sheet regulations: Material Safety Data Sheet in accordance with Directive 91/155/EEC~2001/58/EC.


SDS-112/EN The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 12.12.05 FUTURA PLUS Page: 1/6

SDS-012/EN 1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: FUTURA PLUS Code: 51571 1.2 Use of the preparation: Bodywork repair unsaturated polyester paste. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) 2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health and/or environment hazard, and/or with a Communitary workplace exposure limit: 10-25 % Styrene EC: 202-851-5 R10 Xn; R20 Xi; R36/38 CAS: 100-42-5 No. 601-026-00-0 < 2,5 % Ethyl acetate EC: 205-500-4 F; R11 Xi; R36 R66-R67 CAS: 141-78-6 No. 607-022-00-5 For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Flammable. Harmful by inhalation. Irritating to eyes. Irritating to skin. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. 4.3 By contact with eyes: Remove contact lenses. Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: Extinguishing powder or CO2. In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use for extinguishing: direct water jet.


SDS-012/EN 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sews, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Avoid use of solvents. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. *7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed. - Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. - Flash point: 32ºC Setaflash - Autoignition temperature: 482,5ºC - Flammability range: 1,2 – 6,7 % Volume 25ºC - Recommendations for the prevention of toxicological risks: Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Class B1. According to. ITC MIE APQ-1, RD 379/2001. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 32ºC. - Combustion heat: 5178 Kcal/kg - ncompatible materials: Keep away from oxidizing agents, from strongly alkaline and strongly acid materials. - Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions.


SDS-012/EN - Type of packaging: According to current legislation. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC 8.1 Occupational Exposure Limits: INSHT 2005: Spain VLA-ED-

ppm: VLA-ED-mg/m3:

VLA-EC -ppm:


100-42-5 20 86 40 172 VLB, ae 141-78-6 400 1460 - - - INRS ND 2098, 02/2005:



100-42-5 50 215 - - - 84 141-78-6 400 1400 - - - 84 DFG 2004:


100-42-5 20 86 DFG, Y 141-78-6 400 1500 DFG, Y ACGIH 2004:


STEL-ppm:

STEL-mg/m3: Note:

100-42-5 20 85 40 170 A4 141-78-6 400 1440 - - - 2000/39/EC and 98/24/EC:


mg/m3: Notes:

- - - - - - 8.2 Occupational exposure controls, Directive 89/686/EEC: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particulates and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. - Protection of respiratory system: Avoid the inhalation of vapours. Mask: Mask for gases and vapours (EN141). In order to obtain a suitable protection level, the filter class must be selected depending on the type and concentration of the contaminating agents present, in accordance with the specifications supplied by the filter producers. The respiratory equipment with filters does not work satisfactorily when the air contains high concentrations of vapour. - Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles with suitable lateral protection (EN166). Face shield: No. - Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Gloves resistant against chemicals (EN374). The breakthrough time of the selected glove material should be superior to the pretended period of use. The gloves should be immediately replaced when any sign of degradation is noted. Boots: No. Apron: No. Clothing: Suitable work clothes which avoid contact with the product should be worn. 8.3 Environmental exposure controls: Avoid any spillage in the environment of the product, wastes, packages or spraybooth sewages. Avoid any release into the atmosphere above the legal limits allowed.


SDS-012/EN *9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Paste - Colour: Blue - Odour: Characteristic - Viscosity: 7 x 106 cps 20ºC Brookfield - Specific gravity: 0,85 g/cc a 20ºC - Solubility in water (styrene): 310 mg/l - Boiling point: 77,1ºC at 760 mmHg - Flash point: 32ºC Setaflash - Vapour pressure: 10,9 mmHg at 20ºC 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents, acids, alkalis, peroxides. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced. *11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. 11.2 Dose and lethal concentrations for individual ingredients:


Styrene 2650 Rat 12 Rat Ethyl acetate 5620 Rat 20000 Rabbit 200 Rat For more information about ingredients dangerous to health, see sections 2 and 8. 12. ECOLOGICAL INFORMATION No experimental ecotoxicological data on the preparation as such is available. 12.1 Spills on the soil: Prevent contamination of soil. 12.2 Spills in water: Do not allow to escape into drains, sewers or water courses. 12.3 Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - Mixing application VOC: 8 g/l ASTM D-3960 - Aromatic hydrocarbons: 23,8 % Weight


SDS-012/EN 12.4 Ecotoxicological data for individual ingredients: CL50 CE50 CI50

mg/l.96hours mg/l.48hours mg/l.72hours Styrene 255 Dafnia 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste, Directive 75/442/EEC~91/156/EC: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers, Directive 94/62/EC: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. 14. TRANSPORT INFORMATION 14.1 Transport by road, Directive 94/55/EC (ADR 2005): Free Transport by rail, Directive 96/49/EC (RID 2005): Free 14.2 Transport by sea (IMDG 32-04): Free 14.3 Transport by air (ICAO/IATA): Free 15. INFORMATION ON REGULATIONS 15.1 EC Labelling Xn This product is FLAMMABLE and HARMFUL in accordance with Guideline 67/548/EEC - 2004/73/EC and 1999/45/EC - 2001/60/EC. R10 Flammable. R20 Harmful by inhalation. R36/38 Irritating to eyes and skin. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S51 Use only in well-ventilated areas. Dangerous ingredients: Styrene · It is applicable the Directive 2004/42/EC, Annex I.2): Emission subcategory B). VOC (product ready for use): 8 g/l - 0,07 lb/gal, VOC max: 250 g/l starting from 01.01.2007 15.2 Restrictions to the marketing and use in accordance with Directive 76/769/EEC: Not applicable. 15.3 Other regulations: Not available. 16. OTHER INFORMATION Intended use Only for professional use.


SDS-012/EN Text of R-phrases listed in section 2: R10 Flammable. R11 Highly flammable. R20 Harmful by inhalation. R36 Irritating to eyes. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. R36/38 Irritating to eyes and skin. Material Safety Data Sheet regulations: Material Safety Data Sheet in accordance with Directive 91/155/EEC~2001/58/EC. The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 03.02.04 HARDENER LIQUID FOR POLYESTER Page: 1/7

SDS-628/EN 1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: HARDENER LIQUID FOR POLYESTER Code: 51226 1.2 Use of the preparation: B Component for polyester products. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) 2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 50-100% Dimethyl phthalate CAS: 131-11-3

EC No. 205-011-6 SAX: DTR200

25-50% Ethylmethylketone peroxide R2 R7 R22 R34 O C CAS: 1338-23-4

EC No. 215-661-2 SAX: MKA500

< 2,5 % Ethylmethylketone R11 R36 R66 R67 F Xi CAS: 78-93-3

EC No. 201-159-0 SAX: MKA400 No. 606-002-00-3

For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS May cause fire. Harmful if swallowed. Corrosive. Causes burns. Causes burns to the skin or eyes by direct contact or to the digestive tract if swallowed. The mists of fine particles are skin and respiratory tract irritants. 4. FIRST AID MEASURES In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. If possible, alternate the rinsing with a 5% solution of sodium ascorbate in water or a 2% solution of sodium bicarbonate in water. Both solutions should not to be more than 4 weeks old. Do not apply oils. Call a physician immediately.


SDS-628/EN 4.3 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Apply lanolin ointment. In the event of cutaneous eruptions contact a doctor. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. If there has been any contact with the mouth, rinse out with large quantities of water only. Do not induce vomiting, due to the risk of perforation. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES Not combustible, but helps to cause combustion of other substances. 5.1 Means of Extinction: Extinguishing powder or CO2. In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use for extinguishing: halon. 5.2 Specific risks: As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sewages, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Clean preferably with a detergent. Do not use rags. The peroxide impregnated absorbent must be placed in a safe place and not put into a container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Handle with care, avoiding any discharge. Do not weigh it in the storage area. Avoid friction, rough handling or strong impacts. Avoid any type of leakage or escape. Keep the container tightly closed. - Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used.


SDS-628/EN Recommendations for the prevention of toxicological risks: Do not eat, drink or smoke while handling. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. Keep in a cool place. Keep container in a well-ventilated place. In order to avoid leakages, the containers, after use, should be closed carefully and placed in a vertical position. Due to its corrosive properties, extreme precaution in the selection of materials for pumps, packages and lines should be taken. The floor must be waterproof and corrosion resistant, with a canal system allowing the liquid to be channelled towards a neutralising pit. The electrical equipment must be made of non-corrodible materials. Class of store: Class Xn. According to ITC MIE APQ-4, RD 379/2001. Temperature interval: min: 5ºC, max: 25ºC. 7.3 Incompatible materials: Keep away from reducing agents, oxidizing agents, acids, alkalis, amines, metals, heavy-metal compounds. 7.4 Conditions to avoid: Heat: This preparation is quite stable at normal temperatures (around 20ºC). However, at higher temperatures an exo-thermic decomposing reaction takes place. In the event of the decomposition taking place so fast that the heat only partially dissipates, an increased acceleration of the product's temperature occurs, finally giving rise to an auto-accelerated breaking down of the organic peroxide. Depending on the circumstances, eg. the amount, the degree of containment, etc.., intense decomposition, auto-ignition or even an explosion may take place. Light: Avoid direct contact with sunlight as this could cause a rise in temperature, with the subsequent danger of the peroxide decomposing. Humidity: Avoid extreme humidity conditions. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC 8.1 Occupational Exposure Limits (TLV) AGCIH 2001

TWA STEL C - Ceiling value. Year

ppm mg/m3 ppm mg/m3 Dimethyl phthalate 5.0 1986 Ethylmethylketone peroxide 0.20 1.5 C 1977 Ethylmethylketone 200 590 300 885 1976 8.2 Engineering measures: Explosion-proof ventilation is recommended. 8.3 Protection of respiratory system: Avoid the inhalation of vapours. When operators, whether spraying or not, are inside the spraybooth, and ventilation is unlikely to be sufficent to constantly control particles and solvent vapour in all cases, in such circumstances they should wear a compressed air-fed respirator during the spraying process and until such a time as the particles and solvent vapour concentration has fallen below the exposure limits. Mask: Filter mask. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles for chemicals. Face shield: Recommendable when peroxides are handled in large amounts. 8.5 Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Neoprene rubber gloves. Boots: Neoprene rubber boots. Apron: No. Clothing: Clothing resistant to corrosive products will have to be worn. Put away work clothes under control and separately from the rest. Do not take contaminated clothing home. Wash contaminated work clothes before wearing them again.


SDS-628/EN 9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Liquid - Colour: Colourless - Odour: Characteristic - Viscosity: 20 mPa.s 20ºC - Specific gravity: 1.14 g/cc at 25ºC - Available peroxydic oxygen: 3.09 % OO - Solubility in water: Not miscible - Flash point : 70ºC Setaflash - Autoignition temperature: 558.8ºC - Descomposition temperature: 70ºC 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with reducing agents, oxidizing agents, acids, alkalis, amines, metals, heavy-metal compounds. Special care must be taken under all circumstances that there is no direct contact with accelerators, given that a violent decomposition could take place or even an explosion. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous decomposition products may be produced, such as: oxygen. The vapours given off on decomposing are inflammable, therefore any source of ignition could cause a fire. 11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Some organic peroxides will cause serious, irreversible ocular injuries to the cornea, even after brief contact. Causes burns to the skin or eyes by direct contact or to the digestive tract if swallowed. The mists of fine particles are skin and respiratory tract irritants. 11.2 Dose and lethal concentrations for individual ingredients :

DL50 Oral DL50 Cutaneous CL50 Inhalation mg/kg mg/kg mg/l.4hours Dimethyl phthalate 6800 Rat 4800 Rat 10000 Rabbit Ethylmethylketone peroxide 480 Rat 1.5 Rat Ethylmethylketone 2737 Rat 6480 Rabbit 24 Rat For more information about ingredients dangerous to health, see sections 2 and 8.


SDS-628/EN 12. ECOLOGICAL INFORMATION Prevent contamination of soil. Do not allow to escape into drains, sewers or water courses. Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - VOC: 752 g/l ASTM D-3960 12.1 Ecotoxicity: No experimental ecotoxicological data on the preparation as such is available. Ecotoxicological data for individual ingredients :

CL50 CE50 CI50 mg/l.96hours mg/l.48hours mg/l.72hours Ethylmethylketone peroxide 44 Fishes 12.2 Mobility : N/A 12.3 Persistence and degradability : N/A 12.4 Bioaccumulative potential : log Pow = 1.47 – 2.12 (Dimethyl phthalate) log Pow = 0.29 (Ethylmethylketone) BCF : Fishes 5.4 - 24 hours (Dimethyl phthalate) N/A: Not available. 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. Never re-use a container which has contained peroxides. 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. Before burning dilute with organic solvents. 14. TRANSPORT INFORMATION ORGANIC PEROXYDE TYPE D, LIQUID (contains Ethylmethylketone peroxide) 14.1 Land: Transport by road: ADR-2003

Transport by rail: RID Class: 5.2 UN nº3105 Packaging group: II Transport document: Consignment paper Written instructions.

14.2 Sea: Transport by ship: IMDG 30-00 Class: 5.2 UN nº3105 Marine pollutant: no Packaging group: II Emergency Sheet (EmS): 5.2-01 First Aid Guide (MFAG): 735 Transport document: Shipping Bill of Lading


SDS-628/EN 14.3 Air: Transport by plane: IATA/ICAO

Class: 5.2 UN nº3105 Packaging group: II Transport document: Air Bill of Lading

15. INFORMATION ON REGULATIONS 15.1 EC Labelling: O, C This product is OXIDIZING and CORROSIVE in accordance with Guideline 67/548/EEC - 2001/59/EC and 1999/45/EC - 2001/60/EC. R7 May cause fire. R22 Harmful if swallowed. R34 Causes burns. S3/7 Keep container tightly closed in a cool place. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 Wear suitable protective clothing, gloves and eye/ face protection. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S50 Do not mix with peroxide accelerators or reducing agents. Dangerous ingredients: Ethylmethylketone peroxide 15.2 Type of packaging: According to current legislation. 16. OTHER INFORMATION Intended use Catalyst, mainly for the hardening of unsaturated polyesthers. Only for professional use. Text of R-phrases listed in section 2: R2 Risk of explosion by shock, friction, fire or other sources of ignition. R7 May cause fire. R11 Highly flammable. R22 Harmful if swallowed. R34 Causes burns. R36 Irritating to eyes. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. Labelling regulations: The information provided in this Material Safety Data Sheet has been written in accordance wit 67/548/EEC (Substances), 88/379/EEC (Preparations) and 91/155/EEC (Material Safety Data Sheet) directives. It has been updated to 2001/59/EC (Substances), 2001/60/EC (Preparations) and 2001/58/EC (Material Safety Data Sheet) directives. The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified,


SDS-628/EN without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 30.08.04 C254 - C354 Page: 1/8

SDS-623/EN 1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: C254 Code: 51473 C354 Code: 52443 1.2 Use of the preparation: B Component for acrylic paints. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) *2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 25-50 % Aliphatic polyisocyanate R43 Xi NLP No. 500-060-2 CAS: 28182-81-2 10-25 % 1-methoxypropyl acetate R10 R36 Xi EC No. 203-603-9 CAS: 108-65-6 No. 607-195-00-7 10-25 % Naphtha solvent (oil), light aromatic R10 R65 R66 R67 R51/53 Xn N EC No. 265-199-0 CAS: 64742-95-6 No. 649-356-00-4 (Note P) 2,5-10 % Xylene (mixture of isomers) R10 R38 R20/21 Xn EC No. 215-535-7 CAS: 1330-20-7 SAX: XGS000 No. 601-022-00-9 2,5-10 % 1,2,4-trimethylbenzene R10 R20 R36/37/38 R51/53 Xn N EC No. 202-436-9 CAS: 95-63-6 SAX: TLL750 No. 601-043-00-3 < 2,5 % n-butyl acetate R10 R66 R67 EC No. 204-658-1 CAS: 123-86-4 SAX: BPU750 No. 607-025-00-1 < 2,5 % Mesitylene R10 R37 R51/53 Xi N EC No. 203-604-4 CAS: 108-67-8 SAX: TLM050 No. 601-025-00-5 < 2,5 % Ethylbenzene R11 R20 F Xn EC No. 202-849-4 CAS: 100-41-4 SAX: EGP500 No. 601-023-00-4 < 1 % Cumene R10 R37 R65 R51/53 Xn N EC No. 202-704-5 CAS: 98-82-8 SAX: COE750 No. 601-024-00-X For more information on dangerous ingredients, see sections 8, 11, 12 and 16.


SDS-623/EN 3. IDENTIFICATION OF HAZARDS Flammable. Harmful by inhalation. Irritating to eyes. May cause sensitization by skin contact. Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. In the case of skin reddening or rashes, contact a doctor immediately. 4.3 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: Extinguishing powder or CO2. In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide, nitrogen oxides, isocyanate vapours, traces of hydrocyanic acid. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sews, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). The contaminated area should be cleaned up immediately with a suitable decontaminant. One possible (flammable) decontaminant comprises: water/ethanol or isopropanol/concentrated ammonia solution (d=0,880) = 45/50/5 parts by volume. Another possible (non-flammable) decontaminant is made up of water/sodium carbonate = 95/5 parts by weight. Add the same decontaminant to any residues and allow to stand for several days in an unsealed container until no further reaction occurs. Keep the


SDS-623/EN remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed. Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. Recommendations for the prevention of toxicological risks: People with a history of asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which isocyanate containing products are used. Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. Keep away from food, drink and animal foodstuffs. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Class B1. According to ITC MIE APQ-1, RD.379/2001. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 35ºC. 7.3 Incompatible materials: Keep away from water, oxidizing agents, acids, alkalis, amines, alcohols, peroxides. 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Precautions should be taken to minimise exposure to atmospheric humidity or water, as carbon dioxide may be formed which, in closed containers can result in pressurisation. Care should be taken when re-opening partly used containers. Due to the sensitivity to humidity of the isocyanates, this product should be kept in the original container, or under pressure of dried nitrogen, for example. *8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC People with a history of asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which isocyanate containing products are used. 8.1 Occupational Exposure Limits (TLV) AGCIH 2002 TWA STEL Year ppm mg/m3 ppm mg/m3 1-methoxypropyl acetate 50 275 100 550 Recommended Dermal Naphtha solvent (oil), 50 260 Internal value light aromatic Xylene (mixture of isomers) 100 434 150 651 A4 1996 n-butyl acetate 150 713 200 950 1998 1,2,4-trimethylbenzene 25 123 1987 Mesitylene 25 123 1987


SDS-623/EN TWA STEL Year ppm mg/m3 ppm mg/m3 Ethylbenzene 100 434 125 543 1976 Cumene 50 246 1999 A4 - Non classified as carcinogenic in humans. 8.2 Engineering measures: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particles and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. Vapour density: 4,08 Air = 1 at 20ºC Relative (C254) 4,09 Air = 1 at 20ºC Relative (C354) Lower explosive limit: 1,4 % Volume Ventilation requirement: 82 m3/l Air/Preparation (C254) 78 m3/l Air/Preparation (C354) to keep below 1/10 of the Lower Explosive Limit. 8.3 Protection of respiratory system: Avoid the inhalation of vapours. If the working area is insufficiently ventilated, or when operators, whether spraying or not, are inside the spraybooth, air-fed respiratory protective equipment is required. - Mask: For short periods of work, an air-fed mask or a combination of charcoal filter and particle filter mask is recommended. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles designed to protect against liquid splashes. Face shield: No. 8.5 Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Personnel should wear antistatic clothing made of natural fibre or of high temperature resistant synthetic fibre. Wash contaminated work clothes before wearing them again. 9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Liquid - Colour: Colourless - Odour: Characteristic - Viscosity: 12 sec.FC4 20ºC ASTM D 1200-88 - Specific gravity: 1 g/ccc at 20ºC (C254) 1,01 g/cc at 20ºC (C354) - Boiling point: 126,3ºC at 760 mmHg - Flash point: 38ºC Setaflash - Autoignition temperature: 399,2ºC (C254)

398,8ºC (C354) - Vapour pressure: 3,7 mmHg at 20ºC *10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Possible dangerous reaction with water, oxidizing agents, acids, alkalis, amines, alcohols, peroxides. Exothermic reaction with amines and alcohols. Reacts with water under evolution of CO2.


SDS-623/EN 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced: nitrogen oxides, hydrocyanic acid. *11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. - Based on the properties of the isocyanate content of this product and existing technical data of similar preparations, it can be concluded that respiratory exposure may cause acute irritation and/or sensitization of the respiratory system, resulting in asthmatic symptoms, wheezing and a tightness of the chest. Sensitised persons may subsequently show asthmatic symptoms when exposed to airborne concentrations of isocyanates well below the occupational exposure limit. Repeated exposure may lead to permanent respiratory disability. In case of prolonged contact, the skin can dry up and irritation could appear. 11.2 Dose and lethal concentrations for individual ingredients: DL50 Oral DL50 Cutaneous CL50 Inhalation mg/kg mg/kg mg/l.4hours 1-methoxypropyl acetate 8532 Rat Naphtha solvent (oil), 3900 Rat 3160 Rabbit light aromatic Xylene (mixture of isomers) 4300 Rat 1700 Rabbit 22 Rat 1,2,4-trimethylbenzene 5000 Rat n-butyl acetate 10768 Rat 17600 Rabbit 9.7 Rat Ethylbenzene 3500 Rat 17800 Rabbit Cumene 1400 Rat 12300 Rabbit For more information about ingredients dangerous to health, see sections 2 and 8. *12. ECOLOGICAL INFORMATION No experimental ecotoxicological data on the preparation as such is available. 12.1 Spills on the soil: Prevent contamination of soil. 12.2 Spills in water: Harmful to aquatic organisms. May cause long-term adverse effects on the aquatic environment. Do not allow to escape into drains, sewers or water courses. - Hydrolysis: Reacts with water forming carbon dioxide and a solid insoluble product with high melting point (polyurea). This reaction is accelerated by surfactants (e.g. detergents) or by watersoluble solvents. 12.3 Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - VOC: 580 g/l (C254) ASTM D-3960 551 g/l (C354) - Aromatic hydrocarbons: 35,1 % Weight (C254) 32,7 % Weight (C354)


SDS-623/EN 12.4 Ecotoxicological data for individual ingredients: CL50 CE50 CI50 mg/l.96hours mg/l.48hours mg/l.72hours Naphtha solvent (oil), light aromatic 9,2 Fishes 6,1 Daphnia Xylene (mixture of isomers) 75 Fishes 16 Daphnia n-butyl acetate 18 Fishes Mesitylene 13 Fishes Ethylbenzene 12 Fishes 33 Algae 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. 14. TRANSPORT INFORMATION PAINT RELATED MATERIAL (FP>23ºC) 14.1 Land: Transport by road: ADR 2003 Transport by rail: RID Class: 3 Packaging group: III UN no. 1263 Transport document: Consignment paper Written instructions. 14.2 Sea: Transport by ship: IMDG 30-00 Class: 3 Packaging group: III UN no. 1263 Emergency Sheet (EmS): 3-05, 07 First Aid Guide (MFAG): 310, 313 Marine pollutant: Weak Transport document: Shipping Bill of lading 14.3 Air: Transport by plane: IATA/ICAO Class: 3 Packaging group: III UN no. 1263 Transport document: Air Bill of lading 15. INFORMATION ON REGULATIONS 15.1 EC Labelling: Xn This product is FLAMMABLE and HARMFUL in accordance with Guideline 67/548/CEE - 2001/59/CE and 1999/45/CE - 2001/60/CE. R10 Flammable.


SDS-623/EN R20/21 Harmful by inhalation and in contact with skin. R36 Irritating to eyes. R43 May cause sensitization by skin contact. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S23 Do not breathe vapour/spray. S24/25 Avoid contact with skin and eyes. S36/37 Wear suitable protective clothing and gloves. S51 Use only in well-ventilated areas. P91 Contains isocyanates. See information supplied by the manufacturer. Dangerous ingredients: Aliphatic polyisocyanate 15.2 Type of packaging: According to current legislation. 16. OTHER INFORMATION Intended use This material is to be used as a hardener component, in combination with hydroxylated polymers, mainly polyesthers and polyacrylates, in order to prepare 2 component systems. Only for professional use. Indications for preparations containing isocyanates: Ready-to-use preparations containing isocyanates may have an irritant effect on mucous membranes -especially on breathing organs- and cause hypersensitivity reactions. Inhalation of vapour or spray mist may cause sensitisation. When handling preparations containing isocyanates all precautions required for solvent-containing preparations must be followed. Vapour and spray mist in particular should not be inhaled. Allergics and asthmatics, as well as people prone to respiratory ailments should not work with isocyanate-containing preparations. Text of R-phrases listed in section 2: R10 Flammable. R11 Highly flammable. R20 Harmful by inhalation. R36 Irritating to eyes. R37 Irritating to respiratory system. R38 Irritating to skin. R43 May cause sensitization by skin contact. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. R20/21 Harmful by inhalation and in contact with skin. R36/37/38 Irritating to eyes, respiratory system and skin. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic

environment. Note P : It is unnecessary to apply the classification as carcinogenic if it can be proofed that the substance contains less than 0.1% benzene (EC No. 200-753-7) in weight. Labelling regulations: The information provided in this Material Safety Data Sheet has been written in accordance with Guideline 67/548/EEC (Substances), 88/379/EEC (Preparations) and 91/155/EEC (Material Safety Data Sheet). It has been updated to Guideline 2001/59/EC (Substances), 2001/60/EC (Preparations) and 2001/58/EC (Material Safety Data Sheet). The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified,

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 30.08.04 C255 - C256 - C257 Page: 1/7

SDS-624/EN 1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: C255 Code: 51464 C256 Code: 51474 C257 Code: 51475 1.2 Use of the preparation: B Component for acrylic paints. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) 2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 25-50 % Aliphatic polyisocyanate R43 Xi NLP No. 500-060-2 CAS: 28182-81-2 10-25 % n-butyl acetate R10 R66 R67 EC No. 204-658-1 CAS: 123-86-4 SAX: BPU750 No. 607-025-00-1 10-25 % 1-methoxypropyl acetate R10 R36 Xi EC No. 203-603-9 CAS: 108-65-6 No. 607-195-00-7 10-25 % Xylene (mixture of isomers) R10 R38 R20/21 Xn EC No. 215-535-7 CAS: 1330-20-7 SAX: XGS000 No. 601-022-00-9 2,5-10 % Ethylbenzene R11 R20 F Xn EC No. 202-849-4 CAS: 100-41-4 SAX: EGP500 No. 601-023-00-4 < 2,5% Naphtha solvent (oil), light aromatic R10 R65 R66 R67 R51/53 Xn N EC No. 265-199-0 CAS: 64742-95-6 No. 649-356-00-4 (Note P) < 1 % 1,2,4-trimethylbenzene R10 R20 R36/37/38 R51/53 Xn N EC No. 202-436-9 CAS: 95-63-6 SAX: TLL750 No. 601-043-00-3 For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Flammable. Harmful by inhalation. Harmful in contact with skin. May cause sensitization by skin contact. Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment.


SDS-624/EN 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. In the case of skin reddening or rashes, contact a doctor immediately. 4.3 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: Extinguishing powder or CO2. In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide, nitrogen oxides, isocyanate vapours, traces of hydrocyanic acid. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sews, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). The contaminated area should be cleaned up immediately with a suitable decontaminant. One possible (flammable) decontaminant comprises: water/ethanol or isopropanol/concentrated ammonia solution (d=0,880) = 45/50/5 parts by volume. Another possible (non-flammable) decontaminant is made up of water/sodium carbonate = 95/5 parts by weight. Add the same decontaminant to any residues and allow to stand for several days in an unsealed container until no further reaction occurs. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13.


SDS-624/EN 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed. Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. Recommendations for the prevention of toxicological risks: People with a history of asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which isocyanate containing products are used. Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. Keep away from food, drink and animal foodstuffs. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Class B1. According to ITC MIE APQ-1, RD.379/2001. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 35ºC. 7.3 Incompatible materials: Keep away from water, oxidizing agents, acids, alkalis, amines, alcohols, peroxides. 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Precautions should be taken to minimise exposure to atmospheric humidity or water, as carbon dioxide may be formed which, in closed containers can result in pressurisation. Care should be taken when re-opening partly used containers. Due to the sensitivity to humidity of the isocyanates, this product should be kept in the original container, or under pressure of dried nitrogen, for example. *8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC People with a history of asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which isocyanate containing products are used. 8.1 Occupational Exposure Limits (TLV) AGCIH 2002 TWA STEL Year ppm mg/m3 ppm mg/m3 n-butyl acetate 150 713 200 950 1998 1-methoxypropyl acetate 50 275 100 550 Recommended Dermal Xylene (mixture of isomers) 100 434 150 651 A4 1996 Ethylbenzene 100 434 125 543 1976 Naphtha solvent (oil), 50 260 Internal value light aromatic 1,2,4-trimethylbenzene 25 123 1987 A4 - Non classified as carcinogenic in humans. 8.2 Engineering measures: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particles and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn.


SDS-624/EN Vapour density: 3,96 Air = 1 at 20ºC Relative Lower explosive limit: 1,4 % Volume Ventilation requirement: 71 m3/l Air/Preparation to keep below 1/10 of the Lower Explosive Limit. 8.3 Protection of respiratory system: Avoid the inhalation of vapours. If the working area is insufficiently ventilated, or when operators, whether spraying or not, are inside the spraybooth, air-fed respiratory protective equipment is required. - Mask: For short periods of work, an air-fed mask or a combination of charcoal filter and particle filter mask is recommended. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles designed to protect against liquid splashes. Face shield: No. 8.5 Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Personnel should wear antistatic clothing made of natural fibre or of high temperature resistant synthetic fibre. Wash contaminated work clothes before wearing them again. *9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Liquid - Colour: Colourless - Odour: Characteristic - Viscosity: 12 sec.FC4 20ºC ASTM D 1200-88 - Specific gravity: 1,000 g/cc at 20ºC (C255, C257) 0,998 g/cc at 20ºC (C256) - Boiling point: 126,3ºC at 760 mmHg - Flash point: 28ºC Setaflash - Autoignition temperature: 376,3ºC - Vapour pressure: 6,7 mmHg at 20ºC *10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Possible dangerous reaction with water, oxidizing agents, acids, alkalis, amines, alcohols, peroxides. Exothermic reaction with amines and alcohols. Reacts with water under evolution of CO2. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced: nitrogen oxides, hydrocyanic acid. 11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic


SDS-624/EN contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. - Based on the properties of the isocyanate content of this product and existing technical data of similar preparations, it can be concluded that respiratory exposure may cause acute irritation and/or sensitization of the respiratory system, resulting in asthmatic symptoms, wheezing and a tightness of the chest. Sensitised persons may subsequently show asthmatic symptoms when exposed to airborne concentrations of isocyanates well below the occupational exposure limit. Repeated exposure may lead to permanent respiratory disability. In case of prolonged contact, the skin can dry up and irritation could appear. 11.2 Dose and lethal concentrations for individual ingredients: DL50 Oral DL50 Cutaneous CL50 Inhalation mg/kg mg/kg mg/l.4hours n-butyl acetate 10768 Rat 17600 Rabbit 9,7 Rat 1-methoxypropyl acetate 8532 Rat Xylene (mixture of isomers) 4300 Rat 1700 Rabbit 22 Rat Ethylbenzene 3500 Rat 17800 Rabbit Naphtha solvent (oil), 3900 Rat 3160 Rabbit light aromatic 1,2,4-trimethylbenzene 5000 Rat For more information about ingredients dangerous to health, see sections 2 and 8. *12. ECOLOGICAL INFORMATION No experimental ecotoxicological data on the preparation as such is available. 12.1 Spills on the soil: Prevent contamination of soil. 12.2 Spills in water: Harmful to aquatic organisms. May cause long-term adverse effects on the aquatic environment. Do not allow to escape into drains, sewers or water courses. - Hydrolysis: Reacts with water forming carbon dioxide and a solid insoluble product with high melting point (polyurea). This reaction is accelerated by surfactants (e.g. detergents) or by watersoluble solvents. 12.3 Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - VOC: 580 g/l (C255) / 574 g/l (C256) / 570 g/l (C257) ASTM D-3960 - Aromatic hydrocarbons: 20,5 % Weight 12.4 Ecotoxicological data for individual ingredients: CL50 CE50 CI50 mg/l.96hours mg/l.48hours mg/l.72hours n-butyl acetate 18 Fishes Xylene (mixture of isomers) 75 Fishes 16 Daphnia Ethylbenzene 12 Fishes 33 Algae Naphtha solvent (oil), light aromatic 9,2 Fishes 6,1 Daphnia 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations.


SDS-624/EN 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. 14. TRANSPORT INFORMATION PAINT RELATED MATERIAL (FP>23ºC) 14.1 Land: Transport by road: ADR 2003 Transport by rail: RID Class: 3 Packaging group: III UN no. 1263 Transport document: Consignment paper Written instructions. 14.2 Sea: Transport by ship: IMDG 30-00 Class: 3 Packaging group: III UN no. 1263 Emergency Sheet (EmS): 3-05, 07 First Aid Guide (MFAG): 310, 313 Marine pollutant: No Transport document: Shipping Bill of lading 14.3 Air: Transport by plane: IATA/ICAO Class: 3 Packaging group: III UN no. 1263 Transport document: Air Bill of lading 15. INFORMATION ON REGULATIONS 15.1 EC Labelling: Xn This product is FLAMMABLE and HARMFUL in accordance with Guideline 67/548/EEC~2001/59/EC and 1999/45/EC~2001/60/EC R10 Flammable. R20/21 Harmful by inhalation and in contact with skin. R43 May cause sensitization by skin contact. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic

environment. S23 Do not breathe vapour/spray. S36/37 Wear suitable protective clothing and gloves. S51 Use only in well-ventilated areas. P91 Contains isocyanates. See information supplied by the manufacturer. - Dangerous ingredients: Aliphatic polyisocyanate Xylene (mixture of isomers) 15.2 Type of packaging: According to current legislation. 16. OTHER INFORMATION Intended use This material is to be used as a hardener component, in combination with hydroxylated polymers, mainly polyesthers and polyacrylates, in order to prepare 2 component systems. Only for professional use.


SDS-624/EN Indications for preparations containing isocyanates: Ready-to-use preparations containing isocyanates may have an irritant effect on mucous membranes -especially on breathing organs- and cause hypersensitivity reactions. Inhalation of vapour or spray mist may cause sensitisation. When handling preparations containing isocyanates all precautions required for solvent-containing preparations must be followed. Vapour and spray mist in particular should not be inhaled. Allergics and asthmatics, as well as people prone to respiratory ailments should not work with isocyanate-containing preparations. Text of R-phrases listed in section 2: R10 Flammable. R11 Highly flammable. R20 Harmful by inhalation. R36 Irritating to eyes. R38 Irritating to skin. R43 May cause sensitization by skin contact. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. R20/21 Harmful by inhalation and in contact with skin. R36/37/38 Irritating to eyes, respiratory system and skin. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic

environment. Note P : It is unnecessary to apply the classification as carcinogenic if it can be proofed that the substance contains less than 0.1% benzene (EC No. 200-753-7) in weight. Labelling regulations: The information provided in this Material Safety Data Sheet has been written in accordance with Guideline 67/548/EEC (Substances), 88/379/EEC (Preparations) and 91/155/EEC (Material Safety Data Sheet). It has been updated to Guideline 2001/59/EC (Substances), 2001/60/EC (Preparations) and 2001/58/EC (Material Safety Data Sheet). The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.


SDS-625/EN 1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: C355 Code: 51442 C356 Code: 51472 1.2 Use of the preparation: B Component for acrylic paints. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) 2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 25-50 % Aliphatic polyisocyanate R43 Xi NLP No. 500-060-2 CAS: 28182-81-2 10-25 % Xylene (mixture of isomers) R10 R38 R20/21 Xn EC No. 215-535-7 CAS:1330-20-7 SAX: XGS000

No. 601-022-00-9 10-25 % n-butyl acetate R10 R66 R67 EC No. 204-658-1 CAS: 123-86-4 SAX: BPU750 No. 607-025-00-1 2,5-10 % 1-methoxypropyl acetate R10 R36 Xi EC No. 203-603-9 CAS: 108-65-6 No. 607-195-00-7 2,5-10 % Ethylbenzene R11 R20 F Xn EC No. 202-849-4 CAS: 100-41-4 SAX: EGP500 No. 601-023-00-4 < 2,5 % Naphtha solvent (oil), light aromatic R10 R65 R66 R67 R51/53 Xn N EC No. 265-199-0 CAS: 64742-95-6 No. 649-356-00-4 (Note P) < 1 % 1,2,4-trimethylbenzene R10 R20 R36/37/38 R51/53 Xn N EC No. 202-436-9 CAS: 95-63-6 SAX: TLL750 No. 601-043-00-3 For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Flammable. Harmful by inhalation. Harmful in contact with skin. Irritating to skin. May cause sensitization by skin contact. Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment.


SDS-625/EN 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. In the case of skin reddening or rashes, contact a doctor immediately. 4.3 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: Extinguishing powder or CO2. In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide, nitrogen oxides, isocyanate vapours, traces of hydrocyanic acid. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sews, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). The contaminated area should be cleaned up immediately with a suitable decontaminant. One possible (flammable) decontaminant comprises: water/ethanol or isopropanol/concentrated ammonia solution (d=0,880) = 45/50/5 parts by volume. Another possible (non-flammable) decontaminant is made up of water/sodium carbonate = 95/5 parts by weight. Add the same decontaminant to any residues and allow to stand for several days in an unsealed container until no further reaction occurs. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13.


SDS-625/EN 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed. Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. Recommendations for the prevention of toxicological risks: People with a history of asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which isocyanate containing products are used. Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. Keep away from food, drink and animal foodstuffs. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Class B1. According to ITC MIE APQ-1, RD.379/2001. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 35ºC. 7.3 Incompatible materials: Keep away from water, oxidizing agents, acids, alkalis, amines, alcohols, peroxides. 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Precautions should be taken to minimise exposure to atmospheric humidity or water, as carbon dioxide may be formed which, in closed containers can result in pressurisation. Care should be taken when re-opening partly used containers. Due to the sensitivity to humidity of the isocyanates, this product should be kept in the original container, or under pressure of dried nitrogen, for example. *8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC People with a history of asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which isocyanate containing products are used. 8.1 Occupational Exposure Limits (TLV) AGCIH 2002 TWA STEL Year ppm mg/m3 ppm mg/m3 Xylene (mixture of isomers) 100 434 150 651 A4 1996 n-butyl acetate 150 713 200 950 1998 1-methoxypropyl acetate 50 275 100 550 Recommended Dermal Ethylbenzene 100 434 125 543 1976 Naphtha solvent (oil), 50 260 Internal value light aromatic 1,2,4-trimethylbenzene 25 123 1987 A4 - Non classified as carcinogenic in humans. 8.2 Engineering measures: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particles and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn.


SDS-625/EN Vapour density: 3,9 Air = 1 at 20ºC Relative Lower explosive limit: 1,3 % Volume Ventilation requirement: 67 m3/l Air/Preparation to keep below 1/10 of the Lower Explosive Limit. 8.3 Protection of respiratory system: Avoid the inhalation of vapours. If the working area is insufficiently ventilated, or when operators, whether spraying or not, are inside the spraybooth, air-fed respiratory protective equipment is required. - Mask: For short periods of work, an air-fed mask or a combination of charcoal filter and particle filter mask is recommended. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles designed to protect against liquid splashes. Face shield: No. 8.5 Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Personnel should wear antistatic clothing made of natural fibre or of high temperature resistant synthetic fibre. Wash contaminated work clothes before wearing them again. *9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Liquid - Colour: Colourless - Odour: Characteristic - Viscosity: 12 sec.FC4 20ºC ASTM D 1200-88 - Specific gravity: 1,003 g/cc at 20ºC - Boiling point: 126,3ºC at 760 mmHg - Flash point: 27ºC Setaflash - Autoignition temperature: 393,4ºC - Vapour pressure: 6,9 mmHg at 20ºC *10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Possible dangerous reaction with water, oxidizing agents, acids, alkalis, amines, alcohols, peroxides. Exothermic reaction with amines and alcohols. Reacts with water under evolution of CO2. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced: nitrogen oxides, hydrocyanic acid. 11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic


SDS-625/EN contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. - Based on the properties of the isocyanate content of this product and existing technical data of similar preparations, it can be concluded that respiratory exposure may cause acute irritation and/or sensitization of the respiratory system, resulting in asthmatic symptoms, wheezing and a tightness of the chest. Sensitised persons may subsequently show asthmatic symptoms when exposed to airborne concentrations of isocyanates well below the occupational exposure limit. Repeated exposure may lead to permanent respiratory disability. In case of prolonged contact, the skin can dry up and irritation could appear. 11.2 Dose and lethal concentrations for individual ingredients: DL50 Oral DL50 Cutaneous CL50 Inhalation mg/kg mg/kg mg/l.4hours Xylene (mixture of isomers) 4300 Rat 1700 Rabbit 22 Rat n-butyl acetate 10768 Rat 17600 Rabbit 9,7 Rat 1-methoxypropyl acetate 8532 Rat Ethylbenzene 3500 Rat 17800 Rabbit Naphtha solvent (oil), 3900 Rat 3160 Rabbit light aromatic 1,2,4-trimethylbenzene 5000 Rat For more information about ingredients dangerous to health, see sections 2 and 8. *12. ECOLOGICAL INFORMATION No experimental ecotoxicological data on the preparation as such is available. 12.1 Spills on the soil: Prevent contamination of soil. 12.2 Spills in water: Harmful to aquatic organisms. May cause long-term adverse effects on the aquatic environment. Do not allow to escape into drains, sewers or water courses. - Hydrolysis: Reacts with water forming carbon dioxide and a solid insoluble product with high melting point (polyurea). This reaction is accelerated by surfactants (e.g. detergents) or by watersoluble solvents. 12.3 Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - VOC: 547 g/l (C355) / 532 g/l (C356) ASTM D-3960 - Aromatic hydrocarbons: 26,5 % Weight 12.4 Ecotoxicological data for individual ingredients:


Xylene (mixture of isomers) 75 Fishes 16 Daphnia n-butyl acetate 18 Fishes 10 Daphnia 21 Algae Naphtha solvent (oil), 9,2 Fishes 6,1 Daphnia light aromatic Ethylbenzene 12 Fishes 33 Algae 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations.


SDS-625/EN 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. 14. TRANSPORT INFORMATION PAINT RELATED MATERIAL (FP>23ºC) 14.1 Land: Transport by road: ADR 2003 Transport by rail: RID Class: 3 Packaging group: III UN no. 1263 Transport document: Consignment paper Written instructions. 14.2 Sea: Transport by ship: IMDG 30-00 Class: 3 Packaging group: III UN no. 1263 Emergency Sheet (EmS): 3-05, 07 First Aid Guide (MFAG): 310, 313 Marine pollutant: No Transport document: Shipping Bill of lading 14.3 Air: Transport by plane: IATA/ICAO Class: 3 Packaging group: III UN no. 1263 Transport document: Air Bill of lading 15. INFORMATION ON REGULATIONS 15.1 EC Labelling: Xn This product is FLAMMABLE and HARMFUL in accordance with Guideline 67/548/EEC~2001/59/EC and 1999/45/EC~2001/60/EC. R10 Flammable. R20/21 Harmful by inhalation and in contact with skin. R43 May cause sensitization by skin contact. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S23 Do not breathe vapour/spray. S36/37 Wear suitable protective clothing and gloves. S51 Use only in well-ventilated areas. P91 Contains isocyanates. See information supplied by the manufacturer. - Dangerous ingredients: Aliphatic polyisocyanate Xylene (mixture of isomers) 15.2 Type of packaging: According to current legislation. 16. OTHER INFORMATION Intended use This material is to be used as a hardener component, in combination with hydroxylated polymers, mainly polyesthers and polyacrylates, in order to prepare 2 component systems. Only for professional use.


SDS-625/EN Indications for preparations containing isocyanates: Ready-to-use preparations containing isocyanates may have an irritant effect on mucous membranes -especially on breathing organs- and cause hypersensitivity reactions. Inhalation of vapour or spray mist may cause sensitisation. When handling preparations containing isocyanates all precautions required for solvent-containing preparations must be followed. Vapour and spray mist in particular should not be inhaled. Allergics and asthmatics, as well as people prone to respiratory ailments should not work with isocyanate-containing preparations. Text of R-phrases listed in section 2: R10 Flammable. R11 Highly flammable. R20 Harmful by inhalation. R36 Irritating to eyes. R38 Irritating to skin. R43 May cause sensitization by skin contact. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. R20/21 Harmful by inhalation and in contact with skin. R36/37/38 Irritating to eyes, respiratory system and skin. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic


* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 30.08.04 C454 Page: 1/7

SDS-626/EN 1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: C454 Code: 51432 1.2 Use of the preparation: B Component for acrylic paints. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) *2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 25-50 % Aliphatic polyisocyanate R43 Xi NLP No. 500-060-2 CAS: 28182-81-2 10-25 % 1-methoxypropyl acetate R10 R36 Xi EC No. 203-603-9 CAS: 108-65-6 No. 607-195-00-7 10-25 % Naphtha solvent (oil), light aromatic R10 R65 R66 R67 R51/53 Xn N EC No. 265-199-0 CAS: 64742-95-6 No. 649-356-00-4 (Note P) 2,5-10 % Xylene (mixture of isomers) R10 R38 R20/21 Xn EC No. 215-535-7 CAS: 1330-20-7 SAX: XGS000 No. 601-022-00-9 2,5-10 % 1,2,4-trimethylbenzene R10 R20 R36/37/38 R51/53 Xn N EC No. 202-436-9 CAS: 95-63-6 SAX: TLL750 No. 601-043-00-3 2,5-10 % n-butyl acetate R10 R66 R67 EC No. 204-658-1 CAS: 123-86-4 SAX: BPU750 No. 607-025-00-1 < 2,5 % Mesitylene R10 R37 R51/53 Xi N EC No. 203-604-4 CAS: 108-67-8 SAX: TLM050 No. 601-025-00-5 < 2,5 % Ethylbenzene R11 R20 F Xn EC No. 202-849-4 CAS: 100-41-4 SAX: EGP500 No. 601-023-00-4 < 1 % Cumene R10 R37 R65 R51/53 Xn N EC No. 202-704-5 CAS: 98-82-8 SAX: COE750 No. 601-024-00-X For more information on dangerous ingredients, see sections 8, 11, 12 and 16.


SDS-626/EN 3. IDENTIFICATION OF HAZARDS Flammable. Harmful by inhalation. Irritating to eyes. May cause sensitization by skin contact. Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. In the case of skin reddening or rashes, contact a doctor immediately. 4.3 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: Extinguishing powder or CO2. In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide, nitrogen oxides, isocyanate vapours, traces of hydrocyanic acid. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sews, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). The contaminated area should be cleaned up immediately with a suitable decontaminant. One possible (flammable) decontaminant comprises: water/ethanol or isopropanol/concentrated ammonia solution (d=0,880) = 45/50/5 parts by volume. Another possible (non-flammable) decontaminant is made up of water/sodium carbonate = 95/5 parts by weight. Add the same decontaminant to any residues and allow to stand for several days in an unsealed container until no further reaction occurs. Keep the


SDS-626/EN remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed. Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. Recommendations for the prevention of toxicological risks: People with a history of asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which isocyanate containing products are used. Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. Keep away from food, drink and animal foodstuffs. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Class B1. According to ITC MIE APQ-1, RD.379/2001. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 35ºC. 7.3 Incompatible materials: Keep away from water, oxidizing agents, acids, alkalis, amines, alcohols, peroxides. 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Precautions should be taken to minimise exposure to atmospheric humidity or water, as carbon dioxide may be formed which, in closed containers can result in pressurisation. Care should be taken when re-opening partly used containers. Due to the sensitivity to humidity of the isocyanates, this product should be kept in the original container, or under pressure of dried nitrogen, for example. *8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC People with a history of asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which isocyanate containing products are used. 8.1 Occupational Exposure Limits (TLV) AGCIH 2002 TWA STEL Year ppm mg/m3 ppm mg/m3 1-methoxypropyl acetate 50 275 100 550 Recommended Dermal Naphtha solvent (oil), 50 260 Internal value light aromatic Xylene (mixture of isomers) 100 434 150 651 A4 1996 n-butyl acetate 150 713 200 950 1998 1,2,4-trimethylbenzene 25 123 1987 Mesitylene 25 123 1987 Ethylbenzene 100 434 125 543 1976 Cumene 50 246 1999


SDS-626/EN A4 - Non classified as carcinogenic in humans. 8.2 Engineering measures: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particles and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. Vapour density: 4,08 Air = 1 at 20ºC Relative Lower explosive limit: 1,4 % Volume Ventilation requirement: 73 m3/l Air/Preparation to keep below 1/10 of the Lower Explosive Limit. 8.3 Protection of respiratory system: Avoid the inhalation of vapours. If the working area is insufficiently ventilated, or when operators, whether spraying or not, are inside the spraybooth, air-fed respiratory protective equipment is required. - Mask: For short periods of work, an air-fed mask or a combination of charcoal filter and particle filter mask is recommended. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles designed to protect against liquid splashes. Face shield: No. 8.5 Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Personnel should wear antistatic clothing made of natural fibre or of high temperature resistant synthetic fibre. Wash contaminated work clothes before wearing them again. 9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Liquid - Colour: Colourless - Odour: Characteristic - Viscosity: 13 sec.FC4 20ºC ASTM D 1200-88 - Specific gravity: 1,03 g/cc at 20ºC - Boiling point: 126,3ºC at 760 mmHg - Flash point: 38ºC Setaflash - Autoignition temperature: 399,5ºC - Vapour pressure: 3,8 mmHg at 20ºC *10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Possible dangerous reaction with water, oxidizing agents, acids, alkalis, amines, alcohols, peroxides. Exothermic reaction with amines and alcohols. Reacts with water under evolution of CO2. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced: nitrogen oxides, hydrocyanic acid. *11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous


SDS-626/EN system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. - Based on the properties of the isocyanate content of this product and existing technical data of similar preparations, it can be concluded that respiratory exposure may cause acute irritation and/or sensitization of the respiratory system, resulting in asthmatic symptoms, wheezing and a tightness of the chest. Sensitised persons may subsequently show asthmatic symptoms when exposed to airborne concentrations of isocyanates well below the occupational exposure limit. Repeated exposure may lead to permanent respiratory disability. In case of prolonged contact, the skin can dry up and irritation could appear. 11.2 Dose and lethal concentrations for individual ingredients: DL50 Oral DL50 Cutaneous CL50 Inhalation mg/kg mg/kg mg/l.4hours 1-methoxypropyl acetate 8532 Rat Naphtha solvent (oil), 3900 Rat 3160 Rabbit light aromatic Xylene (mixture of isomers) 4300 Rat 1700 Rabbit 22 Rat 1,2,4-trimethylbenzene 5000 Rat n-butyl acetate 10768 Rat 17600 Rabbit 9.7 Rat Ethylbenzene 3500 Rat 17800 Rabbit Cumene 1400 Rat 12300 Rabbit For more information about ingredients dangerous to health, see sections 2 and 8. *12. ECOLOGICAL INFORMATION No experimental ecotoxicological data on the preparation as such is available. 12.1 Spills on the soil: Prevent contamination of soil. 12.2 Spills in water: Harmful to aquatic organisms. May cause long-term adverse effects on the aquatic environment. Do not allow to escape into drains, sewers or water courses. - Hydrolysis: Reacts with water forming carbon dioxide and a solid insoluble product with high melting point (polyurea). This reaction is accelerated by surfactants (e.g. detergents) or by watersoluble solvents. 12.3 Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - VOC: 510 g/l ASTM D-3960 - Aromatic hydrocarbons: 30 % Weight 12.4 Ecotoxicological data for individual ingredients: CL50 CE50 CI50 mg/l.96hours mg/l.48hours mg/l.72hours Naphtha solvent (oil), light aromatic 9.2 Fishes 6.1 Daphnia Xylene (mixture of isomers) 75 Fishes 16 Daphnia n-butyl acetate 18 Fishes Mesitylene 13 Fishes Ethylbenzene 12 Fishes 33 Algae 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into


SDS-626/EN drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. 14. TRANSPORT INFORMATION PAINT RELATED MATERIAL (FP>23ºC) 14.1 Land: Transport by road: ADR 2003 Transport by rail: RID Class: 3 Packaging group: III UN no. 1263 Transport document: Consignment paper Written instructions. 14.2 Sea: Transport by ship: IMDG 30-00 Class: 3 Packaging group: III UN no. 1263 Emergency Sheet (EmS): 3-05, 07 First Aid Guide (MFAG): 310, 313 Marine pollutant: Weak Transport document: Shipping Bill of lading 14.3 Air: Transport by plane: IATA/ICAO Class: 3 Packaging group: III UN no. 1263 Transport document: Air Bill of lading 15. INFORMATION ON REGULATIONS 15.1 EC Labelling: Xn This product is FLAMMABLE and HARMFUL in accordance with Guideline 67/548/CEE - 2001/59/CE and 1999/45/CE - 2001/60/CE. R10 Flammable. R20/21 Harmful by inhalation and in contact with skin. R36 Irritating to eyes. R43 May cause sensitization by skin contact. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S23 Do not breathe vapour/spray. S24/25 Avoid contact with skin and eyes. S36/37 Wear suitable protective clothing and gloves. S51 Use only in well-ventilated areas. P91 Contains isocyanates. See information supplied by the manufacturer. - Dangerous ingredients: Aliphatic polyisocyanate 15.2 Type of packaging: According to current legislation.


SDS-626/EN 16. OTHER INFORMATION Intended use: This material is to be used as a hardener component, in combination with hydroxylated polymers, mainly polyesthers and polyacrylates, in order to prepare 2 component systems. Only for professional use. Indications for preparations containing isocyanates: Ready-to-use preparations containing isocyanates may have an irritant effect on mucous membranes -especially on breathing organs- and cause hypersensitivity reactions. Inhalation of vapour or spray mist may cause sensitisation. When handling preparations containing isocyanates all precautions required for solvent-containing preparations must be followed. Vapour and spray mist in particular should not be inhaled. Allergics and asthmatics, as well as people prone to respiratory ailments should not work with isocyanate-containing preparations. Text of R-phrases listed in section 2: R10 Flammable. R11 Highly flammable. R20 Harmful by inhalation. R36 Irritating to eyes. R37 Irritating to respiratory system. R38 Irritating to skin. R43 May cause sensitization by skin contact. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. R20/21 Harmful by inhalation and in contact with skin. R36/37/38 Irritating to eyes, respiratory system and skin. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic



SDS-627/EN 1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: C455 Code: 51402 C456 Code: 51471 1.2 Use of the preparation: B Component for acrylic paints. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) 2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 25-50 % Aliphatic polyisocyanate R43 Xi NLP No. 500-060-2 CAS: 28182-81-2 25-50 % n-butyl acetate R10 R66 R67 EC No. 204-658-1 CAS: 123-86-4 SAX: BPU750 No. 607-025-00-1 10-25 % 1-methoxypropyl acetate R10 R36 Xi EC No. 203-603-9 CAS: 108-65-6 No. 607-195-00-7 2,5-10% Naphtha solvent (oil), light aromatic R10 R65 R66 R67 R51/53 Xn N EC No. 265-199-0 CAS: 64742-95-6 No. 649-356-00-4 (Note P) < 1 % 1,2,4-trimethylbenzene R10 R20 R36/37/38 R51/53 Xn N EC No. 202-436-9 CAS: 95-63-6 SAX: TLL750 No. 601-043-00-3 For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Flammable. May cause sensitization by skin contact. Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and dizziness. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious,


SDS-627/EN place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. In the case of skin reddening or rashes, contact a doctor immediately. 4.3 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: In case of fire, use water spray, alcohol-resistant foam, dry chemical powder, carbon dioxide, AFFF. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide, nitrogen oxides, isocyanate vapours, traces of hydrocyanic acid. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sews, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). The contaminated area should be cleaned up immediately with a suitable decontaminant. One possible (flammable) decontaminant comprises: water/ethanol or isopropanol/concentrated ammonia solution (d=0,880) = 45/50/5 parts by volume. Another possible (non-flammable) decontaminant is made up of water/sodium carbonate = 95/5 parts by weight. Add the same decontaminant to any residues and allow to stand for several days in an unsealed container until no further reaction occurs. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed. Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its


SDS-627/EN flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. Recommendations for the prevention of toxicological risks: People with a history of asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which isocyanate containing products are used. Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. Keep away from food, drink and animal foodstuffs. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Class B1. According to ITC MIE APQ-1, RD.379/2001. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 35ºC. 7.3 Incompatible materials: Keep away from water, oxidizing agents, acids, alkalis, amines, alcohols, peroxides. 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Precautions should be taken to minimise exposure to atmospheric humidity or water, as carbon dioxide may be formed which, in closed containers can result in pressurisation. Care should be taken when re-opening partly used containers. Due to the sensitivity to humidity of the isocyanates, this product should be kept in the original container, or under pressure of dried nitrogen, for example. *8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC People with a history of asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which isocyanate containing products are used. 8.1 Occupational Exposure Limits (TLV) AGCIH 2002 TWA STEL Year ppm mg/m3 ppm mg/m3 n-butyl acetate 150 713 200 950 1998 1-methoxypropyl acetate 50 275 100 550 Recommended Dermal Naphtha solvent (oil), 50 260 Internal value light aromatic 1,2,4-trimethylbenzene 25 123 1987 8.2 Engineering measures: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particles and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. Vapour density: 4,1 Air = 1 at 20ºC Relative Lower explosive limit: 1,6 % Volume Ventilation requirement: 59 m3/l Air/Preparation to keep below 1/10 of the Lower Explosive Limit. 8.3 Protection of respiratory system: Avoid the inhalation of vapours. If the working area is insufficiently ventilated, or when operators, whether spraying or not, are inside the spraybooth, air-fed respiratory protective equipment is required. - Mask: For short periods of work, an air-fed mask or a combination of charcoal filter and particle filter mask is recommended. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles designed to protect against liquid splashes. Face shield: No.


SDS-627/EN 8.5 Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Personnel should wear antistatic clothing made of natural fibre or of high temperature resistant synthetic fibre. Wash contaminated work clothes before wearing them again. *9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Liquid - Colour: Colourless - Odour: Characteristic - Viscosity: 13 sec.FC4 20ºC ASTM D 1200-88 - Specific gravity: 1,03 g/cc at 20ºC - Boiling point: 126,3ºC at 760 mmHg - Flash point: 31ºC Setaflash - Autoignition temperature: 349,4ºC - Vapour pressure: 6,8 mmHg at 20ºC *10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Possible dangerous reaction with water, oxidizing agents, acids, alkalis, amines, alcohols, peroxides. Exothermic reaction with amines and alcohols. Reacts with water under evolution of CO2. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced: nitrogen oxides, hydrocyanic acid. 11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. - Based on the properties of the isocyanate content of this product and existing technical data of similar preparations, it can be concluded that respiratory exposure may cause acute irritation and/or sensitization of the respiratory system, resulting in asthmatic symptoms, wheezing and a tightness of the chest. Sensitised persons may subsequently show asthmatic symptoms when exposed to airborne concentrations of isocyanates well below the occupational exposure limit. Repeated exposure may lead to permanent respiratory disability. In case of prolonged contact, the skin can dry up and irritation could appear.


SDS-627/EN 11.2 Dose and lethal concentrations for individual ingredients: DL50 Oral DL50 Cutaneous CL50 Inhalation mg/kg mg/kg mg/l.4hours n-butyl acetate 10768 Rat 17600 Rabbit 9.7 Rat 1-methoxypropyl acetate 8532 Rat Naphtha solvent (oil), 3900 Rat 3160 Rabbit light aromatic 1,2,4-trimethylbenzene 5000 Rat For more information about ingredients dangerous to health, see sections 2 and 8. *12. ECOLOGICAL INFORMATION No experimental ecotoxicological data on the preparation as such is available. 12.1 Spills on the soil: Prevent contamination of soil. 12.2 Spills in water: Harmful to aquatic organisms. May cause long-term adverse effects on the aquatic environment. Do not allow to escape into drains, sewers or water courses. - Hydrolysis: Reacts with water forming carbon dioxide and a solid insoluble product with high melting point (polyurea). This reaction is accelerated by surfactants (e.g. detergents) or by watersoluble solvents. 12.3 Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - VOC: 510 g/l (C455) / 500 g/l (C456) ASTM D-3960 - Aromatic hydrocarbons: 3,7 % Weight 12.4 Ecotoxicological data for individual ingredients: CL50 CE50 CI50 mg/l.96hours mg/l.48hours mg/l.72hours n-butyl acetate 18 Fishes Naphtha solvent (oil), light aromatic 9,2 Fishes 6,1 Daphnia 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. 14. TRANSPORT INFORMATION PAINT RELATED MATERIAL (FP>23ºC) 14.1 Land: Transport by road: ADR 2003 Transport by rail: RID Class: 3 Packaging group: III UN no. 1263 Transport document: Consignment paper Written instructions.


SDS-627/EN 14.2 Sea: Transport by ship: IMDG 30-00 Class: 3 Packaging group: III UN no. 1263 Emergency Sheet (EmS): 3-05, 07 First Aid Guide (MFAG): 310, 313 Marine pollutant: No Transport document: Shipping Bill of lading 14.3 Air: Transport by plane: IATA/ICAO Class: 3 Packaging group: III UN no. 1263 Transport document: Air Bill of lading 15. INFORMATION ON REGULATIONS 15.1 EC Labelling: Xn This product is FLAMMABLE and HARMFUL in accordance with Guideline 67/548/CEE - 2001/59/CE and 1999/45/CE - 2001/60/CE. R10 Flammable. R20/21 Harmful by inhalation and in contact with skin. R43 May cause sensitization by skin contact. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S23 Do not breathe vapour/spray. S24/25 Avoid contact with skin and eyes. S36/37 Wear suitable protective clothing and gloves. S51 Use only in well-ventilated areas. P91 Contains isocyanates. See information supplied by the manufacturer. - Dangerous ingredients: Aliphatic polyisocyanate 15.2 Type of packaging: According to current legislation. 16. OTHER INFORMATION Intended use This material is to be used as a hardener component, in combination with hydroxylated polymers, mainly polyesthers and polyacrylates, in order to prepare 2 component systems. Only for professional use. Indications for preparations containing isocyanates: Ready-to-use preparations containing isocyanates may have an irritant effect on mucous membranes -especially on breathing organs- and cause hypersensitivity reactions. Inhalation of vapour or spray mist may cause sensitisation. When handling preparations containing isocyanates all precautions required for solvent-containing preparations must be followed. Vapour and spray mist in particular should not be inhaled. Allergics and asthmatics, as well as people prone to respiratory ailments should not work with isocyanate-containing preparations. Text of R-phrases listed in section 2: R10 Flammable. R20 Harmful by inhalation. R36 Irritating to eyes. R43 May cause sensitization by skin contact.


SDS-627/EN R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. R36/37/38 Irritating to eyes, respiratory system and skin. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic


* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 06.09.05 F500 – F600 Page: 1/7

SDS-601/EN 1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: F500 Code: 51227 F600 Code: 51231 1.2 Use of the preparation: Hardener for acrylic paints. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) *2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health and/or environment hazard, and/or with a Communitary workplace exposure limit: 25-50 % Aliphatic polyisocyanate R43 EC: 500-060-2 CAS: 28182-81-2 25-50 % n-butyl acetate R10 R66-R67 EC: 204-658-1 CAS: 123-86-4 SAX: BPU750 No. 607-025-00-1 ATP25 10-25 % Xylene (mixture of isomers) R10 Xn; R20/21 Xi; R38 EC: 215-535-7 CAS: 1330-20-7 SAX: XGS000 No. 601-022-00-9 ATP25 2,5-10 % 2-methoxy-1-methylethyl acetate R10 Xi; R36 EC: 203-603-9 CAS: 108-65-6 No. 607-195-00-7 ATP19 2,5-10 % Ethylbenzene F; R11 Xn; R20 EC: 202-849-4 CAS: 100-41-4 SAX: EGP500 No. 601-023-00-4 ATP12 < 0,5 % Hexamethylene-1,6-diisocyanate T; R23 Xi; R36/37/38 R42/43 EC: 212-485-8 CAS: 822-06-0 SAX: DNJ800 No. 615-011-00-1 ATP12

For more information on dangerous ingredients, see sections 8, 11, 12 and 16. *3. IDENTIFICATION OF HAZARDS Flammable. Harmful by inhalation. Harmful in contact with skin. May cause sensitization by skin contact. Irritating to skin. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person.


SDS-601/EN 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. In the case of skin reddening or rashes, contact a doctor immediately. 4.3 By contact with eyes: Remove contact lenses. Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: Extinguishing powder or CO2. In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use for extinguishing: direct water jet. 5.2 Specific risks: As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide, nitrogen oxides, isocyanate vapours, traces of hydrocyanic acid. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sews, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). The contaminated area should be cleaned up immediately with a suitable decontaminant. One possible (flammable) decontaminant comprises: water/ethanol or isopropanol/concentrated ammonia solution (d=0,880) = 45/50/5 parts by volume. Another possible (non-flammable) decontaminant is made up of water/sodium carbonate = 95/5 parts by weight. Add the same decontaminant to any residues and allow to stand for several days in an un-sealed container until no further reaction occurs. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. *7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed.


SDS-601/EN Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. - Flash point: 28ºC Setaflash - Autoignition temperature: 392,5ºC - Flammability range: 1,5-7,9 % Volume 25ºC - Flammability range: 1,1-10,8 % Volume 300ºC Recommendations for the prevention of toxicological risks: People with a history of asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which isocyanate containing products are used. Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. Keep away from living quarters. Keep away from food, drink and animal foodstuffs. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Class B1. According to ITC MIE APQ-1, RD.379/2001. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 35ºC. - Incompatible materials: Keep away from oxidizing agents, acids, alkalis, amines, alcohols, peroxides. - Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions. Precautions should be taken to minimise exposure to atmospheric humidity or water, as carbon dioxide may be formed which, in closed containers can result in pressurisation. Care should be taken when re-opening partly used containers. Due to the sensitivity to humidity of the isocyanates, this product should be kept in the original container, or under pressure of dried nitrogen, for example. - Type of packaging: According to current legislation. *8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC People with a history of asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which isocyanate containing products are used. 8.1 Occupational Exposure Limits: INSHT 2005: Spain VLA-ED-

ppm: VLA-ED-mg/m3:

VLA-EC -ppm:


123-86-4 150 724 200 965 - 1330-20-7 50 221 100 442 Dermal, VLB, VLI 108-65-6 50 275 100 550 Dermal, VLI 100-41-4 100 441 200 884 Dermal, VLB, VLI 822-06-0 0,005 0,035 - - Sen INRS ND 2098, 02/2005:



123-86-4 150 710 200 940 - 84 108-65-6 50 275 100 550 * - 100-41-4 100 442 200 884 * 84 822-06-0 0,01 0,075 0,02 0,15 AR 62 1330-20-7 50 221 100 442 * 4bis, 84


SDS-601/EN DFG 2004:


123-86-4 100 480 DFG, 37, Y 1330-20-7 100 440 DFG, H 108-65-6 50 270 DFG, EU, Y 100-41-4 100 440 DFG, H 822-06-0 0,005 0,035 DFG, 36 ACGIH 2004:

ACGIH(TLV) TWA-ppm: TWA-mg/m3: STEL-ppm: STEL-

mg/m3: Note: Note:

123-86-4 150 713 200 950 - - 1330-20-7 100 434 150 651 A4 S 108-65-6 50 275 100 550 - - 100-41-4 100 434 125 543 A3 - 822-06-0 0,005 0,034 - - - - 2000/39/EC and 98/24/EC:


mg/m3: Notes:

1330-20-7 50 221 100 442 Skin 108-65-6 50 275 100 550 Skin 100-41-4 100 442 200 884 Skin 8.2 Occupational exposure controls, Directive 89/686/EEC: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particles and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. - Protection of respiratory system: Avoid the inhalation of vapours. Avoid the inhalation of particles or spray mist arising from the application of this preparation. Mask: For short periods of work, you can consider the utilization of a combination mask with gas and particle filters, type A2-P2 (EN141/EN143). In order to obtain a suitable protection level, the filter class must be selected depending on the type and concentration of the contaminating agents present, in accordance with the specifications supplied by the filter producers. If the working area is insufficiently ventilated, or when operators, whether spraying or not, are inside the spraybooth, compressed air-fed respiratory protective equipment (EN137) is required. - Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles designed to protect against liquid splashes, with suitable lateral protection (EN166). Face shield: No. - Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Gloves resistant against chemicals (EN374). Boots: No. Apron: No. Clothing: It is advisable personnel wear antistatic clothing made of natural fibre or of high temperature resistant synthetic fibre. Wash contaminated work clothes before wearing them again. 8.3 Environmental exposure controls: Avoid any spillage in the environment of the product, wastes, packages or spraybooth sewages. Avoid any release into the atmosphere above the legal limits allowed. *9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Liquid - Colour: Colourless - Odour: Characteristic


SDS-601/EN - Viscosity: 12 sec CF/4 at 20ºC F500 ASTM D 1200-88 13 sec CF/4 at 20ºC F600 ASTM D 1200-88 - Specific gravity: 0,970 g/cc at 20ºC - Boiling point: 126,3ºC at 760 mmHg - Flash point: 28ºC Setaflash - Vapour pressure: 7,4 mmHg at 20ºC *10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Possible dangerous reaction with water, oxidizing agents, acids, alkalis, amines, alcohols, peroxides. Exothermic reaction with amines and alcohols. Reacts with water under evolution of CO2. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced, including isocyanates. *11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. Based on the properties of the isocyanate content of this product and existing technical data of similar preparations, it can be concluded that respiratory exposure may cause acute irritation and/or sensitization of the respiratory system, resulting in asthmatic symptoms, wheezing and a tightness of the chest. Sensitised persons may subsequently show asthmatic symptoms when exposed to airborne concentrations of isocyanates well below the occupational exposure limit. Repeated exposure may lead to permanent respiratory disability. In case of prolonged contact, the skin can dry up and irritation could appear. 11.2 Dose and lethal concentrations for individual ingredients:


n-butyl acetate 10768 Rat 17600 Rabbit 9,7 Rat Xylene (mixture of isomers) 4300 Rat 1700 Rabbit 22 Rat 1-methoxypropyl acetate 8532 Rat Ethylbenzene 3500 Rat 17800 Rabbit Hexamethylene- 738 Rat 593 Rabbit 1,6-diisocyanate For more information about ingredients dangerous to health, see sections 2 and 8. *12. ECOLOGICAL INFORMATION No experimental ecotoxicological data on the preparation as such is available.


SDS-601/EN 12.1 Spills on the soil: Prevent contamination of soil. 12.2 Spills in water: Do not allow to escape into drains, sewers or water courses. - Hydrolisis: Reacts with water forming carbon dioxide and a solid insoluble product with high melting point (polyurea). This reaction is accelerated by surfactants (e.g. detergents) or by watersoluble solvents. 12.3 Emissions to the atmosphere: Avoid any release into the atmosphere. - VOC: 616 g/l F500 ASTM D-3960

582 g/l F600 - Aromatic hydrocarbons: 26,1 % Weight 12.4 Ecotoxicological data for individual ingredients:


n-butyl acetate 18 Fishes Xylene (mixture of isomers) 75 Fishes 16 Daphnia Ethylbenzene 12 Fishes 33 Algae *13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste, Directive 75/442/EEC~91/156/EC: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers, Directive 94/62/EC: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. *14. TRANSPORT INFORMATION PAINT RELATED MATERIAL (FP>23ºC) 14.1 Transport by road, Directive 94/55/EC (ADR 2005): Transport by rail, Directive 96/49/EC (RID 2005): Class: 3 Packaging group: III UN no. 1263 Transport document: Consignment paper Written instructions. 14.2 Transport by sea (IMDG 32-04): Class: 3 Packaging group: III UN no. 1263 Emergency Sheet (EmS): 3-05,07 First Aid Guide (MFAG): 310,313 Marine pollutant: No Transport document: Shipping Bill of lading 14.3 Transport by air (ICAO/IATA): Class: 3 Packaging group: III UN no. 1263 Transport document: Air Bill of lading


SDS-601/EN *15. INFORMATION ON REGULATIONS 15.1 EC Labelling Xn This product is FLAMMABLE and HARMFUL in accordance with Guideline 67/548/EEC - 2004/73/EC and 1999/45/EC - 2001/60/EC. R10 Flammable. R20/21 Harmful by inhalation and in contact with skin. R43 May cause sensitization by skin contact. S23 Do not breathe vapour/spray. S36/37 Wear suitable protective clothing and gloves. S51 Use only in well-ventilated areas. P91 Contains isocyanates. See information supplied by the manufacturer Dangerous ingredients: Xylene (mixture of isomers) 15.2 Restrictions to the marketing and use in accordance with Directive 76/769/EEC: Not applicable. 15.3 Other regulations: Not available *16. OTHER INFORMATION - Intended use: This material is to be used as a hardener component, in combination with hydroxylated polymers, mainly polyesthers and polyacrylates, in order to prepare 2 component systems. Only for professional use. - Indications for preparations containing isocyanates: Ready-to-use preparations containing isocyanates may have an irritant effect on mucous membranes -especially on breathing organs- and cause hypersensitivity reactions. Inhalation of vapour or spray mist may cause sensitisation. When handling preparations containing isocyanates all precautions required for solvent-containing preparations must be followed. Vapour and spray mist in particular should not be inhaled. Allergics and asthmatics, as well as people prone to respiratory ailments should not work with isocyanate-containing preparations. - Text of R-phrases listed in section 2: R10 Flammable. R11 Highly flammable. R20 Harmful by inhalation. R23 Toxic by inhalation. R36 Irritating to eyes. R38 Irritating to skin. R43 May cause sensitization by skin contact. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. R20/21 Harmful by inhalation and in contact with skin. R36/37/38 Irritating to eyes, respiratory system and skin. R42/43 May cause sensitization by inhalation and skin contact. Material Safety Data Sheet regulations: Material Safety Data Sheet in accordance with Directive 91/155/EEC~2001/58/EC. The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 16.11.05 HARDENER POLYESTER Page: 1/6

SDS-609/EN 1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: HARDENER POLYESTER Code: 51224-51225 1.2 Use of the preparation: Polyester unsaturated hardener. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) *2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health and/or environment hazard, and/or with a Communitary workplace exposure limit: 25-50 % Dibenzoyl peroxide R2 R36 R43 E Xi CAS: 94-36-0

EC No. 202-327-6 SAX: BDS000 No. 617-008-00-0

25-50 % Diisobutyl phthalate CAS: 84-69-5 EC No. 201-553-2 SAX: DNJ400

For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS May cause fire. Irritating to eyes. May cause sensitization by skin contact. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Apply lanolin ointment. In the event of cutaneous eruptions contact a doctor. In the case of skin reddening or rashes, contact a doctor immediately. 4.3 By contact with eyes: Remove contact lenses. Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. If possible, alternate the rinsing with a 5% solution of sodium ascorbate in water or a 2% solution of sodium bicarbonate in water. Both solutions should not to be more than 4 weeks old. Do not apply oils. Call a physician immediately.


SDS-609/EN 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. If there has been any contact with the mouth, rinse out with large quantities of water only. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: Extinguishing powder or CO2. In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use for extinguishing: halon. 5.2 Specific risks: As a consequence of combustion or thermal decomposition, hazardous decomposition products may be produced: carbon monoxide, carbon dioxide. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sewages, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Do not use rags. The peroxide impregnated absorbent must be placed in a safe place and not put into a container. For subsequent waste disposal, follow the recommendations in section 13. *7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Do not weigh it in the storage area. Avoid friction, rough handling or strong impacts. Avoid any type of leakage or escape. Keep the container tightly closed. - Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. - Flash point: >55ºC Setaflash - Autoignition temperature: 80ºC - Flammability range: 0,8 – 3,2 % Volume 25ºC - Recommendations for the prevention of toxicological risks: Do not eat, drink or smoke while handling. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage


SDS-609/EN area. Keep in a cool place. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: According to current legislation. Temperature interval: min: 5ºC, max: 25ºC. - Incompatible materials: Keep away from reducing agents, oxidizing agents, acids, alkalis, amines, metals, heavy-metal compounds. - Conditions to avoid: Heat: This preparation is quite stable at normal temperatures (around 20ºC). However, at higher temperatures an exo-thermic decomposing reaction takes place. In the event of the decomposition taking place so fast that the heat only partially dissipates, an increased acceleration of the product's temperature occurs, finally giving rise to an auto-accelerated breaking down of the organic peroxide. Depending on the circumstances, eg. the amount, the degree of containment, etc.., intense decomposition, auto-ignition or even an explosion may take place. Light: Avoid direct contact with sunlight as this could cause a rise in temperature, with the subsequent danger of the peroxide decomposing. Humidity: Avoid extreme humidity conditions. - Type of packaging: According to current legislation. *8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC 8.1 Occupational Exposure Limits (TLV) AGCIH 2004

TWA STEL Year ppm mg/m3 ppm mg/m3 Dibenzoyl peroxide 5,0 A4 1996 A4 - Non classified as carcinogenic in humans. 8.2 Occupational exposure controls, Directive 89/686/EEC: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. - Protection of respiratory system: Mask: Advisable. - Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles with suitable lateral protection (EN166). Face shield: Recommendable when peroxides are handled in large amounts. - Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Gloves resistant against chemicals (EN374). The breakthrough time of the selected glove material should be superior to the pretended period of use. The gloves should be immediately replaced when any sign of degradation is noted. Boots: No. Apron: No. Clothing: Suitable work clothes which avoid contact with the product should be worn. Put away work clothes under control and separately from the rest. Do not take contaminated clothing home. Wash contaminated work clothes before wearing them again. 8.3 Environmental exposure controls: Avoid any spillage in the environment. 9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Paste - Colour: White / Red - Odour: Characteristic - Specific gravity: 1,15 g/cc at 20ºC - Solubility in water: Insoluble - Available peroxydic oxygen: 3,3 % OO - Flash point: >55ºC Setaflash - Descomposition temperature: 103ºC - Vapour pressure: 0,07 mmHg at 20ºC


SDS-609/EN 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with reducing agents, oxidizing agents, acids, alkalis, amines, metals, heavy-metal compounds. Special care must be taken under all circumstances that there is no direct contact with accelerators, given that a violent decomposition could take place or even an explosion. 10.3 Thermal decomposition: As a consequence of thermal decomposition, hazardous decomposition products may be produced: oxygen. The vapours given off on decomposing are inflammable, therefore any source of ignition could cause a fire. *11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Irritating to eyes. Some organic peroxides will cause serious, irreversible ocular injuries to the cornea, even after brief contact. 11.2 Dose and lethal concentrations for individual ingredients:

DL50 Oral DL50 Cutaneous CL50 Inhalation mg/kg mg/kg mg/l.4hours Dibenzoyl peroxide 7710 Rat Diisobutyl phthalate 2000 Rat 20000 Rabbit For more information about ingredients dangerous to health, see sections 2 and 8. 12. ECOLOGICAL INFORMATION No experimental ecotoxicological data on the preparation as such is available. 12.1 Spills on the soil: Prevent contamination of soil. 12.2 Spills in water: Do not allow to escape into drains, sewers or water courses. 12.3 Emissions to the atmosphere: Not applicable. 12.4 Ecotoxicological data for individual ingredients:

CL50 CE50 CI50 mg/l.96hours mg/l.48hours mg/l.72hours Dibenzoyl peroxide 2000 Fishes Diisobutyl phthalate 3,0 Fishes 7,4 Daphnia 2,2 Algae *13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste, Directive 75/442/EEC~91/156/EC: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers, Directive 94/62/EC: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. Never re-use a container which has contained peroxides. 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. Before burning dilute with organic solvents.


SDS-609/EN 14. TRANSPORT INFORMATION ORGANIC PEROXYDE TYPE E, SOLID (contains dibenzoyl peroxide) 14.1 Transport by road, Directive 94/55/EC (ADR 2005): Transport by rail, Directive 96/49/EC (RID 2005): Class: 5.2 Packaging group: II UN no. 3108 Transport document: Consignment paper Written instructions. 14.2 Transport by sea (IMDG 32-04): Class: 5.2 Packaging group: II UN no. 3108 Emergency Sheet (EmS): 5.2-01 First Aid Guide (MFAG): 735 Marine pollutant: No Transport document: Shipping Bill of lading 14.3 Transport by air (ICAO/IATA): Class: 5.2 Packaging group: II UN no. 3108 Transport document: Air Bill of lading *15. INFORMATION ON REGULATIONS 15.1 EC Labelling: O, Xi This product is OXIDIZING and IRRITANT in accordance with Guideline 67/548/EEC - 2004/73/EC and 1999/45/EC - 2001/60/EC. R7 May cause fire. R36 Irritating to eyes. R43 May cause sensitization by skin contact. S3/7 Keep container tightly closed in a cool place. S14 Keep away from reducing agents, oxidizing agents, acids, alkalis, amines, metals, heavy-metal compounds. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 Wear suitable protective clothing, gloves and protection for eyes, face. S50 Do not mix with accelerators or reducing agents. Dangerous ingredients: Dibenzoyl peroxide 15.2 Restrictions to the marketing and use in accordance with Directive 76/769/EEC: Not applicable. 15.3 Other regulations: Not available. *16. OTHER INFORMATION Intended use: This material is used as a hardening catalyst, mainly for unsaturated polyesthers. Only for professional use. Text of R-phrases listed in section 2: R2 Risk of explosion by shock, friction, fire or other sources of ignition. R36 Irritating to eyes. R43 May cause sensitization by skin contact. Material Safety Data Sheet regulations: Material Safety Data Sheet in accordance with Directive 91/155/EEC~2001/58/EC.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 06.05.04 MX503 - MX603 Page: 1/7

SDS-619/EN *1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: MX503 Code: 51229 MX603 Code: 51233 1.2 Use of the preparation: Hardener for 2K primers. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) *2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 25-50 % Aliphatic polyisocyanate R43 Xi NLP No. 500-060-2 CAS: 28182-81-2 10-25 % n-butyl acetate R10 R66 R67 EC No. 204-658-1

CAS: 123-86-4 SAX: BPU750 No. 607-025-00-1 10-25 % 1-methoxypropyl acetate R10 R36 Xi EC No. 203-603-9 CAS: 108-65-6 No. 607-195-00-7 10-25 % Xylene (mixture of isomers) R10 R38 R20/21 Xn EC No. 215-535-7

CAS: 1330-20-7 SAX: XGS000

No. 601-022-00-9 2,5-10 % Ethylbenzene R11 R20 F Xn EC No. 202-849-4 CAS: 100-41-4 SAX: EGP500 No. 601-023-00-4 < 2,5 % Naphtha solvent (oil), light aromatic R10 R65 R66 R67 R51/53 Xn N EC No. 265-199-0 CAS: 64742-95-6 No. 649-356-00-4 (Note P) < 1 % 1,2,4-trimethylbenzene R10 R20 R36/37/38 R51/53 Xn N EC No. 202-436-9 CAS: 95-63-6 SAX: TLL750 No. 601-043-00-3 For more information on dangerous ingredients, see sections 8, 11, 12 and 16. *3. IDENTIFICATION OF HAZARDS Flammable. Harmful by inhalation. Harmful in contact with skin. May cause sensitisation by skin contact. Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment.


SDS-619/EN *4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. In the case of skin reddening or rashes, contact a doctor immediately. 4.3 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. *5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: Extinguishing powder or CO2. In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide, nitrogen oxides, isocyanate vapours, traces of hydrocyanic acid. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sews, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). The contaminated area should be cleaned up immediately with a suitable decontaminant. One possible (flammable) decontaminant comprises: water/ethanol or isopropanol/concentrated ammonia solution (d=0,880) = 45/50/5 parts by volume. Another possible (non-flammable) decontaminant is made up of water/sodium carbonate = 95/5 parts by weight. Add the same decontaminant to any residues and allow standing for several days in an unsealed container until no further reaction occurs. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13.


SDS-619/EN 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed. Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. Recommendations for the prevention of toxicological risks: People with a history of asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which isocyanate containing products are used. Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorised access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. Keep away from food, drink and animal foodstuffs. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Class B1. According to ITC MIE APQ-1, RD.379/2001. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 35ºC. 7.3 Incompatible materials: Keep away from water, oxidising agents, acids, alkalis, amines, alcohols, peroxides. 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions. Precautions should be taken to minimise exposure to atmospheric humidity or water, as carbon dioxide may be formed which, in closed containers can result in pressurisation. Care should be taken when re-opening partly used containers. Due to the sensitivity to humidity of the isocyanates, this product should be kept in the original container, or under pressure of dried nitrogen, for example. *8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC People with a history of asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which isocyanate containing products are used. 8.1 Occupational Exposure Limits (TLV) AGCIH 2002 TWA STEL Year ppm mg/m3 ppm mg/m3 n-butyl acetate 150 713 200 950 1998 1-methoxypropyl acetate 50 275 100 550 Recommended Dermal Xylene (mixture of isomers) 100 434 150 651 A4 1996 Ethylbenzene 100 434 125 543 1976 Naphtha solvent (oil), light aromatic 50 260 Internal value 1,2,4-trimethylbenzene 25 123 1987 A4 - Non classified as carcinogenic in humans. 8.2 Engineering measures: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particles and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn.


SDS-619/EN Vapour density: 3,9 Air = 1 at 20ºC Relative Lower explosive limit: 1,4 % Volume Ventilation requirement: 73 m3/l Air/Preparation to keep below 1/10 of the Lower Explosive Limit. 8.3 Protection of respiratory system: Avoid the inhalation of vapours. If the working area is insufficiently ventilated, or when operators, whether spraying or not, are inside the spraybooth, air-fed respiratory protective equipment is required. - Mask: For short periods of work, an air-fed mask or a combination of charcoal filter and particle filter mask is recommended. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles designed to protect against liquid splashes. Face shield: No. 8.5 Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Personnel should wear antistatic clothing made of natural fibre or of high temperature resistant synthetic fibre. Wash contaminated work clothes before wearing them again. *9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Liquid - Colour: Colourless - Odour: Characteristic - Viscosity: 12 sec.FC4 20ºC ASTM D 1200-88 - Specific gravity: 0,993 g/cc at 20ºC MX503 0,994 g/cc at 20ºC MX603 - Boiling point: 126,3ºC at 760 mmHg - Flash point: 28ºC Setaflash - Vapour pressure: 6,7 mmHg at 20ºC *10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Possible dangerous reaction with water, oxidising agents, acids, alkalis, amines, alcohols, peroxides. Exothermic reaction with amines and alcohols. Reacts with water under evolution of CO2. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced: nitrogen oxides, hydrocyanic acid.. *11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic


SDS-619/EN contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. - Based on the properties of the isocyanate content of this product and existing technical data of similar preparations, it can be concluded that respiratory exposure may cause acute irritation and/or sensitisation of the respiratory system, resulting in asthmatic symptoms, wheezing and a tightness of the chest. Sensitised persons may subsequently show asthmatic symptoms when exposed to airborne concentrations of isocyanates well below the occupational exposure limit. Repeated exposure may lead to permanent respiratory disability. In case of prolonged contact, the skin can dry up and irritation could appear. 11.2 Dose and lethal concentrations for individual ingredients:


n-butyl acetate 10768 Rat 17600 Rabbit 9,7 Rat 1-methoxypropyl acetate 8532 Rat Xylene (mixture of isomers) 4300 Rat 1700 Rabbit 22 Rat Ethylbenzene 3500 Rat 17800 Rabbit Naphtha solvent (oil), light aromatic 3900 Rat 3160 Rabbit 1,2,4- trimethylbenzene 5000 Rat For more information about ingredients dangerous to health, see sections 2 and 8. *12. ECOLOGICAL INFORMATION No experimental ecotoxicological data on the preparation as such is available. 12.1 Spills on the soil: Prevent contamination of soil. 12.2 Spills in water: Harmful to aquatic organisms. May cause long-term adverse effects on the aquatic environment. Do not allow to escape into drains, sewers or water courses. - Hydrolysis: Reacts with water forming carbon dioxide and a solid insoluble product with high melting point (polyurea). This reaction is accelerated by surfactants (e.g. detergents) or by watersoluble solvents. 12.3 Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - VOC: 611 g/l MX503 ASTM D-3960 596 g/l MX603 - Aromatic hydrocarbons: 21 % Weight 12.4 Ecotoxicological data for individual ingredients: CL50 CE50 CI50 mg/l.96hours mg/l.48hours mg/l.72hours n-butyl acetate 18 Fishes Xylene (mixture of isomers) 75 Fishes 16 Daphnia Ethylbenzene 12 Fishes 33 Algae Naphtha solvent (oil), light aromatic 9,2 Fishes 6,1 Daphnia 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations.


SDS-619/EN 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. *14. TRANSPORT INFORMATION PAINT RELATED MATERIAL (FP>23ºC) 14.1 Land: Transport by road: ADR 2003 Transport by rail: RID Class: 3 Packaging group: III UN no. 1263 Transport document: Consignment paper Written instructions. 14.2 Sea: Transport by ship: IMDG 30-00 Class: 3 Packaging group: III UN no. 1263 Emergency Sheet (EmS): 3-05, 07 First Aid Guide (MFAG): 310, 313 Marine pollutant: No Transport document: Shipping Bill of lading 14.3 Air: Transport by plane: IATA/ICAO Class: 3 Packaging group: III UN no. 1263 Transport document: Air Bill of lading *15. INFORMATION ON REGULATIONS 15.1 EC Labelling: Xn This product is FLAMMABLE and HARMFUL in accordance with Guideline 67/548/CEE - 2001/59/CE and 1999/45/CE - 2001/60/CE. R10 Flammable. R20/21 Harmful by inhalation and in contact with skin. R43 May cause sensitisation by skin contact. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S23 Do not breathe vapour/spray. S36/37 Wear suitable protective clothing and gloves. S51 Use only in well-ventilated areas. P91 Contains isocyanates. See information supplied by the manufacturer. - Dangerous ingredients: Xylene (mixture of isomers) 15.2 Type of packaging: According to current legislation. *16. OTHER INFORMATION Intended use: This material is to be used as a hardener component, in combination with hydroxylated polymers, mainly polyesthers and polyacrylates, in order to prepare 2 component systems. Only for professional use.


SDS-619/EN Indications for preparations containing isocyanates: Ready-to-use preparations containing isocyanates may have an irritant effect on mucous membranes -especially on breathing organs- and cause hypersensitivity reactions. Inhalation of vapour or spray mist may cause sensitisation. When handling preparations containing isocyanates all precautions required for solvent-containing preparations must be followed. Vapour and spray mist in particular should not be inhaled. Allergics and asthmatics, as well as people prone to respiratory ailments should not work with isocyanate-containing preparations. Text of R-phrases listed in section 2: R10 Flammable. R11 Highly flammable. R20 Harmful by inhalation. R36 Irritating to eyes. R38 Irritating to skin. R43 May cause sensitisation by skin contact. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. R20/21 Harmful by inhalation and in contact with skin. R36/37/38 Irritating to eyes, respiratory system and skin. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Note P : It is unnecessary to apply the classification as carcinogenic if it can be proved that the substance contains less than 0.1% benzene (EC No. 200-753-7) in weight. Labelling regulations: The information provided in this Material Safety Data Sheet has been written in accordance with 67/548/EEC (Substances), 88/379/EEC (Preparations) and 91/155/EEC (Material Safety Data Sheet) directives. It has been updated to Guideline 2001/59/EC (Substances), 2001/60/EC (Preparations) and 2001/58/EC (Material Safety Data Sheet). The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 06.05.04 MX703 Page: 1/7

SDS-621/EN *1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: MX703 Code: 51235 1.2 Use of the preparation: Hardener for 2K primers. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) *2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 25-50 % Aliphatic polyisocyanate R43 Xi NLP No. 500-060-2 CAS: 28182-81-2 25-50 % Toluene R11 R20 F Xn EC No. 203-625-9 CAS: 108-88-3 SAX: TGK750 No. 601-021-00-3 10-25 % Ethyl acetate R11 R36 R66 R67 F Xi EC No. 205-500-4 CAS: 141-78-6 SAX: EFR000 No. 607-022-00-5 10-25 % n-butyl acetate R10 R66 R67 EC No. 204-658-1 CAS: 123-86-4 SAX: BPU750 No. 607-025-00-1 2,5-10 % Xylene (mixture of isomers) R10 R38 R20/21 Xn EC No. 215-535-7 CAS: 1330-20-7 SAX: XGS000 No. 601-022-00-9 < 2,5 % Naphtha solvent (oil), light aromatic R10 R65 R66 R67 R51/53 Xn N EC No. 265-199-0 CAS: 64742-95-6 No. 649-356-00-4 (Note P) < 1 % 1,2,4-trimethylbenzene R10 R20 R36/37/38 R51/53 Xn N EC No. 202-436-9 CAS: 95-63-6 SAX: TLL750 No. 601-043-00-3 For more information on dangerous ingredients, see sections 8, 11, 12 and 16. *3. IDENTIFICATION OF HAZARDS Highly flammable. Harmful by inhalation. May cause sensitisation by skin contact. Repeated exposure may cause skin dryness or cracking. Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment.


SDS-621/EN *4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. In the case of skin reddening or rashes, contact a doctor immediately. 4.3 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. *5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: Extinguishing powder or CO2. In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide, nitrogen oxides, isocyanate vapours, traces of hydrocyanic acid. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sews, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). The contaminated area should be cleaned up immediately with a suitable decontaminant. One possible (flammable) decontaminant comprises: water/ethanol or isopropanol/concentrated ammonia solution (d=0,880) = 45/50/5 parts by volume. Another possible (non-flammable) decontaminant is made up of water/sodium carbonate = 95/5 parts by weight. Add the same decontaminant to any residues and allow to stand for several days in an unsealed container until no further reaction occurs. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13.


SDS-621/EN *7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed. Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. Recommendations for the prevention of toxicological risks: People with a history of asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which isocyanate containing products are used. Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorised access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. Keep away from food, drink and animal foodstuffs. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Class B1. According to ITC MIE APQ-1, RD.379/2001. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 35ºC. 7.3 Incompatible materials: Keep away from water, oxidising agents, acids, alkalis, amines, alcohols, peroxides. 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions. Precautions should be taken to minimise exposure to atmospheric humidity or water, as carbon dioxide may be formed which, in closed containers can result in pressurisation. Care should be taken when re-opening partly used containers. Due to the sensitivity to humidity of the isocyanates, this product should be kept in the original container, or under pressure of dried nitrogen, for example. *8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC People with a history of asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which isocyanate containing products are used. 8.1 Occupational Exposure Limits (TLV) AGCIH 2002 TWA STEL Year ppm mg/m3 ppm mg/m3 Toluene 50 188 A4 Dermal 1996 Ethyl acetate 400 1440 1996 n-butyl acetate 150 713 200 950 1998 Xylene (mixture of isomers) 100 434 150 651 A4 1996 Naphtha solvent (oil), 50 260 Internal value light aromatic 1,2,4-trimethylbenzene 25 123 1987 A4 - Non classified as carcinogenic in humans. 8.2 Engineering measures: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particles and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn.


SDS-621/EN Vapour density: 3,14 Air = 1 at 20ºC Relative Lower explosive limit: 2,1 % Volume Ventilation requirement: 96 m3/l Air/Preparation to keep below 1/10 of the Lower Explosive Limit. 8.3 Protection of respiratory system: Avoid the inhalation of vapours. If the working area is insufficiently ventilated, or when operators, whether spraying or not, are inside the spraybooth, air-fed respiratory protective equipment is required. Mask: For short periods of work, an air-fed mask or a combination of charcoal filter and particle filter mask is recommended. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles designed to protect against liquid splashes. Face shield: No. 8.5 Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Personnel should wear antistatic clothing made of natural fibre or of high temperature resistant synthetic fibre. Wash contaminated work clothes before wearing them again. *9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Liquid - Colour: Colourless - Odour: Characteristic - Viscosity: 11 sec.FC4 20ºC ASTM D 1200-88 - Specific gravity: 0,98 g/cc at 20ºC - Boiling point: 77,1ºC at 760 mmHg - Flash point: 7ºC Setaflash - Autoignition temperature: 462,7ºC - Vapour pressure: 31,8 mmHg at 20ºC 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Possible dangerous reaction with water, oxidising agents, acids, alkalis, amines, alcohols, peroxides. Exothermic reaction with amines and alcohols. Reacts with water under evolution of CO2. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced. *11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic


SDS-621/EN contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. - Based on the properties of the isocyanate content of this product and existing technical data of similar preparations, it can be concluded that respiratory exposure may cause acute irritation and/or sensitisation of the respiratory system, resulting in asthmatic symptoms, wheezing and a tightness of the chest. Sensitised persons may subsequently show asthmatic symptoms when exposed to airborne concentrations of isocyanates well below the occupational exposure limit. Repeated exposure may lead to permanent respiratory disability. In case of prolonged contact, the skin can dry up and irritation could appear. 11.2 Dose and lethal concentrations for individual ingredients: DL50 Oral DL50 Cutaneous CL50 Inhalation mg/kg mg/kg mg/l.4hours Toluene 636 Rat 12124 Rabbit 49 Rat Ethyl acetate 5620 Rat 20000 Rabbit 200 Rat n-butyl acetate 10768 Rat 17600 Rabbit 9,7 Rat Xylene (mixture of isomers) 4300 Rat 1700 Rabbit 22 Rat Naphtha solvent (oil), 3900 Rat 3160 Rabbit light aromatic 1,2,4-trimethylbenzene 5000 Rat For more information about ingredients dangerous to health, see sections 2 and 8. *12. ECOLOGICAL INFORMATION No experimental ecotoxicological data on the preparation as such is available. 12.1 Spills on the soil: Prevent contamination of soil. 12.2 Spills in water: Harmful to aquatic organisms. May cause long-term adverse effects on the aquatic environment. Do not allow to escape into drains, sewers or water courses. - Hydrolisis: Reacts with water forming carbon dioxide and a solid insoluble product with high melting point (polyurea). This reaction is accelerated by surfactants (e.g. detergents) or by watersoluble solvents. 12.3 Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - VOC: 588 g/l ASTM D-3960 - Aromatic hydrocarbons: 36 % Weight 12.4 Ecotoxicological data for individual ingredients:


Toluene 24 Fishes 12 Daphnia 400 Algae n-butyl acetate 18 Fishes Xylene (mixture of isomers) 75 Fishes 16 Daphnia Naphtha solvent (oil), 9,2 Fishes 6,1 Daphnia light aromatic 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations.


SDS-621/EN 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. *14. TRANSPORT INFORMATION PAINT RELATED MATERIAL (FP<23ºC, viscous according 2.2.3.1.4, VP<110 kPa50ºC) 14.1 Land: Transport by road: ADR 2003 Transport by rail: RID Class: 3 Packaging group: III UN no. 1263 Transport document: Consignment paper Written instructions. 14.2 Sea: Transport by ship: IMDG 30-00 Class: 3 Packaging group: III UN no. 1263 Emergency Sheet (EmS): 3-05, 07 First Aid Guide (MFAG): 310, 313 Marine pollutant: No Transport document: Shipping Bill of lading 14.3 Air: Transport by plane: IATA/ICAO Class: 3 Packaging group: III UN no. 1263 Transport document: Air Bill of lading *15. INFORMATION ON REGULATIONS 15.1 EC Labelling: F, Xn This product is HIGHLY FLAMMABLE and HARMFUL in accordance with Guideline 67/548/EEC~2001/59/EC and 1999/45/EC~2001/60/EC. R20/21 Harmful by inhalation and in contact with skin. R43 May cause sensitisation by skin contact. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S23 Do not breathe vapour/spray. S36/37 Wear suitable protective clothing and gloves. S51 Use only in well-ventilated areas. P91 Contains isocyanates. See information supplied by the manufacturer. - Dangerous ingredients: Toluene 15.2 Type of packaging: According to current legislation. *16. OTHER INFORMATION Intended use: This material is to be used as a hardener component, in combination with hydroxylated polymers, mainly polyesthers and polyacrylates, in order to prepare 2 component systems. Only for professional use.


SDS-621/EN Indications for preparations containing isocyanates: Ready-to-use preparations containing isocyanates may have an irritant effect on mucous membranes -especially on breathing organs- and cause hypersensitivity reactions. Inhalation of vapour or spray mist may cause sensitisation. When handling preparations containing isocyanates all precautions required for solvent-containing preparations must be followed. Vapour and spray mist in particular should not be inhaled. Allergics and asthmatics, as well as people prone to respiratory ailments should not work with isocyanate-containing preparations. Text of R-phrases listed in section 2: R10 Flammable. R11 Highly flammable. R20 Harmful by inhalation. R36 Irritating to eyes. R38 Irritating to skin. R43 May cause sensitisation by skin contact. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. R20/21 Harmful by inhalation and in contact with skin. R36/37/38 Irritating to eyes, respiratory system and skin. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic

environment. Note P : It is unnecessary to apply the classification as carcinogenic if it can be proofed that the substance contains less than 0.1% benzene (EC No. 200-753-7) in weight. Labelling regulations: The information provided in this Material Safety Data Sheet has been written in accordance with 67/548/EEC (Substances), 88/379/EEC (Preparations) and 91/155/EEC (Material Safety Data Sheet) directives. It has been updated to 2001/59/EC (Substances), 2001/60/EC (Preparations) and 2001/58/EC (Material Safety Data Sheet) directives. The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 06.09.05 P5000 – P6000 – F1000 Page: 1/7

SDS-600/EN 1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: P5000 Code: 51227 P6000 Code: 51231 F1000 Code: 51227 1.2 Use of the preparation: Hardener for acrylic paints. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) *2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health and/or environment hazard, and/or with a Communitary workplace exposure limit: 25-50 % Aliphatic polyisocyanate R43 EC: 500-060-2 CAS: 28182-81-2 25-50 % n-butyl acetate R10 R66-R67 EC: 204-658-1 CAS: 123-86-4 SAX: BPU750 No. 607-025-00-1 ATP25 10-25 % Xylene (mixture of isomers) R10 Xn; R20/21 Xi; R38 EC: 215-535-7 CAS: 1330-20-7 SAX: XGS000 No. 601-022-00-9 ATP25 2,5-10 % 2-methoxy-1-methylethyl acetate R10 Xi; R36 EC: 203-603-9 CAS: 108-65-6 No. 607-195-00-7 ATP19 2,5-10 % Ethylbenzene F; R11 Xn; R20 EC: 202-849-4 CAS: 100-41-4 SAX: EGP500 No. 601-023-00-4 ATP12 < 0,5 % Hexamethylene-1,6-diisocyanate T; R23 Xi; R36/37/38 R42/43 EC: 212-485-8 CAS: 822-06-0 SAX: DNJ800 No. 615-011-00-1 ATP12 For more information on dangerous ingredients, see sections 8, 11, 12 and 16. *3. IDENTIFICATION OF HAZARDS Flammable. Harmful by inhalation. Harmful in contact with skin. May cause sensitization by skin contact. Irritating to skin. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person.


SDS-600/EN 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. In the case of skin reddening or rashes, contact a doctor immediately. 4.3 By contact with eyes: Remove contact lenses. Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: Extinguishing powder or CO2. In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use for extinguishing: direct water jet. 5.2 Specific risks: As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide, nitrogen oxides, isocyanate vapours, traces of hydrocyanic acid. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sews, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). The contaminated area should be cleaned up immediately with a suitable decontaminant. One possible (flammable) decontaminant comprises: water/ethanol or isopropanol/concentrated ammonia solution (d=0,880) = 45/50/5 parts by volume. Another possible (non-flammable) decontaminant is made up of water/sodium carbonate = 95/5 parts by weight. Add the same decontaminant to any residues and allow to stand for several days in an un-sealed container until no further reaction occurs. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. *7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed.


SDS-600/EN Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. - Flash point: 28ºC Setaflash - Autoignition temperature: 392,5ºC - Flammability range: 1,5-7,9 % Volume 25ºC - Flammability range: 1,1-10,8 % Volume 300ºC Recommendations for the prevention of toxicological risks: People with a history of asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which isocyanate containing products are used. Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. Keep away from living quarters. Keep away from food, drink and animal foodstuffs. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Class B1. According to ITC MIE APQ-1, RD.379/2001. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 35ºC. - Incompatible materials: Keep away from oxidizing agents, acids, alkalis, amines, alcohols, peroxides. - Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions. Precautions should be taken to minimise exposure to atmospheric humidity or water, as carbon dioxide may be formed which, in closed containers can result in pressurisation. Care should be taken when re-opening partly used containers. Due to the sensitivity to humidity of the isocyanates, this product should be kept in the original container, or under pressure of dried nitrogen, for example. - Type of packaging: According to current legislation. *8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC People with a history of asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which isocyanate containing products are used. 8.1 Occupational Exposure Limits: INSHT 2005: Spain VLA-ED-

ppm: VLA-ED-mg/m3:

VLA-EC -ppm:


123-86-4 150 724 200 965 - 1330-20-7 50 221 100 442 Dermal, VLB, VLI 108-65-6 50 275 100 550 Dermal, VLI 100-41-4 100 441 200 884 Dermal, VLB, VLI 822-06-0 0,005 0,035 - - Sen INRS ND 2098, 02/2005:



123-86-4 150 710 200 940 - 84 108-65-6 50 275 100 550 * - 100-41-4 100 442 200 884 * 84 822-06-0 0,01 0,075 0,02 0,15 AR 62 1330-20-7 50 221 100 442 * 4bis, 84


SDS-600/EN DFG 2004:


123-86-4 100 480 DFG, 37, Y 1330-20-7 100 440 DFG, H 108-65-6 50 270 DFG, EU, Y 100-41-4 100 440 DFG, H 822-06-0 0,005 0,035 DFG, 36 ACGIH 2004:

ACGIH(TLV) TWA-ppm: TWA-mg/m3: STEL-ppm: STEL-

mg/m3: Note: Note:

123-86-4 150 713 200 950 - - 1330-20-7 100 434 150 651 A4 S 108-65-6 50 275 100 550 - - 100-41-4 100 434 125 543 A3 - 822-06-0 0,005 0,034 - - - - 2000/39/EC and 98/24/EC:


mg/m3: Notes:

1330-20-7 50 221 100 442 Skin 108-65-6 50 275 100 550 Skin 100-41-4 100 442 200 884 Skin 8.2 Occupational exposure controls, Directive 89/686/EEC: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particles and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. - Protection of respiratory system: Avoid the inhalation of vapours. Avoid the inhalation of particles or spray mist arising from the application of this preparation. Mask: For short periods of work, you can consider the utilization of a combination mask with gas and particle filters, type A2-P2 (EN141/EN143). In order to obtain a suitable protection level, the filter class must be selected depending on the type and concentration of the contaminating agents present, in accordance with the specifications supplied by the filter producers. If the working area is insufficiently ventilated, or when operators, whether spraying or not, are inside the spraybooth, compressed air-fed respiratory protective equipment (EN137) is required. - Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles designed to protect against liquid splashes, with suitable lateral protection (EN166). Face shield: No. - Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Gloves resistant against chemicals (EN374). Boots: No. Apron: No. Clothing: It is advisable personnel wear antistatic clothing made of natural fibre or of high temperature resistant synthetic fibre. Wash contaminated work clothes before wearing them again. 8.3 Environmental exposure controls: Avoid any spillage in the environment of the product, wastes, packages or spraybooth sewages. Avoid any release into the atmosphere above the legal limits allowed. *9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Liquid - Colour: Colourless - Odour: Characteristic


SDS-600/EN - Viscosity: 12 sec CF/4 at 20ºC P5000 F1000 ASTM D 1200-88 13 sec CF/4 at 20ºC P6000 ASTM D 1200-88 - Specific gravity: 0,970 g/cc at 20ºC - Boiling point: 126,3ºC at 760 mmHg - Flash point: 28ºC Setaflash - Vapour pressure: 7,4 mmHg at 20ºC *10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Possible dangerous reaction with water, oxidizing agents, acids, alkalis, amines, alcohols, peroxides. Exothermic reaction with amines and alcohols. Reacts with water under evolution of CO2. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced, including isocyanates. *11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. Based on the properties of the isocyanate content of this product and existing technical data of similar preparations, it can be concluded that respiratory exposure may cause acute irritation and/or sensitization of the respiratory system, resulting in asthmatic symptoms, wheezing and a tightness of the chest. Sensitised persons may subsequently show asthmatic symptoms when exposed to airborne concentrations of isocyanates well below the occupational exposure limit. Repeated exposure may lead to permanent respiratory disability. In case of prolonged contact, the skin can dry up and irritation could appear. 11.2 Dose and lethal concentrations for individual ingredients:


n-butyl acetate 10768 Rat 17600 Rabbit 9,7 Rat Xylene (mixture of isomers) 4300 Rat 1700 Rabbit 22 Rat 1-methoxypropyl acetate 8532 Rat Ethylbenzene 3500 Rat 17800 Rabbit Hexamethylene- 738 Rat 593 Rabbit 1,6-diisocyanate For more information about ingredients dangerous to health, see sections 2 and 8. *12. ECOLOGICAL INFORMATION No experimental ecotoxicological data on the preparation as such is available.


SDS-600/EN 12.1 Spills on the soil: Prevent contamination of soil. 12.2 Spills in water: Do not allow to escape into drains, sewers or water courses. - Hydrolisis: Reacts with water forming carbon dioxide and a solid insoluble product with high melting point (polyurea). This reaction is accelerated by surfactants (e.g. detergents) or by watersoluble solvents. 12.3 Emissions to the atmosphere: Avoid any release into the atmosphere. - VOC: 616 g/l P5000 F1000 ASTM D-3960

582 g/l P6000 - Aromatic hydrocarbons: 26,1 % Weight 12.4 Ecotoxicological data for individual ingredients:


n-butyl acetate 18 Fishes Xylene (mixture of isomers) 75 Fishes 16 Daphnia Ethylbenzene 12 Fishes 33 Algae *13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste, Directive 75/442/EEC~91/156/EC: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers, Directive 94/62/EC: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. *14. TRANSPORT INFORMATION PAINT RELATED MATERIAL (FP>23ºC) 14.1 Transport by road, Directive 94/55/EC (ADR 2005): Transport by rail, Directive 96/49/EC (RID 2005): Class: 3 Packaging group: III UN no. 1263 Transport document: Consignment paper Written instructions. 14.2 Transport by sea (IMDG 32-04): Class: 3 Packaging group: III UN no. 1263 Emergency Sheet (EmS): 3-05,07 First Aid Guide (MFAG): 310,313 Marine pollutant: No Transport document: Shipping Bill of lading 14.3 Transport by air (ICAO/IATA): Class: 3 Packaging group: III UN no. 1263 Transport document: Air Bill of lading


SDS-600/EN *15. INFORMATION ON REGULATIONS 15.1 EC Labelling Xn This product is FLAMMABLE and HARMFUL in accordance with Guideline 67/548/EEC - 2004/73/EC and 1999/45/EC - 2001/60/EC. R10 Flammable. R20/21 Harmful by inhalation and in contact with skin. R43 May cause sensitization by skin contact. S23 Do not breathe vapour/spray. S36/37 Wear suitable protective clothing and gloves. S51 Use only in well-ventilated areas. P91 Contains isocyanates. See information supplied by the manufacturer Dangerous ingredients: Xylene (mixture of isomers) 15.2 Restrictions to the marketing and use in accordance with Directive 76/769/EEC: Not applicable. 15.3 Other regulations: Not available *16. OTHER INFORMATION - Intended use: This material is to be used as a hardener component, in combination with hydroxylated polymers, mainly polyesthers and polyacrylates, in order to prepare 2 component systems. Only for professional use. - Indications for preparations containing isocyanates: Ready-to-use preparations containing isocyanates may have an irritant effect on mucous membranes -especially on breathing organs- and cause hypersensitivity reactions. Inhalation of vapour or spray mist may cause sensitisation. When handling preparations containing isocyanates all precautions required for solvent-containing preparations must be followed. Vapour and spray mist in particular should not be inhaled. Allergics and asthmatics, as well as people prone to respiratory ailments should not work with isocyanate-containing preparations. - Text of R-phrases listed in section 2: R10 Flammable. R11 Highly flammable. R20 Harmful by inhalation. R23 Toxic by inhalation. R36 Irritating to eyes. R38 Irritating to skin. R43 May cause sensitization by skin contact. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. R20/21 Harmful by inhalation and in contact with skin. R36/37/38 Irritating to eyes, respiratory system and skin. R42/43 May cause sensitization by inhalation and skin contact. Material Safety Data Sheet regulations: Material Safety Data Sheet in accordance with Directive 91/155/EEC~2001/58/EC. The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 28.09.05 HIDROTEX Page: 1/5

SDS-505/EN 1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: HIDROTEX Grey Code: 51079 HIDROTEX Black Code: 51080 1.2 Use of the preparation: Stone chip protector for bodywork. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) 2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health and/or environment hazard, and/or with a Communitary workplace exposure limit: 2,5-10 % Butylglycol EC: 203-905-0 Xn; R20/21/22 Xi; R36/38 CAS: 111-76-2 No. 603-014-00-0 For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS This product is not considered dangerous. in accordance with Directive 67/548/EEC - 2004/73/EC and 1999/45/EC - 2001/60/EC. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. 4.3 By contact with eyes: Remove contact lenses. Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: Extinguishing powder or CO2. In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use for extinguishing: direct water jet.


SDS-505/EN 5.2 Specific risks: As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sews, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Avoid use of solvents. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Use in areas free from sources of ignition and away from heat or electrical sources. Do not smoke. Avoid any type of leakage or escape. Keep the container tightly closed. - Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. - Flash point: >61ºC Setaflash - Flammability range: 1,1 – 11,7 % Volume 25ºC - Flammability range: 0,7 – 14,5 % Volume 300ºC - Recommendations for the prevention of toxicological risks: Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: According to current legislation. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 35ºC. - Incompatible materials: Keep away from oxidizing agents, from strongly alkaline and strongly acid materials. - Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions. - Type of packaging: According to current legislation.


SDS-505/EN 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC 8.1 Occupational Exposure Limits (TLV) AGCIH 2004


Butylglycol 20 98 A3 2003 8.2 Ocupational exposure controls, Directive 89/686/EEC: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficent to maintain concentrations of particulates and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. - Protection of respiratory system: Avoid the inhalation of vapours. Avoid the inhalation of particles or spray mist arising from the application of this preparation. Mask: Suitable combined filter mask for gases, vapours and particles (EN141/EN143). In order to obtain a suitable protection level, the filter class must be selected depending on the type and concentration of the contaminating agents present, in accordance with the specifications supplied by the filter producers. - Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles designed to protect against liquid splashes, with suitable lateral protection (EN166). Face shield: No. - Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Gloves resistant against chemicals (EN374). Boots: No. Apron: No. Clothing: Advisable. 8.3 Environmental exposure controls: Avoid any spillage in the environment of the product, wastes, packages or spraybooth sewages. Avoid any release into the atmosphere above the legal limits allowed. 9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Liquid - Colour: Grey / Black - Viscosity: 350.000 cps 20ºC Brookfield - Specific gravity: 1,19 g/cc at 20ºC Hidrotex grey 1,20 g/cc at 20ºC Hidrotex black - Boiling point: >100ºC at 760 mmHg - Flash point: >61ºC Setaflash - Vapour pressure: 17,2 mmHg at 20ºC 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced. 11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available.


SDS-505/EN 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. This preparation contains glycols that are readily absorbed through the skin and may cause harmful effects on the blood. 11.2 Dose and lethal concentrations for individual ingredients:


Butylglycol 470 Rat 220 Rabbit For more information about ingredients dangerous to health, see sections 2 and 8. 12. ECOLOGICAL INFORMATION No experimental ecotoxicological data on the preparation as such is available. 12.1 Spills on the soil: Prevent contamination of soil. 12.2 Spills in water: Do not allow to escape into drains, sewers or water courses. 12.3 Emissions to the atmosphere: Avoid any release into the atmosphere. - Product VOC: 93 g/l Hidrotex grey ASTM D-3960 94 g/l Hidrotex black ASTM D-3960 12.4 Ecotoxicological data for individual ingredients: CL50 CE50 CI50

mg/l.96hours mg/l.48hours mg/l.72hours Butylglycol 1395 Fishes 1815 Daphnia 500 Algae 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste, Directive 75/442/EEC~91/156/EC: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers, Directive 94/62/EC: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. 13.3 Procedures for neutralising or destroying the product: Authorised landfill in accordance with local regulations. 14. TRANSPORT INFORMATION 14.1 Transport by road, Directive 94/55/EC (ADR 2005): Free Transport by rail, Directive 96/49/EC (RID 2005): Free


SDS-505/EN 14.2 Transport by sea (IMDG 32-04): Free 14.3 Transport by air (ICAO/IATA): Free 15. INFORMATION ON REGULATIONS 15.1 EC Labelling This product does not require pictograms in accordance with Directive 67/548/EEC - 2004/73/EC and 1999/45/EC - 2001/60/EC. S23 Do not breathe vapour, spray. S29 Do not empty into drains. S51 Use only in well-ventilated areas. Safety data sheet available for professional user on request. Dangerous ingredients: None in a percentage equal to or higher than the limit for the name. · It is applicable the Directive 2004/42/EC, Annex I.2): Emission subcategory E). VOC (product ready for use): 93 g/l (grey) 94 g/l (black) , VOC max: 840 g/l starting from 01.01.2007 15.2 Restrictions to the marketing and use in accordance with Directive 76/769/EEC: Not applicable. 15.3 Other regulations: Not available 16. OTHER INFORMATION Intended use Only for professional use. Text of R-phrases listed in section 2: R20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R36/38 Irritating to eyes and skin. Material Safety Data Sheet regulations: Material Safety Data Sheet in accordance with Directive 91/155/EEC~2001/58/EC. The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 06.05.04 ISOLCAR Page: 1/6

SDS-311/EN *1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: ISOLCAR Code: 51191 1.2 Use of the preparation: Bodywork nytrosynthetic base. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) 2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 10-25 % Xylene (mixture of isomers) R10 R38 R20/21 Xn EC No. 215-535-7 CAS: 1330-20-7 SAX: XGS000 No. 601-022-00-9 2,5-10 % Ethyl acetate R11 R36 R66 R67 F Xi EC No. 205-500-4 CAS: 141-78-6 SAX: EFR000 No. 607-022-00-5 2,5-10 % Toluene R11 R20 F Xn EC No. 203-625-9

CAS: 108-88-3 SAX: TGK750 No. 601-021-00-3 2,5-10 % n-butyl acetate R10 R66 R67 EC No. 204-658-1 CAS: 123-86-4 SAX: BPU750 No. 607-025-00-1 2,5-10 % Ethylbenzene R11 R20 F Xn EC No. 202-849-4 CAS: 100-41-4 SAX: EGP500 No. 601-023-00-4

For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Highly flammable. Harmful by inhalation. Harmful in contact with skin. *4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives.


SDS-311/EN 4.2 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. 4.3 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. *5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: In case of fire, use alcohol-resistant foam, dry chemical powder, carbon dioxide, AFFF. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous products may be produced: carbon monoxide, carbon dioxide, nitrogen oxides. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sewages, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Clean preferably with a detergent. Avoid use of solvents. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed. Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. Recommendations for the prevention of toxicological risks: Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8.


SDS-311/EN 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Class B1. According to MIE APQ-1, RD.379/2001. Maximum storage period: 12. months. Temperature interval: min: 5ºC, max: 30ºC. 7.3 Incompatible materials: Keep away from oxidizing agents, from strongly alkaline and strongly acid materials. 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions. *8. EXPOSURE CONTROLS/PERSONAL PROTECTION (98/24/CE) 8.1 Occupational Exposure Limits (TLV) AGCIH 2002


Ethyl acetate 400 1440 1996 Toluene 50 188 A4 Dermal 1996 Xylene (mixture of isomers) 100 434 150 651 A4 1996 n-butyl acetate 150 713 200 950 1998 Ethylbenzene 100 434 125 543 1976 A4 - Non classified as carcinogenic in humans. 8.2 Engineering measures: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particles and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. Vapour density: 2,98 Air=1 at 20ºC Relative Lower explosive limit: 1,9 % Volume Ventilation requirement: 56 m3/l Air/Preparation to keep below 1/10 of the Lower Explosive Limit. 8.3 Protection of respiratory system: Avoid the inhalation of vapours. When operators, whether spraying or not, are inside the spraybooth, and ventilation is unlikely to be sufficient to constantly control particles and solvent vapour in all cases, in such circumstances they should wear a compressed air-fed respirator during the spraying process and until such a time as the particles and solvent vapour concentration has fallen below the exposure limits. Mask: Filter mask. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles designed to protect against liquid splashes. Face shield: No. 8.5 Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Personnel should wear antistatic clothing made of natural fibre or of high temperature resistant synthetic fibre. Wash contaminated work clothes before wearing them again. *9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Liquid - Colour: Grey - Odour: Characteristic - Viscosity: 8000 cps at 20ºC Brookfield - Specific gravity: 1,32 g/cc at 20ºC - Boiling point: 77,1ºC a 760 mmHg


SDS-311/EN - Decomposition temperature: 170ºC - Flash point: 9ºC Setaflash - Autoignition temperature: 170ºC - Vapour pressure: 26,8 mmHg at 20ºC 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents, acids, alkalis, amines, peroxides. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced: nitrogen oxides. *11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. 11.2 Dose and lethal concentrations for individual ingredients:


Ethyl acetate 5620 Rat 20000 Rabbit 200 Rat Toluene 636 Rat 12124 Rabbit 49 Rat Xylene (mixture 4300 Rat 1700 Rabbit 22 Rat of isomers) n-butyl acetate 10768 Rat 17600 Rabbit 9,7 Rat Ethylbenzene 3500 Rat 17800 Rabbit For more information about ingredients dangerous to health, see sections 2 and 8. *12. ECOLOGICAL INFORMATION No experimental ecotoxicological data on the preparation as such is available. 12.1 Spills on the soil: Prevent contamination of soil. 12.2 Spills in water: Do not allow to escape into drains, sewers or water courses. 12.3 Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - VOC: 535 g/l ASTM D-3960 - Aromatic hydrocarbons: 26,8 % Weight 12.4 Ecotoxicity: Ecotoxicological data for individual ingredients: CL50 CE50 CI50

mg/l.96hours mg/l.48hours mg/l.72hours Toluene 24 Fishes 12 Daphnia 400 Algae Xylene (mixture of isomers) 75 Fishes 16 Daphnia


SDS-311/EN CL50 CE50 CI50

mg/l.96hours mg/l.48hours mg/l.72hours n-butyl acetate 18 Fishes Ethylbenzene 12 Fishes 33 Algae 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. *14. TRANSPORT INFORMATION PAINTS (FP<23ºC, viscous according to 2.2.3.1.4, VP<110 kPa50ºC) 14.1 Land: Transport by road: ADR 2003 Transport by rail: RID Class: 3 Packaging group: III UN no. 1263 Transport document: Consignment paper Written instructions. 14.2 Sea: Transport by ship: IMDG 30-00 Class: 3 Packaging group: III UN no. 1263 Emergency Sheet (EmS): 3-05, 07 First Aid Guide (MFAG): 310, 313 Marine pollutant: No Transport document: Shipping Bill of lading 14.3 Air: Transport by plane: IATA/ICAO Class: 3 Packaging group: III UN no. 1263 Transport document: Air Bill of lading *15. INFORMATION ON REGULATIONS 15.1 EC Labelling F, Xn This product is HIGHLY FLAMMABLE and HARMFUL in accordance with Guideline 67/548/EEC - 2001/59/EC and 1999/45/EC - 2001/60/EC. R20/21 Harmful by inhalation and in contact with skin. S23 Do not breathe vapour, spray. S36/37 Wear suitable protective clothing and gloves. S43 In case of fire, use water spray, alcohol-resistant foam, dry chemical powder, carbon

dioxide, AFFF. S51 Use only in well-ventilated areas.


SDS-311/EN Dangerous ingredients: Xylene (mixture of isomers) 15.2 Type of packaging: According to current legislation. *16. OTHER INFORMATION Intended use Only for professional use. Text of R-phrases listed in section 2: R10 Flammable. R11 Highly flammable. R21 Harmful in contact with skin. R36 Irritating to eyes. R38 Irritating to skin. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. R20/21 Harmful by inhalation and in contact with skin. Labelling regulations: The information provided in this Material Safety Data Sheet has been written in accordance with Guideline 67/548/EEC (Substances), 88/379/EEC (Preparations) and 91/155/EEC (Material Safety Data Sheet). It has been updated to Guideline 2001/59/EC (Substances), 2001/60/EC (Preparations) and 2001/58/EC (Material Safety Data Sheet). The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 24.01.06 MASTICPLAST - SN96 - ALUMINIO Page: 1/6

SDS-101/EN 1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: MASTICPLAST Code: 51170 SN96 Code: 51172 ALUMINIO Code: 51173 1.2 Use of the preparation: Bodywork repair unsaturated polyester paste. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) *2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health and/or environment hazard, and/or with a Communitary workplace exposure limit: 10-25 % Styrene EC: 202-851-5 R10 Xn; R20 Xi; R36/38 CAS: 100-42-5 No. 601-026-00-0 For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Flammable. Harmful by inhalation. Irritating to eyes. Irritating to skin. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. 4.3 By contact with eyes: Remove contact lenses. Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: Extinguishing powder or CO2. In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use for extinguishing: direct water jet.


SDS-101/EN 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sews, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Avoid use of solvents. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. *7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed. - Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. - Flash point: 32ºC Setaflash - Autoignition temperature: 490ºC - Flammability range: 1,1 – 6,2 % Volume 25ºC - Recommendations for the prevention of toxicological risks: Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Class B1. According to. ITC MIE APQ-1, RD 379/2001. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 32ºC. - Combustion heat: 4607 Kcal/kg SN96 3050 Kcal/kg Aluminio - Incompatible materials: Keep away from oxidizing agents, from strongly alkaline and strongly acid materials. - Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions.


SDS-101/EN - Type of packaging: According to current legislation. *8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC 8.1 Occupational Exposure Limits: INSHT 2005: Spain VLA-ED-

ppm: VLA-ED-mg/m3:

VLA-EC -ppm:


100-42-5 20 86 40 172 VLB, ae INRS ND 2098, 02/2005:



100-42-5 50 215 - - - 84 DFG 2004:


100-42-5 20 86 DFG, Y ACGIH 2004:


STEL-ppm:

STEL-mg/m3: Note:

100-42-5 20 85 40 170 A4 2000/39/EC and 98/24/EC:


mg/m3: Notes:



SDS-101/EN *9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Paste - Colour: Grey (Masticplast)/ Metallic (SN96, Aluminio) - Odour: Characteristic - Viscosity: 10 x 106 cps 20ºC Brookfield (Masticplast) 8,5 x 106 cps 20ºC Brookfield (SN96) 7 x 106 cps 20ºC Brookfield (Aluminio) - Specific gravity: 1,80 g/cc at 20ºC (Masticplast) 1,55 g/cc at 20ºC (SN96) 1,85 g/cc at 20ºC (Aluminio) - Solubility in water (styrene): 310 mg/l - Boiling point: 145,2ºC at 760 mmHg - Flash point: 32ºC Setaflash - Vapour pressure: 4,5 mmHg at 20ºC 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents, acids, alkalis, peroxides. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced. 11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. 11.2 Dose and lethal concentrations for individual ingredients:


Styrene 2650 Rat 12 Rat For more information about ingredients dangerous to health, see sections 2 and 8. *12. ECOLOGICAL INFORMATION No experimental ecotoxicological data on the preparation as such is available. 12.1 Spills on the soil: Prevent contamination of soil. 12.2 Spills in water: Do not allow to escape into drains, sewers or water courses. 12.3 Emissions to the atmosphere: Avoid any solvent release into the atmosphere.


SDS-101/EN - Mixing application VOC: 50 g/l Masticplast ASTM D-3960 26 g/l SN96 24 g/l Aluminio - Aliphatic hydrocarbons: 0,2 (Masticplast) / 0,3 (SN96) % Weight - Aromatic hydrocarbons: 14,8 (Masticplast)/ 23,3 (SN96)/ 16,1 (Aluminio) % Weight 12.4 Ecotoxicological data for individual ingredients: CL50 CE50 CI50

mg/l.96hours mg/l.48hours mg/l.72hours Styrene 255 Dafnia *13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste, Directive 75/442/EEC~91/156/EC: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers, Directive 94/62/EC: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. *14. TRANSPORT INFORMATION 14.1 Transport by road, Directive 94/55/EC (ADR 2005): Free Transport by rail, Directive 96/49/EC (RID 2005): Free 14.2 Transport by sea (IMDG 32-04): Free 14.3 Transport by air (ICAO/IATA): Free *15. INFORMATION ON REGULATIONS 15.1 EC Labelling Xn This product is FLAMMABLE and HARMFUL in accordance with Guideline 67/548/EEC - 2004/73/EC and 1999/45/EC - 2001/60/EC. R10 Flammable. R20 Harmful by inhalation. R36/38 Irritating to eyes and skin. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S51 Use only in well-ventilated areas. Dangerous ingredients: Styrene · It is applicable the Directive 2004/42/EC, Annex I.2): Emission subcategory B). VOC (product ready for use): 50 g/l (Masticplast), 26 g/l (SN96), 24 g/l (Aluminio), VOC max: 250 g/l starting from 01.01.2007 15.2 Restrictions to the marketing and use in accordance with Directive 76/769/EEC: Not applicable. 15.3 Other regulations: Not available.


SDS-101/EN *16. OTHER INFORMATION Intended use: Only for professional use. Text of R-phrases listed in section 2: R10 Flammable. R20 Harmful by inhalation. R36/38 Irritating to eyes and skin. Material Safety Data Sheet regulations: Material Safety Data Sheet in accordance with Directive 91/155/EEC~2001/58/EC. The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 23.03.06 MAXILIGHT Page: 1/6

SDS-004/EN 1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: MAXILIGHT Code: 51043 1.2 Use of the preparation: Bodywork repair unsaturated polyester paste. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) 2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health and/or environment hazard, and/or with a Communitary workplace exposure limit: 10-25 % Styrene EC: 202-851-5 R10 Xn; R20 Xi; R36/38 CAS: 100-42-5 No. 601-026-00-0 For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Flammable. Harmful by inhalation. Irritating to eyes. Irritating to skin. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. 4.3 By contact with eyes: Remove contact lenses. Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: Extinguishing powder or CO2. In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon


SDS-004/EN monoxide, carbon dioxide. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sews, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Avoid use of solvents. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed. - Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. - Flash point: 32ºC Setaflash - Autoignition temperature: 490ºC - Flammability range: 1,1 – 6,3 % Volume 25ºC - Flammability range: 0,8 – 8,9 % Volume 300ºC - Recommendations for the prevention of toxicological risks: Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Class B1. According to. ITC MIE APQ-1, RD 379/2001. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 32ºC. - Combustion heat: 3480 Kcal/kg - ncompatible materials: Keep away from oxidizing agents, from strongly alkaline and strongly acid materials. - Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions. - Type of packaging: According to current legislation.


SDS-004/EN 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC 8.1 Occupational Exposure Limits: INSHT 2005: Spain VLA-ED-

ppm: VLA-ED-mg/m3:

VLA-EC -ppm:


100-42-5 20 86 40 172 VLB, ae INRS ND 2098, 02/2005:



100-42-5 50 215 - - - 84 DFG 2004:


100-42-5 20 86 DFG, Y ACGIH 2004:


STEL-ppm:

STEL-mg/m3: Note:

100-42-5 20 85 40 170 A4 2000/39/EC and 98/24/EC:


mg/m3: Notes:

- - - - - - 8.2 Occupational exposure controls, Directive 89/686/EEC: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particulates and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. - Protection of respiratory system: Avoid the inhalation of vapours. Mask: Mask for gases and vapours (EN141). In order to obtain a suitable protection level, the filter class must be selected depending on the type and concentration of the contaminating agents present, in accordance with the specifications supplied by the filter producers. The respiratory equipment with filters does not work satisfactorily when the air contains high concentrations of vapour. - Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles with suitable lateral protection (EN166). Face shield: No. - Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Gloves resistant against chemicals (EN374). The breakthrough time of the selected glove material should be superior to the pretended period of use. The gloves should be immediately replaced when any sign of degradation is noted. Boots: No. Apron: No. Clothing: Suitable work clothes which avoid contact with the product should be worn. 8.3 Environmental exposure controls: Avoid any spillage in the environment of the product, wastes, packages or spraybooth sewages. Avoid any release into the atmosphere above the legal limits allowed. *9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Paste - Colour: Cream, grey - Odour: Characteristic - Viscosity: 1,9 x 106 cps 20ºC Brookfield


SDS-004/EN - Specific gravity: 1,10 g/cc at 20ºC Cream - 1,20 g/cc at 20ºC Grey - Solubility in water (styrene): 310 mg/l - Boiling point: 145,2ºC at 760 mmHg - Flash point: 32ºC Setaflash - Vapour pressure: 4,5 mmHg at 20ºC 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents, acids, alkalis, peroxides. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced. 11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. 11.2 Dose and lethal concentrations for individual ingredients:


Styrene 2650 Rat 12 Rat For more information about ingredients dangerous to health, see sections 2 and 8. 12. ECOLOGICAL INFORMATION No experimental ecotoxicological data on the preparation as such is available. 12.1 Spills on the soil: Prevent contamination of soil. 12.2 Spills in water: Do not allow to escape into drains, sewers or water courses. 12.3 Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - Mixing application VOC: 25 g/l ASTM D-3960 - Aromatic hydrocarbons: 19,2 % Weight 12.4 Ecotoxicological data for individual ingredients: CL50 CE50 CI50

mg/l.96hours mg/l.48hours mg/l.72hours Styrene 255 Dafnia


SDS-004/EN 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste, Directive 75/442/EEC~91/156/EC: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers, Directive 94/62/EC: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. 14. TRANSPORT INFORMATION 14.1 Transport by road, Directive 94/55/EC (ADR 2005): Free Transport by rail, Directive 96/49/EC (RID 2005): Free 14.2 Transport by sea (IMDG 32-04): Free 14.3 Transport by air (ICAO/IATA): Free 15. INFORMATION ON REGULATIONS 15.1 EC Labelling Xn This product is FLAMMABLE and HARMFUL in accordance with Guideline 67/548/EEC - 2004/73/EC and 1999/45/EC - 2001/60/EC. R10 Flammable. R20 Harmful by inhalation. R36/38 Irritating to eyes and skin. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S51 Use only in well-ventilated areas. Dangerous ingredients: Styrene · It is applicable the Directive 2004/42/EC, Annex I.2): Emission subcategory B). VOC (product ready for use): 25 g/l, VOC max: 250 g/l starting from 01.01.2007 15.2 Restrictions to the marketing and use in accordance with Directive 76/769/EEC: Not applicable. 15.3 Other regulations: Not available. 16. OTHER INFORMATION Intended use: Only for professional use. Text of R-phrases listed in section 2: R10 Flammable. R20 Harmful by inhalation. R36/38 Irritating to eyes and skin. Material Safety Data Sheet regulations: Material Safety Data Sheet in accordance with Directive 91/155/EEC~2001/58/EC.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 04.02.03 MEGAX M1 / MEGAX X5 Page: 1/7

SDS-312/EN *1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: MEGAX M1 Code: 51187 MEGAX X5 Code: 51188 1.2 Use of the preparation: Bodywork repair filler. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) *2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 10-25% Xylene R10 R38 R20/21 Xn CAS: 1330-20-7

(mixture of isomers) EC No. 215-535-7 SAX: XGS000 No. 601-022-00-9

2,5-10% n-butyl acetate R10 R66 R67 CAS: 123-86-4 EC No. 204-658-1 SAX: BPU750 No. 607-025-00-1

2,5-10% 1-methoxypropyl acetate R10 R36 Xi CAS: 108-65-6 EC No. 203-603-9 No. 607-195-00-7 <2,5 % Naphtha solvent (oil), light aromatic

R10 R65 R66 R67 R51/53 Xn N CAS: 64742-95-6 EC No. 265-199-0

No. 649-356-00-4 (Note P) <2,5 % Ethylbenzene R11 R20 F Xn CAS: 100-41-4

EC No. 202-849-4 SAX: EGP500 No. 601-023-00-4

For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Flammable. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives.


SDS-312/EN 4.2 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.3 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sewages, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Clean preferably with a detergent. Avoid use of solvents. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed. - Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off.


SDS-312/EN - Recommendations for the prevention of toxicological risks: Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. Keep away from living quarters. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Class B1. According to ITC MIE APQ-1, RD.379/2001. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 35ºC. 7.3 Incompatible materials: Keep away from oxidizing agents from strongly alkaline and strongly acid materials. 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions. *8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/CE 8.1 Occupational Exposure Limits (TLV) AGCIH 2001


Xylene (mixture of isomers) 100 434 150 651 A4 1996 n-butyl acetate 150 713 200 950 1998 1-methoxypropyl acetate 50 275 100 550 Recommended Dermal Naphtha solvent (oil), 50 260 Internal value light aromatic Ethylbenzene 100 434 125 543 1976 A4 - Non classified as carcinogenic in humans. 8.2 Engineering measures: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particles and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. - Vapour density: 3.87 Air = 1 at 20ºC Relative - Lower explosive limit: 1.4 % Volume - Ventilation requirement: 41 m3/l Air/Preparation MEGAX M1 42 m3/l Air/ Preparation MEGAX X5 to keep below 1/10 of the Lower Explosive Limit. - Ventilation requirement: 16907 m3/l (maximum) Air/Preparation to keep below the Occupational Exposure Limit of the product. (application by pulverization and assuming a transfer efficiency of 80%). Special ventilation is required. 8.3 Protection of respiratory system: Avoid the inhalation of vapours. When operators, whether spraying or not, are inside the spraybooth, and ventilation is unlikely to be sufficient to constantly control particles and solvent vapour in all cases, in such circumstances they should wear a compressed air-fed respirator during the spraying process and until such a time as the particles and solvent vapour concentration has fallen below the exposure limits. Mask: Filter mask. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles designed to protect against liquid splashes. Face shield: No. 8.5 Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Personnel should wear antistatic clothing made of natural fibre or of high temperature resistant synthetic fibre.


SDS-312/EN *9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Viscous liquid - Colour: Light grey/Dark grey - Odour: Characteristic - Viscosity: 50.000 cps 20ºC Brookfield - Specific gravity: 1.61 g/cc at 20ºC MEGAX M1 1.51 g/cc at 20ºC MEGAX X5 - Boiling point: 126.3ºC at 760 mmHg - Flash point: 27ºC Setaflash - Autoignition temperature: 402.2ºC - Decomposition temperature: 350ºC - Vapour pressure: 6.9 mmHg at 20ºC 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents, acids, alkalis, peroxides. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced. 11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. 11.2 Dose and lethal concentrations for individual ingredients:


Xylene (mixture of isomers) 4300 Rat 1700 Rabbit 22 Rat n-butyl acetate 13100Rat 5000 Rabbit 9.7 Rat 1-methoxypropyl acetate 8532 Rat Naphtha solvent (oil), 3900 Rat 3160 Rabbit 14 Rat light aromatic Ethylbenzene 3500 Rat 17800Rabbit For more information about ingredients dangerous to health, see sections 2 and 8. *12. ECOLOGICAL INFORMATION Prevent contamination of soil. Do not allow to escape into drains, sewers or water courses.


SDS-312/EN Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - VOC: 390 g/l MEGAX M1 ASTM D-3960 402 g/l MEGAX X5 - Aromatic hydrocarbons: 14% Weight 12.1 Ecotoxicity: No experimental ecotoxicological data on the preparation as such is available. Ecotoxicological data for individual ingredients: CL50 CE50 CI50

mg/l.96hours mg/l.48hours mg/l.72hours Xylene (mixture of isomers) 75 Fishes 16 Daphnia n-butyl acetate 18 Fishes 10 Daphnia 21 Algae Naphtha solvent (oil), 9.2 Fishes 6.1Daphnia light aromatic Ethylbenzene 12 Fishes 33 Algae 12.2 Mobility : N/A 12.3 Persistence and degradability: In water : t ½ life = 29 - 144 hours (Xylene) In air: t ½ life = 1 - 18 hours (Xylene) 12.4 Bioaccumulative potential : log Pow = 1.82 (n-butyl acetate) log Pow = 3.12 - 3.20 (Xylene) BCF = 14 (n-butyl acetate) N/A: Not available. 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. *14. TRANSPORT INFORMATION PAINTS (FP>23ºC, viscous according to 2.2.3.1.5) 14.1 Land: Transport by road: ADR-2001

Transport by rail: RID/TPF Good not submitted to Class 3.¹

¹ Transport in accordance with 2.2.3.1.5 for viscous liquids in packages with capacity under 450 L


14.2 Sea: Transport by ship: IMDG Class: 3 UN nº1263 Marine pollutant: no Packaging group: III Emergency Sheet (EmS): 3-05, 07 First Aid Guide (MFAG): 310, 313 Transport document: Shipping Bill of Lading




15. INFORMATION ON REGULATIONS 15.1 EC Labelling: This product is flammable in accordance with 67/548/EEC - 2001/59/EC and 1999/45/EC - 2001/60/EC directives. R10 Flammable. S23 Do not breathe vapour, spray. S36/37 Wear suitable protective clothing and gloves. S51 Use only in well-ventilated areas Dangerous ingredients: None in a percentage equal to or higher than the limit for the name. 15.2 Type of packaging: According to current legislation. *16. OTHER INFORMATION Intended use Only for professional use. Text of R-phrases listed in section 2: R10 Flammable. R11 Highly flammable. R20 Harmful by inhalation. R36 Irritating to eyes. R38 Irritating to skin. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. R20/21 Harmful by inhalation and in contact with skin. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic

environment. Note P : It is unnecessary to apply the classification as carcinogenic if it can be proved that the substance contains less than 0.1% benzene (EC No. 200-753-7) in weight. Labelling regulations: The information provided in this Material Safety Data Sheet has been written in accordance wit 67/548/EEC (Substances), 88/379/EEC (Preparations) and 91/155/EEC (Material Safety Data Sheet) directives. It has been updated to 2001/59/EC (Substances), 2001/60/EC (Preparations) and 2001/58/EC (Material Safety Data Sheet) directives. The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to


SDS-312/EN take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 12.01.05 ROBERCAR MORDENTE - ROBERCAR LUCIDANTE Page: 1/5

SDS-200/EN 1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: ROBERCAR MORDENTE Code: 51176 ROBERCAR LUCIDANTE Code: 51177 1.2 Use of the preparation: Rubbing compound. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) 2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health and/or environment hazard, and/or with a Communitary workplace exposure limit: 10-25 % Gasoil R40 R65 R66 R51/53 Xn N EC No. 269-822-7

CAS: 68334-30-5 No. 649-224-00-6 2,5-10 % Distilates (oil), light hydrotreated R65 R66 Xn EC No. 265-149-8 CAS: 64742-47-8 No. 649-422-00-2 2,5-10 % Kerosene (oil), hydrodesulfurized R65 R66 Xn EC No. 265-184-9

CAS: 64742-81-0 No. 649-423-00-8 For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Limited evidence of a carcinogenic effect. Repeated exposure may cause skin dryness or cracking. Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and a solution of 5% sodium bicarbonate. Finally, rewash the affected area with soap and water. Do not use solvents or thinners. 4.3 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately.


SDS-200/EN 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Due to its acid condition, the effects can be reduced to a minimumm by drinking plenty of water, to which milk of magnesia has been added. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: Extinguishing powder or CO2. In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide, sulfur oxides. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sews, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with electrically-protected vacuum cleaner or by wet brushing. Do not use a dry brush as dust clouds or static electricity can be created. Avoid use of solvents. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Use in areas free from sources of ignition and away from heat or electrical sources. Do not smoke. Avoid any type of leakage or escape. Keep the container tightly closed. - Recommendations for the prevention of fire and explosion risks: Flash point: > 50ºC Recommendations for the prevention of toxicological risks: Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: According to current legislation. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 35ºC. - Incompatible materials: Keep away from oxidizing agents, from strongly alkaline and strongly acid materials.


SDS-200/EN - Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. - Type of packaging: According to current legislation. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC 8.1 Occupational Exposure Limits (TLV) AGCIH 2002


Distilates (oil), light hydrotreated 100 525 Internal value Kerosene (oil), hydrodesulfurized 100 525 Internal value 8.2 Ocupational exposure controls, Directive 89/686/EEC: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. - Protection of respiratory system: Mask: Dust mask. - Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Suitable safety goggles. Face shield: No. - Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Suitable work clothes which avoid contact with the product should be worn. 8.3 Environmental exposure controls: Avoid any spillage in the environment of the product, wastes, packages or spraybooth sewages. Avoid any release into the atmosphere above the legal limits allowed in accordance with Directive 1999/13/EC. 9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Solid - Colour: White / Pink - Odour: Characteristic - Specific gravity: 1,73 g/cc at 20ºC Robercar Mordente 1,77 g/cc at 20ºC Robercar Lucidante 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents, acids. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced. 11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Los pulmones pueden ser afectados por la exposición prolongada o repetida, dando lugar a neumoconiosis (silicosis). May be absorbed by inhalation.


SDS-200/EN Carcinogen effects: This preparation contains the following ingredients which can cause cancer: Gasoil (cat.3). 11.2 Dose and lethal concentrations for individual ingredients:

DL50 Oral DL50 Cutaneous CL50 Inhalation mg/kg mg/kg mg/l.4 hours

Distilates (oil), light hydrotreated 5000 Rat 2000 Rabbit Kerosene (oil), hydrodesulfurized 5000 Rat 5000 Rat For more information about ingredients dangerous to health, see sections 2 and 8. 12. ECOLOGICAL INFORMATION No experimental ecotoxicological data on the preparation as such is available. 12.1 Spills on the soil: Prevent contamination of soil. 12.2 Spills in water: Harmful to aquatic organisms. May cause long-term adverse effects on the aquatic environment. Do not allow to escape into drains, sewers or water courses. 12.3 Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - VOC: 502 g/l Robercar Mordente ASTM D-3960 478 g/l Robercar Lucidante ASTM D-3960 12.4 Ecotoxicological data for individual ingredients: Not available. 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. 13.3 Procedures for neutralising or destroying the product: Authorised landfill in accordance with local regulations. 14. TRANSPORT INFORMATION 14.1 Land: Transport by road: ADR/Transport by rail: RID: Free 14.2 Sea: Transport by ship: IMDG: Free 14.3 Air: Transport by plane: IATA/ICAO: Free 15. INFORMATION ON REGULATIONS 15.1 EC Labelling: Xn This product is HARMFUL in accordance with Guideline 67/548/EEC~2001/59/EC and 1999/45/EC~2001/60/EC. R40 Limited evidence of a carcinogenic effect.


SDS-200/EN R66 Repeated exposure may cause skin dryness or cracking. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S36/37 Wear suitable protective clothing and gloves. Dangerous ingredients: Gasoil. 15.2 Restrictions to the marketing and use in accordance with Directive 76/769/EEC: Not applicable. 15.3 Other regulations: Not available. 16. OTHER INFORMATION Intended use Only for professional use. Text of R-phrases listed in section 2: R40 Limited evidence of a carcinogenic effect. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic

environment. Labelling regulations: The information provided in this Material Safety Data Sheet has been written in accordance with Guideline 67/548/EEC (Substances), 88/379/EEC (Preparations) and 91/155/EEC (Material Safety Data Sheet). It has been updated to Guideline 2001/59/EC (Substances), 2001/60/EC (Preparations) and 2001/58/EC (Material Safety Data Sheet). The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 28.10.05 MULTIEXTENDER – POLYMAX – F250 Page: 1/6

SDS-002/EN 1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: MULTIEXTENDER Code: 51160 POLYMAX Code: 51166 F250 Code: 51164 1.2 Use of the preparation: Bodywork repair unsaturated polyester paste. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) *2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health and/or environment hazard, and/or with a Communitary workplace exposure limit: 10-25 % Styrene EC: 202-851-5 R10 Xn; R20 Xi; R36/38 CAS: 100-42-5 No. 601-026-00-0 For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Flammable. Harmful by inhalation. Irritating to eyes. Irritating to skin. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. 4.3 By contact with eyes: Remove contact lenses. Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: Extinguishing powder or CO2. In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use for extinguishing: direct water jet.


SDS-002/EN 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sews, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Avoid use of solvents. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. *7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed. - Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. - Flash point: 32ºC Setaflash - Autoignition temperature: 490ºC - Flammability range: 1,1 – 6,7 % Volume 25ºC - Recommendations for the prevention of toxicological risks: Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Class B1. According to. ITC MIE APQ-1, RD 379/2001. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 32ºC. - Combustion heat: 3504 Kcal/kg Multiextender 2863 Kcal/kg Polymax 2871 Kcal/kg F250 - Incompatible materials: Keep away from oxidizing agents, from strongly alkaline and strongly acid materials.


SDS-002/EN - Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions. - Type of packaging: According to current legislation. *8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC 8.1 Occupational Exposure Limits: INSHT 2005: Spain VLA-ED-

ppm: VLA-ED-mg/m3:

VLA-EC -ppm:


100-42-5 20 86 40 172 VLB, ae INRS ND 2098, 02/2005:



100-42-5 50 215 - - - 84 DFG 2004:


100-42-5 20 86 DFG, Y ACGIH 2004:


STEL-ppm:

STEL-mg/m3: Note:

100-42-5 20 85 40 170 A4 2000/39/EC and 98/24/EC:


mg/m3: Notes:



SDS-002/EN *9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Paste - Colour: White (Multiextender, F250)/ Cream (Polymax) - Odour: Characteristic - Viscosity: 7,25 x 106cps 20ºC (Multiextender) Brookfield 5 x 106 cps 20ºC (Polymax) Brookfield 7,5 x 106 cps 20ºC (F250) Brookfield - Specific gravity: 1,30 g/cc a 20ºC (Multiextender) 1,90 g/cc a 20ºC (Polymax) 1,95 g/cc a 20ºC (F250) - Solubility in water (styrene): 310 mg/l - Boiling point: 77,1ºC at 760 mmHg (Multiextender, F250) 145,2ºC at 760 mmHg (Polymax) - Flash point: 32ºC Setaflash - Vapour pressure: 11 mmHg at 20ºC (Multiextender) 4,5 mmHg at 20ºC (Polymax) 10,4 mmHg at 20ºC (F250) 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents, acids, alkalis, peroxides. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced. 11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. 11.2 Dose and lethal concentrations for individual ingredients:


Styrene 2650 Rat 12 Rat For more information about ingredients dangerous to health, see sections 2 and 8. *12. ECOLOGICAL INFORMATION No experimental ecotoxicological data on the preparation as such is available. 12.1 Spills on the soil: Prevent contamination of soil.


SDS-002/EN 12.2 Spills in water: Do not allow to escape into drains, sewers or water courses. 12.3 Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - Mixing application VOC: 25 g/l (Multiextender) ASTM D-3960 26 g/l (Polymax) ASTM D-3960 39 g/l (F250) ASTM D-3960 - Aliphatic hydrocarbons: 0,2 % Weight (Multiextender) 0,1 % Weight (F250) - Aromatic hydrocarbons: 16,5 % Weight (Multiextender) 13,3 % Weight (Polymax) 13,8 % Weight (F250) 12.4 Ecotoxicological data for individual ingredients: CL50 CE50 CI50

mg/l.96hours mg/l.48hours mg/l.72hours Styrene 255 Dafnia *13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste, Directive 75/442/EEC~91/156/EC: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers, Directive 94/62/EC: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. *14. TRANSPORT INFORMATION 14.1 Transport by road, Directive 94/55/EC (ADR 2005): Free Transport by rail, Directive 96/49/EC (RID 2005): Free 14.2 Transport by sea (IMDG 32-04): Free 14.3 Transport by air (ICAO/IATA): Free *15. INFORMATION ON REGULATIONS 15.1 EC Labelling Xn This product is FLAMMABLE and HARMFUL in accordance with Guideline 67/548/EEC - 2004/73/EC and 1999/45/EC - 2001/60/EC. R10 Flammable. R20 Harmful by inhalation. R36/38 Irritating to eyes and skin. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S51 Use only in well-ventilated areas. Dangerous ingredients: Styrene · It is applicable the Directive 2004/42/EC, Annex I.2): Emission subcategory B). VOC (product ready for use): 25 g/l (Multiextender), 26 g/l (Polymax), 39 g/l (F250), VOC max: 250 g/l starting from 01.01.2007


SDS-002/EN 15.2 Restrictions to the marketing and use in accordance with Directive 76/769/EEC: Not applicable. 15.3 Other regulations: Not available. *16. OTHER INFORMATION Intended use: Only for professional use. Text of R-phrases listed in section 2: R10 Flammable. R20 Harmful by inhalation. R36/38 Irritating to eyes and skin. Material Safety Data Sheet regulations: Material Safety Data Sheet in accordance with Directive 91/155/EEC~2001/58/EC. The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 06.03.03 MULTYFILLER PLUS Page: 1/7

SDS-313/EN *1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: MULTYFILLER PLUS Z1 Code: 51183 MULTYFILLER PLUS Z4 Code: 51184 1.2 Use of the preparation: Bodywork repair filler. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) 2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 10-25% Xylene R10 R38 R20/21 Xn CAS: 1330-20-7


10-25% n-butyl acetate R10 R66 R67 CAS: 123-86-4 EC No. 204-658-1 SAX: BPU750 No. 607-025-00-1

2,5-10% 1-methoxypropyl acetate R10 R36 Xi CAS: 108-65-6 EC No. 203-603-9 No. 607-195-00-7 <2,5 % Naphtha solvent (oil), light aromatic

R10 R65 R66 R67 R51/53 Xn N CAS: 64742-95-6 EC No. 265-199-0

No. 649-356-00-4 (Note P) <2,5 % Ethylbenzene R11 R20 F Xn CAS: 100-41-4

EC No. 202-849-4 SAX: EGP500 No. 601-023-00-4

For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Flammable. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives.


SDS-313/EN 4.2 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.3 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: Extinguishing powder or CO2. In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sewages, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Clean preferably with a detergent. Avoid use of solvents. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed. - Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off.


SDS-313/EN - Recommendations for the prevention of toxicological risks: Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. Keep away from living quarters. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Class B1. According to ITC MIE APQ-1, RD.379/2001. Maximum storage period: 12 months. Temperature interval: min: 5 ºC, max: 35ºC. 7.3 Incompatible materials: Keep away from oxidizing agents from strongly alkaline and strongly acid materials. 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/CE 8.1 Occupational Exposure Limits (TLV) AGCIH 2001


Xylene (mixture of isomers) 100 434 150 651 A4 1996 n-butyl acetate 150 713 200 950 1998 Naphtha solvent (oil), 50 260 Internal value light aromatic Ethylbenzene 100 434 125 543 1976 A4 - Non classified as carcinogenic in humans. 8.2 Engineering measures: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particles and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. - Vapour density: 3.88 Air = 1 at 20ºC Relative - Lower explosive limit: 1.3 % Volume MULTYFILLER PLUS Z1 1.4 % Volume MULTYFILLER PLUS Z4 - Ventilation requirement: 23 m3/l Air/Preparation MULTYFILLER PLUS Z1 22 m3/l Air/ Preparation MULTYFILLER PLUS Z4 to keep below 1/10 of the Lower Explosive Limit. - Ventilation requirement: 419 m3/l (maximum) Air/Preparation MULTYFILLER PLUS Z1 410 m3/l (maximum) Air/Preparation MULTYFILLER PLUS Z4 to keep below the Occupational Exposure Limit of the product. 8.3 Protection of respiratory system: Avoid the inhalation of vapours. Mask: Filter mask. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles designed to protect against liquid splashes. Face shield: No. 8.5 Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Personnel should wear antistatic clothing made of natural fibre or of high temperature resistant synthetic fibre. *9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Viscous liquid - Colour: Light grey/Dark grey


SDS-313/EN - Odour: Characteristic - Viscosity: 50.000 cps 20ºC Brookfield - Specific gravity: 1.49 g/cc at 20ºC MULTYFILLER PLUS Z1 1.43 g/cc at 20ºC MULTYFILLER PLUS Z4 - Boiling point: 126ºC at 760 mmHg - Flash point: 27ºC Setaflash - Autoignition temperature: 401ºC - Decomposition temperature: 350ºC - Vapour pressure: 7 mmHg at 20ºC 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents, acids, alkalis, peroxides. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced. 11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. g 11.2 Dose and lethal concentrations for individual ingredients:


Xylene (mixture of isomers) 4300 Rat 1700 Rabbit 22 Rat n-butyl acetate 13100Rat 5000 Rabbit 9.7 Rat 1-methoxypropyl acetate 8532 Rat Naphtha solvent (oil), 3900 Rat 3160 Rabbit 14 Rat light aromatic Ethylbenzene 3500 Rat 17800Rabbit For more information about ingredients dangerous to health, see sections 2 and 8. 12. ECOLOGICAL INFORMATION Prevent contamination of soil. Do not allow to escape into drains, sewers or water courses. Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - VOC: 390 g/l ASTM D-3960 MULTYFILLER PLUS Z1 398 g/l ASTM D-3960 MULTYFILLER PLUS Z4


SDS-313/EN - Aromatic hydrocarbons: 16% Weight 12.1 Ecotoxicity: No experimental ecotoxicological data on the preparation as such is available. Ecotoxicological data for individual ingredients: CL50 CE50 CI50

mg/l.96hours mg/l.48hours mg/l.72hours Xylene (mixture of isomers) 75 Fishes 16 Daphnia n-butyl acetate 18 Fishes 10 Daphnia 21 Algae Naphtha solvent (oil), 9.2 Fishes 6.1Daphnia light aromaticg Ethylbenzene 12 Fishes 33 Algae 12.2 Mobility : N/A 12.3 Persistence and degradability: In water : t ½ life = 29 - 144 hours (Xylene) In air: t ½ life = 1 - 18 hours (Xylene) 12.4 Bioaccumulative potential : log Pow = 1.82 (n-butyl acetate) log Pow = 3.12 - 3.20 (Xylene) BCF = 14 (n-butyl acetate) N/A: Not available. 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. *14. TRANSPORT INFORMATION PAINTS (FP>23ºC, viscous according to 2.2.3.1.5) 14.1 Land: Transport by road: ADR-2001

Transport by rail: RID/TPF Good not submitted to Class 3.¹




Class: 3 UN nº1263 Marine pollutant: no Packaging group: III Emergency Sheet (EmS): 3-05, 07 First Aid Guide (MFAG): 310, 313 Transport document: Shipping Bill of Lading




15. INFORMATION ON REGULATIONS 15.1 EC Labelling: This product is flammable in accordance with 67/548/EEC - 2001/59/EC and 1999/45/EC - 2001/60/EC directives. R10 Flammable. S23 Do not breathe vapour, spray. S24/25 Avoid contact with skin and eyes. S51 Use only in well-ventilated areas Dangerous ingredients: None in a percentage equal to or higher than the limit for the name. 15.2 Type of packaging: According to current legislation. 16. OTHER INFORMATION Intended use Only for professional use. Text of R-phrases listed in section 2: R10 Flammable. R11 Highly flammable. R20 Harmful by inhalation. R36 Irritating to eyes. R38 Irritating to skin. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. R20/21 Harmful by inhalation and in contact with skin. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic

environment. Note P : It is unnecessary to apply the classification as carcinogenic if it can be proved that the substance contains less than 0.1% benzene (EC No. 200-753-7) in weight. Labelling regulations: The information provided in this Material Safety Data Sheet has been written in accordance wit 67/548/EEC (Substances), 88/379/EEC (Preparations) and 91/155/EEC (Material Safety Data Sheet) directives. It has been updated to 2001/59/EC (Substances), 2001/60/EC (Preparations) and 2001/58/EC (Material Safety Data Sheet) directives. The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our


SDS-313/EN knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 21.01.04 990 F Page: 1/5

SDS-206/EN 1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: 990 F Code: 51461 1.2 Use of the preparation: Polisher for paint. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) 2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit. 25-50 % Distilates (oil), light hydrotreated R65 R66 Xn EC No. 265-149-8 CAS: 64742-47-8 No. 649-422-00-2 < 2,5 % 2-diethylaminoethanol R10 R34 R20/21/22 C EC No. 202-845-2 CAS: 100-37-8 SAX: DHO500 No. 603-048-00-6 For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Flammable. Repeated exposure may cause skin dryness or cracking. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.3 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and a solution of 5% sodium bicarbonate. Finally, rewash the affected area with soap and water. Do not use solvents or thinners. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Due to its acid condition, the effects can be reduced to a minimumm by drinking plenty of water, to which milk of magnesia has been added. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest.


SDS-206/EN 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: Extinguishing powder or CO2. In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide, nitrogen oxides. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sews, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Transfer to a suitable container for recovery or elimination. Neutralize with carbonate or sodium bicarbonate. Finally, clean up the area with plenty of water. Avoid use of solvents. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed. Recommendations for the prevention of toxicological risks: Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Class B2. According to ITC MIE APQ-1, RD.379/2001. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 35ºC. 7.3 Incompatible materials: Keep away from oxidizing agents, from strongly alkaline and strongly acid materials. 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. 7.5 Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not


SDS-206/EN smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC 8.1 Occupational Exposure Limits (TLV) AGCIH 2001


Distilates (oil), light hydrotreated 100 525 Internal value 2-diethylaminoethanol 2.0 9.6 Dermal 1994 8.2 Engineering measures: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particles and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. 8.3 Protection of respiratory system: Avoid the inhalation of vapours. Mask: Filter mask. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Suitable safety goggles. Face shield: No. 8.5 Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Advisable. Wash contaminated work clothes before wearing them again. *9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Paste - Colour: White - Odour: Characteristic - Viscosity: 87500 cps 20ºC Brookfield - Specific gravity: 1.25 g/cc at 20ºC - Decomposition temperature: 80ºC - Flash point: 54ºC - Autoignition temperature: 254ºC - Vapour pressure: 15.3 mmHg at 20ºC 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents, acids. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced. 11. TOXICOLOGICAL INFORMATION 11.1 Toxicological effects:


SDS-206/EN · Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. 11.2 Dose and lethal concentrations for individual ingredients:


Distilates (oil), light hydrotreated 5000 Rat 2000 Rabbit 2-diethylaminoethanol 1300 Rat 1260 Rabbit For more information about ingredients dangerous to health, see sections 2 and 8. *12. ECOLOGICAL INFORMATION Prevent contamination of soil. Because of its acidity, it is harmful to aquatic organisms. Do not allow to escape into drains, sewers or water courses. Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - VOC: 394 g/l ASTM D-3960 - Aliphatic hydrocarbons: 31.5 % Weight 12.1 Ecotoxicity: No experimental ecotoxicological data on the preparation as such is available. Ecotoxicological data for individual ingredients: N/A: Not available. 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. 14. TRANSPORT INFORMATION 14.1 Land: Transport by road: ADR-2003/Transport by rail: RID: Free 14.2 Sea: Transport by ship: IMDG 30-00: Free 14.3 Air: Transport by plane: IATA/ICAO: Free


SDS-206/EN 15. INFORMATION ON REGULATIONS 15.1 EC Labelling: This product is FLAMMABLE in accordance with Guideline 67/548/EEC~2001/59/EC and 1999/45/EC~2001/60/EC. R10 Flammable. R66 Repeated exposure may cause skin dryness or cracking. S24/25 Avoid contact with skin and eyes. S51 Use only in well-ventilated areas. P101 Safety data sheet available for professional user on request. Dangerous ingredients: None in a percentage equal to or higher than the limit for the name. 15.2 Type of packaging: According to current legislation. 16. OTHER INFORMATION Intended use Only for professional use. Text of R-phrases listed in section 2: R10 Flammable. R34 Causes burns. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R20/21/22 Harmful by inhalation, in contact with skin and if swallowed. Labelling regulations: The information provided in this Material Safety Data Sheet has been written in accordance with 67/548/EEC (Substances), 88/379/EEC (Preparations) and 91/155/EEC (Material Safety Data Sheet) directives. It has been updated to 2001/59/EC (Substances), 2001/60/EC (Preparations) and 2001/58/EC (Material Safety Data Sheet) directives. The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 21.01.04 992 S Page: 1/5

SDS-205/EN 1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: 992 S Code: 51447 1.2 Use of the preparation: Polisher for paint. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) 2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit. 25-50 % Naphtha (oil), heavy hydrotreated R10 R65 R66 R67 Xn EC No. 265-150-3 CAS: 64742-48-9 No. 649-327-00-6 (Note P) < 2,5 % 2-diethylaminoethanol R10 R34 R20/21/22 C EC No. 202-845-2 CAS: 100-37-8 SAX: DHO500 No. 603-048-00-6 < 0,5 % Octane R11 R38 R65 R67 R50/53 F Xn N EC No. 203-892-1 CAS: 111-65-9 SAX: OCU000 No. 601-009-00-8 For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and dizziness. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.3 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and a solution of 5% sodium bicarbonate. Finally, rewash the affected area with soap and water. Do not use solvents or thinners. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: Extinguishing powder or CO2. In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use for extinguishing: direct water jet.


SDS-205/EN 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide, nitrogen oxides, formaldehyde. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sews, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with absorbent materials (sawdust, earth, sand, vermiculite, diatomaceous earth, etc..). Transfer to a suitable container for recovery or elimination. Neutralize with carbonate or sodium bicarbonate. Finally, clean up the area with plenty of water. Avoid use of solvents. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed. Recommendations for the prevention of toxicological risks: Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: According to current legislation. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 35ºC. 7.3 Incompatible materials: Keep away from oxidizing agents, from strongly alkaline and strongly acid materials. 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC 8.1 Occupational Exposure Limits (TLV) TWA STEL Year AGCIH 2001 ppm mg/m3 ppm mg/m3 Naphtha (oil), heavy hydrotreated 100 525 Internal value 2-diethylaminoethanol 2.0 9.6 Dermal 1994 Octane 300 1400 1999


SDS-205/EN 8.2 Engineering measures: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particles and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. 8.3 Protection of respiratory system: Avoid the inhalation of vapours. Mask: Filter mask. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Suitable safety goggles. Face shield: No. 8.5 Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Advisable. *9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Paste - Colour: White - Viscosity: 15000 cps 20ºC Brookfield - Specific gravity: 0.90 g/cc at 20ºC - Decomposition temperature: 80ºC - Flash point: -- - Vapour pressure: 16.3 mmHg at 20ºC *10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents, acids. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced: formaldehyde. 11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: · May irritate the eyes and skin. 11.2 Dose and lethal concentrations for individual ingredients:


Naphtha (oil), 15000 Rat 3000 Rabbit heavy hydrotreated 2-diethylaminoethanol 1300 Rat 1260 Rabbit For more information about ingredients dangerous to health, see sections 2 and 8.


SDS-205/EN *12. ECOLOGICAL INFORMATION Prevent contamination of soil. Harmful to aquatic organisms. May cause long-term adverse effects on the aquatic environment. Do not allow to escape into drains, sewers or water courses. Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - VOC: 335 g/l ASTM D-3960 - Aliphatic hydrocarbons: 37.1 % Weight 12.1 Ecotoxicity: No experimental ecotoxicological data on the preparation as such is available. Ecotoxicological data for individual ingredients:

CL50 CE50 CI50 mg/l.96 hours mg/l.48hours mg/l.72 hours

2-diethylaminoethanol 73 Fishes 44 Daphnia 12.2 Mobility : N/A 12.3 Persistence and degradability : N/A 12.4 Bioaccumulative potential : N/A N/A: Not available. *13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorized waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. 13.3 Procedures for neutralizing or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. 14. TRANSPORT INFORMATION 14.1 Land: Transport by road: ADR-2003/Transport by rail: RID: Free 14.2 Sea: Transport by ship: IMDG 30-00: Free 14.3 Air: Transport by plane: IATA/ICAO: Free 15. INFORMATION ON REGULATIONS 15.1 EC Labelling This product does not require pictograms in accordance with Guideline 67/548/EEC - 2001/59/EC and 1999/45/EC - 2001/60/EC. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. S23 Do not breathe vapour, spray.


SDS-205/EN S24/25 Avoid contact with skin and eyes. S51 Use only in well-ventilated areas. P101 Safety data sheet available for professional user on request. - Dangerous ingredients: None in a percentage equal to or higher than the limit for the name. 15.2 Type of packaging: According to current legislation. 16. OTHER INFORMATION Intended use Only for professional use. Text of R-phrases listed in section 2: R10 Flammable. R11 Highly flammable. R34 Causes burns. R38 Irritating to skin. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. R20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Note P : It is unnecessary to apply the classification as carcinogenic if it can be prooved that the substance contains less than 0.1% bencene (EC No. 200-753-7) in weight. Labelling regulations: The information provided in this Material Safety Data Sheet has been written in accordance with 67/548/EEC (Substances), 88/379/EEC (Preparations) and 91/155/EEC (Material Safety Data Sheet) directives. It has been updated to 2001/59/EC (Substances), 2001/60/EC (Preparations) and 2001/58/EC (Material Safety Data Sheet) directives. The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 10.05.06 POLYFIXER PS - POLYFIXER VS Page: 1/7

SDS-108/EN 1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: POLYFIXER PS Code: 51444 POLYFIXER VS Code: 51569 HARDENER POLYFIXER Code: 51545 1.2 Use of the preparation: Chemical anchoring for the building industry. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) 2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health and/or environment hazard, and/or with a Communitarian workplace exposure limit: 10-25 % Styrene R10 | Xn:R20 | Xi:R36/38 EC 202-851-5 Index No. 601-026-00-0 CAS 100-42-5 < 2,5 % Dibenzoyl peroxide E:R2 | Xi:R36 | R43 EC No. 202-327-6

Index No. 617-008-00-0 CAS: 94-36-0 For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Flammable. Harmful by inhalation. Irritating to eyes. Irritating to skin. May cause sensitization by skin contact. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Apply lanolin ointment. In the event of cutaneous eruptions contact a doctor. In the case of skin reddening or rashes, contact a doctor immediately. 4.3 By contact with eyes: Remove contact lenses. Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. If possible, alternate the rinsing with a 5% solution of sodium ascorbate in water or a 2% solution of sodium bicarbonate in water. Both solutions should not to be more than 4 weeks old. Do not apply oils. Call a physician immediately.


SDS-108/EN 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. If there has been any contact with the mouth, rinse out with large quantities of water only. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: Extinguishing powder or CO2. In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use for extinguishing: halon. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sews, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Do not use rags. The peroxide impregnated absorbent must be placed in a safe place and not put into a container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Do not weigh it in the storage area. Avoid friction, rough handling or strong impacts. Avoid any type of leakage or escape. Keep the container tightly closed. Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. - Flash point: 33ºC Setaflash - Autoignition temperature: 80ºC - Flammability range: 1,1 – 6,3 % Volume 25ºC Polyfixer PS 1,1 – 6,5 % Volume 25ºC Polyfixer VS


SDS-108/EN Recommendations for the prevention of toxicological risks: Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Xn. According to ITC MIE APQ-7, RD 379/2001. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 32ºC. - Incompatible materials: Keep away from reducing agents, oxidizing agents, acids, alkalis, amines, metals, heavy-metal compounds, peroxides, polimerization initiators. - Conditions to avoid: Heat: This preparation is quite stable at normal temperatures (around 20ºC). However, at higher temperatures an exo-thermic decomposing reaction takes place. In the event of the decomposition taking place so fast that the heat only partially dissipates, an increased acceleration of the product's temperature occurs, finally giving rise to an auto-accelerated breaking down of the organic peroxide. Depending on the circumstances, eg. the amount, the degree of containment, etc.., intense decomposition, auto-ignition or even an explosion may take place. Light: Avoid direct contact with sunlight as this could cause a rise in temperature, with the subsequent danger of the peroxide decomposing. Humidity: Avoid extreme humidity conditions. - Type of packaging: According to current legislation. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC 8.1 Occupational Exposure Limits (TLV) AGCIH 2004

TWA STEL Year ppm mg/m3 ppm mg/m3 Styrene 20 85 40 170 A4 1997 Dibenzoyl peroxide 5,0 A4 1996 A4 - Non classified as carcinogenic in humans. 8.2 Occupational exposure controls, Directive 89/686/EEC: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particulates and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. - Protection of respiratory system: Avoid the inhalation of vapours. Mask: Mask for gases and vapours (EN141). In order to obtain a suitable protection level, the filter class must be selected depending on the type and concentration of the contaminating agents present, in accordance with the specifications supplied by the filter producers. The respiratory equipment with filters does not work satisfactorily when the air contains high concentrations of vapour. - Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles with suitable lateral protection (EN166). Face shield: Recommendable when there is a risk of spillage, diffusion or atomization of the liquid. - Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Gloves resistant against chemicals (EN374). The breakthrough time of the selected glove material should be superior to the pretended period of use. The gloves should be immediately replaced when any sign of degradation is noted. Boots: No. Apron: No. Clothing: It is advisable personnel wear antistatic clothing made of natural fibre or of high temperature resistant synthetic fibre. Put away work clothes under control and separately from the rest. Do not take contaminated clothing home. Wash contaminated work clothes before wearing them again.


SDS-108/EN 8.3 Environmental exposure controls: Avoid any spillage in the environment. Avoid any release into the atmosphere. *9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Paste - Colour: Beige (Polyfixer PS) / Grey (Polyfixer VS) / Black (Comp. B) - Odour: Characteristic - Viscosity: 6 x 106 cps 20ºC Brookfield (Polyfixer PS) 2,5 x106 cps 20ºC Brookfield (Polyfixer VS) - Specific gravity: 1,62 g/cc at 20ºC (Comp. A) / 1,6 g/cc at 20ºC (Comp. B) - Solubility in water (styrene): 310 mg/l - Flash point: 33ºC - Decomposition temperature: 103ºC - Vapour pressure: 4,1 mmHg at 20ºC 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with reducing agents, oxidizing agents, acids, alkalis, amines, metals, heavy-metal compounds. Special care must be taken under all circumstances that there is no direct contact with accelerators, given that a violent decomposition could take place or even an explosion. 10.3 Thermal decomposition: As a consequence of thermal decomposition, hazardous decomposition products may be produced: oxygen. The vapours given off on decomposing are inflammable, therefore any source of ignition could cause a fire. 11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. Some organic peroxides will cause serious, irreversible ocular injuries to the cornea, even after brief contact. 11.2 Dose and lethal concentrations for individual ingredients:


Styrene 2650 Rat 12 Rat Dibenzoyl peroxide 7710 Rat For more information about ingredients dangerous to health, see sections 2 and 8.


SDS-108/EN 12. ECOLOGICAL INFORMATION No experimental ecotoxicological data on the preparation as such is available. 12.1 Spills on the soil: Prevent contamination of soil. 12.2 Spills in water: Do not allow to escape into drains, sewers or water courses. 12.3 Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - Mixing application VOC: 42 g/l (Polyfixer PS) ASTM D-3960 86 g/l (Polyfixer VS) - Aromatic hydrocarbons: 16,9 % Weight (Polyfixer PS) 17,4 % Weight (Polyfixer VS) 12.4 Ecotoxicological data for individual ingredients: CL50 CE50 CI50

mg/l.96hours mg/l.48hours mg/l.72hours Dibenzoyl peroxide 2000 Fishes Styrene 255 Daphnia 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste, Directive 75/442/EEC~91/156/EC: Take all necessary measures to prevent the production of waste whenever possible. Analyze possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorized waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers, Directive 94/62/EC: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. Never re-use a container which has contained peroxides. 13.3 Procedures for neutralizing or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. Before burning dilute with organic solvents. 14. TRANSPORT INFORMATION POLYESTER RESIN KIT 14.1 Transport by road, Directive 94/55/EC (ADR 2005): Transport by rail, Directive 96/49/EC (RID 2005): Class: 3 Packaging group: III UN no. 3269 Transport document: Consignment paper Written instructions. 14.2 Transport by sea (IMDG 32-04): Class: 3 Packaging group: III UN no. 3269 Emergency Sheet (EmS): F-E,S-D First Aid Guide (MFAG): - Marine pollutant: No Transport document: Shipping Bill of lading 14.3 Transport by air (ICAO/IATA): Class: 3 Packaging group: III UN no. 3269 Transport document: Air Bill of lading


SDS-108/EN 15. INFORMATION ON REGULATIONS 15.1 EC Labelling: Comp. A: Xn This product is FLAMMABLE and HARMFUL in accordance with Guideline 67/548/EEC - 2004/73/EC and 1999/45/EC - 2001/60/EC. R10 Flammable. R20 Harmful by inhalation. R36/38 Irritating to eyes and skin. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S51 Use only in well-ventilated areas. Dangerous ingredients: Styrene. Comp. B: O, Xi This product is OXIDIZING and IRRITANT in accordance with Guideline 67/548/EEC - 2004/73/EC and 1999/45/EC - 2001/60/EC. R7 May cause fire. R36 Irritating to eyes. R43 May cause sensitization by skin contact. S3/7 Keep container tightly closed in a cool place. S14 Keep away from reducing agents, oxidizing agents, acids, alkalis, amines, metals, heavy-metal compounds. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 Wear suitable protective clothing, gloves and protection for eyes, face. S50 Do not mix with accelerators or reducing agents. Dangerous ingredients: Dibenzoyl peroxide. 15.2 Restrictions to the marketing and use in accordance with Directive 76/769/EEC: Not applicable. 15.3 Other regulations: Not available. 16. OTHER INFORMATION Intended use: Only for professional use. Text of R-phrases listed in section 2: R2 Risk of explosion by shock, friction, fire or other sources of ignition. R10 Flammable. R20 Harmful by inhalation. R36 Irritating to eyes. R43 May cause sensitization by skin contact. R36/38 Irritating to eyes and skin. Material Safety Data Sheet regulations: Material Safety Data Sheet in accordance with Directive 91/155/EEC~2001/58/EC. The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified,

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 03.03.03 PRIMERPLAST Page: 1/6

SDS-314/EN *1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: PRIMERPLAST Code: 51201 1.2 Use of the preparation: Adherent primer for plastics paint. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) 2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 60-90 % Toluene R11 R20 F Xn CAS: 108-88-3

EC No. 203-625-9 SAX: TGK750 No. 601-021-00-3

10-25 % Xylene R10 R38 R20/21 Xn CAS: 1330-20-7 (mixture of isomers) EC No. 215-535-7

SAX: XGS000 No. 601-022-00-9

<0,5 % Chlorobenzene R10 R20 R51/53 Xn N CAS: 108-90-7 EC No. 203-628-5

SAX: CEJ125 No. 602-033-00-1 For more information on dangerous ingredients, see sections 8, 11, 12 and 16. *3. IDENTIFICATION OF HAZARDS Highly flammable. Harmful by inhalation. Harmful in contact with skin. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.3 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest.


SDS-314/EN *5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: In case of fire, use water spray/mist, alcohol-resistant foam, dry chemical powder, carbonic anhydride. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide, halogenated compounds, hydrochloric acid. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sewages, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Clean preferably with a detergent. Avoid use of solvents. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. *7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed. Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. Recommendations for the prevention of toxicological risks: Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Class B1. According to MIE APQ-1, RD.379/2001. Maximum storage period: 12 months. Temperature interval: min:5ºC, max: 35ºC. 7.3 Incompatible materials: Keep away from oxidizing agents, acids, metals.


SDS-314/EN 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions. *8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/CE 8.1 Occupational Exposure Limits (TLV) AGCIH 2001


Toluene 50 188 A4 Dermal 1996 Xylene 100 434 150 651 A4 1996 (mixture of isomers) Chlorobenzene 10 46 A3 1996 A3 - Carcinogenic in animals. A4 - Non classified as carcinogenic in humans. 8.2 Engineering measures: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particles and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. Vapour density: 3.2 Air=1 at 20ºC Relative Lower explosive limit: 1.3 % Volume Ventilation requirement: 160 m3/l Air/Preparation to keep below 1/10 of the Lower Explosive Limit. Ventilation requirement: 3766 m3/l (maximum) Air/Preparation to keep below the Occupational Exposure Limit of the product (application by pulverization and assuming a transfer efficiency of 80%). Special ventilation is required. 8.3 Protection of respiratory system: Avoid the inhalation of vapours. When operators, whether spraying or not, are inside the spraybooth, and ventilation is unlikely to be sufficient to constantly control particles and solvent vapour in all cases, in such circumstances they should wear a compressed air-fed respirator during the spraying process and until such a time as the particles and solvent vapour concentration has fallen below the exposure limits. Mask: Filter mask. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles designed to protect against liquid splashes. Face shield: No. 8.5 Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Personnel should wear antistatic clothing made of natural fibre or of high temperature resistant synthetic fibre. *9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Liquid - Colour: Colourless - Odour: Characteristic - Viscosity: 10.5 sec CF4 at 20ºC - Specific gravity: 0.88 g/cc at 20ºC - Water solubility: Not miscible - Flash point: 7.7ºC Setaflash


SDS-314/EN - Autoignition temperature: 522.9ºC - Decomposition temperature:>100ºC - Vapour pressure: 20.2 mmHg at 20ºC 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents, acids, metals. 10.3Thermal decomposition: As consequence of thermal decomposition, hazardous decomposition products may be produced: hydrochloric acid. 11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. 11.2 Dose and lethal concentrations for individual ingredients:


Toluene 5000 Rat 12124 Rabbit 15 Rat Xylene 4300 Rat 1700 Rabbit 22 Rat (mixture of isomers) Chlorobenzene 2290 Rat For more information about ingredients dangerous to health, see sections 2 and 8. *12. ECOLOGICAL INFORMATION Prevent contamination of soil. Do not allow to escape into drains, sewers or water courses. Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - VOC: 843 g/l ASTM D-3960 - Aromatic hydrocarbons: 95% Weight - Halogenated hydrocarbons: 0.2% Weight 12.1 Ecotoxicity: No experimental ecotoxicological data on the preparation as such is available. Ecotoxicological data for individual ingredients:


Toluene 24 Fishes 12 Daphnia 400 Algae Xylene (mixture of isomers) 75 Fishes 16 Daphnia


SDS-314/EN 12.2 Mobility : N/A 12.3 Persistence and degradability: In water : t ½ life = 2.9 - 5.7 hours (Toluene) t ½ life = 29 - 144 hours (Xylene) In air: t ½ life = 3 hours - 1 day (Toluene) t ½ life = 1 - 18 hours (Xylene) 12.4 Bioaccumulative potential : log Pow = 2 .6 (Toluene) log Pow = 3.12 - 3.20 (Xylene) N/A: Not available 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. Contains halogenated compounds: In the case of incineration, take all necessary measures in order to avoid production and emission of furanes and dioxines into the atmosphere above the legal limits allowed. *14. TRANSPORT INFORMATION PAINTS (VP<110 kPa50ºC) 14.1 Land: Transport by road: ADR 2001 Transport by rail: RID/TPF Class: 3 Packaging group: II UN no. 1263 Transport document: Consignment paper Written instructions. 14.2 Sea: Transport by ship: IMDG 30-00 Class: 3 Packaging group: II UN no. 1263 Emergency Sheet (EmS): 3-05,07 First Aid Guide (MFAG): 310,313 Marine pollutant: No Transport document: Shipping Bill of lading 14.3 Air: Transport by plane: IATA/ICAO Class: 3 Packaging group: II UN no. 1263 Transport document: Air Bill of lading *15. INFORMATION ON REGULATIONS 15.1 EC Labelling F, Xn


SDS-314/EN This product is highly flammable and harmful in accordance with 67/548/EEC - 2001/59/EC and 1999/45/EC - 2001/60/EC directives. R20/21 Harmful by inhalation and in contact with skin. S16 Keep away from sources of ignition – No smoking. S23 Do not breathe vapour/spray. S36/37 Wear suitable protective clothing and gloves. S38 In case of insufficient ventilation, wear suitable respiratory equipment. Dangerous ingredients: Toluene Xylene (mixture of isomers) 15.2 Type of packaging: According to current legislation. *16. OTHER INFORMATION Intended use Only for professional use. Text of R-phrases listed in section 2: R10 Flammable. R11 Highly flammable. R20 Harmful by inhalation. R38 Irritating to skin. R20/21 Harmful by inhalation and in contact with skin. R51/53 Toxic to aquatic organisms, may cause long term adverse effects in the aquatic

environment. Labelling regulations: The information provided in this Material Safety Data Sheet has been written in accordance wit 67/548/EEC (Substances), 88/379/EEC (Preparations) and 91/155/EEC (Material Safety Data Sheet) directives. It has been updated to 2001/59/EC (Substances), 2001/60/EC (Preparations) and 2001/58/EC (Material Safety Data Sheet) directives. The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 18.06.04 RESINPLAST Page: 1/5

SDS-103/EN *1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: RESINPLAST Code: 51174 1.2 Use of the preparation: Bodywork repair unsaturated polyester paste. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) 2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 10-25 % Styrene R10 R20 R36/38 Xn EC No. 202-851-5 CAS: 100-42-5

SAX: SMQ000 No. 601-026-00-0

For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Flammable. Harmful by inhalation. Irritating to eyes. Irritating to skin. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. 4.3 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: Extinguishing powder or CO2. In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon


SDS-103/EN monoxide, carbon dioxide. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. *6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sews, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Avoid use of solvents. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed. Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. Recommendations for the prevention of toxicological risks: Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Class B1. According to. ITC MIE APQ-1, RD 379/2001. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 32ºC. 7.3 Incompatible materials: Keep away from oxidizing agents, from strongly alkaline and strongly acid materials. 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions. *8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC 8.1 Occupational Exposure Limits (TLV) AGCIH 2002


SDS-103/EN


Styrene 20 85 40 170 A4 1997 A4 - Non classified as carcinogenic in humans. 8.2 Engineering measures: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. Vapour density: 3,56 Air=1 at 20ºC Relative Lower explosive limit: 1,5 % Volume 8.3 Protection of respiratory system: Avoid the inhalation of vapours. Mask: Filter mask. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Suitable safety goggles. Face shield: No. 8.5 Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Suitable work clothes which avoid contact with the product should be worn. Wash contaminated work clothes before wearing them again. 9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Paste - Colour: Grey - Odour: Characteristic - Viscosity: 6 x 106 cps 20ºC Brookfield - Specific gravity: 1,75 g/cc a 20ºC - Solubility in water (styrene): 310 mg/l - Boiling point: 145,2ºC at 760 mmHg - Flash point: 32ºC Setaflash - Autoignition temperature: 490ºC - Vapour pressure: 5,8 mmHg at 20ºC 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents, acids, alkalis, peroxides. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced. *11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic


SDS-103/EN contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. 11.2 Dose and lethal concentrations for individual ingredients:


Styrene 2650 Rat 12 Rat For more information about ingredients dangerous to health, see sections 2 and 8. *12. ECOLOGICAL INFORMATION No experimental ecotoxicological data on the preparation as such is available. 12.1 Spills on the soil: Prevent contamination of soil. 12.2 Spills in water: Do not allow to escape into drains, sewers or water courses. 12.3 Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - Mixing application VOC: 37 g/l ASTM D-3960 - Aliphatic hydrocarbons: 0,2 % Weight - Aromatic hydrocarbons: 17,6 % Weight 12.4 Ecotoxicological data for individual ingredients: CL50 CE50 CI50

mg/l.96hours mg/l.48hours mg/l.72hours Styrene 255 Dafnia 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. *14. TRANSPORT INFORMATION 14.1 Land: Transport by road: ADR-2003/Transport by rail: RID: Free 14.2 Sea: Transport by ship: IMDG 30-00: Free 14.3 Air: Transport by plane: IATA/ICAO: Free 15. INFORMATION ON REGULATIONS 15.1 EC Labelling Xn This product is FLAMMABLE and HARMFUL in accordance with Guideline 67/548/EEC - 2001/59/EC and 1999/45/EC - 2001/60/EC. R10 Flammable.


SDS-103/EN R20 Harmful by inhalation. R36/38 Irritating to eyes and skin. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S51 Use only in well-ventilated areas. Dangerous ingredients: Styrene 15.2 Type of packaging: According to current legislation. 16. OTHER INFORMATION Intended use Only for professional use. Text of R-phrases listed in section 2: R10 Flammable. R20 Harmful by inhalation. R36/38 Irritating to eyes and skin. Labelling regulations: The information provided in this Material Safety Data Sheet has been written in accordance with Guideline 67/548/EEC (Substances), 88/379/EEC (Preparations) and 91/155/EEC (Material Safety Data Sheet). It has been updated to Guideline 2001/59/EC (Substances), 2001/60/EC (Preparations) and 2001/58/EC (Material Safety Data Sheet). The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 13.02.06 RPS 45 Page: 1/7

SDS-802/EN 1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: RPS 45 Code: 62378, 62379, 62380 1.2 Use of the preparation: Polyurethane sealer. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) 2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit: 2,5-10 % Xylene (mixture of isomers) R10 R38 R20/21 Xn EC: 215-535-7 CAS: 1330-20-7 SAX: XGS000 No. 601-022-00-9 2,5-10 % Solvent naphtha (petroleum), heavy aromatic R65 R66 R67 R51/53 Xn, N EC: 265-198-5 CAS: 64742-94-5 No. 649-424-00-3 <2,5 % 3-isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate R36/37/38 R42/43 R51/53 R23 T, N EC: 223-861-6 CAS: 4098-71-9 SAX: IMG000 No. 615-008-00-5 <2,5 % Isocyanate R14 R36/37/38 R42 Xn CAS: -- For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS This product is not considered dangerous. in accordance with Directive 67/548/EEC~2004/73/EC and 1999/45/EC~2001/60/EC. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners.


SDS-802/EN 4.3 By contact with eyes: Remove contact lenses. Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: Extinguishing powder or CO2. In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide, nitrogen oxides. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sews, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). The contaminated area should be cleaned up immediately with a suitable decontaminant. One possible (flammable) decontaminant comprises: water/ethanol or isopropanol/concentrated ammonia solution (d=0,880) = 45/50/5 parts by volume. Another possible (non-flammable) decontaminant is made up of water/sodium carbonate = 95/5 parts by weight. Add the same decontaminant to any residues and allow to stand for several days in an un-sealed container until no further reaction occurs. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed. Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used.


SDS-802/EN Flash point: 58ºC Setaflash Recommendations for the prevention of toxicological risks: People with a history of asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which isocyanate containing products are used. Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: According to current legislation. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 32ºC. - Incompatible materials: Keep away from oxidizing agents, acids. - Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Precautions should be taken to minimise exposure to atmospheric humidity or water, as carbon dioxide may be formed which, in closed containers can result in pressurisation. Care should be taken when re-opening partly used containers. Due to the sensitivity to humidity of the isocyanates, this product should be kept in the original container, or under pressure of dried nitrogen, for example. - Type of packaging: According to current legislation. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC People with a history of asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which isocyanate containing products are used. 8.1 Occupational Exposure Limits: INSHT 2005: Spain TWA-ppm: TWA-

mg/m3: STEL-ppm: STEL-mg/m3: Notes:

4098-71-9 0,005 0,046 - - Sen

1330-20-7 50 221 100 442 Dermal, VLB, VLI

INRS ND 2098, 02/2005:


mg/m3 Notes: TMP Nº

4098-71-9 0,01 0,09 0,02 0,18 AR 62 1330-20-7 50 221 100 442 - 4bis, 84 DFG 2004:

Germany Class: MAK-ppm: MAK-mg/m3: Note:

4098-71-9 I, 1 0,01 0,092 Sah 1330-20-7 II,2 100 440 D ACGIH 2004:


STEL-ppm:

STEL-mg/m3: Note: Note:

4098-71-9 0,005 0,045 - - - - 1330-20-7 100 434 150 651 A4 S 2000/39/EC and 98/24/EC:


mg/m3: Notes:

1330-20-7 50 221 100 442 A4


SDS-802/EN 8.2 Occupational exposure controls, Directive 89/686/EEC: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particulates and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. - Protection of respiratory system: Avoid the inhalation of vapours. Mask: For short periods of work, you can consider the utilisation of a combination mask with gas and particle filters, type A2-P2 (EN141/EN143). In order to obtain a suitable protection level, the filter class must be selected depending on the type and concentration of the contaminating agents present, in accordance with the specifications supplied by the filter producers. If the working area is insufficiently ventilated, or when operators, whether spraying or not, are inside the spraybooth, compressed air-fed respiratory protective equipment (EN137) is required. - Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles with suitable lateral protection (EN166). Face shield: No. - Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Recommended gloves: polyethylene, polypropylene textile-lined, polyvinyl alcohol or nitrile rubber. Do not use PVC gloves. Boots: No. Apron: No. Clothing: Advisable. Wash contaminated work clothes before wearing them again. 8.3 Environmental exposure controls: Avoid any spillage in the environment of the product, wastes, packages or spraybooth sewages. Avoid any release into the atmosphere above the legal limits allowed. 9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Paste - Colour: White, black, grey, brown - Specific gravity: 1,2 g/cc at 20ºC - Solubility in water: Not miscible - Flash point: 58ºC Setaflash 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents, acids. Exothermic reaction with amines and alcohols. Reacts with water under evolution of CO2. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced, including isocyanates. 11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic


SDS-802/EN contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. Based on the properties of the isocyanate content of this product and existing technical data of similar preparations, it can be concluded that respiratory exposure may cause acute irritation and/or sensitization of the respiratory system, resulting in asthmatic symptoms, wheezing and a tightness of the chest. Sensitised persons may subsequently show asthmatic symptoms when exposed to airborne concentrations of isocyanates well below the occupational exposure limit. Repeated exposure may lead to permanent respiratory disability. In case of prolonged contact, the skin can dry up and irritation could appear. 11.2 Dose and lethal concentrations for individual ingredients:


Xylene (mixture of isomers) 4300 Rat 1700 Rabbit 22 Rat Solvent naphtha (petroleum), heavy aromatic 9000 Rat 3000 Rabbit 3-isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate 4825 Rat 1060 Rat 0,123 Rat For more information about ingredients dangerous to health, see sections 2 and 8. 12. ECOLOGICAL INFORMATION No experimental ecotoxicological data on the preparation as such is available. 12.1 Spills on the soil: Prevent contamination of soil. 12.2 Spills in water: Do not allow to escape into drains, sewers or water courses. - Hydrolisis: Reacts with water forming carbon dioxide and a solid insoluble product with high melting point (polyurea). This reaction is accelerated by surfactants (e.g. detergents) or by watersoluble solvents. 12.3 Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - VOC: 120 g/l ASTM D-3960 12.4 Ecotoxicological data for individual ingredients: CL50 CE50 CI50

mg/l.96hours mg/l.48hours mg/l.72hours Xylene (mixture of isomers) 75 Fishes 16 Daphnia 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste, Directive 75/442/EEC~91/156/EC: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers, Directive 94/62/EC: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. *14. TRANSPORT INFORMATION ADHESIVES (FP>23ºC, viscous according to 2.2.3.1.5)


SDS-802/EN 14.1 Land: Transport by road: ADR 2005

Transport by rail: RID 2005 Good not submitted to Class 3.¹ ¹ Transport in accordance with 2.2.3.1.5 for viscous liquids in packages with capacity under 450 L 14.2 Sea: Transport by ship: IMDG 32-04

Class: 3 UN nº1133 Marine pollutant: no Packaging group: III Emergency Sheet (EmS): F-E,S-D First Aid Guide (MFAG): 330 Transport document: Shipping Bill of Lading

14.3 Air: Transport by plane: IATA/ICAO Class: 3 UN nº1133 Packaging group: III Transport document: Air Bill of Lading

15. INFORMATION ON REGULATIONS 15.1 EC Labelling: This product does not require pictograms, in accordance with Directive 67/548/EEC~2004/73/EC and 1999/45/EC~2001/60/EC. P91 Contains isocyanates. See information supplied by the manufacturer. P99 Contains 3-isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate and NONE249 Isocyanate. May produce an allergic reaction. Dangerous ingredients: None in a percentage equal to or higher than the limit for the name. 15.2 Restrictions to the marketing and use in accordance with Directive 76/769/EEC: Not applicable. 15.3 Other regulations: Not available. 16. OTHER INFORMATION Intended use: Only for professional use. Text of R-phrases listed in section 2: R10 Flammable. R14 Reacts violently with water. R23 Toxic by inhalation. R38 Irritating to skin. R65 Harmful: may cause lung damage if swallowed. R20/21 Harmful by inhalation and in contact with skin. R36/37/38 Irritating to eyes, respiratory system and skin. R42/43 May cause sensitization by inhalation and skin contact. Indications for preparations containing isocyanates: Ready-to-use preparations containing isocyanates may have an irritant effect on mucous membranes -especially on breathing organs- and cause hypersensitivity reactions. Inhalation of vapour or spray mist may cause sensitisation. When handling preparations containing isocyanates all precautions required for solvent-containing preparations must be followed. Vapour and spray mist in particular should not be inhaled. Allergics and asthmatics, as well as people prone to respiratory ailments should not work with isocyanate-containing preparations. Material Safety Data Sheet regulations: Material Safety Data Sheet in accordance with Directive 91/155/EEC~2001/58/EC.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 04.02.03 SELLADOR 92 Page: 1/6 SDS-801/EN *1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: SELLADOR 92 Code: 51268 1.2 Use of the preparation: Bodywork sealer for joining points. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia)

2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 10-25 % Toluene R11 R20 F Xn CAS: 108-88-3

EC No. 203-625-9 SAX: TGK750 No. 601-021-00-3

10-25 % Ethylmethylketone R11 R36 R66 R67 F Xi CAS: 78-93-3 EC No. 201-159-0 SAX: MKA400 No. 606-002-00-3

<2,5 % Ethyl Englicol R22 Xn CAS: 107-21-1 EC No. 203-473-3 SAX: EJC500 No. 603-027-00-1

For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Highly flammable. Harmful by inhalation. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.3 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. In the case of skin reddening or rashes, contact a doctor immediately. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 04.02.03 SELLADOR 92 Page: 2/6 SDS-801/EN *5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: In case of fire, use water spray, alcohol-resistant foam, dry chemical powder, carbon dioxide, AFFF. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide, halogenated compounds, hydrochloric acid. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sewages, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Avoid use of solvents. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. *7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed. Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. Recommendations for the prevention of toxicological risks: Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. Keep away from living quarters. Keep away from food, drink and animal foodstuffs. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Class B1. According to ITC MIE APQ-1, RD.379/2001. Maximum storage period: 12 months. Temperature interval: min:5ºC, max: 35ºC. 7.3 Incompatible materials: Keep away from oxidizing agents from strongly alkaline and strongly acid materials.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 04.02.03 SELLADOR 92 Page: 3/6 SDS-801/EN 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions. *8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/CE 8.1 Occupational Exposure Limits (TLV) AGCIH 2001 TWA STEL Year

ppm mg/m3 ppm mg/m3 Toluene 50 191 Dermal 1996 Ethylmethylketone 200 600 300 885 1976 Ethyleneglycol 20 52 40 104 Dermal 1995 8.2 Engineering measures: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. - Vapour density: 2.63 Air = 1 at 20ºC Relative - Lower explosive limit: 2.2% Volume 8.3 Protection of respiratory system: Avoid the inhalation of vapours. Mask: Filter mask. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Suitable safety goggles. Face shield: No. 8.5 Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Suitable work clothes which avoid contact with the product should be worn. *9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Paste - Colour: Grey - Odour: Characteristic - Viscosity: 1x106 cps 20ºC Brookfield - Specific gravity: 1.16 g/cc at 20ºC - Boiling point: 79.6ºC at 760 mmHg - Flash point: 1 ºC Setaflash - Autoignition temperature: 512.9ºC - Descomposition temperature: 180ºC - Vapour pressure: 47.5 mmHg at 20ºC 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents, acids, alkalis, metals. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced, such as: hydrochloric acid.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 04.02.03 SELLADOR 92 Page: 4/6 SDS-801/EN *11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. 11.2 Dose and lethal concentrations for individual ingredients:


Toluene 636 Rat 12124 Rabbit 49 Rat Ethylmethylketone 2737 Rat 6480 Rabbit 24 Rat Ethyleneglycol 4700 Rat 9530 Rabbit For more information about ingredients dangerous to health, see sections 2 and 8. *12. ECOLOGICAL INFORMATION Prevent contamination of soil. Do not allow to escape into drains, sewers or water courses. Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - VOC: 452 g/l ASTM D-3960 - Aromatic hydrocarbons: 19.1 % Weight 12.1 Ecotoxicity: No experimental ecotoxicological data on the preparation as such is available. Ecotoxicological data for individual ingredients:

CL50 CE50 CI50 mg/l.96hours mg/l.48hours mg/l.72hours Toluene 24 Fishes 12 Daphnia 400 Algae Ethyleneglycol 18500 Fishes 1000 Daphnia 2000 Algae 12.2 Mobility : N/A 12.3 Persistence and degradability: N/A 12.4 Bioaccumulative potential : N/A N/A: Not available. 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 04.02.03 SELLADOR 92 Page: 5/6 SDS-801/EN 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. Contains halogenated compounds: In the case of incineration, take all necessary measures in order to avoid production and emission of furanes and dioxines into the atmosphere above the legal limits allowed. *14. TRANSPORT INFORMATION PAINTS (FP<23ºC, viscous according to 2.2.3.1.4, VP<110 kPa50ºC) 14.1 Land: Transport by road: ADR 2001 Transport by rail: RID/TPF Class: 3 Packaging group: III UN no. 1263 Transport document: Consignment paper Written instructions. 14.2 Sea: Transport by ship: IMDG 30-00 Class: 3 Packaging group: III UN no. 1263 Emergency Sheet (EmS): 3-05 First Aid Guide (MFAG): 310, 313 Marine pollutant: No Transport document: Shipping Bill of lading 14.3 Air: Transport by plane: IATA/ICAO Class: 3 Packaging group: III UN no. 1263 Transport document: Air Bill of lading

*15. INFORMATION ON REGULATIONS 15.1 EC Labelling F, Xn This product is HIGHLY FLAMMABLE and HARMFUL in accordance with 67/548/EEC - 2001/59/EC and 1999/45/EC - 2001/60/EC directives. R20 Harmful by inhalation. S16 Keep away from sources of ignition- No smoking. S26 In case of contact with eyes, rinse immediately with plenty of water and seek

medical advice. S51 Use only in well-ventilated areas. Dangerous ingredients: Toluene. 15.2 Type of packaging: According to current legislation. *16. OTHER INFORMATION Intended use Only for professional use. Text of R-phrases listed in section 2: R11 Highly flammable.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 04.02.03 SELLADOR 92 Page: 6/6 SDS-801/EN R20 Harmful by inhalation. R22 Harmful if swallowed. R36 Irritating to eyes. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. Labelling regulations: The information provided in this Material Safety Data Sheet has been written in accordance wit 67/548/EEC (Substances), 88/379/EEC (Preparations) and 91/155/EEC (Material Safety Data Sheet) directives. It has been updated to 2001/59/EC (Substances), 2001/60/EC (Preparations) and 2001/58/EC (Material Safety Data Sheet) directives. The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 14.02.06 SILTEX 800 – PROTEX 50 Page: 1/6

SDS-501/EN 1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: SILTEX 800 WHITE Code: 51718 SILTEX 800 GREY 51719 SILTEX 800 BLACK 51720 PROTEX 50 WHITE 51721 PROTEX 50 GREY 51722 PROTEX 50 BLACK 51723 1.2 Use of the preparation: Bodywork protector treatment. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) 2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health and/or environment hazard, and/or with a Communitary workplace exposure limit: 10-25 % Toluene EC 203-625-9 F:R11 | Repr.Cat.3:R63 | Xn:R48/20-65 | Xi:R38 | R67 Index No. 601-021-00-3 CAS 108-88-3 10-25 % (1) Ethyl acetate EC 205-500-4 2,5-10 % (2) F:R11 | Xi:R36 | R66-R67 Index No. 607-022-00-5 CAS 141-78-6 2,5-10 % Ethylmethylketone EC 201-159-0 F:R11 | Xi:R36 | R66-R67 Index No. 606-002-00-3 CAS 78-93-3 1. Siltex 800 2. Protex 50 For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Highly flammable. Possible risk of harm to the unborn child. Danger of serious damage to health by prolonged exposure. Irritating to skin. Vapours may cause drowsiness and dizziness. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners.


SDS-501/EN 4.3 By contact with eyes: Remove contact lenses. Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: In case of fire, use water spray, alcohol-resistant foam, dry chemical powder, carbon dioxide, AFFF. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sews, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Clean preferably with a detergent. Avoid use of solvents. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed. - Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. - Flash point: 0,2ºC Setaflash - Autoignition temperature: 498ºC - Flammability range: 1,6 – 9,2 % Volume 25ºC


SDS-501/EN - Recommendations for the prevention of toxicological risks: Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Class B1. According to. ITC MIE APQ-1, RD 379/2001. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 32ºC. - ncompatible materials: Keep away from oxidizing agents, from strongly alkaline and strongly acid materials. - Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions. - Type of packaging: According to current legislation. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC 8.1 Occupational Exposure Limits (TLV) AGCIH 2004 TWA STEL Year ppm mg/m3 ppm mg/m3 Toluene 50 188 A4 Dermal 1996 Ethyl acetate 400 1440 1996 Ethylmethylketone 200 590 300 885 1976 A4 - Non classified as carcinogenic in humans. 8.2 Occupational exposure controls, Directive 89/686/EEC: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particulates and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. - Protection of respiratory system: Avoid the inhalation of vapours. Avoid the inhalation of particles or spray mist arising from the application of this preparation. Mask: Suitable combined filter mask for gases, vapours and particles (EN141/EN143). In order to obtain a suitable protection level, the filter class must be selected depending on the type and concentration of the contaminating agents present, in accordance with the specifications supplied by the filter producers. The respiratory equipment with filters does not work satisfactorily when the air contains high concentrations of vapour. If mask use is not sufficent, when operators, whether spraying or not, are inside the spraybooth, and ventilation is unlikely to be sufficent to constantly control particulates and solvent vapour in all cases, in such circumstances they should wear a compressed air-fed respiratory protective equipment (EN137) during the spraying process and until such a time as the particulates and solvent vapour concentration has fallen below the exposure limits. - Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles designed to protect against liquid splashes, with suitable lateral protection (EN166). Face shield: No. - Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Gloves resistant against chemicals (EN374). The breakthrough time of the selected glove material should be superior to the pretended period of use. The gloves should be immediately replaced when any sign of degradation is noted. Boots: No. Apron: No. Clothing: Personnel should wear antistatic clothing made of natural fibre or of high temperature resistant synthetic fibre.


SDS-501/EN 8.3 Environmental exposure controls: Avoid any spillage in the environment of the product, wastes, packages or spraybooth sewages. Avoid any release into the atmosphere above the legal limits allowed. 9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Liquid - Colour: White, grey, black - Odour: Characteristic - Viscosity: Siltex 800: 350000 cps 20ºC Brookfield Protex 50: 300000 cps 20ºC Brookfield - Specific gravity: Siltex 800: 1,30 g/cc at 20ºC (white) 1,26 g/cc at 20ºC (grey, black) Protex 50: 1,40 g/cc at 20ºC - Boiling point: 77,1ºC at 760 mmHg - Flash point: 0,2ºC Setaflash - Vapour pressure: 47,2 mmHg at 20ºC 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents, acids, alkalis. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced. 11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. - Toxicity for reproduction: This preparation contains the following ingredients which can toxic for human reproduction: Toluene (cat.3). 11.2 Dose and lethal concentrations for individual ingredients: DL50 Oral DL50 Cutaneous CL50 Inhalation mg/kg mg/kg mg/l.4hours Toluene 636 Rat 12124 Rabbit 49000 Rat Ethyl acetate 5620 Rat 20000 Rabbit 200000 Rat Ethylmethylketone 2737 Rat 6480 Rabbit 23500 Rat For more information about ingredients dangerous to health, see sections 2 and 8.


SDS-501/EN 12. ECOLOGICAL INFORMATION No experimental ecotoxicological data on the preparation as such is available. 12.1 Spills on the soil: Prevent contamination of soil. 12.2 Spills in water: Do not allow to escape into drains, sewers or water courses. 12.3 Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - Aromatic hydrocarbons: 23,3 % Weight Siltex 800 Protex 50 - COV: 468 448 g/l white ASTM D-3960 466 462 g/l grey ASTM D-3960 466 462 g/l black ASTM D-3960 12.4 Ecotoxicological data for individual ingredients: CL50 CE50 CI50 mg/l.96hours mg/l.48hours mg/l.72hours Toluene 24 Fishes 12 Daphnia 400 Algae 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste, Directive 75/442/EEC~91/156/EC: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers, Directive 94/62/EC: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. 14. TRANSPORT INFORMATION PAINTS (FP<23ºC, viscous according to 2.2.3.1.4, VP<110 kPa50ºC) 14.1 Transport by road, Directive 94/55/EC (ADR 2005): Transport by rail, Directive 96/49/EC (RID 2005): Class: 3 Packaging group: III UN no. 1263 Transport document: Consignment paper Written instructions. 14.2 Transport by sea (IMDG 32-04): Class: 3 Packaging group: III UN no. 1263 Emergency Sheet (EmS): F-E,S_E First Aid Guide (MFAG): 310, 313 Marine pollutant: No Transport document: Shipping Bill of lading 14.3 Transport by air (ICAO/IATA): Class: 3 Packaging group: III UN no. 1263 Transport document: Air Bill of lading 15. INFORMATION ON REGULATIONS 15.1 EC Labelling F, Xn


SDS-501/EN This product is labeled as HIGHLY FLAMMABLE and HARMFUL in accordance with Guideline 67/548/EEC - 2004/73/EC and 1999/45/EC - 2001/60/EC. R36/38 Irritating to eyes and skin. R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. R63 Possible risk of harm to the unborn child. R67 Vapours may cause drowsiness and dizziness. S16 Keep away from sources of ignition- No smoking. S23 Do not breathe vapour, spray. S37 Wear suitable gloves. S51 Use only in well-ventilated areas. Dangerous ingredients: Toluene · It is applicable the Directive 2004/42/EC, Annex I.2): Emission subcategory E). VOC (product ready for use): 448-468 g/l, VOC max: 840 g/l starting from 01.01.2007 15.2 Restrictions to the marketing and use in accordance with Directive 76/769/EEC: Not applicable. 15.3 Other regulations: Not available. 16. OTHER INFORMATION Intended use Only for professional use. Text of R-phrases listed in section 2: R11 Highly flammable. R36 Irritating to eyes. R38 Irritating to skin. R63 Possible risk of harm to the unborn child. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. R48/20 Harmful: danger of serious damage to health by prolonged exposure through

inhalation. Material Safety Data Sheet regulations: Material Safety Data Sheet in accordance with Directive 91/155/EEC~2001/58/EC. The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 04.07.05 SUPREME - TOPFLOW Page: 1/6

SDS-009/EN *1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: SUPREME Code: 51448 TOPFLOW Code: 51449 1.2 Use of the preparation: Bodywork repair unsaturated polyester paste. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) 2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 10-25 % Styrene R10 R20 R36/38 Xn EC No. 202-851-5 CAS: 100-42-5

SAX: SMQ000 No. 601-026-00-0

< 0,5 % Naphtha solvent (oil), light aromatic R10 R65 R66 R67 R51/53 Xn N EC No. 265-199-0 CAS: 64742-95-6 No. 649-356-00-4 (Note P) For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Flammable. Harmful by inhalation. Irritating to eyes. Irritating to skin. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. 4.3 By contact with eyes: Remove contact lenses. Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest.


SDS-009/EN 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: Extinguishing powder or CO2. In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sews, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Avoid use of solvents. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed. Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Flash point: 31ºC Setaflash Autoignition temperature: 490ºC Lower explosive limit: 1,4 % Volume Recommendations for the prevention of toxicological risks: Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Class B1. According to. ITC MIE APQ-1, RD 379/2001. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 32ºC. - Incompatible materials: Keep away from oxidizing agents, from strongly alkaline and strongly acid materials.


SDS-009/EN - Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions. - Type of packaging: According to current legislation. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC 8.1 Occupational Exposure Limits (TLV) AGCIH 2002


Styrene 20 85 40 170 A4 1997 Naphtha solvent (oil) 50 260 Internal value light aromatic A4 - Non classified as carcinogenic in humans. 8.2 Ocupational exposure controls, Directive 89/686/EEC: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. - Protection of respiratory system: Avoid the inhalation of vapours. Mask: Filter mask. - Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Suitable safety goggles. Face shield: No. - Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Suitable work clothes which avoid contact with the product should be worn. 8.3 Environmental exposure controls: Avoid any spillage in the environment of the product, wastes, packages or spraybooth sewages. Avoid any release into the atmosphere above the legal limits allowed in accordance with Directive 1999/13/EC. *9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Paste - Colour: Cream / Light green - Odour: Characteristic - Viscosity: 1,6 x 106 cps 20ºC Brookfield Supreme 4x105 cps 20ºC Brookfield Topflow - Specific gravity: 1,40 g/cc at 20ºC Supreme

1,19 g/cc at 20ºC Topflow - Solubility in water (styrene): 310 mg/l - Boiling point: 145,2ºC at 760 mmHg - Flash point: 31ºC Setaflash - Autoignition temperature: 490ºC - Vapour pressure: 5,8 mmHg at 20ºC - Vapour density: 3,42 Air=1 at 20ºC Relative Supreme 3,52 Aire = 1 at 20ºC Relative Topflow 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents, acids, alkalis, peroxides.




Styrene 2650 Rat 12 Rat Naphtha solvent (oil) 3900 Rat 3160 Rabbit light aromatic For more information about ingredients dangerous to health, see sections 2 and 8. *12. ECOLOGICAL INFORMATION No experimental ecotoxicological data on the preparation as such is available. 12.1 Spills on the soil: Prevent contamination of soil. 12.2 Spills in water: Do not allow to escape into drains, sewers or water courses. 12.3 Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - Mixing application VOC: 36 g/l Supreme ASTM D-3960 3 g/l Topflow ASTM D-3960 - Aromatic hydrocarbons: 13,4 % Weight Supreme 17,9 % Weight Topflow 12.4 Ecotoxicological data for individual ingredients: CL50 CE50 CI50

mg/l.96hours mg/l.48hours mg/l.72hours Styrene 255 Daphnia Naphtha solvent (oil), light aromatic 9,2 Fishes 6,1 Daphnia 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations.


SDS-009/EN 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. 14. TRANSPORT INFORMATION 14.1 Land: Transport by road: ADR/Transport by rail: RID: Free 14.2 Sea: Transport by ship: IMDG: Free 14.3 Air: Transport by plane: IATA/ICAO: Free 15. INFORMATION ON REGULATIONS 15.1 EC Labelling Xn This product is FLAMMABLE and HARMFUL in accordance with Guideline 67/548/EEC - 2001/59/EC and 1999/45/EC - 2001/60/EC. R10 Flammable. R20 Harmful by inhalation. R36/38 Irritating to eyes and skin. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S51 Use only in well-ventilated areas. Dangerous ingredients: Styrene 15.2 Restrictions to the marketing and use in accordance with Directive 76/769/EEC: Not applicable. 15.3 Other regulations: 16. OTHER INFORMATION Intended use: Only for professional use. Text of R-phrases listed in section 2: R10 Flammable. R20 Harmful by inhalation. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. R36/38 Irritating to eyes and skin. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic

environment. Note P : It is unnecessary to apply the classification as carcinogenic if it can be prooved that the substance contains less than 0.1% bencene (EC No. 200-753-7) in weight. Labelling regulations: The information provided in this Material Safety Data Sheet has been written in accordance with Guideline 67/548/EEC (Substances), 88/379/EEC (Preparations) and


SDS-009/EN 91/155/EEC (Material Safety Data Sheet). It has been updated to Guideline 2001/59/EC (Substances), 2001/60/EC (Preparations) and 2001/58/EC (Material Safety Data Sheet). The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 17.12.02 SURVINIL Page: 1/7

SDS-304/EN *1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: SURVINIL Code: 51200 1.2 Use of the preparation: Anti-corrosive primer. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) *2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 10-25 %Xylene R10 R38 R20/21 Xn CAS: 1330-20-7


10-25 % Isopropyl alcohol R11 R36 R67 F Xi CAS: 67-63-0 EC No. 200-661-7 SAX: INJ000 No. 603-117-00-0

10-25 % Isobutanol R10 R41 R37/38 Xn CAS: 78-83-1 EC No. 201-148-0 SAX: IIL000 No. 603-108-00-1

2,5-10 % Ethylbenzene R11 R20 F Xn CAS: 100-41-4 EC No. 202-849-4 SAX: EGP500 No. 601-023-00-4

< 0,1 % Phenol R34 R24/25 T CAS: 108-95-2 EC No. 203-632-7 SAX: PDO000 No. 604-001-00-2 For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Highly flammable. Harmful by inhalation. Harmful in contact with skin. Irritating to skin. Risk of serious damage to eyes. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious,


SDS-304/EN place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.3 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: Extinguishing powder or CO2. In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sewage, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Clean preferably with a detergent. Avoid use of solvents. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. *7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed. - Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off.


SDS-304/EN - Recommendations for the prevention of toxicological risks: Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. - Recommendations for the prevention of environmental contamination: Product dangerous to the environment. Avoid any spillage in the environment. Pay special attention to the cleaning water. In the case of accidental spillage, follow the instructions indicated in section 6. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. Keep away from living quarters. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Class B1. According to ITC MIE APQ-1, RD.379/2001. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 35ºC. 7.3 Incompatible materials: Keep away from oxidizing agents from strongly alkaline and strongly acid materials. 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions. *8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/CE 8.1 Occupational Exposure Limits (TLV) AGCIH 2001


Xylene (mixture of isomers) 100 434 150 651 A4 1996 Isopropyl alcohol 400 983 500 1230 1976 Isobutanol 50 152 1987 Ethylbenzene 100 434 125 543 1976 Phenol 5.0 19 A4 Dermal 1996 A4 - Non classified as carcinogenic in humans. 8.2 Engineering measures: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particles and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. - Vapour density: 2.44 Air = 1 at 20ºC Relative 8.3 Protection of respiratory system: Avoid the inhalation of vapours. When operators, whether spraying or not, are inside the spraybooth, and ventilation is unlikely to be sufficient to constantly control particles and solvent vapour in all cases, in such circumstances they should wear a compressed air-fed respirator during the spraying process and until such a time as the particles and solvent vapour concentration has fallen below the exposure limits. Mask: Filter mask. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles designed to protect against liquid splashes. Face shield: No. 8.5 Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Personnel should wear antistatic clothing made of natural fibre or of high temperature resistant synthetic fibre. *9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Liquid - Colour: Green


SDS-304/EN - Odour: Characteristic - Viscosity: 8000 cps at 20ºC Brookfield - Specific gravity: 1.19 g/cc at 20ºC - Solubility in water: Insoluble - Boiling point: 82ºC at 760 mmHg - Flash point: 17ºC Setaflash - Autoignition temperature: 441ºC - Decomposition temperature: 150ºC - Vapour pressure: 15 mmHg at 20ºC 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents, acids. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced. *11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. 11.2 Dose and lethal concentrations for individual ingredients:


Xylene (mixture of isomers) 4300 Rat 1700 Rabbit 22 Rat Isopropyl alcohol 5045 Rat 12800 Rabbit Isobutanol 2460 Rat 3400 Rabbit Ethylbenzene 3500 Rat 17800 Rabbit Phenol 317 Rat 850 Rabbit For more information about ingredients dangerous to health, see sections 2 and 8. *12. ECOLOGICAL INFORMATION Prevent contamination of soil. Do not allow to escape into drains, sewers or water courses. Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - VOC: 545 g/l ASTM D-3960 - Aromatic hydrocarbons: 23% Weight


SDS-304/EN 12.1 Ecotoxicity: No experimental ecotoxicological data on the preparation as such is available. Ecotoxicological data for individual ingredients:


Xylene(mixture of isomers) 75 Fishes 16 Daphnia Ethylbenzene 12 Fishes 33 Algae Phenol 5.6 Fishes 4.6 Algae 12.2 Mobility : N/A 12.3 Persistence and degradability: In water : t ½ life = 29 - 144 hours (Xylene) t ½ life = 2 - 20 days (Phenol) In air: t ½ life = 1 - 18 hours (Xylene) t ½ life = 0,5 - 2 days (Ethylbenzene) t ½ life = less than 1 day (Phenol) 12.4 Bioaccumulative potential : log Pow = 3.12 - 3.20 (Xylene) log Pow = 3.2 (Ethylbenzene) log Pow = 1.46 (Phenol) BCF = 0,67-1,9 in Fishes (Ethylbenzene) BCF = less than 100 (Phenol) N/A: Not available. 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. *14. TRANSPORT INFORMATION PAINTS (FP<23ºC, viscous according to 2.2.3.1.4, VP<110 kPa50ºC) 14.1 Land: Transport by road: ADR Transport by rail: RID/TPF Class: 3 Packaging group: III UN no. 1263 Transport document: Consignment paper Written instructions. 14.2 Sea: Transport by ship: IMDG 30-00 Class: 3 Packaging group: III UN no. 1263 Emergency Sheet (EmS): 3-05, 07 First Aid Guide (MFAG): 310, 313 Marine pollutant: No Transport document: Shipping Bill of lading


SDS-304/EN 14.3 Air: Transport by plane: IATA/ICAO Class: 3 Packaging group: III UN no. 1263 Transport document: Air Bill of lading *15. INFORMATION ON REGULATIONS 15.1 EC Labelling: F, Xn This product is HIGHLY FLAMMABLE and HARMFUL in accordance with 67/548/EEC - 2001/59/EC and 1999/45/EC - 2001/60/EC directives. R20/21 Harmful by inhalation and in contact with skin. R38 Irritating to skin. R41 Risk of serious damage to eyes. S16 Keep away from sources of ignition – No smoking. S23 Do not breathe vapour, spray. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical

advice. S36/37/39 Wear suitable protective clothing, gloves and protection for eyes. S51 Use only in well-ventilated areas. Dangerous ingredients: Xylene (mixture of isomers) 15.2 Type of packaging: According to current legislation. *16. OTHER INFORMATION Intended use Only for professional use. Text of R-phrases listed in section 2: R10 Flammable. R11 Highly flammable. R20 Harmful by inhalation. R34 Causes burns. R36 Irritating to eyes. R38 Irritating to skin. R41 Risk of serious damage to eyes. R67 Vapours may cause drowsiness and dizziness. R20/21 Harmful by inhalation and in contact with skin. R24/25 Toxic in contact with skin and if swallowed. R37/38 Irritating to respiratory system and skin. Labelling regulations: The information provided in this Material Safety Data Sheet has been written in accordance wit 67/548/EEC (Substances), 88/379/EEC (Preparations) and 91/155/EEC (Material Safety Data Sheet) directives. It has been updated to 2001/59/EC (Substances), 2001/60/EC (Preparations) and 2001/58/EC (Material Safety Data Sheet) directives.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 12.01.05 SURVINIL HARDENER Page: 1/6

SDS-606/EN *1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: SURVINIL HARDENER Code: 51239 1.2 Use of the preparation: B component for Survinil. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) 2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 60-80 % Xylene R10 R38 R20/21 Xn CAS: 1330-20-7


10-25 % Isopropyl alcohol R11 R36 R67 F Xi CAS: 67-63-0 EC No. 200-661-7 SAX: INJ000 No. 603-117-00-0

10-25 % Ethylbenzene R11 R20 F Xn CAS: 100-41-4 EC No. 202-849-4 SAX: EGP500 No. 601-023-00-4

2,5-10 % Isobutanol R10 R41 R37/38 Xn CAS: 78-83-1 EC No. 201-148-0 SAX: IIL000 No. 603-108-00-1

< 2,5 % Phosphoric acid R34 C EC No. 231-633-2 CAS: 7664-38-2 SAX: PHB250 No. 015-011-00-6 For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Highly flammable. Harmful by inhalation. Harmful in contact with skin. Irritating to skin. Irritating to eyes. *4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious,


SDS-606/EN place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and a solution of 5% sodium bicarbonate. Finally, rewash the affected area with soap and water. Do not use solvents or thinners. 4.3 By contact with eyes: Remove contact lenses. Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, holding the eyelids apart, until the irritation is reduced. Call a physician immediately. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Due to its acid condition, the effects can be reduced to a minimumm by drinking plenty of water, to which milk of magnesia has been added. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of extinction: In case of fire, use water spray, alcohol-resistant foam, dry chemical powder, carbon dioxide. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous products may be produced: carbon monoxide, carbon dioxide, phosphorus oxides. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sewage, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Clean preferably with a detergent. Avoid use of solvents. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. *7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed. - Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not


SDS-606/EN smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. Flash point: 20ºC Autoignition temperature: 455,6ºC Lower explosive limit: 1,7 % Volume Ventilation requirement: 124 m3/l Air/Preparation to keep below 1/10 of the Lower Explosive Limit. - Recommendations for the prevention of toxicological risks: Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. - Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. Keep away from living quarters. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Class B1. According to ITC MIE APQ-1, RD.379/2001. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 35ºC. - Incompatible materials: Keep away from oxidizing agents, acids, alkalis, amines, alcohols, ketones, metals. Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions. - Type of packaging: According to current legislation. *8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/CE 8.1 Occupational Exposure Limits (TLV) AGCIH 2002


Xylene (mixture of isomers) 100 434 150 651 A4 1996 Isopropyl alcohol 400 983 500 1230 1976 Ethylbenzene 100 434 125 543 1976 Isobutanol 50 152 1987 Phosphoric acid 1,0 3,0 1976 A4 - Non classified as carcinogenic in humans. 8.2 Ocupational exposure controls, Directive 89/686/EEC: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. If these measures are not sufficient to maintain concentrations of particles and vapours below the Occupational Exposure Limits, suitable respiratory protection must be worn. - Protection of respiratory system: Avoid the inhalation of vapours. When operators, whether spraying or not, are inside the spraybooth, and ventilation is unlikely to be sufficient to constantly control particles and solvent vapour in all cases, in such circumstances they should wear a compressed air-fed respirator during the spraying process and until such a time as the particles and solvent vapour concentration has fallen below the exposure limits. Mask: Filter mask. - Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles designed to protect against liquid splashes. Face shield: No. - Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Personnel should wear antistatic clothing made of natural fibre or of high temperature resistant synthetic fibre.


SDS-606/EN 8.3 Environmental exposure controls: Avoid any spillage in the environment of the product, wastes, packages or spraybooth sewages. Avoid any release into the atmosphere above the legal limits allowed in accordance with Directive 1999/13/EC. *9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Liquid - Colour: Colourless - Odour: Characteristic - Viscosity: 11 sec.FC4 20ºC ASTM D 1200-88 - Specific gravity: 0,858 g/cc at 20ºC - Boiling point: 82,3ºC at 760 mmHg - Decomposition temperature: 250ºC - Vapour pressure: 12,4 mmHg at 20ºC - Vapour density: 2,65 Air = 1 at 20ºC Relative 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents, acids, alkalis, amines, alcohols, ketones, metals. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced: phosphorus oxides. 11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. 11.2 Dose and lethal concentrations for individual ingredients:


Xylene (mixture of isomers) 4300 Rat 1700 Rabbit 22 Rat Isopropyl alcohol 5045 Rat 12800 Rabbit Ethylbenzene 3500 Rat 17800 Rabbit Phosphoric acid 1530 Rat 2740 Rabbit Isobutanol 2460 Rat 3400 Rabbit For more information about ingredients dangerous to health, see sections 2 and 8.


SDS-606/EN *12. ECOLOGICAL INFORMATION 12.1 Spills on the soil: Prevent contamination of soil. 12.2 Spills in water: Because of its acidity, it is harmful to aquatic organisms. Do not allow to escape into drains, sewers or water courses. 12.3 Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - VOC: 847 g/l ASTM D-3960 - Aromatic hydrocarbons: 76,3% Weight 12.4 Ecotoxicological data for individual ingredients:


Xylene(mixture of isomers) 75 Fishes 16 Daphnia Ethylbenzene 12 Fishes 33 Algae 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. *14. TRANSPORT INFORMATION PAINT RELATED MATERIAL (VP<110 kPa50ºC) 14.1 Land: Transport by road: ADR Transport by rail: RID Class: 3 Packaging group: II UN no. 1263 Transport document: Consignment paper Written instructions. 14.2 Sea: Transport by ship: IMDG Class: 3 Packaging group: II UN no. 1263 Emergency Sheet (EmS): 3-05 First Aid Guide (MFAG): 310 Marine pollutant: No Transport document: Shipping Bill of lading 14.3 Air: Transport by plane: IATA/ICAO Class: 3 Packaging group: II UN no. 1263 Transport document: Air Bill of lading *15. INFORMATION ON REGULATIONS 15.1 EC Labelling: F, Xn


SDS-606/EN This product is HIGHLY FLAMMABLE and HARMFUL in accordance with Guideline 67/548/EEC - 2001/59/EC and 1999/45/EC - 2001/60/EC. R20/21 Harmful by inhalation and in contact with skin. R36/38 Irritating to eyes and skin. S23 Do not breathe vapour, spray. S36/37 Wear suitable protective clothing and gloves. S43 In case of fire, use water spray, alcohol-resistant foam, dry chemical powder, carbon dioxide. S51 Use only in well-ventilated areas. Dangerous ingredients: Xylene (mixture of isomers) 15.2 Restrictions to the marketing and use in accordance with Directive 76/769/EEC: Not applicable. 15.3 Other regulations: Not available. *16. OTHER INFORMATION Intended use Only for professional use. Text of R-phrases listed in section 2: R10 Flammable. R11 Highly flammable. R20 Harmful by inhalation. R34 Causes burns. R36 Irritating to eyes. R38 Irritating to skin. R41 Risk of serious damage to eyes. R67 Vapours may cause drowsiness and dizziness. R20/21 Harmful by inhalation and in contact with skin. R37/38 Irritating to respiratory system and skin. Labelling regulations: The information provided in this Material Safety Data Sheet has been written in accordance with Guideline 67/548/EEC (Substances), 88/379/EEC (Preparations) and 91/155/EEC (Material Safety Data Sheet) directives. It has been updated to Guideline 2001/59/EC (Substances), 2001/60/EC (Preparations) and 2001/58/EC (Material Safety Data Sheet). The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 17.06.05 TENON 710 Page: 1/5

SDS-111/EN *1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: TENON 710 Code: 51543, 51563-51567, 51617 1.2 Use of the preparation: Wood unsaturated polyester paste. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) 2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 10-25 % Styrene R10 R20 R36/38 Xn EC No. 202-851-5 CAS: 100-42-5

SAX: SMQ000 No. 601-026-00-0

For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Flammable. Harmful by inhalation. Irritating to eyes. Irritating to skin. 4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. 4.3 By contact with eyes: Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: Extinguishing powder or CO2. In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use for extinguishing: direct water jet. 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon


SDS-111/EN monoxide, carbon dioxide. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. 6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sews, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Avoid use of solvents. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. 7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed. Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. Recommendations for the prevention of toxicological risks: Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Class B1. According to. ITC MIE APQ-1, RD 379/2001. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 32ºC. 7.3 Incompatible materials: Keep away from oxidizing agents, from strongly alkaline and strongly acid materials. 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC 8.1 Occupational Exposure Limits (TLV) AGCIH 2002


SDS-111/EN


Styrene 20 85 40 170 A4 1997 A4 - Non classified as carcinogenic in humans. 8.2 Engineering measures: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. Vapour density: 3,59 Air=1 at 20ºC Relative Lower explosive limit: 1,4 % Volume 8.3 Protection of respiratory system: Avoid the inhalation of vapours. Mask: Filter mask. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Suitable safety goggles. Face shield: No. 8.5 Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: Suitable work clothes which avoid contact with the product should be worn. Wash contaminated work clothes before wearing them again. *9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Paste - Colour: Walnut, Mahogany, White, Oak, Pine, Douglas, Translucent beige - Odour: Characteristic - Viscosity: 9 x 106cps 20ºC Brookfield - Specific gravity: 1,70 g/cc a 20ºC - Solubility in water (styrene): 310 mg/l - Boiling point: 145,2ºC at 760 mmHg - Flash point: 32ºC Setaflash - Autoignition temperature: 490ºC - Vapour pressure: 5,8 mmHg at 20ºC 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents, acids, alkalis, peroxides. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced. 11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic


SDS-111/EN contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. 11.2 Dose and lethal concentrations for individual ingredients:


Styrene 2650 Rat 12 Rat For more information about ingredients dangerous to health, see sections 2 and 8. *12. ECOLOGICAL INFORMATION No experimental ecotoxicological data on the preparation as such is available. 12.1 Spills on the soil: Prevent contamination of soil. 12.2 Spills in water: Do not allow to escape into drains, sewers or water courses. 12.3 Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - Product VOC: 199 g/l ASTM D-3960 - Mixing application VOC: 66 g/l ASTM D-3960 - Aromatic hydrocarbons: 13,3 % Weight 12.4 Ecotoxicological data for individual ingredients: CL50 CE50 CI50

mg/l.96hours mg/l.48hours mg/l.72hours Styrene 255 Dafnia 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. 14. TRANSPORT INFORMATION 14.1 Land: Transport by road: ADR/Transport by rail: RID: Free 14.2 Sea: Transport by ship: IMDG: Free 14.3 Air: Transport by plane: IATA/ICAO: Free 15. INFORMATION ON REGULATIONS 15.1 EC Labelling Xn This product is FLAMMABLE and HARMFUL in accordance with Guideline 67/548/EEC - 2001/59/EC and 1999/45/EC - 2001/60/EC. R10 Flammable.


SDS-111/EN R20 Harmful by inhalation. R36/38 Irritating to eyes and skin. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S51 Use only in well-ventilated areas. Dangerous ingredients: Styrene 15.2 Type of packaging: According to current legislation. 16. OTHER INFORMATION Intended use Only for professional use. Text of R-phrases listed in section 2: R10 Flammable. R20 Harmful by inhalation. R36/38 Irritating to eyes and skin. Labelling regulations: The information provided in this Material Safety Data Sheet has been written in accordance with Guideline 67/548/EEC (Substances), 88/379/EEC (Preparations) and 91/155/EEC (Material Safety Data Sheet) directives. It has been updated to Guideline 2001/59/EC (Substances), 2001/60/EC (Preparations) and 2001/58/EC (Material Safety Data Sheet) directives. The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

* MATERIAL SAFETY DATA SHEET 2001/58/EC Revision date: 18.06.04 VETRORESINA Page: 1/5

SDS-102/EN 1. IDENTIFICATION OF THE PRODUCT AND COMPANY 1.1 Identification of the preparation: VETRORESINA Code: 51175 1.2 Use of the preparation: Polyester resin for polyester repair. 1.3 Company: ROBERLO, S.A. Carretera N-II, Km. 706,5 - E-17457 - Riudellots de la Selva (Girona) - SPAIN Phone: +34 972 478060 - Fax: +34 972 477394 - [email protected] – www.roberlo.com 1.4 Emergency phone number: +34 91 5620420 (National Institute of Toxicology - Spain) 13 11 26 (Poisons Information Centre - Australia) 2. COMPOSITION/INFORMATION ON INGREDIENTS Substances taking part in a percentage higher than the exemption limit and presenting a health or environment hazard, and/or with a recognised exposure limit value: 25-50 % Styrene R10 R20 R36/38 Xn EC No. 202-851-5 CAS: 100-42-5

SAX: SMQ000 No. 601-026-00-0

For more information on dangerous ingredients, see sections 8, 11, 12 and 16. 3. IDENTIFICATION OF HAZARDS Flammable. Harmful by inhalation. Irritating to eyes. Irritating to skin. *4. FIRST AID MEASURES When in doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. 4.1 By inhalation: Remove the patient out of the contaminated area into the fresh air. If breathing is irregular or stops, administer artificial respiration. If the person is unconscious, place in appropriate recovery position. Keep the patient warm and at rest until medical attention arrives. 4.2 By contact with the skin: Remove contaminated clothing. Wash thoroughly the affected area with plenty of cold or lukewarm water and neutral soap, or use a suitable skin cleanser. Do not use solvents or thinners. 4.3 By contact with eyes: Remove contact lenses. Rinse eyes copiously by irrigation with plenty of clean, fresh water for at least 15 minutes, until the irritation is reduced. Call a physician immediately. 4.4 By ingestion: In case of accidental swallowing, seek immediate medical attention. Do not induce vomiting, due to the risk of aspiration. Keep the patient at rest. 5. FIRE-FIGHTING MEASURES 5.1 Means of Extinction: Extinguishing powder or CO2. In the case of more important fires, also alcohol resistant foam and water spray/mist. Do not use for extinguishing: direct water jet.


SDS-102/EN 5.2 Specific risks: Fire can produce a dense black smoke. As consequence of combustion or thermal decomposition, hazardous decomposition products may be produced, such as: carbon monoxide, carbon dioxide. Exposure to combustion or decomposition products may be a hazard to health. 5.3 Fire-proof protective equipment: Depending on magnitude of fire, heat-proof protective clothing may be required, appropriate independent breathing apparatus, gloves, protective glasses or face masks and boots. 5.4 Other recommendations: Cool with water the tanks, cisterns or containers close to sources of heat or fire. Bear in mind the direction of the wind. Do not allow fire-fighting residue to enter drains, sewers or water courses. *6. ACCIDENTAL SPILLAGE MEASURES 6.1 Personal precautions: Eliminate possible sources of ignition and when appropriate, ventilate the area. Do not smoke. Avoid direct contact with this product. Avoid breathing vapours. For exposure controls and personal protection measures, see section 8. 6.2 Environmental precautions: Avoid contamination of drains, surface or subterranean water and soil. In the case of large scale spills or when the product contaminates lakes, rivers or sews, inform the appropriate authorities in accordance with local regulations. 6.3 Cleaning-up methods: Contain and mop up spills with non-combustible absorbent materials (earth, sand, vermiculite, diatomaceous earth, etc..). Clean preferably with a detergent. Keep the remains in a closed container. For subsequent waste disposal, follow the recommendations in section 13. *7. HANDLING AND STORAGE 7.1 Handling precautions: Comply with the health and safety at work laws. - General recommendations: Avoid any type of leakage or escape. Keep the container tightly closed. Recommendations for the prevention of fire and explosion risks: Vapours are heavier than air and may spread along floors to a considerable distance. Vapours can form explosive mixtures with air and are able to reach distant ignition sources and flame up or explode. Due to its flammability, this material should only be used in areas from which all naked lights and other sources of ignition have been excluded and away from other heat or electrical sources. Do not smoke. Electrical equipment should be protected to the appropriate standard. No tools with a potential for sparks should be used. Use explosion protected equipment. Switch mobile phones off. Recommendations for the prevention of toxicological risks: Do not eat, drink or smoke in application and drying areas. After handling, wash hands with soap and water. For exposure controls and personal protection measures, see section 8. 7.2 Storage conditions: Prevent unauthorized access. Keep out of reach of children. This product should be stored isolated from heat and electrical sources. Do not smoke in storage area. In order to avoid leaks, the containers, after use, should be closed carefully and placed in a vertical position. Class of store: Class B1. According to. ITC MIE APQ-1, RD 379/2001. Maximum storage period: 12 months. Temperature interval: min: 5ºC, max: 32ºC. 7.3 Incompatible materials: Keep away from oxidizing agents, acids, alkalis, peroxides. 7.4 Conditions to avoid: Heat: Keep away from sources of heat. Light: Avoid direct contact with sunlight. Humidity: Avoid extreme humidity conditions.


SDS-102/EN *8. EXPOSURE CONTROLS/PERSONAL PROTECTION 98/24/EC 8.1 Occupational Exposure Limits (TLV) AGCIH 2002


Styrene 20 85 40 170 A4 1997 A4 - Non classified as carcinogenic in humans. 8.2 Engineering measures: Provide adequate ventilation. Where reasonably practicable, this should be achieved by the use of local exhaust ventilation and good general extraction. Vapour density: 3,57 Air=1 at 20ºC Relative Lower explosive limit: 1,4 % Volume 8.3 Protection of respiratory system: Avoid the inhalation of vapours. Mask: Filter mask. 8.4 Protection of eyes and face: Install emergency eye baths close to the working area. Goggles: Safety goggles designed to protect against liquid splashes. Face shield: No. 8.5 Protection of hands and skin: Install emergency showers close to the working area. Barrier creams may help to protect the exposed areas of the skin. Barrier creams should not be applied once exposure has occurred. Gloves: Protective gloves of a suitable material. Boots: No. Apron: No. Clothing: It is advisable personnel wear antistatic clothing made of natural fibre or of high temperature resistant synthetic fibre. 9. PHYSICAL AND CHEMICAL PROPERTIES - Physical state: Liquid - Colour: Transparent yellow - Odour: Characteristic - Viscosity: 126” FC/4 at 20ºC 68ºF ASTM D 1200-88 - Specific gravity: 1,10 g/cc a 20ºC - Solubility in water (styrene): 310 mg/l - Boiling point: 145,2ºC at 760 mmHg - Flash point: 32ºC Setaflash - Autoignition temperature: 490ºC - Vapour pressure: 5,8 mmHg at 20ºC 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Dangerous reactions: Possible dangerous reaction with oxidizing agents, acids, alkalis, peroxides. 10.3 Thermal decomposition: As consequence of thermal decomposition, hazardous products may be produced. *11. TOXICOLOGICAL INFORMATION No experimental toxicological data on the preparation is available. 11.1 Toxicological effects: Exposure to solvent vapour concentrations in excess of the stated occupational exposure limit, may result in adverse health effects, such as mucous membrane and respiratory system irritation and adverse effects on kidneys, liver and central nervous system. Symptoms and signs include: headache, dizziness, fatigue, muscular weakness,


SDS-102/EN drowsiness and, in extreme cases, unconsciousness. Ingestion may result in the following effects: sore throat, abdominal pain, drowsiness, nausea, vomiting and diarrhoea; other effects may be as described for exposure to vapours. Repeated or prolonged contact with the solvents of the preparation, may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin. Liquid splashes in the eyes may cause irritation and reversible damage. 11.2 Dose and lethal concentrations for individual ingredients:


Styrene 2650 Rat 12 Rat For more information about ingredients dangerous to health, see sections 2 and 8. *12. ECOLOGICAL INFORMATION No experimental ecotoxicological data on the preparation as such is available. 12.1 Spills on the soil: Prevent contamination of soil. 12.2 Spills in water: Do not allow to escape into drains, sewers or water courses. 12.3 Emissions to the atmosphere: Avoid any solvent release into the atmosphere. - Mixing application VOC: 38 g/l ASTM D-3960 - Aromatic hydrocarbons: 37,5 % Weight 12.4 Ecotoxicological data for individual ingredients: CL50 CE50 CI50

mg/l.96hours mg/l.48hours mg/l.72hours Styrene 255 Dafnia 13. CONSIDERATIONS FOR DISPOSAL 13.1 Handling of waste: Take all necessary measures to prevent the production of waste whenever possible. Analyse possible methods for revaluation or recycling. Do not discharge into drains or the environment, dispose of at an authorised waste collection point. Waste should be handled and disposed of in accordance with current local/national regulations. For exposure controls and personal protection measures, see section 8. 13.2 Disposal of empty containers: Emptied containers and packaging should be disposed of in accordance with currently local/national regulations. 13.3 Procedures for neutralising or destroying the product: Controlled incineration in special facilities for chemical waste, but in accordance with local regulations. *14. TRANSPORT INFORMATION RESIN SOLUTION (contains styrene) 14.1 Land: Transport by road: ADR-2003

Transport by rail: RID Good not submitted to Class 3.¹



14.2 Sea: Transport by ship: IMDG 30-00 Class: 3 UN nº1866 Marine pollutant: no Packaging group: III


SDS-102/EN

Emergency Sheet (EmS): 3-05 First Aid Guide (MFAG): 310 Transport document: Shipping Bill of Lading

14.3 Air: Transport by plane: IATA/ICAO Class: 3 UN nº1866 Packaging group: III Transport document: Air Bill of Lading

15. INFORMATION ON REGULATIONS 15.1 EC Labelling Xn This product is FLAMMABLE and HARMFUL in accordance with Guideline 67/548/EEC - 2001/59/EC and 1999/45/EC - 2001/60/EC. R10 Flammable. R20 Harmful by inhalation. R36/38 Irritating to eyes and skin. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S51 Use only in well-ventilated areas. Dangerous ingredients: Styrene 15.2 Type of packaging: According to current legislation. 16. OTHER INFORMATION Intended use Only for professional use. Text of R-phrases listed in section 2: R10 Flammable. R20 Harmful by inhalation. R36/38 Irritating to eyes and skin. Labelling regulations: The information provided in this Material Safety Data Sheet has been written in accordance with Guideline 67/548/EEC (Substances), 88/379/EEC (Preparations) and 91/155/EEC (Material Safety Data Sheet). It has been updated to Guideline 2001/59/EC (Substances), 2001/60/EC (Preparations) and 2001/58/EC (Material Safety Data Sheet). The information of this Material Safety Data Sheet, is based on the present state of knowledge and on current UE and national laws, as the users' working conditions are beyond our knowledge and control. The product is not to be used for other purposes than those specified, without first obtaining written handling instruction. It is always the responsibility of the user to take all necessary steps in order to fulfil the demand laid down in the local rules and legislation. The information in this Material Safety Data Sheet is meant as a description of the safety requirements of the product and it is not to be considered as a guarantee of the product's properties.

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