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2/5/2014 1 Methamphetamine - PowerPoint - Chemicals and Ingredients Used to Make Meth CJUS 240 1 2 3 Equipment Used in Meth Production Pyrex or Corning dishes Equipment Used in Meth Production Pyrex or Corning dishes Plastic or rubber tubing Equipment Used in Meth Production Pyrex or Corning dishes Plastic or rubber tubing Rubber gloves Equipment Used in Meth Production Pyrex or Corning dishes Plastic or rubber tubing Rubber gloves Glass containers (all types) Equipment Used in Meth Production Pyrex or Corning dishes Plastic or rubber tubing Rubber gloves Glass containers (all types) • Funnels Equipment Used in Meth Production Pyrex or Corning dishes Plastic or rubber tubing Rubber gloves Glass containers (all types) • Funnels Propane tanks Equipment Used in Meth Production Pyrex or Corning dishes Plastic or rubber tubing Rubber gloves Glass containers (all types) • Funnels 8 9 10 11 12 13 14 15

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Page 1: Methamphetamine - PowerPoint - Chemicals and Ingredients ... · 2/5/2014 1 Methamphetamine - PowerPoint - Chemicals and Ingredients Used to Make Meth CJUS 240 Economic Costs of Meth

2/5/2014

1

Methamphetamine- PowerPoint

- Chemicals and Ingredients Used to Make Meth

CJUS 240

Economic Costs of Meth

• The economic cost of methamphetamine use in the U.S. reached $23.4 billion in

2005.

– This includes the burden of addiction, premature death, drug treatment, child

care, and cleaning of lab sites.

– This figure does NOT take into account the future needs of the meth user.

Concerns with ACTIVE Meth Labs

• Danger of fire and explosion

• Chemical spills

• Inhalation of solvents, corrosives, and toxic gases

• “Booby traps”

• Waste disposal

Concerns with FORMER Meth Labs

• Vapors

• Chemical residues

• Methamphetamine residues

• Waste disposal

Equipment Used in Meth Production

• Pyrex or Corning dishes

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

• Coffee Filters

Equipment Used in Meth Production

Equipment Used in Meth Production

Basic Chemical Requirements

• In a clandestine laboratory, basic types of chemicals are necessary in order to

produce the desired drug.

– The basic types of chemicals needed are:

1) Precursor Chemicals

2) Reagent Chemicals

3) Catalyst Chemicals

4) Solvent Chemicals

List I Chemical

• The term “List I chemical” means a chemical specified by regulation of the Attorney General as a chemical that is used in manufacturing a controlled substance and is

IMPORTANT to the manufacture of the controlled substance.

• Examples of List I chemicals are:

– GBL

– Red Phosphorus

– Pseudoephedrine

List II Chemical

• The term “List II chemical” means a chemical (other than a List I chemical) specified by regulation of the Attorney General as a chemical that is USED in

manufacturing a controlled substance.

• Examples of List II chemicals are:

– Toluene

– Iodine

– Hydrochloric Acid

Precursor Chemicals

• Precursor Chemicals:

– A chemical that is ESSENTIAL to the production of a controlled substance and for

which NO SUBSTITUTION can be made.

Pseudoephedrine

• Pseudoephedrine is a decongestant found in cold medicine.

– Large amounts of pseudoephedrine on its own can harm the respiratory and nervous systems, as well as the heart.

Pseudoephedrine (Continued)

• Some of the common ways used to divert products containing pseudoephedrine

include:

– “Smurfing” – making multiple purchases at different locations

– Shelf-Sweeping – the theft of all shelf stock

– Shoplifting

– Theft from wholesalers

Pseudoephedrine (Continued)

• Pseudoephedrine smurfing is a method used by some methamphetamine producers to acquire large quantities of pseudoephedrine by enlisting the assistance of several

friends or associates (often referred to as “smurfers”) to make purchases at or below the legal thresholds from multiple retail locations.

– Smurfers are often addicts who trade the pseudoephedrine for finished methamphetamine.

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

• About 680 pseudoephedrine tablets are needed to produce one ounce of meth…

Pseudoephedrine (Continued)

Out With a Bang

An Unstable Recipe…

• Meth contains a variety of poisonous ingredients…

– Some become EVEN MORE DANGEROUS once the cooking process begins…

Common Ingredients to Make Methamphetamine

Reagent Chemicals

• Reagent Chemicals:

– Chemicals which REACT upon the precursor chemical causing it to chemicallyCHANGE.

• A reagent chemical is a chemical which is required for the synthesis of an illicit drug substance, but which is NOT incorporated into the final chemical product.

Hydrochloric Acid

• Hydrochloric acid is a highly corrosive liquid that is used to make plastic (such as PVC pipe and polyurethane).

– It can remove rust and iron-oxide from steel and is highly corrosive to human

skin.

•Hydrochloric acid makes up the majority of the gastric acid in the human

digestive fluid.

• In high concentrations, hydrochloric acid will literally eat away human flesh…

Hydrochloric Acid (Continued)

• Hydrochloric acid can be purchased from hardware stores as:

– Tile and Grout Acid Cleaner

– Muriatic Acid

– Pool Acid

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

• Hydrochloric acid is a solution of hydrogen chloride gas suspended in water.

– Hydrochloric acid is corrosive and is a light yellow liquid color from traces of iron, chlorine, and organic matter.

• Inhaling hydrochloric acid may cause coughing or choking, inflammation, and ulceration of the respiratory tract.

• Concentrated solutions of hydrochloric acid can cause severe burns and irritate the

mucous membranes, eyes, and respiratory tract.

– Exposure to hydrochloric acid vapors may result in pulmonary edema and

possibly death.

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

Sodium Hydroxide (NaOH)

• Sodium hydroxide is also called Lye.

• Sodium hydroxide is classified as a corrosive, and it is one of the main chemicals in

drain cleaner.

– It is also used in aluminum etching and to create biodiesal.

– It can burn the skin or cause blindness.

• Sodium hydroxide is used to dispose of road kill because it turns the dead bodies

into a coffee-like liquid.

Sodium Hydroxide (NaOH) (Continued)

• Drain cleaner (sodium hydroxide) is extremely corrosive, and without wearing

protection, even the smallest spill on the skin can eat through flesh…

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sulfuric Acid (H2SO4)

• Sulfuric acid is used in drain or toilet bowl cleaner as well as battery acid.

– It is another highly corrosive substance that burns the skin on contact.

Sulfuric Acid (H2SO4) (Continued)

• The product label warning for Drano® (sulfuric acid) says it all:

– DANGER: MAY BURN EYES AND SKIN ON CONTACT.

•HARMFUL IF SWALLOWED.

–Avoid contact with body and clothing.

•TOXIC GAS MAY FORM IF MIXED WITH OTHER CHEMICALS.

–If gases are released, leave immediately and ventilate area.

•FIRST AID: Give Immediately:

–EYES AND SKIN:

»Flush with water for 20 minutes.

»Remove affected clothing.

–IF SWALLOWED:

»Rinse mouth and drink a glass of water or milk.

»Do not induce vomiting.

–THEN SEEK MEDICAL AID.

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Hypophosphorous Acid (H3PO2)

• Hypophosphorous acid, which is used legally for a variety of commercial purposes,

is a chemical that increasingly is substituted for red phosphorus in the methamphetamine production process.

– The use of hypophospherous acid SIGNIFICANTLY increases the risk of fire!!!

• The federal government regulates the sale of hypophosphorous acid through registration, record keeping, reporting, and import/export requirements regardless

of the quantity being handled or distributed.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid is a colorless oily liquid that emits a SOUR odor.

– There is an extreme fire and explosion hazard if the hypophosphorous acid

comes into contact with a solvent such as acetone, toluene, or Coleman fuel.

• Hypophosphorous acid will also emit phosphine gas and the fumes can ignite.

Hypophosphorous Acid (H3PO2) (Continued)

• Although hypophosphorous acid is a List I chemical under the Controlled Substances Act, methamphetamine producers typically purchase the chemical via

the internet or from associates who also are engaged in methamphetamine

production.

– The use of hypophosphorous acid in methamphetamine production is an

EXTREMELY DANGEROUS PRACTICE because of the deadly gases that can be generated as well as the risk of fire or explosion.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid (H3PO2, also called phosphinic acid) is a strong acid that

typically is prepared as a solution of colorless, oily liquid in strengths of 50%, 30 to 32%, and 10%.

– It also is prepared in the form of salts (referred to as hypophosphite salts), particularly ammonium hypophosphite, calcium hypophosphite, iron (ferric)

hypophosphite, magnesium hypophosphite, manganese hypophosphite,

potassium hypophosphite, and sodium hypophosphite.

Hypophosphorous Acid (H3PO2) (Continued)

• Over 100 chemical firms located throughout the world produce hypophosphorous acid.

– The People's Republic of China and India have the largest numbers of

hypophosphorous acid producers, although there are a few producers in the United States.

• There are a wide variety of uses for hypophosphorous acid and its salts in

commercial industry; however, the chemicals have no legitimate household or retail uses.

Hypophosphorous Acid (H3PO2) (Continued)

• The legitimate commercial and laboratory fields that use hypophosphorous acid and its salts include the following:

– Chemical plating

– Food preparation

– Water treatment

– Polymers (as a bleaching agent, color stabilizer, or catalyst)

– Education and research in analytical chemistry

Hypophosphorous Acid (H3PO2) (Continued)

• Chemical suppliers typically distribute hypophosphorous acid in large quantities, for example, in drums containing 275 pounds of the diluted solution.

– Hypophosphorous acid also is distributed in smaller quantities.

• One-half liter of 50% concentrate hypophosphorous acid solution can be obtained from chemical suppliers for as little as $14.

Hypophosphorous Acid (H3PO2) (Continued)

• Methamphetamine laboratory operators typically obtain small quantities of the chemical from other laboratory operators who purchase large quantities of the

chemical and repackage it for further distribution.

– According to law enforcement sources, these individuals sell hypophosphorous acid for as much as $1,000 per half-liter.

•Methamphetamine laboratory operators also purchase hypophosphorous acidvia the internet.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid and the Internet

• The internet is a source of a great deal of information regarding hypophosphorous acid.

• Popular internet sites that disseminate information about illicit drugs contain information about the chemical, including numerous recipes for home production of

methamphetamine using hypophosphorous acid.

• There also are recipes for synthesizing hypophosphorous acid from available chemicals.

• Hypophosphorous acid solutions and salts have been sold to the general public via the internet.

• The Drug Enforcement Administration (DEA) has strong concerns regarding the sale

of chemicals on the internet and has requested that any sites (such as auction sites) that allow the sale of regulated chemicals on their domains require proof of

DEA registration from their clients.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid Used in Methamphetamine Production

• Hypophosphorous acid is used in the ephedrine-pseudoephedrine reduction method

of methamphetamine production.

– It is used in the methamphetamine production process to produce hydriodic acid,

an important reagent (it reacts with the ephedrine-pseudoephedrine but does NOT become part of the finished product).

Hypophosphorous Acid (H3PO2) (Continued)

• The regulation of hydriodic acid by DEA in 1993 rendered it virtually unavailable in

the United States.

– However, methamphetamine laboratory operators discovered methods to

produce hydriodic acid using a combination of iodine in water with red phosphorus.

• Laboratory operators found that red phosphorus could be obtained easily, either

from commercial supply companies or by scraping the striker pads from matchbooks or matchboxes.

• Methamphetamine producers soon discovered that hypophosphorous acid ALSO could be used in combination with iodine and water to produce hydriodic acid.

Hypophosphorous Acid (H3PO2) (Continued)

• The practice of using hypophosphorous acid in methamphetamine production is

believed to have begun in the United States in the late 1990s when a methamphetamine producer in Colorado obtained the recipe from Australia, where

the hypophosphorous acid method is prevalent.

– This man was known as a serial cook who had a long history of

methamphetamine production.

•Over several years he trained other laboratory operators in Colorado to produce methamphetamine using hypophosphorous acid.

• As his techniques were passed on to others, the number of methamphetaminelaboratories in Colorado using hypophosphorous acid continued to increase, and the

technique was passed on to numerous methamphetamine producers in other

states.

Hypophosphorous Acid (H3PO2) (Continued)

• According to the El Paso Intelligence Center (EPIC) National Clandestine Laboratory

Seizure System, from 2000 through 2002 the number of seized methamphetaminelaboratories in the United States in which hypophosphorous acid was found

increased overall. (See Table 1.)

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid found at methamphetamine laboratories is packaged in a variety of ways.

• The chemical has been found in 1-gallon bottles of solution or in 1-pound jars of salts.

• Some hypophosphorous acid containers are labeled as "plating solution."

• Pint-sized brown glass bottles wrapped in red electrical tape also have been found to contain hypophosphorous acid; they have been discovered primarily in Colorado.

• The vast majority of hypophosphorous acid found at laboratory sites has been recovered from small toxic laboratories (STLs), those which yield gram to ounce

quantities per production cycle.

• Hypophosphorous acid has not been reported at large-scale laboratories operated by Mexican criminal groups in the United States.

Hypophosphorous Acid (H3PO2) (Continued)

• Hazards

• The iodine-hypophosphorous acid method is MORE HAZORDOUS than the iodine-red phosphorus method, although the reaction using hypophosphorous acid is

faster and gives slightly higher yields.

– When hypophosphorous acid is used, the chemicals must be mixed together

SLOWLY in a PARTICULAR ORDER to prevent them from reacting violently.

Hypophosphorous Acid (H3PO2) (Continued)

• The combination of hypophosphorous acid with the other chemicals and with

certain metals can produce deadly phosphine gas during the initial mixing step and

can CONTINUE to produce phosphine gas for several days AFTER production has been completed…

Hypophosphorous Acid (H3PO2) (Continued)

• The iodine-hypophosphorous acid mixture has a tendency to decompose quickly when overheated or if heated for long periods of time, becoming cloudy or "milky-

white" just prior to giving off a cloud of phosphine gas that can ignite spontaneously.

– Hypophosphorous acid solutions may become unstable if evaporation results in

concentrations above 50%.

Hypophosphorous Acid (H3PO2) (Continued)

• [Note: Law enforcement or emergency personnel who encounter suspected

containers of hypophosphorous acid should use extreme care during handling because laboratory operators often attempt to obtain a more concentrated acid by

allowing water to evaporate from the mixture.]

• Because hypophosphorous acid often is used at small methamphetaminelaboratories operated by inexperienced or careless individuals, the potential hazards

of using this method are even greater.

• The risk of fire and explosion is higher in these laboratories, where professional

laboratory equipment typically is not used to contain the phosphine gas and where

safe handling precautions are not employed.

• In addition, these laboratories often are located in homes where children are

present and may come into contact with hypophosphorous acid.

• A child can easily mistake hypophosphorous acid for any other clear liquid,

particularly if it is stored in household containers or drinking glasses.

• Skin, eye, or inhalation exposure can be extremely harmful or fatal.

Hypophosphorous Acid (H3PO2) (Continued)

• Safety Precautions

• Always wear a self-contained breathing apparatus as well as protective clothing when entering areas where hypophosphorous acid may be present.

• When in contact with metals or in a high-temperature environment,

hypophosphorous acid can break down and liberate phosphine and flammable hydrogen gas.

• Do not allow the use of open flames, open lights, matches, or smoking in or around laboratories or dumpsites where hypophosphorous acid is handled.

• In case of fire, use a self-contained positive pressure breathing apparatus and full

protective equipment.

• Use water spray, fog, foam, dry chemicals, or other reagents as may be

appropriate for materials in the surrounding fire.

• Water may be used to cool the containers of hypophosphorous acid; however, use extreme care to avoid allowing water to enter the container.

• In case of spills, neutralize the spilled chemical with alkaline material (soda ash, lime), then absorb it with an inert material such as vermiculite, dry sand, or earth

and place in a chemical waste container.

• Do not use combustible materials such as sawdust.

Hypophosphorous Acid (H3PO2) (Continued)

• Legislation and Control

• In the United States hypophosphorous acid is one of 38 chemicals (or groups of

chemicals) controlled under law by DEA.

• On October 17, 2001, hypophosphorous acid and its salts, along with red and white phosphorus, were officially added as List I chemicals under section 1310 of the

Code of Federal Regulations.

• List I chemicals are defined as chemicals that are used in the manufacture of a

controlled substance in violation of the Controlled Substances Act (CSA) and are

important to the manufacture of a controlled substance.

• Under the law, suppliers are required to maintain records and report receipts, sales,

imports, and exports of these chemicals to DEA.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid, red phosphorus, and white phosphorus, as well as

ephedrine, are unique in that suppliers are required to report all transactions of

these chemicals, regardless of the amount.

• By contrast, the other 34 listed chemicals are only reportable after a supplier's

transactions for a chemical reach an established weight or volume threshold in a calendar month.

• In addition to reporting all transactions involving the chemical, suppliers are

expected to "know their customers" in order to prevent the diversion of these substances to methamphetamine laboratories, as it is illegal to import, export,

purchase, or sell hypophosphorous acid or any other listed chemical in the United States if it is used or intended to be used in the production of a controlled

substance.

• Chemical suppliers are held liable for selling listed chemicals if they know or suspect that the chemical will be used for illicit purposes.

Hypophosphorous Acid (H3PO2) (Continued)

• Outlook

• The use of hypophosphorous acid in the production of methamphetamine is likely

to increase, particularly in the Midwest and Southwest regions of the United States

where methamphetamine production is prevalent.

– Injuries, property damage, and deaths also will increase as a growing number of

inexperienced methamphetamine producers experiment with hypophosphorous acid.

Anhydrous Ammonia

• Anhydrous ammonia is found in fertilizer, countertop cleaner, and commercial refrigerant.

– On its own, it has a pungent, suffocating odor.

• Mixing anhydrous ammonia with other chemicals can release highly toxic gases.

– Because anhydrous ammonia seeks out water (anhydrous means “without

water”) and causes severe burns, any body part that comes into contact with it

should be flushed with water for at least 15 minutes to remove the ammoniafrom the skin.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia has extremely destructive effects on humans.

– Anhydrous ammonia gives off vapors during cooking that can burn the mouth,

throat, and lung tissue.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Anhydrous ammonia seeks water from the nearest source, including the human body (anhydrous means “without water”).

– Because of their high moisture content, EYES, LUNGS, and SKIN are at the

greatest risk of attracting the ammonia.

• When large amounts of anhydrous ammonia are inhaled, the throat swells and the

victim suffocates.

– Exposure to the vapors or liquids can cause severe burns, blindness, or death.

• Anhydrous ammonia has an IDLH (immediately dangerous to life and health) at

only 300 parts per million...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is poses MANY hazards, especially when it is placed in improper vessels and handled/transported by individuals unfamiliar with the

dangers.

• Anhydrous ammonia has a boiling point of -28 degrees below zero.

– When a vessel containing anhydrous ammonia is MOVED, the anhydrous

ammonia will reach its boiling point and pressurize.

•This pressurization can cause vessels to violently RUPTURE, or if the vessel pressurizes and does NOT rupture, the opening of the container of anhydrous ammonia at a later time can cause RAPID, VIOLENT depressurization.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is mainly used in the U.S. as either a fertilizer or a refrigerant.

– Meth producers tend to store the anhydrous ammonia in IMPROPER/UNAPPROVED containers such as:

•Propane tanks,

• Igloo coolers, or

•Fire extinguishers.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia leaves a tell-tell sign as it flows through these UNAPPROVED CONTAINERS – a blue or blue green discoloration on the valve.

– PAY ATTENTION to details!!!

Anhydrous Ammonia (Continued)

• Because propane cylinders (and the other unapproved containers) are NOT designed to store anhydrous ammonia, they can EXPLODE as the ammonia eats

through the walls of the cylinders.

– The valves, which take on a bluish/green color, frequently deteriorate and can cause hazardous leaks!!!

Anhydrous Ammonia (Continued)

• Do NOT touch, move, or open any kind of tank or sealed container!!!

– Be aware that propane tanks are often WEAKENED and BRITTLE due to the

anhydrous ammonia and are SENSITIVE to ANY kind of movement or impact.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• These pictures show what happened to a fire extinguisher that was used to store

anhydrous ammonia…

Anhydrous Ammonia (Continued)

• Illegal drug makers often STEAL anhydrous ammonia from areas where it is stored

and used, such as farms.

• Attempted thefts have also occurred at places such as:

– Refrigeration systems holding ammonia,

– Underground pipelines carrying ammonia, and

– Rail cars transporting anhydrous ammonia.

• Often thefts are aborted when thieves are injured or overcome by the toxic gas...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia thieves had better beware!!!

• There is a new product called GloTell that farmers can add to their anhydrous

ammonia tanks…

• Meth cooks will run the risk that the GloTell additive will turn their hands bright

pink!

– This bright pink stain will fluoresce under ultraviolet light even if washed off!!!

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Also, GloTell will produce pink methamphetamine that CANNOT be bleached.

– Users who snort meth made with GloTell will find that they have PINK NOSES!

– Users who inject meth made with GloTell will see a pink stain at the point of

injection!

Sodium Carbonate (Soda Ash)

Sodium Carbonate (Soda Ash) (Continued)

Lead Acetate

Iodine

• Iodine is a natural element, and it is helpful to the body in SMALL amounts.

– However, if iodine is taken in large amounts it can become toxic.

•Extremely high does of iodine can limit the function of the thyroid.

Iodine (Continued)

Iodine (Continued)

• Iodine is bluish-black, and it has a characteristic odor, a sharp acrid taste, and it produces a violet corrosive vapor.

– The vapor is irritating to the respiratory system and eyes.

• The solid iodine irritates the eyes and may burn the skin, and it may cause severe

internal irritation and damage if ingested.

Iodine (Continued)

• Iodine is known as the “blue ingredient” in the production of meth (in the “red, white, and blue” method).

Iodine (Continued)

Iodine (Continued)

• It takes approximately 4 bottles of iodine tincture to produce 2 – 3 grams of meth.

Iodine (Continued)

Iodine (Continued)

• Iodine leaves distinctive yellow-blue or brown stains on surfaces in former methlabs.

Iodine (Continued)

Iodine (Continued)

Iodine (Continued)

• The only good thing about iodine is that it leaves yellow stains.

• If you see yellow stained coffee filters, gloves or paper towels, this could be an

indicator that you’re in a lab.

• If you see yellow stains, you can spray some starch on them.

– If they turn a purplish blue/black, it’s iodine.

• Iodine is the only substance that reacts with soluble starch to produce a purplish black color.

– The only way to get iodine vapor all over the walls is to cook meth.

Mercurous Chloride

Rock Salt

Hydrogen Chloride

• Hydrogen chloride gas is commercially available.

• Hydrogen chloride gas can also be made by mixing sulfuric acid and salt.

• Muriatic acid is simply hydrogen chloride gas suspended in water.

• Hydrogen chloride gas can be seen as a pale white smoke.

– It is a poisonous gas that can cause respiratory problems and death.

Hydrogen Chloride (Continued)

Ammonium Nitrate

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Hydriodic Acid

• Hydriodic acid is a corrosive acid that is colorless when freshly prepared.

– When hydriodic acid is exposed to light and air, it turns yellowish and brown.

• Hydriodic acid is a solution of hydrogen iodide gas in water.

• Hydriodic acid vapor is irritating to the respiratory system, skin, and eyes.

• Hydriodic acid liquid causes severe burns to the eyes and skin.

• If hydriodic acid is accidentally ingested, it can cause severe internal irritation and

damage.

Hydriodic Acid (Continued)

Catalyst Chemicals

• Catalyst Chemicals:

– Chemicals which SPEED UP a reaction process and/or cause it to go to GREATER COMPLETION.

Red Phosphorus

• Red phosphorus is found ON matchboxes, in road flares, and other explosives.

– Red Phosphorus IGNITES when OVERHEATED!!!

• By combining red phosphorus and iodine, you can easily create the highly

controlled substance known as hydriodic acid (which is an essential ingredient in making meth).

– Creating 2 – 3 grams of meth requires about 4 big boxes of matches.

Red Phosphorus (Continued)

• Red phosphorous is highly flammable and if it is overheated it can become white

phosphorous…

– White phosphorous is a volatile and highly explosive substance.

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Lithium

• Lithium is used in batteries.

• Lithium seriously burns the skin upon contact.

– It also reacts VIOLENTLY with WATER and is highly explosive.

Lithium (Continued)

• Lithium reacts VIOLENTLY with WATER, and if it is splashed in the eyes during

cooking it will cause blindness.

– Lithium is extremely caustic to all body tissues.

Lithium (Continued)

Lithium (Continued)

• Lithium metal is HIGHLY water reactive and it will BURN or EXPLODE if it comes into contact with WATER!

• Because of the moisture in your skin, it will burn exposed flesh.

• Lithium metal will DEGRADE when exposed to atmospheric moisture…

– This is why meth cooks store lithium metal in a solvent prior to use.

• It is typical to see harvested lithium strips in Coleman fuel or Mineral Spirits to prevent explosions.

•Large quantities can be harvested and saved in these containers until needed

for a cook.

Lithium (Continued)

• If you see battery shells in the trashcan, on the floor, etc. – this is a VERY GOOD

indicator that you might be entering a meth lab!

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

• Lithium catches fire when in contact with water...

Solvent Chemicals

• Solvent Chemicals:

– A medium (liquid) in which a chemical operation takes place.

• Solvent chemicals (UNLIKE the precursor chemicals) CAN be

substituted/interchanged.

Ether

• Ether was once called “sweet vitriol” because of its hypnotic effect.

• Ether is a highly flammable substance that is used as an anesthetic agent –especially in third world countries where more expensive anesthesia is not available.

– While inhaling the ether, patients could undergo complete surgical procedures while otherwise awake without feeling pain or concern.

Ether (Continued)

• Ether can be obtained from engine starting fluid.

• Ether is a solvent and it is flammable.

– It is particularly hazardous because it can cause BOTH fire and explosion.

• It has been said that a quart of ether can “level” a small house.

Ethyl Ether (Continued)

Ethyl Ether (Continued)

• Ether is VERY flammable and is HEAVIER than air.

– NEVER use ether near flames or non-sparkless motors.

– Ether is very PUNGENT – even a small evaporated amount of ether is VERY noticeable.

Acetone

• Acetone can be found in nail polish remover or paint thinner.

– It is extremely flammable.

• In the setting of a meth lab where meth is being cooked with high heat, acetone is

very dangerous.

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Toluene

• Toluene is used in brake fluid.

– When working with brake fluid (toluene), be careful not to spill it on your car

because it will eat away the paint and chrome…

• You also have to be careful using toluene around other household chemicals

because its high concentration of polyethylene glycol can cause it to ignite in a

violent fireball.

• Toluene is powerful enough to dissolve rubber.

Toluene (Continued)

• Toluene is used to form meth crystals.

– The fumes toluene releases can cause brain damage or death.

Toluene (Continued)

Toluene (Continued)

Ethanol

Isopropanol

Isopropanol (Continued)

Isopropyl Alcohol

Methanol

Methanol (Continued)

Methanol (Continued)

Benzene

Benzene (Continued)

Which of these is NOT a common ingredient in Meth?

Nail Polish Remover

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Methamphetamine- PowerPoint

- Chemicals and Ingredients Used to Make Meth

CJUS 240

Economic Costs of Meth

• The economic cost of methamphetamine use in the U.S. reached $23.4 billion in

2005.

– This includes the burden of addiction, premature death, drug treatment, child

care, and cleaning of lab sites.

– This figure does NOT take into account the future needs of the meth user.

Concerns with ACTIVE Meth Labs

• Danger of fire and explosion

• Chemical spills

• Inhalation of solvents, corrosives, and toxic gases

• “Booby traps”

• Waste disposal

Concerns with FORMER Meth Labs

• Vapors

• Chemical residues

• Methamphetamine residues

• Waste disposal

Equipment Used in Meth Production

• Pyrex or Corning dishes

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

• Coffee Filters

Equipment Used in Meth Production

Equipment Used in Meth Production

Basic Chemical Requirements

• In a clandestine laboratory, basic types of chemicals are necessary in order to

produce the desired drug.

– The basic types of chemicals needed are:

1) Precursor Chemicals

2) Reagent Chemicals

3) Catalyst Chemicals

4) Solvent Chemicals

List I Chemical

• The term “List I chemical” means a chemical specified by regulation of the Attorney General as a chemical that is used in manufacturing a controlled substance and is

IMPORTANT to the manufacture of the controlled substance.

• Examples of List I chemicals are:

– GBL

– Red Phosphorus

– Pseudoephedrine

List II Chemical

• The term “List II chemical” means a chemical (other than a List I chemical) specified by regulation of the Attorney General as a chemical that is USED in

manufacturing a controlled substance.

• Examples of List II chemicals are:

– Toluene

– Iodine

– Hydrochloric Acid

Precursor Chemicals

• Precursor Chemicals:

– A chemical that is ESSENTIAL to the production of a controlled substance and for

which NO SUBSTITUTION can be made.

Pseudoephedrine

• Pseudoephedrine is a decongestant found in cold medicine.

– Large amounts of pseudoephedrine on its own can harm the respiratory and nervous systems, as well as the heart.

Pseudoephedrine (Continued)

• Some of the common ways used to divert products containing pseudoephedrine

include:

– “Smurfing” – making multiple purchases at different locations

– Shelf-Sweeping – the theft of all shelf stock

– Shoplifting

– Theft from wholesalers

Pseudoephedrine (Continued)

• Pseudoephedrine smurfing is a method used by some methamphetamine producers to acquire large quantities of pseudoephedrine by enlisting the assistance of several

friends or associates (often referred to as “smurfers”) to make purchases at or below the legal thresholds from multiple retail locations.

– Smurfers are often addicts who trade the pseudoephedrine for finished

methamphetamine.

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

• About 680 pseudoephedrine tablets are needed to produce one ounce of meth…

Pseudoephedrine (Continued)

Out With a Bang

An Unstable Recipe…

• Meth contains a variety of poisonous ingredients…

– Some become EVEN MORE DANGEROUS once the cooking process begins…

Common Ingredients to Make Methamphetamine

Reagent Chemicals

• Reagent Chemicals:

– Chemicals which REACT upon the precursor chemical causing it to chemicallyCHANGE.

• A reagent chemical is a chemical which is required for the synthesis of an illicit drug substance, but which is NOT incorporated into the final chemical product.

Hydrochloric Acid

• Hydrochloric acid is a highly corrosive liquid that is used to make plastic (such as PVC pipe and polyurethane).

– It can remove rust and iron-oxide from steel and is highly corrosive to human

skin.

•Hydrochloric acid makes up the majority of the gastric acid in the human

digestive fluid.

• In high concentrations, hydrochloric acid will literally eat away human flesh…

Hydrochloric Acid (Continued)

• Hydrochloric acid can be purchased from hardware stores as:

– Tile and Grout Acid Cleaner

– Muriatic Acid

– Pool Acid

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

• Hydrochloric acid is a solution of hydrogen chloride gas suspended in water.

– Hydrochloric acid is corrosive and is a light yellow liquid color from traces of iron, chlorine, and organic matter.

• Inhaling hydrochloric acid may cause coughing or choking, inflammation, and

ulceration of the respiratory tract.

• Concentrated solutions of hydrochloric acid can cause severe burns and irritate the

mucous membranes, eyes, and respiratory tract.

– Exposure to hydrochloric acid vapors may result in pulmonary edema and

possibly death.

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

Sodium Hydroxide (NaOH)

• Sodium hydroxide is also called Lye.

• Sodium hydroxide is classified as a corrosive, and it is one of the main chemicals in

drain cleaner.

– It is also used in aluminum etching and to create biodiesal.

– It can burn the skin or cause blindness.

• Sodium hydroxide is used to dispose of road kill because it turns the dead bodies

into a coffee-like liquid.

Sodium Hydroxide (NaOH) (Continued)

• Drain cleaner (sodium hydroxide) is extremely corrosive, and without wearing

protection, even the smallest spill on the skin can eat through flesh…

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sulfuric Acid (H2SO4)

• Sulfuric acid is used in drain or toilet bowl cleaner as well as battery acid.

– It is another highly corrosive substance that burns the skin on contact.

Sulfuric Acid (H2SO4) (Continued)

• The product label warning for Drano® (sulfuric acid) says it all:

– DANGER: MAY BURN EYES AND SKIN ON CONTACT.

•HARMFUL IF SWALLOWED.

–Avoid contact with body and clothing.

•TOXIC GAS MAY FORM IF MIXED WITH OTHER CHEMICALS.

–If gases are released, leave immediately and ventilate area.

•FIRST AID: Give Immediately:

–EYES AND SKIN:

»Flush with water for 20 minutes.

»Remove affected clothing.

–IF SWALLOWED:

»Rinse mouth and drink a glass of water or milk.

»Do not induce vomiting.

–THEN SEEK MEDICAL AID.

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Hypophosphorous Acid (H3PO2)

• Hypophosphorous acid, which is used legally for a variety of commercial purposes,

is a chemical that increasingly is substituted for red phosphorus in the methamphetamine production process.

– The use of hypophospherous acid SIGNIFICANTLY increases the risk of fire!!!

• The federal government regulates the sale of hypophosphorous acid through registration, record keeping, reporting, and import/export requirements regardless

of the quantity being handled or distributed.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid is a colorless oily liquid that emits a SOUR odor.

– There is an extreme fire and explosion hazard if the hypophosphorous acid

comes into contact with a solvent such as acetone, toluene, or Coleman fuel.

• Hypophosphorous acid will also emit phosphine gas and the fumes can ignite.

Hypophosphorous Acid (H3PO2) (Continued)

• Although hypophosphorous acid is a List I chemical under the Controlled Substances Act, methamphetamine producers typically purchase the chemical via

the internet or from associates who also are engaged in methamphetamine

production.

– The use of hypophosphorous acid in methamphetamine production is an

EXTREMELY DANGEROUS PRACTICE because of the deadly gases that can be generated as well as the risk of fire or explosion.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid (H3PO2, also called phosphinic acid) is a strong acid that

typically is prepared as a solution of colorless, oily liquid in strengths of 50%, 30 to 32%, and 10%.

– It also is prepared in the form of salts (referred to as hypophosphite salts), particularly ammonium hypophosphite, calcium hypophosphite, iron (ferric)

hypophosphite, magnesium hypophosphite, manganese hypophosphite,

potassium hypophosphite, and sodium hypophosphite.

Hypophosphorous Acid (H3PO2) (Continued)

• Over 100 chemical firms located throughout the world produce hypophosphorous

acid.

– The People's Republic of China and India have the largest numbers of

hypophosphorous acid producers, although there are a few producers in the United States.

• There are a wide variety of uses for hypophosphorous acid and its salts in

commercial industry; however, the chemicals have no legitimate household or retail uses.

Hypophosphorous Acid (H3PO2) (Continued)

• The legitimate commercial and laboratory fields that use hypophosphorous acid and its salts include the following:

– Chemical plating

– Food preparation

– Water treatment

– Polymers (as a bleaching agent, color stabilizer, or catalyst)

– Education and research in analytical chemistry

Hypophosphorous Acid (H3PO2) (Continued)

• Chemical suppliers typically distribute hypophosphorous acid in large quantities, for example, in drums containing 275 pounds of the diluted solution.

– Hypophosphorous acid also is distributed in smaller quantities.

• One-half liter of 50% concentrate hypophosphorous acid solution can be obtained from chemical suppliers for as little as $14.

Hypophosphorous Acid (H3PO2) (Continued)

• Methamphetamine laboratory operators typically obtain small quantities of the chemical from other laboratory operators who purchase large quantities of the

chemical and repackage it for further distribution.

– According to law enforcement sources, these individuals sell hypophosphorous acid for as much as $1,000 per half-liter.

•Methamphetamine laboratory operators also purchase hypophosphorous acidvia the internet.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid and the Internet

• The internet is a source of a great deal of information regarding hypophosphorous acid.

• Popular internet sites that disseminate information about illicit drugs contain information about the chemical, including numerous recipes for home production of

methamphetamine using hypophosphorous acid.

• There also are recipes for synthesizing hypophosphorous acid from available chemicals.

• Hypophosphorous acid solutions and salts have been sold to the general public via the internet.

• The Drug Enforcement Administration (DEA) has strong concerns regarding the sale

of chemicals on the internet and has requested that any sites (such as auction sites) that allow the sale of regulated chemicals on their domains require proof of

DEA registration from their clients.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid Used in Methamphetamine Production

• Hypophosphorous acid is used in the ephedrine-pseudoephedrine reduction method

of methamphetamine production.

– It is used in the methamphetamine production process to produce hydriodic acid,

an important reagent (it reacts with the ephedrine-pseudoephedrine but does NOT become part of the finished product).

Hypophosphorous Acid (H3PO2) (Continued)

• The regulation of hydriodic acid by DEA in 1993 rendered it virtually unavailable in

the United States.

– However, methamphetamine laboratory operators discovered methods to

produce hydriodic acid using a combination of iodine in water with red phosphorus.

• Laboratory operators found that red phosphorus could be obtained easily, either

from commercial supply companies or by scraping the striker pads from matchbooks or matchboxes.

• Methamphetamine producers soon discovered that hypophosphorous acid ALSO could be used in combination with iodine and water to produce hydriodic acid.

Hypophosphorous Acid (H3PO2) (Continued)

• The practice of using hypophosphorous acid in methamphetamine production is

believed to have begun in the United States in the late 1990s when a methamphetamine producer in Colorado obtained the recipe from Australia, where

the hypophosphorous acid method is prevalent.

– This man was known as a serial cook who had a long history of

methamphetamine production.

•Over several years he trained other laboratory operators in Colorado to produce methamphetamine using hypophosphorous acid.

• As his techniques were passed on to others, the number of methamphetaminelaboratories in Colorado using hypophosphorous acid continued to increase, and the

technique was passed on to numerous methamphetamine producers in other

states.

Hypophosphorous Acid (H3PO2) (Continued)

• According to the El Paso Intelligence Center (EPIC) National Clandestine Laboratory

Seizure System, from 2000 through 2002 the number of seized methamphetaminelaboratories in the United States in which hypophosphorous acid was found

increased overall. (See Table 1.)

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid found at methamphetamine laboratories is packaged in a variety of ways.

• The chemical has been found in 1-gallon bottles of solution or in 1-pound jars of salts.

• Some hypophosphorous acid containers are labeled as "plating solution."

• Pint-sized brown glass bottles wrapped in red electrical tape also have been found to contain hypophosphorous acid; they have been discovered primarily in Colorado.

• The vast majority of hypophosphorous acid found at laboratory sites has been recovered from small toxic laboratories (STLs), those which yield gram to ounce

quantities per production cycle.

• Hypophosphorous acid has not been reported at large-scale laboratories operated by Mexican criminal groups in the United States.

Hypophosphorous Acid (H3PO2) (Continued)

• Hazards

• The iodine-hypophosphorous acid method is MORE HAZORDOUS than the iodine-

red phosphorus method, although the reaction using hypophosphorous acid is

faster and gives slightly higher yields.

– When hypophosphorous acid is used, the chemicals must be mixed together

SLOWLY in a PARTICULAR ORDER to prevent them from reacting violently.

Hypophosphorous Acid (H3PO2) (Continued)

• The combination of hypophosphorous acid with the other chemicals and with

certain metals can produce deadly phosphine gas during the initial mixing step and

can CONTINUE to produce phosphine gas for several days AFTER production has been completed…

Hypophosphorous Acid (H3PO2) (Continued)

• The iodine-hypophosphorous acid mixture has a tendency to decompose quickly when overheated or if heated for long periods of time, becoming cloudy or "milky-

white" just prior to giving off a cloud of phosphine gas that can ignite spontaneously.

– Hypophosphorous acid solutions may become unstable if evaporation results in

concentrations above 50%.

Hypophosphorous Acid (H3PO2) (Continued)

• [Note: Law enforcement or emergency personnel who encounter suspected

containers of hypophosphorous acid should use extreme care during handling because laboratory operators often attempt to obtain a more concentrated acid by

allowing water to evaporate from the mixture.]

• Because hypophosphorous acid often is used at small methamphetaminelaboratories operated by inexperienced or careless individuals, the potential hazards

of using this method are even greater.

• The risk of fire and explosion is higher in these laboratories, where professional

laboratory equipment typically is not used to contain the phosphine gas and where

safe handling precautions are not employed.

• In addition, these laboratories often are located in homes where children are

present and may come into contact with hypophosphorous acid.

• A child can easily mistake hypophosphorous acid for any other clear liquid,

particularly if it is stored in household containers or drinking glasses.

• Skin, eye, or inhalation exposure can be extremely harmful or fatal.

Hypophosphorous Acid (H3PO2) (Continued)

• Safety Precautions

• Always wear a self-contained breathing apparatus as well as protective clothing when entering areas where hypophosphorous acid may be present.

• When in contact with metals or in a high-temperature environment,

hypophosphorous acid can break down and liberate phosphine and flammable hydrogen gas.

• Do not allow the use of open flames, open lights, matches, or smoking in or around laboratories or dumpsites where hypophosphorous acid is handled.

• In case of fire, use a self-contained positive pressure breathing apparatus and full

protective equipment.

• Use water spray, fog, foam, dry chemicals, or other reagents as may be

appropriate for materials in the surrounding fire.

• Water may be used to cool the containers of hypophosphorous acid; however, use extreme care to avoid allowing water to enter the container.

• In case of spills, neutralize the spilled chemical with alkaline material (soda ash, lime), then absorb it with an inert material such as vermiculite, dry sand, or earth

and place in a chemical waste container.

• Do not use combustible materials such as sawdust.

Hypophosphorous Acid (H3PO2) (Continued)

• Legislation and Control

• In the United States hypophosphorous acid is one of 38 chemicals (or groups of

chemicals) controlled under law by DEA.

• On October 17, 2001, hypophosphorous acid and its salts, along with red and white phosphorus, were officially added as List I chemicals under section 1310 of the

Code of Federal Regulations.

• List I chemicals are defined as chemicals that are used in the manufacture of a

controlled substance in violation of the Controlled Substances Act (CSA) and are

important to the manufacture of a controlled substance.

• Under the law, suppliers are required to maintain records and report receipts, sales, imports, and exports of these chemicals to DEA.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid, red phosphorus, and white phosphorus, as well as

ephedrine, are unique in that suppliers are required to report all transactions of

these chemicals, regardless of the amount.

• By contrast, the other 34 listed chemicals are only reportable after a supplier's

transactions for a chemical reach an established weight or volume threshold in a calendar month.

• In addition to reporting all transactions involving the chemical, suppliers are

expected to "know their customers" in order to prevent the diversion of these substances to methamphetamine laboratories, as it is illegal to import, export, purchase, or sell hypophosphorous acid or any other listed chemical in the United States if it is used or intended to be used in the production of a controlled

substance.

• Chemical suppliers are held liable for selling listed chemicals if they know or suspect that the chemical will be used for illicit purposes.

Hypophosphorous Acid (H3PO2) (Continued)

• Outlook

• The use of hypophosphorous acid in the production of methamphetamine is likely

to increase, particularly in the Midwest and Southwest regions of the United States

where methamphetamine production is prevalent.

– Injuries, property damage, and deaths also will increase as a growing number of inexperienced methamphetamine producers experiment with hypophosphorous acid.

Anhydrous Ammonia

• Anhydrous ammonia is found in fertilizer, countertop cleaner, and commercial refrigerant.

– On its own, it has a pungent, suffocating odor.

• Mixing anhydrous ammonia with other chemicals can release highly toxic gases.

– Because anhydrous ammonia seeks out water (anhydrous means “without

water”) and causes severe burns, any body part that comes into contact with it

should be flushed with water for at least 15 minutes to remove the ammoniafrom the skin.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia has extremely destructive effects on humans.

– Anhydrous ammonia gives off vapors during cooking that can burn the mouth,

throat, and lung tissue.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Anhydrous ammonia seeks water from the nearest source, including the human body (anhydrous means “without water”).

– Because of their high moisture content, EYES, LUNGS, and SKIN are at the

greatest risk of attracting the ammonia.

• When large amounts of anhydrous ammonia are inhaled, the throat swells and the

victim suffocates.

– Exposure to the vapors or liquids can cause severe burns, blindness, or death.

• Anhydrous ammonia has an IDLH (immediately dangerous to life and health) at only 300 parts per million...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is poses MANY hazards, especially when it is placed in improper vessels and handled/transported by individuals unfamiliar with the

dangers.

• Anhydrous ammonia has a boiling point of -28 degrees below zero.

– When a vessel containing anhydrous ammonia is MOVED, the anhydrous

ammonia will reach its boiling point and pressurize.

•This pressurization can cause vessels to violently RUPTURE, or if the vessel pressurizes and does NOT rupture, the opening of the container of anhydrous

ammonia at a later time can cause RAPID, VIOLENT depressurization.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is mainly used in the U.S. as either a fertilizer or a refrigerant.

– Meth producers tend to store the anhydrous ammonia in IMPROPER/UNAPPROVED containers such as:

•Propane tanks,

• Igloo coolers, or

•Fire extinguishers.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia leaves a tell-tell sign as it flows through these UNAPPROVED

CONTAINERS – a blue or blue green discoloration on the valve.

– PAY ATTENTION to details!!!

Anhydrous Ammonia (Continued)

• Because propane cylinders (and the other unapproved containers) are NOT designed to store anhydrous ammonia, they can EXPLODE as the ammonia eats

through the walls of the cylinders.

– The valves, which take on a bluish/green color, frequently deteriorate and can cause hazardous leaks!!!

Anhydrous Ammonia (Continued)

• Do NOT touch, move, or open any kind of tank or sealed container!!!

– Be aware that propane tanks are often WEAKENED and BRITTLE due to the

anhydrous ammonia and are SENSITIVE to ANY kind of movement or impact.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• These pictures show what happened to a fire extinguisher that was used to store

anhydrous ammonia…

Anhydrous Ammonia (Continued)

• Illegal drug makers often STEAL anhydrous ammonia from areas where it is stored

and used, such as farms.

• Attempted thefts have also occurred at places such as:

– Refrigeration systems holding ammonia,

– Underground pipelines carrying ammonia, and

– Rail cars transporting anhydrous ammonia.

• Often thefts are aborted when thieves are injured or overcome by the toxic gas...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia thieves had better beware!!!

• There is a new product called GloTell that farmers can add to their anhydrous

ammonia tanks…

• Meth cooks will run the risk that the GloTell additive will turn their hands bright

pink!

– This bright pink stain will fluoresce under ultraviolet light even if washed off!!!

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Also, GloTell will produce pink methamphetamine that CANNOT be bleached.

– Users who snort meth made with GloTell will find that they have PINK NOSES!

– Users who inject meth made with GloTell will see a pink stain at the point of

injection!

Sodium Carbonate (Soda Ash)

Sodium Carbonate (Soda Ash) (Continued)

Lead Acetate

Iodine

• Iodine is a natural element, and it is helpful to the body in SMALL amounts.

– However, if iodine is taken in large amounts it can become toxic.

•Extremely high does of iodine can limit the function of the thyroid.

Iodine (Continued)

Iodine (Continued)

• Iodine is bluish-black, and it has a characteristic odor, a sharp acrid taste, and it produces a violet corrosive vapor.

– The vapor is irritating to the respiratory system and eyes.

• The solid iodine irritates the eyes and may burn the skin, and it may cause severe

internal irritation and damage if ingested.

Iodine (Continued)

• Iodine is known as the “blue ingredient” in the production of meth (in the “red, white, and blue” method).

Iodine (Continued)

Iodine (Continued)

• It takes approximately 4 bottles of iodine tincture to produce 2 – 3 grams of meth.

Iodine (Continued)

Iodine (Continued)

• Iodine leaves distinctive yellow-blue or brown stains on surfaces in former methlabs.

Iodine (Continued)

Iodine (Continued)

Iodine (Continued)

• The only good thing about iodine is that it leaves yellow stains.

• If you see yellow stained coffee filters, gloves or paper towels, this could be an

indicator that you’re in a lab.

• If you see yellow stains, you can spray some starch on them.

– If they turn a purplish blue/black, it’s iodine.

• Iodine is the only substance that reacts with soluble starch to produce a purplish black color.

– The only way to get iodine vapor all over the walls is to cook meth.

Mercurous Chloride

Rock Salt

Hydrogen Chloride

• Hydrogen chloride gas is commercially available.

• Hydrogen chloride gas can also be made by mixing sulfuric acid and salt.

• Muriatic acid is simply hydrogen chloride gas suspended in water.

• Hydrogen chloride gas can be seen as a pale white smoke.

– It is a poisonous gas that can cause respiratory problems and death.

Hydrogen Chloride (Continued)

Ammonium Nitrate

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Hydriodic Acid

• Hydriodic acid is a corrosive acid that is colorless when freshly prepared.

– When hydriodic acid is exposed to light and air, it turns yellowish and brown.

• Hydriodic acid is a solution of hydrogen iodide gas in water.

• Hydriodic acid vapor is irritating to the respiratory system, skin, and eyes.

• Hydriodic acid liquid causes severe burns to the eyes and skin.

• If hydriodic acid is accidentally ingested, it can cause severe internal irritation and

damage.

Hydriodic Acid (Continued)

Catalyst Chemicals

• Catalyst Chemicals:

– Chemicals which SPEED UP a reaction process and/or cause it to go to GREATER COMPLETION.

Red Phosphorus

• Red phosphorus is found ON matchboxes, in road flares, and other explosives.

– Red Phosphorus IGNITES when OVERHEATED!!!

• By combining red phosphorus and iodine, you can easily create the highly

controlled substance known as hydriodic acid (which is an essential ingredient in making meth).

– Creating 2 – 3 grams of meth requires about 4 big boxes of matches.

Red Phosphorus (Continued)

• Red phosphorous is highly flammable and if it is overheated it can become white

phosphorous…

– White phosphorous is a volatile and highly explosive substance.

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Lithium

• Lithium is used in batteries.

• Lithium seriously burns the skin upon contact.

– It also reacts VIOLENTLY with WATER and is highly explosive.

Lithium (Continued)

• Lithium reacts VIOLENTLY with WATER, and if it is splashed in the eyes during

cooking it will cause blindness.

– Lithium is extremely caustic to all body tissues.

Lithium (Continued)

Lithium (Continued)

• Lithium metal is HIGHLY water reactive and it will BURN or EXPLODE if it comes into contact with WATER!

• Because of the moisture in your skin, it will burn exposed flesh.

• Lithium metal will DEGRADE when exposed to atmospheric moisture…

– This is why meth cooks store lithium metal in a solvent prior to use.

• It is typical to see harvested lithium strips in Coleman fuel or Mineral Spirits to prevent explosions.

•Large quantities can be harvested and saved in these containers until needed

for a cook.

Lithium (Continued)

• If you see battery shells in the trashcan, on the floor, etc. – this is a VERY GOOD indicator that you might be entering a meth lab!

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

• Lithium catches fire when in contact with water...

Solvent Chemicals

• Solvent Chemicals:

– A medium (liquid) in which a chemical operation takes place.

• Solvent chemicals (UNLIKE the precursor chemicals) CAN be

substituted/interchanged.

Ether

• Ether was once called “sweet vitriol” because of its hypnotic effect.

• Ether is a highly flammable substance that is used as an anesthetic agent –

especially in third world countries where more expensive anesthesia is not available.

– While inhaling the ether, patients could undergo complete surgical procedures while otherwise awake without feeling pain or concern.

Ether (Continued)

• Ether can be obtained from engine starting fluid.

• Ether is a solvent and it is flammable.

– It is particularly hazardous because it can cause BOTH fire and explosion.

• It has been said that a quart of ether can “level” a small house.

Ethyl Ether (Continued)

Ethyl Ether (Continued)

• Ether is VERY flammable and is HEAVIER than air.

– NEVER use ether near flames or non-sparkless motors.

– Ether is very PUNGENT – even a small evaporated amount of ether is VERY noticeable.

Acetone

• Acetone can be found in nail polish remover or paint thinner.

– It is extremely flammable.

• In the setting of a meth lab where meth is being cooked with high heat, acetone is

very dangerous.

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Toluene

• Toluene is used in brake fluid.

– When working with brake fluid (toluene), be careful not to spill it on your car

because it will eat away the paint and chrome…

• You also have to be careful using toluene around other household chemicals

because its high concentration of polyethylene glycol can cause it to ignite in a

violent fireball.

• Toluene is powerful enough to dissolve rubber.

Toluene (Continued)

• Toluene is used to form meth crystals.

– The fumes toluene releases can cause brain damage or death.

Toluene (Continued)

Toluene (Continued)

Ethanol

Isopropanol

Isopropanol (Continued)

Isopropyl Alcohol

Methanol

Methanol (Continued)

Methanol (Continued)

Benzene

Benzene (Continued)

Which of these is NOT a common ingredient in Meth?

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Page 2: Methamphetamine - PowerPoint - Chemicals and Ingredients ... · 2/5/2014 1 Methamphetamine - PowerPoint - Chemicals and Ingredients Used to Make Meth CJUS 240 Economic Costs of Meth

2/5/2014

2

Methamphetamine- PowerPoint

- Chemicals and Ingredients Used to Make Meth

CJUS 240

Economic Costs of Meth

• The economic cost of methamphetamine use in the U.S. reached $23.4 billion in

2005.

– This includes the burden of addiction, premature death, drug treatment, child care, and cleaning of lab sites.

– This figure does NOT take into account the future needs of the meth user.

Concerns with ACTIVE Meth Labs

• Danger of fire and explosion

• Chemical spills

• Inhalation of solvents, corrosives, and toxic gases

• “Booby traps”

• Waste disposal

Concerns with FORMER Meth Labs

• Vapors

• Chemical residues

• Methamphetamine residues

• Waste disposal

Equipment Used in Meth Production

• Pyrex or Corning dishes

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

• Coffee Filters

Equipment Used in Meth Production

Equipment Used in Meth Production

Basic Chemical Requirements

• In a clandestine laboratory, basic types of chemicals are necessary in order to

produce the desired drug.

– The basic types of chemicals needed are:

1) Precursor Chemicals

2) Reagent Chemicals

3) Catalyst Chemicals

4) Solvent Chemicals

List I Chemical

• The term “List I chemical” means a chemical specified by regulation of the Attorney General as a chemical that is used in manufacturing a controlled substance and is

IMPORTANT to the manufacture of the controlled substance.

• Examples of List I chemicals are:

– GBL

– Red Phosphorus

– Pseudoephedrine

List II Chemical

• The term “List II chemical” means a chemical (other than a List I chemical) specified by regulation of the Attorney General as a chemical that is USED in

manufacturing a controlled substance.

• Examples of List II chemicals are:

– Toluene

– Iodine

– Hydrochloric Acid

Precursor Chemicals

• Precursor Chemicals:

– A chemical that is ESSENTIAL to the production of a controlled substance and for

which NO SUBSTITUTION can be made.

Pseudoephedrine

• Pseudoephedrine is a decongestant found in cold medicine.

– Large amounts of pseudoephedrine on its own can harm the respiratory and nervous systems, as well as the heart.

Pseudoephedrine (Continued)

• Some of the common ways used to divert products containing pseudoephedrine

include:

– “Smurfing” – making multiple purchases at different locations

– Shelf-Sweeping – the theft of all shelf stock

– Shoplifting

– Theft from wholesalers

Pseudoephedrine (Continued)

• Pseudoephedrine smurfing is a method used by some methamphetamine producers to acquire large quantities of pseudoephedrine by enlisting the assistance of several

friends or associates (often referred to as “smurfers”) to make purchases at or below the legal thresholds from multiple retail locations.

– Smurfers are often addicts who trade the pseudoephedrine for finished methamphetamine.

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

• About 680 pseudoephedrine tablets are needed to produce one ounce of meth…

Pseudoephedrine (Continued)

Out With a Bang

An Unstable Recipe…

• Meth contains a variety of poisonous ingredients…

– Some become EVEN MORE DANGEROUS once the cooking process begins…

Common Ingredients to Make Methamphetamine

Reagent Chemicals

• Reagent Chemicals:

– Chemicals which REACT upon the precursor chemical causing it to chemicallyCHANGE.

• A reagent chemical is a chemical which is required for the synthesis of an illicit drug substance, but which is NOT incorporated into the final chemical product.

Hydrochloric Acid

• Hydrochloric acid is a highly corrosive liquid that is used to make plastic (such as PVC pipe and polyurethane).

– It can remove rust and iron-oxide from steel and is highly corrosive to human

skin.

•Hydrochloric acid makes up the majority of the gastric acid in the human

digestive fluid.

• In high concentrations, hydrochloric acid will literally eat away human flesh…

Hydrochloric Acid (Continued)

• Hydrochloric acid can be purchased from hardware stores as:

– Tile and Grout Acid Cleaner

– Muriatic Acid

– Pool Acid

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

• Hydrochloric acid is a solution of hydrogen chloride gas suspended in water.

– Hydrochloric acid is corrosive and is a light yellow liquid color from traces of iron, chlorine, and organic matter.

• Inhaling hydrochloric acid may cause coughing or choking, inflammation, and

ulceration of the respiratory tract.

• Concentrated solutions of hydrochloric acid can cause severe burns and irritate the

mucous membranes, eyes, and respiratory tract.

– Exposure to hydrochloric acid vapors may result in pulmonary edema and

possibly death.

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

Sodium Hydroxide (NaOH)

• Sodium hydroxide is also called Lye.

• Sodium hydroxide is classified as a corrosive, and it is one of the main chemicals in

drain cleaner.

– It is also used in aluminum etching and to create biodiesal.

– It can burn the skin or cause blindness.

• Sodium hydroxide is used to dispose of road kill because it turns the dead bodies

into a coffee-like liquid.

Sodium Hydroxide (NaOH) (Continued)

• Drain cleaner (sodium hydroxide) is extremely corrosive, and without wearing protection, even the smallest spill on the skin can eat through flesh…

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sulfuric Acid (H2SO4)

• Sulfuric acid is used in drain or toilet bowl cleaner as well as battery acid.

– It is another highly corrosive substance that burns the skin on contact.

Sulfuric Acid (H2SO4) (Continued)

• The product label warning for Drano® (sulfuric acid) says it all:

– DANGER: MAY BURN EYES AND SKIN ON CONTACT.

•HARMFUL IF SWALLOWED.

–Avoid contact with body and clothing.

•TOXIC GAS MAY FORM IF MIXED WITH OTHER CHEMICALS.

–If gases are released, leave immediately and ventilate area.

•FIRST AID: Give Immediately:

–EYES AND SKIN:

»Flush with water for 20 minutes.

»Remove affected clothing.

–IF SWALLOWED:

»Rinse mouth and drink a glass of water or milk.

»Do not induce vomiting.

–THEN SEEK MEDICAL AID.

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Hypophosphorous Acid (H3PO2)

• Hypophosphorous acid, which is used legally for a variety of commercial purposes,

is a chemical that increasingly is substituted for red phosphorus in the methamphetamine production process.

– The use of hypophospherous acid SIGNIFICANTLY increases the risk of fire!!!

• The federal government regulates the sale of hypophosphorous acid through registration, record keeping, reporting, and import/export requirements regardless

of the quantity being handled or distributed.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid is a colorless oily liquid that emits a SOUR odor.

– There is an extreme fire and explosion hazard if the hypophosphorous acid

comes into contact with a solvent such as acetone, toluene, or Coleman fuel.

• Hypophosphorous acid will also emit phosphine gas and the fumes can ignite.

Hypophosphorous Acid (H3PO2) (Continued)

• Although hypophosphorous acid is a List I chemical under the Controlled Substances Act, methamphetamine producers typically purchase the chemical via

the internet or from associates who also are engaged in methamphetamine

production.

– The use of hypophosphorous acid in methamphetamine production is an

EXTREMELY DANGEROUS PRACTICE because of the deadly gases that can be generated as well as the risk of fire or explosion.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid (H3PO2, also called phosphinic acid) is a strong acid that

typically is prepared as a solution of colorless, oily liquid in strengths of 50%, 30 to 32%, and 10%.

– It also is prepared in the form of salts (referred to as hypophosphite salts), particularly ammonium hypophosphite, calcium hypophosphite, iron (ferric)

hypophosphite, magnesium hypophosphite, manganese hypophosphite,

potassium hypophosphite, and sodium hypophosphite.

Hypophosphorous Acid (H3PO2) (Continued)

• Over 100 chemical firms located throughout the world produce hypophosphorous

acid.

– The People's Republic of China and India have the largest numbers of

hypophosphorous acid producers, although there are a few producers in the United States.

• There are a wide variety of uses for hypophosphorous acid and its salts in

commercial industry; however, the chemicals have no legitimate household or retail uses.

Hypophosphorous Acid (H3PO2) (Continued)

• The legitimate commercial and laboratory fields that use hypophosphorous acid and its salts include the following:

– Chemical plating

– Food preparation

– Water treatment

– Polymers (as a bleaching agent, color stabilizer, or catalyst)

– Education and research in analytical chemistry

Hypophosphorous Acid (H3PO2) (Continued)

• Chemical suppliers typically distribute hypophosphorous acid in large quantities, for example, in drums containing 275 pounds of the diluted solution.

– Hypophosphorous acid also is distributed in smaller quantities.

• One-half liter of 50% concentrate hypophosphorous acid solution can be obtained from chemical suppliers for as little as $14.

Hypophosphorous Acid (H3PO2) (Continued)

• Methamphetamine laboratory operators typically obtain small quantities of the chemical from other laboratory operators who purchase large quantities of the

chemical and repackage it for further distribution.

– According to law enforcement sources, these individuals sell hypophosphorous acid for as much as $1,000 per half-liter.

•Methamphetamine laboratory operators also purchase hypophosphorous acidvia the internet.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid and the Internet

• The internet is a source of a great deal of information regarding hypophosphorous acid.

• Popular internet sites that disseminate information about illicit drugs contain information about the chemical, including numerous recipes for home production of

methamphetamine using hypophosphorous acid.

• There also are recipes for synthesizing hypophosphorous acid from available chemicals.

• Hypophosphorous acid solutions and salts have been sold to the general public via the internet.

• The Drug Enforcement Administration (DEA) has strong concerns regarding the sale

of chemicals on the internet and has requested that any sites (such as auction sites) that allow the sale of regulated chemicals on their domains require proof of

DEA registration from their clients.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid Used in Methamphetamine Production

• Hypophosphorous acid is used in the ephedrine-pseudoephedrine reduction method

of methamphetamine production.

– It is used in the methamphetamine production process to produce hydriodic acid,

an important reagent (it reacts with the ephedrine-pseudoephedrine but does NOT become part of the finished product).

Hypophosphorous Acid (H3PO2) (Continued)

• The regulation of hydriodic acid by DEA in 1993 rendered it virtually unavailable in

the United States.

– However, methamphetamine laboratory operators discovered methods to

produce hydriodic acid using a combination of iodine in water with red phosphorus.

• Laboratory operators found that red phosphorus could be obtained easily, either

from commercial supply companies or by scraping the striker pads from matchbooks or matchboxes.

• Methamphetamine producers soon discovered that hypophosphorous acid ALSO could be used in combination with iodine and water to produce hydriodic acid.

Hypophosphorous Acid (H3PO2) (Continued)

• The practice of using hypophosphorous acid in methamphetamine production is

believed to have begun in the United States in the late 1990s when a methamphetamine producer in Colorado obtained the recipe from Australia, where

the hypophosphorous acid method is prevalent.

– This man was known as a serial cook who had a long history of

methamphetamine production.

•Over several years he trained other laboratory operators in Colorado to produce methamphetamine using hypophosphorous acid.

• As his techniques were passed on to others, the number of methamphetaminelaboratories in Colorado using hypophosphorous acid continued to increase, and the

technique was passed on to numerous methamphetamine producers in other states.

Hypophosphorous Acid (H3PO2) (Continued)

• According to the El Paso Intelligence Center (EPIC) National Clandestine Laboratory

Seizure System, from 2000 through 2002 the number of seized methamphetaminelaboratories in the United States in which hypophosphorous acid was found

increased overall. (See Table 1.)

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid found at methamphetamine laboratories is packaged in a variety of ways.

• The chemical has been found in 1-gallon bottles of solution or in 1-pound jars of salts.

• Some hypophosphorous acid containers are labeled as "plating solution."

• Pint-sized brown glass bottles wrapped in red electrical tape also have been found to contain hypophosphorous acid; they have been discovered primarily in Colorado.

• The vast majority of hypophosphorous acid found at laboratory sites has been recovered from small toxic laboratories (STLs), those which yield gram to ounce

quantities per production cycle.

• Hypophosphorous acid has not been reported at large-scale laboratories operated by Mexican criminal groups in the United States.

Hypophosphorous Acid (H3PO2) (Continued)

• Hazards

• The iodine-hypophosphorous acid method is MORE HAZORDOUS than the iodine-

red phosphorus method, although the reaction using hypophosphorous acid is

faster and gives slightly higher yields.

– When hypophosphorous acid is used, the chemicals must be mixed together

SLOWLY in a PARTICULAR ORDER to prevent them from reacting violently.

Hypophosphorous Acid (H3PO2) (Continued)

• The combination of hypophosphorous acid with the other chemicals and with

certain metals can produce deadly phosphine gas during the initial mixing step and

can CONTINUE to produce phosphine gas for several days AFTER production has been completed…

Hypophosphorous Acid (H3PO2) (Continued)

• The iodine-hypophosphorous acid mixture has a tendency to decompose quickly when overheated or if heated for long periods of time, becoming cloudy or "milky-

white" just prior to giving off a cloud of phosphine gas that can ignite spontaneously.

– Hypophosphorous acid solutions may become unstable if evaporation results in

concentrations above 50%.

Hypophosphorous Acid (H3PO2) (Continued)

• [Note: Law enforcement or emergency personnel who encounter suspected

containers of hypophosphorous acid should use extreme care during handling because laboratory operators often attempt to obtain a more concentrated acid by

allowing water to evaporate from the mixture.]

• Because hypophosphorous acid often is used at small methamphetaminelaboratories operated by inexperienced or careless individuals, the potential hazards

of using this method are even greater.

• The risk of fire and explosion is higher in these laboratories, where professional

laboratory equipment typically is not used to contain the phosphine gas and where

safe handling precautions are not employed.

• In addition, these laboratories often are located in homes where children are

present and may come into contact with hypophosphorous acid.

• A child can easily mistake hypophosphorous acid for any other clear liquid,

particularly if it is stored in household containers or drinking glasses.

• Skin, eye, or inhalation exposure can be extremely harmful or fatal.

Hypophosphorous Acid (H3PO2) (Continued)

• Safety Precautions

• Always wear a self-contained breathing apparatus as well as protective clothing when entering areas where hypophosphorous acid may be present.

• When in contact with metals or in a high-temperature environment,

hypophosphorous acid can break down and liberate phosphine and flammable hydrogen gas.

• Do not allow the use of open flames, open lights, matches, or smoking in or around laboratories or dumpsites where hypophosphorous acid is handled.

• In case of fire, use a self-contained positive pressure breathing apparatus and full

protective equipment.

• Use water spray, fog, foam, dry chemicals, or other reagents as may be

appropriate for materials in the surrounding fire.

• Water may be used to cool the containers of hypophosphorous acid; however, use extreme care to avoid allowing water to enter the container.

• In case of spills, neutralize the spilled chemical with alkaline material (soda ash, lime), then absorb it with an inert material such as vermiculite, dry sand, or earth

and place in a chemical waste container.

• Do not use combustible materials such as sawdust.

Hypophosphorous Acid (H3PO2) (Continued)

• Legislation and Control

• In the United States hypophosphorous acid is one of 38 chemicals (or groups of

chemicals) controlled under law by DEA.

• On October 17, 2001, hypophosphorous acid and its salts, along with red and white phosphorus, were officially added as List I chemicals under section 1310 of the

Code of Federal Regulations.

• List I chemicals are defined as chemicals that are used in the manufacture of a

controlled substance in violation of the Controlled Substances Act (CSA) and are

important to the manufacture of a controlled substance.

• Under the law, suppliers are required to maintain records and report receipts, sales,

imports, and exports of these chemicals to DEA.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid, red phosphorus, and white phosphorus, as well as

ephedrine, are unique in that suppliers are required to report all transactions of

these chemicals, regardless of the amount.

• By contrast, the other 34 listed chemicals are only reportable after a supplier's

transactions for a chemical reach an established weight or volume threshold in a calendar month.

• In addition to reporting all transactions involving the chemical, suppliers are

expected to "know their customers" in order to prevent the diversion of these substances to methamphetamine laboratories, as it is illegal to import, export,

purchase, or sell hypophosphorous acid or any other listed chemical in the United States if it is used or intended to be used in the production of a controlled substance.

• Chemical suppliers are held liable for selling listed chemicals if they know or suspect that the chemical will be used for illicit purposes.

Hypophosphorous Acid (H3PO2) (Continued)

• Outlook

• The use of hypophosphorous acid in the production of methamphetamine is likely

to increase, particularly in the Midwest and Southwest regions of the United States

where methamphetamine production is prevalent.

– Injuries, property damage, and deaths also will increase as a growing number of

inexperienced methamphetamine producers experiment with hypophosphorous acid.

Anhydrous Ammonia

• Anhydrous ammonia is found in fertilizer, countertop cleaner, and commercial refrigerant.

– On its own, it has a pungent, suffocating odor.

• Mixing anhydrous ammonia with other chemicals can release highly toxic gases.

– Because anhydrous ammonia seeks out water (anhydrous means “without

water”) and causes severe burns, any body part that comes into contact with it

should be flushed with water for at least 15 minutes to remove the ammoniafrom the skin.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia has extremely destructive effects on humans.

– Anhydrous ammonia gives off vapors during cooking that can burn the mouth,

throat, and lung tissue.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Anhydrous ammonia seeks water from the nearest source, including the human body (anhydrous means “without water”).

– Because of their high moisture content, EYES, LUNGS, and SKIN are at the

greatest risk of attracting the ammonia.

• When large amounts of anhydrous ammonia are inhaled, the throat swells and the

victim suffocates.

– Exposure to the vapors or liquids can cause severe burns, blindness, or death.

• Anhydrous ammonia has an IDLH (immediately dangerous to life and health) at

only 300 parts per million...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is poses MANY hazards, especially when it is placed in improper vessels and handled/transported by individuals unfamiliar with the

dangers.

• Anhydrous ammonia has a boiling point of -28 degrees below zero.

– When a vessel containing anhydrous ammonia is MOVED, the anhydrous

ammonia will reach its boiling point and pressurize.

•This pressurization can cause vessels to violently RUPTURE, or if the vessel pressurizes and does NOT rupture, the opening of the container of anhydrous ammonia at a later time can cause RAPID, VIOLENT depressurization.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is mainly used in the U.S. as either a fertilizer or a refrigerant.

– Meth producers tend to store the anhydrous ammonia in IMPROPER/UNAPPROVED containers such as:

•Propane tanks,

• Igloo coolers, or

•Fire extinguishers.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia leaves a tell-tell sign as it flows through these UNAPPROVED CONTAINERS – a blue or blue green discoloration on the valve.

– PAY ATTENTION to details!!!

Anhydrous Ammonia (Continued)

• Because propane cylinders (and the other unapproved containers) are NOT designed to store anhydrous ammonia, they can EXPLODE as the ammonia eats

through the walls of the cylinders.

– The valves, which take on a bluish/green color, frequently deteriorate and can cause hazardous leaks!!!

Anhydrous Ammonia (Continued)

• Do NOT touch, move, or open any kind of tank or sealed container!!!

– Be aware that propane tanks are often WEAKENED and BRITTLE due to the

anhydrous ammonia and are SENSITIVE to ANY kind of movement or impact.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• These pictures show what happened to a fire extinguisher that was used to store

anhydrous ammonia…

Anhydrous Ammonia (Continued)

• Illegal drug makers often STEAL anhydrous ammonia from areas where it is stored

and used, such as farms.

• Attempted thefts have also occurred at places such as:

– Refrigeration systems holding ammonia,

– Underground pipelines carrying ammonia, and

– Rail cars transporting anhydrous ammonia.

• Often thefts are aborted when thieves are injured or overcome by the toxic gas...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia thieves had better beware!!!

• There is a new product called GloTell that farmers can add to their anhydrous

ammonia tanks…

• Meth cooks will run the risk that the GloTell additive will turn their hands bright

pink!

– This bright pink stain will fluoresce under ultraviolet light even if washed off!!!

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Also, GloTell will produce pink methamphetamine that CANNOT be bleached.

– Users who snort meth made with GloTell will find that they have PINK NOSES!

– Users who inject meth made with GloTell will see a pink stain at the point of

injection!

Sodium Carbonate (Soda Ash)

Sodium Carbonate (Soda Ash) (Continued)

Lead Acetate

Iodine

• Iodine is a natural element, and it is helpful to the body in SMALL amounts.

– However, if iodine is taken in large amounts it can become toxic.

•Extremely high does of iodine can limit the function of the thyroid.

Iodine (Continued)

Iodine (Continued)

• Iodine is bluish-black, and it has a characteristic odor, a sharp acrid taste, and it produces a violet corrosive vapor.

– The vapor is irritating to the respiratory system and eyes.

• The solid iodine irritates the eyes and may burn the skin, and it may cause severe

internal irritation and damage if ingested.

Iodine (Continued)

• Iodine is known as the “blue ingredient” in the production of meth (in the “red, white, and blue” method).

Iodine (Continued)

Iodine (Continued)

• It takes approximately 4 bottles of iodine tincture to produce 2 – 3 grams of meth.

Iodine (Continued)

Iodine (Continued)

• Iodine leaves distinctive yellow-blue or brown stains on surfaces in former methlabs.

Iodine (Continued)

Iodine (Continued)

Iodine (Continued)

• The only good thing about iodine is that it leaves yellow stains.

• If you see yellow stained coffee filters, gloves or paper towels, this could be an

indicator that you’re in a lab.

• If you see yellow stains, you can spray some starch on them.

– If they turn a purplish blue/black, it’s iodine.

• Iodine is the only substance that reacts with soluble starch to produce a purplish black color.

– The only way to get iodine vapor all over the walls is to cook meth.

Mercurous Chloride

Rock Salt

Hydrogen Chloride

• Hydrogen chloride gas is commercially available.

• Hydrogen chloride gas can also be made by mixing sulfuric acid and salt.

• Muriatic acid is simply hydrogen chloride gas suspended in water.

• Hydrogen chloride gas can be seen as a pale white smoke.

– It is a poisonous gas that can cause respiratory problems and death.

Hydrogen Chloride (Continued)

Ammonium Nitrate

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Hydriodic Acid

• Hydriodic acid is a corrosive acid that is colorless when freshly prepared.

– When hydriodic acid is exposed to light and air, it turns yellowish and brown.

• Hydriodic acid is a solution of hydrogen iodide gas in water.

• Hydriodic acid vapor is irritating to the respiratory system, skin, and eyes.

• Hydriodic acid liquid causes severe burns to the eyes and skin.

• If hydriodic acid is accidentally ingested, it can cause severe internal irritation and

damage.

Hydriodic Acid (Continued)

Catalyst Chemicals

• Catalyst Chemicals:

– Chemicals which SPEED UP a reaction process and/or cause it to go to GREATER COMPLETION.

Red Phosphorus

• Red phosphorus is found ON matchboxes, in road flares, and other explosives.

– Red Phosphorus IGNITES when OVERHEATED!!!

• By combining red phosphorus and iodine, you can easily create the highly

controlled substance known as hydriodic acid (which is an essential ingredient in making meth).

– Creating 2 – 3 grams of meth requires about 4 big boxes of matches.

Red Phosphorus (Continued)

• Red phosphorous is highly flammable and if it is overheated it can become white

phosphorous…

– White phosphorous is a volatile and highly explosive substance.

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Lithium

• Lithium is used in batteries.

• Lithium seriously burns the skin upon contact.

– It also reacts VIOLENTLY with WATER and is highly explosive.

Lithium (Continued)

• Lithium reacts VIOLENTLY with WATER, and if it is splashed in the eyes during

cooking it will cause blindness.

– Lithium is extremely caustic to all body tissues.

Lithium (Continued)

Lithium (Continued)

• Lithium metal is HIGHLY water reactive and it will BURN or EXPLODE if it comes into contact with WATER!

• Because of the moisture in your skin, it will burn exposed flesh.

• Lithium metal will DEGRADE when exposed to atmospheric moisture…

– This is why meth cooks store lithium metal in a solvent prior to use.

• It is typical to see harvested lithium strips in Coleman fuel or Mineral Spirits to prevent explosions.

•Large quantities can be harvested and saved in these containers until needed

for a cook.

Lithium (Continued)

• If you see battery shells in the trashcan, on the floor, etc. – this is a VERY GOOD

indicator that you might be entering a meth lab!

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

• Lithium catches fire when in contact with water...

Solvent Chemicals

• Solvent Chemicals:

– A medium (liquid) in which a chemical operation takes place.

• Solvent chemicals (UNLIKE the precursor chemicals) CAN be

substituted/interchanged.

Ether

• Ether was once called “sweet vitriol” because of its hypnotic effect.

• Ether is a highly flammable substance that is used as an anesthetic agent –

especially in third world countries where more expensive anesthesia is not available.

– While inhaling the ether, patients could undergo complete surgical procedures while otherwise awake without feeling pain or concern.

Ether (Continued)

• Ether can be obtained from engine starting fluid.

• Ether is a solvent and it is flammable.

– It is particularly hazardous because it can cause BOTH fire and explosion.

• It has been said that a quart of ether can “level” a small house.

Ethyl Ether (Continued)

Ethyl Ether (Continued)

• Ether is VERY flammable and is HEAVIER than air.

– NEVER use ether near flames or non-sparkless motors.

– Ether is very PUNGENT – even a small evaporated amount of ether is VERY noticeable.

Acetone

• Acetone can be found in nail polish remover or paint thinner.

– It is extremely flammable.

• In the setting of a meth lab where meth is being cooked with high heat, acetone is

very dangerous.

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Toluene

• Toluene is used in brake fluid.

– When working with brake fluid (toluene), be careful not to spill it on your car

because it will eat away the paint and chrome…

• You also have to be careful using toluene around other household chemicals

because its high concentration of polyethylene glycol can cause it to ignite in a

violent fireball.

• Toluene is powerful enough to dissolve rubber.

Toluene (Continued)

• Toluene is used to form meth crystals.

– The fumes toluene releases can cause brain damage or death.

Toluene (Continued)

Toluene (Continued)

Ethanol

Isopropanol

Isopropanol (Continued)

Isopropyl Alcohol

Methanol

Methanol (Continued)

Methanol (Continued)

Benzene

Benzene (Continued)

Which of these is NOT a common ingredient in Meth?

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Page 3: Methamphetamine - PowerPoint - Chemicals and Ingredients ... · 2/5/2014 1 Methamphetamine - PowerPoint - Chemicals and Ingredients Used to Make Meth CJUS 240 Economic Costs of Meth

2/5/2014

3

Methamphetamine- PowerPoint- Chemicals and Ingredients Used to Make Meth

CJUS 240

Economic Costs of Meth

• The economic cost of methamphetamine use in the U.S. reached $23.4 billion in

2005.

– This includes the burden of addiction, premature death, drug treatment, child

care, and cleaning of lab sites.

– This figure does NOT take into account the future needs of the meth user.

Concerns with ACTIVE Meth Labs

• Danger of fire and explosion

• Chemical spills

• Inhalation of solvents, corrosives, and toxic gases

• “Booby traps”

• Waste disposal

Concerns with FORMER Meth Labs

• Vapors

• Chemical residues

• Methamphetamine residues

• Waste disposal

Equipment Used in Meth Production

• Pyrex or Corning dishes

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

• Coffee Filters

Equipment Used in Meth Production

Equipment Used in Meth Production

Basic Chemical Requirements

• In a clandestine laboratory, basic types of chemicals are necessary in order to

produce the desired drug.

– The basic types of chemicals needed are:

1) Precursor Chemicals

2) Reagent Chemicals

3) Catalyst Chemicals

4) Solvent Chemicals

List I Chemical

• The term “List I chemical” means a chemical specified by regulation of the Attorney General as a chemical that is used in manufacturing a controlled substance and is

IMPORTANT to the manufacture of the controlled substance.

• Examples of List I chemicals are:

– GBL

– Red Phosphorus

– Pseudoephedrine

List II Chemical

• The term “List II chemical” means a chemical (other than a List I chemical) specified by regulation of the Attorney General as a chemical that is USED in

manufacturing a controlled substance.

• Examples of List II chemicals are:

– Toluene

– Iodine

– Hydrochloric Acid

Precursor Chemicals

• Precursor Chemicals:

– A chemical that is ESSENTIAL to the production of a controlled substance and for

which NO SUBSTITUTION can be made.

Pseudoephedrine

• Pseudoephedrine is a decongestant found in cold medicine.

– Large amounts of pseudoephedrine on its own can harm the respiratory and nervous systems, as well as the heart.

Pseudoephedrine (Continued)

• Some of the common ways used to divert products containing pseudoephedrine

include:

– “Smurfing” – making multiple purchases at different locations

– Shelf-Sweeping – the theft of all shelf stock

– Shoplifting

– Theft from wholesalers

Pseudoephedrine (Continued)

• Pseudoephedrine smurfing is a method used by some methamphetamine producers to acquire large quantities of pseudoephedrine by enlisting the assistance of several

friends or associates (often referred to as “smurfers”) to make purchases at or below the legal thresholds from multiple retail locations.

– Smurfers are often addicts who trade the pseudoephedrine for finished

methamphetamine.

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

• About 680 pseudoephedrine tablets are needed to produce one ounce of meth…

Pseudoephedrine (Continued)

Out With a Bang

An Unstable Recipe…

• Meth contains a variety of poisonous ingredients…

– Some become EVEN MORE DANGEROUS once the cooking process begins…

Common Ingredients to Make Methamphetamine

Reagent Chemicals

• Reagent Chemicals:

– Chemicals which REACT upon the precursor chemical causing it to chemicallyCHANGE.

• A reagent chemical is a chemical which is required for the synthesis of an illicit drug substance, but which is NOT incorporated into the final chemical product.

Hydrochloric Acid

• Hydrochloric acid is a highly corrosive liquid that is used to make plastic (such as PVC pipe and polyurethane).

– It can remove rust and iron-oxide from steel and is highly corrosive to human

skin.

•Hydrochloric acid makes up the majority of the gastric acid in the human

digestive fluid.

• In high concentrations, hydrochloric acid will literally eat away human flesh…

Hydrochloric Acid (Continued)

• Hydrochloric acid can be purchased from hardware stores as:

– Tile and Grout Acid Cleaner

– Muriatic Acid

– Pool Acid

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

• Hydrochloric acid is a solution of hydrogen chloride gas suspended in water.

– Hydrochloric acid is corrosive and is a light yellow liquid color from traces of iron, chlorine, and organic matter.

• Inhaling hydrochloric acid may cause coughing or choking, inflammation, and

ulceration of the respiratory tract.

• Concentrated solutions of hydrochloric acid can cause severe burns and irritate the

mucous membranes, eyes, and respiratory tract.

– Exposure to hydrochloric acid vapors may result in pulmonary edema and

possibly death.

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

Sodium Hydroxide (NaOH)

• Sodium hydroxide is also called Lye.

• Sodium hydroxide is classified as a corrosive, and it is one of the main chemicals in

drain cleaner.

– It is also used in aluminum etching and to create biodiesal.

– It can burn the skin or cause blindness.

• Sodium hydroxide is used to dispose of road kill because it turns the dead bodies

into a coffee-like liquid.

Sodium Hydroxide (NaOH) (Continued)

• Drain cleaner (sodium hydroxide) is extremely corrosive, and without wearing

protection, even the smallest spill on the skin can eat through flesh…

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sulfuric Acid (H2SO4)

• Sulfuric acid is used in drain or toilet bowl cleaner as well as battery acid.

– It is another highly corrosive substance that burns the skin on contact.

Sulfuric Acid (H2SO4) (Continued)

• The product label warning for Drano® (sulfuric acid) says it all:

– DANGER: MAY BURN EYES AND SKIN ON CONTACT.

•HARMFUL IF SWALLOWED.

–Avoid contact with body and clothing.

•TOXIC GAS MAY FORM IF MIXED WITH OTHER CHEMICALS.

–If gases are released, leave immediately and ventilate area.

•FIRST AID: Give Immediately:

–EYES AND SKIN:

»Flush with water for 20 minutes.

»Remove affected clothing.

–IF SWALLOWED:

»Rinse mouth and drink a glass of water or milk.

»Do not induce vomiting.

–THEN SEEK MEDICAL AID.

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Hypophosphorous Acid (H3PO2)

• Hypophosphorous acid, which is used legally for a variety of commercial purposes,

is a chemical that increasingly is substituted for red phosphorus in the methamphetamine production process.

– The use of hypophospherous acid SIGNIFICANTLY increases the risk of fire!!!

• The federal government regulates the sale of hypophosphorous acid through registration, record keeping, reporting, and import/export requirements regardless

of the quantity being handled or distributed.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid is a colorless oily liquid that emits a SOUR odor.

– There is an extreme fire and explosion hazard if the hypophosphorous acid

comes into contact with a solvent such as acetone, toluene, or Coleman fuel.

• Hypophosphorous acid will also emit phosphine gas and the fumes can ignite.

Hypophosphorous Acid (H3PO2) (Continued)

• Although hypophosphorous acid is a List I chemical under the Controlled Substances Act, methamphetamine producers typically purchase the chemical via

the internet or from associates who also are engaged in methamphetamine

production.

– The use of hypophosphorous acid in methamphetamine production is an

EXTREMELY DANGEROUS PRACTICE because of the deadly gases that can be generated as well as the risk of fire or explosion.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid (H3PO2, also called phosphinic acid) is a strong acid that

typically is prepared as a solution of colorless, oily liquid in strengths of 50%, 30 to 32%, and 10%.

– It also is prepared in the form of salts (referred to as hypophosphite salts), particularly ammonium hypophosphite, calcium hypophosphite, iron (ferric)

hypophosphite, magnesium hypophosphite, manganese hypophosphite,

potassium hypophosphite, and sodium hypophosphite.

Hypophosphorous Acid (H3PO2) (Continued)

• Over 100 chemical firms located throughout the world produce hypophosphorous

acid.

– The People's Republic of China and India have the largest numbers of

hypophosphorous acid producers, although there are a few producers in the United States.

• There are a wide variety of uses for hypophosphorous acid and its salts in

commercial industry; however, the chemicals have no legitimate household or retail uses.

Hypophosphorous Acid (H3PO2) (Continued)

• The legitimate commercial and laboratory fields that use hypophosphorous acid and its salts include the following:

– Chemical plating

– Food preparation

– Water treatment

– Polymers (as a bleaching agent, color stabilizer, or catalyst)

– Education and research in analytical chemistry

Hypophosphorous Acid (H3PO2) (Continued)

• Chemical suppliers typically distribute hypophosphorous acid in large quantities, for example, in drums containing 275 pounds of the diluted solution.

– Hypophosphorous acid also is distributed in smaller quantities.

• One-half liter of 50% concentrate hypophosphorous acid solution can be obtained from chemical suppliers for as little as $14.

Hypophosphorous Acid (H3PO2) (Continued)

• Methamphetamine laboratory operators typically obtain small quantities of the chemical from other laboratory operators who purchase large quantities of the

chemical and repackage it for further distribution.

– According to law enforcement sources, these individuals sell hypophosphorous acid for as much as $1,000 per half-liter.

•Methamphetamine laboratory operators also purchase hypophosphorous acidvia the internet.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid and the Internet

• The internet is a source of a great deal of information regarding hypophosphorous acid.

• Popular internet sites that disseminate information about illicit drugs contain information about the chemical, including numerous recipes for home production of

methamphetamine using hypophosphorous acid.

• There also are recipes for synthesizing hypophosphorous acid from available chemicals.

• Hypophosphorous acid solutions and salts have been sold to the general public via the internet.

• The Drug Enforcement Administration (DEA) has strong concerns regarding the sale

of chemicals on the internet and has requested that any sites (such as auction sites) that allow the sale of regulated chemicals on their domains require proof of DEA registration from their clients.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid Used in Methamphetamine Production

• Hypophosphorous acid is used in the ephedrine-pseudoephedrine reduction method

of methamphetamine production.

– It is used in the methamphetamine production process to produce hydriodic acid,

an important reagent (it reacts with the ephedrine-pseudoephedrine but does NOT become part of the finished product).

Hypophosphorous Acid (H3PO2) (Continued)

• The regulation of hydriodic acid by DEA in 1993 rendered it virtually unavailable in the United States.

– However, methamphetamine laboratory operators discovered methods to

produce hydriodic acid using a combination of iodine in water with red phosphorus.

• Laboratory operators found that red phosphorus could be obtained easily, either

from commercial supply companies or by scraping the striker pads from matchbooks or matchboxes.

• Methamphetamine producers soon discovered that hypophosphorous acid ALSO could be used in combination with iodine and water to produce hydriodic acid.

Hypophosphorous Acid (H3PO2) (Continued)

• The practice of using hypophosphorous acid in methamphetamine production is believed to have begun in the United States in the late 1990s when a methamphetamine producer in Colorado obtained the recipe from Australia, where

the hypophosphorous acid method is prevalent.

– This man was known as a serial cook who had a long history of

methamphetamine production.

•Over several years he trained other laboratory operators in Colorado to produce methamphetamine using hypophosphorous acid.

• As his techniques were passed on to others, the number of methamphetaminelaboratories in Colorado using hypophosphorous acid continued to increase, and the

technique was passed on to numerous methamphetamine producers in other

states.

Hypophosphorous Acid (H3PO2) (Continued)

• According to the El Paso Intelligence Center (EPIC) National Clandestine Laboratory

Seizure System, from 2000 through 2002 the number of seized methamphetaminelaboratories in the United States in which hypophosphorous acid was found

increased overall. (See Table 1.)

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid found at methamphetamine laboratories is packaged in a variety of ways.

• The chemical has been found in 1-gallon bottles of solution or in 1-pound jars of salts.

• Some hypophosphorous acid containers are labeled as "plating solution."

• Pint-sized brown glass bottles wrapped in red electrical tape also have been found to contain hypophosphorous acid; they have been discovered primarily in Colorado.

• The vast majority of hypophosphorous acid found at laboratory sites has been recovered from small toxic laboratories (STLs), those which yield gram to ounce

quantities per production cycle.

• Hypophosphorous acid has not been reported at large-scale laboratories operated by Mexican criminal groups in the United States.

Hypophosphorous Acid (H3PO2) (Continued)

• Hazards

• The iodine-hypophosphorous acid method is MORE HAZORDOUS than the iodine-

red phosphorus method, although the reaction using hypophosphorous acid is

faster and gives slightly higher yields.

– When hypophosphorous acid is used, the chemicals must be mixed together

SLOWLY in a PARTICULAR ORDER to prevent them from reacting violently.

Hypophosphorous Acid (H3PO2) (Continued)

• The combination of hypophosphorous acid with the other chemicals and with

certain metals can produce deadly phosphine gas during the initial mixing step and

can CONTINUE to produce phosphine gas for several days AFTER production has been completed…

Hypophosphorous Acid (H3PO2) (Continued)

• The iodine-hypophosphorous acid mixture has a tendency to decompose quickly when overheated or if heated for long periods of time, becoming cloudy or "milky-

white" just prior to giving off a cloud of phosphine gas that can ignite spontaneously.

– Hypophosphorous acid solutions may become unstable if evaporation results in

concentrations above 50%.

Hypophosphorous Acid (H3PO2) (Continued)

• [Note: Law enforcement or emergency personnel who encounter suspected

containers of hypophosphorous acid should use extreme care during handling because laboratory operators often attempt to obtain a more concentrated acid by

allowing water to evaporate from the mixture.]

• Because hypophosphorous acid often is used at small methamphetaminelaboratories operated by inexperienced or careless individuals, the potential hazards

of using this method are even greater.

• The risk of fire and explosion is higher in these laboratories, where professional

laboratory equipment typically is not used to contain the phosphine gas and where

safe handling precautions are not employed.

• In addition, these laboratories often are located in homes where children are

present and may come into contact with hypophosphorous acid.

• A child can easily mistake hypophosphorous acid for any other clear liquid,

particularly if it is stored in household containers or drinking glasses.

• Skin, eye, or inhalation exposure can be extremely harmful or fatal.

Hypophosphorous Acid (H3PO2) (Continued)

• Safety Precautions

• Always wear a self-contained breathing apparatus as well as protective clothing when entering areas where hypophosphorous acid may be present.

• When in contact with metals or in a high-temperature environment,

hypophosphorous acid can break down and liberate phosphine and flammable hydrogen gas.

• Do not allow the use of open flames, open lights, matches, or smoking in or around laboratories or dumpsites where hypophosphorous acid is handled.

• In case of fire, use a self-contained positive pressure breathing apparatus and full

protective equipment.

• Use water spray, fog, foam, dry chemicals, or other reagents as may be appropriate for materials in the surrounding fire.

• Water may be used to cool the containers of hypophosphorous acid; however, use extreme care to avoid allowing water to enter the container.

• In case of spills, neutralize the spilled chemical with alkaline material (soda ash, lime), then absorb it with an inert material such as vermiculite, dry sand, or earth

and place in a chemical waste container.

• Do not use combustible materials such as sawdust.

Hypophosphorous Acid (H3PO2) (Continued)

• Legislation and Control

• In the United States hypophosphorous acid is one of 38 chemicals (or groups of chemicals) controlled under law by DEA.

• On October 17, 2001, hypophosphorous acid and its salts, along with red and white phosphorus, were officially added as List I chemicals under section 1310 of the

Code of Federal Regulations.

• List I chemicals are defined as chemicals that are used in the manufacture of a

controlled substance in violation of the Controlled Substances Act (CSA) and are

important to the manufacture of a controlled substance.

• Under the law, suppliers are required to maintain records and report receipts, sales,

imports, and exports of these chemicals to DEA.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid, red phosphorus, and white phosphorus, as well as ephedrine, are unique in that suppliers are required to report all transactions of

these chemicals, regardless of the amount.

• By contrast, the other 34 listed chemicals are only reportable after a supplier's

transactions for a chemical reach an established weight or volume threshold in a calendar month.

• In addition to reporting all transactions involving the chemical, suppliers are

expected to "know their customers" in order to prevent the diversion of these substances to methamphetamine laboratories, as it is illegal to import, export,

purchase, or sell hypophosphorous acid or any other listed chemical in the United States if it is used or intended to be used in the production of a controlled

substance.

• Chemical suppliers are held liable for selling listed chemicals if they know or suspect that the chemical will be used for illicit purposes.

Hypophosphorous Acid (H3PO2) (Continued)

• Outlook

• The use of hypophosphorous acid in the production of methamphetamine is likely

to increase, particularly in the Midwest and Southwest regions of the United States

where methamphetamine production is prevalent.

– Injuries, property damage, and deaths also will increase as a growing number of

inexperienced methamphetamine producers experiment with hypophosphorous acid.

Anhydrous Ammonia

• Anhydrous ammonia is found in fertilizer, countertop cleaner, and commercial refrigerant.

– On its own, it has a pungent, suffocating odor.

• Mixing anhydrous ammonia with other chemicals can release highly toxic gases.

– Because anhydrous ammonia seeks out water (anhydrous means “without

water”) and causes severe burns, any body part that comes into contact with it

should be flushed with water for at least 15 minutes to remove the ammoniafrom the skin.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia has extremely destructive effects on humans.

– Anhydrous ammonia gives off vapors during cooking that can burn the mouth,

throat, and lung tissue.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Anhydrous ammonia seeks water from the nearest source, including the human body (anhydrous means “without water”).

– Because of their high moisture content, EYES, LUNGS, and SKIN are at the

greatest risk of attracting the ammonia.

• When large amounts of anhydrous ammonia are inhaled, the throat swells and the

victim suffocates.

– Exposure to the vapors or liquids can cause severe burns, blindness, or death.

• Anhydrous ammonia has an IDLH (immediately dangerous to life and health) at

only 300 parts per million...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is poses MANY hazards, especially when it is placed in improper vessels and handled/transported by individuals unfamiliar with the

dangers.

• Anhydrous ammonia has a boiling point of -28 degrees below zero.

– When a vessel containing anhydrous ammonia is MOVED, the anhydrous

ammonia will reach its boiling point and pressurize.

•This pressurization can cause vessels to violently RUPTURE, or if the vessel pressurizes and does NOT rupture, the opening of the container of anhydrous

ammonia at a later time can cause RAPID, VIOLENT depressurization.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is mainly used in the U.S. as either a fertilizer or a refrigerant.

– Meth producers tend to store the anhydrous ammonia in IMPROPER/UNAPPROVED containers such as:

•Propane tanks,

• Igloo coolers, or

•Fire extinguishers.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia leaves a tell-tell sign as it flows through these UNAPPROVED

CONTAINERS – a blue or blue green discoloration on the valve.

– PAY ATTENTION to details!!!

Anhydrous Ammonia (Continued)

• Because propane cylinders (and the other unapproved containers) are NOT designed to store anhydrous ammonia, they can EXPLODE as the ammonia eats

through the walls of the cylinders.

– The valves, which take on a bluish/green color, frequently deteriorate and can cause hazardous leaks!!!

Anhydrous Ammonia (Continued)

• Do NOT touch, move, or open any kind of tank or sealed container!!!

– Be aware that propane tanks are often WEAKENED and BRITTLE due to the anhydrous ammonia and are SENSITIVE to ANY kind of movement or impact.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• These pictures show what happened to a fire extinguisher that was used to store

anhydrous ammonia…

Anhydrous Ammonia (Continued)

• Illegal drug makers often STEAL anhydrous ammonia from areas where it is stored

and used, such as farms.

• Attempted thefts have also occurred at places such as:

– Refrigeration systems holding ammonia,

– Underground pipelines carrying ammonia, and

– Rail cars transporting anhydrous ammonia.

• Often thefts are aborted when thieves are injured or overcome by the toxic gas...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia thieves had better beware!!!

• There is a new product called GloTell that farmers can add to their anhydrous

ammonia tanks…

• Meth cooks will run the risk that the GloTell additive will turn their hands bright

pink!

– This bright pink stain will fluoresce under ultraviolet light even if washed off!!!

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Also, GloTell will produce pink methamphetamine that CANNOT be bleached.

– Users who snort meth made with GloTell will find that they have PINK NOSES!

– Users who inject meth made with GloTell will see a pink stain at the point of

injection!

Sodium Carbonate (Soda Ash)

Sodium Carbonate (Soda Ash) (Continued)

Lead Acetate

Iodine

• Iodine is a natural element, and it is helpful to the body in SMALL amounts.

– However, if iodine is taken in large amounts it can become toxic.

•Extremely high does of iodine can limit the function of the thyroid.

Iodine (Continued)

Iodine (Continued)

• Iodine is bluish-black, and it has a characteristic odor, a sharp acrid taste, and it produces a violet corrosive vapor.

– The vapor is irritating to the respiratory system and eyes.

• The solid iodine irritates the eyes and may burn the skin, and it may cause severe

internal irritation and damage if ingested.

Iodine (Continued)

• Iodine is known as the “blue ingredient” in the production of meth (in the “red, white, and blue” method).

Iodine (Continued)

Iodine (Continued)

• It takes approximately 4 bottles of iodine tincture to produce 2 – 3 grams of meth.

Iodine (Continued)

Iodine (Continued)

• Iodine leaves distinctive yellow-blue or brown stains on surfaces in former methlabs.

Iodine (Continued)

Iodine (Continued)

Iodine (Continued)

• The only good thing about iodine is that it leaves yellow stains.

• If you see yellow stained coffee filters, gloves or paper towels, this could be an

indicator that you’re in a lab.

• If you see yellow stains, you can spray some starch on them.

– If they turn a purplish blue/black, it’s iodine.

• Iodine is the only substance that reacts with soluble starch to produce a purplish black color.

– The only way to get iodine vapor all over the walls is to cook meth.

Mercurous Chloride

Rock Salt

Hydrogen Chloride

• Hydrogen chloride gas is commercially available.

• Hydrogen chloride gas can also be made by mixing sulfuric acid and salt.

• Muriatic acid is simply hydrogen chloride gas suspended in water.

• Hydrogen chloride gas can be seen as a pale white smoke.

– It is a poisonous gas that can cause respiratory problems and death.

Hydrogen Chloride (Continued)

Ammonium Nitrate

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Hydriodic Acid

• Hydriodic acid is a corrosive acid that is colorless when freshly prepared.

– When hydriodic acid is exposed to light and air, it turns yellowish and brown.

• Hydriodic acid is a solution of hydrogen iodide gas in water.

• Hydriodic acid vapor is irritating to the respiratory system, skin, and eyes.

• Hydriodic acid liquid causes severe burns to the eyes and skin.

• If hydriodic acid is accidentally ingested, it can cause severe internal irritation and damage.

Hydriodic Acid (Continued)

Catalyst Chemicals

• Catalyst Chemicals:

– Chemicals which SPEED UP a reaction process and/or cause it to go to GREATER COMPLETION.

Red Phosphorus

• Red phosphorus is found ON matchboxes, in road flares, and other explosives.

– Red Phosphorus IGNITES when OVERHEATED!!!

• By combining red phosphorus and iodine, you can easily create the highly

controlled substance known as hydriodic acid (which is an essential ingredient in making meth).

– Creating 2 – 3 grams of meth requires about 4 big boxes of matches.

Red Phosphorus (Continued)

• Red phosphorous is highly flammable and if it is overheated it can become white

phosphorous…

– White phosphorous is a volatile and highly explosive substance.

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Lithium

• Lithium is used in batteries.

• Lithium seriously burns the skin upon contact.

– It also reacts VIOLENTLY with WATER and is highly explosive.

Lithium (Continued)

• Lithium reacts VIOLENTLY with WATER, and if it is splashed in the eyes during

cooking it will cause blindness.

– Lithium is extremely caustic to all body tissues.

Lithium (Continued)

Lithium (Continued)

• Lithium metal is HIGHLY water reactive and it will BURN or EXPLODE if it comes into contact with WATER!

• Because of the moisture in your skin, it will burn exposed flesh.

• Lithium metal will DEGRADE when exposed to atmospheric moisture…

– This is why meth cooks store lithium metal in a solvent prior to use.

• It is typical to see harvested lithium strips in Coleman fuel or Mineral Spirits to prevent explosions.

•Large quantities can be harvested and saved in these containers until needed

for a cook.

Lithium (Continued)

• If you see battery shells in the trashcan, on the floor, etc. – this is a VERY GOOD

indicator that you might be entering a meth lab!

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

• Lithium catches fire when in contact with water...

Solvent Chemicals

• Solvent Chemicals:

– A medium (liquid) in which a chemical operation takes place.

• Solvent chemicals (UNLIKE the precursor chemicals) CAN be

substituted/interchanged.

Ether

• Ether was once called “sweet vitriol” because of its hypnotic effect.

• Ether is a highly flammable substance that is used as an anesthetic agent –

especially in third world countries where more expensive anesthesia is not available.

– While inhaling the ether, patients could undergo complete surgical procedures while otherwise awake without feeling pain or concern.

Ether (Continued)

• Ether can be obtained from engine starting fluid.

• Ether is a solvent and it is flammable.

– It is particularly hazardous because it can cause BOTH fire and explosion.

• It has been said that a quart of ether can “level” a small house.

Ethyl Ether (Continued)

Ethyl Ether (Continued)

• Ether is VERY flammable and is HEAVIER than air.

– NEVER use ether near flames or non-sparkless motors.

– Ether is very PUNGENT – even a small evaporated amount of ether is VERY noticeable.

Acetone

• Acetone can be found in nail polish remover or paint thinner.

– It is extremely flammable.

• In the setting of a meth lab where meth is being cooked with high heat, acetone is

very dangerous.

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Toluene

• Toluene is used in brake fluid.

– When working with brake fluid (toluene), be careful not to spill it on your car

because it will eat away the paint and chrome…

• You also have to be careful using toluene around other household chemicals

because its high concentration of polyethylene glycol can cause it to ignite in a

violent fireball.

• Toluene is powerful enough to dissolve rubber.

Toluene (Continued)

• Toluene is used to form meth crystals.

– The fumes toluene releases can cause brain damage or death.

Toluene (Continued)

Toluene (Continued)

Ethanol

Isopropanol

Isopropanol (Continued)

Isopropyl Alcohol

Methanol

Methanol (Continued)

Methanol (Continued)

Benzene

Benzene (Continued)

Which of these is NOT a common ingredient in Meth?

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Methamphetamine- PowerPoint

- Chemicals and Ingredients Used to Make Meth

CJUS 240

Economic Costs of Meth

• The economic cost of methamphetamine use in the U.S. reached $23.4 billion in

2005.

– This includes the burden of addiction, premature death, drug treatment, child

care, and cleaning of lab sites.

– This figure does NOT take into account the future needs of the meth user.

Concerns with ACTIVE Meth Labs

• Danger of fire and explosion

• Chemical spills

• Inhalation of solvents, corrosives, and toxic gases

• “Booby traps”

• Waste disposal

Concerns with FORMER Meth Labs

• Vapors

• Chemical residues

• Methamphetamine residues

• Waste disposal

Equipment Used in Meth Production

• Pyrex or Corning dishes

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

• Coffee Filters

Equipment Used in Meth Production

Equipment Used in Meth Production

Basic Chemical Requirements

• In a clandestine laboratory, basic types of chemicals are necessary in order to

produce the desired drug.

– The basic types of chemicals needed are:

1) Precursor Chemicals

2) Reagent Chemicals

3) Catalyst Chemicals

4) Solvent Chemicals

List I Chemical

• The term “List I chemical” means a chemical specified by regulation of the Attorney General as a chemical that is used in manufacturing a controlled substance and is

IMPORTANT to the manufacture of the controlled substance.

• Examples of List I chemicals are:

– GBL

– Red Phosphorus

– Pseudoephedrine

List II Chemical

• The term “List II chemical” means a chemical (other than a List I chemical) specified by regulation of the Attorney General as a chemical that is USED in

manufacturing a controlled substance.

• Examples of List II chemicals are:

– Toluene

– Iodine

– Hydrochloric Acid

Precursor Chemicals

• Precursor Chemicals:

– A chemical that is ESSENTIAL to the production of a controlled substance and for which NO SUBSTITUTION can be made.

Pseudoephedrine

• Pseudoephedrine is a decongestant found in cold medicine.

– Large amounts of pseudoephedrine on its own can harm the respiratory and nervous systems, as well as the heart.

Pseudoephedrine (Continued)

• Some of the common ways used to divert products containing pseudoephedrine

include:

– “Smurfing” – making multiple purchases at different locations

– Shelf-Sweeping – the theft of all shelf stock

– Shoplifting

– Theft from wholesalers

Pseudoephedrine (Continued)

• Pseudoephedrine smurfing is a method used by some methamphetamine producers to acquire large quantities of pseudoephedrine by enlisting the assistance of several

friends or associates (often referred to as “smurfers”) to make purchases at or below the legal thresholds from multiple retail locations.

– Smurfers are often addicts who trade the pseudoephedrine for finished

methamphetamine.

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

• About 680 pseudoephedrine tablets are needed to produce one ounce of meth…

Pseudoephedrine (Continued)

Out With a Bang

An Unstable Recipe…

• Meth contains a variety of poisonous ingredients…

– Some become EVEN MORE DANGEROUS once the cooking process begins…

Common Ingredients to Make Methamphetamine

Reagent Chemicals

• Reagent Chemicals:

– Chemicals which REACT upon the precursor chemical causing it to chemicallyCHANGE.

• A reagent chemical is a chemical which is required for the synthesis of an illicit drug substance, but which is NOT incorporated into the final chemical product.

Hydrochloric Acid

• Hydrochloric acid is a highly corrosive liquid that is used to make plastic (such as PVC pipe and polyurethane).

– It can remove rust and iron-oxide from steel and is highly corrosive to human

skin.

•Hydrochloric acid makes up the majority of the gastric acid in the human

digestive fluid.

• In high concentrations, hydrochloric acid will literally eat away human flesh…

Hydrochloric Acid (Continued)

• Hydrochloric acid can be purchased from hardware stores as:

– Tile and Grout Acid Cleaner

– Muriatic Acid

– Pool Acid

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

• Hydrochloric acid is a solution of hydrogen chloride gas suspended in water.

– Hydrochloric acid is corrosive and is a light yellow liquid color from traces of iron, chlorine, and organic matter.

• Inhaling hydrochloric acid may cause coughing or choking, inflammation, and

ulceration of the respiratory tract.

• Concentrated solutions of hydrochloric acid can cause severe burns and irritate the

mucous membranes, eyes, and respiratory tract.

– Exposure to hydrochloric acid vapors may result in pulmonary edema and possibly death.

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

Sodium Hydroxide (NaOH)

• Sodium hydroxide is also called Lye.

• Sodium hydroxide is classified as a corrosive, and it is one of the main chemicals in

drain cleaner.

– It is also used in aluminum etching and to create biodiesal.

– It can burn the skin or cause blindness.

• Sodium hydroxide is used to dispose of road kill because it turns the dead bodies

into a coffee-like liquid.

Sodium Hydroxide (NaOH) (Continued)

• Drain cleaner (sodium hydroxide) is extremely corrosive, and without wearing

protection, even the smallest spill on the skin can eat through flesh…

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sulfuric Acid (H2SO4)

• Sulfuric acid is used in drain or toilet bowl cleaner as well as battery acid.

– It is another highly corrosive substance that burns the skin on contact.

Sulfuric Acid (H2SO4) (Continued)

• The product label warning for Drano® (sulfuric acid) says it all:

– DANGER: MAY BURN EYES AND SKIN ON CONTACT.

•HARMFUL IF SWALLOWED.

–Avoid contact with body and clothing.

•TOXIC GAS MAY FORM IF MIXED WITH OTHER CHEMICALS.

–If gases are released, leave immediately and ventilate area.

•FIRST AID: Give Immediately:

–EYES AND SKIN:

»Flush with water for 20 minutes.

»Remove affected clothing.

–IF SWALLOWED:

»Rinse mouth and drink a glass of water or milk.

»Do not induce vomiting.

–THEN SEEK MEDICAL AID.

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Hypophosphorous Acid (H3PO2)

• Hypophosphorous acid, which is used legally for a variety of commercial purposes,

is a chemical that increasingly is substituted for red phosphorus in the methamphetamine production process.

– The use of hypophospherous acid SIGNIFICANTLY increases the risk of fire!!!

• The federal government regulates the sale of hypophosphorous acid through registration, record keeping, reporting, and import/export requirements regardless

of the quantity being handled or distributed.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid is a colorless oily liquid that emits a SOUR odor.

– There is an extreme fire and explosion hazard if the hypophosphorous acid

comes into contact with a solvent such as acetone, toluene, or Coleman fuel.

• Hypophosphorous acid will also emit phosphine gas and the fumes can ignite.

Hypophosphorous Acid (H3PO2) (Continued)

• Although hypophosphorous acid is a List I chemical under the Controlled Substances Act, methamphetamine producers typically purchase the chemical via

the internet or from associates who also are engaged in methamphetamine

production.

– The use of hypophosphorous acid in methamphetamine production is an

EXTREMELY DANGEROUS PRACTICE because of the deadly gases that can be generated as well as the risk of fire or explosion.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid (H3PO2, also called phosphinic acid) is a strong acid that

typically is prepared as a solution of colorless, oily liquid in strengths of 50%, 30 to 32%, and 10%.

– It also is prepared in the form of salts (referred to as hypophosphite salts), particularly ammonium hypophosphite, calcium hypophosphite, iron (ferric)

hypophosphite, magnesium hypophosphite, manganese hypophosphite,

potassium hypophosphite, and sodium hypophosphite.

Hypophosphorous Acid (H3PO2) (Continued)

• Over 100 chemical firms located throughout the world produce hypophosphorous

acid.

– The People's Republic of China and India have the largest numbers of

hypophosphorous acid producers, although there are a few producers in the United States.

• There are a wide variety of uses for hypophosphorous acid and its salts in

commercial industry; however, the chemicals have no legitimate household or retail uses.

Hypophosphorous Acid (H3PO2) (Continued)

• The legitimate commercial and laboratory fields that use hypophosphorous acid and its salts include the following:

– Chemical plating

– Food preparation

– Water treatment

– Polymers (as a bleaching agent, color stabilizer, or catalyst)

– Education and research in analytical chemistry

Hypophosphorous Acid (H3PO2) (Continued)

• Chemical suppliers typically distribute hypophosphorous acid in large quantities, for example, in drums containing 275 pounds of the diluted solution.

– Hypophosphorous acid also is distributed in smaller quantities.

• One-half liter of 50% concentrate hypophosphorous acid solution can be obtained from chemical suppliers for as little as $14.

Hypophosphorous Acid (H3PO2) (Continued)

• Methamphetamine laboratory operators typically obtain small quantities of the chemical from other laboratory operators who purchase large quantities of the

chemical and repackage it for further distribution.

– According to law enforcement sources, these individuals sell hypophosphorous acid for as much as $1,000 per half-liter.

•Methamphetamine laboratory operators also purchase hypophosphorous acidvia the internet.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid and the Internet

• The internet is a source of a great deal of information regarding hypophosphorous acid.

• Popular internet sites that disseminate information about illicit drugs contain information about the chemical, including numerous recipes for home production of

methamphetamine using hypophosphorous acid.

• There also are recipes for synthesizing hypophosphorous acid from available chemicals.

• Hypophosphorous acid solutions and salts have been sold to the general public via the internet.

• The Drug Enforcement Administration (DEA) has strong concerns regarding the sale

of chemicals on the internet and has requested that any sites (such as auction sites) that allow the sale of regulated chemicals on their domains require proof of

DEA registration from their clients.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid Used in Methamphetamine Production

• Hypophosphorous acid is used in the ephedrine-pseudoephedrine reduction method

of methamphetamine production.

– It is used in the methamphetamine production process to produce hydriodic acid,

an important reagent (it reacts with the ephedrine-pseudoephedrine but does NOT become part of the finished product).

Hypophosphorous Acid (H3PO2) (Continued)

• The regulation of hydriodic acid by DEA in 1993 rendered it virtually unavailable in

the United States.

– However, methamphetamine laboratory operators discovered methods to

produce hydriodic acid using a combination of iodine in water with red phosphorus.

• Laboratory operators found that red phosphorus could be obtained easily, either

from commercial supply companies or by scraping the striker pads from matchbooks or matchboxes.

• Methamphetamine producers soon discovered that hypophosphorous acid ALSO could be used in combination with iodine and water to produce hydriodic acid.

Hypophosphorous Acid (H3PO2) (Continued)

• The practice of using hypophosphorous acid in methamphetamine production is

believed to have begun in the United States in the late 1990s when a methamphetamine producer in Colorado obtained the recipe from Australia, where

the hypophosphorous acid method is prevalent.

– This man was known as a serial cook who had a long history of

methamphetamine production.

•Over several years he trained other laboratory operators in Colorado to produce methamphetamine using hypophosphorous acid.

• As his techniques were passed on to others, the number of methamphetaminelaboratories in Colorado using hypophosphorous acid continued to increase, and the

technique was passed on to numerous methamphetamine producers in other

states.

Hypophosphorous Acid (H3PO2) (Continued)

• According to the El Paso Intelligence Center (EPIC) National Clandestine Laboratory

Seizure System, from 2000 through 2002 the number of seized methamphetaminelaboratories in the United States in which hypophosphorous acid was found

increased overall. (See Table 1.)

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid found at methamphetamine laboratories is packaged in a variety of ways.

• The chemical has been found in 1-gallon bottles of solution or in 1-pound jars of salts.

• Some hypophosphorous acid containers are labeled as "plating solution."

• Pint-sized brown glass bottles wrapped in red electrical tape also have been found to contain hypophosphorous acid; they have been discovered primarily in Colorado.

• The vast majority of hypophosphorous acid found at laboratory sites has been recovered from small toxic laboratories (STLs), those which yield gram to ounce

quantities per production cycle.

• Hypophosphorous acid has not been reported at large-scale laboratories operated by Mexican criminal groups in the United States.

Hypophosphorous Acid (H3PO2) (Continued)

• Hazards

• The iodine-hypophosphorous acid method is MORE HAZORDOUS than the iodine-

red phosphorus method, although the reaction using hypophosphorous acid is

faster and gives slightly higher yields.

– When hypophosphorous acid is used, the chemicals must be mixed together

SLOWLY in a PARTICULAR ORDER to prevent them from reacting violently.

Hypophosphorous Acid (H3PO2) (Continued)

• The combination of hypophosphorous acid with the other chemicals and with

certain metals can produce deadly phosphine gas during the initial mixing step and

can CONTINUE to produce phosphine gas for several days AFTER production has been completed…

Hypophosphorous Acid (H3PO2) (Continued)

• The iodine-hypophosphorous acid mixture has a tendency to decompose quickly when overheated or if heated for long periods of time, becoming cloudy or "milky-

white" just prior to giving off a cloud of phosphine gas that can ignite spontaneously.

– Hypophosphorous acid solutions may become unstable if evaporation results in

concentrations above 50%.

Hypophosphorous Acid (H3PO2) (Continued)

• [Note: Law enforcement or emergency personnel who encounter suspected

containers of hypophosphorous acid should use extreme care during handling because laboratory operators often attempt to obtain a more concentrated acid by

allowing water to evaporate from the mixture.]

• Because hypophosphorous acid often is used at small methamphetaminelaboratories operated by inexperienced or careless individuals, the potential hazards

of using this method are even greater.

• The risk of fire and explosion is higher in these laboratories, where professional laboratory equipment typically is not used to contain the phosphine gas and where

safe handling precautions are not employed.

• In addition, these laboratories often are located in homes where children are

present and may come into contact with hypophosphorous acid.

• A child can easily mistake hypophosphorous acid for any other clear liquid,

particularly if it is stored in household containers or drinking glasses.

• Skin, eye, or inhalation exposure can be extremely harmful or fatal.

Hypophosphorous Acid (H3PO2) (Continued)

• Safety Precautions

• Always wear a self-contained breathing apparatus as well as protective clothing when entering areas where hypophosphorous acid may be present.

• When in contact with metals or in a high-temperature environment,

hypophosphorous acid can break down and liberate phosphine and flammable hydrogen gas.

• Do not allow the use of open flames, open lights, matches, or smoking in or around laboratories or dumpsites where hypophosphorous acid is handled.

• In case of fire, use a self-contained positive pressure breathing apparatus and full

protective equipment.

• Use water spray, fog, foam, dry chemicals, or other reagents as may be

appropriate for materials in the surrounding fire.

• Water may be used to cool the containers of hypophosphorous acid; however, use extreme care to avoid allowing water to enter the container.

• In case of spills, neutralize the spilled chemical with alkaline material (soda ash, lime), then absorb it with an inert material such as vermiculite, dry sand, or earth

and place in a chemical waste container.

• Do not use combustible materials such as sawdust.

Hypophosphorous Acid (H3PO2) (Continued)

• Legislation and Control

• In the United States hypophosphorous acid is one of 38 chemicals (or groups of

chemicals) controlled under law by DEA.

• On October 17, 2001, hypophosphorous acid and its salts, along with red and white phosphorus, were officially added as List I chemicals under section 1310 of the Code of Federal Regulations.

• List I chemicals are defined as chemicals that are used in the manufacture of a

controlled substance in violation of the Controlled Substances Act (CSA) and are

important to the manufacture of a controlled substance.

• Under the law, suppliers are required to maintain records and report receipts, sales,

imports, and exports of these chemicals to DEA.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid, red phosphorus, and white phosphorus, as well as

ephedrine, are unique in that suppliers are required to report all transactions of

these chemicals, regardless of the amount.

• By contrast, the other 34 listed chemicals are only reportable after a supplier's transactions for a chemical reach an established weight or volume threshold in a calendar month.

• In addition to reporting all transactions involving the chemical, suppliers are

expected to "know their customers" in order to prevent the diversion of these substances to methamphetamine laboratories, as it is illegal to import, export,

purchase, or sell hypophosphorous acid or any other listed chemical in the United States if it is used or intended to be used in the production of a controlled

substance.

• Chemical suppliers are held liable for selling listed chemicals if they know or suspect that the chemical will be used for illicit purposes.

Hypophosphorous Acid (H3PO2) (Continued)

• Outlook

• The use of hypophosphorous acid in the production of methamphetamine is likely

to increase, particularly in the Midwest and Southwest regions of the United States

where methamphetamine production is prevalent.

– Injuries, property damage, and deaths also will increase as a growing number of

inexperienced methamphetamine producers experiment with hypophosphorous acid.

Anhydrous Ammonia

• Anhydrous ammonia is found in fertilizer, countertop cleaner, and commercial refrigerant.

– On its own, it has a pungent, suffocating odor.

• Mixing anhydrous ammonia with other chemicals can release highly toxic gases.

– Because anhydrous ammonia seeks out water (anhydrous means “without

water”) and causes severe burns, any body part that comes into contact with it

should be flushed with water for at least 15 minutes to remove the ammoniafrom the skin.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia has extremely destructive effects on humans.

– Anhydrous ammonia gives off vapors during cooking that can burn the mouth, throat, and lung tissue.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Anhydrous ammonia seeks water from the nearest source, including the human body (anhydrous means “without water”).

– Because of their high moisture content, EYES, LUNGS, and SKIN are at the

greatest risk of attracting the ammonia.

• When large amounts of anhydrous ammonia are inhaled, the throat swells and the

victim suffocates.

– Exposure to the vapors or liquids can cause severe burns, blindness, or death.

• Anhydrous ammonia has an IDLH (immediately dangerous to life and health) at

only 300 parts per million...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is poses MANY hazards, especially when it is placed in improper vessels and handled/transported by individuals unfamiliar with the

dangers.

• Anhydrous ammonia has a boiling point of -28 degrees below zero.

– When a vessel containing anhydrous ammonia is MOVED, the anhydrous

ammonia will reach its boiling point and pressurize.

•This pressurization can cause vessels to violently RUPTURE, or if the vessel pressurizes and does NOT rupture, the opening of the container of anhydrous

ammonia at a later time can cause RAPID, VIOLENT depressurization.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is mainly used in the U.S. as either a fertilizer or a refrigerant.

– Meth producers tend to store the anhydrous ammonia in IMPROPER/UNAPPROVED containers such as:

•Propane tanks,

• Igloo coolers, or

•Fire extinguishers.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia leaves a tell-tell sign as it flows through these UNAPPROVED

CONTAINERS – a blue or blue green discoloration on the valve.

– PAY ATTENTION to details!!!

Anhydrous Ammonia (Continued)

• Because propane cylinders (and the other unapproved containers) are NOT designed to store anhydrous ammonia, they can EXPLODE as the ammonia eats

through the walls of the cylinders.

– The valves, which take on a bluish/green color, frequently deteriorate and can cause hazardous leaks!!!

Anhydrous Ammonia (Continued)

• Do NOT touch, move, or open any kind of tank or sealed container!!!

– Be aware that propane tanks are often WEAKENED and BRITTLE due to the

anhydrous ammonia and are SENSITIVE to ANY kind of movement or impact.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• These pictures show what happened to a fire extinguisher that was used to store

anhydrous ammonia…

Anhydrous Ammonia (Continued)

• Illegal drug makers often STEAL anhydrous ammonia from areas where it is stored and used, such as farms.

• Attempted thefts have also occurred at places such as:

– Refrigeration systems holding ammonia,

– Underground pipelines carrying ammonia, and

– Rail cars transporting anhydrous ammonia.

• Often thefts are aborted when thieves are injured or overcome by the toxic gas...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia thieves had better beware!!!

• There is a new product called GloTell that farmers can add to their anhydrous

ammonia tanks…

• Meth cooks will run the risk that the GloTell additive will turn their hands bright

pink!

– This bright pink stain will fluoresce under ultraviolet light even if washed off!!!

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Also, GloTell will produce pink methamphetamine that CANNOT be bleached.

– Users who snort meth made with GloTell will find that they have PINK NOSES!

– Users who inject meth made with GloTell will see a pink stain at the point of

injection!

Sodium Carbonate (Soda Ash)

Sodium Carbonate (Soda Ash) (Continued)

Lead Acetate

Iodine

• Iodine is a natural element, and it is helpful to the body in SMALL amounts.

– However, if iodine is taken in large amounts it can become toxic.

•Extremely high does of iodine can limit the function of the thyroid.

Iodine (Continued)

Iodine (Continued)

• Iodine is bluish-black, and it has a characteristic odor, a sharp acrid taste, and it produces a violet corrosive vapor.

– The vapor is irritating to the respiratory system and eyes.

• The solid iodine irritates the eyes and may burn the skin, and it may cause severe

internal irritation and damage if ingested.

Iodine (Continued)

• Iodine is known as the “blue ingredient” in the production of meth (in the “red, white, and blue” method).

Iodine (Continued)

Iodine (Continued)

• It takes approximately 4 bottles of iodine tincture to produce 2 – 3 grams of meth.

Iodine (Continued)

Iodine (Continued)

• Iodine leaves distinctive yellow-blue or brown stains on surfaces in former methlabs.

Iodine (Continued)

Iodine (Continued)

Iodine (Continued)

• The only good thing about iodine is that it leaves yellow stains.

• If you see yellow stained coffee filters, gloves or paper towels, this could be an

indicator that you’re in a lab.

• If you see yellow stains, you can spray some starch on them.

– If they turn a purplish blue/black, it’s iodine.

• Iodine is the only substance that reacts with soluble starch to produce a purplish black color.

– The only way to get iodine vapor all over the walls is to cook meth.

Mercurous Chloride

Rock Salt

Hydrogen Chloride

• Hydrogen chloride gas is commercially available.

• Hydrogen chloride gas can also be made by mixing sulfuric acid and salt.

• Muriatic acid is simply hydrogen chloride gas suspended in water.

• Hydrogen chloride gas can be seen as a pale white smoke.

– It is a poisonous gas that can cause respiratory problems and death.

Hydrogen Chloride (Continued)

Ammonium Nitrate

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Hydriodic Acid

• Hydriodic acid is a corrosive acid that is colorless when freshly prepared.

– When hydriodic acid is exposed to light and air, it turns yellowish and brown.

• Hydriodic acid is a solution of hydrogen iodide gas in water.

• Hydriodic acid vapor is irritating to the respiratory system, skin, and eyes.

• Hydriodic acid liquid causes severe burns to the eyes and skin.

• If hydriodic acid is accidentally ingested, it can cause severe internal irritation and

damage.

Hydriodic Acid (Continued)

Catalyst Chemicals

• Catalyst Chemicals:

– Chemicals which SPEED UP a reaction process and/or cause it to go to GREATER COMPLETION.

Red Phosphorus

• Red phosphorus is found ON matchboxes, in road flares, and other explosives.

– Red Phosphorus IGNITES when OVERHEATED!!!

• By combining red phosphorus and iodine, you can easily create the highly controlled substance known as hydriodic acid (which is an essential ingredient in making meth).

– Creating 2 – 3 grams of meth requires about 4 big boxes of matches.

Red Phosphorus (Continued)

• Red phosphorous is highly flammable and if it is overheated it can become white

phosphorous…

– White phosphorous is a volatile and highly explosive substance.

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Lithium

• Lithium is used in batteries.

• Lithium seriously burns the skin upon contact.

– It also reacts VIOLENTLY with WATER and is highly explosive.

Lithium (Continued)

• Lithium reacts VIOLENTLY with WATER, and if it is splashed in the eyes during

cooking it will cause blindness.

– Lithium is extremely caustic to all body tissues.

Lithium (Continued)

Lithium (Continued)

• Lithium metal is HIGHLY water reactive and it will BURN or EXPLODE if it comes into contact with WATER!

• Because of the moisture in your skin, it will burn exposed flesh.

• Lithium metal will DEGRADE when exposed to atmospheric moisture…

– This is why meth cooks store lithium metal in a solvent prior to use.

• It is typical to see harvested lithium strips in Coleman fuel or Mineral Spirits to prevent explosions.

•Large quantities can be harvested and saved in these containers until needed

for a cook.

Lithium (Continued)

• If you see battery shells in the trashcan, on the floor, etc. – this is a VERY GOOD

indicator that you might be entering a meth lab!

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

• Lithium catches fire when in contact with water...

Solvent Chemicals

• Solvent Chemicals:

– A medium (liquid) in which a chemical operation takes place.

• Solvent chemicals (UNLIKE the precursor chemicals) CAN be

substituted/interchanged.

Ether

• Ether was once called “sweet vitriol” because of its hypnotic effect.

• Ether is a highly flammable substance that is used as an anesthetic agent –

especially in third world countries where more expensive anesthesia is not available.

– While inhaling the ether, patients could undergo complete surgical procedures while otherwise awake without feeling pain or concern.

Ether (Continued)

• Ether can be obtained from engine starting fluid.

• Ether is a solvent and it is flammable.

– It is particularly hazardous because it can cause BOTH fire and explosion.

• It has been said that a quart of ether can “level” a small house.

Ethyl Ether (Continued)

Ethyl Ether (Continued)

• Ether is VERY flammable and is HEAVIER than air.

– NEVER use ether near flames or non-sparkless motors.

– Ether is very PUNGENT – even a small evaporated amount of ether is VERY noticeable.

Acetone

• Acetone can be found in nail polish remover or paint thinner.

– It is extremely flammable.

• In the setting of a meth lab where meth is being cooked with high heat, acetone is

very dangerous.

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Toluene

• Toluene is used in brake fluid.

– When working with brake fluid (toluene), be careful not to spill it on your car

because it will eat away the paint and chrome…

• You also have to be careful using toluene around other household chemicals

because its high concentration of polyethylene glycol can cause it to ignite in a

violent fireball.

• Toluene is powerful enough to dissolve rubber.

Toluene (Continued)

• Toluene is used to form meth crystals.

– The fumes toluene releases can cause brain damage or death.

Toluene (Continued)

Toluene (Continued)

Ethanol

Isopropanol

Isopropanol (Continued)

Isopropyl Alcohol

Methanol

Methanol (Continued)

Methanol (Continued)

Benzene

Benzene (Continued)

Which of these is NOT a common ingredient in Meth?

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Page 4: Methamphetamine - PowerPoint - Chemicals and Ingredients ... · 2/5/2014 1 Methamphetamine - PowerPoint - Chemicals and Ingredients Used to Make Meth CJUS 240 Economic Costs of Meth

2/5/2014

4

Methamphetamine- PowerPoint

- Chemicals and Ingredients Used to Make Meth

CJUS 240

Economic Costs of Meth

• The economic cost of methamphetamine use in the U.S. reached $23.4 billion in

2005.

– This includes the burden of addiction, premature death, drug treatment, child

care, and cleaning of lab sites.

– This figure does NOT take into account the future needs of the meth user.

Concerns with ACTIVE Meth Labs

• Danger of fire and explosion

• Chemical spills

• Inhalation of solvents, corrosives, and toxic gases

• “Booby traps”

• Waste disposal

Concerns with FORMER Meth Labs

• Vapors

• Chemical residues

• Methamphetamine residues

• Waste disposal

Equipment Used in Meth Production

• Pyrex or Corning dishes

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

• Coffee Filters

Equipment Used in Meth Production

Equipment Used in Meth Production

Basic Chemical Requirements

• In a clandestine laboratory, basic types of chemicals are necessary in order to

produce the desired drug.

– The basic types of chemicals needed are:

1) Precursor Chemicals

2) Reagent Chemicals

3) Catalyst Chemicals

4) Solvent Chemicals

List I Chemical

• The term “List I chemical” means a chemical specified by regulation of the Attorney General as a chemical that is used in manufacturing a controlled substance and is

IMPORTANT to the manufacture of the controlled substance.

• Examples of List I chemicals are:

– GBL

– Red Phosphorus

– Pseudoephedrine

List II Chemical

• The term “List II chemical” means a chemical (other than a List I chemical) specified by regulation of the Attorney General as a chemical that is USED in

manufacturing a controlled substance.

• Examples of List II chemicals are:

– Toluene

– Iodine

– Hydrochloric Acid

Precursor Chemicals

• Precursor Chemicals:

– A chemical that is ESSENTIAL to the production of a controlled substance and for

which NO SUBSTITUTION can be made.

Pseudoephedrine

• Pseudoephedrine is a decongestant found in cold medicine.

– Large amounts of pseudoephedrine on its own can harm the respiratory and nervous systems, as well as the heart.

Pseudoephedrine (Continued)

• Some of the common ways used to divert products containing pseudoephedrine

include:

– “Smurfing” – making multiple purchases at different locations

– Shelf-Sweeping – the theft of all shelf stock

– Shoplifting

– Theft from wholesalers

Pseudoephedrine (Continued)

• Pseudoephedrine smurfing is a method used by some methamphetamine producers to acquire large quantities of pseudoephedrine by enlisting the assistance of several

friends or associates (often referred to as “smurfers”) to make purchases at or below the legal thresholds from multiple retail locations.

– Smurfers are often addicts who trade the pseudoephedrine for finished

methamphetamine.

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

• About 680 pseudoephedrine tablets are needed to produce one ounce of meth…

Pseudoephedrine (Continued)

Out With a Bang

An Unstable Recipe…

• Meth contains a variety of poisonous ingredients…

– Some become EVEN MORE DANGEROUS once the cooking process begins…

Common Ingredients to Make Methamphetamine

Reagent Chemicals

• Reagent Chemicals:

– Chemicals which REACT upon the precursor chemical causing it to chemicallyCHANGE.

• A reagent chemical is a chemical which is required for the synthesis of an illicit drug substance, but which is NOT incorporated into the final chemical product.

Hydrochloric Acid

• Hydrochloric acid is a highly corrosive liquid that is used to make plastic (such as PVC pipe and polyurethane).

– It can remove rust and iron-oxide from steel and is highly corrosive to human skin.

•Hydrochloric acid makes up the majority of the gastric acid in the human

digestive fluid.

• In high concentrations, hydrochloric acid will literally eat away human flesh…

Hydrochloric Acid (Continued)

• Hydrochloric acid can be purchased from hardware stores as:

– Tile and Grout Acid Cleaner

– Muriatic Acid

– Pool Acid

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

• Hydrochloric acid is a solution of hydrogen chloride gas suspended in water.

– Hydrochloric acid is corrosive and is a light yellow liquid color from traces of iron, chlorine, and organic matter.

• Inhaling hydrochloric acid may cause coughing or choking, inflammation, and

ulceration of the respiratory tract.

• Concentrated solutions of hydrochloric acid can cause severe burns and irritate the

mucous membranes, eyes, and respiratory tract.

– Exposure to hydrochloric acid vapors may result in pulmonary edema and

possibly death.

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

Sodium Hydroxide (NaOH)

• Sodium hydroxide is also called Lye.

• Sodium hydroxide is classified as a corrosive, and it is one of the main chemicals in

drain cleaner.

– It is also used in aluminum etching and to create biodiesal.

– It can burn the skin or cause blindness.

• Sodium hydroxide is used to dispose of road kill because it turns the dead bodies

into a coffee-like liquid.

Sodium Hydroxide (NaOH) (Continued)

• Drain cleaner (sodium hydroxide) is extremely corrosive, and without wearing

protection, even the smallest spill on the skin can eat through flesh…

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sulfuric Acid (H2SO4)

• Sulfuric acid is used in drain or toilet bowl cleaner as well as battery acid.

– It is another highly corrosive substance that burns the skin on contact.

Sulfuric Acid (H2SO4) (Continued)

• The product label warning for Drano® (sulfuric acid) says it all:

– DANGER: MAY BURN EYES AND SKIN ON CONTACT.

•HARMFUL IF SWALLOWED.

–Avoid contact with body and clothing.

•TOXIC GAS MAY FORM IF MIXED WITH OTHER CHEMICALS.

–If gases are released, leave immediately and ventilate area.

•FIRST AID: Give Immediately:

–EYES AND SKIN:

»Flush with water for 20 minutes.

»Remove affected clothing.

–IF SWALLOWED:

»Rinse mouth and drink a glass of water or milk.

»Do not induce vomiting.

–THEN SEEK MEDICAL AID.

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Hypophosphorous Acid (H3PO2)

• Hypophosphorous acid, which is used legally for a variety of commercial purposes,

is a chemical that increasingly is substituted for red phosphorus in the methamphetamine production process.

– The use of hypophospherous acid SIGNIFICANTLY increases the risk of fire!!!

• The federal government regulates the sale of hypophosphorous acid through registration, record keeping, reporting, and import/export requirements regardless

of the quantity being handled or distributed.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid is a colorless oily liquid that emits a SOUR odor.

– There is an extreme fire and explosion hazard if the hypophosphorous acid

comes into contact with a solvent such as acetone, toluene, or Coleman fuel.

• Hypophosphorous acid will also emit phosphine gas and the fumes can ignite.

Hypophosphorous Acid (H3PO2) (Continued)

• Although hypophosphorous acid is a List I chemical under the Controlled Substances Act, methamphetamine producers typically purchase the chemical via

the internet or from associates who also are engaged in methamphetamine

production.

– The use of hypophosphorous acid in methamphetamine production is an

EXTREMELY DANGEROUS PRACTICE because of the deadly gases that can be generated as well as the risk of fire or explosion.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid (H3PO2, also called phosphinic acid) is a strong acid that

typically is prepared as a solution of colorless, oily liquid in strengths of 50%, 30 to 32%, and 10%.

– It also is prepared in the form of salts (referred to as hypophosphite salts), particularly ammonium hypophosphite, calcium hypophosphite, iron (ferric)

hypophosphite, magnesium hypophosphite, manganese hypophosphite,

potassium hypophosphite, and sodium hypophosphite.

Hypophosphorous Acid (H3PO2) (Continued)

• Over 100 chemical firms located throughout the world produce hypophosphorous

acid.

– The People's Republic of China and India have the largest numbers of

hypophosphorous acid producers, although there are a few producers in the United States.

• There are a wide variety of uses for hypophosphorous acid and its salts in commercial industry; however, the chemicals have no legitimate household or retail uses.

Hypophosphorous Acid (H3PO2) (Continued)

• The legitimate commercial and laboratory fields that use hypophosphorous acid and its salts include the following:

– Chemical plating

– Food preparation

– Water treatment

– Polymers (as a bleaching agent, color stabilizer, or catalyst)

– Education and research in analytical chemistry

Hypophosphorous Acid (H3PO2) (Continued)

• Chemical suppliers typically distribute hypophosphorous acid in large quantities, for example, in drums containing 275 pounds of the diluted solution.

– Hypophosphorous acid also is distributed in smaller quantities.

• One-half liter of 50% concentrate hypophosphorous acid solution can be obtained from chemical suppliers for as little as $14.

Hypophosphorous Acid (H3PO2) (Continued)

• Methamphetamine laboratory operators typically obtain small quantities of the chemical from other laboratory operators who purchase large quantities of the

chemical and repackage it for further distribution.

– According to law enforcement sources, these individuals sell hypophosphorous acid for as much as $1,000 per half-liter.

•Methamphetamine laboratory operators also purchase hypophosphorous acidvia the internet.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid and the Internet

• The internet is a source of a great deal of information regarding hypophosphorous acid.

• Popular internet sites that disseminate information about illicit drugs contain information about the chemical, including numerous recipes for home production of

methamphetamine using hypophosphorous acid.

• There also are recipes for synthesizing hypophosphorous acid from available chemicals.

• Hypophosphorous acid solutions and salts have been sold to the general public via the internet.

• The Drug Enforcement Administration (DEA) has strong concerns regarding the sale

of chemicals on the internet and has requested that any sites (such as auction sites) that allow the sale of regulated chemicals on their domains require proof of

DEA registration from their clients.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid Used in Methamphetamine Production

• Hypophosphorous acid is used in the ephedrine-pseudoephedrine reduction method

of methamphetamine production.

– It is used in the methamphetamine production process to produce hydriodic acid,

an important reagent (it reacts with the ephedrine-pseudoephedrine but does NOT become part of the finished product).

Hypophosphorous Acid (H3PO2) (Continued)

• The regulation of hydriodic acid by DEA in 1993 rendered it virtually unavailable in

the United States.

– However, methamphetamine laboratory operators discovered methods to

produce hydriodic acid using a combination of iodine in water with red phosphorus.

• Laboratory operators found that red phosphorus could be obtained easily, either

from commercial supply companies or by scraping the striker pads from matchbooks or matchboxes.

• Methamphetamine producers soon discovered that hypophosphorous acid ALSO could be used in combination with iodine and water to produce hydriodic acid.

Hypophosphorous Acid (H3PO2) (Continued)

• The practice of using hypophosphorous acid in methamphetamine production is

believed to have begun in the United States in the late 1990s when a methamphetamine producer in Colorado obtained the recipe from Australia, where

the hypophosphorous acid method is prevalent.

– This man was known as a serial cook who had a long history of methamphetamine production.

•Over several years he trained other laboratory operators in Colorado to produce methamphetamine using hypophosphorous acid.

• As his techniques were passed on to others, the number of methamphetaminelaboratories in Colorado using hypophosphorous acid continued to increase, and the

technique was passed on to numerous methamphetamine producers in other

states.

Hypophosphorous Acid (H3PO2) (Continued)

• According to the El Paso Intelligence Center (EPIC) National Clandestine Laboratory

Seizure System, from 2000 through 2002 the number of seized methamphetaminelaboratories in the United States in which hypophosphorous acid was found increased overall. (See Table 1.)

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid found at methamphetamine laboratories is packaged in a variety of ways.

• The chemical has been found in 1-gallon bottles of solution or in 1-pound jars of salts.

• Some hypophosphorous acid containers are labeled as "plating solution."

• Pint-sized brown glass bottles wrapped in red electrical tape also have been found to contain hypophosphorous acid; they have been discovered primarily in Colorado.

• The vast majority of hypophosphorous acid found at laboratory sites has been recovered from small toxic laboratories (STLs), those which yield gram to ounce quantities per production cycle.

• Hypophosphorous acid has not been reported at large-scale laboratories operated by Mexican criminal groups in the United States.

Hypophosphorous Acid (H3PO2) (Continued)

• Hazards

• The iodine-hypophosphorous acid method is MORE HAZORDOUS than the iodine-

red phosphorus method, although the reaction using hypophosphorous acid is

faster and gives slightly higher yields.

– When hypophosphorous acid is used, the chemicals must be mixed together

SLOWLY in a PARTICULAR ORDER to prevent them from reacting violently.

Hypophosphorous Acid (H3PO2) (Continued)

• The combination of hypophosphorous acid with the other chemicals and with

certain metals can produce deadly phosphine gas during the initial mixing step and

can CONTINUE to produce phosphine gas for several days AFTER production has been completed…

Hypophosphorous Acid (H3PO2) (Continued)

• The iodine-hypophosphorous acid mixture has a tendency to decompose quickly when overheated or if heated for long periods of time, becoming cloudy or "milky-

white" just prior to giving off a cloud of phosphine gas that can ignite spontaneously.

– Hypophosphorous acid solutions may become unstable if evaporation results in concentrations above 50%.

Hypophosphorous Acid (H3PO2) (Continued)

• [Note: Law enforcement or emergency personnel who encounter suspected

containers of hypophosphorous acid should use extreme care during handling because laboratory operators often attempt to obtain a more concentrated acid by

allowing water to evaporate from the mixture.]

• Because hypophosphorous acid often is used at small methamphetaminelaboratories operated by inexperienced or careless individuals, the potential hazards

of using this method are even greater.

• The risk of fire and explosion is higher in these laboratories, where professional

laboratory equipment typically is not used to contain the phosphine gas and where safe handling precautions are not employed.

• In addition, these laboratories often are located in homes where children are

present and may come into contact with hypophosphorous acid.

• A child can easily mistake hypophosphorous acid for any other clear liquid,

particularly if it is stored in household containers or drinking glasses.

• Skin, eye, or inhalation exposure can be extremely harmful or fatal.

Hypophosphorous Acid (H3PO2) (Continued)

• Safety Precautions

• Always wear a self-contained breathing apparatus as well as protective clothing when entering areas where hypophosphorous acid may be present.

• When in contact with metals or in a high-temperature environment, hypophosphorous acid can break down and liberate phosphine and flammable hydrogen gas.

• Do not allow the use of open flames, open lights, matches, or smoking in or around laboratories or dumpsites where hypophosphorous acid is handled.

• In case of fire, use a self-contained positive pressure breathing apparatus and full

protective equipment.

• Use water spray, fog, foam, dry chemicals, or other reagents as may be

appropriate for materials in the surrounding fire.

• Water may be used to cool the containers of hypophosphorous acid; however, use extreme care to avoid allowing water to enter the container.

• In case of spills, neutralize the spilled chemical with alkaline material (soda ash, lime), then absorb it with an inert material such as vermiculite, dry sand, or earth

and place in a chemical waste container.

• Do not use combustible materials such as sawdust.

Hypophosphorous Acid (H3PO2) (Continued)

• Legislation and Control

• In the United States hypophosphorous acid is one of 38 chemicals (or groups of

chemicals) controlled under law by DEA.

• On October 17, 2001, hypophosphorous acid and its salts, along with red and white phosphorus, were officially added as List I chemicals under section 1310 of the

Code of Federal Regulations.

• List I chemicals are defined as chemicals that are used in the manufacture of a

controlled substance in violation of the Controlled Substances Act (CSA) and are

important to the manufacture of a controlled substance.

• Under the law, suppliers are required to maintain records and report receipts, sales,

imports, and exports of these chemicals to DEA.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid, red phosphorus, and white phosphorus, as well as

ephedrine, are unique in that suppliers are required to report all transactions of

these chemicals, regardless of the amount.

• By contrast, the other 34 listed chemicals are only reportable after a supplier's

transactions for a chemical reach an established weight or volume threshold in a calendar month.

• In addition to reporting all transactions involving the chemical, suppliers are

expected to "know their customers" in order to prevent the diversion of these substances to methamphetamine laboratories, as it is illegal to import, export,

purchase, or sell hypophosphorous acid or any other listed chemical in the United States if it is used or intended to be used in the production of a controlled

substance.

• Chemical suppliers are held liable for selling listed chemicals if they know or suspect that the chemical will be used for illicit purposes.

Hypophosphorous Acid (H3PO2) (Continued)

• Outlook

• The use of hypophosphorous acid in the production of methamphetamine is likely

to increase, particularly in the Midwest and Southwest regions of the United States

where methamphetamine production is prevalent.

– Injuries, property damage, and deaths also will increase as a growing number of

inexperienced methamphetamine producers experiment with hypophosphorous acid.

Anhydrous Ammonia

• Anhydrous ammonia is found in fertilizer, countertop cleaner, and commercial refrigerant.

– On its own, it has a pungent, suffocating odor.

• Mixing anhydrous ammonia with other chemicals can release highly toxic gases.

– Because anhydrous ammonia seeks out water (anhydrous means “without

water”) and causes severe burns, any body part that comes into contact with it

should be flushed with water for at least 15 minutes to remove the ammoniafrom the skin.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia has extremely destructive effects on humans.

– Anhydrous ammonia gives off vapors during cooking that can burn the mouth,

throat, and lung tissue.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Anhydrous ammonia seeks water from the nearest source, including the human body (anhydrous means “without water”).

– Because of their high moisture content, EYES, LUNGS, and SKIN are at the

greatest risk of attracting the ammonia.

• When large amounts of anhydrous ammonia are inhaled, the throat swells and the

victim suffocates.

– Exposure to the vapors or liquids can cause severe burns, blindness, or death.

• Anhydrous ammonia has an IDLH (immediately dangerous to life and health) at

only 300 parts per million...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is poses MANY hazards, especially when it is placed in improper vessels and handled/transported by individuals unfamiliar with the dangers.

• Anhydrous ammonia has a boiling point of -28 degrees below zero.

– When a vessel containing anhydrous ammonia is MOVED, the anhydrous

ammonia will reach its boiling point and pressurize.

•This pressurization can cause vessels to violently RUPTURE, or if the vessel pressurizes and does NOT rupture, the opening of the container of anhydrous

ammonia at a later time can cause RAPID, VIOLENT depressurization.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is mainly used in the U.S. as either a fertilizer or a refrigerant.

– Meth producers tend to store the anhydrous ammonia in IMPROPER/UNAPPROVED containers such as:

•Propane tanks,

• Igloo coolers, or

•Fire extinguishers.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia leaves a tell-tell sign as it flows through these UNAPPROVED

CONTAINERS – a blue or blue green discoloration on the valve.

– PAY ATTENTION to details!!!

Anhydrous Ammonia (Continued)

• Because propane cylinders (and the other unapproved containers) are NOT designed to store anhydrous ammonia, they can EXPLODE as the ammonia eats

through the walls of the cylinders.

– The valves, which take on a bluish/green color, frequently deteriorate and can cause hazardous leaks!!!

Anhydrous Ammonia (Continued)

• Do NOT touch, move, or open any kind of tank or sealed container!!!

– Be aware that propane tanks are often WEAKENED and BRITTLE due to the

anhydrous ammonia and are SENSITIVE to ANY kind of movement or impact.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• These pictures show what happened to a fire extinguisher that was used to store

anhydrous ammonia…

Anhydrous Ammonia (Continued)

• Illegal drug makers often STEAL anhydrous ammonia from areas where it is stored

and used, such as farms.

• Attempted thefts have also occurred at places such as:

– Refrigeration systems holding ammonia,

– Underground pipelines carrying ammonia, and

– Rail cars transporting anhydrous ammonia.

• Often thefts are aborted when thieves are injured or overcome by the toxic gas...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia thieves had better beware!!!

• There is a new product called GloTell that farmers can add to their anhydrous

ammonia tanks…

• Meth cooks will run the risk that the GloTell additive will turn their hands bright

pink!

– This bright pink stain will fluoresce under ultraviolet light even if washed off!!!

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Also, GloTell will produce pink methamphetamine that CANNOT be bleached.

– Users who snort meth made with GloTell will find that they have PINK NOSES!

– Users who inject meth made with GloTell will see a pink stain at the point of

injection!

Sodium Carbonate (Soda Ash)

Sodium Carbonate (Soda Ash) (Continued)

Lead Acetate

Iodine

• Iodine is a natural element, and it is helpful to the body in SMALL amounts.

– However, if iodine is taken in large amounts it can become toxic.

•Extremely high does of iodine can limit the function of the thyroid.

Iodine (Continued)

Iodine (Continued)

• Iodine is bluish-black, and it has a characteristic odor, a sharp acrid taste, and it produces a violet corrosive vapor.

– The vapor is irritating to the respiratory system and eyes.

• The solid iodine irritates the eyes and may burn the skin, and it may cause severe internal irritation and damage if ingested.

Iodine (Continued)

• Iodine is known as the “blue ingredient” in the production of meth (in the “red, white, and blue” method).

Iodine (Continued)

Iodine (Continued)

• It takes approximately 4 bottles of iodine tincture to produce 2 – 3 grams of meth.

Iodine (Continued)

Iodine (Continued)

• Iodine leaves distinctive yellow-blue or brown stains on surfaces in former methlabs.

Iodine (Continued)

Iodine (Continued)

Iodine (Continued)

• The only good thing about iodine is that it leaves yellow stains.

• If you see yellow stained coffee filters, gloves or paper towels, this could be an indicator that you’re in a lab.

• If you see yellow stains, you can spray some starch on them.

– If they turn a purplish blue/black, it’s iodine.

• Iodine is the only substance that reacts with soluble starch to produce a purplish black color.

– The only way to get iodine vapor all over the walls is to cook meth.

Mercurous Chloride

Rock Salt

Hydrogen Chloride

• Hydrogen chloride gas is commercially available.

• Hydrogen chloride gas can also be made by mixing sulfuric acid and salt.

• Muriatic acid is simply hydrogen chloride gas suspended in water.

• Hydrogen chloride gas can be seen as a pale white smoke.

– It is a poisonous gas that can cause respiratory problems and death.

Hydrogen Chloride (Continued)

Ammonium Nitrate

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Hydriodic Acid

• Hydriodic acid is a corrosive acid that is colorless when freshly prepared.

– When hydriodic acid is exposed to light and air, it turns yellowish and brown.

• Hydriodic acid is a solution of hydrogen iodide gas in water.

• Hydriodic acid vapor is irritating to the respiratory system, skin, and eyes.

• Hydriodic acid liquid causes severe burns to the eyes and skin.

• If hydriodic acid is accidentally ingested, it can cause severe internal irritation and

damage.

Hydriodic Acid (Continued)

Catalyst Chemicals

• Catalyst Chemicals:

– Chemicals which SPEED UP a reaction process and/or cause it to go to GREATER COMPLETION.

Red Phosphorus

• Red phosphorus is found ON matchboxes, in road flares, and other explosives.

– Red Phosphorus IGNITES when OVERHEATED!!!

• By combining red phosphorus and iodine, you can easily create the highly

controlled substance known as hydriodic acid (which is an essential ingredient in making meth).

– Creating 2 – 3 grams of meth requires about 4 big boxes of matches.

Red Phosphorus (Continued)

• Red phosphorous is highly flammable and if it is overheated it can become white

phosphorous…

– White phosphorous is a volatile and highly explosive substance.

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Lithium

• Lithium is used in batteries.

• Lithium seriously burns the skin upon contact.

– It also reacts VIOLENTLY with WATER and is highly explosive.

Lithium (Continued)

• Lithium reacts VIOLENTLY with WATER, and if it is splashed in the eyes during

cooking it will cause blindness.

– Lithium is extremely caustic to all body tissues.

Lithium (Continued)

Lithium (Continued)

• Lithium metal is HIGHLY water reactive and it will BURN or EXPLODE if it comes into contact with WATER!

• Because of the moisture in your skin, it will burn exposed flesh.

• Lithium metal will DEGRADE when exposed to atmospheric moisture…

– This is why meth cooks store lithium metal in a solvent prior to use.

• It is typical to see harvested lithium strips in Coleman fuel or Mineral Spirits to prevent explosions.

•Large quantities can be harvested and saved in these containers until needed

for a cook.

Lithium (Continued)

• If you see battery shells in the trashcan, on the floor, etc. – this is a VERY GOOD

indicator that you might be entering a meth lab!

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

• Lithium catches fire when in contact with water...

Solvent Chemicals

• Solvent Chemicals:

– A medium (liquid) in which a chemical operation takes place.

• Solvent chemicals (UNLIKE the precursor chemicals) CAN be substituted/interchanged.

Ether

• Ether was once called “sweet vitriol” because of its hypnotic effect.

• Ether is a highly flammable substance that is used as an anesthetic agent –

especially in third world countries where more expensive anesthesia is not available.

– While inhaling the ether, patients could undergo complete surgical procedures while otherwise awake without feeling pain or concern.

Ether (Continued)

• Ether can be obtained from engine starting fluid.

• Ether is a solvent and it is flammable.

– It is particularly hazardous because it can cause BOTH fire and explosion.

• It has been said that a quart of ether can “level” a small house.

Ethyl Ether (Continued)

Ethyl Ether (Continued)

• Ether is VERY flammable and is HEAVIER than air.

– NEVER use ether near flames or non-sparkless motors.

– Ether is very PUNGENT – even a small evaporated amount of ether is VERY noticeable.

Acetone

• Acetone can be found in nail polish remover or paint thinner.

– It is extremely flammable.

• In the setting of a meth lab where meth is being cooked with high heat, acetone is

very dangerous.

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Toluene

• Toluene is used in brake fluid.

– When working with brake fluid (toluene), be careful not to spill it on your car

because it will eat away the paint and chrome…

• You also have to be careful using toluene around other household chemicals

because its high concentration of polyethylene glycol can cause it to ignite in a

violent fireball.

• Toluene is powerful enough to dissolve rubber.

Toluene (Continued)

• Toluene is used to form meth crystals.

– The fumes toluene releases can cause brain damage or death.

Toluene (Continued)

Toluene (Continued)

Ethanol

Isopropanol

Isopropanol (Continued)

Isopropyl Alcohol

Methanol

Methanol (Continued)

Methanol (Continued)

Benzene

Benzene (Continued)

Which of these is NOT a common ingredient in Meth?

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Methamphetamine- PowerPoint

- Chemicals and Ingredients Used to Make Meth

CJUS 240

Economic Costs of Meth

• The economic cost of methamphetamine use in the U.S. reached $23.4 billion in

2005.

– This includes the burden of addiction, premature death, drug treatment, child

care, and cleaning of lab sites.

– This figure does NOT take into account the future needs of the meth user.

Concerns with ACTIVE Meth Labs

• Danger of fire and explosion

• Chemical spills

• Inhalation of solvents, corrosives, and toxic gases

• “Booby traps”

• Waste disposal

Concerns with FORMER Meth Labs

• Vapors

• Chemical residues

• Methamphetamine residues

• Waste disposal

Equipment Used in Meth Production

• Pyrex or Corning dishes

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

• Coffee Filters

Equipment Used in Meth Production

Equipment Used in Meth Production

Basic Chemical Requirements

• In a clandestine laboratory, basic types of chemicals are necessary in order to

produce the desired drug.

– The basic types of chemicals needed are:

1) Precursor Chemicals

2) Reagent Chemicals

3) Catalyst Chemicals

4) Solvent Chemicals

List I Chemical

• The term “List I chemical” means a chemical specified by regulation of the Attorney General as a chemical that is used in manufacturing a controlled substance and is

IMPORTANT to the manufacture of the controlled substance.

• Examples of List I chemicals are:

– GBL

– Red Phosphorus

– Pseudoephedrine

List II Chemical

• The term “List II chemical” means a chemical (other than a List I chemical) specified by regulation of the Attorney General as a chemical that is USED in

manufacturing a controlled substance.

• Examples of List II chemicals are:

– Toluene

– Iodine

– Hydrochloric Acid

Precursor Chemicals

• Precursor Chemicals:

– A chemical that is ESSENTIAL to the production of a controlled substance and for

which NO SUBSTITUTION can be made.

Pseudoephedrine

• Pseudoephedrine is a decongestant found in cold medicine.

– Large amounts of pseudoephedrine on its own can harm the respiratory and nervous systems, as well as the heart.

Pseudoephedrine (Continued)

• Some of the common ways used to divert products containing pseudoephedrine

include:

– “Smurfing” – making multiple purchases at different locations

– Shelf-Sweeping – the theft of all shelf stock

– Shoplifting

– Theft from wholesalers

Pseudoephedrine (Continued)

• Pseudoephedrine smurfing is a method used by some methamphetamine producers to acquire large quantities of pseudoephedrine by enlisting the assistance of several

friends or associates (often referred to as “smurfers”) to make purchases at or below the legal thresholds from multiple retail locations.

– Smurfers are often addicts who trade the pseudoephedrine for finished

methamphetamine.

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

• About 680 pseudoephedrine tablets are needed to produce one ounce of meth…

Pseudoephedrine (Continued)

Out With a Bang

An Unstable Recipe…

• Meth contains a variety of poisonous ingredients…

– Some become EVEN MORE DANGEROUS once the cooking process begins…

Common Ingredients to Make Methamphetamine

Reagent Chemicals

• Reagent Chemicals:

– Chemicals which REACT upon the precursor chemical causing it to chemicallyCHANGE.

• A reagent chemical is a chemical which is required for the synthesis of an illicit drug substance, but which is NOT incorporated into the final chemical product.

Hydrochloric Acid

• Hydrochloric acid is a highly corrosive liquid that is used to make plastic (such as PVC pipe and polyurethane).

– It can remove rust and iron-oxide from steel and is highly corrosive to human

skin.

•Hydrochloric acid makes up the majority of the gastric acid in the human

digestive fluid.

• In high concentrations, hydrochloric acid will literally eat away human flesh…

Hydrochloric Acid (Continued)

• Hydrochloric acid can be purchased from hardware stores as:

– Tile and Grout Acid Cleaner

– Muriatic Acid

– Pool Acid

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

• Hydrochloric acid is a solution of hydrogen chloride gas suspended in water.

– Hydrochloric acid is corrosive and is a light yellow liquid color from traces of iron, chlorine, and organic matter.

• Inhaling hydrochloric acid may cause coughing or choking, inflammation, and

ulceration of the respiratory tract.

• Concentrated solutions of hydrochloric acid can cause severe burns and irritate the

mucous membranes, eyes, and respiratory tract.

– Exposure to hydrochloric acid vapors may result in pulmonary edema and

possibly death.

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

Sodium Hydroxide (NaOH)

• Sodium hydroxide is also called Lye.

• Sodium hydroxide is classified as a corrosive, and it is one of the main chemicals in

drain cleaner.

– It is also used in aluminum etching and to create biodiesal.

– It can burn the skin or cause blindness.

• Sodium hydroxide is used to dispose of road kill because it turns the dead bodies into a coffee-like liquid.

Sodium Hydroxide (NaOH) (Continued)

• Drain cleaner (sodium hydroxide) is extremely corrosive, and without wearing

protection, even the smallest spill on the skin can eat through flesh…

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sulfuric Acid (H2SO4)

• Sulfuric acid is used in drain or toilet bowl cleaner as well as battery acid.

– It is another highly corrosive substance that burns the skin on contact.

Sulfuric Acid (H2SO4) (Continued)

• The product label warning for Drano® (sulfuric acid) says it all:

– DANGER: MAY BURN EYES AND SKIN ON CONTACT.

•HARMFUL IF SWALLOWED.

–Avoid contact with body and clothing.

•TOXIC GAS MAY FORM IF MIXED WITH OTHER CHEMICALS.

–If gases are released, leave immediately and ventilate area.

•FIRST AID: Give Immediately:

–EYES AND SKIN:

»Flush with water for 20 minutes.

»Remove affected clothing.

–IF SWALLOWED:

»Rinse mouth and drink a glass of water or milk.

»Do not induce vomiting.

–THEN SEEK MEDICAL AID.

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Hypophosphorous Acid (H3PO2)

• Hypophosphorous acid, which is used legally for a variety of commercial purposes,

is a chemical that increasingly is substituted for red phosphorus in the methamphetamine production process.

– The use of hypophospherous acid SIGNIFICANTLY increases the risk of fire!!!

• The federal government regulates the sale of hypophosphorous acid through registration, record keeping, reporting, and import/export requirements regardless

of the quantity being handled or distributed.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid is a colorless oily liquid that emits a SOUR odor.

– There is an extreme fire and explosion hazard if the hypophosphorous acid

comes into contact with a solvent such as acetone, toluene, or Coleman fuel.

• Hypophosphorous acid will also emit phosphine gas and the fumes can ignite.

Hypophosphorous Acid (H3PO2) (Continued)

• Although hypophosphorous acid is a List I chemical under the Controlled Substances Act, methamphetamine producers typically purchase the chemical via

the internet or from associates who also are engaged in methamphetamine

production.

– The use of hypophosphorous acid in methamphetamine production is an

EXTREMELY DANGEROUS PRACTICE because of the deadly gases that can be generated as well as the risk of fire or explosion.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid (H3PO2, also called phosphinic acid) is a strong acid that

typically is prepared as a solution of colorless, oily liquid in strengths of 50%, 30 to 32%, and 10%.

– It also is prepared in the form of salts (referred to as hypophosphite salts), particularly ammonium hypophosphite, calcium hypophosphite, iron (ferric)

hypophosphite, magnesium hypophosphite, manganese hypophosphite,

potassium hypophosphite, and sodium hypophosphite.

Hypophosphorous Acid (H3PO2) (Continued)

• Over 100 chemical firms located throughout the world produce hypophosphorous

acid.

– The People's Republic of China and India have the largest numbers of

hypophosphorous acid producers, although there are a few producers in the United States.

• There are a wide variety of uses for hypophosphorous acid and its salts in

commercial industry; however, the chemicals have no legitimate household or retail uses.

Hypophosphorous Acid (H3PO2) (Continued)

• The legitimate commercial and laboratory fields that use hypophosphorous acid and its salts include the following:

– Chemical plating

– Food preparation

– Water treatment

– Polymers (as a bleaching agent, color stabilizer, or catalyst)

– Education and research in analytical chemistry

Hypophosphorous Acid (H3PO2) (Continued)

• Chemical suppliers typically distribute hypophosphorous acid in large quantities, for example, in drums containing 275 pounds of the diluted solution.

– Hypophosphorous acid also is distributed in smaller quantities.

• One-half liter of 50% concentrate hypophosphorous acid solution can be obtained from chemical suppliers for as little as $14.

Hypophosphorous Acid (H3PO2) (Continued)

• Methamphetamine laboratory operators typically obtain small quantities of the chemical from other laboratory operators who purchase large quantities of the

chemical and repackage it for further distribution.

– According to law enforcement sources, these individuals sell hypophosphorous acid for as much as $1,000 per half-liter.

•Methamphetamine laboratory operators also purchase hypophosphorous acidvia the internet.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid and the Internet

• The internet is a source of a great deal of information regarding hypophosphorous acid.

• Popular internet sites that disseminate information about illicit drugs contain information about the chemical, including numerous recipes for home production of

methamphetamine using hypophosphorous acid.

• There also are recipes for synthesizing hypophosphorous acid from available chemicals.

• Hypophosphorous acid solutions and salts have been sold to the general public via the internet.

• The Drug Enforcement Administration (DEA) has strong concerns regarding the sale

of chemicals on the internet and has requested that any sites (such as auction sites) that allow the sale of regulated chemicals on their domains require proof of

DEA registration from their clients.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid Used in Methamphetamine Production

• Hypophosphorous acid is used in the ephedrine-pseudoephedrine reduction method

of methamphetamine production.

– It is used in the methamphetamine production process to produce hydriodic acid,

an important reagent (it reacts with the ephedrine-pseudoephedrine but does NOT become part of the finished product).

Hypophosphorous Acid (H3PO2) (Continued)

• The regulation of hydriodic acid by DEA in 1993 rendered it virtually unavailable in

the United States.

– However, methamphetamine laboratory operators discovered methods to

produce hydriodic acid using a combination of iodine in water with red phosphorus.

• Laboratory operators found that red phosphorus could be obtained easily, either

from commercial supply companies or by scraping the striker pads from matchbooks or matchboxes.

• Methamphetamine producers soon discovered that hypophosphorous acid ALSO could be used in combination with iodine and water to produce hydriodic acid.

Hypophosphorous Acid (H3PO2) (Continued)

• The practice of using hypophosphorous acid in methamphetamine production is

believed to have begun in the United States in the late 1990s when a methamphetamine producer in Colorado obtained the recipe from Australia, where

the hypophosphorous acid method is prevalent.

– This man was known as a serial cook who had a long history of

methamphetamine production.

•Over several years he trained other laboratory operators in Colorado to produce methamphetamine using hypophosphorous acid.

• As his techniques were passed on to others, the number of methamphetaminelaboratories in Colorado using hypophosphorous acid continued to increase, and the

technique was passed on to numerous methamphetamine producers in other

states.

Hypophosphorous Acid (H3PO2) (Continued)

• According to the El Paso Intelligence Center (EPIC) National Clandestine Laboratory

Seizure System, from 2000 through 2002 the number of seized methamphetaminelaboratories in the United States in which hypophosphorous acid was found

increased overall. (See Table 1.)

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid found at methamphetamine laboratories is packaged in a variety of ways.

• The chemical has been found in 1-gallon bottles of solution or in 1-pound jars of salts.

• Some hypophosphorous acid containers are labeled as "plating solution."

• Pint-sized brown glass bottles wrapped in red electrical tape also have been found to contain hypophosphorous acid; they have been discovered primarily in Colorado.

• The vast majority of hypophosphorous acid found at laboratory sites has been recovered from small toxic laboratories (STLs), those which yield gram to ounce

quantities per production cycle.

• Hypophosphorous acid has not been reported at large-scale laboratories operated by Mexican criminal groups in the United States.

Hypophosphorous Acid (H3PO2) (Continued)

• Hazards

• The iodine-hypophosphorous acid method is MORE HAZORDOUS than the iodine-

red phosphorus method, although the reaction using hypophosphorous acid is

faster and gives slightly higher yields.

– When hypophosphorous acid is used, the chemicals must be mixed together

SLOWLY in a PARTICULAR ORDER to prevent them from reacting violently.

Hypophosphorous Acid (H3PO2) (Continued)

• The combination of hypophosphorous acid with the other chemicals and with certain metals can produce deadly phosphine gas during the initial mixing step and

can CONTINUE to produce phosphine gas for several days AFTER production has been completed…

Hypophosphorous Acid (H3PO2) (Continued)

• The iodine-hypophosphorous acid mixture has a tendency to decompose quickly when overheated or if heated for long periods of time, becoming cloudy or "milky-

white" just prior to giving off a cloud of phosphine gas that can ignite spontaneously.

– Hypophosphorous acid solutions may become unstable if evaporation results in

concentrations above 50%.

Hypophosphorous Acid (H3PO2) (Continued)

• [Note: Law enforcement or emergency personnel who encounter suspected

containers of hypophosphorous acid should use extreme care during handling because laboratory operators often attempt to obtain a more concentrated acid by

allowing water to evaporate from the mixture.]

• Because hypophosphorous acid often is used at small methamphetaminelaboratories operated by inexperienced or careless individuals, the potential hazards

of using this method are even greater.

• The risk of fire and explosion is higher in these laboratories, where professional

laboratory equipment typically is not used to contain the phosphine gas and where

safe handling precautions are not employed.

• In addition, these laboratories often are located in homes where children are present and may come into contact with hypophosphorous acid.

• A child can easily mistake hypophosphorous acid for any other clear liquid,

particularly if it is stored in household containers or drinking glasses.

• Skin, eye, or inhalation exposure can be extremely harmful or fatal.

Hypophosphorous Acid (H3PO2) (Continued)

• Safety Precautions

• Always wear a self-contained breathing apparatus as well as protective clothing when entering areas where hypophosphorous acid may be present.

• When in contact with metals or in a high-temperature environment,

hypophosphorous acid can break down and liberate phosphine and flammable hydrogen gas.

• Do not allow the use of open flames, open lights, matches, or smoking in or around laboratories or dumpsites where hypophosphorous acid is handled.

• In case of fire, use a self-contained positive pressure breathing apparatus and full

protective equipment.

• Use water spray, fog, foam, dry chemicals, or other reagents as may be

appropriate for materials in the surrounding fire.

• Water may be used to cool the containers of hypophosphorous acid; however, use extreme care to avoid allowing water to enter the container.

• In case of spills, neutralize the spilled chemical with alkaline material (soda ash, lime), then absorb it with an inert material such as vermiculite, dry sand, or earth

and place in a chemical waste container.

• Do not use combustible materials such as sawdust.

Hypophosphorous Acid (H3PO2) (Continued)

• Legislation and Control

• In the United States hypophosphorous acid is one of 38 chemicals (or groups of

chemicals) controlled under law by DEA.

• On October 17, 2001, hypophosphorous acid and its salts, along with red and white phosphorus, were officially added as List I chemicals under section 1310 of the

Code of Federal Regulations.

• List I chemicals are defined as chemicals that are used in the manufacture of a

controlled substance in violation of the Controlled Substances Act (CSA) and are

important to the manufacture of a controlled substance.

• Under the law, suppliers are required to maintain records and report receipts, sales,

imports, and exports of these chemicals to DEA.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid, red phosphorus, and white phosphorus, as well as

ephedrine, are unique in that suppliers are required to report all transactions of

these chemicals, regardless of the amount.

• By contrast, the other 34 listed chemicals are only reportable after a supplier's

transactions for a chemical reach an established weight or volume threshold in a calendar month.

• In addition to reporting all transactions involving the chemical, suppliers are

expected to "know their customers" in order to prevent the diversion of these substances to methamphetamine laboratories, as it is illegal to import, export,

purchase, or sell hypophosphorous acid or any other listed chemical in the United States if it is used or intended to be used in the production of a controlled

substance.

• Chemical suppliers are held liable for selling listed chemicals if they know or suspect that the chemical will be used for illicit purposes.

Hypophosphorous Acid (H3PO2) (Continued)

• Outlook

• The use of hypophosphorous acid in the production of methamphetamine is likely to increase, particularly in the Midwest and Southwest regions of the United States

where methamphetamine production is prevalent.

– Injuries, property damage, and deaths also will increase as a growing number of

inexperienced methamphetamine producers experiment with hypophosphorous acid.

Anhydrous Ammonia

• Anhydrous ammonia is found in fertilizer, countertop cleaner, and commercial refrigerant.

– On its own, it has a pungent, suffocating odor.

• Mixing anhydrous ammonia with other chemicals can release highly toxic gases.

– Because anhydrous ammonia seeks out water (anhydrous means “without

water”) and causes severe burns, any body part that comes into contact with it

should be flushed with water for at least 15 minutes to remove the ammoniafrom the skin.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia has extremely destructive effects on humans.

– Anhydrous ammonia gives off vapors during cooking that can burn the mouth,

throat, and lung tissue.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Anhydrous ammonia seeks water from the nearest source, including the human body (anhydrous means “without water”).

– Because of their high moisture content, EYES, LUNGS, and SKIN are at the

greatest risk of attracting the ammonia.

• When large amounts of anhydrous ammonia are inhaled, the throat swells and the victim suffocates.

– Exposure to the vapors or liquids can cause severe burns, blindness, or death.

• Anhydrous ammonia has an IDLH (immediately dangerous to life and health) at

only 300 parts per million...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is poses MANY hazards, especially when it is placed in improper vessels and handled/transported by individuals unfamiliar with the

dangers.

• Anhydrous ammonia has a boiling point of -28 degrees below zero.

– When a vessel containing anhydrous ammonia is MOVED, the anhydrous

ammonia will reach its boiling point and pressurize.

•This pressurization can cause vessels to violently RUPTURE, or if the vessel pressurizes and does NOT rupture, the opening of the container of anhydrous

ammonia at a later time can cause RAPID, VIOLENT depressurization.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is mainly used in the U.S. as either a fertilizer or a refrigerant.

– Meth producers tend to store the anhydrous ammonia in IMPROPER/UNAPPROVED containers such as:

•Propane tanks,

• Igloo coolers, or

•Fire extinguishers.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia leaves a tell-tell sign as it flows through these UNAPPROVED

CONTAINERS – a blue or blue green discoloration on the valve.

– PAY ATTENTION to details!!!

Anhydrous Ammonia (Continued)

• Because propane cylinders (and the other unapproved containers) are NOT designed to store anhydrous ammonia, they can EXPLODE as the ammonia eats

through the walls of the cylinders.

– The valves, which take on a bluish/green color, frequently deteriorate and can cause hazardous leaks!!!

Anhydrous Ammonia (Continued)

• Do NOT touch, move, or open any kind of tank or sealed container!!!

– Be aware that propane tanks are often WEAKENED and BRITTLE due to the

anhydrous ammonia and are SENSITIVE to ANY kind of movement or impact.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• These pictures show what happened to a fire extinguisher that was used to store

anhydrous ammonia…

Anhydrous Ammonia (Continued)

• Illegal drug makers often STEAL anhydrous ammonia from areas where it is stored

and used, such as farms.

• Attempted thefts have also occurred at places such as:

– Refrigeration systems holding ammonia,

– Underground pipelines carrying ammonia, and

– Rail cars transporting anhydrous ammonia.

• Often thefts are aborted when thieves are injured or overcome by the toxic gas...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia thieves had better beware!!!

• There is a new product called GloTell that farmers can add to their anhydrous

ammonia tanks…

• Meth cooks will run the risk that the GloTell additive will turn their hands bright

pink!

– This bright pink stain will fluoresce under ultraviolet light even if washed off!!!

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Also, GloTell will produce pink methamphetamine that CANNOT be bleached.

– Users who snort meth made with GloTell will find that they have PINK NOSES!

– Users who inject meth made with GloTell will see a pink stain at the point of

injection!

Sodium Carbonate (Soda Ash)

Sodium Carbonate (Soda Ash) (Continued)

Lead Acetate

Iodine

• Iodine is a natural element, and it is helpful to the body in SMALL amounts.

– However, if iodine is taken in large amounts it can become toxic.

•Extremely high does of iodine can limit the function of the thyroid.

Iodine (Continued)

Iodine (Continued)

• Iodine is bluish-black, and it has a characteristic odor, a sharp acrid taste, and it produces a violet corrosive vapor.

– The vapor is irritating to the respiratory system and eyes.

• The solid iodine irritates the eyes and may burn the skin, and it may cause severe

internal irritation and damage if ingested.

Iodine (Continued)

• Iodine is known as the “blue ingredient” in the production of meth (in the “red, white, and blue” method).

Iodine (Continued)

Iodine (Continued)

• It takes approximately 4 bottles of iodine tincture to produce 2 – 3 grams of meth.

Iodine (Continued)

Iodine (Continued)

• Iodine leaves distinctive yellow-blue or brown stains on surfaces in former methlabs.

Iodine (Continued)

Iodine (Continued)

Iodine (Continued)

• The only good thing about iodine is that it leaves yellow stains.

• If you see yellow stained coffee filters, gloves or paper towels, this could be an

indicator that you’re in a lab.

• If you see yellow stains, you can spray some starch on them.

– If they turn a purplish blue/black, it’s iodine.

• Iodine is the only substance that reacts with soluble starch to produce a purplish black color.

– The only way to get iodine vapor all over the walls is to cook meth.

Mercurous Chloride

Rock Salt

Hydrogen Chloride

• Hydrogen chloride gas is commercially available.

• Hydrogen chloride gas can also be made by mixing sulfuric acid and salt.

• Muriatic acid is simply hydrogen chloride gas suspended in water.

• Hydrogen chloride gas can be seen as a pale white smoke.

– It is a poisonous gas that can cause respiratory problems and death.

Hydrogen Chloride (Continued)

Ammonium Nitrate

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Hydriodic Acid

• Hydriodic acid is a corrosive acid that is colorless when freshly prepared.

– When hydriodic acid is exposed to light and air, it turns yellowish and brown.

• Hydriodic acid is a solution of hydrogen iodide gas in water.

• Hydriodic acid vapor is irritating to the respiratory system, skin, and eyes.

• Hydriodic acid liquid causes severe burns to the eyes and skin.

• If hydriodic acid is accidentally ingested, it can cause severe internal irritation and

damage.

Hydriodic Acid (Continued)

Catalyst Chemicals

• Catalyst Chemicals:

– Chemicals which SPEED UP a reaction process and/or cause it to go to GREATER COMPLETION.

Red Phosphorus

• Red phosphorus is found ON matchboxes, in road flares, and other explosives.

– Red Phosphorus IGNITES when OVERHEATED!!!

• By combining red phosphorus and iodine, you can easily create the highly

controlled substance known as hydriodic acid (which is an essential ingredient in making meth).

– Creating 2 – 3 grams of meth requires about 4 big boxes of matches.

Red Phosphorus (Continued)

• Red phosphorous is highly flammable and if it is overheated it can become white

phosphorous…

– White phosphorous is a volatile and highly explosive substance.

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Lithium

• Lithium is used in batteries.

• Lithium seriously burns the skin upon contact.

– It also reacts VIOLENTLY with WATER and is highly explosive.

Lithium (Continued)

• Lithium reacts VIOLENTLY with WATER, and if it is splashed in the eyes during

cooking it will cause blindness.

– Lithium is extremely caustic to all body tissues.

Lithium (Continued)

Lithium (Continued)

• Lithium metal is HIGHLY water reactive and it will BURN or EXPLODE if it comes into contact with WATER!

• Because of the moisture in your skin, it will burn exposed flesh.

• Lithium metal will DEGRADE when exposed to atmospheric moisture…

– This is why meth cooks store lithium metal in a solvent prior to use.

• It is typical to see harvested lithium strips in Coleman fuel or Mineral Spirits to prevent explosions.

•Large quantities can be harvested and saved in these containers until needed

for a cook.

Lithium (Continued)

• If you see battery shells in the trashcan, on the floor, etc. – this is a VERY GOOD

indicator that you might be entering a meth lab!

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

• Lithium catches fire when in contact with water...

Solvent Chemicals

• Solvent Chemicals:

– A medium (liquid) in which a chemical operation takes place.

• Solvent chemicals (UNLIKE the precursor chemicals) CAN be

substituted/interchanged.

Ether

• Ether was once called “sweet vitriol” because of its hypnotic effect.

• Ether is a highly flammable substance that is used as an anesthetic agent –

especially in third world countries where more expensive anesthesia is not available.

– While inhaling the ether, patients could undergo complete surgical procedures while otherwise awake without feeling pain or concern.

Ether (Continued)

• Ether can be obtained from engine starting fluid.

• Ether is a solvent and it is flammable.

– It is particularly hazardous because it can cause BOTH fire and explosion.

• It has been said that a quart of ether can “level” a small house.

Ethyl Ether (Continued)

Ethyl Ether (Continued)

• Ether is VERY flammable and is HEAVIER than air.

– NEVER use ether near flames or non-sparkless motors.

– Ether is very PUNGENT – even a small evaporated amount of ether is VERY noticeable.

Acetone

• Acetone can be found in nail polish remover or paint thinner.

– It is extremely flammable.

• In the setting of a meth lab where meth is being cooked with high heat, acetone is

very dangerous.

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Toluene

• Toluene is used in brake fluid.

– When working with brake fluid (toluene), be careful not to spill it on your car

because it will eat away the paint and chrome…

• You also have to be careful using toluene around other household chemicals

because its high concentration of polyethylene glycol can cause it to ignite in a

violent fireball.

• Toluene is powerful enough to dissolve rubber.

Toluene (Continued)

• Toluene is used to form meth crystals.

– The fumes toluene releases can cause brain damage or death.

Toluene (Continued)

Toluene (Continued)

Ethanol

Isopropanol

Isopropanol (Continued)

Isopropyl Alcohol

Methanol

Methanol (Continued)

Methanol (Continued)

Benzene

Benzene (Continued)

Which of these is NOT a common ingredient in Meth?

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Page 5: Methamphetamine - PowerPoint - Chemicals and Ingredients ... · 2/5/2014 1 Methamphetamine - PowerPoint - Chemicals and Ingredients Used to Make Meth CJUS 240 Economic Costs of Meth

2/5/2014

5

Methamphetamine- PowerPoint

- Chemicals and Ingredients Used to Make Meth

CJUS 240

Economic Costs of Meth

• The economic cost of methamphetamine use in the U.S. reached $23.4 billion in

2005.

– This includes the burden of addiction, premature death, drug treatment, child

care, and cleaning of lab sites.

– This figure does NOT take into account the future needs of the meth user.

Concerns with ACTIVE Meth Labs

• Danger of fire and explosion

• Chemical spills

• Inhalation of solvents, corrosives, and toxic gases

• “Booby traps”

• Waste disposal

Concerns with FORMER Meth Labs

• Vapors

• Chemical residues

• Methamphetamine residues

• Waste disposal

Equipment Used in Meth Production

• Pyrex or Corning dishes

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

• Coffee Filters

Equipment Used in Meth Production

Equipment Used in Meth Production

Basic Chemical Requirements

• In a clandestine laboratory, basic types of chemicals are necessary in order to produce the desired drug.

– The basic types of chemicals needed are:

1) Precursor Chemicals

2) Reagent Chemicals

3) Catalyst Chemicals

4) Solvent Chemicals

List I Chemical

• The term “List I chemical” means a chemical specified by regulation of the Attorney General as a chemical that is used in manufacturing a controlled substance and is

IMPORTANT to the manufacture of the controlled substance.

• Examples of List I chemicals are:

– GBL

– Red Phosphorus

– Pseudoephedrine

List II Chemical

• The term “List II chemical” means a chemical (other than a List I chemical) specified by regulation of the Attorney General as a chemical that is USED in

manufacturing a controlled substance.

• Examples of List II chemicals are:

– Toluene

– Iodine

– Hydrochloric Acid

Precursor Chemicals

• Precursor Chemicals:

– A chemical that is ESSENTIAL to the production of a controlled substance and for

which NO SUBSTITUTION can be made.

Pseudoephedrine

• Pseudoephedrine is a decongestant found in cold medicine.

– Large amounts of pseudoephedrine on its own can harm the respiratory and nervous systems, as well as the heart.

Pseudoephedrine (Continued)

• Some of the common ways used to divert products containing pseudoephedrine

include:

– “Smurfing” – making multiple purchases at different locations

– Shelf-Sweeping – the theft of all shelf stock

– Shoplifting

– Theft from wholesalers

Pseudoephedrine (Continued)

• Pseudoephedrine smurfing is a method used by some methamphetamine producers to acquire large quantities of pseudoephedrine by enlisting the assistance of several

friends or associates (often referred to as “smurfers”) to make purchases at or below the legal thresholds from multiple retail locations.

– Smurfers are often addicts who trade the pseudoephedrine for finished

methamphetamine.

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

• About 680 pseudoephedrine tablets are needed to produce one ounce of meth…

Pseudoephedrine (Continued)

Out With a Bang

An Unstable Recipe…

• Meth contains a variety of poisonous ingredients…

– Some become EVEN MORE DANGEROUS once the cooking process begins…

Common Ingredients to Make Methamphetamine

Reagent Chemicals

• Reagent Chemicals:

– Chemicals which REACT upon the precursor chemical causing it to chemicallyCHANGE.

• A reagent chemical is a chemical which is required for the synthesis of an illicit drug substance, but which is NOT incorporated into the final chemical product.

Hydrochloric Acid

• Hydrochloric acid is a highly corrosive liquid that is used to make plastic (such as PVC pipe and polyurethane).

– It can remove rust and iron-oxide from steel and is highly corrosive to human

skin.

•Hydrochloric acid makes up the majority of the gastric acid in the human digestive fluid.

• In high concentrations, hydrochloric acid will literally eat away human flesh…

Hydrochloric Acid (Continued)

• Hydrochloric acid can be purchased from hardware stores as:

– Tile and Grout Acid Cleaner

– Muriatic Acid

– Pool Acid

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

• Hydrochloric acid is a solution of hydrogen chloride gas suspended in water.

– Hydrochloric acid is corrosive and is a light yellow liquid color from traces of iron, chlorine, and organic matter.

• Inhaling hydrochloric acid may cause coughing or choking, inflammation, and

ulceration of the respiratory tract.

• Concentrated solutions of hydrochloric acid can cause severe burns and irritate the

mucous membranes, eyes, and respiratory tract.

– Exposure to hydrochloric acid vapors may result in pulmonary edema and

possibly death.

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

Sodium Hydroxide (NaOH)

• Sodium hydroxide is also called Lye.

• Sodium hydroxide is classified as a corrosive, and it is one of the main chemicals in

drain cleaner.

– It is also used in aluminum etching and to create biodiesal.

– It can burn the skin or cause blindness.

• Sodium hydroxide is used to dispose of road kill because it turns the dead bodies

into a coffee-like liquid.

Sodium Hydroxide (NaOH) (Continued)

• Drain cleaner (sodium hydroxide) is extremely corrosive, and without wearing

protection, even the smallest spill on the skin can eat through flesh…

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sulfuric Acid (H2SO4)

• Sulfuric acid is used in drain or toilet bowl cleaner as well as battery acid.

– It is another highly corrosive substance that burns the skin on contact.

Sulfuric Acid (H2SO4) (Continued)

• The product label warning for Drano® (sulfuric acid) says it all:

– DANGER: MAY BURN EYES AND SKIN ON CONTACT.

•HARMFUL IF SWALLOWED.

–Avoid contact with body and clothing.

•TOXIC GAS MAY FORM IF MIXED WITH OTHER CHEMICALS.

–If gases are released, leave immediately and ventilate area.

•FIRST AID: Give Immediately:

–EYES AND SKIN:

»Flush with water for 20 minutes.

»Remove affected clothing.

–IF SWALLOWED:

»Rinse mouth and drink a glass of water or milk.

»Do not induce vomiting.

–THEN SEEK MEDICAL AID.

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Hypophosphorous Acid (H3PO2)

• Hypophosphorous acid, which is used legally for a variety of commercial purposes,

is a chemical that increasingly is substituted for red phosphorus in the methamphetamine production process.

– The use of hypophospherous acid SIGNIFICANTLY increases the risk of fire!!!

• The federal government regulates the sale of hypophosphorous acid through registration, record keeping, reporting, and import/export requirements regardless

of the quantity being handled or distributed.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid is a colorless oily liquid that emits a SOUR odor.

– There is an extreme fire and explosion hazard if the hypophosphorous acid

comes into contact with a solvent such as acetone, toluene, or Coleman fuel.

• Hypophosphorous acid will also emit phosphine gas and the fumes can ignite.

Hypophosphorous Acid (H3PO2) (Continued)

• Although hypophosphorous acid is a List I chemical under the Controlled Substances Act, methamphetamine producers typically purchase the chemical via the internet or from associates who also are engaged in methamphetamine

production.

– The use of hypophosphorous acid in methamphetamine production is an

EXTREMELY DANGEROUS PRACTICE because of the deadly gases that can be generated as well as the risk of fire or explosion.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid (H3PO2, also called phosphinic acid) is a strong acid that

typically is prepared as a solution of colorless, oily liquid in strengths of 50%, 30 to 32%, and 10%.

– It also is prepared in the form of salts (referred to as hypophosphite salts), particularly ammonium hypophosphite, calcium hypophosphite, iron (ferric) hypophosphite, magnesium hypophosphite, manganese hypophosphite,

potassium hypophosphite, and sodium hypophosphite.

Hypophosphorous Acid (H3PO2) (Continued)

• Over 100 chemical firms located throughout the world produce hypophosphorous

acid.

– The People's Republic of China and India have the largest numbers of

hypophosphorous acid producers, although there are a few producers in the United States.

• There are a wide variety of uses for hypophosphorous acid and its salts in

commercial industry; however, the chemicals have no legitimate household or retail uses.

Hypophosphorous Acid (H3PO2) (Continued)

• The legitimate commercial and laboratory fields that use hypophosphorous acid and its salts include the following:

– Chemical plating

– Food preparation

– Water treatment

– Polymers (as a bleaching agent, color stabilizer, or catalyst)

– Education and research in analytical chemistry

Hypophosphorous Acid (H3PO2) (Continued)

• Chemical suppliers typically distribute hypophosphorous acid in large quantities, for example, in drums containing 275 pounds of the diluted solution.

– Hypophosphorous acid also is distributed in smaller quantities.

• One-half liter of 50% concentrate hypophosphorous acid solution can be obtained from chemical suppliers for as little as $14.

Hypophosphorous Acid (H3PO2) (Continued)

• Methamphetamine laboratory operators typically obtain small quantities of the chemical from other laboratory operators who purchase large quantities of the

chemical and repackage it for further distribution.

– According to law enforcement sources, these individuals sell hypophosphorous acid for as much as $1,000 per half-liter.

•Methamphetamine laboratory operators also purchase hypophosphorous acidvia the internet.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid and the Internet

• The internet is a source of a great deal of information regarding hypophosphorous acid.

• Popular internet sites that disseminate information about illicit drugs contain information about the chemical, including numerous recipes for home production of

methamphetamine using hypophosphorous acid.

• There also are recipes for synthesizing hypophosphorous acid from available chemicals.

• Hypophosphorous acid solutions and salts have been sold to the general public via the internet.

• The Drug Enforcement Administration (DEA) has strong concerns regarding the sale

of chemicals on the internet and has requested that any sites (such as auction sites) that allow the sale of regulated chemicals on their domains require proof of

DEA registration from their clients.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid Used in Methamphetamine Production

• Hypophosphorous acid is used in the ephedrine-pseudoephedrine reduction method

of methamphetamine production.

– It is used in the methamphetamine production process to produce hydriodic acid,

an important reagent (it reacts with the ephedrine-pseudoephedrine but does NOT become part of the finished product).

Hypophosphorous Acid (H3PO2) (Continued)

• The regulation of hydriodic acid by DEA in 1993 rendered it virtually unavailable in

the United States.

– However, methamphetamine laboratory operators discovered methods to

produce hydriodic acid using a combination of iodine in water with red phosphorus.

• Laboratory operators found that red phosphorus could be obtained easily, either

from commercial supply companies or by scraping the striker pads from matchbooks or matchboxes.

• Methamphetamine producers soon discovered that hypophosphorous acid ALSO could be used in combination with iodine and water to produce hydriodic acid.

Hypophosphorous Acid (H3PO2) (Continued)

• The practice of using hypophosphorous acid in methamphetamine production is

believed to have begun in the United States in the late 1990s when a methamphetamine producer in Colorado obtained the recipe from Australia, where

the hypophosphorous acid method is prevalent.

– This man was known as a serial cook who had a long history of

methamphetamine production.

•Over several years he trained other laboratory operators in Colorado to produce methamphetamine using hypophosphorous acid.

• As his techniques were passed on to others, the number of methamphetaminelaboratories in Colorado using hypophosphorous acid continued to increase, and the

technique was passed on to numerous methamphetamine producers in other

states.

Hypophosphorous Acid (H3PO2) (Continued)

• According to the El Paso Intelligence Center (EPIC) National Clandestine Laboratory

Seizure System, from 2000 through 2002 the number of seized methamphetaminelaboratories in the United States in which hypophosphorous acid was found

increased overall. (See Table 1.)

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid found at methamphetamine laboratories is packaged in a variety of ways.

• The chemical has been found in 1-gallon bottles of solution or in 1-pound jars of salts.

• Some hypophosphorous acid containers are labeled as "plating solution."

• Pint-sized brown glass bottles wrapped in red electrical tape also have been found to contain hypophosphorous acid; they have been discovered primarily in Colorado.

• The vast majority of hypophosphorous acid found at laboratory sites has been recovered from small toxic laboratories (STLs), those which yield gram to ounce

quantities per production cycle.

• Hypophosphorous acid has not been reported at large-scale laboratories operated by Mexican criminal groups in the United States.

Hypophosphorous Acid (H3PO2) (Continued)

• Hazards

• The iodine-hypophosphorous acid method is MORE HAZORDOUS than the iodine-

red phosphorus method, although the reaction using hypophosphorous acid is

faster and gives slightly higher yields.

– When hypophosphorous acid is used, the chemicals must be mixed together

SLOWLY in a PARTICULAR ORDER to prevent them from reacting violently.

Hypophosphorous Acid (H3PO2) (Continued)

• The combination of hypophosphorous acid with the other chemicals and with

certain metals can produce deadly phosphine gas during the initial mixing step and

can CONTINUE to produce phosphine gas for several days AFTER production has been completed…

Hypophosphorous Acid (H3PO2) (Continued)

• The iodine-hypophosphorous acid mixture has a tendency to decompose quickly when overheated or if heated for long periods of time, becoming cloudy or "milky-

white" just prior to giving off a cloud of phosphine gas that can ignite spontaneously.

– Hypophosphorous acid solutions may become unstable if evaporation results in

concentrations above 50%.

Hypophosphorous Acid (H3PO2) (Continued)

• [Note: Law enforcement or emergency personnel who encounter suspected

containers of hypophosphorous acid should use extreme care during handling because laboratory operators often attempt to obtain a more concentrated acid by

allowing water to evaporate from the mixture.]

• Because hypophosphorous acid often is used at small methamphetaminelaboratories operated by inexperienced or careless individuals, the potential hazards

of using this method are even greater.

• The risk of fire and explosion is higher in these laboratories, where professional

laboratory equipment typically is not used to contain the phosphine gas and where

safe handling precautions are not employed.

• In addition, these laboratories often are located in homes where children are

present and may come into contact with hypophosphorous acid.

• A child can easily mistake hypophosphorous acid for any other clear liquid,

particularly if it is stored in household containers or drinking glasses.

• Skin, eye, or inhalation exposure can be extremely harmful or fatal.

Hypophosphorous Acid (H3PO2) (Continued)

• Safety Precautions

• Always wear a self-contained breathing apparatus as well as protective clothing when entering areas where hypophosphorous acid may be present.

• When in contact with metals or in a high-temperature environment,

hypophosphorous acid can break down and liberate phosphine and flammable hydrogen gas.

• Do not allow the use of open flames, open lights, matches, or smoking in or around laboratories or dumpsites where hypophosphorous acid is handled.

• In case of fire, use a self-contained positive pressure breathing apparatus and full

protective equipment.

• Use water spray, fog, foam, dry chemicals, or other reagents as may be

appropriate for materials in the surrounding fire.

• Water may be used to cool the containers of hypophosphorous acid; however, use extreme care to avoid allowing water to enter the container.

• In case of spills, neutralize the spilled chemical with alkaline material (soda ash, lime), then absorb it with an inert material such as vermiculite, dry sand, or earth

and place in a chemical waste container.

• Do not use combustible materials such as sawdust.

Hypophosphorous Acid (H3PO2) (Continued)

• Legislation and Control

• In the United States hypophosphorous acid is one of 38 chemicals (or groups of

chemicals) controlled under law by DEA.

• On October 17, 2001, hypophosphorous acid and its salts, along with red and white phosphorus, were officially added as List I chemicals under section 1310 of the

Code of Federal Regulations.

• List I chemicals are defined as chemicals that are used in the manufacture of a

controlled substance in violation of the Controlled Substances Act (CSA) and are important to the manufacture of a controlled substance.

• Under the law, suppliers are required to maintain records and report receipts, sales,

imports, and exports of these chemicals to DEA.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid, red phosphorus, and white phosphorus, as well as

ephedrine, are unique in that suppliers are required to report all transactions of

these chemicals, regardless of the amount.

• By contrast, the other 34 listed chemicals are only reportable after a supplier's

transactions for a chemical reach an established weight or volume threshold in a calendar month.

• In addition to reporting all transactions involving the chemical, suppliers are expected to "know their customers" in order to prevent the diversion of these substances to methamphetamine laboratories, as it is illegal to import, export,

purchase, or sell hypophosphorous acid or any other listed chemical in the United States if it is used or intended to be used in the production of a controlled

substance.

• Chemical suppliers are held liable for selling listed chemicals if they know or suspect that the chemical will be used for illicit purposes.

Hypophosphorous Acid (H3PO2) (Continued)

• Outlook

• The use of hypophosphorous acid in the production of methamphetamine is likely

to increase, particularly in the Midwest and Southwest regions of the United States where methamphetamine production is prevalent.

– Injuries, property damage, and deaths also will increase as a growing number of

inexperienced methamphetamine producers experiment with hypophosphorous acid.

Anhydrous Ammonia

• Anhydrous ammonia is found in fertilizer, countertop cleaner, and commercial refrigerant.

– On its own, it has a pungent, suffocating odor.

• Mixing anhydrous ammonia with other chemicals can release highly toxic gases.

– Because anhydrous ammonia seeks out water (anhydrous means “without

water”) and causes severe burns, any body part that comes into contact with it

should be flushed with water for at least 15 minutes to remove the ammoniafrom the skin.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia has extremely destructive effects on humans.

– Anhydrous ammonia gives off vapors during cooking that can burn the mouth,

throat, and lung tissue.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Anhydrous ammonia seeks water from the nearest source, including the human body (anhydrous means “without water”).

– Because of their high moisture content, EYES, LUNGS, and SKIN are at the

greatest risk of attracting the ammonia.

• When large amounts of anhydrous ammonia are inhaled, the throat swells and the

victim suffocates.

– Exposure to the vapors or liquids can cause severe burns, blindness, or death.

• Anhydrous ammonia has an IDLH (immediately dangerous to life and health) at

only 300 parts per million...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is poses MANY hazards, especially when it is placed in improper vessels and handled/transported by individuals unfamiliar with the

dangers.

• Anhydrous ammonia has a boiling point of -28 degrees below zero.

– When a vessel containing anhydrous ammonia is MOVED, the anhydrous

ammonia will reach its boiling point and pressurize.

•This pressurization can cause vessels to violently RUPTURE, or if the vessel pressurizes and does NOT rupture, the opening of the container of anhydrous

ammonia at a later time can cause RAPID, VIOLENT depressurization.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is mainly used in the U.S. as either a fertilizer or a refrigerant.

– Meth producers tend to store the anhydrous ammonia in IMPROPER/UNAPPROVED containers such as:

•Propane tanks,

• Igloo coolers, or

•Fire extinguishers.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia leaves a tell-tell sign as it flows through these UNAPPROVED

CONTAINERS – a blue or blue green discoloration on the valve.

– PAY ATTENTION to details!!!

Anhydrous Ammonia (Continued)

• Because propane cylinders (and the other unapproved containers) are NOT designed to store anhydrous ammonia, they can EXPLODE as the ammonia eats

through the walls of the cylinders.

– The valves, which take on a bluish/green color, frequently deteriorate and can cause hazardous leaks!!!

Anhydrous Ammonia (Continued)

• Do NOT touch, move, or open any kind of tank or sealed container!!!

– Be aware that propane tanks are often WEAKENED and BRITTLE due to the

anhydrous ammonia and are SENSITIVE to ANY kind of movement or impact.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• These pictures show what happened to a fire extinguisher that was used to store

anhydrous ammonia…

Anhydrous Ammonia (Continued)

• Illegal drug makers often STEAL anhydrous ammonia from areas where it is stored

and used, such as farms.

• Attempted thefts have also occurred at places such as:

– Refrigeration systems holding ammonia,

– Underground pipelines carrying ammonia, and

– Rail cars transporting anhydrous ammonia.

• Often thefts are aborted when thieves are injured or overcome by the toxic gas...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia thieves had better beware!!!

• There is a new product called GloTell that farmers can add to their anhydrous

ammonia tanks…

• Meth cooks will run the risk that the GloTell additive will turn their hands bright

pink!

– This bright pink stain will fluoresce under ultraviolet light even if washed off!!!

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Also, GloTell will produce pink methamphetamine that CANNOT be bleached.

– Users who snort meth made with GloTell will find that they have PINK NOSES!

– Users who inject meth made with GloTell will see a pink stain at the point of

injection!

Sodium Carbonate (Soda Ash)

Sodium Carbonate (Soda Ash) (Continued)

Lead Acetate

Iodine

• Iodine is a natural element, and it is helpful to the body in SMALL amounts.

– However, if iodine is taken in large amounts it can become toxic.

•Extremely high does of iodine can limit the function of the thyroid.

Iodine (Continued)

Iodine (Continued)

• Iodine is bluish-black, and it has a characteristic odor, a sharp acrid taste, and it produces a violet corrosive vapor.

– The vapor is irritating to the respiratory system and eyes.

• The solid iodine irritates the eyes and may burn the skin, and it may cause severe

internal irritation and damage if ingested.

Iodine (Continued)

• Iodine is known as the “blue ingredient” in the production of meth (in the “red, white, and blue” method).

Iodine (Continued)

Iodine (Continued)

• It takes approximately 4 bottles of iodine tincture to produce 2 – 3 grams of meth.

Iodine (Continued)

Iodine (Continued)

• Iodine leaves distinctive yellow-blue or brown stains on surfaces in former methlabs.

Iodine (Continued)

Iodine (Continued)

Iodine (Continued)

• The only good thing about iodine is that it leaves yellow stains.

• If you see yellow stained coffee filters, gloves or paper towels, this could be an

indicator that you’re in a lab.

• If you see yellow stains, you can spray some starch on them.

– If they turn a purplish blue/black, it’s iodine.

• Iodine is the only substance that reacts with soluble starch to produce a purplish black color.

– The only way to get iodine vapor all over the walls is to cook meth.

Mercurous Chloride

Rock Salt

Hydrogen Chloride

• Hydrogen chloride gas is commercially available.

• Hydrogen chloride gas can also be made by mixing sulfuric acid and salt.

• Muriatic acid is simply hydrogen chloride gas suspended in water.

• Hydrogen chloride gas can be seen as a pale white smoke.

– It is a poisonous gas that can cause respiratory problems and death.

Hydrogen Chloride (Continued)

Ammonium Nitrate

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Hydriodic Acid

• Hydriodic acid is a corrosive acid that is colorless when freshly prepared.

– When hydriodic acid is exposed to light and air, it turns yellowish and brown.

• Hydriodic acid is a solution of hydrogen iodide gas in water.

• Hydriodic acid vapor is irritating to the respiratory system, skin, and eyes.

• Hydriodic acid liquid causes severe burns to the eyes and skin.

• If hydriodic acid is accidentally ingested, it can cause severe internal irritation and

damage.

Hydriodic Acid (Continued)

Catalyst Chemicals

• Catalyst Chemicals:

– Chemicals which SPEED UP a reaction process and/or cause it to go to GREATER COMPLETION.

Red Phosphorus

• Red phosphorus is found ON matchboxes, in road flares, and other explosives.

– Red Phosphorus IGNITES when OVERHEATED!!!

• By combining red phosphorus and iodine, you can easily create the highly

controlled substance known as hydriodic acid (which is an essential ingredient in making meth).

– Creating 2 – 3 grams of meth requires about 4 big boxes of matches.

Red Phosphorus (Continued)

• Red phosphorous is highly flammable and if it is overheated it can become white

phosphorous…

– White phosphorous is a volatile and highly explosive substance.

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Lithium

• Lithium is used in batteries.

• Lithium seriously burns the skin upon contact.

– It also reacts VIOLENTLY with WATER and is highly explosive.

Lithium (Continued)

• Lithium reacts VIOLENTLY with WATER, and if it is splashed in the eyes during

cooking it will cause blindness.

– Lithium is extremely caustic to all body tissues.

Lithium (Continued)

Lithium (Continued)

• Lithium metal is HIGHLY water reactive and it will BURN or EXPLODE if it comes into contact with WATER!

• Because of the moisture in your skin, it will burn exposed flesh.

• Lithium metal will DEGRADE when exposed to atmospheric moisture…

– This is why meth cooks store lithium metal in a solvent prior to use.

• It is typical to see harvested lithium strips in Coleman fuel or Mineral Spirits to prevent explosions.

•Large quantities can be harvested and saved in these containers until needed

for a cook.

Lithium (Continued)

• If you see battery shells in the trashcan, on the floor, etc. – this is a VERY GOOD

indicator that you might be entering a meth lab!

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

• Lithium catches fire when in contact with water...

Solvent Chemicals

• Solvent Chemicals:

– A medium (liquid) in which a chemical operation takes place.

• Solvent chemicals (UNLIKE the precursor chemicals) CAN be

substituted/interchanged.

Ether

• Ether was once called “sweet vitriol” because of its hypnotic effect.

• Ether is a highly flammable substance that is used as an anesthetic agent –

especially in third world countries where more expensive anesthesia is not available.

– While inhaling the ether, patients could undergo complete surgical procedures while otherwise awake without feeling pain or concern.

Ether (Continued)

• Ether can be obtained from engine starting fluid.

• Ether is a solvent and it is flammable.

– It is particularly hazardous because it can cause BOTH fire and explosion.

• It has been said that a quart of ether can “level” a small house.

Ethyl Ether (Continued)

Ethyl Ether (Continued)

• Ether is VERY flammable and is HEAVIER than air.

– NEVER use ether near flames or non-sparkless motors.

– Ether is very PUNGENT – even a small evaporated amount of ether is VERY noticeable.

Acetone

• Acetone can be found in nail polish remover or paint thinner.

– It is extremely flammable.

• In the setting of a meth lab where meth is being cooked with high heat, acetone is

very dangerous.

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Toluene

• Toluene is used in brake fluid.

– When working with brake fluid (toluene), be careful not to spill it on your car

because it will eat away the paint and chrome…

• You also have to be careful using toluene around other household chemicals

because its high concentration of polyethylene glycol can cause it to ignite in a

violent fireball.

• Toluene is powerful enough to dissolve rubber.

Toluene (Continued)

• Toluene is used to form meth crystals.

– The fumes toluene releases can cause brain damage or death.

Toluene (Continued)

Toluene (Continued)

Ethanol

Isopropanol

Isopropanol (Continued)

Isopropyl Alcohol

Methanol

Methanol (Continued)

Methanol (Continued)

Benzene

Benzene (Continued)

Which of these is NOT a common ingredient in Meth?

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Page 6: Methamphetamine - PowerPoint - Chemicals and Ingredients ... · 2/5/2014 1 Methamphetamine - PowerPoint - Chemicals and Ingredients Used to Make Meth CJUS 240 Economic Costs of Meth

2/5/2014

6

Methamphetamine- PowerPoint

- Chemicals and Ingredients Used to Make Meth

CJUS 240

Economic Costs of Meth

• The economic cost of methamphetamine use in the U.S. reached $23.4 billion in 2005.

– This includes the burden of addiction, premature death, drug treatment, child

care, and cleaning of lab sites.

– This figure does NOT take into account the future needs of the meth user.

Concerns with ACTIVE Meth Labs

• Danger of fire and explosion

• Chemical spills

• Inhalation of solvents, corrosives, and toxic gases

• “Booby traps”

• Waste disposal

Concerns with FORMER Meth Labs

• Vapors

• Chemical residues

• Methamphetamine residues

• Waste disposal

Equipment Used in Meth Production

• Pyrex or Corning dishes

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

• Coffee Filters

Equipment Used in Meth Production

Equipment Used in Meth Production

Basic Chemical Requirements

• In a clandestine laboratory, basic types of chemicals are necessary in order to

produce the desired drug.

– The basic types of chemicals needed are:

1) Precursor Chemicals

2) Reagent Chemicals

3) Catalyst Chemicals

4) Solvent Chemicals

List I Chemical

• The term “List I chemical” means a chemical specified by regulation of the Attorney General as a chemical that is used in manufacturing a controlled substance and is

IMPORTANT to the manufacture of the controlled substance.

• Examples of List I chemicals are:

– GBL

– Red Phosphorus

– Pseudoephedrine

List II Chemical

• The term “List II chemical” means a chemical (other than a List I chemical) specified by regulation of the Attorney General as a chemical that is USED in

manufacturing a controlled substance.

• Examples of List II chemicals are:

– Toluene

– Iodine

– Hydrochloric Acid

Precursor Chemicals

• Precursor Chemicals:

– A chemical that is ESSENTIAL to the production of a controlled substance and for

which NO SUBSTITUTION can be made.

Pseudoephedrine

• Pseudoephedrine is a decongestant found in cold medicine.

– Large amounts of pseudoephedrine on its own can harm the respiratory and nervous systems, as well as the heart.

Pseudoephedrine (Continued)

• Some of the common ways used to divert products containing pseudoephedrine

include:

– “Smurfing” – making multiple purchases at different locations

– Shelf-Sweeping – the theft of all shelf stock

– Shoplifting

– Theft from wholesalers

Pseudoephedrine (Continued)

• Pseudoephedrine smurfing is a method used by some methamphetamine producers to acquire large quantities of pseudoephedrine by enlisting the assistance of several

friends or associates (often referred to as “smurfers”) to make purchases at or below the legal thresholds from multiple retail locations.

– Smurfers are often addicts who trade the pseudoephedrine for finished

methamphetamine.

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

• About 680 pseudoephedrine tablets are needed to produce one ounce of meth…

Pseudoephedrine (Continued)

Out With a Bang

An Unstable Recipe…

• Meth contains a variety of poisonous ingredients…

– Some become EVEN MORE DANGEROUS once the cooking process begins…

Common Ingredients to Make Methamphetamine

Reagent Chemicals

• Reagent Chemicals:

– Chemicals which REACT upon the precursor chemical causing it to chemicallyCHANGE.

• A reagent chemical is a chemical which is required for the synthesis of an illicit drug substance, but which is NOT incorporated into the final chemical product.

Hydrochloric Acid

• Hydrochloric acid is a highly corrosive liquid that is used to make plastic (such as PVC pipe and polyurethane).

– It can remove rust and iron-oxide from steel and is highly corrosive to human

skin.

•Hydrochloric acid makes up the majority of the gastric acid in the human

digestive fluid.

• In high concentrations, hydrochloric acid will literally eat away human flesh…

Hydrochloric Acid (Continued)

• Hydrochloric acid can be purchased from hardware stores as:

– Tile and Grout Acid Cleaner

– Muriatic Acid

– Pool Acid

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

• Hydrochloric acid is a solution of hydrogen chloride gas suspended in water.

– Hydrochloric acid is corrosive and is a light yellow liquid color from traces of iron, chlorine, and organic matter.

• Inhaling hydrochloric acid may cause coughing or choking, inflammation, and

ulceration of the respiratory tract.

• Concentrated solutions of hydrochloric acid can cause severe burns and irritate the

mucous membranes, eyes, and respiratory tract.

– Exposure to hydrochloric acid vapors may result in pulmonary edema and

possibly death.

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

Sodium Hydroxide (NaOH)

• Sodium hydroxide is also called Lye.

• Sodium hydroxide is classified as a corrosive, and it is one of the main chemicals in

drain cleaner.

– It is also used in aluminum etching and to create biodiesal.

– It can burn the skin or cause blindness.

• Sodium hydroxide is used to dispose of road kill because it turns the dead bodies

into a coffee-like liquid.

Sodium Hydroxide (NaOH) (Continued)

• Drain cleaner (sodium hydroxide) is extremely corrosive, and without wearing

protection, even the smallest spill on the skin can eat through flesh…

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sulfuric Acid (H2SO4)

• Sulfuric acid is used in drain or toilet bowl cleaner as well as battery acid.

– It is another highly corrosive substance that burns the skin on contact.

Sulfuric Acid (H2SO4) (Continued)

• The product label warning for Drano® (sulfuric acid) says it all:

– DANGER: MAY BURN EYES AND SKIN ON CONTACT.

•HARMFUL IF SWALLOWED.

–Avoid contact with body and clothing.

•TOXIC GAS MAY FORM IF MIXED WITH OTHER CHEMICALS.

–If gases are released, leave immediately and ventilate area.

•FIRST AID: Give Immediately:

–EYES AND SKIN:

»Flush with water for 20 minutes.

»Remove affected clothing.

–IF SWALLOWED:

»Rinse mouth and drink a glass of water or milk.

»Do not induce vomiting.

–THEN SEEK MEDICAL AID.

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Hypophosphorous Acid (H3PO2)

• Hypophosphorous acid, which is used legally for a variety of commercial purposes,

is a chemical that increasingly is substituted for red phosphorus in the methamphetamine production process.

– The use of hypophospherous acid SIGNIFICANTLY increases the risk of fire!!!

• The federal government regulates the sale of hypophosphorous acid through registration, record keeping, reporting, and import/export requirements regardless

of the quantity being handled or distributed.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid is a colorless oily liquid that emits a SOUR odor.

– There is an extreme fire and explosion hazard if the hypophosphorous acid

comes into contact with a solvent such as acetone, toluene, or Coleman fuel.

• Hypophosphorous acid will also emit phosphine gas and the fumes can ignite.

Hypophosphorous Acid (H3PO2) (Continued)

• Although hypophosphorous acid is a List I chemical under the Controlled Substances Act, methamphetamine producers typically purchase the chemical via

the internet or from associates who also are engaged in methamphetamine

production.

– The use of hypophosphorous acid in methamphetamine production is an

EXTREMELY DANGEROUS PRACTICE because of the deadly gases that can be generated as well as the risk of fire or explosion.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid (H3PO2, also called phosphinic acid) is a strong acid that

typically is prepared as a solution of colorless, oily liquid in strengths of 50%, 30 to 32%, and 10%.

– It also is prepared in the form of salts (referred to as hypophosphite salts), particularly ammonium hypophosphite, calcium hypophosphite, iron (ferric)

hypophosphite, magnesium hypophosphite, manganese hypophosphite,

potassium hypophosphite, and sodium hypophosphite.

Hypophosphorous Acid (H3PO2) (Continued)

• Over 100 chemical firms located throughout the world produce hypophosphorous

acid.

– The People's Republic of China and India have the largest numbers of

hypophosphorous acid producers, although there are a few producers in the United States.

• There are a wide variety of uses for hypophosphorous acid and its salts in

commercial industry; however, the chemicals have no legitimate household or retail uses.

Hypophosphorous Acid (H3PO2) (Continued)

• The legitimate commercial and laboratory fields that use hypophosphorous acid and its salts include the following:

– Chemical plating

– Food preparation

– Water treatment

– Polymers (as a bleaching agent, color stabilizer, or catalyst)

– Education and research in analytical chemistry

Hypophosphorous Acid (H3PO2) (Continued)

• Chemical suppliers typically distribute hypophosphorous acid in large quantities, for example, in drums containing 275 pounds of the diluted solution.

– Hypophosphorous acid also is distributed in smaller quantities.

• One-half liter of 50% concentrate hypophosphorous acid solution can be obtained from chemical suppliers for as little as $14.

Hypophosphorous Acid (H3PO2) (Continued)

• Methamphetamine laboratory operators typically obtain small quantities of the chemical from other laboratory operators who purchase large quantities of the

chemical and repackage it for further distribution.

– According to law enforcement sources, these individuals sell hypophosphorous acid for as much as $1,000 per half-liter.

•Methamphetamine laboratory operators also purchase hypophosphorous acidvia the internet.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid and the Internet

• The internet is a source of a great deal of information regarding hypophosphorous acid.

• Popular internet sites that disseminate information about illicit drugs contain information about the chemical, including numerous recipes for home production of

methamphetamine using hypophosphorous acid.

• There also are recipes for synthesizing hypophosphorous acid from available chemicals.

• Hypophosphorous acid solutions and salts have been sold to the general public via the internet.

• The Drug Enforcement Administration (DEA) has strong concerns regarding the sale

of chemicals on the internet and has requested that any sites (such as auction sites) that allow the sale of regulated chemicals on their domains require proof of

DEA registration from their clients.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid Used in Methamphetamine Production

• Hypophosphorous acid is used in the ephedrine-pseudoephedrine reduction method

of methamphetamine production.

– It is used in the methamphetamine production process to produce hydriodic acid,

an important reagent (it reacts with the ephedrine-pseudoephedrine but does NOT become part of the finished product).

Hypophosphorous Acid (H3PO2) (Continued)

• The regulation of hydriodic acid by DEA in 1993 rendered it virtually unavailable in

the United States.

– However, methamphetamine laboratory operators discovered methods to

produce hydriodic acid using a combination of iodine in water with red phosphorus.

• Laboratory operators found that red phosphorus could be obtained easily, either

from commercial supply companies or by scraping the striker pads from matchbooks or matchboxes.

• Methamphetamine producers soon discovered that hypophosphorous acid ALSO could be used in combination with iodine and water to produce hydriodic acid.

Hypophosphorous Acid (H3PO2) (Continued)

• The practice of using hypophosphorous acid in methamphetamine production is

believed to have begun in the United States in the late 1990s when a methamphetamine producer in Colorado obtained the recipe from Australia, where

the hypophosphorous acid method is prevalent.

– This man was known as a serial cook who had a long history of

methamphetamine production.

•Over several years he trained other laboratory operators in Colorado to produce methamphetamine using hypophosphorous acid.

• As his techniques were passed on to others, the number of methamphetaminelaboratories in Colorado using hypophosphorous acid continued to increase, and the

technique was passed on to numerous methamphetamine producers in other

states.

Hypophosphorous Acid (H3PO2) (Continued)

• According to the El Paso Intelligence Center (EPIC) National Clandestine Laboratory

Seizure System, from 2000 through 2002 the number of seized methamphetaminelaboratories in the United States in which hypophosphorous acid was found

increased overall. (See Table 1.)

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid found at methamphetamine laboratories is packaged in a variety of ways.

• The chemical has been found in 1-gallon bottles of solution or in 1-pound jars of salts.

• Some hypophosphorous acid containers are labeled as "plating solution."

• Pint-sized brown glass bottles wrapped in red electrical tape also have been found to contain hypophosphorous acid; they have been discovered primarily in Colorado.

• The vast majority of hypophosphorous acid found at laboratory sites has been recovered from small toxic laboratories (STLs), those which yield gram to ounce

quantities per production cycle.

• Hypophosphorous acid has not been reported at large-scale laboratories operated by Mexican criminal groups in the United States.

Hypophosphorous Acid (H3PO2) (Continued)

• Hazards

• The iodine-hypophosphorous acid method is MORE HAZORDOUS than the iodine-

red phosphorus method, although the reaction using hypophosphorous acid is

faster and gives slightly higher yields.

– When hypophosphorous acid is used, the chemicals must be mixed together

SLOWLY in a PARTICULAR ORDER to prevent them from reacting violently.

Hypophosphorous Acid (H3PO2) (Continued)

• The combination of hypophosphorous acid with the other chemicals and with

certain metals can produce deadly phosphine gas during the initial mixing step and

can CONTINUE to produce phosphine gas for several days AFTER production has been completed…

Hypophosphorous Acid (H3PO2) (Continued)

• The iodine-hypophosphorous acid mixture has a tendency to decompose quickly when overheated or if heated for long periods of time, becoming cloudy or "milky-

white" just prior to giving off a cloud of phosphine gas that can ignite spontaneously.

– Hypophosphorous acid solutions may become unstable if evaporation results in

concentrations above 50%.

Hypophosphorous Acid (H3PO2) (Continued)

• [Note: Law enforcement or emergency personnel who encounter suspected

containers of hypophosphorous acid should use extreme care during handling because laboratory operators often attempt to obtain a more concentrated acid by

allowing water to evaporate from the mixture.]

• Because hypophosphorous acid often is used at small methamphetaminelaboratories operated by inexperienced or careless individuals, the potential hazards

of using this method are even greater.

• The risk of fire and explosion is higher in these laboratories, where professional

laboratory equipment typically is not used to contain the phosphine gas and where

safe handling precautions are not employed.

• In addition, these laboratories often are located in homes where children are

present and may come into contact with hypophosphorous acid.

• A child can easily mistake hypophosphorous acid for any other clear liquid, particularly if it is stored in household containers or drinking glasses.

• Skin, eye, or inhalation exposure can be extremely harmful or fatal.

Hypophosphorous Acid (H3PO2) (Continued)

• Safety Precautions

• Always wear a self-contained breathing apparatus as well as protective clothing when entering areas where hypophosphorous acid may be present.

• When in contact with metals or in a high-temperature environment,

hypophosphorous acid can break down and liberate phosphine and flammable hydrogen gas.

• Do not allow the use of open flames, open lights, matches, or smoking in or around laboratories or dumpsites where hypophosphorous acid is handled.

• In case of fire, use a self-contained positive pressure breathing apparatus and full

protective equipment.

• Use water spray, fog, foam, dry chemicals, or other reagents as may be

appropriate for materials in the surrounding fire.

• Water may be used to cool the containers of hypophosphorous acid; however, use extreme care to avoid allowing water to enter the container.

• In case of spills, neutralize the spilled chemical with alkaline material (soda ash, lime), then absorb it with an inert material such as vermiculite, dry sand, or earth

and place in a chemical waste container.

• Do not use combustible materials such as sawdust.

Hypophosphorous Acid (H3PO2) (Continued)

• Legislation and Control

• In the United States hypophosphorous acid is one of 38 chemicals (or groups of

chemicals) controlled under law by DEA.

• On October 17, 2001, hypophosphorous acid and its salts, along with red and white phosphorus, were officially added as List I chemicals under section 1310 of the

Code of Federal Regulations.

• List I chemicals are defined as chemicals that are used in the manufacture of a

controlled substance in violation of the Controlled Substances Act (CSA) and are

important to the manufacture of a controlled substance.

• Under the law, suppliers are required to maintain records and report receipts, sales, imports, and exports of these chemicals to DEA.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid, red phosphorus, and white phosphorus, as well as

ephedrine, are unique in that suppliers are required to report all transactions of

these chemicals, regardless of the amount.

• By contrast, the other 34 listed chemicals are only reportable after a supplier's

transactions for a chemical reach an established weight or volume threshold in a calendar month.

• In addition to reporting all transactions involving the chemical, suppliers are

expected to "know their customers" in order to prevent the diversion of these substances to methamphetamine laboratories, as it is illegal to import, export, purchase, or sell hypophosphorous acid or any other listed chemical in the United States if it is used or intended to be used in the production of a controlled

substance.

• Chemical suppliers are held liable for selling listed chemicals if they know or suspect that the chemical will be used for illicit purposes.

Hypophosphorous Acid (H3PO2) (Continued)

• Outlook

• The use of hypophosphorous acid in the production of methamphetamine is likely

to increase, particularly in the Midwest and Southwest regions of the United States

where methamphetamine production is prevalent.

– Injuries, property damage, and deaths also will increase as a growing number of inexperienced methamphetamine producers experiment with hypophosphorous acid.

Anhydrous Ammonia

• Anhydrous ammonia is found in fertilizer, countertop cleaner, and commercial refrigerant.

– On its own, it has a pungent, suffocating odor.

• Mixing anhydrous ammonia with other chemicals can release highly toxic gases.

– Because anhydrous ammonia seeks out water (anhydrous means “without

water”) and causes severe burns, any body part that comes into contact with it should be flushed with water for at least 15 minutes to remove the ammoniafrom the skin.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia has extremely destructive effects on humans.

– Anhydrous ammonia gives off vapors during cooking that can burn the mouth,

throat, and lung tissue.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Anhydrous ammonia seeks water from the nearest source, including the human body (anhydrous means “without water”).

– Because of their high moisture content, EYES, LUNGS, and SKIN are at the

greatest risk of attracting the ammonia.

• When large amounts of anhydrous ammonia are inhaled, the throat swells and the

victim suffocates.

– Exposure to the vapors or liquids can cause severe burns, blindness, or death.

• Anhydrous ammonia has an IDLH (immediately dangerous to life and health) at

only 300 parts per million...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is poses MANY hazards, especially when it is placed in improper vessels and handled/transported by individuals unfamiliar with the

dangers.

• Anhydrous ammonia has a boiling point of -28 degrees below zero.

– When a vessel containing anhydrous ammonia is MOVED, the anhydrous

ammonia will reach its boiling point and pressurize.

•This pressurization can cause vessels to violently RUPTURE, or if the vessel pressurizes and does NOT rupture, the opening of the container of anhydrous

ammonia at a later time can cause RAPID, VIOLENT depressurization.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is mainly used in the U.S. as either a fertilizer or a refrigerant.

– Meth producers tend to store the anhydrous ammonia in IMPROPER/UNAPPROVED containers such as:

•Propane tanks,

• Igloo coolers, or

•Fire extinguishers.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia leaves a tell-tell sign as it flows through these UNAPPROVED

CONTAINERS – a blue or blue green discoloration on the valve.

– PAY ATTENTION to details!!!

Anhydrous Ammonia (Continued)

• Because propane cylinders (and the other unapproved containers) are NOT designed to store anhydrous ammonia, they can EXPLODE as the ammonia eats

through the walls of the cylinders.

– The valves, which take on a bluish/green color, frequently deteriorate and can cause hazardous leaks!!!

Anhydrous Ammonia (Continued)

• Do NOT touch, move, or open any kind of tank or sealed container!!!

– Be aware that propane tanks are often WEAKENED and BRITTLE due to the

anhydrous ammonia and are SENSITIVE to ANY kind of movement or impact.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• These pictures show what happened to a fire extinguisher that was used to store

anhydrous ammonia…

Anhydrous Ammonia (Continued)

• Illegal drug makers often STEAL anhydrous ammonia from areas where it is stored

and used, such as farms.

• Attempted thefts have also occurred at places such as:

– Refrigeration systems holding ammonia,

– Underground pipelines carrying ammonia, and

– Rail cars transporting anhydrous ammonia.

• Often thefts are aborted when thieves are injured or overcome by the toxic gas...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia thieves had better beware!!!

• There is a new product called GloTell that farmers can add to their anhydrous

ammonia tanks…

• Meth cooks will run the risk that the GloTell additive will turn their hands bright

pink!

– This bright pink stain will fluoresce under ultraviolet light even if washed off!!!

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Also, GloTell will produce pink methamphetamine that CANNOT be bleached.

– Users who snort meth made with GloTell will find that they have PINK NOSES!

– Users who inject meth made with GloTell will see a pink stain at the point of

injection!

Sodium Carbonate (Soda Ash)

Sodium Carbonate (Soda Ash) (Continued)

Lead Acetate

Iodine

• Iodine is a natural element, and it is helpful to the body in SMALL amounts.

– However, if iodine is taken in large amounts it can become toxic.

•Extremely high does of iodine can limit the function of the thyroid.

Iodine (Continued)

Iodine (Continued)

• Iodine is bluish-black, and it has a characteristic odor, a sharp acrid taste, and it produces a violet corrosive vapor.

– The vapor is irritating to the respiratory system and eyes.

• The solid iodine irritates the eyes and may burn the skin, and it may cause severe

internal irritation and damage if ingested.

Iodine (Continued)

• Iodine is known as the “blue ingredient” in the production of meth (in the “red, white, and blue” method).

Iodine (Continued)

Iodine (Continued)

• It takes approximately 4 bottles of iodine tincture to produce 2 – 3 grams of meth.

Iodine (Continued)

Iodine (Continued)

• Iodine leaves distinctive yellow-blue or brown stains on surfaces in former methlabs.

Iodine (Continued)

Iodine (Continued)

Iodine (Continued)

• The only good thing about iodine is that it leaves yellow stains.

• If you see yellow stained coffee filters, gloves or paper towels, this could be an

indicator that you’re in a lab.

• If you see yellow stains, you can spray some starch on them.

– If they turn a purplish blue/black, it’s iodine.

• Iodine is the only substance that reacts with soluble starch to produce a purplish black color.

– The only way to get iodine vapor all over the walls is to cook meth.

Mercurous Chloride

Rock Salt

Hydrogen Chloride

• Hydrogen chloride gas is commercially available.

• Hydrogen chloride gas can also be made by mixing sulfuric acid and salt.

• Muriatic acid is simply hydrogen chloride gas suspended in water.

• Hydrogen chloride gas can be seen as a pale white smoke.

– It is a poisonous gas that can cause respiratory problems and death.

Hydrogen Chloride (Continued)

Ammonium Nitrate

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Hydriodic Acid

• Hydriodic acid is a corrosive acid that is colorless when freshly prepared.

– When hydriodic acid is exposed to light and air, it turns yellowish and brown.

• Hydriodic acid is a solution of hydrogen iodide gas in water.

• Hydriodic acid vapor is irritating to the respiratory system, skin, and eyes.

• Hydriodic acid liquid causes severe burns to the eyes and skin.

• If hydriodic acid is accidentally ingested, it can cause severe internal irritation and

damage.

Hydriodic Acid (Continued)

Catalyst Chemicals

• Catalyst Chemicals:

– Chemicals which SPEED UP a reaction process and/or cause it to go to GREATER COMPLETION.

Red Phosphorus

• Red phosphorus is found ON matchboxes, in road flares, and other explosives.

– Red Phosphorus IGNITES when OVERHEATED!!!

• By combining red phosphorus and iodine, you can easily create the highly

controlled substance known as hydriodic acid (which is an essential ingredient in making meth).

– Creating 2 – 3 grams of meth requires about 4 big boxes of matches.

Red Phosphorus (Continued)

• Red phosphorous is highly flammable and if it is overheated it can become white

phosphorous…

– White phosphorous is a volatile and highly explosive substance.

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Lithium

• Lithium is used in batteries.

• Lithium seriously burns the skin upon contact.

– It also reacts VIOLENTLY with WATER and is highly explosive.

Lithium (Continued)

• Lithium reacts VIOLENTLY with WATER, and if it is splashed in the eyes during

cooking it will cause blindness.

– Lithium is extremely caustic to all body tissues.

Lithium (Continued)

Lithium (Continued)

• Lithium metal is HIGHLY water reactive and it will BURN or EXPLODE if it comes into contact with WATER!

• Because of the moisture in your skin, it will burn exposed flesh.

• Lithium metal will DEGRADE when exposed to atmospheric moisture…

– This is why meth cooks store lithium metal in a solvent prior to use.

• It is typical to see harvested lithium strips in Coleman fuel or Mineral Spirits to prevent explosions.

•Large quantities can be harvested and saved in these containers until needed

for a cook.

Lithium (Continued)

• If you see battery shells in the trashcan, on the floor, etc. – this is a VERY GOOD

indicator that you might be entering a meth lab!

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

• Lithium catches fire when in contact with water...

Solvent Chemicals

• Solvent Chemicals:

– A medium (liquid) in which a chemical operation takes place.

• Solvent chemicals (UNLIKE the precursor chemicals) CAN be

substituted/interchanged.

Ether

• Ether was once called “sweet vitriol” because of its hypnotic effect.

• Ether is a highly flammable substance that is used as an anesthetic agent –

especially in third world countries where more expensive anesthesia is not available.

– While inhaling the ether, patients could undergo complete surgical procedures while otherwise awake without feeling pain or concern.

Ether (Continued)

• Ether can be obtained from engine starting fluid.

• Ether is a solvent and it is flammable.

– It is particularly hazardous because it can cause BOTH fire and explosion.

• It has been said that a quart of ether can “level” a small house.

Ethyl Ether (Continued)

Ethyl Ether (Continued)

• Ether is VERY flammable and is HEAVIER than air.

– NEVER use ether near flames or non-sparkless motors.

– Ether is very PUNGENT – even a small evaporated amount of ether is VERY noticeable.

Acetone

• Acetone can be found in nail polish remover or paint thinner.

– It is extremely flammable.

• In the setting of a meth lab where meth is being cooked with high heat, acetone is

very dangerous.

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Toluene

• Toluene is used in brake fluid.

– When working with brake fluid (toluene), be careful not to spill it on your car

because it will eat away the paint and chrome…

• You also have to be careful using toluene around other household chemicals

because its high concentration of polyethylene glycol can cause it to ignite in a

violent fireball.

• Toluene is powerful enough to dissolve rubber.

Toluene (Continued)

• Toluene is used to form meth crystals.

– The fumes toluene releases can cause brain damage or death.

Toluene (Continued)

Toluene (Continued)

Ethanol

Isopropanol

Isopropanol (Continued)

Isopropyl Alcohol

Methanol

Methanol (Continued)

Methanol (Continued)

Benzene

Benzene (Continued)

Which of these is NOT a common ingredient in Meth?

Nail Polish Remover

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Methamphetamine- PowerPoint

- Chemicals and Ingredients Used to Make Meth

CJUS 240

Economic Costs of Meth

• The economic cost of methamphetamine use in the U.S. reached $23.4 billion in

2005.

– This includes the burden of addiction, premature death, drug treatment, child

care, and cleaning of lab sites.

– This figure does NOT take into account the future needs of the meth user.

Concerns with ACTIVE Meth Labs

• Danger of fire and explosion

• Chemical spills

• Inhalation of solvents, corrosives, and toxic gases

• “Booby traps”

• Waste disposal

Concerns with FORMER Meth Labs

• Vapors

• Chemical residues

• Methamphetamine residues

• Waste disposal

Equipment Used in Meth Production

• Pyrex or Corning dishes

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

• Coffee Filters

Equipment Used in Meth Production

Equipment Used in Meth Production

Basic Chemical Requirements

• In a clandestine laboratory, basic types of chemicals are necessary in order to

produce the desired drug.

– The basic types of chemicals needed are:

1) Precursor Chemicals

2) Reagent Chemicals

3) Catalyst Chemicals

4) Solvent Chemicals

List I Chemical

• The term “List I chemical” means a chemical specified by regulation of the Attorney General as a chemical that is used in manufacturing a controlled substance and is

IMPORTANT to the manufacture of the controlled substance.

• Examples of List I chemicals are:

– GBL

– Red Phosphorus

– Pseudoephedrine

List II Chemical

• The term “List II chemical” means a chemical (other than a List I chemical) specified by regulation of the Attorney General as a chemical that is USED in

manufacturing a controlled substance.

• Examples of List II chemicals are:

– Toluene

– Iodine

– Hydrochloric Acid

Precursor Chemicals

• Precursor Chemicals:

– A chemical that is ESSENTIAL to the production of a controlled substance and for

which NO SUBSTITUTION can be made.

Pseudoephedrine

• Pseudoephedrine is a decongestant found in cold medicine.

– Large amounts of pseudoephedrine on its own can harm the respiratory and nervous systems, as well as the heart.

Pseudoephedrine (Continued)

• Some of the common ways used to divert products containing pseudoephedrine

include:

– “Smurfing” – making multiple purchases at different locations

– Shelf-Sweeping – the theft of all shelf stock

– Shoplifting

– Theft from wholesalers

Pseudoephedrine (Continued)

• Pseudoephedrine smurfing is a method used by some methamphetamine producers to acquire large quantities of pseudoephedrine by enlisting the assistance of several

friends or associates (often referred to as “smurfers”) to make purchases at or below the legal thresholds from multiple retail locations.

– Smurfers are often addicts who trade the pseudoephedrine for finished

methamphetamine.

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

• About 680 pseudoephedrine tablets are needed to produce one ounce of meth…

Pseudoephedrine (Continued)

Out With a Bang

An Unstable Recipe…

• Meth contains a variety of poisonous ingredients…

– Some become EVEN MORE DANGEROUS once the cooking process begins…

Common Ingredients to Make Methamphetamine

Reagent Chemicals

• Reagent Chemicals:

– Chemicals which REACT upon the precursor chemical causing it to chemicallyCHANGE.

• A reagent chemical is a chemical which is required for the synthesis of an illicit drug substance, but which is NOT incorporated into the final chemical product.

Hydrochloric Acid

• Hydrochloric acid is a highly corrosive liquid that is used to make plastic (such as PVC pipe and polyurethane).

– It can remove rust and iron-oxide from steel and is highly corrosive to human

skin.

•Hydrochloric acid makes up the majority of the gastric acid in the human

digestive fluid.

• In high concentrations, hydrochloric acid will literally eat away human flesh…

Hydrochloric Acid (Continued)

• Hydrochloric acid can be purchased from hardware stores as:

– Tile and Grout Acid Cleaner

– Muriatic Acid

– Pool Acid

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

• Hydrochloric acid is a solution of hydrogen chloride gas suspended in water.

– Hydrochloric acid is corrosive and is a light yellow liquid color from traces of iron, chlorine, and organic matter.

• Inhaling hydrochloric acid may cause coughing or choking, inflammation, and

ulceration of the respiratory tract.

• Concentrated solutions of hydrochloric acid can cause severe burns and irritate the

mucous membranes, eyes, and respiratory tract.

– Exposure to hydrochloric acid vapors may result in pulmonary edema and

possibly death.

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

Sodium Hydroxide (NaOH)

• Sodium hydroxide is also called Lye.

• Sodium hydroxide is classified as a corrosive, and it is one of the main chemicals in

drain cleaner.

– It is also used in aluminum etching and to create biodiesal.

– It can burn the skin or cause blindness.

• Sodium hydroxide is used to dispose of road kill because it turns the dead bodies

into a coffee-like liquid.

Sodium Hydroxide (NaOH) (Continued)

• Drain cleaner (sodium hydroxide) is extremely corrosive, and without wearing protection, even the smallest spill on the skin can eat through flesh…

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sulfuric Acid (H2SO4)

• Sulfuric acid is used in drain or toilet bowl cleaner as well as battery acid.

– It is another highly corrosive substance that burns the skin on contact.

Sulfuric Acid (H2SO4) (Continued)

• The product label warning for Drano® (sulfuric acid) says it all:

– DANGER: MAY BURN EYES AND SKIN ON CONTACT.

•HARMFUL IF SWALLOWED.

–Avoid contact with body and clothing.

•TOXIC GAS MAY FORM IF MIXED WITH OTHER CHEMICALS.

–If gases are released, leave immediately and ventilate area.

•FIRST AID: Give Immediately:

–EYES AND SKIN:

»Flush with water for 20 minutes.

»Remove affected clothing.

–IF SWALLOWED:

»Rinse mouth and drink a glass of water or milk.

»Do not induce vomiting.

–THEN SEEK MEDICAL AID.

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Hypophosphorous Acid (H3PO2)

• Hypophosphorous acid, which is used legally for a variety of commercial purposes,

is a chemical that increasingly is substituted for red phosphorus in the methamphetamine production process.

– The use of hypophospherous acid SIGNIFICANTLY increases the risk of fire!!!

• The federal government regulates the sale of hypophosphorous acid through registration, record keeping, reporting, and import/export requirements regardless

of the quantity being handled or distributed.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid is a colorless oily liquid that emits a SOUR odor.

– There is an extreme fire and explosion hazard if the hypophosphorous acid

comes into contact with a solvent such as acetone, toluene, or Coleman fuel.

• Hypophosphorous acid will also emit phosphine gas and the fumes can ignite.

Hypophosphorous Acid (H3PO2) (Continued)

• Although hypophosphorous acid is a List I chemical under the Controlled Substances Act, methamphetamine producers typically purchase the chemical via

the internet or from associates who also are engaged in methamphetamine

production.

– The use of hypophosphorous acid in methamphetamine production is an

EXTREMELY DANGEROUS PRACTICE because of the deadly gases that can be generated as well as the risk of fire or explosion.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid (H3PO2, also called phosphinic acid) is a strong acid that

typically is prepared as a solution of colorless, oily liquid in strengths of 50%, 30 to 32%, and 10%.

– It also is prepared in the form of salts (referred to as hypophosphite salts), particularly ammonium hypophosphite, calcium hypophosphite, iron (ferric)

hypophosphite, magnesium hypophosphite, manganese hypophosphite,

potassium hypophosphite, and sodium hypophosphite.

Hypophosphorous Acid (H3PO2) (Continued)

• Over 100 chemical firms located throughout the world produce hypophosphorous

acid.

– The People's Republic of China and India have the largest numbers of

hypophosphorous acid producers, although there are a few producers in the United States.

• There are a wide variety of uses for hypophosphorous acid and its salts in

commercial industry; however, the chemicals have no legitimate household or retail uses.

Hypophosphorous Acid (H3PO2) (Continued)

• The legitimate commercial and laboratory fields that use hypophosphorous acid and its salts include the following:

– Chemical plating

– Food preparation

– Water treatment

– Polymers (as a bleaching agent, color stabilizer, or catalyst)

– Education and research in analytical chemistry

Hypophosphorous Acid (H3PO2) (Continued)

• Chemical suppliers typically distribute hypophosphorous acid in large quantities, for example, in drums containing 275 pounds of the diluted solution.

– Hypophosphorous acid also is distributed in smaller quantities.

• One-half liter of 50% concentrate hypophosphorous acid solution can be obtained from chemical suppliers for as little as $14.

Hypophosphorous Acid (H3PO2) (Continued)

• Methamphetamine laboratory operators typically obtain small quantities of the chemical from other laboratory operators who purchase large quantities of the

chemical and repackage it for further distribution.

– According to law enforcement sources, these individuals sell hypophosphorous acid for as much as $1,000 per half-liter.

•Methamphetamine laboratory operators also purchase hypophosphorous acidvia the internet.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid and the Internet

• The internet is a source of a great deal of information regarding hypophosphorous acid.

• Popular internet sites that disseminate information about illicit drugs contain information about the chemical, including numerous recipes for home production of

methamphetamine using hypophosphorous acid.

• There also are recipes for synthesizing hypophosphorous acid from available chemicals.

• Hypophosphorous acid solutions and salts have been sold to the general public via the internet.

• The Drug Enforcement Administration (DEA) has strong concerns regarding the sale of chemicals on the internet and has requested that any sites (such as auction sites) that allow the sale of regulated chemicals on their domains require proof of

DEA registration from their clients.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid Used in Methamphetamine Production

• Hypophosphorous acid is used in the ephedrine-pseudoephedrine reduction method

of methamphetamine production.

– It is used in the methamphetamine production process to produce hydriodic acid,

an important reagent (it reacts with the ephedrine-pseudoephedrine but does NOT become part of the finished product).

Hypophosphorous Acid (H3PO2) (Continued)

• The regulation of hydriodic acid by DEA in 1993 rendered it virtually unavailable in

the United States.

– However, methamphetamine laboratory operators discovered methods to

produce hydriodic acid using a combination of iodine in water with red phosphorus.

• Laboratory operators found that red phosphorus could be obtained easily, either

from commercial supply companies or by scraping the striker pads from matchbooks or matchboxes.

• Methamphetamine producers soon discovered that hypophosphorous acid ALSO could be used in combination with iodine and water to produce hydriodic acid.

Hypophosphorous Acid (H3PO2) (Continued)

• The practice of using hypophosphorous acid in methamphetamine production is

believed to have begun in the United States in the late 1990s when a methamphetamine producer in Colorado obtained the recipe from Australia, where

the hypophosphorous acid method is prevalent.

– This man was known as a serial cook who had a long history of

methamphetamine production.

•Over several years he trained other laboratory operators in Colorado to produce methamphetamine using hypophosphorous acid.

• As his techniques were passed on to others, the number of methamphetaminelaboratories in Colorado using hypophosphorous acid continued to increase, and the

technique was passed on to numerous methamphetamine producers in other states.

Hypophosphorous Acid (H3PO2) (Continued)

• According to the El Paso Intelligence Center (EPIC) National Clandestine Laboratory

Seizure System, from 2000 through 2002 the number of seized methamphetaminelaboratories in the United States in which hypophosphorous acid was found

increased overall. (See Table 1.)

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid found at methamphetamine laboratories is packaged in a variety of ways.

• The chemical has been found in 1-gallon bottles of solution or in 1-pound jars of salts.

• Some hypophosphorous acid containers are labeled as "plating solution."

• Pint-sized brown glass bottles wrapped in red electrical tape also have been found to contain hypophosphorous acid; they have been discovered primarily in Colorado.

• The vast majority of hypophosphorous acid found at laboratory sites has been recovered from small toxic laboratories (STLs), those which yield gram to ounce

quantities per production cycle.

• Hypophosphorous acid has not been reported at large-scale laboratories operated by Mexican criminal groups in the United States.

Hypophosphorous Acid (H3PO2) (Continued)

• Hazards

• The iodine-hypophosphorous acid method is MORE HAZORDOUS than the iodine-

red phosphorus method, although the reaction using hypophosphorous acid is

faster and gives slightly higher yields.

– When hypophosphorous acid is used, the chemicals must be mixed together

SLOWLY in a PARTICULAR ORDER to prevent them from reacting violently.

Hypophosphorous Acid (H3PO2) (Continued)

• The combination of hypophosphorous acid with the other chemicals and with

certain metals can produce deadly phosphine gas during the initial mixing step and

can CONTINUE to produce phosphine gas for several days AFTER production has been completed…

Hypophosphorous Acid (H3PO2) (Continued)

• The iodine-hypophosphorous acid mixture has a tendency to decompose quickly when overheated or if heated for long periods of time, becoming cloudy or "milky-

white" just prior to giving off a cloud of phosphine gas that can ignite spontaneously.

– Hypophosphorous acid solutions may become unstable if evaporation results in

concentrations above 50%.

Hypophosphorous Acid (H3PO2) (Continued)

• [Note: Law enforcement or emergency personnel who encounter suspected

containers of hypophosphorous acid should use extreme care during handling because laboratory operators often attempt to obtain a more concentrated acid by allowing water to evaporate from the mixture.]

• Because hypophosphorous acid often is used at small methamphetaminelaboratories operated by inexperienced or careless individuals, the potential hazards

of using this method are even greater.

• The risk of fire and explosion is higher in these laboratories, where professional

laboratory equipment typically is not used to contain the phosphine gas and where

safe handling precautions are not employed.

• In addition, these laboratories often are located in homes where children are

present and may come into contact with hypophosphorous acid.

• A child can easily mistake hypophosphorous acid for any other clear liquid,

particularly if it is stored in household containers or drinking glasses.

• Skin, eye, or inhalation exposure can be extremely harmful or fatal.

Hypophosphorous Acid (H3PO2) (Continued)

• Safety Precautions

• Always wear a self-contained breathing apparatus as well as protective clothing when entering areas where hypophosphorous acid may be present.

• When in contact with metals or in a high-temperature environment,

hypophosphorous acid can break down and liberate phosphine and flammable hydrogen gas.

• Do not allow the use of open flames, open lights, matches, or smoking in or around laboratories or dumpsites where hypophosphorous acid is handled.

• In case of fire, use a self-contained positive pressure breathing apparatus and full

protective equipment.

• Use water spray, fog, foam, dry chemicals, or other reagents as may be

appropriate for materials in the surrounding fire.

• Water may be used to cool the containers of hypophosphorous acid; however, use extreme care to avoid allowing water to enter the container.

• In case of spills, neutralize the spilled chemical with alkaline material (soda ash, lime), then absorb it with an inert material such as vermiculite, dry sand, or earth

and place in a chemical waste container.

• Do not use combustible materials such as sawdust.

Hypophosphorous Acid (H3PO2) (Continued)

• Legislation and Control

• In the United States hypophosphorous acid is one of 38 chemicals (or groups of

chemicals) controlled under law by DEA.

• On October 17, 2001, hypophosphorous acid and its salts, along with red and white phosphorus, were officially added as List I chemicals under section 1310 of the

Code of Federal Regulations.

• List I chemicals are defined as chemicals that are used in the manufacture of a

controlled substance in violation of the Controlled Substances Act (CSA) and are

important to the manufacture of a controlled substance.

• Under the law, suppliers are required to maintain records and report receipts, sales,

imports, and exports of these chemicals to DEA.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid, red phosphorus, and white phosphorus, as well as

ephedrine, are unique in that suppliers are required to report all transactions of

these chemicals, regardless of the amount.

• By contrast, the other 34 listed chemicals are only reportable after a supplier's

transactions for a chemical reach an established weight or volume threshold in a calendar month.

• In addition to reporting all transactions involving the chemical, suppliers are

expected to "know their customers" in order to prevent the diversion of these substances to methamphetamine laboratories, as it is illegal to import, export,

purchase, or sell hypophosphorous acid or any other listed chemical in the United States if it is used or intended to be used in the production of a controlled

substance.

• Chemical suppliers are held liable for selling listed chemicals if they know or suspect that the chemical will be used for illicit purposes.

Hypophosphorous Acid (H3PO2) (Continued)

• Outlook

• The use of hypophosphorous acid in the production of methamphetamine is likely

to increase, particularly in the Midwest and Southwest regions of the United States

where methamphetamine production is prevalent.

– Injuries, property damage, and deaths also will increase as a growing number of

inexperienced methamphetamine producers experiment with hypophosphorous acid.

Anhydrous Ammonia

• Anhydrous ammonia is found in fertilizer, countertop cleaner, and commercial refrigerant.

– On its own, it has a pungent, suffocating odor.

• Mixing anhydrous ammonia with other chemicals can release highly toxic gases.

– Because anhydrous ammonia seeks out water (anhydrous means “without

water”) and causes severe burns, any body part that comes into contact with it

should be flushed with water for at least 15 minutes to remove the ammoniafrom the skin.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia has extremely destructive effects on humans.

– Anhydrous ammonia gives off vapors during cooking that can burn the mouth,

throat, and lung tissue.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Anhydrous ammonia seeks water from the nearest source, including the human body (anhydrous means “without water”).

– Because of their high moisture content, EYES, LUNGS, and SKIN are at the

greatest risk of attracting the ammonia.

• When large amounts of anhydrous ammonia are inhaled, the throat swells and the

victim suffocates.

– Exposure to the vapors or liquids can cause severe burns, blindness, or death.

• Anhydrous ammonia has an IDLH (immediately dangerous to life and health) at

only 300 parts per million...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is poses MANY hazards, especially when it is placed in improper vessels and handled/transported by individuals unfamiliar with the

dangers.

• Anhydrous ammonia has a boiling point of -28 degrees below zero.

– When a vessel containing anhydrous ammonia is MOVED, the anhydrous

ammonia will reach its boiling point and pressurize.

•This pressurization can cause vessels to violently RUPTURE, or if the vessel pressurizes and does NOT rupture, the opening of the container of anhydrous

ammonia at a later time can cause RAPID, VIOLENT depressurization.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is mainly used in the U.S. as either a fertilizer or a refrigerant.

– Meth producers tend to store the anhydrous ammonia in IMPROPER/UNAPPROVED containers such as:

•Propane tanks,

• Igloo coolers, or

•Fire extinguishers.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia leaves a tell-tell sign as it flows through these UNAPPROVED

CONTAINERS – a blue or blue green discoloration on the valve.

– PAY ATTENTION to details!!!

Anhydrous Ammonia (Continued)

• Because propane cylinders (and the other unapproved containers) are NOT designed to store anhydrous ammonia, they can EXPLODE as the ammonia eats

through the walls of the cylinders.

– The valves, which take on a bluish/green color, frequently deteriorate and can cause hazardous leaks!!!

Anhydrous Ammonia (Continued)

• Do NOT touch, move, or open any kind of tank or sealed container!!!

– Be aware that propane tanks are often WEAKENED and BRITTLE due to the

anhydrous ammonia and are SENSITIVE to ANY kind of movement or impact.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• These pictures show what happened to a fire extinguisher that was used to store

anhydrous ammonia…

Anhydrous Ammonia (Continued)

• Illegal drug makers often STEAL anhydrous ammonia from areas where it is stored

and used, such as farms.

• Attempted thefts have also occurred at places such as:

– Refrigeration systems holding ammonia,

– Underground pipelines carrying ammonia, and

– Rail cars transporting anhydrous ammonia.

• Often thefts are aborted when thieves are injured or overcome by the toxic gas...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia thieves had better beware!!!

• There is a new product called GloTell that farmers can add to their anhydrous

ammonia tanks…

• Meth cooks will run the risk that the GloTell additive will turn their hands bright

pink!

– This bright pink stain will fluoresce under ultraviolet light even if washed off!!!

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Also, GloTell will produce pink methamphetamine that CANNOT be bleached.

– Users who snort meth made with GloTell will find that they have PINK NOSES!

– Users who inject meth made with GloTell will see a pink stain at the point of

injection!

Sodium Carbonate (Soda Ash)

Sodium Carbonate (Soda Ash) (Continued)

Lead Acetate

Iodine

• Iodine is a natural element, and it is helpful to the body in SMALL amounts.

– However, if iodine is taken in large amounts it can become toxic.

•Extremely high does of iodine can limit the function of the thyroid.

Iodine (Continued)

Iodine (Continued)

• Iodine is bluish-black, and it has a characteristic odor, a sharp acrid taste, and it produces a violet corrosive vapor.

– The vapor is irritating to the respiratory system and eyes.

• The solid iodine irritates the eyes and may burn the skin, and it may cause severe

internal irritation and damage if ingested.

Iodine (Continued)

• Iodine is known as the “blue ingredient” in the production of meth (in the “red, white, and blue” method).

Iodine (Continued)

Iodine (Continued)

• It takes approximately 4 bottles of iodine tincture to produce 2 – 3 grams of meth.

Iodine (Continued)

Iodine (Continued)

• Iodine leaves distinctive yellow-blue or brown stains on surfaces in former methlabs.

Iodine (Continued)

Iodine (Continued)

Iodine (Continued)

• The only good thing about iodine is that it leaves yellow stains.

• If you see yellow stained coffee filters, gloves or paper towels, this could be an

indicator that you’re in a lab.

• If you see yellow stains, you can spray some starch on them.

– If they turn a purplish blue/black, it’s iodine.

• Iodine is the only substance that reacts with soluble starch to produce a purplish black color.

– The only way to get iodine vapor all over the walls is to cook meth.

Mercurous Chloride

Rock Salt

Hydrogen Chloride

• Hydrogen chloride gas is commercially available.

• Hydrogen chloride gas can also be made by mixing sulfuric acid and salt.

• Muriatic acid is simply hydrogen chloride gas suspended in water.

• Hydrogen chloride gas can be seen as a pale white smoke.

– It is a poisonous gas that can cause respiratory problems and death.

Hydrogen Chloride (Continued)

Ammonium Nitrate

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Hydriodic Acid

• Hydriodic acid is a corrosive acid that is colorless when freshly prepared.

– When hydriodic acid is exposed to light and air, it turns yellowish and brown.

• Hydriodic acid is a solution of hydrogen iodide gas in water.

• Hydriodic acid vapor is irritating to the respiratory system, skin, and eyes.

• Hydriodic acid liquid causes severe burns to the eyes and skin.

• If hydriodic acid is accidentally ingested, it can cause severe internal irritation and

damage.

Hydriodic Acid (Continued)

Catalyst Chemicals

• Catalyst Chemicals:

– Chemicals which SPEED UP a reaction process and/or cause it to go to GREATER COMPLETION.

Red Phosphorus

• Red phosphorus is found ON matchboxes, in road flares, and other explosives.

– Red Phosphorus IGNITES when OVERHEATED!!!

• By combining red phosphorus and iodine, you can easily create the highly

controlled substance known as hydriodic acid (which is an essential ingredient in making meth).

– Creating 2 – 3 grams of meth requires about 4 big boxes of matches.

Red Phosphorus (Continued)

• Red phosphorous is highly flammable and if it is overheated it can become white phosphorous…

– White phosphorous is a volatile and highly explosive substance.

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Lithium

• Lithium is used in batteries.

• Lithium seriously burns the skin upon contact.

– It also reacts VIOLENTLY with WATER and is highly explosive.

Lithium (Continued)

• Lithium reacts VIOLENTLY with WATER, and if it is splashed in the eyes during

cooking it will cause blindness.

– Lithium is extremely caustic to all body tissues.

Lithium (Continued)

Lithium (Continued)

• Lithium metal is HIGHLY water reactive and it will BURN or EXPLODE if it comes into contact with WATER!

• Because of the moisture in your skin, it will burn exposed flesh.

• Lithium metal will DEGRADE when exposed to atmospheric moisture…

– This is why meth cooks store lithium metal in a solvent prior to use.

• It is typical to see harvested lithium strips in Coleman fuel or Mineral Spirits to prevent explosions.

•Large quantities can be harvested and saved in these containers until needed

for a cook.

Lithium (Continued)

• If you see battery shells in the trashcan, on the floor, etc. – this is a VERY GOOD

indicator that you might be entering a meth lab!

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

• Lithium catches fire when in contact with water...

Solvent Chemicals

• Solvent Chemicals:

– A medium (liquid) in which a chemical operation takes place.

• Solvent chemicals (UNLIKE the precursor chemicals) CAN be

substituted/interchanged.

Ether

• Ether was once called “sweet vitriol” because of its hypnotic effect.

• Ether is a highly flammable substance that is used as an anesthetic agent –

especially in third world countries where more expensive anesthesia is not available.

– While inhaling the ether, patients could undergo complete surgical procedures while otherwise awake without feeling pain or concern.

Ether (Continued)

• Ether can be obtained from engine starting fluid.

• Ether is a solvent and it is flammable.

– It is particularly hazardous because it can cause BOTH fire and explosion.

• It has been said that a quart of ether can “level” a small house.

Ethyl Ether (Continued)

Ethyl Ether (Continued)

• Ether is VERY flammable and is HEAVIER than air.

– NEVER use ether near flames or non-sparkless motors.

– Ether is very PUNGENT – even a small evaporated amount of ether is VERY noticeable.

Acetone

• Acetone can be found in nail polish remover or paint thinner.

– It is extremely flammable.

• In the setting of a meth lab where meth is being cooked with high heat, acetone is

very dangerous.

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Toluene

• Toluene is used in brake fluid.

– When working with brake fluid (toluene), be careful not to spill it on your car

because it will eat away the paint and chrome…

• You also have to be careful using toluene around other household chemicals

because its high concentration of polyethylene glycol can cause it to ignite in a

violent fireball.

• Toluene is powerful enough to dissolve rubber.

Toluene (Continued)

• Toluene is used to form meth crystals.

– The fumes toluene releases can cause brain damage or death.

Toluene (Continued)

Toluene (Continued)

Ethanol

Isopropanol

Isopropanol (Continued)

Isopropyl Alcohol

Methanol

Methanol (Continued)

Methanol (Continued)

Benzene

Benzene (Continued)

Which of these is NOT a common ingredient in Meth?

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Methamphetamine- PowerPoint

- Chemicals and Ingredients Used to Make Meth

CJUS 240

Economic Costs of Meth

• The economic cost of methamphetamine use in the U.S. reached $23.4 billion in

2005.

– This includes the burden of addiction, premature death, drug treatment, child

care, and cleaning of lab sites.

– This figure does NOT take into account the future needs of the meth user.

Concerns with ACTIVE Meth Labs

• Danger of fire and explosion

• Chemical spills

• Inhalation of solvents, corrosives, and toxic gases

• “Booby traps”

• Waste disposal

Concerns with FORMER Meth Labs

• Vapors

• Chemical residues

• Methamphetamine residues

• Waste disposal

Equipment Used in Meth Production

• Pyrex or Corning dishes

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

• Coffee Filters

Equipment Used in Meth Production

Equipment Used in Meth Production

Basic Chemical Requirements

• In a clandestine laboratory, basic types of chemicals are necessary in order to

produce the desired drug.

– The basic types of chemicals needed are:

1) Precursor Chemicals

2) Reagent Chemicals

3) Catalyst Chemicals

4) Solvent Chemicals

List I Chemical

• The term “List I chemical” means a chemical specified by regulation of the Attorney General as a chemical that is used in manufacturing a controlled substance and is

IMPORTANT to the manufacture of the controlled substance.

• Examples of List I chemicals are:

– GBL

– Red Phosphorus

– Pseudoephedrine

List II Chemical

• The term “List II chemical” means a chemical (other than a List I chemical) specified by regulation of the Attorney General as a chemical that is USED in

manufacturing a controlled substance.

• Examples of List II chemicals are:

– Toluene

– Iodine

– Hydrochloric Acid

Precursor Chemicals

• Precursor Chemicals:

– A chemical that is ESSENTIAL to the production of a controlled substance and for

which NO SUBSTITUTION can be made.

Pseudoephedrine

• Pseudoephedrine is a decongestant found in cold medicine.

– Large amounts of pseudoephedrine on its own can harm the respiratory and nervous systems, as well as the heart.

Pseudoephedrine (Continued)

• Some of the common ways used to divert products containing pseudoephedrine

include:

– “Smurfing” – making multiple purchases at different locations

– Shelf-Sweeping – the theft of all shelf stock

– Shoplifting

– Theft from wholesalers

Pseudoephedrine (Continued)

• Pseudoephedrine smurfing is a method used by some methamphetamine producers to acquire large quantities of pseudoephedrine by enlisting the assistance of several

friends or associates (often referred to as “smurfers”) to make purchases at or below the legal thresholds from multiple retail locations.

– Smurfers are often addicts who trade the pseudoephedrine for finished

methamphetamine.

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

• About 680 pseudoephedrine tablets are needed to produce one ounce of meth…

Pseudoephedrine (Continued)

Out With a Bang

An Unstable Recipe…

• Meth contains a variety of poisonous ingredients…

– Some become EVEN MORE DANGEROUS once the cooking process begins…

Common Ingredients to Make Methamphetamine

Reagent Chemicals

• Reagent Chemicals:

– Chemicals which REACT upon the precursor chemical causing it to chemicallyCHANGE.

• A reagent chemical is a chemical which is required for the synthesis of an illicit drug substance, but which is NOT incorporated into the final chemical product.

Hydrochloric Acid

• Hydrochloric acid is a highly corrosive liquid that is used to make plastic (such as PVC pipe and polyurethane).

– It can remove rust and iron-oxide from steel and is highly corrosive to human

skin.

•Hydrochloric acid makes up the majority of the gastric acid in the human digestive fluid.

• In high concentrations, hydrochloric acid will literally eat away human flesh…

Hydrochloric Acid (Continued)

• Hydrochloric acid can be purchased from hardware stores as:

– Tile and Grout Acid Cleaner

– Muriatic Acid

– Pool Acid

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

• Hydrochloric acid is a solution of hydrogen chloride gas suspended in water.

– Hydrochloric acid is corrosive and is a light yellow liquid color from traces of iron, chlorine, and organic matter.

• Inhaling hydrochloric acid may cause coughing or choking, inflammation, and

ulceration of the respiratory tract.

• Concentrated solutions of hydrochloric acid can cause severe burns and irritate the

mucous membranes, eyes, and respiratory tract.

– Exposure to hydrochloric acid vapors may result in pulmonary edema and

possibly death.

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

Sodium Hydroxide (NaOH)

• Sodium hydroxide is also called Lye.

• Sodium hydroxide is classified as a corrosive, and it is one of the main chemicals in

drain cleaner.

– It is also used in aluminum etching and to create biodiesal.

– It can burn the skin or cause blindness.

• Sodium hydroxide is used to dispose of road kill because it turns the dead bodies

into a coffee-like liquid.

Sodium Hydroxide (NaOH) (Continued)

• Drain cleaner (sodium hydroxide) is extremely corrosive, and without wearing

protection, even the smallest spill on the skin can eat through flesh…

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sulfuric Acid (H2SO4)

• Sulfuric acid is used in drain or toilet bowl cleaner as well as battery acid.

– It is another highly corrosive substance that burns the skin on contact.

Sulfuric Acid (H2SO4) (Continued)

• The product label warning for Drano® (sulfuric acid) says it all:

– DANGER: MAY BURN EYES AND SKIN ON CONTACT.

•HARMFUL IF SWALLOWED.

–Avoid contact with body and clothing.

•TOXIC GAS MAY FORM IF MIXED WITH OTHER CHEMICALS.

–If gases are released, leave immediately and ventilate area.

•FIRST AID: Give Immediately:

–EYES AND SKIN:

»Flush with water for 20 minutes.

»Remove affected clothing.

–IF SWALLOWED:

»Rinse mouth and drink a glass of water or milk.

»Do not induce vomiting.

–THEN SEEK MEDICAL AID.

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Hypophosphorous Acid (H3PO2)

• Hypophosphorous acid, which is used legally for a variety of commercial purposes,

is a chemical that increasingly is substituted for red phosphorus in the methamphetamine production process.

– The use of hypophospherous acid SIGNIFICANTLY increases the risk of fire!!!

• The federal government regulates the sale of hypophosphorous acid through registration, record keeping, reporting, and import/export requirements regardless

of the quantity being handled or distributed.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid is a colorless oily liquid that emits a SOUR odor.

– There is an extreme fire and explosion hazard if the hypophosphorous acid

comes into contact with a solvent such as acetone, toluene, or Coleman fuel.

• Hypophosphorous acid will also emit phosphine gas and the fumes can ignite.

Hypophosphorous Acid (H3PO2) (Continued)

• Although hypophosphorous acid is a List I chemical under the Controlled Substances Act, methamphetamine producers typically purchase the chemical via the internet or from associates who also are engaged in methamphetamine

production.

– The use of hypophosphorous acid in methamphetamine production is an

EXTREMELY DANGEROUS PRACTICE because of the deadly gases that can be generated as well as the risk of fire or explosion.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid (H3PO2, also called phosphinic acid) is a strong acid that

typically is prepared as a solution of colorless, oily liquid in strengths of 50%, 30 to 32%, and 10%.

– It also is prepared in the form of salts (referred to as hypophosphite salts), particularly ammonium hypophosphite, calcium hypophosphite, iron (ferric) hypophosphite, magnesium hypophosphite, manganese hypophosphite,

potassium hypophosphite, and sodium hypophosphite.

Hypophosphorous Acid (H3PO2) (Continued)

• Over 100 chemical firms located throughout the world produce hypophosphorous

acid.

– The People's Republic of China and India have the largest numbers of

hypophosphorous acid producers, although there are a few producers in the United States.

• There are a wide variety of uses for hypophosphorous acid and its salts in

commercial industry; however, the chemicals have no legitimate household or retail uses.

Hypophosphorous Acid (H3PO2) (Continued)

• The legitimate commercial and laboratory fields that use hypophosphorous acid and its salts include the following:

– Chemical plating

– Food preparation

– Water treatment

– Polymers (as a bleaching agent, color stabilizer, or catalyst)

– Education and research in analytical chemistry

Hypophosphorous Acid (H3PO2) (Continued)

• Chemical suppliers typically distribute hypophosphorous acid in large quantities, for example, in drums containing 275 pounds of the diluted solution.

– Hypophosphorous acid also is distributed in smaller quantities.

• One-half liter of 50% concentrate hypophosphorous acid solution can be obtained from chemical suppliers for as little as $14.

Hypophosphorous Acid (H3PO2) (Continued)

• Methamphetamine laboratory operators typically obtain small quantities of the chemical from other laboratory operators who purchase large quantities of the

chemical and repackage it for further distribution.

– According to law enforcement sources, these individuals sell hypophosphorous acid for as much as $1,000 per half-liter.

•Methamphetamine laboratory operators also purchase hypophosphorous acidvia the internet.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid and the Internet

• The internet is a source of a great deal of information regarding hypophosphorous acid.

• Popular internet sites that disseminate information about illicit drugs contain information about the chemical, including numerous recipes for home production of

methamphetamine using hypophosphorous acid.

• There also are recipes for synthesizing hypophosphorous acid from available chemicals.

• Hypophosphorous acid solutions and salts have been sold to the general public via the internet.

• The Drug Enforcement Administration (DEA) has strong concerns regarding the sale

of chemicals on the internet and has requested that any sites (such as auction sites) that allow the sale of regulated chemicals on their domains require proof of

DEA registration from their clients.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid Used in Methamphetamine Production

• Hypophosphorous acid is used in the ephedrine-pseudoephedrine reduction method

of methamphetamine production.

– It is used in the methamphetamine production process to produce hydriodic acid,

an important reagent (it reacts with the ephedrine-pseudoephedrine but does NOT become part of the finished product).

Hypophosphorous Acid (H3PO2) (Continued)

• The regulation of hydriodic acid by DEA in 1993 rendered it virtually unavailable in

the United States.

– However, methamphetamine laboratory operators discovered methods to

produce hydriodic acid using a combination of iodine in water with red phosphorus.

• Laboratory operators found that red phosphorus could be obtained easily, either

from commercial supply companies or by scraping the striker pads from matchbooks or matchboxes.

• Methamphetamine producers soon discovered that hypophosphorous acid ALSO could be used in combination with iodine and water to produce hydriodic acid.

Hypophosphorous Acid (H3PO2) (Continued)

• The practice of using hypophosphorous acid in methamphetamine production is

believed to have begun in the United States in the late 1990s when a methamphetamine producer in Colorado obtained the recipe from Australia, where

the hypophosphorous acid method is prevalent.

– This man was known as a serial cook who had a long history of

methamphetamine production.

•Over several years he trained other laboratory operators in Colorado to produce methamphetamine using hypophosphorous acid.

• As his techniques were passed on to others, the number of methamphetaminelaboratories in Colorado using hypophosphorous acid continued to increase, and the

technique was passed on to numerous methamphetamine producers in other

states.

Hypophosphorous Acid (H3PO2) (Continued)

• According to the El Paso Intelligence Center (EPIC) National Clandestine Laboratory

Seizure System, from 2000 through 2002 the number of seized methamphetaminelaboratories in the United States in which hypophosphorous acid was found

increased overall. (See Table 1.)

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid found at methamphetamine laboratories is packaged in a variety of ways.

• The chemical has been found in 1-gallon bottles of solution or in 1-pound jars of salts.

• Some hypophosphorous acid containers are labeled as "plating solution."

• Pint-sized brown glass bottles wrapped in red electrical tape also have been found to contain hypophosphorous acid; they have been discovered primarily in Colorado.

• The vast majority of hypophosphorous acid found at laboratory sites has been recovered from small toxic laboratories (STLs), those which yield gram to ounce

quantities per production cycle.

• Hypophosphorous acid has not been reported at large-scale laboratories operated by Mexican criminal groups in the United States.

Hypophosphorous Acid (H3PO2) (Continued)

• Hazards

• The iodine-hypophosphorous acid method is MORE HAZORDOUS than the iodine-

red phosphorus method, although the reaction using hypophosphorous acid is

faster and gives slightly higher yields.

– When hypophosphorous acid is used, the chemicals must be mixed together

SLOWLY in a PARTICULAR ORDER to prevent them from reacting violently.

Hypophosphorous Acid (H3PO2) (Continued)

• The combination of hypophosphorous acid with the other chemicals and with certain metals can produce deadly phosphine gas during the initial mixing step and

can CONTINUE to produce phosphine gas for several days AFTER production has been completed…

Hypophosphorous Acid (H3PO2) (Continued)

• The iodine-hypophosphorous acid mixture has a tendency to decompose quickly when overheated or if heated for long periods of time, becoming cloudy or "milky-

white" just prior to giving off a cloud of phosphine gas that can ignite spontaneously.

– Hypophosphorous acid solutions may become unstable if evaporation results in

concentrations above 50%.

Hypophosphorous Acid (H3PO2) (Continued)

• [Note: Law enforcement or emergency personnel who encounter suspected

containers of hypophosphorous acid should use extreme care during handling because laboratory operators often attempt to obtain a more concentrated acid by

allowing water to evaporate from the mixture.]

• Because hypophosphorous acid often is used at small methamphetaminelaboratories operated by inexperienced or careless individuals, the potential hazards

of using this method are even greater.

• The risk of fire and explosion is higher in these laboratories, where professional

laboratory equipment typically is not used to contain the phosphine gas and where

safe handling precautions are not employed.

• In addition, these laboratories often are located in homes where children are present and may come into contact with hypophosphorous acid.

• A child can easily mistake hypophosphorous acid for any other clear liquid,

particularly if it is stored in household containers or drinking glasses.

• Skin, eye, or inhalation exposure can be extremely harmful or fatal.

Hypophosphorous Acid (H3PO2) (Continued)

• Safety Precautions

• Always wear a self-contained breathing apparatus as well as protective clothing when entering areas where hypophosphorous acid may be present.

• When in contact with metals or in a high-temperature environment,

hypophosphorous acid can break down and liberate phosphine and flammable hydrogen gas.

• Do not allow the use of open flames, open lights, matches, or smoking in or around laboratories or dumpsites where hypophosphorous acid is handled.

• In case of fire, use a self-contained positive pressure breathing apparatus and full

protective equipment.

• Use water spray, fog, foam, dry chemicals, or other reagents as may be

appropriate for materials in the surrounding fire.

• Water may be used to cool the containers of hypophosphorous acid; however, use extreme care to avoid allowing water to enter the container.

• In case of spills, neutralize the spilled chemical with alkaline material (soda ash, lime), then absorb it with an inert material such as vermiculite, dry sand, or earth

and place in a chemical waste container.

• Do not use combustible materials such as sawdust.

Hypophosphorous Acid (H3PO2) (Continued)

• Legislation and Control

• In the United States hypophosphorous acid is one of 38 chemicals (or groups of

chemicals) controlled under law by DEA.

• On October 17, 2001, hypophosphorous acid and its salts, along with red and white phosphorus, were officially added as List I chemicals under section 1310 of the

Code of Federal Regulations.

• List I chemicals are defined as chemicals that are used in the manufacture of a

controlled substance in violation of the Controlled Substances Act (CSA) and are important to the manufacture of a controlled substance.

• Under the law, suppliers are required to maintain records and report receipts, sales,

imports, and exports of these chemicals to DEA.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid, red phosphorus, and white phosphorus, as well as

ephedrine, are unique in that suppliers are required to report all transactions of

these chemicals, regardless of the amount.

• By contrast, the other 34 listed chemicals are only reportable after a supplier's

transactions for a chemical reach an established weight or volume threshold in a calendar month.

• In addition to reporting all transactions involving the chemical, suppliers are expected to "know their customers" in order to prevent the diversion of these substances to methamphetamine laboratories, as it is illegal to import, export,

purchase, or sell hypophosphorous acid or any other listed chemical in the United States if it is used or intended to be used in the production of a controlled

substance.

• Chemical suppliers are held liable for selling listed chemicals if they know or suspect that the chemical will be used for illicit purposes.

Hypophosphorous Acid (H3PO2) (Continued)

• Outlook

• The use of hypophosphorous acid in the production of methamphetamine is likely

to increase, particularly in the Midwest and Southwest regions of the United States

where methamphetamine production is prevalent.

– Injuries, property damage, and deaths also will increase as a growing number of

inexperienced methamphetamine producers experiment with hypophosphorous acid.

Anhydrous Ammonia

• Anhydrous ammonia is found in fertilizer, countertop cleaner, and commercial refrigerant.

– On its own, it has a pungent, suffocating odor.

• Mixing anhydrous ammonia with other chemicals can release highly toxic gases.

– Because anhydrous ammonia seeks out water (anhydrous means “without

water”) and causes severe burns, any body part that comes into contact with it

should be flushed with water for at least 15 minutes to remove the ammoniafrom the skin.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia has extremely destructive effects on humans.

– Anhydrous ammonia gives off vapors during cooking that can burn the mouth,

throat, and lung tissue.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Anhydrous ammonia seeks water from the nearest source, including the human body (anhydrous means “without water”).

– Because of their high moisture content, EYES, LUNGS, and SKIN are at the

greatest risk of attracting the ammonia.

• When large amounts of anhydrous ammonia are inhaled, the throat swells and the

victim suffocates.

– Exposure to the vapors or liquids can cause severe burns, blindness, or death.

• Anhydrous ammonia has an IDLH (immediately dangerous to life and health) at

only 300 parts per million...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is poses MANY hazards, especially when it is placed in improper vessels and handled/transported by individuals unfamiliar with the

dangers.

• Anhydrous ammonia has a boiling point of -28 degrees below zero.

– When a vessel containing anhydrous ammonia is MOVED, the anhydrous

ammonia will reach its boiling point and pressurize.

•This pressurization can cause vessels to violently RUPTURE, or if the vessel pressurizes and does NOT rupture, the opening of the container of anhydrous

ammonia at a later time can cause RAPID, VIOLENT depressurization.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is mainly used in the U.S. as either a fertilizer or a refrigerant.

– Meth producers tend to store the anhydrous ammonia in IMPROPER/UNAPPROVED containers such as:

•Propane tanks,

• Igloo coolers, or

•Fire extinguishers.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia leaves a tell-tell sign as it flows through these UNAPPROVED

CONTAINERS – a blue or blue green discoloration on the valve.

– PAY ATTENTION to details!!!

Anhydrous Ammonia (Continued)

• Because propane cylinders (and the other unapproved containers) are NOT designed to store anhydrous ammonia, they can EXPLODE as the ammonia eats

through the walls of the cylinders.

– The valves, which take on a bluish/green color, frequently deteriorate and can cause hazardous leaks!!!

Anhydrous Ammonia (Continued)

• Do NOT touch, move, or open any kind of tank or sealed container!!!

– Be aware that propane tanks are often WEAKENED and BRITTLE due to the

anhydrous ammonia and are SENSITIVE to ANY kind of movement or impact.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• These pictures show what happened to a fire extinguisher that was used to store

anhydrous ammonia…

Anhydrous Ammonia (Continued)

• Illegal drug makers often STEAL anhydrous ammonia from areas where it is stored

and used, such as farms.

• Attempted thefts have also occurred at places such as:

– Refrigeration systems holding ammonia,

– Underground pipelines carrying ammonia, and

– Rail cars transporting anhydrous ammonia.

• Often thefts are aborted when thieves are injured or overcome by the toxic gas...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia thieves had better beware!!!

• There is a new product called GloTell that farmers can add to their anhydrous

ammonia tanks…

• Meth cooks will run the risk that the GloTell additive will turn their hands bright

pink!

– This bright pink stain will fluoresce under ultraviolet light even if washed off!!!

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Also, GloTell will produce pink methamphetamine that CANNOT be bleached.

– Users who snort meth made with GloTell will find that they have PINK NOSES!

– Users who inject meth made with GloTell will see a pink stain at the point of

injection!

Sodium Carbonate (Soda Ash)

Sodium Carbonate (Soda Ash) (Continued)

Lead Acetate

Iodine

• Iodine is a natural element, and it is helpful to the body in SMALL amounts.

– However, if iodine is taken in large amounts it can become toxic.

•Extremely high does of iodine can limit the function of the thyroid.

Iodine (Continued)

Iodine (Continued)

• Iodine is bluish-black, and it has a characteristic odor, a sharp acrid taste, and it produces a violet corrosive vapor.

– The vapor is irritating to the respiratory system and eyes.

• The solid iodine irritates the eyes and may burn the skin, and it may cause severe

internal irritation and damage if ingested.

Iodine (Continued)

• Iodine is known as the “blue ingredient” in the production of meth (in the “red, white, and blue” method).

Iodine (Continued)

Iodine (Continued)

• It takes approximately 4 bottles of iodine tincture to produce 2 – 3 grams of meth.

Iodine (Continued)

Iodine (Continued)

• Iodine leaves distinctive yellow-blue or brown stains on surfaces in former methlabs.

Iodine (Continued)

Iodine (Continued)

Iodine (Continued)

• The only good thing about iodine is that it leaves yellow stains.

• If you see yellow stained coffee filters, gloves or paper towels, this could be an

indicator that you’re in a lab.

• If you see yellow stains, you can spray some starch on them.

– If they turn a purplish blue/black, it’s iodine.

• Iodine is the only substance that reacts with soluble starch to produce a purplish black color.

– The only way to get iodine vapor all over the walls is to cook meth.

Mercurous Chloride

Rock Salt

Hydrogen Chloride

• Hydrogen chloride gas is commercially available.

• Hydrogen chloride gas can also be made by mixing sulfuric acid and salt.

• Muriatic acid is simply hydrogen chloride gas suspended in water.

• Hydrogen chloride gas can be seen as a pale white smoke.

– It is a poisonous gas that can cause respiratory problems and death.

Hydrogen Chloride (Continued)

Ammonium Nitrate

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Hydriodic Acid

• Hydriodic acid is a corrosive acid that is colorless when freshly prepared.

– When hydriodic acid is exposed to light and air, it turns yellowish and brown.

• Hydriodic acid is a solution of hydrogen iodide gas in water.

• Hydriodic acid vapor is irritating to the respiratory system, skin, and eyes.

• Hydriodic acid liquid causes severe burns to the eyes and skin.

• If hydriodic acid is accidentally ingested, it can cause severe internal irritation and

damage.

Hydriodic Acid (Continued)

Catalyst Chemicals

• Catalyst Chemicals:

– Chemicals which SPEED UP a reaction process and/or cause it to go to GREATER COMPLETION.

Red Phosphorus

• Red phosphorus is found ON matchboxes, in road flares, and other explosives.

– Red Phosphorus IGNITES when OVERHEATED!!!

• By combining red phosphorus and iodine, you can easily create the highly

controlled substance known as hydriodic acid (which is an essential ingredient in making meth).

– Creating 2 – 3 grams of meth requires about 4 big boxes of matches.

Red Phosphorus (Continued)

• Red phosphorous is highly flammable and if it is overheated it can become white

phosphorous…

– White phosphorous is a volatile and highly explosive substance.

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Lithium

• Lithium is used in batteries.

• Lithium seriously burns the skin upon contact.

– It also reacts VIOLENTLY with WATER and is highly explosive.

Lithium (Continued)

• Lithium reacts VIOLENTLY with WATER, and if it is splashed in the eyes during

cooking it will cause blindness.

– Lithium is extremely caustic to all body tissues.

Lithium (Continued)

Lithium (Continued)

• Lithium metal is HIGHLY water reactive and it will BURN or EXPLODE if it comes into contact with WATER!

• Because of the moisture in your skin, it will burn exposed flesh.

• Lithium metal will DEGRADE when exposed to atmospheric moisture…

– This is why meth cooks store lithium metal in a solvent prior to use.

• It is typical to see harvested lithium strips in Coleman fuel or Mineral Spirits to prevent explosions.

•Large quantities can be harvested and saved in these containers until needed

for a cook.

Lithium (Continued)

• If you see battery shells in the trashcan, on the floor, etc. – this is a VERY GOOD

indicator that you might be entering a meth lab!

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

• Lithium catches fire when in contact with water...

Solvent Chemicals

• Solvent Chemicals:

– A medium (liquid) in which a chemical operation takes place.

• Solvent chemicals (UNLIKE the precursor chemicals) CAN be

substituted/interchanged.

Ether

• Ether was once called “sweet vitriol” because of its hypnotic effect.

• Ether is a highly flammable substance that is used as an anesthetic agent –

especially in third world countries where more expensive anesthesia is not available.

– While inhaling the ether, patients could undergo complete surgical procedures while otherwise awake without feeling pain or concern.

Ether (Continued)

• Ether can be obtained from engine starting fluid.

• Ether is a solvent and it is flammable.

– It is particularly hazardous because it can cause BOTH fire and explosion.

• It has been said that a quart of ether can “level” a small house.

Ethyl Ether (Continued)

Ethyl Ether (Continued)

• Ether is VERY flammable and is HEAVIER than air.

– NEVER use ether near flames or non-sparkless motors.

– Ether is very PUNGENT – even a small evaporated amount of ether is VERY noticeable.

Acetone

• Acetone can be found in nail polish remover or paint thinner.

– It is extremely flammable.

• In the setting of a meth lab where meth is being cooked with high heat, acetone is

very dangerous.

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Toluene

• Toluene is used in brake fluid.

– When working with brake fluid (toluene), be careful not to spill it on your car

because it will eat away the paint and chrome…

• You also have to be careful using toluene around other household chemicals

because its high concentration of polyethylene glycol can cause it to ignite in a

violent fireball.

• Toluene is powerful enough to dissolve rubber.

Toluene (Continued)

• Toluene is used to form meth crystals.

– The fumes toluene releases can cause brain damage or death.

Toluene (Continued)

Toluene (Continued)

Ethanol

Isopropanol

Isopropanol (Continued)

Isopropyl Alcohol

Methanol

Methanol (Continued)

Methanol (Continued)

Benzene

Benzene (Continued)

Which of these is NOT a common ingredient in Meth?

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Page 7: Methamphetamine - PowerPoint - Chemicals and Ingredients ... · 2/5/2014 1 Methamphetamine - PowerPoint - Chemicals and Ingredients Used to Make Meth CJUS 240 Economic Costs of Meth

2/5/2014

7

Methamphetamine- PowerPoint

- Chemicals and Ingredients Used to Make Meth

CJUS 240

Economic Costs of Meth

• The economic cost of methamphetamine use in the U.S. reached $23.4 billion in

2005.

– This includes the burden of addiction, premature death, drug treatment, child

care, and cleaning of lab sites.

– This figure does NOT take into account the future needs of the meth user.

Concerns with ACTIVE Meth Labs

• Danger of fire and explosion

• Chemical spills

• Inhalation of solvents, corrosives, and toxic gases

• “Booby traps”

• Waste disposal

Concerns with FORMER Meth Labs

• Vapors

• Chemical residues

• Methamphetamine residues

• Waste disposal

Equipment Used in Meth Production

• Pyrex or Corning dishes

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

• Coffee Filters

Equipment Used in Meth Production

Equipment Used in Meth Production

Basic Chemical Requirements

• In a clandestine laboratory, basic types of chemicals are necessary in order to

produce the desired drug.

– The basic types of chemicals needed are:

1) Precursor Chemicals

2) Reagent Chemicals

3) Catalyst Chemicals

4) Solvent Chemicals

List I Chemical

• The term “List I chemical” means a chemical specified by regulation of the Attorney General as a chemical that is used in manufacturing a controlled substance and is

IMPORTANT to the manufacture of the controlled substance.

• Examples of List I chemicals are:

– GBL

– Red Phosphorus

– Pseudoephedrine

List II Chemical

• The term “List II chemical” means a chemical (other than a List I chemical) specified by regulation of the Attorney General as a chemical that is USED in

manufacturing a controlled substance.

• Examples of List II chemicals are:

– Toluene

– Iodine

– Hydrochloric Acid

Precursor Chemicals

• Precursor Chemicals:

– A chemical that is ESSENTIAL to the production of a controlled substance and for

which NO SUBSTITUTION can be made.

Pseudoephedrine

• Pseudoephedrine is a decongestant found in cold medicine.

– Large amounts of pseudoephedrine on its own can harm the respiratory and nervous systems, as well as the heart.

Pseudoephedrine (Continued)

• Some of the common ways used to divert products containing pseudoephedrine

include:

– “Smurfing” – making multiple purchases at different locations

– Shelf-Sweeping – the theft of all shelf stock

– Shoplifting

– Theft from wholesalers

Pseudoephedrine (Continued)

• Pseudoephedrine smurfing is a method used by some methamphetamine producers to acquire large quantities of pseudoephedrine by enlisting the assistance of several friends or associates (often referred to as “smurfers”) to make purchases at or below the legal thresholds from multiple retail locations.

– Smurfers are often addicts who trade the pseudoephedrine for finished

methamphetamine.

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

• About 680 pseudoephedrine tablets are needed to produce one ounce of meth…

Pseudoephedrine (Continued)

Out With a Bang

An Unstable Recipe…

• Meth contains a variety of poisonous ingredients…

– Some become EVEN MORE DANGEROUS once the cooking process begins…

Common Ingredients to Make Methamphetamine

Reagent Chemicals

• Reagent Chemicals:

– Chemicals which REACT upon the precursor chemical causing it to chemicallyCHANGE.

• A reagent chemical is a chemical which is required for the synthesis of an illicit drug substance, but which is NOT incorporated into the final chemical product.

Hydrochloric Acid

• Hydrochloric acid is a highly corrosive liquid that is used to make plastic (such as PVC pipe and polyurethane).

– It can remove rust and iron-oxide from steel and is highly corrosive to human

skin.

•Hydrochloric acid makes up the majority of the gastric acid in the human

digestive fluid.

• In high concentrations, hydrochloric acid will literally eat away human flesh…

Hydrochloric Acid (Continued)

• Hydrochloric acid can be purchased from hardware stores as:

– Tile and Grout Acid Cleaner

– Muriatic Acid

– Pool Acid

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

• Hydrochloric acid is a solution of hydrogen chloride gas suspended in water.

– Hydrochloric acid is corrosive and is a light yellow liquid color from traces of iron, chlorine, and organic matter.

• Inhaling hydrochloric acid may cause coughing or choking, inflammation, and

ulceration of the respiratory tract.

• Concentrated solutions of hydrochloric acid can cause severe burns and irritate the

mucous membranes, eyes, and respiratory tract.

– Exposure to hydrochloric acid vapors may result in pulmonary edema and

possibly death.

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

Sodium Hydroxide (NaOH)

• Sodium hydroxide is also called Lye.

• Sodium hydroxide is classified as a corrosive, and it is one of the main chemicals in

drain cleaner.

– It is also used in aluminum etching and to create biodiesal.

– It can burn the skin or cause blindness.

• Sodium hydroxide is used to dispose of road kill because it turns the dead bodies

into a coffee-like liquid.

Sodium Hydroxide (NaOH) (Continued)

• Drain cleaner (sodium hydroxide) is extremely corrosive, and without wearing

protection, even the smallest spill on the skin can eat through flesh…

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sulfuric Acid (H2SO4)

• Sulfuric acid is used in drain or toilet bowl cleaner as well as battery acid.

– It is another highly corrosive substance that burns the skin on contact.

Sulfuric Acid (H2SO4) (Continued)

• The product label warning for Drano® (sulfuric acid) says it all:

– DANGER: MAY BURN EYES AND SKIN ON CONTACT.

•HARMFUL IF SWALLOWED.

–Avoid contact with body and clothing.

•TOXIC GAS MAY FORM IF MIXED WITH OTHER CHEMICALS.

–If gases are released, leave immediately and ventilate area.

•FIRST AID: Give Immediately:

–EYES AND SKIN:

»Flush with water for 20 minutes.

»Remove affected clothing.

–IF SWALLOWED:

»Rinse mouth and drink a glass of water or milk.

»Do not induce vomiting.

–THEN SEEK MEDICAL AID.

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Hypophosphorous Acid (H3PO2)

• Hypophosphorous acid, which is used legally for a variety of commercial purposes,

is a chemical that increasingly is substituted for red phosphorus in the methamphetamine production process.

– The use of hypophospherous acid SIGNIFICANTLY increases the risk of fire!!!

• The federal government regulates the sale of hypophosphorous acid through registration, record keeping, reporting, and import/export requirements regardless

of the quantity being handled or distributed.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid is a colorless oily liquid that emits a SOUR odor.

– There is an extreme fire and explosion hazard if the hypophosphorous acid

comes into contact with a solvent such as acetone, toluene, or Coleman fuel.

• Hypophosphorous acid will also emit phosphine gas and the fumes can ignite.

Hypophosphorous Acid (H3PO2) (Continued)

• Although hypophosphorous acid is a List I chemical under the Controlled Substances Act, methamphetamine producers typically purchase the chemical via

the internet or from associates who also are engaged in methamphetamineproduction.

– The use of hypophosphorous acid in methamphetamine production is an

EXTREMELY DANGEROUS PRACTICE because of the deadly gases that can be generated as well as the risk of fire or explosion.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid (H3PO2, also called phosphinic acid) is a strong acid that

typically is prepared as a solution of colorless, oily liquid in strengths of 50%, 30 to 32%, and 10%.

– It also is prepared in the form of salts (referred to as hypophosphite salts), particularly ammonium hypophosphite, calcium hypophosphite, iron (ferric)

hypophosphite, magnesium hypophosphite, manganese hypophosphite, potassium hypophosphite, and sodium hypophosphite.

Hypophosphorous Acid (H3PO2) (Continued)

• Over 100 chemical firms located throughout the world produce hypophosphorous

acid.

– The People's Republic of China and India have the largest numbers of

hypophosphorous acid producers, although there are a few producers in the United States.

• There are a wide variety of uses for hypophosphorous acid and its salts in

commercial industry; however, the chemicals have no legitimate household or retail uses.

Hypophosphorous Acid (H3PO2) (Continued)

• The legitimate commercial and laboratory fields that use hypophosphorous acid and its salts include the following:

– Chemical plating

– Food preparation

– Water treatment

– Polymers (as a bleaching agent, color stabilizer, or catalyst)

– Education and research in analytical chemistry

Hypophosphorous Acid (H3PO2) (Continued)

• Chemical suppliers typically distribute hypophosphorous acid in large quantities, for example, in drums containing 275 pounds of the diluted solution.

– Hypophosphorous acid also is distributed in smaller quantities.

• One-half liter of 50% concentrate hypophosphorous acid solution can be obtained from chemical suppliers for as little as $14.

Hypophosphorous Acid (H3PO2) (Continued)

• Methamphetamine laboratory operators typically obtain small quantities of the chemical from other laboratory operators who purchase large quantities of the

chemical and repackage it for further distribution.

– According to law enforcement sources, these individuals sell hypophosphorous acid for as much as $1,000 per half-liter.

•Methamphetamine laboratory operators also purchase hypophosphorous acidvia the internet.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid and the Internet

• The internet is a source of a great deal of information regarding hypophosphorous acid.

• Popular internet sites that disseminate information about illicit drugs contain information about the chemical, including numerous recipes for home production of

methamphetamine using hypophosphorous acid.

• There also are recipes for synthesizing hypophosphorous acid from available chemicals.

• Hypophosphorous acid solutions and salts have been sold to the general public via the internet.

• The Drug Enforcement Administration (DEA) has strong concerns regarding the sale

of chemicals on the internet and has requested that any sites (such as auction sites) that allow the sale of regulated chemicals on their domains require proof of

DEA registration from their clients.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid Used in Methamphetamine Production

• Hypophosphorous acid is used in the ephedrine-pseudoephedrine reduction method

of methamphetamine production.

– It is used in the methamphetamine production process to produce hydriodic acid, an important reagent (it reacts with the ephedrine-pseudoephedrine but does NOT become part of the finished product).

Hypophosphorous Acid (H3PO2) (Continued)

• The regulation of hydriodic acid by DEA in 1993 rendered it virtually unavailable in

the United States.

– However, methamphetamine laboratory operators discovered methods to

produce hydriodic acid using a combination of iodine in water with red phosphorus.

• Laboratory operators found that red phosphorus could be obtained easily, either

from commercial supply companies or by scraping the striker pads from matchbooks or matchboxes.

• Methamphetamine producers soon discovered that hypophosphorous acid ALSO could be used in combination with iodine and water to produce hydriodic acid.

Hypophosphorous Acid (H3PO2) (Continued)

• The practice of using hypophosphorous acid in methamphetamine production is

believed to have begun in the United States in the late 1990s when a methamphetamine producer in Colorado obtained the recipe from Australia, where

the hypophosphorous acid method is prevalent.

– This man was known as a serial cook who had a long history of

methamphetamine production.

•Over several years he trained other laboratory operators in Colorado to produce methamphetamine using hypophosphorous acid.

• As his techniques were passed on to others, the number of methamphetaminelaboratories in Colorado using hypophosphorous acid continued to increase, and the

technique was passed on to numerous methamphetamine producers in other

states.

Hypophosphorous Acid (H3PO2) (Continued)

• According to the El Paso Intelligence Center (EPIC) National Clandestine Laboratory

Seizure System, from 2000 through 2002 the number of seized methamphetaminelaboratories in the United States in which hypophosphorous acid was found

increased overall. (See Table 1.)

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid found at methamphetamine laboratories is packaged in a variety of ways.

• The chemical has been found in 1-gallon bottles of solution or in 1-pound jars of salts.

• Some hypophosphorous acid containers are labeled as "plating solution."

• Pint-sized brown glass bottles wrapped in red electrical tape also have been found to contain hypophosphorous acid; they have been discovered primarily in Colorado.

• The vast majority of hypophosphorous acid found at laboratory sites has been recovered from small toxic laboratories (STLs), those which yield gram to ounce

quantities per production cycle.

• Hypophosphorous acid has not been reported at large-scale laboratories operated by Mexican criminal groups in the United States.

Hypophosphorous Acid (H3PO2) (Continued)

• Hazards

• The iodine-hypophosphorous acid method is MORE HAZORDOUS than the iodine-

red phosphorus method, although the reaction using hypophosphorous acid is

faster and gives slightly higher yields.

– When hypophosphorous acid is used, the chemicals must be mixed together

SLOWLY in a PARTICULAR ORDER to prevent them from reacting violently.

Hypophosphorous Acid (H3PO2) (Continued)

• The combination of hypophosphorous acid with the other chemicals and with

certain metals can produce deadly phosphine gas during the initial mixing step and can CONTINUE to produce phosphine gas for several days AFTER production has been completed…

Hypophosphorous Acid (H3PO2) (Continued)

• The iodine-hypophosphorous acid mixture has a tendency to decompose quickly when overheated or if heated for long periods of time, becoming cloudy or "milky-

white" just prior to giving off a cloud of phosphine gas that can ignite spontaneously.

– Hypophosphorous acid solutions may become unstable if evaporation results in

concentrations above 50%.

Hypophosphorous Acid (H3PO2) (Continued)

• [Note: Law enforcement or emergency personnel who encounter suspected

containers of hypophosphorous acid should use extreme care during handling because laboratory operators often attempt to obtain a more concentrated acid by

allowing water to evaporate from the mixture.]

• Because hypophosphorous acid often is used at small methamphetaminelaboratories operated by inexperienced or careless individuals, the potential hazards

of using this method are even greater.

• The risk of fire and explosion is higher in these laboratories, where professional

laboratory equipment typically is not used to contain the phosphine gas and where

safe handling precautions are not employed.

• In addition, these laboratories often are located in homes where children are

present and may come into contact with hypophosphorous acid.

• A child can easily mistake hypophosphorous acid for any other clear liquid,

particularly if it is stored in household containers or drinking glasses.

• Skin, eye, or inhalation exposure can be extremely harmful or fatal.

Hypophosphorous Acid (H3PO2) (Continued)

• Safety Precautions

• Always wear a self-contained breathing apparatus as well as protective clothing when entering areas where hypophosphorous acid may be present.

• When in contact with metals or in a high-temperature environment,

hypophosphorous acid can break down and liberate phosphine and flammable hydrogen gas.

• Do not allow the use of open flames, open lights, matches, or smoking in or around laboratories or dumpsites where hypophosphorous acid is handled.

• In case of fire, use a self-contained positive pressure breathing apparatus and full

protective equipment.

• Use water spray, fog, foam, dry chemicals, or other reagents as may be

appropriate for materials in the surrounding fire.

• Water may be used to cool the containers of hypophosphorous acid; however, use extreme care to avoid allowing water to enter the container.

• In case of spills, neutralize the spilled chemical with alkaline material (soda ash, lime), then absorb it with an inert material such as vermiculite, dry sand, or earth

and place in a chemical waste container.

• Do not use combustible materials such as sawdust.

Hypophosphorous Acid (H3PO2) (Continued)

• Legislation and Control

• In the United States hypophosphorous acid is one of 38 chemicals (or groups of

chemicals) controlled under law by DEA.

• On October 17, 2001, hypophosphorous acid and its salts, along with red and white phosphorus, were officially added as List I chemicals under section 1310 of the

Code of Federal Regulations.

• List I chemicals are defined as chemicals that are used in the manufacture of a

controlled substance in violation of the Controlled Substances Act (CSA) and are

important to the manufacture of a controlled substance.

• Under the law, suppliers are required to maintain records and report receipts, sales,

imports, and exports of these chemicals to DEA.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid, red phosphorus, and white phosphorus, as well as

ephedrine, are unique in that suppliers are required to report all transactions of

these chemicals, regardless of the amount.

• By contrast, the other 34 listed chemicals are only reportable after a supplier's

transactions for a chemical reach an established weight or volume threshold in a calendar month.

• In addition to reporting all transactions involving the chemical, suppliers are

expected to "know their customers" in order to prevent the diversion of these substances to methamphetamine laboratories, as it is illegal to import, export,

purchase, or sell hypophosphorous acid or any other listed chemical in the United States if it is used or intended to be used in the production of a controlled

substance.

• Chemical suppliers are held liable for selling listed chemicals if they know or suspect that the chemical will be used for illicit purposes.

Hypophosphorous Acid (H3PO2) (Continued)

• Outlook

• The use of hypophosphorous acid in the production of methamphetamine is likely

to increase, particularly in the Midwest and Southwest regions of the United States

where methamphetamine production is prevalent.

– Injuries, property damage, and deaths also will increase as a growing number of

inexperienced methamphetamine producers experiment with hypophosphorous acid.

Anhydrous Ammonia

• Anhydrous ammonia is found in fertilizer, countertop cleaner, and commercial refrigerant.

– On its own, it has a pungent, suffocating odor.

• Mixing anhydrous ammonia with other chemicals can release highly toxic gases.

– Because anhydrous ammonia seeks out water (anhydrous means “without water”) and causes severe burns, any body part that comes into contact with it

should be flushed with water for at least 15 minutes to remove the ammoniafrom the skin.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia has extremely destructive effects on humans.

– Anhydrous ammonia gives off vapors during cooking that can burn the mouth,

throat, and lung tissue.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Anhydrous ammonia seeks water from the nearest source, including the human body (anhydrous means “without water”).

– Because of their high moisture content, EYES, LUNGS, and SKIN are at the

greatest risk of attracting the ammonia.

• When large amounts of anhydrous ammonia are inhaled, the throat swells and the

victim suffocates.

– Exposure to the vapors or liquids can cause severe burns, blindness, or death.

• Anhydrous ammonia has an IDLH (immediately dangerous to life and health) at

only 300 parts per million...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is poses MANY hazards, especially when it is placed in improper vessels and handled/transported by individuals unfamiliar with the

dangers.

• Anhydrous ammonia has a boiling point of -28 degrees below zero.

– When a vessel containing anhydrous ammonia is MOVED, the anhydrous

ammonia will reach its boiling point and pressurize.

•This pressurization can cause vessels to violently RUPTURE, or if the vessel pressurizes and does NOT rupture, the opening of the container of anhydrous

ammonia at a later time can cause RAPID, VIOLENT depressurization.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is mainly used in the U.S. as either a fertilizer or a refrigerant.

– Meth producers tend to store the anhydrous ammonia in IMPROPER/UNAPPROVED containers such as:

•Propane tanks,

• Igloo coolers, or

•Fire extinguishers.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia leaves a tell-tell sign as it flows through these UNAPPROVED

CONTAINERS – a blue or blue green discoloration on the valve.

– PAY ATTENTION to details!!!

Anhydrous Ammonia (Continued)

• Because propane cylinders (and the other unapproved containers) are NOT designed to store anhydrous ammonia, they can EXPLODE as the ammonia eats

through the walls of the cylinders.

– The valves, which take on a bluish/green color, frequently deteriorate and can cause hazardous leaks!!!

Anhydrous Ammonia (Continued)

• Do NOT touch, move, or open any kind of tank or sealed container!!!

– Be aware that propane tanks are often WEAKENED and BRITTLE due to the

anhydrous ammonia and are SENSITIVE to ANY kind of movement or impact.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• These pictures show what happened to a fire extinguisher that was used to store

anhydrous ammonia…

Anhydrous Ammonia (Continued)

• Illegal drug makers often STEAL anhydrous ammonia from areas where it is stored

and used, such as farms.

• Attempted thefts have also occurred at places such as:

– Refrigeration systems holding ammonia,

– Underground pipelines carrying ammonia, and

– Rail cars transporting anhydrous ammonia.

• Often thefts are aborted when thieves are injured or overcome by the toxic gas...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia thieves had better beware!!!

• There is a new product called GloTell that farmers can add to their anhydrous

ammonia tanks…

• Meth cooks will run the risk that the GloTell additive will turn their hands bright

pink!

– This bright pink stain will fluoresce under ultraviolet light even if washed off!!!

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Also, GloTell will produce pink methamphetamine that CANNOT be bleached.

– Users who snort meth made with GloTell will find that they have PINK NOSES!

– Users who inject meth made with GloTell will see a pink stain at the point of

injection!

Sodium Carbonate (Soda Ash)

Sodium Carbonate (Soda Ash) (Continued)

Lead Acetate

Iodine

• Iodine is a natural element, and it is helpful to the body in SMALL amounts.

– However, if iodine is taken in large amounts it can become toxic.

•Extremely high does of iodine can limit the function of the thyroid.

Iodine (Continued)

Iodine (Continued)

• Iodine is bluish-black, and it has a characteristic odor, a sharp acrid taste, and it produces a violet corrosive vapor.

– The vapor is irritating to the respiratory system and eyes.

• The solid iodine irritates the eyes and may burn the skin, and it may cause severe

internal irritation and damage if ingested.

Iodine (Continued)

• Iodine is known as the “blue ingredient” in the production of meth (in the “red, white, and blue” method).

Iodine (Continued)

Iodine (Continued)

• It takes approximately 4 bottles of iodine tincture to produce 2 – 3 grams of meth.

Iodine (Continued)

Iodine (Continued)

• Iodine leaves distinctive yellow-blue or brown stains on surfaces in former methlabs.

Iodine (Continued)

Iodine (Continued)

Iodine (Continued)

• The only good thing about iodine is that it leaves yellow stains.

• If you see yellow stained coffee filters, gloves or paper towels, this could be an

indicator that you’re in a lab.

• If you see yellow stains, you can spray some starch on them.

– If they turn a purplish blue/black, it’s iodine.

• Iodine is the only substance that reacts with soluble starch to produce a purplish black color.

– The only way to get iodine vapor all over the walls is to cook meth.

Mercurous Chloride

Rock Salt

Hydrogen Chloride

• Hydrogen chloride gas is commercially available.

• Hydrogen chloride gas can also be made by mixing sulfuric acid and salt.

• Muriatic acid is simply hydrogen chloride gas suspended in water.

• Hydrogen chloride gas can be seen as a pale white smoke.

– It is a poisonous gas that can cause respiratory problems and death.

Hydrogen Chloride (Continued)

Ammonium Nitrate

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Hydriodic Acid

• Hydriodic acid is a corrosive acid that is colorless when freshly prepared.

– When hydriodic acid is exposed to light and air, it turns yellowish and brown.

• Hydriodic acid is a solution of hydrogen iodide gas in water.

• Hydriodic acid vapor is irritating to the respiratory system, skin, and eyes.

• Hydriodic acid liquid causes severe burns to the eyes and skin.

• If hydriodic acid is accidentally ingested, it can cause severe internal irritation and

damage.

Hydriodic Acid (Continued)

Catalyst Chemicals

• Catalyst Chemicals:

– Chemicals which SPEED UP a reaction process and/or cause it to go to GREATER COMPLETION.

Red Phosphorus

• Red phosphorus is found ON matchboxes, in road flares, and other explosives.

– Red Phosphorus IGNITES when OVERHEATED!!!

• By combining red phosphorus and iodine, you can easily create the highly

controlled substance known as hydriodic acid (which is an essential ingredient in making meth).

– Creating 2 – 3 grams of meth requires about 4 big boxes of matches.

Red Phosphorus (Continued)

• Red phosphorous is highly flammable and if it is overheated it can become white

phosphorous…

– White phosphorous is a volatile and highly explosive substance.

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Lithium

• Lithium is used in batteries.

• Lithium seriously burns the skin upon contact.

– It also reacts VIOLENTLY with WATER and is highly explosive.

Lithium (Continued)

• Lithium reacts VIOLENTLY with WATER, and if it is splashed in the eyes during

cooking it will cause blindness.

– Lithium is extremely caustic to all body tissues.

Lithium (Continued)

Lithium (Continued)

• Lithium metal is HIGHLY water reactive and it will BURN or EXPLODE if it comes into contact with WATER!

• Because of the moisture in your skin, it will burn exposed flesh.

• Lithium metal will DEGRADE when exposed to atmospheric moisture…

– This is why meth cooks store lithium metal in a solvent prior to use.

• It is typical to see harvested lithium strips in Coleman fuel or Mineral Spirits to prevent explosions.

•Large quantities can be harvested and saved in these containers until needed

for a cook.

Lithium (Continued)

• If you see battery shells in the trashcan, on the floor, etc. – this is a VERY GOOD

indicator that you might be entering a meth lab!

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

• Lithium catches fire when in contact with water...

Solvent Chemicals

• Solvent Chemicals:

– A medium (liquid) in which a chemical operation takes place.

• Solvent chemicals (UNLIKE the precursor chemicals) CAN be

substituted/interchanged.

Ether

• Ether was once called “sweet vitriol” because of its hypnotic effect.

• Ether is a highly flammable substance that is used as an anesthetic agent –

especially in third world countries where more expensive anesthesia is not available.

– While inhaling the ether, patients could undergo complete surgical procedures while otherwise awake without feeling pain or concern.

Ether (Continued)

• Ether can be obtained from engine starting fluid.

• Ether is a solvent and it is flammable.

– It is particularly hazardous because it can cause BOTH fire and explosion.

• It has been said that a quart of ether can “level” a small house.

Ethyl Ether (Continued)

Ethyl Ether (Continued)

• Ether is VERY flammable and is HEAVIER than air.

– NEVER use ether near flames or non-sparkless motors.

– Ether is very PUNGENT – even a small evaporated amount of ether is VERY noticeable.

Acetone

• Acetone can be found in nail polish remover or paint thinner.

– It is extremely flammable.

• In the setting of a meth lab where meth is being cooked with high heat, acetone is

very dangerous.

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Toluene

• Toluene is used in brake fluid.

– When working with brake fluid (toluene), be careful not to spill it on your car

because it will eat away the paint and chrome…

• You also have to be careful using toluene around other household chemicals

because its high concentration of polyethylene glycol can cause it to ignite in a

violent fireball.

• Toluene is powerful enough to dissolve rubber.

Toluene (Continued)

• Toluene is used to form meth crystals.

– The fumes toluene releases can cause brain damage or death.

Toluene (Continued)

Toluene (Continued)

Ethanol

Isopropanol

Isopropanol (Continued)

Isopropyl Alcohol

Methanol

Methanol (Continued)

Methanol (Continued)

Benzene

Benzene (Continued)

Which of these is NOT a common ingredient in Meth?

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Methamphetamine- PowerPoint

- Chemicals and Ingredients Used to Make Meth

CJUS 240

Economic Costs of Meth

• The economic cost of methamphetamine use in the U.S. reached $23.4 billion in

2005.

– This includes the burden of addiction, premature death, drug treatment, child

care, and cleaning of lab sites.

– This figure does NOT take into account the future needs of the meth user.

Concerns with ACTIVE Meth Labs

• Danger of fire and explosion

• Chemical spills

• Inhalation of solvents, corrosives, and toxic gases

• “Booby traps”

• Waste disposal

Concerns with FORMER Meth Labs

• Vapors

• Chemical residues

• Methamphetamine residues

• Waste disposal

Equipment Used in Meth Production

• Pyrex or Corning dishes

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

• Coffee Filters

Equipment Used in Meth Production

Equipment Used in Meth Production

Basic Chemical Requirements

• In a clandestine laboratory, basic types of chemicals are necessary in order to

produce the desired drug.

– The basic types of chemicals needed are:

1) Precursor Chemicals

2) Reagent Chemicals

3) Catalyst Chemicals

4) Solvent Chemicals

List I Chemical

• The term “List I chemical” means a chemical specified by regulation of the Attorney General as a chemical that is used in manufacturing a controlled substance and is

IMPORTANT to the manufacture of the controlled substance.

• Examples of List I chemicals are:

– GBL

– Red Phosphorus

– Pseudoephedrine

List II Chemical

• The term “List II chemical” means a chemical (other than a List I chemical) specified by regulation of the Attorney General as a chemical that is USED in

manufacturing a controlled substance.

• Examples of List II chemicals are:

– Toluene

– Iodine

– Hydrochloric Acid

Precursor Chemicals

• Precursor Chemicals:

– A chemical that is ESSENTIAL to the production of a controlled substance and for

which NO SUBSTITUTION can be made.

Pseudoephedrine

• Pseudoephedrine is a decongestant found in cold medicine.

– Large amounts of pseudoephedrine on its own can harm the respiratory and nervous systems, as well as the heart.

Pseudoephedrine (Continued)

• Some of the common ways used to divert products containing pseudoephedrineinclude:

– “Smurfing” – making multiple purchases at different locations

– Shelf-Sweeping – the theft of all shelf stock

– Shoplifting

– Theft from wholesalers

Pseudoephedrine (Continued)

• Pseudoephedrine smurfing is a method used by some methamphetamine producers to acquire large quantities of pseudoephedrine by enlisting the assistance of several

friends or associates (often referred to as “smurfers”) to make purchases at or below the legal thresholds from multiple retail locations.

– Smurfers are often addicts who trade the pseudoephedrine for finished

methamphetamine.

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

• About 680 pseudoephedrine tablets are needed to produce one ounce of meth…

Pseudoephedrine (Continued)

Out With a Bang

An Unstable Recipe…

• Meth contains a variety of poisonous ingredients…

– Some become EVEN MORE DANGEROUS once the cooking process begins…

Common Ingredients to Make Methamphetamine

Reagent Chemicals

• Reagent Chemicals:

– Chemicals which REACT upon the precursor chemical causing it to chemicallyCHANGE.

• A reagent chemical is a chemical which is required for the synthesis of an illicit drug substance, but which is NOT incorporated into the final chemical product.

Hydrochloric Acid

• Hydrochloric acid is a highly corrosive liquid that is used to make plastic (such as PVC pipe and polyurethane).

– It can remove rust and iron-oxide from steel and is highly corrosive to human

skin.

•Hydrochloric acid makes up the majority of the gastric acid in the human

digestive fluid.

• In high concentrations, hydrochloric acid will literally eat away human flesh…

Hydrochloric Acid (Continued)

• Hydrochloric acid can be purchased from hardware stores as:

– Tile and Grout Acid Cleaner

– Muriatic Acid

– Pool Acid

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

• Hydrochloric acid is a solution of hydrogen chloride gas suspended in water.

– Hydrochloric acid is corrosive and is a light yellow liquid color from traces of iron, chlorine, and organic matter.

• Inhaling hydrochloric acid may cause coughing or choking, inflammation, and

ulceration of the respiratory tract.

• Concentrated solutions of hydrochloric acid can cause severe burns and irritate the

mucous membranes, eyes, and respiratory tract.

– Exposure to hydrochloric acid vapors may result in pulmonary edema and

possibly death.

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

Sodium Hydroxide (NaOH)

• Sodium hydroxide is also called Lye.

• Sodium hydroxide is classified as a corrosive, and it is one of the main chemicals in

drain cleaner.

– It is also used in aluminum etching and to create biodiesal.

– It can burn the skin or cause blindness.

• Sodium hydroxide is used to dispose of road kill because it turns the dead bodies

into a coffee-like liquid.

Sodium Hydroxide (NaOH) (Continued)

• Drain cleaner (sodium hydroxide) is extremely corrosive, and without wearing

protection, even the smallest spill on the skin can eat through flesh…

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sulfuric Acid (H2SO4)

• Sulfuric acid is used in drain or toilet bowl cleaner as well as battery acid.

– It is another highly corrosive substance that burns the skin on contact.

Sulfuric Acid (H2SO4) (Continued)

• The product label warning for Drano® (sulfuric acid) says it all:

– DANGER: MAY BURN EYES AND SKIN ON CONTACT.

•HARMFUL IF SWALLOWED.

–Avoid contact with body and clothing.

•TOXIC GAS MAY FORM IF MIXED WITH OTHER CHEMICALS.

–If gases are released, leave immediately and ventilate area.

•FIRST AID: Give Immediately:

–EYES AND SKIN:

»Flush with water for 20 minutes.

»Remove affected clothing.

–IF SWALLOWED:

»Rinse mouth and drink a glass of water or milk.

»Do not induce vomiting.

–THEN SEEK MEDICAL AID.

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Hypophosphorous Acid (H3PO2)

• Hypophosphorous acid, which is used legally for a variety of commercial purposes,

is a chemical that increasingly is substituted for red phosphorus in the methamphetamine production process.

– The use of hypophospherous acid SIGNIFICANTLY increases the risk of fire!!!

• The federal government regulates the sale of hypophosphorous acid through registration, record keeping, reporting, and import/export requirements regardless

of the quantity being handled or distributed.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid is a colorless oily liquid that emits a SOUR odor.

– There is an extreme fire and explosion hazard if the hypophosphorous acid

comes into contact with a solvent such as acetone, toluene, or Coleman fuel.

• Hypophosphorous acid will also emit phosphine gas and the fumes can ignite.

Hypophosphorous Acid (H3PO2) (Continued)

• Although hypophosphorous acid is a List I chemical under the Controlled Substances Act, methamphetamine producers typically purchase the chemical via

the internet or from associates who also are engaged in methamphetamine

production.

– The use of hypophosphorous acid in methamphetamine production is an

EXTREMELY DANGEROUS PRACTICE because of the deadly gases that can be generated as well as the risk of fire or explosion.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid (H3PO2, also called phosphinic acid) is a strong acid that

typically is prepared as a solution of colorless, oily liquid in strengths of 50%, 30 to 32%, and 10%.

– It also is prepared in the form of salts (referred to as hypophosphite salts), particularly ammonium hypophosphite, calcium hypophosphite, iron (ferric)

hypophosphite, magnesium hypophosphite, manganese hypophosphite,

potassium hypophosphite, and sodium hypophosphite.

Hypophosphorous Acid (H3PO2) (Continued)

• Over 100 chemical firms located throughout the world produce hypophosphorous

acid.

– The People's Republic of China and India have the largest numbers of

hypophosphorous acid producers, although there are a few producers in the United States.

• There are a wide variety of uses for hypophosphorous acid and its salts in

commercial industry; however, the chemicals have no legitimate household or retail uses.

Hypophosphorous Acid (H3PO2) (Continued)

• The legitimate commercial and laboratory fields that use hypophosphorous acid and its salts include the following:

– Chemical plating

– Food preparation

– Water treatment

– Polymers (as a bleaching agent, color stabilizer, or catalyst)

– Education and research in analytical chemistry

Hypophosphorous Acid (H3PO2) (Continued)

• Chemical suppliers typically distribute hypophosphorous acid in large quantities, for example, in drums containing 275 pounds of the diluted solution.

– Hypophosphorous acid also is distributed in smaller quantities.

• One-half liter of 50% concentrate hypophosphorous acid solution can be obtained from chemical suppliers for as little as $14.

Hypophosphorous Acid (H3PO2) (Continued)

• Methamphetamine laboratory operators typically obtain small quantities of the chemical from other laboratory operators who purchase large quantities of the

chemical and repackage it for further distribution.

– According to law enforcement sources, these individuals sell hypophosphorous acid for as much as $1,000 per half-liter.

•Methamphetamine laboratory operators also purchase hypophosphorous acidvia the internet.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid and the Internet

• The internet is a source of a great deal of information regarding hypophosphorous acid.

• Popular internet sites that disseminate information about illicit drugs contain information about the chemical, including numerous recipes for home production of

methamphetamine using hypophosphorous acid.

• There also are recipes for synthesizing hypophosphorous acid from available chemicals.

• Hypophosphorous acid solutions and salts have been sold to the general public via the internet.

• The Drug Enforcement Administration (DEA) has strong concerns regarding the sale

of chemicals on the internet and has requested that any sites (such as auction sites) that allow the sale of regulated chemicals on their domains require proof of

DEA registration from their clients.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid Used in Methamphetamine Production

• Hypophosphorous acid is used in the ephedrine-pseudoephedrine reduction method

of methamphetamine production.

– It is used in the methamphetamine production process to produce hydriodic acid,

an important reagent (it reacts with the ephedrine-pseudoephedrine but does NOT become part of the finished product).

Hypophosphorous Acid (H3PO2) (Continued)

• The regulation of hydriodic acid by DEA in 1993 rendered it virtually unavailable in

the United States.

– However, methamphetamine laboratory operators discovered methods to

produce hydriodic acid using a combination of iodine in water with red phosphorus.

• Laboratory operators found that red phosphorus could be obtained easily, either

from commercial supply companies or by scraping the striker pads from matchbooks or matchboxes.

• Methamphetamine producers soon discovered that hypophosphorous acid ALSO could be used in combination with iodine and water to produce hydriodic acid.

Hypophosphorous Acid (H3PO2) (Continued)

• The practice of using hypophosphorous acid in methamphetamine production is

believed to have begun in the United States in the late 1990s when a methamphetamine producer in Colorado obtained the recipe from Australia, where

the hypophosphorous acid method is prevalent.

– This man was known as a serial cook who had a long history of

methamphetamine production.

•Over several years he trained other laboratory operators in Colorado to produce methamphetamine using hypophosphorous acid.

• As his techniques were passed on to others, the number of methamphetaminelaboratories in Colorado using hypophosphorous acid continued to increase, and the

technique was passed on to numerous methamphetamine producers in other

states.

Hypophosphorous Acid (H3PO2) (Continued)

• According to the El Paso Intelligence Center (EPIC) National Clandestine Laboratory

Seizure System, from 2000 through 2002 the number of seized methamphetaminelaboratories in the United States in which hypophosphorous acid was found

increased overall. (See Table 1.)

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid found at methamphetamine laboratories is packaged in a variety of ways.

• The chemical has been found in 1-gallon bottles of solution or in 1-pound jars of salts.

• Some hypophosphorous acid containers are labeled as "plating solution."

• Pint-sized brown glass bottles wrapped in red electrical tape also have been found to contain hypophosphorous acid; they have been discovered primarily in Colorado.

• The vast majority of hypophosphorous acid found at laboratory sites has been recovered from small toxic laboratories (STLs), those which yield gram to ounce

quantities per production cycle.

• Hypophosphorous acid has not been reported at large-scale laboratories operated by Mexican criminal groups in the United States.

Hypophosphorous Acid (H3PO2) (Continued)

• Hazards

• The iodine-hypophosphorous acid method is MORE HAZORDOUS than the iodine-

red phosphorus method, although the reaction using hypophosphorous acid is

faster and gives slightly higher yields.

– When hypophosphorous acid is used, the chemicals must be mixed together

SLOWLY in a PARTICULAR ORDER to prevent them from reacting violently.

Hypophosphorous Acid (H3PO2) (Continued)

• The combination of hypophosphorous acid with the other chemicals and with

certain metals can produce deadly phosphine gas during the initial mixing step and

can CONTINUE to produce phosphine gas for several days AFTER production has been completed…

Hypophosphorous Acid (H3PO2) (Continued)

• The iodine-hypophosphorous acid mixture has a tendency to decompose quickly when overheated or if heated for long periods of time, becoming cloudy or "milky-

white" just prior to giving off a cloud of phosphine gas that can ignite spontaneously.

– Hypophosphorous acid solutions may become unstable if evaporation results in

concentrations above 50%.

Hypophosphorous Acid (H3PO2) (Continued)

• [Note: Law enforcement or emergency personnel who encounter suspected

containers of hypophosphorous acid should use extreme care during handling because laboratory operators often attempt to obtain a more concentrated acid by

allowing water to evaporate from the mixture.]

• Because hypophosphorous acid often is used at small methamphetaminelaboratories operated by inexperienced or careless individuals, the potential hazards

of using this method are even greater.

• The risk of fire and explosion is higher in these laboratories, where professional

laboratory equipment typically is not used to contain the phosphine gas and where

safe handling precautions are not employed.

• In addition, these laboratories often are located in homes where children are

present and may come into contact with hypophosphorous acid.

• A child can easily mistake hypophosphorous acid for any other clear liquid,

particularly if it is stored in household containers or drinking glasses.

• Skin, eye, or inhalation exposure can be extremely harmful or fatal.

Hypophosphorous Acid (H3PO2) (Continued)

• Safety Precautions

• Always wear a self-contained breathing apparatus as well as protective clothing when entering areas where hypophosphorous acid may be present.

• When in contact with metals or in a high-temperature environment,

hypophosphorous acid can break down and liberate phosphine and flammable hydrogen gas.

• Do not allow the use of open flames, open lights, matches, or smoking in or around laboratories or dumpsites where hypophosphorous acid is handled.

• In case of fire, use a self-contained positive pressure breathing apparatus and full

protective equipment.

• Use water spray, fog, foam, dry chemicals, or other reagents as may be

appropriate for materials in the surrounding fire.

• Water may be used to cool the containers of hypophosphorous acid; however, use extreme care to avoid allowing water to enter the container.

• In case of spills, neutralize the spilled chemical with alkaline material (soda ash, lime), then absorb it with an inert material such as vermiculite, dry sand, or earth

and place in a chemical waste container.

• Do not use combustible materials such as sawdust.

Hypophosphorous Acid (H3PO2) (Continued)

• Legislation and Control

• In the United States hypophosphorous acid is one of 38 chemicals (or groups of

chemicals) controlled under law by DEA.

• On October 17, 2001, hypophosphorous acid and its salts, along with red and white phosphorus, were officially added as List I chemicals under section 1310 of the

Code of Federal Regulations.

• List I chemicals are defined as chemicals that are used in the manufacture of a

controlled substance in violation of the Controlled Substances Act (CSA) and are

important to the manufacture of a controlled substance.

• Under the law, suppliers are required to maintain records and report receipts, sales,

imports, and exports of these chemicals to DEA.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid, red phosphorus, and white phosphorus, as well as

ephedrine, are unique in that suppliers are required to report all transactions of

these chemicals, regardless of the amount.

• By contrast, the other 34 listed chemicals are only reportable after a supplier's

transactions for a chemical reach an established weight or volume threshold in a calendar month.

• In addition to reporting all transactions involving the chemical, suppliers are

expected to "know their customers" in order to prevent the diversion of these substances to methamphetamine laboratories, as it is illegal to import, export, purchase, or sell hypophosphorous acid or any other listed chemical in the United States if it is used or intended to be used in the production of a controlled

substance.

• Chemical suppliers are held liable for selling listed chemicals if they know or suspect that the chemical will be used for illicit purposes.

Hypophosphorous Acid (H3PO2) (Continued)

• Outlook

• The use of hypophosphorous acid in the production of methamphetamine is likely

to increase, particularly in the Midwest and Southwest regions of the United States

where methamphetamine production is prevalent.

– Injuries, property damage, and deaths also will increase as a growing number of inexperienced methamphetamine producers experiment with hypophosphorous acid.

Anhydrous Ammonia

• Anhydrous ammonia is found in fertilizer, countertop cleaner, and commercial refrigerant.

– On its own, it has a pungent, suffocating odor.

• Mixing anhydrous ammonia with other chemicals can release highly toxic gases.

– Because anhydrous ammonia seeks out water (anhydrous means “without

water”) and causes severe burns, any body part that comes into contact with it

should be flushed with water for at least 15 minutes to remove the ammoniafrom the skin.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia has extremely destructive effects on humans.

– Anhydrous ammonia gives off vapors during cooking that can burn the mouth,

throat, and lung tissue.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Anhydrous ammonia seeks water from the nearest source, including the human body (anhydrous means “without water”).

– Because of their high moisture content, EYES, LUNGS, and SKIN are at the

greatest risk of attracting the ammonia.

• When large amounts of anhydrous ammonia are inhaled, the throat swells and the

victim suffocates.

– Exposure to the vapors or liquids can cause severe burns, blindness, or death.

• Anhydrous ammonia has an IDLH (immediately dangerous to life and health) at only 300 parts per million...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is poses MANY hazards, especially when it is placed in improper vessels and handled/transported by individuals unfamiliar with the

dangers.

• Anhydrous ammonia has a boiling point of -28 degrees below zero.

– When a vessel containing anhydrous ammonia is MOVED, the anhydrous

ammonia will reach its boiling point and pressurize.

•This pressurization can cause vessels to violently RUPTURE, or if the vessel pressurizes and does NOT rupture, the opening of the container of anhydrous

ammonia at a later time can cause RAPID, VIOLENT depressurization.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is mainly used in the U.S. as either a fertilizer or a refrigerant.

– Meth producers tend to store the anhydrous ammonia in IMPROPER/UNAPPROVED containers such as:

•Propane tanks,

• Igloo coolers, or

•Fire extinguishers.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia leaves a tell-tell sign as it flows through these UNAPPROVED

CONTAINERS – a blue or blue green discoloration on the valve.

– PAY ATTENTION to details!!!

Anhydrous Ammonia (Continued)

• Because propane cylinders (and the other unapproved containers) are NOT designed to store anhydrous ammonia, they can EXPLODE as the ammonia eats

through the walls of the cylinders.

– The valves, which take on a bluish/green color, frequently deteriorate and can cause hazardous leaks!!!

Anhydrous Ammonia (Continued)

• Do NOT touch, move, or open any kind of tank or sealed container!!!

– Be aware that propane tanks are often WEAKENED and BRITTLE due to the

anhydrous ammonia and are SENSITIVE to ANY kind of movement or impact.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• These pictures show what happened to a fire extinguisher that was used to store

anhydrous ammonia…

Anhydrous Ammonia (Continued)

• Illegal drug makers often STEAL anhydrous ammonia from areas where it is stored

and used, such as farms.

• Attempted thefts have also occurred at places such as:

– Refrigeration systems holding ammonia,

– Underground pipelines carrying ammonia, and

– Rail cars transporting anhydrous ammonia.

• Often thefts are aborted when thieves are injured or overcome by the toxic gas...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia thieves had better beware!!!

• There is a new product called GloTell that farmers can add to their anhydrous

ammonia tanks…

• Meth cooks will run the risk that the GloTell additive will turn their hands bright

pink!

– This bright pink stain will fluoresce under ultraviolet light even if washed off!!!

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Also, GloTell will produce pink methamphetamine that CANNOT be bleached.

– Users who snort meth made with GloTell will find that they have PINK NOSES!

– Users who inject meth made with GloTell will see a pink stain at the point of

injection!

Sodium Carbonate (Soda Ash)

Sodium Carbonate (Soda Ash) (Continued)

Lead Acetate

Iodine

• Iodine is a natural element, and it is helpful to the body in SMALL amounts.

– However, if iodine is taken in large amounts it can become toxic.

•Extremely high does of iodine can limit the function of the thyroid.

Iodine (Continued)

Iodine (Continued)

• Iodine is bluish-black, and it has a characteristic odor, a sharp acrid taste, and it produces a violet corrosive vapor.

– The vapor is irritating to the respiratory system and eyes.

• The solid iodine irritates the eyes and may burn the skin, and it may cause severe

internal irritation and damage if ingested.

Iodine (Continued)

• Iodine is known as the “blue ingredient” in the production of meth (in the “red, white, and blue” method).

Iodine (Continued)

Iodine (Continued)

• It takes approximately 4 bottles of iodine tincture to produce 2 – 3 grams of meth.

Iodine (Continued)

Iodine (Continued)

• Iodine leaves distinctive yellow-blue or brown stains on surfaces in former methlabs.

Iodine (Continued)

Iodine (Continued)

Iodine (Continued)

• The only good thing about iodine is that it leaves yellow stains.

• If you see yellow stained coffee filters, gloves or paper towels, this could be an

indicator that you’re in a lab.

• If you see yellow stains, you can spray some starch on them.

– If they turn a purplish blue/black, it’s iodine.

• Iodine is the only substance that reacts with soluble starch to produce a purplish black color.

– The only way to get iodine vapor all over the walls is to cook meth.

Mercurous Chloride

Rock Salt

Hydrogen Chloride

• Hydrogen chloride gas is commercially available.

• Hydrogen chloride gas can also be made by mixing sulfuric acid and salt.

• Muriatic acid is simply hydrogen chloride gas suspended in water.

• Hydrogen chloride gas can be seen as a pale white smoke.

– It is a poisonous gas that can cause respiratory problems and death.

Hydrogen Chloride (Continued)

Ammonium Nitrate

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Hydriodic Acid

• Hydriodic acid is a corrosive acid that is colorless when freshly prepared.

– When hydriodic acid is exposed to light and air, it turns yellowish and brown.

• Hydriodic acid is a solution of hydrogen iodide gas in water.

• Hydriodic acid vapor is irritating to the respiratory system, skin, and eyes.

• Hydriodic acid liquid causes severe burns to the eyes and skin.

• If hydriodic acid is accidentally ingested, it can cause severe internal irritation and

damage.

Hydriodic Acid (Continued)

Catalyst Chemicals

• Catalyst Chemicals:

– Chemicals which SPEED UP a reaction process and/or cause it to go to GREATER COMPLETION.

Red Phosphorus

• Red phosphorus is found ON matchboxes, in road flares, and other explosives.

– Red Phosphorus IGNITES when OVERHEATED!!!

• By combining red phosphorus and iodine, you can easily create the highly

controlled substance known as hydriodic acid (which is an essential ingredient in making meth).

– Creating 2 – 3 grams of meth requires about 4 big boxes of matches.

Red Phosphorus (Continued)

• Red phosphorous is highly flammable and if it is overheated it can become white

phosphorous…

– White phosphorous is a volatile and highly explosive substance.

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Lithium

• Lithium is used in batteries.

• Lithium seriously burns the skin upon contact.

– It also reacts VIOLENTLY with WATER and is highly explosive.

Lithium (Continued)

• Lithium reacts VIOLENTLY with WATER, and if it is splashed in the eyes during

cooking it will cause blindness.

– Lithium is extremely caustic to all body tissues.

Lithium (Continued)

Lithium (Continued)

• Lithium metal is HIGHLY water reactive and it will BURN or EXPLODE if it comes into contact with WATER!

• Because of the moisture in your skin, it will burn exposed flesh.

• Lithium metal will DEGRADE when exposed to atmospheric moisture…

– This is why meth cooks store lithium metal in a solvent prior to use.

• It is typical to see harvested lithium strips in Coleman fuel or Mineral Spirits to prevent explosions.

•Large quantities can be harvested and saved in these containers until needed

for a cook.

Lithium (Continued)

• If you see battery shells in the trashcan, on the floor, etc. – this is a VERY GOOD indicator that you might be entering a meth lab!

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

• Lithium catches fire when in contact with water...

Solvent Chemicals

• Solvent Chemicals:

– A medium (liquid) in which a chemical operation takes place.

• Solvent chemicals (UNLIKE the precursor chemicals) CAN be

substituted/interchanged.

Ether

• Ether was once called “sweet vitriol” because of its hypnotic effect.

• Ether is a highly flammable substance that is used as an anesthetic agent –

especially in third world countries where more expensive anesthesia is not available.

– While inhaling the ether, patients could undergo complete surgical procedures while otherwise awake without feeling pain or concern.

Ether (Continued)

• Ether can be obtained from engine starting fluid.

• Ether is a solvent and it is flammable.

– It is particularly hazardous because it can cause BOTH fire and explosion.

• It has been said that a quart of ether can “level” a small house.

Ethyl Ether (Continued)

Ethyl Ether (Continued)

• Ether is VERY flammable and is HEAVIER than air.

– NEVER use ether near flames or non-sparkless motors.

– Ether is very PUNGENT – even a small evaporated amount of ether is VERY noticeable.

Acetone

• Acetone can be found in nail polish remover or paint thinner.

– It is extremely flammable.

• In the setting of a meth lab where meth is being cooked with high heat, acetone is

very dangerous.

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Toluene

• Toluene is used in brake fluid.

– When working with brake fluid (toluene), be careful not to spill it on your car

because it will eat away the paint and chrome…

• You also have to be careful using toluene around other household chemicals

because its high concentration of polyethylene glycol can cause it to ignite in a

violent fireball.

• Toluene is powerful enough to dissolve rubber.

Toluene (Continued)

• Toluene is used to form meth crystals.

– The fumes toluene releases can cause brain damage or death.

Toluene (Continued)

Toluene (Continued)

Ethanol

Isopropanol

Isopropanol (Continued)

Isopropyl Alcohol

Methanol

Methanol (Continued)

Methanol (Continued)

Benzene

Benzene (Continued)

Which of these is NOT a common ingredient in Meth?

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Page 8: Methamphetamine - PowerPoint - Chemicals and Ingredients ... · 2/5/2014 1 Methamphetamine - PowerPoint - Chemicals and Ingredients Used to Make Meth CJUS 240 Economic Costs of Meth

2/5/2014

8

Methamphetamine- PowerPoint

- Chemicals and Ingredients Used to Make Meth

CJUS 240

Economic Costs of Meth

• The economic cost of methamphetamine use in the U.S. reached $23.4 billion in

2005.

– This includes the burden of addiction, premature death, drug treatment, child care, and cleaning of lab sites.

– This figure does NOT take into account the future needs of the meth user.

Concerns with ACTIVE Meth Labs

• Danger of fire and explosion

• Chemical spills

• Inhalation of solvents, corrosives, and toxic gases

• “Booby traps”

• Waste disposal

Concerns with FORMER Meth Labs

• Vapors

• Chemical residues

• Methamphetamine residues

• Waste disposal

Equipment Used in Meth Production

• Pyrex or Corning dishes

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

• Coffee Filters

Equipment Used in Meth Production

Equipment Used in Meth Production

Basic Chemical Requirements

• In a clandestine laboratory, basic types of chemicals are necessary in order to

produce the desired drug.

– The basic types of chemicals needed are:

1) Precursor Chemicals

2) Reagent Chemicals

3) Catalyst Chemicals

4) Solvent Chemicals

List I Chemical

• The term “List I chemical” means a chemical specified by regulation of the Attorney General as a chemical that is used in manufacturing a controlled substance and is

IMPORTANT to the manufacture of the controlled substance.

• Examples of List I chemicals are:

– GBL

– Red Phosphorus

– Pseudoephedrine

List II Chemical

• The term “List II chemical” means a chemical (other than a List I chemical) specified by regulation of the Attorney General as a chemical that is USED in

manufacturing a controlled substance.

• Examples of List II chemicals are:

– Toluene

– Iodine

– Hydrochloric Acid

Precursor Chemicals

• Precursor Chemicals:

– A chemical that is ESSENTIAL to the production of a controlled substance and for

which NO SUBSTITUTION can be made.

Pseudoephedrine

• Pseudoephedrine is a decongestant found in cold medicine.

– Large amounts of pseudoephedrine on its own can harm the respiratory and nervous systems, as well as the heart.

Pseudoephedrine (Continued)

• Some of the common ways used to divert products containing pseudoephedrine

include:

– “Smurfing” – making multiple purchases at different locations

– Shelf-Sweeping – the theft of all shelf stock

– Shoplifting

– Theft from wholesalers

Pseudoephedrine (Continued)

• Pseudoephedrine smurfing is a method used by some methamphetamine producers to acquire large quantities of pseudoephedrine by enlisting the assistance of several

friends or associates (often referred to as “smurfers”) to make purchases at or below the legal thresholds from multiple retail locations.

– Smurfers are often addicts who trade the pseudoephedrine for finished methamphetamine.

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

• About 680 pseudoephedrine tablets are needed to produce one ounce of meth…

Pseudoephedrine (Continued)

Out With a Bang

An Unstable Recipe…

• Meth contains a variety of poisonous ingredients…

– Some become EVEN MORE DANGEROUS once the cooking process begins…

Common Ingredients to Make Methamphetamine

Reagent Chemicals

• Reagent Chemicals:

– Chemicals which REACT upon the precursor chemical causing it to chemicallyCHANGE.

• A reagent chemical is a chemical which is required for the synthesis of an illicit drug substance, but which is NOT incorporated into the final chemical product.

Hydrochloric Acid

• Hydrochloric acid is a highly corrosive liquid that is used to make plastic (such as PVC pipe and polyurethane).

– It can remove rust and iron-oxide from steel and is highly corrosive to human

skin.

•Hydrochloric acid makes up the majority of the gastric acid in the human

digestive fluid.

• In high concentrations, hydrochloric acid will literally eat away human flesh…

Hydrochloric Acid (Continued)

• Hydrochloric acid can be purchased from hardware stores as:

– Tile and Grout Acid Cleaner

– Muriatic Acid

– Pool Acid

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

• Hydrochloric acid is a solution of hydrogen chloride gas suspended in water.

– Hydrochloric acid is corrosive and is a light yellow liquid color from traces of iron, chlorine, and organic matter.

• Inhaling hydrochloric acid may cause coughing or choking, inflammation, and

ulceration of the respiratory tract.

• Concentrated solutions of hydrochloric acid can cause severe burns and irritate the

mucous membranes, eyes, and respiratory tract.

– Exposure to hydrochloric acid vapors may result in pulmonary edema and

possibly death.

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

Sodium Hydroxide (NaOH)

• Sodium hydroxide is also called Lye.

• Sodium hydroxide is classified as a corrosive, and it is one of the main chemicals in

drain cleaner.

– It is also used in aluminum etching and to create biodiesal.

– It can burn the skin or cause blindness.

• Sodium hydroxide is used to dispose of road kill because it turns the dead bodies

into a coffee-like liquid.

Sodium Hydroxide (NaOH) (Continued)

• Drain cleaner (sodium hydroxide) is extremely corrosive, and without wearing protection, even the smallest spill on the skin can eat through flesh…

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sulfuric Acid (H2SO4)

• Sulfuric acid is used in drain or toilet bowl cleaner as well as battery acid.

– It is another highly corrosive substance that burns the skin on contact.

Sulfuric Acid (H2SO4) (Continued)

• The product label warning for Drano® (sulfuric acid) says it all:

– DANGER: MAY BURN EYES AND SKIN ON CONTACT.

•HARMFUL IF SWALLOWED.

–Avoid contact with body and clothing.

•TOXIC GAS MAY FORM IF MIXED WITH OTHER CHEMICALS.

–If gases are released, leave immediately and ventilate area.

•FIRST AID: Give Immediately:

–EYES AND SKIN:

»Flush with water for 20 minutes.

»Remove affected clothing.

–IF SWALLOWED:

»Rinse mouth and drink a glass of water or milk.

»Do not induce vomiting.

–THEN SEEK MEDICAL AID.

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Hypophosphorous Acid (H3PO2)

• Hypophosphorous acid, which is used legally for a variety of commercial purposes,

is a chemical that increasingly is substituted for red phosphorus in the methamphetamine production process.

– The use of hypophospherous acid SIGNIFICANTLY increases the risk of fire!!!

• The federal government regulates the sale of hypophosphorous acid through registration, record keeping, reporting, and import/export requirements regardless

of the quantity being handled or distributed.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid is a colorless oily liquid that emits a SOUR odor.

– There is an extreme fire and explosion hazard if the hypophosphorous acid

comes into contact with a solvent such as acetone, toluene, or Coleman fuel.

• Hypophosphorous acid will also emit phosphine gas and the fumes can ignite.

Hypophosphorous Acid (H3PO2) (Continued)

• Although hypophosphorous acid is a List I chemical under the Controlled Substances Act, methamphetamine producers typically purchase the chemical via

the internet or from associates who also are engaged in methamphetamine

production.

– The use of hypophosphorous acid in methamphetamine production is an

EXTREMELY DANGEROUS PRACTICE because of the deadly gases that can be generated as well as the risk of fire or explosion.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid (H3PO2, also called phosphinic acid) is a strong acid that

typically is prepared as a solution of colorless, oily liquid in strengths of 50%, 30 to 32%, and 10%.

– It also is prepared in the form of salts (referred to as hypophosphite salts), particularly ammonium hypophosphite, calcium hypophosphite, iron (ferric)

hypophosphite, magnesium hypophosphite, manganese hypophosphite,

potassium hypophosphite, and sodium hypophosphite.

Hypophosphorous Acid (H3PO2) (Continued)

• Over 100 chemical firms located throughout the world produce hypophosphorous acid.

– The People's Republic of China and India have the largest numbers of

hypophosphorous acid producers, although there are a few producers in the United States.

• There are a wide variety of uses for hypophosphorous acid and its salts in

commercial industry; however, the chemicals have no legitimate household or retail uses.

Hypophosphorous Acid (H3PO2) (Continued)

• The legitimate commercial and laboratory fields that use hypophosphorous acid and its salts include the following:

– Chemical plating

– Food preparation

– Water treatment

– Polymers (as a bleaching agent, color stabilizer, or catalyst)

– Education and research in analytical chemistry

Hypophosphorous Acid (H3PO2) (Continued)

• Chemical suppliers typically distribute hypophosphorous acid in large quantities, for example, in drums containing 275 pounds of the diluted solution.

– Hypophosphorous acid also is distributed in smaller quantities.

• One-half liter of 50% concentrate hypophosphorous acid solution can be obtained from chemical suppliers for as little as $14.

Hypophosphorous Acid (H3PO2) (Continued)

• Methamphetamine laboratory operators typically obtain small quantities of the chemical from other laboratory operators who purchase large quantities of the

chemical and repackage it for further distribution.

– According to law enforcement sources, these individuals sell hypophosphorous acid for as much as $1,000 per half-liter.

•Methamphetamine laboratory operators also purchase hypophosphorous acidvia the internet.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid and the Internet

• The internet is a source of a great deal of information regarding hypophosphorous acid.

• Popular internet sites that disseminate information about illicit drugs contain information about the chemical, including numerous recipes for home production of

methamphetamine using hypophosphorous acid.

• There also are recipes for synthesizing hypophosphorous acid from available chemicals.

• Hypophosphorous acid solutions and salts have been sold to the general public via the internet.

• The Drug Enforcement Administration (DEA) has strong concerns regarding the sale

of chemicals on the internet and has requested that any sites (such as auction sites) that allow the sale of regulated chemicals on their domains require proof of

DEA registration from their clients.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid Used in Methamphetamine Production

• Hypophosphorous acid is used in the ephedrine-pseudoephedrine reduction method

of methamphetamine production.

– It is used in the methamphetamine production process to produce hydriodic acid,

an important reagent (it reacts with the ephedrine-pseudoephedrine but does NOT become part of the finished product).

Hypophosphorous Acid (H3PO2) (Continued)

• The regulation of hydriodic acid by DEA in 1993 rendered it virtually unavailable in

the United States.

– However, methamphetamine laboratory operators discovered methods to

produce hydriodic acid using a combination of iodine in water with red phosphorus.

• Laboratory operators found that red phosphorus could be obtained easily, either

from commercial supply companies or by scraping the striker pads from matchbooks or matchboxes.

• Methamphetamine producers soon discovered that hypophosphorous acid ALSO could be used in combination with iodine and water to produce hydriodic acid.

Hypophosphorous Acid (H3PO2) (Continued)

• The practice of using hypophosphorous acid in methamphetamine production is

believed to have begun in the United States in the late 1990s when a methamphetamine producer in Colorado obtained the recipe from Australia, where

the hypophosphorous acid method is prevalent.

– This man was known as a serial cook who had a long history of

methamphetamine production.

•Over several years he trained other laboratory operators in Colorado to produce methamphetamine using hypophosphorous acid.

• As his techniques were passed on to others, the number of methamphetaminelaboratories in Colorado using hypophosphorous acid continued to increase, and the

technique was passed on to numerous methamphetamine producers in other states.

Hypophosphorous Acid (H3PO2) (Continued)

• According to the El Paso Intelligence Center (EPIC) National Clandestine Laboratory

Seizure System, from 2000 through 2002 the number of seized methamphetaminelaboratories in the United States in which hypophosphorous acid was found

increased overall. (See Table 1.)

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid found at methamphetamine laboratories is packaged in a variety of ways.

• The chemical has been found in 1-gallon bottles of solution or in 1-pound jars of salts.

• Some hypophosphorous acid containers are labeled as "plating solution."

• Pint-sized brown glass bottles wrapped in red electrical tape also have been found to contain hypophosphorous acid; they have been discovered primarily in Colorado.

• The vast majority of hypophosphorous acid found at laboratory sites has been recovered from small toxic laboratories (STLs), those which yield gram to ounce

quantities per production cycle.

• Hypophosphorous acid has not been reported at large-scale laboratories operated by Mexican criminal groups in the United States.

Hypophosphorous Acid (H3PO2) (Continued)

• Hazards

• The iodine-hypophosphorous acid method is MORE HAZORDOUS than the iodine-

red phosphorus method, although the reaction using hypophosphorous acid is

faster and gives slightly higher yields.

– When hypophosphorous acid is used, the chemicals must be mixed together

SLOWLY in a PARTICULAR ORDER to prevent them from reacting violently.

Hypophosphorous Acid (H3PO2) (Continued)

• The combination of hypophosphorous acid with the other chemicals and with

certain metals can produce deadly phosphine gas during the initial mixing step and

can CONTINUE to produce phosphine gas for several days AFTER production has been completed…

Hypophosphorous Acid (H3PO2) (Continued)

• The iodine-hypophosphorous acid mixture has a tendency to decompose quickly when overheated or if heated for long periods of time, becoming cloudy or "milky-

white" just prior to giving off a cloud of phosphine gas that can ignite spontaneously.

– Hypophosphorous acid solutions may become unstable if evaporation results in

concentrations above 50%.

Hypophosphorous Acid (H3PO2) (Continued)

• [Note: Law enforcement or emergency personnel who encounter suspected

containers of hypophosphorous acid should use extreme care during handling because laboratory operators often attempt to obtain a more concentrated acid by

allowing water to evaporate from the mixture.]

• Because hypophosphorous acid often is used at small methamphetaminelaboratories operated by inexperienced or careless individuals, the potential hazards

of using this method are even greater.

• The risk of fire and explosion is higher in these laboratories, where professional

laboratory equipment typically is not used to contain the phosphine gas and where

safe handling precautions are not employed.

• In addition, these laboratories often are located in homes where children are

present and may come into contact with hypophosphorous acid.

• A child can easily mistake hypophosphorous acid for any other clear liquid,

particularly if it is stored in household containers or drinking glasses.

• Skin, eye, or inhalation exposure can be extremely harmful or fatal.

Hypophosphorous Acid (H3PO2) (Continued)

• Safety Precautions

• Always wear a self-contained breathing apparatus as well as protective clothing when entering areas where hypophosphorous acid may be present.

• When in contact with metals or in a high-temperature environment,

hypophosphorous acid can break down and liberate phosphine and flammable hydrogen gas.

• Do not allow the use of open flames, open lights, matches, or smoking in or around laboratories or dumpsites where hypophosphorous acid is handled.

• In case of fire, use a self-contained positive pressure breathing apparatus and full

protective equipment.

• Use water spray, fog, foam, dry chemicals, or other reagents as may be

appropriate for materials in the surrounding fire.

• Water may be used to cool the containers of hypophosphorous acid; however, use extreme care to avoid allowing water to enter the container.

• In case of spills, neutralize the spilled chemical with alkaline material (soda ash, lime), then absorb it with an inert material such as vermiculite, dry sand, or earth

and place in a chemical waste container.

• Do not use combustible materials such as sawdust.

Hypophosphorous Acid (H3PO2) (Continued)

• Legislation and Control

• In the United States hypophosphorous acid is one of 38 chemicals (or groups of

chemicals) controlled under law by DEA.

• On October 17, 2001, hypophosphorous acid and its salts, along with red and white phosphorus, were officially added as List I chemicals under section 1310 of the

Code of Federal Regulations.

• List I chemicals are defined as chemicals that are used in the manufacture of a

controlled substance in violation of the Controlled Substances Act (CSA) and are

important to the manufacture of a controlled substance.

• Under the law, suppliers are required to maintain records and report receipts, sales,

imports, and exports of these chemicals to DEA.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid, red phosphorus, and white phosphorus, as well as

ephedrine, are unique in that suppliers are required to report all transactions of

these chemicals, regardless of the amount.

• By contrast, the other 34 listed chemicals are only reportable after a supplier's

transactions for a chemical reach an established weight or volume threshold in a calendar month.

• In addition to reporting all transactions involving the chemical, suppliers are

expected to "know their customers" in order to prevent the diversion of these substances to methamphetamine laboratories, as it is illegal to import, export,

purchase, or sell hypophosphorous acid or any other listed chemical in the United States if it is used or intended to be used in the production of a controlled substance.

• Chemical suppliers are held liable for selling listed chemicals if they know or suspect that the chemical will be used for illicit purposes.

Hypophosphorous Acid (H3PO2) (Continued)

• Outlook

• The use of hypophosphorous acid in the production of methamphetamine is likely

to increase, particularly in the Midwest and Southwest regions of the United States

where methamphetamine production is prevalent.

– Injuries, property damage, and deaths also will increase as a growing number of

inexperienced methamphetamine producers experiment with hypophosphorous acid.

Anhydrous Ammonia

• Anhydrous ammonia is found in fertilizer, countertop cleaner, and commercial refrigerant.

– On its own, it has a pungent, suffocating odor.

• Mixing anhydrous ammonia with other chemicals can release highly toxic gases.

– Because anhydrous ammonia seeks out water (anhydrous means “without

water”) and causes severe burns, any body part that comes into contact with it

should be flushed with water for at least 15 minutes to remove the ammoniafrom the skin.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia has extremely destructive effects on humans.

– Anhydrous ammonia gives off vapors during cooking that can burn the mouth,

throat, and lung tissue.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Anhydrous ammonia seeks water from the nearest source, including the human body (anhydrous means “without water”).

– Because of their high moisture content, EYES, LUNGS, and SKIN are at the

greatest risk of attracting the ammonia.

• When large amounts of anhydrous ammonia are inhaled, the throat swells and the

victim suffocates.

– Exposure to the vapors or liquids can cause severe burns, blindness, or death.

• Anhydrous ammonia has an IDLH (immediately dangerous to life and health) at

only 300 parts per million...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is poses MANY hazards, especially when it is placed in improper vessels and handled/transported by individuals unfamiliar with the

dangers.

• Anhydrous ammonia has a boiling point of -28 degrees below zero.

– When a vessel containing anhydrous ammonia is MOVED, the anhydrous

ammonia will reach its boiling point and pressurize.

•This pressurization can cause vessels to violently RUPTURE, or if the vessel pressurizes and does NOT rupture, the opening of the container of anhydrous ammonia at a later time can cause RAPID, VIOLENT depressurization.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is mainly used in the U.S. as either a fertilizer or a refrigerant.

– Meth producers tend to store the anhydrous ammonia in IMPROPER/UNAPPROVED containers such as:

•Propane tanks,

• Igloo coolers, or

•Fire extinguishers.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia leaves a tell-tell sign as it flows through these UNAPPROVED CONTAINERS – a blue or blue green discoloration on the valve.

– PAY ATTENTION to details!!!

Anhydrous Ammonia (Continued)

• Because propane cylinders (and the other unapproved containers) are NOT designed to store anhydrous ammonia, they can EXPLODE as the ammonia eats

through the walls of the cylinders.

– The valves, which take on a bluish/green color, frequently deteriorate and can cause hazardous leaks!!!

Anhydrous Ammonia (Continued)

• Do NOT touch, move, or open any kind of tank or sealed container!!!

– Be aware that propane tanks are often WEAKENED and BRITTLE due to the

anhydrous ammonia and are SENSITIVE to ANY kind of movement or impact.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• These pictures show what happened to a fire extinguisher that was used to store

anhydrous ammonia…

Anhydrous Ammonia (Continued)

• Illegal drug makers often STEAL anhydrous ammonia from areas where it is stored

and used, such as farms.

• Attempted thefts have also occurred at places such as:

– Refrigeration systems holding ammonia,

– Underground pipelines carrying ammonia, and

– Rail cars transporting anhydrous ammonia.

• Often thefts are aborted when thieves are injured or overcome by the toxic gas...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia thieves had better beware!!!

• There is a new product called GloTell that farmers can add to their anhydrous

ammonia tanks…

• Meth cooks will run the risk that the GloTell additive will turn their hands bright

pink!

– This bright pink stain will fluoresce under ultraviolet light even if washed off!!!

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Also, GloTell will produce pink methamphetamine that CANNOT be bleached.

– Users who snort meth made with GloTell will find that they have PINK NOSES!

– Users who inject meth made with GloTell will see a pink stain at the point of

injection!

Sodium Carbonate (Soda Ash)

Sodium Carbonate (Soda Ash) (Continued)

Lead Acetate

Iodine

• Iodine is a natural element, and it is helpful to the body in SMALL amounts.

– However, if iodine is taken in large amounts it can become toxic.

•Extremely high does of iodine can limit the function of the thyroid.

Iodine (Continued)

Iodine (Continued)

• Iodine is bluish-black, and it has a characteristic odor, a sharp acrid taste, and it produces a violet corrosive vapor.

– The vapor is irritating to the respiratory system and eyes.

• The solid iodine irritates the eyes and may burn the skin, and it may cause severe

internal irritation and damage if ingested.

Iodine (Continued)

• Iodine is known as the “blue ingredient” in the production of meth (in the “red, white, and blue” method).

Iodine (Continued)

Iodine (Continued)

• It takes approximately 4 bottles of iodine tincture to produce 2 – 3 grams of meth.

Iodine (Continued)

Iodine (Continued)

• Iodine leaves distinctive yellow-blue or brown stains on surfaces in former methlabs.

Iodine (Continued)

Iodine (Continued)

Iodine (Continued)

• The only good thing about iodine is that it leaves yellow stains.

• If you see yellow stained coffee filters, gloves or paper towels, this could be an

indicator that you’re in a lab.

• If you see yellow stains, you can spray some starch on them.

– If they turn a purplish blue/black, it’s iodine.

• Iodine is the only substance that reacts with soluble starch to produce a purplish black color.

– The only way to get iodine vapor all over the walls is to cook meth.

Mercurous Chloride

Rock Salt

Hydrogen Chloride

• Hydrogen chloride gas is commercially available.

• Hydrogen chloride gas can also be made by mixing sulfuric acid and salt.

• Muriatic acid is simply hydrogen chloride gas suspended in water.

• Hydrogen chloride gas can be seen as a pale white smoke.

– It is a poisonous gas that can cause respiratory problems and death.

Hydrogen Chloride (Continued)

Ammonium Nitrate

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Hydriodic Acid

• Hydriodic acid is a corrosive acid that is colorless when freshly prepared.

– When hydriodic acid is exposed to light and air, it turns yellowish and brown.

• Hydriodic acid is a solution of hydrogen iodide gas in water.

• Hydriodic acid vapor is irritating to the respiratory system, skin, and eyes.

• Hydriodic acid liquid causes severe burns to the eyes and skin.

• If hydriodic acid is accidentally ingested, it can cause severe internal irritation and

damage.

Hydriodic Acid (Continued)

Catalyst Chemicals

• Catalyst Chemicals:

– Chemicals which SPEED UP a reaction process and/or cause it to go to GREATER COMPLETION.

Red Phosphorus

• Red phosphorus is found ON matchboxes, in road flares, and other explosives.

– Red Phosphorus IGNITES when OVERHEATED!!!

• By combining red phosphorus and iodine, you can easily create the highly

controlled substance known as hydriodic acid (which is an essential ingredient in making meth).

– Creating 2 – 3 grams of meth requires about 4 big boxes of matches.

Red Phosphorus (Continued)

• Red phosphorous is highly flammable and if it is overheated it can become white

phosphorous…

– White phosphorous is a volatile and highly explosive substance.

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Lithium

• Lithium is used in batteries.

• Lithium seriously burns the skin upon contact.

– It also reacts VIOLENTLY with WATER and is highly explosive.

Lithium (Continued)

• Lithium reacts VIOLENTLY with WATER, and if it is splashed in the eyes during

cooking it will cause blindness.

– Lithium is extremely caustic to all body tissues.

Lithium (Continued)

Lithium (Continued)

• Lithium metal is HIGHLY water reactive and it will BURN or EXPLODE if it comes into contact with WATER!

• Because of the moisture in your skin, it will burn exposed flesh.

• Lithium metal will DEGRADE when exposed to atmospheric moisture…

– This is why meth cooks store lithium metal in a solvent prior to use.

• It is typical to see harvested lithium strips in Coleman fuel or Mineral Spirits to prevent explosions.

•Large quantities can be harvested and saved in these containers until needed

for a cook.

Lithium (Continued)

• If you see battery shells in the trashcan, on the floor, etc. – this is a VERY GOOD

indicator that you might be entering a meth lab!

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

• Lithium catches fire when in contact with water...

Solvent Chemicals

• Solvent Chemicals:

– A medium (liquid) in which a chemical operation takes place.

• Solvent chemicals (UNLIKE the precursor chemicals) CAN be

substituted/interchanged.

Ether

• Ether was once called “sweet vitriol” because of its hypnotic effect.

• Ether is a highly flammable substance that is used as an anesthetic agent –especially in third world countries where more expensive anesthesia is not available.

– While inhaling the ether, patients could undergo complete surgical procedures while otherwise awake without feeling pain or concern.

Ether (Continued)

• Ether can be obtained from engine starting fluid.

• Ether is a solvent and it is flammable.

– It is particularly hazardous because it can cause BOTH fire and explosion.

• It has been said that a quart of ether can “level” a small house.

Ethyl Ether (Continued)

Ethyl Ether (Continued)

• Ether is VERY flammable and is HEAVIER than air.

– NEVER use ether near flames or non-sparkless motors.

– Ether is very PUNGENT – even a small evaporated amount of ether is VERY noticeable.

Acetone

• Acetone can be found in nail polish remover or paint thinner.

– It is extremely flammable.

• In the setting of a meth lab where meth is being cooked with high heat, acetone is

very dangerous.

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Toluene

• Toluene is used in brake fluid.

– When working with brake fluid (toluene), be careful not to spill it on your car

because it will eat away the paint and chrome…

• You also have to be careful using toluene around other household chemicals

because its high concentration of polyethylene glycol can cause it to ignite in a

violent fireball.

• Toluene is powerful enough to dissolve rubber.

Toluene (Continued)

• Toluene is used to form meth crystals.

– The fumes toluene releases can cause brain damage or death.

Toluene (Continued)

Toluene (Continued)

Ethanol

Isopropanol

Isopropanol (Continued)

Isopropyl Alcohol

Methanol

Methanol (Continued)

Methanol (Continued)

Benzene

Benzene (Continued)

Which of these is NOT a common ingredient in Meth?

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Methamphetamine- PowerPoint- Chemicals and Ingredients Used to Make Meth

CJUS 240

Economic Costs of Meth

• The economic cost of methamphetamine use in the U.S. reached $23.4 billion in

2005.

– This includes the burden of addiction, premature death, drug treatment, child

care, and cleaning of lab sites.

– This figure does NOT take into account the future needs of the meth user.

Concerns with ACTIVE Meth Labs

• Danger of fire and explosion

• Chemical spills

• Inhalation of solvents, corrosives, and toxic gases

• “Booby traps”

• Waste disposal

Concerns with FORMER Meth Labs

• Vapors

• Chemical residues

• Methamphetamine residues

• Waste disposal

Equipment Used in Meth Production

• Pyrex or Corning dishes

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

• Coffee Filters

Equipment Used in Meth Production

Equipment Used in Meth Production

Basic Chemical Requirements

• In a clandestine laboratory, basic types of chemicals are necessary in order to

produce the desired drug.

– The basic types of chemicals needed are:

1) Precursor Chemicals

2) Reagent Chemicals

3) Catalyst Chemicals

4) Solvent Chemicals

List I Chemical

• The term “List I chemical” means a chemical specified by regulation of the Attorney General as a chemical that is used in manufacturing a controlled substance and is

IMPORTANT to the manufacture of the controlled substance.

• Examples of List I chemicals are:

– GBL

– Red Phosphorus

– Pseudoephedrine

List II Chemical

• The term “List II chemical” means a chemical (other than a List I chemical) specified by regulation of the Attorney General as a chemical that is USED in

manufacturing a controlled substance.

• Examples of List II chemicals are:

– Toluene

– Iodine

– Hydrochloric Acid

Precursor Chemicals

• Precursor Chemicals:

– A chemical that is ESSENTIAL to the production of a controlled substance and for

which NO SUBSTITUTION can be made.

Pseudoephedrine

• Pseudoephedrine is a decongestant found in cold medicine.

– Large amounts of pseudoephedrine on its own can harm the respiratory and nervous systems, as well as the heart.

Pseudoephedrine (Continued)

• Some of the common ways used to divert products containing pseudoephedrine

include:

– “Smurfing” – making multiple purchases at different locations

– Shelf-Sweeping – the theft of all shelf stock

– Shoplifting

– Theft from wholesalers

Pseudoephedrine (Continued)

• Pseudoephedrine smurfing is a method used by some methamphetamine producers to acquire large quantities of pseudoephedrine by enlisting the assistance of several

friends or associates (often referred to as “smurfers”) to make purchases at or below the legal thresholds from multiple retail locations.

– Smurfers are often addicts who trade the pseudoephedrine for finished

methamphetamine.

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

• About 680 pseudoephedrine tablets are needed to produce one ounce of meth…

Pseudoephedrine (Continued)

Out With a Bang

An Unstable Recipe…

• Meth contains a variety of poisonous ingredients…

– Some become EVEN MORE DANGEROUS once the cooking process begins…

Common Ingredients to Make Methamphetamine

Reagent Chemicals

• Reagent Chemicals:

– Chemicals which REACT upon the precursor chemical causing it to chemicallyCHANGE.

• A reagent chemical is a chemical which is required for the synthesis of an illicit drug substance, but which is NOT incorporated into the final chemical product.

Hydrochloric Acid

• Hydrochloric acid is a highly corrosive liquid that is used to make plastic (such as PVC pipe and polyurethane).

– It can remove rust and iron-oxide from steel and is highly corrosive to human

skin.

•Hydrochloric acid makes up the majority of the gastric acid in the human

digestive fluid.

• In high concentrations, hydrochloric acid will literally eat away human flesh…

Hydrochloric Acid (Continued)

• Hydrochloric acid can be purchased from hardware stores as:

– Tile and Grout Acid Cleaner

– Muriatic Acid

– Pool Acid

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

• Hydrochloric acid is a solution of hydrogen chloride gas suspended in water.

– Hydrochloric acid is corrosive and is a light yellow liquid color from traces of iron, chlorine, and organic matter.

• Inhaling hydrochloric acid may cause coughing or choking, inflammation, and

ulceration of the respiratory tract.

• Concentrated solutions of hydrochloric acid can cause severe burns and irritate the

mucous membranes, eyes, and respiratory tract.

– Exposure to hydrochloric acid vapors may result in pulmonary edema and

possibly death.

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

Sodium Hydroxide (NaOH)

• Sodium hydroxide is also called Lye.

• Sodium hydroxide is classified as a corrosive, and it is one of the main chemicals in

drain cleaner.

– It is also used in aluminum etching and to create biodiesal.

– It can burn the skin or cause blindness.

• Sodium hydroxide is used to dispose of road kill because it turns the dead bodies

into a coffee-like liquid.

Sodium Hydroxide (NaOH) (Continued)

• Drain cleaner (sodium hydroxide) is extremely corrosive, and without wearing

protection, even the smallest spill on the skin can eat through flesh…

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sulfuric Acid (H2SO4)

• Sulfuric acid is used in drain or toilet bowl cleaner as well as battery acid.

– It is another highly corrosive substance that burns the skin on contact.

Sulfuric Acid (H2SO4) (Continued)

• The product label warning for Drano® (sulfuric acid) says it all:

– DANGER: MAY BURN EYES AND SKIN ON CONTACT.

•HARMFUL IF SWALLOWED.

–Avoid contact with body and clothing.

•TOXIC GAS MAY FORM IF MIXED WITH OTHER CHEMICALS.

–If gases are released, leave immediately and ventilate area.

•FIRST AID: Give Immediately:

–EYES AND SKIN:

»Flush with water for 20 minutes.

»Remove affected clothing.

–IF SWALLOWED:

»Rinse mouth and drink a glass of water or milk.

»Do not induce vomiting.

–THEN SEEK MEDICAL AID.

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Hypophosphorous Acid (H3PO2)

• Hypophosphorous acid, which is used legally for a variety of commercial purposes,

is a chemical that increasingly is substituted for red phosphorus in the methamphetamine production process.

– The use of hypophospherous acid SIGNIFICANTLY increases the risk of fire!!!

• The federal government regulates the sale of hypophosphorous acid through registration, record keeping, reporting, and import/export requirements regardless

of the quantity being handled or distributed.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid is a colorless oily liquid that emits a SOUR odor.

– There is an extreme fire and explosion hazard if the hypophosphorous acidcomes into contact with a solvent such as acetone, toluene, or Coleman fuel.

• Hypophosphorous acid will also emit phosphine gas and the fumes can ignite.

Hypophosphorous Acid (H3PO2) (Continued)

• Although hypophosphorous acid is a List I chemical under the Controlled Substances Act, methamphetamine producers typically purchase the chemical via

the internet or from associates who also are engaged in methamphetamine

production.

– The use of hypophosphorous acid in methamphetamine production is an

EXTREMELY DANGEROUS PRACTICE because of the deadly gases that can be generated as well as the risk of fire or explosion.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid (H3PO2, also called phosphinic acid) is a strong acid that

typically is prepared as a solution of colorless, oily liquid in strengths of 50%, 30 to 32%, and 10%.

– It also is prepared in the form of salts (referred to as hypophosphite salts), particularly ammonium hypophosphite, calcium hypophosphite, iron (ferric)

hypophosphite, magnesium hypophosphite, manganese hypophosphite,

potassium hypophosphite, and sodium hypophosphite.

Hypophosphorous Acid (H3PO2) (Continued)

• Over 100 chemical firms located throughout the world produce hypophosphorous

acid.

– The People's Republic of China and India have the largest numbers of

hypophosphorous acid producers, although there are a few producers in the United States.

• There are a wide variety of uses for hypophosphorous acid and its salts in

commercial industry; however, the chemicals have no legitimate household or retail uses.

Hypophosphorous Acid (H3PO2) (Continued)

• The legitimate commercial and laboratory fields that use hypophosphorous acid and its salts include the following:

– Chemical plating

– Food preparation

– Water treatment

– Polymers (as a bleaching agent, color stabilizer, or catalyst)

– Education and research in analytical chemistry

Hypophosphorous Acid (H3PO2) (Continued)

• Chemical suppliers typically distribute hypophosphorous acid in large quantities, for example, in drums containing 275 pounds of the diluted solution.

– Hypophosphorous acid also is distributed in smaller quantities.

• One-half liter of 50% concentrate hypophosphorous acid solution can be obtained from chemical suppliers for as little as $14.

Hypophosphorous Acid (H3PO2) (Continued)

• Methamphetamine laboratory operators typically obtain small quantities of the chemical from other laboratory operators who purchase large quantities of the

chemical and repackage it for further distribution.

– According to law enforcement sources, these individuals sell hypophosphorous acid for as much as $1,000 per half-liter.

•Methamphetamine laboratory operators also purchase hypophosphorous acidvia the internet.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid and the Internet

• The internet is a source of a great deal of information regarding hypophosphorous acid.

• Popular internet sites that disseminate information about illicit drugs contain information about the chemical, including numerous recipes for home production of

methamphetamine using hypophosphorous acid.

• There also are recipes for synthesizing hypophosphorous acid from available chemicals.

• Hypophosphorous acid solutions and salts have been sold to the general public via the internet.

• The Drug Enforcement Administration (DEA) has strong concerns regarding the sale

of chemicals on the internet and has requested that any sites (such as auction sites) that allow the sale of regulated chemicals on their domains require proof of DEA registration from their clients.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid Used in Methamphetamine Production

• Hypophosphorous acid is used in the ephedrine-pseudoephedrine reduction method

of methamphetamine production.

– It is used in the methamphetamine production process to produce hydriodic acid,

an important reagent (it reacts with the ephedrine-pseudoephedrine but does NOT become part of the finished product).

Hypophosphorous Acid (H3PO2) (Continued)

• The regulation of hydriodic acid by DEA in 1993 rendered it virtually unavailable in

the United States.

– However, methamphetamine laboratory operators discovered methods to

produce hydriodic acid using a combination of iodine in water with red phosphorus.

• Laboratory operators found that red phosphorus could be obtained easily, either

from commercial supply companies or by scraping the striker pads from matchbooks or matchboxes.

• Methamphetamine producers soon discovered that hypophosphorous acid ALSO could be used in combination with iodine and water to produce hydriodic acid.

Hypophosphorous Acid (H3PO2) (Continued)

• The practice of using hypophosphorous acid in methamphetamine production is

believed to have begun in the United States in the late 1990s when a methamphetamine producer in Colorado obtained the recipe from Australia, where

the hypophosphorous acid method is prevalent.

– This man was known as a serial cook who had a long history of

methamphetamine production.

•Over several years he trained other laboratory operators in Colorado to produce methamphetamine using hypophosphorous acid.

• As his techniques were passed on to others, the number of methamphetaminelaboratories in Colorado using hypophosphorous acid continued to increase, and the

technique was passed on to numerous methamphetamine producers in other

states.

Hypophosphorous Acid (H3PO2) (Continued)

• According to the El Paso Intelligence Center (EPIC) National Clandestine Laboratory

Seizure System, from 2000 through 2002 the number of seized methamphetaminelaboratories in the United States in which hypophosphorous acid was found

increased overall. (See Table 1.)

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid found at methamphetamine laboratories is packaged in a variety of ways.

• The chemical has been found in 1-gallon bottles of solution or in 1-pound jars of salts.

• Some hypophosphorous acid containers are labeled as "plating solution."

• Pint-sized brown glass bottles wrapped in red electrical tape also have been found to contain hypophosphorous acid; they have been discovered primarily in Colorado.

• The vast majority of hypophosphorous acid found at laboratory sites has been recovered from small toxic laboratories (STLs), those which yield gram to ounce

quantities per production cycle.

• Hypophosphorous acid has not been reported at large-scale laboratories operated by Mexican criminal groups in the United States.

Hypophosphorous Acid (H3PO2) (Continued)

• Hazards

• The iodine-hypophosphorous acid method is MORE HAZORDOUS than the iodine-

red phosphorus method, although the reaction using hypophosphorous acid is faster and gives slightly higher yields.

– When hypophosphorous acid is used, the chemicals must be mixed together

SLOWLY in a PARTICULAR ORDER to prevent them from reacting violently.

Hypophosphorous Acid (H3PO2) (Continued)

• The combination of hypophosphorous acid with the other chemicals and with

certain metals can produce deadly phosphine gas during the initial mixing step and

can CONTINUE to produce phosphine gas for several days AFTER production has been completed…

Hypophosphorous Acid (H3PO2) (Continued)

• The iodine-hypophosphorous acid mixture has a tendency to decompose quickly when overheated or if heated for long periods of time, becoming cloudy or "milky-

white" just prior to giving off a cloud of phosphine gas that can ignite spontaneously.

– Hypophosphorous acid solutions may become unstable if evaporation results in

concentrations above 50%.

Hypophosphorous Acid (H3PO2) (Continued)

• [Note: Law enforcement or emergency personnel who encounter suspected

containers of hypophosphorous acid should use extreme care during handling because laboratory operators often attempt to obtain a more concentrated acid by

allowing water to evaporate from the mixture.]

• Because hypophosphorous acid often is used at small methamphetaminelaboratories operated by inexperienced or careless individuals, the potential hazards

of using this method are even greater.

• The risk of fire and explosion is higher in these laboratories, where professional

laboratory equipment typically is not used to contain the phosphine gas and where

safe handling precautions are not employed.

• In addition, these laboratories often are located in homes where children are

present and may come into contact with hypophosphorous acid.

• A child can easily mistake hypophosphorous acid for any other clear liquid,

particularly if it is stored in household containers or drinking glasses.

• Skin, eye, or inhalation exposure can be extremely harmful or fatal.

Hypophosphorous Acid (H3PO2) (Continued)

• Safety Precautions

• Always wear a self-contained breathing apparatus as well as protective clothing when entering areas where hypophosphorous acid may be present.

• When in contact with metals or in a high-temperature environment,

hypophosphorous acid can break down and liberate phosphine and flammable hydrogen gas.

• Do not allow the use of open flames, open lights, matches, or smoking in or around laboratories or dumpsites where hypophosphorous acid is handled.

• In case of fire, use a self-contained positive pressure breathing apparatus and full

protective equipment.

• Use water spray, fog, foam, dry chemicals, or other reagents as may be

appropriate for materials in the surrounding fire.

• Water may be used to cool the containers of hypophosphorous acid; however, use extreme care to avoid allowing water to enter the container.

• In case of spills, neutralize the spilled chemical with alkaline material (soda ash, lime), then absorb it with an inert material such as vermiculite, dry sand, or earth

and place in a chemical waste container.

• Do not use combustible materials such as sawdust.

Hypophosphorous Acid (H3PO2) (Continued)

• Legislation and Control

• In the United States hypophosphorous acid is one of 38 chemicals (or groups of chemicals) controlled under law by DEA.

• On October 17, 2001, hypophosphorous acid and its salts, along with red and white phosphorus, were officially added as List I chemicals under section 1310 of the

Code of Federal Regulations.

• List I chemicals are defined as chemicals that are used in the manufacture of a

controlled substance in violation of the Controlled Substances Act (CSA) and are

important to the manufacture of a controlled substance.

• Under the law, suppliers are required to maintain records and report receipts, sales,

imports, and exports of these chemicals to DEA.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid, red phosphorus, and white phosphorus, as well as ephedrine, are unique in that suppliers are required to report all transactions of

these chemicals, regardless of the amount.

• By contrast, the other 34 listed chemicals are only reportable after a supplier's

transactions for a chemical reach an established weight or volume threshold in a calendar month.

• In addition to reporting all transactions involving the chemical, suppliers are

expected to "know their customers" in order to prevent the diversion of these substances to methamphetamine laboratories, as it is illegal to import, export,

purchase, or sell hypophosphorous acid or any other listed chemical in the United States if it is used or intended to be used in the production of a controlled

substance.

• Chemical suppliers are held liable for selling listed chemicals if they know or suspect that the chemical will be used for illicit purposes.

Hypophosphorous Acid (H3PO2) (Continued)

• Outlook

• The use of hypophosphorous acid in the production of methamphetamine is likely

to increase, particularly in the Midwest and Southwest regions of the United States

where methamphetamine production is prevalent.

– Injuries, property damage, and deaths also will increase as a growing number of

inexperienced methamphetamine producers experiment with hypophosphorous acid.

Anhydrous Ammonia

• Anhydrous ammonia is found in fertilizer, countertop cleaner, and commercial refrigerant.

– On its own, it has a pungent, suffocating odor.

• Mixing anhydrous ammonia with other chemicals can release highly toxic gases.

– Because anhydrous ammonia seeks out water (anhydrous means “without

water”) and causes severe burns, any body part that comes into contact with it

should be flushed with water for at least 15 minutes to remove the ammoniafrom the skin.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia has extremely destructive effects on humans.

– Anhydrous ammonia gives off vapors during cooking that can burn the mouth,

throat, and lung tissue.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Anhydrous ammonia seeks water from the nearest source, including the human body (anhydrous means “without water”).

– Because of their high moisture content, EYES, LUNGS, and SKIN are at the

greatest risk of attracting the ammonia.

• When large amounts of anhydrous ammonia are inhaled, the throat swells and the

victim suffocates.

– Exposure to the vapors or liquids can cause severe burns, blindness, or death.

• Anhydrous ammonia has an IDLH (immediately dangerous to life and health) at

only 300 parts per million...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is poses MANY hazards, especially when it is placed in improper vessels and handled/transported by individuals unfamiliar with the

dangers.

• Anhydrous ammonia has a boiling point of -28 degrees below zero.

– When a vessel containing anhydrous ammonia is MOVED, the anhydrous

ammonia will reach its boiling point and pressurize.

•This pressurization can cause vessels to violently RUPTURE, or if the vessel pressurizes and does NOT rupture, the opening of the container of anhydrous

ammonia at a later time can cause RAPID, VIOLENT depressurization.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is mainly used in the U.S. as either a fertilizer or a refrigerant.

– Meth producers tend to store the anhydrous ammonia in IMPROPER/UNAPPROVED containers such as:

•Propane tanks,

• Igloo coolers, or

•Fire extinguishers.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia leaves a tell-tell sign as it flows through these UNAPPROVED

CONTAINERS – a blue or blue green discoloration on the valve.

– PAY ATTENTION to details!!!

Anhydrous Ammonia (Continued)

• Because propane cylinders (and the other unapproved containers) are NOT designed to store anhydrous ammonia, they can EXPLODE as the ammonia eats

through the walls of the cylinders.

– The valves, which take on a bluish/green color, frequently deteriorate and can cause hazardous leaks!!!

Anhydrous Ammonia (Continued)

• Do NOT touch, move, or open any kind of tank or sealed container!!!

– Be aware that propane tanks are often WEAKENED and BRITTLE due to the

anhydrous ammonia and are SENSITIVE to ANY kind of movement or impact.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• These pictures show what happened to a fire extinguisher that was used to store

anhydrous ammonia…

Anhydrous Ammonia (Continued)

• Illegal drug makers often STEAL anhydrous ammonia from areas where it is stored

and used, such as farms.

• Attempted thefts have also occurred at places such as:

– Refrigeration systems holding ammonia,

– Underground pipelines carrying ammonia, and

– Rail cars transporting anhydrous ammonia.

• Often thefts are aborted when thieves are injured or overcome by the toxic gas...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia thieves had better beware!!!

• There is a new product called GloTell that farmers can add to their anhydrous

ammonia tanks…

• Meth cooks will run the risk that the GloTell additive will turn their hands bright

pink!

– This bright pink stain will fluoresce under ultraviolet light even if washed off!!!

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Also, GloTell will produce pink methamphetamine that CANNOT be bleached.

– Users who snort meth made with GloTell will find that they have PINK NOSES!

– Users who inject meth made with GloTell will see a pink stain at the point of

injection!

Sodium Carbonate (Soda Ash)

Sodium Carbonate (Soda Ash) (Continued)

Lead Acetate

Iodine

• Iodine is a natural element, and it is helpful to the body in SMALL amounts.

– However, if iodine is taken in large amounts it can become toxic.

•Extremely high does of iodine can limit the function of the thyroid.

Iodine (Continued)

Iodine (Continued)

• Iodine is bluish-black, and it has a characteristic odor, a sharp acrid taste, and it produces a violet corrosive vapor.

– The vapor is irritating to the respiratory system and eyes.

• The solid iodine irritates the eyes and may burn the skin, and it may cause severe

internal irritation and damage if ingested.

Iodine (Continued)

• Iodine is known as the “blue ingredient” in the production of meth (in the “red, white, and blue” method).

Iodine (Continued)

Iodine (Continued)

• It takes approximately 4 bottles of iodine tincture to produce 2 – 3 grams of meth.

Iodine (Continued)

Iodine (Continued)

• Iodine leaves distinctive yellow-blue or brown stains on surfaces in former methlabs.

Iodine (Continued)

Iodine (Continued)

Iodine (Continued)

• The only good thing about iodine is that it leaves yellow stains.

• If you see yellow stained coffee filters, gloves or paper towels, this could be an

indicator that you’re in a lab.

• If you see yellow stains, you can spray some starch on them.

– If they turn a purplish blue/black, it’s iodine.

• Iodine is the only substance that reacts with soluble starch to produce a purplish black color.

– The only way to get iodine vapor all over the walls is to cook meth.

Mercurous Chloride

Rock Salt

Hydrogen Chloride

• Hydrogen chloride gas is commercially available.

• Hydrogen chloride gas can also be made by mixing sulfuric acid and salt.

• Muriatic acid is simply hydrogen chloride gas suspended in water.

• Hydrogen chloride gas can be seen as a pale white smoke.

– It is a poisonous gas that can cause respiratory problems and death.

Hydrogen Chloride (Continued)

Ammonium Nitrate

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Hydriodic Acid

• Hydriodic acid is a corrosive acid that is colorless when freshly prepared.

– When hydriodic acid is exposed to light and air, it turns yellowish and brown.

• Hydriodic acid is a solution of hydrogen iodide gas in water.

• Hydriodic acid vapor is irritating to the respiratory system, skin, and eyes.

• Hydriodic acid liquid causes severe burns to the eyes and skin.

• If hydriodic acid is accidentally ingested, it can cause severe internal irritation and

damage.

Hydriodic Acid (Continued)

Catalyst Chemicals

• Catalyst Chemicals:

– Chemicals which SPEED UP a reaction process and/or cause it to go to GREATER COMPLETION.

Red Phosphorus

• Red phosphorus is found ON matchboxes, in road flares, and other explosives.

– Red Phosphorus IGNITES when OVERHEATED!!!

• By combining red phosphorus and iodine, you can easily create the highly

controlled substance known as hydriodic acid (which is an essential ingredient in making meth).

– Creating 2 – 3 grams of meth requires about 4 big boxes of matches.

Red Phosphorus (Continued)

• Red phosphorous is highly flammable and if it is overheated it can become white

phosphorous…

– White phosphorous is a volatile and highly explosive substance.

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Lithium

• Lithium is used in batteries.

• Lithium seriously burns the skin upon contact.

– It also reacts VIOLENTLY with WATER and is highly explosive.

Lithium (Continued)

• Lithium reacts VIOLENTLY with WATER, and if it is splashed in the eyes during

cooking it will cause blindness.

– Lithium is extremely caustic to all body tissues.

Lithium (Continued)

Lithium (Continued)

• Lithium metal is HIGHLY water reactive and it will BURN or EXPLODE if it comes into contact with WATER!

• Because of the moisture in your skin, it will burn exposed flesh.

• Lithium metal will DEGRADE when exposed to atmospheric moisture…

– This is why meth cooks store lithium metal in a solvent prior to use.

• It is typical to see harvested lithium strips in Coleman fuel or Mineral Spirits to prevent explosions.

•Large quantities can be harvested and saved in these containers until needed

for a cook.

Lithium (Continued)

• If you see battery shells in the trashcan, on the floor, etc. – this is a VERY GOOD

indicator that you might be entering a meth lab!

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

• Lithium catches fire when in contact with water...

Solvent Chemicals

• Solvent Chemicals:

– A medium (liquid) in which a chemical operation takes place.

• Solvent chemicals (UNLIKE the precursor chemicals) CAN be

substituted/interchanged.

Ether

• Ether was once called “sweet vitriol” because of its hypnotic effect.

• Ether is a highly flammable substance that is used as an anesthetic agent –

especially in third world countries where more expensive anesthesia is not available.

– While inhaling the ether, patients could undergo complete surgical procedures while otherwise awake without feeling pain or concern.

Ether (Continued)

• Ether can be obtained from engine starting fluid.

• Ether is a solvent and it is flammable.

– It is particularly hazardous because it can cause BOTH fire and explosion.

• It has been said that a quart of ether can “level” a small house.

Ethyl Ether (Continued)

Ethyl Ether (Continued)

• Ether is VERY flammable and is HEAVIER than air.

– NEVER use ether near flames or non-sparkless motors.

– Ether is very PUNGENT – even a small evaporated amount of ether is VERY noticeable.

Acetone

• Acetone can be found in nail polish remover or paint thinner.

– It is extremely flammable.

• In the setting of a meth lab where meth is being cooked with high heat, acetone is

very dangerous.

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Toluene

• Toluene is used in brake fluid.

– When working with brake fluid (toluene), be careful not to spill it on your car

because it will eat away the paint and chrome…

• You also have to be careful using toluene around other household chemicals

because its high concentration of polyethylene glycol can cause it to ignite in a

violent fireball.

• Toluene is powerful enough to dissolve rubber.

Toluene (Continued)

• Toluene is used to form meth crystals.

– The fumes toluene releases can cause brain damage or death.

Toluene (Continued)

Toluene (Continued)

Ethanol

Isopropanol

Isopropanol (Continued)

Isopropyl Alcohol

Methanol

Methanol (Continued)

Methanol (Continued)

Benzene

Benzene (Continued)

Which of these is NOT a common ingredient in Meth?

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Methamphetamine- PowerPoint

- Chemicals and Ingredients Used to Make Meth

CJUS 240

Economic Costs of Meth

• The economic cost of methamphetamine use in the U.S. reached $23.4 billion in

2005.

– This includes the burden of addiction, premature death, drug treatment, child

care, and cleaning of lab sites.

– This figure does NOT take into account the future needs of the meth user.

Concerns with ACTIVE Meth Labs

• Danger of fire and explosion

• Chemical spills

• Inhalation of solvents, corrosives, and toxic gases

• “Booby traps”

• Waste disposal

Concerns with FORMER Meth Labs

• Vapors

• Chemical residues

• Methamphetamine residues

• Waste disposal

Equipment Used in Meth Production

• Pyrex or Corning dishes

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

• Coffee Filters

Equipment Used in Meth Production

Equipment Used in Meth Production

Basic Chemical Requirements

• In a clandestine laboratory, basic types of chemicals are necessary in order to

produce the desired drug.

– The basic types of chemicals needed are:

1) Precursor Chemicals

2) Reagent Chemicals

3) Catalyst Chemicals

4) Solvent Chemicals

List I Chemical

• The term “List I chemical” means a chemical specified by regulation of the Attorney General as a chemical that is used in manufacturing a controlled substance and is

IMPORTANT to the manufacture of the controlled substance.

• Examples of List I chemicals are:

– GBL

– Red Phosphorus

– Pseudoephedrine

List II Chemical

• The term “List II chemical” means a chemical (other than a List I chemical) specified by regulation of the Attorney General as a chemical that is USED in manufacturing a controlled substance.

• Examples of List II chemicals are:

– Toluene

– Iodine

– Hydrochloric Acid

Precursor Chemicals

• Precursor Chemicals:

– A chemical that is ESSENTIAL to the production of a controlled substance and for which NO SUBSTITUTION can be made.

Pseudoephedrine

• Pseudoephedrine is a decongestant found in cold medicine.

– Large amounts of pseudoephedrine on its own can harm the respiratory and nervous systems, as well as the heart.

Pseudoephedrine (Continued)

• Some of the common ways used to divert products containing pseudoephedrine

include:

– “Smurfing” – making multiple purchases at different locations

– Shelf-Sweeping – the theft of all shelf stock

– Shoplifting

– Theft from wholesalers

Pseudoephedrine (Continued)

• Pseudoephedrine smurfing is a method used by some methamphetamine producers to acquire large quantities of pseudoephedrine by enlisting the assistance of several

friends or associates (often referred to as “smurfers”) to make purchases at or below the legal thresholds from multiple retail locations.

– Smurfers are often addicts who trade the pseudoephedrine for finished

methamphetamine.

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

• About 680 pseudoephedrine tablets are needed to produce one ounce of meth…

Pseudoephedrine (Continued)

Out With a Bang

An Unstable Recipe…

• Meth contains a variety of poisonous ingredients…

– Some become EVEN MORE DANGEROUS once the cooking process begins…

Common Ingredients to Make Methamphetamine

Reagent Chemicals

• Reagent Chemicals:

– Chemicals which REACT upon the precursor chemical causing it to chemicallyCHANGE.

• A reagent chemical is a chemical which is required for the synthesis of an illicit drug substance, but which is NOT incorporated into the final chemical product.

Hydrochloric Acid

• Hydrochloric acid is a highly corrosive liquid that is used to make plastic (such as PVC pipe and polyurethane).

– It can remove rust and iron-oxide from steel and is highly corrosive to human

skin.

•Hydrochloric acid makes up the majority of the gastric acid in the human

digestive fluid.

• In high concentrations, hydrochloric acid will literally eat away human flesh…

Hydrochloric Acid (Continued)

• Hydrochloric acid can be purchased from hardware stores as:

– Tile and Grout Acid Cleaner

– Muriatic Acid

– Pool Acid

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

• Hydrochloric acid is a solution of hydrogen chloride gas suspended in water.

– Hydrochloric acid is corrosive and is a light yellow liquid color from traces of iron, chlorine, and organic matter.

• Inhaling hydrochloric acid may cause coughing or choking, inflammation, and

ulceration of the respiratory tract.

• Concentrated solutions of hydrochloric acid can cause severe burns and irritate the

mucous membranes, eyes, and respiratory tract.

– Exposure to hydrochloric acid vapors may result in pulmonary edema and possibly death.

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

Sodium Hydroxide (NaOH)

• Sodium hydroxide is also called Lye.

• Sodium hydroxide is classified as a corrosive, and it is one of the main chemicals in

drain cleaner.

– It is also used in aluminum etching and to create biodiesal.

– It can burn the skin or cause blindness.

• Sodium hydroxide is used to dispose of road kill because it turns the dead bodies

into a coffee-like liquid.

Sodium Hydroxide (NaOH) (Continued)

• Drain cleaner (sodium hydroxide) is extremely corrosive, and without wearing

protection, even the smallest spill on the skin can eat through flesh…

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sulfuric Acid (H2SO4)

• Sulfuric acid is used in drain or toilet bowl cleaner as well as battery acid.

– It is another highly corrosive substance that burns the skin on contact.

Sulfuric Acid (H2SO4) (Continued)

• The product label warning for Drano® (sulfuric acid) says it all:

– DANGER: MAY BURN EYES AND SKIN ON CONTACT.

•HARMFUL IF SWALLOWED.

–Avoid contact with body and clothing.

•TOXIC GAS MAY FORM IF MIXED WITH OTHER CHEMICALS.

–If gases are released, leave immediately and ventilate area.

•FIRST AID: Give Immediately:

–EYES AND SKIN:

»Flush with water for 20 minutes.

»Remove affected clothing.

–IF SWALLOWED:

»Rinse mouth and drink a glass of water or milk.

»Do not induce vomiting.

–THEN SEEK MEDICAL AID.

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Hypophosphorous Acid (H3PO2)

• Hypophosphorous acid, which is used legally for a variety of commercial purposes,

is a chemical that increasingly is substituted for red phosphorus in the methamphetamine production process.

– The use of hypophospherous acid SIGNIFICANTLY increases the risk of fire!!!

• The federal government regulates the sale of hypophosphorous acid through registration, record keeping, reporting, and import/export requirements regardless

of the quantity being handled or distributed.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid is a colorless oily liquid that emits a SOUR odor.

– There is an extreme fire and explosion hazard if the hypophosphorous acid

comes into contact with a solvent such as acetone, toluene, or Coleman fuel.

• Hypophosphorous acid will also emit phosphine gas and the fumes can ignite.

Hypophosphorous Acid (H3PO2) (Continued)

• Although hypophosphorous acid is a List I chemical under the Controlled Substances Act, methamphetamine producers typically purchase the chemical via

the internet or from associates who also are engaged in methamphetamine

production.

– The use of hypophosphorous acid in methamphetamine production is an

EXTREMELY DANGEROUS PRACTICE because of the deadly gases that can be generated as well as the risk of fire or explosion.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid (H3PO2, also called phosphinic acid) is a strong acid that

typically is prepared as a solution of colorless, oily liquid in strengths of 50%, 30 to 32%, and 10%.

– It also is prepared in the form of salts (referred to as hypophosphite salts), particularly ammonium hypophosphite, calcium hypophosphite, iron (ferric)

hypophosphite, magnesium hypophosphite, manganese hypophosphite,

potassium hypophosphite, and sodium hypophosphite.

Hypophosphorous Acid (H3PO2) (Continued)

• Over 100 chemical firms located throughout the world produce hypophosphorous

acid.

– The People's Republic of China and India have the largest numbers of

hypophosphorous acid producers, although there are a few producers in the United States.

• There are a wide variety of uses for hypophosphorous acid and its salts in

commercial industry; however, the chemicals have no legitimate household or retail uses.

Hypophosphorous Acid (H3PO2) (Continued)

• The legitimate commercial and laboratory fields that use hypophosphorous acid and its salts include the following:

– Chemical plating

– Food preparation

– Water treatment

– Polymers (as a bleaching agent, color stabilizer, or catalyst)

– Education and research in analytical chemistry

Hypophosphorous Acid (H3PO2) (Continued)

• Chemical suppliers typically distribute hypophosphorous acid in large quantities, for example, in drums containing 275 pounds of the diluted solution.

– Hypophosphorous acid also is distributed in smaller quantities.

• One-half liter of 50% concentrate hypophosphorous acid solution can be obtained from chemical suppliers for as little as $14.

Hypophosphorous Acid (H3PO2) (Continued)

• Methamphetamine laboratory operators typically obtain small quantities of the chemical from other laboratory operators who purchase large quantities of the chemical and repackage it for further distribution.

– According to law enforcement sources, these individuals sell hypophosphorous acid for as much as $1,000 per half-liter.

•Methamphetamine laboratory operators also purchase hypophosphorous acidvia the internet.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid and the Internet

• The internet is a source of a great deal of information regarding hypophosphorous acid.

• Popular internet sites that disseminate information about illicit drugs contain information about the chemical, including numerous recipes for home production of methamphetamine using hypophosphorous acid.

• There also are recipes for synthesizing hypophosphorous acid from available chemicals.

• Hypophosphorous acid solutions and salts have been sold to the general public via the internet.

• The Drug Enforcement Administration (DEA) has strong concerns regarding the sale

of chemicals on the internet and has requested that any sites (such as auction sites) that allow the sale of regulated chemicals on their domains require proof of

DEA registration from their clients.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid Used in Methamphetamine Production

• Hypophosphorous acid is used in the ephedrine-pseudoephedrine reduction method

of methamphetamine production.

– It is used in the methamphetamine production process to produce hydriodic acid,

an important reagent (it reacts with the ephedrine-pseudoephedrine but does NOT become part of the finished product).

Hypophosphorous Acid (H3PO2) (Continued)

• The regulation of hydriodic acid by DEA in 1993 rendered it virtually unavailable in

the United States.

– However, methamphetamine laboratory operators discovered methods to

produce hydriodic acid using a combination of iodine in water with red phosphorus.

• Laboratory operators found that red phosphorus could be obtained easily, either

from commercial supply companies or by scraping the striker pads from matchbooks or matchboxes.

• Methamphetamine producers soon discovered that hypophosphorous acid ALSO could be used in combination with iodine and water to produce hydriodic acid.

Hypophosphorous Acid (H3PO2) (Continued)

• The practice of using hypophosphorous acid in methamphetamine production is

believed to have begun in the United States in the late 1990s when a methamphetamine producer in Colorado obtained the recipe from Australia, where

the hypophosphorous acid method is prevalent.

– This man was known as a serial cook who had a long history of

methamphetamine production.

•Over several years he trained other laboratory operators in Colorado to produce methamphetamine using hypophosphorous acid.

• As his techniques were passed on to others, the number of methamphetaminelaboratories in Colorado using hypophosphorous acid continued to increase, and the

technique was passed on to numerous methamphetamine producers in other

states.

Hypophosphorous Acid (H3PO2) (Continued)

• According to the El Paso Intelligence Center (EPIC) National Clandestine Laboratory

Seizure System, from 2000 through 2002 the number of seized methamphetaminelaboratories in the United States in which hypophosphorous acid was found

increased overall. (See Table 1.)

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid found at methamphetamine laboratories is packaged in a variety of ways.

• The chemical has been found in 1-gallon bottles of solution or in 1-pound jars of salts.

• Some hypophosphorous acid containers are labeled as "plating solution."

• Pint-sized brown glass bottles wrapped in red electrical tape also have been found to contain hypophosphorous acid; they have been discovered primarily in Colorado.

• The vast majority of hypophosphorous acid found at laboratory sites has been recovered from small toxic laboratories (STLs), those which yield gram to ounce

quantities per production cycle.

• Hypophosphorous acid has not been reported at large-scale laboratories operated by Mexican criminal groups in the United States.

Hypophosphorous Acid (H3PO2) (Continued)

• Hazards

• The iodine-hypophosphorous acid method is MORE HAZORDOUS than the iodine-

red phosphorus method, although the reaction using hypophosphorous acid is

faster and gives slightly higher yields.

– When hypophosphorous acid is used, the chemicals must be mixed together

SLOWLY in a PARTICULAR ORDER to prevent them from reacting violently.

Hypophosphorous Acid (H3PO2) (Continued)

• The combination of hypophosphorous acid with the other chemicals and with

certain metals can produce deadly phosphine gas during the initial mixing step and

can CONTINUE to produce phosphine gas for several days AFTER production has been completed…

Hypophosphorous Acid (H3PO2) (Continued)

• The iodine-hypophosphorous acid mixture has a tendency to decompose quickly when overheated or if heated for long periods of time, becoming cloudy or "milky-

white" just prior to giving off a cloud of phosphine gas that can ignite spontaneously.

– Hypophosphorous acid solutions may become unstable if evaporation results in

concentrations above 50%.

Hypophosphorous Acid (H3PO2) (Continued)

• [Note: Law enforcement or emergency personnel who encounter suspected

containers of hypophosphorous acid should use extreme care during handling because laboratory operators often attempt to obtain a more concentrated acid by

allowing water to evaporate from the mixture.]

• Because hypophosphorous acid often is used at small methamphetaminelaboratories operated by inexperienced or careless individuals, the potential hazards

of using this method are even greater.

• The risk of fire and explosion is higher in these laboratories, where professional

laboratory equipment typically is not used to contain the phosphine gas and where

safe handling precautions are not employed.

• In addition, these laboratories often are located in homes where children are

present and may come into contact with hypophosphorous acid.

• A child can easily mistake hypophosphorous acid for any other clear liquid,

particularly if it is stored in household containers or drinking glasses.

• Skin, eye, or inhalation exposure can be extremely harmful or fatal.

Hypophosphorous Acid (H3PO2) (Continued)

• Safety Precautions

• Always wear a self-contained breathing apparatus as well as protective clothing when entering areas where hypophosphorous acid may be present.

• When in contact with metals or in a high-temperature environment,

hypophosphorous acid can break down and liberate phosphine and flammable hydrogen gas.

• Do not allow the use of open flames, open lights, matches, or smoking in or around laboratories or dumpsites where hypophosphorous acid is handled.

• In case of fire, use a self-contained positive pressure breathing apparatus and full

protective equipment.

• Use water spray, fog, foam, dry chemicals, or other reagents as may be

appropriate for materials in the surrounding fire.

• Water may be used to cool the containers of hypophosphorous acid; however, use extreme care to avoid allowing water to enter the container.

• In case of spills, neutralize the spilled chemical with alkaline material (soda ash, lime), then absorb it with an inert material such as vermiculite, dry sand, or earth

and place in a chemical waste container.

• Do not use combustible materials such as sawdust.

Hypophosphorous Acid (H3PO2) (Continued)

• Legislation and Control

• In the United States hypophosphorous acid is one of 38 chemicals (or groups of

chemicals) controlled under law by DEA.

• On October 17, 2001, hypophosphorous acid and its salts, along with red and white phosphorus, were officially added as List I chemicals under section 1310 of the Code of Federal Regulations.

• List I chemicals are defined as chemicals that are used in the manufacture of a

controlled substance in violation of the Controlled Substances Act (CSA) and are

important to the manufacture of a controlled substance.

• Under the law, suppliers are required to maintain records and report receipts, sales,

imports, and exports of these chemicals to DEA.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid, red phosphorus, and white phosphorus, as well as

ephedrine, are unique in that suppliers are required to report all transactions of

these chemicals, regardless of the amount.

• By contrast, the other 34 listed chemicals are only reportable after a supplier's transactions for a chemical reach an established weight or volume threshold in a calendar month.

• In addition to reporting all transactions involving the chemical, suppliers are

expected to "know their customers" in order to prevent the diversion of these substances to methamphetamine laboratories, as it is illegal to import, export,

purchase, or sell hypophosphorous acid or any other listed chemical in the United States if it is used or intended to be used in the production of a controlled

substance.

• Chemical suppliers are held liable for selling listed chemicals if they know or suspect that the chemical will be used for illicit purposes.

Hypophosphorous Acid (H3PO2) (Continued)

• Outlook

• The use of hypophosphorous acid in the production of methamphetamine is likely

to increase, particularly in the Midwest and Southwest regions of the United States

where methamphetamine production is prevalent.

– Injuries, property damage, and deaths also will increase as a growing number of

inexperienced methamphetamine producers experiment with hypophosphorous acid.

Anhydrous Ammonia

• Anhydrous ammonia is found in fertilizer, countertop cleaner, and commercial refrigerant.

– On its own, it has a pungent, suffocating odor.

• Mixing anhydrous ammonia with other chemicals can release highly toxic gases.

– Because anhydrous ammonia seeks out water (anhydrous means “without

water”) and causes severe burns, any body part that comes into contact with it

should be flushed with water for at least 15 minutes to remove the ammoniafrom the skin.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia has extremely destructive effects on humans.

– Anhydrous ammonia gives off vapors during cooking that can burn the mouth, throat, and lung tissue.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Anhydrous ammonia seeks water from the nearest source, including the human body (anhydrous means “without water”).

– Because of their high moisture content, EYES, LUNGS, and SKIN are at the greatest risk of attracting the ammonia.

• When large amounts of anhydrous ammonia are inhaled, the throat swells and the

victim suffocates.

– Exposure to the vapors or liquids can cause severe burns, blindness, or death.

• Anhydrous ammonia has an IDLH (immediately dangerous to life and health) at

only 300 parts per million...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is poses MANY hazards, especially when it is placed in improper vessels and handled/transported by individuals unfamiliar with the

dangers.

• Anhydrous ammonia has a boiling point of -28 degrees below zero.

– When a vessel containing anhydrous ammonia is MOVED, the anhydrous

ammonia will reach its boiling point and pressurize.

•This pressurization can cause vessels to violently RUPTURE, or if the vessel pressurizes and does NOT rupture, the opening of the container of anhydrous

ammonia at a later time can cause RAPID, VIOLENT depressurization.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is mainly used in the U.S. as either a fertilizer or a refrigerant.

– Meth producers tend to store the anhydrous ammonia in IMPROPER/UNAPPROVED containers such as:

•Propane tanks,

• Igloo coolers, or

•Fire extinguishers.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia leaves a tell-tell sign as it flows through these UNAPPROVED

CONTAINERS – a blue or blue green discoloration on the valve.

– PAY ATTENTION to details!!!

Anhydrous Ammonia (Continued)

• Because propane cylinders (and the other unapproved containers) are NOT designed to store anhydrous ammonia, they can EXPLODE as the ammonia eats

through the walls of the cylinders.

– The valves, which take on a bluish/green color, frequently deteriorate and can cause hazardous leaks!!!

Anhydrous Ammonia (Continued)

• Do NOT touch, move, or open any kind of tank or sealed container!!!

– Be aware that propane tanks are often WEAKENED and BRITTLE due to the

anhydrous ammonia and are SENSITIVE to ANY kind of movement or impact.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• These pictures show what happened to a fire extinguisher that was used to store

anhydrous ammonia…

Anhydrous Ammonia (Continued)

• Illegal drug makers often STEAL anhydrous ammonia from areas where it is stored

and used, such as farms.

• Attempted thefts have also occurred at places such as:

– Refrigeration systems holding ammonia,

– Underground pipelines carrying ammonia, and

– Rail cars transporting anhydrous ammonia.

• Often thefts are aborted when thieves are injured or overcome by the toxic gas...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia thieves had better beware!!!

• There is a new product called GloTell that farmers can add to their anhydrous

ammonia tanks…

• Meth cooks will run the risk that the GloTell additive will turn their hands bright

pink!

– This bright pink stain will fluoresce under ultraviolet light even if washed off!!!

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Also, GloTell will produce pink methamphetamine that CANNOT be bleached.

– Users who snort meth made with GloTell will find that they have PINK NOSES!

– Users who inject meth made with GloTell will see a pink stain at the point of

injection!

Sodium Carbonate (Soda Ash)

Sodium Carbonate (Soda Ash) (Continued)

Lead Acetate

Iodine

• Iodine is a natural element, and it is helpful to the body in SMALL amounts.

– However, if iodine is taken in large amounts it can become toxic.

•Extremely high does of iodine can limit the function of the thyroid.

Iodine (Continued)

Iodine (Continued)

• Iodine is bluish-black, and it has a characteristic odor, a sharp acrid taste, and it produces a violet corrosive vapor.

– The vapor is irritating to the respiratory system and eyes.

• The solid iodine irritates the eyes and may burn the skin, and it may cause severe

internal irritation and damage if ingested.

Iodine (Continued)

• Iodine is known as the “blue ingredient” in the production of meth (in the “red, white, and blue” method).

Iodine (Continued)

Iodine (Continued)

• It takes approximately 4 bottles of iodine tincture to produce 2 – 3 grams of meth.

Iodine (Continued)

Iodine (Continued)

• Iodine leaves distinctive yellow-blue or brown stains on surfaces in former methlabs.

Iodine (Continued)

Iodine (Continued)

Iodine (Continued)

• The only good thing about iodine is that it leaves yellow stains.

• If you see yellow stained coffee filters, gloves or paper towels, this could be an

indicator that you’re in a lab.

• If you see yellow stains, you can spray some starch on them.

– If they turn a purplish blue/black, it’s iodine.

• Iodine is the only substance that reacts with soluble starch to produce a purplish black color.

– The only way to get iodine vapor all over the walls is to cook meth.

Mercurous Chloride

Rock Salt

Hydrogen Chloride

• Hydrogen chloride gas is commercially available.

• Hydrogen chloride gas can also be made by mixing sulfuric acid and salt.

• Muriatic acid is simply hydrogen chloride gas suspended in water.

• Hydrogen chloride gas can be seen as a pale white smoke.

– It is a poisonous gas that can cause respiratory problems and death.

Hydrogen Chloride (Continued)

Ammonium Nitrate

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Hydriodic Acid

• Hydriodic acid is a corrosive acid that is colorless when freshly prepared.

– When hydriodic acid is exposed to light and air, it turns yellowish and brown.

• Hydriodic acid is a solution of hydrogen iodide gas in water.

• Hydriodic acid vapor is irritating to the respiratory system, skin, and eyes.

• Hydriodic acid liquid causes severe burns to the eyes and skin.

• If hydriodic acid is accidentally ingested, it can cause severe internal irritation and

damage.

Hydriodic Acid (Continued)

Catalyst Chemicals

• Catalyst Chemicals:

– Chemicals which SPEED UP a reaction process and/or cause it to go to GREATER COMPLETION.

Red Phosphorus

• Red phosphorus is found ON matchboxes, in road flares, and other explosives.

– Red Phosphorus IGNITES when OVERHEATED!!!

• By combining red phosphorus and iodine, you can easily create the highly controlled substance known as hydriodic acid (which is an essential ingredient in making meth).

– Creating 2 – 3 grams of meth requires about 4 big boxes of matches.

Red Phosphorus (Continued)

• Red phosphorous is highly flammable and if it is overheated it can become white

phosphorous…

– White phosphorous is a volatile and highly explosive substance.

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Lithium

• Lithium is used in batteries.

• Lithium seriously burns the skin upon contact.

– It also reacts VIOLENTLY with WATER and is highly explosive.

Lithium (Continued)

• Lithium reacts VIOLENTLY with WATER, and if it is splashed in the eyes during

cooking it will cause blindness.

– Lithium is extremely caustic to all body tissues.

Lithium (Continued)

Lithium (Continued)

• Lithium metal is HIGHLY water reactive and it will BURN or EXPLODE if it comes into contact with WATER!

• Because of the moisture in your skin, it will burn exposed flesh.

• Lithium metal will DEGRADE when exposed to atmospheric moisture…

– This is why meth cooks store lithium metal in a solvent prior to use.

• It is typical to see harvested lithium strips in Coleman fuel or Mineral Spirits to prevent explosions.

•Large quantities can be harvested and saved in these containers until needed

for a cook.

Lithium (Continued)

• If you see battery shells in the trashcan, on the floor, etc. – this is a VERY GOOD

indicator that you might be entering a meth lab!

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

• Lithium catches fire when in contact with water...

Solvent Chemicals

• Solvent Chemicals:

– A medium (liquid) in which a chemical operation takes place.

• Solvent chemicals (UNLIKE the precursor chemicals) CAN be

substituted/interchanged.

Ether

• Ether was once called “sweet vitriol” because of its hypnotic effect.

• Ether is a highly flammable substance that is used as an anesthetic agent –

especially in third world countries where more expensive anesthesia is not available.

– While inhaling the ether, patients could undergo complete surgical procedures while otherwise awake without feeling pain or concern.

Ether (Continued)

• Ether can be obtained from engine starting fluid.

• Ether is a solvent and it is flammable.

– It is particularly hazardous because it can cause BOTH fire and explosion.

• It has been said that a quart of ether can “level” a small house.

Ethyl Ether (Continued)

Ethyl Ether (Continued)

• Ether is VERY flammable and is HEAVIER than air.

– NEVER use ether near flames or non-sparkless motors.

– Ether is very PUNGENT – even a small evaporated amount of ether is VERY noticeable.

Acetone

• Acetone can be found in nail polish remover or paint thinner.

– It is extremely flammable.

• In the setting of a meth lab where meth is being cooked with high heat, acetone is

very dangerous.

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Toluene

• Toluene is used in brake fluid.

– When working with brake fluid (toluene), be careful not to spill it on your car

because it will eat away the paint and chrome…

• You also have to be careful using toluene around other household chemicalsbecause its high concentration of polyethylene glycol can cause it to ignite in a

violent fireball.

• Toluene is powerful enough to dissolve rubber.

Toluene (Continued)

• Toluene is used to form meth crystals.

– The fumes toluene releases can cause brain damage or death.

Toluene (Continued)

Toluene (Continued)

Ethanol

Isopropanol

Isopropanol (Continued)

Isopropyl Alcohol

Methanol

Methanol (Continued)

Methanol (Continued)

Benzene

Benzene (Continued)

Which of these is NOT a common ingredient in Meth?

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Page 9: Methamphetamine - PowerPoint - Chemicals and Ingredients ... · 2/5/2014 1 Methamphetamine - PowerPoint - Chemicals and Ingredients Used to Make Meth CJUS 240 Economic Costs of Meth

2/5/2014

9

Methamphetamine- PowerPoint

- Chemicals and Ingredients Used to Make Meth

CJUS 240

Economic Costs of Meth

• The economic cost of methamphetamine use in the U.S. reached $23.4 billion in

2005.

– This includes the burden of addiction, premature death, drug treatment, child

care, and cleaning of lab sites.

– This figure does NOT take into account the future needs of the meth user.

Concerns with ACTIVE Meth Labs

• Danger of fire and explosion

• Chemical spills

• Inhalation of solvents, corrosives, and toxic gases

• “Booby traps”

• Waste disposal

Concerns with FORMER Meth Labs

• Vapors

• Chemical residues

• Methamphetamine residues

• Waste disposal

Equipment Used in Meth Production

• Pyrex or Corning dishes

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

• Coffee Filters

Equipment Used in Meth Production

Equipment Used in Meth Production

Basic Chemical Requirements

• In a clandestine laboratory, basic types of chemicals are necessary in order to

produce the desired drug.

– The basic types of chemicals needed are:

1) Precursor Chemicals

2) Reagent Chemicals

3) Catalyst Chemicals

4) Solvent Chemicals

List I Chemical

• The term “List I chemical” means a chemical specified by regulation of the Attorney General as a chemical that is used in manufacturing a controlled substance and is

IMPORTANT to the manufacture of the controlled substance.

• Examples of List I chemicals are:

– GBL

– Red Phosphorus

– Pseudoephedrine

List II Chemical

• The term “List II chemical” means a chemical (other than a List I chemical) specified by regulation of the Attorney General as a chemical that is USED in

manufacturing a controlled substance.

• Examples of List II chemicals are:

– Toluene

– Iodine

– Hydrochloric Acid

Precursor Chemicals

• Precursor Chemicals:

– A chemical that is ESSENTIAL to the production of a controlled substance and for

which NO SUBSTITUTION can be made.

Pseudoephedrine

• Pseudoephedrine is a decongestant found in cold medicine.

– Large amounts of pseudoephedrine on its own can harm the respiratory and nervous systems, as well as the heart.

Pseudoephedrine (Continued)

• Some of the common ways used to divert products containing pseudoephedrine

include:

– “Smurfing” – making multiple purchases at different locations

– Shelf-Sweeping – the theft of all shelf stock

– Shoplifting

– Theft from wholesalers

Pseudoephedrine (Continued)

• Pseudoephedrine smurfing is a method used by some methamphetamine producers to acquire large quantities of pseudoephedrine by enlisting the assistance of several

friends or associates (often referred to as “smurfers”) to make purchases at or below the legal thresholds from multiple retail locations.

– Smurfers are often addicts who trade the pseudoephedrine for finished

methamphetamine.

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

• About 680 pseudoephedrine tablets are needed to produce one ounce of meth…

Pseudoephedrine (Continued)

Out With a Bang

An Unstable Recipe…

• Meth contains a variety of poisonous ingredients…

– Some become EVEN MORE DANGEROUS once the cooking process begins…

Common Ingredients to Make Methamphetamine

Reagent Chemicals

• Reagent Chemicals:

– Chemicals which REACT upon the precursor chemical causing it to chemicallyCHANGE.

• A reagent chemical is a chemical which is required for the synthesis of an illicit drug substance, but which is NOT incorporated into the final chemical product.

Hydrochloric Acid

• Hydrochloric acid is a highly corrosive liquid that is used to make plastic (such as PVC pipe and polyurethane).

– It can remove rust and iron-oxide from steel and is highly corrosive to human

skin.

•Hydrochloric acid makes up the majority of the gastric acid in the human

digestive fluid.

• In high concentrations, hydrochloric acid will literally eat away human flesh…

Hydrochloric Acid (Continued)

• Hydrochloric acid can be purchased from hardware stores as:

– Tile and Grout Acid Cleaner

– Muriatic Acid

– Pool Acid

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

• Hydrochloric acid is a solution of hydrogen chloride gas suspended in water.

– Hydrochloric acid is corrosive and is a light yellow liquid color from traces of iron, chlorine, and organic matter.

• Inhaling hydrochloric acid may cause coughing or choking, inflammation, and

ulceration of the respiratory tract.

• Concentrated solutions of hydrochloric acid can cause severe burns and irritate the

mucous membranes, eyes, and respiratory tract.

– Exposure to hydrochloric acid vapors may result in pulmonary edema and

possibly death.

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

Sodium Hydroxide (NaOH)

• Sodium hydroxide is also called Lye.

• Sodium hydroxide is classified as a corrosive, and it is one of the main chemicals in

drain cleaner.

– It is also used in aluminum etching and to create biodiesal.

– It can burn the skin or cause blindness.

• Sodium hydroxide is used to dispose of road kill because it turns the dead bodies

into a coffee-like liquid.

Sodium Hydroxide (NaOH) (Continued)

• Drain cleaner (sodium hydroxide) is extremely corrosive, and without wearing

protection, even the smallest spill on the skin can eat through flesh…

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sulfuric Acid (H2SO4)

• Sulfuric acid is used in drain or toilet bowl cleaner as well as battery acid.

– It is another highly corrosive substance that burns the skin on contact.

Sulfuric Acid (H2SO4) (Continued)

• The product label warning for Drano® (sulfuric acid) says it all:

– DANGER: MAY BURN EYES AND SKIN ON CONTACT.

•HARMFUL IF SWALLOWED.

–Avoid contact with body and clothing.

•TOXIC GAS MAY FORM IF MIXED WITH OTHER CHEMICALS.

–If gases are released, leave immediately and ventilate area.

•FIRST AID: Give Immediately:

–EYES AND SKIN:

»Flush with water for 20 minutes.

»Remove affected clothing.

–IF SWALLOWED:

»Rinse mouth and drink a glass of water or milk.

»Do not induce vomiting.

–THEN SEEK MEDICAL AID.

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Hypophosphorous Acid (H3PO2)

• Hypophosphorous acid, which is used legally for a variety of commercial purposes,

is a chemical that increasingly is substituted for red phosphorus in the methamphetamine production process.

– The use of hypophospherous acid SIGNIFICANTLY increases the risk of fire!!!

• The federal government regulates the sale of hypophosphorous acid through registration, record keeping, reporting, and import/export requirements regardless

of the quantity being handled or distributed.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid is a colorless oily liquid that emits a SOUR odor.

– There is an extreme fire and explosion hazard if the hypophosphorous acid

comes into contact with a solvent such as acetone, toluene, or Coleman fuel.

• Hypophosphorous acid will also emit phosphine gas and the fumes can ignite.

Hypophosphorous Acid (H3PO2) (Continued)

• Although hypophosphorous acid is a List I chemical under the Controlled Substances Act, methamphetamine producers typically purchase the chemical via

the internet or from associates who also are engaged in methamphetamine

production.

– The use of hypophosphorous acid in methamphetamine production is an

EXTREMELY DANGEROUS PRACTICE because of the deadly gases that can be generated as well as the risk of fire or explosion.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid (H3PO2, also called phosphinic acid) is a strong acid that

typically is prepared as a solution of colorless, oily liquid in strengths of 50%, 30 to 32%, and 10%.

– It also is prepared in the form of salts (referred to as hypophosphite salts), particularly ammonium hypophosphite, calcium hypophosphite, iron (ferric)

hypophosphite, magnesium hypophosphite, manganese hypophosphite,

potassium hypophosphite, and sodium hypophosphite.

Hypophosphorous Acid (H3PO2) (Continued)

• Over 100 chemical firms located throughout the world produce hypophosphorous

acid.

– The People's Republic of China and India have the largest numbers of

hypophosphorous acid producers, although there are a few producers in the United States.

• There are a wide variety of uses for hypophosphorous acid and its salts in

commercial industry; however, the chemicals have no legitimate household or retail uses.

Hypophosphorous Acid (H3PO2) (Continued)

• The legitimate commercial and laboratory fields that use hypophosphorous acid and its salts include the following:

– Chemical plating

– Food preparation

– Water treatment

– Polymers (as a bleaching agent, color stabilizer, or catalyst)

– Education and research in analytical chemistry

Hypophosphorous Acid (H3PO2) (Continued)

• Chemical suppliers typically distribute hypophosphorous acid in large quantities, for example, in drums containing 275 pounds of the diluted solution.

– Hypophosphorous acid also is distributed in smaller quantities.

• One-half liter of 50% concentrate hypophosphorous acid solution can be obtained from chemical suppliers for as little as $14.

Hypophosphorous Acid (H3PO2) (Continued)

• Methamphetamine laboratory operators typically obtain small quantities of the chemical from other laboratory operators who purchase large quantities of the

chemical and repackage it for further distribution.

– According to law enforcement sources, these individuals sell hypophosphorous acid for as much as $1,000 per half-liter.

•Methamphetamine laboratory operators also purchase hypophosphorous acidvia the internet.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid and the Internet

• The internet is a source of a great deal of information regarding hypophosphorous acid.

• Popular internet sites that disseminate information about illicit drugs contain information about the chemical, including numerous recipes for home production of

methamphetamine using hypophosphorous acid.

• There also are recipes for synthesizing hypophosphorous acid from available chemicals.

• Hypophosphorous acid solutions and salts have been sold to the general public via the internet.

• The Drug Enforcement Administration (DEA) has strong concerns regarding the sale

of chemicals on the internet and has requested that any sites (such as auction sites) that allow the sale of regulated chemicals on their domains require proof of

DEA registration from their clients.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid Used in Methamphetamine Production

• Hypophosphorous acid is used in the ephedrine-pseudoephedrine reduction method of methamphetamine production.

– It is used in the methamphetamine production process to produce hydriodic acid,

an important reagent (it reacts with the ephedrine-pseudoephedrine but does NOT become part of the finished product).

Hypophosphorous Acid (H3PO2) (Continued)

• The regulation of hydriodic acid by DEA in 1993 rendered it virtually unavailable in

the United States.

– However, methamphetamine laboratory operators discovered methods to

produce hydriodic acid using a combination of iodine in water with red phosphorus.

• Laboratory operators found that red phosphorus could be obtained easily, either from commercial supply companies or by scraping the striker pads from matchbooks or matchboxes.

• Methamphetamine producers soon discovered that hypophosphorous acid ALSO could be used in combination with iodine and water to produce hydriodic acid.

Hypophosphorous Acid (H3PO2) (Continued)

• The practice of using hypophosphorous acid in methamphetamine production is

believed to have begun in the United States in the late 1990s when a methamphetamine producer in Colorado obtained the recipe from Australia, where

the hypophosphorous acid method is prevalent.

– This man was known as a serial cook who had a long history of

methamphetamine production.

•Over several years he trained other laboratory operators in Colorado to produce methamphetamine using hypophosphorous acid.

• As his techniques were passed on to others, the number of methamphetaminelaboratories in Colorado using hypophosphorous acid continued to increase, and the

technique was passed on to numerous methamphetamine producers in other

states.

Hypophosphorous Acid (H3PO2) (Continued)

• According to the El Paso Intelligence Center (EPIC) National Clandestine Laboratory

Seizure System, from 2000 through 2002 the number of seized methamphetaminelaboratories in the United States in which hypophosphorous acid was found

increased overall. (See Table 1.)

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid found at methamphetamine laboratories is packaged in a variety of ways.

• The chemical has been found in 1-gallon bottles of solution or in 1-pound jars of salts.

• Some hypophosphorous acid containers are labeled as "plating solution."

• Pint-sized brown glass bottles wrapped in red electrical tape also have been found to contain hypophosphorous acid; they have been discovered primarily in Colorado.

• The vast majority of hypophosphorous acid found at laboratory sites has been recovered from small toxic laboratories (STLs), those which yield gram to ounce quantities per production cycle.

• Hypophosphorous acid has not been reported at large-scale laboratories operated by Mexican criminal groups in the United States.

Hypophosphorous Acid (H3PO2) (Continued)

• Hazards

• The iodine-hypophosphorous acid method is MORE HAZORDOUS than the iodine-

red phosphorus method, although the reaction using hypophosphorous acid is

faster and gives slightly higher yields.

– When hypophosphorous acid is used, the chemicals must be mixed together

SLOWLY in a PARTICULAR ORDER to prevent them from reacting violently.

Hypophosphorous Acid (H3PO2) (Continued)

• The combination of hypophosphorous acid with the other chemicals and with

certain metals can produce deadly phosphine gas during the initial mixing step and

can CONTINUE to produce phosphine gas for several days AFTER production has been completed…

Hypophosphorous Acid (H3PO2) (Continued)

• The iodine-hypophosphorous acid mixture has a tendency to decompose quickly when overheated or if heated for long periods of time, becoming cloudy or "milky-

white" just prior to giving off a cloud of phosphine gas that can ignite spontaneously.

– Hypophosphorous acid solutions may become unstable if evaporation results in

concentrations above 50%.

Hypophosphorous Acid (H3PO2) (Continued)

• [Note: Law enforcement or emergency personnel who encounter suspected

containers of hypophosphorous acid should use extreme care during handling because laboratory operators often attempt to obtain a more concentrated acid by

allowing water to evaporate from the mixture.]

• Because hypophosphorous acid often is used at small methamphetaminelaboratories operated by inexperienced or careless individuals, the potential hazards

of using this method are even greater.

• The risk of fire and explosion is higher in these laboratories, where professional

laboratory equipment typically is not used to contain the phosphine gas and where

safe handling precautions are not employed.

• In addition, these laboratories often are located in homes where children are

present and may come into contact with hypophosphorous acid.

• A child can easily mistake hypophosphorous acid for any other clear liquid,

particularly if it is stored in household containers or drinking glasses.

• Skin, eye, or inhalation exposure can be extremely harmful or fatal.

Hypophosphorous Acid (H3PO2) (Continued)

• Safety Precautions

• Always wear a self-contained breathing apparatus as well as protective clothing when entering areas where hypophosphorous acid may be present.

• When in contact with metals or in a high-temperature environment, hypophosphorous acid can break down and liberate phosphine and flammable hydrogen gas.

• Do not allow the use of open flames, open lights, matches, or smoking in or around laboratories or dumpsites where hypophosphorous acid is handled.

• In case of fire, use a self-contained positive pressure breathing apparatus and full

protective equipment.

• Use water spray, fog, foam, dry chemicals, or other reagents as may be

appropriate for materials in the surrounding fire.

• Water may be used to cool the containers of hypophosphorous acid; however, use extreme care to avoid allowing water to enter the container.

• In case of spills, neutralize the spilled chemical with alkaline material (soda ash, lime), then absorb it with an inert material such as vermiculite, dry sand, or earth and place in a chemical waste container.

• Do not use combustible materials such as sawdust.

Hypophosphorous Acid (H3PO2) (Continued)

• Legislation and Control

• In the United States hypophosphorous acid is one of 38 chemicals (or groups of

chemicals) controlled under law by DEA.

• On October 17, 2001, hypophosphorous acid and its salts, along with red and white phosphorus, were officially added as List I chemicals under section 1310 of the

Code of Federal Regulations.

• List I chemicals are defined as chemicals that are used in the manufacture of a

controlled substance in violation of the Controlled Substances Act (CSA) and are

important to the manufacture of a controlled substance.

• Under the law, suppliers are required to maintain records and report receipts, sales,

imports, and exports of these chemicals to DEA.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid, red phosphorus, and white phosphorus, as well as

ephedrine, are unique in that suppliers are required to report all transactions of

these chemicals, regardless of the amount.

• By contrast, the other 34 listed chemicals are only reportable after a supplier's

transactions for a chemical reach an established weight or volume threshold in a calendar month.

• In addition to reporting all transactions involving the chemical, suppliers are

expected to "know their customers" in order to prevent the diversion of these substances to methamphetamine laboratories, as it is illegal to import, export,

purchase, or sell hypophosphorous acid or any other listed chemical in the United States if it is used or intended to be used in the production of a controlled

substance.

• Chemical suppliers are held liable for selling listed chemicals if they know or suspect that the chemical will be used for illicit purposes.

Hypophosphorous Acid (H3PO2) (Continued)

• Outlook

• The use of hypophosphorous acid in the production of methamphetamine is likely

to increase, particularly in the Midwest and Southwest regions of the United States

where methamphetamine production is prevalent.

– Injuries, property damage, and deaths also will increase as a growing number of

inexperienced methamphetamine producers experiment with hypophosphorous acid.

Anhydrous Ammonia

• Anhydrous ammonia is found in fertilizer, countertop cleaner, and commercial refrigerant.

– On its own, it has a pungent, suffocating odor.

• Mixing anhydrous ammonia with other chemicals can release highly toxic gases.

– Because anhydrous ammonia seeks out water (anhydrous means “without

water”) and causes severe burns, any body part that comes into contact with it

should be flushed with water for at least 15 minutes to remove the ammoniafrom the skin.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia has extremely destructive effects on humans.

– Anhydrous ammonia gives off vapors during cooking that can burn the mouth,

throat, and lung tissue.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Anhydrous ammonia seeks water from the nearest source, including the human body (anhydrous means “without water”).

– Because of their high moisture content, EYES, LUNGS, and SKIN are at the

greatest risk of attracting the ammonia.

• When large amounts of anhydrous ammonia are inhaled, the throat swells and the

victim suffocates.

– Exposure to the vapors or liquids can cause severe burns, blindness, or death.

• Anhydrous ammonia has an IDLH (immediately dangerous to life and health) at

only 300 parts per million...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is poses MANY hazards, especially when it is placed in improper vessels and handled/transported by individuals unfamiliar with the dangers.

• Anhydrous ammonia has a boiling point of -28 degrees below zero.

– When a vessel containing anhydrous ammonia is MOVED, the anhydrous

ammonia will reach its boiling point and pressurize.

•This pressurization can cause vessels to violently RUPTURE, or if the vessel pressurizes and does NOT rupture, the opening of the container of anhydrous

ammonia at a later time can cause RAPID, VIOLENT depressurization.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is mainly used in the U.S. as either a fertilizer or a refrigerant.

– Meth producers tend to store the anhydrous ammonia in IMPROPER/UNAPPROVED containers such as:

•Propane tanks,

• Igloo coolers, or

•Fire extinguishers.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia leaves a tell-tell sign as it flows through these UNAPPROVED

CONTAINERS – a blue or blue green discoloration on the valve.

– PAY ATTENTION to details!!!

Anhydrous Ammonia (Continued)

• Because propane cylinders (and the other unapproved containers) are NOT designed to store anhydrous ammonia, they can EXPLODE as the ammonia eats through the walls of the cylinders.

– The valves, which take on a bluish/green color, frequently deteriorate and can cause hazardous leaks!!!

Anhydrous Ammonia (Continued)

• Do NOT touch, move, or open any kind of tank or sealed container!!!

– Be aware that propane tanks are often WEAKENED and BRITTLE due to the

anhydrous ammonia and are SENSITIVE to ANY kind of movement or impact.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• These pictures show what happened to a fire extinguisher that was used to store

anhydrous ammonia…

Anhydrous Ammonia (Continued)

• Illegal drug makers often STEAL anhydrous ammonia from areas where it is stored

and used, such as farms.

• Attempted thefts have also occurred at places such as:

– Refrigeration systems holding ammonia,

– Underground pipelines carrying ammonia, and

– Rail cars transporting anhydrous ammonia.

• Often thefts are aborted when thieves are injured or overcome by the toxic gas...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia thieves had better beware!!!

• There is a new product called GloTell that farmers can add to their anhydrous

ammonia tanks…

• Meth cooks will run the risk that the GloTell additive will turn their hands bright pink!

– This bright pink stain will fluoresce under ultraviolet light even if washed off!!!

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Also, GloTell will produce pink methamphetamine that CANNOT be bleached.

– Users who snort meth made with GloTell will find that they have PINK NOSES!

– Users who inject meth made with GloTell will see a pink stain at the point of

injection!

Sodium Carbonate (Soda Ash)

Sodium Carbonate (Soda Ash) (Continued)

Lead Acetate

Iodine

• Iodine is a natural element, and it is helpful to the body in SMALL amounts.

– However, if iodine is taken in large amounts it can become toxic.

•Extremely high does of iodine can limit the function of the thyroid.

Iodine (Continued)

Iodine (Continued)

• Iodine is bluish-black, and it has a characteristic odor, a sharp acrid taste, and it produces a violet corrosive vapor.

– The vapor is irritating to the respiratory system and eyes.

• The solid iodine irritates the eyes and may burn the skin, and it may cause severe

internal irritation and damage if ingested.

Iodine (Continued)

• Iodine is known as the “blue ingredient” in the production of meth (in the “red, white, and blue” method).

Iodine (Continued)

Iodine (Continued)

• It takes approximately 4 bottles of iodine tincture to produce 2 – 3 grams of meth.

Iodine (Continued)

Iodine (Continued)

• Iodine leaves distinctive yellow-blue or brown stains on surfaces in former methlabs.

Iodine (Continued)

Iodine (Continued)

Iodine (Continued)

• The only good thing about iodine is that it leaves yellow stains.

• If you see yellow stained coffee filters, gloves or paper towels, this could be an

indicator that you’re in a lab.

• If you see yellow stains, you can spray some starch on them.

– If they turn a purplish blue/black, it’s iodine.

• Iodine is the only substance that reacts with soluble starch to produce a purplish black color.

– The only way to get iodine vapor all over the walls is to cook meth.

Mercurous Chloride

Rock Salt

Hydrogen Chloride

• Hydrogen chloride gas is commercially available.

• Hydrogen chloride gas can also be made by mixing sulfuric acid and salt.

• Muriatic acid is simply hydrogen chloride gas suspended in water.

• Hydrogen chloride gas can be seen as a pale white smoke.

– It is a poisonous gas that can cause respiratory problems and death.

Hydrogen Chloride (Continued)

Ammonium Nitrate

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Hydriodic Acid

• Hydriodic acid is a corrosive acid that is colorless when freshly prepared.

– When hydriodic acid is exposed to light and air, it turns yellowish and brown.

• Hydriodic acid is a solution of hydrogen iodide gas in water.

• Hydriodic acid vapor is irritating to the respiratory system, skin, and eyes.

• Hydriodic acid liquid causes severe burns to the eyes and skin.

• If hydriodic acid is accidentally ingested, it can cause severe internal irritation and

damage.

Hydriodic Acid (Continued)

Catalyst Chemicals

• Catalyst Chemicals:

– Chemicals which SPEED UP a reaction process and/or cause it to go to GREATER COMPLETION.

Red Phosphorus

• Red phosphorus is found ON matchboxes, in road flares, and other explosives.

– Red Phosphorus IGNITES when OVERHEATED!!!

• By combining red phosphorus and iodine, you can easily create the highly

controlled substance known as hydriodic acid (which is an essential ingredient in making meth).

– Creating 2 – 3 grams of meth requires about 4 big boxes of matches.

Red Phosphorus (Continued)

• Red phosphorous is highly flammable and if it is overheated it can become white

phosphorous…

– White phosphorous is a volatile and highly explosive substance.

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Lithium

• Lithium is used in batteries.

• Lithium seriously burns the skin upon contact.

– It also reacts VIOLENTLY with WATER and is highly explosive.

Lithium (Continued)

• Lithium reacts VIOLENTLY with WATER, and if it is splashed in the eyes during

cooking it will cause blindness.

– Lithium is extremely caustic to all body tissues.

Lithium (Continued)

Lithium (Continued)

• Lithium metal is HIGHLY water reactive and it will BURN or EXPLODE if it comes into contact with WATER!

• Because of the moisture in your skin, it will burn exposed flesh.

• Lithium metal will DEGRADE when exposed to atmospheric moisture…

– This is why meth cooks store lithium metal in a solvent prior to use.

• It is typical to see harvested lithium strips in Coleman fuel or Mineral Spirits to prevent explosions.

•Large quantities can be harvested and saved in these containers until needed

for a cook.

Lithium (Continued)

• If you see battery shells in the trashcan, on the floor, etc. – this is a VERY GOOD

indicator that you might be entering a meth lab!

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

• Lithium catches fire when in contact with water...

Solvent Chemicals

• Solvent Chemicals:

– A medium (liquid) in which a chemical operation takes place.

• Solvent chemicals (UNLIKE the precursor chemicals) CAN be substituted/interchanged.

Ether

• Ether was once called “sweet vitriol” because of its hypnotic effect.

• Ether is a highly flammable substance that is used as an anesthetic agent –

especially in third world countries where more expensive anesthesia is not available.

– While inhaling the ether, patients could undergo complete surgical procedures while otherwise awake without feeling pain or concern.

Ether (Continued)

• Ether can be obtained from engine starting fluid.

• Ether is a solvent and it is flammable.

– It is particularly hazardous because it can cause BOTH fire and explosion.

• It has been said that a quart of ether can “level” a small house.

Ethyl Ether (Continued)

Ethyl Ether (Continued)

• Ether is VERY flammable and is HEAVIER than air.

– NEVER use ether near flames or non-sparkless motors.

– Ether is very PUNGENT – even a small evaporated amount of ether is VERY noticeable.

Acetone

• Acetone can be found in nail polish remover or paint thinner.

– It is extremely flammable.

• In the setting of a meth lab where meth is being cooked with high heat, acetone is

very dangerous.

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Toluene

• Toluene is used in brake fluid.

– When working with brake fluid (toluene), be careful not to spill it on your car

because it will eat away the paint and chrome…

• You also have to be careful using toluene around other household chemicals

because its high concentration of polyethylene glycol can cause it to ignite in a violent fireball.

• Toluene is powerful enough to dissolve rubber.

Toluene (Continued)

• Toluene is used to form meth crystals.

– The fumes toluene releases can cause brain damage or death.

Toluene (Continued)

Toluene (Continued)

Ethanol

Isopropanol

Isopropanol (Continued)

Isopropyl Alcohol

Methanol

Methanol (Continued)

Methanol (Continued)

Benzene

Benzene (Continued)

Which of these is NOT a common ingredient in Meth?

Nail Polish Remover

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Methamphetamine- PowerPoint

- Chemicals and Ingredients Used to Make Meth

CJUS 240

Economic Costs of Meth

• The economic cost of methamphetamine use in the U.S. reached $23.4 billion in

2005.

– This includes the burden of addiction, premature death, drug treatment, child care, and cleaning of lab sites.

– This figure does NOT take into account the future needs of the meth user.

Concerns with ACTIVE Meth Labs

• Danger of fire and explosion

• Chemical spills

• Inhalation of solvents, corrosives, and toxic gases

• “Booby traps”

• Waste disposal

Concerns with FORMER Meth Labs

• Vapors

• Chemical residues

• Methamphetamine residues

• Waste disposal

Equipment Used in Meth Production

• Pyrex or Corning dishes

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

• Coffee Filters

Equipment Used in Meth Production

Equipment Used in Meth Production

Basic Chemical Requirements

• In a clandestine laboratory, basic types of chemicals are necessary in order to

produce the desired drug.

– The basic types of chemicals needed are:

1) Precursor Chemicals

2) Reagent Chemicals

3) Catalyst Chemicals

4) Solvent Chemicals

List I Chemical

• The term “List I chemical” means a chemical specified by regulation of the Attorney General as a chemical that is used in manufacturing a controlled substance and is

IMPORTANT to the manufacture of the controlled substance.

• Examples of List I chemicals are:

– GBL

– Red Phosphorus

– Pseudoephedrine

List II Chemical

• The term “List II chemical” means a chemical (other than a List I chemical) specified by regulation of the Attorney General as a chemical that is USED in

manufacturing a controlled substance.

• Examples of List II chemicals are:

– Toluene

– Iodine

– Hydrochloric Acid

Precursor Chemicals

• Precursor Chemicals:

– A chemical that is ESSENTIAL to the production of a controlled substance and for

which NO SUBSTITUTION can be made.

Pseudoephedrine

• Pseudoephedrine is a decongestant found in cold medicine.

– Large amounts of pseudoephedrine on its own can harm the respiratory and nervous systems, as well as the heart.

Pseudoephedrine (Continued)

• Some of the common ways used to divert products containing pseudoephedrine

include:

– “Smurfing” – making multiple purchases at different locations

– Shelf-Sweeping – the theft of all shelf stock

– Shoplifting

– Theft from wholesalers

Pseudoephedrine (Continued)

• Pseudoephedrine smurfing is a method used by some methamphetamine producers to acquire large quantities of pseudoephedrine by enlisting the assistance of several

friends or associates (often referred to as “smurfers”) to make purchases at or below the legal thresholds from multiple retail locations.

– Smurfers are often addicts who trade the pseudoephedrine for finished

methamphetamine.

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

• About 680 pseudoephedrine tablets are needed to produce one ounce of meth…

Pseudoephedrine (Continued)

Out With a Bang

An Unstable Recipe…

• Meth contains a variety of poisonous ingredients…

– Some become EVEN MORE DANGEROUS once the cooking process begins…

Common Ingredients to Make Methamphetamine

Reagent Chemicals

• Reagent Chemicals:

– Chemicals which REACT upon the precursor chemical causing it to chemicallyCHANGE.

• A reagent chemical is a chemical which is required for the synthesis of an illicit drug substance, but which is NOT incorporated into the final chemical product.

Hydrochloric Acid

• Hydrochloric acid is a highly corrosive liquid that is used to make plastic (such as PVC pipe and polyurethane).

– It can remove rust and iron-oxide from steel and is highly corrosive to human

skin.

•Hydrochloric acid makes up the majority of the gastric acid in the human

digestive fluid.

• In high concentrations, hydrochloric acid will literally eat away human flesh…

Hydrochloric Acid (Continued)

• Hydrochloric acid can be purchased from hardware stores as:

– Tile and Grout Acid Cleaner

– Muriatic Acid

– Pool Acid

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

• Hydrochloric acid is a solution of hydrogen chloride gas suspended in water.

– Hydrochloric acid is corrosive and is a light yellow liquid color from traces of iron, chlorine, and organic matter.

• Inhaling hydrochloric acid may cause coughing or choking, inflammation, and

ulceration of the respiratory tract.

• Concentrated solutions of hydrochloric acid can cause severe burns and irritate the

mucous membranes, eyes, and respiratory tract.

– Exposure to hydrochloric acid vapors may result in pulmonary edema and

possibly death.

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

Sodium Hydroxide (NaOH)

• Sodium hydroxide is also called Lye.

• Sodium hydroxide is classified as a corrosive, and it is one of the main chemicals in

drain cleaner.

– It is also used in aluminum etching and to create biodiesal.

– It can burn the skin or cause blindness.

• Sodium hydroxide is used to dispose of road kill because it turns the dead bodies

into a coffee-like liquid.

Sodium Hydroxide (NaOH) (Continued)

• Drain cleaner (sodium hydroxide) is extremely corrosive, and without wearing protection, even the smallest spill on the skin can eat through flesh…

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sulfuric Acid (H2SO4)

• Sulfuric acid is used in drain or toilet bowl cleaner as well as battery acid.

– It is another highly corrosive substance that burns the skin on contact.

Sulfuric Acid (H2SO4) (Continued)

• The product label warning for Drano® (sulfuric acid) says it all:

– DANGER: MAY BURN EYES AND SKIN ON CONTACT.

•HARMFUL IF SWALLOWED.

–Avoid contact with body and clothing.

•TOXIC GAS MAY FORM IF MIXED WITH OTHER CHEMICALS.

–If gases are released, leave immediately and ventilate area.

•FIRST AID: Give Immediately:

–EYES AND SKIN:

»Flush with water for 20 minutes.

»Remove affected clothing.

–IF SWALLOWED:

»Rinse mouth and drink a glass of water or milk.

»Do not induce vomiting.

–THEN SEEK MEDICAL AID.

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Hypophosphorous Acid (H3PO2)

• Hypophosphorous acid, which is used legally for a variety of commercial purposes,

is a chemical that increasingly is substituted for red phosphorus in the methamphetamine production process.

– The use of hypophospherous acid SIGNIFICANTLY increases the risk of fire!!!

• The federal government regulates the sale of hypophosphorous acid through registration, record keeping, reporting, and import/export requirements regardless

of the quantity being handled or distributed.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid is a colorless oily liquid that emits a SOUR odor.

– There is an extreme fire and explosion hazard if the hypophosphorous acid

comes into contact with a solvent such as acetone, toluene, or Coleman fuel.

• Hypophosphorous acid will also emit phosphine gas and the fumes can ignite.

Hypophosphorous Acid (H3PO2) (Continued)

• Although hypophosphorous acid is a List I chemical under the Controlled Substances Act, methamphetamine producers typically purchase the chemical via

the internet or from associates who also are engaged in methamphetamine

production.

– The use of hypophosphorous acid in methamphetamine production is an

EXTREMELY DANGEROUS PRACTICE because of the deadly gases that can be generated as well as the risk of fire or explosion.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid (H3PO2, also called phosphinic acid) is a strong acid that

typically is prepared as a solution of colorless, oily liquid in strengths of 50%, 30 to 32%, and 10%.

– It also is prepared in the form of salts (referred to as hypophosphite salts), particularly ammonium hypophosphite, calcium hypophosphite, iron (ferric)

hypophosphite, magnesium hypophosphite, manganese hypophosphite,

potassium hypophosphite, and sodium hypophosphite.

Hypophosphorous Acid (H3PO2) (Continued)

• Over 100 chemical firms located throughout the world produce hypophosphorous

acid.

– The People's Republic of China and India have the largest numbers of

hypophosphorous acid producers, although there are a few producers in the United States.

• There are a wide variety of uses for hypophosphorous acid and its salts in

commercial industry; however, the chemicals have no legitimate household or retail uses.

Hypophosphorous Acid (H3PO2) (Continued)

• The legitimate commercial and laboratory fields that use hypophosphorous acid and its salts include the following:

– Chemical plating

– Food preparation

– Water treatment

– Polymers (as a bleaching agent, color stabilizer, or catalyst)

– Education and research in analytical chemistry

Hypophosphorous Acid (H3PO2) (Continued)

• Chemical suppliers typically distribute hypophosphorous acid in large quantities, for example, in drums containing 275 pounds of the diluted solution.

– Hypophosphorous acid also is distributed in smaller quantities.

• One-half liter of 50% concentrate hypophosphorous acid solution can be obtained from chemical suppliers for as little as $14.

Hypophosphorous Acid (H3PO2) (Continued)

• Methamphetamine laboratory operators typically obtain small quantities of the chemical from other laboratory operators who purchase large quantities of the

chemical and repackage it for further distribution.

– According to law enforcement sources, these individuals sell hypophosphorous acid for as much as $1,000 per half-liter.

•Methamphetamine laboratory operators also purchase hypophosphorous acidvia the internet.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid and the Internet

• The internet is a source of a great deal of information regarding hypophosphorous acid.

• Popular internet sites that disseminate information about illicit drugs contain information about the chemical, including numerous recipes for home production of

methamphetamine using hypophosphorous acid.

• There also are recipes for synthesizing hypophosphorous acid from available chemicals.

• Hypophosphorous acid solutions and salts have been sold to the general public via the internet.

• The Drug Enforcement Administration (DEA) has strong concerns regarding the sale of chemicals on the internet and has requested that any sites (such as auction sites) that allow the sale of regulated chemicals on their domains require proof of

DEA registration from their clients.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid Used in Methamphetamine Production

• Hypophosphorous acid is used in the ephedrine-pseudoephedrine reduction method

of methamphetamine production.

– It is used in the methamphetamine production process to produce hydriodic acid,

an important reagent (it reacts with the ephedrine-pseudoephedrine but does NOT become part of the finished product).

Hypophosphorous Acid (H3PO2) (Continued)

• The regulation of hydriodic acid by DEA in 1993 rendered it virtually unavailable in

the United States.

– However, methamphetamine laboratory operators discovered methods to

produce hydriodic acid using a combination of iodine in water with red phosphorus.

• Laboratory operators found that red phosphorus could be obtained easily, either

from commercial supply companies or by scraping the striker pads from matchbooks or matchboxes.

• Methamphetamine producers soon discovered that hypophosphorous acid ALSO could be used in combination with iodine and water to produce hydriodic acid.

Hypophosphorous Acid (H3PO2) (Continued)

• The practice of using hypophosphorous acid in methamphetamine production is

believed to have begun in the United States in the late 1990s when a methamphetamine producer in Colorado obtained the recipe from Australia, where

the hypophosphorous acid method is prevalent.

– This man was known as a serial cook who had a long history of

methamphetamine production.

•Over several years he trained other laboratory operators in Colorado to produce methamphetamine using hypophosphorous acid.

• As his techniques were passed on to others, the number of methamphetaminelaboratories in Colorado using hypophosphorous acid continued to increase, and the

technique was passed on to numerous methamphetamine producers in other states.

Hypophosphorous Acid (H3PO2) (Continued)

• According to the El Paso Intelligence Center (EPIC) National Clandestine Laboratory

Seizure System, from 2000 through 2002 the number of seized methamphetaminelaboratories in the United States in which hypophosphorous acid was found

increased overall. (See Table 1.)

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid found at methamphetamine laboratories is packaged in a variety of ways.

• The chemical has been found in 1-gallon bottles of solution or in 1-pound jars of salts.

• Some hypophosphorous acid containers are labeled as "plating solution."

• Pint-sized brown glass bottles wrapped in red electrical tape also have been found to contain hypophosphorous acid; they have been discovered primarily in Colorado.

• The vast majority of hypophosphorous acid found at laboratory sites has been recovered from small toxic laboratories (STLs), those which yield gram to ounce

quantities per production cycle.

• Hypophosphorous acid has not been reported at large-scale laboratories operated by Mexican criminal groups in the United States.

Hypophosphorous Acid (H3PO2) (Continued)

• Hazards

• The iodine-hypophosphorous acid method is MORE HAZORDOUS than the iodine-

red phosphorus method, although the reaction using hypophosphorous acid is

faster and gives slightly higher yields.

– When hypophosphorous acid is used, the chemicals must be mixed together

SLOWLY in a PARTICULAR ORDER to prevent them from reacting violently.

Hypophosphorous Acid (H3PO2) (Continued)

• The combination of hypophosphorous acid with the other chemicals and with

certain metals can produce deadly phosphine gas during the initial mixing step and

can CONTINUE to produce phosphine gas for several days AFTER production has been completed…

Hypophosphorous Acid (H3PO2) (Continued)

• The iodine-hypophosphorous acid mixture has a tendency to decompose quickly when overheated or if heated for long periods of time, becoming cloudy or "milky-

white" just prior to giving off a cloud of phosphine gas that can ignite spontaneously.

– Hypophosphorous acid solutions may become unstable if evaporation results in

concentrations above 50%.

Hypophosphorous Acid (H3PO2) (Continued)

• [Note: Law enforcement or emergency personnel who encounter suspected

containers of hypophosphorous acid should use extreme care during handling because laboratory operators often attempt to obtain a more concentrated acid by allowing water to evaporate from the mixture.]

• Because hypophosphorous acid often is used at small methamphetaminelaboratories operated by inexperienced or careless individuals, the potential hazards

of using this method are even greater.

• The risk of fire and explosion is higher in these laboratories, where professional

laboratory equipment typically is not used to contain the phosphine gas and where

safe handling precautions are not employed.

• In addition, these laboratories often are located in homes where children are

present and may come into contact with hypophosphorous acid.

• A child can easily mistake hypophosphorous acid for any other clear liquid,

particularly if it is stored in household containers or drinking glasses.

• Skin, eye, or inhalation exposure can be extremely harmful or fatal.

Hypophosphorous Acid (H3PO2) (Continued)

• Safety Precautions

• Always wear a self-contained breathing apparatus as well as protective clothing when entering areas where hypophosphorous acid may be present.

• When in contact with metals or in a high-temperature environment,

hypophosphorous acid can break down and liberate phosphine and flammable hydrogen gas.

• Do not allow the use of open flames, open lights, matches, or smoking in or around laboratories or dumpsites where hypophosphorous acid is handled.

• In case of fire, use a self-contained positive pressure breathing apparatus and full

protective equipment.

• Use water spray, fog, foam, dry chemicals, or other reagents as may be

appropriate for materials in the surrounding fire.

• Water may be used to cool the containers of hypophosphorous acid; however, use extreme care to avoid allowing water to enter the container.

• In case of spills, neutralize the spilled chemical with alkaline material (soda ash, lime), then absorb it with an inert material such as vermiculite, dry sand, or earth

and place in a chemical waste container.

• Do not use combustible materials such as sawdust.

Hypophosphorous Acid (H3PO2) (Continued)

• Legislation and Control

• In the United States hypophosphorous acid is one of 38 chemicals (or groups of

chemicals) controlled under law by DEA.

• On October 17, 2001, hypophosphorous acid and its salts, along with red and white phosphorus, were officially added as List I chemicals under section 1310 of the

Code of Federal Regulations.

• List I chemicals are defined as chemicals that are used in the manufacture of a

controlled substance in violation of the Controlled Substances Act (CSA) and are

important to the manufacture of a controlled substance.

• Under the law, suppliers are required to maintain records and report receipts, sales,

imports, and exports of these chemicals to DEA.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid, red phosphorus, and white phosphorus, as well as

ephedrine, are unique in that suppliers are required to report all transactions of

these chemicals, regardless of the amount.

• By contrast, the other 34 listed chemicals are only reportable after a supplier's

transactions for a chemical reach an established weight or volume threshold in a calendar month.

• In addition to reporting all transactions involving the chemical, suppliers are

expected to "know their customers" in order to prevent the diversion of these substances to methamphetamine laboratories, as it is illegal to import, export,

purchase, or sell hypophosphorous acid or any other listed chemical in the United States if it is used or intended to be used in the production of a controlled

substance.

• Chemical suppliers are held liable for selling listed chemicals if they know or suspect that the chemical will be used for illicit purposes.

Hypophosphorous Acid (H3PO2) (Continued)

• Outlook

• The use of hypophosphorous acid in the production of methamphetamine is likely

to increase, particularly in the Midwest and Southwest regions of the United States

where methamphetamine production is prevalent.

– Injuries, property damage, and deaths also will increase as a growing number of

inexperienced methamphetamine producers experiment with hypophosphorous acid.

Anhydrous Ammonia

• Anhydrous ammonia is found in fertilizer, countertop cleaner, and commercial refrigerant.

– On its own, it has a pungent, suffocating odor.

• Mixing anhydrous ammonia with other chemicals can release highly toxic gases.

– Because anhydrous ammonia seeks out water (anhydrous means “without

water”) and causes severe burns, any body part that comes into contact with it

should be flushed with water for at least 15 minutes to remove the ammoniafrom the skin.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia has extremely destructive effects on humans.

– Anhydrous ammonia gives off vapors during cooking that can burn the mouth,

throat, and lung tissue.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Anhydrous ammonia seeks water from the nearest source, including the human body (anhydrous means “without water”).

– Because of their high moisture content, EYES, LUNGS, and SKIN are at the

greatest risk of attracting the ammonia.

• When large amounts of anhydrous ammonia are inhaled, the throat swells and the

victim suffocates.

– Exposure to the vapors or liquids can cause severe burns, blindness, or death.

• Anhydrous ammonia has an IDLH (immediately dangerous to life and health) at

only 300 parts per million...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is poses MANY hazards, especially when it is placed in improper vessels and handled/transported by individuals unfamiliar with the

dangers.

• Anhydrous ammonia has a boiling point of -28 degrees below zero.

– When a vessel containing anhydrous ammonia is MOVED, the anhydrous

ammonia will reach its boiling point and pressurize.

•This pressurization can cause vessels to violently RUPTURE, or if the vessel pressurizes and does NOT rupture, the opening of the container of anhydrous

ammonia at a later time can cause RAPID, VIOLENT depressurization.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is mainly used in the U.S. as either a fertilizer or a refrigerant.

– Meth producers tend to store the anhydrous ammonia in IMPROPER/UNAPPROVED containers such as:

•Propane tanks,

• Igloo coolers, or

•Fire extinguishers.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia leaves a tell-tell sign as it flows through these UNAPPROVED

CONTAINERS – a blue or blue green discoloration on the valve.

– PAY ATTENTION to details!!!

Anhydrous Ammonia (Continued)

• Because propane cylinders (and the other unapproved containers) are NOT designed to store anhydrous ammonia, they can EXPLODE as the ammonia eats

through the walls of the cylinders.

– The valves, which take on a bluish/green color, frequently deteriorate and can cause hazardous leaks!!!

Anhydrous Ammonia (Continued)

• Do NOT touch, move, or open any kind of tank or sealed container!!!

– Be aware that propane tanks are often WEAKENED and BRITTLE due to the

anhydrous ammonia and are SENSITIVE to ANY kind of movement or impact.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• These pictures show what happened to a fire extinguisher that was used to store

anhydrous ammonia…

Anhydrous Ammonia (Continued)

• Illegal drug makers often STEAL anhydrous ammonia from areas where it is stored

and used, such as farms.

• Attempted thefts have also occurred at places such as:

– Refrigeration systems holding ammonia,

– Underground pipelines carrying ammonia, and

– Rail cars transporting anhydrous ammonia.

• Often thefts are aborted when thieves are injured or overcome by the toxic gas...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia thieves had better beware!!!

• There is a new product called GloTell that farmers can add to their anhydrous

ammonia tanks…

• Meth cooks will run the risk that the GloTell additive will turn their hands bright

pink!

– This bright pink stain will fluoresce under ultraviolet light even if washed off!!!

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Also, GloTell will produce pink methamphetamine that CANNOT be bleached.

– Users who snort meth made with GloTell will find that they have PINK NOSES!

– Users who inject meth made with GloTell will see a pink stain at the point of

injection!

Sodium Carbonate (Soda Ash)

Sodium Carbonate (Soda Ash) (Continued)

Lead Acetate

Iodine

• Iodine is a natural element, and it is helpful to the body in SMALL amounts.

– However, if iodine is taken in large amounts it can become toxic.

•Extremely high does of iodine can limit the function of the thyroid.

Iodine (Continued)

Iodine (Continued)

• Iodine is bluish-black, and it has a characteristic odor, a sharp acrid taste, and it produces a violet corrosive vapor.

– The vapor is irritating to the respiratory system and eyes.

• The solid iodine irritates the eyes and may burn the skin, and it may cause severe

internal irritation and damage if ingested.

Iodine (Continued)

• Iodine is known as the “blue ingredient” in the production of meth (in the “red, white, and blue” method).

Iodine (Continued)

Iodine (Continued)

• It takes approximately 4 bottles of iodine tincture to produce 2 – 3 grams of meth.

Iodine (Continued)

Iodine (Continued)

• Iodine leaves distinctive yellow-blue or brown stains on surfaces in former methlabs.

Iodine (Continued)

Iodine (Continued)

Iodine (Continued)

• The only good thing about iodine is that it leaves yellow stains.

• If you see yellow stained coffee filters, gloves or paper towels, this could be an

indicator that you’re in a lab.

• If you see yellow stains, you can spray some starch on them.

– If they turn a purplish blue/black, it’s iodine.

• Iodine is the only substance that reacts with soluble starch to produce a purplish black color.

– The only way to get iodine vapor all over the walls is to cook meth.

Mercurous Chloride

Rock Salt

Hydrogen Chloride

• Hydrogen chloride gas is commercially available.

• Hydrogen chloride gas can also be made by mixing sulfuric acid and salt.

• Muriatic acid is simply hydrogen chloride gas suspended in water.

• Hydrogen chloride gas can be seen as a pale white smoke.

– It is a poisonous gas that can cause respiratory problems and death.

Hydrogen Chloride (Continued)

Ammonium Nitrate

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Hydriodic Acid

• Hydriodic acid is a corrosive acid that is colorless when freshly prepared.

– When hydriodic acid is exposed to light and air, it turns yellowish and brown.

• Hydriodic acid is a solution of hydrogen iodide gas in water.

• Hydriodic acid vapor is irritating to the respiratory system, skin, and eyes.

• Hydriodic acid liquid causes severe burns to the eyes and skin.

• If hydriodic acid is accidentally ingested, it can cause severe internal irritation and

damage.

Hydriodic Acid (Continued)

Catalyst Chemicals

• Catalyst Chemicals:

– Chemicals which SPEED UP a reaction process and/or cause it to go to GREATER COMPLETION.

Red Phosphorus

• Red phosphorus is found ON matchboxes, in road flares, and other explosives.

– Red Phosphorus IGNITES when OVERHEATED!!!

• By combining red phosphorus and iodine, you can easily create the highly

controlled substance known as hydriodic acid (which is an essential ingredient in making meth).

– Creating 2 – 3 grams of meth requires about 4 big boxes of matches.

Red Phosphorus (Continued)

• Red phosphorous is highly flammable and if it is overheated it can become white phosphorous…

– White phosphorous is a volatile and highly explosive substance.

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Lithium

• Lithium is used in batteries.

• Lithium seriously burns the skin upon contact.

– It also reacts VIOLENTLY with WATER and is highly explosive.

Lithium (Continued)

• Lithium reacts VIOLENTLY with WATER, and if it is splashed in the eyes during

cooking it will cause blindness.

– Lithium is extremely caustic to all body tissues.

Lithium (Continued)

Lithium (Continued)

• Lithium metal is HIGHLY water reactive and it will BURN or EXPLODE if it comes into contact with WATER!

• Because of the moisture in your skin, it will burn exposed flesh.

• Lithium metal will DEGRADE when exposed to atmospheric moisture…

– This is why meth cooks store lithium metal in a solvent prior to use.

• It is typical to see harvested lithium strips in Coleman fuel or Mineral Spirits to prevent explosions.

•Large quantities can be harvested and saved in these containers until needed

for a cook.

Lithium (Continued)

• If you see battery shells in the trashcan, on the floor, etc. – this is a VERY GOOD

indicator that you might be entering a meth lab!

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

• Lithium catches fire when in contact with water...

Solvent Chemicals

• Solvent Chemicals:

– A medium (liquid) in which a chemical operation takes place.

• Solvent chemicals (UNLIKE the precursor chemicals) CAN be

substituted/interchanged.

Ether

• Ether was once called “sweet vitriol” because of its hypnotic effect.

• Ether is a highly flammable substance that is used as an anesthetic agent –

especially in third world countries where more expensive anesthesia is not available.

– While inhaling the ether, patients could undergo complete surgical procedures while otherwise awake without feeling pain or concern.

Ether (Continued)

• Ether can be obtained from engine starting fluid.

• Ether is a solvent and it is flammable.

– It is particularly hazardous because it can cause BOTH fire and explosion.

• It has been said that a quart of ether can “level” a small house.

Ethyl Ether (Continued)

Ethyl Ether (Continued)

• Ether is VERY flammable and is HEAVIER than air.

– NEVER use ether near flames or non-sparkless motors.

– Ether is very PUNGENT – even a small evaporated amount of ether is VERY noticeable.

Acetone

• Acetone can be found in nail polish remover or paint thinner.

– It is extremely flammable.

• In the setting of a meth lab where meth is being cooked with high heat, acetone is

very dangerous.

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Toluene

• Toluene is used in brake fluid.

– When working with brake fluid (toluene), be careful not to spill it on your car

because it will eat away the paint and chrome…

• You also have to be careful using toluene around other household chemicals

because its high concentration of polyethylene glycol can cause it to ignite in a

violent fireball.

• Toluene is powerful enough to dissolve rubber.

Toluene (Continued)

• Toluene is used to form meth crystals.

– The fumes toluene releases can cause brain damage or death.

Toluene (Continued)

Toluene (Continued)

Ethanol

Isopropanol

Isopropanol (Continued)

Isopropyl Alcohol

Methanol

Methanol (Continued)

Methanol (Continued)

Benzene

Benzene (Continued)

Which of these is NOT a common ingredient in Meth?

Nail Polish Remover

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Methamphetamine- PowerPoint

- Chemicals and Ingredients Used to Make Meth

CJUS 240

Economic Costs of Meth

• The economic cost of methamphetamine use in the U.S. reached $23.4 billion in

2005.

– This includes the burden of addiction, premature death, drug treatment, child

care, and cleaning of lab sites.

– This figure does NOT take into account the future needs of the meth user.

Concerns with ACTIVE Meth Labs

• Danger of fire and explosion

• Chemical spills

• Inhalation of solvents, corrosives, and toxic gases

• “Booby traps”

• Waste disposal

Concerns with FORMER Meth Labs

• Vapors

• Chemical residues

• Methamphetamine residues

• Waste disposal

Equipment Used in Meth Production

• Pyrex or Corning dishes

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

• Coffee Filters

Equipment Used in Meth Production

Equipment Used in Meth Production

Basic Chemical Requirements

• In a clandestine laboratory, basic types of chemicals are necessary in order to

produce the desired drug.

– The basic types of chemicals needed are:

1) Precursor Chemicals

2) Reagent Chemicals

3) Catalyst Chemicals

4) Solvent Chemicals

List I Chemical

• The term “List I chemical” means a chemical specified by regulation of the Attorney General as a chemical that is used in manufacturing a controlled substance and is

IMPORTANT to the manufacture of the controlled substance.

• Examples of List I chemicals are:

– GBL

– Red Phosphorus

– Pseudoephedrine

List II Chemical

• The term “List II chemical” means a chemical (other than a List I chemical) specified by regulation of the Attorney General as a chemical that is USED in

manufacturing a controlled substance.

• Examples of List II chemicals are:

– Toluene

– Iodine

– Hydrochloric Acid

Precursor Chemicals

• Precursor Chemicals:

– A chemical that is ESSENTIAL to the production of a controlled substance and for

which NO SUBSTITUTION can be made.

Pseudoephedrine

• Pseudoephedrine is a decongestant found in cold medicine.

– Large amounts of pseudoephedrine on its own can harm the respiratory and nervous systems, as well as the heart.

Pseudoephedrine (Continued)

• Some of the common ways used to divert products containing pseudoephedrine

include:

– “Smurfing” – making multiple purchases at different locations

– Shelf-Sweeping – the theft of all shelf stock

– Shoplifting

– Theft from wholesalers

Pseudoephedrine (Continued)

• Pseudoephedrine smurfing is a method used by some methamphetamine producers to acquire large quantities of pseudoephedrine by enlisting the assistance of several

friends or associates (often referred to as “smurfers”) to make purchases at or below the legal thresholds from multiple retail locations.

– Smurfers are often addicts who trade the pseudoephedrine for finished

methamphetamine.

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

• About 680 pseudoephedrine tablets are needed to produce one ounce of meth…

Pseudoephedrine (Continued)

Out With a Bang

An Unstable Recipe…

• Meth contains a variety of poisonous ingredients…

– Some become EVEN MORE DANGEROUS once the cooking process begins…

Common Ingredients to Make Methamphetamine

Reagent Chemicals

• Reagent Chemicals:

– Chemicals which REACT upon the precursor chemical causing it to chemicallyCHANGE.

• A reagent chemical is a chemical which is required for the synthesis of an illicit drug substance, but which is NOT incorporated into the final chemical product.

Hydrochloric Acid

• Hydrochloric acid is a highly corrosive liquid that is used to make plastic (such as PVC pipe and polyurethane).

– It can remove rust and iron-oxide from steel and is highly corrosive to human

skin.

•Hydrochloric acid makes up the majority of the gastric acid in the human

digestive fluid.

• In high concentrations, hydrochloric acid will literally eat away human flesh…

Hydrochloric Acid (Continued)

• Hydrochloric acid can be purchased from hardware stores as:

– Tile and Grout Acid Cleaner

– Muriatic Acid

– Pool Acid

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

• Hydrochloric acid is a solution of hydrogen chloride gas suspended in water.

– Hydrochloric acid is corrosive and is a light yellow liquid color from traces of iron, chlorine, and organic matter.

• Inhaling hydrochloric acid may cause coughing or choking, inflammation, and

ulceration of the respiratory tract.

• Concentrated solutions of hydrochloric acid can cause severe burns and irritate the

mucous membranes, eyes, and respiratory tract.

– Exposure to hydrochloric acid vapors may result in pulmonary edema and

possibly death.

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

Sodium Hydroxide (NaOH)

• Sodium hydroxide is also called Lye.

• Sodium hydroxide is classified as a corrosive, and it is one of the main chemicals in

drain cleaner.

– It is also used in aluminum etching and to create biodiesal.

– It can burn the skin or cause blindness.

• Sodium hydroxide is used to dispose of road kill because it turns the dead bodies

into a coffee-like liquid.

Sodium Hydroxide (NaOH) (Continued)

• Drain cleaner (sodium hydroxide) is extremely corrosive, and without wearing

protection, even the smallest spill on the skin can eat through flesh…

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sulfuric Acid (H2SO4)

• Sulfuric acid is used in drain or toilet bowl cleaner as well as battery acid.

– It is another highly corrosive substance that burns the skin on contact.

Sulfuric Acid (H2SO4) (Continued)

• The product label warning for Drano® (sulfuric acid) says it all:

– DANGER: MAY BURN EYES AND SKIN ON CONTACT.

•HARMFUL IF SWALLOWED.

–Avoid contact with body and clothing.

•TOXIC GAS MAY FORM IF MIXED WITH OTHER CHEMICALS.

–If gases are released, leave immediately and ventilate area.

•FIRST AID: Give Immediately:

–EYES AND SKIN:

»Flush with water for 20 minutes.

»Remove affected clothing.

–IF SWALLOWED:

»Rinse mouth and drink a glass of water or milk.

»Do not induce vomiting.

–THEN SEEK MEDICAL AID.

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Hypophosphorous Acid (H3PO2)

• Hypophosphorous acid, which is used legally for a variety of commercial purposes,

is a chemical that increasingly is substituted for red phosphorus in the methamphetamine production process.

– The use of hypophospherous acid SIGNIFICANTLY increases the risk of fire!!!

• The federal government regulates the sale of hypophosphorous acid through registration, record keeping, reporting, and import/export requirements regardless

of the quantity being handled or distributed.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid is a colorless oily liquid that emits a SOUR odor.

– There is an extreme fire and explosion hazard if the hypophosphorous acid

comes into contact with a solvent such as acetone, toluene, or Coleman fuel.

• Hypophosphorous acid will also emit phosphine gas and the fumes can ignite.

Hypophosphorous Acid (H3PO2) (Continued)

• Although hypophosphorous acid is a List I chemical under the Controlled Substances Act, methamphetamine producers typically purchase the chemical via

the internet or from associates who also are engaged in methamphetamine

production.

– The use of hypophosphorous acid in methamphetamine production is an

EXTREMELY DANGEROUS PRACTICE because of the deadly gases that can be generated as well as the risk of fire or explosion.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid (H3PO2, also called phosphinic acid) is a strong acid that

typically is prepared as a solution of colorless, oily liquid in strengths of 50%, 30 to 32%, and 10%.

– It also is prepared in the form of salts (referred to as hypophosphite salts), particularly ammonium hypophosphite, calcium hypophosphite, iron (ferric)

hypophosphite, magnesium hypophosphite, manganese hypophosphite,

potassium hypophosphite, and sodium hypophosphite.

Hypophosphorous Acid (H3PO2) (Continued)

• Over 100 chemical firms located throughout the world produce hypophosphorous

acid.

– The People's Republic of China and India have the largest numbers of

hypophosphorous acid producers, although there are a few producers in the United States.

• There are a wide variety of uses for hypophosphorous acid and its salts in

commercial industry; however, the chemicals have no legitimate household or retail uses.

Hypophosphorous Acid (H3PO2) (Continued)

• The legitimate commercial and laboratory fields that use hypophosphorous acid and its salts include the following:

– Chemical plating

– Food preparation

– Water treatment

– Polymers (as a bleaching agent, color stabilizer, or catalyst)

– Education and research in analytical chemistry

Hypophosphorous Acid (H3PO2) (Continued)

• Chemical suppliers typically distribute hypophosphorous acid in large quantities, for example, in drums containing 275 pounds of the diluted solution.

– Hypophosphorous acid also is distributed in smaller quantities.

• One-half liter of 50% concentrate hypophosphorous acid solution can be obtained from chemical suppliers for as little as $14.

Hypophosphorous Acid (H3PO2) (Continued)

• Methamphetamine laboratory operators typically obtain small quantities of the chemical from other laboratory operators who purchase large quantities of the

chemical and repackage it for further distribution.

– According to law enforcement sources, these individuals sell hypophosphorous acid for as much as $1,000 per half-liter.

•Methamphetamine laboratory operators also purchase hypophosphorous acidvia the internet.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid and the Internet

• The internet is a source of a great deal of information regarding hypophosphorous acid.

• Popular internet sites that disseminate information about illicit drugs contain information about the chemical, including numerous recipes for home production of

methamphetamine using hypophosphorous acid.

• There also are recipes for synthesizing hypophosphorous acid from available chemicals.

• Hypophosphorous acid solutions and salts have been sold to the general public via the internet.

• The Drug Enforcement Administration (DEA) has strong concerns regarding the sale

of chemicals on the internet and has requested that any sites (such as auction sites) that allow the sale of regulated chemicals on their domains require proof of

DEA registration from their clients.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid Used in Methamphetamine Production

• Hypophosphorous acid is used in the ephedrine-pseudoephedrine reduction method

of methamphetamine production.

– It is used in the methamphetamine production process to produce hydriodic acid,

an important reagent (it reacts with the ephedrine-pseudoephedrine but does NOT become part of the finished product).

Hypophosphorous Acid (H3PO2) (Continued)

• The regulation of hydriodic acid by DEA in 1993 rendered it virtually unavailable in

the United States.

– However, methamphetamine laboratory operators discovered methods to

produce hydriodic acid using a combination of iodine in water with red phosphorus.

• Laboratory operators found that red phosphorus could be obtained easily, either

from commercial supply companies or by scraping the striker pads from matchbooks or matchboxes.

• Methamphetamine producers soon discovered that hypophosphorous acid ALSO could be used in combination with iodine and water to produce hydriodic acid.

Hypophosphorous Acid (H3PO2) (Continued)

• The practice of using hypophosphorous acid in methamphetamine production is

believed to have begun in the United States in the late 1990s when a methamphetamine producer in Colorado obtained the recipe from Australia, where

the hypophosphorous acid method is prevalent.

– This man was known as a serial cook who had a long history of

methamphetamine production.

•Over several years he trained other laboratory operators in Colorado to produce methamphetamine using hypophosphorous acid.

• As his techniques were passed on to others, the number of methamphetaminelaboratories in Colorado using hypophosphorous acid continued to increase, and the

technique was passed on to numerous methamphetamine producers in other

states.

Hypophosphorous Acid (H3PO2) (Continued)

• According to the El Paso Intelligence Center (EPIC) National Clandestine Laboratory

Seizure System, from 2000 through 2002 the number of seized methamphetaminelaboratories in the United States in which hypophosphorous acid was found

increased overall. (See Table 1.)

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid found at methamphetamine laboratories is packaged in a variety of ways.

• The chemical has been found in 1-gallon bottles of solution or in 1-pound jars of salts.

• Some hypophosphorous acid containers are labeled as "plating solution."

• Pint-sized brown glass bottles wrapped in red electrical tape also have been found to contain hypophosphorous acid; they have been discovered primarily in Colorado.

• The vast majority of hypophosphorous acid found at laboratory sites has been recovered from small toxic laboratories (STLs), those which yield gram to ounce

quantities per production cycle.

• Hypophosphorous acid has not been reported at large-scale laboratories operated by Mexican criminal groups in the United States.

Hypophosphorous Acid (H3PO2) (Continued)

• Hazards

• The iodine-hypophosphorous acid method is MORE HAZORDOUS than the iodine-

red phosphorus method, although the reaction using hypophosphorous acid is

faster and gives slightly higher yields.

– When hypophosphorous acid is used, the chemicals must be mixed together

SLOWLY in a PARTICULAR ORDER to prevent them from reacting violently.

Hypophosphorous Acid (H3PO2) (Continued)

• The combination of hypophosphorous acid with the other chemicals and with

certain metals can produce deadly phosphine gas during the initial mixing step and

can CONTINUE to produce phosphine gas for several days AFTER production has been completed…

Hypophosphorous Acid (H3PO2) (Continued)

• The iodine-hypophosphorous acid mixture has a tendency to decompose quickly when overheated or if heated for long periods of time, becoming cloudy or "milky-

white" just prior to giving off a cloud of phosphine gas that can ignite spontaneously.

– Hypophosphorous acid solutions may become unstable if evaporation results in

concentrations above 50%.

Hypophosphorous Acid (H3PO2) (Continued)

• [Note: Law enforcement or emergency personnel who encounter suspected

containers of hypophosphorous acid should use extreme care during handling because laboratory operators often attempt to obtain a more concentrated acid by

allowing water to evaporate from the mixture.]

• Because hypophosphorous acid often is used at small methamphetaminelaboratories operated by inexperienced or careless individuals, the potential hazards

of using this method are even greater.

• The risk of fire and explosion is higher in these laboratories, where professional laboratory equipment typically is not used to contain the phosphine gas and where

safe handling precautions are not employed.

• In addition, these laboratories often are located in homes where children are

present and may come into contact with hypophosphorous acid.

• A child can easily mistake hypophosphorous acid for any other clear liquid,

particularly if it is stored in household containers or drinking glasses.

• Skin, eye, or inhalation exposure can be extremely harmful or fatal.

Hypophosphorous Acid (H3PO2) (Continued)

• Safety Precautions

• Always wear a self-contained breathing apparatus as well as protective clothing when entering areas where hypophosphorous acid may be present.

• When in contact with metals or in a high-temperature environment,

hypophosphorous acid can break down and liberate phosphine and flammable hydrogen gas.

• Do not allow the use of open flames, open lights, matches, or smoking in or around laboratories or dumpsites where hypophosphorous acid is handled.

• In case of fire, use a self-contained positive pressure breathing apparatus and full

protective equipment.

• Use water spray, fog, foam, dry chemicals, or other reagents as may be

appropriate for materials in the surrounding fire.

• Water may be used to cool the containers of hypophosphorous acid; however, use extreme care to avoid allowing water to enter the container.

• In case of spills, neutralize the spilled chemical with alkaline material (soda ash, lime), then absorb it with an inert material such as vermiculite, dry sand, or earth

and place in a chemical waste container.

• Do not use combustible materials such as sawdust.

Hypophosphorous Acid (H3PO2) (Continued)

• Legislation and Control

• In the United States hypophosphorous acid is one of 38 chemicals (or groups of

chemicals) controlled under law by DEA.

• On October 17, 2001, hypophosphorous acid and its salts, along with red and white phosphorus, were officially added as List I chemicals under section 1310 of the Code of Federal Regulations.

• List I chemicals are defined as chemicals that are used in the manufacture of a

controlled substance in violation of the Controlled Substances Act (CSA) and are

important to the manufacture of a controlled substance.

• Under the law, suppliers are required to maintain records and report receipts, sales,

imports, and exports of these chemicals to DEA.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid, red phosphorus, and white phosphorus, as well as

ephedrine, are unique in that suppliers are required to report all transactions of

these chemicals, regardless of the amount.

• By contrast, the other 34 listed chemicals are only reportable after a supplier's transactions for a chemical reach an established weight or volume threshold in a calendar month.

• In addition to reporting all transactions involving the chemical, suppliers are

expected to "know their customers" in order to prevent the diversion of these substances to methamphetamine laboratories, as it is illegal to import, export,

purchase, or sell hypophosphorous acid or any other listed chemical in the United States if it is used or intended to be used in the production of a controlled

substance.

• Chemical suppliers are held liable for selling listed chemicals if they know or suspect that the chemical will be used for illicit purposes.

Hypophosphorous Acid (H3PO2) (Continued)

• Outlook

• The use of hypophosphorous acid in the production of methamphetamine is likely

to increase, particularly in the Midwest and Southwest regions of the United States

where methamphetamine production is prevalent.

– Injuries, property damage, and deaths also will increase as a growing number of

inexperienced methamphetamine producers experiment with hypophosphorous acid.

Anhydrous Ammonia

• Anhydrous ammonia is found in fertilizer, countertop cleaner, and commercial refrigerant.

– On its own, it has a pungent, suffocating odor.

• Mixing anhydrous ammonia with other chemicals can release highly toxic gases.

– Because anhydrous ammonia seeks out water (anhydrous means “without

water”) and causes severe burns, any body part that comes into contact with it

should be flushed with water for at least 15 minutes to remove the ammoniafrom the skin.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia has extremely destructive effects on humans.

– Anhydrous ammonia gives off vapors during cooking that can burn the mouth, throat, and lung tissue.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Anhydrous ammonia seeks water from the nearest source, including the human body (anhydrous means “without water”).

– Because of their high moisture content, EYES, LUNGS, and SKIN are at the

greatest risk of attracting the ammonia.

• When large amounts of anhydrous ammonia are inhaled, the throat swells and the

victim suffocates.

– Exposure to the vapors or liquids can cause severe burns, blindness, or death.

• Anhydrous ammonia has an IDLH (immediately dangerous to life and health) at

only 300 parts per million...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is poses MANY hazards, especially when it is placed in improper vessels and handled/transported by individuals unfamiliar with the

dangers.

• Anhydrous ammonia has a boiling point of -28 degrees below zero.

– When a vessel containing anhydrous ammonia is MOVED, the anhydrous

ammonia will reach its boiling point and pressurize.

•This pressurization can cause vessels to violently RUPTURE, or if the vessel pressurizes and does NOT rupture, the opening of the container of anhydrous

ammonia at a later time can cause RAPID, VIOLENT depressurization.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is mainly used in the U.S. as either a fertilizer or a refrigerant.

– Meth producers tend to store the anhydrous ammonia in IMPROPER/UNAPPROVED containers such as:

•Propane tanks,

• Igloo coolers, or

•Fire extinguishers.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia leaves a tell-tell sign as it flows through these UNAPPROVED

CONTAINERS – a blue or blue green discoloration on the valve.

– PAY ATTENTION to details!!!

Anhydrous Ammonia (Continued)

• Because propane cylinders (and the other unapproved containers) are NOT designed to store anhydrous ammonia, they can EXPLODE as the ammonia eats

through the walls of the cylinders.

– The valves, which take on a bluish/green color, frequently deteriorate and can cause hazardous leaks!!!

Anhydrous Ammonia (Continued)

• Do NOT touch, move, or open any kind of tank or sealed container!!!

– Be aware that propane tanks are often WEAKENED and BRITTLE due to the

anhydrous ammonia and are SENSITIVE to ANY kind of movement or impact.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• These pictures show what happened to a fire extinguisher that was used to store

anhydrous ammonia…

Anhydrous Ammonia (Continued)

• Illegal drug makers often STEAL anhydrous ammonia from areas where it is stored and used, such as farms.

• Attempted thefts have also occurred at places such as:

– Refrigeration systems holding ammonia,

– Underground pipelines carrying ammonia, and

– Rail cars transporting anhydrous ammonia.

• Often thefts are aborted when thieves are injured or overcome by the toxic gas...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia thieves had better beware!!!

• There is a new product called GloTell that farmers can add to their anhydrous

ammonia tanks…

• Meth cooks will run the risk that the GloTell additive will turn their hands bright

pink!

– This bright pink stain will fluoresce under ultraviolet light even if washed off!!!

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Also, GloTell will produce pink methamphetamine that CANNOT be bleached.

– Users who snort meth made with GloTell will find that they have PINK NOSES!

– Users who inject meth made with GloTell will see a pink stain at the point of

injection!

Sodium Carbonate (Soda Ash)

Sodium Carbonate (Soda Ash) (Continued)

Lead Acetate

Iodine

• Iodine is a natural element, and it is helpful to the body in SMALL amounts.

– However, if iodine is taken in large amounts it can become toxic.

•Extremely high does of iodine can limit the function of the thyroid.

Iodine (Continued)

Iodine (Continued)

• Iodine is bluish-black, and it has a characteristic odor, a sharp acrid taste, and it produces a violet corrosive vapor.

– The vapor is irritating to the respiratory system and eyes.

• The solid iodine irritates the eyes and may burn the skin, and it may cause severe

internal irritation and damage if ingested.

Iodine (Continued)

• Iodine is known as the “blue ingredient” in the production of meth (in the “red, white, and blue” method).

Iodine (Continued)

Iodine (Continued)

• It takes approximately 4 bottles of iodine tincture to produce 2 – 3 grams of meth.

Iodine (Continued)

Iodine (Continued)

• Iodine leaves distinctive yellow-blue or brown stains on surfaces in former methlabs.

Iodine (Continued)

Iodine (Continued)

Iodine (Continued)

• The only good thing about iodine is that it leaves yellow stains.

• If you see yellow stained coffee filters, gloves or paper towels, this could be an

indicator that you’re in a lab.

• If you see yellow stains, you can spray some starch on them.

– If they turn a purplish blue/black, it’s iodine.

• Iodine is the only substance that reacts with soluble starch to produce a purplish black color.

– The only way to get iodine vapor all over the walls is to cook meth.

Mercurous Chloride

Rock Salt

Hydrogen Chloride

• Hydrogen chloride gas is commercially available.

• Hydrogen chloride gas can also be made by mixing sulfuric acid and salt.

• Muriatic acid is simply hydrogen chloride gas suspended in water.

• Hydrogen chloride gas can be seen as a pale white smoke.

– It is a poisonous gas that can cause respiratory problems and death.

Hydrogen Chloride (Continued)

Ammonium Nitrate

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Hydriodic Acid

• Hydriodic acid is a corrosive acid that is colorless when freshly prepared.

– When hydriodic acid is exposed to light and air, it turns yellowish and brown.

• Hydriodic acid is a solution of hydrogen iodide gas in water.

• Hydriodic acid vapor is irritating to the respiratory system, skin, and eyes.

• Hydriodic acid liquid causes severe burns to the eyes and skin.

• If hydriodic acid is accidentally ingested, it can cause severe internal irritation and

damage.

Hydriodic Acid (Continued)

Catalyst Chemicals

• Catalyst Chemicals:

– Chemicals which SPEED UP a reaction process and/or cause it to go to GREATER COMPLETION.

Red Phosphorus

• Red phosphorus is found ON matchboxes, in road flares, and other explosives.

– Red Phosphorus IGNITES when OVERHEATED!!!

• By combining red phosphorus and iodine, you can easily create the highly controlled substance known as hydriodic acid (which is an essential ingredient in making meth).

– Creating 2 – 3 grams of meth requires about 4 big boxes of matches.

Red Phosphorus (Continued)

• Red phosphorous is highly flammable and if it is overheated it can become white

phosphorous…

– White phosphorous is a volatile and highly explosive substance.

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Lithium

• Lithium is used in batteries.

• Lithium seriously burns the skin upon contact.

– It also reacts VIOLENTLY with WATER and is highly explosive.

Lithium (Continued)

• Lithium reacts VIOLENTLY with WATER, and if it is splashed in the eyes during

cooking it will cause blindness.

– Lithium is extremely caustic to all body tissues.

Lithium (Continued)

Lithium (Continued)

• Lithium metal is HIGHLY water reactive and it will BURN or EXPLODE if it comes into contact with WATER!

• Because of the moisture in your skin, it will burn exposed flesh.

• Lithium metal will DEGRADE when exposed to atmospheric moisture…

– This is why meth cooks store lithium metal in a solvent prior to use.

• It is typical to see harvested lithium strips in Coleman fuel or Mineral Spirits to prevent explosions.

•Large quantities can be harvested and saved in these containers until needed

for a cook.

Lithium (Continued)

• If you see battery shells in the trashcan, on the floor, etc. – this is a VERY GOOD

indicator that you might be entering a meth lab!

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

• Lithium catches fire when in contact with water...

Solvent Chemicals

• Solvent Chemicals:

– A medium (liquid) in which a chemical operation takes place.

• Solvent chemicals (UNLIKE the precursor chemicals) CAN be

substituted/interchanged.

Ether

• Ether was once called “sweet vitriol” because of its hypnotic effect.

• Ether is a highly flammable substance that is used as an anesthetic agent –

especially in third world countries where more expensive anesthesia is not available.

– While inhaling the ether, patients could undergo complete surgical procedures while otherwise awake without feeling pain or concern.

Ether (Continued)

• Ether can be obtained from engine starting fluid.

• Ether is a solvent and it is flammable.

– It is particularly hazardous because it can cause BOTH fire and explosion.

• It has been said that a quart of ether can “level” a small house.

Ethyl Ether (Continued)

Ethyl Ether (Continued)

• Ether is VERY flammable and is HEAVIER than air.

– NEVER use ether near flames or non-sparkless motors.

– Ether is very PUNGENT – even a small evaporated amount of ether is VERY noticeable.

Acetone

• Acetone can be found in nail polish remover or paint thinner.

– It is extremely flammable.

• In the setting of a meth lab where meth is being cooked with high heat, acetone is

very dangerous.

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Toluene

• Toluene is used in brake fluid.

– When working with brake fluid (toluene), be careful not to spill it on your car

because it will eat away the paint and chrome…

• You also have to be careful using toluene around other household chemicals

because its high concentration of polyethylene glycol can cause it to ignite in a

violent fireball.

• Toluene is powerful enough to dissolve rubber.

Toluene (Continued)

• Toluene is used to form meth crystals.

– The fumes toluene releases can cause brain damage or death.

Toluene (Continued)

Toluene (Continued)

Ethanol

Isopropanol

Isopropanol (Continued)

Isopropyl Alcohol

Methanol

Methanol (Continued)

Methanol (Continued)

Benzene

Benzene (Continued)

Which of these is NOT a common ingredient in Meth?

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Page 10: Methamphetamine - PowerPoint - Chemicals and Ingredients ... · 2/5/2014 1 Methamphetamine - PowerPoint - Chemicals and Ingredients Used to Make Meth CJUS 240 Economic Costs of Meth

2/5/2014

10

Methamphetamine- PowerPoint

- Chemicals and Ingredients Used to Make Meth

CJUS 240

Economic Costs of Meth

• The economic cost of methamphetamine use in the U.S. reached $23.4 billion in

2005.

– This includes the burden of addiction, premature death, drug treatment, child

care, and cleaning of lab sites.

– This figure does NOT take into account the future needs of the meth user.

Concerns with ACTIVE Meth Labs

• Danger of fire and explosion

• Chemical spills

• Inhalation of solvents, corrosives, and toxic gases

• “Booby traps”

• Waste disposal

Concerns with FORMER Meth Labs

• Vapors

• Chemical residues

• Methamphetamine residues

• Waste disposal

Equipment Used in Meth Production

• Pyrex or Corning dishes

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

• Coffee Filters

Equipment Used in Meth Production

Equipment Used in Meth Production

Basic Chemical Requirements

• In a clandestine laboratory, basic types of chemicals are necessary in order to

produce the desired drug.

– The basic types of chemicals needed are:

1) Precursor Chemicals

2) Reagent Chemicals

3) Catalyst Chemicals

4) Solvent Chemicals

List I Chemical

• The term “List I chemical” means a chemical specified by regulation of the Attorney General as a chemical that is used in manufacturing a controlled substance and is

IMPORTANT to the manufacture of the controlled substance.

• Examples of List I chemicals are:

– GBL

– Red Phosphorus

– Pseudoephedrine

List II Chemical

• The term “List II chemical” means a chemical (other than a List I chemical) specified by regulation of the Attorney General as a chemical that is USED in

manufacturing a controlled substance.

• Examples of List II chemicals are:

– Toluene

– Iodine

– Hydrochloric Acid

Precursor Chemicals

• Precursor Chemicals:

– A chemical that is ESSENTIAL to the production of a controlled substance and for

which NO SUBSTITUTION can be made.

Pseudoephedrine

• Pseudoephedrine is a decongestant found in cold medicine.

– Large amounts of pseudoephedrine on its own can harm the respiratory and nervous systems, as well as the heart.

Pseudoephedrine (Continued)

• Some of the common ways used to divert products containing pseudoephedrine

include:

– “Smurfing” – making multiple purchases at different locations

– Shelf-Sweeping – the theft of all shelf stock

– Shoplifting

– Theft from wholesalers

Pseudoephedrine (Continued)

• Pseudoephedrine smurfing is a method used by some methamphetamine producers to acquire large quantities of pseudoephedrine by enlisting the assistance of several

friends or associates (often referred to as “smurfers”) to make purchases at or below the legal thresholds from multiple retail locations.

– Smurfers are often addicts who trade the pseudoephedrine for finished

methamphetamine.

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

• About 680 pseudoephedrine tablets are needed to produce one ounce of meth…

Pseudoephedrine (Continued)

Out With a Bang

An Unstable Recipe…

• Meth contains a variety of poisonous ingredients…

– Some become EVEN MORE DANGEROUS once the cooking process begins…

Common Ingredients to Make Methamphetamine

Reagent Chemicals

• Reagent Chemicals:

– Chemicals which REACT upon the precursor chemical causing it to chemicallyCHANGE.

• A reagent chemical is a chemical which is required for the synthesis of an illicit drug substance, but which is NOT incorporated into the final chemical product.

Hydrochloric Acid

• Hydrochloric acid is a highly corrosive liquid that is used to make plastic (such as PVC pipe and polyurethane).

– It can remove rust and iron-oxide from steel and is highly corrosive to human

skin.

•Hydrochloric acid makes up the majority of the gastric acid in the human

digestive fluid.

• In high concentrations, hydrochloric acid will literally eat away human flesh…

Hydrochloric Acid (Continued)

• Hydrochloric acid can be purchased from hardware stores as:

– Tile and Grout Acid Cleaner

– Muriatic Acid

– Pool Acid

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

• Hydrochloric acid is a solution of hydrogen chloride gas suspended in water.

– Hydrochloric acid is corrosive and is a light yellow liquid color from traces of iron, chlorine, and organic matter.

• Inhaling hydrochloric acid may cause coughing or choking, inflammation, and

ulceration of the respiratory tract.

• Concentrated solutions of hydrochloric acid can cause severe burns and irritate the

mucous membranes, eyes, and respiratory tract.

– Exposure to hydrochloric acid vapors may result in pulmonary edema and

possibly death.

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

Sodium Hydroxide (NaOH)

• Sodium hydroxide is also called Lye.

• Sodium hydroxide is classified as a corrosive, and it is one of the main chemicals in

drain cleaner.

– It is also used in aluminum etching and to create biodiesal.

– It can burn the skin or cause blindness.

• Sodium hydroxide is used to dispose of road kill because it turns the dead bodies

into a coffee-like liquid.

Sodium Hydroxide (NaOH) (Continued)

• Drain cleaner (sodium hydroxide) is extremely corrosive, and without wearing

protection, even the smallest spill on the skin can eat through flesh…

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sulfuric Acid (H2SO4)

• Sulfuric acid is used in drain or toilet bowl cleaner as well as battery acid.

– It is another highly corrosive substance that burns the skin on contact.

Sulfuric Acid (H2SO4) (Continued)

• The product label warning for Drano® (sulfuric acid) says it all:

– DANGER: MAY BURN EYES AND SKIN ON CONTACT.

•HARMFUL IF SWALLOWED.

–Avoid contact with body and clothing.

•TOXIC GAS MAY FORM IF MIXED WITH OTHER CHEMICALS.

–If gases are released, leave immediately and ventilate area.

•FIRST AID: Give Immediately:

–EYES AND SKIN:

»Flush with water for 20 minutes.

»Remove affected clothing.

–IF SWALLOWED:

»Rinse mouth and drink a glass of water or milk.

»Do not induce vomiting.

–THEN SEEK MEDICAL AID.

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Hypophosphorous Acid (H3PO2)

• Hypophosphorous acid, which is used legally for a variety of commercial purposes,

is a chemical that increasingly is substituted for red phosphorus in the methamphetamine production process.

– The use of hypophospherous acid SIGNIFICANTLY increases the risk of fire!!!

• The federal government regulates the sale of hypophosphorous acid through registration, record keeping, reporting, and import/export requirements regardless

of the quantity being handled or distributed.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid is a colorless oily liquid that emits a SOUR odor.

– There is an extreme fire and explosion hazard if the hypophosphorous acid

comes into contact with a solvent such as acetone, toluene, or Coleman fuel.

• Hypophosphorous acid will also emit phosphine gas and the fumes can ignite.

Hypophosphorous Acid (H3PO2) (Continued)

• Although hypophosphorous acid is a List I chemical under the Controlled Substances Act, methamphetamine producers typically purchase the chemical via

the internet or from associates who also are engaged in methamphetamine

production.

– The use of hypophosphorous acid in methamphetamine production is an

EXTREMELY DANGEROUS PRACTICE because of the deadly gases that can be generated as well as the risk of fire or explosion.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid (H3PO2, also called phosphinic acid) is a strong acid that

typically is prepared as a solution of colorless, oily liquid in strengths of 50%, 30 to 32%, and 10%.

– It also is prepared in the form of salts (referred to as hypophosphite salts), particularly ammonium hypophosphite, calcium hypophosphite, iron (ferric)

hypophosphite, magnesium hypophosphite, manganese hypophosphite,

potassium hypophosphite, and sodium hypophosphite.

Hypophosphorous Acid (H3PO2) (Continued)

• Over 100 chemical firms located throughout the world produce hypophosphorous

acid.

– The People's Republic of China and India have the largest numbers of

hypophosphorous acid producers, although there are a few producers in the United States.

• There are a wide variety of uses for hypophosphorous acid and its salts in

commercial industry; however, the chemicals have no legitimate household or retail uses.

Hypophosphorous Acid (H3PO2) (Continued)

• The legitimate commercial and laboratory fields that use hypophosphorous acid and its salts include the following:

– Chemical plating

– Food preparation

– Water treatment

– Polymers (as a bleaching agent, color stabilizer, or catalyst)

– Education and research in analytical chemistry

Hypophosphorous Acid (H3PO2) (Continued)

• Chemical suppliers typically distribute hypophosphorous acid in large quantities, for example, in drums containing 275 pounds of the diluted solution.

– Hypophosphorous acid also is distributed in smaller quantities.

• One-half liter of 50% concentrate hypophosphorous acid solution can be obtained from chemical suppliers for as little as $14.

Hypophosphorous Acid (H3PO2) (Continued)

• Methamphetamine laboratory operators typically obtain small quantities of the chemical from other laboratory operators who purchase large quantities of the

chemical and repackage it for further distribution.

– According to law enforcement sources, these individuals sell hypophosphorous acid for as much as $1,000 per half-liter.

•Methamphetamine laboratory operators also purchase hypophosphorous acidvia the internet.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid and the Internet

• The internet is a source of a great deal of information regarding hypophosphorous acid.

• Popular internet sites that disseminate information about illicit drugs contain information about the chemical, including numerous recipes for home production of

methamphetamine using hypophosphorous acid.

• There also are recipes for synthesizing hypophosphorous acid from available chemicals.

• Hypophosphorous acid solutions and salts have been sold to the general public via the internet.

• The Drug Enforcement Administration (DEA) has strong concerns regarding the sale

of chemicals on the internet and has requested that any sites (such as auction sites) that allow the sale of regulated chemicals on their domains require proof of

DEA registration from their clients.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid Used in Methamphetamine Production

• Hypophosphorous acid is used in the ephedrine-pseudoephedrine reduction method of methamphetamine production.

– It is used in the methamphetamine production process to produce hydriodic acid,

an important reagent (it reacts with the ephedrine-pseudoephedrine but does NOT become part of the finished product).

Hypophosphorous Acid (H3PO2) (Continued)

• The regulation of hydriodic acid by DEA in 1993 rendered it virtually unavailable in

the United States.

– However, methamphetamine laboratory operators discovered methods to

produce hydriodic acid using a combination of iodine in water with red phosphorus.

• Laboratory operators found that red phosphorus could be obtained easily, either from commercial supply companies or by scraping the striker pads from matchbooks or matchboxes.

• Methamphetamine producers soon discovered that hypophosphorous acid ALSO could be used in combination with iodine and water to produce hydriodic acid.

Hypophosphorous Acid (H3PO2) (Continued)

• The practice of using hypophosphorous acid in methamphetamine production is

believed to have begun in the United States in the late 1990s when a methamphetamine producer in Colorado obtained the recipe from Australia, where

the hypophosphorous acid method is prevalent.

– This man was known as a serial cook who had a long history of

methamphetamine production.

•Over several years he trained other laboratory operators in Colorado to produce methamphetamine using hypophosphorous acid.

• As his techniques were passed on to others, the number of methamphetaminelaboratories in Colorado using hypophosphorous acid continued to increase, and the

technique was passed on to numerous methamphetamine producers in other

states.

Hypophosphorous Acid (H3PO2) (Continued)

• According to the El Paso Intelligence Center (EPIC) National Clandestine Laboratory

Seizure System, from 2000 through 2002 the number of seized methamphetaminelaboratories in the United States in which hypophosphorous acid was found

increased overall. (See Table 1.)

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid found at methamphetamine laboratories is packaged in a variety of ways.

• The chemical has been found in 1-gallon bottles of solution or in 1-pound jars of salts.

• Some hypophosphorous acid containers are labeled as "plating solution."

• Pint-sized brown glass bottles wrapped in red electrical tape also have been found to contain hypophosphorous acid; they have been discovered primarily in Colorado.

• The vast majority of hypophosphorous acid found at laboratory sites has been recovered from small toxic laboratories (STLs), those which yield gram to ounce

quantities per production cycle.

• Hypophosphorous acid has not been reported at large-scale laboratories operated by Mexican criminal groups in the United States.

Hypophosphorous Acid (H3PO2) (Continued)

• Hazards

• The iodine-hypophosphorous acid method is MORE HAZORDOUS than the iodine-

red phosphorus method, although the reaction using hypophosphorous acid is

faster and gives slightly higher yields.

– When hypophosphorous acid is used, the chemicals must be mixed together

SLOWLY in a PARTICULAR ORDER to prevent them from reacting violently.

Hypophosphorous Acid (H3PO2) (Continued)

• The combination of hypophosphorous acid with the other chemicals and with

certain metals can produce deadly phosphine gas during the initial mixing step and

can CONTINUE to produce phosphine gas for several days AFTER production has been completed…

Hypophosphorous Acid (H3PO2) (Continued)

• The iodine-hypophosphorous acid mixture has a tendency to decompose quickly when overheated or if heated for long periods of time, becoming cloudy or "milky-

white" just prior to giving off a cloud of phosphine gas that can ignite spontaneously.

– Hypophosphorous acid solutions may become unstable if evaporation results in

concentrations above 50%.

Hypophosphorous Acid (H3PO2) (Continued)

• [Note: Law enforcement or emergency personnel who encounter suspected

containers of hypophosphorous acid should use extreme care during handling because laboratory operators often attempt to obtain a more concentrated acid by

allowing water to evaporate from the mixture.]

• Because hypophosphorous acid often is used at small methamphetaminelaboratories operated by inexperienced or careless individuals, the potential hazards

of using this method are even greater.

• The risk of fire and explosion is higher in these laboratories, where professional

laboratory equipment typically is not used to contain the phosphine gas and where

safe handling precautions are not employed.

• In addition, these laboratories often are located in homes where children are

present and may come into contact with hypophosphorous acid.

• A child can easily mistake hypophosphorous acid for any other clear liquid,

particularly if it is stored in household containers or drinking glasses.

• Skin, eye, or inhalation exposure can be extremely harmful or fatal.

Hypophosphorous Acid (H3PO2) (Continued)

• Safety Precautions

• Always wear a self-contained breathing apparatus as well as protective clothing when entering areas where hypophosphorous acid may be present.

• When in contact with metals or in a high-temperature environment, hypophosphorous acid can break down and liberate phosphine and flammable hydrogen gas.

• Do not allow the use of open flames, open lights, matches, or smoking in or around laboratories or dumpsites where hypophosphorous acid is handled.

• In case of fire, use a self-contained positive pressure breathing apparatus and full

protective equipment.

• Use water spray, fog, foam, dry chemicals, or other reagents as may be

appropriate for materials in the surrounding fire.

• Water may be used to cool the containers of hypophosphorous acid; however, use extreme care to avoid allowing water to enter the container.

• In case of spills, neutralize the spilled chemical with alkaline material (soda ash, lime), then absorb it with an inert material such as vermiculite, dry sand, or earth and place in a chemical waste container.

• Do not use combustible materials such as sawdust.

Hypophosphorous Acid (H3PO2) (Continued)

• Legislation and Control

• In the United States hypophosphorous acid is one of 38 chemicals (or groups of

chemicals) controlled under law by DEA.

• On October 17, 2001, hypophosphorous acid and its salts, along with red and white phosphorus, were officially added as List I chemicals under section 1310 of the

Code of Federal Regulations.

• List I chemicals are defined as chemicals that are used in the manufacture of a

controlled substance in violation of the Controlled Substances Act (CSA) and are

important to the manufacture of a controlled substance.

• Under the law, suppliers are required to maintain records and report receipts, sales,

imports, and exports of these chemicals to DEA.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid, red phosphorus, and white phosphorus, as well as

ephedrine, are unique in that suppliers are required to report all transactions of

these chemicals, regardless of the amount.

• By contrast, the other 34 listed chemicals are only reportable after a supplier's

transactions for a chemical reach an established weight or volume threshold in a calendar month.

• In addition to reporting all transactions involving the chemical, suppliers are

expected to "know their customers" in order to prevent the diversion of these substances to methamphetamine laboratories, as it is illegal to import, export,

purchase, or sell hypophosphorous acid or any other listed chemical in the United States if it is used or intended to be used in the production of a controlled

substance.

• Chemical suppliers are held liable for selling listed chemicals if they know or suspect that the chemical will be used for illicit purposes.

Hypophosphorous Acid (H3PO2) (Continued)

• Outlook

• The use of hypophosphorous acid in the production of methamphetamine is likely

to increase, particularly in the Midwest and Southwest regions of the United States

where methamphetamine production is prevalent.

– Injuries, property damage, and deaths also will increase as a growing number of

inexperienced methamphetamine producers experiment with hypophosphorous acid.

Anhydrous Ammonia

• Anhydrous ammonia is found in fertilizer, countertop cleaner, and commercial refrigerant.

– On its own, it has a pungent, suffocating odor.

• Mixing anhydrous ammonia with other chemicals can release highly toxic gases.

– Because anhydrous ammonia seeks out water (anhydrous means “without

water”) and causes severe burns, any body part that comes into contact with it

should be flushed with water for at least 15 minutes to remove the ammoniafrom the skin.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia has extremely destructive effects on humans.

– Anhydrous ammonia gives off vapors during cooking that can burn the mouth,

throat, and lung tissue.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Anhydrous ammonia seeks water from the nearest source, including the human body (anhydrous means “without water”).

– Because of their high moisture content, EYES, LUNGS, and SKIN are at the

greatest risk of attracting the ammonia.

• When large amounts of anhydrous ammonia are inhaled, the throat swells and the

victim suffocates.

– Exposure to the vapors or liquids can cause severe burns, blindness, or death.

• Anhydrous ammonia has an IDLH (immediately dangerous to life and health) at

only 300 parts per million...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is poses MANY hazards, especially when it is placed in improper vessels and handled/transported by individuals unfamiliar with the dangers.

• Anhydrous ammonia has a boiling point of -28 degrees below zero.

– When a vessel containing anhydrous ammonia is MOVED, the anhydrous

ammonia will reach its boiling point and pressurize.

•This pressurization can cause vessels to violently RUPTURE, or if the vessel pressurizes and does NOT rupture, the opening of the container of anhydrous

ammonia at a later time can cause RAPID, VIOLENT depressurization.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is mainly used in the U.S. as either a fertilizer or a refrigerant.

– Meth producers tend to store the anhydrous ammonia in IMPROPER/UNAPPROVED containers such as:

•Propane tanks,

• Igloo coolers, or

•Fire extinguishers.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia leaves a tell-tell sign as it flows through these UNAPPROVED

CONTAINERS – a blue or blue green discoloration on the valve.

– PAY ATTENTION to details!!!

Anhydrous Ammonia (Continued)

• Because propane cylinders (and the other unapproved containers) are NOT designed to store anhydrous ammonia, they can EXPLODE as the ammonia eats through the walls of the cylinders.

– The valves, which take on a bluish/green color, frequently deteriorate and can cause hazardous leaks!!!

Anhydrous Ammonia (Continued)

• Do NOT touch, move, or open any kind of tank or sealed container!!!

– Be aware that propane tanks are often WEAKENED and BRITTLE due to the

anhydrous ammonia and are SENSITIVE to ANY kind of movement or impact.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• These pictures show what happened to a fire extinguisher that was used to store

anhydrous ammonia…

Anhydrous Ammonia (Continued)

• Illegal drug makers often STEAL anhydrous ammonia from areas where it is stored

and used, such as farms.

• Attempted thefts have also occurred at places such as:

– Refrigeration systems holding ammonia,

– Underground pipelines carrying ammonia, and

– Rail cars transporting anhydrous ammonia.

• Often thefts are aborted when thieves are injured or overcome by the toxic gas...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia thieves had better beware!!!

• There is a new product called GloTell that farmers can add to their anhydrous

ammonia tanks…

• Meth cooks will run the risk that the GloTell additive will turn their hands bright pink!

– This bright pink stain will fluoresce under ultraviolet light even if washed off!!!

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Also, GloTell will produce pink methamphetamine that CANNOT be bleached.

– Users who snort meth made with GloTell will find that they have PINK NOSES!

– Users who inject meth made with GloTell will see a pink stain at the point of

injection!

Sodium Carbonate (Soda Ash)

Sodium Carbonate (Soda Ash) (Continued)

Lead Acetate

Iodine

• Iodine is a natural element, and it is helpful to the body in SMALL amounts.

– However, if iodine is taken in large amounts it can become toxic.

•Extremely high does of iodine can limit the function of the thyroid.

Iodine (Continued)

Iodine (Continued)

• Iodine is bluish-black, and it has a characteristic odor, a sharp acrid taste, and it produces a violet corrosive vapor.

– The vapor is irritating to the respiratory system and eyes.

• The solid iodine irritates the eyes and may burn the skin, and it may cause severe

internal irritation and damage if ingested.

Iodine (Continued)

• Iodine is known as the “blue ingredient” in the production of meth (in the “red, white, and blue” method).

Iodine (Continued)

Iodine (Continued)

• It takes approximately 4 bottles of iodine tincture to produce 2 – 3 grams of meth.

Iodine (Continued)

Iodine (Continued)

• Iodine leaves distinctive yellow-blue or brown stains on surfaces in former methlabs.

Iodine (Continued)

Iodine (Continued)

Iodine (Continued)

• The only good thing about iodine is that it leaves yellow stains.

• If you see yellow stained coffee filters, gloves or paper towels, this could be an

indicator that you’re in a lab.

• If you see yellow stains, you can spray some starch on them.

– If they turn a purplish blue/black, it’s iodine.

• Iodine is the only substance that reacts with soluble starch to produce a purplish black color.

– The only way to get iodine vapor all over the walls is to cook meth.

Mercurous Chloride

Rock Salt

Hydrogen Chloride

• Hydrogen chloride gas is commercially available.

• Hydrogen chloride gas can also be made by mixing sulfuric acid and salt.

• Muriatic acid is simply hydrogen chloride gas suspended in water.

• Hydrogen chloride gas can be seen as a pale white smoke.

– It is a poisonous gas that can cause respiratory problems and death.

Hydrogen Chloride (Continued)

Ammonium Nitrate

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Hydriodic Acid

• Hydriodic acid is a corrosive acid that is colorless when freshly prepared.

– When hydriodic acid is exposed to light and air, it turns yellowish and brown.

• Hydriodic acid is a solution of hydrogen iodide gas in water.

• Hydriodic acid vapor is irritating to the respiratory system, skin, and eyes.

• Hydriodic acid liquid causes severe burns to the eyes and skin.

• If hydriodic acid is accidentally ingested, it can cause severe internal irritation and

damage.

Hydriodic Acid (Continued)

Catalyst Chemicals

• Catalyst Chemicals:

– Chemicals which SPEED UP a reaction process and/or cause it to go to GREATER COMPLETION.

Red Phosphorus

• Red phosphorus is found ON matchboxes, in road flares, and other explosives.

– Red Phosphorus IGNITES when OVERHEATED!!!

• By combining red phosphorus and iodine, you can easily create the highly

controlled substance known as hydriodic acid (which is an essential ingredient in making meth).

– Creating 2 – 3 grams of meth requires about 4 big boxes of matches.

Red Phosphorus (Continued)

• Red phosphorous is highly flammable and if it is overheated it can become white

phosphorous…

– White phosphorous is a volatile and highly explosive substance.

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Lithium

• Lithium is used in batteries.

• Lithium seriously burns the skin upon contact.

– It also reacts VIOLENTLY with WATER and is highly explosive.

Lithium (Continued)

• Lithium reacts VIOLENTLY with WATER, and if it is splashed in the eyes during

cooking it will cause blindness.

– Lithium is extremely caustic to all body tissues.

Lithium (Continued)

Lithium (Continued)

• Lithium metal is HIGHLY water reactive and it will BURN or EXPLODE if it comes into contact with WATER!

• Because of the moisture in your skin, it will burn exposed flesh.

• Lithium metal will DEGRADE when exposed to atmospheric moisture…

– This is why meth cooks store lithium metal in a solvent prior to use.

• It is typical to see harvested lithium strips in Coleman fuel or Mineral Spirits to prevent explosions.

•Large quantities can be harvested and saved in these containers until needed

for a cook.

Lithium (Continued)

• If you see battery shells in the trashcan, on the floor, etc. – this is a VERY GOOD

indicator that you might be entering a meth lab!

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

• Lithium catches fire when in contact with water...

Solvent Chemicals

• Solvent Chemicals:

– A medium (liquid) in which a chemical operation takes place.

• Solvent chemicals (UNLIKE the precursor chemicals) CAN be substituted/interchanged.

Ether

• Ether was once called “sweet vitriol” because of its hypnotic effect.

• Ether is a highly flammable substance that is used as an anesthetic agent –

especially in third world countries where more expensive anesthesia is not available.

– While inhaling the ether, patients could undergo complete surgical procedures while otherwise awake without feeling pain or concern.

Ether (Continued)

• Ether can be obtained from engine starting fluid.

• Ether is a solvent and it is flammable.

– It is particularly hazardous because it can cause BOTH fire and explosion.

• It has been said that a quart of ether can “level” a small house.

Ethyl Ether (Continued)

Ethyl Ether (Continued)

• Ether is VERY flammable and is HEAVIER than air.

– NEVER use ether near flames or non-sparkless motors.

– Ether is very PUNGENT – even a small evaporated amount of ether is VERY noticeable.

Acetone

• Acetone can be found in nail polish remover or paint thinner.

– It is extremely flammable.

• In the setting of a meth lab where meth is being cooked with high heat, acetone is

very dangerous.

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Toluene

• Toluene is used in brake fluid.

– When working with brake fluid (toluene), be careful not to spill it on your car

because it will eat away the paint and chrome…

• You also have to be careful using toluene around other household chemicals

because its high concentration of polyethylene glycol can cause it to ignite in a violent fireball.

• Toluene is powerful enough to dissolve rubber.

Toluene (Continued)

• Toluene is used to form meth crystals.

– The fumes toluene releases can cause brain damage or death.

Toluene (Continued)

Toluene (Continued)

Ethanol

Isopropanol

Isopropanol (Continued)

Isopropyl Alcohol

Methanol

Methanol (Continued)

Methanol (Continued)

Benzene

Benzene (Continued)

Which of these is NOT a common ingredient in Meth?

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Methamphetamine- PowerPoint

- Chemicals and Ingredients Used to Make Meth

CJUS 240

Economic Costs of Meth

• The economic cost of methamphetamine use in the U.S. reached $23.4 billion in

2005.

– This includes the burden of addiction, premature death, drug treatment, child

care, and cleaning of lab sites.

– This figure does NOT take into account the future needs of the meth user.

Concerns with ACTIVE Meth Labs

• Danger of fire and explosion

• Chemical spills

• Inhalation of solvents, corrosives, and toxic gases

• “Booby traps”

• Waste disposal

Concerns with FORMER Meth Labs

• Vapors

• Chemical residues

• Methamphetamine residues

• Waste disposal

Equipment Used in Meth Production

• Pyrex or Corning dishes

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

• Coffee Filters

Equipment Used in Meth Production

Equipment Used in Meth Production

Basic Chemical Requirements

• In a clandestine laboratory, basic types of chemicals are necessary in order to

produce the desired drug.

– The basic types of chemicals needed are:

1) Precursor Chemicals

2) Reagent Chemicals

3) Catalyst Chemicals

4) Solvent Chemicals

List I Chemical

• The term “List I chemical” means a chemical specified by regulation of the Attorney General as a chemical that is used in manufacturing a controlled substance and is

IMPORTANT to the manufacture of the controlled substance.

• Examples of List I chemicals are:

– GBL

– Red Phosphorus

– Pseudoephedrine

List II Chemical

• The term “List II chemical” means a chemical (other than a List I chemical) specified by regulation of the Attorney General as a chemical that is USED in

manufacturing a controlled substance.

• Examples of List II chemicals are:

– Toluene

– Iodine

– Hydrochloric Acid

Precursor Chemicals

• Precursor Chemicals:

– A chemical that is ESSENTIAL to the production of a controlled substance and for

which NO SUBSTITUTION can be made.

Pseudoephedrine

• Pseudoephedrine is a decongestant found in cold medicine.

– Large amounts of pseudoephedrine on its own can harm the respiratory and nervous systems, as well as the heart.

Pseudoephedrine (Continued)

• Some of the common ways used to divert products containing pseudoephedrine

include:

– “Smurfing” – making multiple purchases at different locations

– Shelf-Sweeping – the theft of all shelf stock

– Shoplifting

– Theft from wholesalers

Pseudoephedrine (Continued)

• Pseudoephedrine smurfing is a method used by some methamphetamine producers to acquire large quantities of pseudoephedrine by enlisting the assistance of several

friends or associates (often referred to as “smurfers”) to make purchases at or below the legal thresholds from multiple retail locations.

– Smurfers are often addicts who trade the pseudoephedrine for finished

methamphetamine.

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

• About 680 pseudoephedrine tablets are needed to produce one ounce of meth…

Pseudoephedrine (Continued)

Out With a Bang

An Unstable Recipe…

• Meth contains a variety of poisonous ingredients…

– Some become EVEN MORE DANGEROUS once the cooking process begins…

Common Ingredients to Make Methamphetamine

Reagent Chemicals

• Reagent Chemicals:

– Chemicals which REACT upon the precursor chemical causing it to chemicallyCHANGE.

• A reagent chemical is a chemical which is required for the synthesis of an illicit drug substance, but which is NOT incorporated into the final chemical product.

Hydrochloric Acid

• Hydrochloric acid is a highly corrosive liquid that is used to make plastic (such as PVC pipe and polyurethane).

– It can remove rust and iron-oxide from steel and is highly corrosive to human

skin.

•Hydrochloric acid makes up the majority of the gastric acid in the human

digestive fluid.

• In high concentrations, hydrochloric acid will literally eat away human flesh…

Hydrochloric Acid (Continued)

• Hydrochloric acid can be purchased from hardware stores as:

– Tile and Grout Acid Cleaner

– Muriatic Acid

– Pool Acid

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

• Hydrochloric acid is a solution of hydrogen chloride gas suspended in water.

– Hydrochloric acid is corrosive and is a light yellow liquid color from traces of iron, chlorine, and organic matter.

• Inhaling hydrochloric acid may cause coughing or choking, inflammation, and

ulceration of the respiratory tract.

• Concentrated solutions of hydrochloric acid can cause severe burns and irritate the

mucous membranes, eyes, and respiratory tract.

– Exposure to hydrochloric acid vapors may result in pulmonary edema and

possibly death.

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

Sodium Hydroxide (NaOH)

• Sodium hydroxide is also called Lye.

• Sodium hydroxide is classified as a corrosive, and it is one of the main chemicals in

drain cleaner.

– It is also used in aluminum etching and to create biodiesal.

– It can burn the skin or cause blindness.

• Sodium hydroxide is used to dispose of road kill because it turns the dead bodies

into a coffee-like liquid.

Sodium Hydroxide (NaOH) (Continued)

• Drain cleaner (sodium hydroxide) is extremely corrosive, and without wearing

protection, even the smallest spill on the skin can eat through flesh…

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sulfuric Acid (H2SO4)

• Sulfuric acid is used in drain or toilet bowl cleaner as well as battery acid.

– It is another highly corrosive substance that burns the skin on contact.

Sulfuric Acid (H2SO4) (Continued)

• The product label warning for Drano® (sulfuric acid) says it all:

– DANGER: MAY BURN EYES AND SKIN ON CONTACT.

•HARMFUL IF SWALLOWED.

–Avoid contact with body and clothing.

•TOXIC GAS MAY FORM IF MIXED WITH OTHER CHEMICALS.

–If gases are released, leave immediately and ventilate area.

•FIRST AID: Give Immediately:

–EYES AND SKIN:

»Flush with water for 20 minutes.

»Remove affected clothing.

–IF SWALLOWED:

»Rinse mouth and drink a glass of water or milk.

»Do not induce vomiting.

–THEN SEEK MEDICAL AID.

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Hypophosphorous Acid (H3PO2)

• Hypophosphorous acid, which is used legally for a variety of commercial purposes,

is a chemical that increasingly is substituted for red phosphorus in the methamphetamine production process.

– The use of hypophospherous acid SIGNIFICANTLY increases the risk of fire!!!

• The federal government regulates the sale of hypophosphorous acid through registration, record keeping, reporting, and import/export requirements regardless

of the quantity being handled or distributed.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid is a colorless oily liquid that emits a SOUR odor.

– There is an extreme fire and explosion hazard if the hypophosphorous acid

comes into contact with a solvent such as acetone, toluene, or Coleman fuel.

• Hypophosphorous acid will also emit phosphine gas and the fumes can ignite.

Hypophosphorous Acid (H3PO2) (Continued)

• Although hypophosphorous acid is a List I chemical under the Controlled Substances Act, methamphetamine producers typically purchase the chemical via

the internet or from associates who also are engaged in methamphetamine

production.

– The use of hypophosphorous acid in methamphetamine production is an

EXTREMELY DANGEROUS PRACTICE because of the deadly gases that can be generated as well as the risk of fire or explosion.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid (H3PO2, also called phosphinic acid) is a strong acid that

typically is prepared as a solution of colorless, oily liquid in strengths of 50%, 30 to 32%, and 10%.

– It also is prepared in the form of salts (referred to as hypophosphite salts), particularly ammonium hypophosphite, calcium hypophosphite, iron (ferric)

hypophosphite, magnesium hypophosphite, manganese hypophosphite,

potassium hypophosphite, and sodium hypophosphite.

Hypophosphorous Acid (H3PO2) (Continued)

• Over 100 chemical firms located throughout the world produce hypophosphorous

acid.

– The People's Republic of China and India have the largest numbers of hypophosphorous acid producers, although there are a few producers in the United States.

• There are a wide variety of uses for hypophosphorous acid and its salts in

commercial industry; however, the chemicals have no legitimate household or retail uses.

Hypophosphorous Acid (H3PO2) (Continued)

• The legitimate commercial and laboratory fields that use hypophosphorous acid and its salts include the following:

– Chemical plating

– Food preparation

– Water treatment

– Polymers (as a bleaching agent, color stabilizer, or catalyst)

– Education and research in analytical chemistry

Hypophosphorous Acid (H3PO2) (Continued)

• Chemical suppliers typically distribute hypophosphorous acid in large quantities, for example, in drums containing 275 pounds of the diluted solution.

– Hypophosphorous acid also is distributed in smaller quantities.

• One-half liter of 50% concentrate hypophosphorous acid solution can be obtained from chemical suppliers for as little as $14.

Hypophosphorous Acid (H3PO2) (Continued)

• Methamphetamine laboratory operators typically obtain small quantities of the chemical from other laboratory operators who purchase large quantities of the

chemical and repackage it for further distribution.

– According to law enforcement sources, these individuals sell hypophosphorous acid for as much as $1,000 per half-liter.

•Methamphetamine laboratory operators also purchase hypophosphorous acidvia the internet.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid and the Internet

• The internet is a source of a great deal of information regarding hypophosphorous acid.

• Popular internet sites that disseminate information about illicit drugs contain information about the chemical, including numerous recipes for home production of

methamphetamine using hypophosphorous acid.

• There also are recipes for synthesizing hypophosphorous acid from available chemicals.

• Hypophosphorous acid solutions and salts have been sold to the general public via the internet.

• The Drug Enforcement Administration (DEA) has strong concerns regarding the sale

of chemicals on the internet and has requested that any sites (such as auction sites) that allow the sale of regulated chemicals on their domains require proof of

DEA registration from their clients.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid Used in Methamphetamine Production

• Hypophosphorous acid is used in the ephedrine-pseudoephedrine reduction method

of methamphetamine production.

– It is used in the methamphetamine production process to produce hydriodic acid,

an important reagent (it reacts with the ephedrine-pseudoephedrine but does NOT become part of the finished product).

Hypophosphorous Acid (H3PO2) (Continued)

• The regulation of hydriodic acid by DEA in 1993 rendered it virtually unavailable in

the United States.

– However, methamphetamine laboratory operators discovered methods to

produce hydriodic acid using a combination of iodine in water with red phosphorus.

• Laboratory operators found that red phosphorus could be obtained easily, either

from commercial supply companies or by scraping the striker pads from matchbooks or matchboxes.

• Methamphetamine producers soon discovered that hypophosphorous acid ALSO could be used in combination with iodine and water to produce hydriodic acid.

Hypophosphorous Acid (H3PO2) (Continued)

• The practice of using hypophosphorous acid in methamphetamine production is

believed to have begun in the United States in the late 1990s when a methamphetamine producer in Colorado obtained the recipe from Australia, where

the hypophosphorous acid method is prevalent.

– This man was known as a serial cook who had a long history of

methamphetamine production.

•Over several years he trained other laboratory operators in Colorado to produce methamphetamine using hypophosphorous acid.

• As his techniques were passed on to others, the number of methamphetaminelaboratories in Colorado using hypophosphorous acid continued to increase, and the

technique was passed on to numerous methamphetamine producers in other

states.

Hypophosphorous Acid (H3PO2) (Continued)

• According to the El Paso Intelligence Center (EPIC) National Clandestine Laboratory

Seizure System, from 2000 through 2002 the number of seized methamphetaminelaboratories in the United States in which hypophosphorous acid was found

increased overall. (See Table 1.)

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid found at methamphetamine laboratories is packaged in a variety of ways.

• The chemical has been found in 1-gallon bottles of solution or in 1-pound jars of salts.

• Some hypophosphorous acid containers are labeled as "plating solution."

• Pint-sized brown glass bottles wrapped in red electrical tape also have been found to contain hypophosphorous acid; they have been discovered primarily in Colorado.

• The vast majority of hypophosphorous acid found at laboratory sites has been recovered from small toxic laboratories (STLs), those which yield gram to ounce

quantities per production cycle.

• Hypophosphorous acid has not been reported at large-scale laboratories operated by Mexican criminal groups in the United States.

Hypophosphorous Acid (H3PO2) (Continued)

• Hazards

• The iodine-hypophosphorous acid method is MORE HAZORDOUS than the iodine-

red phosphorus method, although the reaction using hypophosphorous acid is

faster and gives slightly higher yields.

– When hypophosphorous acid is used, the chemicals must be mixed together

SLOWLY in a PARTICULAR ORDER to prevent them from reacting violently.

Hypophosphorous Acid (H3PO2) (Continued)

• The combination of hypophosphorous acid with the other chemicals and with

certain metals can produce deadly phosphine gas during the initial mixing step and

can CONTINUE to produce phosphine gas for several days AFTER production has been completed…

Hypophosphorous Acid (H3PO2) (Continued)

• The iodine-hypophosphorous acid mixture has a tendency to decompose quickly when overheated or if heated for long periods of time, becoming cloudy or "milky-white" just prior to giving off a cloud of phosphine gas that can ignite spontaneously.

– Hypophosphorous acid solutions may become unstable if evaporation results in

concentrations above 50%.

Hypophosphorous Acid (H3PO2) (Continued)

• [Note: Law enforcement or emergency personnel who encounter suspected

containers of hypophosphorous acid should use extreme care during handling because laboratory operators often attempt to obtain a more concentrated acid by

allowing water to evaporate from the mixture.]

• Because hypophosphorous acid often is used at small methamphetaminelaboratories operated by inexperienced or careless individuals, the potential hazards of using this method are even greater.

• The risk of fire and explosion is higher in these laboratories, where professional

laboratory equipment typically is not used to contain the phosphine gas and where

safe handling precautions are not employed.

• In addition, these laboratories often are located in homes where children are

present and may come into contact with hypophosphorous acid.

• A child can easily mistake hypophosphorous acid for any other clear liquid,

particularly if it is stored in household containers or drinking glasses.

• Skin, eye, or inhalation exposure can be extremely harmful or fatal.

Hypophosphorous Acid (H3PO2) (Continued)

• Safety Precautions

• Always wear a self-contained breathing apparatus as well as protective clothing when entering areas where hypophosphorous acid may be present.

• When in contact with metals or in a high-temperature environment,

hypophosphorous acid can break down and liberate phosphine and flammable hydrogen gas.

• Do not allow the use of open flames, open lights, matches, or smoking in or around laboratories or dumpsites where hypophosphorous acid is handled.

• In case of fire, use a self-contained positive pressure breathing apparatus and full

protective equipment.

• Use water spray, fog, foam, dry chemicals, or other reagents as may be

appropriate for materials in the surrounding fire.

• Water may be used to cool the containers of hypophosphorous acid; however, use extreme care to avoid allowing water to enter the container.

• In case of spills, neutralize the spilled chemical with alkaline material (soda ash, lime), then absorb it with an inert material such as vermiculite, dry sand, or earth

and place in a chemical waste container.

• Do not use combustible materials such as sawdust.

Hypophosphorous Acid (H3PO2) (Continued)

• Legislation and Control

• In the United States hypophosphorous acid is one of 38 chemicals (or groups of

chemicals) controlled under law by DEA.

• On October 17, 2001, hypophosphorous acid and its salts, along with red and white phosphorus, were officially added as List I chemicals under section 1310 of the

Code of Federal Regulations.

• List I chemicals are defined as chemicals that are used in the manufacture of a

controlled substance in violation of the Controlled Substances Act (CSA) and are

important to the manufacture of a controlled substance.

• Under the law, suppliers are required to maintain records and report receipts, sales,

imports, and exports of these chemicals to DEA.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid, red phosphorus, and white phosphorus, as well as

ephedrine, are unique in that suppliers are required to report all transactions of

these chemicals, regardless of the amount.

• By contrast, the other 34 listed chemicals are only reportable after a supplier's

transactions for a chemical reach an established weight or volume threshold in a calendar month.

• In addition to reporting all transactions involving the chemical, suppliers are

expected to "know their customers" in order to prevent the diversion of these substances to methamphetamine laboratories, as it is illegal to import, export,

purchase, or sell hypophosphorous acid or any other listed chemical in the United States if it is used or intended to be used in the production of a controlled

substance.

• Chemical suppliers are held liable for selling listed chemicals if they know or suspect that the chemical will be used for illicit purposes.

Hypophosphorous Acid (H3PO2) (Continued)

• Outlook

• The use of hypophosphorous acid in the production of methamphetamine is likely

to increase, particularly in the Midwest and Southwest regions of the United States

where methamphetamine production is prevalent.

– Injuries, property damage, and deaths also will increase as a growing number of

inexperienced methamphetamine producers experiment with hypophosphorous acid.

Anhydrous Ammonia

• Anhydrous ammonia is found in fertilizer, countertop cleaner, and commercial refrigerant.

– On its own, it has a pungent, suffocating odor.

• Mixing anhydrous ammonia with other chemicals can release highly toxic gases.

– Because anhydrous ammonia seeks out water (anhydrous means “without

water”) and causes severe burns, any body part that comes into contact with it

should be flushed with water for at least 15 minutes to remove the ammoniafrom the skin.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia has extremely destructive effects on humans.

– Anhydrous ammonia gives off vapors during cooking that can burn the mouth,

throat, and lung tissue.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Anhydrous ammonia seeks water from the nearest source, including the human body (anhydrous means “without water”).

– Because of their high moisture content, EYES, LUNGS, and SKIN are at the

greatest risk of attracting the ammonia.

• When large amounts of anhydrous ammonia are inhaled, the throat swells and the

victim suffocates.

– Exposure to the vapors or liquids can cause severe burns, blindness, or death.

• Anhydrous ammonia has an IDLH (immediately dangerous to life and health) at

only 300 parts per million...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is poses MANY hazards, especially when it is placed in improper vessels and handled/transported by individuals unfamiliar with the

dangers.

• Anhydrous ammonia has a boiling point of -28 degrees below zero.

– When a vessel containing anhydrous ammonia is MOVED, the anhydrous

ammonia will reach its boiling point and pressurize.

•This pressurization can cause vessels to violently RUPTURE, or if the vessel pressurizes and does NOT rupture, the opening of the container of anhydrous

ammonia at a later time can cause RAPID, VIOLENT depressurization.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is mainly used in the U.S. as either a fertilizer or a refrigerant.

– Meth producers tend to store the anhydrous ammonia in IMPROPER/UNAPPROVED containers such as:

•Propane tanks,

• Igloo coolers, or

•Fire extinguishers.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia leaves a tell-tell sign as it flows through these UNAPPROVED

CONTAINERS – a blue or blue green discoloration on the valve.

– PAY ATTENTION to details!!!

Anhydrous Ammonia (Continued)

• Because propane cylinders (and the other unapproved containers) are NOT designed to store anhydrous ammonia, they can EXPLODE as the ammonia eats

through the walls of the cylinders.

– The valves, which take on a bluish/green color, frequently deteriorate and can cause hazardous leaks!!!

Anhydrous Ammonia (Continued)

• Do NOT touch, move, or open any kind of tank or sealed container!!!

– Be aware that propane tanks are often WEAKENED and BRITTLE due to the

anhydrous ammonia and are SENSITIVE to ANY kind of movement or impact.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• These pictures show what happened to a fire extinguisher that was used to store

anhydrous ammonia…

Anhydrous Ammonia (Continued)

• Illegal drug makers often STEAL anhydrous ammonia from areas where it is stored

and used, such as farms.

• Attempted thefts have also occurred at places such as:

– Refrigeration systems holding ammonia,

– Underground pipelines carrying ammonia, and

– Rail cars transporting anhydrous ammonia.

• Often thefts are aborted when thieves are injured or overcome by the toxic gas...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia thieves had better beware!!!

• There is a new product called GloTell that farmers can add to their anhydrous

ammonia tanks…

• Meth cooks will run the risk that the GloTell additive will turn their hands bright

pink!

– This bright pink stain will fluoresce under ultraviolet light even if washed off!!!

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Also, GloTell will produce pink methamphetamine that CANNOT be bleached.

– Users who snort meth made with GloTell will find that they have PINK NOSES!

– Users who inject meth made with GloTell will see a pink stain at the point of

injection!

Sodium Carbonate (Soda Ash)

Sodium Carbonate (Soda Ash) (Continued)

Lead Acetate

Iodine

• Iodine is a natural element, and it is helpful to the body in SMALL amounts.

– However, if iodine is taken in large amounts it can become toxic.

•Extremely high does of iodine can limit the function of the thyroid.

Iodine (Continued)

Iodine (Continued)

• Iodine is bluish-black, and it has a characteristic odor, a sharp acrid taste, and it produces a violet corrosive vapor.

– The vapor is irritating to the respiratory system and eyes.

• The solid iodine irritates the eyes and may burn the skin, and it may cause severe

internal irritation and damage if ingested.

Iodine (Continued)

• Iodine is known as the “blue ingredient” in the production of meth (in the “red, white, and blue” method).

Iodine (Continued)

Iodine (Continued)

• It takes approximately 4 bottles of iodine tincture to produce 2 – 3 grams of meth.

Iodine (Continued)

Iodine (Continued)

• Iodine leaves distinctive yellow-blue or brown stains on surfaces in former methlabs.

Iodine (Continued)

Iodine (Continued)

Iodine (Continued)

• The only good thing about iodine is that it leaves yellow stains.

• If you see yellow stained coffee filters, gloves or paper towels, this could be an

indicator that you’re in a lab.

• If you see yellow stains, you can spray some starch on them.

– If they turn a purplish blue/black, it’s iodine.

• Iodine is the only substance that reacts with soluble starch to produce a purplish black color.

– The only way to get iodine vapor all over the walls is to cook meth.

Mercurous Chloride

Rock Salt

Hydrogen Chloride

• Hydrogen chloride gas is commercially available.

• Hydrogen chloride gas can also be made by mixing sulfuric acid and salt.

• Muriatic acid is simply hydrogen chloride gas suspended in water.

• Hydrogen chloride gas can be seen as a pale white smoke.

– It is a poisonous gas that can cause respiratory problems and death.

Hydrogen Chloride (Continued)

Ammonium Nitrate

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Hydriodic Acid

• Hydriodic acid is a corrosive acid that is colorless when freshly prepared.

– When hydriodic acid is exposed to light and air, it turns yellowish and brown.

• Hydriodic acid is a solution of hydrogen iodide gas in water.

• Hydriodic acid vapor is irritating to the respiratory system, skin, and eyes.

• Hydriodic acid liquid causes severe burns to the eyes and skin.

• If hydriodic acid is accidentally ingested, it can cause severe internal irritation and

damage.

Hydriodic Acid (Continued)

Catalyst Chemicals

• Catalyst Chemicals:

– Chemicals which SPEED UP a reaction process and/or cause it to go to GREATER COMPLETION.

Red Phosphorus

• Red phosphorus is found ON matchboxes, in road flares, and other explosives.

– Red Phosphorus IGNITES when OVERHEATED!!!

• By combining red phosphorus and iodine, you can easily create the highly

controlled substance known as hydriodic acid (which is an essential ingredient in making meth).

– Creating 2 – 3 grams of meth requires about 4 big boxes of matches.

Red Phosphorus (Continued)

• Red phosphorous is highly flammable and if it is overheated it can become white

phosphorous…

– White phosphorous is a volatile and highly explosive substance.

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Lithium

• Lithium is used in batteries.

• Lithium seriously burns the skin upon contact.

– It also reacts VIOLENTLY with WATER and is highly explosive.

Lithium (Continued)

• Lithium reacts VIOLENTLY with WATER, and if it is splashed in the eyes during

cooking it will cause blindness.

– Lithium is extremely caustic to all body tissues.

Lithium (Continued)

Lithium (Continued)

• Lithium metal is HIGHLY water reactive and it will BURN or EXPLODE if it comes into contact with WATER!

• Because of the moisture in your skin, it will burn exposed flesh.

• Lithium metal will DEGRADE when exposed to atmospheric moisture…

– This is why meth cooks store lithium metal in a solvent prior to use.

• It is typical to see harvested lithium strips in Coleman fuel or Mineral Spirits to prevent explosions.

•Large quantities can be harvested and saved in these containers until needed

for a cook.

Lithium (Continued)

• If you see battery shells in the trashcan, on the floor, etc. – this is a VERY GOOD

indicator that you might be entering a meth lab!

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

• Lithium catches fire when in contact with water...

Solvent Chemicals

• Solvent Chemicals:

– A medium (liquid) in which a chemical operation takes place.

• Solvent chemicals (UNLIKE the precursor chemicals) CAN be

substituted/interchanged.

Ether

• Ether was once called “sweet vitriol” because of its hypnotic effect.

• Ether is a highly flammable substance that is used as an anesthetic agent –

especially in third world countries where more expensive anesthesia is not available.

– While inhaling the ether, patients could undergo complete surgical procedures while otherwise awake without feeling pain or concern.

Ether (Continued)

• Ether can be obtained from engine starting fluid.

• Ether is a solvent and it is flammable.

– It is particularly hazardous because it can cause BOTH fire and explosion.

• It has been said that a quart of ether can “level” a small house.

Ethyl Ether (Continued)

Ethyl Ether (Continued)

• Ether is VERY flammable and is HEAVIER than air.

– NEVER use ether near flames or non-sparkless motors.

– Ether is very PUNGENT – even a small evaporated amount of ether is VERY noticeable.

Acetone

• Acetone can be found in nail polish remover or paint thinner.

– It is extremely flammable.

• In the setting of a meth lab where meth is being cooked with high heat, acetone is

very dangerous.

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Toluene

• Toluene is used in brake fluid.

– When working with brake fluid (toluene), be careful not to spill it on your car

because it will eat away the paint and chrome…

• You also have to be careful using toluene around other household chemicals

because its high concentration of polyethylene glycol can cause it to ignite in a

violent fireball.

• Toluene is powerful enough to dissolve rubber.

Toluene (Continued)

• Toluene is used to form meth crystals.

– The fumes toluene releases can cause brain damage or death.

Toluene (Continued)

Toluene (Continued)

Ethanol

Isopropanol

Isopropanol (Continued)

Isopropyl Alcohol

Methanol

Methanol (Continued)

Methanol (Continued)

Benzene

Benzene (Continued)

Which of these is NOT a common ingredient in Meth?

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Methamphetamine- PowerPoint

- Chemicals and Ingredients Used to Make Meth

CJUS 240

Economic Costs of Meth

• The economic cost of methamphetamine use in the U.S. reached $23.4 billion in

2005.

– This includes the burden of addiction, premature death, drug treatment, child

care, and cleaning of lab sites.

– This figure does NOT take into account the future needs of the meth user.

Concerns with ACTIVE Meth Labs

• Danger of fire and explosion

• Chemical spills

• Inhalation of solvents, corrosives, and toxic gases

• “Booby traps”

• Waste disposal

Concerns with FORMER Meth Labs

• Vapors

• Chemical residues

• Methamphetamine residues

• Waste disposal

Equipment Used in Meth Production

• Pyrex or Corning dishes

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

• Coffee Filters

Equipment Used in Meth Production

Equipment Used in Meth Production

Basic Chemical Requirements

• In a clandestine laboratory, basic types of chemicals are necessary in order to

produce the desired drug.

– The basic types of chemicals needed are:

1) Precursor Chemicals

2) Reagent Chemicals

3) Catalyst Chemicals

4) Solvent Chemicals

List I Chemical

• The term “List I chemical” means a chemical specified by regulation of the Attorney General as a chemical that is used in manufacturing a controlled substance and is

IMPORTANT to the manufacture of the controlled substance.

• Examples of List I chemicals are:

– GBL

– Red Phosphorus

– Pseudoephedrine

List II Chemical

• The term “List II chemical” means a chemical (other than a List I chemical) specified by regulation of the Attorney General as a chemical that is USED in

manufacturing a controlled substance.

• Examples of List II chemicals are:

– Toluene

– Iodine

– Hydrochloric Acid

Precursor Chemicals

• Precursor Chemicals:

– A chemical that is ESSENTIAL to the production of a controlled substance and for

which NO SUBSTITUTION can be made.

Pseudoephedrine

• Pseudoephedrine is a decongestant found in cold medicine.

– Large amounts of pseudoephedrine on its own can harm the respiratory and nervous systems, as well as the heart.

Pseudoephedrine (Continued)

• Some of the common ways used to divert products containing pseudoephedrine

include:

– “Smurfing” – making multiple purchases at different locations

– Shelf-Sweeping – the theft of all shelf stock

– Shoplifting

– Theft from wholesalers

Pseudoephedrine (Continued)

• Pseudoephedrine smurfing is a method used by some methamphetamine producers to acquire large quantities of pseudoephedrine by enlisting the assistance of several

friends or associates (often referred to as “smurfers”) to make purchases at or below the legal thresholds from multiple retail locations.

– Smurfers are often addicts who trade the pseudoephedrine for finished

methamphetamine.

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

• About 680 pseudoephedrine tablets are needed to produce one ounce of meth…

Pseudoephedrine (Continued)

Out With a Bang

An Unstable Recipe…

• Meth contains a variety of poisonous ingredients…

– Some become EVEN MORE DANGEROUS once the cooking process begins…

Common Ingredients to Make Methamphetamine

Reagent Chemicals

• Reagent Chemicals:

– Chemicals which REACT upon the precursor chemical causing it to chemicallyCHANGE.

• A reagent chemical is a chemical which is required for the synthesis of an illicit drug substance, but which is NOT incorporated into the final chemical product.

Hydrochloric Acid

• Hydrochloric acid is a highly corrosive liquid that is used to make plastic (such as PVC pipe and polyurethane).

– It can remove rust and iron-oxide from steel and is highly corrosive to human

skin.

•Hydrochloric acid makes up the majority of the gastric acid in the human

digestive fluid.

• In high concentrations, hydrochloric acid will literally eat away human flesh…

Hydrochloric Acid (Continued)

• Hydrochloric acid can be purchased from hardware stores as:

– Tile and Grout Acid Cleaner

– Muriatic Acid

– Pool Acid

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

• Hydrochloric acid is a solution of hydrogen chloride gas suspended in water.

– Hydrochloric acid is corrosive and is a light yellow liquid color from traces of iron, chlorine, and organic matter.

• Inhaling hydrochloric acid may cause coughing or choking, inflammation, and

ulceration of the respiratory tract.

• Concentrated solutions of hydrochloric acid can cause severe burns and irritate the

mucous membranes, eyes, and respiratory tract.

– Exposure to hydrochloric acid vapors may result in pulmonary edema and

possibly death.

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

Sodium Hydroxide (NaOH)

• Sodium hydroxide is also called Lye.

• Sodium hydroxide is classified as a corrosive, and it is one of the main chemicals in

drain cleaner.

– It is also used in aluminum etching and to create biodiesal.

– It can burn the skin or cause blindness.

• Sodium hydroxide is used to dispose of road kill because it turns the dead bodies

into a coffee-like liquid.

Sodium Hydroxide (NaOH) (Continued)

• Drain cleaner (sodium hydroxide) is extremely corrosive, and without wearing

protection, even the smallest spill on the skin can eat through flesh…

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sulfuric Acid (H2SO4)

• Sulfuric acid is used in drain or toilet bowl cleaner as well as battery acid.

– It is another highly corrosive substance that burns the skin on contact.

Sulfuric Acid (H2SO4) (Continued)

• The product label warning for Drano® (sulfuric acid) says it all:

– DANGER: MAY BURN EYES AND SKIN ON CONTACT.

•HARMFUL IF SWALLOWED.

–Avoid contact with body and clothing.

•TOXIC GAS MAY FORM IF MIXED WITH OTHER CHEMICALS.

–If gases are released, leave immediately and ventilate area.

•FIRST AID: Give Immediately:

–EYES AND SKIN:

»Flush with water for 20 minutes.

»Remove affected clothing.

–IF SWALLOWED:

»Rinse mouth and drink a glass of water or milk.

»Do not induce vomiting.

–THEN SEEK MEDICAL AID.

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Hypophosphorous Acid (H3PO2)

• Hypophosphorous acid, which is used legally for a variety of commercial purposes, is a chemical that increasingly is substituted for red phosphorus in the methamphetamine production process.

– The use of hypophospherous acid SIGNIFICANTLY increases the risk of fire!!!

• The federal government regulates the sale of hypophosphorous acid through registration, record keeping, reporting, and import/export requirements regardless

of the quantity being handled or distributed.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid is a colorless oily liquid that emits a SOUR odor.

– There is an extreme fire and explosion hazard if the hypophosphorous acid

comes into contact with a solvent such as acetone, toluene, or Coleman fuel.

• Hypophosphorous acid will also emit phosphine gas and the fumes can ignite.

Hypophosphorous Acid (H3PO2) (Continued)

• Although hypophosphorous acid is a List I chemical under the Controlled Substances Act, methamphetamine producers typically purchase the chemical via

the internet or from associates who also are engaged in methamphetamine

production.

– The use of hypophosphorous acid in methamphetamine production is an

EXTREMELY DANGEROUS PRACTICE because of the deadly gases that can be generated as well as the risk of fire or explosion.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid (H3PO2, also called phosphinic acid) is a strong acid that typically is prepared as a solution of colorless, oily liquid in strengths of 50%, 30 to 32%, and 10%.

– It also is prepared in the form of salts (referred to as hypophosphite salts), particularly ammonium hypophosphite, calcium hypophosphite, iron (ferric)

hypophosphite, magnesium hypophosphite, manganese hypophosphite,

potassium hypophosphite, and sodium hypophosphite.

Hypophosphorous Acid (H3PO2) (Continued)

• Over 100 chemical firms located throughout the world produce hypophosphorous

acid.

– The People's Republic of China and India have the largest numbers of

hypophosphorous acid producers, although there are a few producers in the United States.

• There are a wide variety of uses for hypophosphorous acid and its salts in

commercial industry; however, the chemicals have no legitimate household or retail uses.

Hypophosphorous Acid (H3PO2) (Continued)

• The legitimate commercial and laboratory fields that use hypophosphorous acid and its salts include the following:

– Chemical plating

– Food preparation

– Water treatment

– Polymers (as a bleaching agent, color stabilizer, or catalyst)

– Education and research in analytical chemistry

Hypophosphorous Acid (H3PO2) (Continued)

• Chemical suppliers typically distribute hypophosphorous acid in large quantities, for example, in drums containing 275 pounds of the diluted solution.

– Hypophosphorous acid also is distributed in smaller quantities.

• One-half liter of 50% concentrate hypophosphorous acid solution can be obtained from chemical suppliers for as little as $14.

Hypophosphorous Acid (H3PO2) (Continued)

• Methamphetamine laboratory operators typically obtain small quantities of the chemical from other laboratory operators who purchase large quantities of the

chemical and repackage it for further distribution.

– According to law enforcement sources, these individuals sell hypophosphorous acid for as much as $1,000 per half-liter.

•Methamphetamine laboratory operators also purchase hypophosphorous acidvia the internet.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid and the Internet

• The internet is a source of a great deal of information regarding hypophosphorous acid.

• Popular internet sites that disseminate information about illicit drugs contain information about the chemical, including numerous recipes for home production of

methamphetamine using hypophosphorous acid.

• There also are recipes for synthesizing hypophosphorous acid from available chemicals.

• Hypophosphorous acid solutions and salts have been sold to the general public via the internet.

• The Drug Enforcement Administration (DEA) has strong concerns regarding the sale

of chemicals on the internet and has requested that any sites (such as auction sites) that allow the sale of regulated chemicals on their domains require proof of

DEA registration from their clients.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid Used in Methamphetamine Production

• Hypophosphorous acid is used in the ephedrine-pseudoephedrine reduction method

of methamphetamine production.

– It is used in the methamphetamine production process to produce hydriodic acid,

an important reagent (it reacts with the ephedrine-pseudoephedrine but does NOT become part of the finished product).

Hypophosphorous Acid (H3PO2) (Continued)

• The regulation of hydriodic acid by DEA in 1993 rendered it virtually unavailable in

the United States.

– However, methamphetamine laboratory operators discovered methods to

produce hydriodic acid using a combination of iodine in water with red phosphorus.

• Laboratory operators found that red phosphorus could be obtained easily, either

from commercial supply companies or by scraping the striker pads from matchbooks or matchboxes.

• Methamphetamine producers soon discovered that hypophosphorous acid ALSO could be used in combination with iodine and water to produce hydriodic acid.

Hypophosphorous Acid (H3PO2) (Continued)

• The practice of using hypophosphorous acid in methamphetamine production is

believed to have begun in the United States in the late 1990s when a methamphetamine producer in Colorado obtained the recipe from Australia, where

the hypophosphorous acid method is prevalent.

– This man was known as a serial cook who had a long history of

methamphetamine production.

•Over several years he trained other laboratory operators in Colorado to produce methamphetamine using hypophosphorous acid.

• As his techniques were passed on to others, the number of methamphetaminelaboratories in Colorado using hypophosphorous acid continued to increase, and the

technique was passed on to numerous methamphetamine producers in other

states.

Hypophosphorous Acid (H3PO2) (Continued)

• According to the El Paso Intelligence Center (EPIC) National Clandestine Laboratory

Seizure System, from 2000 through 2002 the number of seized methamphetaminelaboratories in the United States in which hypophosphorous acid was found

increased overall. (See Table 1.)

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid found at methamphetamine laboratories is packaged in a variety of ways.

• The chemical has been found in 1-gallon bottles of solution or in 1-pound jars of salts.

• Some hypophosphorous acid containers are labeled as "plating solution."

• Pint-sized brown glass bottles wrapped in red electrical tape also have been found to contain hypophosphorous acid; they have been discovered primarily in Colorado.

• The vast majority of hypophosphorous acid found at laboratory sites has been recovered from small toxic laboratories (STLs), those which yield gram to ounce

quantities per production cycle.

• Hypophosphorous acid has not been reported at large-scale laboratories operated by Mexican criminal groups in the United States.

Hypophosphorous Acid (H3PO2) (Continued)

• Hazards

• The iodine-hypophosphorous acid method is MORE HAZORDOUS than the iodine-

red phosphorus method, although the reaction using hypophosphorous acid is

faster and gives slightly higher yields.

– When hypophosphorous acid is used, the chemicals must be mixed together SLOWLY in a PARTICULAR ORDER to prevent them from reacting violently.

Hypophosphorous Acid (H3PO2) (Continued)

• The combination of hypophosphorous acid with the other chemicals and with

certain metals can produce deadly phosphine gas during the initial mixing step and

can CONTINUE to produce phosphine gas for several days AFTER production has been completed…

Hypophosphorous Acid (H3PO2) (Continued)

• The iodine-hypophosphorous acid mixture has a tendency to decompose quickly when overheated or if heated for long periods of time, becoming cloudy or "milky-

white" just prior to giving off a cloud of phosphine gas that can ignite spontaneously.

– Hypophosphorous acid solutions may become unstable if evaporation results in

concentrations above 50%.

Hypophosphorous Acid (H3PO2) (Continued)

• [Note: Law enforcement or emergency personnel who encounter suspected

containers of hypophosphorous acid should use extreme care during handling because laboratory operators often attempt to obtain a more concentrated acid by

allowing water to evaporate from the mixture.]

• Because hypophosphorous acid often is used at small methamphetaminelaboratories operated by inexperienced or careless individuals, the potential hazards

of using this method are even greater.

• The risk of fire and explosion is higher in these laboratories, where professional

laboratory equipment typically is not used to contain the phosphine gas and where

safe handling precautions are not employed.

• In addition, these laboratories often are located in homes where children are

present and may come into contact with hypophosphorous acid.

• A child can easily mistake hypophosphorous acid for any other clear liquid,

particularly if it is stored in household containers or drinking glasses.

• Skin, eye, or inhalation exposure can be extremely harmful or fatal.

Hypophosphorous Acid (H3PO2) (Continued)

• Safety Precautions

• Always wear a self-contained breathing apparatus as well as protective clothing when entering areas where hypophosphorous acid may be present.

• When in contact with metals or in a high-temperature environment,

hypophosphorous acid can break down and liberate phosphine and flammable hydrogen gas.

• Do not allow the use of open flames, open lights, matches, or smoking in or around laboratories or dumpsites where hypophosphorous acid is handled.

• In case of fire, use a self-contained positive pressure breathing apparatus and full

protective equipment.

• Use water spray, fog, foam, dry chemicals, or other reagents as may be

appropriate for materials in the surrounding fire.

• Water may be used to cool the containers of hypophosphorous acid; however, use extreme care to avoid allowing water to enter the container.

• In case of spills, neutralize the spilled chemical with alkaline material (soda ash, lime), then absorb it with an inert material such as vermiculite, dry sand, or earth

and place in a chemical waste container.

• Do not use combustible materials such as sawdust.

Hypophosphorous Acid (H3PO2) (Continued)

• Legislation and Control

• In the United States hypophosphorous acid is one of 38 chemicals (or groups of

chemicals) controlled under law by DEA.

• On October 17, 2001, hypophosphorous acid and its salts, along with red and white phosphorus, were officially added as List I chemicals under section 1310 of the

Code of Federal Regulations.

• List I chemicals are defined as chemicals that are used in the manufacture of a

controlled substance in violation of the Controlled Substances Act (CSA) and are

important to the manufacture of a controlled substance.

• Under the law, suppliers are required to maintain records and report receipts, sales,

imports, and exports of these chemicals to DEA.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid, red phosphorus, and white phosphorus, as well as

ephedrine, are unique in that suppliers are required to report all transactions of

these chemicals, regardless of the amount.

• By contrast, the other 34 listed chemicals are only reportable after a supplier's

transactions for a chemical reach an established weight or volume threshold in a calendar month.

• In addition to reporting all transactions involving the chemical, suppliers are

expected to "know their customers" in order to prevent the diversion of these substances to methamphetamine laboratories, as it is illegal to import, export,

purchase, or sell hypophosphorous acid or any other listed chemical in the United States if it is used or intended to be used in the production of a controlled

substance.

• Chemical suppliers are held liable for selling listed chemicals if they know or suspect that the chemical will be used for illicit purposes.

Hypophosphorous Acid (H3PO2) (Continued)

• Outlook

• The use of hypophosphorous acid in the production of methamphetamine is likely

to increase, particularly in the Midwest and Southwest regions of the United States

where methamphetamine production is prevalent.

– Injuries, property damage, and deaths also will increase as a growing number of

inexperienced methamphetamine producers experiment with hypophosphorous acid.

Anhydrous Ammonia

• Anhydrous ammonia is found in fertilizer, countertop cleaner, and commercial refrigerant.

– On its own, it has a pungent, suffocating odor.

• Mixing anhydrous ammonia with other chemicals can release highly toxic gases.

– Because anhydrous ammonia seeks out water (anhydrous means “without

water”) and causes severe burns, any body part that comes into contact with it

should be flushed with water for at least 15 minutes to remove the ammoniafrom the skin.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia has extremely destructive effects on humans.

– Anhydrous ammonia gives off vapors during cooking that can burn the mouth,

throat, and lung tissue.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Anhydrous ammonia seeks water from the nearest source, including the human body (anhydrous means “without water”).

– Because of their high moisture content, EYES, LUNGS, and SKIN are at the

greatest risk of attracting the ammonia.

• When large amounts of anhydrous ammonia are inhaled, the throat swells and the

victim suffocates.

– Exposure to the vapors or liquids can cause severe burns, blindness, or death.

• Anhydrous ammonia has an IDLH (immediately dangerous to life and health) at

only 300 parts per million...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is poses MANY hazards, especially when it is placed in improper vessels and handled/transported by individuals unfamiliar with the

dangers.

• Anhydrous ammonia has a boiling point of -28 degrees below zero.

– When a vessel containing anhydrous ammonia is MOVED, the anhydrous

ammonia will reach its boiling point and pressurize.

•This pressurization can cause vessels to violently RUPTURE, or if the vessel pressurizes and does NOT rupture, the opening of the container of anhydrous

ammonia at a later time can cause RAPID, VIOLENT depressurization.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is mainly used in the U.S. as either a fertilizer or a refrigerant.

– Meth producers tend to store the anhydrous ammonia in IMPROPER/UNAPPROVED containers such as:

•Propane tanks,

• Igloo coolers, or

•Fire extinguishers.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia leaves a tell-tell sign as it flows through these UNAPPROVED

CONTAINERS – a blue or blue green discoloration on the valve.

– PAY ATTENTION to details!!!

Anhydrous Ammonia (Continued)

• Because propane cylinders (and the other unapproved containers) are NOT designed to store anhydrous ammonia, they can EXPLODE as the ammonia eats

through the walls of the cylinders.

– The valves, which take on a bluish/green color, frequently deteriorate and can cause hazardous leaks!!!

Anhydrous Ammonia (Continued)

• Do NOT touch, move, or open any kind of tank or sealed container!!!

– Be aware that propane tanks are often WEAKENED and BRITTLE due to the

anhydrous ammonia and are SENSITIVE to ANY kind of movement or impact.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• These pictures show what happened to a fire extinguisher that was used to store

anhydrous ammonia…

Anhydrous Ammonia (Continued)

• Illegal drug makers often STEAL anhydrous ammonia from areas where it is stored

and used, such as farms.

• Attempted thefts have also occurred at places such as:

– Refrigeration systems holding ammonia,

– Underground pipelines carrying ammonia, and

– Rail cars transporting anhydrous ammonia.

• Often thefts are aborted when thieves are injured or overcome by the toxic gas...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia thieves had better beware!!!

• There is a new product called GloTell that farmers can add to their anhydrous ammonia tanks…

• Meth cooks will run the risk that the GloTell additive will turn their hands bright

pink!

– This bright pink stain will fluoresce under ultraviolet light even if washed off!!!

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Also, GloTell will produce pink methamphetamine that CANNOT be bleached.

– Users who snort meth made with GloTell will find that they have PINK NOSES!

– Users who inject meth made with GloTell will see a pink stain at the point of

injection!

Sodium Carbonate (Soda Ash)

Sodium Carbonate (Soda Ash) (Continued)

Lead Acetate

Iodine

• Iodine is a natural element, and it is helpful to the body in SMALL amounts.

– However, if iodine is taken in large amounts it can become toxic.

•Extremely high does of iodine can limit the function of the thyroid.

Iodine (Continued)

Iodine (Continued)

• Iodine is bluish-black, and it has a characteristic odor, a sharp acrid taste, and it produces a violet corrosive vapor.

– The vapor is irritating to the respiratory system and eyes.

• The solid iodine irritates the eyes and may burn the skin, and it may cause severe

internal irritation and damage if ingested.

Iodine (Continued)

• Iodine is known as the “blue ingredient” in the production of meth (in the “red, white, and blue” method).

Iodine (Continued)

Iodine (Continued)

• It takes approximately 4 bottles of iodine tincture to produce 2 – 3 grams of meth.

Iodine (Continued)

Iodine (Continued)

• Iodine leaves distinctive yellow-blue or brown stains on surfaces in former methlabs.

Iodine (Continued)

Iodine (Continued)

Iodine (Continued)

• The only good thing about iodine is that it leaves yellow stains.

• If you see yellow stained coffee filters, gloves or paper towels, this could be an

indicator that you’re in a lab.

• If you see yellow stains, you can spray some starch on them.

– If they turn a purplish blue/black, it’s iodine.

• Iodine is the only substance that reacts with soluble starch to produce a purplish black color.

– The only way to get iodine vapor all over the walls is to cook meth.

Mercurous Chloride

Rock Salt

Hydrogen Chloride

• Hydrogen chloride gas is commercially available.

• Hydrogen chloride gas can also be made by mixing sulfuric acid and salt.

• Muriatic acid is simply hydrogen chloride gas suspended in water.

• Hydrogen chloride gas can be seen as a pale white smoke.

– It is a poisonous gas that can cause respiratory problems and death.

Hydrogen Chloride (Continued)

Ammonium Nitrate

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Hydriodic Acid

• Hydriodic acid is a corrosive acid that is colorless when freshly prepared.

– When hydriodic acid is exposed to light and air, it turns yellowish and brown.

• Hydriodic acid is a solution of hydrogen iodide gas in water.

• Hydriodic acid vapor is irritating to the respiratory system, skin, and eyes.

• Hydriodic acid liquid causes severe burns to the eyes and skin.

• If hydriodic acid is accidentally ingested, it can cause severe internal irritation and

damage.

Hydriodic Acid (Continued)

Catalyst Chemicals

• Catalyst Chemicals:

– Chemicals which SPEED UP a reaction process and/or cause it to go to GREATER COMPLETION.

Red Phosphorus

• Red phosphorus is found ON matchboxes, in road flares, and other explosives.

– Red Phosphorus IGNITES when OVERHEATED!!!

• By combining red phosphorus and iodine, you can easily create the highly

controlled substance known as hydriodic acid (which is an essential ingredient in making meth).

– Creating 2 – 3 grams of meth requires about 4 big boxes of matches.

Red Phosphorus (Continued)

• Red phosphorous is highly flammable and if it is overheated it can become white

phosphorous…

– White phosphorous is a volatile and highly explosive substance.

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Lithium

• Lithium is used in batteries.

• Lithium seriously burns the skin upon contact.

– It also reacts VIOLENTLY with WATER and is highly explosive.

Lithium (Continued)

• Lithium reacts VIOLENTLY with WATER, and if it is splashed in the eyes during

cooking it will cause blindness.

– Lithium is extremely caustic to all body tissues.

Lithium (Continued)

Lithium (Continued)

• Lithium metal is HIGHLY water reactive and it will BURN or EXPLODE if it comes into contact with WATER!

• Because of the moisture in your skin, it will burn exposed flesh.

• Lithium metal will DEGRADE when exposed to atmospheric moisture…

– This is why meth cooks store lithium metal in a solvent prior to use.

• It is typical to see harvested lithium strips in Coleman fuel or Mineral Spirits to prevent explosions.

•Large quantities can be harvested and saved in these containers until needed

for a cook.

Lithium (Continued)

• If you see battery shells in the trashcan, on the floor, etc. – this is a VERY GOOD

indicator that you might be entering a meth lab!

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

• Lithium catches fire when in contact with water...

Solvent Chemicals

• Solvent Chemicals:

– A medium (liquid) in which a chemical operation takes place.

• Solvent chemicals (UNLIKE the precursor chemicals) CAN be

substituted/interchanged.

Ether

• Ether was once called “sweet vitriol” because of its hypnotic effect.

• Ether is a highly flammable substance that is used as an anesthetic agent –

especially in third world countries where more expensive anesthesia is not available.

– While inhaling the ether, patients could undergo complete surgical procedures while otherwise awake without feeling pain or concern.

Ether (Continued)

• Ether can be obtained from engine starting fluid.

• Ether is a solvent and it is flammable.

– It is particularly hazardous because it can cause BOTH fire and explosion.

• It has been said that a quart of ether can “level” a small house.

Ethyl Ether (Continued)

Ethyl Ether (Continued)

• Ether is VERY flammable and is HEAVIER than air.

– NEVER use ether near flames or non-sparkless motors.

– Ether is very PUNGENT – even a small evaporated amount of ether is VERY noticeable.

Acetone

• Acetone can be found in nail polish remover or paint thinner.

– It is extremely flammable.

• In the setting of a meth lab where meth is being cooked with high heat, acetone is

very dangerous.

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Toluene

• Toluene is used in brake fluid.

– When working with brake fluid (toluene), be careful not to spill it on your car

because it will eat away the paint and chrome…

• You also have to be careful using toluene around other household chemicals

because its high concentration of polyethylene glycol can cause it to ignite in a

violent fireball.

• Toluene is powerful enough to dissolve rubber.

Toluene (Continued)

• Toluene is used to form meth crystals.

– The fumes toluene releases can cause brain damage or death.

Toluene (Continued)

Toluene (Continued)

Ethanol

Isopropanol

Isopropanol (Continued)

Isopropyl Alcohol

Methanol

Methanol (Continued)

Methanol (Continued)

Benzene

Benzene (Continued)

Which of these is NOT a common ingredient in Meth?

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Page 11: Methamphetamine - PowerPoint - Chemicals and Ingredients ... · 2/5/2014 1 Methamphetamine - PowerPoint - Chemicals and Ingredients Used to Make Meth CJUS 240 Economic Costs of Meth

2/5/2014

11

Methamphetamine- PowerPoint

- Chemicals and Ingredients Used to Make Meth

CJUS 240

Economic Costs of Meth

• The economic cost of methamphetamine use in the U.S. reached $23.4 billion in

2005.

– This includes the burden of addiction, premature death, drug treatment, child

care, and cleaning of lab sites.

– This figure does NOT take into account the future needs of the meth user.

Concerns with ACTIVE Meth Labs

• Danger of fire and explosion

• Chemical spills

• Inhalation of solvents, corrosives, and toxic gases

• “Booby traps”

• Waste disposal

Concerns with FORMER Meth Labs

• Vapors

• Chemical residues

• Methamphetamine residues

• Waste disposal

Equipment Used in Meth Production

• Pyrex or Corning dishes

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

• Coffee Filters

Equipment Used in Meth Production

Equipment Used in Meth Production

Basic Chemical Requirements

• In a clandestine laboratory, basic types of chemicals are necessary in order to

produce the desired drug.

– The basic types of chemicals needed are:

1) Precursor Chemicals

2) Reagent Chemicals

3) Catalyst Chemicals

4) Solvent Chemicals

List I Chemical

• The term “List I chemical” means a chemical specified by regulation of the Attorney General as a chemical that is used in manufacturing a controlled substance and is

IMPORTANT to the manufacture of the controlled substance.

• Examples of List I chemicals are:

– GBL

– Red Phosphorus

– Pseudoephedrine

List II Chemical

• The term “List II chemical” means a chemical (other than a List I chemical) specified by regulation of the Attorney General as a chemical that is USED in

manufacturing a controlled substance.

• Examples of List II chemicals are:

– Toluene

– Iodine

– Hydrochloric Acid

Precursor Chemicals

• Precursor Chemicals:

– A chemical that is ESSENTIAL to the production of a controlled substance and for

which NO SUBSTITUTION can be made.

Pseudoephedrine

• Pseudoephedrine is a decongestant found in cold medicine.

– Large amounts of pseudoephedrine on its own can harm the respiratory and nervous systems, as well as the heart.

Pseudoephedrine (Continued)

• Some of the common ways used to divert products containing pseudoephedrine

include:

– “Smurfing” – making multiple purchases at different locations

– Shelf-Sweeping – the theft of all shelf stock

– Shoplifting

– Theft from wholesalers

Pseudoephedrine (Continued)

• Pseudoephedrine smurfing is a method used by some methamphetamine producers to acquire large quantities of pseudoephedrine by enlisting the assistance of several

friends or associates (often referred to as “smurfers”) to make purchases at or below the legal thresholds from multiple retail locations.

– Smurfers are often addicts who trade the pseudoephedrine for finished

methamphetamine.

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

• About 680 pseudoephedrine tablets are needed to produce one ounce of meth…

Pseudoephedrine (Continued)

Out With a Bang

An Unstable Recipe…

• Meth contains a variety of poisonous ingredients…

– Some become EVEN MORE DANGEROUS once the cooking process begins…

Common Ingredients to Make Methamphetamine

Reagent Chemicals

• Reagent Chemicals:

– Chemicals which REACT upon the precursor chemical causing it to chemicallyCHANGE.

• A reagent chemical is a chemical which is required for the synthesis of an illicit drug substance, but which is NOT incorporated into the final chemical product.

Hydrochloric Acid

• Hydrochloric acid is a highly corrosive liquid that is used to make plastic (such as PVC pipe and polyurethane).

– It can remove rust and iron-oxide from steel and is highly corrosive to human skin.

•Hydrochloric acid makes up the majority of the gastric acid in the human

digestive fluid.

• In high concentrations, hydrochloric acid will literally eat away human flesh…

Hydrochloric Acid (Continued)

• Hydrochloric acid can be purchased from hardware stores as:

– Tile and Grout Acid Cleaner

– Muriatic Acid

– Pool Acid

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

• Hydrochloric acid is a solution of hydrogen chloride gas suspended in water.

– Hydrochloric acid is corrosive and is a light yellow liquid color from traces of iron, chlorine, and organic matter.

• Inhaling hydrochloric acid may cause coughing or choking, inflammation, and

ulceration of the respiratory tract.

• Concentrated solutions of hydrochloric acid can cause severe burns and irritate the

mucous membranes, eyes, and respiratory tract.

– Exposure to hydrochloric acid vapors may result in pulmonary edema and

possibly death.

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

Sodium Hydroxide (NaOH)

• Sodium hydroxide is also called Lye.

• Sodium hydroxide is classified as a corrosive, and it is one of the main chemicals in

drain cleaner.

– It is also used in aluminum etching and to create biodiesal.

– It can burn the skin or cause blindness.

• Sodium hydroxide is used to dispose of road kill because it turns the dead bodies

into a coffee-like liquid.

Sodium Hydroxide (NaOH) (Continued)

• Drain cleaner (sodium hydroxide) is extremely corrosive, and without wearing

protection, even the smallest spill on the skin can eat through flesh…

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sulfuric Acid (H2SO4)

• Sulfuric acid is used in drain or toilet bowl cleaner as well as battery acid.

– It is another highly corrosive substance that burns the skin on contact.

Sulfuric Acid (H2SO4) (Continued)

• The product label warning for Drano® (sulfuric acid) says it all:

– DANGER: MAY BURN EYES AND SKIN ON CONTACT.

•HARMFUL IF SWALLOWED.

–Avoid contact with body and clothing.

•TOXIC GAS MAY FORM IF MIXED WITH OTHER CHEMICALS.

–If gases are released, leave immediately and ventilate area.

•FIRST AID: Give Immediately:

–EYES AND SKIN:

»Flush with water for 20 minutes.

»Remove affected clothing.

–IF SWALLOWED:

»Rinse mouth and drink a glass of water or milk.

»Do not induce vomiting.

–THEN SEEK MEDICAL AID.

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Hypophosphorous Acid (H3PO2)

• Hypophosphorous acid, which is used legally for a variety of commercial purposes,

is a chemical that increasingly is substituted for red phosphorus in the methamphetamine production process.

– The use of hypophospherous acid SIGNIFICANTLY increases the risk of fire!!!

• The federal government regulates the sale of hypophosphorous acid through registration, record keeping, reporting, and import/export requirements regardless

of the quantity being handled or distributed.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid is a colorless oily liquid that emits a SOUR odor.

– There is an extreme fire and explosion hazard if the hypophosphorous acid

comes into contact with a solvent such as acetone, toluene, or Coleman fuel.

• Hypophosphorous acid will also emit phosphine gas and the fumes can ignite.

Hypophosphorous Acid (H3PO2) (Continued)

• Although hypophosphorous acid is a List I chemical under the Controlled Substances Act, methamphetamine producers typically purchase the chemical via

the internet or from associates who also are engaged in methamphetamine

production.

– The use of hypophosphorous acid in methamphetamine production is an

EXTREMELY DANGEROUS PRACTICE because of the deadly gases that can be generated as well as the risk of fire or explosion.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid (H3PO2, also called phosphinic acid) is a strong acid that

typically is prepared as a solution of colorless, oily liquid in strengths of 50%, 30 to 32%, and 10%.

– It also is prepared in the form of salts (referred to as hypophosphite salts), particularly ammonium hypophosphite, calcium hypophosphite, iron (ferric)

hypophosphite, magnesium hypophosphite, manganese hypophosphite,

potassium hypophosphite, and sodium hypophosphite.

Hypophosphorous Acid (H3PO2) (Continued)

• Over 100 chemical firms located throughout the world produce hypophosphorous

acid.

– The People's Republic of China and India have the largest numbers of

hypophosphorous acid producers, although there are a few producers in the United States.

• There are a wide variety of uses for hypophosphorous acid and its salts in commercial industry; however, the chemicals have no legitimate household or retail uses.

Hypophosphorous Acid (H3PO2) (Continued)

• The legitimate commercial and laboratory fields that use hypophosphorous acid and its salts include the following:

– Chemical plating

– Food preparation

– Water treatment

– Polymers (as a bleaching agent, color stabilizer, or catalyst)

– Education and research in analytical chemistry

Hypophosphorous Acid (H3PO2) (Continued)

• Chemical suppliers typically distribute hypophosphorous acid in large quantities, for example, in drums containing 275 pounds of the diluted solution.

– Hypophosphorous acid also is distributed in smaller quantities.

• One-half liter of 50% concentrate hypophosphorous acid solution can be obtained from chemical suppliers for as little as $14.

Hypophosphorous Acid (H3PO2) (Continued)

• Methamphetamine laboratory operators typically obtain small quantities of the chemical from other laboratory operators who purchase large quantities of the

chemical and repackage it for further distribution.

– According to law enforcement sources, these individuals sell hypophosphorous acid for as much as $1,000 per half-liter.

•Methamphetamine laboratory operators also purchase hypophosphorous acidvia the internet.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid and the Internet

• The internet is a source of a great deal of information regarding hypophosphorous acid.

• Popular internet sites that disseminate information about illicit drugs contain information about the chemical, including numerous recipes for home production of

methamphetamine using hypophosphorous acid.

• There also are recipes for synthesizing hypophosphorous acid from available chemicals.

• Hypophosphorous acid solutions and salts have been sold to the general public via the internet.

• The Drug Enforcement Administration (DEA) has strong concerns regarding the sale

of chemicals on the internet and has requested that any sites (such as auction sites) that allow the sale of regulated chemicals on their domains require proof of

DEA registration from their clients.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid Used in Methamphetamine Production

• Hypophosphorous acid is used in the ephedrine-pseudoephedrine reduction method

of methamphetamine production.

– It is used in the methamphetamine production process to produce hydriodic acid,

an important reagent (it reacts with the ephedrine-pseudoephedrine but does NOT become part of the finished product).

Hypophosphorous Acid (H3PO2) (Continued)

• The regulation of hydriodic acid by DEA in 1993 rendered it virtually unavailable in

the United States.

– However, methamphetamine laboratory operators discovered methods to

produce hydriodic acid using a combination of iodine in water with red phosphorus.

• Laboratory operators found that red phosphorus could be obtained easily, either

from commercial supply companies or by scraping the striker pads from matchbooks or matchboxes.

• Methamphetamine producers soon discovered that hypophosphorous acid ALSO could be used in combination with iodine and water to produce hydriodic acid.

Hypophosphorous Acid (H3PO2) (Continued)

• The practice of using hypophosphorous acid in methamphetamine production is

believed to have begun in the United States in the late 1990s when a methamphetamine producer in Colorado obtained the recipe from Australia, where

the hypophosphorous acid method is prevalent.

– This man was known as a serial cook who had a long history of methamphetamine production.

•Over several years he trained other laboratory operators in Colorado to produce methamphetamine using hypophosphorous acid.

• As his techniques were passed on to others, the number of methamphetaminelaboratories in Colorado using hypophosphorous acid continued to increase, and the

technique was passed on to numerous methamphetamine producers in other

states.

Hypophosphorous Acid (H3PO2) (Continued)

• According to the El Paso Intelligence Center (EPIC) National Clandestine Laboratory

Seizure System, from 2000 through 2002 the number of seized methamphetaminelaboratories in the United States in which hypophosphorous acid was found increased overall. (See Table 1.)

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid found at methamphetamine laboratories is packaged in a variety of ways.

• The chemical has been found in 1-gallon bottles of solution or in 1-pound jars of salts.

• Some hypophosphorous acid containers are labeled as "plating solution."

• Pint-sized brown glass bottles wrapped in red electrical tape also have been found to contain hypophosphorous acid; they have been discovered primarily in Colorado.

• The vast majority of hypophosphorous acid found at laboratory sites has been recovered from small toxic laboratories (STLs), those which yield gram to ounce quantities per production cycle.

• Hypophosphorous acid has not been reported at large-scale laboratories operated by Mexican criminal groups in the United States.

Hypophosphorous Acid (H3PO2) (Continued)

• Hazards

• The iodine-hypophosphorous acid method is MORE HAZORDOUS than the iodine-

red phosphorus method, although the reaction using hypophosphorous acid is

faster and gives slightly higher yields.

– When hypophosphorous acid is used, the chemicals must be mixed together

SLOWLY in a PARTICULAR ORDER to prevent them from reacting violently.

Hypophosphorous Acid (H3PO2) (Continued)

• The combination of hypophosphorous acid with the other chemicals and with

certain metals can produce deadly phosphine gas during the initial mixing step and

can CONTINUE to produce phosphine gas for several days AFTER production has been completed…

Hypophosphorous Acid (H3PO2) (Continued)

• The iodine-hypophosphorous acid mixture has a tendency to decompose quickly when overheated or if heated for long periods of time, becoming cloudy or "milky-

white" just prior to giving off a cloud of phosphine gas that can ignite spontaneously.

– Hypophosphorous acid solutions may become unstable if evaporation results in concentrations above 50%.

Hypophosphorous Acid (H3PO2) (Continued)

• [Note: Law enforcement or emergency personnel who encounter suspected

containers of hypophosphorous acid should use extreme care during handling because laboratory operators often attempt to obtain a more concentrated acid by

allowing water to evaporate from the mixture.]

• Because hypophosphorous acid often is used at small methamphetaminelaboratories operated by inexperienced or careless individuals, the potential hazards

of using this method are even greater.

• The risk of fire and explosion is higher in these laboratories, where professional

laboratory equipment typically is not used to contain the phosphine gas and where safe handling precautions are not employed.

• In addition, these laboratories often are located in homes where children are

present and may come into contact with hypophosphorous acid.

• A child can easily mistake hypophosphorous acid for any other clear liquid,

particularly if it is stored in household containers or drinking glasses.

• Skin, eye, or inhalation exposure can be extremely harmful or fatal.

Hypophosphorous Acid (H3PO2) (Continued)

• Safety Precautions

• Always wear a self-contained breathing apparatus as well as protective clothing when entering areas where hypophosphorous acid may be present.

• When in contact with metals or in a high-temperature environment, hypophosphorous acid can break down and liberate phosphine and flammable hydrogen gas.

• Do not allow the use of open flames, open lights, matches, or smoking in or around laboratories or dumpsites where hypophosphorous acid is handled.

• In case of fire, use a self-contained positive pressure breathing apparatus and full

protective equipment.

• Use water spray, fog, foam, dry chemicals, or other reagents as may be

appropriate for materials in the surrounding fire.

• Water may be used to cool the containers of hypophosphorous acid; however, use extreme care to avoid allowing water to enter the container.

• In case of spills, neutralize the spilled chemical with alkaline material (soda ash, lime), then absorb it with an inert material such as vermiculite, dry sand, or earth

and place in a chemical waste container.

• Do not use combustible materials such as sawdust.

Hypophosphorous Acid (H3PO2) (Continued)

• Legislation and Control

• In the United States hypophosphorous acid is one of 38 chemicals (or groups of

chemicals) controlled under law by DEA.

• On October 17, 2001, hypophosphorous acid and its salts, along with red and white phosphorus, were officially added as List I chemicals under section 1310 of the

Code of Federal Regulations.

• List I chemicals are defined as chemicals that are used in the manufacture of a

controlled substance in violation of the Controlled Substances Act (CSA) and are

important to the manufacture of a controlled substance.

• Under the law, suppliers are required to maintain records and report receipts, sales,

imports, and exports of these chemicals to DEA.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid, red phosphorus, and white phosphorus, as well as

ephedrine, are unique in that suppliers are required to report all transactions of

these chemicals, regardless of the amount.

• By contrast, the other 34 listed chemicals are only reportable after a supplier's

transactions for a chemical reach an established weight or volume threshold in a calendar month.

• In addition to reporting all transactions involving the chemical, suppliers are

expected to "know their customers" in order to prevent the diversion of these substances to methamphetamine laboratories, as it is illegal to import, export,

purchase, or sell hypophosphorous acid or any other listed chemical in the United States if it is used or intended to be used in the production of a controlled

substance.

• Chemical suppliers are held liable for selling listed chemicals if they know or suspect that the chemical will be used for illicit purposes.

Hypophosphorous Acid (H3PO2) (Continued)

• Outlook

• The use of hypophosphorous acid in the production of methamphetamine is likely

to increase, particularly in the Midwest and Southwest regions of the United States

where methamphetamine production is prevalent.

– Injuries, property damage, and deaths also will increase as a growing number of

inexperienced methamphetamine producers experiment with hypophosphorous acid.

Anhydrous Ammonia

• Anhydrous ammonia is found in fertilizer, countertop cleaner, and commercial refrigerant.

– On its own, it has a pungent, suffocating odor.

• Mixing anhydrous ammonia with other chemicals can release highly toxic gases.

– Because anhydrous ammonia seeks out water (anhydrous means “without

water”) and causes severe burns, any body part that comes into contact with it

should be flushed with water for at least 15 minutes to remove the ammoniafrom the skin.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia has extremely destructive effects on humans.

– Anhydrous ammonia gives off vapors during cooking that can burn the mouth,

throat, and lung tissue.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Anhydrous ammonia seeks water from the nearest source, including the human body (anhydrous means “without water”).

– Because of their high moisture content, EYES, LUNGS, and SKIN are at the

greatest risk of attracting the ammonia.

• When large amounts of anhydrous ammonia are inhaled, the throat swells and the

victim suffocates.

– Exposure to the vapors or liquids can cause severe burns, blindness, or death.

• Anhydrous ammonia has an IDLH (immediately dangerous to life and health) at

only 300 parts per million...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is poses MANY hazards, especially when it is placed in improper vessels and handled/transported by individuals unfamiliar with the dangers.

• Anhydrous ammonia has a boiling point of -28 degrees below zero.

– When a vessel containing anhydrous ammonia is MOVED, the anhydrous

ammonia will reach its boiling point and pressurize.

•This pressurization can cause vessels to violently RUPTURE, or if the vessel pressurizes and does NOT rupture, the opening of the container of anhydrous

ammonia at a later time can cause RAPID, VIOLENT depressurization.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is mainly used in the U.S. as either a fertilizer or a refrigerant.

– Meth producers tend to store the anhydrous ammonia in IMPROPER/UNAPPROVED containers such as:

•Propane tanks,

• Igloo coolers, or

•Fire extinguishers.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia leaves a tell-tell sign as it flows through these UNAPPROVED

CONTAINERS – a blue or blue green discoloration on the valve.

– PAY ATTENTION to details!!!

Anhydrous Ammonia (Continued)

• Because propane cylinders (and the other unapproved containers) are NOT designed to store anhydrous ammonia, they can EXPLODE as the ammonia eats through the walls of the cylinders.

– The valves, which take on a bluish/green color, frequently deteriorate and can cause hazardous leaks!!!

Anhydrous Ammonia (Continued)

• Do NOT touch, move, or open any kind of tank or sealed container!!!

– Be aware that propane tanks are often WEAKENED and BRITTLE due to the

anhydrous ammonia and are SENSITIVE to ANY kind of movement or impact.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• These pictures show what happened to a fire extinguisher that was used to store

anhydrous ammonia…

Anhydrous Ammonia (Continued)

• Illegal drug makers often STEAL anhydrous ammonia from areas where it is stored

and used, such as farms.

• Attempted thefts have also occurred at places such as:

– Refrigeration systems holding ammonia,

– Underground pipelines carrying ammonia, and

– Rail cars transporting anhydrous ammonia.

• Often thefts are aborted when thieves are injured or overcome by the toxic gas...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia thieves had better beware!!!

• There is a new product called GloTell that farmers can add to their anhydrous

ammonia tanks…

• Meth cooks will run the risk that the GloTell additive will turn their hands bright

pink!

– This bright pink stain will fluoresce under ultraviolet light even if washed off!!!

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Also, GloTell will produce pink methamphetamine that CANNOT be bleached.

– Users who snort meth made with GloTell will find that they have PINK NOSES!

– Users who inject meth made with GloTell will see a pink stain at the point of

injection!

Sodium Carbonate (Soda Ash)

Sodium Carbonate (Soda Ash) (Continued)

Lead Acetate

Iodine

• Iodine is a natural element, and it is helpful to the body in SMALL amounts.

– However, if iodine is taken in large amounts it can become toxic.

•Extremely high does of iodine can limit the function of the thyroid.

Iodine (Continued)

Iodine (Continued)

• Iodine is bluish-black, and it has a characteristic odor, a sharp acrid taste, and it produces a violet corrosive vapor.

– The vapor is irritating to the respiratory system and eyes.

• The solid iodine irritates the eyes and may burn the skin, and it may cause severe

internal irritation and damage if ingested.

Iodine (Continued)

• Iodine is known as the “blue ingredient” in the production of meth (in the “red, white, and blue” method).

Iodine (Continued)

Iodine (Continued)

• It takes approximately 4 bottles of iodine tincture to produce 2 – 3 grams of meth.

Iodine (Continued)

Iodine (Continued)

• Iodine leaves distinctive yellow-blue or brown stains on surfaces in former methlabs.

Iodine (Continued)

Iodine (Continued)

Iodine (Continued)

• The only good thing about iodine is that it leaves yellow stains.

• If you see yellow stained coffee filters, gloves or paper towels, this could be an indicator that you’re in a lab.

• If you see yellow stains, you can spray some starch on them.

– If they turn a purplish blue/black, it’s iodine.

• Iodine is the only substance that reacts with soluble starch to produce a purplish black color.

– The only way to get iodine vapor all over the walls is to cook meth.

Mercurous Chloride

Rock Salt

Hydrogen Chloride

• Hydrogen chloride gas is commercially available.

• Hydrogen chloride gas can also be made by mixing sulfuric acid and salt.

• Muriatic acid is simply hydrogen chloride gas suspended in water.

• Hydrogen chloride gas can be seen as a pale white smoke.

– It is a poisonous gas that can cause respiratory problems and death.

Hydrogen Chloride (Continued)

Ammonium Nitrate

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Hydriodic Acid

• Hydriodic acid is a corrosive acid that is colorless when freshly prepared.

– When hydriodic acid is exposed to light and air, it turns yellowish and brown.

• Hydriodic acid is a solution of hydrogen iodide gas in water.

• Hydriodic acid vapor is irritating to the respiratory system, skin, and eyes.

• Hydriodic acid liquid causes severe burns to the eyes and skin.

• If hydriodic acid is accidentally ingested, it can cause severe internal irritation and

damage.

Hydriodic Acid (Continued)

Catalyst Chemicals

• Catalyst Chemicals:

– Chemicals which SPEED UP a reaction process and/or cause it to go to GREATER COMPLETION.

Red Phosphorus

• Red phosphorus is found ON matchboxes, in road flares, and other explosives.

– Red Phosphorus IGNITES when OVERHEATED!!!

• By combining red phosphorus and iodine, you can easily create the highly

controlled substance known as hydriodic acid (which is an essential ingredient in making meth).

– Creating 2 – 3 grams of meth requires about 4 big boxes of matches.

Red Phosphorus (Continued)

• Red phosphorous is highly flammable and if it is overheated it can become white

phosphorous…

– White phosphorous is a volatile and highly explosive substance.

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Lithium

• Lithium is used in batteries.

• Lithium seriously burns the skin upon contact.

– It also reacts VIOLENTLY with WATER and is highly explosive.

Lithium (Continued)

• Lithium reacts VIOLENTLY with WATER, and if it is splashed in the eyes during

cooking it will cause blindness.

– Lithium is extremely caustic to all body tissues.

Lithium (Continued)

Lithium (Continued)

• Lithium metal is HIGHLY water reactive and it will BURN or EXPLODE if it comes into contact with WATER!

• Because of the moisture in your skin, it will burn exposed flesh.

• Lithium metal will DEGRADE when exposed to atmospheric moisture…

– This is why meth cooks store lithium metal in a solvent prior to use.

• It is typical to see harvested lithium strips in Coleman fuel or Mineral Spirits to prevent explosions.

•Large quantities can be harvested and saved in these containers until needed

for a cook.

Lithium (Continued)

• If you see battery shells in the trashcan, on the floor, etc. – this is a VERY GOOD

indicator that you might be entering a meth lab!

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

• Lithium catches fire when in contact with water...

Solvent Chemicals

• Solvent Chemicals:

– A medium (liquid) in which a chemical operation takes place.

• Solvent chemicals (UNLIKE the precursor chemicals) CAN be substituted/interchanged.

Ether

• Ether was once called “sweet vitriol” because of its hypnotic effect.

• Ether is a highly flammable substance that is used as an anesthetic agent –

especially in third world countries where more expensive anesthesia is not available.

– While inhaling the ether, patients could undergo complete surgical procedures while otherwise awake without feeling pain or concern.

Ether (Continued)

• Ether can be obtained from engine starting fluid.

• Ether is a solvent and it is flammable.

– It is particularly hazardous because it can cause BOTH fire and explosion.

• It has been said that a quart of ether can “level” a small house.

Ethyl Ether (Continued)

Ethyl Ether (Continued)

• Ether is VERY flammable and is HEAVIER than air.

– NEVER use ether near flames or non-sparkless motors.

– Ether is very PUNGENT – even a small evaporated amount of ether is VERY noticeable.

Acetone

• Acetone can be found in nail polish remover or paint thinner.

– It is extremely flammable.

• In the setting of a meth lab where meth is being cooked with high heat, acetone is

very dangerous.

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Toluene

• Toluene is used in brake fluid.

– When working with brake fluid (toluene), be careful not to spill it on your car

because it will eat away the paint and chrome…

• You also have to be careful using toluene around other household chemicals

because its high concentration of polyethylene glycol can cause it to ignite in a violent fireball.

• Toluene is powerful enough to dissolve rubber.

Toluene (Continued)

• Toluene is used to form meth crystals.

– The fumes toluene releases can cause brain damage or death.

Toluene (Continued)

Toluene (Continued)

Ethanol

Isopropanol

Isopropanol (Continued)

Isopropyl Alcohol

Methanol

Methanol (Continued)

Methanol (Continued)

Benzene

Benzene (Continued)

Which of these is NOT a common ingredient in Meth?

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Methamphetamine- PowerPoint

- Chemicals and Ingredients Used to Make Meth

CJUS 240

Economic Costs of Meth

• The economic cost of methamphetamine use in the U.S. reached $23.4 billion in

2005.

– This includes the burden of addiction, premature death, drug treatment, child

care, and cleaning of lab sites.

– This figure does NOT take into account the future needs of the meth user.

Concerns with ACTIVE Meth Labs

• Danger of fire and explosion

• Chemical spills

• Inhalation of solvents, corrosives, and toxic gases

• “Booby traps”

• Waste disposal

Concerns with FORMER Meth Labs

• Vapors

• Chemical residues

• Methamphetamine residues

• Waste disposal

Equipment Used in Meth Production

• Pyrex or Corning dishes

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

• Coffee Filters

Equipment Used in Meth Production

Equipment Used in Meth Production

Basic Chemical Requirements

• In a clandestine laboratory, basic types of chemicals are necessary in order to

produce the desired drug.

– The basic types of chemicals needed are:

1) Precursor Chemicals

2) Reagent Chemicals

3) Catalyst Chemicals

4) Solvent Chemicals

List I Chemical

• The term “List I chemical” means a chemical specified by regulation of the Attorney General as a chemical that is used in manufacturing a controlled substance and is

IMPORTANT to the manufacture of the controlled substance.

• Examples of List I chemicals are:

– GBL

– Red Phosphorus

– Pseudoephedrine

List II Chemical

• The term “List II chemical” means a chemical (other than a List I chemical) specified by regulation of the Attorney General as a chemical that is USED in

manufacturing a controlled substance.

• Examples of List II chemicals are:

– Toluene

– Iodine

– Hydrochloric Acid

Precursor Chemicals

• Precursor Chemicals:

– A chemical that is ESSENTIAL to the production of a controlled substance and for

which NO SUBSTITUTION can be made.

Pseudoephedrine

• Pseudoephedrine is a decongestant found in cold medicine.

– Large amounts of pseudoephedrine on its own can harm the respiratory and nervous systems, as well as the heart.

Pseudoephedrine (Continued)

• Some of the common ways used to divert products containing pseudoephedrine

include:

– “Smurfing” – making multiple purchases at different locations

– Shelf-Sweeping – the theft of all shelf stock

– Shoplifting

– Theft from wholesalers

Pseudoephedrine (Continued)

• Pseudoephedrine smurfing is a method used by some methamphetamine producers to acquire large quantities of pseudoephedrine by enlisting the assistance of several

friends or associates (often referred to as “smurfers”) to make purchases at or below the legal thresholds from multiple retail locations.

– Smurfers are often addicts who trade the pseudoephedrine for finished

methamphetamine.

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

• About 680 pseudoephedrine tablets are needed to produce one ounce of meth…

Pseudoephedrine (Continued)

Out With a Bang

An Unstable Recipe…

• Meth contains a variety of poisonous ingredients…

– Some become EVEN MORE DANGEROUS once the cooking process begins…

Common Ingredients to Make Methamphetamine

Reagent Chemicals

• Reagent Chemicals:

– Chemicals which REACT upon the precursor chemical causing it to chemicallyCHANGE.

• A reagent chemical is a chemical which is required for the synthesis of an illicit drug substance, but which is NOT incorporated into the final chemical product.

Hydrochloric Acid

• Hydrochloric acid is a highly corrosive liquid that is used to make plastic (such as PVC pipe and polyurethane).

– It can remove rust and iron-oxide from steel and is highly corrosive to human

skin.

•Hydrochloric acid makes up the majority of the gastric acid in the human

digestive fluid.

• In high concentrations, hydrochloric acid will literally eat away human flesh…

Hydrochloric Acid (Continued)

• Hydrochloric acid can be purchased from hardware stores as:

– Tile and Grout Acid Cleaner

– Muriatic Acid

– Pool Acid

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

• Hydrochloric acid is a solution of hydrogen chloride gas suspended in water.

– Hydrochloric acid is corrosive and is a light yellow liquid color from traces of iron, chlorine, and organic matter.

• Inhaling hydrochloric acid may cause coughing or choking, inflammation, and

ulceration of the respiratory tract.

• Concentrated solutions of hydrochloric acid can cause severe burns and irritate the

mucous membranes, eyes, and respiratory tract.

– Exposure to hydrochloric acid vapors may result in pulmonary edema and

possibly death.

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

Sodium Hydroxide (NaOH)

• Sodium hydroxide is also called Lye.

• Sodium hydroxide is classified as a corrosive, and it is one of the main chemicals in

drain cleaner.

– It is also used in aluminum etching and to create biodiesal.

– It can burn the skin or cause blindness.

• Sodium hydroxide is used to dispose of road kill because it turns the dead bodies

into a coffee-like liquid.

Sodium Hydroxide (NaOH) (Continued)

• Drain cleaner (sodium hydroxide) is extremely corrosive, and without wearing

protection, even the smallest spill on the skin can eat through flesh…

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sulfuric Acid (H2SO4)

• Sulfuric acid is used in drain or toilet bowl cleaner as well as battery acid.

– It is another highly corrosive substance that burns the skin on contact.

Sulfuric Acid (H2SO4) (Continued)

• The product label warning for Drano® (sulfuric acid) says it all:

– DANGER: MAY BURN EYES AND SKIN ON CONTACT.

•HARMFUL IF SWALLOWED.

–Avoid contact with body and clothing.

•TOXIC GAS MAY FORM IF MIXED WITH OTHER CHEMICALS.

–If gases are released, leave immediately and ventilate area.

•FIRST AID: Give Immediately:

–EYES AND SKIN:

»Flush with water for 20 minutes.

»Remove affected clothing.

–IF SWALLOWED:

»Rinse mouth and drink a glass of water or milk.

»Do not induce vomiting.

–THEN SEEK MEDICAL AID.

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Hypophosphorous Acid (H3PO2)

• Hypophosphorous acid, which is used legally for a variety of commercial purposes,

is a chemical that increasingly is substituted for red phosphorus in the methamphetamine production process.

– The use of hypophospherous acid SIGNIFICANTLY increases the risk of fire!!!

• The federal government regulates the sale of hypophosphorous acid through registration, record keeping, reporting, and import/export requirements regardless

of the quantity being handled or distributed.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid is a colorless oily liquid that emits a SOUR odor.

– There is an extreme fire and explosion hazard if the hypophosphorous acid

comes into contact with a solvent such as acetone, toluene, or Coleman fuel.

• Hypophosphorous acid will also emit phosphine gas and the fumes can ignite.

Hypophosphorous Acid (H3PO2) (Continued)

• Although hypophosphorous acid is a List I chemical under the Controlled Substances Act, methamphetamine producers typically purchase the chemical via

the internet or from associates who also are engaged in methamphetamine

production.

– The use of hypophosphorous acid in methamphetamine production is an

EXTREMELY DANGEROUS PRACTICE because of the deadly gases that can be generated as well as the risk of fire or explosion.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid (H3PO2, also called phosphinic acid) is a strong acid that

typically is prepared as a solution of colorless, oily liquid in strengths of 50%, 30 to 32%, and 10%.

– It also is prepared in the form of salts (referred to as hypophosphite salts), particularly ammonium hypophosphite, calcium hypophosphite, iron (ferric)

hypophosphite, magnesium hypophosphite, manganese hypophosphite,

potassium hypophosphite, and sodium hypophosphite.

Hypophosphorous Acid (H3PO2) (Continued)

• Over 100 chemical firms located throughout the world produce hypophosphorous

acid.

– The People's Republic of China and India have the largest numbers of

hypophosphorous acid producers, although there are a few producers in the United States.

• There are a wide variety of uses for hypophosphorous acid and its salts in

commercial industry; however, the chemicals have no legitimate household or retail uses.

Hypophosphorous Acid (H3PO2) (Continued)

• The legitimate commercial and laboratory fields that use hypophosphorous acid and its salts include the following:

– Chemical plating

– Food preparation

– Water treatment

– Polymers (as a bleaching agent, color stabilizer, or catalyst)

– Education and research in analytical chemistry

Hypophosphorous Acid (H3PO2) (Continued)

• Chemical suppliers typically distribute hypophosphorous acid in large quantities, for example, in drums containing 275 pounds of the diluted solution.

– Hypophosphorous acid also is distributed in smaller quantities.

• One-half liter of 50% concentrate hypophosphorous acid solution can be obtained from chemical suppliers for as little as $14.

Hypophosphorous Acid (H3PO2) (Continued)

• Methamphetamine laboratory operators typically obtain small quantities of the chemical from other laboratory operators who purchase large quantities of the

chemical and repackage it for further distribution.

– According to law enforcement sources, these individuals sell hypophosphorous acid for as much as $1,000 per half-liter.

•Methamphetamine laboratory operators also purchase hypophosphorous acidvia the internet.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid and the Internet

• The internet is a source of a great deal of information regarding hypophosphorous acid.

• Popular internet sites that disseminate information about illicit drugs contain information about the chemical, including numerous recipes for home production of

methamphetamine using hypophosphorous acid.

• There also are recipes for synthesizing hypophosphorous acid from available chemicals.

• Hypophosphorous acid solutions and salts have been sold to the general public via the internet.

• The Drug Enforcement Administration (DEA) has strong concerns regarding the sale

of chemicals on the internet and has requested that any sites (such as auction sites) that allow the sale of regulated chemicals on their domains require proof of

DEA registration from their clients.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid Used in Methamphetamine Production

• Hypophosphorous acid is used in the ephedrine-pseudoephedrine reduction method

of methamphetamine production.

– It is used in the methamphetamine production process to produce hydriodic acid,

an important reagent (it reacts with the ephedrine-pseudoephedrine but does NOT become part of the finished product).

Hypophosphorous Acid (H3PO2) (Continued)

• The regulation of hydriodic acid by DEA in 1993 rendered it virtually unavailable in

the United States.

– However, methamphetamine laboratory operators discovered methods to

produce hydriodic acid using a combination of iodine in water with red phosphorus.

• Laboratory operators found that red phosphorus could be obtained easily, either

from commercial supply companies or by scraping the striker pads from matchbooks or matchboxes.

• Methamphetamine producers soon discovered that hypophosphorous acid ALSO could be used in combination with iodine and water to produce hydriodic acid.

Hypophosphorous Acid (H3PO2) (Continued)

• The practice of using hypophosphorous acid in methamphetamine production is

believed to have begun in the United States in the late 1990s when a methamphetamine producer in Colorado obtained the recipe from Australia, where

the hypophosphorous acid method is prevalent.

– This man was known as a serial cook who had a long history of

methamphetamine production.

•Over several years he trained other laboratory operators in Colorado to produce methamphetamine using hypophosphorous acid.

• As his techniques were passed on to others, the number of methamphetaminelaboratories in Colorado using hypophosphorous acid continued to increase, and the

technique was passed on to numerous methamphetamine producers in other

states.

Hypophosphorous Acid (H3PO2) (Continued)

• According to the El Paso Intelligence Center (EPIC) National Clandestine Laboratory

Seizure System, from 2000 through 2002 the number of seized methamphetaminelaboratories in the United States in which hypophosphorous acid was found

increased overall. (See Table 1.)

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid found at methamphetamine laboratories is packaged in a variety of ways.

• The chemical has been found in 1-gallon bottles of solution or in 1-pound jars of salts.

• Some hypophosphorous acid containers are labeled as "plating solution."

• Pint-sized brown glass bottles wrapped in red electrical tape also have been found to contain hypophosphorous acid; they have been discovered primarily in Colorado.

• The vast majority of hypophosphorous acid found at laboratory sites has been recovered from small toxic laboratories (STLs), those which yield gram to ounce

quantities per production cycle.

• Hypophosphorous acid has not been reported at large-scale laboratories operated by Mexican criminal groups in the United States.

Hypophosphorous Acid (H3PO2) (Continued)

• Hazards

• The iodine-hypophosphorous acid method is MORE HAZORDOUS than the iodine-

red phosphorus method, although the reaction using hypophosphorous acid is

faster and gives slightly higher yields.

– When hypophosphorous acid is used, the chemicals must be mixed together

SLOWLY in a PARTICULAR ORDER to prevent them from reacting violently.

Hypophosphorous Acid (H3PO2) (Continued)

• The combination of hypophosphorous acid with the other chemicals and with certain metals can produce deadly phosphine gas during the initial mixing step and

can CONTINUE to produce phosphine gas for several days AFTER production has been completed…

Hypophosphorous Acid (H3PO2) (Continued)

• The iodine-hypophosphorous acid mixture has a tendency to decompose quickly when overheated or if heated for long periods of time, becoming cloudy or "milky-

white" just prior to giving off a cloud of phosphine gas that can ignite spontaneously.

– Hypophosphorous acid solutions may become unstable if evaporation results in

concentrations above 50%.

Hypophosphorous Acid (H3PO2) (Continued)

• [Note: Law enforcement or emergency personnel who encounter suspected

containers of hypophosphorous acid should use extreme care during handling because laboratory operators often attempt to obtain a more concentrated acid by

allowing water to evaporate from the mixture.]

• Because hypophosphorous acid often is used at small methamphetaminelaboratories operated by inexperienced or careless individuals, the potential hazards

of using this method are even greater.

• The risk of fire and explosion is higher in these laboratories, where professional

laboratory equipment typically is not used to contain the phosphine gas and where

safe handling precautions are not employed.

• In addition, these laboratories often are located in homes where children are present and may come into contact with hypophosphorous acid.

• A child can easily mistake hypophosphorous acid for any other clear liquid,

particularly if it is stored in household containers or drinking glasses.

• Skin, eye, or inhalation exposure can be extremely harmful or fatal.

Hypophosphorous Acid (H3PO2) (Continued)

• Safety Precautions

• Always wear a self-contained breathing apparatus as well as protective clothing when entering areas where hypophosphorous acid may be present.

• When in contact with metals or in a high-temperature environment,

hypophosphorous acid can break down and liberate phosphine and flammable hydrogen gas.

• Do not allow the use of open flames, open lights, matches, or smoking in or around laboratories or dumpsites where hypophosphorous acid is handled.

• In case of fire, use a self-contained positive pressure breathing apparatus and full

protective equipment.

• Use water spray, fog, foam, dry chemicals, or other reagents as may be

appropriate for materials in the surrounding fire.

• Water may be used to cool the containers of hypophosphorous acid; however, use extreme care to avoid allowing water to enter the container.

• In case of spills, neutralize the spilled chemical with alkaline material (soda ash, lime), then absorb it with an inert material such as vermiculite, dry sand, or earth

and place in a chemical waste container.

• Do not use combustible materials such as sawdust.

Hypophosphorous Acid (H3PO2) (Continued)

• Legislation and Control

• In the United States hypophosphorous acid is one of 38 chemicals (or groups of

chemicals) controlled under law by DEA.

• On October 17, 2001, hypophosphorous acid and its salts, along with red and white phosphorus, were officially added as List I chemicals under section 1310 of the

Code of Federal Regulations.

• List I chemicals are defined as chemicals that are used in the manufacture of a

controlled substance in violation of the Controlled Substances Act (CSA) and are

important to the manufacture of a controlled substance.

• Under the law, suppliers are required to maintain records and report receipts, sales,

imports, and exports of these chemicals to DEA.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid, red phosphorus, and white phosphorus, as well as

ephedrine, are unique in that suppliers are required to report all transactions of

these chemicals, regardless of the amount.

• By contrast, the other 34 listed chemicals are only reportable after a supplier's

transactions for a chemical reach an established weight or volume threshold in a calendar month.

• In addition to reporting all transactions involving the chemical, suppliers are

expected to "know their customers" in order to prevent the diversion of these substances to methamphetamine laboratories, as it is illegal to import, export,

purchase, or sell hypophosphorous acid or any other listed chemical in the United States if it is used or intended to be used in the production of a controlled

substance.

• Chemical suppliers are held liable for selling listed chemicals if they know or suspect that the chemical will be used for illicit purposes.

Hypophosphorous Acid (H3PO2) (Continued)

• Outlook

• The use of hypophosphorous acid in the production of methamphetamine is likely

to increase, particularly in the Midwest and Southwest regions of the United States

where methamphetamine production is prevalent.

– Injuries, property damage, and deaths also will increase as a growing number of

inexperienced methamphetamine producers experiment with hypophosphorous acid.

Anhydrous Ammonia

• Anhydrous ammonia is found in fertilizer, countertop cleaner, and commercial refrigerant.

– On its own, it has a pungent, suffocating odor.

• Mixing anhydrous ammonia with other chemicals can release highly toxic gases.

– Because anhydrous ammonia seeks out water (anhydrous means “without

water”) and causes severe burns, any body part that comes into contact with it

should be flushed with water for at least 15 minutes to remove the ammoniafrom the skin.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia has extremely destructive effects on humans.

– Anhydrous ammonia gives off vapors during cooking that can burn the mouth,

throat, and lung tissue.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Anhydrous ammonia seeks water from the nearest source, including the human body (anhydrous means “without water”).

– Because of their high moisture content, EYES, LUNGS, and SKIN are at the

greatest risk of attracting the ammonia.

• When large amounts of anhydrous ammonia are inhaled, the throat swells and the victim suffocates.

– Exposure to the vapors or liquids can cause severe burns, blindness, or death.

• Anhydrous ammonia has an IDLH (immediately dangerous to life and health) at

only 300 parts per million...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is poses MANY hazards, especially when it is placed in improper vessels and handled/transported by individuals unfamiliar with the

dangers.

• Anhydrous ammonia has a boiling point of -28 degrees below zero.

– When a vessel containing anhydrous ammonia is MOVED, the anhydrous

ammonia will reach its boiling point and pressurize.

•This pressurization can cause vessels to violently RUPTURE, or if the vessel pressurizes and does NOT rupture, the opening of the container of anhydrous

ammonia at a later time can cause RAPID, VIOLENT depressurization.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is mainly used in the U.S. as either a fertilizer or a refrigerant.

– Meth producers tend to store the anhydrous ammonia in IMPROPER/UNAPPROVED containers such as:

•Propane tanks,

• Igloo coolers, or

•Fire extinguishers.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia leaves a tell-tell sign as it flows through these UNAPPROVED

CONTAINERS – a blue or blue green discoloration on the valve.

– PAY ATTENTION to details!!!

Anhydrous Ammonia (Continued)

• Because propane cylinders (and the other unapproved containers) are NOT designed to store anhydrous ammonia, they can EXPLODE as the ammonia eats

through the walls of the cylinders.

– The valves, which take on a bluish/green color, frequently deteriorate and can cause hazardous leaks!!!

Anhydrous Ammonia (Continued)

• Do NOT touch, move, or open any kind of tank or sealed container!!!

– Be aware that propane tanks are often WEAKENED and BRITTLE due to the

anhydrous ammonia and are SENSITIVE to ANY kind of movement or impact.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• These pictures show what happened to a fire extinguisher that was used to store

anhydrous ammonia…

Anhydrous Ammonia (Continued)

• Illegal drug makers often STEAL anhydrous ammonia from areas where it is stored

and used, such as farms.

• Attempted thefts have also occurred at places such as:

– Refrigeration systems holding ammonia,

– Underground pipelines carrying ammonia, and

– Rail cars transporting anhydrous ammonia.

• Often thefts are aborted when thieves are injured or overcome by the toxic gas...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia thieves had better beware!!!

• There is a new product called GloTell that farmers can add to their anhydrous

ammonia tanks…

• Meth cooks will run the risk that the GloTell additive will turn their hands bright

pink!

– This bright pink stain will fluoresce under ultraviolet light even if washed off!!!

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Also, GloTell will produce pink methamphetamine that CANNOT be bleached.

– Users who snort meth made with GloTell will find that they have PINK NOSES!

– Users who inject meth made with GloTell will see a pink stain at the point of

injection!

Sodium Carbonate (Soda Ash)

Sodium Carbonate (Soda Ash) (Continued)

Lead Acetate

Iodine

• Iodine is a natural element, and it is helpful to the body in SMALL amounts.

– However, if iodine is taken in large amounts it can become toxic.

•Extremely high does of iodine can limit the function of the thyroid.

Iodine (Continued)

Iodine (Continued)

• Iodine is bluish-black, and it has a characteristic odor, a sharp acrid taste, and it produces a violet corrosive vapor.

– The vapor is irritating to the respiratory system and eyes.

• The solid iodine irritates the eyes and may burn the skin, and it may cause severe

internal irritation and damage if ingested.

Iodine (Continued)

• Iodine is known as the “blue ingredient” in the production of meth (in the “red, white, and blue” method).

Iodine (Continued)

Iodine (Continued)

• It takes approximately 4 bottles of iodine tincture to produce 2 – 3 grams of meth.

Iodine (Continued)

Iodine (Continued)

• Iodine leaves distinctive yellow-blue or brown stains on surfaces in former methlabs.

Iodine (Continued)

Iodine (Continued)

Iodine (Continued)

• The only good thing about iodine is that it leaves yellow stains.

• If you see yellow stained coffee filters, gloves or paper towels, this could be an

indicator that you’re in a lab.

• If you see yellow stains, you can spray some starch on them.

– If they turn a purplish blue/black, it’s iodine.

• Iodine is the only substance that reacts with soluble starch to produce a purplish black color.

– The only way to get iodine vapor all over the walls is to cook meth.

Mercurous Chloride

Rock Salt

Hydrogen Chloride

• Hydrogen chloride gas is commercially available.

• Hydrogen chloride gas can also be made by mixing sulfuric acid and salt.

• Muriatic acid is simply hydrogen chloride gas suspended in water.

• Hydrogen chloride gas can be seen as a pale white smoke.

– It is a poisonous gas that can cause respiratory problems and death.

Hydrogen Chloride (Continued)

Ammonium Nitrate

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Hydriodic Acid

• Hydriodic acid is a corrosive acid that is colorless when freshly prepared.

– When hydriodic acid is exposed to light and air, it turns yellowish and brown.

• Hydriodic acid is a solution of hydrogen iodide gas in water.

• Hydriodic acid vapor is irritating to the respiratory system, skin, and eyes.

• Hydriodic acid liquid causes severe burns to the eyes and skin.

• If hydriodic acid is accidentally ingested, it can cause severe internal irritation and

damage.

Hydriodic Acid (Continued)

Catalyst Chemicals

• Catalyst Chemicals:

– Chemicals which SPEED UP a reaction process and/or cause it to go to GREATER COMPLETION.

Red Phosphorus

• Red phosphorus is found ON matchboxes, in road flares, and other explosives.

– Red Phosphorus IGNITES when OVERHEATED!!!

• By combining red phosphorus and iodine, you can easily create the highly

controlled substance known as hydriodic acid (which is an essential ingredient in making meth).

– Creating 2 – 3 grams of meth requires about 4 big boxes of matches.

Red Phosphorus (Continued)

• Red phosphorous is highly flammable and if it is overheated it can become white

phosphorous…

– White phosphorous is a volatile and highly explosive substance.

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Lithium

• Lithium is used in batteries.

• Lithium seriously burns the skin upon contact.

– It also reacts VIOLENTLY with WATER and is highly explosive.

Lithium (Continued)

• Lithium reacts VIOLENTLY with WATER, and if it is splashed in the eyes during

cooking it will cause blindness.

– Lithium is extremely caustic to all body tissues.

Lithium (Continued)

Lithium (Continued)

• Lithium metal is HIGHLY water reactive and it will BURN or EXPLODE if it comes into contact with WATER!

• Because of the moisture in your skin, it will burn exposed flesh.

• Lithium metal will DEGRADE when exposed to atmospheric moisture…

– This is why meth cooks store lithium metal in a solvent prior to use.

• It is typical to see harvested lithium strips in Coleman fuel or Mineral Spirits to prevent explosions.

•Large quantities can be harvested and saved in these containers until needed

for a cook.

Lithium (Continued)

• If you see battery shells in the trashcan, on the floor, etc. – this is a VERY GOOD

indicator that you might be entering a meth lab!

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

• Lithium catches fire when in contact with water...

Solvent Chemicals

• Solvent Chemicals:

– A medium (liquid) in which a chemical operation takes place.

• Solvent chemicals (UNLIKE the precursor chemicals) CAN be

substituted/interchanged.

Ether

• Ether was once called “sweet vitriol” because of its hypnotic effect.

• Ether is a highly flammable substance that is used as an anesthetic agent –

especially in third world countries where more expensive anesthesia is not available.

– While inhaling the ether, patients could undergo complete surgical procedures while otherwise awake without feeling pain or concern.

Ether (Continued)

• Ether can be obtained from engine starting fluid.

• Ether is a solvent and it is flammable.

– It is particularly hazardous because it can cause BOTH fire and explosion.

• It has been said that a quart of ether can “level” a small house.

Ethyl Ether (Continued)

Ethyl Ether (Continued)

• Ether is VERY flammable and is HEAVIER than air.

– NEVER use ether near flames or non-sparkless motors.

– Ether is very PUNGENT – even a small evaporated amount of ether is VERY noticeable.

Acetone

• Acetone can be found in nail polish remover or paint thinner.

– It is extremely flammable.

• In the setting of a meth lab where meth is being cooked with high heat, acetone is

very dangerous.

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Toluene

• Toluene is used in brake fluid.

– When working with brake fluid (toluene), be careful not to spill it on your car

because it will eat away the paint and chrome…

• You also have to be careful using toluene around other household chemicals

because its high concentration of polyethylene glycol can cause it to ignite in a

violent fireball.

• Toluene is powerful enough to dissolve rubber.

Toluene (Continued)

• Toluene is used to form meth crystals.

– The fumes toluene releases can cause brain damage or death.

Toluene (Continued)

Toluene (Continued)

Ethanol

Isopropanol

Isopropanol (Continued)

Isopropyl Alcohol

Methanol

Methanol (Continued)

Methanol (Continued)

Benzene

Benzene (Continued)

Which of these is NOT a common ingredient in Meth?

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Methamphetamine- PowerPoint

- Chemicals and Ingredients Used to Make Meth

CJUS 240

Economic Costs of Meth

• The economic cost of methamphetamine use in the U.S. reached $23.4 billion in

2005.

– This includes the burden of addiction, premature death, drug treatment, child

care, and cleaning of lab sites.

– This figure does NOT take into account the future needs of the meth user.

Concerns with ACTIVE Meth Labs

• Danger of fire and explosion

• Chemical spills

• Inhalation of solvents, corrosives, and toxic gases

• “Booby traps”

• Waste disposal

Concerns with FORMER Meth Labs

• Vapors

• Chemical residues

• Methamphetamine residues

• Waste disposal

Equipment Used in Meth Production

• Pyrex or Corning dishes

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

• Coffee Filters

Equipment Used in Meth Production

Equipment Used in Meth Production

Basic Chemical Requirements

• In a clandestine laboratory, basic types of chemicals are necessary in order to

produce the desired drug.

– The basic types of chemicals needed are:

1) Precursor Chemicals

2) Reagent Chemicals

3) Catalyst Chemicals

4) Solvent Chemicals

List I Chemical

• The term “List I chemical” means a chemical specified by regulation of the Attorney General as a chemical that is used in manufacturing a controlled substance and is

IMPORTANT to the manufacture of the controlled substance.

• Examples of List I chemicals are:

– GBL

– Red Phosphorus

– Pseudoephedrine

List II Chemical

• The term “List II chemical” means a chemical (other than a List I chemical) specified by regulation of the Attorney General as a chemical that is USED in

manufacturing a controlled substance.

• Examples of List II chemicals are:

– Toluene

– Iodine

– Hydrochloric Acid

Precursor Chemicals

• Precursor Chemicals:

– A chemical that is ESSENTIAL to the production of a controlled substance and for

which NO SUBSTITUTION can be made.

Pseudoephedrine

• Pseudoephedrine is a decongestant found in cold medicine.

– Large amounts of pseudoephedrine on its own can harm the respiratory and nervous systems, as well as the heart.

Pseudoephedrine (Continued)

• Some of the common ways used to divert products containing pseudoephedrine

include:

– “Smurfing” – making multiple purchases at different locations

– Shelf-Sweeping – the theft of all shelf stock

– Shoplifting

– Theft from wholesalers

Pseudoephedrine (Continued)

• Pseudoephedrine smurfing is a method used by some methamphetamine producers to acquire large quantities of pseudoephedrine by enlisting the assistance of several friends or associates (often referred to as “smurfers”) to make purchases at or below the legal thresholds from multiple retail locations.

– Smurfers are often addicts who trade the pseudoephedrine for finished

methamphetamine.

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

• About 680 pseudoephedrine tablets are needed to produce one ounce of meth…

Pseudoephedrine (Continued)

Out With a Bang

An Unstable Recipe…

• Meth contains a variety of poisonous ingredients…

– Some become EVEN MORE DANGEROUS once the cooking process begins…

Common Ingredients to Make Methamphetamine

Reagent Chemicals

• Reagent Chemicals:

– Chemicals which REACT upon the precursor chemical causing it to chemicallyCHANGE.

• A reagent chemical is a chemical which is required for the synthesis of an illicit drug substance, but which is NOT incorporated into the final chemical product.

Hydrochloric Acid

• Hydrochloric acid is a highly corrosive liquid that is used to make plastic (such as PVC pipe and polyurethane).

– It can remove rust and iron-oxide from steel and is highly corrosive to human

skin.

•Hydrochloric acid makes up the majority of the gastric acid in the human

digestive fluid.

• In high concentrations, hydrochloric acid will literally eat away human flesh…

Hydrochloric Acid (Continued)

• Hydrochloric acid can be purchased from hardware stores as:

– Tile and Grout Acid Cleaner

– Muriatic Acid

– Pool Acid

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

• Hydrochloric acid is a solution of hydrogen chloride gas suspended in water.

– Hydrochloric acid is corrosive and is a light yellow liquid color from traces of iron, chlorine, and organic matter.

• Inhaling hydrochloric acid may cause coughing or choking, inflammation, and

ulceration of the respiratory tract.

• Concentrated solutions of hydrochloric acid can cause severe burns and irritate the

mucous membranes, eyes, and respiratory tract.

– Exposure to hydrochloric acid vapors may result in pulmonary edema and

possibly death.

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

Sodium Hydroxide (NaOH)

• Sodium hydroxide is also called Lye.

• Sodium hydroxide is classified as a corrosive, and it is one of the main chemicals in

drain cleaner.

– It is also used in aluminum etching and to create biodiesal.

– It can burn the skin or cause blindness.

• Sodium hydroxide is used to dispose of road kill because it turns the dead bodies

into a coffee-like liquid.

Sodium Hydroxide (NaOH) (Continued)

• Drain cleaner (sodium hydroxide) is extremely corrosive, and without wearing

protection, even the smallest spill on the skin can eat through flesh…

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sulfuric Acid (H2SO4)

• Sulfuric acid is used in drain or toilet bowl cleaner as well as battery acid.

– It is another highly corrosive substance that burns the skin on contact.

Sulfuric Acid (H2SO4) (Continued)

• The product label warning for Drano® (sulfuric acid) says it all:

– DANGER: MAY BURN EYES AND SKIN ON CONTACT.

•HARMFUL IF SWALLOWED.

–Avoid contact with body and clothing.

•TOXIC GAS MAY FORM IF MIXED WITH OTHER CHEMICALS.

–If gases are released, leave immediately and ventilate area.

•FIRST AID: Give Immediately:

–EYES AND SKIN:

»Flush with water for 20 minutes.

»Remove affected clothing.

–IF SWALLOWED:

»Rinse mouth and drink a glass of water or milk.

»Do not induce vomiting.

–THEN SEEK MEDICAL AID.

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Hypophosphorous Acid (H3PO2)

• Hypophosphorous acid, which is used legally for a variety of commercial purposes,

is a chemical that increasingly is substituted for red phosphorus in the methamphetamine production process.

– The use of hypophospherous acid SIGNIFICANTLY increases the risk of fire!!!

• The federal government regulates the sale of hypophosphorous acid through registration, record keeping, reporting, and import/export requirements regardless of the quantity being handled or distributed.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid is a colorless oily liquid that emits a SOUR odor.

– There is an extreme fire and explosion hazard if the hypophosphorous acid

comes into contact with a solvent such as acetone, toluene, or Coleman fuel.

• Hypophosphorous acid will also emit phosphine gas and the fumes can ignite.

Hypophosphorous Acid (H3PO2) (Continued)

• Although hypophosphorous acid is a List I chemical under the Controlled Substances Act, methamphetamine producers typically purchase the chemical via

the internet or from associates who also are engaged in methamphetamineproduction.

– The use of hypophosphorous acid in methamphetamine production is an

EXTREMELY DANGEROUS PRACTICE because of the deadly gases that can be generated as well as the risk of fire or explosion.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid (H3PO2, also called phosphinic acid) is a strong acid that

typically is prepared as a solution of colorless, oily liquid in strengths of 50%, 30 to 32%, and 10%.

– It also is prepared in the form of salts (referred to as hypophosphite salts), particularly ammonium hypophosphite, calcium hypophosphite, iron (ferric)

hypophosphite, magnesium hypophosphite, manganese hypophosphite, potassium hypophosphite, and sodium hypophosphite.

Hypophosphorous Acid (H3PO2) (Continued)

• Over 100 chemical firms located throughout the world produce hypophosphorous

acid.

– The People's Republic of China and India have the largest numbers of

hypophosphorous acid producers, although there are a few producers in the United States.

• There are a wide variety of uses for hypophosphorous acid and its salts in

commercial industry; however, the chemicals have no legitimate household or retail uses.

Hypophosphorous Acid (H3PO2) (Continued)

• The legitimate commercial and laboratory fields that use hypophosphorous acid and its salts include the following:

– Chemical plating

– Food preparation

– Water treatment

– Polymers (as a bleaching agent, color stabilizer, or catalyst)

– Education and research in analytical chemistry

Hypophosphorous Acid (H3PO2) (Continued)

• Chemical suppliers typically distribute hypophosphorous acid in large quantities, for example, in drums containing 275 pounds of the diluted solution.

– Hypophosphorous acid also is distributed in smaller quantities.

• One-half liter of 50% concentrate hypophosphorous acid solution can be obtained from chemical suppliers for as little as $14.

Hypophosphorous Acid (H3PO2) (Continued)

• Methamphetamine laboratory operators typically obtain small quantities of the chemical from other laboratory operators who purchase large quantities of the

chemical and repackage it for further distribution.

– According to law enforcement sources, these individuals sell hypophosphorous acid for as much as $1,000 per half-liter.

•Methamphetamine laboratory operators also purchase hypophosphorous acidvia the internet.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid and the Internet

• The internet is a source of a great deal of information regarding hypophosphorous acid.

• Popular internet sites that disseminate information about illicit drugs contain information about the chemical, including numerous recipes for home production of

methamphetamine using hypophosphorous acid.

• There also are recipes for synthesizing hypophosphorous acid from available chemicals.

• Hypophosphorous acid solutions and salts have been sold to the general public via the internet.

• The Drug Enforcement Administration (DEA) has strong concerns regarding the sale

of chemicals on the internet and has requested that any sites (such as auction sites) that allow the sale of regulated chemicals on their domains require proof of

DEA registration from their clients.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid Used in Methamphetamine Production

• Hypophosphorous acid is used in the ephedrine-pseudoephedrine reduction method

of methamphetamine production.

– It is used in the methamphetamine production process to produce hydriodic acid,

an important reagent (it reacts with the ephedrine-pseudoephedrine but does NOT become part of the finished product).

Hypophosphorous Acid (H3PO2) (Continued)

• The regulation of hydriodic acid by DEA in 1993 rendered it virtually unavailable in

the United States.

– However, methamphetamine laboratory operators discovered methods to

produce hydriodic acid using a combination of iodine in water with red phosphorus.

• Laboratory operators found that red phosphorus could be obtained easily, either

from commercial supply companies or by scraping the striker pads from matchbooks or matchboxes.

• Methamphetamine producers soon discovered that hypophosphorous acid ALSO could be used in combination with iodine and water to produce hydriodic acid.

Hypophosphorous Acid (H3PO2) (Continued)

• The practice of using hypophosphorous acid in methamphetamine production is

believed to have begun in the United States in the late 1990s when a methamphetamine producer in Colorado obtained the recipe from Australia, where

the hypophosphorous acid method is prevalent.

– This man was known as a serial cook who had a long history of

methamphetamine production.

•Over several years he trained other laboratory operators in Colorado to produce methamphetamine using hypophosphorous acid.

• As his techniques were passed on to others, the number of methamphetaminelaboratories in Colorado using hypophosphorous acid continued to increase, and the

technique was passed on to numerous methamphetamine producers in other

states.

Hypophosphorous Acid (H3PO2) (Continued)

• According to the El Paso Intelligence Center (EPIC) National Clandestine Laboratory

Seizure System, from 2000 through 2002 the number of seized methamphetaminelaboratories in the United States in which hypophosphorous acid was found

increased overall. (See Table 1.)

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid found at methamphetamine laboratories is packaged in a variety of ways.

• The chemical has been found in 1-gallon bottles of solution or in 1-pound jars of salts.

• Some hypophosphorous acid containers are labeled as "plating solution."

• Pint-sized brown glass bottles wrapped in red electrical tape also have been found to contain hypophosphorous acid; they have been discovered primarily in Colorado.

• The vast majority of hypophosphorous acid found at laboratory sites has been recovered from small toxic laboratories (STLs), those which yield gram to ounce

quantities per production cycle.

• Hypophosphorous acid has not been reported at large-scale laboratories operated by Mexican criminal groups in the United States.

Hypophosphorous Acid (H3PO2) (Continued)

• Hazards

• The iodine-hypophosphorous acid method is MORE HAZORDOUS than the iodine-

red phosphorus method, although the reaction using hypophosphorous acid is

faster and gives slightly higher yields.

– When hypophosphorous acid is used, the chemicals must be mixed together

SLOWLY in a PARTICULAR ORDER to prevent them from reacting violently.

Hypophosphorous Acid (H3PO2) (Continued)

• The combination of hypophosphorous acid with the other chemicals and with

certain metals can produce deadly phosphine gas during the initial mixing step and can CONTINUE to produce phosphine gas for several days AFTER production has been completed…

Hypophosphorous Acid (H3PO2) (Continued)

• The iodine-hypophosphorous acid mixture has a tendency to decompose quickly when overheated or if heated for long periods of time, becoming cloudy or "milky-

white" just prior to giving off a cloud of phosphine gas that can ignite spontaneously.

– Hypophosphorous acid solutions may become unstable if evaporation results in

concentrations above 50%.

Hypophosphorous Acid (H3PO2) (Continued)

• [Note: Law enforcement or emergency personnel who encounter suspected containers of hypophosphorous acid should use extreme care during handling because laboratory operators often attempt to obtain a more concentrated acid by

allowing water to evaporate from the mixture.]

• Because hypophosphorous acid often is used at small methamphetaminelaboratories operated by inexperienced or careless individuals, the potential hazards

of using this method are even greater.

• The risk of fire and explosion is higher in these laboratories, where professional

laboratory equipment typically is not used to contain the phosphine gas and where

safe handling precautions are not employed.

• In addition, these laboratories often are located in homes where children are

present and may come into contact with hypophosphorous acid.

• A child can easily mistake hypophosphorous acid for any other clear liquid,

particularly if it is stored in household containers or drinking glasses.

• Skin, eye, or inhalation exposure can be extremely harmful or fatal.

Hypophosphorous Acid (H3PO2) (Continued)

• Safety Precautions

• Always wear a self-contained breathing apparatus as well as protective clothing when entering areas where hypophosphorous acid may be present.

• When in contact with metals or in a high-temperature environment,

hypophosphorous acid can break down and liberate phosphine and flammable hydrogen gas.

• Do not allow the use of open flames, open lights, matches, or smoking in or around laboratories or dumpsites where hypophosphorous acid is handled.

• In case of fire, use a self-contained positive pressure breathing apparatus and full

protective equipment.

• Use water spray, fog, foam, dry chemicals, or other reagents as may be

appropriate for materials in the surrounding fire.

• Water may be used to cool the containers of hypophosphorous acid; however, use extreme care to avoid allowing water to enter the container.

• In case of spills, neutralize the spilled chemical with alkaline material (soda ash, lime), then absorb it with an inert material such as vermiculite, dry sand, or earth

and place in a chemical waste container.

• Do not use combustible materials such as sawdust.

Hypophosphorous Acid (H3PO2) (Continued)

• Legislation and Control

• In the United States hypophosphorous acid is one of 38 chemicals (or groups of

chemicals) controlled under law by DEA.

• On October 17, 2001, hypophosphorous acid and its salts, along with red and white phosphorus, were officially added as List I chemicals under section 1310 of the

Code of Federal Regulations.

• List I chemicals are defined as chemicals that are used in the manufacture of a

controlled substance in violation of the Controlled Substances Act (CSA) and are

important to the manufacture of a controlled substance.

• Under the law, suppliers are required to maintain records and report receipts, sales,

imports, and exports of these chemicals to DEA.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid, red phosphorus, and white phosphorus, as well as

ephedrine, are unique in that suppliers are required to report all transactions of

these chemicals, regardless of the amount.

• By contrast, the other 34 listed chemicals are only reportable after a supplier's

transactions for a chemical reach an established weight or volume threshold in a calendar month.

• In addition to reporting all transactions involving the chemical, suppliers are

expected to "know their customers" in order to prevent the diversion of these substances to methamphetamine laboratories, as it is illegal to import, export,

purchase, or sell hypophosphorous acid or any other listed chemical in the United States if it is used or intended to be used in the production of a controlled

substance.

• Chemical suppliers are held liable for selling listed chemicals if they know or suspect that the chemical will be used for illicit purposes.

Hypophosphorous Acid (H3PO2) (Continued)

• Outlook

• The use of hypophosphorous acid in the production of methamphetamine is likely

to increase, particularly in the Midwest and Southwest regions of the United States

where methamphetamine production is prevalent.

– Injuries, property damage, and deaths also will increase as a growing number of

inexperienced methamphetamine producers experiment with hypophosphorous acid.

Anhydrous Ammonia

• Anhydrous ammonia is found in fertilizer, countertop cleaner, and commercial refrigerant.

– On its own, it has a pungent, suffocating odor.

• Mixing anhydrous ammonia with other chemicals can release highly toxic gases.

– Because anhydrous ammonia seeks out water (anhydrous means “without water”) and causes severe burns, any body part that comes into contact with it

should be flushed with water for at least 15 minutes to remove the ammoniafrom the skin.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia has extremely destructive effects on humans.

– Anhydrous ammonia gives off vapors during cooking that can burn the mouth,

throat, and lung tissue.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Anhydrous ammonia seeks water from the nearest source, including the human body (anhydrous means “without water”).

– Because of their high moisture content, EYES, LUNGS, and SKIN are at the

greatest risk of attracting the ammonia.

• When large amounts of anhydrous ammonia are inhaled, the throat swells and the

victim suffocates.

– Exposure to the vapors or liquids can cause severe burns, blindness, or death.

• Anhydrous ammonia has an IDLH (immediately dangerous to life and health) at

only 300 parts per million...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is poses MANY hazards, especially when it is placed in improper vessels and handled/transported by individuals unfamiliar with the

dangers.

• Anhydrous ammonia has a boiling point of -28 degrees below zero.

– When a vessel containing anhydrous ammonia is MOVED, the anhydrous ammonia will reach its boiling point and pressurize.

•This pressurization can cause vessels to violently RUPTURE, or if the vessel pressurizes and does NOT rupture, the opening of the container of anhydrous

ammonia at a later time can cause RAPID, VIOLENT depressurization.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is mainly used in the U.S. as either a fertilizer or a refrigerant.

– Meth producers tend to store the anhydrous ammonia in IMPROPER/UNAPPROVED containers such as:

•Propane tanks,

• Igloo coolers, or

•Fire extinguishers.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia leaves a tell-tell sign as it flows through these UNAPPROVED

CONTAINERS – a blue or blue green discoloration on the valve.

– PAY ATTENTION to details!!!

Anhydrous Ammonia (Continued)

• Because propane cylinders (and the other unapproved containers) are NOT designed to store anhydrous ammonia, they can EXPLODE as the ammonia eats

through the walls of the cylinders.

– The valves, which take on a bluish/green color, frequently deteriorate and can cause hazardous leaks!!!

Anhydrous Ammonia (Continued)

• Do NOT touch, move, or open any kind of tank or sealed container!!!

– Be aware that propane tanks are often WEAKENED and BRITTLE due to the

anhydrous ammonia and are SENSITIVE to ANY kind of movement or impact.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• These pictures show what happened to a fire extinguisher that was used to store

anhydrous ammonia…

Anhydrous Ammonia (Continued)

• Illegal drug makers often STEAL anhydrous ammonia from areas where it is stored

and used, such as farms.

• Attempted thefts have also occurred at places such as:

– Refrigeration systems holding ammonia,

– Underground pipelines carrying ammonia, and

– Rail cars transporting anhydrous ammonia.

• Often thefts are aborted when thieves are injured or overcome by the toxic gas...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia thieves had better beware!!!

• There is a new product called GloTell that farmers can add to their anhydrous

ammonia tanks…

• Meth cooks will run the risk that the GloTell additive will turn their hands bright

pink!

– This bright pink stain will fluoresce under ultraviolet light even if washed off!!!

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Also, GloTell will produce pink methamphetamine that CANNOT be bleached.

– Users who snort meth made with GloTell will find that they have PINK NOSES!

– Users who inject meth made with GloTell will see a pink stain at the point of

injection!

Sodium Carbonate (Soda Ash)

Sodium Carbonate (Soda Ash) (Continued)

Lead Acetate

Iodine

• Iodine is a natural element, and it is helpful to the body in SMALL amounts.

– However, if iodine is taken in large amounts it can become toxic.

•Extremely high does of iodine can limit the function of the thyroid.

Iodine (Continued)

Iodine (Continued)

• Iodine is bluish-black, and it has a characteristic odor, a sharp acrid taste, and it produces a violet corrosive vapor.

– The vapor is irritating to the respiratory system and eyes.

• The solid iodine irritates the eyes and may burn the skin, and it may cause severe

internal irritation and damage if ingested.

Iodine (Continued)

• Iodine is known as the “blue ingredient” in the production of meth (in the “red, white, and blue” method).

Iodine (Continued)

Iodine (Continued)

• It takes approximately 4 bottles of iodine tincture to produce 2 – 3 grams of meth.

Iodine (Continued)

Iodine (Continued)

• Iodine leaves distinctive yellow-blue or brown stains on surfaces in former methlabs.

Iodine (Continued)

Iodine (Continued)

Iodine (Continued)

• The only good thing about iodine is that it leaves yellow stains.

• If you see yellow stained coffee filters, gloves or paper towels, this could be an

indicator that you’re in a lab.

• If you see yellow stains, you can spray some starch on them.

– If they turn a purplish blue/black, it’s iodine.

• Iodine is the only substance that reacts with soluble starch to produce a purplish black color.

– The only way to get iodine vapor all over the walls is to cook meth.

Mercurous Chloride

Rock Salt

Hydrogen Chloride

• Hydrogen chloride gas is commercially available.

• Hydrogen chloride gas can also be made by mixing sulfuric acid and salt.

• Muriatic acid is simply hydrogen chloride gas suspended in water.

• Hydrogen chloride gas can be seen as a pale white smoke.

– It is a poisonous gas that can cause respiratory problems and death.

Hydrogen Chloride (Continued)

Ammonium Nitrate

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Hydriodic Acid

• Hydriodic acid is a corrosive acid that is colorless when freshly prepared.

– When hydriodic acid is exposed to light and air, it turns yellowish and brown.

• Hydriodic acid is a solution of hydrogen iodide gas in water.

• Hydriodic acid vapor is irritating to the respiratory system, skin, and eyes.

• Hydriodic acid liquid causes severe burns to the eyes and skin.

• If hydriodic acid is accidentally ingested, it can cause severe internal irritation and

damage.

Hydriodic Acid (Continued)

Catalyst Chemicals

• Catalyst Chemicals:

– Chemicals which SPEED UP a reaction process and/or cause it to go to GREATER COMPLETION.

Red Phosphorus

• Red phosphorus is found ON matchboxes, in road flares, and other explosives.

– Red Phosphorus IGNITES when OVERHEATED!!!

• By combining red phosphorus and iodine, you can easily create the highly

controlled substance known as hydriodic acid (which is an essential ingredient in making meth).

– Creating 2 – 3 grams of meth requires about 4 big boxes of matches.

Red Phosphorus (Continued)

• Red phosphorous is highly flammable and if it is overheated it can become white

phosphorous…

– White phosphorous is a volatile and highly explosive substance.

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Lithium

• Lithium is used in batteries.

• Lithium seriously burns the skin upon contact.

– It also reacts VIOLENTLY with WATER and is highly explosive.

Lithium (Continued)

• Lithium reacts VIOLENTLY with WATER, and if it is splashed in the eyes during

cooking it will cause blindness.

– Lithium is extremely caustic to all body tissues.

Lithium (Continued)

Lithium (Continued)

• Lithium metal is HIGHLY water reactive and it will BURN or EXPLODE if it comes into contact with WATER!

• Because of the moisture in your skin, it will burn exposed flesh.

• Lithium metal will DEGRADE when exposed to atmospheric moisture…

– This is why meth cooks store lithium metal in a solvent prior to use.

• It is typical to see harvested lithium strips in Coleman fuel or Mineral Spirits to prevent explosions.

•Large quantities can be harvested and saved in these containers until needed

for a cook.

Lithium (Continued)

• If you see battery shells in the trashcan, on the floor, etc. – this is a VERY GOOD

indicator that you might be entering a meth lab!

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

• Lithium catches fire when in contact with water...

Solvent Chemicals

• Solvent Chemicals:

– A medium (liquid) in which a chemical operation takes place.

• Solvent chemicals (UNLIKE the precursor chemicals) CAN be

substituted/interchanged.

Ether

• Ether was once called “sweet vitriol” because of its hypnotic effect.

• Ether is a highly flammable substance that is used as an anesthetic agent –

especially in third world countries where more expensive anesthesia is not available.

– While inhaling the ether, patients could undergo complete surgical procedures while otherwise awake without feeling pain or concern.

Ether (Continued)

• Ether can be obtained from engine starting fluid.

• Ether is a solvent and it is flammable.

– It is particularly hazardous because it can cause BOTH fire and explosion.

• It has been said that a quart of ether can “level” a small house.

Ethyl Ether (Continued)

Ethyl Ether (Continued)

• Ether is VERY flammable and is HEAVIER than air.

– NEVER use ether near flames or non-sparkless motors.

– Ether is very PUNGENT – even a small evaporated amount of ether is VERY noticeable.

Acetone

• Acetone can be found in nail polish remover or paint thinner.

– It is extremely flammable.

• In the setting of a meth lab where meth is being cooked with high heat, acetone is

very dangerous.

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Toluene

• Toluene is used in brake fluid.

– When working with brake fluid (toluene), be careful not to spill it on your car

because it will eat away the paint and chrome…

• You also have to be careful using toluene around other household chemicals

because its high concentration of polyethylene glycol can cause it to ignite in a

violent fireball.

• Toluene is powerful enough to dissolve rubber.

Toluene (Continued)

• Toluene is used to form meth crystals.

– The fumes toluene releases can cause brain damage or death.

Toluene (Continued)

Toluene (Continued)

Ethanol

Isopropanol

Isopropanol (Continued)

Isopropyl Alcohol

Methanol

Methanol (Continued)

Methanol (Continued)

Benzene

Benzene (Continued)

Which of these is NOT a common ingredient in Meth?

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Page 12: Methamphetamine - PowerPoint - Chemicals and Ingredients ... · 2/5/2014 1 Methamphetamine - PowerPoint - Chemicals and Ingredients Used to Make Meth CJUS 240 Economic Costs of Meth

2/5/2014

12

Methamphetamine- PowerPoint

- Chemicals and Ingredients Used to Make Meth

CJUS 240

Economic Costs of Meth

• The economic cost of methamphetamine use in the U.S. reached $23.4 billion in

2005.

– This includes the burden of addiction, premature death, drug treatment, child

care, and cleaning of lab sites.

– This figure does NOT take into account the future needs of the meth user.

Concerns with ACTIVE Meth Labs

• Danger of fire and explosion

• Chemical spills

• Inhalation of solvents, corrosives, and toxic gases

• “Booby traps”

• Waste disposal

Concerns with FORMER Meth Labs

• Vapors

• Chemical residues

• Methamphetamine residues

• Waste disposal

Equipment Used in Meth Production

• Pyrex or Corning dishes

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

• Coffee Filters

Equipment Used in Meth Production

Equipment Used in Meth Production

Basic Chemical Requirements

• In a clandestine laboratory, basic types of chemicals are necessary in order to

produce the desired drug.

– The basic types of chemicals needed are:

1) Precursor Chemicals

2) Reagent Chemicals

3) Catalyst Chemicals

4) Solvent Chemicals

List I Chemical

• The term “List I chemical” means a chemical specified by regulation of the Attorney General as a chemical that is used in manufacturing a controlled substance and is

IMPORTANT to the manufacture of the controlled substance.

• Examples of List I chemicals are:

– GBL

– Red Phosphorus

– Pseudoephedrine

List II Chemical

• The term “List II chemical” means a chemical (other than a List I chemical) specified by regulation of the Attorney General as a chemical that is USED in

manufacturing a controlled substance.

• Examples of List II chemicals are:

– Toluene

– Iodine

– Hydrochloric Acid

Precursor Chemicals

• Precursor Chemicals:

– A chemical that is ESSENTIAL to the production of a controlled substance and for

which NO SUBSTITUTION can be made.

Pseudoephedrine

• Pseudoephedrine is a decongestant found in cold medicine.

– Large amounts of pseudoephedrine on its own can harm the respiratory and nervous systems, as well as the heart.

Pseudoephedrine (Continued)

• Some of the common ways used to divert products containing pseudoephedrineinclude:

– “Smurfing” – making multiple purchases at different locations

– Shelf-Sweeping – the theft of all shelf stock

– Shoplifting

– Theft from wholesalers

Pseudoephedrine (Continued)

• Pseudoephedrine smurfing is a method used by some methamphetamine producers to acquire large quantities of pseudoephedrine by enlisting the assistance of several

friends or associates (often referred to as “smurfers”) to make purchases at or below the legal thresholds from multiple retail locations.

– Smurfers are often addicts who trade the pseudoephedrine for finished

methamphetamine.

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

• About 680 pseudoephedrine tablets are needed to produce one ounce of meth…

Pseudoephedrine (Continued)

Out With a Bang

An Unstable Recipe…

• Meth contains a variety of poisonous ingredients…

– Some become EVEN MORE DANGEROUS once the cooking process begins…

Common Ingredients to Make Methamphetamine

Reagent Chemicals

• Reagent Chemicals:

– Chemicals which REACT upon the precursor chemical causing it to chemicallyCHANGE.

• A reagent chemical is a chemical which is required for the synthesis of an illicit drug substance, but which is NOT incorporated into the final chemical product.

Hydrochloric Acid

• Hydrochloric acid is a highly corrosive liquid that is used to make plastic (such as PVC pipe and polyurethane).

– It can remove rust and iron-oxide from steel and is highly corrosive to human

skin.

•Hydrochloric acid makes up the majority of the gastric acid in the human

digestive fluid.

• In high concentrations, hydrochloric acid will literally eat away human flesh…

Hydrochloric Acid (Continued)

• Hydrochloric acid can be purchased from hardware stores as:

– Tile and Grout Acid Cleaner

– Muriatic Acid

– Pool Acid

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

• Hydrochloric acid is a solution of hydrogen chloride gas suspended in water.

– Hydrochloric acid is corrosive and is a light yellow liquid color from traces of iron, chlorine, and organic matter.

• Inhaling hydrochloric acid may cause coughing or choking, inflammation, and

ulceration of the respiratory tract.

• Concentrated solutions of hydrochloric acid can cause severe burns and irritate the

mucous membranes, eyes, and respiratory tract.

– Exposure to hydrochloric acid vapors may result in pulmonary edema and

possibly death.

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

Sodium Hydroxide (NaOH)

• Sodium hydroxide is also called Lye.

• Sodium hydroxide is classified as a corrosive, and it is one of the main chemicals in

drain cleaner.

– It is also used in aluminum etching and to create biodiesal.

– It can burn the skin or cause blindness.

• Sodium hydroxide is used to dispose of road kill because it turns the dead bodies

into a coffee-like liquid.

Sodium Hydroxide (NaOH) (Continued)

• Drain cleaner (sodium hydroxide) is extremely corrosive, and without wearing

protection, even the smallest spill on the skin can eat through flesh…

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sulfuric Acid (H2SO4)

• Sulfuric acid is used in drain or toilet bowl cleaner as well as battery acid.

– It is another highly corrosive substance that burns the skin on contact.

Sulfuric Acid (H2SO4) (Continued)

• The product label warning for Drano® (sulfuric acid) says it all:

– DANGER: MAY BURN EYES AND SKIN ON CONTACT.

•HARMFUL IF SWALLOWED.

–Avoid contact with body and clothing.

•TOXIC GAS MAY FORM IF MIXED WITH OTHER CHEMICALS.

–If gases are released, leave immediately and ventilate area.

•FIRST AID: Give Immediately:

–EYES AND SKIN:

»Flush with water for 20 minutes.

»Remove affected clothing.

–IF SWALLOWED:

»Rinse mouth and drink a glass of water or milk.

»Do not induce vomiting.

–THEN SEEK MEDICAL AID.

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Hypophosphorous Acid (H3PO2)

• Hypophosphorous acid, which is used legally for a variety of commercial purposes,

is a chemical that increasingly is substituted for red phosphorus in the methamphetamine production process.

– The use of hypophospherous acid SIGNIFICANTLY increases the risk of fire!!!

• The federal government regulates the sale of hypophosphorous acid through registration, record keeping, reporting, and import/export requirements regardless

of the quantity being handled or distributed.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid is a colorless oily liquid that emits a SOUR odor.

– There is an extreme fire and explosion hazard if the hypophosphorous acid

comes into contact with a solvent such as acetone, toluene, or Coleman fuel.

• Hypophosphorous acid will also emit phosphine gas and the fumes can ignite.

Hypophosphorous Acid (H3PO2) (Continued)

• Although hypophosphorous acid is a List I chemical under the Controlled Substances Act, methamphetamine producers typically purchase the chemical via

the internet or from associates who also are engaged in methamphetamine

production.

– The use of hypophosphorous acid in methamphetamine production is an EXTREMELY DANGEROUS PRACTICE because of the deadly gases that can be generated as well as the risk of fire or explosion.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid (H3PO2, also called phosphinic acid) is a strong acid that

typically is prepared as a solution of colorless, oily liquid in strengths of 50%, 30 to 32%, and 10%.

– It also is prepared in the form of salts (referred to as hypophosphite salts), particularly ammonium hypophosphite, calcium hypophosphite, iron (ferric)

hypophosphite, magnesium hypophosphite, manganese hypophosphite,

potassium hypophosphite, and sodium hypophosphite.

Hypophosphorous Acid (H3PO2) (Continued)

• Over 100 chemical firms located throughout the world produce hypophosphorous

acid.

– The People's Republic of China and India have the largest numbers of

hypophosphorous acid producers, although there are a few producers in the United States.

• There are a wide variety of uses for hypophosphorous acid and its salts in

commercial industry; however, the chemicals have no legitimate household or retail uses.

Hypophosphorous Acid (H3PO2) (Continued)

• The legitimate commercial and laboratory fields that use hypophosphorous acid and its salts include the following:

– Chemical plating

– Food preparation

– Water treatment

– Polymers (as a bleaching agent, color stabilizer, or catalyst)

– Education and research in analytical chemistry

Hypophosphorous Acid (H3PO2) (Continued)

• Chemical suppliers typically distribute hypophosphorous acid in large quantities, for example, in drums containing 275 pounds of the diluted solution.

– Hypophosphorous acid also is distributed in smaller quantities.

• One-half liter of 50% concentrate hypophosphorous acid solution can be obtained from chemical suppliers for as little as $14.

Hypophosphorous Acid (H3PO2) (Continued)

• Methamphetamine laboratory operators typically obtain small quantities of the chemical from other laboratory operators who purchase large quantities of the

chemical and repackage it for further distribution.

– According to law enforcement sources, these individuals sell hypophosphorous acid for as much as $1,000 per half-liter.

•Methamphetamine laboratory operators also purchase hypophosphorous acidvia the internet.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid and the Internet

• The internet is a source of a great deal of information regarding hypophosphorous acid.

• Popular internet sites that disseminate information about illicit drugs contain information about the chemical, including numerous recipes for home production of

methamphetamine using hypophosphorous acid.

• There also are recipes for synthesizing hypophosphorous acid from available chemicals.

• Hypophosphorous acid solutions and salts have been sold to the general public via the internet.

• The Drug Enforcement Administration (DEA) has strong concerns regarding the sale

of chemicals on the internet and has requested that any sites (such as auction sites) that allow the sale of regulated chemicals on their domains require proof of

DEA registration from their clients.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid Used in Methamphetamine Production

• Hypophosphorous acid is used in the ephedrine-pseudoephedrine reduction method

of methamphetamine production.

– It is used in the methamphetamine production process to produce hydriodic acid,

an important reagent (it reacts with the ephedrine-pseudoephedrine but does NOT become part of the finished product).

Hypophosphorous Acid (H3PO2) (Continued)

• The regulation of hydriodic acid by DEA in 1993 rendered it virtually unavailable in

the United States.

– However, methamphetamine laboratory operators discovered methods to

produce hydriodic acid using a combination of iodine in water with red phosphorus.

• Laboratory operators found that red phosphorus could be obtained easily, either

from commercial supply companies or by scraping the striker pads from matchbooks or matchboxes.

• Methamphetamine producers soon discovered that hypophosphorous acid ALSO could be used in combination with iodine and water to produce hydriodic acid.

Hypophosphorous Acid (H3PO2) (Continued)

• The practice of using hypophosphorous acid in methamphetamine production is

believed to have begun in the United States in the late 1990s when a methamphetamine producer in Colorado obtained the recipe from Australia, where

the hypophosphorous acid method is prevalent.

– This man was known as a serial cook who had a long history of

methamphetamine production.

•Over several years he trained other laboratory operators in Colorado to produce methamphetamine using hypophosphorous acid.

• As his techniques were passed on to others, the number of methamphetaminelaboratories in Colorado using hypophosphorous acid continued to increase, and the technique was passed on to numerous methamphetamine producers in other

states.

Hypophosphorous Acid (H3PO2) (Continued)

• According to the El Paso Intelligence Center (EPIC) National Clandestine Laboratory

Seizure System, from 2000 through 2002 the number of seized methamphetaminelaboratories in the United States in which hypophosphorous acid was found

increased overall. (See Table 1.)

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid found at methamphetamine laboratories is packaged in a variety of ways.

• The chemical has been found in 1-gallon bottles of solution or in 1-pound jars of salts.

• Some hypophosphorous acid containers are labeled as "plating solution."

• Pint-sized brown glass bottles wrapped in red electrical tape also have been found to contain hypophosphorous acid; they have been discovered primarily in Colorado.

• The vast majority of hypophosphorous acid found at laboratory sites has been recovered from small toxic laboratories (STLs), those which yield gram to ounce

quantities per production cycle.

• Hypophosphorous acid has not been reported at large-scale laboratories operated by Mexican criminal groups in the United States.

Hypophosphorous Acid (H3PO2) (Continued)

• Hazards

• The iodine-hypophosphorous acid method is MORE HAZORDOUS than the iodine-

red phosphorus method, although the reaction using hypophosphorous acid is

faster and gives slightly higher yields.

– When hypophosphorous acid is used, the chemicals must be mixed together

SLOWLY in a PARTICULAR ORDER to prevent them from reacting violently.

Hypophosphorous Acid (H3PO2) (Continued)

• The combination of hypophosphorous acid with the other chemicals and with

certain metals can produce deadly phosphine gas during the initial mixing step and

can CONTINUE to produce phosphine gas for several days AFTER production has been completed…

Hypophosphorous Acid (H3PO2) (Continued)

• The iodine-hypophosphorous acid mixture has a tendency to decompose quickly when overheated or if heated for long periods of time, becoming cloudy or "milky-

white" just prior to giving off a cloud of phosphine gas that can ignite spontaneously.

– Hypophosphorous acid solutions may become unstable if evaporation results in

concentrations above 50%.

Hypophosphorous Acid (H3PO2) (Continued)

• [Note: Law enforcement or emergency personnel who encounter suspected

containers of hypophosphorous acid should use extreme care during handling because laboratory operators often attempt to obtain a more concentrated acid by

allowing water to evaporate from the mixture.]

• Because hypophosphorous acid often is used at small methamphetaminelaboratories operated by inexperienced or careless individuals, the potential hazards

of using this method are even greater.

• The risk of fire and explosion is higher in these laboratories, where professional

laboratory equipment typically is not used to contain the phosphine gas and where

safe handling precautions are not employed.

• In addition, these laboratories often are located in homes where children are

present and may come into contact with hypophosphorous acid.

• A child can easily mistake hypophosphorous acid for any other clear liquid,

particularly if it is stored in household containers or drinking glasses.

• Skin, eye, or inhalation exposure can be extremely harmful or fatal.

Hypophosphorous Acid (H3PO2) (Continued)

• Safety Precautions

• Always wear a self-contained breathing apparatus as well as protective clothing when entering areas where hypophosphorous acid may be present.

• When in contact with metals or in a high-temperature environment,

hypophosphorous acid can break down and liberate phosphine and flammable hydrogen gas.

• Do not allow the use of open flames, open lights, matches, or smoking in or around laboratories or dumpsites where hypophosphorous acid is handled.

• In case of fire, use a self-contained positive pressure breathing apparatus and full protective equipment.

• Use water spray, fog, foam, dry chemicals, or other reagents as may be

appropriate for materials in the surrounding fire.

• Water may be used to cool the containers of hypophosphorous acid; however, use extreme care to avoid allowing water to enter the container.

• In case of spills, neutralize the spilled chemical with alkaline material (soda ash, lime), then absorb it with an inert material such as vermiculite, dry sand, or earth

and place in a chemical waste container.

• Do not use combustible materials such as sawdust.

Hypophosphorous Acid (H3PO2) (Continued)

• Legislation and Control

• In the United States hypophosphorous acid is one of 38 chemicals (or groups of

chemicals) controlled under law by DEA.

• On October 17, 2001, hypophosphorous acid and its salts, along with red and white phosphorus, were officially added as List I chemicals under section 1310 of the

Code of Federal Regulations.

• List I chemicals are defined as chemicals that are used in the manufacture of a

controlled substance in violation of the Controlled Substances Act (CSA) and are

important to the manufacture of a controlled substance.

• Under the law, suppliers are required to maintain records and report receipts, sales,

imports, and exports of these chemicals to DEA.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid, red phosphorus, and white phosphorus, as well as

ephedrine, are unique in that suppliers are required to report all transactions of

these chemicals, regardless of the amount.

• By contrast, the other 34 listed chemicals are only reportable after a supplier's

transactions for a chemical reach an established weight or volume threshold in a calendar month.

• In addition to reporting all transactions involving the chemical, suppliers are

expected to "know their customers" in order to prevent the diversion of these substances to methamphetamine laboratories, as it is illegal to import, export,

purchase, or sell hypophosphorous acid or any other listed chemical in the United States if it is used or intended to be used in the production of a controlled

substance.

• Chemical suppliers are held liable for selling listed chemicals if they know or suspect that the chemical will be used for illicit purposes.

Hypophosphorous Acid (H3PO2) (Continued)

• Outlook

• The use of hypophosphorous acid in the production of methamphetamine is likely

to increase, particularly in the Midwest and Southwest regions of the United States

where methamphetamine production is prevalent.

– Injuries, property damage, and deaths also will increase as a growing number of

inexperienced methamphetamine producers experiment with hypophosphorous acid.

Anhydrous Ammonia

• Anhydrous ammonia is found in fertilizer, countertop cleaner, and commercial refrigerant.

– On its own, it has a pungent, suffocating odor.

• Mixing anhydrous ammonia with other chemicals can release highly toxic gases.

– Because anhydrous ammonia seeks out water (anhydrous means “without

water”) and causes severe burns, any body part that comes into contact with it

should be flushed with water for at least 15 minutes to remove the ammoniafrom the skin.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia has extremely destructive effects on humans.

– Anhydrous ammonia gives off vapors during cooking that can burn the mouth,

throat, and lung tissue.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Anhydrous ammonia seeks water from the nearest source, including the human body (anhydrous means “without water”).

– Because of their high moisture content, EYES, LUNGS, and SKIN are at the

greatest risk of attracting the ammonia.

• When large amounts of anhydrous ammonia are inhaled, the throat swells and the

victim suffocates.

– Exposure to the vapors or liquids can cause severe burns, blindness, or death.

• Anhydrous ammonia has an IDLH (immediately dangerous to life and health) at only 300 parts per million...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is poses MANY hazards, especially when it is placed in improper vessels and handled/transported by individuals unfamiliar with the

dangers.

• Anhydrous ammonia has a boiling point of -28 degrees below zero.

– When a vessel containing anhydrous ammonia is MOVED, the anhydrous

ammonia will reach its boiling point and pressurize.

•This pressurization can cause vessels to violently RUPTURE, or if the vessel pressurizes and does NOT rupture, the opening of the container of anhydrous

ammonia at a later time can cause RAPID, VIOLENT depressurization.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is mainly used in the U.S. as either a fertilizer or a refrigerant.

– Meth producers tend to store the anhydrous ammonia in IMPROPER/UNAPPROVED containers such as:

•Propane tanks,

• Igloo coolers, or

•Fire extinguishers.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia leaves a tell-tell sign as it flows through these UNAPPROVED

CONTAINERS – a blue or blue green discoloration on the valve.

– PAY ATTENTION to details!!!

Anhydrous Ammonia (Continued)

• Because propane cylinders (and the other unapproved containers) are NOT designed to store anhydrous ammonia, they can EXPLODE as the ammonia eats

through the walls of the cylinders.

– The valves, which take on a bluish/green color, frequently deteriorate and can cause hazardous leaks!!!

Anhydrous Ammonia (Continued)

• Do NOT touch, move, or open any kind of tank or sealed container!!!

– Be aware that propane tanks are often WEAKENED and BRITTLE due to the

anhydrous ammonia and are SENSITIVE to ANY kind of movement or impact.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• These pictures show what happened to a fire extinguisher that was used to store

anhydrous ammonia…

Anhydrous Ammonia (Continued)

• Illegal drug makers often STEAL anhydrous ammonia from areas where it is stored

and used, such as farms.

• Attempted thefts have also occurred at places such as:

– Refrigeration systems holding ammonia,

– Underground pipelines carrying ammonia, and

– Rail cars transporting anhydrous ammonia.

• Often thefts are aborted when thieves are injured or overcome by the toxic gas...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia thieves had better beware!!!

• There is a new product called GloTell that farmers can add to their anhydrous

ammonia tanks…

• Meth cooks will run the risk that the GloTell additive will turn their hands bright

pink!

– This bright pink stain will fluoresce under ultraviolet light even if washed off!!!

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Also, GloTell will produce pink methamphetamine that CANNOT be bleached.

– Users who snort meth made with GloTell will find that they have PINK NOSES!

– Users who inject meth made with GloTell will see a pink stain at the point of

injection!

Sodium Carbonate (Soda Ash)

Sodium Carbonate (Soda Ash) (Continued)

Lead Acetate

Iodine

• Iodine is a natural element, and it is helpful to the body in SMALL amounts.

– However, if iodine is taken in large amounts it can become toxic.

•Extremely high does of iodine can limit the function of the thyroid.

Iodine (Continued)

Iodine (Continued)

• Iodine is bluish-black, and it has a characteristic odor, a sharp acrid taste, and it produces a violet corrosive vapor.

– The vapor is irritating to the respiratory system and eyes.

• The solid iodine irritates the eyes and may burn the skin, and it may cause severe

internal irritation and damage if ingested.

Iodine (Continued)

• Iodine is known as the “blue ingredient” in the production of meth (in the “red, white, and blue” method).

Iodine (Continued)

Iodine (Continued)

• It takes approximately 4 bottles of iodine tincture to produce 2 – 3 grams of meth.

Iodine (Continued)

Iodine (Continued)

• Iodine leaves distinctive yellow-blue or brown stains on surfaces in former methlabs.

Iodine (Continued)

Iodine (Continued)

Iodine (Continued)

• The only good thing about iodine is that it leaves yellow stains.

• If you see yellow stained coffee filters, gloves or paper towels, this could be an

indicator that you’re in a lab.

• If you see yellow stains, you can spray some starch on them.

– If they turn a purplish blue/black, it’s iodine.

• Iodine is the only substance that reacts with soluble starch to produce a purplish black color.

– The only way to get iodine vapor all over the walls is to cook meth.

Mercurous Chloride

Rock Salt

Hydrogen Chloride

• Hydrogen chloride gas is commercially available.

• Hydrogen chloride gas can also be made by mixing sulfuric acid and salt.

• Muriatic acid is simply hydrogen chloride gas suspended in water.

• Hydrogen chloride gas can be seen as a pale white smoke.

– It is a poisonous gas that can cause respiratory problems and death.

Hydrogen Chloride (Continued)

Ammonium Nitrate

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Hydriodic Acid

• Hydriodic acid is a corrosive acid that is colorless when freshly prepared.

– When hydriodic acid is exposed to light and air, it turns yellowish and brown.

• Hydriodic acid is a solution of hydrogen iodide gas in water.

• Hydriodic acid vapor is irritating to the respiratory system, skin, and eyes.

• Hydriodic acid liquid causes severe burns to the eyes and skin.

• If hydriodic acid is accidentally ingested, it can cause severe internal irritation and

damage.

Hydriodic Acid (Continued)

Catalyst Chemicals

• Catalyst Chemicals:

– Chemicals which SPEED UP a reaction process and/or cause it to go to GREATER COMPLETION.

Red Phosphorus

• Red phosphorus is found ON matchboxes, in road flares, and other explosives.

– Red Phosphorus IGNITES when OVERHEATED!!!

• By combining red phosphorus and iodine, you can easily create the highly

controlled substance known as hydriodic acid (which is an essential ingredient in making meth).

– Creating 2 – 3 grams of meth requires about 4 big boxes of matches.

Red Phosphorus (Continued)

• Red phosphorous is highly flammable and if it is overheated it can become white

phosphorous…

– White phosphorous is a volatile and highly explosive substance.

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Lithium

• Lithium is used in batteries.

• Lithium seriously burns the skin upon contact.

– It also reacts VIOLENTLY with WATER and is highly explosive.

Lithium (Continued)

• Lithium reacts VIOLENTLY with WATER, and if it is splashed in the eyes during

cooking it will cause blindness.

– Lithium is extremely caustic to all body tissues.

Lithium (Continued)

Lithium (Continued)

• Lithium metal is HIGHLY water reactive and it will BURN or EXPLODE if it comes into contact with WATER!

• Because of the moisture in your skin, it will burn exposed flesh.

• Lithium metal will DEGRADE when exposed to atmospheric moisture…

– This is why meth cooks store lithium metal in a solvent prior to use.

• It is typical to see harvested lithium strips in Coleman fuel or Mineral Spirits to prevent explosions.

•Large quantities can be harvested and saved in these containers until needed

for a cook.

Lithium (Continued)

• If you see battery shells in the trashcan, on the floor, etc. – this is a VERY GOOD indicator that you might be entering a meth lab!

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

• Lithium catches fire when in contact with water...

Solvent Chemicals

• Solvent Chemicals:

– A medium (liquid) in which a chemical operation takes place.

• Solvent chemicals (UNLIKE the precursor chemicals) CAN be

substituted/interchanged.

Ether

• Ether was once called “sweet vitriol” because of its hypnotic effect.

• Ether is a highly flammable substance that is used as an anesthetic agent –

especially in third world countries where more expensive anesthesia is not available.

– While inhaling the ether, patients could undergo complete surgical procedures while otherwise awake without feeling pain or concern.

Ether (Continued)

• Ether can be obtained from engine starting fluid.

• Ether is a solvent and it is flammable.

– It is particularly hazardous because it can cause BOTH fire and explosion.

• It has been said that a quart of ether can “level” a small house.

Ethyl Ether (Continued)

Ethyl Ether (Continued)

• Ether is VERY flammable and is HEAVIER than air.

– NEVER use ether near flames or non-sparkless motors.

– Ether is very PUNGENT – even a small evaporated amount of ether is VERY noticeable.

Acetone

• Acetone can be found in nail polish remover or paint thinner.

– It is extremely flammable.

• In the setting of a meth lab where meth is being cooked with high heat, acetone is

very dangerous.

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Toluene

• Toluene is used in brake fluid.

– When working with brake fluid (toluene), be careful not to spill it on your car

because it will eat away the paint and chrome…

• You also have to be careful using toluene around other household chemicals

because its high concentration of polyethylene glycol can cause it to ignite in a

violent fireball.

• Toluene is powerful enough to dissolve rubber.

Toluene (Continued)

• Toluene is used to form meth crystals.

– The fumes toluene releases can cause brain damage or death.

Toluene (Continued)

Toluene (Continued)

Ethanol

Isopropanol

Isopropanol (Continued)

Isopropyl Alcohol

Methanol

Methanol (Continued)

Methanol (Continued)

Benzene

Benzene (Continued)

Which of these is NOT a common ingredient in Meth?

Nail Polish Remover

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Methamphetamine- PowerPoint

- Chemicals and Ingredients Used to Make Meth

CJUS 240

Economic Costs of Meth

• The economic cost of methamphetamine use in the U.S. reached $23.4 billion in

2005.

– This includes the burden of addiction, premature death, drug treatment, child

care, and cleaning of lab sites.

– This figure does NOT take into account the future needs of the meth user.

Concerns with ACTIVE Meth Labs

• Danger of fire and explosion

• Chemical spills

• Inhalation of solvents, corrosives, and toxic gases

• “Booby traps”

• Waste disposal

Concerns with FORMER Meth Labs

• Vapors

• Chemical residues

• Methamphetamine residues

• Waste disposal

Equipment Used in Meth Production

• Pyrex or Corning dishes

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

• Coffee Filters

Equipment Used in Meth Production

Equipment Used in Meth Production

Basic Chemical Requirements

• In a clandestine laboratory, basic types of chemicals are necessary in order to

produce the desired drug.

– The basic types of chemicals needed are:

1) Precursor Chemicals

2) Reagent Chemicals

3) Catalyst Chemicals

4) Solvent Chemicals

List I Chemical

• The term “List I chemical” means a chemical specified by regulation of the Attorney General as a chemical that is used in manufacturing a controlled substance and is IMPORTANT to the manufacture of the controlled substance.

• Examples of List I chemicals are:

– GBL

– Red Phosphorus

– Pseudoephedrine

List II Chemical

• The term “List II chemical” means a chemical (other than a List I chemical) specified by regulation of the Attorney General as a chemical that is USED in

manufacturing a controlled substance.

• Examples of List II chemicals are:

– Toluene

– Iodine

– Hydrochloric Acid

Precursor Chemicals

• Precursor Chemicals:

– A chemical that is ESSENTIAL to the production of a controlled substance and for

which NO SUBSTITUTION can be made.

Pseudoephedrine

• Pseudoephedrine is a decongestant found in cold medicine.

– Large amounts of pseudoephedrine on its own can harm the respiratory and nervous systems, as well as the heart.

Pseudoephedrine (Continued)

• Some of the common ways used to divert products containing pseudoephedrine

include:

– “Smurfing” – making multiple purchases at different locations

– Shelf-Sweeping – the theft of all shelf stock

– Shoplifting

– Theft from wholesalers

Pseudoephedrine (Continued)

• Pseudoephedrine smurfing is a method used by some methamphetamine producers to acquire large quantities of pseudoephedrine by enlisting the assistance of several

friends or associates (often referred to as “smurfers”) to make purchases at or below the legal thresholds from multiple retail locations.

– Smurfers are often addicts who trade the pseudoephedrine for finished

methamphetamine.

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

• About 680 pseudoephedrine tablets are needed to produce one ounce of meth…

Pseudoephedrine (Continued)

Out With a Bang

An Unstable Recipe…

• Meth contains a variety of poisonous ingredients…

– Some become EVEN MORE DANGEROUS once the cooking process begins…

Common Ingredients to Make Methamphetamine

Reagent Chemicals

• Reagent Chemicals:

– Chemicals which REACT upon the precursor chemical causing it to chemicallyCHANGE.

• A reagent chemical is a chemical which is required for the synthesis of an illicit drug substance, but which is NOT incorporated into the final chemical product.

Hydrochloric Acid

• Hydrochloric acid is a highly corrosive liquid that is used to make plastic (such as PVC pipe and polyurethane).

– It can remove rust and iron-oxide from steel and is highly corrosive to human

skin.

•Hydrochloric acid makes up the majority of the gastric acid in the human

digestive fluid.

• In high concentrations, hydrochloric acid will literally eat away human flesh…

Hydrochloric Acid (Continued)

• Hydrochloric acid can be purchased from hardware stores as:

– Tile and Grout Acid Cleaner

– Muriatic Acid

– Pool Acid

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

• Hydrochloric acid is a solution of hydrogen chloride gas suspended in water.

– Hydrochloric acid is corrosive and is a light yellow liquid color from traces of iron, chlorine, and organic matter.

• Inhaling hydrochloric acid may cause coughing or choking, inflammation, and

ulceration of the respiratory tract.

• Concentrated solutions of hydrochloric acid can cause severe burns and irritate the

mucous membranes, eyes, and respiratory tract.

– Exposure to hydrochloric acid vapors may result in pulmonary edema and

possibly death.

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

Sodium Hydroxide (NaOH)

• Sodium hydroxide is also called Lye.

• Sodium hydroxide is classified as a corrosive, and it is one of the main chemicals in

drain cleaner.

– It is also used in aluminum etching and to create biodiesal.

– It can burn the skin or cause blindness.

• Sodium hydroxide is used to dispose of road kill because it turns the dead bodies into a coffee-like liquid.

Sodium Hydroxide (NaOH) (Continued)

• Drain cleaner (sodium hydroxide) is extremely corrosive, and without wearing

protection, even the smallest spill on the skin can eat through flesh…

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sulfuric Acid (H2SO4)

• Sulfuric acid is used in drain or toilet bowl cleaner as well as battery acid.

– It is another highly corrosive substance that burns the skin on contact.

Sulfuric Acid (H2SO4) (Continued)

• The product label warning for Drano® (sulfuric acid) says it all:

– DANGER: MAY BURN EYES AND SKIN ON CONTACT.

•HARMFUL IF SWALLOWED.

–Avoid contact with body and clothing.

•TOXIC GAS MAY FORM IF MIXED WITH OTHER CHEMICALS.

–If gases are released, leave immediately and ventilate area.

•FIRST AID: Give Immediately:

–EYES AND SKIN:

»Flush with water for 20 minutes.

»Remove affected clothing.

–IF SWALLOWED:

»Rinse mouth and drink a glass of water or milk.

»Do not induce vomiting.

–THEN SEEK MEDICAL AID.

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Hypophosphorous Acid (H3PO2)

• Hypophosphorous acid, which is used legally for a variety of commercial purposes,

is a chemical that increasingly is substituted for red phosphorus in the methamphetamine production process.

– The use of hypophospherous acid SIGNIFICANTLY increases the risk of fire!!!

• The federal government regulates the sale of hypophosphorous acid through registration, record keeping, reporting, and import/export requirements regardless

of the quantity being handled or distributed.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid is a colorless oily liquid that emits a SOUR odor.

– There is an extreme fire and explosion hazard if the hypophosphorous acid

comes into contact with a solvent such as acetone, toluene, or Coleman fuel.

• Hypophosphorous acid will also emit phosphine gas and the fumes can ignite.

Hypophosphorous Acid (H3PO2) (Continued)

• Although hypophosphorous acid is a List I chemical under the Controlled Substances Act, methamphetamine producers typically purchase the chemical via

the internet or from associates who also are engaged in methamphetamine

production.

– The use of hypophosphorous acid in methamphetamine production is an

EXTREMELY DANGEROUS PRACTICE because of the deadly gases that can be generated as well as the risk of fire or explosion.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid (H3PO2, also called phosphinic acid) is a strong acid that

typically is prepared as a solution of colorless, oily liquid in strengths of 50%, 30 to 32%, and 10%.

– It also is prepared in the form of salts (referred to as hypophosphite salts), particularly ammonium hypophosphite, calcium hypophosphite, iron (ferric)

hypophosphite, magnesium hypophosphite, manganese hypophosphite,

potassium hypophosphite, and sodium hypophosphite.

Hypophosphorous Acid (H3PO2) (Continued)

• Over 100 chemical firms located throughout the world produce hypophosphorous

acid.

– The People's Republic of China and India have the largest numbers of

hypophosphorous acid producers, although there are a few producers in the United States.

• There are a wide variety of uses for hypophosphorous acid and its salts in

commercial industry; however, the chemicals have no legitimate household or retail uses.

Hypophosphorous Acid (H3PO2) (Continued)

• The legitimate commercial and laboratory fields that use hypophosphorous acid and its salts include the following:

– Chemical plating

– Food preparation

– Water treatment

– Polymers (as a bleaching agent, color stabilizer, or catalyst)

– Education and research in analytical chemistry

Hypophosphorous Acid (H3PO2) (Continued)

• Chemical suppliers typically distribute hypophosphorous acid in large quantities, for example, in drums containing 275 pounds of the diluted solution.

– Hypophosphorous acid also is distributed in smaller quantities.

• One-half liter of 50% concentrate hypophosphorous acid solution can be obtained from chemical suppliers for as little as $14.

Hypophosphorous Acid (H3PO2) (Continued)

• Methamphetamine laboratory operators typically obtain small quantities of the chemical from other laboratory operators who purchase large quantities of the

chemical and repackage it for further distribution.

– According to law enforcement sources, these individuals sell hypophosphorous acid for as much as $1,000 per half-liter.

•Methamphetamine laboratory operators also purchase hypophosphorous acidvia the internet.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid and the Internet

• The internet is a source of a great deal of information regarding hypophosphorous acid.

• Popular internet sites that disseminate information about illicit drugs contain information about the chemical, including numerous recipes for home production of

methamphetamine using hypophosphorous acid.

• There also are recipes for synthesizing hypophosphorous acid from available chemicals.

• Hypophosphorous acid solutions and salts have been sold to the general public via the internet.

• The Drug Enforcement Administration (DEA) has strong concerns regarding the sale

of chemicals on the internet and has requested that any sites (such as auction sites) that allow the sale of regulated chemicals on their domains require proof of

DEA registration from their clients.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid Used in Methamphetamine Production

• Hypophosphorous acid is used in the ephedrine-pseudoephedrine reduction method

of methamphetamine production.

– It is used in the methamphetamine production process to produce hydriodic acid,

an important reagent (it reacts with the ephedrine-pseudoephedrine but does NOT become part of the finished product).

Hypophosphorous Acid (H3PO2) (Continued)

• The regulation of hydriodic acid by DEA in 1993 rendered it virtually unavailable in

the United States.

– However, methamphetamine laboratory operators discovered methods to

produce hydriodic acid using a combination of iodine in water with red phosphorus.

• Laboratory operators found that red phosphorus could be obtained easily, either from commercial supply companies or by scraping the striker pads from matchbooks or matchboxes.

• Methamphetamine producers soon discovered that hypophosphorous acid ALSO could be used in combination with iodine and water to produce hydriodic acid.

Hypophosphorous Acid (H3PO2) (Continued)

• The practice of using hypophosphorous acid in methamphetamine production is

believed to have begun in the United States in the late 1990s when a methamphetamine producer in Colorado obtained the recipe from Australia, where

the hypophosphorous acid method is prevalent.

– This man was known as a serial cook who had a long history of

methamphetamine production.

•Over several years he trained other laboratory operators in Colorado to produce methamphetamine using hypophosphorous acid.

• As his techniques were passed on to others, the number of methamphetaminelaboratories in Colorado using hypophosphorous acid continued to increase, and the

technique was passed on to numerous methamphetamine producers in other

states.

Hypophosphorous Acid (H3PO2) (Continued)

• According to the El Paso Intelligence Center (EPIC) National Clandestine Laboratory

Seizure System, from 2000 through 2002 the number of seized methamphetaminelaboratories in the United States in which hypophosphorous acid was found

increased overall. (See Table 1.)

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid found at methamphetamine laboratories is packaged in a variety of ways.

• The chemical has been found in 1-gallon bottles of solution or in 1-pound jars of salts.

• Some hypophosphorous acid containers are labeled as "plating solution."

• Pint-sized brown glass bottles wrapped in red electrical tape also have been found to contain hypophosphorous acid; they have been discovered primarily in Colorado.

• The vast majority of hypophosphorous acid found at laboratory sites has been recovered from small toxic laboratories (STLs), those which yield gram to ounce

quantities per production cycle.

• Hypophosphorous acid has not been reported at large-scale laboratories operated by Mexican criminal groups in the United States.

Hypophosphorous Acid (H3PO2) (Continued)

• Hazards

• The iodine-hypophosphorous acid method is MORE HAZORDOUS than the iodine-

red phosphorus method, although the reaction using hypophosphorous acid is

faster and gives slightly higher yields.

– When hypophosphorous acid is used, the chemicals must be mixed together

SLOWLY in a PARTICULAR ORDER to prevent them from reacting violently.

Hypophosphorous Acid (H3PO2) (Continued)

• The combination of hypophosphorous acid with the other chemicals and with

certain metals can produce deadly phosphine gas during the initial mixing step and

can CONTINUE to produce phosphine gas for several days AFTER production has been completed…

Hypophosphorous Acid (H3PO2) (Continued)

• The iodine-hypophosphorous acid mixture has a tendency to decompose quickly when overheated or if heated for long periods of time, becoming cloudy or "milky-

white" just prior to giving off a cloud of phosphine gas that can ignite spontaneously.

– Hypophosphorous acid solutions may become unstable if evaporation results in

concentrations above 50%.

Hypophosphorous Acid (H3PO2) (Continued)

• [Note: Law enforcement or emergency personnel who encounter suspected

containers of hypophosphorous acid should use extreme care during handling because laboratory operators often attempt to obtain a more concentrated acid by

allowing water to evaporate from the mixture.]

• Because hypophosphorous acid often is used at small methamphetaminelaboratories operated by inexperienced or careless individuals, the potential hazards

of using this method are even greater.

• The risk of fire and explosion is higher in these laboratories, where professional

laboratory equipment typically is not used to contain the phosphine gas and where

safe handling precautions are not employed.

• In addition, these laboratories often are located in homes where children are

present and may come into contact with hypophosphorous acid.

• A child can easily mistake hypophosphorous acid for any other clear liquid,

particularly if it is stored in household containers or drinking glasses.

• Skin, eye, or inhalation exposure can be extremely harmful or fatal.

Hypophosphorous Acid (H3PO2) (Continued)

• Safety Precautions

• Always wear a self-contained breathing apparatus as well as protective clothing when entering areas where hypophosphorous acid may be present.

• When in contact with metals or in a high-temperature environment,

hypophosphorous acid can break down and liberate phosphine and flammable hydrogen gas.

• Do not allow the use of open flames, open lights, matches, or smoking in or around laboratories or dumpsites where hypophosphorous acid is handled.

• In case of fire, use a self-contained positive pressure breathing apparatus and full

protective equipment.

• Use water spray, fog, foam, dry chemicals, or other reagents as may be

appropriate for materials in the surrounding fire.

• Water may be used to cool the containers of hypophosphorous acid; however, use extreme care to avoid allowing water to enter the container.

• In case of spills, neutralize the spilled chemical with alkaline material (soda ash, lime), then absorb it with an inert material such as vermiculite, dry sand, or earth and place in a chemical waste container.

• Do not use combustible materials such as sawdust.

Hypophosphorous Acid (H3PO2) (Continued)

• Legislation and Control

• In the United States hypophosphorous acid is one of 38 chemicals (or groups of

chemicals) controlled under law by DEA.

• On October 17, 2001, hypophosphorous acid and its salts, along with red and white phosphorus, were officially added as List I chemicals under section 1310 of the

Code of Federal Regulations.

• List I chemicals are defined as chemicals that are used in the manufacture of a controlled substance in violation of the Controlled Substances Act (CSA) and are

important to the manufacture of a controlled substance.

• Under the law, suppliers are required to maintain records and report receipts, sales,

imports, and exports of these chemicals to DEA.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid, red phosphorus, and white phosphorus, as well as

ephedrine, are unique in that suppliers are required to report all transactions of

these chemicals, regardless of the amount.

• By contrast, the other 34 listed chemicals are only reportable after a supplier's

transactions for a chemical reach an established weight or volume threshold in a calendar month.

• In addition to reporting all transactions involving the chemical, suppliers are

expected to "know their customers" in order to prevent the diversion of these substances to methamphetamine laboratories, as it is illegal to import, export,

purchase, or sell hypophosphorous acid or any other listed chemical in the United States if it is used or intended to be used in the production of a controlled

substance.

• Chemical suppliers are held liable for selling listed chemicals if they know or suspect that the chemical will be used for illicit purposes.

Hypophosphorous Acid (H3PO2) (Continued)

• Outlook

• The use of hypophosphorous acid in the production of methamphetamine is likely to increase, particularly in the Midwest and Southwest regions of the United States

where methamphetamine production is prevalent.

– Injuries, property damage, and deaths also will increase as a growing number of

inexperienced methamphetamine producers experiment with hypophosphorous acid.

Anhydrous Ammonia

• Anhydrous ammonia is found in fertilizer, countertop cleaner, and commercial refrigerant.

– On its own, it has a pungent, suffocating odor.

• Mixing anhydrous ammonia with other chemicals can release highly toxic gases.

– Because anhydrous ammonia seeks out water (anhydrous means “without

water”) and causes severe burns, any body part that comes into contact with it

should be flushed with water for at least 15 minutes to remove the ammoniafrom the skin.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia has extremely destructive effects on humans.

– Anhydrous ammonia gives off vapors during cooking that can burn the mouth,

throat, and lung tissue.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Anhydrous ammonia seeks water from the nearest source, including the human body (anhydrous means “without water”).

– Because of their high moisture content, EYES, LUNGS, and SKIN are at the

greatest risk of attracting the ammonia.

• When large amounts of anhydrous ammonia are inhaled, the throat swells and the victim suffocates.

– Exposure to the vapors or liquids can cause severe burns, blindness, or death.

• Anhydrous ammonia has an IDLH (immediately dangerous to life and health) at

only 300 parts per million...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is poses MANY hazards, especially when it is placed in improper vessels and handled/transported by individuals unfamiliar with the

dangers.

• Anhydrous ammonia has a boiling point of -28 degrees below zero.

– When a vessel containing anhydrous ammonia is MOVED, the anhydrous

ammonia will reach its boiling point and pressurize.

•This pressurization can cause vessels to violently RUPTURE, or if the vessel pressurizes and does NOT rupture, the opening of the container of anhydrous

ammonia at a later time can cause RAPID, VIOLENT depressurization.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is mainly used in the U.S. as either a fertilizer or a refrigerant.

– Meth producers tend to store the anhydrous ammonia in IMPROPER/UNAPPROVED containers such as:

•Propane tanks,

• Igloo coolers, or

•Fire extinguishers.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia leaves a tell-tell sign as it flows through these UNAPPROVED

CONTAINERS – a blue or blue green discoloration on the valve.

– PAY ATTENTION to details!!!

Anhydrous Ammonia (Continued)

• Because propane cylinders (and the other unapproved containers) are NOT designed to store anhydrous ammonia, they can EXPLODE as the ammonia eats

through the walls of the cylinders.

– The valves, which take on a bluish/green color, frequently deteriorate and can cause hazardous leaks!!!

Anhydrous Ammonia (Continued)

• Do NOT touch, move, or open any kind of tank or sealed container!!!

– Be aware that propane tanks are often WEAKENED and BRITTLE due to the

anhydrous ammonia and are SENSITIVE to ANY kind of movement or impact.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• These pictures show what happened to a fire extinguisher that was used to store

anhydrous ammonia…

Anhydrous Ammonia (Continued)

• Illegal drug makers often STEAL anhydrous ammonia from areas where it is stored

and used, such as farms.

• Attempted thefts have also occurred at places such as:

– Refrigeration systems holding ammonia,

– Underground pipelines carrying ammonia, and

– Rail cars transporting anhydrous ammonia.

• Often thefts are aborted when thieves are injured or overcome by the toxic gas...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia thieves had better beware!!!

• There is a new product called GloTell that farmers can add to their anhydrous

ammonia tanks…

• Meth cooks will run the risk that the GloTell additive will turn their hands bright

pink!

– This bright pink stain will fluoresce under ultraviolet light even if washed off!!!

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Also, GloTell will produce pink methamphetamine that CANNOT be bleached.

– Users who snort meth made with GloTell will find that they have PINK NOSES!

– Users who inject meth made with GloTell will see a pink stain at the point of

injection!

Sodium Carbonate (Soda Ash)

Sodium Carbonate (Soda Ash) (Continued)

Lead Acetate

Iodine

• Iodine is a natural element, and it is helpful to the body in SMALL amounts.

– However, if iodine is taken in large amounts it can become toxic.

•Extremely high does of iodine can limit the function of the thyroid.

Iodine (Continued)

Iodine (Continued)

• Iodine is bluish-black, and it has a characteristic odor, a sharp acrid taste, and it produces a violet corrosive vapor.

– The vapor is irritating to the respiratory system and eyes.

• The solid iodine irritates the eyes and may burn the skin, and it may cause severe

internal irritation and damage if ingested.

Iodine (Continued)

• Iodine is known as the “blue ingredient” in the production of meth (in the “red, white, and blue” method).

Iodine (Continued)

Iodine (Continued)

• It takes approximately 4 bottles of iodine tincture to produce 2 – 3 grams of meth.

Iodine (Continued)

Iodine (Continued)

• Iodine leaves distinctive yellow-blue or brown stains on surfaces in former methlabs.

Iodine (Continued)

Iodine (Continued)

Iodine (Continued)

• The only good thing about iodine is that it leaves yellow stains.

• If you see yellow stained coffee filters, gloves or paper towels, this could be an

indicator that you’re in a lab.

• If you see yellow stains, you can spray some starch on them.

– If they turn a purplish blue/black, it’s iodine.

• Iodine is the only substance that reacts with soluble starch to produce a purplish black color.

– The only way to get iodine vapor all over the walls is to cook meth.

Mercurous Chloride

Rock Salt

Hydrogen Chloride

• Hydrogen chloride gas is commercially available.

• Hydrogen chloride gas can also be made by mixing sulfuric acid and salt.

• Muriatic acid is simply hydrogen chloride gas suspended in water.

• Hydrogen chloride gas can be seen as a pale white smoke.

– It is a poisonous gas that can cause respiratory problems and death.

Hydrogen Chloride (Continued)

Ammonium Nitrate

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Hydriodic Acid

• Hydriodic acid is a corrosive acid that is colorless when freshly prepared.

– When hydriodic acid is exposed to light and air, it turns yellowish and brown.

• Hydriodic acid is a solution of hydrogen iodide gas in water.

• Hydriodic acid vapor is irritating to the respiratory system, skin, and eyes.

• Hydriodic acid liquid causes severe burns to the eyes and skin.

• If hydriodic acid is accidentally ingested, it can cause severe internal irritation and

damage.

Hydriodic Acid (Continued)

Catalyst Chemicals

• Catalyst Chemicals:

– Chemicals which SPEED UP a reaction process and/or cause it to go to GREATER COMPLETION.

Red Phosphorus

• Red phosphorus is found ON matchboxes, in road flares, and other explosives.

– Red Phosphorus IGNITES when OVERHEATED!!!

• By combining red phosphorus and iodine, you can easily create the highly

controlled substance known as hydriodic acid (which is an essential ingredient in making meth).

– Creating 2 – 3 grams of meth requires about 4 big boxes of matches.

Red Phosphorus (Continued)

• Red phosphorous is highly flammable and if it is overheated it can become white

phosphorous…

– White phosphorous is a volatile and highly explosive substance.

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Lithium

• Lithium is used in batteries.

• Lithium seriously burns the skin upon contact.

– It also reacts VIOLENTLY with WATER and is highly explosive.

Lithium (Continued)

• Lithium reacts VIOLENTLY with WATER, and if it is splashed in the eyes during

cooking it will cause blindness.

– Lithium is extremely caustic to all body tissues.

Lithium (Continued)

Lithium (Continued)

• Lithium metal is HIGHLY water reactive and it will BURN or EXPLODE if it comes into contact with WATER!

• Because of the moisture in your skin, it will burn exposed flesh.

• Lithium metal will DEGRADE when exposed to atmospheric moisture…

– This is why meth cooks store lithium metal in a solvent prior to use.

• It is typical to see harvested lithium strips in Coleman fuel or Mineral Spirits to prevent explosions.

•Large quantities can be harvested and saved in these containers until needed for a cook.

Lithium (Continued)

• If you see battery shells in the trashcan, on the floor, etc. – this is a VERY GOOD

indicator that you might be entering a meth lab!

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

• Lithium catches fire when in contact with water...

Solvent Chemicals

• Solvent Chemicals:

– A medium (liquid) in which a chemical operation takes place.

• Solvent chemicals (UNLIKE the precursor chemicals) CAN be

substituted/interchanged.

Ether

• Ether was once called “sweet vitriol” because of its hypnotic effect.

• Ether is a highly flammable substance that is used as an anesthetic agent –

especially in third world countries where more expensive anesthesia is not available.

– While inhaling the ether, patients could undergo complete surgical procedures while otherwise awake without feeling pain or concern.

Ether (Continued)

• Ether can be obtained from engine starting fluid.

• Ether is a solvent and it is flammable.

– It is particularly hazardous because it can cause BOTH fire and explosion.

• It has been said that a quart of ether can “level” a small house.

Ethyl Ether (Continued)

Ethyl Ether (Continued)

• Ether is VERY flammable and is HEAVIER than air.

– NEVER use ether near flames or non-sparkless motors.

– Ether is very PUNGENT – even a small evaporated amount of ether is VERY noticeable.

Acetone

• Acetone can be found in nail polish remover or paint thinner.

– It is extremely flammable.

• In the setting of a meth lab where meth is being cooked with high heat, acetone is

very dangerous.

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Toluene

• Toluene is used in brake fluid.

– When working with brake fluid (toluene), be careful not to spill it on your car

because it will eat away the paint and chrome…

• You also have to be careful using toluene around other household chemicals

because its high concentration of polyethylene glycol can cause it to ignite in a

violent fireball.

• Toluene is powerful enough to dissolve rubber.

Toluene (Continued)

• Toluene is used to form meth crystals.

– The fumes toluene releases can cause brain damage or death.

Toluene (Continued)

Toluene (Continued)

Ethanol

Isopropanol

Isopropanol (Continued)

Isopropyl Alcohol

Methanol

Methanol (Continued)

Methanol (Continued)

Benzene

Benzene (Continued)

Which of these is NOT a common ingredient in Meth?

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Page 13: Methamphetamine - PowerPoint - Chemicals and Ingredients ... · 2/5/2014 1 Methamphetamine - PowerPoint - Chemicals and Ingredients Used to Make Meth CJUS 240 Economic Costs of Meth

2/5/2014

13

Methamphetamine- PowerPoint

- Chemicals and Ingredients Used to Make Meth

CJUS 240

Economic Costs of Meth

• The economic cost of methamphetamine use in the U.S. reached $23.4 billion in

2005.

– This includes the burden of addiction, premature death, drug treatment, child

care, and cleaning of lab sites.

– This figure does NOT take into account the future needs of the meth user.

Concerns with ACTIVE Meth Labs

• Danger of fire and explosion

• Chemical spills

• Inhalation of solvents, corrosives, and toxic gases

• “Booby traps”

• Waste disposal

Concerns with FORMER Meth Labs

• Vapors

• Chemical residues

• Methamphetamine residues

• Waste disposal

Equipment Used in Meth Production

• Pyrex or Corning dishes

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

• Coffee Filters

Equipment Used in Meth Production

Equipment Used in Meth Production

Basic Chemical Requirements

• In a clandestine laboratory, basic types of chemicals are necessary in order to

produce the desired drug.

– The basic types of chemicals needed are:

1) Precursor Chemicals

2) Reagent Chemicals

3) Catalyst Chemicals

4) Solvent Chemicals

List I Chemical

• The term “List I chemical” means a chemical specified by regulation of the Attorney General as a chemical that is used in manufacturing a controlled substance and is

IMPORTANT to the manufacture of the controlled substance.

• Examples of List I chemicals are:

– GBL

– Red Phosphorus

– Pseudoephedrine

List II Chemical

• The term “List II chemical” means a chemical (other than a List I chemical) specified by regulation of the Attorney General as a chemical that is USED in

manufacturing a controlled substance.

• Examples of List II chemicals are:

– Toluene

– Iodine

– Hydrochloric Acid

Precursor Chemicals

• Precursor Chemicals:

– A chemical that is ESSENTIAL to the production of a controlled substance and for

which NO SUBSTITUTION can be made.

Pseudoephedrine

• Pseudoephedrine is a decongestant found in cold medicine.

– Large amounts of pseudoephedrine on its own can harm the respiratory and nervous systems, as well as the heart.

Pseudoephedrine (Continued)

• Some of the common ways used to divert products containing pseudoephedrine

include:

– “Smurfing” – making multiple purchases at different locations

– Shelf-Sweeping – the theft of all shelf stock

– Shoplifting

– Theft from wholesalers

Pseudoephedrine (Continued)

• Pseudoephedrine smurfing is a method used by some methamphetamine producers to acquire large quantities of pseudoephedrine by enlisting the assistance of several

friends or associates (often referred to as “smurfers”) to make purchases at or below the legal thresholds from multiple retail locations.

– Smurfers are often addicts who trade the pseudoephedrine for finished

methamphetamine.

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

• About 680 pseudoephedrine tablets are needed to produce one ounce of meth…

Pseudoephedrine (Continued)

Out With a Bang

An Unstable Recipe…

• Meth contains a variety of poisonous ingredients…

– Some become EVEN MORE DANGEROUS once the cooking process begins…

Common Ingredients to Make Methamphetamine

Reagent Chemicals

• Reagent Chemicals:

– Chemicals which REACT upon the precursor chemical causing it to chemicallyCHANGE.

• A reagent chemical is a chemical which is required for the synthesis of an illicit drug substance, but which is NOT incorporated into the final chemical product.

Hydrochloric Acid

• Hydrochloric acid is a highly corrosive liquid that is used to make plastic (such as PVC pipe and polyurethane).

– It can remove rust and iron-oxide from steel and is highly corrosive to human

skin.

•Hydrochloric acid makes up the majority of the gastric acid in the human digestive fluid.

• In high concentrations, hydrochloric acid will literally eat away human flesh…

Hydrochloric Acid (Continued)

• Hydrochloric acid can be purchased from hardware stores as:

– Tile and Grout Acid Cleaner

– Muriatic Acid

– Pool Acid

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

• Hydrochloric acid is a solution of hydrogen chloride gas suspended in water.

– Hydrochloric acid is corrosive and is a light yellow liquid color from traces of iron, chlorine, and organic matter.

• Inhaling hydrochloric acid may cause coughing or choking, inflammation, and

ulceration of the respiratory tract.

• Concentrated solutions of hydrochloric acid can cause severe burns and irritate the

mucous membranes, eyes, and respiratory tract.

– Exposure to hydrochloric acid vapors may result in pulmonary edema and

possibly death.

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

Sodium Hydroxide (NaOH)

• Sodium hydroxide is also called Lye.

• Sodium hydroxide is classified as a corrosive, and it is one of the main chemicals in

drain cleaner.

– It is also used in aluminum etching and to create biodiesal.

– It can burn the skin or cause blindness.

• Sodium hydroxide is used to dispose of road kill because it turns the dead bodies

into a coffee-like liquid.

Sodium Hydroxide (NaOH) (Continued)

• Drain cleaner (sodium hydroxide) is extremely corrosive, and without wearing

protection, even the smallest spill on the skin can eat through flesh…

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sulfuric Acid (H2SO4)

• Sulfuric acid is used in drain or toilet bowl cleaner as well as battery acid.

– It is another highly corrosive substance that burns the skin on contact.

Sulfuric Acid (H2SO4) (Continued)

• The product label warning for Drano® (sulfuric acid) says it all:

– DANGER: MAY BURN EYES AND SKIN ON CONTACT.

•HARMFUL IF SWALLOWED.

–Avoid contact with body and clothing.

•TOXIC GAS MAY FORM IF MIXED WITH OTHER CHEMICALS.

–If gases are released, leave immediately and ventilate area.

•FIRST AID: Give Immediately:

–EYES AND SKIN:

»Flush with water for 20 minutes.

»Remove affected clothing.

–IF SWALLOWED:

»Rinse mouth and drink a glass of water or milk.

»Do not induce vomiting.

–THEN SEEK MEDICAL AID.

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Hypophosphorous Acid (H3PO2)

• Hypophosphorous acid, which is used legally for a variety of commercial purposes,

is a chemical that increasingly is substituted for red phosphorus in the methamphetamine production process.

– The use of hypophospherous acid SIGNIFICANTLY increases the risk of fire!!!

• The federal government regulates the sale of hypophosphorous acid through registration, record keeping, reporting, and import/export requirements regardless

of the quantity being handled or distributed.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid is a colorless oily liquid that emits a SOUR odor.

– There is an extreme fire and explosion hazard if the hypophosphorous acid

comes into contact with a solvent such as acetone, toluene, or Coleman fuel.

• Hypophosphorous acid will also emit phosphine gas and the fumes can ignite.

Hypophosphorous Acid (H3PO2) (Continued)

• Although hypophosphorous acid is a List I chemical under the Controlled Substances Act, methamphetamine producers typically purchase the chemical via the internet or from associates who also are engaged in methamphetamine

production.

– The use of hypophosphorous acid in methamphetamine production is an

EXTREMELY DANGEROUS PRACTICE because of the deadly gases that can be generated as well as the risk of fire or explosion.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid (H3PO2, also called phosphinic acid) is a strong acid that

typically is prepared as a solution of colorless, oily liquid in strengths of 50%, 30 to 32%, and 10%.

– It also is prepared in the form of salts (referred to as hypophosphite salts), particularly ammonium hypophosphite, calcium hypophosphite, iron (ferric) hypophosphite, magnesium hypophosphite, manganese hypophosphite,

potassium hypophosphite, and sodium hypophosphite.

Hypophosphorous Acid (H3PO2) (Continued)

• Over 100 chemical firms located throughout the world produce hypophosphorous

acid.

– The People's Republic of China and India have the largest numbers of

hypophosphorous acid producers, although there are a few producers in the United States.

• There are a wide variety of uses for hypophosphorous acid and its salts in

commercial industry; however, the chemicals have no legitimate household or retail uses.

Hypophosphorous Acid (H3PO2) (Continued)

• The legitimate commercial and laboratory fields that use hypophosphorous acid and its salts include the following:

– Chemical plating

– Food preparation

– Water treatment

– Polymers (as a bleaching agent, color stabilizer, or catalyst)

– Education and research in analytical chemistry

Hypophosphorous Acid (H3PO2) (Continued)

• Chemical suppliers typically distribute hypophosphorous acid in large quantities, for example, in drums containing 275 pounds of the diluted solution.

– Hypophosphorous acid also is distributed in smaller quantities.

• One-half liter of 50% concentrate hypophosphorous acid solution can be obtained from chemical suppliers for as little as $14.

Hypophosphorous Acid (H3PO2) (Continued)

• Methamphetamine laboratory operators typically obtain small quantities of the chemical from other laboratory operators who purchase large quantities of the

chemical and repackage it for further distribution.

– According to law enforcement sources, these individuals sell hypophosphorous acid for as much as $1,000 per half-liter.

•Methamphetamine laboratory operators also purchase hypophosphorous acidvia the internet.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid and the Internet

• The internet is a source of a great deal of information regarding hypophosphorous acid.

• Popular internet sites that disseminate information about illicit drugs contain information about the chemical, including numerous recipes for home production of

methamphetamine using hypophosphorous acid.

• There also are recipes for synthesizing hypophosphorous acid from available chemicals.

• Hypophosphorous acid solutions and salts have been sold to the general public via the internet.

• The Drug Enforcement Administration (DEA) has strong concerns regarding the sale

of chemicals on the internet and has requested that any sites (such as auction sites) that allow the sale of regulated chemicals on their domains require proof of

DEA registration from their clients.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid Used in Methamphetamine Production

• Hypophosphorous acid is used in the ephedrine-pseudoephedrine reduction method

of methamphetamine production.

– It is used in the methamphetamine production process to produce hydriodic acid,

an important reagent (it reacts with the ephedrine-pseudoephedrine but does NOT become part of the finished product).

Hypophosphorous Acid (H3PO2) (Continued)

• The regulation of hydriodic acid by DEA in 1993 rendered it virtually unavailable in

the United States.

– However, methamphetamine laboratory operators discovered methods to

produce hydriodic acid using a combination of iodine in water with red phosphorus.

• Laboratory operators found that red phosphorus could be obtained easily, either

from commercial supply companies or by scraping the striker pads from matchbooks or matchboxes.

• Methamphetamine producers soon discovered that hypophosphorous acid ALSO could be used in combination with iodine and water to produce hydriodic acid.

Hypophosphorous Acid (H3PO2) (Continued)

• The practice of using hypophosphorous acid in methamphetamine production is

believed to have begun in the United States in the late 1990s when a methamphetamine producer in Colorado obtained the recipe from Australia, where

the hypophosphorous acid method is prevalent.

– This man was known as a serial cook who had a long history of

methamphetamine production.

•Over several years he trained other laboratory operators in Colorado to produce methamphetamine using hypophosphorous acid.

• As his techniques were passed on to others, the number of methamphetaminelaboratories in Colorado using hypophosphorous acid continued to increase, and the

technique was passed on to numerous methamphetamine producers in other

states.

Hypophosphorous Acid (H3PO2) (Continued)

• According to the El Paso Intelligence Center (EPIC) National Clandestine Laboratory

Seizure System, from 2000 through 2002 the number of seized methamphetaminelaboratories in the United States in which hypophosphorous acid was found

increased overall. (See Table 1.)

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid found at methamphetamine laboratories is packaged in a variety of ways.

• The chemical has been found in 1-gallon bottles of solution or in 1-pound jars of salts.

• Some hypophosphorous acid containers are labeled as "plating solution."

• Pint-sized brown glass bottles wrapped in red electrical tape also have been found to contain hypophosphorous acid; they have been discovered primarily in Colorado.

• The vast majority of hypophosphorous acid found at laboratory sites has been recovered from small toxic laboratories (STLs), those which yield gram to ounce

quantities per production cycle.

• Hypophosphorous acid has not been reported at large-scale laboratories operated by Mexican criminal groups in the United States.

Hypophosphorous Acid (H3PO2) (Continued)

• Hazards

• The iodine-hypophosphorous acid method is MORE HAZORDOUS than the iodine-

red phosphorus method, although the reaction using hypophosphorous acid is

faster and gives slightly higher yields.

– When hypophosphorous acid is used, the chemicals must be mixed together

SLOWLY in a PARTICULAR ORDER to prevent them from reacting violently.

Hypophosphorous Acid (H3PO2) (Continued)

• The combination of hypophosphorous acid with the other chemicals and with certain metals can produce deadly phosphine gas during the initial mixing step and

can CONTINUE to produce phosphine gas for several days AFTER production has been completed…

Hypophosphorous Acid (H3PO2) (Continued)

• The iodine-hypophosphorous acid mixture has a tendency to decompose quickly when overheated or if heated for long periods of time, becoming cloudy or "milky-

white" just prior to giving off a cloud of phosphine gas that can ignite spontaneously.

– Hypophosphorous acid solutions may become unstable if evaporation results in

concentrations above 50%.

Hypophosphorous Acid (H3PO2) (Continued)

• [Note: Law enforcement or emergency personnel who encounter suspected

containers of hypophosphorous acid should use extreme care during handling because laboratory operators often attempt to obtain a more concentrated acid by

allowing water to evaporate from the mixture.]

• Because hypophosphorous acid often is used at small methamphetaminelaboratories operated by inexperienced or careless individuals, the potential hazards

of using this method are even greater.

• The risk of fire and explosion is higher in these laboratories, where professional

laboratory equipment typically is not used to contain the phosphine gas and where

safe handling precautions are not employed.

• In addition, these laboratories often are located in homes where children are present and may come into contact with hypophosphorous acid.

• A child can easily mistake hypophosphorous acid for any other clear liquid,

particularly if it is stored in household containers or drinking glasses.

• Skin, eye, or inhalation exposure can be extremely harmful or fatal.

Hypophosphorous Acid (H3PO2) (Continued)

• Safety Precautions

• Always wear a self-contained breathing apparatus as well as protective clothing when entering areas where hypophosphorous acid may be present.

• When in contact with metals or in a high-temperature environment,

hypophosphorous acid can break down and liberate phosphine and flammable hydrogen gas.

• Do not allow the use of open flames, open lights, matches, or smoking in or around laboratories or dumpsites where hypophosphorous acid is handled.

• In case of fire, use a self-contained positive pressure breathing apparatus and full

protective equipment.

• Use water spray, fog, foam, dry chemicals, or other reagents as may be

appropriate for materials in the surrounding fire.

• Water may be used to cool the containers of hypophosphorous acid; however, use extreme care to avoid allowing water to enter the container.

• In case of spills, neutralize the spilled chemical with alkaline material (soda ash, lime), then absorb it with an inert material such as vermiculite, dry sand, or earth

and place in a chemical waste container.

• Do not use combustible materials such as sawdust.

Hypophosphorous Acid (H3PO2) (Continued)

• Legislation and Control

• In the United States hypophosphorous acid is one of 38 chemicals (or groups of

chemicals) controlled under law by DEA.

• On October 17, 2001, hypophosphorous acid and its salts, along with red and white phosphorus, were officially added as List I chemicals under section 1310 of the

Code of Federal Regulations.

• List I chemicals are defined as chemicals that are used in the manufacture of a

controlled substance in violation of the Controlled Substances Act (CSA) and are important to the manufacture of a controlled substance.

• Under the law, suppliers are required to maintain records and report receipts, sales,

imports, and exports of these chemicals to DEA.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid, red phosphorus, and white phosphorus, as well as

ephedrine, are unique in that suppliers are required to report all transactions of

these chemicals, regardless of the amount.

• By contrast, the other 34 listed chemicals are only reportable after a supplier's

transactions for a chemical reach an established weight or volume threshold in a calendar month.

• In addition to reporting all transactions involving the chemical, suppliers are

expected to "know their customers" in order to prevent the diversion of these substances to methamphetamine laboratories, as it is illegal to import, export,

purchase, or sell hypophosphorous acid or any other listed chemical in the United States if it is used or intended to be used in the production of a controlled

substance.

• Chemical suppliers are held liable for selling listed chemicals if they know or suspect that the chemical will be used for illicit purposes.

Hypophosphorous Acid (H3PO2) (Continued)

• Outlook

• The use of hypophosphorous acid in the production of methamphetamine is likely

to increase, particularly in the Midwest and Southwest regions of the United States

where methamphetamine production is prevalent.

– Injuries, property damage, and deaths also will increase as a growing number of

inexperienced methamphetamine producers experiment with hypophosphorous acid.

Anhydrous Ammonia

• Anhydrous ammonia is found in fertilizer, countertop cleaner, and commercial refrigerant.

– On its own, it has a pungent, suffocating odor.

• Mixing anhydrous ammonia with other chemicals can release highly toxic gases.

– Because anhydrous ammonia seeks out water (anhydrous means “without

water”) and causes severe burns, any body part that comes into contact with it

should be flushed with water for at least 15 minutes to remove the ammoniafrom the skin.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia has extremely destructive effects on humans.

– Anhydrous ammonia gives off vapors during cooking that can burn the mouth,

throat, and lung tissue.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Anhydrous ammonia seeks water from the nearest source, including the human body (anhydrous means “without water”).

– Because of their high moisture content, EYES, LUNGS, and SKIN are at the

greatest risk of attracting the ammonia.

• When large amounts of anhydrous ammonia are inhaled, the throat swells and the victim suffocates.

– Exposure to the vapors or liquids can cause severe burns, blindness, or death.

• Anhydrous ammonia has an IDLH (immediately dangerous to life and health) at

only 300 parts per million...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is poses MANY hazards, especially when it is placed in improper vessels and handled/transported by individuals unfamiliar with the

dangers.

• Anhydrous ammonia has a boiling point of -28 degrees below zero.

– When a vessel containing anhydrous ammonia is MOVED, the anhydrous

ammonia will reach its boiling point and pressurize.

•This pressurization can cause vessels to violently RUPTURE, or if the vessel pressurizes and does NOT rupture, the opening of the container of anhydrous

ammonia at a later time can cause RAPID, VIOLENT depressurization.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is mainly used in the U.S. as either a fertilizer or a refrigerant.

– Meth producers tend to store the anhydrous ammonia in IMPROPER/UNAPPROVED containers such as:

•Propane tanks,

• Igloo coolers, or

•Fire extinguishers.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia leaves a tell-tell sign as it flows through these UNAPPROVED

CONTAINERS – a blue or blue green discoloration on the valve.

– PAY ATTENTION to details!!!

Anhydrous Ammonia (Continued)

• Because propane cylinders (and the other unapproved containers) are NOT designed to store anhydrous ammonia, they can EXPLODE as the ammonia eats

through the walls of the cylinders.

– The valves, which take on a bluish/green color, frequently deteriorate and can cause hazardous leaks!!!

Anhydrous Ammonia (Continued)

• Do NOT touch, move, or open any kind of tank or sealed container!!!

– Be aware that propane tanks are often WEAKENED and BRITTLE due to the

anhydrous ammonia and are SENSITIVE to ANY kind of movement or impact.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• These pictures show what happened to a fire extinguisher that was used to store

anhydrous ammonia…

Anhydrous Ammonia (Continued)

• Illegal drug makers often STEAL anhydrous ammonia from areas where it is stored

and used, such as farms.

• Attempted thefts have also occurred at places such as:

– Refrigeration systems holding ammonia,

– Underground pipelines carrying ammonia, and

– Rail cars transporting anhydrous ammonia.

• Often thefts are aborted when thieves are injured or overcome by the toxic gas...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia thieves had better beware!!!

• There is a new product called GloTell that farmers can add to their anhydrous

ammonia tanks…

• Meth cooks will run the risk that the GloTell additive will turn their hands bright

pink!

– This bright pink stain will fluoresce under ultraviolet light even if washed off!!!

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Also, GloTell will produce pink methamphetamine that CANNOT be bleached.

– Users who snort meth made with GloTell will find that they have PINK NOSES!

– Users who inject meth made with GloTell will see a pink stain at the point of

injection!

Sodium Carbonate (Soda Ash)

Sodium Carbonate (Soda Ash) (Continued)

Lead Acetate

Iodine

• Iodine is a natural element, and it is helpful to the body in SMALL amounts.

– However, if iodine is taken in large amounts it can become toxic.

•Extremely high does of iodine can limit the function of the thyroid.

Iodine (Continued)

Iodine (Continued)

• Iodine is bluish-black, and it has a characteristic odor, a sharp acrid taste, and it produces a violet corrosive vapor.

– The vapor is irritating to the respiratory system and eyes.

• The solid iodine irritates the eyes and may burn the skin, and it may cause severe

internal irritation and damage if ingested.

Iodine (Continued)

• Iodine is known as the “blue ingredient” in the production of meth (in the “red, white, and blue” method).

Iodine (Continued)

Iodine (Continued)

• It takes approximately 4 bottles of iodine tincture to produce 2 – 3 grams of meth.

Iodine (Continued)

Iodine (Continued)

• Iodine leaves distinctive yellow-blue or brown stains on surfaces in former methlabs.

Iodine (Continued)

Iodine (Continued)

Iodine (Continued)

• The only good thing about iodine is that it leaves yellow stains.

• If you see yellow stained coffee filters, gloves or paper towels, this could be an

indicator that you’re in a lab.

• If you see yellow stains, you can spray some starch on them.

– If they turn a purplish blue/black, it’s iodine.

• Iodine is the only substance that reacts with soluble starch to produce a purplish black color.

– The only way to get iodine vapor all over the walls is to cook meth.

Mercurous Chloride

Rock Salt

Hydrogen Chloride

• Hydrogen chloride gas is commercially available.

• Hydrogen chloride gas can also be made by mixing sulfuric acid and salt.

• Muriatic acid is simply hydrogen chloride gas suspended in water.

• Hydrogen chloride gas can be seen as a pale white smoke.

– It is a poisonous gas that can cause respiratory problems and death.

Hydrogen Chloride (Continued)

Ammonium Nitrate

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Hydriodic Acid

• Hydriodic acid is a corrosive acid that is colorless when freshly prepared.

– When hydriodic acid is exposed to light and air, it turns yellowish and brown.

• Hydriodic acid is a solution of hydrogen iodide gas in water.

• Hydriodic acid vapor is irritating to the respiratory system, skin, and eyes.

• Hydriodic acid liquid causes severe burns to the eyes and skin.

• If hydriodic acid is accidentally ingested, it can cause severe internal irritation and

damage.

Hydriodic Acid (Continued)

Catalyst Chemicals

• Catalyst Chemicals:

– Chemicals which SPEED UP a reaction process and/or cause it to go to GREATER COMPLETION.

Red Phosphorus

• Red phosphorus is found ON matchboxes, in road flares, and other explosives.

– Red Phosphorus IGNITES when OVERHEATED!!!

• By combining red phosphorus and iodine, you can easily create the highly

controlled substance known as hydriodic acid (which is an essential ingredient in making meth).

– Creating 2 – 3 grams of meth requires about 4 big boxes of matches.

Red Phosphorus (Continued)

• Red phosphorous is highly flammable and if it is overheated it can become white

phosphorous…

– White phosphorous is a volatile and highly explosive substance.

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Lithium

• Lithium is used in batteries.

• Lithium seriously burns the skin upon contact.

– It also reacts VIOLENTLY with WATER and is highly explosive.

Lithium (Continued)

• Lithium reacts VIOLENTLY with WATER, and if it is splashed in the eyes during

cooking it will cause blindness.

– Lithium is extremely caustic to all body tissues.

Lithium (Continued)

Lithium (Continued)

• Lithium metal is HIGHLY water reactive and it will BURN or EXPLODE if it comes into contact with WATER!

• Because of the moisture in your skin, it will burn exposed flesh.

• Lithium metal will DEGRADE when exposed to atmospheric moisture…

– This is why meth cooks store lithium metal in a solvent prior to use.

• It is typical to see harvested lithium strips in Coleman fuel or Mineral Spirits to prevent explosions.

•Large quantities can be harvested and saved in these containers until needed

for a cook.

Lithium (Continued)

• If you see battery shells in the trashcan, on the floor, etc. – this is a VERY GOOD

indicator that you might be entering a meth lab!

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

• Lithium catches fire when in contact with water...

Solvent Chemicals

• Solvent Chemicals:

– A medium (liquid) in which a chemical operation takes place.

• Solvent chemicals (UNLIKE the precursor chemicals) CAN be

substituted/interchanged.

Ether

• Ether was once called “sweet vitriol” because of its hypnotic effect.

• Ether is a highly flammable substance that is used as an anesthetic agent –

especially in third world countries where more expensive anesthesia is not available.

– While inhaling the ether, patients could undergo complete surgical procedures while otherwise awake without feeling pain or concern.

Ether (Continued)

• Ether can be obtained from engine starting fluid.

• Ether is a solvent and it is flammable.

– It is particularly hazardous because it can cause BOTH fire and explosion.

• It has been said that a quart of ether can “level” a small house.

Ethyl Ether (Continued)

Ethyl Ether (Continued)

• Ether is VERY flammable and is HEAVIER than air.

– NEVER use ether near flames or non-sparkless motors.

– Ether is very PUNGENT – even a small evaporated amount of ether is VERY noticeable.

Acetone

• Acetone can be found in nail polish remover or paint thinner.

– It is extremely flammable.

• In the setting of a meth lab where meth is being cooked with high heat, acetone is

very dangerous.

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Toluene

• Toluene is used in brake fluid.

– When working with brake fluid (toluene), be careful not to spill it on your car

because it will eat away the paint and chrome…

• You also have to be careful using toluene around other household chemicals

because its high concentration of polyethylene glycol can cause it to ignite in a

violent fireball.

• Toluene is powerful enough to dissolve rubber.

Toluene (Continued)

• Toluene is used to form meth crystals.

– The fumes toluene releases can cause brain damage or death.

Toluene (Continued)

Toluene (Continued)

Ethanol

Isopropanol

Isopropanol (Continued)

Isopropyl Alcohol

Methanol

Methanol (Continued)

Methanol (Continued)

Benzene

Benzene (Continued)

Which of these is NOT a common ingredient in Meth?

Nail Polish Remover

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Methamphetamine- PowerPoint

- Chemicals and Ingredients Used to Make Meth

CJUS 240

Economic Costs of Meth

• The economic cost of methamphetamine use in the U.S. reached $23.4 billion in

2005.

– This includes the burden of addiction, premature death, drug treatment, child

care, and cleaning of lab sites.

– This figure does NOT take into account the future needs of the meth user.

Concerns with ACTIVE Meth Labs

• Danger of fire and explosion

• Chemical spills

• Inhalation of solvents, corrosives, and toxic gases

• “Booby traps”

• Waste disposal

Concerns with FORMER Meth Labs

• Vapors

• Chemical residues

• Methamphetamine residues

• Waste disposal

Equipment Used in Meth Production

• Pyrex or Corning dishes

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

• Coffee Filters

Equipment Used in Meth Production

Equipment Used in Meth Production

Basic Chemical Requirements

• In a clandestine laboratory, basic types of chemicals are necessary in order to

produce the desired drug.

– The basic types of chemicals needed are:

1) Precursor Chemicals

2) Reagent Chemicals

3) Catalyst Chemicals

4) Solvent Chemicals

List I Chemical

• The term “List I chemical” means a chemical specified by regulation of the Attorney General as a chemical that is used in manufacturing a controlled substance and is

IMPORTANT to the manufacture of the controlled substance.

• Examples of List I chemicals are:

– GBL

– Red Phosphorus

– Pseudoephedrine

List II Chemical

• The term “List II chemical” means a chemical (other than a List I chemical) specified by regulation of the Attorney General as a chemical that is USED in

manufacturing a controlled substance.

• Examples of List II chemicals are:

– Toluene

– Iodine

– Hydrochloric Acid

Precursor Chemicals

• Precursor Chemicals:

– A chemical that is ESSENTIAL to the production of a controlled substance and for

which NO SUBSTITUTION can be made.

Pseudoephedrine

• Pseudoephedrine is a decongestant found in cold medicine.

– Large amounts of pseudoephedrine on its own can harm the respiratory and nervous systems, as well as the heart.

Pseudoephedrine (Continued)

• Some of the common ways used to divert products containing pseudoephedrine

include:

– “Smurfing” – making multiple purchases at different locations

– Shelf-Sweeping – the theft of all shelf stock

– Shoplifting

– Theft from wholesalers

Pseudoephedrine (Continued)

• Pseudoephedrine smurfing is a method used by some methamphetamine producers to acquire large quantities of pseudoephedrine by enlisting the assistance of several

friends or associates (often referred to as “smurfers”) to make purchases at or below the legal thresholds from multiple retail locations.

– Smurfers are often addicts who trade the pseudoephedrine for finished

methamphetamine.

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

• About 680 pseudoephedrine tablets are needed to produce one ounce of meth…

Pseudoephedrine (Continued)

Out With a Bang

An Unstable Recipe…

• Meth contains a variety of poisonous ingredients…

– Some become EVEN MORE DANGEROUS once the cooking process begins…

Common Ingredients to Make Methamphetamine

Reagent Chemicals

• Reagent Chemicals:

– Chemicals which REACT upon the precursor chemical causing it to chemicallyCHANGE.

• A reagent chemical is a chemical which is required for the synthesis of an illicit drug substance, but which is NOT incorporated into the final chemical product.

Hydrochloric Acid

• Hydrochloric acid is a highly corrosive liquid that is used to make plastic (such as PVC pipe and polyurethane).

– It can remove rust and iron-oxide from steel and is highly corrosive to human

skin.

•Hydrochloric acid makes up the majority of the gastric acid in the human

digestive fluid.

• In high concentrations, hydrochloric acid will literally eat away human flesh…

Hydrochloric Acid (Continued)

• Hydrochloric acid can be purchased from hardware stores as:

– Tile and Grout Acid Cleaner

– Muriatic Acid

– Pool Acid

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

• Hydrochloric acid is a solution of hydrogen chloride gas suspended in water.

– Hydrochloric acid is corrosive and is a light yellow liquid color from traces of iron, chlorine, and organic matter.

• Inhaling hydrochloric acid may cause coughing or choking, inflammation, and

ulceration of the respiratory tract.

• Concentrated solutions of hydrochloric acid can cause severe burns and irritate the

mucous membranes, eyes, and respiratory tract.

– Exposure to hydrochloric acid vapors may result in pulmonary edema and

possibly death.

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

Sodium Hydroxide (NaOH)

• Sodium hydroxide is also called Lye.

• Sodium hydroxide is classified as a corrosive, and it is one of the main chemicals in

drain cleaner.

– It is also used in aluminum etching and to create biodiesal.

– It can burn the skin or cause blindness.

• Sodium hydroxide is used to dispose of road kill because it turns the dead bodies

into a coffee-like liquid.

Sodium Hydroxide (NaOH) (Continued)

• Drain cleaner (sodium hydroxide) is extremely corrosive, and without wearing

protection, even the smallest spill on the skin can eat through flesh…

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sulfuric Acid (H2SO4)

• Sulfuric acid is used in drain or toilet bowl cleaner as well as battery acid.

– It is another highly corrosive substance that burns the skin on contact.

Sulfuric Acid (H2SO4) (Continued)

• The product label warning for Drano® (sulfuric acid) says it all:

– DANGER: MAY BURN EYES AND SKIN ON CONTACT.

•HARMFUL IF SWALLOWED.

–Avoid contact with body and clothing.

•TOXIC GAS MAY FORM IF MIXED WITH OTHER CHEMICALS.

–If gases are released, leave immediately and ventilate area.

•FIRST AID: Give Immediately:

–EYES AND SKIN:

»Flush with water for 20 minutes.

»Remove affected clothing.

–IF SWALLOWED:

»Rinse mouth and drink a glass of water or milk.

»Do not induce vomiting.

–THEN SEEK MEDICAL AID.

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Hypophosphorous Acid (H3PO2)

• Hypophosphorous acid, which is used legally for a variety of commercial purposes, is a chemical that increasingly is substituted for red phosphorus in the methamphetamine production process.

– The use of hypophospherous acid SIGNIFICANTLY increases the risk of fire!!!

• The federal government regulates the sale of hypophosphorous acid through registration, record keeping, reporting, and import/export requirements regardless

of the quantity being handled or distributed.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid is a colorless oily liquid that emits a SOUR odor.

– There is an extreme fire and explosion hazard if the hypophosphorous acid

comes into contact with a solvent such as acetone, toluene, or Coleman fuel.

• Hypophosphorous acid will also emit phosphine gas and the fumes can ignite.

Hypophosphorous Acid (H3PO2) (Continued)

• Although hypophosphorous acid is a List I chemical under the Controlled Substances Act, methamphetamine producers typically purchase the chemical via

the internet or from associates who also are engaged in methamphetamine

production.

– The use of hypophosphorous acid in methamphetamine production is an

EXTREMELY DANGEROUS PRACTICE because of the deadly gases that can be generated as well as the risk of fire or explosion.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid (H3PO2, also called phosphinic acid) is a strong acid that typically is prepared as a solution of colorless, oily liquid in strengths of 50%, 30 to 32%, and 10%.

– It also is prepared in the form of salts (referred to as hypophosphite salts), particularly ammonium hypophosphite, calcium hypophosphite, iron (ferric)

hypophosphite, magnesium hypophosphite, manganese hypophosphite,

potassium hypophosphite, and sodium hypophosphite.

Hypophosphorous Acid (H3PO2) (Continued)

• Over 100 chemical firms located throughout the world produce hypophosphorous

acid.

– The People's Republic of China and India have the largest numbers of

hypophosphorous acid producers, although there are a few producers in the United States.

• There are a wide variety of uses for hypophosphorous acid and its salts in

commercial industry; however, the chemicals have no legitimate household or retail uses.

Hypophosphorous Acid (H3PO2) (Continued)

• The legitimate commercial and laboratory fields that use hypophosphorous acid and its salts include the following:

– Chemical plating

– Food preparation

– Water treatment

– Polymers (as a bleaching agent, color stabilizer, or catalyst)

– Education and research in analytical chemistry

Hypophosphorous Acid (H3PO2) (Continued)

• Chemical suppliers typically distribute hypophosphorous acid in large quantities, for example, in drums containing 275 pounds of the diluted solution.

– Hypophosphorous acid also is distributed in smaller quantities.

• One-half liter of 50% concentrate hypophosphorous acid solution can be obtained from chemical suppliers for as little as $14.

Hypophosphorous Acid (H3PO2) (Continued)

• Methamphetamine laboratory operators typically obtain small quantities of the chemical from other laboratory operators who purchase large quantities of the

chemical and repackage it for further distribution.

– According to law enforcement sources, these individuals sell hypophosphorous acid for as much as $1,000 per half-liter.

•Methamphetamine laboratory operators also purchase hypophosphorous acidvia the internet.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid and the Internet

• The internet is a source of a great deal of information regarding hypophosphorous acid.

• Popular internet sites that disseminate information about illicit drugs contain information about the chemical, including numerous recipes for home production of

methamphetamine using hypophosphorous acid.

• There also are recipes for synthesizing hypophosphorous acid from available chemicals.

• Hypophosphorous acid solutions and salts have been sold to the general public via the internet.

• The Drug Enforcement Administration (DEA) has strong concerns regarding the sale

of chemicals on the internet and has requested that any sites (such as auction sites) that allow the sale of regulated chemicals on their domains require proof of

DEA registration from their clients.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid Used in Methamphetamine Production

• Hypophosphorous acid is used in the ephedrine-pseudoephedrine reduction method

of methamphetamine production.

– It is used in the methamphetamine production process to produce hydriodic acid,

an important reagent (it reacts with the ephedrine-pseudoephedrine but does NOT become part of the finished product).

Hypophosphorous Acid (H3PO2) (Continued)

• The regulation of hydriodic acid by DEA in 1993 rendered it virtually unavailable in

the United States.

– However, methamphetamine laboratory operators discovered methods to produce hydriodic acid using a combination of iodine in water with red phosphorus.

• Laboratory operators found that red phosphorus could be obtained easily, either

from commercial supply companies or by scraping the striker pads from matchbooks or matchboxes.

• Methamphetamine producers soon discovered that hypophosphorous acid ALSO could be used in combination with iodine and water to produce hydriodic acid.

Hypophosphorous Acid (H3PO2) (Continued)

• The practice of using hypophosphorous acid in methamphetamine production is

believed to have begun in the United States in the late 1990s when a methamphetamine producer in Colorado obtained the recipe from Australia, where the hypophosphorous acid method is prevalent.

– This man was known as a serial cook who had a long history of

methamphetamine production.

•Over several years he trained other laboratory operators in Colorado to produce methamphetamine using hypophosphorous acid.

• As his techniques were passed on to others, the number of methamphetaminelaboratories in Colorado using hypophosphorous acid continued to increase, and the

technique was passed on to numerous methamphetamine producers in other

states.

Hypophosphorous Acid (H3PO2) (Continued)

• According to the El Paso Intelligence Center (EPIC) National Clandestine Laboratory Seizure System, from 2000 through 2002 the number of seized methamphetaminelaboratories in the United States in which hypophosphorous acid was found

increased overall. (See Table 1.)

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid found at methamphetamine laboratories is packaged in a variety of ways.

• The chemical has been found in 1-gallon bottles of solution or in 1-pound jars of salts.

• Some hypophosphorous acid containers are labeled as "plating solution."

• Pint-sized brown glass bottles wrapped in red electrical tape also have been found to contain hypophosphorous acid; they have been discovered primarily in Colorado.

• The vast majority of hypophosphorous acid found at laboratory sites has been recovered from small toxic laboratories (STLs), those which yield gram to ounce

quantities per production cycle.

• Hypophosphorous acid has not been reported at large-scale laboratories operated by Mexican criminal groups in the United States.

Hypophosphorous Acid (H3PO2) (Continued)

• Hazards

• The iodine-hypophosphorous acid method is MORE HAZORDOUS than the iodine-

red phosphorus method, although the reaction using hypophosphorous acid is

faster and gives slightly higher yields.

– When hypophosphorous acid is used, the chemicals must be mixed together SLOWLY in a PARTICULAR ORDER to prevent them from reacting violently.

Hypophosphorous Acid (H3PO2) (Continued)

• The combination of hypophosphorous acid with the other chemicals and with

certain metals can produce deadly phosphine gas during the initial mixing step and

can CONTINUE to produce phosphine gas for several days AFTER production has been completed…

Hypophosphorous Acid (H3PO2) (Continued)

• The iodine-hypophosphorous acid mixture has a tendency to decompose quickly when overheated or if heated for long periods of time, becoming cloudy or "milky-

white" just prior to giving off a cloud of phosphine gas that can ignite spontaneously.

– Hypophosphorous acid solutions may become unstable if evaporation results in

concentrations above 50%.

Hypophosphorous Acid (H3PO2) (Continued)

• [Note: Law enforcement or emergency personnel who encounter suspected

containers of hypophosphorous acid should use extreme care during handling because laboratory operators often attempt to obtain a more concentrated acid by

allowing water to evaporate from the mixture.]

• Because hypophosphorous acid often is used at small methamphetaminelaboratories operated by inexperienced or careless individuals, the potential hazards

of using this method are even greater.

• The risk of fire and explosion is higher in these laboratories, where professional

laboratory equipment typically is not used to contain the phosphine gas and where

safe handling precautions are not employed.

• In addition, these laboratories often are located in homes where children are

present and may come into contact with hypophosphorous acid.

• A child can easily mistake hypophosphorous acid for any other clear liquid,

particularly if it is stored in household containers or drinking glasses.

• Skin, eye, or inhalation exposure can be extremely harmful or fatal.

Hypophosphorous Acid (H3PO2) (Continued)

• Safety Precautions

• Always wear a self-contained breathing apparatus as well as protective clothing when entering areas where hypophosphorous acid may be present.

• When in contact with metals or in a high-temperature environment,

hypophosphorous acid can break down and liberate phosphine and flammable hydrogen gas.

• Do not allow the use of open flames, open lights, matches, or smoking in or around laboratories or dumpsites where hypophosphorous acid is handled.

• In case of fire, use a self-contained positive pressure breathing apparatus and full

protective equipment.

• Use water spray, fog, foam, dry chemicals, or other reagents as may be

appropriate for materials in the surrounding fire.

• Water may be used to cool the containers of hypophosphorous acid; however, use extreme care to avoid allowing water to enter the container.

• In case of spills, neutralize the spilled chemical with alkaline material (soda ash, lime), then absorb it with an inert material such as vermiculite, dry sand, or earth

and place in a chemical waste container.

• Do not use combustible materials such as sawdust.

Hypophosphorous Acid (H3PO2) (Continued)

• Legislation and Control

• In the United States hypophosphorous acid is one of 38 chemicals (or groups of

chemicals) controlled under law by DEA.

• On October 17, 2001, hypophosphorous acid and its salts, along with red and white phosphorus, were officially added as List I chemicals under section 1310 of the

Code of Federal Regulations.

• List I chemicals are defined as chemicals that are used in the manufacture of a

controlled substance in violation of the Controlled Substances Act (CSA) and are

important to the manufacture of a controlled substance.

• Under the law, suppliers are required to maintain records and report receipts, sales,

imports, and exports of these chemicals to DEA.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid, red phosphorus, and white phosphorus, as well as

ephedrine, are unique in that suppliers are required to report all transactions of

these chemicals, regardless of the amount.

• By contrast, the other 34 listed chemicals are only reportable after a supplier's

transactions for a chemical reach an established weight or volume threshold in a calendar month.

• In addition to reporting all transactions involving the chemical, suppliers are

expected to "know their customers" in order to prevent the diversion of these substances to methamphetamine laboratories, as it is illegal to import, export,

purchase, or sell hypophosphorous acid or any other listed chemical in the United States if it is used or intended to be used in the production of a controlled

substance.

• Chemical suppliers are held liable for selling listed chemicals if they know or suspect that the chemical will be used for illicit purposes.

Hypophosphorous Acid (H3PO2) (Continued)

• Outlook

• The use of hypophosphorous acid in the production of methamphetamine is likely

to increase, particularly in the Midwest and Southwest regions of the United States

where methamphetamine production is prevalent.

– Injuries, property damage, and deaths also will increase as a growing number of

inexperienced methamphetamine producers experiment with hypophosphorous acid.

Anhydrous Ammonia

• Anhydrous ammonia is found in fertilizer, countertop cleaner, and commercial refrigerant.

– On its own, it has a pungent, suffocating odor.

• Mixing anhydrous ammonia with other chemicals can release highly toxic gases.

– Because anhydrous ammonia seeks out water (anhydrous means “without

water”) and causes severe burns, any body part that comes into contact with it

should be flushed with water for at least 15 minutes to remove the ammoniafrom the skin.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia has extremely destructive effects on humans.

– Anhydrous ammonia gives off vapors during cooking that can burn the mouth,

throat, and lung tissue.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Anhydrous ammonia seeks water from the nearest source, including the human body (anhydrous means “without water”).

– Because of their high moisture content, EYES, LUNGS, and SKIN are at the

greatest risk of attracting the ammonia.

• When large amounts of anhydrous ammonia are inhaled, the throat swells and the

victim suffocates.

– Exposure to the vapors or liquids can cause severe burns, blindness, or death.

• Anhydrous ammonia has an IDLH (immediately dangerous to life and health) at

only 300 parts per million...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is poses MANY hazards, especially when it is placed in improper vessels and handled/transported by individuals unfamiliar with the

dangers.

• Anhydrous ammonia has a boiling point of -28 degrees below zero.

– When a vessel containing anhydrous ammonia is MOVED, the anhydrous

ammonia will reach its boiling point and pressurize.

•This pressurization can cause vessels to violently RUPTURE, or if the vessel pressurizes and does NOT rupture, the opening of the container of anhydrous

ammonia at a later time can cause RAPID, VIOLENT depressurization.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is mainly used in the U.S. as either a fertilizer or a refrigerant.

– Meth producers tend to store the anhydrous ammonia in IMPROPER/UNAPPROVED containers such as:

•Propane tanks,

• Igloo coolers, or

•Fire extinguishers.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia leaves a tell-tell sign as it flows through these UNAPPROVED

CONTAINERS – a blue or blue green discoloration on the valve.

– PAY ATTENTION to details!!!

Anhydrous Ammonia (Continued)

• Because propane cylinders (and the other unapproved containers) are NOT designed to store anhydrous ammonia, they can EXPLODE as the ammonia eats

through the walls of the cylinders.

– The valves, which take on a bluish/green color, frequently deteriorate and can cause hazardous leaks!!!

Anhydrous Ammonia (Continued)

• Do NOT touch, move, or open any kind of tank or sealed container!!!

– Be aware that propane tanks are often WEAKENED and BRITTLE due to the

anhydrous ammonia and are SENSITIVE to ANY kind of movement or impact.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• These pictures show what happened to a fire extinguisher that was used to store

anhydrous ammonia…

Anhydrous Ammonia (Continued)

• Illegal drug makers often STEAL anhydrous ammonia from areas where it is stored

and used, such as farms.

• Attempted thefts have also occurred at places such as:

– Refrigeration systems holding ammonia,

– Underground pipelines carrying ammonia, and

– Rail cars transporting anhydrous ammonia.

• Often thefts are aborted when thieves are injured or overcome by the toxic gas...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia thieves had better beware!!!

• There is a new product called GloTell that farmers can add to their anhydrous

ammonia tanks…

• Meth cooks will run the risk that the GloTell additive will turn their hands bright

pink!

– This bright pink stain will fluoresce under ultraviolet light even if washed off!!!

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Also, GloTell will produce pink methamphetamine that CANNOT be bleached.

– Users who snort meth made with GloTell will find that they have PINK NOSES!

– Users who inject meth made with GloTell will see a pink stain at the point of

injection!

Sodium Carbonate (Soda Ash)

Sodium Carbonate (Soda Ash) (Continued)

Lead Acetate

Iodine

• Iodine is a natural element, and it is helpful to the body in SMALL amounts.

– However, if iodine is taken in large amounts it can become toxic.

•Extremely high does of iodine can limit the function of the thyroid.

Iodine (Continued)

Iodine (Continued)

• Iodine is bluish-black, and it has a characteristic odor, a sharp acrid taste, and it produces a violet corrosive vapor.

– The vapor is irritating to the respiratory system and eyes.

• The solid iodine irritates the eyes and may burn the skin, and it may cause severe

internal irritation and damage if ingested.

Iodine (Continued)

• Iodine is known as the “blue ingredient” in the production of meth (in the “red, white, and blue” method).

Iodine (Continued)

Iodine (Continued)

• It takes approximately 4 bottles of iodine tincture to produce 2 – 3 grams of meth.

Iodine (Continued)

Iodine (Continued)

• Iodine leaves distinctive yellow-blue or brown stains on surfaces in former methlabs.

Iodine (Continued)

Iodine (Continued)

Iodine (Continued)

• The only good thing about iodine is that it leaves yellow stains.

• If you see yellow stained coffee filters, gloves or paper towels, this could be an

indicator that you’re in a lab.

• If you see yellow stains, you can spray some starch on them.

– If they turn a purplish blue/black, it’s iodine.

• Iodine is the only substance that reacts with soluble starch to produce a purplish black color.

– The only way to get iodine vapor all over the walls is to cook meth.

Mercurous Chloride

Rock Salt

Hydrogen Chloride

• Hydrogen chloride gas is commercially available.

• Hydrogen chloride gas can also be made by mixing sulfuric acid and salt.

• Muriatic acid is simply hydrogen chloride gas suspended in water.

• Hydrogen chloride gas can be seen as a pale white smoke.

– It is a poisonous gas that can cause respiratory problems and death.

Hydrogen Chloride (Continued)

Ammonium Nitrate

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Hydriodic Acid

• Hydriodic acid is a corrosive acid that is colorless when freshly prepared.

– When hydriodic acid is exposed to light and air, it turns yellowish and brown.

• Hydriodic acid is a solution of hydrogen iodide gas in water.

• Hydriodic acid vapor is irritating to the respiratory system, skin, and eyes.

• Hydriodic acid liquid causes severe burns to the eyes and skin.

• If hydriodic acid is accidentally ingested, it can cause severe internal irritation and

damage.

Hydriodic Acid (Continued)

Catalyst Chemicals

• Catalyst Chemicals:

– Chemicals which SPEED UP a reaction process and/or cause it to go to GREATER COMPLETION.

Red Phosphorus

• Red phosphorus is found ON matchboxes, in road flares, and other explosives.

– Red Phosphorus IGNITES when OVERHEATED!!!

• By combining red phosphorus and iodine, you can easily create the highly

controlled substance known as hydriodic acid (which is an essential ingredient in making meth).

– Creating 2 – 3 grams of meth requires about 4 big boxes of matches.

Red Phosphorus (Continued)

• Red phosphorous is highly flammable and if it is overheated it can become white

phosphorous…

– White phosphorous is a volatile and highly explosive substance.

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Lithium

• Lithium is used in batteries.

• Lithium seriously burns the skin upon contact.

– It also reacts VIOLENTLY with WATER and is highly explosive.

Lithium (Continued)

• Lithium reacts VIOLENTLY with WATER, and if it is splashed in the eyes during

cooking it will cause blindness.

– Lithium is extremely caustic to all body tissues.

Lithium (Continued)

Lithium (Continued)

• Lithium metal is HIGHLY water reactive and it will BURN or EXPLODE if it comes into contact with WATER!

• Because of the moisture in your skin, it will burn exposed flesh.

• Lithium metal will DEGRADE when exposed to atmospheric moisture…

– This is why meth cooks store lithium metal in a solvent prior to use.

• It is typical to see harvested lithium strips in Coleman fuel or Mineral Spirits to prevent explosions.

•Large quantities can be harvested and saved in these containers until needed

for a cook.

Lithium (Continued)

• If you see battery shells in the trashcan, on the floor, etc. – this is a VERY GOOD

indicator that you might be entering a meth lab!

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

• Lithium catches fire when in contact with water...

Solvent Chemicals

• Solvent Chemicals:

– A medium (liquid) in which a chemical operation takes place.

• Solvent chemicals (UNLIKE the precursor chemicals) CAN be

substituted/interchanged.

Ether

• Ether was once called “sweet vitriol” because of its hypnotic effect.

• Ether is a highly flammable substance that is used as an anesthetic agent –

especially in third world countries where more expensive anesthesia is not available.

– While inhaling the ether, patients could undergo complete surgical procedures while otherwise awake without feeling pain or concern.

Ether (Continued)

• Ether can be obtained from engine starting fluid.

• Ether is a solvent and it is flammable.

– It is particularly hazardous because it can cause BOTH fire and explosion.

• It has been said that a quart of ether can “level” a small house.

Ethyl Ether (Continued)

Ethyl Ether (Continued)

• Ether is VERY flammable and is HEAVIER than air.

– NEVER use ether near flames or non-sparkless motors.

– Ether is very PUNGENT – even a small evaporated amount of ether is VERY noticeable.

Acetone

• Acetone can be found in nail polish remover or paint thinner.

– It is extremely flammable.

• In the setting of a meth lab where meth is being cooked with high heat, acetone is

very dangerous.

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Toluene

• Toluene is used in brake fluid.

– When working with brake fluid (toluene), be careful not to spill it on your car

because it will eat away the paint and chrome…

• You also have to be careful using toluene around other household chemicals

because its high concentration of polyethylene glycol can cause it to ignite in a

violent fireball.

• Toluene is powerful enough to dissolve rubber.

Toluene (Continued)

• Toluene is used to form meth crystals.

– The fumes toluene releases can cause brain damage or death.

Toluene (Continued)

Toluene (Continued)

Ethanol

Isopropanol

Isopropanol (Continued)

Isopropyl Alcohol

Methanol

Methanol (Continued)

Methanol (Continued)

Benzene

Benzene (Continued)

Which of these is NOT a common ingredient in Meth?

Nail Polish Remover

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Methamphetamine- PowerPoint

- Chemicals and Ingredients Used to Make Meth

CJUS 240

Economic Costs of Meth

• The economic cost of methamphetamine use in the U.S. reached $23.4 billion in

2005.

– This includes the burden of addiction, premature death, drug treatment, child

care, and cleaning of lab sites.

– This figure does NOT take into account the future needs of the meth user.

Concerns with ACTIVE Meth Labs

• Danger of fire and explosion

• Chemical spills

• Inhalation of solvents, corrosives, and toxic gases

• “Booby traps”

• Waste disposal

Concerns with FORMER Meth Labs

• Vapors

• Chemical residues

• Methamphetamine residues

• Waste disposal

Equipment Used in Meth Production

• Pyrex or Corning dishes

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

• Coffee Filters

Equipment Used in Meth Production

Equipment Used in Meth Production

Basic Chemical Requirements

• In a clandestine laboratory, basic types of chemicals are necessary in order to

produce the desired drug.

– The basic types of chemicals needed are:

1) Precursor Chemicals

2) Reagent Chemicals

3) Catalyst Chemicals

4) Solvent Chemicals

List I Chemical

• The term “List I chemical” means a chemical specified by regulation of the Attorney General as a chemical that is used in manufacturing a controlled substance and is IMPORTANT to the manufacture of the controlled substance.

• Examples of List I chemicals are:

– GBL

– Red Phosphorus

– Pseudoephedrine

List II Chemical

• The term “List II chemical” means a chemical (other than a List I chemical) specified by regulation of the Attorney General as a chemical that is USED in

manufacturing a controlled substance.

• Examples of List II chemicals are:

– Toluene

– Iodine

– Hydrochloric Acid

Precursor Chemicals

• Precursor Chemicals:

– A chemical that is ESSENTIAL to the production of a controlled substance and for

which NO SUBSTITUTION can be made.

Pseudoephedrine

• Pseudoephedrine is a decongestant found in cold medicine.

– Large amounts of pseudoephedrine on its own can harm the respiratory and nervous systems, as well as the heart.

Pseudoephedrine (Continued)

• Some of the common ways used to divert products containing pseudoephedrine

include:

– “Smurfing” – making multiple purchases at different locations

– Shelf-Sweeping – the theft of all shelf stock

– Shoplifting

– Theft from wholesalers

Pseudoephedrine (Continued)

• Pseudoephedrine smurfing is a method used by some methamphetamine producers to acquire large quantities of pseudoephedrine by enlisting the assistance of several

friends or associates (often referred to as “smurfers”) to make purchases at or below the legal thresholds from multiple retail locations.

– Smurfers are often addicts who trade the pseudoephedrine for finished

methamphetamine.

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

• About 680 pseudoephedrine tablets are needed to produce one ounce of meth…

Pseudoephedrine (Continued)

Out With a Bang

An Unstable Recipe…

• Meth contains a variety of poisonous ingredients…

– Some become EVEN MORE DANGEROUS once the cooking process begins…

Common Ingredients to Make Methamphetamine

Reagent Chemicals

• Reagent Chemicals:

– Chemicals which REACT upon the precursor chemical causing it to chemicallyCHANGE.

• A reagent chemical is a chemical which is required for the synthesis of an illicit drug substance, but which is NOT incorporated into the final chemical product.

Hydrochloric Acid

• Hydrochloric acid is a highly corrosive liquid that is used to make plastic (such as PVC pipe and polyurethane).

– It can remove rust and iron-oxide from steel and is highly corrosive to human

skin.

•Hydrochloric acid makes up the majority of the gastric acid in the human

digestive fluid.

• In high concentrations, hydrochloric acid will literally eat away human flesh…

Hydrochloric Acid (Continued)

• Hydrochloric acid can be purchased from hardware stores as:

– Tile and Grout Acid Cleaner

– Muriatic Acid

– Pool Acid

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

• Hydrochloric acid is a solution of hydrogen chloride gas suspended in water.

– Hydrochloric acid is corrosive and is a light yellow liquid color from traces of iron, chlorine, and organic matter.

• Inhaling hydrochloric acid may cause coughing or choking, inflammation, and

ulceration of the respiratory tract.

• Concentrated solutions of hydrochloric acid can cause severe burns and irritate the

mucous membranes, eyes, and respiratory tract.

– Exposure to hydrochloric acid vapors may result in pulmonary edema and

possibly death.

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

Sodium Hydroxide (NaOH)

• Sodium hydroxide is also called Lye.

• Sodium hydroxide is classified as a corrosive, and it is one of the main chemicals in

drain cleaner.

– It is also used in aluminum etching and to create biodiesal.

– It can burn the skin or cause blindness.

• Sodium hydroxide is used to dispose of road kill because it turns the dead bodies into a coffee-like liquid.

Sodium Hydroxide (NaOH) (Continued)

• Drain cleaner (sodium hydroxide) is extremely corrosive, and without wearing

protection, even the smallest spill on the skin can eat through flesh…

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sulfuric Acid (H2SO4)

• Sulfuric acid is used in drain or toilet bowl cleaner as well as battery acid.

– It is another highly corrosive substance that burns the skin on contact.

Sulfuric Acid (H2SO4) (Continued)

• The product label warning for Drano® (sulfuric acid) says it all:

– DANGER: MAY BURN EYES AND SKIN ON CONTACT.

•HARMFUL IF SWALLOWED.

–Avoid contact with body and clothing.

•TOXIC GAS MAY FORM IF MIXED WITH OTHER CHEMICALS.

–If gases are released, leave immediately and ventilate area.

•FIRST AID: Give Immediately:

–EYES AND SKIN:

»Flush with water for 20 minutes.

»Remove affected clothing.

–IF SWALLOWED:

»Rinse mouth and drink a glass of water or milk.

»Do not induce vomiting.

–THEN SEEK MEDICAL AID.

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Hypophosphorous Acid (H3PO2)

• Hypophosphorous acid, which is used legally for a variety of commercial purposes,

is a chemical that increasingly is substituted for red phosphorus in the methamphetamine production process.

– The use of hypophospherous acid SIGNIFICANTLY increases the risk of fire!!!

• The federal government regulates the sale of hypophosphorous acid through registration, record keeping, reporting, and import/export requirements regardless

of the quantity being handled or distributed.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid is a colorless oily liquid that emits a SOUR odor.

– There is an extreme fire and explosion hazard if the hypophosphorous acid

comes into contact with a solvent such as acetone, toluene, or Coleman fuel.

• Hypophosphorous acid will also emit phosphine gas and the fumes can ignite.

Hypophosphorous Acid (H3PO2) (Continued)

• Although hypophosphorous acid is a List I chemical under the Controlled Substances Act, methamphetamine producers typically purchase the chemical via

the internet or from associates who also are engaged in methamphetamine

production.

– The use of hypophosphorous acid in methamphetamine production is an

EXTREMELY DANGEROUS PRACTICE because of the deadly gases that can be generated as well as the risk of fire or explosion.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid (H3PO2, also called phosphinic acid) is a strong acid that

typically is prepared as a solution of colorless, oily liquid in strengths of 50%, 30 to 32%, and 10%.

– It also is prepared in the form of salts (referred to as hypophosphite salts), particularly ammonium hypophosphite, calcium hypophosphite, iron (ferric)

hypophosphite, magnesium hypophosphite, manganese hypophosphite,

potassium hypophosphite, and sodium hypophosphite.

Hypophosphorous Acid (H3PO2) (Continued)

• Over 100 chemical firms located throughout the world produce hypophosphorous

acid.

– The People's Republic of China and India have the largest numbers of

hypophosphorous acid producers, although there are a few producers in the United States.

• There are a wide variety of uses for hypophosphorous acid and its salts in

commercial industry; however, the chemicals have no legitimate household or retail uses.

Hypophosphorous Acid (H3PO2) (Continued)

• The legitimate commercial and laboratory fields that use hypophosphorous acid and its salts include the following:

– Chemical plating

– Food preparation

– Water treatment

– Polymers (as a bleaching agent, color stabilizer, or catalyst)

– Education and research in analytical chemistry

Hypophosphorous Acid (H3PO2) (Continued)

• Chemical suppliers typically distribute hypophosphorous acid in large quantities, for example, in drums containing 275 pounds of the diluted solution.

– Hypophosphorous acid also is distributed in smaller quantities.

• One-half liter of 50% concentrate hypophosphorous acid solution can be obtained from chemical suppliers for as little as $14.

Hypophosphorous Acid (H3PO2) (Continued)

• Methamphetamine laboratory operators typically obtain small quantities of the chemical from other laboratory operators who purchase large quantities of the

chemical and repackage it for further distribution.

– According to law enforcement sources, these individuals sell hypophosphorous acid for as much as $1,000 per half-liter.

•Methamphetamine laboratory operators also purchase hypophosphorous acidvia the internet.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid and the Internet

• The internet is a source of a great deal of information regarding hypophosphorous acid.

• Popular internet sites that disseminate information about illicit drugs contain information about the chemical, including numerous recipes for home production of

methamphetamine using hypophosphorous acid.

• There also are recipes for synthesizing hypophosphorous acid from available chemicals.

• Hypophosphorous acid solutions and salts have been sold to the general public via the internet.

• The Drug Enforcement Administration (DEA) has strong concerns regarding the sale

of chemicals on the internet and has requested that any sites (such as auction sites) that allow the sale of regulated chemicals on their domains require proof of

DEA registration from their clients.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid Used in Methamphetamine Production

• Hypophosphorous acid is used in the ephedrine-pseudoephedrine reduction method

of methamphetamine production.

– It is used in the methamphetamine production process to produce hydriodic acid,

an important reagent (it reacts with the ephedrine-pseudoephedrine but does NOT become part of the finished product).

Hypophosphorous Acid (H3PO2) (Continued)

• The regulation of hydriodic acid by DEA in 1993 rendered it virtually unavailable in

the United States.

– However, methamphetamine laboratory operators discovered methods to

produce hydriodic acid using a combination of iodine in water with red phosphorus.

• Laboratory operators found that red phosphorus could be obtained easily, either from commercial supply companies or by scraping the striker pads from matchbooks or matchboxes.

• Methamphetamine producers soon discovered that hypophosphorous acid ALSO could be used in combination with iodine and water to produce hydriodic acid.

Hypophosphorous Acid (H3PO2) (Continued)

• The practice of using hypophosphorous acid in methamphetamine production is

believed to have begun in the United States in the late 1990s when a methamphetamine producer in Colorado obtained the recipe from Australia, where

the hypophosphorous acid method is prevalent.

– This man was known as a serial cook who had a long history of

methamphetamine production.

•Over several years he trained other laboratory operators in Colorado to produce methamphetamine using hypophosphorous acid.

• As his techniques were passed on to others, the number of methamphetaminelaboratories in Colorado using hypophosphorous acid continued to increase, and the

technique was passed on to numerous methamphetamine producers in other

states.

Hypophosphorous Acid (H3PO2) (Continued)

• According to the El Paso Intelligence Center (EPIC) National Clandestine Laboratory

Seizure System, from 2000 through 2002 the number of seized methamphetaminelaboratories in the United States in which hypophosphorous acid was found

increased overall. (See Table 1.)

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid found at methamphetamine laboratories is packaged in a variety of ways.

• The chemical has been found in 1-gallon bottles of solution or in 1-pound jars of salts.

• Some hypophosphorous acid containers are labeled as "plating solution."

• Pint-sized brown glass bottles wrapped in red electrical tape also have been found to contain hypophosphorous acid; they have been discovered primarily in Colorado.

• The vast majority of hypophosphorous acid found at laboratory sites has been recovered from small toxic laboratories (STLs), those which yield gram to ounce

quantities per production cycle.

• Hypophosphorous acid has not been reported at large-scale laboratories operated by Mexican criminal groups in the United States.

Hypophosphorous Acid (H3PO2) (Continued)

• Hazards

• The iodine-hypophosphorous acid method is MORE HAZORDOUS than the iodine-

red phosphorus method, although the reaction using hypophosphorous acid is

faster and gives slightly higher yields.

– When hypophosphorous acid is used, the chemicals must be mixed together

SLOWLY in a PARTICULAR ORDER to prevent them from reacting violently.

Hypophosphorous Acid (H3PO2) (Continued)

• The combination of hypophosphorous acid with the other chemicals and with

certain metals can produce deadly phosphine gas during the initial mixing step and

can CONTINUE to produce phosphine gas for several days AFTER production has been completed…

Hypophosphorous Acid (H3PO2) (Continued)

• The iodine-hypophosphorous acid mixture has a tendency to decompose quickly when overheated or if heated for long periods of time, becoming cloudy or "milky-

white" just prior to giving off a cloud of phosphine gas that can ignite spontaneously.

– Hypophosphorous acid solutions may become unstable if evaporation results in

concentrations above 50%.

Hypophosphorous Acid (H3PO2) (Continued)

• [Note: Law enforcement or emergency personnel who encounter suspected

containers of hypophosphorous acid should use extreme care during handling because laboratory operators often attempt to obtain a more concentrated acid by

allowing water to evaporate from the mixture.]

• Because hypophosphorous acid often is used at small methamphetaminelaboratories operated by inexperienced or careless individuals, the potential hazards

of using this method are even greater.

• The risk of fire and explosion is higher in these laboratories, where professional

laboratory equipment typically is not used to contain the phosphine gas and where

safe handling precautions are not employed.

• In addition, these laboratories often are located in homes where children are

present and may come into contact with hypophosphorous acid.

• A child can easily mistake hypophosphorous acid for any other clear liquid,

particularly if it is stored in household containers or drinking glasses.

• Skin, eye, or inhalation exposure can be extremely harmful or fatal.

Hypophosphorous Acid (H3PO2) (Continued)

• Safety Precautions

• Always wear a self-contained breathing apparatus as well as protective clothing when entering areas where hypophosphorous acid may be present.

• When in contact with metals or in a high-temperature environment,

hypophosphorous acid can break down and liberate phosphine and flammable hydrogen gas.

• Do not allow the use of open flames, open lights, matches, or smoking in or around laboratories or dumpsites where hypophosphorous acid is handled.

• In case of fire, use a self-contained positive pressure breathing apparatus and full

protective equipment.

• Use water spray, fog, foam, dry chemicals, or other reagents as may be

appropriate for materials in the surrounding fire.

• Water may be used to cool the containers of hypophosphorous acid; however, use extreme care to avoid allowing water to enter the container.

• In case of spills, neutralize the spilled chemical with alkaline material (soda ash, lime), then absorb it with an inert material such as vermiculite, dry sand, or earth and place in a chemical waste container.

• Do not use combustible materials such as sawdust.

Hypophosphorous Acid (H3PO2) (Continued)

• Legislation and Control

• In the United States hypophosphorous acid is one of 38 chemicals (or groups of

chemicals) controlled under law by DEA.

• On October 17, 2001, hypophosphorous acid and its salts, along with red and white phosphorus, were officially added as List I chemicals under section 1310 of the

Code of Federal Regulations.

• List I chemicals are defined as chemicals that are used in the manufacture of a controlled substance in violation of the Controlled Substances Act (CSA) and are

important to the manufacture of a controlled substance.

• Under the law, suppliers are required to maintain records and report receipts, sales,

imports, and exports of these chemicals to DEA.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid, red phosphorus, and white phosphorus, as well as

ephedrine, are unique in that suppliers are required to report all transactions of

these chemicals, regardless of the amount.

• By contrast, the other 34 listed chemicals are only reportable after a supplier's

transactions for a chemical reach an established weight or volume threshold in a calendar month.

• In addition to reporting all transactions involving the chemical, suppliers are

expected to "know their customers" in order to prevent the diversion of these substances to methamphetamine laboratories, as it is illegal to import, export,

purchase, or sell hypophosphorous acid or any other listed chemical in the United States if it is used or intended to be used in the production of a controlled

substance.

• Chemical suppliers are held liable for selling listed chemicals if they know or suspect that the chemical will be used for illicit purposes.

Hypophosphorous Acid (H3PO2) (Continued)

• Outlook

• The use of hypophosphorous acid in the production of methamphetamine is likely to increase, particularly in the Midwest and Southwest regions of the United States

where methamphetamine production is prevalent.

– Injuries, property damage, and deaths also will increase as a growing number of

inexperienced methamphetamine producers experiment with hypophosphorous acid.

Anhydrous Ammonia

• Anhydrous ammonia is found in fertilizer, countertop cleaner, and commercial refrigerant.

– On its own, it has a pungent, suffocating odor.

• Mixing anhydrous ammonia with other chemicals can release highly toxic gases.

– Because anhydrous ammonia seeks out water (anhydrous means “without

water”) and causes severe burns, any body part that comes into contact with it

should be flushed with water for at least 15 minutes to remove the ammoniafrom the skin.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia has extremely destructive effects on humans.

– Anhydrous ammonia gives off vapors during cooking that can burn the mouth,

throat, and lung tissue.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Anhydrous ammonia seeks water from the nearest source, including the human body (anhydrous means “without water”).

– Because of their high moisture content, EYES, LUNGS, and SKIN are at the

greatest risk of attracting the ammonia.

• When large amounts of anhydrous ammonia are inhaled, the throat swells and the victim suffocates.

– Exposure to the vapors or liquids can cause severe burns, blindness, or death.

• Anhydrous ammonia has an IDLH (immediately dangerous to life and health) at

only 300 parts per million...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is poses MANY hazards, especially when it is placed in improper vessels and handled/transported by individuals unfamiliar with the

dangers.

• Anhydrous ammonia has a boiling point of -28 degrees below zero.

– When a vessel containing anhydrous ammonia is MOVED, the anhydrous

ammonia will reach its boiling point and pressurize.

•This pressurization can cause vessels to violently RUPTURE, or if the vessel pressurizes and does NOT rupture, the opening of the container of anhydrous

ammonia at a later time can cause RAPID, VIOLENT depressurization.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is mainly used in the U.S. as either a fertilizer or a refrigerant.

– Meth producers tend to store the anhydrous ammonia in IMPROPER/UNAPPROVED containers such as:

•Propane tanks,

• Igloo coolers, or

•Fire extinguishers.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia leaves a tell-tell sign as it flows through these UNAPPROVED

CONTAINERS – a blue or blue green discoloration on the valve.

– PAY ATTENTION to details!!!

Anhydrous Ammonia (Continued)

• Because propane cylinders (and the other unapproved containers) are NOT designed to store anhydrous ammonia, they can EXPLODE as the ammonia eats

through the walls of the cylinders.

– The valves, which take on a bluish/green color, frequently deteriorate and can cause hazardous leaks!!!

Anhydrous Ammonia (Continued)

• Do NOT touch, move, or open any kind of tank or sealed container!!!

– Be aware that propane tanks are often WEAKENED and BRITTLE due to the

anhydrous ammonia and are SENSITIVE to ANY kind of movement or impact.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• These pictures show what happened to a fire extinguisher that was used to store

anhydrous ammonia…

Anhydrous Ammonia (Continued)

• Illegal drug makers often STEAL anhydrous ammonia from areas where it is stored

and used, such as farms.

• Attempted thefts have also occurred at places such as:

– Refrigeration systems holding ammonia,

– Underground pipelines carrying ammonia, and

– Rail cars transporting anhydrous ammonia.

• Often thefts are aborted when thieves are injured or overcome by the toxic gas...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia thieves had better beware!!!

• There is a new product called GloTell that farmers can add to their anhydrous

ammonia tanks…

• Meth cooks will run the risk that the GloTell additive will turn their hands bright

pink!

– This bright pink stain will fluoresce under ultraviolet light even if washed off!!!

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Also, GloTell will produce pink methamphetamine that CANNOT be bleached.

– Users who snort meth made with GloTell will find that they have PINK NOSES!

– Users who inject meth made with GloTell will see a pink stain at the point of

injection!

Sodium Carbonate (Soda Ash)

Sodium Carbonate (Soda Ash) (Continued)

Lead Acetate

Iodine

• Iodine is a natural element, and it is helpful to the body in SMALL amounts.

– However, if iodine is taken in large amounts it can become toxic.

•Extremely high does of iodine can limit the function of the thyroid.

Iodine (Continued)

Iodine (Continued)

• Iodine is bluish-black, and it has a characteristic odor, a sharp acrid taste, and it produces a violet corrosive vapor.

– The vapor is irritating to the respiratory system and eyes.

• The solid iodine irritates the eyes and may burn the skin, and it may cause severe

internal irritation and damage if ingested.

Iodine (Continued)

• Iodine is known as the “blue ingredient” in the production of meth (in the “red, white, and blue” method).

Iodine (Continued)

Iodine (Continued)

• It takes approximately 4 bottles of iodine tincture to produce 2 – 3 grams of meth.

Iodine (Continued)

Iodine (Continued)

• Iodine leaves distinctive yellow-blue or brown stains on surfaces in former methlabs.

Iodine (Continued)

Iodine (Continued)

Iodine (Continued)

• The only good thing about iodine is that it leaves yellow stains.

• If you see yellow stained coffee filters, gloves or paper towels, this could be an

indicator that you’re in a lab.

• If you see yellow stains, you can spray some starch on them.

– If they turn a purplish blue/black, it’s iodine.

• Iodine is the only substance that reacts with soluble starch to produce a purplish black color.

– The only way to get iodine vapor all over the walls is to cook meth.

Mercurous Chloride

Rock Salt

Hydrogen Chloride

• Hydrogen chloride gas is commercially available.

• Hydrogen chloride gas can also be made by mixing sulfuric acid and salt.

• Muriatic acid is simply hydrogen chloride gas suspended in water.

• Hydrogen chloride gas can be seen as a pale white smoke.

– It is a poisonous gas that can cause respiratory problems and death.

Hydrogen Chloride (Continued)

Ammonium Nitrate

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Hydriodic Acid

• Hydriodic acid is a corrosive acid that is colorless when freshly prepared.

– When hydriodic acid is exposed to light and air, it turns yellowish and brown.

• Hydriodic acid is a solution of hydrogen iodide gas in water.

• Hydriodic acid vapor is irritating to the respiratory system, skin, and eyes.

• Hydriodic acid liquid causes severe burns to the eyes and skin.

• If hydriodic acid is accidentally ingested, it can cause severe internal irritation and

damage.

Hydriodic Acid (Continued)

Catalyst Chemicals

• Catalyst Chemicals:

– Chemicals which SPEED UP a reaction process and/or cause it to go to GREATER COMPLETION.

Red Phosphorus

• Red phosphorus is found ON matchboxes, in road flares, and other explosives.

– Red Phosphorus IGNITES when OVERHEATED!!!

• By combining red phosphorus and iodine, you can easily create the highly

controlled substance known as hydriodic acid (which is an essential ingredient in making meth).

– Creating 2 – 3 grams of meth requires about 4 big boxes of matches.

Red Phosphorus (Continued)

• Red phosphorous is highly flammable and if it is overheated it can become white

phosphorous…

– White phosphorous is a volatile and highly explosive substance.

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Lithium

• Lithium is used in batteries.

• Lithium seriously burns the skin upon contact.

– It also reacts VIOLENTLY with WATER and is highly explosive.

Lithium (Continued)

• Lithium reacts VIOLENTLY with WATER, and if it is splashed in the eyes during

cooking it will cause blindness.

– Lithium is extremely caustic to all body tissues.

Lithium (Continued)

Lithium (Continued)

• Lithium metal is HIGHLY water reactive and it will BURN or EXPLODE if it comes into contact with WATER!

• Because of the moisture in your skin, it will burn exposed flesh.

• Lithium metal will DEGRADE when exposed to atmospheric moisture…

– This is why meth cooks store lithium metal in a solvent prior to use.

• It is typical to see harvested lithium strips in Coleman fuel or Mineral Spirits to prevent explosions.

•Large quantities can be harvested and saved in these containers until needed for a cook.

Lithium (Continued)

• If you see battery shells in the trashcan, on the floor, etc. – this is a VERY GOOD

indicator that you might be entering a meth lab!

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

• Lithium catches fire when in contact with water...

Solvent Chemicals

• Solvent Chemicals:

– A medium (liquid) in which a chemical operation takes place.

• Solvent chemicals (UNLIKE the precursor chemicals) CAN be

substituted/interchanged.

Ether

• Ether was once called “sweet vitriol” because of its hypnotic effect.

• Ether is a highly flammable substance that is used as an anesthetic agent –

especially in third world countries where more expensive anesthesia is not available.

– While inhaling the ether, patients could undergo complete surgical procedures while otherwise awake without feeling pain or concern.

Ether (Continued)

• Ether can be obtained from engine starting fluid.

• Ether is a solvent and it is flammable.

– It is particularly hazardous because it can cause BOTH fire and explosion.

• It has been said that a quart of ether can “level” a small house.

Ethyl Ether (Continued)

Ethyl Ether (Continued)

• Ether is VERY flammable and is HEAVIER than air.

– NEVER use ether near flames or non-sparkless motors.

– Ether is very PUNGENT – even a small evaporated amount of ether is VERY noticeable.

Acetone

• Acetone can be found in nail polish remover or paint thinner.

– It is extremely flammable.

• In the setting of a meth lab where meth is being cooked with high heat, acetone is

very dangerous.

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Toluene

• Toluene is used in brake fluid.

– When working with brake fluid (toluene), be careful not to spill it on your car

because it will eat away the paint and chrome…

• You also have to be careful using toluene around other household chemicals

because its high concentration of polyethylene glycol can cause it to ignite in a

violent fireball.

• Toluene is powerful enough to dissolve rubber.

Toluene (Continued)

• Toluene is used to form meth crystals.

– The fumes toluene releases can cause brain damage or death.

Toluene (Continued)

Toluene (Continued)

Ethanol

Isopropanol

Isopropanol (Continued)

Isopropyl Alcohol

Methanol

Methanol (Continued)

Methanol (Continued)

Benzene

Benzene (Continued)

Which of these is NOT a common ingredient in Meth?

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Methamphetamine- PowerPoint

- Chemicals and Ingredients Used to Make Meth

CJUS 240

Economic Costs of Meth

• The economic cost of methamphetamine use in the U.S. reached $23.4 billion in

2005.

– This includes the burden of addiction, premature death, drug treatment, child

care, and cleaning of lab sites.

– This figure does NOT take into account the future needs of the meth user.

Concerns with ACTIVE Meth Labs

• Danger of fire and explosion

• Chemical spills

• Inhalation of solvents, corrosives, and toxic gases

• “Booby traps”

• Waste disposal

Concerns with FORMER Meth Labs

• Vapors

• Chemical residues

• Methamphetamine residues

• Waste disposal

Equipment Used in Meth Production

• Pyrex or Corning dishes

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

Equipment Used in Meth Production

• Pyrex or Corning dishes

• Plastic or rubber tubing

• Rubber gloves

• Glass containers (all types)

• Funnels

• Propane tanks

• Foil

• Hot Plates

• Coffee Filters

Equipment Used in Meth Production

Equipment Used in Meth Production

Basic Chemical Requirements

• In a clandestine laboratory, basic types of chemicals are necessary in order to

produce the desired drug.

– The basic types of chemicals needed are:

1) Precursor Chemicals

2) Reagent Chemicals

3) Catalyst Chemicals

4) Solvent Chemicals

List I Chemical

• The term “List I chemical” means a chemical specified by regulation of the Attorney General as a chemical that is used in manufacturing a controlled substance and is

IMPORTANT to the manufacture of the controlled substance.

• Examples of List I chemicals are:

– GBL

– Red Phosphorus

– Pseudoephedrine

List II Chemical

• The term “List II chemical” means a chemical (other than a List I chemical) specified by regulation of the Attorney General as a chemical that is USED in

manufacturing a controlled substance.

• Examples of List II chemicals are:

– Toluene

– Iodine

– Hydrochloric Acid

Precursor Chemicals

• Precursor Chemicals:

– A chemical that is ESSENTIAL to the production of a controlled substance and for

which NO SUBSTITUTION can be made.

Pseudoephedrine

• Pseudoephedrine is a decongestant found in cold medicine.

– Large amounts of pseudoephedrine on its own can harm the respiratory and nervous systems, as well as the heart.

Pseudoephedrine (Continued)

• Some of the common ways used to divert products containing pseudoephedrine

include:

– “Smurfing” – making multiple purchases at different locations

– Shelf-Sweeping – the theft of all shelf stock

– Shoplifting

– Theft from wholesalers

Pseudoephedrine (Continued)

• Pseudoephedrine smurfing is a method used by some methamphetamine producers to acquire large quantities of pseudoephedrine by enlisting the assistance of several

friends or associates (often referred to as “smurfers”) to make purchases at or below the legal thresholds from multiple retail locations.

– Smurfers are often addicts who trade the pseudoephedrine for finished

methamphetamine.

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

Pseudoephedrine (Continued)

• About 680 pseudoephedrine tablets are needed to produce one ounce of meth…

Pseudoephedrine (Continued)

Out With a Bang

An Unstable Recipe…

• Meth contains a variety of poisonous ingredients…

– Some become EVEN MORE DANGEROUS once the cooking process begins…

Common Ingredients to Make Methamphetamine

Reagent Chemicals

• Reagent Chemicals:

– Chemicals which REACT upon the precursor chemical causing it to chemicallyCHANGE.

• A reagent chemical is a chemical which is required for the synthesis of an illicit drug substance, but which is NOT incorporated into the final chemical product.

Hydrochloric Acid

• Hydrochloric acid is a highly corrosive liquid that is used to make plastic (such as PVC pipe and polyurethane).

– It can remove rust and iron-oxide from steel and is highly corrosive to human

skin.

•Hydrochloric acid makes up the majority of the gastric acid in the human

digestive fluid.

• In high concentrations, hydrochloric acid will literally eat away human flesh…

Hydrochloric Acid (Continued)

• Hydrochloric acid can be purchased from hardware stores as:

– Tile and Grout Acid Cleaner

– Muriatic Acid

– Pool Acid

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

• Hydrochloric acid is a solution of hydrogen chloride gas suspended in water.

– Hydrochloric acid is corrosive and is a light yellow liquid color from traces of iron, chlorine, and organic matter.

• Inhaling hydrochloric acid may cause coughing or choking, inflammation, and

ulceration of the respiratory tract.

• Concentrated solutions of hydrochloric acid can cause severe burns and irritate the

mucous membranes, eyes, and respiratory tract.

– Exposure to hydrochloric acid vapors may result in pulmonary edema and

possibly death.

Hydrochloric Acid (Continued)

Hydrochloric Acid (Continued)

Sodium Hydroxide (NaOH)

• Sodium hydroxide is also called Lye.

• Sodium hydroxide is classified as a corrosive, and it is one of the main chemicals in

drain cleaner.

– It is also used in aluminum etching and to create biodiesal.

– It can burn the skin or cause blindness.

• Sodium hydroxide is used to dispose of road kill because it turns the dead bodies

into a coffee-like liquid.

Sodium Hydroxide (NaOH) (Continued)

• Drain cleaner (sodium hydroxide) is extremely corrosive, and without wearing

protection, even the smallest spill on the skin can eat through flesh…

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sodium Hydroxide (NaOH) (Continued)

Sulfuric Acid (H2SO4)

• Sulfuric acid is used in drain or toilet bowl cleaner as well as battery acid.

– It is another highly corrosive substance that burns the skin on contact.

Sulfuric Acid (H2SO4) (Continued)

• The product label warning for Drano® (sulfuric acid) says it all:

– DANGER: MAY BURN EYES AND SKIN ON CONTACT.

•HARMFUL IF SWALLOWED.

–Avoid contact with body and clothing.

•TOXIC GAS MAY FORM IF MIXED WITH OTHER CHEMICALS.

–If gases are released, leave immediately and ventilate area.

•FIRST AID: Give Immediately:

–EYES AND SKIN:

»Flush with water for 20 minutes.

»Remove affected clothing.

–IF SWALLOWED:

»Rinse mouth and drink a glass of water or milk.

»Do not induce vomiting.

–THEN SEEK MEDICAL AID.

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Sulfuric Acid (H2SO4) (Continued)

Hypophosphorous Acid (H3PO2)

• Hypophosphorous acid, which is used legally for a variety of commercial purposes,

is a chemical that increasingly is substituted for red phosphorus in the methamphetamine production process.

– The use of hypophospherous acid SIGNIFICANTLY increases the risk of fire!!!

• The federal government regulates the sale of hypophosphorous acid through registration, record keeping, reporting, and import/export requirements regardless

of the quantity being handled or distributed.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid is a colorless oily liquid that emits a SOUR odor.

– There is an extreme fire and explosion hazard if the hypophosphorous acid

comes into contact with a solvent such as acetone, toluene, or Coleman fuel.

• Hypophosphorous acid will also emit phosphine gas and the fumes can ignite.

Hypophosphorous Acid (H3PO2) (Continued)

• Although hypophosphorous acid is a List I chemical under the Controlled Substances Act, methamphetamine producers typically purchase the chemical via

the internet or from associates who also are engaged in methamphetamine

production.

– The use of hypophosphorous acid in methamphetamine production is an

EXTREMELY DANGEROUS PRACTICE because of the deadly gases that can be generated as well as the risk of fire or explosion.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid (H3PO2, also called phosphinic acid) is a strong acid that

typically is prepared as a solution of colorless, oily liquid in strengths of 50%, 30 to 32%, and 10%.

– It also is prepared in the form of salts (referred to as hypophosphite salts), particularly ammonium hypophosphite, calcium hypophosphite, iron (ferric)

hypophosphite, magnesium hypophosphite, manganese hypophosphite,

potassium hypophosphite, and sodium hypophosphite.

Hypophosphorous Acid (H3PO2) (Continued)

• Over 100 chemical firms located throughout the world produce hypophosphorous

acid.

– The People's Republic of China and India have the largest numbers of

hypophosphorous acid producers, although there are a few producers in the United States.

• There are a wide variety of uses for hypophosphorous acid and its salts in

commercial industry; however, the chemicals have no legitimate household or retail uses.

Hypophosphorous Acid (H3PO2) (Continued)

• The legitimate commercial and laboratory fields that use hypophosphorous acid and its salts include the following:

– Chemical plating

– Food preparation

– Water treatment

– Polymers (as a bleaching agent, color stabilizer, or catalyst)

– Education and research in analytical chemistry

Hypophosphorous Acid (H3PO2) (Continued)

• Chemical suppliers typically distribute hypophosphorous acid in large quantities, for example, in drums containing 275 pounds of the diluted solution.

– Hypophosphorous acid also is distributed in smaller quantities.

• One-half liter of 50% concentrate hypophosphorous acid solution can be obtained from chemical suppliers for as little as $14.

Hypophosphorous Acid (H3PO2) (Continued)

• Methamphetamine laboratory operators typically obtain small quantities of the chemical from other laboratory operators who purchase large quantities of the

chemical and repackage it for further distribution.

– According to law enforcement sources, these individuals sell hypophosphorous acid for as much as $1,000 per half-liter.

•Methamphetamine laboratory operators also purchase hypophosphorous acidvia the internet.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid and the Internet

• The internet is a source of a great deal of information regarding hypophosphorous acid.

• Popular internet sites that disseminate information about illicit drugs contain information about the chemical, including numerous recipes for home production of

methamphetamine using hypophosphorous acid.

• There also are recipes for synthesizing hypophosphorous acid from available chemicals.

• Hypophosphorous acid solutions and salts have been sold to the general public via the internet.

• The Drug Enforcement Administration (DEA) has strong concerns regarding the sale

of chemicals on the internet and has requested that any sites (such as auction sites) that allow the sale of regulated chemicals on their domains require proof of DEA registration from their clients.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous Acid Used in Methamphetamine Production

• Hypophosphorous acid is used in the ephedrine-pseudoephedrine reduction method

of methamphetamine production.

– It is used in the methamphetamine production process to produce hydriodic acid,

an important reagent (it reacts with the ephedrine-pseudoephedrine but does NOT become part of the finished product).

Hypophosphorous Acid (H3PO2) (Continued)

• The regulation of hydriodic acid by DEA in 1993 rendered it virtually unavailable in the United States.

– However, methamphetamine laboratory operators discovered methods to

produce hydriodic acid using a combination of iodine in water with red phosphorus.

• Laboratory operators found that red phosphorus could be obtained easily, either

from commercial supply companies or by scraping the striker pads from matchbooks or matchboxes.

• Methamphetamine producers soon discovered that hypophosphorous acid ALSO could be used in combination with iodine and water to produce hydriodic acid.

Hypophosphorous Acid (H3PO2) (Continued)

• The practice of using hypophosphorous acid in methamphetamine production is believed to have begun in the United States in the late 1990s when a methamphetamine producer in Colorado obtained the recipe from Australia, where

the hypophosphorous acid method is prevalent.

– This man was known as a serial cook who had a long history of

methamphetamine production.

•Over several years he trained other laboratory operators in Colorado to produce methamphetamine using hypophosphorous acid.

• As his techniques were passed on to others, the number of methamphetaminelaboratories in Colorado using hypophosphorous acid continued to increase, and the

technique was passed on to numerous methamphetamine producers in other

states.

Hypophosphorous Acid (H3PO2) (Continued)

• According to the El Paso Intelligence Center (EPIC) National Clandestine Laboratory

Seizure System, from 2000 through 2002 the number of seized methamphetaminelaboratories in the United States in which hypophosphorous acid was found

increased overall. (See Table 1.)

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid found at methamphetamine laboratories is packaged in a variety of ways.

• The chemical has been found in 1-gallon bottles of solution or in 1-pound jars of salts.

• Some hypophosphorous acid containers are labeled as "plating solution."

• Pint-sized brown glass bottles wrapped in red electrical tape also have been found to contain hypophosphorous acid; they have been discovered primarily in Colorado.

• The vast majority of hypophosphorous acid found at laboratory sites has been recovered from small toxic laboratories (STLs), those which yield gram to ounce

quantities per production cycle.

• Hypophosphorous acid has not been reported at large-scale laboratories operated by Mexican criminal groups in the United States.

Hypophosphorous Acid (H3PO2) (Continued)

• Hazards

• The iodine-hypophosphorous acid method is MORE HAZORDOUS than the iodine-

red phosphorus method, although the reaction using hypophosphorous acid is

faster and gives slightly higher yields.

– When hypophosphorous acid is used, the chemicals must be mixed together

SLOWLY in a PARTICULAR ORDER to prevent them from reacting violently.

Hypophosphorous Acid (H3PO2) (Continued)

• The combination of hypophosphorous acid with the other chemicals and with

certain metals can produce deadly phosphine gas during the initial mixing step and

can CONTINUE to produce phosphine gas for several days AFTER production has been completed…

Hypophosphorous Acid (H3PO2) (Continued)

• The iodine-hypophosphorous acid mixture has a tendency to decompose quickly when overheated or if heated for long periods of time, becoming cloudy or "milky-

white" just prior to giving off a cloud of phosphine gas that can ignite spontaneously.

– Hypophosphorous acid solutions may become unstable if evaporation results in

concentrations above 50%.

Hypophosphorous Acid (H3PO2) (Continued)

• [Note: Law enforcement or emergency personnel who encounter suspected

containers of hypophosphorous acid should use extreme care during handling because laboratory operators often attempt to obtain a more concentrated acid by

allowing water to evaporate from the mixture.]

• Because hypophosphorous acid often is used at small methamphetaminelaboratories operated by inexperienced or careless individuals, the potential hazards

of using this method are even greater.

• The risk of fire and explosion is higher in these laboratories, where professional

laboratory equipment typically is not used to contain the phosphine gas and where

safe handling precautions are not employed.

• In addition, these laboratories often are located in homes where children are

present and may come into contact with hypophosphorous acid.

• A child can easily mistake hypophosphorous acid for any other clear liquid,

particularly if it is stored in household containers or drinking glasses.

• Skin, eye, or inhalation exposure can be extremely harmful or fatal.

Hypophosphorous Acid (H3PO2) (Continued)

• Safety Precautions

• Always wear a self-contained breathing apparatus as well as protective clothing when entering areas where hypophosphorous acid may be present.

• When in contact with metals or in a high-temperature environment,

hypophosphorous acid can break down and liberate phosphine and flammable hydrogen gas.

• Do not allow the use of open flames, open lights, matches, or smoking in or around laboratories or dumpsites where hypophosphorous acid is handled.

• In case of fire, use a self-contained positive pressure breathing apparatus and full

protective equipment.

• Use water spray, fog, foam, dry chemicals, or other reagents as may be appropriate for materials in the surrounding fire.

• Water may be used to cool the containers of hypophosphorous acid; however, use extreme care to avoid allowing water to enter the container.

• In case of spills, neutralize the spilled chemical with alkaline material (soda ash, lime), then absorb it with an inert material such as vermiculite, dry sand, or earth

and place in a chemical waste container.

• Do not use combustible materials such as sawdust.

Hypophosphorous Acid (H3PO2) (Continued)

• Legislation and Control

• In the United States hypophosphorous acid is one of 38 chemicals (or groups of chemicals) controlled under law by DEA.

• On October 17, 2001, hypophosphorous acid and its salts, along with red and white phosphorus, were officially added as List I chemicals under section 1310 of the

Code of Federal Regulations.

• List I chemicals are defined as chemicals that are used in the manufacture of a

controlled substance in violation of the Controlled Substances Act (CSA) and are

important to the manufacture of a controlled substance.

• Under the law, suppliers are required to maintain records and report receipts, sales,

imports, and exports of these chemicals to DEA.

Hypophosphorous Acid (H3PO2) (Continued)

• Hypophosphorous acid, red phosphorus, and white phosphorus, as well as ephedrine, are unique in that suppliers are required to report all transactions of

these chemicals, regardless of the amount.

• By contrast, the other 34 listed chemicals are only reportable after a supplier's

transactions for a chemical reach an established weight or volume threshold in a calendar month.

• In addition to reporting all transactions involving the chemical, suppliers are

expected to "know their customers" in order to prevent the diversion of these substances to methamphetamine laboratories, as it is illegal to import, export,

purchase, or sell hypophosphorous acid or any other listed chemical in the United States if it is used or intended to be used in the production of a controlled

substance.

• Chemical suppliers are held liable for selling listed chemicals if they know or suspect that the chemical will be used for illicit purposes.

Hypophosphorous Acid (H3PO2) (Continued)

• Outlook

• The use of hypophosphorous acid in the production of methamphetamine is likely

to increase, particularly in the Midwest and Southwest regions of the United States

where methamphetamine production is prevalent.

– Injuries, property damage, and deaths also will increase as a growing number of

inexperienced methamphetamine producers experiment with hypophosphorous acid.

Anhydrous Ammonia

• Anhydrous ammonia is found in fertilizer, countertop cleaner, and commercial refrigerant.

– On its own, it has a pungent, suffocating odor.

• Mixing anhydrous ammonia with other chemicals can release highly toxic gases.

– Because anhydrous ammonia seeks out water (anhydrous means “without

water”) and causes severe burns, any body part that comes into contact with it

should be flushed with water for at least 15 minutes to remove the ammoniafrom the skin.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia has extremely destructive effects on humans.

– Anhydrous ammonia gives off vapors during cooking that can burn the mouth,

throat, and lung tissue.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Anhydrous ammonia seeks water from the nearest source, including the human body (anhydrous means “without water”).

– Because of their high moisture content, EYES, LUNGS, and SKIN are at the

greatest risk of attracting the ammonia.

• When large amounts of anhydrous ammonia are inhaled, the throat swells and the

victim suffocates.

– Exposure to the vapors or liquids can cause severe burns, blindness, or death.

• Anhydrous ammonia has an IDLH (immediately dangerous to life and health) at

only 300 parts per million...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is poses MANY hazards, especially when it is placed in improper vessels and handled/transported by individuals unfamiliar with the

dangers.

• Anhydrous ammonia has a boiling point of -28 degrees below zero.

– When a vessel containing anhydrous ammonia is MOVED, the anhydrous

ammonia will reach its boiling point and pressurize.

•This pressurization can cause vessels to violently RUPTURE, or if the vessel pressurizes and does NOT rupture, the opening of the container of anhydrous

ammonia at a later time can cause RAPID, VIOLENT depressurization.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia is mainly used in the U.S. as either a fertilizer or a refrigerant.

– Meth producers tend to store the anhydrous ammonia in IMPROPER/UNAPPROVED containers such as:

•Propane tanks,

• Igloo coolers, or

•Fire extinguishers.

Anhydrous Ammonia (Continued)

• Anhydrous ammonia leaves a tell-tell sign as it flows through these UNAPPROVED

CONTAINERS – a blue or blue green discoloration on the valve.

– PAY ATTENTION to details!!!

Anhydrous Ammonia (Continued)

• Because propane cylinders (and the other unapproved containers) are NOT designed to store anhydrous ammonia, they can EXPLODE as the ammonia eats

through the walls of the cylinders.

– The valves, which take on a bluish/green color, frequently deteriorate and can cause hazardous leaks!!!

Anhydrous Ammonia (Continued)

• Do NOT touch, move, or open any kind of tank or sealed container!!!

– Be aware that propane tanks are often WEAKENED and BRITTLE due to the anhydrous ammonia and are SENSITIVE to ANY kind of movement or impact.

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• These pictures show what happened to a fire extinguisher that was used to store

anhydrous ammonia…

Anhydrous Ammonia (Continued)

• Illegal drug makers often STEAL anhydrous ammonia from areas where it is stored

and used, such as farms.

• Attempted thefts have also occurred at places such as:

– Refrigeration systems holding ammonia,

– Underground pipelines carrying ammonia, and

– Rail cars transporting anhydrous ammonia.

• Often thefts are aborted when thieves are injured or overcome by the toxic gas...

Anhydrous Ammonia (Continued)

• Anhydrous ammonia thieves had better beware!!!

• There is a new product called GloTell that farmers can add to their anhydrous

ammonia tanks…

• Meth cooks will run the risk that the GloTell additive will turn their hands bright

pink!

– This bright pink stain will fluoresce under ultraviolet light even if washed off!!!

Anhydrous Ammonia (Continued)

Anhydrous Ammonia (Continued)

• Also, GloTell will produce pink methamphetamine that CANNOT be bleached.

– Users who snort meth made with GloTell will find that they have PINK NOSES!

– Users who inject meth made with GloTell will see a pink stain at the point of

injection!

Sodium Carbonate (Soda Ash)

Sodium Carbonate (Soda Ash) (Continued)

Lead Acetate

Iodine

• Iodine is a natural element, and it is helpful to the body in SMALL amounts.

– However, if iodine is taken in large amounts it can become toxic.

•Extremely high does of iodine can limit the function of the thyroid.

Iodine (Continued)

Iodine (Continued)

• Iodine is bluish-black, and it has a characteristic odor, a sharp acrid taste, and it produces a violet corrosive vapor.

– The vapor is irritating to the respiratory system and eyes.

• The solid iodine irritates the eyes and may burn the skin, and it may cause severe

internal irritation and damage if ingested.

Iodine (Continued)

• Iodine is known as the “blue ingredient” in the production of meth (in the “red, white, and blue” method).

Iodine (Continued)

Iodine (Continued)

• It takes approximately 4 bottles of iodine tincture to produce 2 – 3 grams of meth.

Iodine (Continued)

Iodine (Continued)

• Iodine leaves distinctive yellow-blue or brown stains on surfaces in former methlabs.

Iodine (Continued)

Iodine (Continued)

Iodine (Continued)

• The only good thing about iodine is that it leaves yellow stains.

• If you see yellow stained coffee filters, gloves or paper towels, this could be an

indicator that you’re in a lab.

• If you see yellow stains, you can spray some starch on them.

– If they turn a purplish blue/black, it’s iodine.

• Iodine is the only substance that reacts with soluble starch to produce a purplish black color.

– The only way to get iodine vapor all over the walls is to cook meth.

Mercurous Chloride

Rock Salt

Hydrogen Chloride

• Hydrogen chloride gas is commercially available.

• Hydrogen chloride gas can also be made by mixing sulfuric acid and salt.

• Muriatic acid is simply hydrogen chloride gas suspended in water.

• Hydrogen chloride gas can be seen as a pale white smoke.

– It is a poisonous gas that can cause respiratory problems and death.

Hydrogen Chloride (Continued)

Ammonium Nitrate

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Ammonium Nitrate (Continued)

Hydriodic Acid

• Hydriodic acid is a corrosive acid that is colorless when freshly prepared.

– When hydriodic acid is exposed to light and air, it turns yellowish and brown.

• Hydriodic acid is a solution of hydrogen iodide gas in water.

• Hydriodic acid vapor is irritating to the respiratory system, skin, and eyes.

• Hydriodic acid liquid causes severe burns to the eyes and skin.

• If hydriodic acid is accidentally ingested, it can cause severe internal irritation and damage.

Hydriodic Acid (Continued)

Catalyst Chemicals

• Catalyst Chemicals:

– Chemicals which SPEED UP a reaction process and/or cause it to go to GREATER COMPLETION.

Red Phosphorus

• Red phosphorus is found ON matchboxes, in road flares, and other explosives.

– Red Phosphorus IGNITES when OVERHEATED!!!

• By combining red phosphorus and iodine, you can easily create the highly

controlled substance known as hydriodic acid (which is an essential ingredient in making meth).

– Creating 2 – 3 grams of meth requires about 4 big boxes of matches.

Red Phosphorus (Continued)

• Red phosphorous is highly flammable and if it is overheated it can become white

phosphorous…

– White phosphorous is a volatile and highly explosive substance.

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Red Phosphorus (Continued)

Lithium

• Lithium is used in batteries.

• Lithium seriously burns the skin upon contact.

– It also reacts VIOLENTLY with WATER and is highly explosive.

Lithium (Continued)

• Lithium reacts VIOLENTLY with WATER, and if it is splashed in the eyes during

cooking it will cause blindness.

– Lithium is extremely caustic to all body tissues.

Lithium (Continued)

Lithium (Continued)

• Lithium metal is HIGHLY water reactive and it will BURN or EXPLODE if it comes into contact with WATER!

• Because of the moisture in your skin, it will burn exposed flesh.

• Lithium metal will DEGRADE when exposed to atmospheric moisture…

– This is why meth cooks store lithium metal in a solvent prior to use.

• It is typical to see harvested lithium strips in Coleman fuel or Mineral Spirits to prevent explosions.

•Large quantities can be harvested and saved in these containers until needed

for a cook.

Lithium (Continued)

• If you see battery shells in the trashcan, on the floor, etc. – this is a VERY GOOD

indicator that you might be entering a meth lab!

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

Lithium (Continued)

• Lithium catches fire when in contact with water...

Solvent Chemicals

• Solvent Chemicals:

– A medium (liquid) in which a chemical operation takes place.

• Solvent chemicals (UNLIKE the precursor chemicals) CAN be

substituted/interchanged.

Ether

• Ether was once called “sweet vitriol” because of its hypnotic effect.

• Ether is a highly flammable substance that is used as an anesthetic agent –

especially in third world countries where more expensive anesthesia is not available.

– While inhaling the ether, patients could undergo complete surgical procedures while otherwise awake without feeling pain or concern.

Ether (Continued)

• Ether can be obtained from engine starting fluid.

• Ether is a solvent and it is flammable.

– It is particularly hazardous because it can cause BOTH fire and explosion.

• It has been said that a quart of ether can “level” a small house.

Ethyl Ether (Continued)

Ethyl Ether (Continued)

• Ether is VERY flammable and is HEAVIER than air.

– NEVER use ether near flames or non-sparkless motors.

– Ether is very PUNGENT – even a small evaporated amount of ether is VERY noticeable.

Acetone

• Acetone can be found in nail polish remover or paint thinner.

– It is extremely flammable.

• In the setting of a meth lab where meth is being cooked with high heat, acetone is

very dangerous.

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Acetone (Continued)

Toluene

• Toluene is used in brake fluid.

– When working with brake fluid (toluene), be careful not to spill it on your car

because it will eat away the paint and chrome…

• You also have to be careful using toluene around other household chemicals

because its high concentration of polyethylene glycol can cause it to ignite in a

violent fireball.

• Toluene is powerful enough to dissolve rubber.

Toluene (Continued)

• Toluene is used to form meth crystals.

– The fumes toluene releases can cause brain damage or death.

Toluene (Continued)

Toluene (Continued)

Ethanol

Isopropanol

Isopropanol (Continued)

Isopropyl Alcohol

Methanol

Methanol (Continued)

Methanol (Continued)

Benzene

Benzene (Continued)

Which of these is NOT a common ingredient in Meth?

Nail Polish Remover

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