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Mater ia l Sa fe ty Data Shee t

Product Name

Product Code{s}

UN-No

Recommended Use

Company

Company Emergency Phone Number Emergency Telephone Number

•"O-^ Urt* l o ' i n n r t | , - y ! - = - n . J - p - h —

1. PRODUCT AND COMPANY IDENTIFICATION

CAUTION!

Appearance Black

AC-<S251 Black Class B Base

AC-251 Black Class B Base

Not regulatKi

Sealant.

Advanced Chemistry 8> Technology, Inc. 7341 Anaconda Avenue Garden Grove, CA 92841

714-373-2837 (8 AM to 5 PM Pacific)

Chemtrec 1-800-424-9300

2. HAZARDS IDENTIFICATION

Emergency Overview May cause skin, eye, and respiratory tract irritation

Physical State Paste/Gel Odor Sulphurous

OSHA Regulatory Status

Potential Health Effects Principle Routes of Exposure

Acute Toxicity Eyes Skin inhalation Ingestion

Chronic Effects

This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Skin contact. Inhalation, Eye contact

Contact with eyes may cause irritation. May cause irritation. May cause irritation of respiratory tract. Ingestion may cause imtation to mucous membranes. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.

Repeated or prolonged skin cxintact may cause skin irritation and/or dermatitis and sensitization of susceptible pereons.

A§gra¥ated Medical Condltlorss Skin disorders. Lr er disoi^^s. Kidney disordsm. Altergies.

3. COMPOSITION.INFORMATION ON INGREDIENTS

AC-^51 Black Class B Base Revision Date December 23, 2009

Caldum carbonate Phenol

Formaldehyde Carbon black

471-34-1 108-95-2 50-00-0

~~~'""~~"~~^"^'ni^S;8&4 ~"^~—^-1

30-40 .001-.004

.0001-0.004 0.1-0,5

Eye Contact

Skin Contact

inhalation

ingestion

Notes to Physician

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Get medical attention immediately if symptoms occur.

Wash skin with soap and water.

Administer oxygen if breathing is difficult and you are trained. Apply artificial respiration If victim is not breatiiing.

Do not induce vomiting without medical advice. Consult a physician.

Treat symptomaticaNy.

S. FIRE-FIGHTING MEASURES

Flash Point Method

Suitable Extinguishing Media

Hazardous Combustion Products

Explosion Data Sensitivify to Mechanical Impact Sensitivity to Static Discharge

Protective Equipment and Precautions for Firefighters

> 93 °C / > 200 T Ctos^ cup

Use:. Water spray. Cafton dioxide (CO2). Dry chemical.

Carbon monoxide, Cart)on dioxide (COE). Sulfur oxides. Nitrogen oxides (NOx), Aldehyde

Not impact sensitive. Not sensitive.

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NiOSH (approved or equivalent) and full protective gear.

NFPA Health Hazard 1 Flammabillty 1 Stability 0 Physical and Chemical Hazards N/A

Personal Precautions

Methods for Containment

6. ACCIDENTAL RELEASE MEASURES

Avoid contact with the skin and the eyes. Use personal protective equipment. Ensure adequate ventilation. Refer to Sections.

Contain and col!s:t spillage with non-combustible absorbent materia!, (e.g. sand, earth, diatoma<^ous earth, vemiiculite) and place in container for disposal aaxirding to local /

7. HANDLING AND STORAGE

wash contaminated clothing before re-use, Do not smoke,

sp at temperatures below 28''C.. Keep out of ttie reac^ of chj;

AC-^SI Black Class B Base Revision Date December 23, 2009

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Chemical Name Catcium carbonate

471-34-1 Phenol 108-95-2

Fomialdehyde 50-00-0

Carton btack 1333-86-4

ACGfH TLV

TWA: 5 ppm

TWA: 3.5 mg/m^

OSHA PEL TWA; 5 mg/m^ TWA-ISmg/m*

TWA: 5 ppm TWA: 19 mg/m^

TWA: 0.75 ppm

TWA: 3.5 mg/m'* (vacated) TWA: 3.5 mg/m^

L NIOSH iDLH TWA: 5 mg/m^ TWA: lOmq/m^ IDLH: 250 ppm

Ceiling: 60 mg/m^ Ceiling: 15.6 ppm

TWA: 5 ppm TWA: 19 mq/m^ IDLH: 20 ppm

Ceiling: 0.1 ppm TWA: 0.016 ppm

IDLH: 1750mg/m= TWA: 0.1 mg/m-' TWA: 3.5rmlm^

Engineering Measures

Personal Protectiye Eguiprnent Eyeff^ace Protection Skin and Body Protection Respiratory Protection

Hygiene Measures

Showers, eyewash stations, and ventilation systems.

Safety glasses with side-shields. Wear protective gloves/clothing. Maintain adequate ventilation.

Do not eat, drink or smoke when using this product. Remove and wash (X)ntaminated clothing before re-use. General industrial hygiene practice.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance Physical State Flasii Point Autoignltion Temperature

Explosion Limits

Specific Gravit/

Evaporation Rate Vapor Density Actual VOC (Ib/ga!) EPA VOC (g/l)

Btack Paste/Get > 93 "C / > 200 T No data available

No information available

1.61 glee

No information available No infonnatlon available. 0,07

Odor pH Method Boiling Point/Range Flammabiiity Limi^ in Air

Solubility

Vapor Pressure Weight per Gallon (lbs) EPA VOC (lb/gat) Viscosity

Sulphurous No data available Closed cup Not applicable No infotmation available

Soluble in aromatic hydrocarbons and ketones No information available 13.41 0.07 Thixotropic paste

10. STABILITY AND REACTIVITY

Stability Stable under norma! conditions.

j m

1 1 . TOXICOLOGICAL INFORMATION

AC-€a51 Black Class B Base Revision Date December 23, 2009

Acute Toxicity

Product Information

Irritation

The product ifeelf has not been t e s t ^ . May be harmful if swallowed.

Moderately irritating to eyes, skin and respiratory system.

Chemicaf Name Calcium carbonate

Phenol

Formaldehyde

Carbon blade

LD50 Oral 6450 mg/kg ( Rat)

31?mg/kg (Rat)

100mgfl<g (Rat)

15400 mgjkg { Rat)

UJSO Dermal

525 mg/kg ( Ral) 630 mq/kq { Rabbit) 270mg/kg (Rabbit)

3 g/kg { Rabbit)

LC50 inhalation

0,578mg/L (Ra t )4h 250 ppm (Rat )4h

Chronic Toxicity

Chronic T o x i c i ^

Carcinogenicity

Repeated or prolonged skin contact may cause skin irritation and/or dermatitis and sensitization of susceptible persons.

The table below indicates whether each agency has listed any ingredient as a carcinogen.

Cliemlcal Name \ ACGIH Fomialdehyde 1 A2

i Carbon black j

lARC Group 1

Group 2B

NTP Reasonably Anticipated

OSHA X

X

Target Organ Effects Liver, Kidney, Skin

12. ECOLOGICAL INFORMATION

Ecotoxicity This product contains an ingredient that is classified, acxx)rding to European regulations, as "harmful to aquatic organisms, may cause long-term adverse effects In the aquatic environment".

Chemical Name Toxicity to Algae Toxicity to Fish Microtox Daphnia Magna (Water Flea)

Phenol EC50=150mg/L96h LC50 5 -12 mg/L Oncorhynchus mykiss 96 h LC50= 23-88 mg/L Lepomis

macroctiirus 96 h LC50= 24 mg/L Pimephales

promelas % h LC50- 27.8 mg^

Brachydanlo rerio 96 h LCK3= 40 mg/L Pc^dlia

reticulata 96 h LC50= S.g mg/L

lus mylcfss 96 h

EC50 21-36 mg/L 30 min EC50 = 23.28 mg/L 5 min EC50 = 25.61 mg/L 15 min EC50 = 2a.8mg/L5min

EC5Q = 31.6 mg/L 15 min

LC50 = 13mg/L48h EC50 = 23.0 mg/L 48 h

Chemicai Name

AC-€S!51 Black Class B Base Revision Date December 23, 2009

= 1,47 ^onnafdehyde = 0,35 25 X

Waste Disposal Method Dispose of contents/container in accordance with local regulation.

Chemical Name

Calcium carijonate! - 471-34-1

Phenol - 108-95-2 Formaldehyde - 50-00-0

Carbon black-1333-86-4

RCRA • Haiogenated Organic Compounds

RCRA - P Series Wastes RCRA-F Series Wastes RCRA - K Series Wastes

Chemicat Name PhencJ

Fomialdehyde

CaltfcH-nia Hazardous Waste Stetus Toxic; Corrosive Toxic; iqnitable

DOT UN-No

lATA

IMDG/IMO

Not regulated Not regulated

Not regulated

Not regulated

15. REGULATORY INFORMATION

International Inventories

TSCA DSL EINECS/ELINCS ENCS lECSC KECL PICCS AlCS

U.S. Federal Regulations

Complin Complies Complies Complin Complies Complies Complies Complies

SARA 313 Section 313of Title ill of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations,

Acute Health Hazard Chronic Health Hazard Fire Hazard

Yes

AC-®251 Black Class B Base Revision Date December 23, 2009

Sudden Release of Pressure Hazard Reactive Hazard

No

Clean Water Act Component

Phenol 108-95-2 ( .001-004)

Formaldehyde 50-00-0 ( .0001-0,004 )

CWA - Reportable Quantities

10001b

1001b

CWA - Toxic Pollutents CWA-Priority Pollutants: CWA - Hazardous 1 Substances

X X X

X

Chemical Name

Pheni^

Formaldehyde

CAS-No

108-95-2

50-00-0

Weight %

.001-004

.0001-0.004

HAPS data

Present

Present

VOC Chemicals

Group III

Group!

Class 1 Ozone ! Class 2 Ozone Deptetors ; Depletors

CERCLA

Chenric^ Name Phenc^

Formaldehyde

Hazardous Substences RQs 10001b

1001b

Extremely Hazardous Substances RQs 10001b

1001b

U.S. State Regulations

California Proposition 65 This product contains the following Proposition 65 chemicals:

Chemical Name i CAS-No Fomialdehyde

CartKjn black

50-00-0

1333-86-4

California Prop. 65 Carcinogen

Carcinogen

Chemical Name Caldum cartjonate

Phenol

Formaldehyde

Carbon blade

Massachusetts X

X

X

X

New Jersey Pennsvlvania

! ^

X

X

X

X

X

X

illlnots

X

X

X

Rhode Island X

X

X

X

International Regulations

Mexico - Grade Slight risk, Grade 1

Carcinogen Stattis Exposure Limits Mexico. TV-JA---- 10

Mexico: TWA" 5 ppm Mexfcp: TWA= 18 rf^m^

Mexico. TWA= 3.5 mg/m^ . Mexico; STEL= T mg/m^

Canada

AC^251 Biack Class B Base Revision Date December 23. 2009

This product has been classified tn acconjance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.

WHMIS Hazard Class D2A Very toxic materials D2B Toxic materials

© Ch^TiIca) Name

Phend Formaldetiyde

NPRi X X

OTHER INFORMATION

NFPA HMiS PPE Transpor t Symbo l

K 'Rd l l l Hrtxj^-;-

1 --mi R^AcUvity

1

1

0

Not regulated

Prepared By David Jordan Director of R&D

Issuing Date

Revision Date

Revision Note

December 24, 2009

December 23, 2009

(M)SDS sections updated. 1. 16.

Disclaimer The information provided on tiiis SOS is correct to the best of our Itnowtedge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless speci^ed in tiie text

Material Safety Data Sheet

U.n., T A I r t T l f t

Product Name

Product Code{s}

UN-No

Recommended Use

Company


F*i---!-si-— p-i*<- n « « « ~ . u ^ , -Ti n n n n P^.^.!-.!-,^ I J - . ^ t ^^^

1. PRODUCT AND COMPANY IDENTIFICATION

AC-®251 Catalyst

AC-251 Blacl< and Gray Catalyst

Not r^utated

Hardener.

Advanced Chemistry & Technology, Inc. 7341 Anaconda Avenue Garden Grove, CA 92841

714-373-2839 (8 AM to 5 PM Pacific)

Chemtrec 1-800-424-9300

2. HAZARDS IDENTIFICATION CAUTION!

Emergency Overview May be hannfui if inhaled

May cause skin, eye, and respiratory tract irritation May be harmftjl if swallowed

Appearance Viscous liquid, Blacic Physical State Viscous liquid Odor Sligtit

OSHA Regulatory Stetus


Acute Toxicity Eyes Skin inhalation ingestion

Chronic Effecte


Eye contact, Skin contact. Ingestion

May cause slight imtation. Substance may cause slight skin irritation. May cause irritation of respiratory tract. May be harmful if swrallowed.

Repeated or prolonged si in cont^jt may cause skin irritation and/or dermatitis and

Environmental Hmax4 May cause long-temi adveree etf^ts in the aquatic environment.

3. COMPOSITION INFORMATION ON INGREDIENTS

AC-msi Catal^t Revision Date December 23. 2009

Chemical Name Hydrcigenated tetphenyis

Terphenyis Manganese dioxide

Cartx)n black

CAS-No 61788-32-7 26140-60-3 1313-13-9 1333-86-4

^"^"^"""^w^iiiszizir^ 35-40 1 -5

45-50 1 -5

Eye Contect

Skin Contect

Inhalation

Ingestion

Notes to Physician

Protection of First-aiders

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If eye invitation persists, consult a specialist.

Wash off immediately with soap and plenty of water, (f skin irritation persists, call a physician. Remove and wash cxjntaminated clothing before re-use.

Move to fresh air. If symptoms peralst. rail a physician, if breathing is irregular or stopped, administer artificiaf respiration.

Do not induce vomiting wittiout medical advice. Consult a physician. Never give anytfting by mouth to an unconscious person.

Treat symptomatically.

Avoid contact with skin, eyes and clothing.

Flash Point Method

Suitebte Extinguishing Media

Hazardous Combustion Producte

Explosion Data Sensitivity to Mechanical Impact Sensitivity to Stetic Discharge

> 1 1 0 X />230°F Closed ojp

Dry chemical, CO2. water spray or aicohol-resistant foam.

Carbon oxides. Cartoon monoxide. Carbon dioxide (CO2)

Not sensitive. Not sensitive.

Specific Hazards Arising from the Chemicat in the event of fire and/or explosion do not breathe fumes. Do not allow run-off from fire fighting to enter drains or water courees.

Protective Equipment and Precautions for Firetightets As in any fire, wear s€^-a)ntained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and fui! protective gear.

NFPA Health Hazard 1 Flammabili^ 1 Stability 0 Physical and Cfiemlcal

6. ACCIDENTAL RELEASE MEASURES

diatomaceous earth, vemiicuiite) and place in container for dispcsa! according to ICK^I / national regulations (see Section 13).

AC-®251 Catai^t Revision Date Etecemiber 23, 2009

Methods for Cleaning Up Prevent product from entering drains. Take up medianicalty and collect in suitable container for disposal. Use personal prot^tive equipment.

Handling

Storage

Wear personal protective equipment. Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminate clothing before re-use.

Keep tightly closed in a dry and cool place. K^p away from heat and sources of ignition. Keep at temperatures below 28°C..

Chemical Name Hydrogenated terphenyis

6178&-32-7 Terphenyis 26140-60-3

Manganese dioxide 1313-13-9

Carixjn black 1333-86-4

ACGIH TLV TWA: 0.5 ppm

TWAr 0.2 mg/m^

TWA: 3.5 mg/m^

OSHA PEL (vacated) TWA: 0,5 ppm {vacated) TWA: 5 mq/m^

(vacated) Ceifing: 0.5 ppm (vacated) Ceiling: 5 mglnr

Ceiling: 1 ppm Ceiling: Qmq/m^

(vacated) Ceiling; 5 mg/m^ Ceiling: 5 mg/m^

TWA: 3.5 mginf (vacated) TWA: 3.5 mg/m^

NIOSH IDLH TWA; 0.5 ppm TWA; 5 mq/m^

IDLH; 500 mg/m^

IDLH; 500 mg/m^ TWA: 1 mg/m^ STEL: 3 mq/m^

IDLH: 1750 mg/m' TWA; 0,1 mg/m^ TWA: 3.5 mq/m^


Pereonal Protective Equipment Eye/Face Protection Skin and Body Protection Respiratory Protection

Hygiene Measures

Showera Eyewash stations Ventilation systems.

Safety glasses with side-shiefds. Wear protective gloves/ctothing. Wear latex or Nitrite gloves. If exposure limits are exceeded or in-itation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Respiratoiy protection must be provided in accordance with current local regulations.

Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing and glov^, including the inside, before re-use. Handle in accordance with good industrial hygiene and safety practice.


Appearance Physical State Flash Point Autoignltion Temperatum

VisoDus liquid Black ViSOTus liquid >110°C / > 2 3 0 T No information avai

Odor pH Method Boiling Point/Range Flammabilft/ Limite in Air

Slight Not applicable Closed cup Not applicable No information

10. STABILITY AND REACTIVITY

AC-(§a51 Catalyst Revision Date December 23,2009

Stebility

Incompatible Products

Conditions to Avoid

Stable.

Adds. Strong reducing agents.

Excessive heat.

Hazardous Decomposition Products Carbon oxides. Nitrogen oxides (NOx). Thermal decomposition can lead to release of irritating gases and vapors.

Hazardous Reactions

Hazardous Polymerization

Acute Toxicity

Product Information

None under normal processing.

Hazardous polymeri^ion does not occur.


Product does not present an acute toxicity hazard based on known or supplied information.

Chemical Name JHydrogenated terphenyis_

Terphenyis

LD50 Oral J02.0P mg/kg_ lRatJ_

__ LD50 Dermal _ 6800 mg/kg ( Rabbit} 12500mgftg (Rabbit)

LC5Q Inliaiation^ 4.3mq/L7"Rat"}4h

Manganese dioxide 9000 mg/kg { Rat) Carbon black 15400 mgfl g (Rat) 3g/kg (Rabbit)

Chronic Toxicity

Chronic Toxicity

Carcinogenicity

Repeated or prolonged skin contact may cause sidn irritation and/or dermatitis and sensitization of susceptible persons.

The table below indicates whether each agency has listed any ingredient as a carcinc^en.

Cheirricai Name Carbon biack

ACGIH lARC Group 2 B ^ ^ |

NTP OSHA X

Legend: lARC: {International Agency for Research on Cancer) GnDup 2B - Possibly Carcinogenic to Humans

Target Organ Effects Liver, Kidney, Skin, Central nervous s retem (CNS)

Ecotoxicity The environmental Impact of this


LC^> 0.53 mgA-Onajrti^fffihus mykiss 96 h

LC50> 0.53 mg/L Prmephates promejas 96 h

AC-®251 Catalyst Revision Date December 23. 2009

Terphenyis

CartMn t^ack

EC50 = 0,02 mg/L 96 h LC50> 0.11 mg/L Lepomis maaochirus 96 h LC5O0-11 mqH.

OncoftiyncSius mykiss 96 h LC50>0.11 mg^

Pimeti^aies promelas 96 h 1

EC50> 0.11 mg/L 48 h

EC50 > 5600 mg/L 24 h

Persistence and Degradability No data is available on the product itself.

_Chemicai Name Manganese dioxide

LoflPow <0 20 "C

.13. DISPOSAL CONSIDERATIONS

Waste Disposal Method Dispose of in accordance with local regulations.

Contaminated Packaging Dispose of in accordance with local regulations.

Chemical Name

Hydrogenated terphenyis -61788-32-7

Terphenyis - 26140-60-3 Manganese diOJdde -1313-

13-9 Carbon black -1333-86-4

RCRA • Halogenated | RCRA - P Series Wastes Organic Compounds

i

RCRA - F Series Wastes RCRA - K Series Wastes

1

14. TRANSPORT INFORMATION

DOT UN-No

lATA

IMDG/IMO

Not regulated Not regulated

Not regulated

Not regulated


TSCA DSL EINECS/ELINCS ENCS lECSC KECL

Complies Complies Complies Does not Comply Complies

U.S. Federal Regyiations

SARA 313 Section 313 of Title ill of frie Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372:

AC-®251 Catalyst Revision Date Decemt>er23. 2009

Chemical Name

Manganese dksxide

CAS-No

1313-13-9

Weight %

45-50

SARA 313-Threshold 1 Values %

1.0

SARA 311/312 Hazard Categories Acute htealth Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard

No Yes No No No

Clean Water Act This product does not contain any sulastances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42).

Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) {see 40 CFR 61) This product contains the following substances which are listed hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act:.

Chemical Name

Manganese dioxide

CAS-No

1313-13-9

Weight %

^ 45-50

HAPS data ! VOC Chemicals

Present (includes any unique

chemKaf substance that contains

Manganese as part of its infrastructure)

Class 1 Ozone Depletors


CERCLA

U.S. State Regu la t ions

California Proposition 65 This product contains the foltow/ing Proposition 65 chemicals:

Chemical Name Carbon btack

CAS-No 1333-86-4

California Prop. 65 Carcinogen

Chemical Name Hydrogenated terphenyis

Terphenyis Manganese dioxide

Hiflassachusetts

Carbon black

New Jersey Pennsylvania (lilnois Rhode Island

In ternat iona l Regu la t ions

l^exlco - Grade Slight risk. Grade 1

Chen^cai Hams Hydrogenated terphenyis

Terphenyla Manganese diOKKJe

Gatbon biack

Carcinoiien Status Exposure Urr^te Mejdcs: T^A= G-5 ppm Mexico: TWA= 5 rssq/m^

Msjtico: Ceiling- 0.5 ppm Mexfco: TWA- 0.2 mg/m^ Mexico: TWA= 3,5 mg/rrfl Mexico: STEL= 7 mq/m^

Canada

Page 6 (7

AC-^51 Catalyst Revision Date December 23, 2009

This product has been classified in accordance with ttie hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.

WHMIS Hazard Class D2A Very toxic materials D28 Toxic materials

Chemical Name Manganese dioxide

NPRI X

16, OTHER INFORMATIOI

NFPA HMIS PPE Transport Symbol Not regulated

^ M 1

K j t t l ^ ^H .1 R«4Ctf^ty 0

Prepared By

Issuing Date

Revision Date

Revision Note

David Jordan Director of R&D

December 24, 2009

December 23, 2009

3.9.12. 16.

Disclaimer The infomiation provided on ttiis MSDS is correct to the best of our knoviHedge, information and belief at the date of its publication. The infomiation given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warrant or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text

AC-TECH. Material Safety Data Sheet

Issuing Date June 9, 2010 Revision Date June 8, 2010 Revision Number 06

1 . PRODUCT AND COMPANY IDENTIFICATION

Product Name

Product Code(s)

UN-No

Recommended Use

Company


AC-®137Red

AC-137 Red Adhesion Promoter

1170

Metal adhesion promoter.

Advanced Chemistry & Technology, Inc. 7341 Anaconda Avenue Garden Grove, CA 92841

714-373-2837 (8 AM to 5 PM Pacific)

Chemtrec 1-800-424-9300

2. HAZARDS IDENTIFICATION DANGER!

Appearance Red

Emergency Overview FLAMMABLE LIQUID AND VAPOR

Harmful by inhalation Harmful if swallowed

Physical State Liquid Odor Alcohol

OSHA Regulatory Status


Acute Toxicity Eyes Skin Inhalation

Ingestion

Chronic Effects

Main Symptoms

Aggravated Medical Conditions

Environmental Hazard


Skin contact, Inhalation, Eye contact.

Irritating to eyes. Vapor may cause irritation. Irritating to skin. Prolonged skin contact may defat the skin and produce dermatitis. Harmful by inhalation. Avoid breathing vapors or mists. Inhalation of vapors in high

concentration may cause irritation of respiratory system. Symptoms of overexposure are dizziness, headache, tiredness, nausea, unconsciousness, cessation of breathing. Harmful if swallowed.

Repeated or prolonged skin contact with the unexposed coating may cause skin irritation and/or dermatitis and sensitization of susceptible persons. See Section 11 for additional Toxicological Information.

Redness. Inhalation of high vapor concentrations may cause symptoms like headache,

dizziness, tiredness, nausea and vomiting.

Skin disorders. Liver disorders. Kidney disorders. Allergies.

See Section 12 for additional Ecological Information.

Page 1 / 9

AC-®137Red Revision Date June 8, 2010

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name Ethanol

Isopropyl alcohol Methyl alcohol

CAS-No 64-17-5 67-63-0 67-56-1

Weight % 70-80 2.5-10 2.5-10

4. FIRST AID MEASURES

Eye Contact

Skin Contact

Inhalation

Ingestion

Notes to Physician

Protection of First-aiders

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

Wash skin with soap and water.

Move to fresh air. Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult and you are trained. Call a physician immediately.

Immediate medical attention is required. Induce vomiting, but only if victim is fully conscious.

Treat symptomatically.

Remove all sources of ignition.

5. FIRE-FIGHTING MEASURES

Flammable Properties

Flash Point Method

Suitable Extinguishing Media

Uniform Fire Code

Hazardous Combustion Products

Explosion Data Sensitivity to Mechanical Impact

Specific Hazards Arising from the Chemical In the event of fire, cool tanks with water spray.

Protective Equipment and Precautions for Firefighters

Flammable.

13 "C I 55 T Closed cup

Use:. Water spray. Carbon dioxide {CO2). Dry chemical.

• Flammable Liquid: l-B

Carbon monoxide. Carbon dioxide (CO2), Aldehydes.

Not impact sensitive.

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

NFPA Health Hazard 2 Flammabiiity 3 Stability 0 Physical and Chemical Hazards N/A

Page 2 / 9


6. ACCIDENTAL RELEASE MEASURE!

Personal Precautions

Methods for Containment

Methods for Cleaning Up

Avoid contact with the skin and the eyes. Use personal protective equipment. Ensure adequate ventilation. Refer to Section 8.

Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see Section 13).

Pick up and transfer to properly labeled containers. Ground and bond containers when transferring material. Clean contaminated surface thoroughly. Prevent product from entering drains.

7. HANDLING AND STORAGE

Handling

Storage

Wear personal protective equipment. Keep away from open flames, hot surfaces and sources of ignition. Avoid contact with skin, eyes and clothing. Do not smoke. Remove and wash contaminated clothing before re-use.

Keep at temperatures below 28°C. Keep away from open flames, hot surfaces and sources of ignition. Keep out of the reach of children.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Chemical Name Ethanol 64-17-5

Isopropyl alcohol 67-63-0

Methyl alcohol 67-56-1

ACGIH TLV

= 400 ppm STEL TWA: 200 ppm

= 250 ppm STEL TWA: 200 ppm

OSHA PEL TWA: 1000 ppm

TWA: 1900 mg/m^ (vacated) TWA: 1000 ppm

(vacated) TWA: 1900 mq/m^ TWA: 400 ppm


(vacated) TWA: 980 mg/m^ (vacated) STEL: 1225 mg/m^

(vacated) STEL: 500 ppm TWA: 200 ppm


(vacated) TWA: 260 mg/m^ (vacated) STEL: 250 ppm

(vacated) STEL: 325 mg/m^ Skin

NIOSH IDLH IDLH: 3300 ppm 10% LEL

TWA: 1000 ppm TWA: 1900 mg/m^

IDLH: 2000 ppm 10% LEL TWA: 400 ppm

TWA: 980 mg/m^ STEL: 1225 mg/m^

STEL: 500 ppm

IDLH: 6000 ppm TWA: 200 ppm

TWA: 260 mg/m^ STEL: 325 mg/m^ STEL: 250 ppm


Personal Protective Equipment Eye/Face Protection SIdn and Body Protection Respiratory Protection

Hygiene Measures

Showers, eyewash stations, and ventilation systems.

Safety glasses with side-shields. If splashes are likely to occur, wear:. Face-shield. Wear protective gloves/clothing. Maintain adequate ventilation. When workers are facing concentrations above the

exposure limit they must use appropriate certified respirators.

Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing before re-use. General industrial hygiene practice.


Appearance Red Odor Alcohol

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Physical State

Flash Point Autoignltion Temperature

Explosion Limits Specific Gravity

Evaporation Rate Vapor Density Actual VOC (lb/gal) EPA VOC (g/l)

Liquid

13 "C / 55 "F No data available

No information available 0.82 g/cc

No information available No information available. 6.07 723

pH

Method

Boiling Point/Range

Flammabiiity Limits in Air

Solubility

Vapor Pressure Weight per Gallon (lbs) EPA VOC (lb/gal) Viscosity

No data available

Closed cup Not applicable

No information available

Soluble in aromatic hydrocarbons and ketones No information available 6.83 6.07 (Water)

Stability

Incompatible Products

Conditions to Avoid

10- STABILITY AND REACTIVITY

Stable under normal conditions.

Incompatible with strong acids and bases. Strong oxidizing agents.

Keep away from open flames, hot surfaces and sources of ignition. Keep away from children.

Hazardous Decomposition Products Carbon oxides. Aldehydes.

Hazardous Polymerization Hazardous polymerization does not occur.


Acute Toxicity

Product Information

Irritation

The product itself has not been tested. Harmful by inhalation. Product is harmful by ingestion.

Moderately irritating to eyes, skin and respiratory system.


Isopropyl alcohol

Methyl alcohol

LD50 Oral 7060 mg/kg ( Rat)

4396 mg/kg ( Rat)

5628 mg/kg ( Rat)

LD50 Dermal

12800 mg/kg (Rat) 12870 mg/kg (Rabbit) 15800 mg/kg (Rabbit)

LC50 Inhalation

72.6 mg/L ( Rat) 4 h

64000 ppm ( Rat) 4 h 83.2 mq/L ( Rat) 4 h

Chronic Toxicity

Chronic Toxicity

Carcinogenicity

Repeated or prolonged skin contact with the unexposed coating may cause skin irritation and/or dermatitis and sensitization of susceptible persons. See Section 11 for additional Toxicological Information.

The table below indicates whether each agency has listed any ingredient as a carcinogen.


ACGIH lARC Group 1

NTP Known

OSHA X

lARC: (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans

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Target Organ Effects Liver, Kidney, Skin, Central nervous system (CNS), Lungs.


Ecotoxicity Chemical Name

Ethanol

Isopropyl alcohol

Methyl alcohol

Toxicity to Algae

EC50> 1000 mg/L 72 h EC50> 1000 mg/L 96 h

Toxicity to Fish

LC50= 12900 mg/L Oncorhynchus mykiss 96 h

LC50= 14.2 mg/L Pimephales promelas 96 h

LC50= 61200 mg/L Pimephales promelas 96 h



LC50= 13200 mg/L Oncorhynchus mykiss 96 h


Microtox

EC50 = 34634 mg/L 30 min EC50 = 35470 mg/L 5 min

EC50 = 35390 mg/L 5 min

EC50 = 39000 mg/L 25 min EC50 = 40000 mg/L 15 min EC50 = 43000 mg/L 5 min

Daphnia Magna {Water Flea)

EC50= 10800 mg/L 24 h EC50 = 9268 mg/L 48 h

EC50 = 13299 mg/L 48 h



Loq Pow -0.32

= 0.05 25 °C = -0.77

13. DISPOSAL CONSIDERATIONS

Waste Disposal Method Dispose of contents/container in accordance with local regulation. Can be incinerated, when in compliance with local regulations. This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261).

Contaminated Packaging Dispose of in accordance with local regulations.



California Hazardous Waste Status Toxic; Ignitable Toxic, Ignitable Toxic; Ignitable

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I l 4 . TRANSPORT INFORMATION

DOT Proper Shipping Hazard Class UN-No Packing Group

lATA UN-No Proper Shipping Hazard Class Packing Group ERG Code

IMDG/IMO Proper Shipping Hazard Class UN-No Packing Group EmS No.

Name

Name

Name

Ethanol Solution 3 1170 II

1170 Ethanol Solution 3 II 127

Ethanol Solution 3.2 1170 II F-E, S-D

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1 5 . R E G U L A T O R Y I N F O R M A T I O N


TSCA DSL EINECS/ELINCS ENCS lECSC KECL PICCS AlCS

Listed Listed Listed Not Listed Listed Listed Listed Listed

U.S. Federal Regulations

SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical

or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

Chemical Name


CAS-No

67-63-0 67-56-1

Weight %

2.5-10 2.5-10

SARA 313-Threshold Values %

1.0 1.0

SARA 311/312 Hazard Categories Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard

Yes Yes Yes No No

Clean Water Act This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21

and 40 CFR 122.42). Component

Isopropyl alcohol 67-63-0(2.5-10)

CWA - Reportable Quantities

CWA - Toxic Pollutants CWA - Priority Pollutants

CWA - Hazardous Substances

X

Chemical Name

Methyl alcohol

CAS-No

67-56-1

Weight %

2.5-10

HAPS data

Present

VOC Chemicals

Group IV



CERCLA

Chemical Name Methyl alcohol

•Hazardous Substances RQs 5000 lb

Extremely IHazardous Substances RQs

U.S. state Regulat ions

California Proposition 65 This product does not contain any Proposition 65 chemicals.


CAS-No 64-17-5

California Prop. 65 Developmental

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Isopropyl alcohol

Methyl alcohol

IVIassachu setts X

X

X

New Jersey X

X

X

Pennsylvania X

X

X

Illinois

X

Rhode Island X

X

X

International Regulat ions

Mexico -Grade Moderate risl<, Grade 2


Isopropyl alcohol

Methyl alcohol

Carcinoqen Status Exposure Limits Mexico: TWA= 1900 mg/m^ Mexico: TWA= 1000 ppm Mexico: TWA= 400 ppm

Mexico: TWA= 980 mg/m^ Mexico: STEL= 1225 mg/m^

Mexico: STEL= 500 ppm Mexico: TWA= 200 ppm

Mexico: TWA= 260 mg/m^ Mexico: STEL= 250 ppm

Mexico: STEL= 310 mq/m^

Canada

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.

WHMIS Hazard Class B2 Flammable liquid

D2A Very toxic materials D2B Toxic materials

Chemical Name Isopropyl alcohol Methyl alcohol

NPRI X X

1 6 . O T H E R I N F O R M A T I O N

N F P A HMIS PPE T r a n s p o r t S y m b o l

Prepared By David Jordan Director of R&D

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AC-®137 Red Revision Date June 8, 2010

Issuing Date June 9, 2010

Revision Date June 8, 2010

Revision Note (M)SDS sections updated. 9. 16.

Disclaimer The information provided on this SDS is correct to the best of our l<nowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.

End of MSDS

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