meinsberg electrodes - meinsberger elektroden · pdf filemeinsberg electrodes for laboratory...

42
Meinsberg Electrodes for Laboratory and Process www.meinsberg.de pH mV S mS O 2 Cl 2 ISE NTU

Upload: duonghuong

Post on 07-Feb-2018

238 views

Category:

Documents


1 download

TRANSCRIPT

Meinsberg Electrodesfor Laboratory and Process

www.meinsberg.de

pH mV S mS O2 Cl2 ISE NTU

Instructions for using pH and redox combination electrodes Storage1

pH and redox combination electrodes are stored in this medium which is filled in the reference system of the sensor. It is 3 mol/l or saturated KCl solution which is in the watering cap. pH and redox combination electrodes must never be stored in deionised water.

Calibration1

1. Rinse the sensor with deionised water. 2. Immerse the sensor in the buffer solution that the diaphragm is wetted completely. 3. Be sure that the sensor and the buffer have taken the same temperature value. 4. Rinse the sensor with deionised water before changing to the next buffer.

Dispose the used buffer solution. Pay attention to the manual of the sensor and the measuring instrument.

Cleaning1

Clean diaphragm, glass membrane or platinum disc of the sensor with water and dap it dry with a paper towel. Oily and organic contamination: Rinse the sensor with ethanol. Protein contamination: Immerse the sensor in pepsin cleaning solution that the diaphragm is

wetted completely. After cleaning rinse the sensor with deionised water and put it in its storage solution. Before the next measurement calibrating is necessary.

Reconditioning1

pH combination electrodes with decreasing slope and a slow response time can be reconditioned with a special solution. The glass membrane of the sensor is immersed for 2 minutes in maximum in the reconditioning solution. The diaphragm must never be wetted. After that the sensor is rinsed with deionised water and kept in its storage solution for 1 hour. Before the next measurement calibrating is necessary.

1 The order code for storage, buffer, cleaning and reconditioning solutions is printed on page 33.

Order key for reference electrodes and pH combination electrodes

reference electrodes There is a plug head or a fixed cable with plug available. Please set your choice according to the following:

Example: SE 20 with 3 m special cable length, banana plug and screwable thread PG 13.5 = SE 20-SK030-H-P

pH combination electrodes without temperature sensor There is a plug head or a fixed cable with plug available for choice. Please set your choice according to the following:

Example: EGA 151 with 3 m special cable length and BNC plug = EGA 151-SK030-B

pH combination electrodes with temperature sensor There is a plug head or a fixed cable with plug available. Please set your choice according to the following:

Example: EGA 143 with Pt 100, 12.50 m special cable length and stripped ends = EGA 143-Y-SK125-F

1 The following standard cable lengths are available: 1 m, 2 m, 5 m, 10 m and 15 m 2 „SMEK“ is another description for „SixPlug“.

EG... X000 X X - - - X -

P = screwable thread PG 13.5

XXX X -

BH = BNC plug and 4 mm banana plug BG = BNC plug and Cinch plug BM = BNC plug and German MiniDIN plug DH = German DIN plug and 4 mm banana plug F = stripped ends K = standard cable length1 (additional setting of wished standard cable length, e. g. K010 for 1 m or K100 for 10 m) SK = special cable length (additional setting of wished special cable length, e. g. SK015 for 1.50 m or SK155 for 15.50 m) E = SMEK lab plug head2 X = with Pt 1000 Y = with Pt 100 Z30 = with NTC 30 kΩ Continuation of the marking (e. g. 143) Marking of basic type (EGA/EGC) A = standard glass C = HT-glass (for strong alkaline mediums)

EG… X000 X X - - -

P = screwable thread PG 13.5

X - XXX

B = BNC plug G = Cinch plug D = German DIN plug F = stripped ends K = standard cable length1 (additional setting of wished standard cable length, e. g. K010 for 1 m or K100 for 10 m) SK = special cable length (additional setting of wished special cable length, e. g. SK015 for 1.50 m or SK155 for 15.50 m) L = S7 coaxial lab plug head Continuation of the marking (e. g. 153) Marking of basic type (EGA/EGC) A = standard glass C = HT-glass (for strong alkaline mediums)

SE/KE… X000 X X - - - P = screwable thread PG 13.5

X -

H = 4 mm banana plug F = stripped ends K = standard cable length1 (additional setting of wished standard cable length, e. g. K010 for 1 m or K100 for 10 m) SK = special cable length (additional setting of wished special cable length, e. g. SK015 for 1.50 m or SK155 for 15.50 m)

L = S7 coaxial lab plug head

Marking of basic type

Order key for redox combination electrodes, conductivity cells, oxygen sensors

redox(ORP) combination electrodes There is a plug head or a fixed cable with plug available. Please set your choice according to the following:

Example: EMC 133 with 5 m standard cable length and German DIN plug = EMC 133-K050-D

conductivity cells with temperature sensor There is a plug head or a fixed cable available. Please set your choice according to the following:

Example: LTG 1/23 with 12.50 m special cable length and stripped ends = LTG 1/23-SK125-F

oxygen sensors with temperature sensor There is a plug head or a fixed cable with plug available for choice. Please set your choice according to the following:

Example: MF 41-N with 10 m standard cable length and multipin plug = MF 41-N-K100-U

1 The following standard cable lengths are available: 1 m, 2 m, 5 m, 10 m and 15 m 2 „SMEK“ is another description for „SixPlug“.

MF… X000 X X - -

P = screwable thread PG 13.5

X -

U = multipin plug (6 pins) F = stripped ends K = standard cable length1 (additional setting of wished standard cable length, e. g. K010 for 1 m or K100 for 10 m) SK = special cable length (additional setting of wished special cable length, e. g. SK015 for 1.50 m or SK155 for 15.50 m)

E = SMEK lab plug head2 Marking of basic type

LTG/LTC… X000 X X - - -

P = screwable thread PG 13.5

X -

F = stripped ends K = standard cable length1 (additional setting of wished standard cable length, e. g. K010 for 1 m or K100 for 10 m) SK = special cable length (additional setting of wished special cable length, e. g. SK015 for 1.50 m or SK155 for 15.50 m)

E = SMEK lab plug head2 Marking of basic type

EMC… X000 X X - - -

P = screwable thread PG 13.5

X -

B = BNC plug G = Cinch plug D = German DIN plug F = stripped ends K = standard cable length1 (additional setting of wished standard cable length, e. g. K010 for 1 m or K100 for 10 m) SK = special cable length (additional setting of wished special cable length, e. g. SK015 for 1.50 m or SK155 for 15.50 m) L = S7 coaxial lab plug head Marking of basic type

Meinsberg electrodes for laboratory and process • Electrochemical sensors are developed and manufactured in

Meinsberg (Saxony/Germany) for more than 65 years.

• The innovative team of experienced chemists, design engineers, technicians and glassblowers realises high reliability, flexibility and quality.

• This catalogue presents our standard range of sensors for measuring pH value, redox potential, conductivity, dissolved oxygen, chlorine and temperature for application in laboratory and process.

• In the first part of the catalogue you find sensors for measuring in laboratory which are configured individually. These laboratory electrodes are available with plug or cable connection. Furthermore cable length and cable plug can be chosen. The order key for the different sensors (reference electrodes, pH and redox combination electrodes, conductivity cells and oxygen sensors) is illustrated in the folding book cover.

• In the second part of the catalogue you find sensors which are designed for online measurements in process. These process electrodes are always equipped with a plug connector with thread PG 13.5 for easy mounting in immersion or flow through housings. The order codes are shown in chapter “process electrodes” below the sensor pictures.

• On the following pages (2-5) the most important electrodes for laboratory and process with technical data and application advices are listed.

1

Content

1. Electrode selection table for application in laboratory and process ........................................................... 2

2. Technical data of pH- and redox combination electrodes ............................................................................. 4

3. Electrodes for Laboratory ................................................................................................................................. 6

3.1 Reference electrodes .......................................................................................................................... 6 3.2 pH combination electrodes .................................................................................................................. 8 3.3 Redox combination electrodes .......................................................................................................... 12 3.4 Conductivity cells ............................................................................................................................... 13 3.5 Oxygen sensors ................................................................................................................................ 15 3.6 Connection cables for laboratory ...................................................................................................... 16

4. Electrodes for Process .................................................................................................................................... 17

4.1 Temperature sensors ........................................................................................................................ 17 4.2 pH glass electrodes and reference electrodes .................................................................................. 18 4.3 pH combination electrodes ................................................................................................................ 19 4.4 Redox combination electrodes .......................................................................................................... 22 4.5 Conductivity cells ............................................................................................................................... 23 4.6 Oxygen sensors ................................................................................................................................ 25 4.7 Chlorine sensors ............................................................................................................................... 27 4.8 Turbidity- and suspended solids sensors .......................................................................................... 29 4.9 Connection cables for process .......................................................................................................... 30

5. Electrical and process connection ................................................................................................................. 31

6. Standard Solutions and Electrolytes ............................................................................................................. 33

7. Temperature range of standard solutions, standard potentials of reference electrodes ........................ 34

2

1. Electrode selection table for application in laboratory and process (pH, redox, conductivity, oxygen and chlorine)

aq

uariu

ms

aque

ous

solu

tions

biot

echn

olog

y (fe

rmen

ter)

cosm

etic

s

drin

king

wat

er

drin

ks

elec

trop

latin

g

field

mea

sure

men

ts

high

pH

val

ues

low

ioni

c m

ediu

ms

EGA 121 EGA 131 EGA 133 EGA 140 EGA 141 EGA 142 EGA 143 EGA 150 EGA 151 EGA 153 EGA 161 EGA 173 EGA 184 EGA 186 EGA 233 EGA 81 EGC 151 EGC 151 I/S EGP 150 EGV 150 OGA 201 EMC 133 EMC 173 EMC 30 EMC 33 LTC 0,35/23 LTC 1/23 LTG 0,1/23 LTG 1/23 LVV 0,1/23 MF 39 MF 39-T MF 41 CL 4 CS 2, CP 2 MCL 10

3

pene

trat

ion

mea

sure

men

ts in

che

sse

or m

eat

pene

trat

ion

mea

sure

men

ts in

soi

l

proc

ess

chem

istr

y

sea

wat

er

smal

l vol

ume

sam

ples

soap

wat

er

surf

aces

(e

. g. p

aper

)

swim

min

g po

ols

tem

pera

ture

co

mpe

nsat

ed

mea

sure

men

ts

was

te w

ater

/sew

age

wat

er s

olub

le la

cque

rs

page

8 8 8, 19 19 9 9 19 20 10 20 9, 21 21 11 11 19 11 10 20 21 21 10 12, 22 22 12 22 13, 23 13 13, 23 14, 24 14, 24 25 25 15, 25 27 28 27

4

2. Technical data of pH- and redox combination electrodes

All combination electrodes which are shown in the following table are equipped with a Ag/AgCl reference electrode. pH combination electrodes

type shaft material

shaft length (standard) in mm

shaft diameter (mm)

shaft diameter below (mm)

temperature sensor

membrane shape

reference electrolyte (KCl concentration)

EGA 121 glass 120 12 12 yes cylinder fluid (3 M)

EGA 131 plastic 120 12 12 no ball fluid (3 M)

EGA 133 plastic 120 12 12 no cylinder gel (3 M)

EGA 140 glass 120 12 12 yes cylinder gel (3 M)

EGA 141 glass 120 12 12 yes cylinder fluid (3 M)

EGA 142 plastic 120 12 12 yes cylinder gel (3 M)

EGA 143

glass

120

12

12

yes

cylinder

gel (3 M)

EGA 150 glass 120 12 12 no cylinder gel (3 M)

EGA 151 glass 120 12 12 no cylinder fluid (3 M)

EGA 153 glass 120 12 12 no cylinder gel (3 M)

EGA 161

glass

120

12

12

no

cylinder

fluid (3 M)

EGA 173

glass

120

12

12

no

cylinder

gel (3 M)

EGA 184 glass 120 12 6 no spear gel (3 M)

EGA 186 glass 170 12 6 no cylinder fluid (3 M)

EGA 233 plastic 120 12 12 no cylinder gel (3 M)

EGA 81 glass 120 12 12 no spear fluid (3 M)

EGC 151 glass 120 12 12 no cylinder fluid (3 M)

EGC 151 I/S glass 120 12 12 no cylinder fluid (saturated)

EGP 150 glass 120 12 12 no cylinder gel (3 M)

EGV 150 glass 120 12 12 no cylinder gel (3 M)

OGA 201 glass 120 12 17 no flat fluid (3 M)

redox combination electrodes

type shaft material shaft length (standard) in mm

shaft diameter (mm) metall electrode

reference electrolyte (KCl concentration)

EMC 133 plastic 120 12 platinum disc gel (3 M)

EMC 173

glass

120

12

platinum disc

gel (3 M)

EMC 30 glass 120 12 platinum disc fluid (3 M)

EMC 33 glass 120 12 platinum disc gel (3 M)

5

diaphragm number of diaphragms pH range temperature

range (°C) pressure (bar) sample: minimum conductivity (µS/cm)

minimum immersion depth (mm)

page

ceramic 1 2 … 11 -5 … 60 pressureless 100 15 8

ceramic 2 0 … 14 -5 … 80 pressureless 100 15 8

ceramic 2 0 … 14 -5 … 80 < 6 100 15 8, 19

ceramic 2 0 … 14 -5 … 80 < 6 100 22 19

ceramic 2 0 … 14 -5 … 80 pressureless 100 22 9

ceramic 2 0 … 14 -5 … 80 pressureless 100 15 9

ring-shaped sleeve junction

1

0 … 14

-5 … 80

< 6

50

27

19

ceramic 1 0 … 14 -5 … 80 < 6 100 22 20

ceramic 1 0 … 14 -5 … 80 pressureless 100 22 10

ceramic 3 0 … 14 -5 … 80 < 6 100 22 20 1

flexible sleeve junction

1

0 … 14

-5 … 80

pressureless

20

32

9, 21

ring-shaped sleeve junction

1

0 … 14

-5 … 80

< 6

50

27

21

1

ceramic 2 2 … 11 -5 … 60 pressureless 100 15 11

ceramic 2 2 … 11 -5 … 60 pressureless 100 15 11

ceramic 2 0 … 14 -5 … 80 < 6 100 15 19

ceramic 3 0 … 14 -5 … 80 pressureless 100 22 11

ceramic 1 0 … 14 -5 … 100 pressureless 100 22 10

ceramic 1 0 … 14 -5 … 100 pressureless 100 22 20

ceramic 3 0 … 14 -5 … 130 < 15 100 22 21

hole 2 0 … 14 -5 … 130 < 6 50 22 21

ceramic 1 2 … 11 -5 … 60 pressureless 100 2 10

diaphragm number of

diaphragms measuring range (mV)

temperature range (°C) pressure (bar)

sample: minimum conductivity (µS/cm)

minimum immersion depth (mm)

page

ceramic 2 ± 2000 -5 … 80 < 6 100 15 12, 22

ring-shaped sleeve junction

1

± 2000

-5 … 80

< 6

50

17

22

1

ceramic 1 ± 2000 -5 … 80 < 6 100 12 12

ceramic 1 ± 2000 -5 … 80 < 6 100 12 22

1 This sensor contains a KCl reserve pipe in the reference electrolyte.

6

3. Electrodes for Laboratory

3.1 Reference electrodes KE 10, KE 11 SE 10, SE 11

• calomel electrode for measurements

in very small volumes • long-term stable (electrolyte with

saturated KCl solution and KCl reserve) • shaft diameter: 5 mm • standard glass cone (NSK 7) is

available for gas tight mounting in corrosion measuring cells with the according sleeve

• reference electrode with Ag/AgCl

reference system for measurements in very small volumes

• long-term stable (electrolyte with saturated KCl solution and KCl reserve)

• shaft diameter: 5 mm • easy cleaning by removing the sleeve

connector • standard glass cone (NSK 7) is

available for gas tight mounting in corrosion measuring cells with the according sleeve

Technical Data: Type KE 10 KE 11 SE 10 SE 11 Shaft glass, Ø 12/5 mm glass, Ø 12/5 mm glass, Ø 12/5 mm glass, Ø 12/5 mm Shaft length 155 mm 155 mm 155 mm 155 mm Reference system

calomel calomel Ag/AgCl Ag/AgCl

Electrolyte (KCl)

fluid (saturated) with KCl reserve

fluid (saturated) with KCl reserve

fluid (saturated) with KCl reserve

fluid (saturated) with KCl reserve

Bridge electrolyte

- - - -

Diaphragm

sleeve junction 1 x ceramic sleeve junction 1 x ceramic

Temperature range -5 … 60 °C -5 … 60 °C -5 … 80 °C -5 … 80 °C Minimum immersion depth

10 mm 10 mm 10 mm 10 mm

Application

small volume sample, aqueous solutions

small volume sample, aqueous solutions

small volume sample, aqueous solutions

small volume sample, aqueous solutions

Electrical connection

4 mm banana socket 4 mm banana socket 4 mm banana socket 4 mm banana socket

Order code/ Order key

KE 10, KE 10 NSK-7

KE 11, KE 11 NSK-7

SE 10, SE 10 NSK-7

SE 11, SE 11 NSK-7

SE 10 NSK 7 KE 11

7

SE 20, SE 21 SE 20 EB, SE 21 EB

• reference electrode with Ag/AgCl reference system for

measurements in connection with ion-selective electrodes • long-term stable (electrolyte with saturated KCl solution

and KCl reserve) • shaft diameter: 12 mm

• reference electrode with Ag/AgCl double-junction

reference system for measurements in critical mediums • measurements in connection with ion-selective electrodes • long-term stable (electrolyte with saturated KCl solution

and KCl reserve) • the bridge electrolyte is defined by the customer

SE 20 SE 21 SE 20 EB SE 21 EB glass, Ø 12 mm glass, Ø 12 mm glass, Ø 12 mm glass, Ø 12 mm 120 mm 120 mm 160 mm 160 mm

Ag/AgCl Ag/AgCl Ag/AgCl Ag/AgCl

fluid (saturated) with KCl reserve

fluid (saturated) with KCl reserve

fluid (saturated) with KCl reserve

fluid (saturated) with KCl reserve

- - customer request customer request

flexible sleeve junction 1 x ceramic flexible sleeve junction (outside), 2 x ceramic (inside), (double junction reference system)

1 x ceramic (outside) 2 x ceramic (inside), (double junction reference system)

-5 … 100 °C -5 … 100 °C -5 … 100 °C -5 … 100 °C

20 mm 10 mm 20 mm 10 mm

polluted or low ionic mediums

aqueous solutions polluted mediums, strong acids and bases

critical mediums (strong acids and bases)

S7 coaxial lab plug head, fixed cable

S7 coaxial lab plug head, fixed cable

S7 coaxial lab plug head, fixed cable

S7 coaxial lab plug head, fixed cable

Refer to the left book cover! Refer to the left book cover! Refer to the left book cover! Refer to the left book cover!

All electrodes can be configured according to plug connector, cable length, plug and thread PG 13.5 (Refer to the left book cover!). The connection cable for the S7 coaxial lab plug head is illustrated on page 16.

SE 21-L SE 20 EB-L

8

3.2 pH combination electrodes EGA 131 EGA 133 EGA 121

• pH combination

electrode for swimming pool and aquarium water

• robust plastic shaft with integrated pH membrane protection

• refillable electrolyte

• pH combination

electrode for swimming pool and aquarium water

• robust plastic shaft with integrated pH membrane protection

• gel electrolyte

• pH combination

electrode for pocket meters

• integrated temperature sensor

• refillable electrolyte • robust plastic shaft

with integrated pH membrane protection

Technical Data: Type EGA 131 EGA 133 EGA 121 Shaft plastic, Ø 12 mm plastic, Ø 12 mm plastic, Ø 12 mm Shaft length 120 mm 120 mm 120 mm Temperature sensor

- - Pt 1000 or Pt 100 or NTC 30 kΩ

Membrane shape ball cylinder cylinder Reference system Ag/AgCl Ag/AgCl Ag/AgCl Electrolyte (KCl) fluid (3 M) gel (3 M) fluid (3 M) Diaphragm 2 x ceramic 2 x ceramic 1 x ceramic Isopotential point 7.0 ± 0.3 7.0 ± 0.3 7.0 ± 0.3 pH range 0 … 14 0 … 14 2 … 11 Temperature range -5 … 80 °C -5 … 80 °C -5 … 60 °C Minimum immersion depth

15 mm 15 mm 15 mm

Application

field measurements, aquarium water, surface water, swimming pools

field measurements, aquarium water, surface water, swimming pools

field measurements, aquarium water,surface water, swimming pools, waste water, environmental analysis

Electrical connection

S7 coaxial lab plug head, fixed cable

S7 coaxial lab plug head, fixed cable

SMEK lab plug head, fixed cable

Order key

Refer to the left book cover! Refer to the left book cover! Refer to the left book cover!

All electrodes can be configured according to plug connector, cable length, plug and thread PG 13.5 (Refer to the left book cover!). The connection cable for the S7 coaxial lab plug head is illustrated on page 16. The connection cable for the SMEK lab plug head is illustrated on page 16 and 30.

EGA 131-L EGA 133-L EGA 121-X-E

9

EGA 141 EGA 142 EGA 161

• pH combination electrode for

pocket meters • integrated temperature sensor • refillable electrolyte • glass shaft can be cleaned very

well

• pH combination electrode for

pocket meters • integrated temperature sensor • low maintenance • robust plastic shaft with

integrated pH membrane protection

• pH combination electrode for

measurements in low ionic mediums and cosmetics

• refillable electrolyte • flexible sleeve junction

EGA 141 EGA 142 EGA 161 glass, Ø 12 mm plastic, Ø 12 mm glass, Ø 12 mm 120 mm 120 mm 120 mm

Pt 1000 or Pt 100 or NTC 30 kΩ

Pt 1000 or Pt 100 or NTC 30 kΩ

-

cylinder cylinder cylinder Ag/AgCl Ag/AgCl Ag/AgCl fluid (3 M) gel (3 M) fluid (3 M) 2 x ceramic 2 x ceramic flexible sleeve junction 7.0 ± 0.3 7.0 ± 0.3 7.0 ± 0.3 0 … 14 0 … 14 0 … 14 -5 … 80 °C -5 … 80 °C -5 … 80 °C

22 mm 15 mm 32 mm

aquarium water, surface water, swimming pools, waste water, environmental analysis

field measurements, aquarium water, surface water, swimming pools, waste water, environmental analysis

low ionic mediums, cosmetics

SMEK lab plug head, fixed cable SMEK lab plug head, fixed cable S7 coaxial lab plug head, fixed cable

Refer to the left book cover! Refer to the left book cover! Refer to the left book cover!

The pH combination electrode EGA 141 is also available with HT-glass (EGC 141). EGC 141 can be used in hot (100 °C) mediums with extreme pH values. All electrodes can be configured according to plug connector, cable length, plug and thread PG 13.5 (Refer to the left book cover!). The connection cable for the S7 coaxial lab plug head is illustrated on page 16. The connection cable for the SMEK lab plug head is illustrated on page 16 and 30.

EGA 161-L EGA 141-X-E EGA 142-X-E

10

EGA 151, EGC 151 OGA 201

EGA 151: • pH combination electrode for general application in

laboratory and beverage industry • refillable electrolyte • glass shaft can be cleaned very well EGC 151: • pH combination electrode for measurements in hot

(100 °C) mediums with extreme pH values • refillable electrolyte • glass shaft can be cleaned very well

• pH combination electrode for

measurements on surfaces, e. g. paper

• flat membrane

Technical Data: Type EGA 151 EGC 151 OGA 201 Shaft glass, Ø 12 mm glass, Ø 12 mm glass, Ø 12 mm Shaft length 120 mm 120 mm 120 mm Temperature sensor

- - -

Membrane shape cylinder cylinder flat Reference system Ag/AgCl Ag/AgCl Ag/AgCl Electrolyte (KCl) fluid (3 M) fluid (3 M) fluid (3 M) Diaphragm 1 x ceramic 1 x ceramic 1 x ceramic Isopotential point 7.0 ± 0.3 7.0 ± 0.3 7.0 ± 0.3 pH range 0 … 14 0 … 14 2 … 11 Temperature range -5 … 80 °C -5 … 100 °C -5 … 60 °C Minimum immersion depth

22 mm 22 mm 2 mm

Application

aquarium water, beverages, environmental analysis

hot (100 °C) mediums with extreme pH values

pH measurements on surfaces, e. g. paper

Electrical connection

S7 coaxial lab plug head, fixed cable

S7 coaxial lab plug head, fixed cable

S7 coaxial lab plug head, fixed cable

Order key

Refer to the left book cover!

Refer to the left book cover!

Refer to the left book cover!

All electrodes can be configured according to plug connector, cable length and plug (Refer to the left book cover!). The OGA 201 can not be equipped with thread PG 13.5 (P). The connection cable for the S7 coaxial lab plug head is illustrated on page 16.

EGA 151-L OGA 201-L

11

EGA 81 EGA 184 EGA 186

• pH combination electrode for

penetration measurements in soil • spear membrane

• pH combination electrode for

penetration measurements in meat and cheese

• internal gel electrolyte (a measurement is possible in every position)

• spear membrane

• pH combination electrode for

measurements in small volumes • shaft diameter: 6 mm • refillable electrolyte

EGA 81 EGA 184 EGA 186 glass, Ø 12 mm glass, Ø 12/6 mm glass, Ø 12/6 mm 120 mm 120 mm 170 mm

- - -

spear spear cylinder Ag/AgCl Ag/AgCl Ag/AgCl fluid (3 M) gel (3 M) fluid (3 M) 3 x ceramic 2 x ceramic 2 x ceramic 7.0 ± 0.3 7.0 ± 0.3 7.0 ± 0.3 0 … 14 2 … 11 2 … 11 -5 … 80 °C -5 … 60 °C -5 … 60 °C

22 mm 15 mm 15 mm

viscous mediums, samples of soil penetration measurements in food small volume samples

S7 coaxial lab plug head, fixed cable S7 coaxial lab plug head, fixed cable S7 coaxial lab plug head, fixed cable

Refer to the left book cover! Refer to the left book cover! Refer to the left book cover!

All electrodes can be configured according to plug connector, cable length and plug (Refer to the left book cover!). The connection cable for the S7 coaxial lab plug head is illustrated on page 16.

EGA 81-L EGA 184-L EGA 186-L

12

EMC 133-L EMC 30-L

3.3 Redox combination electrodes EMC 133 EMC 30

• redox combination electrode for swimming

pool and aquarium water • mechanical stable platinum disc • robust plastic shaft with integrated

sensor protection

• redox combination electrode for general

application in laboratory and soap water • mechanical stable platinum disc • refillable electrolyte • glass shaft can be cleaned very well

Technical Data: Type EMC 133 EMC 30 Shaft plastic, Ø 12 mm glass, Ø 12 mm Shaft length 120 mm 120 mm Measuring electrode

platinum disc Ø 5 mm platinum disc Ø 5 mm

Reference system Ag/AgCl Ag/AgCl Electrolyte (KCl) gel (3 M) fluid (3 M) Diaphragm

2 x ceramic 1 x ceramic

Measuring range ± 2000 mV ± 2000 mV Temperature range -5 … 80 °C -5 … 80 °C Minimum immersion depth

15 mm 12 mm

Application

field measurements, aquarium water, surface water, swimming pools

raw water, soap water, environmental analysis

Electrical connection

S7 coaxial lab plug head, fixed cable S7 coaxial lab plug head, fixed cable

Order key

Refer to the right book cover! Refer to the right book cover!

All electrodes can be configured according to plug connector, cable length, plug and thread PG 13.5 (Refer to the right book cover!). The connection cable for the S7 coaxial lab plug head is illustrated on page 16.

13

LTC 1/23-E LTC 0,35/23-E

3.4 Conductivity cells LTC 0,35/23 LTC 1/22 or LTC 1/23

• conductivity cell for pocket meters • 4-electrode technology • wide measuring range:

5 µS/cm … 500 mS/cm • integrated temperature sensor • robust plastic shaft

• conductivity cell for pocket meters and

aquaristics • 2-electrode technology • robust plastic shaft • graphite electrodes can be cleaned

very well • integrated temperature sensor

Technical Data: Type LTC 0,35/23 LTC 1/22 or LTC 1/23 Shaft plastic, Ø 12 mm plastic, Ø 12 mm Shaft length 120 mm 120 mm Electrode material

graphite graphite

Temperature sensor

Pt 1000 LTC 1/22: Pt 100 LTC 1/23: Pt 1000

Measuring principle

4-electrode technology 2-electrode technology

Cell constant 0.33 cm-1 ± 5 % 1 cm-1 ± 20 % Measuring range 5 µS/cm … 500 mS/cm 10 µS/cm … 20 mS/cm Temperature range -5 … 80 °C -5 … 80 °C Minimum mmersion depth

20 mm 15 mm

Application

drinking water, surface water, waste water, sea water, industrial process water, acids, bases

drinking water, surface water, waste water, sea water

Electrical connection

SMEK lab plug head, fixed cable SMEK lab plug head, fixed cable

Order key

Refer to the right book cover! Refer to the right book cover!

All electrodes can be configured according to plug connector, cable length and thread PG 13.5 (Refer to the right book cover!). The connection cable for the SMEK lab plug head is illustrated on page 16 and 30.

14

LTG 0,1/23-E LTG 1/23-E

LTG 0,1/22 or LTG 0,1/23 LTG 1/22 or LTG 1/23

• conductivity cell for measurements in

low ionic mediums e. g. distilled water • 2-electrode technology • low conductivity values:

1 µS/cm … 200 µS/cm • long-term stable platinum electrodes • integrated temperature sensor

• conductivity cell for measurements in

swimming pools and beverage industry • 2-electrode technology • wide measuring range:

10 µS/cm … 20 mS/cm • long-term stable platinum electrodes

realise measurements in critical mediums • integrated temperature sensor

Technical Data: Type LTG 0,1/22 or LTG 0,1/23 LTG 1/22 or LTG 1/23 Shaft glass, Ø 12 mm glass, Ø 12 mm Shaft length 120 mm 120 mm Electrode material

platinum (8x17 mm) platinum (3x4 mm)

Temperature sensor

LTG 0,1/22: Pt 100 LTG 0,1/23: Pt 1000

LTG 1/22: Pt 100 LTG 1/23: Pt 1000

Measuring principle

2-electrode technology 2-electrode technology

Cell constant 0.1 cm-1 ± 20 % 1 cm-1 ± 20 % Measuring range 1 µS/cm … 200 µS/cm 10 µS/cm … 20 mS/cm Temperature range -5 … 100 °C -5 … 100 °C Minimum immersion depth

35 mm 25 mm

Application

low ionic mediums (distillation plants, ion exchanger)

drinking water, surface water, waste water, sea water, swimming pools, beverages

Electrical connection

SMEK lab plug head, fixed cable SMEK lab plug head, fixed cable

Order key

Refer to the right book cover! Refer to the right book cover!

All electrodes can be configured according to plug connector, cable length and thread PG 13.5 (Refer to the right book cover!). The connection cable for the SMEK lab plug head is illustrated on page 16 and 30.

15

MF 41-N-E

3.5 Oxygen sensors MF 41-N

• oxygen sensor for measurements in

aqueous solutions in connection with pocket meters

• corrosion-resistant for application in sea water

• integrated temperature sensor for temperature compensation

• robust plastic shaft • membrane head is changeable

Technical Data: Type MF 41-N Shaft plastic, Ø 12 mm Shaft length 120 mm Cathode platinum Anode Ag/AgCl Temperature sensor Pt 1000 Measuring principle amperometric (Clark) Signal in air 100 … 130 nA Response time in N2 t90 < 30 s Flow rate > 9 cm/s Measuring range 0 … 20 mg/l, 0 … 200 % air saturation Temperature range -5 … 45 °C Minimum immersion depth

30 mm

Application

field measurements, aquarium water, surface water, sea water

Electrical connection

SMEK lab plug head, fixed cable

Order key

Refer to the right book cover!

All electrodes can be configured according to plug connector, cable length and thread PG 13.5 (Refer to the right book cover!). The connection cable for the SMEK lab plug head is illustrated on page 16 and 30.

16

3.6 Connection cables for laboratory The following standard cable lengths are available: 1 m, 2 m, 5 m, 10 m and 15 m Special cable lengths are possible. order code cable 1. cable end 2. cable end sensors Koax 3 Ø 3 mm,

coax S7 cable socket

German DIN plug

pH combination electrode, redox combination electrode

Koax 4 Ø 3 mm, coax

S7 cable socket

4 mm banana plug

reference electrode

Koax 5 Ø 3 mm, coax

S7 cable socket

BNC plug

pH combination electrode, redox combination electrode, 2-electrode conductivity cell, oxygen sensor

Koax 6 Ø 5 mm, coax

S7 cable socket

2 x 4 mm banana plug

2-electrode conductivity cell, temperature sensor

Koax 7 Ø 3 mm, coax

S7 cable socket

Cinch plug

pH combination electrode, redox combination electrode

Koax 9 Ø 5 mm, 1 shield, 1 coax, 4 wires

SMEK socket

BNC plug, 2 x 4 mm banana plug

pH combination electrode with temperature sensor (e. g. for LM 2000)

Koax 10 Ø 5 mm, 1 shield, 6 wires

SMEK socket

BNC plug, 2 x 4 mm banana plug

oxygen sensor with temperature sensor (e. g. for LM 2000)

Koax 11 Ø 5 mm, 1 shield, 6 wires

SMEK socket

BNC plug, 2 x 4 mm banana plug

2-electrode conductivity cell with temperature sensor (e. g. for LM 2000)

Example: measuring cable Koax 3 with 1 m standard cable length = Koax 3/1 „SMEK“ is another description for „SixPlug“.

17

Pt 1000 I

4. Electrodes for Process

4.1 Temperature sensors Pt 100 I, Pt 1000 I

• platinum temperature sensor in accordance with DIN EN 60751, class A • long-term stable • glass shaft can be cleaned very well • for temperature compensation of electrochemical parameters

Technical Data: Type Pt 100 I Pt 1000 I Shaft

glass, Ø 12 mm glass, Ø 12 mm

Immersion length

120 mm 120 mm

Temperature sensor

Pt 100 platinum temperature sensor in accordance with DIN EN 60751, class A

Pt 1000 platinum temperature sensor in accordance with DIN EN 60751, class A

Temperature range

-10 … 100 °C -10 … 100 °C

Pressure

< 6 bar < 6 bar

Application

fluids fluids

Electrical connection

S7 coaxial plug head with thread PG 13.5 S7 coaxial plug head with thread PG 13.5

Order code

Pt 100 I Pt 1000 I

The connection cable for the S7 coaxial plug head with thread PG 13.5 is illustrated on page 30.

18

GA 151 I SE 23 I

4.2 pH glass electrodes and reference electrodes GA 151 I SE 23 I

• pH glass electrode for measurements in

aqueous solutions • measuring in connection with the

reference electrode SE 23 I

• reference electrode for measurements in

aqueous solutions • measuring in connection with the pH

glass electrode GA 151 I or with ion-selective electrodes

• gel electrolyte and 3 KCl reserve pipes • low maintenance

Technical Data: Type GA 151 I SE 23 I Shaft glass, Ø 12 mm glass, Ø 12 mm Immersion length 120 mm 120 mm Temperature sensor

- -

Membrane shape cylinder - Reference system - Ag/AgCl Electrolyte (KCl)

- gel (3 M)

Diaphragm - 3 x ceramic Isopotential point 7.0 ± 0.3 - pH range 0 … 14 - Temperature range -5 … 80 °C -5 … 80 °C Pressure

< 6 bar < 6 bar

Minimum conductivity of the medium

-

100 µS/cm

Application

aqueous solutions aqueous solutions

Electrical connection

S7 coaxial plug head with thread PG 13.5 S7 coaxial plug head with thread PG 13.5

Order code

GA 151 I SE 23 I

The connection cable for the S7 coaxial plug head with thread PG 13.5 is illustrated on page 30.

19

EGA 133 I EGA 233 I EGA 140 SMEK-X EGA 143 SMEK-X

4.3 pH combination electrodes

EGA 133 I EGA 233 I EGA 140 EGA 143

• pH combination

electrode for swimming pool and aquarium water

• robust plastic shaft with integrated pH membrane protection

• gel electrolyte

• pH combination

electrode for measurements in so called “electrode toxins” (sulphides)

• double-junction reference system

• gel electrolyte

• pH combination

electrode for beverage industry

• integrated temperature sensor

• gel electrolyte

• pH combination

electrode for heavily polluted waste water

• ring-shaped sleeve junction

• integrated temperature sensor

• gel electrolyte

EGA 133 I EGA 233 I EGA 140 EGA 143 plastic, Ø 12 mm plastic, Ø 12 mm glass, Ø 12 mm glass, Ø 12 mm 120 mm 120 mm 120 mm 120 mm

-

-

Pt 1000 or Pt 100 or NTC 30 kΩ

Pt 1000 or Pt 100 or NTC 30 kΩ

cylinder cylinder cylinder cylinder Ag/AgCl Ag/AgCl Ag/AgCl Ag/AgCl

gel (3 M) gel (3 M) gel (3 M) gel (3 M)

2 x ceramic 4 x ceramic 2 x ceramic ring-shaped sleeve junction 7.0 ± 0.3 7.0 ± 0.3 7.0 ± 0.3 7.0 ± 0.3 0 … 14 0 … 14 0 … 14 0 … 14 -5 … 80 °C -5 … 80 °C -5 … 80 °C -5 … 80 °C

< 6 bar < 6 bar < 6 bar < 6 bar

100 µS/cm

100 µS/cm

100 µS/cm

50 µS/cm

raw water, waste water, surface water, swimming pools

waste water, electroplating, mediums in so called „electrode toxins“

surface water, soap water, beverages

heavily polluted waste water, electroplating

S7 coaxial plug head with thread PG 13.5

S7 coaxial plug head with thread PG 13.5

SMEK plug head with thread PG 13.5 or Variopin plug head with thread PG 13.5

SMEK plug head with thread PG 13.5 or Variopin plug head with thread PG 13.5

EGA 133 I EGA 233 I EGA 140 SMEK EGA 140 VP EGC 140 SMEK EGC 140 VP

EGA 143 SMEK EGA 143 VP EGC 143 SMEK EGC 143 VP

The pH combination electrodes EGA 140 and EGA 143 are also available with HT-glass (EGC 140 and EGC 143). EGC 140 and EGC 143 can be used in hot (100 °C) mediums with extreme pH values. The connection cables for the plug connectors (S7 coaxial plug head with thread PG 13.5, SMEK plug head with thread PG 13.5 or Variopin plug head with thread PG 13.5) are illustrated on page 30.

20

EGA 150 I EGA 153 I EGC 151 I/S

EGA 150 I EGC 151 I/S EGA 153 I

• pH combination

electrode for swimming pool and aquarium water

• gel electrolyte

• pH combination

electrode for pressureless application in process chemistry (sugar industry)

• thermally stable up to 100 °C

• long-term stable (electrolyte with saturated KCl solution and KCl reserve)

• pH combination

electrode for waste water and electroplating

• 3 ceramic diaphragms

• gel electrolyte with KCl reserve pipe

Technical Data: Type EGA 150 I EGC 151 I/S EGA 153 I Shaft glass, Ø 12 mm glass, Ø 12 mm glass, Ø 12 mm Immersion length 120 mm 120 mm 120 mm Temperature sensor - - - Membrane shape cylinder cylinder cylinder Reference system Ag/AgCl Ag/AgCl Ag/AgCl Electrolyte (KCl)

gel (3 M) fluid (saturated) with KCl reserve

gel (3 M)

Diaphragm 1 x ceramic 1 x ceramic 3 x ceramic Isopotential point

7.0 ± 0.3 7.0 ± 0.3 7.0 ± 0.3

pH range 0 … 14 0 … 14 0 … 14 Temperature range -5 … 80 °C -5 … 100 °C -5 … 80 °C Pressure

< 6 bar pressureless < 6 bar

Minimum conductivity of the medium

100 µS/cm 100 µS/cm 100 µS/cm

Application

raw water, waste water, surface water, swimming pools

hot (100 °C) mediums with extreme pH values

heavily waste water, electroplating

Electrical connection

S7 coaxial plug head with thread PG 13.5

S7 coaxial plug head with thread PG 13.5

S7 coaxial plug head with thread PG 13.5

Order code

EGA 150 I EGC 150 I

EGC 151 I/S EGA 151 I/S

EGA 153 I EGC 153 I

The pH combination electrodes EGA 150 and EGA 153 are also available with HT-glass (EGC 150 and EGC 153). EGC 150 and EGC 153 can be used in hot (100 °C) mediums with extreme pH values. The pH combination electrode EGC 151 I/S is also available with standard glass (EGA 151 I/S). EGA 151 I/S can be used in low ionic mediums. The connection cable for the S7 coaxial plug head with thread PG 13.5 is illustrated on page 30.

21

EGA 173 I EGA 161 L/PG EGP 150 I EGV 150 I

EGP 150 I EGV 150 I EGA 161 L/PG EGA 173 I

• pH combination

electrode for measurements in process chemistry

• thermally stable up to 130 °C

• gel electrolyte

• pH combination

electrode for sterilisations in biotechnology

• thermally stable up to 130 °C

• gel electrolyte

• pH combination

electrode for low ionic mediums

• side tube realises connecting to an electrolyte reservoir constant outflow of electrolyte

• flexible sleeve junction

• pH combination

electrode for heavily polluted waste water and electroplating

• ring-shaped sleeve junction

• gel electrolyte with KCl reserve pipe

EGP 150 I EGV 150 I EGA 161 L/PG EGA 173 I glass, Ø 12 mm glass, Ø 12 mm glass, Ø 12 mm glass, Ø 12 mm 120 mm 120 mm 120 mm 120 mm - - - - cylinder cylinder cylinder cylinder Ag/AgCl Ag/AgCl Ag/AgCl Ag/AgCl

gel (3 M) gel (3 M) fluid (3 M) gel (3 M)

3 x ceramic 2 x holes flexible sleeve junction sleeve junction 7.0 ± 0.3

7.0 ± 0.3 7.0 ± 0.3 7.0 ± 0.3

0 … 14 0 … 14 0 …14 0 … 14 -5 … 130 °C -5 … 130 °C -5 … 80 °C -5 … 80 °C

< 15 bar < 6 bar < 1 bar with pressure load at side tube connector

< 6 bar

100 µS/cm

50 µS/cm 20 µS/cm 50 µS/cm

process chemistry, high temperatures

biotechnology, fermenters low ionic mediums, drinking water with low conductivity

drinking water, water soluble lacquers, electroplating, waste water

S7 coaxial plug head with thread PG 13.5

S7 coaxial plug head with thread PG 13.5

S7 coaxial lab plug head with thread PG 13.5 (shaft)

S7 coaxial plug head with thread PG 13.5

EGP 150 I EGV 150 I EGA 161 L/PG EGA 173 I EGC 173 I

The pH combination electrode EGA 173 is also available with HT-glass (EGC 173). EGC 173 can be used for hot (100 °C) mediums and extreme pH values. The connection cables for the plug connectors (S7 coaxial lab plug head, S7 coaxial plug head with thread PG 13.5) are illustrated on page 30.

22

EMC 133 I EMC 173 I EMC 33 I

4.4 Redox combination electrodes EMC 133 I EMC 173 I EMC 33 I

• redox combination

electrode for swimming pool and aquarium water

• mechanical stable platinum disc

• robust plastic shaft with integrated sensor protection

• gel electrolyte

• redox combination

electrode for waste water and electroplating

• mechanical stable platinum disc

• ring-shaped sleeve junction

• gel electrolyte with KCl reserve pipe

• redox combination

electrode for swimming pool and fish farming

• mechanical stable platinum disc

• gel electrolyte

Technical Data: Type EMC 133 I EMC 173 I EMC 33 I Shaft plastic, Ø 12 mm glass, Ø 12 mm glass, Ø 12 mm Immersion length 120 mm 120 mm 120 mm Measuring electrode platinum disc Ø 5 mm platinum disc Ø 5 mm platinum disc Ø 5 mm Reference system

Ag/AgCl Ag/AgCl Ag/AgCl

Electrolyte (KCl) gel (3 M) gel (3 M) gel (3 M) Diaphragm 2 x ceramic sleeve junction 1 x ceramic Measuring range

± 2000 mV ± 2000 mV ± 2000 mV

Temperature range -5 … 80 °C -5 … 80 °C -5 … 80 °C Pressure < 6 bar < 6 bar < 6 bar Minimum conductivity of the medium

100 µS/cm 50 µS/cm 100 µS/cm

Application

raw water, waste water, surface water, swimming pools

drinking water, water soluble lacquers, electroplating, waste water

raw water, waste water, surface water, swimming pools

Electrical connection

S7 coaxial plug head with thread PG 13.5

S7 coaxial plug head with thread PG 13.5

S7 coaxial plug head with thread PG 13.5

Order code

EMC 133 I EMC 173 I EMC 33 I

The connection cable for the S7 coaxial plug head with thread PG 13.5 is illustrated on page 30.

23

LTC 0,35/23 SMEK LTG 0,1/23 SMEK

4.5 Conductivity cells LTC 0,35/23 LTG 0,1/22 or LTG 0,1/23

• conductivity cell for waste and sea water • 4-electrode technology • wide measuring range:

5 µS/cm … 500 mS/cm • robust plastic shaft

• conductivity cell for measurements in

low ionic mediums e. g. distilled water • 2-electrode technology • low conductivity values:

1 µS/cm … 200 µS/cm • long-term stable platinum electrodes • integrated temperature sensor

Technical Data: Type LTC 0,35/23 LTG 0,1/22 or LTG 0,1/23 Shaft plastic, Ø 12 mm glass, Ø 12 mm Immersion length 120 mm 120 mm Electrode material graphite platinum (8x17 mm) Temperature sensor

Pt 1000 LTG 0,1/22: Pt 100 LTG 0,1/23: Pt 1000

Measuring principle

4-electrode technology 2-electrode technology

Cell constant 0.33 cm-1 ± 5 % 0.1 cm-1 ± 20 % Measuring range 5 µS/cm … 500 mS/cm 1 µS/cm … 200 µS/cm Temperature range -5 … 80 °C -5 … 100 °C Pressure < 6 bar < 6 bar Application

waste water, sea water, industrial process water, acids, bases

low ionic mediums (distillation plants, ion exchanger)

Electrical connection

SMEK plug head with thread PG 13.5 or Variopin plug head with thread PG 13.5

SMEK plug head with thread PG 13.5 or Variopin plug head with thread PG 13.5

Order code

LTC 0,35/23 SMEK LTC 0,35/23 VP

LTG 0,1/22 SMEK LTG 0,1/22 VP LTG 0,1/23 SMEK LTG 0,1/23 VP

The connection cables for the plug connectors (SMEK plug head with thread PG 13.5 or Variopin plug head with thread PG 13.5) are illustrated on page 30.

24

LVV 0,1/23 SMEK LTG 1/23 SMEK LVV 0,1/23 SMEK-S

LTG 1/22 or LTG 1/23 LVV 0,1/23

• conductivity cell for measurements in

swimming pools and beverage industry • 2-electrode technology • wide measuring range:

10 µS/cm … 20 mS/cm • long-term stable platinum electrodes

realise measurements in critical mediums

• integrated temperature sensor

• robust stainless steel conductivity cell

for industrial application • measurements in low ionic mediums

e. g. distilled water • 2-electrode technology • low conductivity values:

1 µS/cm … 200 µS/cm • integrated temperature sensor

Technical Data: Type LTG 1/22 or LTG 1/23 LVV 0,1/23 Shaft glass, Ø 12 mm stainless steel, Ø 12 mm Immersion length 120 mm 120 mm Electrode material platinum (3x4 mm) stainless steel Temperature sensor

LTG 1/22: Pt 100 LTG 1/23: Pt 1000

Pt 1000

Measuring principle

2-electrode technology 2-electrode technology

Cell constant 1 cm-1 ± 20 % 0.1 cm-1 ± 20 % Measuring range 10 µS/cm … 20 mS/cm 1 µS/cm … 200 µS/cm Temperature range -5 … 100 °C -5 … 100 °C Pressure < 6 bar < 6 bar Application

drinking water, surface water, waste water, sea water

low ionic mediums (distillation plants, ion exchanger)

Electrical connection

SMEK plug head with thread PG 13.5 or Variopin plug head with thread PG 13.5

SMEK plug head with thread PG 13.5 or Variopin plug head with thread PG 13.5

Order code

LTG 1/22 SMEK LTG 1/22 VP LTG 1/23 SMEK LTG 1/23 VP

LVV 0,1/23 SMEK LVV 0,1/23 VP

The connection cables for the plug connectors (SMEK plug head with thread PG 13.5 or Variopin plug head with thread PG 13.5) are illustrated on page 30.

25

MF 39 SMEK MF 41-N SMEK

4.6 Oxygen sensors MF 39, MF 39-T MF 41-N SMEK

MF 39: • oxygen sensor for waste water • integrated temperature sensor • robust plastic shaft • membrane head is changeable MF 39-T: • oxygen sensor for sea water and process

chemistry • corrosion-resistant because of titanium design • integrated temperature sensor • robust plastic shaft • membrane head is changeable

• oxygen sensor for fish farming

in fresh water and sea water • corrosion-resistant • integrated temperature sensor • robust plastic shaft • membrane head is changeable

Technical Data: Type MF 39 MF 39-T MF 41-N SMEK Shaft plastic, stainless steel,

Ø 18 mm plastic, titanium, Ø 18 mm

plastic, Ø 12 mm

Immersion length 120 mm 120 mm 120 mm Cathode platinum platinum platinum Anode Ag/AgCl Ag/AgCl Ag/AgCl Temperature sensor Pt 1000 Pt 1000 Pt 1000 Measuring principle

amperometric (Clark) amperometric (Clark) amperometric (Clark)

Signal in air 100 … 130 nA 100 … 130 nA 100 … 130 nA Response time in N2 t90 < 70 s t90 < 70 s t90 < 30 s Flow rate > 9 cm/s > 9 cm/s > 9 cm/s Measuring range

0 … 60 mg/l, 0 … 200 % air saturation

0 … 60 mg/l, 0 … 200 % air saturation

0 … 20 mg/l, 0 … 200 % air saturation

Temperature range -5 … 45 °C -5 … 45 °C -5 … 45 °C Pressure < 3 bar < 3 bar < 1 bar Application

drinking water, aquarium water, surface water, waste water

sea water, corrosive mediums

aquarium water, surface water, sea water

Electrical connection

SMEK lab plug head with thread PG 16 or Variopin plug head with thread PG 16

SMEK lab plug head with thread PG 16 or Variopin plug head with thread PG 16

SMEK plug head with thread PG 13.5

Order code/ Order key

MF 39 SMEK MF 39 VP

MF 39-T SMEK MF 39-T VP

MF 41-N SMEK

The connection cables for the plug connectors (SMEK lab plug head, Variopin plug head and SMEK plug head with thread PG 13.5) are illustrated on page 30.

26

MF 441

• oxygen sensor for composting plants • integrated temperature sensor • design in stainless steel • membrane head is changeable

Technical Data: Type MF 441 Shaft stainless steel, Ø 18 mm Immersion length shaft length: 105 mm Cathode platinum Anode Ag/AgCl Temperature sensor Pt 1000 Measuring principle

amperometric (Clark)

Signal in air 60 … 80 nA Response time in N2 t90 < 180 s Flow rate - Measuring range

0 … 20 mg/l, 0 … 200 % air saturation

Temperature range -5 … 80 °C Pressure < 1 bar Application

oxygen measurements in composting plants

Electrical connection

fixed cable

Order code/ Order key

Refer to the right book cover!

The oxygen sensor MF 441 can be configured according to cable length and plug (Refer to the right book cover!). The MF 441 can not be equipped with SMEK lab plug head (E) and thread PG 13.5 (P).

MF 441-K010-F

27

CL 4 MCL 10 I

4.7 Chlorine sensors MCL 10 I CL 4

• chlorine sensor for swimming pool and

drinking water treatment • free chlorine • shaft diameter: 12 mm • system depends on pH value and

temperature

• chlorine sensor for swimming pool and

drinking water treatment • free chlorine • system depends on pH value

Technical Data: Type MCL 10 I CL 4 Shaft plastic, Ø 12 mm plastic, Ø 25 mm Immersion length 120 mm 120 mm Measuring principle

amperometric 2-electrode system amperometric 2-electrode system

Measuring range

0 … 2 mg/l 0 … 2 mg/l

pH range

pH 6 … 8 pH 6 … 8

pH dependency in correlation with the dissociation curve of HOCl

in correlation with the dissociation curve of HOCl; pH 7.2 … 7.4 recommended

Flow rate 50 l/h recommended 30 l/h recommended Temperature range 0 … 30 °C 0 … 45 °C (temperature compensated) Pressure

< 1 bar < 1 bar

Application

swimming pools, drinking water, sea and process water

swimming pools, drinking water, sea and process water

Electrical connection

S7 coaxial plug head with thread PG 13.5 CL 4: 4-20 mA, 2-wire connection CL 4-R: -100 mV per mg/l, 4-pin plug connection

Order code

MCL 10 I CL 4 CL 4-R

The connection cables for chlorine sensors are illustrated on page 30.

28

CS 2

CS 2, CP 2

CS 2: • chlorine sensor for swimming pool and drinking water treatment • free chlorine • system with very low pH dependency CP 2: • chlorine sensor for swimming pool and drinking water treatment • total chlorine • system with very low pH dependency

Technical Data: Type CS 2 CP 2 Shaft plastic, stainless steel, Ø 25 mm plastic, stainless steel, Ø 25 mm Immersion length 120 mm 120 mm Measuring principle

amperometric working potentiostatic 3-electrode system

amperometric working potentiostatic 3-electrode system

Measuring range

0 … 2 mg/l 0 … 2 mg/l

pH range

pH 4 … 12 pH 4 … 12

pH dependency about 10 % slope reduction per pH unit about 10 % slope reduction per pH unit Flow rate 30 l/h recommended 30 l/h recommended Temperature range 0 … 45 °C (temperature compensated) 0 … 45 °C (temperature compensated) Pressure

< 0.5 bar < 0.5 bar

Application

swimming pools, drinking and process water

swimming pools, drinking and process water

Electrical connection

CS 2: 4-20 mA, 2-wire connection CS 2-R: -100 mV per mg/l, 4-pin plug connection

CP 2: 4-20 mA, 2-wire connection CP 2-R: -100 mV per mg/l , 4-pin plug connection

Order code

CS 2 CS 2-R

CP 2 CP 2-R

The connection cables for chlorine sensors are illustrated on page 30. Other measuring ranges on request.

29

SSN-T

4.8 Turbidity- and suspended solids sensors SAM-T, SSN-T

SAM-T: • submersible suspended solid probe for measurements in

suspensions and sludges • infrared absorption measurement SSN-T: • submersible turbidity probe for measurements in dirty water

up to 1000 NTU • infrared scattered-light measurement at ISO 7027/EN 27027

Technical Data: Type SAM-T SSN-T Shaft

stainless steel, sensor window epoxy resin, Ø 38 mm

stainless steel, sensor window POM, Ø 38 mm

Shaft length 146 mm, screw mounted cap R 1" 137 mm, screw mounted cap R 1" Optical components light absorption method with four-beam pulsed

light method, infrared light, wavelength 880 nm (absorption maximum)

90° scattered light measurement with pulsed infrared light, wavelength 880 nm, multi-beam pulsed light evaluation

Measuring range 5 … 1000 FNU/NTU 5 … 1000 FNU/NTU Temperature range

0 … 50 °C 0 … 50 °C

Pressure

< 6 bar < 6 bar

Application

waste water, raw water, suspensions, sludges river water, boiler water, purified waste water, surface water, raw and drinking water

Electrical connection

13 m fixed cable with multipin plug, IP 68 13 m fixed cable with multipin plug, IP 68

Order code

SAM-T SSN-T

30

4.9 Connection cables for process The following standard cable lengths are available: 1 m, 2 m, 5 m, 10 m and 15 m Special cable lengths are possible. Cables for process (coaxial cable)

order code cable 1. cable end 2. cable end sensors K 43 Ø 5 mm,

coax S7 cable socket

stripped ends pH combination electrode, redox combination electrode, 2-electrode conductivity cell, oxygen sensor, temperature sensor

K 43-Pt Ø 5 mm, coax

S7 cable socket

stripped ends (divided shield, divided core)

temperature sensor for measuring instruments with 4-wire input

Example: measuring cable K 43 with 5 m standard cable length = K 43/5

Signal cables for chlorine sensors

order code cable 1. cable end 2. cable end sensors C 2000 Ø 3 mm,

2 wires stripped ends stripped ends chlorine sensor with current output

K 100-1 Ø 5 mm, 4 wires

4-pin plug

stripped ends chlorine sensor with voltage output (4 pins)

Example: signal cable C 2000 with 6 m special cable length = C 2000/6

Cables for process (multipin cable)

order code cable 1. cable end 2. cable end sensors K 17 Ø 5 mm,

1 shield, 7 wires

SMEK socket

stripped ends 4-electrode conductivity cell with temperature sensor

K 18 Ø 5 mm, 1 shield, 6 wires

SMEK socket

stripped ends 2-electrode conductivity cell with temperature sensor

K 19 Ø 5 mm, 1 shield, 1 coax, 4 wires

SMEK socket

stripped ends pH combination electrode with temperature sensor

K 39 Ø 5 mm, 1 shield, 6 wires

SMEK socket

stripped ends oxygen sensor with temperature sensor

K-VP Ø 7.5 mm, 1 coax, 1 shield, 6 wires

Variopin socket

stripped ends 2-electrode conductivity cell, 4-electrode conductivity cell, pH combination electrode, oxygen sensor with temperature sensor

Example: multipin cable K 39 with 10 m standard cable length = K 39/10 „SMEK“ is another description for „SixPlug“.

31

5. Electrical and process connection (cables, plug connectors, screwable threads PG 13.5)

Meinsberg electrodes are equipped with fixed cable (length and plug are available) or plug head for applications in laboratory and process. Sensor with fixed cable

type of sensor Kabeltyp cable plugs reference electrode one-wire

cable • 4 mm banana plug

• stripped ends

pH/redox combination electrode

coaxial cable • DIN-, BNC-, Cinch plug • stripped ends

2-electrode conductivity cell, oxygen sensor

coaxial cable • BNC plug • stripped ends

pH combination electrode with temperature sensor

triaxial cable • German DIN plug and 4 mm banana plug (Y-cable) • BNC plug and 4 mm banana plug (Y-cable)

• BNC plug and Cinch plug (Y-cable)

• BNC plug and German MiniDIN plug (Y-cable)

• stripped ends

oxygen sensor with temperature sensor

6-pin cable • multipin plug (6-pin) • stripped ends

32

Sensor with plug head

type of sensor plug connector pH combination electrode, redox combination electrode, 2-electrode conductivity cell, oxygen sensor, temperature sensor

S7 coaxial lab plug head, S7 coaxial plug head with thread PG 13.5

pH combination electrode, 2-electrode conductivity cell, 4-electrode conductivity cell, oxygen sensor with temperature sensor

SMEK lab plug head, SMEK plug head with thread PG 13.5, Variopin plug head with thread PG 13.5

Our sensors are compatible to nearly all measuring instruments worldwide, because of using different plug connector systems Table about different plug connections

plug heads cable socket S7 coaxial lab plug head

S7 cable socket

S7 coaxial plug head with thread PG 13.5

S7 cable socket

SMEK lab plug head

SMEK socket

SMEK plug head with thread PG 13.5

SMEK socket

Variopin plug head with thread PG 13.5

Variopin socket

„SMEK“ is another description for „SixPlug“. Process connections with thread PG 13.5

screwable thread PG 13.5 example application PG 13.5 head

EGA 133 with fixed cable and thread PG 13.5 (head)

gel filled pH-/redox combination electrodes, conductivity cells and oxygen sensors with fixed cable

PG 13.5 shaft

EGA 161 with fixed cable and thread PG 13.5 (shaft)

fluid filled pH combination electrodes and reference electrodes with fixed cable or plug head

Our sensors can be integrated in every process, because of installing a thread PG 13.5 on electrode head or shaft.

33

6. Standard Solutions and Electrolytes

order code pH value 25 °C

storage life (months)

quantity (filled in HDPE bottles)

quality certifcate on request

pH buffer solution (acc. NBS and DIN 19266)

1.68 4.01 6.87 9.18

12 12 12

6

250 ml or 1000 ml X X X X

Industrial pH buffer solution (acc. DIN 19267)

4.65 6.79 9.23

12 12

6

250 ml or 1000 ml X X X

Laboratory pH buffer solution (STM)

4.0 7.0

10.0

12 12

6

250 ml or 1000 ml X X X

Triple-Set pH buffer solution (acc. NBS and DIN 19266)

4.01 6.87 9.18

12 12

6

3 x 250 ml X X X

Triple-Set Laboratory pH buffer solution (STM)

4.0 7.0

10.0

12 12

6

3 x 250 ml X X X

pH buffer solution, coloured pH 4 red; pH 7 green; pH 9 blue

4.0 7.0 9.0

12 12

6

250 ml or 1000 ml X X X

Redox buffer solution UH = 427 mV (Pt-Ag/AgCl: 220 mV) UH = 675 mV (Pt-Ag/AgCl: 468 mV)

app. 7 app. 1

6

12

250 ml or 1000 ml X X

Conductivity standard solution 0.1 N KCl 0.01 N KCl 0.001 N KCl

12

6 6

250 ml or 1000 ml 12.9 mS/cm (25 °C) 1.41 mS/cm (25 °C) 147 µS/cm (25 °C)

X X X

Electrolyte solution KCl solution, saturated KCl solution, 3 mol/l

12 12

250 ml or 1000 ml electrolyte refilling and storage solution for pH/Redox(ORP) combination electrodes and reference electrodes

X X

Electrolyte solution for oxygen sensors Electrolyte II/1 for MF 441 Electrolyte VI for MF 39, MF 40, MF 41

12 12

10 x 1 ml or 50 ml

X X

Cleaning solution 12 250 ml pepsin-hydrochloric acid X Maintenance kit pH 12

12

12

250 ml cleaning solution pepsin- hydrochloric acid

250 ml reconditioning solution hydrofloric acid

250 ml electrolyte 3 mol/l KCl

X

X

X

34

7. Temperature range of standard solutions, standard potentials of reference electrodes

Standard-buffer solution acc. DIN 19266 or NBS

T in °C pH values

A C D F 0 4.010 6.984 9.464 5 1.668 4.004 6.951 9.395 10 1.670 4.000 6.923 9.332 15 1.672 3.999 6.900 9.276 20 1.675 4.001 6.881 9.225 25 1.679 4.006 6.865 9.180 30 1.683 4.012 6.853 9.139 35 1.688 4.021 6.844 9.102 38 1.691 4.027 6.840 9.081 40 1.694 4.031 6.838 9.068 45 1.700 4.043 6.834 9.038 50 1.707 4.057 6.833 9.011 55 1.715 4.071 6.934 8.985 60 1.723 4.087 6.836 8.962

Technical buffer solution acc. DIN 19267 Meinsberg Lab-buffer solution (STM)

Redox-buffer solution 427 mV; pH 7.0 Conductivity standard solution (KCl)

UA: redox potential measured against Ag/AgCl-reference electrode 3 mol/l KCl

UH: redox potential measured against standard hydrogen electrode

T in °C pH values

TC TD TE 0 4.67 6.89 9.48 10 4.66 6.84 9.37 20 4.65 6.80 9.27 25 4.65 6.79 9.23 30 4.65 6.78 9.18 40 4.66 6.76 9.09 50 4.68 6.76 9.00 60 4.70 6.76 8.92 70 4.72 6.76 8.88 80 4.75 6.78 8.85

T in °C pH values

4.0 7.0 10.0 0 4.01 7.13 10.65 5 4.01 7.07 10.52 10 4.00 7.05 10.39 15 4.00 7.02 10.26 20 4.00 7.00 10.13 25 4.01 6.98 10.00 30 4.01 6.98 9.87 35 4.02 6.96 9.74 40 4.03 6.95 9.61 45 4.04 6.95 9.48 50 4.06 6.95 9.35

T in °C pH value UA in mV UH in mV 10 7.06 245 462 15 7.04 236 450 20 7.02 228 439 25 7.00 220 427 30 6.98 212 415 35 6.96 204 404 40 6.95 195 391 50 6.95 178 366 60 6.96 160 340

T in °C conductivity in mS/cm

0.001 N 0.01 N 0.1 N 10 1.020 9.33 15 0.118 1.147 10.48 18 0.127 1.225 11.19 19 0.130 1.251 11.43 20 0.133 1.278 11.67 21 0.136 1.305 11.91 22 0.138 1.332 12.15 23 0.141 1.359 12.39 24 0.144 1.386 12.64 25 0.147 1.413 12.88 30 0.163 1.552 14.12

35

Standard potentials of reference electrodes (potentials [mV] refer to standard hydrogen electrode)

T in °C „silver chloride“, Ag/AgCl, KCl „calomel“, Hg/Hg2Cl2, KCl

1 mol/l 3 mol/l 3.5 mol/l saturated 0.1 mol/l 1 mol/l saturated 0 249.3 224.2 222.1 220.5 333.8 285.4 260.2 5 246.9 220.9 218.7 216.1 334.1 284.7 257.2 10 244.4 217.4 215.2 211.5 334.3 283.9 254.1 15 241.8 214.0 211.5 206.8 334.2 282.7 250.9 20 239.6 210.5 207.6 201.9 334.0 281.5 247.7 25 236.3 207.0 203.7 197.0 333.7 280.1 244.4 30 233.4 203.4 199.6 191.9 333.2 278.6 241.1 35 230.4 199.8 195.4 186.7 332.4 277.0 237.7 40 227.3 196.1 191.2 181.4 331.6 275.3 234.3 45 224.1 192.3 186.8 176.1 330.6 273.5 230.8 50 220.8 188.4 182.4 170.7 329.6 271.6 227.2 55 217.4 184.4 178.0 165.3 269.5 223.6 60 213.9 180.3 173.5 159.8 267.3 219.9 65 210.4 176.4 169.0 154.3 264.8 216.2 70 206.9 172.1 164.5 148.8 262.2 212.4 75 203.4 167.7 160.0 143.3 80 199.9 163.1 155.6 137.8 85 196.3 158.3 151.1 132.3 90 192.7 153.3 146.8 126.9 95 189.1 148.1 142.5 121.5

Special Design We manufacture also only a few sensors in special design according to your requests in a short way.

Some examples for sensors in special design:

• oxygen/temperature sensors for controlling composting plants

• conductivity cells for special applications • sensors with special lengths • reference electrodes • platinum electrodes

Other product lines from Meinsberg

• laboratory multi-parameter systems • potentiostat/galvanostat • corrosion measuring cells potentiostat/galvanostat

• controllers

• laboratory and field instrumentation • pH/redox pre-amplifier • column stand with protective roof

• transmitters

• multi-parameter systems for process • water quality measurement systems transmitters • process probe assemblies

SENSORTECHNIK MEINSBERG GmbH Telephone: +49 (0) 34327 6230 Made in GermanyKurt-Schwabe-Straße 6, OT Meinsberg Fax: +49 (0) 34327 62379D - 04720 Ziegra-Knobelsdorf E-Mail: [email protected]

Meinsberg Electrodes

®

LTaubner
Schreibmaschinentext
LTaubner
Schreibmaschinentext
Meinsberg, Kurt-Schwabe-Straße 6 D-04736 Waldheim
LTaubner
Schreibmaschinentext
LTaubner
Schreibmaschinentext
LTaubner
Schreibmaschinentext
LTaubner
Schreibmaschinentext
LTaubner
Schreibmaschinentext
LTaubner
Schreibmaschinentext
LTaubner
Schreibmaschinentext
LTaubner
Schreibmaschinentext
LTaubner
Schreibmaschinentext