micro algae for biodisel, co2 capture and waste water treatment
TRANSCRIPT
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2009 UNLV RENEWABLE ENERGFY SYMPOSIUM
Microalgae forBiodiesel, CO2 Capture,and WastewaterTreatmentDr. Jian Ma
Department of Mechanical EngineeringHarry Reid Center for Environmental Studies
University of Nevada, Las Vegas
12th August 2009
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Outline Introduction of Microalgae for
BiofuelCarbon Dioxide CaptureWastewater treatment
UNLV proposed projects coupled with local
resourcesMicroalgae screening, harvesting and conversionAlgal biomass co-fire model for power plants in Las
VegasMicroalgae production using Las Vegas Wash forwaste water treatment
Summaries
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Examples of microalgae:
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Lipid Productivity of microalgae
- Doug Frater, Algae Feedstock Productionfor Biodiesel, GlobalGreen Solutions
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Land Requirement to Replace 50%OF Current Consumed Petroleum
Soybeans -
1 x106 mile2
Algae
1 x104 mile2
- National Algal Biofuels Technology Roadmap
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Benefits of Microalgae Biofuels Grow faster
CO2 Capture High Vegetable oil content
Use saline, brackish, waste waters, seawater
Do not compete with food/feed crops
Low cost of production/processing Enormous production potential
Co-products, nutrient recycles, wastewater
treatment
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Microalgaliomass Production
MicroalgalBiomass
Biofuel
SolarEnergy
CO2
Water
Nutrients
Conversion
Cultivation
SpeciesScreening
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Strong Solar Radiation in LasVegas
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CO2
Sources Air form Atmosphere
Low CO2 concentration (0.033% by volume)
Emission from Industrial Sources
High CO2 concentrationcoal-fired power plant (13%-15% CO2
concentration by volume),
natural gas-fired power plant (8%-10%)
Clark County has 16 power generation
facilities
CO2
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21 Nevada Power GenerationFacilities
16 facilities in Clark County
CO2
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Water and Cheap Nutrient Sources Water
Algae can thrive in saline, brackish, waste waters orseawater
Nutrient
Utilizing the nutrient content of municipal, agricultural,or industrial waste streams
Las Vegas Resource
Las Vegas Wash, which only has municipal wasteand is free of waste from industry and agriculture, willbe a perfect waste water source for system andeconomy analysis.
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Cultivation Open Pond and ClosePhotobioreactor
Advantages Simple/Cheap to construct Easy to operate & MaintainDisadvantages
Poor light utilization Difficulty controlling lightand temperature
Contaminations &evaporation
Open Ponds ClosePhotobioreactors
Advantages
High productivity Less contamination, water use & CO2losses
Better light utilization & mixing Controlled culture conditions
Disadvantages Cost/complexity Thermal management Oxygen accumulation
Biofouling Cell damage by shear stress Deterioration of materials
Cultivation
MRI KC AlgaeLink PBR, 3500 Lwww.algaelink.com
Raceway in Southeast New Mexicowww.cehmm.org
http://www.algaelink.com/http://www.cehmm.org/http://www.cehmm.org/http://www.algaelink.com/ -
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Microalgae Species ScreeningTargeting algae that are fat and can grow in treated waste water
Cyanobacteria Green algae Diatoms
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Conversion of Algal ExtractsEsterification
Biodiesel
Use in vehicles
Fatty acids
Microalgae
Extra
ctio
n
http://images.google.com/imgres?imgurl=http://i.treehugger.com/files/soybean-biodiesel.jpg&imgrefurl=http://www.treehugger.com/files/2006/03/worlds_largest_2.php&usg=__P53u6JFzZgbPR02VseJs-vym8KA=&h=243&w=468&sz=31&hl=en&start=63&um=1&tbnid=hrPjm4_i2uYxLM:&tbnh=66&tbnw=128&prev=/images%3Fq%3Dbiodiesel%26ndsp%3D18%26hl%3Den%26sa%3DN%26start%3D54%26um%3D1 -
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Past and Future Roadmap ofAlgal Biofuels Development
1978-1996 Aquatic Species Program(ASP) on fuels from algae.
1950s proposed the production ofmethane gas from algal cells.
1940s discovered microalgae canproduce large amount of lipids.
1998 A comprehensiveoverview of ASP.
1996- Present private investment inbiofuels has beenincreasing over the lastfew years as well as
federal funding in 2009
Going
Forward Systems,techno-economicand life cycleanalyses are
critically needed
2009
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Case study of Sunrise PlantOpen pond
Open pond (12.3 sq mi)
PBR20.41 sqmi
PBR1 1.23 sq mi
Photobioreactor (PBR) 1
Photobioreactor (PBR) 2
Productivity
109.5ton/ha/yr
365ton/ha/yr
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Cofire
Model of Microalgal
Biomass
CO2 CO2
CO2
cool water
O2
waste
water
waste Heat
nutrientcool water
microalgae
1
2
3
45
6
7
89
10
11
12
1. Coal burn power plant
2. CO2 storage
3. Cooling unit
4. Nutrient feed and temperature control unit
5. Photo-bioreactor system
6. Light management unit (greenhouse)
7. Inoculums system
8. Flocculation-DAF, Centrifugation Unit
9. Solar Dry System
10. Degassing unit
11. Water Recycling
12. Feedstock to power plant
Airw
ith
CO2
From Ambient air
CO2 Treatment
WaterTreatment
Algal CultureWater PostTreatment
Algal Harvest
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Economy Analysis of Coal-firedand Gas-fired Power Plants
Coal-fire Power Plant (500 MW) Natural Gas-fire Power Plant (149 MW)
Burns coal of ~1,430,000 ton/yr
Emits CO2 of ~3.7 million ton/yr
Generates microalgal biomass of~2.02 x106 ton/yr
Equals to coal of ~0.84 x106
ton/yr
Burns natural gas of ~181,000 ton/yr
Emits CO2 of ~0.641 x106 ton/yr
Generates microalgal biomass of~0.35 x106 ton/yr
Equals to natural gas of ~117 x103
ton/yr
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Economy Analysis ontinued
58.7%replacedbybiomass
Coal Natural Gas 64.5%replacedbybiomass
Coal-fired (500MW) Natural Gas-fired (149 MW)
CO2 Credit: $74 million/yr
Saved Coal: $45 million/yrTotal Save $119 million/yr
Average: $0.24million/MW/yr
CO2 Credit: $13 million/yr
Saved gas: $16 million/yrTotal Save $29 million/yr
Average: $0.19million/MW/yr
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Researches @ UNLV Microalgae species screening (collaborate with
DRI),
Engineering design and techno-economicanalysis for algal biomass cultivation and
harvesting,
Solid acid catalyzed transesterification of
triglycerides obtained from microalgae,
Techno-economic analysis and design of otherapplication using algal biomass.
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Summary Microalgae
Highest energy contentCO2 capture
Waste water treatment Microalgae Production and Resources at
Las Vegas
Researches at UNLV
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Questions and Answer
Thank You!