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    Mercury : Questions on Mercury

    ome > Studies > Mercury

    Scientific Facts on

    Mercury

    Source document:UNEP (2002)

    Summary & Details:GreenFacts (2004)

    About this study

    Questions and Answers presented in 3 levels of increasing detail.

    Context - Mercury is a heavy metal whichis known to be highly toxic. Thoughmercury occurs naturally in theenvironment it is now mainly released byhuman activities.

    Are these releases being controlled? Arehumans and theenvironment at risk?

    Questions on Mercury

    1. What is mercury?

    2. What are the impacts of mercury on human health

    3. What are the impacts of mercury on the

    environment?

    4. Where is mercury found?

    5. Where do the world's supplies of mercury come

    from?

    6. What can be done to reduce mercury releases?

    7. What further research and information is needed?

    8. Conclusions

    9. Other views

    This is a faithful summary of the leading scientific consensus report

    produced in 2002 by the UNEP (United Nations Environment Programme)

    "Executive Summary of the Global Mercury Assessment" More...

    More info on our 3-level structure

    Send this page Subscribe to our newsletter Download this study

    09-Nov-2004 Contact | Copyright | Glossary | Sitemap | Link to us | Feedback | About Top

    GreenFacts is a registered trademark of GreenFacts asbl

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    Mercury : Level 1 - Summary on Mercury

    ome > Studies > Mercury > Level 1

    Scientific Facts on

    Mercury

    Source document:UNEP (2002)

    Summary & Details:GreenFacts (2004)

    About this study

    Info on our studies structure

    Level 1 - Summary on Mercury

    1. What is mercury?

    2. What are the impacts of mercury on human health?

    3. What are the impacts of mercury on the environment?

    4. Where is mercury found?

    5. Where do the world's supplies of mercury come from?

    6. What can be done to reduce mercury releases?

    7. What further research and information is needed?

    8. Conclusions

    9. Other views

    Level 1 Questions More in Details

    Next Question Top

    . What is mercury?

    1.1 Mercury is a heavy metal, sometimes known as quicksilver, that occurs naturally in the environment in different

    chemical forms. The pure form, elemental mercury, is liquid at room temperature and slowly forms a vapour in the

    air. Forms more commonly found in nature are inorganic mercury and organic mercury. More...

    1.2 Natural events (e.g. volcanic activity, weathering of rocks) and human activities (e.g. mining, fuel use, productsand processes) can cause mercury releases into the environment. Once released, it can move easily between air,water and land: natural processes can even change mercury from one form to another. More...

    1.3 Mercury can have adverse effects on living organisms and the environment, though these depend on its form as

    well as dose, etc. More...

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    Mercury : Level 1 - Summary on Mercury

    Conclusion Level 1 Questions More in Details

    Next Question Top

    2. What are the impacts of mercury on human health?

    2.1 Mercury and its compounds are highly toxic substances for humans. Methylmercury and elemental mercury are

    the highest concern. They are poisonous to the nervous system. There is some evidence at present that

    methylmercury can cause cancer in humans, but it is far from conclusive. However, there is no evidence at present

    that elemental mercury causes cancer in humans. Moreover, exposure to methylmercury during pregnancy may

    affect the unborn baby. More...

    2.2 Humans are mainly exposed to methylmercury through their diet (particularly fish), and to elemental mercury

    vapours from tooth fillings and at certain workplaces. More...

    2.3 Governmental bodies have set daily mercury intake levels that are considered safe, but some people take in mo

    than these levels. More...

    2.4 Risks vary from one place to another. The risk from diet mainly depends on how much contaminated fish is

    eaten: moderate consumption of fish with low levels of mercury is not a cause for concern. More...

    Conclusion Level 1 Questions More in Details

    Next Question Top

    3. What are the impacts of mercury on the environment?

    3.1 Mercury can be particularly harmful for the environment because it can accumulate in organisms. The levels of

    methylmercury increase along the food chain and with age. More...

    3.2 Mercury may harm bird reproduction and behaviour. Some seals and whales in the Arctic and some predatorymarine mammals in warm waters may be at risk. More...

    3.3 Some ecosystems, such as forest soils, may be affected by mercury. More...

    Conclusion Level 1 Questions More in Details

    Next Question Top

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    Mercury : Level 1 - Summary on Mercury

    4. Where is mercury found?

    4.1 Mercury is released into the environment through both natural processes (e.g. volcanic activity, weathering ofrocks) and human activities (e.g. mining, fuel use, products and processes). Once released, mercury enters air, watand soil, and moves from one to another until it comes to rest in sediments or landfills. More...

    4.2 Mercury deposited from the atmosphere at any particular place comes from both local and global sources. More

    4.3 Human activity is now the main source of mercury being released into the environment. Much is releasedunintentionally from processes where mercury is an unwanted impurity. Emissions into the air, mainly from fossil fu

    power plants and waste incinerators, are expected to increase unless other energy sources are used or emissionsbetter controlled. However, mercury mining is decreasing and therefore releases from mining and mercury use maybe in decline. More...

    4.4 Weathering and evaporation from mercury-rich rocks and soils lead to natural mercury release, as do forest fireand volcanic activity. Although natural emissions are difficult to determine, current estimates suggest that less than50% of total mercury releases come from natural sources. More...

    Conclusion Level 1 Questions More in Details

    Next Question Top

    5. Where do the world's supplies of mercury come from?

    5.1 Mercury placed on the world market comes mainly from cinnabar mines in Spain, China, Kyrgyzstan and Algeria

    It can also be recycled from industrial processes. More...

    5.2 Large amounts of recycled mercury will be available over the next decade and beyond and steps are being taken

    to manage the way it is used. Increased recycling will reduce the movement of new mercury onto the market andinto the environment. More...

    5.3 Because of its unique properties, mercury has been used for extracting gold and silver from ores, in chlor-alkali

    chemical manufacture, in thermometers and manometers, in lights and switches, and in dental amalgam fillings,

    among others. However, use of mercury and mercury compounds has been reduced for health and environmentalreasons. More...

    Conclusion Level 1 Questions More in Details

    Next Question Top

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    Mercury : Level 1 - Summary on Mercury

    6. What can be done to reduce mercury releases?

    6.1 Mercury releases from current human activity may be limited by either preventive measures or control measure

    Preventive measures include reducing the use of mercury-containing products and raw materials, and replacingproducts and processes that contain or use mercury with ones that do not.

    Control measures include end-of-pipe techniques and effective waste management. More...

    6.2 A suitable approach for reducing mercury emissions should involve both preventive and control measures. More

    6.3 There have been many national initiatives to manage the use and release of mercury. These include the setting mercury emission limits, environmental standards and restrictions on use.

    International initiatives include legally binding agreements, non-binding initiatives and voluntary private-sectorinitiatives. More...

    Conclusion Level 1 Questions More in Details

    Next Question Top

    7. What further research and information is needed?

    7.1 Most countries need more information in order to manage mercury effectively. Some lack basic information aboutheir own uses and releases of mercury, as well as levels in their local environment, while others want moreadvanced data in order to assess and manage the risks better. More...

    7.2 Mercury is one of the best-studied environmental toxicants, but there are still some gaps in understanding a

    number of global issues. However, the information available is sufficient to address, without delay, the global advereffects of mercury. More...

    Conclusion Level 1 Questions More in Details

    Next Question Top

    8. Conclusions

    There should be international action to reduce the risks to human health and the environment arising from mercury

    release into the environment.

    While more data will help, the adverse impacts of mercury need to be addressed at the global, regional, national anlocal levels. Various options for doing this have been identified, and areas for immediate action have been proposedMore...

    Conclusion Level 1 Questions More in Details

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    Mercury : Level 1 - Summary on Mercury

    Top

    9. Other views

    This summary is based on the latest United Nations Environmental Programme (UNEP) Global Assessment Report o

    Mercury. It is considered by most scientists as a consensus document and other recent scientific assessments reach

    similar conclusions - click here for some links

    However, some people and organisations put forward different views:

    q Positions suggesting that mercury poses more risk

    q Positions suggesting that mercury poses less risk

    Conclusion Level 1 Questions

    Send this page Subscribe to our newsletter Download this study

    09-Nov-2004 Contact | Copyright | Glossary | Sitemap | Link to us | Feedback | About Top

    GreenFacts is a registered trademark of GreenFacts asbl

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    Other views on Mercury

    About the Toolbox | Back | Print | Forward

    Other views onMercury

    The links on this page have been selected as examples of views that differ from that of the UNEP.

    This list of links is only a sample and neither pretends to be complete nor fully representative of all the views available.

    GreenFacts takes no position concerning the views expressed in these linked documents.

    the UNEP report a consensus one?

    ost scientists globally agree with the conclusions of the Executive summary of the Global Mercury Assessm

    oduced in 2002.

    her institutions having reached similar conclusions:

    The World Health Organization Regional Office for Europe guidelines for mercury in the air (2000):

    http://www.euro.who.int/document/aiq/

    6_9mercury.pdf

    The UK Committee on Toxicity of Chemicals in Food, Consumer Products and the Environment (COT) updateconclusions on a survey of mercury in fish and shellfish (2004):

    http://www.foodstandards.gov.uk/multimedia/

    pdfs/cotstatementmercuryfish.pdf

    ome of the sites suggesting that mercury poses more risk

    nks will soon be available)

    ome of the sites suggesting that mercury poses less risk

    nks will soon be available)

    The links on this page have been selected as examples of views that differ from that of the UNEP.

    This list of links is only a sample and neither pretends to be complete nor fully representative of all the views available.

    GreenFacts takes no position concerning the views expressed in these linked documents.

    Back | Print | Forward Top

    30-Aug-2004

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    Mercury : Level 2 - Details on Mercury

    ome > Studies > Mercury > Level 2

    Scientific Facts on

    Mercury

    Source document:UNEP (2002)

    Summary & Details:GreenFacts (2004)

    About this study

    Info on our studies structure

    Level 2 - Details on Mercury

    q 1. What is mercury?

    r 1.1 In what forms does mercury exist?

    r 1.2 How does mercury exist in the environment?

    r 1.3 How can the form of mercury affect living organisms and the environment?

    q 2. What are the impacts of mercury on human health?

    r 2.1 What are the potential health effects of mercury?

    r 2.2 How are we exposed to mercury?

    r 2.3 What levels of mercury might cause harm?

    r 2.4 How great are the risks from mercury today?

    q 3 . What are the impacts of mercury on the environment?

    r 3.1 How does mercury accumulate in organisms?

    r 3.2 How is wildlife affected?

    r 3.3 How may certain ecosystems be affected?

    q 4. Where is mercury found?

    r 4.1 How does mercury cycle through the biosphere?

    r 4.2 Do local releases cause global effects?

    r 4.3 How much mercury do we release into the environment?

    r 4.4 How is mercury released naturally?

    q 5. Where do the world's supplies of mercury come from?

    r 5.1 How does mercury reach the world market?

    r 5.2 How important is mercury recycling?

    r 5.3 What is mercury used for?

    q 6. What can be done to reduce mercury releases?

    r 6.1 What are the possible ways of controlling mercury releases?

    r 6.2 What is the best overall approach to reduce emissions?

    r 6.3 What is being done to control mercury?

    q 7. What further research and information is needed?

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    Mercury : Level 2 - Details on Mercury

    r 7.1 What are the needs of individual countries?

    r 7.2 What are the global data gaps?

    q 8. Conclusions

    q 9. Other views (level 1 only)

    Back to Summary Level 2 Questions More in the Source Document

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    Mercury : 1. What is mercury?

    ome > Studies > Mercury > Level 2 > Question 1

    Scientific Facts on

    Mercury

    Source document:UNEP (2002)

    Summary & Details:GreenFacts (2004)

    About this study

    Level 1 Questions Next Question

    . What is mercury?

    1.1 In what forms does mercury exist?

    1.2 How does mercury exist in the environment?

    1.3 How can the form of mercury affect living organisms and the environment?

    .1 In what forms does mercury exist?

    Mercury occurs naturally in the environment. Sometimes known as quicksilver, it is a heavy metal, like lead or

    cadmium, that exists in different chemical forms:

    q Elemental mercury or metallic mercury is the element in its pure, un-combined form. It is a shiny, silver-

    white metal that is liquid at room temperature, but is rarely found in this form in nature. If not sealed off,mercury slowly evaporates into the air, forming a vapour. The quantity of vapour formed increases astemperatures rise. Elemental mercury is traditionally used in thermometers and some electrical switches.

    q Inorganic mercury compounds or mercury salts, more commonly found in nature, include mercuric sulphide

    (HgS), mercuric oxide (HgO) and mercuric chloride (HgCl2). Most of these are white powders or crystals,except for mercuric sulphide which is red and turns black after exposure to light. Some mercury salts, suchas mercury chloride, also form vapour, but they stay in the air for a shorter time than elemental mercury

    because they are more soluble in water and more reactive.

    q Organic mercury is formed when mercury combines with carbon and other elements. Examples oforganic

    mercury compounds are dimethylmercury, phenylmercuric acetate and methylmercuric chloride. The form

    most commonly found in the environment is methylmercury. More...

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    Mercury : 1. What is mercury?

    .2 How does mercury exist in the environment?

    Several forms of mercury exist naturally in the environment, the most common being metallic mercury, mercuric

    sulphide, mercuric chloride, and methylmercury.

    Natural processes can change the mercury from one form to another. For instance, chemical reactions in theatmosphere can transform elemental mercury into inorganic mercury.

    Some micro-organisms can produce organic mercury, particularly methylmercury, from other mercury forms.

    Methylmercury can accumulate in living organisms and reach high levels in fish and marine mammals via a process

    called biomagnification (i.e. concentrations increase in the food chain).

    Because mercury is one of the basic chemical elements, of which all things are made, it cannot be broken down ordegraded into something else. Once released into the biosphere through natural events or human activities (see

    Question 4), mercury readily moves and cycles through the environment. Soil, water bodies and the sediments

    underneath them, are believed to be the places where mercury comes to rest until it is ultimately removed from thebiosphere again. More...

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    .3 How can the form of mercury affect living organisms and the environment?

    Different forms of mercury (see 1.1) affect living organisms and the environment differently.

    For exposed living organisms, the form of mercury affects:

    q how available it is to cause effects within the body;

    q how it moves around inside the body;q how toxic it is;

    q how it accumulates, is transformed and leaves the body;

    q how it biomagnifies (builds up) along the food chain.

    For the environment, the form of mercury influences how readily it can move within and between the atmosphereand oceans, and how far it can travel in the air. For instance, elemental mercury vapour can stay in the atmosphere

    long enough to travel around the world, whereas other forms of mercury may fall back to earth relatively close totheir source.

    Emissions of some forms of mercury into the air (for example from industry) can be controlled more easily thanothers. Inorganic mercury can be removed from air emissions reasonably well, while elemental mercury emissions

    are more difficult to capture and eliminate. More...

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    Mercury : 1. What is mercury?

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    Mercury : 2. What are the impacts of mercury on human health?

    ome > Studies > Mercury > Level 2 > Question 2

    Scientific Facts on

    Mercury

    Source document:UNEP (2002)

    Summary & Details:GreenFacts (2004)

    About this study

    Previous Question Level 1 Questions Next Question

    2. What are the impacts of mercury on human health?

    2.1 What are the potential health effects of mercury?

    2.2 How are we exposed to mercury?

    2.3 What levels of mercury might cause harm?

    2.4 How great are the risks from mercury today?

    2.1 What are the potential health effects of mercury?

    The toxicity of mercury depends on the form of mercury to which people are exposed.

    Although mercury and its compounds are toxic substances, there is ongoing debate about exactly how toxic they are

    Toxic effects, especially in the case ofmethylmercury, may be taking place at lower concentrations than previously

    thought, but this is proving difficult to establish because the suspected toxic effects are subtle and their mechanismcomplex. Methylmercury is of particular concern because it can accumulate in the food chain to reach high

    concentrations (biomagnification). More...

    2.1.1. Methylmercury is special among organic mercury compounds because large numbers of people are exposed t

    it and its toxicity is better understood. Methylmercury in food, such as fish, is a particular health hazard because it i

    easily taken up into the body through the stomach an intestines.

    It is a poison for the nervous system. Exposure during pregnancy is of most concern, because it may harm the

    development of the unborn babys brain. Some studies suggest that small increases in exposure may affect the hea

    and circulatory system.

    Moreover, there is some evidence at present that methylmercury can cause cancer in humans, but it is far from

    conclusive: the International Agency for Research on Cancer (IARC) has classified methylmercury as "possibly

    carcinogenic to humans" (Group 2B).

    Methylmercurys poisonous potential was highlighted by an incident in Minamata (Japan), in the 1950s, where waste

    from a chemical factory using mercury were discharged into the local bay. More...

    2.1.2. Elemental mercury is also poisonous to the nervous system. Humans are mainly exposed by inhaling vapours

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    Mercury : 2. What are the impacts of mercury on human health?

    These are absorbed into the body via the lungs and move easily from the bloodstream into the brain. However, whe

    elemental mercury is ingested, little is absorbed into the body.

    The inhalation ofelemental mercury vapours can cause neurological and behavioural disorders, such as tremors,

    emotional instability, insomnia, memory loss, neuromuscular changes and headaches. They can also harm the

    kidneys and thyroid. High exposures have also led to deaths. However, there is no evidence at present that element

    mercury causes cancer in humans and it has been classified by IARC into Group 3 "unclassifiable as to carcinogenici

    in humans". More...

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    2.2 How are we exposed to mercury?

    The main source ofelemental mercury vapour is dental amalgam (a tooth filling).

    Diet, particularly fish, is generally the main source of both inorganic and organic mercury. Methylmercury is by farthe most common organic form, and is especially found in fish and other seafood.

    For some people, the workplace may also be an important source ofexposure. Examples include chlor-alkali plants,

    mercury mines, thermometer factories, refineries and dental clinics, as well as the mining and manufacturing of goldextracted with mercury.

    People can also receive extra doses in specific situations, such as when mercury compounds are used in skin-

    lightening creams, soaps and traditional medicine. Exposure may also arise from localised pollution through air and

    water, and from mercury spills at home or work (e.g. from certain old gas meters containing mercury). More...

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    2.3 What levels of mercury might cause harm?

    For methylmercury, the US Environmental Protection Agency (EPA) has estimated a safe daily intake level of 0.1

    g/kg body weight per day. This was based on a study in the Faroe Islands, where fish containing significant levels

    mercury form a large part of the diet. The study compared development test scores for children whose mothers had

    been exposed during pregnancy(1)

    . A European Union scientific review, in 2001, has supported this safe daily intaklevel.

    For elemental mercury vapour, several studies show that long-term workplace exposures at around 20 g/m3 of a

    or higher have subtle toxic effects on the central nervous system.

    Other adverse effects of various forms of mercury have been seen in humans, but either the findings are less

    consistent or the doses involved are much higher.

    The Working Group that prepared this assessment, in line with its mandate, did not assess the potential effects ofexposures to elemental mercury vapour from dental amalgams or reach any conclusions about whether or not denta

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    Mercury : 3. What are the impacts of mercury on the environment?

    ome > Studies > Mercury > Level 2 > Question 3

    Scientific Facts on

    Mercury

    Source document:UNEP (2002)

    Summary & Details:GreenFacts (2004)

    About this study

    Previous Question Level 1 Questions Next Question

    3. What are the impacts of mercury on the environment?

    3.1 How does mercury accumulate in organisms?

    3.2 How is wildlife affected?

    3.3 How may certain ecosystems be affected?

    3.1 How does mercury accumulate in organisms?

    The harmful effects that different forms of mercury can have on living things are greatly influenced by

    bioaccumulation (build up inside an organism) and biomagnification (build up along the food chain).

    All forms of mercury can accumulate in organisms. However, methylmercury is taken up at a faster rate than other

    forms and bioaccumulates to a greater extent.

    In fish, methylmercury becomes so tightly bound in the tissues that, ifexposure ceases, it takes a very long time fo

    it to be removed.

    This tighter binding leads methylmercury to build up (biomagnify) much more than other forms of mercury along th

    food chain, e.g. from smaller fish to larger predatory fish. As a result, nearly 100% of the mercury that accumulate

    in predator fish is methylmercury. Another consequence is that older fish typically have higher mercuryconcentrations in their tissue than younger fish of the same species, partly because older fish eat more fish and

    larger fish as they age.

    The extent to which mercury will bioaccumulate in any given situation depends on several factors. One importantfactor is how much mercury is converted to methylmercury, and vice-versa, particularly by some bacteria in the

    aquatic environment. Consequently, the extent ofbioaccumulation and biomagnification of mercury in fish remain

    difficult to predict in specific situations.

    The mercury in fish is passed on to the predators at the top of the food chain (e.g. humans, seabirds, seals, otters,eagles and ospreys) and how much they accumulate depends on the type and size of fish they eat. More...

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    Mercury : 3. What are the impacts of mercury on the environment?

    Next Sub-Question Top

    3.2 How is wildlife affected?

    Methylmercury is a poison for the central nervous system. During the Minamata poisoning incident in Japan (see

    2.1.1.), birds had trouble flying and behaved abnormally in other ways.

    Mercury can also affect reproduction. Methylmercury poses a particular risk to the developing foetus because itreadily moves into the placenta and can damage the developing nervous system. Mercury may be present in eggsand harm bird reproduction even when concentrations in eggs are low.

    The kidneys are the organs most vulnerable to damage from inorganic mercury.

    Rising levels of mercury are a concern for some seals and whales in the Arctic and for predatory marine mammals inwarmer waters. More...

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    Top

    3.3 How may certain ecosystems be affected?

    Recent evidence suggests that mercury is reducing microbiological activity, vital to the terrestrial food chain. This

    may already be affecting forest (3) soils over large parts of Europe and potentially in many other places in the worldwith similar soil characteristics.

    Impacts from long-range transport of mercury in the Arctic region have been the focus of recent discussion, but the

    effects are by no means restricted to this region of the world. The same food web characteristics are found in specifecosystems and human communities in many countries, particularly in places where a fish diet is predominant.

    There are indications that climate change might also increase the levels ofmethylmercury in water in some areas,

    and its accumulation in fish. More...

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    Next question

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    Mercury : 4. Where is mercury found?

    ome > Studies > Mercury > Level 2 > Question 4

    Scientific Facts on

    Mercury

    Source document:UNEP (2002)

    Summary & Details:GreenFacts (2004)

    About this study

    Previous Question Level 1 Questions Next Question

    4. Where is mercury found?

    4.1 How does mercury cycle through the biosphere?

    4.2 Do local releases cause global effects?

    4.3 How much mercury do we release into the environment?

    4.4 How is mercury released naturally?

    4.1 How does mercury cycle through the biosphere?

    Mercury moves from the Earths crust into the biosphere as a result of both natural processes and human activities.

    Examples ofnatural processes include the weathering of rocks and volcanic activity.

    Human activity can release mercury:

    q when it is intentionally mined, processed or used in products;q unintentionally, from processes where mercury is an unwanted impurity in raw materials, minerals and foss

    fuels, particularly coal; and

    q from soils, sediments, water bodies, landfills and waste or tailings piles, contaminated previously by humanactivities.

    Once released, mercury enters the air, water and soil and can continue to move between them over long periods oftime, depending on its chemical form (see section 1.3.).

    Mercury is only removed from the biosphere when it reaches sediments deep under the oceans or when it is

    immobilised in controlled landfills. This implies that, even as we gradually eliminate mercury releases from human

    activity, levels in the environment will take several decades or longer to go back down. However, improvements mabe quicker in places where local or regional contamination is a major source. More...

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    Mercury : 4. Where is mercury found?

    Next Sub-Question Top

    4.2 Do local releases cause global effects?

    Airborne mercury may deposit into water or onto soil close to its source of emission, or even on the other side of theworld, depending on its chemical form. Several studies have concluded that the amount of mercury deposited at anyparticular place can come from both local and global sources. Virtually any local source contributes to the globalmercury pool in the biosphere.

    Most of the mercury emitted to the air through human activity is elemental mercury vapour, which can stay airborn

    long enough to cross continents. Other forms of mercury, such as inorganic mercury, fall to earth within roughly 10

    to 1 000 km. However, how far the mercury travels also depends on whether mercury converts from one form toanother in the air.

    Computer modelling has estimated that 50% of the mercury, released by human activity and deposited in North

    America, comes from elsewhere. This figure is 20% for Europe and 15% for Asia.

    Mercury can also be re-released from water and soil, prolonging the time it stays in the biosphere. One study

    suggests that around 20% of the amount deposited can be re-released over a two-year period. More...

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    4.3 How much mercury do we release into the environment?

    4.3.1. Human activity (see 5.1) is now the main source of mercury to the atmosphere, water and soil. A recent stud

    has suggested that the amount of mercury in the atmosphere has tripled because of this.

    On average around the globe, there are indications that human activity has raised the rate of mercury deposition by1.5 to 3 times since pre-industrial times. In and around industrial areas, the deposition rates have increased by 2 to10 times during the past 200 years. More...

    4.3.2. Much data exists about how much mercury some countries and industries release into the environment, butthe global picture is incomplete.

    Fossil fuel power plants and waste incinerators emit about 70% of the mercury released into the atmosphere by

    human activity, for which there is data.

    These releases are expected to increase unless alternative energy sources or technologies to control emissions arefurther developed and widely used.

    Mercury production from mines has been decreasing from about 6 000 to about 2 000 tonnes per year during the

    1980s and 90s. Thus, releases from mining and mercury use may also be in decline. Small-scale gold and silver

    mining can be an important source in some countries (4). More...

    Emissions from a number of major sources have decreased in North America and Europe. In Canada, for example,emissions into the air were reduced from about 33 to 6 tonnes between 1990 and 2000.

    4.3.3. Emissions from human activities come both from the intentional use of mercury, and the unintentional releas

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    Mercury : 4. Where is mercury found?

    of mercury impurities. The share of emissions into the air emanating from intentional uses ranges between 10% and80% for different countries.

    The relative importance of the two types of source in a country or region depends upon:

    q progress made in substituting mercury use in products and processes;q reliance on fossil fuels for energy production, particularly coal;

    q the size of the mining and mineral extraction industry;q waste disposal methods (incineration or landfill); andq the use of technologies to remove mercury from emissions.

    More...

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    4.4 How is mercury released naturally?

    Mercury occurs naturally in forms that are volatile, so mercury continuously evaporates into the atmosphere, from

    both soils and water. Mercury-rich rocks and soils can lead to elevated mercury levels across wide areas. Theweathering of rocks, volcanic activity and forest fires all contribute to the natural emission of mercury into the air.

    Actual natural mercury emissions are very difficult to determine, because total emissions of mercury from soil andwater surfaces come from both natural sources and from re-emission of previously deposited mercury. This, in turn,will have come from both natural sources and human activity.

    Natural mercury emissions are beyond our control, and it is currently estimated that less than 50% of total mercuryreleases are from natural sources. However, it is important to keep them in mind as significant sources of mercury ithe environment. More...

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    Mercury : 5. Where do the world's supplies of mercury come from?

    ome > Studies > Mercury > Level 2 > Question 5

    Scientific Facts on

    Mercury

    Source document:UNEP (2002)

    Summary & Details:GreenFacts (2004)

    About this study

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    5. Where do the world's supplies of mercury come from?

    5.1 How does mercury reach the world market?

    5.2 How important is mercury recycling?

    5.3 What is mercury used for?

    5.1 How does mercury reach the world market?

    The natural levels of mercury in the Earths crust vary from place to place, but average about 50 mg per tonne of

    rock. Mercury is mined when present in cinnabar ores, which generally contain about 10 kg per tonne of rock.

    Mercury is also present at very low levels throughout the biosphere. Thus, mercury absorbed by ancient plants may

    account for its presence in fossil fuels like coal, oil and gas.

    Today, the world market is supplied by mercury that is:

    q newly extracted from mines;q recovered as a by-product of the mining or refining of other metals, minerals, natural gas and old mining

    waste;q recycled from spent products and waste from industrial processes;

    q held in government reserve stocks; andq held in private stocks, such as in chlor-alkali and other industries.

    By the year 2000, the production of mined mercury had fallen to a third of its level in the early 1980s. Despite lowdemand, low prices and the alternative sources available, mercury is still mined in a number of countries such asSpain, China, Kyrgyzstan and Algeria. Moreover, unrecorded small-scale mercury mines have been reported in Asiaand Latin America. More...

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    Mercury : 5. Where do the world's supplies of mercury come from?

    5.2 How important is mercury recycling?

    Since the 1990s, about 700 to 900 tonnes of recycled mercury have been put on the world market every year. Most

    of this has come from recently closed mercury-based chlor-alkali factories. Their equipment employs a lot of

    mercury, though it is not consumed in the chemical process.

    Over the next decade and beyond, up to 13 000 tonnes of mercury will become available from the European Union

    alone. Similarly, large stocks of mercury held by various governments have become surplus and could be put on the

    market. For instance, the US government has a large mercury stock of 4 435 tonnes and has suspended sales since1994 pending an evaluation of the potential environmental and market impacts.

    The reuse and recycling of mercury replaces the mining processes, and prevents new mercury entering the marketand the environment. However, giving preference to recycled mercury creates complications, because an excesssupply may drive the market price down. This would encourage increased use, and thus disposal of mercury. For thireason, certain steps are being taken to manage supply, for example in Europe. More...

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    5.3 What is mercury used for?

    Mercury is a versatile material known for thousands of years. It is the only metal that is liquid at room temperatureIt is a good electrical conductor, has a very high density and high surface tension, expands and contracts uniformly

    when pressure and temperature change, and it can kill micro-organisms, including pathogenic organisms and other

    pests.

    Elemental mercury has been used:

    q to extract gold and silver from ore (for centuries);q to assist the manufacture ofchlor-alkali chemicals;

    q in manometers, which measure and control pressure;q in thermometers;q in electrical and electronic switches;q in fluorescent lamps; andq in dental amalgam fillings.

    Mercury compounds have been used:

    q in batteries;q as biocides, to control or destroy micro-organisms, e.g. in the paper industry, in paints and on seed grain;

    q as antiseptics in pharmaceuticals;

    q for chemical analysis;q as catalysts, to make the manufacture of other chemicals more efficient; and

    q in pigments and dyes, detergents, and explosives (mainly in the past).

    In industrialised countries, awareness of the potential adverse impacts of mercury on health and the environment hled to a reduction of both the volume and the range of uses of mercury and its compounds, particularly during the1980s and 1990s. Nonetheless, mercury is still used in many ways in some other parts of the world. More...

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