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    Module 1

    Introduction to Engineering Materials

    Sanjib Jaypuria, SME, KIIT University

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    2Sanjib Jaypuria, SME, KIIT University

    1960s Engineering Materials Metals

    Design Choice of Material

    New Materials New Products

    Number of Materials 40 80,000!

    General Definition of Material

    According to Websters dictionary, materials are defined as

    substancesof which som eth ing is composed or made

    Introduction

    Stone Age: Naturally accessible materials, i.e. stone, wood, bone, fur

    Gold was the 1s tmetal used by the mankind fo l lowed by copp er

    Bronze Age: Copper and its alloy like bronze

    Iron Age: Iron (sponge iron & later pig iron)

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    Engineering Material: Part of inanimate matter, which is useful to

    engineer in the practice of his profession (used to produce

    products according to the needs and demand of society)

    Material Science: Primarily concerned with the search for basic

    knowledge about internal structure, properties and processing of

    materials and their complex interactions/relationships

    Material Engineering: Mainly concerned with the use of

    fundamental and applied knowledge of materials, so that they may

    be converted into products, as needed or desired by the society

    (bridges materials knowledge from basic sciences to engineering

    disciplines)

    Note:Mater ial scienc e is the basic kn ow ledge end o f mater ials kn ow ledge

    spectrum , wh ere as, mater ial engineer ing is appl ied know ledge end and

    there is no d emarcat ion l ine between the two sub jects of interest

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    Evolution of Engineering Materials

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    Why Material Science & Engineering is important to technologists?

    Examples:

    Mechanical engineers search for high temp material so that gas

    turbines, jet engines etc can operate more efficiently and wearresistance materials to manufacture bearing materials

    Electrical engineers search for materials by which electrical

    devices or machines can be operated at a faster rate with minimum

    power losses

    Aerospace & automobile engineers search for materials having

    high strength-to-weight ratio

    Electronic engineers search for material that are useful in the

    fabrication & miniaturization of electronic devices

    Chemical engineers search for highly corrosion-resistant materials

    Note: All these demands may be fulfilled when the internal structure

    and engineering properties are known to an engineer or technologist

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    Classification

    It is the systematic arrangement or division of materials into

    groups on the basis of some common characteristic

    1. Ac cord ing to General Propert ies

    2. Ac cord ing to Nature of Mater ials

    3. Ac cord ing to App l icat ions

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    1. According to General Properties

    (a). Metals (e.g.iron, aluminium, copper, zinc, lead, etc)

    Iron as the base metal, and range from plain carbon (> 98 % Fe) to

    ( i). Ferrous : high alloy steel (< 50 % alloying elements), e.g. cast

    iron, wrought iron, steel, alloys like high-speed steel, spring steel,

    etc

    ( i i). Non-Ferrou s: Rest of the all other metals and their alloys, e.g.

    copper, aluminium, zinc lead, alloys like brass, bronze, duralumin,

    etc

    (b). Non-Metals (e.g. leather, rubber, asbestos, plastics, etc)

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    2. According to Nature of Materials

    (a). Metals: e.g. Iron & Steel, Alloys & Superalloys, Intermetallic

    Compounds, etc

    (b). Ceramics: e.g. Structural Ceramics (high-temperature load

    bearing), Refractories (corrosion-resistant, insulating), Whitewares

    (porcelains), Glass, Electrical Ceramics (capacitors, insulators,

    transducers), Chemically Bonded Ceramics (cement & concrete)

    (c).Polymers: e.g. Plastics, Liquid Crystals, Adhesives

    (d). Electronic Materials: e.g. Silicon, Germanium, Photonic

    materials (solid-state lasers, LEDs)

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    (e). Composites: e.g. Particulate composites (small particles

    embedded in a different material), Laminate composites (golf club

    shafts, tennis rackets), Fiber reinforced composites (fiberglass)

    (f). Biomaterials: e.g. Man-made proteins (artificial bacterium),

    Biosensors, etc

    (g). Advanced / Smart Materials: e.g. materials in computers

    (VCRs, CD Players, etc), fibreoptic systems, spacecrafts,

    aircrafts, rockets, shape-memory alloys, piezoelectric ceramics,

    magnetostrictive materials, optical fibres,microelectromechanical (MEMs) devices, electrorheological /

    magnetorheological fluids, Nanomaterials, etc

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    3. According to Applications

    (a). Electr ical Materials :e.g. conductors, insulators, dielectrics,

    etc

    (b). Electronic Materials: e.g. conductors, semi-conductors, etc

    (c ). Magnetic Materials : e.g. ferromagnetic, paramagnetic &diamagnetic materials, etc

    (d). Opt ical Materials : e.g. glass, quartz, etc

    (e). Bio Materials: e.g. man-made proteins, artificial bacterium

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    Engineering Materials

    Ceramics

    Alumina

    Diamond

    Magnesia

    Silicon

    Carbide

    Zirconia

    Composites

    Carbon F iber

    Ceramic

    Matrix

    Glass F iber

    Metal M atrix

    Electronic

    Materials

    Silicon

    Germanium

    Photonic

    Materials

    Solid-State

    Lasers

    LEDs

    Bio-

    Materials

    Man-Made

    Proteins

    Artif icial

    Bacterium

    Biosensors

    Advanced /

    Smart

    Materials

    Shape-Memory Al loys

    Piezoelectric Cerami cs

    Magnetostri ctive Materi als

    Optical Fi bres

    Electrorheological Fl uids

    Nanomaterials

    Metals

    Ferrous

    Non-

    Ferrous

    Cast Ir on

    Carbon Steels

    Al loy Steels

    Stain less Steels

    Aluminium

    Brass

    Bronze

    Copper

    Lead

    Magnesium

    Nickel

    TinZinc

    Titanium

    Polymers

    Thermoplastic

    Thermosetting

    Elastomers

    ABS

    Acrylic

    Nylon

    Polyethylene

    Polystyrene

    Vinyl

    Epoxy

    Phenolic

    Polyester

    Butyl

    Fluorocarbon

    Neoprene

    Rubber

    Silicone

    Classification of Engineering Materials

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    Property Metals Non-MetalsStructure Crystalline AmorphicState Generally solids at room

    temp. Gaseous & solid at ordinary temp.Luster Metallic luster No metallic luster (except iodine &

    graphite)Conductivity Good conductors of heat &

    electricityBad conductors

    Malleability Malleable Not malleableDuctility Ductile Not ductileHardness Generally hard Hardness variesElectrolysis Form anions Form anioinsExcitation ofvalence electron

    by e.m.f.Easy Difficult

    Density High Low

    Difference between Metals & Non-Metals

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    Procedure for Selection of Materials (Engineering Applications)

    Analysis of material application problem

    Translation of material application requirements to material

    property values

    Selection of candidate materials

    Evaluation of candidate materials

    Decision making

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    Factors Affecting Material Selection

    1. Material Performance (depend upon material properties):

    Adequate properties for anticipated operating conditions /

    performance

    2. Cons traints : Design, Availability, Cost etc

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    1. Material Performance

    Physical : e.g. appearance, shape, weight, boiling point, melting

    point, freezing point, density, glass transition temperature,

    permeability

    Mechanical: e.g. strength (tensile, compressive, shear, torsion,

    bending), elasticity, plasticity, ductility, malleability, rigidity,

    toughness, hardness, brittleness, impact, fatigue, creep, strain

    hardening, Bauschinger effect, strain rate effect, vibration

    resistance, wear

    Thermal: e.g. thermal conductivity, expansion coefficient,

    resistivity, thermal shock resistance, thermal diffusivity

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    Types of Force / Stress System

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    Electr ical: e.g. conductivity, resistivity, dielectric strength,

    thermoelectricity, superconductivity, electric hysteresis

    Magnetic: e.g. ferromagnetism, paramagnetism, diamagnetism,

    magnetic permeability, coercive force, curie temperature,

    magnetic hysteresis

    Chemical: e.g. reactivity, corrosion resistance, polymerization,

    composition, acidity, alkalinity

    Optical : e.g. reflectivity, refractivity, absorptivity, transparency,

    opaqueness, color, luster

    Metallurgical: e.g. grain size, heat treatment done / required,

    anisotropy, hardenability

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    2. Constraints

    Design Requirements

    Existing Facilities

    Availability

    Compatibility

    Marketability

    Manufacturability (Fabricability / Castability / Formability /

    Machinability / Weldability)

    Cost (Material + Fabrication / Manufacturing)

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    Others Factors Affecting Material Performance

    Structure-property -Processing Relationships

    Hot Work, Cold Work,

    Solid Solution Strengthening

    Precipitation Hardening

    Inclusions

    Imperfections (Number of Dislocations)

    Crystal structures: Crystalline vs Amorphous

    Toughening

    Heat treatment (Annealing, Normalizing, Quenching)

    Residual Stresses

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    Investigating relationship between Structure & Properties

    Materials Engineering

    Designing the structure

    to achieve the specific

    properties of the

    materials

    Materials Science

    Investigating the

    relationship between

    structure and

    properties of thematerials

    Processing

    Structure

    Properties

    Performance

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    Competition among Materials

    Factors causing material replacement: Cost (breakthrough in

    processing cost) & development of new materials with specific

    properties for some specific applications

    Usage of material in US automobiles