material safety data sheet - home - south dakota solid ... · material safety data sheet date of...

4
ENVIRONMENTAL PROPUCTS, LLCl MATERIAL SAFETY DATA SHEET PRODUCT: I POSI-SHELL <1) SLURRY OSHA 29CFR 1910.1200 DATE OF PREPARATION: APRIL 2006 , ,[ Distributor's Name and Address: SECTION I .• IDENTITY Emergency Telelphone: Chemical Name land Synonyms: Generic Name: Trade Name: LSC Environmental Products, LLC 2183 Pennsylvania Avenue Apalachin, NY 13732 (607) 625-3050 Aqueous clay based slurry N/A Posi-Shell" SECTION II -- HAZARDOUS INGREDIENTS N/A SECTION III -. PHYSICAL DATA Boiling Point (OF) (Aqueous Portion): 212 (100° C) Vapor Pressure (rnrn. Hg): N/A Vapor Density (Air=1): N/A Solubility in Water: N/A Percent Volatile by Volume (%): N/A Specific Gravity (H20='1): 1.21 Evaporation Rate: N/A Appearance and Odor: Brown viscid liquid slurry with a smell similar to liquid clay and wet cement if Portland cement is used. Chemical family: Formula: SECTION IV -- CHEMICAL DATA N/A The major constituents are water (or landfill leachate), sodium rnont- mori/linite clay, cellulosic polymers, soda ash, P.E.T. fibers, iron oxide coloring, and optional Portland cement. Hazardous mixtures of other liquids, solids, or gases: N/A SECTION V -- FIRE AND EXPLOSION HAZARD DATA Non-explosive, Non-flammable

Upload: vuliem

Post on 25-Mar-2019

218 views

Category:

Documents


0 download

TRANSCRIPT

ENVIRONMENTALPROPUCTS, LLCl

MATERIAL SAFETY DATA SHEETPRODUCT: I

POSI-SHELL <1) SLURRY

OSHA 29CFR 1910.1200

DATE OF PREPARATION: APRIL 2006

, ,[Distributor's Name and Address:

SECTION I .• IDENTITY

Emergency Telelphone:Chemical Name land Synonyms:

Generic Name:

Trade Name:

LSC Environmental Products, LLC2183 Pennsylvania AvenueApalachin, NY 13732

(607) 625-3050Aqueous clay based slurry

N/A

Posi-Shell"

SECTION II -- HAZARDOUS INGREDIENTSN/A

SECTION III -. PHYSICAL DATABoiling Point (OF) (Aqueous Portion): 212 (100° C)

Vapor Pressure (rnrn. Hg): N/A

Vapor Density (Air=1): N/ASolubility in Water: N/A

Percent Volatile by Volume (%): N/A

Specific Gravity (H20='1): 1.21Evaporation Rate: N/AAppearance and Odor: Brown viscid liquid slurry with a smell

similar to liquid clay and wet cement ifPortland cement is used.

Chemical family:

Formula:

SECTION IV -- CHEMICAL DATAN/A

The major constituents are water (or landfill leachate), sodium rnont-mori/linite clay, cellulosic polymers, soda ash, P.E.T. fibers, iron oxidecoloring, and optional Portland cement.

Hazardous mixtures of other liquids,solids, or gases: N/A

SECTION V -- FIRE AND EXPLOSION HAZARD DATANon-explosive, Non-flammable

ENVIRONMENTAL

MATERIAL SAFETY DATA SHEETDate of Preparation: February 20'11

SECTION 1 -, IDENTIFICATIONSupplier: LSC Environmental Products, LLC

2183 Pennsylvania AveApalachin, NY 13732

Emergency Telephone: 800-800-7671 (LSC)Product/Trade Name: Posi-Shell Base MixChemical Name: SODIUM MONTMORILLONITE CLAY WITH ADDITIVES AND FIBERSGeneric Name: SMC with proprietary additives and Polyester Fibers

SECTION 2 - HAZARD(S) IDENTIFICATIONPOTENTIAL HEALTH EFFECTS (See Section 11 for toxicological data.)EYE:Mechanical irritant.Sf\lN:Possible drying resulting in dermatitis,INGESTION:No adverse effects,INHALATION:Acuie (short term) exposure to dust levels exceeding the PEL may cause irritation of respira-tory tract resulting in a dry cough, Chronic (long term) exposure to airborne SMC dust containing respirablesize (=10J-l) quarter particles, where respirable quartz particle levels are higher than TLVs, may lead to de-velopment of silicosis or other respiratory problems, Persistent dry cough and labored breathing upon exer-tion may be symptomatic,CARCINOGENICITY:SMC is not listed by ACGIH, IARC, NTP, or OSHA IARC, 1997, concludes that thereis sufficient evidence in humans for the carcinogenicity of inhaled crystalline silica from occupationalsources (IARC Class 1), that carcinogenicity was not detected in all industrial circumstances studied andthat carcinogenicity may depend on characteristics of the crystalline silica or on external factors affecting itsbiological activity, NTP classifies respirable crystalline silica as "known to be a human carcinogen" (NTP9th Report on Car-cinogens - 2000), ACGIH classifies crystalline silica quartz as a suspected human car-cinogen (A2).NOTE: Polyester Staple is a family of fiber products having similar hazard and physical property character-istics, The polymer immobilizes the constituents of the polymer system (delusterants, catalyst residues,etc.) which, therefore, present no likelihood of exposure under normal conditions of processing and han-dling

SECTION 3 - COMPOSITION I INFORMATION ON INGREDIENTSComposition I Information on Ingredients

Sodium Montmorillonite Clay with Additives CASt! -13'18-93-0Crystalline Silica (SiOl) as Quartz CAStt 14808-60-7Polyethylene terephthalaie polymer and one or CAS#25038-59-91110resurface finishes (or-ganic lubricants) - Polyester Staple

SECTION 4 - FIRST AID MEASURESEYE: Flush eyes with plenty of water until irritation ceases.Sf<IN: Wasil with soap and water until clean,INHALATION: Move to area free from dust. If symptoms of irritation persist, contact physician, Inhalationmay aggravate existing respiratory illness.

SECTION 5 - FIRE-FIGHTING MEASURESFLAMMABLE PROPERTIES

FLASH POINT: Not applicable,SPECIAL FIRE FIGHTING PROCEDURES: Not applicable,UNUSUAL FIRE AND EXPLOSION HAZARDS: None, Product will not support combustion,

SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIESBoiling Point (OF): N/AVapor Pressure (mm. Hg): N/AVapor Density (Air=1): N/ASolubility in Water: Insoluble, forms colloidal suspensionDensity (at 20° C): 55 Ibs/cu ft as productSpecific Gravity (H20=1): 2.45-2.55Melting Point: Approx. 1450° CEvaporation Rate (Butyl Acetate=1): N/ApH: 8-'10 (5% aqueous suspension)

SECTION 10 - STABILITY AND REACTIVITYCHEMICAL STABILlTY:Polyetllylene terephthalate is chemically stable and resistant to attack by oils, sol-vents, weak acids, and weak alkalis. SMC is stable.CONDITIONS TO AVOID: None.HAZARDOUS DECOMPOSITION PRODUCTS: None.HAZARDOUS POLYMERIZATION: None.INCOMPATIBILITY WITH OTHER MATERIALS: None.

SECTION 11 - TOXICOLOGICAL INFORMATION(See Section 3 for' Potential Health Effects. For detailed toxicological data, write or call the address or non-emergency number shown in Section 1). This product has not been fully evaluated for toxicological prop-erties. Preliminary evaluation of chemical components used in the finish and toxicological testing of thepolymer have given no indication that health problems would occur in normal handling and use.

SECTION 12 - ECOLOGICAL INFORMATION(For detailed Ecological data, write or call tile address.or non-emergency number shown in Section 1)ECOTOXICITY: Not expected to be acutely toxic.

SECTION 13 - DISPOSAL CONSIDERATIONS(See Section 15 for Regulatory Information)DISPOSAL: Product should be disposed of in accordance with applicable local, state, and federal regula-tions.

SECT/ON 14 - TRANSPORT INFORMATIONDEPARTMENT OF TRANSPORTATION (D.O,T.): This product is not regulated by D.O.T. when shippeddomestically by land.CANADIAN TOG INFORMATION:For TOG regulatory information, if required, consult transportation regu-lations, product shipping papers.

SECTION 15 - REGULATORY INFORMATION(Not meant to be all-inclusive-selected regulations represented)

NOTICE: The information herein is presented in good faith and believed to be accurate as of the effectivedate shown above. However, no warranty, express or implied is given. Regulatory requirements are sub-ject to change and may differ from one location to another; it is the buyer's responsibility to ensure that itsactivities comply with federal, state or provincial, and local laws. The following specific information ismade for tile purpose of complying with numerous federal, state or provincial, and local laws and regula-tions. See other sections for health and safety information.

U.S. REGULATIONSThese products are not classified as hazardous wastes under the Resource Conservation and RecoveryAct, and unless prohibited by state or local regulation, can be disposed of in a municipal landfill or inciner-ated. Any finish oils contained in plant wastewater should be biodegradable in conventional biologicalwastewater treatment systems.

SECTION 16 - OTHER INFORMATIONMSDS STATUS: Revised to '16 Section format.

OTHER FLAMMABILITY INFORMATION: Mechanical handling can cause formation of dusts. To reducethe potential for elust explosion, do not permit dust to accumulate. Material can be ignited by static dis-charge. Electrically ground all equipment. Do not permit dust to accumulate. Dust layers can be ignitedby spontaneous combustion or other ignition sources. When suspended in air dust can pose an explosionhazard.EXTINGUISHING MEDIA: Water, carbon dioxide and dry chemical.FIRE FIGHTING INSTRUCTIONS: Keep people away. Isolate fire area and deny unnecessary entry.Soak thoroughly with water to cool and prevent re-ignition. Cool surroundings with water to localize firezone. Hand held carbon dioxide or dry chemical hazard may result from forceful application of fire extin-guishing agents.PROTECTIVE EQUIPMENT FOR FIRE FIGHTERS: Wear positive-pressure self-contained breathing ap-paratus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, pants, boots, andgloves). If protective equipment is not available or not used, fight fire from a protected location or safe dis-tance.

ACCIDENTAL RELEASE MEASURES (See Section 15 for Regulatory Information)PROTECT PEOPLE: Material becomes slippery when wet.PROTECT THE ENVIRONMENT: Contain spilled material to prevent contamination of soil, surface wateror ground water.CLEANUP: Spills should be cleaned up immediately lIsing care to minimize generation of airborne dust.

HANDLING AND STORAGEHANDLING: Good housekeeping and controlling of dusts are necessary for safe handling of product. Nosmoking, open flames or sources of ignition in handling and storage area.STORAGE: Store in a dry place. Store below 90 F (32 C).

EXPOSURE CONTROLS / PERSONAL PROTECTIONENGINEERING CONTROLS: Provide general and / or local exhaust ventilation to control airborne levels below theexposure guidelines.PERSONAL PROTECTIVE EQUIPMENT

EYE / FACE PROTECTION: Use safety glasses. If there is a potential for exposure to particles, whichcould cause mechanical injury to the eye, wear chemical goggles.SKIN PROTECTION: No precautions other than clean body-covering clothing should be needed.RESPIRATORY PROTECTION: Atmospheric levels should be maintained below the exposure guideline.In dusty atmospheres, use an approved dust respirator.

EXPOSURE GUIDELINES: Hydroxopropyl methyl cellulose: IHG is 10 mg/m3.PHYSICAL AND CHEMICAL PROPERITESAPPEARANCE / PHYSICAL STATE: White to off-white free-flowing powder.

ODOR: Not available.VAPOR PRESSURE: Not applicable.VAPOR DENSITY: Not applicable.BOILING POINT: Not applicable.SOLUBILITY IN WATER I MISCIBILITY: Not applicable.SPECIFIC GRAVITY j OR DENSITY: Not applicable.

STABILITY AND REACTIVITYCHEMICAL STABILITY: Stable under recommended storage conditions. See Storage, Section 7.CONDITIONS TO AVOID: product can decompose at elevated temperatures.HAZARDOUS DECOMPOSITION PRODUCTS: Hazardous decomposition products depend upon tem-perature, air supply and the presence of other materials.HAZARDOUS POLYMERIZATION: Will not occur.INCOMPATIBILITY WITH OTHER MATERIALS: Avoid contact with oxidizing materials. Avoid contact withstrong acids, strong bases.

TOXICOLOGICAL INFORMATION (See Section 3 for Potential Health Effects. For detailed toxicological data,write Or call the address or non-emergency number shown in Section 1)

INGESTION: The oral LD50 for rats is >'10,000 Illg/kg.MUTAGENICITY: For rnethyicellulose, a similar cellulosic: in vitro mutagenicity studies were negative;anirnal mutaqenicity studies were negative.