measuring volume temperature mass distance
DESCRIPTION
Reading the Meniscus Always read volume from the bottom of the meniscus. The meniscus is the curved surface of a liquid in a narrow cylindrical container.TRANSCRIPT
Measuring Volume Temperature Mass Distance
Reading the Meniscus
Always read volume from the bottom of the meniscus. The meniscus is the curved surface of a liquid in a narrow cylindrical container.
Try to avoid parallax errors.Parallax errors arise when a meniscus or needle is viewed from an angle rather than from straight-on at eye level.
Correct: Viewing the meniscus
at eye level
Incorrect: viewing the meniscus
from an angle
Graduated CylindersThe glass cylinder has etched marks to indicate volumes, a pouring lip, and quite often, a plastic bumper to prevent breakage.
Measuring Volume Determine the volume contained in a graduated cylinder by reading the bottom of the meniscus at eye level.
Read the volume using all certain digits and one uncertain digit.
Certain digits are determined from the calibration marks on the cylinder. The uncertain digit (the last digit of the reading) is estimated.
Use the graduations to find all certain digits
There are two unlabeled graduations below the meniscus, and each graduation represents 1 mL, so the certain digits of the reading are…
52 mL.
Estimate the uncertain digit and take a reading
The meniscus is about eight tenths of the way to the next graduation, so the final digit in the reading is . The volume in the graduated cylinder is
0.8 mL
52.8 mL.
10 mL GraduateWhat is the volume of liquid in the graduate?
_ . _ _ mL6 26
25mL graduated cylinder What is the volume of liquid in the graduate?
_ _ . _ mL1 1 5
100mL graduated cylinder What is the volume of liquid in the graduate?
_ _ . _ mL5 2 7
Self TestExamine the meniscus below and determine the volume of liquid contained in the graduated cylinder.
The cylinder contains:_ _ . _ mL7 6 0
The Thermometero Determine the temperature by reading the scale on the thermometer at eye level.
o Read the temperature by using all certain digits and one uncertain digit. o Certain digits are determined from the
calibration marks on the thermometer. o The uncertain digit (the last digit of the
reading) is estimated. o On most thermometers encountered in a
general chemistry lab, the tenths place is the uncertain digit.
Do not allow the tip to touch the walls or the bottom of the flask.
If the thermometer bulb touches the flask, the temperature of the glass will be measured instead of the temperature of the solution. Readings may be incorrect, particularly if the flask is on a hotplate or in an ice bath.
Reading the ThermometerDetermine the readings as shown below on Celsius thermometers:
_ _ . _ C _ _ . _ C8 7 4 3 5 0
Measuring Mass – Electronic balance
Our balances read to the hundredths place,the uncertain digit is the hundredths place ( _ _ _ . _ X)
Balance Rules In order to protect the balances and ensure accurate results, a number of rules should be followed:
Always check that the machine is zeroed before adding any substance on it. This is done by pushing the ZERO button before weighing any substance.
Never weigh directly on the balance pan. Always use a piece of weighing paper, weigh boat, or beaker to protect it.
Do not weigh hot or cold objects. Clean up any spills around the balance
immediately.
Determining Mass
1. Place container (weigh boat or beaker) on the pan
2. Zero the balance by hitting the zero bottom
3. Place object on pan
4. Read the digits to the last digit
Metric Ruler
• Rulers are used to measure distance• Can be used to measure the volume
of a cube (L x W x H) length x width x height
• Determine the temperature by reading the scale on the thermometer at eye level.
• Read the ruler by using all certain digits and one uncertain digit.
Reading a Ruler• Determine the readings as shown below
on centimeter ruler:
_ _ . _ cm
_ _ . _ cm
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The SI System of Measurement
The Nature of Measurement
• Part 1 - number• Part 2 - scale (unit)
• Examples:• 20 grams
• 6.63 x 10-34 Joule·seconds
A Measurement is a quantitative observation consisting of TWO parts
The Fundamental SI Units (le Système International, SI)
Base Quantity Name of unit Symbol
Length Meter m
Mass Kilogram kg
Time Second s
Temperature Kelvin KAmount of Substance Mole mol
SI PrefixesCommon to Chemistry
Prefix Unit Abbr. ExponentKilo k 103
Deci d 10-1
Centi c 10-2
Milli m 10-3
Micro 10-6
Metric Acronym
• K King• H Henry• D Died• M Monday• D Drinking • C Chocolate • M Milk
Metric ConversionsgmL 10-1 10-2 10-3101102103
Baseunit
deci centi millidekahectokilo
Conversions in the metric system are merely a matter of moving a decimal point. The “base unit” means the you have a quantity (grams, meters, Liters, etc without a prefix.
Metric ConversionsgmL 10-1 10-2 10-3101102103
Baseunit
deci centi millidekahectokilo
Example #1: Convert 18 liters to milliliters
18 L1 2 3
18 liters = 18 000 milliliters
Metric ConversionsgmL 10-1 10-2 10-3101102103
Baseunit
deci centi millidekahectokilo
Example #2: Convert 450 milligrams to grams
123450 mg450 mg = 0.450 g
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Metric Conversions Ladder Method
T. Trimpe 2008 http://sciencespot.net/
KILO1000Units
HECTO100
UnitsDEKA
10Units
DECI0.1
UnitCENTI
0.01Unit
MILLI0.001Unit
MetersLitersGrams
Ladder Method
How do you use the “ladder” method? 1st – Determine your starting point.
2nd – Count the “jumps” to your ending point.
3rd – Move the decimal the same number of jumps in the same direction.
4 km = _________ m
12
3
How many jumps does it take?
Starting Point Ending Point
4.1
__.2
__.3
__. = 4000 m
Try these conversions using the ladder method.
1000 mg = _______ g 1 L = _______ mL 160 cm = _______ mm
14 km = _______ m 109 g = _______ kg 250 m = _______ km
Conversion Practice
Compare using <, >, or =.
56 cm 6 m 7 g 698 mg
Write the correct abbreviation for each metric unit.
1) Kilogram _____ 4) Milliliter _____ 7) Kilometer _____
2) Meter _____ 5) Millimeter _____ 8) Centimeter _____
3) Gram _____ 6) Liter _____ 9) Milligram _____
Try these conversions, using the ladder method.
10) 2000 mg = _______ g 15) 5 L = _______ mL 20) 16 cm = _______ mm
11) 104 km = _______ m 16) 198 g = _______ kg 21) 2500 m = _______ km
12) 480 cm = _____ m 17) 75 mL = _____ L 22) 65 g = _____ mg
13) 5.6 kg = _____ g 18) 50 cm = _____ m 23) 6.3 cm = _____ mm
14) 8 mm = _____ cm 19) 5.6 m = _____ cm 24) 120 mg = _____ g
Metric Conversion Challenge
Compare using <, >, or =.
25) 63 cm 6 m 27) 5 g 508 mg 29) 1,500 mL 1.5 L
26) 536 cm 53.6 dm 28) 43 mg 5 g 30) 3.6 m 36 cm
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Metric Dimensional Analysis Practice
Problem #1Convert 400 mL to Liters
400 mL= L
mLL
1 0001 .400
= 0.4 L= 4x10-1 L
Problem #2Convert 10 meters to mm
10 m= m
mmmm1
1 000 10 000
= 1x104 mm
Problem #3Convert 73 grams to kg
73 g= kg
gkg
1 0001 0.073
= 7.3x10-2 kg
Problem #4Convert 0.02 kilometers to m
0.02 km= m
kmm
11 000 20
= 2x101 m
Problem #5Convert 20 centimeters to m
20 cm= m
cmm
1001 0.20
= 2x10-1 m
Problem #6Convert 450 milliliters to dL
450 mL= dL
mLdL
1001 4.5
Problem #7Convert 10 kilograms to grams
10 kg = gkgg
11 000 10 000
= 1x104 g
Problem #8Convert 935 mg to cg
935 mg = cgmgcg
101 93.5
= 9.35x101 cg
Problem #9Convert 5.2 kg to mg
5.2 kg = mgkg
mg1
1 000 000
= 5 200 000 mg= 5.2x106 mg
Problem #10Convert 175 mL to cm3
175 mL = cm3
mLcm3
11 175
= 1.75x102 cm3
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Uncertainty and Significant Figures
Cartoon courtesy of Lab-initio.com
Uncertainty in Measurement
• A digit that must be estimated is called uncertain. A measurement always has some degree of uncertainty.
Why Is there Uncertainty? Measurements are performed with
instruments No instrument can read to an infinite
number of decimal places
Which of these balances has the greatest uncertainty in measurement?
Precision and Accuracy• Accuracy refers to the agreement of a
particular value with the true value.
• Precision refers to the degree of agreement among several measurements made in the same manner.
Neither accurate
nor precise
Precise but not accurate
Precise AND accurate
Types of Error
• Random Error (Indeterminate Error) - measurement has an equal probability of being high or low.
• Systematic Error (Determinate Error) - Occurs in the same direction each time (high or low), often resulting from poor technique or incorrect calibration.
Rules for Counting Significant Figures - Details
• Nonzero integers always count as significant figures.
• 3456 has • 4 significant figures
Rules for Counting Significant Figures - Details
• Zeros• Leading zeros do not count as significant
figures.
• 0.0486 has• 3 significant figures
Rules for Counting Significant Figures - Details
• Zeros• Captive zeros always count as significant
figures.
• 16.07 has• 4 significant figures
Rules for Counting Significant Figures - Details
• Zeros• Trailing zeros are significant only if
the number contains a decimal point.
• 9.300 has• 4 significant figures
Rules for Counting Significant Figures - Details
• Exact numbers have an infinite number of significant figures.
• 1 inch = 2.54 cm, exactly
Sig Fig Practice #1How many significant figures in each of the following?
1.0070 m 5 sig figs
17.10 kg 4 sig figs
100,890 L 5 sig figs
3.29 x 103 s 3 sig figs
0.0054 cm 2 sig figs
3,200,000 2 sig figs
Rules for Significant Figures in Mathematical Operations
• Multiplication and Division: # sig figs in the result equals the number in the least precise measurement used in the calculation.
• 6.38 x 2.0 =• 12.76 13 (2 sig figs)
Sig Fig Practice #2
3.24 m x 7.0 m
Calculation Calculator says: Answer
22.68 m2 23 m2
100.0 g ÷ 23.7 cm3 4.219409283 g/cm3 4.22 g/cm3
0.02 cm x 2.371 cm 0.04742 cm2 0.05 cm2
710 m ÷ 3.0 s 236.6666667 m/s 240 m/s
1818.2 lb x 3.23 ft 5872.786 lb·ft 5870 lb·ft
1.030 g ÷ 2.87 mL 2.9561 g/mL 2.96 g/mL
Rules for Significant Figures in Mathematical Operations
• Addition and Subtraction: The number of decimal places in the result equals the number of decimal places in the least precise measurement.
• 6.8 + 11.934 =• 18.734 18.7 (3 sig figs)
Sig Fig Practice #3
3.24 m + 7.0 m
Calculation Calculator says: Answer
10.24 m 10.2 m
100.0 g - 23.73 g 76.27 g 76.3 g
0.02 cm + 2.371 cm 2.391 cm 2.39 cm
713.1 L - 3.872 L 709.228 L 709.2 L
1818.2 lb + 3.37 lb 1821.57 lb 1821.6 lb
2.030 mL - 1.870 mL 0.16 mL 0.160 mL
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Scientific Notation
In science, we deal with some very LARGE numbers:
1 mole = 602000000000000000000000
In science, we deal with some very SMALL numbers:
Mass of an electron =0.000000000000000000000000000000091 kg
Scientific Notation
Imagine the difficulty of calculating the mass of 1 mole of electrons!
0.000000000000000000000000000000091 kg x 602000000000000000000000 ???????????????????????????????????
Scientific Notation:A method of representing very large
or very small numbers in the form:
M x 10n
M is a number between 1 and 9
n is an integer
2 500 000 000
Step #1: Insert an understood decimal point
.Step #2: Decide where the decimal must end up so that one number is to its leftStep #3: Count how many places you bounce the decimal point
123456789
Step #4: Re-write in the form M x 10n
2.5 x 109
The exponent is the number of places we moved the decimal.
0.0000579
Step #2: Decide where the decimal must end up so that one number is to its leftStep #3: Count how many places you bounce the decimal point
Step #4: Re-write in the form M x 10n
1 2 3 4 5
5.79 x 10-5
The exponent is negative because the number we started with was less than 1.
PERFORMING CALCULATIONS IN SCIENTIFIC
NOTATION
ADDITION AND SUBTRACTION
Review:Scientific notation expresses a number in the form: M x 10n
1 M 10n is an integer
4 x 106
+ 3 x 106IF the exponents are the same, we simply add or subtract the numbers in front and bring the exponent down unchanged.
7 x 106
4 x 106
- 3 x 106The same holds true for subtraction in scientific notation.
1 x 106
4 x 106
+ 3 x 105If the exponents are NOT the same, we must move a decimal to make them the same.
4.00 x 106
+ 3.00 x 105 + .30 x 106
4.30 x 106Move the decimal on the smaller number!
4.00 x 106
A Problem for you… 2.37 x 10-6
+ 3.48 x 10-4
+ 3.48 x 10-4
Solution…002.37 x 10-
6
+ 3.48 x 10-4
Solution…0.0237 x 10-4
3.5037 x 10-4
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Density
Density Density is an important intensive
property, which can be used to help determine the identity of an unknown substance.
While the mass or the volume of a substance will vary from sample to sample, the density will remain the same at a given temperature.
As you know, the density of a substance is a measure of how much mass is present in a given unit of volume.
Density is the measure of the “compactness” of a material
How close the atoms or molecules are to each other
More than “heaviness” - density includes how much space an object takes up!!
All substances have density including liquids, solids, and gases
Density is the measure of the “compactness” of a material
How close the atoms or molecules are to each other
More than “heaviness” - density includes how much space an object takes up!!
All substances have density including liquids, solids, and gases
Density
D = m/vm = mass (g)Which is the amount of matter in a
substance DO NOT confuse mass with weightWeight – is the force of gravity
exerted on an objectv = volume (ml) or (cm3)Is measured by water displacement or
using a ruler
QuestionWhich weighs more?50 kilograms of iron
Or
50 kilograms of feathers
QuestionWhich has a greater density?
iron
Or
feathers
Water
• Waters density = 1.000 g/ml at 4oC • Ice floats on water
Densities of Common Substances
If water has a density of 1.00 g/cm3 , which of the following will float or sink?
Factors that Affect Density
Temperature• For most substances, as temperature
increases the volume increases and as a result the density decreases.
Pressure
Dissolved solids in Liquids
2 Ways to Measure the Volume of a Solid
1. Objects with regular sides calculate L x W x H using a ruler
2. Water displacement. Place irregularly shaped solid into a volumetric cylinder half filled with water and place the solid into the cylinder and subtract the volumes
Useful Conversion Factors
1 cm3 = 1 ml1 dm3 = 1 L
Manipulating the Density Formula
Sample Problem 1
A student determines that a piece of an unknown material has a mass of 5.854 g and a volume of 7.57 cm3. What is the density of the material, rounded to the correct number of significant digits?
Sample Problem 2
Iron has a known density of 7.87 g/cm3. What would be the mass of a 2.5 cm3 piece of iron?
Sample Problem 3
Mercury has a density of 13.5 g/cm3. How much space would 50.0 g of mercury occupy?
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Percent Error
Percent Error
Students often assume that each measurement that they make in the laboratory is true and accurate. Likewise, they often assume that the values that they derive through experimentation are very accurate. However, sources of error often prevent students from being as accurate as they would like. Percent error calculations are used to determine how close to the true values, or how accurate, their experimental values really are.
The value that the student comes up with is usually called the observed value, or the experimental value. A value that can be found in reference tables is usually called the true value, or the accepted value. The percent error can be determined when the true value is compared to the observed value according to the equation below:
Percent Error
Sample Problem 1
A student measures the mass and volume of a piece of copper in the laboratory and uses his data to calculate the density o the metal. According to his results, the copper has a density of 8.37 g/cm3. Curious about the accuracy of his results, the student consults a reference table and finds that the accepted value for the density of copper is 8.92 g/cm3. What would be the student's percent error?
Sample Problem 2
A student experimentally determines the specific heat of water to be 4.29 J/g x Co. He then looks up the specific heat of water on a reference table and finds that is 4.18 J/g x Co. What is his percent error?
Sample Problem 3
A student takes an object with an accepted mass of 200.00 grams and masses it on his own balance. He records the mass of the object as 196.5 g. What is his percent error?
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Classification of Matter
Composition of Matter Flowchart
MATTERCan it be physically
separated?
Homogeneous Mixture
(solution)
Heterogeneous Mixture Compound Element
MIXTURE PURE SUBSTANCE
yes no
Can it be chemically decomposed?
noyesIs the composition uniform?
noyes
Classifying Matter by Composition
Elements- simplest kind of matter, made of one type of atom
An atom is the smallest unit of an element that maintains the properties of that element.
Cannot be broken down into simpler substances by ordinary chemical means
Ex. gold, copper, oxygen (on the periodic table)
Element
Classifying Matter by Composition
Compounds – matter composed of the atoms of two or more elements chemically bonded
Compounds can be broken down by chemical methods
When they are broken down, the components have completely different properties than the compound.
Ex. Sugar, salt, water, carbon dioxide
Compound
Classifying Matter by Composition
A mixture is a blend of two or more kinds of matter, each of which retains its own identity and properties.
A mixture is mixed together physically.
Variable composition, often expressed by a percent composition by mass or volume (Ex. 5% salt and 95% water)
Mixture
Classifying Matter by Composition
Homogeneous Mixture– matter with a uniform compositionHomogeneous mixtures are also called solutions.
Ex. Salt water and Kool –aid
Homogeneous Mixture
Classifying Matter by Composition
A heterogeneous mixture is not the same throughout (not uniform).
Examples: M & M’s, Chocolate chip cookie, gravel, soil, rocks such as granite, blood, milk, salad, ocean water, etc.
Heterogeneous Mixture
Classify Itcopper wire, aluminum foil
Classify It
» EX: table salt (NaCl)
Classify ItGranite Apple Juice
Classify It
Examples:» magnesium» Pizza» Calcium chloride» Orange juice» Club soda
Classify ItExamples:
» magnesium» pizza» Calcium
chloride» Orange juice» Club soda
elementhetero. mixturecompoundhetero. mixtureHomo. (solution)
States of MatterSolid- matter that can not flow and
has definite volume and shapeLiquid- definite volume but no
definite shape and can flowGas- a substance without definite
volume or shape and can flow.Plasma- a substance that is similar to
a gas, but loses electrons due to its high temperature
States of Matter
Gas
Definite Volume?
NO
Definite Shape?
NO
NO
Particle position and movement
Close together, can move past each other - flow
Far apart, move rapidly - flow
Solid
Liquid
YES
YES
YES Packed tightly, vibrate about fixed point
States of Matter
Separating MixturesMixtures are separated by their
physical properties. Primary methods of separatingmixtures are:filtrationdistillationcentrifugechromatography
Separating Mixtures
Filtration is a method used to separate the components of mixtures that contain an insoluble solid and a liquid. Example: sand and water
Filtration
Separating Mixtures
Distillation is a method of separating substances in a mixture by evaporation of a liquid and subsequent condensation of its vapor. Example: desalination of salt water
Separating MixturesCentrifuge Used to separate solid-liquid mixtures such as those in blood. The centrifuge spins rapidly and causes the solid to settle to the bottom.
Ex. Separating blood
Separating MixturesChromatography is a method of
separating mixtures that uses a stationary phase and a mobile phase. Paper chromatography can be used to separate pigments because they move at different rates on the paper.
Chromatography
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Properties & Changes of Matter
Properties of Matter
Physical Property- a property that can be observed and measured without changing the identity of the substance.
Examples? Mass, Density, Melting and Boiling Points
Chemical Property-relates to a substance’s ability to undergo changes that transform it into different substances.
Examples? Reactivity, Toxicity, and Chemical stability
Properties of MatterChemists use properties to identify and
separate matter. More than one property must be used for identification.
Intensive Properties – do not depend on the amount of matter present
Ex. Melting pt., boiling pt, density, conduct electricity
Extensive Properties – depend on the amount of matter present
Ex. Volume, mass
Changes in Matter
A physical change does not change the composition or identity of the substance.• Examples? • Boiled water is still water.• All phase changes are physical
changes
Solid Liquid
Gas
Melt Evaporate
Condense
Freeze
Changes in Matter
Sublimation is a process in which a solid changes directly to a gas without going through the liquid phase.
Ex: dry ice CO2
Deposition is a process in which a gas changes directly to a liquid without going through the liquid phase
Ex: liquid vapor to ice (frost on windshields)
Changes in Matter
A chemical change occurs when one or more substances are changed into new substances.
Reactants- substances that reactProducts- substances that formProducts have NEW PROPERTIES
2H2 + O2 → 2H2O reactants product
Law of Conservation of mass – Also known as Conservation of Matter. Matter can be neither created nor destroyed, though it can be rearranged. Mass remains constant in an ordinary chemical change.
Indications of chemical change
1. Production of energy in the forms of heat, light, sound, or electricity
2. Production of a gas3. Formation of a
precipitate4. A change in color5. A change in odor
What is Energy?Energy - is the ability to or capacity to
do work or to produce changeConservation of Energy (1st Law of Thermodynamics) - Energy can be neither created nor destroyed; the energy of the universe is constant.Two types: Kinetic energy – energy of motionPotential energy – is the energy due to
position of object
Chemical Energy
Chemical energy - is a special kind of potential energy• Is the energy involved in chemical
reactions
Energy Changes
• Some changes in matter release energy.
• For example, the explosion that occurs when hydrogen and oxygen react to form water is a release of energy.
• Heat energy and light energy are released as the reaction takes place.
Energy Changes• A change in matter in which energy is absorbed
from the surroundings is an endothermic process (heat enters).•EXAMPLES: melting ice & boiling water •When barium hydroxide reacts ammonium nitrate are mixed the test-tube feels cold to touch because energy has been absorbed
Energy Changes
• A change in matter in which energy is released is an exothermic process (heat exits).
• Examples: freezing water & condensation
• Burning of paper gives off heat to the surroundings.
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Phase Changes
Courtesy www.lab-initio.com
Water phase
changes
What do you notice about the temperatureduring a phase change?
Phase Diagram
Represents phases as a function of temperature and pressure. Critical temperature: temperature above which the vapor can not be liquefied. Critical pressure: pressure required to liquefy AT the critical temperature. Critical point: critical temperature and pressure (for water, Tc = 374°C and 218 atm).
Phase changes by Name
Water
Carbon dioxidePhase
Diagram for
Carbondioxide
CarbonPhase Diagram
for Carbon
Intro to Thermochemist
ryHeat and
Temperature
Thermochemistry
Thermochemistry – is the study of the transfer of energy as heat that accompany chemical reactions and physical changes
Heat and Temperature
Heat - is energy transferred between a system and its surroundings
• Heat absorbed or released is measured by a calorimeter
Heat
• Energy that flows from something warm to something cooler
• A hotter substance gives KE to a cooler one
• When heat is transferred (lost or gained), there is a change in the energy within the substance
QuestionsA. When you touch ice, heat is transferred from
1) your hand to the ice2) the ice to your hand
B. When you drink a hot cup of
coffee, heat is transferred from
1) your mouth to the coffee2) the coffee to your mouth
Answer
A. When you touch ice, heat is transferred from
1) your hand to the ice
B. When you drink a hot cup of coffee, heat is transferred from
2) the coffee to your mouth
Question
C. When you heat 200 g of water for 1 minute, the water temperature rises from 10°C to 18°C.
If you heat 400 g of water at 10°C in the same pan with the same amount of heat for 1 minute, what would you expect the final temperature to be?1) 10 °C 2) 14°C 3) 18°C
200 g 400 g
Answer2)14°C Heating twice the mass of water
using the same amount of heat will raise the temperature only half as much.
200 g 400 g
TemperatureTemperature – is a measure of the average
kinetic energy of particles• Measured in Kelvin• Common Temperatures you need to
KNOWCelsius Scale (0C)
– 00C water freezes, 1000C water boilsFahrenheit Scale (0F)
– 320F water freezes, 2120F water boilsKelvin Scale (K)
– 273 K water freezes, 373 K water boils– ABSOLUTE Zero 0 K
Temperature
K oC
50357
32298
• Measured in Kelvin K = 273 + oC
Convert the following
Some Equalities for Heat
Heat is measured in calories or joules• 1 kcal = 1000 cal• 1 calorie = 4.18 J (Joules)• 1 kJ = 1000 J
Specific Heat
• Why do some foods stay hot longer than others?
• Why is the beach sand hot, but the water is cool on the same hot day?
Specific HeatDifferent substances have different capacities for storing energy
It may take 20 minutes to heat water to 75°C. However, the same mass of aluminum might require 5 minutes and the same amount of copper may take only 2 minutes to reach the same temperature.
Specific Heat Values Specific heat - is the amount of heat needed
to raise the temperature of 1 g of a substance by 1°Ccal/g°C J/g°Cwater 1.00 4.18 aluminum0.22 0.90
copper 0.093 0.39silver 0.057 0.24
gold 0.031 0.13
QuestionsA. A substance with a large specific heat 1) heats up quickly 2) heats up
slowlyB. When ocean water cools, the
surrounding air 1) cools 2) warms 3) stays the same
C. Sand in the desert is hot in the day, and cool at night. Sand must have a 1) high specific heat 2) low specific heat
AnswersA. A substance with a large specific heat 2) heats up slowlyB. When ocean water cools, the
surrounding air 2) warms
C. Sand in the desert is hot in the day, and cool at night. Sand must have a
2) low specific heat
Measuring Heat
Requires• Grams of substance • Temperature change T
T = Tf - Ti
• Specific heat of the substance
Energy lost or gained
Calculating Heat
= mass x temp. change x specific heat
q = m x ∆T x Cp
A few key ideas:• If a substance receives heat and
experiences an increase in temperature then Q is a positive number and ∆T is a positive number.
• If a substance loses heat and experiences a decrease in temperature then Q is a negative number and ∆T is a negative number.
A few key ideas:• Q, heat energy, can be measured in
either Joules or calories. Just make sure that your units for c are consistent with your units for Q.
• ∆T, change in temperature, can be measured in K, °C, or °F. Just make sure that your units for c are consistent with your units for ∆T.
• Always start a problem by listing the given information (with units) and writing down the specific heat capacity equation.
A few key ideas:• You must ALWAYS show all work and make
sure you have consistent units on your final answer.
• The First Law of Thermodynamics states that if two substances exchange heat, the quantity of heat gained by one substance is exactly equal and opposite to the quantity of heat lost by the other substance.
ProblemThe element hydrogen has the highest specific heat of all elements. At a temperature of 25°C, hydrogen’s specific heat capacity is 14300J/(kg ∙ K). If the temperature of a 0.34 kg sample of hydrogen is to be raised by 25 K, how much heat will have to be transferred to the hydrogen?
ProblemAt 25°C, radon’s specific heat capacity is 94J/(kg ∙K). If the temperature of a 0.34kg sample of radon is to be raised by 25K, how much heat will have to be transferred to the radon?
Problem A 0.59 kg brass candlestick has an initial temperature of 98.0°C. If 21,100J of heat is removed from the candlestick to lower its temperature to 6.8°C, what is the specific heat capacity of brass?
ProblemA 0.38kg drinking glass is filled with a hot liquid. The liquid transfers 7032J of heat to the glass. If the temperature of the glass increases by 22K, what is the specific heat capacity of the glass?
End Of Unit 1