modern spent fuel dissolution in failed container ......(wp leader: lara duro, a21) development and...

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WP5: Chemical modelling (WP leader: Lara Duro, A21) Development and application of thermodynamic and kinetic models as well as reactive transport modeling. This will provide the basis for predicting and understanding the behavior of spent nuclear fuel in the near field. MODERN SPENT FUEL DISSOLUTION IN FAILED CONTAINER CONDITIONS (DISCO) L.Z. Evins 1 , I. Farnan 2 , D. Hambley 3 , E. Gonzalez Robles 4 , O. Roth 5 , D. Bosbach 6 , L. Duro 7 , E. Curti 8 , A. Valls 7 Background & Objectives The Consortium Project Organization & Work Plan The development of robust safety cases for the geological disposal of spent nuclear fuel (SNF) requires a solid understanding of its dissolution mechanisms over very long timescales (up to a million years). DISCO represents a logical follow-on from earlier Euratom projects (SFS, NF-PRO, MICADO, REDUPP and FIRST-Nuclides) This project aims to fill the knowledge gap on spent fuel dissolution arising from the development and use of novel types of fuel (Cr/Al- doped and MOX). Specific objectives : To enhance our understanding of spent fuel matrix dissolution under conditions representative of failed containers in reducing repository environments; To assess if the dissolution behaviour of novel fuel types (MOX, doped) differs from the conventional ones. Duration of the CP : 1 June 2017 to 31 June 2021 The project is implemented by a consortium of 16 Beneficiaries from 8 countries and the European Joint Research Center. The consortium will be advised by an End User Group: Waste Management Organizations from 7 countries: BE, FI, FR, ES, SE, CH, and UK Regulatory authorities in 5 countries: BE, DE, ES, SE, and CH 1 Svensk Kärnbränslehantering AB (SKB), SE; 2 The Chancellor, Masters and Scholars of the University of Cambridge, UK; 3 National Nuclear Laboratory Limited (NNL), UK; 4 Karlsruher Institut für Technologie (KIT-INE), DE; 5 Studsvik Nuclear AB, SE; 6 Forschungzentrum Jülich GmbH (FZJ), DE; 7 Amphos 21 Consulting S.L., ES; 8 Paul Scherrer Institute (PSI), CH This project has received funding from the Euratom research and training programme 2014-2018 under grant agreement No. 755443 Countries involved in the Project (**) Nº of beneficiaries WP2: Preparation and characterisation of samples and experimental systems (WP leader: Ian Farnan, UCAM) Preparation and characterisation of model spent fuel samples and spent fuel experimental systems before dissolution experiments are initiated. WP3: Spent fuel dissolution experiments (WP leader: Volker Metz, KIT-INE) Spent fuel dissolution experiments determining both the matrix dissolution and the instant release fraction (IRF) of various fuel types under different relevant disposal conditions. Leaching experiments will be conducted with cladded segments and fragments (without cladding) and will be performed under reducing (H 2 ), anoxic (N 2 , Ar) and oxic conditions. WP4: Model systems dissolution experiments (WP leader: Dirk Bosbach, JUELICH) Model material dissolution experiments, with the objective of understanding matrix corrosion of modern LWR fuels under deep geological repository relevant conditions. Examples of model materials: samples of natural or depleted UO 2 doped with 233 U that will allow defining alpha activity of aged fuel or samples doped with Pd to simulate ε-particles, or with Cr 2 O 3 to simulate modern fuels. Events The project kick-off meeting was held in Brussels 13 June 2017 The first annual meeting was held Sheffield, May 2018. The second annual meeting will take place in Cologne, May 2019 Project Dissemination Information related with the project can be found via: Webpage: www .disco-h2020.eu LinkedIn Group https://www.linkedin.com/groups/8613921 Hashtag: #discoH2020 Annual Newsletters Photo taken during the Kick-off meeting in Brussels The Associated Group, organizations that are not members of the consortium interested in the project results, are mainly from countries with less advanced programs (LAPs). Organizations from the following countries have already shown interest on DISCO: CZ, LT, HU, SI, PL, FR, UK European Commission Coordinator (SKB) WP1 WP3 WP4 WP5 WP2 AG ExCom EUG General Assembly Modelling Samples and experimental systems Experimental Management, dissemination and training WP1: Management, Coordination and Dissemination (WP leader and Project Coordinator: Lena Z. Evins, SKB) Ensuring that the project runs according to expectations and that the knowledge generated is disseminated and communicated to all interested stakeholders.

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Page 1: MODERN SPENT FUEL DISSOLUTION IN FAILED CONTAINER ......(WP leader: Lara Duro, A21) Development and application of thermodynamic and kinetic models as well as reactive transport modeling

WP5: Chemical modelling(WP leader: Lara Duro, A21)

Development and application of thermodynamicand kinetic models as well as reactive transportmodeling. This will provide the basis for predictingand understanding the behavior of spent nuclearfuel in the near field.

MODERN SPENT FUEL DISSOLUTION IN FAILED

CONTAINER CONDITIONS (DISCO)

L.Z. Evins1, I. Farnan2, D. Hambley3, E. Gonzalez Robles4, O. Roth5, D. Bosbach6, L. Duro7, E. Curti8, A. Valls7

Background & Objectives The Consortium

Project Organization & Work Plan

The development of robust safety cases for the geologicaldisposal of spent nuclear fuel (SNF) requires a solidunderstanding of its dissolution mechanisms over very longtimescales (up to a million years).

DISCO represents a logical follow-on from earlier Euratomprojects (SFS, NF-PRO, MICADO, REDUPP and FIRST-Nuclides)This project aims to fill the knowledge gap on spent fueldissolution arising from the development and use of novel typesof fuel (Cr/Al- doped and MOX).

Specific objectives :

• To enhance our understanding of spent fuel matrixdissolution under conditions representative of failedcontainers in reducing repository environments;

• To assess if the dissolution behaviour of novel fuel types(MOX, doped) differs from the conventional ones.

Duration of the CP : 1 June 2017 to 31 June 2021

The project is implemented by aconsortium of 16 Beneficiaries from 8countries and the European Joint ResearchCenter.

The consortium will be advised by an EndUser Group:

• Waste Management Organizationsfrom 7 countries: BE, FI, FR, ES, SE, CH,and UK

• Regulatory authorities in 5 countries:BE, DE, ES, SE, and CH

1 Svensk Kärnbränslehantering AB (SKB), SE; 2 The Chancellor, Masters and Scholars of the University of Cambridge, UK; 3 National Nuclear LaboratoryLimited (NNL), UK; 4 Karlsruher Institut für Technologie (KIT-INE), DE; 5 Studsvik Nuclear AB, SE; 6 Forschungzentrum Jülich GmbH (FZJ), DE;

7 Amphos 21 Consulting S.L., ES; 8 Paul Scherrer Institute (PSI), CH

This project has received funding from the Euratom research and training programme

2014-2018 under grant agreement No. 755443

Countries involved in the Project(**) Nº of beneficiaries

WP2: Preparation and characterisation of samples and experimental systems

(WP leader: Ian Farnan, UCAM)

Preparation and characterisation of modelspent fuel samples and spent fuel experimentalsystems before dissolution experiments areinitiated.

WP3: Spent fuel dissolution experiments(WP leader: Volker Metz, KIT-INE)

Spent fuel dissolution experiments determiningboth the matrix dissolution and the instantrelease fraction (IRF) of various fuel typesunder different relevant disposal conditions.Leaching experiments will be conducted withcladded segments and fragments (withoutcladding) and will be performed under reducing(H2), anoxic (N2, Ar) and oxic conditions.

WP4: Model systems dissolution experiments(WP leader: Dirk Bosbach, JUELICH)

Model material dissolution experiments, with theobjective of understanding matrix corrosion ofmodern LWR fuels under deep geological repositoryrelevant conditions. Examples of model materials:samples of natural or depleted UO2 doped with 233Uthat will allow defining alpha activity of aged fuel orsamples doped with Pd to simulate ε-particles, orwith Cr2O3 to simulate modern fuels.

Events

• The project kick-off meeting was held in Brussels 13 June 2017

• The first annual meeting was held Sheffield, May 2018.

• The second annual meeting will take place in Cologne, May 2019

Project Dissemination

Information related with the project can be found via:

• Webpage: www.disco-h2020.eu

• LinkedIn Group https://www.linkedin.com/groups/8613921

• Hashtag: #discoH2020

• Annual NewslettersPh

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The Associated Group, organizations that are not members of the consortium interested in theproject results, are mainly from countries with less advanced programs (LAPs).

Organizations from the following countries have already shown interest on DISCO: CZ, LT, HU, SI,PL, FR, UK

European Commission

Coordinator (SKB)

WP1

WP3 WP4 WP5

WP2

AG

ExC

om

EUG

General Assembly

Modelling

Samples and experimental systems

Experimental

Management, dissemination and training

WP1: Management, Coordination and Dissemination(WP leader and Project Coordinator: Lena Z. Evins, SKB)

Ensuring that the project runs according to expectations and that the knowledge generated is disseminated and communicated to all interested stakeholders.