micro algae for biodisel, co2 capture and waste water treatment

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  • 8/6/2019 Micro Algae for Biodisel, Co2 Capture and Waste Water Treatment

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    2009 UNLV RENEWABLE ENERGFY SYMPOSIUM

    Microalgae forBiodiesel, CO2 Capture,and WastewaterTreatmentDr. Jian Ma

    Department of Mechanical EngineeringHarry Reid Center for Environmental Studies

    University of Nevada, Las Vegas

    12th August 2009

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    22009 UNLV RENEWABLE ENERGFY SYMPOSIUM

    Outline Introduction of Microalgae for

    BiofuelCarbon Dioxide CaptureWastewater treatment

    UNLV proposed projects coupled with local

    resourcesMicroalgae screening, harvesting and conversionAlgal biomass co-fire model for power plants in Las

    VegasMicroalgae production using Las Vegas Wash forwaste water treatment

    Summaries

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    32009 UNLV RENEWABLE ENERGFY SYMPOSIUM

    Examples of microalgae:

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    42009 UNLV RENEWABLE ENERGFY SYMPOSIUM

    Lipid Productivity of microalgae

    - Doug Frater, Algae Feedstock Productionfor Biodiesel, GlobalGreen Solutions

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    52009 UNLV RENEWABLE ENERGFY SYMPOSIUM

    Land Requirement to Replace 50%OF Current Consumed Petroleum

    Soybeans -

    1 x106 mile2

    Algae

    1 x104 mile2

    - National Algal Biofuels Technology Roadmap

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    6/2262009 UNLV RENEWABLE ENERGFY SYMPOSIUM

    Benefits of Microalgae Biofuels Grow faster

    CO2 Capture High Vegetable oil content

    Use saline, brackish, waste waters, seawater

    Do not compete with food/feed crops

    Low cost of production/processing Enormous production potential

    Co-products, nutrient recycles, wastewater

    treatment

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    Microalgaliomass Production

    MicroalgalBiomass

    Biofuel

    SolarEnergy

    CO2

    Water

    Nutrients

    Conversion

    Cultivation

    SpeciesScreening

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    8/2282009 UNLV RENEWABLE ENERGFY SYMPOSIUM

    Strong Solar Radiation in LasVegas

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    CO2

    Sources Air form Atmosphere

    Low CO2 concentration (0.033% by volume)

    Emission from Industrial Sources

    High CO2 concentrationcoal-fired power plant (13%-15% CO2

    concentration by volume),

    natural gas-fired power plant (8%-10%)

    Clark County has 16 power generation

    facilities

    CO2

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    21 Nevada Power GenerationFacilities

    16 facilities in Clark County

    CO2

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    112009 UNLV RENEWABLE ENERGFY SYMPOSIUM

    Water and Cheap Nutrient Sources Water

    Algae can thrive in saline, brackish, waste waters orseawater

    Nutrient

    Utilizing the nutrient content of municipal, agricultural,or industrial waste streams

    Las Vegas Resource

    Las Vegas Wash, which only has municipal wasteand is free of waste from industry and agriculture, willbe a perfect waste water source for system andeconomy analysis.

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    122009 UNLV RENEWABLE ENERGFY SYMPOSIUM

    Cultivation Open Pond and ClosePhotobioreactor

    Advantages Simple/Cheap to construct Easy to operate & MaintainDisadvantages

    Poor light utilization Difficulty controlling lightand temperature

    Contaminations &evaporation

    Open Ponds ClosePhotobioreactors

    Advantages

    High productivity Less contamination, water use & CO2losses

    Better light utilization & mixing Controlled culture conditions

    Disadvantages Cost/complexity Thermal management Oxygen accumulation

    Biofouling Cell damage by shear stress Deterioration of materials

    Cultivation

    MRI KC AlgaeLink PBR, 3500 Lwww.algaelink.com

    Raceway in Southeast New Mexicowww.cehmm.org

    http://www.algaelink.com/http://www.cehmm.org/http://www.cehmm.org/http://www.algaelink.com/
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    132009 UNLV RENEWABLE ENERGFY SYMPOSIUM

    Microalgae Species ScreeningTargeting algae that are fat and can grow in treated waste water

    Cyanobacteria Green algae Diatoms

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    142009 UNLV RENEWABLE ENERGFY SYMPOSIUM

    Conversion of Algal ExtractsEsterification

    Biodiesel

    Use in vehicles

    Fatty acids

    Microalgae

    Extra

    ctio

    n

    http://images.google.com/imgres?imgurl=http://i.treehugger.com/files/soybean-biodiesel.jpg&imgrefurl=http://www.treehugger.com/files/2006/03/worlds_largest_2.php&usg=__P53u6JFzZgbPR02VseJs-vym8KA=&h=243&w=468&sz=31&hl=en&start=63&um=1&tbnid=hrPjm4_i2uYxLM:&tbnh=66&tbnw=128&prev=/images%3Fq%3Dbiodiesel%26ndsp%3D18%26hl%3Den%26sa%3DN%26start%3D54%26um%3D1
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    152009 UNLV RENEWABLE ENERGFY SYMPOSIUM

    Past and Future Roadmap ofAlgal Biofuels Development

    1978-1996 Aquatic Species Program(ASP) on fuels from algae.

    1950s proposed the production ofmethane gas from algal cells.

    1940s discovered microalgae canproduce large amount of lipids.

    1998 A comprehensiveoverview of ASP.

    1996- Present private investment inbiofuels has beenincreasing over the lastfew years as well as

    federal funding in 2009

    Going

    Forward Systems,techno-economicand life cycleanalyses are

    critically needed

    2009

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    162009 UNLV RENEWABLE ENERGFY SYMPOSIUM

    Case study of Sunrise PlantOpen pond

    Open pond (12.3 sq mi)

    PBR20.41 sqmi

    PBR1 1.23 sq mi

    Photobioreactor (PBR) 1

    Photobioreactor (PBR) 2

    Productivity

    109.5ton/ha/yr

    365ton/ha/yr

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    172009 UNLV RENEWABLE ENERGFY SYMPOSIUM

    Cofire

    Model of Microalgal

    Biomass

    CO2 CO2

    CO2

    cool water

    O2

    waste

    water

    waste Heat

    nutrientcool water

    microalgae

    1

    2

    3

    45

    6

    7

    89

    10

    11

    12

    1. Coal burn power plant

    2. CO2 storage

    3. Cooling unit

    4. Nutrient feed and temperature control unit

    5. Photo-bioreactor system

    6. Light management unit (greenhouse)

    7. Inoculums system

    8. Flocculation-DAF, Centrifugation Unit

    9. Solar Dry System

    10. Degassing unit

    11. Water Recycling

    12. Feedstock to power plant

    Airw

    ith

    CO2

    From Ambient air

    CO2 Treatment

    WaterTreatment

    Algal CultureWater PostTreatment

    Algal Harvest

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    182009 UNLV RENEWABLE ENERGFY SYMPOSIUM

    Economy Analysis of Coal-firedand Gas-fired Power Plants

    Coal-fire Power Plant (500 MW) Natural Gas-fire Power Plant (149 MW)

    Burns coal of ~1,430,000 ton/yr

    Emits CO2 of ~3.7 million ton/yr

    Generates microalgal biomass of~2.02 x106 ton/yr

    Equals to coal of ~0.84 x106

    ton/yr

    Burns natural gas of ~181,000 ton/yr

    Emits CO2 of ~0.641 x106 ton/yr

    Generates microalgal biomass of~0.35 x106 ton/yr

    Equals to natural gas of ~117 x103

    ton/yr

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    192009 UNLV RENEWABLE ENERGFY SYMPOSIUM

    Economy Analysis ontinued

    58.7%replacedbybiomass

    Coal Natural Gas 64.5%replacedbybiomass

    Coal-fired (500MW) Natural Gas-fired (149 MW)

    CO2 Credit: $74 million/yr

    Saved Coal: $45 million/yrTotal Save $119 million/yr

    Average: $0.24million/MW/yr

    CO2 Credit: $13 million/yr

    Saved gas: $16 million/yrTotal Save $29 million/yr

    Average: $0.19million/MW/yr

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    202009 UNLV RENEWABLE ENERGFY SYMPOSIUM

    Researches @ UNLV Microalgae species screening (collaborate with

    DRI),

    Engineering design and techno-economicanalysis for algal biomass cultivation and

    harvesting,

    Solid acid catalyzed transesterification of

    triglycerides obtained from microalgae,

    Techno-economic analysis and design of otherapplication using algal biomass.

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    212009 UNLV RENEWABLE ENERGFY SYMPOSIUM

    Summary Microalgae

    Highest energy contentCO2 capture

    Waste water treatment Microalgae Production and Resources at

    Las Vegas

    Researches at UNLV

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    2009 UNLV RENEWABLE ENERGFY SYMPOSIUM

    Questions and Answer

    Thank You!