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Metalworking Fluids Biocide Selection Guide For Concentrate and  Tankside Applications Dow Microbial Control

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Page 1: Metalworking Fluids Biocide Selection Guide For ... Latin America Phone+55 11 5188 9555 Fax+55 11 5188 9400 Other Global Areas Phone+1 989 832 1560 Fax+1 989 832 1465 Help where you

Metalworking Fluids Biocide Selection GuideFor Concentrate and  Tankside Applications

Dow Microbial Control

Page 2: Metalworking Fluids Biocide Selection Guide For ... Latin America Phone+55 11 5188 9555 Fax+55 11 5188 9400 Other Global Areas Phone+1 989 832 1560 Fax+1 989 832 1465 Help where you

2

World-class expertise. Rely on the industry’s highly experienced team of experts in microbial control technologies. We offer expertise in application technology, regulatory issues and environmental research. Our products are carefully formulated based on advanced science and exhaustive performance testing.

Local presence, knowledge and support.Dow Microbial Control has Customer Application Centers around the world, offering exceptional microbial control products and services. Each center has a thorough knowledge of the exceptional challenges and opportunities of the region, offering you local personalized support.

Broad range of options.You have complex microbial control challenges. Our BIOBAN™ and KATHON™ products are designed to address those challenges. We understand your needs—and we have the products and expertise to address them.

Around the world, Dow Microbial Control has the expertise and the options to protect your products from microbial contamination. We offer expertise in application technology, regulatory issues and environmental research.

Metalworking Fluids Biocide Selection Guide

Let us help put you in control with:• Biocide recommendations• Customized options• Technical consultation• Problem solving• Analytical support• Safety and handling training• Webinars or onsite training

Brian Corbin, Ph.D. North American Customer Application

Specialist for Metalworking Fluids Dow Microbial Control

Page 3: Metalworking Fluids Biocide Selection Guide For ... Latin America Phone+55 11 5188 9555 Fax+55 11 5188 9400 Other Global Areas Phone+1 989 832 1560 Fax+1 989 832 1465 Help where you

3

Metalworking Fluids Biocide Selection Guide

Dow Microbial Control offers a broad portfolio of metalworking fluid biocides.

Bactericide

NHS

O

1,2-Benzisothiazolin-3-one (BIT)ROCIMA™ BT 2S

N

BrBrNH2

O

2,2-dibromo-3-nitrilopropionamide (DBNPA)

AQUCAR™ DB 20 Water Treatment Microbiocide; SUMP BUDDY™ MWF Antimicrobial Time Release Tablets

OHHONO2Br

2-bromo-2-nitropropane-1,3-diol(BRONOPOL)

BIOBAN™ BP-30 Preservative

H

O

H

O

1,5-Pentanedial (Glutaraldehyde) UCARCIDE™ 50 Antimicrobial; UCARCIDE™ 25 Antimicrobial

NS

CH3

O

2-methyl-4-isothiazolin-3-one (MIT)KORDEK™ LX5000 Industrial Microbicide

Broad Spectrum

NONO2

NO2

NO

NO

+

4-(2-nitrobutyl)-morpholine;4-4’-(2-ethyl-2-nitrotrimethylene)dimorpholine

BIOBAN™ P-1487 Antimicrobial Agent

Na+O-

Sodium o-phenylphenate (NaOPP)DOWICIDE™ A Antimicrobial;

DOWICIDE™ 25L Antimicrobial

NS

CH3

O

ClN

SCH3

O+

5-chloro-2-methyl-4-isothiazolin-3-one (CMIT)2-methyl-4-isothiazolin-3-one (MIT)

KATHON™ 886 MW Industrial Microbicide

OH

o-phenyl phenol (OPP)DOWICIDE™ 1E Antimicrobial

Fungicide

ONH

O

I

3-iodopropynylbutylcarbamate (IPBC)BIOBAN™ IPBC 40 Antimicrobial;

NS

O

2-n-octyl-4-isothiazolin-3-one BIOBAN™ O 45 Antimicrobial

Page 4: Metalworking Fluids Biocide Selection Guide For ... Latin America Phone+55 11 5188 9555 Fax+55 11 5188 9400 Other Global Areas Phone+1 989 832 1560 Fax+1 989 832 1465 Help where you

4

Metalworking Fluids Biocide Selection Guide

Product Chemical Name Phy

sica

l for

m

% A

ctiv

e

Bac

teri

cide

Fung

icid

e

Myc

obac

teri

cide

Non

-for

mal

dehy

de

rele

asin

g

Wat

er s

olub

le

pH/A

min

e st

abili

ty

pH b

uffe

ring

Use rate* (based on

ppm in final diluted

product)

Min Max

BIOBAN™ BP-30 2-Bromo-2-nitropropane-1,3-diol (Bronopol) L 30 + - - +/- + +/- - 333 3,333

AQUCAR™ DB 20 2,2-Dibromo-3-nitrilopropionamide (DBNPA) L 20 + +/- - + + - - 100 250

BIOBAN™ IPBC-40 3-Iodopropynylbutylcarbamate (IPBC) L 40 - + - + +/- + - NA 2,500

DOWICIDE™ 25L Sodium o-phenylphenate (NaOPP) L 25 + + + + + + + 1,000 2,500

DOWICIDE™ A Sodium o-phenylphenate (NaOPP) S 72 + + + + + + + 500 5,000

KATHON™ 886 MW 5-chloro-2-methyl-4-isothiazolin-3-one (CMIT) 2-Methyl-4-isothiazolin-3-one (MIT) L 14 + + + + + - - 26 125

BIOBAN ™ O 45 2-n-Octyl-4-isothiazolin-3-one (OIT) L 45 - + - + + +/- - 11 167

KORDEK™ LX 5000 2-Methyl-4-isothiazolin-3-one (MIT) L 50 + +/- + + + +/- - 150 300

ROCIMA™ BT 2S 1,2-Benzisothiazolin-3-one (BIT) L 19 + - - + + + - 500 1,800

SUMP BUDDY™ TABS** 2,2-Dibromo-3-nitrilopropionamide (DBNPA) S 40 + +/- - + + - - 1 tab

/50 gal 2 tabs

/50 gal

UCARCIDE™ 25 1,5-Pentanedial (Glutaraldehyde) L 25 + +/- - + + - - 160 1,200

UCARCIDE™ 50 1,5-Pentanedial (Glutaraldehyde) L 50 + +/- - + + - - 70 540

Products for Tankside Metalworking Fluid AdditionChoosing the right biocide.Formulating a metalworking fluid is as much an art as it is a science. This flow chart can serve as a good start to help you narrow down which biocides might best fit your needs. You should also consider what metals your fluid is going to be used with and if the biocide may cause staining with those metals. Additionally, you should always verify that the biocide is stable in a concentrate formula for the time period desired as biocides can react with a variety of other components in the fluid.

Please consult with your North American Customer Application Center at 1-800-447-4369 for advice. We are always happy to help.

What microorganisms are you trying to control?

Where are you going to use the biocide?

Fungus

BIOBAN™ IPBC-40DOWICIDE™ 25LDOWICIDE™ A

BIOBAN™ O 45KATHON™ 886 MW

BIOBAN™ IPBC-40DOWICIDE™ 25LDOWICIDE™ A

BIOBAN™ O 45DOWICIDE™ 1EBIOBAN™ P-1487

ConcentrateTankside

Where are you going to use the biocide?

Mycobacteria

DOWICIDE™ 25LDOWICIDE™ A

KATHON™ 886 MWKORDEK™ LX 5000

DOWICIDE™ 25LDOWICIDE™ A KORDEK™ LX 5000

DOWICIDE™ 1EBIOBAN™ P-1487

ConcentrateTankside

Where are you going to use the biocide?

Bacteria

AQUCAR™ DB 20DOWICIDE™ ADOWICIDE™ 25L

KATHON™ 886 MWKORDEK™ LX 5000ROCIMA™ BT 2S

SUMP BUDDY™ TABS**

UCARCIDE™ 25UCARCIDE™ 50

BIOBAN™ P-1487DOWICIDE™ 25LDOWICIDE™ A

DOWICIDE™ 1EKORDEK™ LX 5000ROCIMA™ BT 2S

ConcentrateTankside

Where are you going to use the biocide?

Broad Spectrum

Concentrate

DOWICIDE™ 25LDOWICIDE™ A

KATHON™ 886 MW

Tankside

DOWICIDE™ 25LDOWICIDE™ A

DOWICIDE™ 1EBIOBAN™ P-1487

Page 5: Metalworking Fluids Biocide Selection Guide For ... Latin America Phone+55 11 5188 9555 Fax+55 11 5188 9400 Other Global Areas Phone+1 989 832 1560 Fax+1 989 832 1465 Help where you

5

Metalworking Fluids Biocide Selection Guide

Product Chemical Name Phy

sica

l for

m

% A

ctiv

e

Bac

teri

cide

Fung

icid

e

Myc

obac

teri

cide

Non

-for

mal

dehy

de

rele

asin

g

Wat

er s

olub

le

pH/A

min

e st

abili

ty

pH b

uffe

ring

Use rate* (based on

ppm in final diluted

product)

Min Max

BIOBAN™ BP-30 2-Bromo-2-nitropropane-1,3-diol (Bronopol) L 30 + - - +/- + +/- - 333 3,333

AQUCAR™ DB 20 2,2-Dibromo-3-nitrilopropionamide (DBNPA) L 20 + +/- - + + - - 100 250

BIOBAN™ IPBC-40 3-Iodopropynylbutylcarbamate (IPBC) L 40 - + - + +/- + - NA 2,500

DOWICIDE™ 25L Sodium o-phenylphenate (NaOPP) L 25 + + + + + + + 1,000 2,500

DOWICIDE™ A Sodium o-phenylphenate (NaOPP) S 72 + + + + + + + 500 5,000

KATHON™ 886 MW 5-chloro-2-methyl-4-isothiazolin-3-one (CMIT) 2-Methyl-4-isothiazolin-3-one (MIT) L 14 + + + + + - - 26 125

BIOBAN ™ O 45 2-n-Octyl-4-isothiazolin-3-one (OIT) L 45 - + - + + +/- - 11 167

KORDEK™ LX 5000 2-Methyl-4-isothiazolin-3-one (MIT) L 50 + +/- + + + +/- - 150 300

ROCIMA™ BT 2S 1,2-Benzisothiazolin-3-one (BIT) L 19 + - - + + + - 500 1,800

SUMP BUDDY™ TABS** 2,2-Dibromo-3-nitrilopropionamide (DBNPA) S 40 + +/- - + + - - 1 tab

/50 gal 2 tabs

/50 gal

UCARCIDE™ 25 1,5-Pentanedial (Glutaraldehyde) L 25 + +/- - + + - - 160 1,200

UCARCIDE™ 50 1,5-Pentanedial (Glutaraldehyde) L 50 + +/- - + + - - 70 540

Products for Tankside Metalworking Fluid Addition

* Please refer to the EPA label for exact dosing instructions.** SUMP BUDDY™ MWF Antimicrobial Time Release Tablets are designed to slowly release the active ingredient, DBNPA, over the course of three weeks.

Page 6: Metalworking Fluids Biocide Selection Guide For ... Latin America Phone+55 11 5188 9555 Fax+55 11 5188 9400 Other Global Areas Phone+1 989 832 1560 Fax+1 989 832 1465 Help where you

6

Metalworking Fluids Biocide Selection Guide

Products for Metalworking Fluid Concentrate Addition

Product Chemical Name Phy

sica

l for

m

% A

ctiv

e

Bac

teri

cide

Fung

icid

e

Myc

obac

teri

cide

Non

-for

mal

dehy

de

rele

asin

g

Wat

er s

olub

le

pH/A

min

e st

abili

ty

pH b

uffe

ring

Stab

ilize

r Nee

ded Use rate*

(based on ppm in final diluted product)

Min Max

BIOBAN™ BP-30 2-Bromo-2-nitropropane-1,3-diol (Bronopol) L 30 + - - +/- + +/- - +/- 333 3,333

BIOBAN™ IPBC-40 3-Iodopropynylbutylcarbamate (IPBC) L 40 - + - + +/- + - - NA 2,500

BIOBAN™ P-14874-(2-Nitrobutyl)-morpholine;4,4’-(2-Ethyl-2-nitrotrimethylene)dimorpholine

L 86 + + + + +/- + - - NA 1,000

DOWICIDE™ 1E o-Phenyl phenol (OPP) S 100 + + + + +/- + + - 1,000 8,100

DOWICIDE™ 25L Sodium o-phenylphenate (NaOPP) L 25 + + + + + + + - 1,200 24,000

DOWICIDE™ A Sodium o-phenylphenate (NaOPP) S 72 + + + + + + + - 500 5,000

BIOBAN™ O 45 2-n-Octyl-4-isothiazolin-3-one (OIT) L 45 - + - + +/- +/- - +/- 55 167

KORDEK™ LX 5000 2-Methyl-4-isothiazolin-3-one (MIT) L 50 + +/- + + + +/- - +/- 150 300

ROCIMA™ BT 2S*** 1,2-Benzisothiazolin-3-one (BIT) L 19 + - - + + + - - 500 1,800***

* Please refer to the EPA label for exact dosing instructions. ** Not for use in non-aqueous concentrates.

*** Note: limit amount of ROCIMA™ BT 2S in metalworking fluid concentrate (to be diluted before use) to 3.0% (30,000 ppm) to reduce the possibility of dermal sensitization.

Page 7: Metalworking Fluids Biocide Selection Guide For ... Latin America Phone+55 11 5188 9555 Fax+55 11 5188 9400 Other Global Areas Phone+1 989 832 1560 Fax+1 989 832 1465 Help where you

7

Metalworking Fluids Biocide Selection Guide

Product Chemical Name Phy

sica

l for

m

% A

ctiv

e

Bac

teri

cide

Fung

icid

e

Myc

obac

teri

cide

Non

-for

mal

dehy

de

rele

asin

g

Wat

er s

olub

le

pH/A

min

e st

abili

ty

pH b

uffe

ring

Stab

ilize

r Nee

ded Use rate*

(based on ppm in final diluted product)

Min Max

BIOBAN™ BP-30 2-Bromo-2-nitropropane-1,3-diol (Bronopol) L 30 + - - +/- + +/- - +/- 333 3,333

BIOBAN™ IPBC-40 3-Iodopropynylbutylcarbamate (IPBC) L 40 - + - + +/- + - - NA 2,500

BIOBAN™ P-14874-(2-Nitrobutyl)-morpholine;4,4’-(2-Ethyl-2-nitrotrimethylene)dimorpholine

L 86 + + + + +/- + - - NA 1,000

DOWICIDE™ 1E o-Phenyl phenol (OPP) S 100 + + + + +/- + + - 1,000 8,100

DOWICIDE™ 25L Sodium o-phenylphenate (NaOPP) L 25 + + + + + + + - 1,200 24,000

DOWICIDE™ A Sodium o-phenylphenate (NaOPP) S 72 + + + + + + + - 500 5,000

BIOBAN™ O 45 2-n-Octyl-4-isothiazolin-3-one (OIT) L 45 - + - + +/- +/- - +/- 55 167

KORDEK™ LX 5000 2-Methyl-4-isothiazolin-3-one (MIT) L 50 + +/- + + + +/- - +/- 150 300

ROCIMA™ BT 2S*** 1,2-Benzisothiazolin-3-one (BIT) L 19 + - - + + + - - 500 1,800***

Sustainability without compromise.Take control of your microbial challenges in an effective and sustainable manner. Dow Microbial Control offers the one of the industry’s largest portfolio of biocides for metalworking fluids, including a variety of sustainable product choices. Rely on us for:• Concentrate and tankside dosing

options, including products for Mycobacteria control and low-VOC formulations

• A wide range of non formaldehyde releasing product options

• Options to address evolving regulatory requirements

• Programs for new-product innovation, safety training, regulatory and technical support

Page 8: Metalworking Fluids Biocide Selection Guide For ... Latin America Phone+55 11 5188 9555 Fax+55 11 5188 9400 Other Global Areas Phone+1 989 832 1560 Fax+1 989 832 1465 Help where you

NOTICE: No freedom from infringement of any patent owned by Dow or others is to be inferred. Because use conditions and applicable laws may differ from one location to another and may change with time, Customer is responsible for determining whether products and the information in this document are appropriate for Customer’s use and for ensuring that Customer’s workplace and disposal practices are in compliance with applicable laws and other governmental enactments. The product shown in this literature may not have been approved for use in all countries. Dow assumes no obligation or liability for the information in this document. References to “Dow” or “Company” mean the Dow legal entity selling the products to Customer unless otherwise expressly noted. NO WARRANTIES ARE GIVEN; ALL IMPLIED WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE ARE EXPRESSLY EXCLUDED. Please note that not all products are registered in all regions for all applications. Please contact your local Dow representative for detailed technical information applicable to your individual situation. USE BIOCIDES SAFELY. ALWAYS READ THE LABEL AND PRODUCT INFORMATION BEFORE USE.

®TM Trademark of The Dow Chemical Company (“Dow”) or an affiliated company of Dow. Form number: 253-03132-0316 CDP

Central and Eastern EuropeTurkey +90-216-571-16-00 Russia +7-495-663-78-20 Poland +48-22-543-18-00

Western Europe Toll-free +800-3-694-6367 Phone +31-115-67-26-26 Fax +31-115-67-28-28

North AmericaToll-free +1-800-447-4369 Phone +1-989-832-1560 Fax +1-989-832-1465

Middle East and AfricaUAE +971-4-332-88-66 South Africa (toll-free) +800-99-5078 www.dowmicrobialcontrol.com

Greater ChinaShanghai +86-21-3851-1000 Beijing +86-10-8527-9199 Guangzhou +86-20-3813-0600 Taiwan +886-227-718-000

Southeast AsiaPhilippines +63-2-867-3293 Indonesia +62-21-2995-6273 Singapore +65-6830-4575 +65-6796-6217 Thailand +66-2365-7371 Vietnam +84-8-3822-5808 Malaysia +603-7965-5200

Australia and New ZealandPhone +61-3-9226-3500 Fax +61-3-9226-3562

Japan and KoreaJapan +81-3-5460-2261 Korea +82-2-3490-4348

Indian SubcontinentPhone +91-22-6793-4953 Fax +91-22-6793-4924

Latin AmericaPhone +55-11-5188-9555 Fax +55-11-5188-9400

Other Global AreasPhone +1-989-832-1560 Fax +1-989-832-1465

Help where you need it.With Customer Application Centers around the globe, expert assistance to help solve microbial challenges is always within reach. We offer fully equipped, state-of-the-art laboratory capabilities and knowledgeable technical and sales assistance to help find options for your metalworking fluid challenges.

North America

Western Europe

Middle East and Africa

Japan and Korea

Australia and New Zealand

Southeast Asia

Central Eastern Europe

Indian Subcontinent

Latin America

Greater China