material safety data sheets - olde mill swim...

Material Safety Data Sheets Olde Mill Swim Club

Kevin Kendall May 2013

TABLE OF CONTENTS

Section 1 – chemicals typically provided by the management company & delivered by Amato Industries

• Sodium Hypochlorite Chlorine Bleach

• Muriatic Acid Section 2 – chemicals provided by Olde Mill Swim Club, typically purchased at Leslie’s Swimming Pool Supplies

• Calcium Hypochlorite Leslie’s Power Powder Pro

• Sodium Sulfite Leslie’s Chlorine Neutralizer

• Cyanuric Acid Leslie’s Conditioner

• Sodium Bicarbonate (baking soda) Leslie’s Alkalinity Up

• Calcium Chloride Leslie’s Hardness Plus

• Sodium Carbonate Leslie’s Soda Ash

• Algaecide Leslie’s Algae Control

• Algaecide Leslie’s Copper Algaecide

• Lanthanum Sulfate & Chloride Phos Free phosphate remover

• Enzymes Pool Perfect water cleaning compound Section 3 – testing reagents from Taylor Technologies, provided by Olde Mill Swim Club

• DPD Reagent #1 R-0001



• pH Indicator Solution (Phenol Red) R-0004

• Acid Demand Reagent (ADR) R-0005

• Base Demand Reagent (BDR) R-0006

• Thiosulfate N/10 R-0007

• Total Alkalinity Indicator R-0008

• Sulfuric Acid – .12N R-0009

• Calcium Buffer R-0010

• Calcium Indicator Liquid R-0011L

• Hardness Reagent R-0012

• Cyanuric Acid Reagent R-0013

• Phosphate Reagent #1 R-0980

• Phosphate Reagent #2 R-0981

• Buffer Solution, pH 7.6 R-7062

• CYA Standard 50 ppm R-7065

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Phone: (973) 589-0700

86 North Hackensack Avenue, South Kearny, New Jersey 07032-4673 Fax: (973) 589-4866

MATERIAL SAFETY DATA SHEET

Sodium Hypochlorite MSDS Revision C - 01 July 2011 Page 1 of 14

(This MSDS follows the ANSI Z400.1-1993 format)

SODIUM HYPOCHLORITE (15% by volume – 12.5% by weight)

MSDS NUMBER: KCC – HYPO - 001 MSDS DATE: July 01, 2011 24 HOUR EMERGENCY PHONE NUMBER: (973) 589-0700

Alt. (551) 200-2751 CHEMTREC – (800) 424-9300

SECTION 1 – CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Name: Hypochlorite Solution Chemical Name: Sodium Hypochlorite CAS Number: 7681-52-9 Common Names: Chlorine Bleach, Soda Bleach Chemical Formula: NaOCl Manufacturer: Kuehne Chemical Company, Inc. 86 North Hackensack Avenue South Kearny, New Jersey 07032-4673 (973) 589-0700 Fax: (973) 589-4866

SECTION 2 – COMPOSITION, INFORMATION OR INGREDIENTS

CAS Number Name Common Names 7732-18-5 Water Water Percentage Exposure Limits VOL. 85.75 – 81.25 PEL: Not Established WT. 84.37 – 88.13 TLV: Not Established STEL: Not Established IDLH: Not Established

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SECTION 2 – COMPOSITION, INFORMATION OR INGREDIENTS (Continued)

CAS Number Name Common Names 7681-52-9 Hypochlorous Acid, Sodium Salt Sodium Hypochlorite Percentage Exposure Limits VOL. 14.25 – 18.75 PEL: 1 ppm ceiling (as Cl2) WT: 11.87 – 15.63 TLV: 1 ppm TWA (as Cl2) STEL: 1 ppm ceiling (as Cl2) IDLH: Not Established Listed on: - The EINECS inventory, or in compliance with the inventory.

- The TSCA inventory. - The AICS inventory, or in compliance with the inventory. - The DSL list. - The ENCS inventory, or in compliance with the inventory. - The KECI inventory, or in compliance with the inventory. - The PICCS inventory, or in compliance with the inventory. - The IECSC inventory, or in compliance with the inventory. - The NZIoC inventory, or in compliance with the inventory.

CAS Number Name Common Names 1310-73-2 Sodium Hydroxide (NaOH) Caustic Soda, Lye Percentage Exposure Limits VOL. 1 PEL: 2 ppm ceiling WT. 1 TLV: 2 ppm ceiling STEL: Not Established IDLH: 10 ppm Listed on: - The TSCA Inventory, or in compliance with the inventory.

- PA Requirement - 3% or greater. - NJ Requirement - 1% or greater

CAS Number Name Common Names 7647-14-5 Sodium Chloride (NaCl) Salt Percentage Exposure Limits VOL. >1 PEL: Not Established WT. >1 TLV: Not Established STEL: Not Established IDLH: Not Established


SECTION 2 – COMPOSITION, INFORMATION OR INGREDIENTS (Continued)

CAS Number Name Common Names 497-19-8 Carbonic Acid Disodium Salt Carbonic Acid Sodium Salt Percentage Exposure Limits VOL. >1 PEL: Not Established WT. >1 TLV: Not Established STEL: Not Established IDLH: Not Established

SECTION 3 – HAZARD IDENTIFICATION

HMIS HAZARD RATINGS NFPA HAZARD RATINGS

Based on Nat’l Paint & Coatings Association HMIS system Chemical not listed. Ratings based on NFPA guidelines

Effects of Overexposure Acute: Inhalation – Inhalation of vapors is irritating to the respiratory system,

may cause throat pain and cough, severe respiratory tract irritation and pulmonary edema.

Eyes – May cause severe irritation, burns, and/or corrosion. May

cause vision impairment, corneal damage and blurred vision. Skin – May cause severe irritation and burns or dermatitis. Prolonged

skin exposure may cause destruction of the dermis with impairment of the skin to regenerate at site of contact.

Ingestion – Ingestion of high concentrations may cause injuries to,

liver, kidneys, central nervous system and gastrointestinal tract pain and inflammation, burns and perforation of the esophagus or stomach.

Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea, circulatory collapse, confusion, delirium and coma.

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SECTION 3 – HAZARD IDENTIFICATION (Continued)

Chronic: Repeated inhalation exposure may cause impairment of lung function

and permanent lung damage. Effects from chronic skin exposure would be similar to those from single exposure except for effects secondary to tissue destruction.

Note: Corrosive and strongly irritating to the eyes, skin, and respiratory tract.

Inhalation of fumes may cause pulmonary edema. Ingestion may cause burns to the mouth and digestive tract, and abdominal distress.

Appearance: Colorless to light yellow-green liquid Routes of Entry: Inhalation, Eye Contact, Skin, Ingestion Target Organs: Eyes, Skin, Respiratory Tract, and Gastrointestinal Tract. Cancer Information: This product has not been listed as carcinogenic by the following agencies: IARC, NTP, and OSHA Mutagenicity: Sodium hypochlorite has tested positive in in-vitro test systems and negative in in- vivo test systems. These results are consistent with other germicides. Medical Conditions Aggravated by Exposure: Asthma, Heart disease, Respiratory disorder

SECTION 4 – FIRST AID MEASURES

Inhalation: Remove to fresh air. If breathing is difficult, have qualified person

administer oxygen. If respiration stops, give mouth-to-mouth resuscitation. SEEK MEDICAL ATTENTION IMMEDIATELY.

Eyes: OBJECT IS TO FLUSH MATERIAL OUT IMMEDIATELY AND THEN

SEEK MEDICAL ATTENTION. IMMEDIATELY flush eyes with a directed stream of water for at least 15 minutes while forcibly holding eyelids apart to ensure complete irrigation of all eye and lid tissue. Washing eyes within one (1) minute is essential to achieve maximum effectiveness. SEEK MEDICAL ATTENTION IMMEDIATELY.

Skin: Flush thoroughly with cool water under shower while removing

contaminated clothing and shoes. Discard non-rubber shoes. Wash clothing before reuse. Continue to flush until medical attention arrives. SEEK MEDICAL ATTENTION IMMEDIATELY.

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SECTION 4 – FIRST AID MEASURES (Continued)

Ingestion: NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS

PERSON. If swallowed. DO NOT INDUCE VOMITING. Give large quantities of milk. If this is not available, give large quantities of water. If vomiting occurs spontaneously, keep airway clear and give more milk or water. SEEK MEDICAL ATTENTION IMMEDIATELY. Avoid vomiting, lavage or acidic antidotes.

Note to Physician Sodium Hypochlorite is an alkaline corrosive. For exposure by ingestion do not use emesis, lavage or acidic antidotes. Dilute immediately by giving milk, melted Ice cream, beaten egg white, starch paste or antacids such as milk of magnesia, aluminum hydroxide gel or magnesium trisilicate gel. Avoid sodium bicarbonate because of carbon dioxide release. Sodium thiosulfate solution may prove beneficial by reducing unreacted material.

SECTION 5 – FIRE-FIGHTING MEASURES

Flash Point: N/A Auto-ignition Temperature: N/A Flammable Limits in Air - % by Volume - Upper: N/A Lower: N/A Sensitivity to Mechanical Impact: Not Sensitive Sensitivity to Static Discharge: Not Sensitive Extinguishing Media Use water spray, fog, foam, dry chemical, or carbon dioxide or agents suitable for materials in surrounding fire. Do not use Mono Ammonium Phosphate (MAP) type extinguishers directly on this product. Fire Fighting Procedures Use self-contained breathing apparatus and full protective equipment. Acid contamination will produce very irritating fumes similar to chlorine. Fire and Explosion Hazard Sodium Hypochlorite or its solutions decompose when heated. Decomposition products may cause containers to rupture or explode. Vigorous reaction is possible with organic materials or oxidizing agents and may result in fire, may release toxic gases.

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SECTION 6 – ACCIDENTAL RELEASE MEASURES

Steps to be Taken if Material is Released or Spilled Contain the spilled material in the smallest possible area. Do not allow spilled material to enter sewers, streams or unpaved land. Flush with water to dilute as much as possible and pump into polyethylene containers for disposal. Avoid heat and contamination with acid materials. Do not use combustible materials such as sawdust to absorb Sodium Hypochlorite Solution. Ventilation Requirements Provide good general room ventilation plus local exhaust at points of emission.

SECTION 7 – HANDLING AND STORAGE

Handling Precautions Do not store adjacent to chemicals that may react if spillage occurs. Comply with DOT regulations when shipped. If closed containers become heated, vent to release decomposition products (mainly oxygen under normal decomposition). Do not mix or contaminate with ammonia, hydrocarbons, acids, alcohols or ethers. Do Not Reuse Containers: Product residues may remain in containers. All labeled precautions must be observed. Dispose of container in a manner meeting government regulations.

SECTION 8 – EXPOSURE CONTROLS AND PERSONAL PROTECTION

Specific Personal Protective Equipment Respiratory: NIOSH/MSHA approved respirator with N95 (dust, fume, mist)

cartridges may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Acid gas cartridges may be required if decomposition products are present. A respiratory protection program that meets 29 CFR 1910.134 must be followed whenever workplace conditions warrant use of a respirator.

Eye: Wear chemical safety goggles plus full face shield to protect against

splashing when appropriate. Gloves: Wear impervious gloves such as rubber, neoprene or vinyl. Other: Wear impervious protective clothing including rubber safety shoes.

Eye wash facility and emergency shower should be in close proximity.


SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Colorless to light yellow-green Odor: Pungent chlorine like odor Physical State: Liquid pH: 12 @ 100 g/L Vapor Pressure: Temperature mm Hg PSIA 48.2 oF (9 oC) 3.7 0.071 60.8 oF (16 oC) 8.0 0.15 68.0 oF (20 oC) 12.1 0.23 89.6 oF (32 oC) 31.1 0.60 118.4 oF (48 oC) 100.0 1.93 Boiling Point: Decomposes above 230 oF (110 oC) (@760 mm Hg) Freezing/Melting Point: Weight % Temperature 10 7 oF -13.9 oC 12 - 3 oF -19.4 oC 14 - 14 oF -25.6 oC Solubility in Water: 100% (by weight) Specific Gravity: 1.190 - 1.215 (H2O = 1) Odor Threshold (ppm): 0.9 ppm approximate

SECTION 10 – STABILITY AND REACTIVITY

Conditions Contributing to Instability Strong Oxidizer, stability decreases with concentration, heat, light, decrease in pH and contamination by metals. Incompatibility Avoid contamination with heavy metals, reducing agents, organics, ether, ammonia, and acids.


SECTION 10 – STABILITY AND REACTIVITY (Continued)

Reacts With: Acids – A serious chlorine release can result. Ammonia Compounds – Both toxic and hazardous gases can be formed. Organic Compounds – May react violently with many organic compounds including greases, oils, fuels, etc. Care must be taken to avoid contact with these types of compounds unless you are certain they are compatible or adequate engineering controls and personal protective equipment (PPE) are employed. Other Chlorinating Compounds – Care must be taken when storing or using with other chlorinating compounds. In swimming pool applications, never attempt to pre-blend with concentrated forms of any chemicals including other chlorinating compounds. Concentrated forms of these compounds may react violently. Hazardous Decomposition Products: Acid fumes, Hydrogen chloride and Chlorine. Hazardous Polymerization: Material is not known to polymerize.

SECTION 11 – TOXICOLOGICAL INFORMATION

CAS Number Name Common Names 7681-52-9 Sodium Hypochlorite Bleach Acute Oral LD50: (rat) 3-5 mg/kg Primary Skin Irritation: (rabbit) > 2 mg/kg The toxicity and corrosivity of Sodium Hypochlorite is a function of concentration. Industrial grades of higher concentrations than household bleach are more toxic and corrosive.

SECTION 12 – ECOLOGICAL INFORMATION

Aquatic Ecotox Data Fish: LC50 (96 hr.) (Bluegill sunfish) 2.90 mg/L LC50 (96 hr.) (Fathead minnow) 1.40 mg/L LC50 (0.5 hr.) (Rainbow trout) 0.90 mg/L Biodegradation: This material is inorganic and not subject to biodegradation.

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SECTION 12 – ECOLOGICAL INFORMATION (Continued)

Persistence: This material is believed not to persist in the environment. Bioconcentration: This material is not expected to bioconcentrate in organisms. NOTE: This material is harmful to fish, invertebrates, amphibians, and plants.

SECTION 13 – DISPOSAL CONSIDERATIONS

Waste Disposal Method Reduce with agents such as bisulfites or ferrous salt solutions. Some heat will be produced. Keep on alkaline side and dilute with copious amounts of water. Main end product is salt water. Comply with all applicable governmental regulations. Product Disposal Product should be completely removed from containers. Material that cannot be used or chemically reprocessed should be disposed of in a manner meeting government regulations.

SECTION 14 – TRANSPORT INFORMATION

DOT Proper Shipping Name: Hypochlorite Solutions DOT Hazard Class: 8 DOT ID Number: UN1791 DOT Packing Group: II DOT Hazardous Substance: RQ 100# (Sodium Hypochlorite) DOT Marine Pollutant: N/A Additional Description: N/A


SECTION 15 – REGULATORY INFORMATION

U.S. Federal Regulations Section 311 of The Clean Water Act lists this product as a hazardous substance, which If discharged to water, may require immediate response to mitigate danger to public health and welfare. Spills of 100 pounds or more must be reported to the National Response Center at the following number: 1-800-424-8802 Material is contained on a composite list as required under 101 (14) of CERCLA. Sodium Hypochlorite Solution is regulated by the USEPA under the Federal Insecticide, Fungicide and Rodenticide Act (FIFRA) as a pesticide product. 12.5% by weight Sodium Hypochlorite Solution produced by Kuehne Chemical Company, Inc. is registered with the USEPA under Registration Number 35317-20001. OSHA: This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200) (US). TSCA (Toxic Substances Control Act): This product is not subject to export notification. Other Standards NSF Certification: This product has been classified as an approved drinking water

treatment chemical under ANSI/NSF Standard 60 by Underwriters Laboratories (reference number: MH17612).

USDA Approvals: B-1, D-2, L-1, Q-4 & Fruit and Vegetable washing compounds.

SECTION 16 – OTHER INFORMATION

Prepared By: Kuehne Company’s Environmental, Safety & Security Department Revision C – 01 July 2011 For additional non-emergency health, safety or environmental information, telephone: (973) 589 - 0700 or write to:

Kuehne Chemical Company, Inc. 86 N. Hackensack Avenue

South Kearny, New Jersey 07032-4673


SECTION 16 – OTHER INFORMATION (Continued)

MSDS Legend: ACGIH American Conference of Governmental Industrial Hygienists CAS Chemical Abstracts Service Registry Number CEILING Ceiling Limit (15 Minutes) OSHA Occupational Safety and Health Administration PEL Permissible Exposure Limit (OSHA) STEL Short Term Exposure Limit (15 Minutes) TLV Threshold Limit Value (ACGIH) TWA Time Weighted Average (8 Hours) IMPORTANT: The information contained herein is offered only as a guide to the handling of this specific material and has been prepared in good faith by technically knowledgeable personnel. It is not intended to be all-inclusive and the manner and conditions of use and handling may involve other and additional considerations. The information presented herein, while not guaranteed, was prepared by competent technical personnel and is true and accurate to the best of our knowledge. NO WARRANTY OF MERCHANTABILITY OR FITNESS FOR PURPOSE, OR OF ANY OTHER KIND, EXPRESS OR IMPLIED, IS MADE REGARDING PERFORMANCE, STABILITY OR OTHERWISE. This information is not intended to be all-inclusive as to the manner and conditions of handling and storage. Other factors may involve other or use additional safety or performance considerations. While our technical personnel will be happy to respond to questions regarding safe handling and use procedures, safe handling and use remains the responsibility of the customer. No suggestions for use are intended as, and nothing herein shall be construed as a recommendation to infringe any existing patents or violate any federal, state or local laws, rules, regulations or ordinances. No warranty of any kind is given or implied and Kuehne Chemical Company, Inc. will not be liable for any damages, losses, injuries or consequential damages that may result from the use of or reliance on any information contained herein. This Material Safety Data Sheet (MSDS) covers the following materials: Sodium Hypochlorite - Liquid: 15% by volume – 12.5% by weight REFERENCES:

- American National Standard, Z400.1-1993 - Chlorine Institute Pamphlet 96 (Sodium Hypochlorite Manual), Edition 3, Revision 1, November, 2008. - National Institute for Occupational Safety and Health, US Dept. of Health & Human Services, Cincinnati, June, 1994. - Supplier's Material Safety Data Sheets. - Windholz, Martha, Ed, The Merck Index, 11th ed., Merck and Co, Inc., Rahway, New Jersey, 1989.


WARNING LABEL INFORMATION

Active Ingredient: Sodium Hypochlorite (NaOCl) 11.87 – 15.63 % (by weight) Other Ingredients 84.37 – 84.37 %

Total 100.0 %

KEEP OUT OF REACH OF CHILDREN

DANGER

FIRST AID IF INHALED: Move to fresh air. If person is not breathing, call 911 or an ambulance then give artificial respiration, preferably month-to-mouth if possible. Call a poison control center or doctor for further treatment advice. IF IN EYES: Hold eye open and rinse slowly and gently with water for 15 – 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue to rinse eye. Call a poison control center or doctor for treatment advice. IF ON SKIN OR CLOTHING: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15 – 20 minutes. Call a poison control center or doctor for treatment advice. IF SWALLOWED: Call a poison control center or doctor for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person. NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage. HOT LINE NUMBER: 1-800-POISON-1 Have product container or label with you when calling a poison control center or doctor, or going for treatment.


PRECAUTIONARY STATEMENTS HAZARDOUS TO HUMANS AND DOMESTIC ANIMALS

DANGER: Corrosive may cause severe skin and eye irritation or chemical burns to broken skin. Causes eye damage. Wear safety glasses or goggles and rubber gloves when handling this product. Wash after handling. Avoid breathing vapors. Vacate poorly ventilated areas as soon as possible. Do not return until strong odors have dissipated. Environmental Hazards: This pesticide is toxic to fish and aquatic organisms. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans, or public waters unless this product is specifically identified and addressed in an NPDES permit. Do not discharge effluent containing this product to sewer systems without previously notifying the sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA. Physical and Chemical Hazards: STRONG OXIDIZING AGENT. Mix only with water according to label directions. Mixing this product with chemicals (e.g. ammonia, acids, detergents, etc.) or organic matter (e.g. urine, feces, etc.) will release chlorine gas, which is irritating to eyes, lungs and mucous membranes.

DIRECTION FOR USE IT IS A VIOLATION OF FEDERAL LAW TO USE THIS PRODUCT IN A MANNER INCONSISTENT WITH ITS LABELING. Re-formulators and Re-packagers of this product must obtain their own registrations from the United States Environmental Protection Agency (USEPA). For manufacturing use in the formation of end-use Products NOTE: This product degrades with age. Use a Chlorine test kit and increase dosage as necessary, to obtain the required level of available Chlorine. For specific use directions, see KUEHNE Circular for each particular application. CIRCULAR NUMBER K586A: sanitizers of surfaces (wooden butcher blocks, stainless steel tops, concrete floors, tile walls) CIRCULAR NUMBER K586B: COMMERCIAL LAUNDRY SANITIZERS CIRCULAR NUMBER K586C: AGRICULTURAL USES CIRCULAR NUMBER K586D: DISINFECTION OF DRINKING WATER (EMERGENCY/PUBLIC/INDIVIDUAL SYSTEMS)

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CIRCULAR NUMBER K586E: DISINFECTION OF NONPOROUS NON-FOOD CONTACT SURFACES CIRCULAR NUMBER K586F: SEWAGE & WASTEWATER EFFLUENT TREATMENT CIRCULAR NUMBER K586G: COOLING TOWER & EVAPORATIVE CONDENSER WATER STORAGE AND DISPOSAL Store this product in a cool dry area away from direct sunlight and heat to prevent deterioration. In case of a spill, flood areas with large quantities of water. Product or rinsates that cannot be used should be diluted with water before disposal in a sanitary sewer. Do not contaminate food or feed by storage, disposal or cleaning of equipment. Large storage containers should be rinsed thoroughly with water and returned to manufacturer for reconditioning. Large storage containers should be thoroughly rinsed with water before reuse. IN CASE OF FIRE: Use self-contained breathing apparatus and full protective equipment. Use water spray, foam, dry chemical or C02. Fire may liberate toxic gases. SPILL OR LEAKAGE: Get protective equipment. Contain spill and pump into marked container for reclamation for disposal. Avoid discharges to sewers and streams. Spills of 100 pounds or more must be reported to the National Response Center at the following number:

1-800-424-8802 State and local regulations may have additional reporting requirements, check with the proper state and local authorities. Wear neoprene or rubber gloves.

IN CASE OF CHEMICAL EMERGENCIES CALL: 24 HOUR EMERGENCY PHONE (973) 589-0700

Alt. (551) 200-2751

Material Safety Data Sheet REAGENT CHEMICAL & RESEARCH, INC.May be used to comply with 115 US Hwy 202 Ringoes, NJ 08551OSHA's Hazard Communication Standard29 CFR 1910.1200. Standard must be consulted for specific requirements. REVISED DATE: 1/1/2006 VALID UNTIL 1/1/2011IDENTITY Note: Blank spaces are not permitted. If any item is not applicable, or no

Hydrochloric Acid, 20o Baume information is available, the space must be marked to indicate that.

Section I - Product InformationProduct Name CAS #Hydrochloric Acid 7647-01-0Synonym Chemical FormulaMuriatic Acid HClChemical Name Chemical FamilyHydrochloric Acid Solution Inorganic Acid

Section II - Manufacturers InformationManufacturers Name AddressReagent Chemical & Research, Inc. 124 River Road Middlesex, NJ 08846Emergency Contact Country Robert Dritschel United StatesEmergency Telephone Emergency Telephone #21-409-962-5769 CHEMTREC 1-800-424-9300

Section III - Ingredients/Regulatory InformationSubstance Description Percent CAS #Hydrogen Chloride 31.45 - 33.30 7647-01-0

Water 66.70 - 68.55 7732-18-5EXPOSURE LIMITS/REGULATORY INFORMATIONSubstance PEL TLV STEL TWA CEILING

Hydrogen Chloride C-7 mg/m3 C-5 ppm 50 ppm N/D 5 ppm

Water N/D N/D N/D N/D N/D

N/D - Not Determined C = Ceiling Level

Section IV - Hazards IdentificationAppearance & Odor Statement of HazardsClear/Pale Yellow Liquid/Pungent Odor Severe and painful burns upon contactPrimary Route of ExposureSkin, eye and inhalation contact are the primary routes of exposure to this productInhalation Acute Exposure EffectsInhalation of excessive concentrations of Hydrogen Chloride vapors immediately

produces severe irritation of the upper respiratory tract; resulting in coughing,

burning of the throat, and a choking sensation. Reactions encountered in man have

usually been limited to inflammation occasional ulceration of the nose, throat and

larynx. If inhaled deeply, edema of the lungs may occur.Skin Contact Acute Exposure EffectsConcentrated solutions are destructive to clothing and on contact with skin, causes

severe burns unless promptly washed off. Repeated skin contact with dilute solutions

may lead to the development of dermatitis. Exposure to the concentrated vapors of

Hydrogen Chloride may also result in burns and dermatitis.

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Section IV - Hazards Identification (continued)Eye Contact Acute Exposure EffectsContact of the eyes with Hydrogen Chloride, either as a gas or in solution, rapidly

causes severe irritation and painful burns of the eyes and eyelids. If the acid is not

quickly removed by thorough irrigation with water, there may be prolonged or permanent

visual impairment or total loss of sight.Ingestion Acute Exposure EffectsWhen concentrated Hydrochloric Acid is swallowed, it causes severe burns of the

mucous membranes of the mouth, esophagus and stomach. The lips and mouth usually

turn white, and later brown. There is pain in the throat and stomach, difficulty in

swallowing, intense thirst, nausea and in severe cases, collapse and unconsciousness.Fire and Explosion HazardsNon-flammable, but Hydrochloric Acid reacts with all metals, except gold and

platinum, with rapid evolution of Hydrogen which is flammable and explosive in air.

Firefighters exposed to Hydrochloric Acid vapors should wear Scott Air-Pak, or

equivalent. Hydrogen Chloride vapors are extremely irritating to the respiratory

tract and may cause breathing difficulty.CarcinogenicityIARC …No OSHA …No ACGIH …No

Section V - First Aid MeasuresGeneral If a known exposure occurs or is suspected, immediately initiate the recommended

procedures below. Simultaneously contact a physician, or the nearest Poison Control

Center. Inform the person contacted of the type and extent of exposure, describe the

victim's symptoms and follow the advice given. For additional information, call day or

night, Reagent Chemical (409) 962-5769 or Chemtrec (800) 424-9300.InhalationRemove from contaminated atmosphere. If breathing has ceased, clear the victim's

airway and start mouth-to-mouth artificial respiration, which may be supplemented

by the use of a bag-mask respirator, or a manually-triggered, oxygen supply capable

of delivering 1 liter/second or more. If the victim is breathing, oxygen may be

administered from a demand-type or continuous-flow inhalator, preferably with a

physician's advice. Contact a physician immediately.Eye ContactImmediately flush the eyes with large quantities of running water for 15 minutes.

Hold the eyelids apart during the flushing to ensure rinsing of the entire surface of

the eyes and lids with water. DO NOT attempt to neutralize with chemical agents.

Obtain medical attention as soon as possible. Oils or ointments should not be used.

Continue the flushing for an additional 15 minutes if the physician is not available.

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Section V - First Aid Measures (continued)Skin ContactImmediately remove contaminated clothing under a safety shower. Flush all

affected areas with large amounts of water for 15 minutes. DO NOT attempt to

neutralize with chemical agents. Obtain medical advice.IngestionDO NOT induce vomiting. Immediately give large quantities of water or milk, if

available. If vomiting does occur, give fluids again. Never give anything by mouth

to an unconscious person. Call a physician of the nearest Poison Control Center.Medical Conditions Generally Aggravated by ExposuHydrogen Chloride will aggravate breathing disordersNote to PhysicianAttending Physician should treat exposed patients symptomatically

Section VI - Fire Fighting MeasuresFlash Point Flash MethodN.A. N.A.Extinguishing MethodNot ApplicableUnusual Fire and Explosion HazardsNon-flammable, but Hydrochloric Acid reacts with metals.Special Firefighting ProceduresNon-flammable, but Hydrochloric Acid reacts with all metals, except gold and

platinum, with rapid evolution of Hydrogen which is flammable and explosive in air.

Firefighters exposed to Hydrochloric Acid vapors should wear Scott Air-Pak, or

equivalent. Hydrogen Chloride vapors are extremely irritating to the respiratory

tract and may cause breathing difficulty.

Section VII - Accidental Release MeasuresSteps to be Taken in Case Material is Released or SpilleSpills or discharges into the environment involving large quantities of Hydrochloric

Acid should be controlled and cleaned-up according to a pre-determined, affirmative

written Spill Prevention and Control Program. For assistance in developing a SPCP

contact your nearest Reagent Sales Office.

Spills should be handled immediately by neutralization and dilution of the spilled

product by the use of Soda Ash (Sodium Carbonate), Lime (Calcium Hydroxide), or

Limestone (Calcium Carbonate) with large amounts of water. For an interior (inside

a closed space) spill be aware that the use of Soda Ash, Lime and Limestone will

evolve heat and carbon dioxide and that ample ventilation must be provided.Waste DisposalUnder Federal RCRA, it is the responsibility of the user of products to determine,

at the time of disposal, whether the product falls under RCRA as a hazardous waste.

This is because product uses, transformations, mixtures, etc. may render the

resulting end-product hazardous.Container DisposaContainers should be cleaned of residual product before disposal. Empty containers

should be disposed of in accordance with all applicable laws and regulations.

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Section VII - Accidental Release Measures (continued)Precautions to be Taken in Handling and StoragMake sure all personnel involved in housekeeping and spill clean-up follow good

Industrial Hygiene practices and wear proper protective equipment.

Section VIII - Handling/Storage/TransportationHandlingChemical goggles and full face shield must be worn at all times by personnel

exposed to or handling Hydrochloric Acid. The use of a NIOSH approved cartridge

respirator or a Scott Air-Pak should be used by all personnel exposed.StorageStore containers in a cool, dry location away from direct sunlight, sources of

intense heat, or where freezing may occur. Store material in acid-proof container.

Keep container tightly closed when not in use. Keep container away from incompatible

materials. All loading, unloading, and storage equipment must be inspected prior to

any transfer operations are initiated.General CommentsImpervious clothing, gloves, footwear and head gear must be worn at all times

by personnel exposed to or handling Hydrochloric Acid.

Section IX - Exposure Controls/Personal ProtectionRespiratory Protection (Specify TypeMaintain airborne contaminate levels below listed guidelines. Use with adequate

ventilation. Use a mechanical fan or vent area to scrubber.Ventilation Local Exhaust Special

If PEL exceeded Vent fumes to appropriate scrubberMechanical (General OtherIf PEL exceeded Not Applicable

Skin ProtectionWear neoprene rubber gloves to minimize skin contact.Eye ProtectionSplash goggles or safety glasses. Face shields are recommended.Other ProtectionUse body protection appropriate for task. An apron or other impermeable body

protection is suggested. Full body chemical protection is recommended for

emergency response procedures.Applicable Exposure LimitsOther than any exposure limits which may be displayed in Section 3, there are no other

known exposure limits applicable to this product or its components.

Section X - Physical and Chemical PropertiesBoiling Point Specific Gravity (H2O = 1)

230 F 1.160 - 1.1693Vapor Pressure (mm Hg) Freezing Point

50 - 60 mm .-12 F to -63 FVapor Density (AIR = 1) Density

N.A. 9.671 - 9.748Solubility in WatermiscibleAppearance and OdoClear/Slightly yellow with a sharp pungent odor

Page 4 of 7

Section XI - Stability and ReactivityStability Unstable Conditions to Avoid

Hydrochloric Acid is extremely reactive. Avoid contact withStable

X metal surfaces and oxidizing agents.Incompatibility (Materials to Avoid)Hydrochloric Acid is chemically stable when properly contained and handled. It is a

strong mineral acid and reacts with many metals and metal oxides and hydroxides

to form the equivalent metal chloride. It reacts with zeolites and other silicious

compounds to form Hydrosilicic Acid; it reacts with carbonates to form Carbon

Dioxide and Water. It is oxidized by Oxygen or electrolysis to form Chlorine, a

lethal, poisonous gas. It reacts with alkaline compounds to form a neutral salt.

It is a hydrolyzing agent for carbohydrates, esters and other compounds.

Its reaction with most metals will produce Hydrogen, an explosive gas. Violent

reactions will result when Hydrochloric Acid Reacts with acetic anhydride,

2-aminoethanol, ammonium hydroxide, calcium phosphide, chlorosulfonic acid,

ethylene diamine, ethylene imine, oleum (fuming sulfuric acid), perchloric acid,

beta propiolactone, propylene oxide, sodium hydroxide, sulfuric acid, uranium

phosphide and vinyl acetate. This listing is not all-inclusive.Hazardous Decomposition or By-productsExtreme heat may cause the product to decompose, producing toxic fumes which may

include chlorine compounds.Hazardous May Occur Conditions to AvoidPolymerization Extreme heat and contact with incompatible materials

Will Not OccurX

Section XII - Toxicological InformationRoute(s) of Entry: Inhalation? Skin? Ingestion?

Yes Yes YesHealth Hazards (Acute and ChronicHydrogen Chloride, both as a gas and in a solution as Hydrochloric Acid, is a

corrosive substance and can cause severe and painful burns on contact with any

part of the body or if taken internally. The mucous membranes of the eyes and the

upper respiratory tract are especially susceptible to the irritating effects of high

atmospheric concentrations of Hydrogen Chloride. The gas or vapor is so

penetrating and pungent that when high concentrations do occur, those exposed

should immediately leave the contaminated area.Carcinogenicity NTP? IARC Monographs? OSHA Regulated?

No No NoSigns and Symptoms of ExposureExposure to Hydrochloric acid may cause severe burns at the contact pointsMedical Conditions Generally Aggravated by ExposuExposure to fumes may aggravate dermatitis and breathing disorders.

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Section XII - Toxicological Information (cont.)Toxicology Inhalation DataHydrogen Chloride Human LCLo - 1300 ppm/30 min

Rat LC50 - 4701 ppm/30 minOral (rabbit)LD50 - 900 mg/kgMutagenic EffectsInhalation: 100 ppm/24 hrs (Chromosome damage)

Oral:: 100 ppm (Chromosome damage)

Parental: 20 mg (Cytogenic effects)

Section XIII - Ecological InformationEcological ToxicityAnimals exposed to hydrochloric acid solution will experience tissue damage, burns and

may be killed. Plants contaminated with hydrochloric acid solutions of low pH may be

adversely effected or destroyed. High concentrations have been shown to be detrimental

to aquatic life. A release into a body of water will kill fish and other aquatic life.Other Ecological InformationHydrochloric acid is stable and found naturally in the environment. All work practices

should be aimed at eliminating environmental contamination.Chemical Fate InformationHydrochloric acid is naturally occurring in the environment.Other Regulatory InformationNo other regulatory information is available on this product.

Section XIV - Transportation InformationRegulated MateriaHydrochloric Acid is defined as hazardous by the US Dot and Transport Canada

DOMESTIC SHIPPING INFORMATIONProper Shipping Name Hazard Classification

Hydrochloric Acid CorrosiveUN/NA Identification Hazard Class

UN 1789 Class 8DOT Labels Required Packaging Group

Corrosive II

INTERNATIONAL SHIPPING INFORMATIONProper Shipping Name Hazard Classification

Hydrochloric Acid CorrosiveUN/NA Identification Hazard Class

UN 1789 Class 8Labels Required Packaging Group

Corrosive II

Section XV - Other InformationCreated By MSDS Revision NumberProduct Safety - 4/20/99 Revision # 005Toxic Substances Control Act Superfund Amendment & Reauthorization Act, Title I Acute &TSCA listed 7647-01-0 Hazard Categories HEALTH: ChronicEmergency Planning & Community Right to KnowEHS - Threshold Quantity: None PHYSICAL: NoneIs product Regulated Under 1990 Clean Air Act? Does Product Contain, or is Manufactured with, CFC's?No NoReportable Quantity NSF ListingRQ - 5000 lbs Scale & Corrosion control at maximum 40 mg/lNFPA HMIS3 - 0 - 0 - Acid 3 - 0 - 0 - XIs This Product Regulated Under the EPA's Risk Management PlanNo, Hydrochloric Acid Solution under 37% is not regulated.North American Emergency Response Guide BooID # 1789 Guide #157 1996 Revision

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Disclaimer of Liability

The data contained herein is furnished gratuitously and independent of any sale

of any product. It is supplied only for your investigation and possible independent

verification. While the data is believed to be correct, Reagent Chemical

and Research Inc. makes no representation as to the accuracy of any data

contained herein. In no event shall Reagent Chemical and Research, Inc. be

responsible for any damages of any nature whatsoever directly or indirectly

resulting from the publication, use or reliance upon any data contained herein.

Data Sheets are available for other Reagent Chemical and Research, Inc.

products. You are urged to obtain data sheets for all products you buy, process,

use or distribute and you are encouraged to advise anyone working with or

exposed to such products of the information contained in the applicable data

sheets. The data in this document is provided without any representation or

warranty, express or implied, regarding its accuracy or correctness. No warranty

either expressed or implied of merchant ability or fitness or of any nature is made

with respect to any product referred to herein. Reagent Chemical and Research

Inc. does not assume responsibility and expressly disclaims liability for loss,

damage or expense arising out of or in any way connected with the handling,

storage, use or disposal of the products referred herein.

Page 7 of 7

BLANK PAGE

Product name

Product and company identification:

1 .

PPG Industries, Inc.One PPG PlacePittsburgh, PA 15272

(412) 434-4515 (U.S.)(514) 645-1320 (Canada)01-800-00-21-400 (Mexico)

Supplier

Synonym

Code

Emergency telephonenumber

:

:

:

:

Technical Phone Number : 1-800-245-2974 (Cal Hypo)

Material Safety Data Sheet

Date of issue 20 June 2011

Version 2

Emergency overview

Hazards identification

Potential acute health effects

EyesSkin

Inhalation

Ingestion

DANGER!:

::

:

:

2 .

Over-exposure signs/symptoms

Inhalation :

Keep away from heat, sparks, flames, direct sunlight, and other sources of heat,including lighted tobacco products. Keep away from incompatible materials andcombustible materials. Do not swallow. Do not get in eyes or on skin or clothing. Useonly with adequate ventilation. Keep container closed. If product becomes contaminatedor decomposes do not reseal container. If possible isolate container in open air or well-ventilated area. Wash thoroughly after handling. Keep out of waterways.

STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE. DONOT MIX WITH OTHER CHEMICALS, INCLUDING ANY OTHER POOL CHEMICALSOF ANY KIND. MIXING WITH OTHER CHEMICALS COULD CAUSE A FIRE OREXPLOSION. Contamination with moisture, acids, organic matter, other chemicals(including, but not limited to cleaning chemicals and other pool chemicals), petroleum orpaint products or other easily combustible materials may start a chemical reaction withgeneration of heat, liberation of hazardous gases and possible violent reaction leading tofire or explosion. ALWAYS ADD PRODUCT TO LARGE QUANTITIES OF WATER TOFULLY DISSOLVE PRODUCT. DO NOT POUR WATER INTO PRODUCT, ALWAYSADD PRODUCT TO WATER. Do not add this product to any dispensing devicecontaining remnants of any other product or pool chemical.

CAUSES EYE AND SKIN BURNS. CAUSES RESPIRATORY TRACT IRRITATION.HARMFUL IF INHALED. HARMFUL OR FATAL IF SWALLOWED. CONTAINSMATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMALDATA.

Very toxic to aquatic organisms.

Harmful if inhaled. Severely irritating to the respiratory system. Can irritate eyes, nose,mouth and throat.Harmful or fatal if swallowed. May cause burns to mouth, throat and stomach.

Corrosive to the skin. Causes burns. Harmful in contact with skin.

Corrosive to eyes. Causes burns.

Adverse symptoms may include the following:Respiratory tract irritationcoughingbreathing difficulty or shortness of breathpulmonary edema

Page: 1/9United States - Canada - Mexico

Power Powder® Pro™

Power Powder® Pro™; Cal Hypo Granules; Ca(OCl)2; MSDS No.

8000421

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Product name

2Product code Date of issue Version20 June 2011

Hazards identification2 .

See toxicological information (Section 11)

Medical conditionsaggravated by over-exposure

Pre-existing disorders involving any target organs mentioned in this MSDS as being atrisk may be aggravated by over-exposure to this product.

:

Ingestion :

Skin :

Eyes :

This Material Safety Data Sheet has been prepared in accordance with Canada's Workplace Hazardous MaterialsInformation System (WHMIS) and the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Adverse symptoms may include the following:stomach painsnausea or vomitinggastric perforationAdverse symptoms may include the following:pain or irritationrednessblistering may occurAdverse symptoms may include the following:painwateringrednessDirect contact with the eyes can cause irreversible damage, including blindness.

Composition/information on ingredients3 .

There are no additional ingredients present which, within the current knowledge of the supplier and in theconcentrations applicable, are classified as hazardous to health or the environment and hence require reporting inthis section.

Name

Notes: Available Chlorine: 65-76%, Inert ingredients 24-35 %(includes 5.5-8.5% water).

calcium hypochlorite 7778-54-3 65 - 76sodium chloride 7647-14-5 10 - 30calcium carbonate 471-34-1 1 - 3calcium dihydroxide 1305-62-0 1 - 3calcium chlorate 10137-74-3 0 - 3

CAS number %

First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

Notes to physician

:

:

:

:

:

4 .

Check for and remove any contact lenses. Immediately flush eyes with running waterfor at least 15 minutes, keeping eyelids open. Continue rinsing until medical attentioncan be obtained.

In case of contact, immediately flush skin with plenty of water for at least 15 minuteswhile removing contaminated clothing and shoes. Get immediate medical attention.

Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing isirregular or if respiratory arrest occurs, provide artificial respiration or oxygen bytrained personnel. Get medical attention immediately.

If swallowed, seek medical advice immediately and show this container or label.Keep person warm and at rest. Do not induce vomiting. Get medical attentionimmediately.

If ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of thisproduct, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have MaterialSafety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.

No specific treatment. Treat symptomatically. Contact poison treatment specialistimmediately if large quantities have been ingested or inhaled.



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Fire-fighting measures

Extinguishing media

Product is not known to be flammable, combustible, or pyrophoric. This materialincreases the risk of fire and may aid combustion. Contact with combustible material maycause fire. This product is a strong oxidizer which is capable of intensifying a fire oncestarted. Container may rupture.

Special protectiveequipment for fire-fighters

Fire-fighters should wear appropriate protective equipment and self-contained breathingapparatus (SCBA) with a full face-piece operated in positive pressure mode.

:

5 .

Special exposure hazards :

Suitable :

Not suitable :

Hazardous combustionproducts

:

Flammability of the product :

Drench with large quantities of water only.

Do not use dry chemicals or foams. Product supplies own oxygen, therefore attempts tosmother fire with a wet blanket, carbon dioxide, dry chemical extinguisher or othermeans are not effective. Product has the potential to cause a violent reaction if drychemical fire extinguishers are used.

Promptly isolate the scene by removing all persons from the vicinity of the incident ifthere is a fire. No action shall be taken involving any personal risk or without suitabletraining. Emits toxic fumes under fire conditions. Chlorine gas may be generated. Thismaterial is very toxic to aquatic organisms. Fire water contaminated with this materialmust be contained and prevented from being discharged to any waterway, sewer ordrain.

Decomposition products may include the following materials:carbon oxideshalogenated compoundsmetal oxide/oxides

Environmental precautions

Accidental release measures

:

Personal precautions :

Large spill :

6 .

Small spill :

No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel fromentering. Do not touch or walk through spilled material. Shut off all ignition sources. Noflares, smoking or flames in hazard area. Provide adequate ventilation. Wearappropriate respirator when ventilation is inadequate. Put on appropriate personalprotective equipment.

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drainsand sewers. Inform the relevant authorities if the product has caused environmentalpollution (sewers, waterways, soil or air). Water polluting material. May be harmful tothe environment if released in large quantities.Use extreme caution in handling spilled material. Use spark-proof tools and explosion-proof equipment. Do not mix this product with any other chemicals, including any otherpool chemicals of any kind, such as other disinfection or "shock" pool products.Contamination with moisture, acids, organic matter, other chemicals (including, but notlimited to cleaning chemicals and other pool chemicals), petroleum or paint products orother easily combustible materials may start a chemical reaction with generation of heat,liberation of hazardous gases and possible violent reaction leading to fire or explosion.If fire or decomposition occurs in area of spill, immediately douse with plenty of water.Otherwise, sweep up all visible material using a clean (new, if possible), dry shovel andbroom and immediately dissolve material in a water-filled container. Spilled material thathas been swept up and dissolved in water should be used immediately in the normalapplication for which this product is being consumed. Prevent entry into sewers, watercourses, basements or confined areas. Note: see section 1 for emergency contactinformation and section 13 for waste disposal.

Use extreme caution in handling spilled material. Use spark-proof tools and explosion-proof equipment. Do not mix this product with any other chemicals, including any otherpool chemicals of any kind, such as other disinfection or "shock" pool products.Contamination with moisture, acids, organic matter, other chemicals (including, but notlimited to cleaning chemicals and other pool chemicals), petroleum or paint products orother easily combustible materials may start a chemical reaction with generation of heat,liberation of hazardous gases and possible violent reaction leading to fire or explosion.If fire or decomposition occurs in area of spill, immediately douse with plenty of water.



8000421

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Accidental release measures6 .Otherwise, sweep up all visible material using a clean (new, if possible), dry shovel andbroom and immediately dissolve material in a water-filled container. Spilled material thathas been swept up and dissolved in water should be used immediately in the normalapplication for which this product is being consumed. Prevent entry into sewers, watercourses, basements or confined areas. Note: see section 1 for emergency contactinformation and section 13 for waste disposal.See Section 1 for emergency contact information.See Section 8 for information on appropriate personal protective equipment.See Section 13 for additional waste treatment information.

Reference to other sections :

Use extreme caution in handling spilled material. Put on appropriate personal protectiveequipment (see Section 8). Eating, drinking and smoking should be prohibited in areaswhere this material is handled, stored and processed. Do not swallow. Do not get ineyes or on skin or clothing. Use only with adequate ventilation. Wear appropriaterespirator when ventilation is inadequate. Keep in the original container with the lidsecurely closed. Keep away from heat, sparks, flames, direct sunlight, and othersources of heat, including lighted tobacco products. Keep away from combustiblematerial. Add this product only to water. Never add water to this product. Always add theproduct to large quantities of water. Do not mix this product with any other chemicals,including any other pool chemicals of any kind, such as other disinfection or "shock" poolproducts. Fire may result if contaminated with acids, organic materials and other easilycombustible materials such as oil, kerosene, gasoline, paint products wood and paper.Use only a clean (new, if possible), dry scoop made of metal or plastic each time productis taken from the container. Do not add this product to any dispensing device containingremnants of any other product or pool chemical. Such use may cause violent reactionleading to fire or explosion. Empty containers retain product residue and can behazardous. Do not reuse container. Residual material remaining in empty container canreact to cause fire. Thoroughly flush empty container with water then destroy by placingin trash collection.

Handling and storageHandling

Storage

:

:

7 .

Store in accordance with local regulations. Store in original container protected fromdirect sunlight in a dry, cool and well-ventilated area, away from incompatible materials(see section 10) and food and drink. Separate from reducing agents and combustiblematerials. See NFPA 400. Hazardous Materials Code for further information. (Pleasenote that NFPA 400, Hazardous Materials Code recently replaced NFPA 430, Code forStorage of Liquid and Solid Oxidizers.) Keep container closed. Containers that havebeen opened must be carefully resealed and kept upright to prevent leakage. If productbecomes contaminated or decomposes do not reseal container. If possible isolatecontainer in open air or well-ventilated area. Do not store in unlabeled containers. Useappropriate containment to avoid environmental contamination. Do not contaminatewater, food, or feed by storage or disposal of this product.

Exposure controls/personal protection8 .

calcium hypochlorite TWA Notestablished

Notestablished

Notestablished

Notestablished

1 mg/m³

STEL Notestablished

Notestablished

Notestablished

Notestablished

2 mg/m³

____________________________ ___________ ___________ ___________ ___________ ___________ ___________calcium carbonate TWA 10 MG/M3 TD

3 MG/M3 R5 mg/m³ R15 mg/m³ TD5 mg/m3 R15 mg/m3

Notestablished

Notestablished

Notestablished

____________________________ ___________ ___________ ___________ ___________ ___________ ___________calcium dihydroxide TWA 5 mg/m³ 5 mg/m³ R 5 mg/m³ 5 mg/m³ Not

Name Result ACGIH OSHA Ontario Mexico PPG



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Exposure controls/personal protection8 .

Acceptable Maximum PeakA =ACGIH = American Conference of Governmental Industrial Hygienists.

C = Ceiling Limit

Potential skin absorptionSSR = Respiratory sensitization

= Skin sensitizationSS

TD = Total dust

Key to abbreviations

Personal protection

Eyes

Skin

Respiratory

Consult local authorities for acceptable exposure limits.

:

:

:Gloves :

Engineering measures :

Hygiene measures :

Recommended monitoringprocedures

: If this product contains ingredients with exposure limits, personal, workplace atmosphereor biological monitoring may be required to determine the effectiveness of the ventilationor other control measures and/or the necessity to use respiratory protective equipment.

Environmental exposurecontrols

:

= Threshold Limit ValueTLVTWA = Time Weighted Average

Hands :

Fume=FIPEL = Internal Permissible Exposure Limit

= Occupational Safety and Health Administration.OSHAR = Respirable

OSHA 29CFR 1910.1200 Subpart Z - Toxic and Hazardous Substances=Z

15 mg/m³ TD established____________________________ ___________ ___________ ___________ ___________ ___________ ___________

STEL =

=

Short term Exposure limit values

Use only with adequate ventilation. If user operations generate dust, fumes, gas, vaporor mist, use process enclosures, local exhaust ventilation or other engineering controls tokeep worker exposure to airborne contaminants below any recommended or statutorylimits. Engineering controls may be required to control the primary or secondary risksassociated with this product.Wash hands, forearms and face thoroughly after handling chemical products, beforeeating, smoking and using the lavatory and at the end of the working period. Appropriatetechniques should be used to remove potentially contaminated clothing. Washcontaminated clothing before reusing. Ensure that eyewash stations and safety showersare close to the workstation location.

Chemical splash goggles and face shield.Chemical-resistant, impervious gloves complying with an approved standard should beworn at all times when handling chemical products if a risk assessment indicates this isnecessary.nitrile, neoprene, butyl rubber.If workers are exposed to concentrations above the exposure limit, they must useappropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respiratorcomplying with an approved standard if a risk assessment indicates this is necessary.Respirator selection must be based on known or anticipated exposure levels, thehazards of the product and the safe working limits of the selected respirator.Personal protective equipment for the body should be selected based on the task beingperformed and the risks involved and should be approved by a specialist before handlingthis product.Emissions from ventilation or work process equipment should be checked to ensure theycomply with the requirements of environmental protection legislation. In some cases,fume scrubbers, filters or engineering modifications to the process equipment will benecessary to reduce emissions to acceptable levels.

Decomposes. @ 170-180°C (338-356°F)

Solid. [Granular solid.]

Alkaline.

Not available.

Slight CHLORINE

Various

Boiling/condensation point

Melting/freezing point

Physical and chemical propertiesPhysical state

pH

Odor

Color

:

:

:

:

:

:

Flash point : Closed cup: Not applicable.

9 .

Yes.:Material supportscombustion.

Decomposition temperature : 170 to 180°C (338 to 356°F)



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Physical and chemical properties9 .

0% (v/v), 0% (w/w)

Not available.

Not available.

Not available.

Not available.

Specific gravity

Vapor pressure

Vapor density

Volatility

Evaporation rate

:

:

:

:

:

Partition coefficient: n-octanol/water

: Not available.

% Solid. (w/w) : 100

Bulk Density: 63-67 lbs/ft3 (1 - 1.07 g/cm3)

Viscosity : Not Applicable

Stability and reactivityStability

Conditions to avoid

Materials to avoid

Hazardous decompositionproducts

:

:

:

:

10 .

Heating may cause a fire or explosion. Excessive heat will cause decomposition resultingin the release of oxygen and chlorine gas.Highly reactive or incompatible with the following materials: moisture, combustiblematerials, organic materials, metals, acids, alkalis, oxidizing materials, reducingmaterials, Ammonia., Petroleum products., Paint products., Wood and paper., Poolchemicals.

Acid or ammonia contamination will release toxic gases.

Under normal conditions of storage and use, hazardous polymerization will not occur.

Product slowly releases chlorine gas.

Stable under recommended storage and handling conditions (see section 7). Productdecomposes at approximately 170-180°C (338-356°F) releasing oxygen gas and somechlorine gas.

Possibility of hazardousreactions

:

11 . Toxicological information

Conclusion/Summary : Harmful or fatal if swallowed. May be harmful if absorbed through skin. May be harmful ifinhaled.

Chronic toxicity

Conclusion/Summary : Not available.

calcium hypochlorite LD50 Oral Rat 850 mg/kg -LD50 Dermal Rabbit >1000 mg/kg -

sodium chloride LD50 Oral Rat 3000 mg/kg -calcium carbonate LD50 Oral Rat 6450 mg/kg -calcium dihydroxide LD50 Oral Rat 7340 mg/kg -calcium chlorate LD50 Oral Rat 4.5 g/kg -

Product/ingredient name Result Species Dose Exposure

Acute toxicity

Irritation/Corrosion

Skin :Eyes :Respiratory :

Sensitization

Skin :Respiratory :

Corrosive. Causes burns.Corrosive. Causes eye burns.Severely irritating to the respiratory system.

Not available.Not available.

Corrosive to the eyes, skin, respiratory system and digestive tract.Potential chronic healtheffects

:



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11 . Toxicological information

Carcinogenicity

Mutagenicity

calcium hypochlorite OECD 471 BacterialReverse Mutation Test

Experiment: In vitroSubject: Bacteria

Positive

- Experiment: In vitroSubject: Mammalian-Animal

Positive

OECD 474 MammalianErythrocyte MicronucleusTest

Experiment: In vivoSubject: Mammalian-Animal

Negative

Product/ingredient name Test Experiment Result

Conclusion/Summary : Mutagenic effects - Equivocal evidence.

Classification

calcium hypochlorite - 3 - - - -Product/ingredient name ACGIH EPA NIOSH NTPIARC OSHA

Target organs : Contains material which may cause damage to the following organs: lungs, mucousmembranes, gastrointestinal tract, upper respiratory tract, skin, eye, lens or cornea,stomach.

Ecological informationEnvironmental effects : Very toxic to aquatic organisms.

12 .

Aquatic ecotoxicity

calcium hypochlorite Acute LC50 57 to 60 ug/L Fresh water Fish - Bluegill - Lepomis macrochirus 96 hours_________________________________ ________________________________ __________Acute LC50 37 ug/L Marine water Fish - Atlantic silverside - Menidia

menidia96 hours

_________________________________ ________________________________ __________Acute EC50 0.073 to 0.079 ppm Freshwater

Daphnia - Water flea - Daphnia magna 48 hours

______________________ _________________________________ ________________________________ __________sodium chloride Acute LC50 1294600 ug/L Fresh water Fish - Bluegill - Lepomis macrochirus 96 hours

_________________________________ ________________________________ __________Acute EC50 402600 to 469200 ug/LFresh water

Daphnia - Water flea - Daphnia magna 48 hours

_________________________________ ________________________________ __________Chronic NEL 0.86 g/L Fresh water Fish - Fathead minnow - Pimephales

promelas96 hours

______________________ _________________________________ ________________________________ __________calcium dihydroxide Acute LC50 356 mg/L Marine water Fish - Guppy - Poecilia reticulata 96 hours

_________________________________ ________________________________ __________Chronic NOEC 56 mg/L Marine water Fish - Guppy - Poecilia reticulata 96 hours

______________________ _________________________________ ________________________________ __________

Product/ingredientname

SpeciesResult Exposure

Waste disposal

Disposal considerations:

13 .The generation of waste should be avoided or minimized wherever possible. Thismaterial and its container must be disposed of in a safe way. Spilled material that hasbeen swept up and dissolved in water should be used immediately in the normalapplication for which this product is being consumed. If this is not possible, material maybe neutralized. Please contact PPG Industries, Inc. Emergency Response team forguidance at 412-434-4515. Note: Only properly neutralized material should be flushed tosewer. Unneutralized material can cause environmental damage to receiving water orcan interfere with treatment plant operation. Care must be taken when using or disposing



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Disposal considerations13 .

Disposal should be in accordance with applicable regional, national and local laws and regulations.

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTIONfor additional handling information and protection of employees. Section 6. Accidental release measures

of chemical materials and/or their containers to prevent environmental contamination.Empty containers retain product residue and can be hazardous. Residual materialremaining in empty container can react to cause fire. Thoroughly flush empty containerwith water then destroy by placing in trash collection. Disposal of this product, solutionsand any by-products should at all times comply with the requirements of environmentalprotection and waste disposal legislation and any regional local authority requirements.

Transport information14 .

Regulation UN number Proper shipping name Classes PG*

UN 2880 CALCIUM HYPOCHLORITE,HYDRATED

5.1 II

Additional information

-

IMDG 2880 CALCIUM HYPOCHLORITE,HYDRATED

5.1 -II

DOT -2880 5.1CALCIUM HYPOCHLORITE,HYDRATED

II

CERCLA: Hazardous substances.: calcium hypochlorite: 10 lbs. (4.54 kg);Reportable quantity RQ :

PG* : Packing group

15 . Regulatory information

All components are listed or exempted.







All components are listed or exempted.United States inventory (TSCA 8b) :

Australia inventory (AICS)

Canada inventory ( DSL ) :

China inventory (IECSC) :

Japan inventory (ENCS) :

Korea inventory (KECI) :

New Zealand ( NZIoC ) :

Philippines inventory (PICCS) :

:

Europe inventory ( REACH ) : Please contact your supplier for information on the inventory status of this material.

United States

CERCLA: Hazardous substances.: calcium hypochlorite: 10 lbs. (4.54 kg);

EPA ID No. - Pesticide. : Please contact your supplier to get the information.

SARA 302/304/311/312 extremely hazardous substances: No products were found.SARA 302/304 emergency planning and notification: No products were found.SARA 302/304/311/312 hazardous chemicals: calcium dihydroxide; calcium chlorate; calcium carbonate; sodiumchloride; calcium hypochlorite

SARA 311/312 MSDS Distribution - Chemical Inventory - Hazard Identification:

calcium hypochlorite 7778-54-3 Y N N Y Nsodium chloride 7647-14-5 N N N N Ncalcium dihydroxide 1305-62-0 Y N N N Ncalcium carbonate 471-34-1 N N N N Ncalcium chlorate 10137-74-3 Y N N Y N

Chemical name CAS # Acute Chronic Fire Reactive Pressure

Product as-supplied : Y N N Y N

California Prop. 65



8000421

Product name


15 . Regulatory information

WHMIS (Canada) Class E: Corrosive solid.Class C: Oxidizing material.

:

Canada

Mexico

0 3 2HealthFlammability Reactivity

Classification

: : :

Not applicable.

NSF Drinking Water Treatment Chemicals Listing - PPG calcium hypochlorite(68% nominal product) is certified for maximum use at 15 mg/L under NSF/ANSIStandard 60. NSF Drinking Water Treatment Chemicals Listing - PPG calciumhypochlorite (73% nominal product) is certified for maximum use at 14 mg/L underNSF/ANSI Standard 60.

This product is registered with U.S. EPA as a pesticide.

Other information

Other specialconsiderations

Hazardous Material Information System (U.S.A.)

0

20

National Fire Protection Association (U.S.A.)

Health InstabilityFlammability

Health Flammability Physical hazards

Disclaimer

The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of thisinformation is to draw attention to the health and safety aspects concerning the products supplied by PPG, and torecommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given inrespect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measuresdescribed in this data sheet or for any misuse of the products.

Date of previous issue 10/21/2010.:

:

16 .

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implementedHMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS®materials may be purchased exclusively from J. J. Keller (800) 327-6868.

The customer is responsible for determining the PPE code for this material.

Indicates information that has changed from previously issued version.

Organization that preparedthe MSDS

: EHS

:: :

: : :3

3

2( * ) - Chroniceffects



8000421

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Product: Leslie's Swimming Pool Supplies Chlor Neutralizer

1. Chemical Product and Company Identification

Trade Name of this Product: Leslie's Swimming Pool Supplies Chlor Neutralizer

MSDS ID Solvay 042007 Revision Date 7/2/2008

Repackager:LPM Manufacturing, Inc.3925 East Broadway Rd., Suite 100Phoenix, AZ 85040Phone Number(602) 366-3999 Emergency Phone: (800) 424-9300

2. Composition and Information on Ingredients

Ingredient CAS Number Weight %

Sodium Sulfite 7757-83-7 >=99%Sodium Sulfate 7757-82-6 =<1%

3. Hazard Identification

NFPA Ratings:Health: 2 Fire: 0 Reactivity: 1 Special:None

EMERGENCY OVERVIEWGeneral Information:

Appearance: Granular SolidColor: WhiteOdor Odorless

Main effects:• Irritation• Ingestion may be fatal.• Breathing of dust may aggravate asthma or other pulmonary diseases.• Sulfite sensitive individuals may experience severe allergic reactions.

Potential Health Effects:

Eye Contact:Mild irritationSkin Contact:Mild irritation with prolonged exposure. Inhalation:Mild irritation

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Ingestion:• Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.• Ingestion may be fatal.• Sulfite sensitive individuals may experience a severe allergic reaction.

4. First Aid Information

Eye:• Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.• If eye irritation persists, consult a specialist.Skin:• Wash off with plenty of water.• Wash contaminated clothing before re-use.• If irritation persists, consult a specialist. Inhalation:• Remove the subject from dusty environment and clear nose.• If patient has stopped breathing or experiences difficulty breathing, administer artificial respiration.Ingestion:The following actions are recommended:

If victim is conscious:• Consult a physician.

If victim is unconscious but breathing:• Never give anything by mouth to an unconscious person.• Remove evidence of substance from mouth.

5. Fire Fighting Measures

Flash Point Not applicableFP Method Not applicableFlammable limits:Not applicableExtinguishing Media:Use extinguishing measures that are appropriate to local circumstances and the surroundingenvironment. Hazards to Fire-fighters• Generates hazardous SO2 gas during decomposition.• Not combustibleFire-fighting Equipment:• Wear NIOSH approved self-contained breathing apparatus.• Use water spray to knock down fumes and keep containers cool.

6. Accidental Release Measures

Personal Protection:• Refer to protective measures listed in sections 7 and 8.• Avoid excessive dust.Environmental Hazards:• Should not be released into the environment. Spill Cleanup:• Collect the product with suitable means.CERCLA RQ:Not applicable

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7. Handling and Storage

Handling:• Avoid prolonged or repeated contact with skin or eyes or breathing dust.• Wash exposed areas promptly after skin contact.Storage:• Keep in closed, properly labeled container in a dry area away from acids.Packaging Materials:• Bulk rail car and Truck• Paper + PE• Woven plastic + PE coating• Woven plastic + PE

8. Exposure Controls and Personal Protection

Exposure Limit Values TLV ACGIH USA OSHA PELSodium Sulfite Not listed Nuisance Dust- 5 mg/m3

(Respirable fraction) 15 mg/m3(Total Dust)

Sulfur Dioxide Gas TWA – 2 ppmSTEL – 5 ppmIDEL – 100 ppm

Engineering Controls:• Ensure adequate ventilation.• Provide appropriate exhaust ventilation at machinery.Respiratory Protection:• Use NIOSH approved toxic dust respirators when needed to control exposures below the

applicable exposure limits.• If SO2 is present (see section 10), use NIOSH approved air supplied positive pressure respirator or

appropriate cartridge.Skin Protection:• Normal clothing adequate to prevent skin contact.Eye Protection:• Chemical resistant goggles when needed.Hand Protection:• Protective glovesHygiene Measures:• Minimize dust taken home on clothing.• Eye wash and safety shower.• Use good hygiene practices• Do not eat, drink or smoke in areas where material is handled.

9. Physical and Chemical Properties

Physical State granular solidSpecific Gravity not applicableBulk Density 95-100 lbs./ ft3 (1522-1602 kg/m3)Color/Appearance white Odor NoneBoiling/Cond. Point not applicableMelting/Freezing Point not applicable (decomposes)Decomposition Temperature Decomposes at approximately 600oC (1112oF)Solubility Water: 27g / 100ml @ 20oC (68oF)Evaporation Rate not applicableVOC % not applicable

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Percent Volatile not applicableMolecular Formula not applicableViscosity not applicableVapor Density not applicableVapor Pressure no datapH: 9.6 – 9.8 (Concentration: 1% solution)Oxidizing Properties Decomposition releases oxide of sulfurRelative density/ Density 2.63 @ 20oC (68oF)Chemical Formula Na2So3Chemical Weight 126.04

10. Stability and Reactivity

Stability:Stable under normal conditionsCONDITIONS TO AVOID:• High temperature• MoistureMaterials to Avoid (Incompatibilities):• Strong Oxidizers (vigorous exothermic reactions)• Acids (releases SO2)Hazardous Decomposition Products:• Oxides of sulfur• Sulfur dioxide gas

11. Toxicological Information

Acute Data:Acute oral toxicityLD50, mouse 820 mg/kgAcute inhalation toxicityNo dataSkin irritationMild skin irritationEye irritationIrritationRemarks Can cause allergic reaction (headaches, difficulty breathing, rapid heart rate and anaphylaxis) tosusceptible individuals.

Chronic Toxicity:Not carcinogenic

12. Ecological Information

Ecotoxicity:Acute toxicityFishes, goldfish, LC50, 96h, 100 mg/lFishes, 24, 48, 96 hour TLm Mosquito fish, 2,600 ppm

Mobility:AirNo DataWaterNo DataSoil/sedimentsNo Data

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Persistence and Degradability:Abiotic degradation

AirNo DataWaterNo DataSoilNo Data

BiodegradationAerobic/ anaerobicNo Data

Bioaccumulative potential:BOD (Biological Oxygen Demand) = 0.12 lb./lb. INSTANTANEOUSOther Adverse Effects:Sodium sulfite is an oxygen scavenger when introduced to water

13. Disposal Considerations

Disposal Method:Waste Treatment Sodium sulfite is not a listed hazardous waste under 40 CFR 261. However, state and localregulations for waste disposal may be more restrictive. Spilled product should be disposed of inan EPA approved disposal facility in accordance with applicable national, state, and localenvironmental laws and regulations.Packaging TreatmentTo avoid treatment, use dedicated containers where possible. Rinse the empty containers andtreat the effluent in the same way as waste. Consult current federal, state, and local regulationsregarding the proper disposal of emptied containers.

14. Transportation Information

Mode DOT IMDG IATAUN Number Not a regulated

hazardous materialNot a regulatedhazardous material

Not a regulatedhazardous material

Other It is recommended that ERG guide #111 be used for all non-DOT-regulatedmaterial.

STCC# 28-123-80

15. Regulatory Information

CERCLA RQ:Not applicableSARA Title III:Section 302: Not listed as an extremely hazardous substanceSection 313: Not listed in as a toxic chemical emissionSection 311/312: An acute and chronic health hazard

Threshold planning quantity- 10,000 lbs.USA TSCA:All components of this product are listed on the TSCA Inventory.

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16. Other Information

HMIS:Health: 2 Fire: 0 Reactivity: 1 PPE: Supplied by User; dependent on local conditions

Additional Preparation Information:The above information is based upon information LPM Manufacturing, Inc. believesto be reliable and is supplied for informational purposes only. LPM Manufacturing, Inc. disclaims anyliability for damage which results from the use of the above information and nothing contained thereinshall constitute a guarantee, warranty (including fitness for a particular purpose) or representation byLPM Manufacturing, Inc. with respect to the accuracy or completeness of the data, the productdescribed or its use for any specific purpose even if that purpose is known to LPM Manufacturing, Inc.The final determination of the suitability of the information, the manner of use of the informationor product and potential infringement is the sole responsibility of the user.

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Product: Leslie's Swimming Pool Supplies Conditioner


Trade Name of this Product: Leslie's Swimming Pool Supplies Conditioner

MSDS ID AllChem 7/14/2005 Revision Date 6/19/2008



Ingredient CAS NumberWeight %

Cyanuric Acid 108-80-5 90-99%Sulfuric Acid 7664-93-9 0-1%Ammelide 645-93-2 0-0.5%Ammeline 645-92-1 0-0.5%Water 7732-18-5 0-10%

TLV- TWA: ACGIH: 1 mg/m3 , A2 (Designation refers to sulfuric acid contained in strong inorganic acidmists.USA-OSHA: 1 mg/m3 (Sulfuric Acid)TLV- STEL: ACGIH: 3 mg/m3, 15 min


Primary Routes of Entry:Ingestion: ( )Inhalation: ( ) Skin Contact: ( )Eye Contact: ( )

Eye Contact:Contact with eyes may cause slight irritation consisting of redness, swelling and mucous discharge tothe conjunctiva. No corneal damage or visual impairment.Skin Contact:Skin contact may cause a mild irritation consisting of transient redness. This irritation effect would notbe expected to result in permanent damage.

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Inhalation:No significant adverse effects to health would be expected to occur from inhalation with normal use ofthis product. However if dust is created and inhaled, inhalation may cause mild irritation to the throat,mucous membranes and upper respiratory tract.Ingestion:Ingestion may cause gastrointestinal discomfort with any or all of the following symptoms: nausea,vomiting, lethargy, or diarrhea.Carcinogenicity Listings:OSHA: ( )NTP: ( )IARC: ( )


Eye:Holding the eyelids apart, flush eyes promptly with copious flowing water for at least 20 minutes. Getmedical attention immediately.Skin:Remove contaminated clothing. Wash skin thoroughly with mild soap and plenty of water for least 15minutes. Wash clothing before reuse. Get medical attention immediately. Inhalation:In case of dust inhalation or breathing fumes released from heated material, remove person to freshair. Keep person quiet and warm. Apply artificial respiration if necessary and get medical attentionimmediately. Ingestion:If swallowed, wash mouth thoroughly with plenty of water and give water to drink. Get medicalattention immediately.Note: Never give an unconscious person anything to drink.

Notes to Physician: Irritant. No specific antidote. Treat symptomatically and supportively. In case ofingestion, induce vomiting in alert patient.


Flash Point Not applicableFlammable limits:Not ApplicableExtinguishing Media:Use extinguishing media appropriate to surrounding fire conditions.Unusual Fire and Explosion Hazards:When heated to decomposition, may release poisonous and corrosive fumes, CO2, CO, NOx andcyanic acid.Special Fire Fighting Procedures:Cool containers with water spray. In closed stores, provide fire fighters with self-contained breathingapparatus in positive pressure mode.Auto-ignition Temperature: Not Applicable

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Steps To Be Taken In Case Material is Spilled or Released:• Sweep up, place in a suitable container and hold for waste disposal. Ventilate area and wash spill

site after material pickup is complete.• On Soil: Keep spill materials dry an d free of all forei gn matter. Contain erize in a cl ean d ry

container.• On water: This material is heavier than water. This material is very slightly soluble in water.• In Air: Not Applicable.


Handling:Do not take internally. Avoid contact with skin, eyes, and clothing. Upon contact with skin or eyes,wash off with water.Storage:Store in a dry, cool area. Do not store at temperatures above 60oC/140oF. Product has an indefiniteshelf-life limitation.


Ventilation:Local Exhaust: Use local exhaust as necessary, especially under dusty conditions.Respiratory Protection:When dusty conditions are encountered, wear a NIOSH/OSHA full-face respirator with chlorinecartridges for protection against chlorine gas and dust/mist pre-filter. A respiratory protection programmeeting OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplaceconditions warrant a respirator’s use.Other Protective Clothing or Equipment:Neoprene gloves, chemical safety goggles, body covering clothes and boots.Work/ Hygienic Practices:Safety shower and eye bath should be provided. Do not eat, drink or smoke until after-work showeringand changing clothes.


Physical State: solidSpecific Gravity (H20)=1): 2.5Bulk density: 0.79-0.85 g/cc Color/Appearance: White granules or powderOdor: NoneBoiling/Cond. Point: Not applicableMelting/Freezing Point: Sublimes at 320-330oC (608-626oF)Solubility: 0.27 g/100ml at 25oCEvaporation Rate: Not applicable under standard conditions.pH: 3.8-4.0Molecular Weight: 129.08Thermal Decomposition: Not ApplicableVapor Density (Air=1): Not applicable under standard conditions.Vapor Pressure (mm Hg): Not applicable under standard conditions.

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Stability:Stable under normal conditions.CONDITIONS TO AVOID:Heating above 330oC (626oF)Incompatibility:Oxidizing agents.Hazardous Decomposition or By-Products:Cyanic acid, nitrogen oxides, carbon monoxide, carbon dioxide.Hazardous Polymerization:Will Not Occur


Acute Toxicity:Rat oral LD50: >5,000 mg/kgRat dermal LD 50: >2,000 mg/kgEye Irritant (rabbit): Mild IrritantDermal Irritation (rabbit) Mild Irritant

Target Organ Toxicity:May cause mild skin and eye irritation. Based on data from toxicological investigations, cyanuric aciddoes not result in direct target damage. Damage to the kidneys and bladder has been observed inrats when these animals are provided a saturated solution (5,375 ppm) of cyanuric acid for theirdrinking water. During excretion of high amounts by the kidneys, stones of cyanuric acid can form(calculi) resulting in mechanical damage, which is secondary to stone formation. There should be norisk to humans during manufacturing of the product, its use as a swimming pool disinfectant, or evenby consumption of dilute solutions (1-10 ppm) of cyanuric acid. Cyanuric acid is excreted unchangedrapidly via the kidneys. It lacks the potential to bioaccumulate in the body.

Chronic toxicity: There are no known or reported effects from chronic exposure except for effects similar to thoseexperienced from single exposure.

Reproductive and Development Toxicity: There are no known reported effects on reproductive function or fetal development. Monosodiumcyanurate (the sodium salt of cyanuric acid) has been tested by oral gavage in pregnant rats andrabbits. No teratogenic effects were seen in the offspring of either species. Sulfuric acid aerosol(95.7% purity) was tested in pregnant mice and rabbits exposed to the concentrations of 0. 5 and 20mg/cubic meter by inhalation on gestational days 615 and 618, respectively. No reproductive ordevelopmental effects were seen in either species at any of the exposure concentrations utilized.

Carcinogenicity: Cyanuric acid is not known to be a carcinogen. Not classified by IARC, OSHA, or EPA. Not includedin NTP 8th Report on Carcinogens. Sulfuric acid is not known or reported to be carcinogenic by anyreference source. IARC evaluated several epidermiology studies, where individuals in a variety ofindustries had been exposed to a mixture of strong inorganic acid mists that are carcinogenic tohumans. Because cancer has not been observed in animals when they are exposed only to sulfuricacid mist, exposure to sulfuric acid by itself was not determined to be carcinogenic to humans.

Mutagenicity: Not known or reported to be mutagenic. Cyanuric acid was demonstrated to be non-mutagenic in theAmes assay, either with or without metabolic activation.

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Aquatic Toxicity:96 hour LC50- Fish: > 2,100 mg/l (Rainbow Trout)

> 2,100 mg/l (bluegill sunfish)> 2,100 mg/l (Fathead minnow)

48 hour LC50, Daphnia Magna: 1,000 mg/l

Avian Toxicity: Mallard duck, dietary LC50:>10,000 ppmBobwhite quail, dietary LC50: >10,000 ppm

Environmental Hazards (PR Notice 93-10):This product is toxic to fish and aquatic organisms. Do not contaminate water by cleaning ofequipment or disposal of wastes. Do not discharge effluent containing this product into lakes,streams, ponds, estuaries, oceans, or other waters unless in accordance with the requirements of aNational Pollutant Discharge Elimination System (NPDES) permit and the permitting authority hasbeen notified in writing prior to discharge. Do not discharge effluent containing this product to sewersystems without previously notifying the local sewage treatment plant authority. For guidance,contact your State Water board or Regional Office of the EPA.


Waste Disposal Method:Observe all federal, state and local environmental regulations when disposing of this material.


DOT Status:This material is not a regulated hazardous material for transportation.


CERCLA:No CERCLA Reportable Quantity has been established for this material.

SARA Title III:Section 311/312: Categorization (40 CFR 270.2): this product is categorized as an immediate healthhazard, and fire physical hazard.Section 313: Information (40 CFR 372): This mixture or trade name product contains a toxic chemicalor chemicals subject to the reporting requirements of Section 313 Title III of the SuperfundAmendments and Reauthorization Act of 1986 and 40 CFR 372.

TSCA:Reported in the EPA TSCA Inventory.

Workplace Classification: This product is considered hazardous under the OSHA HazardCommunication Standard (29 CFR 1910.1200).

ECC: Reported in EINECS (No. 2036180)

Adverse Human health effects: Irritant to eyes and respiratory system

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HMIS Rating: Health =1, Fire = 0, Reactivity = 0.


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Product: Leslie's Swimming Pool Supplies Alkalinity Up


Trade Name of this Product: Leslie's Swimming Pool Supplies Alkalinity Up

MSDS ID Solvay Bicarb-0707 Revision Date 06/19/2008



Ingredient CAS Number Weight % FormulaSodium Bicarbonate 144-55-8 >99 NaHCO3


NFPA Ratings:Health: 1 Fire: 0 Reactivity: 0 Specific: N/A

EMERGENCY OVERVIEW

Main Effects• Mechanical irritation• Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea

Potential Health Effects

Eye Contact:May be irritating

Skin Contact:May be irritating

Inhalation:May be irritating to respiratory tract mucous membranes.

Ingestion:May be irritating.Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.

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Eye:• Flush eyes with running water for 15 minutes, maintaining the eyelids wide open to eliminate

the product. • Consult an ophthalmologist in case of persistent pain.

Skin:• Wash off with plenty of water

Inhalation:• Remove subject to a dust free environment and let him/her blow nose.

Ingestion:The following actions are recommended:• If a large amount is swallowed, get medical attention.If victim is conscious:• If swallowed, rinse mouth with water (only if person is conscious).If victim is unconscious but breathing:• Never give anything by mouth to an unconscious person.


Flash Point Not applicableAuto Ignition Temperature: Not applicable Flammability Limits: Not applicable.Unusual Fire and Explosion Hazards: NoneSuitable Extinguishing Media

-Use extinguishing measures that are appropriate to local circumstances and the surroundingenvironment.


Precautions:Refer to sections 7 (Handling and Storage) and 8 (Exposure Controls and Personal Protection).

Cleanup Methods:• Do not flush into surface water or sanitary sewer system. • Prevent any mixture with an acid into the sewer/drain (gas formations).

Precautions for protection of the environment:• Sweep up and shovel into suitable containers for disposal.• Avoid dust formation.• Keep in properly labeled containers.• Keep in suitable, closed containers for disposal.• Treat recovered material as described in the section “Disposal Considerations.”


Handling:Keep away from incompatible products. Storage:Keep in a closed, properly labeled original container in a dry area away from incompatible products. Packaging:

• Paper + PE.• Polypropylene• Polyethylene• Woven Plastic Material

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Other Information:• Avoid dust formation.• Refer to sections 7 (Handling and Storage) and 8 (Exposure Controls and Personal

Protection).


Exposure Limit Values: This material does not have established exposure limits.Exposure Limit Values OSHA PEL SAEL

Sodium Bicarbonate 10 mg/m3 Total Dust Nuisance Dust 5 mg/m3 (Respirable Fraction),

15 mg/m3 (Total Dust)

Engineering Controls: • Ensure adequate ventilation.• Provide adequate exhaust ventilation at places where dust is formed.• Refer to sections 7 (Handling and Storage) and 8 (Exposure Controls and Personal

Protection).• Apply technical measures to comply with the occupational exposure limits.

Personal Protective Equipment:

Respiratory Protection:• Use only respiratory protection that conforms to international/national standards.• Use NIOSH approved respiratory protection.

Hand Protection:• Wear suitable gloves.

Eye Protection:• Dust proof goggles, if dusty.

Skin and Body Protection:• Protective clothing.

Hygiene Measures:• Wash hands before breaks and at the end of the workdays. • When using, do not eat, drink or smoke.• Handle in accordance with good industrial hygiene and safety practice.


Physical State solidSpecific Gravity H20=1Relative Density 2.2Color/Appearance Crystalline powder. WhiteOdor NoneBoiling/Cond. Point Not Applicable (Thermal Decomposition)Melting/Freezing Point Not ApplicableSolubility: Water: 96 g/ liter water @ 20oC (68oF) Other: Slightly soluble in alcoholEvaporation Rate Not ApplicableViscosity Not applicablepH: 8.6 (Concentration: 52 g/l)Flash Point: Not ApplicableFlammability: Not ApplicableExplosive Properties: Not explosiveOxidizing Properties: Non- OxidizerVapor Pressure: Not ApplicablePartition Coefficient: P (n-octanol/water): Not ApplicableVapor Density: (air=1): Not applicableMolecular Weight: 84.02

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Decomposition Temperature: > 60oC (140oF)Viscosity: Not ApplicableBulk-Density: from 0.5 – 1.2 kg/Dm3 (32-79 lbs/ft3– Typically 60 lbs/ft3)Decomposition Temp: >60oC (140oF)


Stability:Stable under recommended storage conditions.CONDITIONS TO AVOID:NoneMaterials to Avoid:AcidsHazardous Decomposition Products:None


Acute toxicity:Inhalation: LC50, rat, >4.74mg/lOral: LD50, rat, >4,000 mg/kgDermal: LD50, rabbit, no data availableIrritation:• Rabbit; slight irritant (skin).• Rabbit, slight irritant (eyes).

Chronic Toxicity: No observed effectGenetic toxicity in vitro: Remarks: No observed effects.Teratogenicity: Oral route (gavage), 10 days, various species, 330 mg/kg, did not show teratogeniceffects in animal experiments.


Acute Ecotoxicity:• Crustaceans, Daphnia magna, EC50, 48 hours, 4,100 mg/l• Crustaceans, Daphnia magna, NOEC, 48 hours, 3,100 mg/l• Fishes, Lepomis macrochirus, LC50, 96 hours, 7,100 mg/l• Fishes, Lepomis macrochirus, NOEC 96 hours 5,200 mg/l• Fishes, Oncorhynchus mykiss, LC50, 96 hours, 7,700 mg/l• Fishes, Oncorhynchus mykiss, NOEC, 96 hours, 2,300 mg/l

Mobility:• Water: Considerable solubility and mobility.• Soil/sediments: Considerable solubility and mobility.• Air: Not applicable

Persistence and Degradation:Abiotic Degradation:

• Water, hydrolysis • Result: Acid/base equilibrium as a function of pH.• Degradation products: carbonic acid/bicarbonate/carbonate

Biodegradation:• Remarks: The methods for determining biodegradability are not applicable to inorganic

substancesPotential for bioaccumulation: Not applicableOther adverse effects/ Comments: No data availableRemarks: Ecological injuries are not known or expected under normal use.

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Waste Treatment:Sodium Bicarbonate is not a listed hazardous waste under 40 CFR 261. However, state and localregulations for waste disposal may be more restrictive. Spilled product should be disposed of in anEPA approved disposal facility in accordance with applicable national, state and local environmentallaws and regulations.

Packaging Treatment:To avoid treatment, use dedicated containers where possible. Rinse the empty containers and treatthe effluent in the same way as waste. Consult current federal, state and local regulations regardingthe proper disposal of emptied containers.

RCRA: Hazardous Waste: Not Listed


Mode DOT IMDG IATAUN Number Not a regulated

hazardous materialNot a regulatedhazardous material.

Not a regulatedhazardous material.

Other It is recommended that ERG Guide #111 be used for all non-DOT- regulatedmaterials.


CERCLA:Listed: No.Unlisted Substance: No

SARA Title III:Sec. 302/303 Extremely Hazardous Substances (40 CFR355): NoSec. 311/312 (40 CFR 370): NoSec. 313 Toxic Chemical Emissions Reporting (40 CFR 372): No

TSCA Inventory 8(b): Yes

State Component Listing: None identified


HMIS Health:1 Fire:0 Reactivity:0 PPE:Supplied by User; dependent on local conditions


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Product: Leslie's Swimming Pool Supplies Hardness Plus


Trade Name of this Product: Leslie's Swimming Pool Supplies Hardness Plus

MSDS ID Dow 12/14/2005 Revision Date 6/20/2008

Repackager: Manufacturer:LPM Manufacturing, Inc. The Dow Chemical Company3925 East Broadway Rd., Suite 100 2030 Willard H. Dow CenterPhoenix, AZ 85040 Midland, WI 48674Phone Number 602) 366-3999 Emergency Phone: 989-636-4400

Emergency Phone: (800) 424-9300



Calcium Chloride 10043-52-4 > 94.0 - < 97.0%Potassium Chloride 7447-40-7 2.5%Water 7732-18-5 > 0.0 - < 2.0%Sodium Chloride 7647-14-5 1.5%


EMERGENCY OVERVIEWWARNING! Causes eye irritation. May cause skin irritation. May be harmful if swallowed.

Potential Health Effects

Eye Contact:For dust: May cause severe eye irritation. May cause corneal injury. Effects may be slow to heal.Skin Contact:Brief contact is essentially nonirritating to skin. Prolonged contact may cause skin irritation, even aburn. Not classified as corrosive to the skin according to DOT guidelines. May cause more severeresponse if skin is damp. May cause more severe response if skin is abraded (scratched or cut). Maycause more severe response on covered skin (under clothing, gloves).Skin Absorption:Prolonged skin contact is unlikely to result in absorption of harmful amounts.Inhalation:Dust may cause irritation to upper respiratory tract (nose and throat). Vapors are unlikely due tophysical properties.Ingestion:Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal handlingoperations are not likely to cause injury. However, swallowing larger amounts may cause injury.Swallowing may result in gastrointestinal irritation or ulceration.

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Chronic Hazards:The data presented are for the following material: Potassium chloride. In animals, effects have beenreported on the following organs after ingestion: gastrointestinal tract, heart, and kidney. Dose levelsproducing these effects were many times higher than any dose levels expected from exposure due touse.


Eye:Immediately flush eyes with water; remove contact lenses, if present, after the first 5 minutes, thencontinue flushing eyes for at least 15 minutes, Obtain medical attention without delay, preferably froman ophthalmologist.Skin:Wash skin with plenty of water.Inhalation:Move person to fresh air; if effects occur, consult a physician.Ingestion:Do not induce vomiting. Give one cup (8 ounces or 240 ml) of water or milk if available and transport toa medical facility. Do not give anything by mouth to an unconscious person.Notes to Physician: Due to irritant properties, swallowing may result in burns/ulceration of mouth, stomach and lowergastrointestinal tract with subsequent stricture. Aspiration of vomitus may cause lung injury. Suggestendotracheal/esophageal control if lavage is done. If burn is present, treat as any thermal burn, afterdecontamination. No specific antidote. Treatment of exposure should be directed at the control ofsymptoms and the clinical condition of the patient.


Flash Point Not applicableFP Method Not applicableFlammable limits: Not applicableExtinguishing Media:This material does not burn. If exposed to fire from another source, use suitable extinguishing agentfor that fire. Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. This materialdoes not burn. Fight fire for other material that is burning. Water should be applied in large quantitiesas fine spray.Unusual Fire and Explosion Hazards:Heat is generated when the product mixes with water.Fire-fighting Equipment:Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing(includes fire fighting helmet, coat, trousers, boots, and gloves). Avoid contact with this material duringfire fighting operations. If contact is likely, change to full chemical resistant fire fighting clothing withself-contained breathing apparatus. If this is not available, wear full chemical resistant clothing withself- contained breathing apparatus and fight fire from a remote location. For protective equipment inpost-fire or non-fire clean-up situations, refer to the relevant sections.Hazardous Combustion Products: Not applicable

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Personal Protection:Isolate area. Keep unnecessary and unprotected personnel from entering the area. Use appropriatesafety equipment. For additional information, refer to Sections 7 (Handling) and 8 (Exposure andPersonal Protection). Environmental Hazards:Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12(Ecological Information).Spill Cleanup:Small and large spills: Contain spilled material if possible. Collect in suitable and properly labeledcontainers. Flush residue with plenty of water. See Section 13 (Disposal Considerations) for additionalinformation.

CERCLA RQ:Not Available.


Handling:Heat developed during diluting or dissolving is very high. Use cool water when diluting or dissolving(temperature less than 80°F, 27°C). Avoid contact with eyes, skin, and clothing. Do not swallow. Washthoroughly after handling. Keep container closed.Storage:Store in a dry place. Protect from atmospheric moisture.


Exposure LimitsCalcium Chloride DOW IHG TWA 10 mg/m3

Engineering Controls:Provide general and/or local exhaust ventilation to control airborne levels below the exposureguidelines.Respiratory Protection:Atmospheric levels should be maintained below the exposure guideline. When respiratory protection isrequired for certain operations, use an approved air-purifying respirator. In dusty or mistyatmospheres, use an approved particulate respirator. The following should be effective types of air-purifying respirators: particulate filter.Skin Protection:Wear clean body-covering clothing.Eye/Face Protection:Use safety glasses. For dusty operations or when handling solutions of the material, wear chemicalgoggles.Hand Protection:Use gloves chemically resistant to this material. If hands are cut or scratched, use gloves chemicallyresistant to this material even for brief exposures.


Physical State PelletsSpecific Gravity Not applicableBulk Density 52-58 lb./cu. ft. EstimatedColor/Appearance white Odor NoneBoiling/Cond. Point Not applicableMelting/Freezing Point > 1422°F (772°C) Approximate

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Solubility Readily solubleEvaporation Rate Not applicableVOC % Not applicablePercent Volatile Not applicableMolecular Formula Not applicableViscosity Not applicableVapor Density Not applicableVapor Pressure Literature negligible at ambient temperature


Stability:Stable. HygroscopicCONDITIONS TO AVOID:Avoid MoistureMaterials to Avoid (Incompatibilities):Heat is generated when mixed with water. Spattering and boiling can occur. Avoid contact withSulfuric Acid. Corrosive when wet. Flammable hydrogen may be generated from contact with metalssuch as: Zinc, Sodium.Thermal Decomposition:Does not decompose


Acute Toxicity:Ingestion: For the major component(s): LD50, Rat 900 – 2,100 mg/kgSkin Absorption: For the major component(s): LD50, Rabbit > 5,000 mg/kgRepeated Dose Toxicity:The data presented are for the following material: Potassium chloride. In animals, effects have beenreported on the following organs after ingestion: gastrointestinal tract, heart, and kidney. Dose levelsproducing these effects were many times higher than any dose levels expected from exposure due touse.Developmental Toxicity:For the major component(s): Did not cause birth defects or any other fetal effects in laboratoryanimals.Genetic Toxicity:The data presented are for the following material: Calcium Chloride or CaCl2. In vitro genetic toxicitystudies were negative. The data presented are for the following material: Potassium Chloride. In vitrogenetic toxicity studies were positive. However, the relevance of this to humans is unknown.


Chemical Fate:Data for Component: Calcium Chloride

Movement and partitioning No bioconcentration is expected because of the relatively high water solubility. Partitioning fromwater to n-octanol is not applicablePersistence and DegradabilityBiodegradation is not applicable

Data for Component: Potassium ChlorideMovement and PartitioningPartitioning from water to n-octanol is not applicablePersistence and DegradabilityBiodegradation is not applicable

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Data for Component: Sodium ChlorideMovement and PartitioningNo bioconcentration is expected because of the relatively high water solubility. Potential formobility in soil is very high. Partitioning from water to n-octanol is not applicable.Persistence and DegradabilityBiodegradation is not applicable

Ecotoxicity:Data for Component: Calcium ChlorideMaterial is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50 > 100 mg/L inthe most sensitive species tested).

Fish Acute & Prolonged ToxicityLC50, bluegill (Lepomis macrochirus): 8,350 – 10,650 mg/lAquatic Invertebrate Acute ToxicityLC50, water flea Daphnia magna: 759 – 3,005 mg/lToxicity to Micro-organismsEC50; activated sludge, respiration inhibition: > 1,000 mg/l

Data for Component: Potassium ChlorideMaterial is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50 > 100 mg/L inthe most sensitive species tested).

Fish Acute & Prolonged ToxicityLC50, rainbow trout (Oncorhynchus mykiss), 96 h: 4,236 mg/lAquatic Invertebrate Acute ToxicityEC50, water flea Daphnia magna, 24h, immobilization: 590 mg/lLC50, water Ceriodaphnia dubia, 96 h: 3,470 mg/l

Data for Component: Sodium ChlorideMaterial is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50 > 100 mg/L inthe most sensitive species tested).

Fish Acute & Prolonged ToxicityLC50, fathead minnow (Pimephales promelas): 10,610 mg/lAquatic Invertebrate Acute ToxicityLC50, water flea Daphnia magna: 4,571 mg/lToxicity to Micro-organismsIC50, OECD 209 Test; activated sludge, respiration inhibition: > 1,000 mg/l


Disposal Method:All disposal practices must be in compliance with all Federal, State/Provincial and local laws andregulations. Regulations may vary in different locations. Waste characterizations and compliance withapplicable laws are the responsibility solely of the waste generator. The information presented herepertains only to the product as shipped in its intended condition as described in MSDS section:Composition and Information on Ingredients. For unused and uncontaminated product, the preferredoptions include sending to a licensed, permitted: Reclaimer, landfill or waste water treatment system.



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CERCLA:Not applicableSARA Title III:Section 302: Not applicableSection 313: No chemicals under regulation.Section 311/312: Acute Health HazardUSA TSCA:All components of this product are listed on the TSCA Inventory or are exempt from TSCA Inventoryrequirements under 40 CFR 720.30.California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986)This product contains no listed substances known to the State of California to cause cancer, birthdefects or other reproductive harm, at levels which would require a warning under the statute.



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Product: Leslie's Swimming Pool Supplies Soda Ash


Trade Name of this Product: Leslie's Swimming Pool Supplies Soda Ash

MSDS ID General Chem 1/07 Revision Date 6/20/2008

RepackagerLPM Manufacturing, Inc.3925 East Broadway Rd., Suite 100Phoenix, AZ 85040Phone Number(602) 366-3999 Emergency Phone: (800) 424-9300



Sodium Carbonate 497-19-8 99.8%


NFPA Ratings:Health: 2 Fire: 0 Reactivity: 0 Specific: N/A

EMERGENCY OVERVIEWWhite, odorless, granular solid. Product is non-combustible. Reacts with acids to release carbondioxide gas and heat. May irritate skin and eyes. Dusts may irritate respiratory tract. Not expected tobe toxic to the environment, nor to aquatic organisms. Avoid simultaneous exposure to soda ash andlime dust. In the presence of moisture (i.e. perspiration) the two materials combine to form causticsoda (NaOh), which may cause burns.

Eye Contact:Irritating to the eyes.Skin Contact:Prolonged contact may cause skin irritation (red, dry, cracked skin).Inhalation:Prolonged inhalation of product dusts may irritate nose, throat, and lungs.Ingestion:Although low in toxicity, ingestion may cause nausea, vomiting, stomachache, and diarrhea.

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Chronic Hazards:Excessive long-term contact may produce “soda ulcers” on hands and perforation of the nasal septum.Sensitivity reactions may occur from prolonged and repeated exposure. This product does not containany ingredient designated by IARC, NTP, ACGIH or OSHA as a probable or suspected humancarcinogen.


Eye:Immediately flush with water for at least 5 minutes lifting the upper and lower eyelids intermittently. See a medical doctor or ophthalmologist as necessary.Skin:Wash with plenty of soap and water. Get medical attention if irritation occurs and persists. Inhalation:Remove to fresh air. If breathing difficulty or discomfort occurs and persists, obtain medical attention.Ingestion:Rinse mouth with water. Dilute by giving 1 or 2 glasses of water. Do not induce vomiting. Never giveanything by mouth to an unconscious person. Contact a doctor or poison control center.Advice to Physicians:While internal toxicity is low, irritant effects of high concentrations may produce corneal opacities, andvesicular skin reactions in humans with abraded skin only. Treatment is symptomatic and supportive.


Flash Point NoneFP Method Not applicableFlammable limits:Not applicableFire/Explosion Hazards:Not applicableExtinguishing Media:Not combustible, use extinguishing method suitable for surrounding fire.Fire-fighting Equipment/ Procedures:Wear full protective clothing and self-contained breathing apparatus. Hazardous Combustion:Carbon DioxideSensitive to Impact: NoneSensitive to Static Discharge: None


Personal Protection:See section 8 (Exposure Controls and Personal Protection).Environmental Hazards:Prevent large quantities of this product from contacting vegetation or waterways; large spills could killvegetation and fish. Cleanup:This product, if spilled, can be recovered and re-used if contamination does not present a problem.Vacuum or sweep up the material. If the spilled product is unusable due to contamination, consultstate or federal environmental agencies for acceptable disposal procedures and locations. See section13 (Disposal Considerations).Notification Requirements: Federal regulations do not require notification for spills of this product. State and local regulations maycontain different requirements; consult local authorities.CERCLA RQ:Not Applicable

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Handling:Use air conveying/mechanical systems for bulk transfer to storage. For manual handling of bulktransfer use mechanical ventilation to remove airborne dust from railcar, ships or trucks. Use approvedrespiratory protection when ventilation systems are not available. Selection of respirators is based onthe dust cloud generation. Keep material out of lakes, streams, ponds, and sewer drains.Avoid eye contact or prolonged skin contact. Avoid breathing dusts. When dissolving, add to watercautiously and with stirring; solution can get hot. Use good personal hygiene and housekeeping.Storage:Store in a cool, dry area, away from acids. Prolonged storage may cause product to cake fromatmospheric moisture.


Engineering Controls:Where possible, provide general mechanical and/or local exhaust ventilation to prevent release ofairborne dust into the work environment. Eye wash facility should be provided in storage and generalwork area. Respiratory Protection:Whenever dust in the worker’s breathing zone cannot be controlled with ventilation or otherengineering means, workers should wear respirators or dust masks approved by NIOSH/MSHA, EUCEN or comparable certification organization to protect them against airborne dust. Skin Protection:Wear long-sleeve shirt and trousers and impervious gloves for routine product use. Cotton gloves aresufficient for dry product; wear impervious (e.g. rubber, neoprene, etc.) gloves when handling solution. Eye/Face Protection:For dusty or misty conditions or when handling solutions where there is reasonable probability of eyecontact, wear chemical safety goggles and hardhat. Under these conditions do not wear contactlenses. Otherwise, appropriate eye and face protection equipment (ANSI Z87 approved) should beselected for the particular use intended for this material. Safety glasses with side shields arerecommended.Exposure Guidelines:Federal guidelines treat the ingredient(s) in this product as a nuisance dust, as no product-specificguidelines have been issued for exposure. As with all nuisance dusts, worker breathing zoneconcentrations should be measured by validated sampling and analytical methods. The following limits(OSHA and MSHA) apply to this material:

Particulates Not Otherwise Regulated:OSHA (PEL/TWA): 15 mg/m3 (total dust); 5 mg/m3 (rasp fraction)MSHA (PEL/TWA): 10 mg/m3 (total dust)

Avoid simultaneous exposure to soda ash and lime dust. In the presence of moisture (i.e. perspiration)the two materials combine to form caustic soda (NaOH), which may cause burns.

The information noted above provides general guidance for handling this product. Specific workenvironments and material handling practices will dictate the selection and use of personal protectiveequipment (PPE).

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Physical State SolidSpecific Gravity 2.533 (vs. water)Bulk Density g/l Dense grades: 0.9-1.1

Natural light grade: 0.7- 0.9Synthetic light grade: 0.5 – 0.7

Color/Appearance White, granular solidOdor NoneBoiling/Cond. Point decomposes (boiling point)Melting/Freezing Point 854oC (1569oF) (melting point)Solubility CompleteEvaporation Rate Not applicableVOC % not ApplicablePercent Volatile 0%Molecular Formula Na2CO3Viscosity Not applicableVapor Density Not applicableVapor Pressure Not applicablepH (1% solution) 11.3


Stability:StableCONDITIONS TO AVOID:Contact with acids will release carbon dioxide, heat.Contact with lime dust in the presence of moisture can produce corrosive sodium hydroxide. Materials to Avoid (Incompatibilities):May react with aluminum, acids, fluorine, lithium, and 2,4,6-Trinitrotoluene.Hazardous Decomposition Products:When heated to decomposition, carbon dioxide is released.Polymerization:Will not occurOther Precautions:When dissolving, add to water cautiously and with stirring; solutions can get hot.


Acute Data:Eye: Severe irritant (50 mg, rabbit).Skin: Mild irritant (500mg.24hr, rabbit). Minor irritation may occur on abraded skin. Not asensitizer (Tested at 0.25% solution).Oral: LD50 Rat: 4,090 mg/kgInhalation: LC50, rat, 2hr 2.3 mg/l24-hour LC50: 800mg/m3, 20h exposure (guinea pig) (moderate toxicity)

Chronic Data:Excessive, long-term contact may produce “soda ulcers” on hands and perforation of the nasalseptum. Sensitivity reactions may occur from prolonged and repeated exposure.Carcinogenicity:Not designated by IARC, NTP, ACGIH or OSHA as probable or suspected human carcinogens.

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Acute Ecotoxicity:96 – hour LC50: 265-565 mg/l (daphnia magnia) (low toxicity)

300-320 mg/l (blue gill sunfish) (low toxicity)96 – hour TLm: 1,200 mg/l (mosquito-fish)48 – hour TLm: 840 mg/l (mosquito-fish)48 – hour EC50: 265 mg/l (daphnia magnia)5 Day EC50: 242 mg/l (Nitszcheria linearis)Chronic Ecotoxicity:7 Day EC, biomass: 14 mg/l (phytoplankton)Mobility:

Air: Not ApplicableWater: Considerable solubility and mobility.Soil/sediments: Non-significant absorption

Abiotic Degradation: Water (hydrolysis): degradation's products: carbonate (pH>10)/ carbonic acid / carbon dioxide(pH<6)Soil: Hydrolysis as a function of pH.

Biotic Degradation:Aerobic/anaerobic: Not applicable (Inorganic compound)

Potential for Bioaccumulaion: Not applicable (ionizable inorganic compound)

Observed effects are related to alkaline properties of the product. Product is not significantlyhazardous for the environment.


Classification:When this product is discarded or disposed of, as purchased, it is neither a characteristic nor a listedhazardous waste according to U.S. Federal RCRA regulations (40 CFR 261). Disposal Method:As a non-hazardous waste the material may be disposed of in a landfill in accordance withgovernment regulations; check local or state regulations for applicable requirements prior to disposal.Any processing, usage, alteration, chemical additions to, or contamination of the product may alterthe disposal requirements. Under Federal regulations, it is the generator’s responsibility to determineif a waste is a hazardous waste.




CERCLA:No CERCLA Reportable Quantity has been established for this material.SARA Title III:Section 302: Not an Extremely Hazardous Substance Section 313: Not a Toxic Chemical Section 311/312:Hazard Categories- Immediate (Acute)USA TSCA:This product is listed on the TSCA Inventory of Chemical Substances. No other TSCA rules affect thisproduct.

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STATE REGULATIONS: This product does not contain any components that are regulated under California Proposition 65.


HMIS:Health: 2 Flammability: 0 Reactivity: 0 Special: None


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Product: Leslie's Swimming Pool Supplies Algae Control


Trade Name of this Product: Leslie's Swimming Pool Algae Control

MSDS ID Buckman 11/3/06 Revision Date 06/19/2008

Registrant: Supplier:LPM Manufacturing, Inc. Buckman Laboratories, Inc.3925 East Broadway Rd., Suite 100 1256 N. McLean Blvd.Phoenix, AZ 85040 Memphis, TN 38108Phone Number Emergency Phone: 901-767-2722(602) 366-3999

Emergency Phone: (800) 424-9300


Ingredient CAS Number Weight % ACGIH TLV PEL STELBased on best available information, this product does not contain any reportable OSHA hazardousmaterials.


NFPA Ratings:Health: 1 Flammability: 1 Reactivity: 0 Specific: N/A

EMERGENCY OVERVIEWIrritating to eyes.

1. Effects from Acute Exposure:Eye Contact:Slightly hazardous in case of eye contact (irritant). Skin Contact:Slightly hazardous in case of skin contact (irritant). Non-sensitizer for skin. Skin inflammation ischaracterized by itching, scaling, reddening, or, occasionally, blistering.Inhalation:Slightly hazardous in case of inhalation. Effects will depend on concentration and length of time of exposure.Ingestion:Ingestion is not expected to be a primary route of exposure.

2. Effects from Chronic Exposure:The effects from chronic exposure to this product have not been fully evaluated.

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Eye:Flush immediately with copious amounts of tap water or normal saline (minimum of 15 minutes). Takeexposed individual to a health care professional, preferably an ophthalmologist, for further evaluation.Skin:Wash exposed area with plenty of water. Repeat washing. Remove contaminated clothing and washthoroughly before reuse. If irritation persists consult a health care professional. Inhalation:If exposure by inhalation is suspected, immediately move exposed individual to fresh air. If individualexperiences nausea, headache, dizziness, has difficulty breathing or is cyanotic, see a health careprofessional immediately.Ingestion:DO NOT INDUCE VOMITING. Rinse with copious amounts of water or milk, first. Irrigate theesophagus and dilute stomach contents by slowly giving one (1) to two (2) glasses of water or milk.Avoid giving alcohol or alcohol related products. In cases where the individual is semi-comatose,comatose or convulsing, DO NO GIVE FLUIDS BY MOUTH. In case of intentional ingestion of theproduct seek medical assistance immediately; take individual to nearest medical facility.


Flammable limits:Not availableExtinguishing Media:Water fog, carbon dioxide, foam, dry chemical.Special Firefighting Procedure:Fire fighters should wear positive pressure self-contained breathing apparatus (SCBA) and full turnoutgear.


Important: Before responding to a spill or leak of this product, review each section of this MSDS.Follow the recommendations given in the Handling and Storage section. Ensure that spilled or leakedproduct does not come into contact with materials listed as incompatible. If irritating fumes are present,consider evacuation of enclosed areas.

Initially minimize area affected by the spill or leak. Block any potential routes to water systems (e.g.sewers, streams, lakes, etc.). Based on the product’s toxicological and chemical properties and on thesize and location of the spill or leak, assess the impact on contaminated environments (e.g. watersystems, ground, air equipment, etc.). There are no methods available to completely eliminate anytoxicity this product may have on aquatic environments. Minimize adverse effects on theseenvironments. Determine if federal, state, and/or local release notification is required. Recover asmuch of the pure product as possible into appropriate containers. Later, determine if this recoveredproduct can be used for its intended purpose. Address clean up of contaminated environments. Spill orleak residuals may have to be collected and disposed of. Clay, soil, or commercially availableabsorbents may be used to recover any materials that can not readily be recovered as pure product.Flushing residual material to an industrial sewer, if present at the site of a spill or leak incident, may beacceptable if authorized approval is obtained. If product and/or spill/leak residuals are flushed to anindustrial sewer, insure that they do not come into contact with incompatible materials.

CERCLA RQ:There is no CERCLA Reportable Quantity for this material. If a spill goes off site, notificationof state and local authorities is recommended.

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Handling:Eyewash fountains in the work place are recommended. Rubber gloves safety glasses or goggles andbody protective clothing and shoes are required. The handling precautions for this product are basedon the characteristics of the neat product unless otherwise specified.


Physical State LiquidDensity 1.15 g/cm3

Color/Appearance Clear, pale yellow liquidOdor MildFlash Point Closed cup: >100°C (212°F) (Tagliabue)Boiling/Cond. Point > 212°F (100°C)Melting/Freezing Point <-16o C (3.2oF)Solubility Easily soluble in cold water. Easily soluble in hot water.pH (Neat) 7 [Neutral.]pH (100 ppm in water) 6-7o/w partition Coefficient Not availableOxidizing/ Reduction Properties Not availableViscosity Kinetic: 125cSVapor Pressure Not availableAdditional pH Information pH (neat) = 6.0 – 8.0

NOTE: The physical data presented above are typical values and should not be construed asspecifications.


Stability:Stable under normal conditions of use and storage. Incompatibility:Anionic polymersHazardous Decomposition Products:Carbon monoxide may be formed upon burning.


Acute Data:Acute Oral (LD50) = 1,951 mg/kg Male ratAcute Oral (LD50) = 2,587 mg/kg Female ratAcute Dermal (LD50) = >2,000 mg/kg RabbitAcute Inhalation (LC50) = 2.9 ppm (4 hours) ratIrritant/Sensitization Effects:Slightly hazardous in case of eye contact (irritant).Slightly hazardous in case of skin contact (irritant). Non-sensitizer for skin. Skin inflammation ischaracterized by itching, scaling, reddening, or, occasionally, blistering.Slightly hazardous in case of inhalation. Effects will depend on concentration and length of time ofexposure. Carcinogenic Potential:Not shown as a carcinogen by OSHA, IARC, or NTP. A two-year rat carcinogenicity study showed aslight increase in c-cell adenomas in female rats. Studies with male rats and male and female micedid not show any evidence of carcinogenic response. This product is not considered a carcinogen. Target Organs Effect:May cause damage to the following organs: upper respiratory tract, skin, eyes.

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Other Health Effects:None known.


LC50 = 0.37 mg/l 48 hours InvertebrateLC50 = 0.26 mg/l 96 hours Fathead MinnowLC50 = 0.21 mg/l 96 hours Bluegill SunfishLC50 = 0.047 mg/l 96 hours Rainbow TroutLC50 = >600 mg/l 96 hours Sheepshead MinnowLC50 = 13 mg/l 96 hours Mysid Shrimp


Contaminated Materials:Determine if waste containing this product can be handled by an available industrial effluent system,or an on-site waste management unit. If off-site management is required, contact a companyexperienced in industrial waste management. This product is not specifically listed in 40CFR 261 as aResource Conservation and Recovery Act (RCRA) hazardous waste. However, spill or leak residualsmay meet the criteria of a characteristic hazardous waste under this Act. Check the characteristics ofthe material to be disposed of and/or the physical and reactivity data given in this MSDS for the neatproduct.

Container Disposal:Empty containers as defined by appropriate sections of the RCRA, are not RCRA hazardous wastes.However, insure proper management of any residuals remaining in the container.


DOT Shipping Information:Not regulated.IMO/IMDG Shipping Information:UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., (Polyoxyethylene(dimethyliminio) ethylene (dimethyliminio) ethylene dichloride]), Class 9, P.G. III, MARINEPOLLUTANT (EMS No. F-A, S-F, ERG Guide 171, Haz Mat Code 4960131)IATA Shipping Information:Not regulatedDOT “RQ”: NONE


CERCLA:No components of this product are listed. SARA:

SARA 302 Extremely Hazardous Substances ListNo components of this product are listedSARA 312 Hazard CategoryImmediate (Acute Health Hazard)SARA 313 Toxic Chemicals ListNo components of this product are present above the de minimus levels.

TSCA:All components may not be listed on the TSCA Inventory. Registered pesticides are exempt fromrequirements of TSCA.RCRA:No components of this product are listed

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CWA:No components of this product are listed.FDA:This product is not approved for food contact uses. NSF:This product is listed by the NSF under NSF/ANSI Standard 60 for use in potable water applicationswith the following maximum allowable use rates: Concentration of 2-5 ppm can be used at theinitiation of treatment for up to 21 days. Thereafter, the maximum use rate is 0.5 ppm for potablewater systems. FIFRA:This product is a registered pesticide. EPA Reg. No. 11411-11.



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Leslie's Copper Algaecide REVISION DATE : 09/14/2011 Page 1 of 14

FOR ANY EMERGENCY, 24 HOURS / 7 DAYS, CALL: FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTREC®: FOR ALL MSDS QUESTIONS & REQUESTS, CALL:

1-800-654-6911 (OUTSIDE USA: 1-423-780-2970) 1-800-424-9300 (OUTSIDE USA: 1-703-527-3887) 1-800-511-MSDS (OUTSIDE USA: 1-423-780-2347)

PRODUCT NAME: Leslie's Copper Algaecide

1. PRODUCT AND COMPANY IDENTIFICATION Supplier Leslie's Pool Mart Inc. 3925 E Broadway Road Ste #100 , Phoenix, AZ, 85040 United States Telephone: +18002338063 Telefax: +16025677991 Web: Manufacturer Advantis Technologies 1400 Bluegrass Lakes Parkway Alpharetta, GA 30004 United States of America

REVISION DATE: 09/14/2011 SUPERCEDES: 06/02/2011

MSDS Number: 000000012492 SYNONYMS: CHEMICAL FAMILY: None DESCRIPTION / USE None established FORMULA: None established

2. HAZARDS IDENTIFICATION

OSHA Hazard Classification:

Slight Eye Irritant

Routes of Entry: Eyes Skin Ingestion Chemical Interactions: None known. Medical Conditions Aggravated: None known.

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Human Threshold Response Data

Odor Threshold Not established for product.

Irritation Threshold Not established for product.

Hazardous Materials Identification System / National Fire Protection Association Classifications

Hazard Ratings : Health Flammability Physical / Instability PPI / Special hazard.

HMIS 1 0 1 NFPA 1 0 0

Immediate (Acute) Health Effects Inhalation Toxicity: Not expected to be an inhalation hazard at ambient conditions.

Inhalation of mist or vapor may cause irritation to the mucous membranes of the respiratory tract.

Skin Toxicity: Not expected to be irritating to the skin. Not expected to be toxic from dermal contact.

Eye Toxicity: Contact would be expected to cause minor irritation, consisting of transient redness and swelling. No corneal involvement or visual impairment is expected.

Ingestion Toxicity: Slightly toxic if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea.

Acute Target Organ Toxicity: May cause mild eye irritation. Ingestion may cause mild gastrointestinal discomfort., Inhalation of mist or vapor may cause irritation to the mucous membranes of the respiratory tract.

Prolonged (Chronic) Health Effects Carcinogenicity: This product is not known or reported to be carcinogenic by any

reference source including IARC, OSHA, NTP or EPA. Reproductive and Developmental Toxicity:

Not known or reported to cause reproductive or developmental toxicity.

Inhalation: There are no known or reported effects from chronic exposure except for effects similar to those experienced from acute exposure.

Skin Contact: There are no known or reported effects from chronic exposure. Skin Absorption: There are no known or reported effects from chronic exposure. Ingestion: There are no known or reported effects from chronic ingestion except for

effects similar to those experienced from single exposure. Sensitization: This material is not known or reported to be a skin or respiratory

sensitizer. Chronic Target Organ Toxicity: There are no known or reported effects to humans from repeated

exposure to this product. Supplemental Health Hazard Information :

No additional health information available.

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3. COMPOSITION / INFORMATION ON INGREDIENTS

CAS OR CHEMICAL NAME CAS # % RANGE Triethanolamine

102-71-6

Ethanolamine

141-43-5

BASIC COPPER CARBONATE

12069-69-1

Citric Acid

77-92-9

4. FIRST AID MEASURES General Advice: Call a poison control center or doctor for treatment advice. For 24-hour

emergency medical assistance, call Arch Chemical Emergency Action Network at 1-800-654-6911. Have the product container or label with you when calling a poison control center or doctor, or going for treatment.

Inhalation: IF INHALED: Move person to fresh air. If person is not breathing, call 911 or an

ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice.

Skin Contact: IF ON SKIN OR CLOTHING: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice.

Eye Contact: IF IN EYES: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice.

Ingestion: IF SWALLOWED: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person.

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5. FIRE FIGHTING MEASURES Flammability Summary (OSHA): The product is not flammable., Not combustible., The substance or

mixture is not classified as pyrophoric., Not explosive

Flammable Properties Fire / Explosion Hazards: Will not burn Extinguishing Media: Carbon dioxide (CO2) Dry powder Foam Fire Fighting Instructions: Use water spray to cool unopened containers. In case of fire, use

normal fire-fighting equipment and the personal protective equipment recommended in Section 8 to include a NIOSH approved self-contained breathing apparatus.

Hazardous Combustion Products: During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.

6. ACCIDENTAL RELEASE MEASURES Personal Protection for Emergency Situations:

Use the personal protective equipment recommended in Section 8 and a NIOSH approved self-contained breathing apparatus.

Spill Mitigation Procedures Air Release: Vapors may be suppressed by the use of water fog.Keep people

away from and upwind of spill/leak. Water Release: This material is soluble in water.If the product contaminates rivers

and lakes or drains inform respective authorities. Land Release: Contain spillage, soak up with non-combustible absorbent material,

(e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13).After removal, flush contaminated area thoroughly with water.Avoid runoff into storm sewers and ditches which lead to waterways.

Additional Spill Information : Prevent further leakage or spillage if safe to do so. Use personal protective equipment as required. Evacuate personnel to safe areas.

7. HANDLING AND STORAGE Handling: Do not take internally. Avoid contact with skin, eyes and clothing. If

in eyes or on skin, rinse well with water. Avoid breathing vapors, mist or gas.

Storage: Store in a cool, dry and well ventilated place. Isolate from incompatible materials. Do not freeze.

MATERIAL SAFETY

DATA SHEET


Incompatible Materials for Storage: Refer to Section 10, "Incompatible Materials."

8. EXPOSURE CONTROLS / PERSONAL PROTECTION Ventilation: Local exhaust ventilation or other engineering controls are normally required

when handling or using this product to keep airborne exposures below the TLV, PEL or other recommended exposure limit.

Protective Equipment for Routine Use of Product Respiratory Protection : Wear a NIOSH approved respirator if levels above the exposure limits are

possible., A NIOSH approved air purifying respirator with organic vapor cartridge and N95 particulate filter. Air purifying respirators should not be used in oxygen deficient or IDLH atmospheres or if exposure concentrations exceed ten (10) times the published limit.

Skin Protection : Avoid contact with skin. Impervious gloves Eye Protection: Safety glasses with side-shields Protective Clothing Type: impervious clothing General Protective Measures:

Emergency eyewash should be provided in the immediate work area.

Exposure Limit Data CHEMICAL NAME CAS # Name of Limit Exposure Triethanolamine 102-71-6 ACGIH 5 mg/m3 TWA

Ethanolamine 141-43-5 ACGIH 3 ppm TWA

Ethanolamine 141-43-5 ACGIH 6 ppm STEL

Ethanolamine 141-43-5 OSHA Z1 3 ppm TWA

6 mg/m3 TWA

Ethanolamine 141-43-5 NIOSH-IDLH 30 ppm

BASIC COPPER CARBONATE 12069-69-1 ACGIH 1 mg/m3 Calculated as Cu TWA dusts and mists

BASIC COPPER CARBONATE 12069-69-1 OSHA Z1 1 mg/m3 TWA dusts and mists

BASIC COPPER CARBONATE 12069-69-1 NIOSH-IDLH 100 mg/m3

MATERIAL SAFETY

DATA SHEET


9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: liquid Form No data. Color: No data. Odor: No data. Molecular Weight: None established Specific Gravity : 1.190 - 1.210

20 °C pH : 9.7 - 10.3

Boiling Point: 100 °C

212 °F

Freezing Point: not applicable

Melting Point: not applicable

Density: not applicable Bulk Density: no data available Vapor Pressure: no data available Vapor Density: no data available Viscosity: no data available no data available Solubility in Water: soluble in cold water Partition coefficient n-octanol/water:

not applicable

Evaporation Rate: <1 Oxidizing: None established Volatiles, % by vol.: no data available VOC Content no data available HAP Content Not applicable

10. STABILITY AND REACTIVITY Stability and Reactivity Summary: Stable under normal conditions. Conditions to Avoid: Heat, flames and sparks. Chemical Incompatibility: Acids, Nitrites Hazardous Decomposition Products: Carbon oxides, nitrogen oxides (NOx), Hydrogen chloride Decomposition Temperature: No data

11. TOXICOLOGICAL INFORMATION

MATERIAL SAFETY

DATA SHEET


Component Animal Toxicology Oral LD50 value: Triethanolamine LD50 = 7,390 mg/kg Rat Ethanolamine LD50 = 1,700 mg/kg rat BASIC COPPER CARBONATE

LD50 = 1,350 mg/kg rat

Citric Acid LD50 = 3,000 mg/kg rat Component Animal Toxicology Dermal LD50 value: Triethanolamine LD50 > 2,000 mg/kg Rabbit Ethanolamine LD50 Approximately 1,000 mg/kg rabbit BASIC COPPER CARBONATE

no data available

Citric Acid LD50 Believed to be > 2,000 mg/kg rabbit Component Animal Toxicology Inhalation LC50 value: Triethanolamine A saturated vapor concentration for 8 hours (rats) did not produce any deaths. Ethanolamine LC50 1 h > 4.8 MG/L mouse Ethanolamine LC50 4 h > 970 ppm mouse BASIC COPPER CARBONATE

no data available

Citric Acid no data available Product Animal Toxicity Oral LD50 value: LD50 Believed to be approximately 4,200 mg/kg rat Dermal LD50 value: LD50 Believed to be > 2,000 mg/kg rabbit Inhalation LC50 value:

no data available

Skin Irritation: Not expected to be irritating to the skin. Eye Irritation: slight irritation Skin Sensitization: This material is not known or reported to be a skin or respiratory sensitizer. Acute Toxicity: May cause mild eye irritation. Ingestion may cause mild gastrointestinal

discomfort.Inhalation of mist or vapor may cause irritation to the mucous membranes of the respiratory tract.

Subchronic / Chronic Toxicity:

Not known or reported to cause subchronic or chronic toxicity.

Reproductive and Developmental Toxicity:

Not known or reported to cause reproductive or developmental toxicity.

Triethanolamine This product has been tested and was shown not to

produce any adverse effects on reproductive function or fetal development when administered to laboratory

MATERIAL SAFETY

DATA SHEET


animals.

Ethanolamine This chemical has been tested in laboratory animals and no evidence of teratogenicity, embryotoxicity or fetotoxicity was seen.

Citric Acid This chemical has been tested in laboratory animals

and there was no evidence of reproductive toxicity or teratogenicity.

Mutagenicity: Not known or reported to be mutagenic.

Triethanolamine This chemical has been shown to be non-mutagenic based on a battery of assays.

Ethanolamine This chemical has been tested in a battery of mutagenicity/genotoxicity assays and the results were negative.

Citric Acid This product was determined to be non-mutagenic in the Ames assay. It was also shown to be negative in the Dominant lethal assay.

Carcinogenicity: This product is not known or reported to be carcinogenic by any reference

source including IARC, OSHA, NTP or EPA. Triethanolamine The International Agency for Research on Cancer

(IARC) has classified this product or a component of this product as a Group 3 substance, Unclassifiable as to Its Carcinogenicity to Humans.

Ethanolamine This product is not known or reported to be carcinogenic by any reference source including IARC, OSHA, NTP or EPA. Chemicals of similar structure have been shown not to cause cancer in laboratory animals.

Citric Acid The carcinogenicity has been evaluated through animal study and it was found not to be carcinogenic.

12. ECOLOGICAL INFORMATION Overview: Toxic to fish and other aquatic organisms. Ecological Toxicity Values for: Triethanolamine

Fathead minnow (Pimephales promelas),

- (measured, flow-through) 96 h LC50 = 11,800 mg/l

Daphnia magna, - (nominal, static). 24 h EC50= 1,850 mg/l Common shrimp (Crangon crangon)

- (nominal, renewal). 48 h LC50> 100 mg/l

MATERIAL SAFETY

DATA SHEET


Green algae (Scenedesmus subspicatus)

- (nominal, static). 48 h EC50 = 750 mg/l

Ecological Toxicity Values for: Ethanolamine

Rainbow trout (Oncorhynchus mykiss)

- (nominal, static). 96 h LC50 = 150 mg/l

Mosquito fish - (nominal, static). 96 h LC50 = 337.5 mg/l Bluegill - (nominal, static). 96 h LC50 = 329.16 mg/l Fathead minnow (Pimephales promelas),

- (measured, flow-through) 96 h LC50 = 2,070 mg/l

Goldfish - (measured, static) 96 h LC50 = 170 mg/l Daphnia magna (Water flea) - (nominal, static). 24 h LC50= 140 mg/l

Crangon crangon (shrimp) - (nominal, renewal). 48 h LC50> 100 mg/l Brine shrimp - 48 h LC50= 7,100 mg/l Daphnia magna (Water flea) - 48 h EC50= 65 mg/l

Ecological Toxicity Values for: Citric Acid

Lepomis macrochirus (Bluegill sunfish)

- (static). 96 h LC50 = 1,516 mg/l

Daphnia magna (Water flea) - 72 h EC50Approximately 120 mg/l

13. DISPOSAL CONSIDERATIONS CARE MUST BE TAKEN TO PREVENT ENVIRONMENTAL CONTAMINATION FROM THE USE OF THE MATERIAL. THE USER OF THE MATERIAL HAS THE RESPONSIBILITY TO DISPOSE OF UNUSED MATERIAL, RESIDUES AND CONTAINERS IN COMPLIANCE WITH ALL RELEVANT LOCAL, STATE AND FEDERAL LAWS AND REGULATIONS REGARDING TREATMENT, STORAGE AND DISPOSAL FOR HAZARDOUS AND NONHAZARDOUS WASTES. Waste Disposal Summary : If this product becomes a waste, it DOES NOT meet the criteria of a

hazardous waste as defined under 40 CFR 261, in that it does not exhibit the characteristics of hazardous waste of Subpart C, nor is it listed as a hazardous waste under Subpart D.As a nonhazardous liquid waste, it should be disposed of in accordance with local, state and federal regulations.

Potential US EPA Waste Codes : not applicable

MATERIAL SAFETY

DATA SHEET


14. TRANSPORT INFORMATION Land (US DOT): Not Regulated NOT REGULATED AS A DOT HAZARDOUS MATERIAL Water (IMDG): Not Regulated NOT REGULATED AS A HAZARDOUS MATERIAL,

Marine Pollutant: No

Air (IATA): Not Regulated NOT REGULATED AS A HAZARDOUS MATERIAL, Emergency Response Guide Number: Not applicable

15. REGULATORY INFORMATION UNITED STATES: Toxic Substances Control Act (TSCA): This is an EPA registered pesticide. EPA Pesticide Registration Number: None established FIFRA Listing of Pesticide Chemicals (40 CFR 180):

This product is regulated under the Federal Insecticide, Fungicide and Rodenticide Act. It must be used for purposes consistent with its labeling.

Superfund Amendments and Reauthorization Act (SARA) Title III: Hazard Categories Sections 311 / 312 (40 CFR 370.2): Health Immediate (Acute) Health Hazard Physical None Emergency Planning & Community Right to Know (40 CFR 355, App. A): Extremely Hazardous Substance Section 302 - Threshold Planning Quantity:

ZUS_SAR302 TPQ (threshold planning quantity)

None established

Reportable Quantity (49 CFR 172.101, Appendix):

ZUS_CERCLA Reportable quantity Diethanolamine Value: 100lbs

ZUS_SAR302 Reportable quantity None established

Supplier Notification Requirements (40 CFR 372.45), 313 Reportable Components

ZUS_SAR313 De minimis concentration Diethanolamine Value: < 1% by weight

Clean Air Act Toxic ARP Section 112r:

MATERIAL SAFETY

DATA SHEET


CAA 112R None established Clean Air Act Socmi: HON SOC US. EPA Hazardous Organic NESHAP (HON) Synthetic Organic Chemicals (40 CFR 63.100-.106, Table 1) 07 1999 Group I DIETHANOLAMINE (2,2'-IMINODIETHANOL) US. EPA Hazardous Organic NESHAP (HON) Synthetic Organic Chemicals (40 CFR 63.100-.106, Table 1) 07 1999 Group I ETHANOLAMINE US. EPA Hazardous Organic NESHAP (HON) Synthetic Organic Chemicals (40 CFR 63.100-.106, Table 1) 07 1999 Group I TRIETHANOLAMINE Clean Air Act VOC Section 111: CAA 111 US. EPA Clean Air Act (CAA) Section 111 SOCMI Intermediate or Final Volatile Organic Compounds (40 CFR 60.489) 01 1996 ETHANOLAMINE Clean Air Act Haz. Air Pollutants Section 112: ZUS_CAAHAP None established ZUS_CAAHRP None established CAA AP US. EPA Hazardous Organic NESHAP (HON) Hazardous Air Pollutants (40 CFR 63.100-.106, Table 2) 04 1999 DIETHANOLAMINE (2,2'-IMINODIETHANOL) State Right-to-Know Regulations Status of Ingredients Pennsylvania:CAS # COMPONENT NAME 141-43-5 Ethanolamine

MATERIAL SAFETY

DATA SHEET


102-71-6 Triethanolamine ZUSPA_RTK Pennsylvania: Hazardous substance list

1989-08-11 ETHANOL, 2-AMINO-

Pennsylvania: Hazardous substance list

1989-08-11 ETHANOL, 2,2',2''-NITRILOTRIS-

New Jersey:CAS # COMPONENT NAME 141-43-5 Ethanolamine 102-71-6 Triethanolamine ZUSNJ_RTK New Jersey Right to Know Hazardous Substance List (RTK-HSL)

2007-03-01 ETHANOLAMINE MONOETHANOLAMINE ETHANOL, 2-AMINO- Special Health Hazard - Corrosive

New Jersey Right to Know Hazardous Substance List (RTK-HSL)

2007-03-01 TRIETHANOLAMINE ETHANOL, 2,2',2"-NITRILOTRIS-

Massachusetts:CAS # COMPONENT NAME 141-43-5 Ethanolamine 102-71-6 Triethanolamine ZUSMA_RTK Massachusetts Right to Know List of Chemicals and Hazard Classifications

1993-04-24 ETHANOLAMINE 2-AMINOETHANOL

Massachusetts Right to Know List of Chemicals and Hazard Classifications

1993-04-24 TRIETHANOLAMINE

MATERIAL SAFETY

DATA SHEET


California Proposition 65: CAS # COMPONENT NAME ZUSCA_P65

None established

WHMIS Hazard Classification: Ingredient Disclosure List (WHMIS) 2007-08-24 Threshold limits: 1 Weight percent 80 Citric acid Ingredient Disclosure List (WHMIS) 2007-08-24 Threshold limits: 1 Weight percent 1170 Monoethanolamine Ingredient Disclosure List (WHMIS) 2007-08-24 Threshold limits: 1 Weight percent 1663 Triethanolamine Ingredient Disclosure List (WHMIS) 2007-08-24 Threshold limits: 1 Weight percent 985 Copper(II) carbonate hydroxide

16. OTHER INFORMATION MSDS REVISION STATUS : SECTIONS REVISED: 2, 4, 8, 11 Major References : Available upon request.

MATERIAL SAFETY

DATA SHEET


THIS MATERIAL SAFETY DATA SHEET (MSDS) HAS BEEN PREPARED IN COMPLIANCE WITH THE FEDERAL OSHA HAZARD COMMUNICATION STANDARD, 29 CFR 1910.1200. THE INFORMATION IN THIS MSDS SHOULD BE PROVIDED TO ALL WHO WILL USE, HANDLE, STORE, TRANSPORT, OR OTHERWISE BE EXPOSED TO THIS PRODUCT. THIS INFORMATION HAS BEEN PREPARED FOR THE GUIDANCE OF PLANT ENGINEERING, OPERATIONS AND MANAGEMENT AND FOR PERSONS WORKING WITH OR HANDLING THIS PRODUCT. ARCH CHEMICALS BELIEVES THIS INFORMATION TO BE RELIABLE AND UP TO DATE AS OF THE DATE OF PUBLICATION BUT, MAKES NO WARRANTY THAT IT IS. ADDITIONALLY, IF THIS MSDS IS MORE THAN THREE YEARS OLD, YOU SHOULD CONTACT ARCH CHEMICALS MSDS CONTROL AT THE PHONE NUMBER ON THE FRONT PAGE TO MAKE CERTAIN THAT THIS DOCUMENT IS CURRENT. .

6Print Rev. Date 02/13/2006

MSDS Document

Product Phos Free


Trade Name of this Product Phos FreeSynonyms: Phosphate Remover

MSDS ID NC-MS017

Manufacturer

Natural Chemistry, Inc.

40 Richards Ave.

Norwalk, CT 06854

Contact Name

Tom Berry

Phone Number

(800) 753-1233

Emergency Phone

CHEMTREC (800) 424-9300

Revision Date 12/16/2005

10

0Health

Fire

Reactivity

Specific

Health:

Fire:

Reactivity:

Specific

1

0

0


Ingredient CAS Number Weight % ACGIH TLV PEL STELLanthanum Sulfate 10099-60-2 3-10 % Not established Not established Not established

Lanthanum Chloride 10099-58-8 5-12 %

Sodium chloride 7647-14-5 2-5 % Not Established Not Established Not Established

Water 7732-18-5 75-88 % 0


Routes of Exposure Ingestion, eye and skin contact are the most significant routes of exposure in occupationaland other settings.

Eye Contact: Causes irritation

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6Print Rev. Date 02/13/2006MSDS ID NC-MS017Phos Free

Skin Contact: Causes irritation

Ingestion Irritation of mouth and throat, nausea and mild diarrhea.

Inhalation Mucous membrane irritation.

Acute and Chronic Exposure May cause irritation to eyes, skin, throat and stomach.

Aggravation of Pre-existing Conditions May aggravate existing skin, respiratory and digestive problems.


Eye: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Getmedical attention.

Skin: In case of contact, immediately flush skin with plenty of water. Remove contaminatedclothing and shoes. Get medical attention.

Ingestion: If swallowed, DO NOT induce vomiting. Get medical attention immediately. If victim is fullyconscious, give a cupful of water. Never give anything by mouth to an unconscious person.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, giveoxygen. Get medical attention.


Flash Point Not KnownFP Method Not known

Fire Non-flammable or combustible

EXTINGUISHING MEDIA: Nonflammable, use agent suitable for surrounding fire.

Unusual Fire or Explosion Procedures Non-explosive. No other special or unusual fire fighting procedures are necessary.


Occupational Release Product is biodegradable. Contain spill and dispose of in accordance with all local, state and


Federal guidelines.


Storage Precautions May induce rusting of mild steel containers.

Storage Information Storage and shipping temperature should not exceed 120° F (49° C)

STORAGE

Keep product away from heat, oxidizers and bactericides. Store out of direct sunlight. Useproduct within 12 months.


Ventilation System Normal ventilation is all that is required.

SKIN PROTECTION: If skin contact is likely, wear rubber gloves and protective clothing. Wash thoroughly afterhandling.

Respiratory Protection: Use a NIOSH-approved dust and mist respirator where spray mist occurs. Observe OSHAregulations for respirator use (29 C.F.R. §1910.134)

Eye Protection: Wear chemical goggles.


Physical State SuspensionSpecific Gravity 1.076Density lbs/Gal. 8.963Color/Appearance White, opaqueOdor Mild sweetpH 2.1 - 2.3Boiling/Cond. Point >212°FMelting/Freezing Point 32°FSolubility Particulate partially solubleVOC % N/APercent Volatile N/AMolecular Formula MixtureViscosity N/AVapor Density N/AVapor Pressure N/A

Physical and chemical properties listed above are general and approximate and are notintended as product specifications.



STABILITY: Stable at normal temperatures and pressure.

HAZARDOUS DECOMPOSITION PRODUCTS: None (Refer to Conditions to Avoid)

HAZARDOUS POLYMERIZATION: Will not occur.

Incompatibilities Caustics above 9.0 pH and acids below 3.5 pH

CONDITIONS TO AVOID Temperatures above 120° FFreezingStrong acids or alkalies

Oxidizers


TOXICITY DATA:

CARCINOGENICITY STATUS: This product is NOT listed as a carcinogen or suspected carcinogen by NTP, IARC, or OSHA.


Environmental Fate: Unknown

Environmental Toxicity Unknown


Classification: Disposed material is not a hazardous waste.

Disposal Guidance Material that cannot be saved for recovery or recycling may be flushed to waste watertreatment facilities or drain systems.

DISPOSAL METHOD: Dispose of in accordance with applicable Federal, State and local environmental andregulatory requirements.


DOT UN Status: This material is not regulated hazardous material for transportation.


Proper Shipping Name: Not applicable/Not regulated


U.S. REGULATIONS:

SARA TITLE III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.30): Not regulated.

CERCLA SECTIONS 102a/103 HAZARDOUS SUBSTANCES (40 CFR 302.4): Not regulated.

U.S. INVENTORY (TSCA): All the components of this substance are listed on or are exempt from the inventory.

STATE REGULATIONS:

CALIFORNIA PROPOSITION 65: Not regulated.

NEW JERSEY WORKER AND COMMUNITY RIGHT TO KNOW:

RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST: Not regulated.

PENNSYLVANIA RIGHT TO KNOW:

RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST: Not regulated.


Other Information The information presented herein, while not guaranteed, was prepared by competenttechnical personnel and is based upon information Natural Chemistry, Inc. believes to betrue, accurate and reliable and is supplied for informational purposes only. NaturalChemistry, Inc. disclaims any liability for damage which results from the use of the aboveinformation and nothing contained therein shall constitute a guarantee, warranty (includingfitness for a particular purpose) or representation by Natural Chemistry, Inc. with respect tothe accuracy or completeness of the data, the product described or their use for any specificpurpose even if that purpose is known to Natural Chemistry, Inc.. Factors pertaining tocertain conditions of storage, handling, or use of this product may involve other oradditional safety or performance considerations. While our technical personnel will behappy to respond to questions regarding safe handling and use procedures, safe handlingand use remains the responsibility of the customer.The final determination of the suitabilityof the information and the manner of use of the information or product is the soleresponsibility of the user.


Physical chemical properties listed in Section 9 are general and approximate and are notintended as product specifications.


Product Name Pool Perfect Concentrate

.

1. Product and Company Identificationspace

CAS # Mixturespace

Product use Water cleaning compoundspace

Manufacturer Natural Chemistry, Inc.40 Richards Ave.Norwalk, CT 06854 USPhone: (800) 753-1233Emergency Phone: CHEMTREC (800) 424-9300

space

Personal Protection

Physical Hazard

Flammability

Health

B

0

0

1/

MinimalSlightModerateSerious

LEGEND

43210

Severe0

1 0

HMIS/NFPA

space

Emergency overview CAUTIONContact with liquid may cause eye and skin irritation.

.

2. Hazards Identificationspace

Routes of exposure

Potential short term health effectsEye, Skin contact, Inhalation, Ingestion.

space

Eyes May cause irritation.space

Skin May cause irritation.space

Inhalation May cause respiratory tract irritation.space

Ingestion May cause stomach distress, nausea or vomiting.space

Target organs Eyes. Skin.space

Chronic effects Prolonged or repeated exposure can cause drying, defatting and dermatitis.space

Signs and symptoms Symptoms may include redness, edema, drying, defatting and cracking of the skin.Symptoms of overexposure may be headache, dizziness, tiredness, nausea andvomiting.

space

Composition comments Non-hazardous by WHMIS/OSHA criteria

.

3. Composition / Information on Ingredientsspace

Eye contact

First aid proceduresFlush with cool water. Remove contact lenses, if applicable, and continue flushing.Obtain medical attention if irritation persists.

.

4. First Aid Measuresspace

Skin contact Flush with cool water. Wash with soap and water. Obtain medical attention if irritationpersists.

space

Inhalation If symptoms develop move victim to fresh air. If symptoms persist, obtain medicalattention.

space

Ingestion Do not induce vomiting. Never give anything by mouth if victim is unconscious, or isconvulsing. Obtain medical attention.

space

General advice If you feel unwell, seek medical advice (show the label where possible). Ensure thatmedical personnel are aware of the material(s) involved, and take precautions to protectthemselves. Show this safety data sheet to the doctor in attendance. Avoid contact witheyes and skin. Keep out of reach of children.

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Page 1 of 5#17663 03-Nov-2010Issue date

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Flammable properties Not flammable by WHMIS/OSHA criteria.

.

5. Fire Fighting Measuresspace

Suitable extinguishing media

Extinguishing mediaDry chemical. Water spray. Carbon dioxide. Foam.

space

Unsuitable extinguishing media Not availablespace

Specific hazards arising fromthe chemical

Protection of firefightersNot available

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Protective equipment forfirefighters

Firefighters should wear full protective clothing including self contained breathingapparatus.

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Hazardous combustion products May include and are not limited to: Oxides of carbon.space

Sensitivity to mechanicalimpact

Explosion dataNot available

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Sensitivity to static discharge Not availablespace

Personal precautions Keep unnecessary personnel away. Do not touch or walk through spilled material. Donot touch damaged containers or spilled material unless wearing appropriate protectiveclothing. Keep people away from and upwind of spill/leak.

.

6. Accidental Release Measuresspace

Methods for containment Stop leak if you can do so without risk. Prevent entry into waterways, sewers,basements or confined areas.

space

Methods for cleaning up Before attempting clean up, refer to hazard data given above. Small spills may beabsorbed with non-reactive absorbent and placed in suitable, covered, labelledcontainers. Prevent large spills from entering sewers or waterways. Contact emergencyservices and supplier for advice. Never return spills in original containers for re-use.

space

Handling Use good industrial hygiene practices in handling this material.

.

7. Handling and Storagespace

Storage Keep out of reach of children. Store in a closed container away from incompatiblematerials.

space

.

8. Exposure Controls / Personal Protectionspace

Engineering controls General ventilation normally adequate.space

Eye / face protection

Personal protective equipmentWear safety glasses with side shields.

space

Hand protection Rubber gloves. Confirm with a reputable supplier first.space

Skin and body protection As required by employer code.space

Respiratory protection Where exposure guideline levels may be exceeded, use an approved NIOSH respirator.space

General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. When using donot eat or drink. Wash hands before breaks and immediately after handling the product.

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Appearance Liquid

.

9. Physical and Chemical Propertiesspace

Color Amberspace

Form Liquidspace

Odor Molassesspace

Odor threshold Not availablespace

Physical state Liquidspace

pH 5.5 - 6.5space

Melting point Not availablespace

Freezing point Not availablespace

Boiling point Not availablespace


Pour point Not availablespace

Evaporation rate Not availablespace

Flash point Not availablespace

Auto-ignition temperature Not availablespace

Flammability limits in air, lower, %by volume

Not availablespace

Flammability limits in air, upper, %by volume

Not availablespace

Vapor pressure Not availablespace

Vapor density Not availablespace

Specific gravity 1.006 - 1.009space

Relative density 8.38 - 8.43space

Octanol/water coefficient Not availablespace

Solubility (H2O) Misciblespace

VOC (Weight %) Not availablespace

Viscosity Not availablespace

Percent volatile Not availablespace

Chemical stability Stable under recommended storage conditions.

.

10. Stability and Reactivityspace

Conditions to avoid Do not mix with other chemicals.space

Incompatible materials Acids. Oxidizers.space

Hazardous decomposition products May include and are not limited to: Oxides of carbon.space

Possibility of hazardous reactions Hazardous polymerization does not occur.space

.

11. Toxicological Informationspace

Eye

Effects of acute exposureMay cause irritation.

space

Skin May cause irritation.space

Inhalation May cause respiratory tract irritation.space

Ingestion May cause stomach distress, nausea or vomiting.space

Sensitization Non-hazardous by WHMIS/OSHA criteria.space

Chronic effects Non-hazardous by WHMIS/OSHA criteria.space

Carcinogenicity Non-hazardous by WHMIS/OSHA criteria.space

Mutagenicity Non-hazardous by WHMIS/OSHA criteria.space

Reproductive effects Non-hazardous by WHMIS/OSHA criteria.space

Teratogenicity Non-hazardous by WHMIS/OSHA criteria.space

Synergistic Materials Not availablespace

Ecotoxicity Components of this product have been identified as having potential environmentalconcerns.

.

12. Ecological Informationspace

Environmental effects Not availablespace

Aquatic toxicity Not availablespace

Persistence / degradability Not availablespace

Bioaccumulation / accumulation Not availablespace

Partition coefficient Not availablespace

Mobility in environmental media Not availablespace

Chemical fate information Not availablespace

Other adverse effects Not availablespace


Waste codes Not available

.

13. Disposal Considerationsspace

Disposal instructions Review federal, state/provincial, and local government requirements prior to disposal.space

Waste from residues / unusedproducts

Not availablespace

Contaminated packaging Not availablespace

U.S. Department of Transportation (DOT)Not regulated as dangerous goods.

.

14. Transport Informationspace

Transportation of Dangerous Goods (TDG - Canada)Not regulated as dangerous goods.

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Canadian federal regulations This product has been classified in accordance with the hazard criteria of the ControlledProducts Regulations and the MSDS contains all the information required by theControlled Products Regulations.

.

15. Regulatory Informationspace

US Federal regulations This product is not known to be a "Hazardous Chemical" as defined by the OSHAHazard Communication Standard, 29 CFR 1910.1200.All components are on the U.S. EPA TSCA Inventory List.

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29 CFR 1910.1200 hazardouschemical

Occupational Safety and Health Administration (OSHA)No

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Hazard categories

Superfund Amendments and Reauthorization Act of 1986 (SARA)Immediate Hazard - NoDelayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No

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Section 302 extremelyhazardous substance

Nospace

Section 311 hazardous chemical Nospace

Clean Air Act (CAA) Not availablespace

Clean Water Act (CWA) Not availablespace

WHMIS status Not Controlledspace

State regulations This product does not contain a chemical known to the State of California to causecancer, birth defects or other reproductive harm.

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A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)

Inventory name

Country(s) or region Inventory name On inventory (yes/no)*Canada Domestic Substances List (DSL) Yes

Canada NoNon-Domestic Substances List (NDSL)

United States & Puerto Rico YesToxic Substances Control Act (TSCA) Inventory

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Disclaimer Information contained herein was obtained from sources considered technically accurateand reliable. While every effort has been made to ensure full disclosure of producthazards, in some cases data is not available and is so stated. Since conditions of actualproduct use are beyond control of the supplier, it is assumed that users of this materialhave been fully trained according to the requirements of all applicable legislation andregulatory instruments. No warranty, expressed or implied, is made and supplier will notbe liable for any losses, injuries or consequential damages which may result from theuse of or reliance on any information contained in this document.

.

16. Other Informationspace

Issue date 03-Nov-2010space

Effective date 01-Dec-2010space

Expiry date 01-Dec-2013space

Prepared by Dell Tech Laboratories Ltd. (519) 858-5021space

Other information For an updated MSDS, please contact the supplier/manufacturer listed on the firstpage of the document.

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BLANK PAGE

R-0001


MANUFACTURER: TAYLOR TECHNOLOGIES, INC 31 LOVETON CIRCLE SPARKS, MD 21152 TELEPHONE: 410-472-4340

1. PRODUCT IDENTIFICATIONCATALOG NO.: R-0001PRODUCT NAME: DPD Reagent #1CHEMICAL FAMILY: Inorganic salt solution

2. INGREDIENTSINGREDIENT CAS NO. % NATURE OF HAZARDPotassium phosphate 7778-77-0 <10 IrritantSodium phosphate 7558-79-4 <10 IrritantNonhazardous ingredients NA <1 NoneDeionized water 7732-18-5 to 100 None

3. PHYSICAL/CHEMICAL CHARACTERISTICSSTATE: Liquid APPEARANCE: Clear, colorless ODOR: NoneBOILING PT (F): 212 pH: 10 SPECIFIC GRAVITY: 1.24VAPOR PRESSURE (mm Hg): 17 VAPOR DENSITY (AIR=1): .64PERCENT VOLATILE BY VOLUME: 68 SOLUBILITY IN WATER: Soluble

4. FIRE, EXPLOSION HAZARD AND REACTIVITY DATAFLASH PT: NA METHOD: NAFLAMMABLE LIMITS: LEL: NA UEL: NAEXTINGUISHING MEDIA: Dry chemical, carbon dioxide, water spray or foamSPECIAL PROCEDURES: Wear self-contained (positive pressure if available) breathing apparatus and full-protective clothingFIRE/EXPLOSION HAZARDS AND HAZARDOUS DECOMPOSITION PRODUCTS: May emittoxic fumes of phosphorus oxidesNFPA CODE: Health: 0 Flammability: 0 Reactivity: 0 Specific: NACONDITIONS TO AVOID: Extreme heat, temperatures.

5. HEALTH HAZARD DATAINGREDIENT: NATOXICITY: NAPEL: NA TLV: NASTEL: NAROUTE(S) OF ENTRY: Inhalation Ingestion X Skin XTARGET ORGAN(S): Eyes, skinCARCINOGENICITY: NTP No IARC No OSHA NoHEALTH HAZARDS AND SYMPTOMS OF EXPOSURE:EYES: Irritant.SKIN: Contact may cause irritation.INGESTION: Irritant. Large quantities may cause gastrointestinal irritation, nausea, and diarrhea.INHALATION: NAMEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye and skin conditions

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R-0001

6. PRECAUTIONARY MEASURESPROTECTIVE EQUIPMENT: General purpose gloves, safety glasses, lab coatHANDLING: Avoid contact with eyes, skin, and clothing. Avoid breathing chemical. Wash thoroughly after handling.STORAGE: Cool, dry area. Avoid direct sunlight.

7. EMERGENCY AND FIRST AID PROCEDURESEYE AND SKIN CONTACT: Immediately flush eyes with water for 20 minutes or until chemical is removed. Call physician. Wash skin thoroughly with soap and water.INGESTION: Give large amounts of water. Call physician. Treat symptoms as needed. DO NOT give anything by mouth to a person who is unconscious, rapidly losing consciousness, or convulsing.INHALATION: NA

8. SPILL AND DISPOSAL PROCEDURESSPILL OR RELEASE: Absorb with vermiculite or other inert material.Containerize for later disposal.DISPOSAL: Incineration or other method to comply with all local, state, and federal regulations.

NA = Not applicable ND = Not determined NE = Not established

This Material Safety Data Sheet has been prepared in accordance with 29 CFR Part 1910.1200 and contains information believed to be accurate and complete at the date of preparation. However, no warranty is expressed or implied. Advice given under “Spill and Disposal Procedures” assumes compli-ance with federal, state, and local regulations regarding the disposal of hazardous waste.

DATE PREPARED: March 2006

LAST REVISION: January 2013, Reformatted

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R-0002



1. PRODUCT IDENTIFICATIONCATALOG NO.: R-0002PRODUCT NAME: DPD Reagent #2CHEMICAL FAMILY: Acidic organic amine solution

2. INGREDIENTSINGREDIENT CAS NO. % NATURE OF HAZARDN,N-Diethyl-p-phenylene- 6283-63-2 <1 Irritant, toxicdiamine sulfateOrganic acid Confidential <10 Irritant acid(trade secret)Nonhazardous ingredients NA <1 NoneDeionized water 7732-18-5 to 100 None

3. PHYSICAL/CHEMICAL CHARACTERISTICSSTATE: Liquid APPEARANCE: Clear, colorless ODOR: NoneBOILING PT (F): 212 pH: 1.3 SPECIFIC GRAVITY: 1.01VAPOR PRESSURE (mm Hg): 17 VAPOR DENSITY (AIR=1): .65PERCENT VOLATILE BY VOLUME: 99 SOLUBILITY IN WATER: Soluble

4. FIRE, EXPLOSION HAZARD AND REACTIVITY DATAFLASH PT: NA METHOD: NAFLAMMABLE LIMITS: LEL: NA UEL: NAEXTINGUISHING MEDIA: NASPECIAL PROCEDURES: Wear self-contained (positive pressure if available)breathing apparatus and special protective clothingFIRE/EXPLOSION HAZARDS AND HAZARDOUS DECOMPOSITION PRODUCTS: May emittoxic fumes of carbon dioxide, carbon monoxide, nitrogen oxides, phosphine, phosphorus oxides, sulfur oxides. Contact with metals may produce hydrogen gas.NFPA CODE: Health: 1 Flammability: 0 Reactivity: 0 Specific: NACONDITIONS TO AVOID: Extreme heat, temperatures. Contact with metals, oxidizers, strong caustic.

5. HEALTH HAZARD DATAINGREDIENT: Organic acidTOXICITY: LD50(orl-rat): 2400 mg/kg LD50(skn-rbt): >7940 mg/kgPEL: NE TLV: NESTEL: NEINGREDIENT: N,N-Diethyl-p-phenylenediamine sulfateTOXICITY: LD50(unr-rat): 450 mg/kgPEL: NE TLV: NESTEL: NE

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R-0002

5. HEALTH HAZARD DATA - continuedROUTE(S) OF ENTRY: Inhalation Ingestion X Skin XTARGET ORGAN(S): Eyes, skin, gastrointestinal tractCARCINOGENICITY: NTP No IARC No OSHA NoHEALTH HAZARDS AND SYMPTOMS OF EXPOSURE:EYES: IrritantSKIN: Irritant. Contact may cause dermatitis.INGESTION: Irritant, toxic. May cause gastrointestinal irritation, nausea, cramps, diarrhea.INHALATION: NAMEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye and skin conditions

6. PRECAUTIONARY MEASURESPROTECTIVE EQUIPMENT: General purpose gloves, safety glasses, lab coatHANDLING: Avoid contact with eyes, skin, and clothing. Avoid breathingchemical. Wash thoroughly after handling.STORAGE: Cool, dry area. Avoid direct sunlight.

7. EMERGENCY AND FIRST AID PROCEDURESEYE AND SKIN CONTACT: Immediately flush eyes with water for 20 minutes or until chemical is removed. Call physician. Wash skin thoroughly with soap and water.INGESTION: Give large amounts of water or large amounts of water with milk of magnesia. Call physician. DO NOT INDUCE VOMITING. DO NOT give anything by mouth to a person who is unconscious, rapidly losing consciousness, or convulsing.INHALATION: NA

8. SPILL AND DISPOSAL PROCEDURESSPILL OR RELEASE: Neutralize with soda ash. Absorb with vermiculite or other inert material. Containerize for later disposal.DISPOSAL: Incineration or other method to comply with all local, state, and federal regulations.

NA = Not applicableND = Not determinedNE = Not established


DATE PREPARED: July 2005


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R-0003



1. PRODUCT IDENTIFICATIONCATALOG NO.: R-0003PRODUCT NAME: DPD Reagent #3CHEMICAL FAMILY: Inorganic salt solution

2. INGREDIENTSINGREDIENT CAS NO. % NATURE OF HAZARDPotassium iodide 7681-11-0 <20 IrritantNonhazardous ingredients NA <1 NoneDeionized water 7732-18-5 to 100 None


4. FIRE, EXPLOSION HAZARD AND REACTIVITY DATAFLASH PT: NA METHOD: NAFLAMMABLE LIMITS: LEL: NA UEL: NAEXTINGUISHING MEDIA: NASPECIAL PROCEDURES: Wear self-contained (positive pressure if available) breathing apparatus and full-protective clothingFIRE/EXPLOSION HAZARDS AND HAZARDOUS DECOMPOSITION PRODUCTS: May emittoxic fumes of iodine.NFPA CODE: Health: 0 Flammability: 0 Reactivity: 0 Specific: NACONDITIONS TO AVOID: Extreme heat, temperatures. Contact with oxidizers, acids.

5. HEALTH HAZARD DATAINGREDIENT: Potassium iodideTOXICITY: LD50(orl-mus): 1862 mg/kgPEL: NE TLV: NESTEL: NEROUTE(S) OF ENTRY: Inhalation Ingestion X Skin XTARGET ORGAN(S): Eyes, skinCARCINOGENICITY: NTP No IARC No OSHA NoHEALTH HAZARDS AND SYMPTOMS OF EXPOSURE:EYES: Contact may cause irritation.SKIN: Contact may cause irritation.INGESTION: Irritant. May cause gastrointestinal irritation.INHALATION: NAMEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye and skin conditions

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R-0003 6. PRECAUTIONARY MEASURES

PROTECTIVE EQUIPMENT: General purpose gloves, safety glasses, lab coatHANDLING: Avoid contact with eyes, skin, and clothing. Avoid breathing chemical. Wash thor-oughly after handling.STORAGE: Cool, dry area. Avoid direct sunlight.

7. EMERGENCY AND FIRST AID PROCEDURESEYE AND SKIN CONTACT: Immediately flush eyes with water for 20 minutes oruntil chemical is removed. Call physician. Wash skin thoroughly with soap and water.INGESTION: Give large amounts of water. Call physician. Treat symptoms as needed. DO NOT give anything by mouth to a person who is unconscious, rapidly losing consciousness, or convuls-ing.INHALATION: NA

8. SPILL AND DISPOSAL PROCEDURESSPILL OR RELEASE: Absorb with vermiculite or other inert material. Containerize for later dispos-al.DISPOSAL: Incineration or other method to comply with all local, state, and federal regulations.



DATE PREPARED: February 2007


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R-0004



1. PRODUCT IDENTIFICATIONCATALOG NO.: R-0004PRODUCT NAME: pH Indicator Solution (Phenol Red)CHEMICAL FAMILY: Sulfonphthalein dye solution

2. INGREDIENTSINGREDIENT CAS NO. % NATURE OF HAZARDNonhazardous ingredients, NA <1 NoneeachDeionized water 7732-18-5 to 100 None

3. PHYSICAL/CHEMICAL CHARACTERISTICSSTATE: Liquid APPEARANCE: Clear, red ODOR: PhenolicBOILING PT (F): 212 pH: 7.7 SPECIFIC GRAVITY: 1VAPOR PRESSURE (mm Hg): 17 VAPOR DENSITY (AIR=1): .6PERCENT VOLATILE BY VOLUME: 98 SOLUBILITY IN WATER: Soluble

4. FIRE, EXPLOSION HAZARD AND REACTIVITY DATAFLASH PT: NA METHOD: NAFLAMMABLE LIMITS: LEL: NA UEL: NAEXTINGUISHING MEDIA: NASPECIAL PROCEDURES: Wear self-contained (positive pressure if available) breathing apparatus and full-protective clothingFIRE/EXPLOSION HAZARDS AND HAZARDOUS DECOMPOSITION PRODUCTS: May emit toxic fumes of carbon oxides, nitrogen oxides, ammonia.NFPA CODE: Health: 0 Flammability: 0 Reactivity: 0 Specific: NACONDITIONS TO AVOID: Extreme heat, temperatures.

5. HEALTH HAZARD DATAINGREDIENT: NATOXICITY: NAPEL: NA TLV: NASTEL: NAROUTE(S) OF ENTRY: Inhalation Ingestion X Skin XTARGET ORGAN(S): Eyes, skinCARCINOGENICITY: NTP No IARC No OSHA NoHEALTH HAZARDS AND SYMPTOMS OF EXPOSURE:EYES: Contact may cause irritation.SKIN: Contact may cause staining.INGESTION: Large quantities may cause gastrointestinal irritation.INHALATION: NAMEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye and skin conditions

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R-0004








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1. PRODUCT IDENTIFICATIONCATALOG NO.: R-0005PRODUCT NAME: Acid Demand Reagent (ADR)CHEMICAL FAMILY: Inorganic acid solution

2. INGREDIENTSINGREDIENT CAS NO. % NATURE OF HAZARDSulfuric acid 7664-93-9 <1 Irritant acidDeionized water 7732-18-5 to 100 None

3. PHYSICAL/CHEMICAL CHARACTERISTICSSTATE: Liquid APPEARANCE: Clear, colorless ODOR: NoneBOILING PT (F): 212 pH: 1.3 SPECIFIC GRAVITY: 1VAPOR PRESSURE (mm Hg): 17 VAPOR DENSITY (AIR=1): .6PERCENT VOLATILE BY VOLUME: 100 SOLUBILITY IN WATER: Soluble

4. FIRE, EXPLOSION HAZARD AND REACTIVITY DATAFLASH PT: NA METHOD: NAFLAMMABLE LIMITS: LEL: NA UEL: NAEXTINGUISHING MEDIA: Dry chemical, carbon dioxideSPECIAL PROCEDURES: Wear self-contained (positive pressure if available) breathing apparatus and special protective clothingFIRE/EXPLOSION HAZARDS AND HAZARDOUS DECOMPOSITION PRODUCTS: May reactviolently with water. May react with metals to produce hydrogen gas. May ignite combustible materials. May emit toxic fumes of sulfur oxides.NFPA CODE: Health: 1 Flammability: 0 Reactivity: 0 Specific: NACONDITIONS TO AVOID: Extreme heat, temperatures. Contact with strong alkali, metals.

5. HEALTH HAZARD DATAINGREDIENT: Sulfuric acidTOXICITY: LD50(orl-rat): 2140 mg/kgPEL: 1 mg/m3 TLV: 1 mg/m3STEL: 3 mg/m3ROUTE(S) OF ENTRY: Inhalation Ingestion X Skin XTARGET ORGAN(S): Eyes, skinCARCINOGENICITY: NTP No IARC No OSHA NoHEALTH HAZARDS AND SYMPTOMS OF EXPOSURE:EYES: Irritant. Contact may cause burns.SKIN: Irritant. Contact may cause burns.INGESTION: Irritant. May cause gastrointestinal irritation.INHALATION: NAMEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye and skin conditions

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R-0005






DATE PREPARED: October 2005


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R-0006



1. PRODUCT IDENTIFICATIONCATALOG NO.: R-0006PRODUCT NAME: Base Demand Reagent (BDR)CHEMICAL FAMILY: Inorganic alkali solution

2. INGREDIENTSINGREDIENT CAS NO. % NATURE OF HAZARDSodium carbonate 497-19-8 <1 Irritant alkaliDeionized water 7732-18-5 to 100 None


4. FIRE, EXPLOSION HAZARD AND REACTIVITY DATAFLASH PT: NA METHOD: NAFLAMMABLE LIMITS: LEL: NA UEL: NAEXTINGUISHING MEDIA: NASPECIAL PROCEDURES: Wear self-contained (positive pressure if available) breathing apparatus and full-protective clothingFIRE/EXPLOSION HAZARDS AND HAZARDOUS DECOMPOSITION PRODUCTS: May reactviolently with strong acids, fluorine, aluminum and lithium metals, and phosphorus pentoxide. May emit toxic fumes of sodium oxide and carbon dioxide.NFPA CODE: Health: 1 Flammability: 0 Reactivity: 0 Specific: NACONDITIONS TO AVOID: Extreme heat, temperatures. Contact with strong acids, fluorine, metals, phosphorus pentoxide.

5. HEALTH HAZARD DATAINGREDIENT: Sodium carbonateTOXICITY: LD50(orl-rat): 4090 mg/kgPEL: NE TLV: NESTEL: NEROUTE(S) OF ENTRY: Inhalation Ingestion X Skin XTARGET ORGAN(S): Eyes, skinCARCINOGENICITY: NTP No IARC No OSHA NoHEALTH HAZARDS AND SYMPTOMS OF EXPOSURE:EYES: Irritant.SKIN: Irritant. Contact may cause irritation.INGESTION: Irritant. May cause gastrointestinal irritation.INHALATION: NAMEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye and skin conditions

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7. EMERGENCY AND FIRST AID PROCEDURESEYE AND SKIN CONTACT: Immediately flush eyes with water for 20 minutes or until chemical is removed. Call physician. Wash skin thoroughly with soap and water.INGESTION: Give large amounts of water. Call physician. DO NOT INDUCE VOMITING. DO NOT give anything by mouth to a person who is unconscious, rapidly losing consciousness, or convulsing.INHALATION: NA

8. SPILL AND DISPOSAL PROCEDURESSPILL OR RELEASE: Neutralize with dilute acid. Absorb with vermiculite or other inert material. Containerize for later disposal.DISPOSAL: Incineration or other method to comply with all local, state, and federal regulations.



DATE PREPARED: July 2005


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R-0007



1. PRODUCT IDENTIFICATIONCATALOG NO.: R-0007PRODUCT NAME: Thiosulfate N/10CHEMICAL FAMILY: Inorganic salt solution

2. INGREDIENTSINGREDIENT CAS NO. % NATURE OF HAZARDSodium thiosulfate 7772-98-7 <5 IrritantNonhazardous ingredients NA <1 NoneDeionized water 7732-18-5 to 100 None


4. FIRE, EXPLOSION HAZARD AND REACTIVITY DATAFLASH PT: NA METHOD: NAFLAMMABLE LIMITS: LEL: NA UEL: NAEXTINGUISHING MEDIA: NASPECIAL PROCEDURES: Wear self-contained (positive pressure if available) breathing apparatus and full-protective clothingFIRE/EXPLOSION HAZARDS AND HAZARDOUS DECOMPOSITION PRODUCTS: May emit toxic fumes of sulfur oxides, hydrogen sulfide.NFPA CODE: Health: 0 Flammability: 0 Reactivity: 0 Specific: NACONDITIONS TO AVOID: Extreme heat, temperatures. Contact with acids, strong oxidizers.

5. HEALTH HAZARD DATAINGREDIENT: Sodium thiosulfateTOXICITY: LD50(orl-rat): >5000 mg/kgPEL: NE TLV: NESTEL: NEROUTE(S) OF ENTRY: Inhalation Ingestion X Skin XTARGET ORGAN(S): Eyes, skinCARCINOGENICITY: NTP No IARC No OSHA NoHEALTH HAZARDS AND SYMPTOMS OF EXPOSURE:EYES: Contact may cause irritation.SKIN: Contact may cause irritation.INGESTION: Large quantities may cause gastrointestinal irritation.INHALATION: NAMEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye and skin conditions

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7. EMERGENCY AND FIRST AID PROCEDURESEYE AND SKIN CONTACT: Immediately flush eyes with water for 20 minutes or until chemical is removed. Call physician. Wash skin thoroughly with soap and water.INGESTION: Give large amounts of water. Call physician. Treat symptoms as needed. DO NOT give anything by mouth to a person who is unconscious, rapidly losing consciousness, or convuls-ing.INHALATION: NA

8. SPILL AND DISPOSAL PROCEDURESSPILL OR RELEASE: Absorb with vermiculite or other inert material. Containerize for later dis-posal.DISPOSAL: Incineration or other method to comply with all local, state, and federal regulations.





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1. PRODUCT IDENTIFICATIONCATALOG NO.: R-0008PRODUCT NAME: Total Alkalinity IndicatorCHEMICAL FAMILY: Organic dye solution

2. INGREDIENTSINGREDIENT CAS NO. % NATURE OF HAZARDNonhazardous ingredients NA <1 NoneDeionized water 7732-18-5 to 100 None

3. PHYSICAL/CHEMICAL CHARACTERISTICSSTATE: Liquid APPEARANCE: Dark green ODOR: NoneBOILING PT (F): 212 pH: 8.5 SPECIFIC GRAVITY: 1VAPOR PRESSURE (mm Hg): 17 VAPOR DENSITY (AIR=1): .6PERCENT VOLATILE BY VOLUME: 99 SOLUBILITY IN WATER: Soluble

4. FIRE, EXPLOSION HAZARD AND REACTIVITY DATAFLASH PT: NA METHOD: NAFLAMMABLE LIMITS: LEL: NA UEL: NAEXTINGUISHING MEDIA: Dry chemical, carbon dioxide, water spray or foamSPECIAL PROCEDURES: Wear self-contained (positive pressure if available) breathing apparatus and full-protective clothingFIRE/EXPLOSION HAZARDS AND HAZARDOUS DECOMPOSITION PRODUCTS: May emittoxic fumes of carbon oxides.NFPA CODE: Health: 0 Flammability: 0 Reactivity: 0 Specific: NACONDITIONS TO AVOID: Extreme heat, temperatures.

5. HEALTH HAZARD DATAINGREDIENT: NATOXICITY: NAPEL: NA TLV: NASTEL: NAROUTE(S) OF ENTRY: Inhalation Ingestion X Skin XTARGET ORGAN(S): Eyes, skinCARCINOGENICITY: NTP No IARC No OSHA NoHEALTH HAZARDS AND SYMPTOMS OF EXPOSURE:EYES: Contact may cause irritation.SKIN: Contact may cause staining.INGESTION: Large quantities may cause gastrointestinal irritation.INHALATION: NAMEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye and skin conditions

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7. EMERGENCY AND FIRST AID PROCEDURESEYE AND SKIN CONTACT: Immediately flush eyes with water for 20 minutes or until chemical is removed. Call physician. Wash skin thoroughly with soap and water.INGESTION: Give large amounts of water. Call physician. Treat symptoms as needed. DO NOT give anything by mouth to a person who is unconscious, rapidly losing consciousness, or convuls-ing.INHALATION: NA

8. SPILL AND DISPOSAL PROCEDURESSPILL OR RELEASE: Absorb with vermiculite or other inert material. Containerize for later dispos-al.DISPOSAL: Incineration or other method to comply with all local, state, and federal regulations.



DATE PREPARED: January 2010


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R-0009



1. PRODUCT IDENTIFICATIONCATALOG NO.: R-0009PRODUCT NAME: Sulfuric Acid .12NCHEMICAL FAMILY: Inorganic acid solution

2. INGREDIENTSINGREDIENT CAS NO. % NATURE OF HAZARDSulfuric acid 7664-93-9 <1 Irritant acidDeionized water 7732-18-5 to 100 None


4. FIRE, EXPLOSION HAZARD AND REACTIVITY DATAFLASH PT: NA METHOD: NAFLAMMABLE LIMITS: LEL: NA UEL: NAEXTINGUISHING MEDIA: Dry chemical, carbon dioxideSPECIAL PROCEDURES: Wear self-contained (positive pressure if available) breathing apparatus and special protective clothingFIRE/EXPLOSION HAZARDS AND HAZARDOUS DECOMPOSITION PRODUCTS: May reactviolently with water. May react with metals to produce hydrogen gas. May ignite combustible ma-terials. May emit toxic fumes of sulfur oxides.NFPA CODE: Health: 1 Flammability: 0 Reactivity: 0 Specific: NACONDITIONS TO AVOID: Extreme heat, temperatures. Contact with strong alkali, metals.

5. HEALTH HAZARD DATAINGREDIENT: Sulfuric acidTOXICITY: LD50(orl-rat): 2140 mg/kgPEL: 1 mg/m3 TLV: 1 mg/m3STEL: 3 mg/m3ROUTE(S) OF ENTRY: Inhalation Ingestion X Skin XTARGET ORGAN(S): Eyes, skinCARCINOGENICITY: NTP No IARC No OSHA NoHEALTH HAZARDS AND SYMPTOMS OF EXPOSURE:EYES: Irritant. Contact may cause burns.SKIN: Irritant. Contact may cause burns.INGESTION: Irritant. May cause gastrointestinal irritation.INHALATION: NAMEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye and skin conditions

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DATE PREPARED: October 2005


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R-0010



1. PRODUCT IDENTIFICATIONCATALOG NO.: R-0010PRODUCT NAME: Calcium BufferCHEMICAL FAMILY: Inorganic alkali solution

2. INGREDIENTSINGREDIENT CAS NO. % NATURE OF HAZARDSodium hydroxide 1310-73-2 <2 Irritant alkaliDeionized water 7732-18-5 to 100 None


4. FIRE, EXPLOSION HAZARD AND REACTIVITY DATAFLASH PT: NA METHOD: NAFLAMMABLE LIMITS: LEL: NA UEL: NAEXTINGUISHING MEDIA: Dry chemical, carbon dioxide, water spray or foamSPECIAL PROCEDURES: Wear self-contained (positive pressure if available) breathing apparatus and special protective clothingFIRE/EXPLOSION HAZARDS AND HAZARDOUS DECOMPOSITION PRODUCTS: May react with metals to produce hydrogen gas. May emit toxic or irritating fumes.NFPA CODE: Health: 2 Flammability: 0 Reactivity: 0 Specific: NACONDITIONS TO AVOID: Extreme heat, temperatures. Contact with strong acids, metals, alde-hydes, organic halogens.

5. HEALTH HAZARD DATAINGREDIENT: Sodium hydroxideTOXICITY: LD50(orl-rat): 140-340 mg/kgPEL: 2 mg/m3 TLV: 2 mg/m3STEL: NEROUTE(S) OF ENTRY: Inhalation Ingestion X Skin XTARGET ORGAN(S): Eyes, skinCARCINOGENICITY: NTP No IARC No OSHA NoHEALTH HAZARDS AND SYMPTOMS OF EXPOSURE:EYES: Irritant. Contact may cause burns.SKIN: Irritant. Contact may cause burns.INGESTION: Irritant. May cause burns of mouth, throat, esophagus, stomach.INHALATION: NAMEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye and skin conditions

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R-00106. PRECAUTIONARY MEASURES


7. EMERGENCY AND FIRST AID PROCEDURESEYE AND SKIN CONTACT: Immediately flush eyes with water for 20 minutes or until chemical is removed. Call physician. Wash skin thoroughly with soap and water.INGESTION: Give large amounts of water. Call physician. DO NOT INDUCE VOMITING. DO NOT give anything by mouth to a person who is unconscious, rapidly losing consciousness, or convulsing.INHALATION: NA

8. SPILL AND DISPOSAL PROCEDURESSPILL OR RELEASE: Neutralize with dilute acid. Absorb with vermiculite or other inert material. Containerize for later disposal.DISPOSAL: Incineration or other method to comply with all local, state, and federal regulations.



DATE PREPARED: November 2005


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R-0011L



1. PRODUCT IDENTIFICATIONCATALOG NO.: R-0011LPRODUCT NAME: Calcium Indicator LiquidCHEMICAL FAMILY: Alcoholic organic dye and amine solution

2. INGREDIENTSINGREDIENT CAS NO. % NATURE OF HAZARDTriethanolamine 102-71-6 77 w/w Irritant vaporIsopropyl alcohol 67-63-0 23 w/w FlammableCalcon 2538-85-4 <1 Irritant

3. PHYSICAL/CHEMICAL CHARACTERISTICSSTATE: Liquid APPEARANCE: Dark purple ODOR: AmmonicalBOILING PT (F): 500-600 pH: 10.3 SPECIFIC GRAVITY: 1.02VAPOR PRESSURE (mm Hg): ND VAPOR DENSITY (AIR=1): 2PERCENT VOLATILE BY VOLUME: 99 SOLUBILITY IN WATER: Soluble

4. FIRE, EXPLOSION HAZARD AND REACTIVITY DATAFLASH PT: 64 F METHOD: Closed cupFLAMMABLE LIMITS: LEL: 2% UEL: 12%EXTINGUISHING MEDIA: Dry chemical, carbon dioxide, water spray, or alcohol foamSPECIAL PROCEDURES: Wear self-contained (positive pressure if available) breathing apparatus and full-protective clothing. Cool exposed containers with water spray. Knock down vapors with water spray.FIRE/EXPLOSION HAZARDS AND HAZARDOUS DECOMPOSITION PRODUCTS: Vaporsflammable. May be ignited by heat, sparks, or flames. May emit toxic fumes of nitrogen oxides and carbon monoxide.NFPA CODE: Health: 1 Flammability: 3 Reactivity: 1 Special: NACONDITIONS TO AVOID: Extreme heat, temperatures. Contact with strong acids, strong oxidizers.

5. HEALTH HAZARD DATAINGREDIENT: TriethanolamineTOXICITY: LD50(orl-rat): 8680 mg/kgPEL: NE TLV: NESTEL: NEINGREDIENT: Isopropyl alcoholTOXICITY: LD50(orl-rat): 5840 mg/kgPEL: 980 mg/m3 TLV: 980 mg/m3STEL: NEROUTE(S) OF ENTRY: Inhalation X Ingestion X Skin XTARGET ORGAN(S): Eyes, skin, respiratory tract

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R-0011L

5. HEALTH HAZARD DATA - continuedCARCINOGENICITY: NTP No IARC No OSHA NoHEALTH HAZARDS AND SYMPTOMS OF EXPOSURE:EYES: IrritantSKIN: Irritant. Contact may cause dermatitis, staining.INGESTION: Irritant. May cause severe gastrointestinal disturbance.INHALATION: Irritant. May cause narcosis.MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye, skin, and respiratory conditions

6. PRECAUTIONARY MEASURESPROTECTIVE EQUIPMENT: General purpose gloves, safety glasses, lab coatHANDLING: Avoid contact with eyes, skin, and clothing. Avoid breathing chemical. Wash thoroughly after handling.STORAGE: Cool, dry, well-ventilated area. Avoid direct sunlight.

7. EMERGENCY AND FIRST AID PROCEDURESEYE AND SKIN CONTACT: Immediately flush eyes with water for 20 minutes or until chemical is removed. Call physician. Wash skin thoroughly with soap and water.INGESTION: Give large amounts of water. Call physician. Induce vomiting under direction of physician. DO NOT induce vomiting or give anything by mouth to a person who is unconscious, rapidly losing consciousness, or convulsing.INHALATION: Remove to fresh air. Call physician.




DATE PREPARED: January 2007


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R-0012



1. PRODUCT IDENTIFICATIONCATALOG NO.: R-0012PRODUCT NAME: Hardness ReagentCHEMICAL FAMILY: Organic chelant solution

2. INGREDIENTSINGREDIENT CAS NO. % NATURE OF HAZARDEthylenediaminetetra- 60-00-4 <5 Irritantacetic acidNonhazardous ingredients NA <1 NoneDeionized water 7732-18-5 to 100 None


4. FIRE, EXPLOSION HAZARD AND REACTIVITY DATAFLASH PT: NA METHOD: NAFLAMMABLE LIMITS: LEL: NA UEL: NAEXTINGUISHING MEDIA: Dry chemical, carbon dioxide, water spray or foamSPECIAL PROCEDURES: Wear self-contained (positive pressure if available) breathing apparatus and full-protective clothingFIRE/EXPLOSION HAZARDS AND HAZARDOUS DECOMPOSITION PRODUCTS: May emittoxic fumes of nitrogen oxides, sodium oxide.NFPA CODE: Health: 0 Flammability: 0 Reactivity: 0 Specific: NACONDITIONS TO AVOID: Extreme heat, temperatures.

5. HEALTH HAZARD DATAINGREDIENT: Ethylenediaminetetraacetic acidTOXICITY: LD50(orl-rat): 2000 mg/kgPEL: NE TLV: NESTEL: NEROUTE(S) OF ENTRY: Inhalation Ingestion X Skin XTARGET ORGAN(S): Eyes, skinCARCINOGENICITY: NTP No IARC No OSHA NoHEALTH HAZARDS AND SYMPTOMS OF EXPOSURE:EYES: Contact may cause irritation.SKIN: Contact may cause irritation.INGESTION: Large quantities may cause gastrointestinal irritation.INHALATION: NAMEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye and skin conditions

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DATE PREPARED: November 2005


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R-0013



1. PRODUCT IDENTIFICATIONCATALOG NO.: R-0013PRODUCT NAME: Cyanuric Acid ReagentCHEMICAL FAMILY: Organic salt solution

2. INGREDIENTSINGREDIENT CAS NO. % NATURE OF HAZARDNonhazardous ingredients NA <1 NoneDeionized water 7732-18-5 to 100 None


4. FIRE, EXPLOSION HAZARD AND REACTIVITY DATAFLASH PT: NA METHOD: NAFLAMMABLE LIMITS: LEL: NA UEL: NAEXTINGUISHING MEDIA: Dry chemical, carbon dioxide, water spray or foamSPECIAL PROCEDURES: Wear self-contained (positive pressure if available) breathing apparatus and full-protective clothingFIRE/EXPLOSION HAZARDS AND HAZARDOUS DECOMPOSITION PRODUCTS: May emittoxic fumes of nitrogen oxides, cyanide.NFPA CODE: Health: 0 Flammability: 0 Reactivity: 0 Specific: NACONDITIONS TO AVOID: Extreme heat, temperatures. Contact with strong oxidizers, fluorine.

5. HEALTH HAZARD DATAINGREDIENT: NATOXICITY: NAPEL: NA TLV: NASTEL: NAROUTE(S) OF ENTRY: Inhalation Ingestion X Skin XTARGET ORGAN(S): Eyes, skinCARCINOGENICITY: NTP No IARC No OSHA NoHEALTH HAZARDS AND SYMPTOMS OF EXPOSURE:EYES: Contact may cause irritation.SKIN: Contact may cause irritation.INGESTION: Large quantities may cause gastrointestinal irritation.INHALATION: NAMEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye and skin conditions

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R-0980



1. PRODUCT IDENTIFICATIONCATALOG NO.: R-0980PRODUCT NAME: Phosphate Reagent #1CHEMICAL FAMILY: Inorganic acid and salt solution

2. INGREDIENTSINGREDIENT CAS NO. % NATURE OF HAZARDSodium molybdate 7631-95-0 <5 IrritantSulfuric acid 7664-93-9 <50 Corrosive acidDeionized water 7732-18-5 to 100 None

3. PHYSICAL/CHEMICAL CHARACTERISTICSSTATE: Liquid APPEARANCE: Clear, colorless ODOR: PungentBOILING PT (F): 217 pH: ND SPECIFIC GRAVITY: 1.3VAPOR PRESSURE (mm Hg): 28 VAPOR DENSITY (AIR=1): .6PERCENT VOLATILE BY VOLUME: 99 SOLUBILITY IN WATER: Soluble

4. FIRE/ EXPLOSION HAZARD AND REACTIVITY DATAFLASH PT: NA METHOD: NAFLAMMABLE LIMITS: LEL: NA UEL: NAEXTINGUISHING MEDIA: Dry chemical, carbon dioxideSPECIAL PROCEDURES: Wear self-contained (positive pressure if available) breathing apparatus and special protective clothingFIRE/EXPLOSION HAZARDS AND HAZARDOUS DECOMPOSITION PRODUCTS: May reactviolently with water. May react with metals to produce hydrogen gas. May ignite combustible materials. May emit toxic fumes of sulfur oxides.NFPA CODE: Health: 3 Flammability: 0 Reactivity: 2 Specific: No waterCONDITIONS TO AVOID: Extreme heat, temperatures. Contact with strong alkali, metals.

5. HEALTH HAZARD DATAINGREDIENT: Sulfuric acidTOXICITY: LD50(orl-rat): 2140 mg/kgPEL: 1 mg/m3 TLV: 1 mg/m3STEL: 3 mg/m3ROUTE(S) OF ENTRY: Inhalation Ingestion X Skin XTARGET ORGAN(S): Eyes, skinCARCINOGENICITY: NTP No IARC No OSHA NoHEALTH HAZARDS AND SYMPTOMS OF EXPOSURE:EYES: Corrosive. Contact causes severe burns.SKIN: Corrosive. Contact causes severe burns.INGESTION: Corrosive. Causes severe gastrointestinal irritation, burns of the mouth, esophagus, and stomach.INHALATION: NAMEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye and skin conditions

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R-0980

6. PRECAUTIONARY MEASURESPROTECTIVE EQUIPMENT: Rubber gloves, safety glasses, lab coat, rubber apron, face shieldHANDLING: Avoid contact with eyes, skin, and clothing. Avoid breathing chemical. Wash thoroughly after handling.STORAGE: Cool, dry area. Avoid direct sunlight.

7. EMERGENCY AND FIRST AID PROCEDURESEYE AND SKIN CONTACT: Immediately flush eyes and skin with water for 20 minutes or until chemical is removed. Call physician. Wash skin thoroughly with soap and water.INGESTION: Give large amounts of water or large amounts of water with milk of magnesia. Call physician. DO NOT INDUCE VOMITING. DO NOT give anything by mouth to a person who is unconscious, rapidly losing consciousness, or convulsing.INHALATION: NA




DATE REVISED: October 2005


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R-0981



1. PRODUCT IDENTIFICATIONCATALOG NO.: R-0981PRODUCT NAME: Phosphate Reagent #2CHEMICAL FAMILY: Inorganic salt/polyhydric alcohol solution

2. INGREDIENTSINGREDIENT CAS NO. % NATURE OF HAZARDStannous chloride 7772-99-8 <1 IrritantGlycerol 56-81-5 to 100 Irritant

3. PHYSICAL/CHEMICAL CHARACTERISTICSSTATE: Liquid APPEARANCE: Viscous, colorless ODOR: SlightBOILING PT (F): 554 (dec) pH: ND SPECIFIC GRAVITY: 1.25VAPOR PRESSURE (mm Hg): 0.0002 VAPOR DENSITY (AIR=1): 3.17PERCENT VOLATILE BY VOLUME: 1 SOLUBILITY IN WATER: Soluble

4. FIRE, EXPLOSION HAZARD AND REACTIVITY DATAFLASH PT: 350 F METHOD: Open cupFLAMMABLE LIMITS: LEL: 0.9% UEL: NAEXTINGUISHING MEDIA: Dry chemical, carbon dioxide, water spray or foamSPECIAL PROCEDURES: Wear self-contained (positive pressure if available) breathing apparatus and full-protective clothingFIRE/EXPLOSION HAZARDS AND HAZARDOUS DECOMPOSITION PRODUCTS: May emitcarbon dioxide and toxic fumes of chlorine and carbon monoxide.NFPA CODE: Health: 1 Flammability: 1 Reactivity: 0 Specific: NACONDITIONS TO AVOID: Extreme heat, temperatures. Contact with strong oxidizers may cause explosion.

5. HEALTH HAZARD DATAINGREDIENT: GlycerolTOXICITY: LD50(orl-rat): 12,600 mg/Kg TDLo (orl-hmn): 1428 mg/KgPEL: 15 mg/m3 (mist, total dust) TLV: 10 mg/m3 (mist)STEL: NEINGREDIENT: Stannous chlorideTOXICITY: LD50(orl-rat): 700 mg/kgPEL: 2 mg/m3 (as tin) TLV: 2 mg/m3 (as tin)STEL: NEROUTE(S) OF ENTRY: Inhalation X Ingestion X Skin XTARGET ORGAN(S): KidneysCARCINOGENICITY: NTP No IARC No OSHA NoHEALTH HAZARDS AND SYMPTOMS OF EXPOSURE:EYES: Irritant.SKIN: Irritant. May be harmful if absorbed through the skin.

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5. HEALTH HAZARD DATA - continuedINGESTION: Irritant. May cause headache, gastrointestinal irritation, nausea, vomiting, dizziness, diarrhea, dry mouth, or increased thirst.INHALATION: Irritant. May be irritating to mucous membranes and upper respiratory tract.MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye, skin, and respiratory conditions.

6. PRECAUTIONARY MEASURESPROTECTIVE EQUIPMENT: General purpose gloves, safety glasses, lab coat.HANDLING: Avoid contact with eyes, skin, and clothing. Wash thoroughly after handling.STORAGE: Cool, dry area. Avoid direct sunlight.

7. EMERGENCY AND FIRST AID PROCEDURESEYE AND SKIN CONTACT: Immediately flush eyes with water for 15 minutes. Call physician. Wash skin thoroughly with soap and water.INGESTION: Give large amounts of water or large amounts of water with milk of magnesia. Contact physician. DO NOT INDUCE VOMITING.INHALATION: Remove to fresh air. Contact physician.




DATE PREPARED: September 2001


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R-7062



1. PRODUCT IDENTIFICATIONCATALOG NO.: R-7062PRODUCT NAME: Buffer Solution, pH 7.6CHEMICAL FAMILY: Inorganic salt solution

2. INGREDIENTSINGREDIENT CAS NO. % NATURE OF HAZARDPotassium phosphate 7778-77-0 <5 IrritantSodium hydroxide 1310-73-2 <1 Irritant alkaliDeionized water 7732-18-5 to 100 None


4. FIRE, EXPLOSION HAZARD AND REACTIVITY DATAFLASH PT: NA METHOD: NAFLAMMABLE LIMITS: LEL: NA UEL: NAEXTINGUISHING MEDIA: Dry chemical, carbon dioxide, water spray or foamSPECIAL PROCEDURES: Wear self-contained (positive pressure if available) breathing apparatus and full-protective clothingFIRE/EXPLOSION HAZARDS AND HAZARDOUS DECOMPOSITION PRODUCTS: May emittoxic fumes of phosphorus oxidesNFPA CODE: Health: 0 Flammability: 0 Reactivity: 0 Specific: NACONDITIONS TO AVOID: Extreme heat, temperatures.

5. HEALTH HAZARD DATAINGREDIENT: Sodium hydroxideTOXICITY: LD50(orl-rat): 140-340 mg/kgPEL: 2 mg/m3 TLV: 2 mg/m3STEL: NEROUTE(S) OF ENTRY: Inhalation Ingestion X Skin XTARGET ORGAN(S): Eyes, skinCARCINOGENICITY: NTP No IARC No OSHA NoHEALTH HAZARDS AND SYMPTOMS OF EXPOSURE:EYES: IrritantSKIN: IrritantINGESTION: Irritant. May cause gastrointestinal irritation, nausea, and diarrhea.INHALATION: NAMEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye and skin conditions

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R-7062


7. EMERGENCY AND FIRST AID PROCEDURESEYE AND SKIN CONTACT: Immediately flush eyes with water for 15 minutes. Call physician. Wash skin thoroughly with soap and water.INGESTION: Give large amounts of water. Call physician. Induce vomiting under direction of physician.INHALATION: NA


NA = Not applicable ND = Not determinedNE = Not established


DATE PREPARED: May 1996


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R-7065



1. PRODUCT IDENTIFICATIONCATALOG NO.: R-7065PRODUCT NAME: CYA Standard 50 ppmCHEMICAL FAMILY: Organic acid solution

2. INGREDIENTSINGREDIENT CAS NO. % NATURE OF HAZARDs-Triazine-2,4,6-triol 108-80-5 <1 Irritant(cyanuric acid)Deionized water 7732-18-5 to 100 None

3. PHYSICAL/CHEMICAL CHARACTERISTICSSTATE: Liquid APPEARANCE: Clear, colorless ODOR: NoneBOILING PT (F): 212 pH: ND SPECIFIC GRAVITY: 1VAPOR PRESSURE (mm Hg): 17 VAPOR DENSITY (AIR=1): .6PERCENT VOLATILE BY VOLUME: 99 SOLUBILITY IN WATER: Soluble

4. FIRE, EXPLOSION HAZARD AND REACTIVITY DATAFLASH PT: NA METHOD: NAFLAMMABLE LIMITS: LEL: NA UEL: NAEXTINGUISHING MEDIA: NASPECIAL PROCEDURES: Wear self-contained (positive pressure if available) breathing apparatus and full-protective clothingFIRE/EXPLOSION HAZARDS AND HAZARDOUS DECOMPOSITION PRODUCTS: May reactviolently with ethanol. May emit toxic fumes of cyanide, nitrogen oxides.NFPA CODE: Health: 0 Flammability: 0 Reactivity: 0 Specific: NACONDITIONS TO AVOID: Extreme heat, temperatures. Contact with strong oxidizers.

5. HEALTH HAZARD DATAINGREDIENT: s-Triazine-2,4,6-triolTOXICITY: LD50(orl-rat): 500 mg/kgPEL: NE TLV: NESTEL: NEROUTE(S) OF ENTRY: Inhalation Ingestion X Skin XTARGET ORGAN(S): Eyes, skinCARCINOGENICITY: NTP No IARC No OSHA NoHEALTH HAZARDS AND SYMPTOMS OF EXPOSURE:EYES: IrritantSKIN: IrritantINGESTION: Irritant. May cause gastrointestinal irritation, nausea, vomiting, headache, burning sensation, shortness of breath.INHALATION: NAMEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye and skin conditions

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7. EMERGENCY AND FIRST AID PROCEDURESEYE AND SKIN CONTACT: Immediately flush eyes with water for 15 minutes. Call physician. Wash skin thoroughly with soap and water.INGESTION: Give large amounts of water. Call physician. Induce vomiting under direction of physician.INHALATION: NA


NA = Not applicable ND = Not determinedNE = Not established


DATE PREPARED: May 1996


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