m.sc. chemistry (two years) evening programmeeveningprogram).pdf · 16 chem-354 inorganic chemistry...

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M.Sc. Chemistry (Two Years) Evening Programme

Sr. # Course Code Course Title Page

No. Semester Credit Hours

Compulsory Courses

1 CHEM-301 Physical Chemistry 3 I 3

2 CHEM-301P Physics Chemistry (Practical) 4 I 1

3 CHEM-302 Organic Chemistry 5 I 3

4 CHEM-302P Organic Chemistry (Practical) 6 I 1

5 CHEM-303 Chemometrics 7 I 3

6 CHEM-303P Chemometrics (Practical) 8 I 1

7 CHEM-304 Bio Chemistry 9 I 3

8 CHEM-304P Bio Chemistry (Practical) 10 I 1

9 CHEM-305 Basic Mathematics for Chemistry 11 I 3

Compulsory Courses

10 CHEM-351 Analytical Chemistry 12 II 3

11 CHEM-351P Analytical Chemistry (Practical) 13 II 1

12 CHEM-352 Industrial Chemistry 14 II 3

13 CHEM-352P Industrial Chemistry (Practical) 15 II 1

14 CHEM-353 Chemical Biology 16 II 3

15 CHEM-353P Chemical Biology (Practical) 17 II 1

16 CHEM-354 Inorganic Chemistry 18 II 3

17 CHEM-354P Inorganic Chemistry (Practical) 19 II 1

18 CHEM-355 Computational Chemistry 20 II 3

Courses of Specialization in Physical / Inorganic / Organic / Analytical / Bio / Applied / Textile Chemistry (Students will study four courses, from area selected as specialization) 1. CHEM-401 Physical Chemistry Paper I 21 III 3

2. CHEM-402 Physical Chemistry Paper II 22 III 3

3. CHEM-403 Physical Chemistry Paper III 23 III 3

4. CHEM-404P Physical Chemistry (Practical) 25 III 2

5. CHEM-405 Organic Chemistry Paper I 26 III 3

6. CHEM-406 Organic Chemistry Paper II 27 III 3

7. CHEM-407 Organic Chemistry Paper III 29 III 3

8. CHEM-408P Organic Chemistry (Practical) 30 III 2

9 CHEM-409 Inorganic Chemistry Paper I 31 III 3

10 CHEM-410 Inorganic Chemistry Paper II 32 III 3

11 CHEM-411 Inorganic Chemistry Paper III 33 III 3

12 CHEM-412P Inorganic Chemistry (Practical) 34 III 2

13 CHEM-413 Bio Chemistry Paper I 35 III 3

14 CHEM-414 Bio Chemistry Paper II 36 III 3

15 CHEM-415 Bio Chemistry Paper III 37 III 3

16 CHEM-416P Bio Chemistry (Practical) 38 III 2

17 CHEM-417 Textile Chemistry Paper I 39 III 3

18 CHEM-418 Textile Chemistry Paper II 40 III 3

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19 CHEM-419 Textile Chemistry Paper III 41 III 3

20 CHEM-420P Textile Chemistry (Practical) 42 III 2

21 CHEM-421 Applied Chemistry Paper I 43 III 3

22 CHEM-422 Applied Chemistry Paper II 44 III 3

23 CHEM-423 Applied Chemistry Paper III 45 III 3

24 CHEM-424P Applied Chemistry (Practical) 46 III 2

25 CHEM-425 Analytical Chemistry Paper I 47 III 3

26 CHEM-426 Analytical Chemistry Paper II 48 III 3

27 CHEM-427 Analytical Chemistry Paper III 49 III 3

28 CHEM-428P Analytical Chemistry (Practical) 50 III 2

29 CHEM-499 Project / Internship / Dissertation III 3

Courses of Specialization in Physical / Inorganic / Organic / Analytical / Bio / Applied / Textile Chemistry (Students will study four courses, from area selected as specialization) 1. CHEM-451 Physical Chemistry Paper IV 51 IV 3

2. CHEM-452 Physical Chemistry Paper V 52 IV 3

3. CHEM-453 Physical Chemistry Paper VI 53 IV 3

4. CHEM-454P Physical Chemistry (Practical) 54 IV 2

5. CHEM-455 Organic Chemistry Paper IV 55 IV 3

6. CHEM-456 Organic Chemistry Paper V 56 IV 3

7. CHEM-457 Organic Chemistry Paper VI 57 IV 3

8. CHEM-458P Organic Chemistry (Practical) 58 IV 2

9 CHEM-459 Inorganic Chemistry Paper IV 59 IV 3

10 CHEM-460 Inorganic Chemistry Paper V 60 IV 3

11 CHEM-461 Inorganic Chemistry Paper VI 61 IV 3

12 CHEM-462P Inorganic Chemistry (Practical) 62 IV 2

13 CHEM-463 Bio Chemistry Paper IV 63 IV 3

14 CHEM-464 Bio Chemistry Paper V 64 IV 3

15 CHEM-465 Bio Chemistry Paper VI 65 IV 3

16 CHEM-466P Bio Chemistry (Practical) 66 IV 2

17 CHEM-467 Textile Chemistry Paper IV 67 IV 3

18 CHEM-468 Textile Chemistry Paper V 68 IV 3

19 CHEM-469 Textile Chemistry Paper VI 69 IV 3

20 CHEM-470P Textile Chemistry (Practical) 70 IV 2

21 CHEM-471 Applied Chemistry Paper IV 71 IV 3

22 CHEM-472 Applied Chemistry Paper V 72 IV 3

23 CHEM-473 Applied Chemistry Paper VI 73 IV 3

24 CHEM-474P Applied Chemistry (Practical) 74 IV 2

25 CHEM-475 Analytical Chemistry Paper IV 75 IV 3

26 CHEM-476 Analytical Chemistry Paper V 76 IV 3

27 CHEM-477 Analytical Chemistry Paper VI 77 IV 3

28 CHEM-478P Analytical Chemistry (Practical) 78 IV 2

29 CHEM-499 Project / Internship / Dissertation IV 3

Total Credit Hours 66

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DETAIL OF NEW COURSE FOR APPROVAL BY ACADEMIC COUNCIL

Name of Academic Program: M.Sc. Chemistry

Department: CHEMISTRY

Course Title: Physical Chemistry No. of Credit Hours ____03_________

Course Code _CHEM-301___ Semester I Implementation Date September 2015__

BoS Approval Date __30-06-2014__ BoF Approval Date __03-12-2014_____

Detail of New Course Contents 1. Gaseous State Kinetic molecular theory of gases. Derivation of mean free path from an imaginary zig-zag cylinder with numerical. Basic idea of distribution of velocities among gas molecules. Derivation of Maxwell’s law of distribution of velocities Maxwell’s curves. Derivation of average and most probable velocities from Maxwell’s law. Maxwell-Boltzmann law of distribution of energies (with numerical). Barometric formula (with numerical). Methods for the determination of Avogadro’s number. 2. Chemical Thermodynamics Various statements of second law of Thermodynamics. Concept of entropy and its physical significance. Entropy changes in reversible and irreversible processes. Clause’s inequalities. Entropy change for an ideal gas under different conditions, entropy change during phase change, entropy of mixing. Third law of thermodynamics, its importance, testing the validity of third law, calculations of entropy for a substance from third law. Residual entropy and its calculations. Gibb’s free energy, Helmoltz free energy and spontaneity of a reaction. Variation of Gibb’s free energy with temperature and pressure, and for processes under isothermal conditions. Gibb’s Helmoltz equation and its applications. Nernst heat theorem. Idea of chemical potential from partial molar quantities. Chemical potential and fugacity. Maxwell’s relations. 3. Chemical Kinetics Examples and kinetic equation of rate constant for a 3rd order reaction with same, and different initial concentrations of reactants. Half life formula and units of rate constant for first, second and third reactions. Examples of zero, first, second and third order reactions from inorganic and organic chemistry (with numerical problems). Effect of temperature on reaction rates, Arrhenius equation, Arrhenius plots and its parameters for many reactions and their justification. Numerical problems involving plotting of Arrhenius plots and determining the values of Arrhenius factor A and energy of activation of reactions. Kinetics of complex reactions as opposing reactions like first order by first order, first by second, second by first and second by second. Parallel reactions, consecutive molecular reactions and chain reactions. Concept of steady state approximation, Lindmann’s theory of unimolecular reactions. Bimolecular collision theory, transition state theory and their comparison. Kinetics of thermal and photochemical reactions. 4. Quantum Mechanics: Postulates of quantum theory. Eigen functions and operators, Schrödinger’s wave equation. Particle in one dimensional box, Normalized wave function and orthogonality, Quantum mechanical tunneling. Motion of particle in three dimensional box and idea of degeneracy. Separation of variables and derivation of quantum numbers. RECOMMENDED BOOKS A` 1. Physical Chemistry, Samuel Glasstone, 1995. Macmillan and Co. Ltd. St. marlins Street, London. 2. Principles of Physical chemistry, Maron and Prutton, 1965 the Macmillan Company, Collier Macmillan Ltd. London. 3. Physical Chemistry, Barrow, 1973, McGraw Hill, Tokyo. 4. Physical Chemistry, Moore, 1972, Rentice Hall, Englewood cliffs, Jersey. 5. Physical Chemistry, Alberty and Daniels, 1962, McGraw Hill Book Company Ltd London. 6. Physical Chemistry, Castallan, 1972, Addson Westey Publishing Company, Menla Park, California, London. 7. Physical Chemistry by Kundu, N and Jain, S.K.,S. Chand and Company Ltd. 1984. 8. Fundamentals of Chemical kinetics by Logan, S.R., Longman Group Ltd. 1996. 9. Elementry reaction kinetics by Latham. J.L. and burgess, A.E., 3rd Ed., Butterworths, London, 1997. 10. Physical Chemistry by Atkins, P.W., 5th Ed., W.H. Freeman and Company, New York, 1994. 11. Physical Chemistry by Alberty, R.A. and Silbey, R.J., John Wiley, New York, 1995. 12. Physical Chemistry by Engel, T. and Ried, P., 1st Ed,. Pearson education, Inc. 2006.

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Course Title: Physical Chemistry (Practical) No. of Credit Hours ___01___

Course Code CHEM-301P Semester I Implementation Date September 2015 _

BoS Approval Date __30-06-2014__ BoF Approval Date __03-12-2014

Detail of New Course Contents 1. Preparation of standard Molar and Normal solutions and percentage compositions of different compounds. 2. Determination of the heat of solution by solubility method. 3. Determination of partition coefficient of a substance between two immiscible liquids. 4. To investigate the kinetics of hydrolysis of ethyl acetate in the presence of an acid. 5. To investigate the kinetics of hydrolysis of sucrose. RECOMMENDED BOOKS

1. McQuarrie, D.A. and Simon, J.d. Physical Chemistry – A Molecular Approach, 1st ed. University Science Books, (1997).

2. Atkins, P. and Paula, J.D., Atkin’s 9th ed. Oxford, University Press, (2010). 3. Shoemaker, D., Experimentsin Physical Chemistry, 8th ed., McGraw-Hill

Publishing Company Limited, (2003). 4. Silbey, R., Alberty, R and Bawendi, M., Physical Chemistry, 4th Ed. (2005). 5. Atkins, P., Jones, L., Chemical Principles, 5th Ed., W.H. Freeman and

Company, New York, (2010). 6. James, A.M., Prichard, F.E., Practical Physical Chemistry, 3rd ed., Longman

Group Limited, New York, (1974). 7. Chaudhary, S.U., Ilmi, Textbook of Physical Chemistry, 2nd ed., Ilmi, Kitab

Khana, Lahore, (2003).

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Course Title: Organic Chemistry No. of Credit Hours _____03_______

Course Code: ___CHEM-302__ Semester _I__ Implementation Date September 2015

BoS Approval Date __30-06-2014__ BoF Approval Date __03-12-2014____

SYLLABUS OUTLINE: 1. Structure And Reactivity: Ka, Kb, pKa and pKb values of acids and bases. Electronic effects (inductive and resonance), field effect, solvent effect. Hyper-conjugation. Hydrogen bonding. Steric and stereo-chemical effects, and hybridization on strengths of acids and bases. Aromaticity and aromatic compounds. Hammett equation and Taft equation. Thermodynamics of organic reactions, energy and entropy changes. Energy diagrams for single step and two step reactions. 2. Stereochemistry (a) Conformation analysis The concept of conformational analysis in ethane, propane, n-butane, pentane, cyclopentane, cyclohexane, substituted alkanes, substituted cycloalkanes and decalins. Their potential energy diagrams and comparison. Relative stability of di and tri substituted cyclohexanes for polar and non-polar substituents. Conformations of heterocyclic six membered rings with substituents. (b) Optical isomerism: Chirality and symmetry. Optical isomerism upto three chiral carbon atoms, enantiomers and diastereomers. Stereogenic centers in open chain and cyclic compounds. R and S nomenclature, labeling of stereogenic centres with R or S. Racemates, racemization and resolution of racemates. Epimerization. Walden inversion. Stereoisomerism in biphenyls, allenes and spiro-compounds. Optical activity of naturally occurring compounds in living bodies. Chiral drugs. (c) Geometrical isomerism Cis and trans, and E and Z configurations, Determination of configuration inter-conversion. Geometrical isomerism in cyclic compounds, Decalins and annulenes 3. Active Methylene Compounds: Alkylation, arylation, and acylation of active methylene compounds, Acid and base catalysed aldol condensation. Conditions, mechanisms and synthetic applications of the following reactions; Claisen, Claisen Schmidt, Knoevenagel, Perkin, Reformatsky, and Stobbes condensations. Darzen’s glycosidic ester synthesis. Mannich and Wittig reactions. RECOMMENDED BOOKS: 1. Organic Chemistry, Volume I (6th ed.) & II (5th ed.) by I.L. Finar, Pearson Education (singapore) Pte Ltd, 2008. 2. March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure, 6th ed. by Michael B. Smith, Jerry March, Wiley, 2007. 3. Organic Chemistry, eth Ed.; by S. H. Pine, McGraw Hill: New York,1987. 4. Organic Chemistry 6th ed. by Francis A. Carey, McGraw Hill, 2005. 5. Organic Chemistry 6th d, by R. T. Morrison, R. N. Boyd, and R. K. Boyd, Benjamin Cummings, 1992. 6. Modern Synthetic Reactions 2nd ed. by H.O.House , W.A. Benjamin Inc., Menlo Park, CA 7. Principles in Organic Synthesis by R.O.C Norman & J. M. Coxon,1993, Chapman and Hall, 1993. 8. Organic Chemistry by Jonathan Clayden, Nick Geeves, Stuart Warren, Oxford University Press 2000. 9. “A Guide book to Mechanism in Organic Chemistry” Longman Group Ltd., 1986.

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Course Title: Organic Chemistry (Practical) No. of Credit Hours ___1__________

Course Code: ___CHEM-302P _ Semester _I_ Implementation Date September 2015

BoS Approval Date __30-06-2014__ BoF Approval Date _03-12-2014

Detail of New Course Contents 1. Organic Preparations: a. Benzyl alcohol; Ethyl benzene; benzilic acid, p-Nitrophenol, acetophenoneoxime, acetophenonearyl Hydrazone. b. Synthesis of compounds containing nitro, halogeno, amino, carboxylic and carbonyl functionalities (depends upon the availability of chemicals).

RECOMMENDED BOOKS 1. Practical Organic Chemistry by F. G. Mann and B. C. Saunders, Longman, UK, 1978 2. Vogel's Textbook of Practical Organic Chemistry (5th ed.) by A.I. Vogel, A.R. Tatchell, B.S. Furnis, A.J. Hannaford, P.W.G. Smith, 1989, Longman UK, 1989. 3. The Systematic Identification of Organic Compounds, (8th ed.) by Ralph L. Shriner et al., Wiley, 2003. 4. Advanced Practical Organic Chemistry, by J. Leonard, B. Lygo, G. Procter, CRC, 1994. 5. Advanced Practical Organic Chemistry (2nd ed.) by N. K. Vishnoi, Vikas Publishing House Pvt Ltd, India, 1996.

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Course Title: Chemometrics No. of Credit Hours ______03____

Course Code: ____CHEM-303___ Semester I_ Implementation Date September 2015___


Detail of New Course Contents 1. Introduction to Chemometrics Overview of chemometrics, fundamental units of measurement. 2. Propagation of Uncertainty Uncertainty when adding subtracting multiplying and dividing, uncertainty for mixed operations. 3. Distribution of Measurement and Results Population and samples, probability distributions for populations and samples and confidence intervals for population and samples. 4. Statistical Analysis of Data Constructing a significance test, one tailed and two tailed significance tests and errors in significant testing. 5. Calibration and Standardization Calibrating signals. Reagents used as standards, single point versus multiple point standardizations, external standards, standard additions and internal standards. 6. Linear Regression, Calibration Curves and Blank Corrections Linear regression of straight line calibration curves, un-weighted and weighted linear regression with errors in Y, weighted linear regression with errors in both X and Y and blank corrections. RECOMMENDED BOOKS 1. Modern Analytical Chemistry by David Harvey ISBN-13: 978-0072375473 ISBN-

10: 0072375477 Edition: 1st 1999. 2. Analytical Chemistry, fifth edition by Gary D. Christian. 3. Analytical Chemistry third edition by R.M. Verma. 4. Applied Chemometrics for Scientists by Richard G. Brereton

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Course Title: Chemometrics (Practical) No. of Credit Hours ______01____ ______

Course Code: ____CHEM-303P__ Semester I_ Implementation Date September 2015____

BoS Approval Date __30-06-2014__ BoF Approval Date ___03-12-2014

Detail of New Course Contents 1. Use of double pan balance, long swing and short swing methods by use of riders 2. Calibration of weights. 3. Conductometric determination of solubility product of AgCl / PbSO

4.

4. Effect of common ions on solubility of sparingly soluble salts (AgCl / PbSO4).

5. Verification of Beer Lambert law by using KMnO4 solution.

6. Determination of λmax of KMnO4 and K

2Cr

2O

7 solutions.

7. Construction of voltaic cell and electrochemical cells. 8. Electrogravimetric determination of copper in given samples. RECOMMENDED BOOKS 1. Modern Analytical Chemistry by David Harvey 2. Analytical Chemistry, fifth edition by Gary D. Christian. 3. Analytical Chemistry third edition by R.M. Verma. 4. Applied Chemometrics for Scientists by Richard G. Brereton.

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Course Title: Bio Chemistry No. of Credit Hours ___3__________

Course Code: ____CHEM-304 _ Semester _I_ Implementation Date September 2015


Detail of New Course Contents 1. BASIC CONCEPTS The concept and role of pH in biological systems, dissociation of organic acids and amino acids Titration curves and determination of pKa, Buffers and buffering mechanism, Henderson Hasselbalch Equation. 2. ENZYMOLOGY Classification and nomenclature, Effects of pH, temperature and concentration of substrate on enzyme catalyzed reactions, Enzyme Inhibition, Kinetics of enzyme catalyzed reaction, Immobilization of enzymes and their industrial applications. 3. CHEMISTRY OF BIOMOLECULES Carbohydrates: Classification, structure, properties and biological importance of carbohydrates. Proteins: Classification, structure and properties of amino acids, biologically active peptides, classification and properties of proteins. Lipids: Structure, distribution and biological importance of fats and fatty acids. Chemical properties and characterization of fats. Waxes, cerebrosides, gangliosides, phospholipids and proteolipids. Steroids and bile salts. Nucleic acids: Structure of purines, pyrimidines, nucleosides and nucleotides. Structure, types and biological role of RNA and DNA. RECOMMENDED BOOKS 1. Voet, D. and Voet,J.D., Biochemistry, 4th ed., illustrated. Publisher: John-Wiley & Sons Canada, Limited, (2011). ISBN: 0470917458, 9780470917459. 2. Nelson, D. L. and Cox, M. M., Lehninger’s Principles of Biochemistry, 6th ed., Freeman, (2012). 3. Murray, R., Bender, D., Botham,K.M., Kennely,P.J., Rodwall,V. and Weil, P.A., Harper’s Biochemistry, 29thed., (2012). 4. Zubay, G. L., Biochemistry, 4thed., illustrated. Publisher: WMC. Brown Publishers, (1998), digitized, (2008). ISBN: 0697219003. 9780697219008. 5. Guyton, A. C. & Hall, J. E., Guyton & Hall Text Book of Medical Physiology, 12thed., Publishers: Saunders Elsevier, (2011). 6. Plummer, D.T., An Introduction to Practical Biochemistry, 3rd ed., TATA MCGraw-Hill Publishing Company LTD, (2010). 7. Sawhney, S. K. and Sing, R., Introductory Practical Biochemistry, 2nd ed., Narosa Publishing House, New Delhi, (2005). 8. Robert A. Copeland, Enzymes: A Practical Introduction to Structure, Mechanism, and Data analysis, 2nd ed., Publishers: John-Wiley & Sons,(2000). ISBN: 0-471-35929-7 9. Lehninger, A. L. Principles of Biochemistry, Worth Publisher, New York (2001). 10. Murray, R. K., P. A. Mayes, D. K. Granner and V. W. Rodwell, Harper’s

Biochemistry, Appleton and Lange (2000).

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Course Title: Bio Chemistry (Practical) No. of Credit Hours 1_

Course Code: ____CHEM-304P _ Semester _I_ Implementation Date September 2015

BoS Approval Date __30-06-2014__ BoF Approval Date _03-12-2014____

Detail of New Course Contents 1. Extraction and estimation of amylase from germinating seeds 2. Estimation of Na ions in blood/urine 3. Estimation of K in blood/urine 4. Estimation of glucose in blood/urine sample using quantitative Benedict’s

reagent 5. Estimation of protein in egg by Lowry’s method 6. Qualitative tests for amino acids 7. Qualitative tests for carbohydrates (pentoses, hexsoses, reducing and non

reducing sugar). 8. Qualitative tests for fats, sterols and phospholipids. 9. Determination of acid value of fat

RECOMMENDED BOOKS 1. Lehninger, A. L. Principles of Biochemistry, Worth Publisher, New York (2001). 2. Murray, R. K., P. A. Mayes, D. K. Granner and V. W. Rodwell, Harper’s

Biochemistry, Appleton and Lange (2000). 3. Watson, J. D., J. Tooze and D. T. Kurtz, Recombinant DNA, Scientific American

Books 4. Darnell Jr., J., H. Lodish and D. Baltimore, Molecular Cell Biology, Scientific

American Books.

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Course Title: Basic Mathematics for Chemistry No. of Credit Hours ___3

Course Code: __CHEM-305 _ Semester _I_ Implementation Date September 2015

BoS Approval Date __30-06-2014__ BoF Approval Date __03-12-2014____

Detail of New Course Contents

BASIC MATHEMATICS

Fundamental Concepts Of

(1) Algebra: Simplifying an algebraic expression, product and quotient rules, square roots and cube roots of unity. Multiplying polynomials in two variables, factorizing involving fractional and negative exponents. Idea of complex numbers. Quadratic equation, Linear functions and slopes. Graphs of exponential function and logarithmic functions. Rules of log system and inter-conversion of natural and common log partial fractions. Arithmetic sequences, geometric sequence and geometric series. (2) Trigonometry: Basic concepts of trigonometry as co-ordinate plane, types of angles, radian measures trigonometric functions, trigonometric functions of acute and non-acute angles, Linear and angular velocities. Graphs of trigonometric functions and their amplitudes. Limits and rules for finding limits. Physical significance of e.Trigonometric identities and their verifications. Half angle identities. Idea of inverse trigonometric functions. (3) Calculus: Derivatives of a function, rules of differentiation; Rate of change. Derivatives of trigonometric function logarithmic differentiation. Differentiation formulas that include chain rule. Derivatives of higher order. Concept of maxima and minima. Partial differentiation and applications in quantum mechanisms electrochemistry and thermodynamics. Integration by substitution logarithmic differentiation. Derivative and

integral of ex. Basic integration formulas, polar coordinates. RECOMMENDED BOOKS 1. Trignometry, Seventh Edition by Lial, Hornsby, Schncider New York. 2. College Algebra 4th Edition, Blitzer, Pearson Prentice Hall, 2007. 3. Collines, W., et al, Algebra 1, McGraw Hill, New York, 1998.

4. Staff, Practical Mathematics, Amer. Tech. Pub. Inc, America 1994.

5. Central Washington University, Ellensburg, 1986. Thermometric functions 6. Books of Mathematics For Chemists.

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Course Title: Analytical Chemistry No. of Credit Hours ___03________

Course Code: ___CHEM-351_ Semester II Implementation Date September 2015

BoS Approval Date __30-06-2014__ BoF Approval Date __03-12-2014___

Detail of New Course Contents 1. Introduction / Assessment of Analytical Data Introduction and scope of analytical chemistry: Analytical problems and their solutions; The nature of analytical methods; trends in analytical methods; Different units of concentration and their conversion; Definition and basic concepts: nature and origin of errors, Classification of errors; Accuracy and precision; Limits of detection, Confidence limits; deviation, standard deviation, Application of statistical tests; Rounding off analytical data; Quality control charts; Computation of analytical data. Significance of sampling, weighing and measuring in Analytical chemistry. 2. Basic Chromatography Techniques Classifications of chromatographic techniques, Paper and thin layer chromatographic techniques; their instrumentation, applications and limitations, Column adsorption Chromatography. 3. Introduction to Spectroscopy / Spectrophotometry Introduction to molecular spectroscopy, absorption in UV and Visible range; Basic principle of spectrophotometry; Beer-Lambert’s law; Deviations; Instrumentation and application. 4. Ion Exchange Chromatography: Cation exchange resin, Anion exchange resin, Cross-linkage, Effect of pH-separation of amino acids, Separation of metal ions on anions exchange columns, Applications of ion exchange chromatography. RECOMMENDED BOOKS: 1. Analytical Chemistry by J.D. Dick, McGraw Hill, 1973, N.Y. also available in International students edition McGraw Hill, Mogakusha, 1973. 2. Instrumental Methods by W.Ewing, McGraw Hill Book Co. N.Y. (Third/Fourth Edition) also available in International students edition. 3. Chromatography by R.K Sharma , Gogel publishing home meerret 4. Introduction to chromatography by Nasir-ud-din, Published by author 5. Paper chromatography by Dr.Friedrich Cramer, London Macmillan and Co Ltd 6. Thin- layer chromatography by Marini, Elservier publisher 7. Modern analytical chemistry by David Harvey, Roohani-art press, Islamabad 8. Principle and Practice of analytical chemistry by Fillfield, Blackwell Science Ltd 9. Fundamentals of Chromatography by H.G. Cassidy, Inter Science Publisher, London, N.Y. 10. Fundamentals of Analytical Chemistry by DoughlasSkoog and Donals M. W. West, Holt Reinchart and Inc, London.

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Department:CHEMISTRY

Course Title: Analytical Chemistry (Practical) No. of Credit Hours ______01__________

Course Code: __CHEM-351P___ Semester II_ Implementation Date September 2015____


Detail of New Course Contents 1. Calibration: Calibration of glassware (pipette, burette and flask) used for volumetric analysis. Use of analytical balance and calculation of standard deviation. Calibration of pH meter and determination of pH of various acidic and basic solutions. Calibration of conductometer and determination of conductance of tap water, distilled water, conductivity water and canal water. Calculation of dissociation constants of various acids. Calculation of variance, mean, median, coefficient of variance of the data. 2. Basic Chromatography: Separation of ink components by paper chromatography. Separation of amino acids by thin layer chromatography. Separation of dyes by column chromatography. Separation of mixtures by circular paper chromatography. RECOMMENDED BOOKS 1. Vogels, s text book of quantitative inorganic analysis by J. Bassett. The English language book Society and Longman. 2. Introduction to chromatography by Nasir-ud-din, Published by author. 3. Paper chromatography by Dr. Friedrich Cramer, London Macmillan and Co Ltd. 4. Thin- layer chromatography by Marini, Elservier publisher

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Course Title: Industrial Chemistry No. of Credit Hours ______03__________

Course Code: ___CHEM-352___ Semester II_ Implementation Date September 2015


Detail of New Course Contents 1. Units operations Brief introduction of the chemical industries, treatment of general unit operations commonly used in industry such as evaporation, size reduction, filtration, distillation and crystallization. 2. Water treatment Water hardness, its measurement and removal, methods used for water softening including ion exchange and reverse osmosis, distillation and precipitation. Types of boilers scales. Chemical and mechanical methods to prevent scale formation. 3. Soaps and detergents Processes involved in soap manufacturing methods use for the manufacture of laundry soap and detergents. Recovery of glycerin. Detergents or surface active agents, cationic, anionic and non ionic agents. 4. Cement industry Raw materials used for cement manufacturing, dry process, wet process, semi-wet process, special cement, chemistry involved in hydration of cement, setting of cement and setting time. RECOMMENDED BOOKS 1. Rao,G.P., Mogarey, R.C., Solomn, S., Rewal,S.S. and Li,Y., Sugar Cane:

Production Management and Agro-Industrial Imperatives, Ibdc Publisher, (2005). 2. Covington, A.D., Tanning Chemistry: The Science of Leather, Royal Society of Chemistry, (2009). 3. Kent, J. A., Riegel’s Handbook of Industrial Chemistry, 10th ed., Kluwer Academic/ Plenum Publishers, (2003). 4. Reigel’s Handbook of industrial chemistry. Von Norstand Reeinhold Co. N. Y. 5. Chemical Process Industries by Shreve and Dum. McGraw Hill. 6. An introduction to industrial organic chemistry by Wiseman. App. Sci. Publ. 7. Water Supply and Sewerage, T.J. McGhee, McGraw Hill Book co. New York. (1991). 8. Unit operations in Chemical Engineering, Chattopadhyay, Khanna Publishers, Delhi-6

(1993). 9. The Chemistry of Cement, H.F.W. Taylor, Academic Press, London, 1964.

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Course Title: Industrial Chemistry (Practical) No. of Credit Hours ______01____ _____

Course Code: ___CHEM-352P___ Semester II_ Implementation Date September 2015____


Detail of New Course Contents 1. Determination of iodine value of the given oil. 2. Determination of acid value of the given oil. 3. To find out the percentage purity of fatty acid. 4. Preparation of gum sample. 5. Preparation of liquid detergent or liquid soap. 6. Estimation of water hardness by complexometry. 7. Determination of percentage purity of the commercial sample of sodium chloride. RECOMMENDED BOOKS

1. T.B. of Quantitative InorganicAnalysis, Vogal’s 4th Ed, Longman Group Limited (1978).

2. Reigel’s Handbook of industrial chemistry. Von Norst and Reeinhold Co. N. Y. 3. Chemical Process Industries by Shreve and Dum. McGraw Hill 5th Edition. 4. Applied Chemistry Theory and Practice, O.P. Vermani &A.K. Narula, Wiley Eastern

Limited (1989).

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Course Title: Chemical Biology No. of Credit Hours 03

Course Code: __CHEM-353___ Semester II_ Implementation Date September 2015


Detail of New Course Contents Course Contents: Cell Theory: Introduction to cell theory including historical perspective; prokaryotic and eukaryotic cell differences including cell wall. Membrane structure and chemical constituents of the cell: Function, isolation and molecular organization of cellular organelles specifically the plasma membrane, endoplasmic reticulum, Golgi bodies, ribosome, lysosomes, Membrane receptors and transport mechanisms. Ultra-structures and mechanisms: Mitochondrial ultra-structure and function, chloroplast ultra-structure and the mechanism of photosynthesis; cell movement-structure and function of cytoskeleton, centriole, cilia and flagella; nucleus. Structure and function of chromosomes: Structure of Chromosomes, Cell cycle, mitosis and meiosis, cell death. Recommended Books 1. Alberts B and Johson A, 2006, Molecular Biology of the Cell. 4th Edition; Garland

Publishers, New York. (available and www.ncbi.nlm.nih.gov) 2. Karp, 2002. Cell and Molecular Biology. 3rd Edition; John Wiley and Sons, New York. 3. Alberts et al., 2009. Essential Cell Biology. 3rd Edition; Garland Publishers, New York. 4. Lodish et al., 2007. Molecular Cell Biology. 6th Edition; Freeman and Company, Nw

York (available at www.ncbi.nlm.nih.gov) 5. Cooper GM and Hausman RE, 2009. The Cell, a molecular approach. 5th Edition;

Sinauer Associates, Inc.

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Course Title: Chemical Biology (Practical) No. of Credit Hours ______01__________

Course Code: _CHEM-353P__ Semester II_ Implementation Date September 2015



Microscopic and staining techniques. Study of prokaryotic, eukaryotic, plant and animal cells; cell structure; study of different types of plastids; cellular reproduction; Mitosis; smear/squash preparation of onion roots. Estimation of total protein, reducing sugar, total sugar from the extracts of seasonal fruits. Determination of citric acid by titration method in the fermentation medium.

RECOMMENDED BOOKS 1. Lehninger, A. L., “Principles of Biochemistry” Worth Publisher, New York (2001) 2. Murray, R. K., P. A. Mayes, D. K. Granner and V. W. Rodwell, “Harper’s.

Biochemistry”, 3. Appleton and Lange (2000). 4. Robert, “Harper’s Biochemistry”, 25th Edition (2000) 5. Stryer, L. “Biochemistry”, Freeman & Co.( 1994) 6. Voet, D. and Voet J.G. “Biochemistry” John Wiley & Sons, New York (2000) 7. West, “Text Book of Biochemistry” 4th Edition. (2000) 8. Zubay, G. “Biochemistry”, 4th Edition Macmillan Publishing Co.(1999) 9. Passmore, R. and M. A. Eastwood, Human Nutrition & Dietetics, Churchill

Livingstone/ELBS.

18




Course Title: Inorganic Chemistry No. of Credit Hours ___03_____________

Course Code: ___CHEM-354 _ Semester II Implementation Date September 2015____


Detail of New Course Contents 1. Chemical bonding: Metallic bond on the basis of band model, X-ray spectra and N(E) curves, n(E) curves. Binding energy in metals, conductors, semi-conductors and insulators. Effect of temperature and impurities on conductivity. 2. Pi- acceptor Ligands: Transition metal carbonyls (mononuclear, binuclear, poylnuclear), synthesis, bonding situation based on spectroscopic evidences; Theoretical rationalization of molecular structures, (close, nido, erachno), synthesis, characteristics and reactivity of derivatives of metal carbonyls (carbonylate anions, carbonyl hydrides and carbonyl halides); Metal nitrosyls including halonitrosyl and their derivatives. 3. Coordination Compounds: (Structure and Bonding) Development of coordination compounds. Rules of inorganic nomenclature for acids, salts, radicals, ions, iso and heteropoly anions and compounds. Hybridization in coordination compounds with coordination number from 2 to 9. MO diagrams for metal complexes of common geometry. Important features of CFT, d-orbitals splitting for various common geometries, measurement of 10 Dq., factors effecting 10 Dq. CFSE, factors influencing magnitude of variation in lattice and hydration energy for ions of first transition series.

RECOMMENDED BOOKS:

1. J H Huheey, Inorganic Chemistry - Principles, structure and reactivity, Harperand Row Publisher, Inc. New York (2008)

2. J. D. Lee, Concise Inorganic Chemistry, Elbs with Chapman and Hall, London 3.Introduction to Chemical Nomenclature by R.S. Cahn and O.E. dermer 2001. Butterworth (London). 4. Stereochemistry and bonding in Inorganic Chemistry by J.E. Ferguson 2001, Prentice Hall, New Jersy. 5. Chemical Bonds, and introduction to atomic and molecular structure by H.B. Gray 1973, W.A. Benjamin, Inc., London 6. Advanced Inorganic Chemistry F.A. Cotton and G. Wilkineon 6th Ed. 2001, Interscience, Publishers, London. 7. Coordination Compounds by S.F.A. Kettle, 1999, Nelson , (Nauohi Kenya). 8. Coordination Chemistry by B.A. Basallo and R. Johnson 1972 W.A. Benhamen, London.

19

DETAIL OF NEW COURSE FOR APPROVAL BY

ACADEMIC COUNCIL Name of Academic Program: M.Sc. Chemistry

Department:CHEMISTRY

Course Title: Inorganic Chemistry (Practical) No. of Credit Hours _____01_______

Course Code: __CHEM-354P _ Semester II_ Implementation Date September 2015


Detail of New Course Contents: 1. Chromatographic Techniques: (a) Separation of metal ions by paper chromatography and their identification with the help of locating agents and comparison of Rf values. (b) Separation of anions by paper chromatography and their identification. 2. Aqueous acid-base Titrations: (a) Estimation of SO2 and SO3 in air and discharged from an industrial process. (b) Estimation of CO2 (c) Estimation of oxalic acid and H2SO4in a mixture. (d) Estimation of H3BO3 and NaH2BO3in a mixture. (e) Determination of %age composition of a mixture containing H3BO3 and CH3COOH. 3. Precipitation Titrations: Estimation of following anions with the help of adsorption indicators: (i) Chloride (ii) Bromide (iii) Sulphate (iv) Chloride and Iodide in a mixture. RECOMMENDED BOOKS: 1. J. Bassett, R. C. Denny, G. H. Jeffery and J. Mendham, Vogel’s Text Book of qualitative Inorganic Analysis, the English Language Book Society and Longman, New York, (2008) 2. Quantitative Analysis Chemistry, James S. Pritz, George H. Sehenk, 2001 Alby and Becon Inc. London. 3. Theory and practice of chromatography by Prof. Dr. Javed Iqbal (2002). 4. Instrumental analysis by Gary D. Christian and James E.O., Reilly, 2007, Allyn and bacon Inc., London. 5. Hand Book of Organic reagents in Inorganic Analysis by ZAVIX Holzbecher and other 1976 Ellis Hurwod Limited, London. 6. Experimental Inorganic Chemistry - W. G. Palmer, 2005. 7. The analysis of minerals and ores of the rarer elements – W. R. Schoeller and A. R.Powell, Charles, Griffin and Company Limited,2004.

20




Course Title: Computational Chemistry No. of Credit Hours ______02__________

Course Code: __CHEM-355___ Semester II_ Implementation Date September 2015

BoS Approval Date __30-06-2014__ BoF Approval Date _03-12-2014_____

Detail of New Course Contents Scope of computational chemistry; course topics; review of key concepts from linear algebra • Molecular Mechanics / Force Field Methods Introduction to molecular mechanics; comparison of popular force fields; performance of molecular mechanics ,Molecular dynamics , Review of postulates of quantum mechanics The Born-Oppenheimer approximation, potential energy surfaces, local and global minima, transition states, and Hessian indices. Review of the variational method, Hartree-Fock molecular orbital theory, Slater determinants, anti-symmetry principle, deriving the Hartree-Fock equations, Hartree-Fock energy expressions for arbitrary spin-orbital configurations, spin integration, restricted and unrestricted references, self-consistent-field (SCF) procedure Vibrational frequency analysis, symmetry analysis, harmonic vs. fundamental frequencies, zero-point vibrational energies (ZPVE’s), Hessian index, distinguishing minima from transition states Electrostatics, atomic charges, dipole moment, polarizability, hyperpolarizability Transition state theory, statistical mechanics, and thermodynamic properties RECOMMENDED BOOKS

1. F. Jensen, Introduction to Computational Chemistry, (Wiley, New York, 1999). 2. A. Szabo and N. S. Ostlund, Modern Quantum Chemistry, Introduction to Advanced

Electronic Structure Theory, 1st ed., revised (Dover, 1989). 3. D. A. McQuarrie, Quantum Chemistry (University Science Books, Mill Valley, CA,

1983). 4. I. N. Levine, Quantum Chemistry, 4th ed. (Prentice Hall, Englewood Cliffs, NJ,

1991). 5. F. A. Cotton, Chemical Applications of Group Theory, 3rd ed. (Wiley, New York,

1990). 6. E. B. Wilson, J. C. Decius, and P. C. Cross, Molecular Vibrations: The Theory of

Infrared and Raman Vibrational Spectra (Dover, New York, 1980

21




Course Title: Physical Chemistry Paper-I No. of Credit Hours _______03_____

Course Code __ ___ Semester-III Implementation Date September 2015


Detail of New Course Contents 1. Polymer Chemistry Introduction to organic and inorganic polymers step growth polymerization. Kinetics of polymer chain growth. Molecular weights of polymers, distribution, averages and methods of measurements, diffusion, sedimentation and optical rotation. Introduction of chain isomerism, stereochemistry, configurations and conformations. Amorphous state of polymers, polymer conformation, microstructure, and dynamics in amorphous state. Polymer viscoelasticity, stress relaxation, mechanical models of polymer behaviour. Crystalline state of polymers. Polymer solutions and blends. 2. Photochemistry Principles of photochemistry, laws of photochemistry, Einstein’s law of photochemical equivalence, chemical reactions and their quantum yields. H2-Br2 and H2-Cl2 reactions

books. Kinetics and quantum yields of radiation and non-radiative process as fluorescence, phosphoresous, intersystem crossing, internal conversions, and quenching. Flash photolysis, techniques in photochemistry. Introduction of light sources, incandescent filament lamps, discharge lamps and lasers. 3. Nuclear Chemistry Comparison of artificial and natural radioactivity. Radioactive series, synthesis of transuranic elements. Nuclear stability, its calculations. Modes of decay. Nuclear energetics. Fission, fusion, and their comparison. Non-spontaneous nuclear processes. Nuclear reactors. Radiation desimetry, Energy states in radiation chemistry, excited states, evidence of existence of excited states and its types. Ion and electrons radiolysis of gases, liquids and solids. Instrumentation, of purity of chemicals and methods. Recent applications of radiation chemistry. RECOMMENDED BOOKS 1. Physical Chemistry, Samuel Glasstone, 1995. Macmillan and Co. Ltd. St. marlins Street, London. 2. Principles of Physical chemistry, Maron and Prutton, 1965 the Macmillan Company, Collier Macmillan Ltd. London. 3. Physical Chemistry, Barrow, 1973, McGraw Hill, Tokyo. 4. Physical Chemistry, Moore, 1972, Rentice Hall, Englewood cliffs, Jersey. 5. Physical Chemistry, Alberty and Daniels, 1962, McGraw Hill Book Company Ltd London. 6. Physical Chemistry, Castallan, 1972, AddsonWestey Publishing Company, Menla Park, California, London. 7. Physical Chemistry by Kundu, N and Jain, S.K.,S. Chand and Company Ltd. 1984. 8. Fundamentals of Chemical kinetics by Logan, S.R., Longman Group Ltd. 1996. 9. Elementry reaction kinetics by Latham. J.L. and burgess, A.E., 3rd Ed., Butterworths, London, 1997. 10. Physical Chemistry by Atkins, P.W., 5th Ed., W.H. Freeman and Company, New York, 1994. 11. Physical Chemistry by Alberty, R.A. and Silbey, R.J., John Wiley, New York, 1995. 12. Electrochemical Methods and applications by bard, A. and Faulkner, L.R., John Wiley, New York, 1980. Elements of classical and statistical thermodynamics by Nash, L.K. Addison Wesley Co. Ltd., 1979. 13. Hand book of surface and Colloid Chemistry by Birdi, K.S., CRC Press, 1997.

22

DETAIL OF NEW COURSE FOR APPROVAL BY

ACADEMIC COUNCIL Name of Academic Program: M.Sc. Chemistry


Course Title: Physical Chemistry Paper-II No. of Credit Hours _______03______

Course Code ___CHEM-402 __ Semester-III Implementation Date September 2015___

BoS Approval Date __30-06-2014__ BoF Approval Date _03-12-2014__

Detail of New Course Contents 1. Colloids and Surfactants: Colloids, colloidal dispersions, sols and their preparation, properties of suspensions, Optional properties of sols, determination of particle size, kinetic properties of sols, sedimention of suspensions, electrical properties of sols, electrophoresis and electro osmosis, stability of suspensoids, precipitation of sols, associated colloids, macromolecular properties in solutions and molecular weight determinations. 2. Statistical Thermodynamics Concept of various systems and states. Accessible states and distribution. Sterling’s formula, Ensembles, Relationship between entropy and thermodynamic probability. Maxwell-Boltzmann’s statistics for the system of independent particles. Partition function and relationship of partition function with various thermodynamic functions as enthalpy, internal energy, entropy, free energy, temperature and pressure. Sakure-Tetrode equation. Derivation of expressions for translational, rotational, vibrational and electronic partition function. Equation of state of an ideal gas from partition function. Applications of statistical thermodynamics with equilibrium and chemical kinetics. 3. Advanced Quantum Mechanics Concept of linear combination of atomic orbitals. Energy calculation for H2 and H2

+ from the approximate wave functions. Applications of Schrodinger wave equation to rigid rotators and determination of bond length of molecules. Linear harmonic oscillators, their quantum mechanical treatment. Probability distribution of an electron in atomic orbitals. RECOMMENDED BOOKS 1. Physical Chemistry by Alberty, R.A. and Silbey, R.J., John Wiley, New York, 1995. 2. Physical Chemistry by Engel, T. and Ried, P., 1st Ed,. Pearson education, Inc. 2006. 3. Elements of classical and statistical thermodynamics by Nash, L.K. Addison Wesley Co. Ltd., 1979. 4. Physical Chemistry by Kundu, N and Jain, S.K.S. Chand and Company Ltd. 1984. 5. Elementry reaction kinetics by Latham.J.L. And Burgess, A.E.3rd Ed., Butterworths, London, 1977. 6. Heterogeneous Catalysis: Principles and applications by Bond, G.C., 2nd Ed., Oxford, Clarendon press, 1987. 7. Physical Chemistry, Samuel Glasstone, 1995. Macmillan and Co. Ltd. St. marlins Street, London. 8. Principles of Physical chemistry, Maron and Prutton, 1965 the Macmillan Company, Collier Macmillan Ltd. London. 9. Physical Chemistry, Barrow, 1973, McGraw Hill, Tokyo. 10. Physical Chemistry, Moore, 1972, Rentice Hall, Englewood cliffs, Jersey.

23




Course Title: Physical Chemistry Paper-III No. of Credit Hours _______03___

Course Code __CHEM-403 __ Semester-III Implementation Date September 2015


Detail of New Course Contents 1. Rotational and Vibrational Spectroscopy: Parts and purposes of various regions of spectra. Types of molecules as, spherical tops, symmetric tops. Physical meanings and diagramic sketches for interaction of radiation with matter, Quantum mechanical formula of rigid rotators. Microwave spectroscopy of simple heteronuclear diatomic molecules. Determination of bond length and exact atomic mass of heavier isotopes by microwave spectrscopy. Non-rigid rotators. Interpretation and applications of distortion of constant. Quantum mechanical formula of vibrational spectroscopy, harmonic oscillators. Calculations of frequency of vibration of a bond with atomic masses and strength of bond. Significance of fundamental and combination bands. Rotational vibrational spectra of diatomic and polyatomic molecules. 2. Electrochemistry Idea of redox potentials, electrochemical series, electrochemical cells and types of electrodes. Nernst equation and its applications, predicting reactions, stability of oxidation states. Cell potential and thermodynamics. Reference electrodes as Ag-Ag, calomel, glass quinhydrone. Measurement of pH of solutions. Potentiometric titrations. Ion in solution, activity and activity coefficient, ionic activity, ionic strengths and Debye-Huckel theory of dilute solutions. Measurement of activity coefficients of ions. Contact adsorption, potential difference across metal solution interfaces, Outer and surface potential difference, Galvanic potential difference, electrocapillary thermodynamics. 3. Theories of Electrolytes Interfacial phenomena. Electrode kinetics. Mechanisms of electrode reactions. Cyclic voltammetry and its applications. Electrochemical impedance spectroscopy. RECOMMENDED BOOKS 1. Physical Chemistry, Castallan, 1972, AddsonWestey Publishing Company, Menla Park, California, London. 2. Physical Chemistry by Kundu, N and Jain, S.K.,S. Chand and Company Ltd. 1984. 3. Fundamentals of Chemical kinetics by Logan, S.R., Longman Group Ltd. 1996. 4. Physical Chemistry by Atkins, P.W., 5th Ed., W.H. Freeman and Company, New York, 1994. 5. Physical Chemistry by Alberty, R.A. and Silbey, R.J., John Wiley, New York, 1995. 6. Physical Chemistry by Engel, T. and Ried, P., 1st Ed,. Pearson education, Inc. 2006. 7. Electrochemical Methods and applications by bard, A. and Faulkner, L.R., John Wiley, New York, 1980. 8. Physical Chemistry, Samuel Glasstone, 1995. Macmillan and Co. Ltd. St. marlins Street, London. 9. Principles of Physical chemistry, Maron and Prutton, 1965 the Macmillan Company, Collier Macmillan Ltd. London. 10. Physical Chemistry, Barrow, 1973, McGraw Hill, Tokyo. 11. Physical Chemistry, Moore, 1972, Rentice Hall, Englewood cliffs, Jersey.

24




Course Title: Physical Chemistry (Practical) No. of Credit Hours _______02___

Course Code ___CHEM-404P ___ Semester-III Implementation Date September 2015


Detail of New Course Contents Electric conductance of electrolytes: To determine the cell constant of given cell. To determine the equivalence conductance of solution of weak electrolyte. To verification of Oswald’s law by dilution method. To determine the solubility of sparingly soluble salt. To determine the solubility of weak base of NH4OH by titrating it against standard solution of HCl by using conductivity method. To determine the strength of given base by titrating it against standard acetic acid solution and HCl solution using conductivity meter. To determine the strength of HCl and CH3COOH in the given mixture of both by titrating it against NaOH conductometrically. To determine the equivalent conductance of a weak electrolyte at infinite dilution using Kohlraush law. RECOMMENDED BOOKS

1. Advanced Experimental Physical Chemistry by Ayodhya Sing. 2. Experimental Physical Chemistry by Daniel 3. Experimental Physical Chemistry by G. Peter Mattews. 4. Experiments in Physical Chemistry by Shoemaker

25




Course Title: Organic Chemistry Paper-I No. of Credit Hours _______03___

Course Code __CHEM-405 ___ Semester-III Implementation Date September 2015


Detail of New Course Contents 1. Determination Of Reaction Mechanism: Determination of reaction mechanism, kinetics, stereochemical, intermediate formation, spectroscopic and isotopic labeling methods 2. Aliphatic Nucleophilic Substitution: Mechanism of SN1, SN2, SNi, reactions, kinetics, stereochemical and other evidence. Effects of other substrate structure, attacking nucleophile, leaving group solvent effect, and neighbouring group participation. 3. Elimination Reactions: Mechanism of E1, E2, and E1cb elimination reactions. Kinetics and stereochemical studies. Applications of thermodynamically and kinetically controlled reactions (Saytzeff and Hoffmann reactions), Effects of substrates, solvent, base, leaving group and temperature on kinetics, competition between elimination and substitution reactions. Pyrolytic elimination reaction mechanism and synthetic applications. 4. Spectroscopy: IR Spectroscopy: Electromagnetic radiations of IR region. Modes of vibration. Hook’s law, Instrumentation sampling techniques. Factors influencing the vibrational frequencies. Interpretation of spectra of various compounds and industrial applications. UV Spectroscopy: Ultraviolet (UV) or electronic spectroscopy. Electronic transition λmax and ϵmax. Values of various functional groups. Factors influencing the λmax value. Woodward Holfmann’s rules. RECOMMENDED BOOKS 1.Organic Chemistry, Volume I &II by I.L. Finar; fifth bedi. Longman scientific technical, 1975. 2. Spectroscopic Methods in organic chemistry by D.Williams and I. Fleming. 3. Spectrometric identification of Organic Compounds by R. M. Silverstein; sixth edition, Wiley, 2007. 4. Organic Spectroscopy and chromatography by M Younas, ILMI, Pakistan 5. Spectroscopy by Pavia, Lampman, Kriz, second Edition, Harcourt Brace College Publishers, 1996. 6. Biosynthesis of Natural Products, Paolo Manito, John Wiley & Sons, 1980. 7. Spectroscopic Methods in Organic Chemistry 6th ed. by D. Williams and I. Fleming. Wiley-VCH, 1991. 8. Spectrometric identification of Organic Compounds 6th ed. by R. M. Silverstein and F. X. Webster, Wiley, 2007. 9. Organic Spectroscopy and Chromatography by M Younas, ILMI, Pakistan, 2007. 19. Pavia.D.L, Lampman.G.M, Kriz.G.S, “Introduction to Spectroscopy: A Guide for

Students of Organic Chemistry” Saunders College Publishing/Holt.Rinehart and Winston (1979).

26




Course Title: Organic Chemistry Paper-II No. of Credit Hours _______03___



Detail of New Course Contents 1. Aromatic Substitution reactions: (a) Electrophilic substitution: General mechanism (kinetic, isotopic and spectroscopic evidences), nitration, sulfonation, halogenation, Friedel-Crafts alkylation and formylation, structure and reactivity, orientation; polysubstitution reactions of aromatic compounds. Their comparison with five and six membered heterocyclic comoounds. (b) Nucleophilic Substitution reactions: SN1, SN2 (addition and elimination), and Benzyne mechanism 2. Molecular Rearrangements: Classification of molecular rearrangements: mechanism of intramolecular 1,2-shifts involving migration of a group from carbon to carbon, carbon to nitrogen, and carbon to oxygen. Mechanism and synthetic applications of Wagner -Meerwein, Pinacolpinacolone, benzidine, benzyl, benzylic acid, Favorski, Wolff, Beckmann, Hoffmann, Curtius, Lossen and Schmidt; Baeyer-Villiger, Dakin and Fries rearrangements. 3. Heterocyclic Chemistry: Five and six membered heterocycles with one and several identical hetero-atoms, Five and six membered heterocycles with two different hetero-atoms. Aromatic character and aromaticity, relative stabilities, condensed heterocyclic rings and their reactivities. Their physical chemistry and important reactions. RECOMMENDED BOOKS

1. March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure, 6th ed. by Michael B. Smith, Jerry March, Wiley, 2007. 2. Organic Chemistry 6th ed. by Francis A. Carey, McGraw Hill, 2005. 3. Organic Chemistry 6th ed, by R. T. Morrison, R. N. Boyd, and R. K. Boyd, Benjamin Cummings, 1992,. 4. Phase-transfer catalysis: fundamentals, applications, and industrial perspectives by C. M. Starks, C.L. Liotta and M. Halpern, Chapman &Hall, 1994. 5. Principles in Organic Synthesis by R.O.C Norman & J. M. Coxon, Chapman and Hall, 1993. 6. Organic Chemistry by Jonathan Clayden, Nick Geeves, Stuart Warren, Oxford University Press 2000. 7. Heterocyclic Chemistry, 4th ed. by J. A. Joule, K. Mills, Blackwell Publishing,2000. 8. Heterocyclic Chemistry, 3rd ed. by T.L. Gilchrist, Longman, 1997. 9. Electrocyclic Reactions by F. L. Ansari, R. Qureshi, M. L. Qureshi, 1999, Wiley-VCH. 15. Designing Organic Synthesis, A Programmed Introduction to synthon approach, S. Warren, John Willey and Son, 1992. 16. Guide book to Organic Syntheses, R. K. Mackie, D. M. Smith, Longman Group Limited, 1982.

27




Course Title: Organic Chemistry Paper-III No. of Credit Hours _______03___



Detail of New Course Contents 1. Nuclear Magnetic Resonance Spectroscopy: Nuclear magnetic resonance: Basic principles, theory, spin flipping, nuclear precession and absorption of electromagnetic radiation, spin relaxation, basic introduction of 1-D (1H and 13 C) NMR spectroscopy, chemical shifts and integration curve, instrumentation, spin-spin splitting and coupling constants. Structure elucidation of small molecules. Introduction of 2-D NMR spectroscopy. 2. Mass Spectroscopy: Introduction; types, Isotopic abundance, molecular and metastable ions; fragmentation pattern, applications of mass spectroscopy in different classes of organic chemistry, interpretation of mass spectra of small organic molecules. 3. Oxidation and Reduction reactions: a. Oxidation Reactions: Introduction, Oxidation of saturated hydrocarbons, olefinic double bonds, aromatic rings, systems containing oxygen such as alcohols, aldehydes, ketones, oxidative decarboxylation, of acids, oxidation of systems containing nitrogen such as amines, hydrazines etc.. b. Reduction Reactions: Introduction, Reduction of alkenes, alkynes, and aromatic rings, hydrogenolysis, reduction of benzylic and allylic systems, aldehydes and ketones, alcohols, pinacols, epoxides, acids and their derivatives, Reduction of system containing nitrogen such as imines, oximes and nitro compounds RECOMMENDED BOOKS: 1. Organic Chemistry, Volume I (6th ed.) & II (5th ed.) by I.L. Finar, Pearson Education (singapore) Pte Ltd, 2008. 2. March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure, 6th ed. by Michael B. Smith, Jerry March, Wiley, 2007. 3. Organic Chemistry, eth Ed.; by S. H. Pine, McGraw Hill: New York,1987. 4. Organic Chemistry 6th ed. by Francis A. Carey, McGraw Hill, 2005. 5. Organic Chemistry 6th d, by R. T. Morrison, R. N. Boyd, and R. K. Boyd, Benjamin Cummings, 1992,. 6. Modern Synthetic Reactions 2nd ed. by H.O. House , W.A. Benjamin Inc., Menlo Park, CA 7. Principles in Organic Synthesis by R.O.C Norman & J. M. Coxon,1993, Chapman and Hall, 1993. 8. Organic Chemistry by Jonathan Clayden, Nick Geeves, Stuart Warren, Oxford University Press 2000.

28




Course Title: Organic Chemistry (Practical No. of Credit Hours _______02___

Course Code ___CHEM-408P _ Semester-III Implementation Date September 2015


Detail of New Course Contents 1. Qualitative analysis: Three component organic mixture analysis (separation and identification of the unknown components) 2. Chromatography and Spectroscopy: Separation of mixtures by chromatography and identification by spectroscopy 3. Organic Synthesis: (a) Multi-step preparation and spectroscopic characterization: p-nitroaniline from aniline; p-bromotoluene from p-toluidine, o-Bromotoluene from o-toluidine (b) Preparation, separation and identification of regio-isomers: o-nitrotoluene and p-nitrotoluene from toluene; o-nitrosophenol and p-nitrosophenol from phenol RECOMMENDED BOOKS

1. Practical Organic Chemistry by F. G. Mann and B. C. Saunders, 1978, Longman, UK, 1978 2. Vogel's Textbook of Practical Organic Chemistry (5th ed.) by A.I. Vogel, A.R. Tatchell, B.S. Furnis, A.J. Hannaford, P.W.G. Smith, Longman UK, 1989. 3. Advanced Practical Organic Chemistry, by J. Leonard, B. Lygo, G. Procter, CRC. 1994. 4. Advanced Practical Organic Chemistry (2nd ed.) by N. K. Vishnoi, Vikas Publishing House Pvt Ltd. India, 1996.

29




Course Title: Inorganic Chemistry Paper-I No. of Credit Hours _______03___



Detail of New Course Contents Classification of reaction mechanisms; rate laws; steady state approximation; inert and

labile complexes; substitution reactions in octahedral complexes and square planar

complexes, acid hydrolysis, base hydrolysis, steric effects of inert ligands, nucleophilic

reactivity, trans-effect, cis-effect, racemization reactions. Mechanism of electron transfer

reactions, oxidation reduction reactions of metal ions, outer and inner sphere mechanisms,

factors affecting rate of electron transfer reactions, two electrons transfer reactions,

complementary or non-complementary electron transfer reactions, oxidative addition,

addition of oxygen, hydrogen, HX, organic halides and bimetallic species, Reductive

Elimination Reactions.

RECOMMENDED BOOKS:

1. Huheey, J. E., Keiter, E. A., Keiter, R. L., Inorganic Chemistry: Principles of Structure and Reactivity, 4th ed., Prentice Hall, (1997). 2. Shriver, D. F., Atkins, P. W., Inorganic Chemistry, 3rd ed., Oxford University Press, (2001). 3. Wilkins, R. G., Kinetics and Mechanism of Reactions of Transition Metal Complex, 2nd ed., (Rev.), Wiley-VCH, (1991). 4. Jolly, W. L., Modern Inorganic Chemistry, 2nd ed., McGraw-Hill Company, (1991). 5. Jordan, R. B., Reaction Mechanisms of Inorganic and Organomettalic Systems, 2nd ed., Oxford University Press, New York, (1998). 6. Atwood, J. D., Inorganic and Organometallic Reaction Mechanisms, 2nd ed., Wiley- VCH, Inc., (1997). 7. Sharma, S. K., Inorganic Reaction Mechanisms, Discovery Publishing House, (2007).

30




Course Title: Inorganic Chemistry Paper-II No. of Credit Hours _______03___

Course Code ______CHEM-410 ___ Semester-III Implementation Date September 2015


Detail of New Course Contents Metal carbonyls: Introduction to π-acceptor ligands, effective atomic number (EAN) rule, 18 electron rule and chemistry of metal carbonyls, nitrosyls, and isocyanides, structure elucidation based on spectroscopic evidences, applications and uses of metal carbonyls and their derivatives for catalysis and organic synthesis.

Organometallic compounds: Chemistry and bonding of metal-sigma and pi-complexes,

Nature of Metal carbon bond, fundamental processes in organometallic compounds, catalysis by organometallic compounds.

RECOMMENDED BOOKS:

1. A. Yamamoto, Organotransition Metal Chemistry: Fundamental Concepts and Applications, John Wiley & Sons (1986).

2. P. Power, Principles of Organometallic Chemistry, 2nd ed., Chapman and Hall, London (1988).

3. R.H. Crabtree, The Organometallic Chemistry of the Transition Metals, 2nd ed., John Wiley & Sons (1994).

31




Course Title: Inorganic Chemistry Paper-III No. of Credit Hours _______03___



Detail of New Course Contents Flame Photometry: Origin and classification of atomic spectroscopic methods, origin of atomic spectrum, position of the signal, intensity of the signal, spectral line width, principle of flame photometry, fate of the sample in the flame, flame and its characteristics, instrumentation for flame photometry, merits and limitations. Atomic Absorption Spectrophotometry: Principle of atomic absorption spectrophotometry, concentration dependence of absorption, quantitative methodology, instrumentation for atomic absorption spectrophotometry, radiation sources, atomizers, flames, graphite furnaces and electrochemical atomizers, monochromators, detectors, handling background absorption, interferences in atomic absorption spectrophotometry, sample handling in atomic absorption spectrophotometry, preparation of the sample, use of organic solvents, microwave, digestion, sample introduction methods, applications of atomic absorption spectrophotometry. Atomic Emission Spectrophotometry: Introduction, principle of atomic emission spectrometry, atomic emission spectrometry using plasma sources, plasma and its characteristics, inductively coupled plasma, direct current plasma, microwave induced plasma, choice of argon as plasma gas, instrumentation for ICP-MS.

RECOMMENDED BOOKS:

1. Christian, G. D., Analytical Chemistry, 6th ed., John-Wiley & Sons, New York, (2006). 2. Harris, D. C., Quantitative Chemical Analysis, 8th ed., W. H. Freeman and Company, New York, (2011). 3. Kealey, D. and Haines, P. J., BIOS Instant Notes in Analytical Chemistry, Bios Scientific Publishers Limited, Oxford, UK, (2002). 4. Sharma, B. K., Instrumental Methods of Chemical Analysis, 24th ed., Goel Publishing House, Meerut, India, (2005). 5. Skoog, D. A. and West., D. M., Fundamentals of Analytical Chemistry, 8th ed., Hot Reinehart Inc., London, (2008). 6. Ebdon,L., Evaus, E.H, Fischer, A., and Hill, S.J., An Introduction to Analytical Atomic Spectrometry, John Wiley & Sons, England. (1998). 7. Bernhard Welz, Michael Sperling, Atomic Absorption Spectrometry, 3rd ed., Wiley-VCH, Germany, (1998). 8. Farrukh, M. A., Atomic Absorption Spectroscopy, InTech, (2012). 9. Kellner, R., Mermet,J.M, Otto,M., Valcarcel, M., Widmer, H.M., Analytical Chemistry : A Modern Approach to Anlytical Science, Wiley-VCH,(2004)

32




Course Title: Inorganic Chemistry (Practical) No. of Credit Hours _______02___

Course Code ______CHEM-412P ___ Semester-III Implementation Date September 2015



1. Synthesis of selected coordination/organometallic compounds such as:

a) K3[Cr(C2O4)3] b) [Co(NH3)5Cl]Cl2 2. Estimation of Al (III) and Fe (III) using 8-hydroxyquinoloine. 3. Estimation of Ni (II) in the presence of Cu (II). 4. Determination of chloride in the presence of iodide and evaluation of Ksp of AgI and AgCl. 5. Determination of dissociation constant Ka for acetic acid. 6. Determination of Ni+2 ions by EDTA (Back titration). 7. Determination of Ca+2 and Zn +2 ions by EDTA (Masking titration). 8. Determination of different metals by AAS. 9. Precipitation titration involving AgNO3 and KCl. RECOMMENDED BOOKS:

1. J. Bassett, R. C. Denny, G. H. Jeffery and J. Mendham, Vogel’s Text Book of qualitative Inorganic Analysis, the English Language Book Society and Longman, New York, (2008) 2. Quantitative Analysis Chemistry, James S. Pritz, George H. Sehenk, 2001 Alby and Becon Inc. London. 3. Theory and practice of chromatography by Prof. Dr. Javed Iqbal (2002). 4. Instrumental analysis by Gary D. Christian and James E.O., Reilly, 2007, Allyn and bacon Inc., London. 5. 2. Pass, G., Sutcliffe, H., Practical Inorganic Chemistry: Preparation Reactions and Instrumental Methods, 2nd ed., Chapman and Hall, (1974).

33




Course Title: Bio Chemistry Paper-I No. of Credit Hours _______03___



Detail of New Course Contents 1. Carbohydrate metabolism Carbohydrate metabolism, pentose phosphate pathway, uronic acid pathway, gluconeogenesis, glycogenesis and glycogenolysis. Regulation of carbohydrate metabolism. Photosynthesis. 2. Metabolism of Lipids Lipid metabolism, biosynthesis of fatty acids, glycerides, phospholipids and ketone bodies. Degradation and biosynthesis of sterols and bile acids. Regulations of lipid metabolism. RECOMMENDED BOOKS

1. Lehninger, A. L. Principles of Biochemistry, Worth Publisher, New York (2001). 2. Voet, D. and J. G. Voet,. Biochemistry, John Wiley & Sons, New York. (2000) 3. Murray, R. K., P. A. Mayes, D. K. Granner and V. W. Rodwell, Harper’s. Biochemistry,

Appleton and Lange(2000). 4. Robert, Harper’s Biochemistry, 25th Edition. (2000) 5. West, Text Book of Biochemistry 4th Edition. (2000) 6. Zubay, G. Biochemistry, 4th Edition Macmillan Publishing Co.(1999) 7. Stryer, L. Biochemistry, Freeman & Co.( 1994) 8. Alberts, B., D. Bray, J. Lewis, M. Raff, K. Roberts and J. D. Watson, Molecular Biology of Cell, McGraw Hill Book Co., New York. 9. Watson, J. D., N. H. Hopkins, J. W. Roberts, J. A. Steitz and A. M. Weiner, Molecular

Biology of the Gene, Benjamin/Cummins. 10. Darnell Jr., J., H. Lodish and D. Baltimore, Molecular Cell Biology, Scientific

American Books. 11. Dawis, B. D., R. Dulbecco, H. N. Eisen and H. S. Ginsbery, Microbiology, Harper &

Row. 12. Bryce, C. F. A., Microcomputers in Biochemistry: A practical approach, Oxford

University Press. 13. Passmore, R. and M. A. Eastwood, Human Nutrition & Dietetics, Churchill

Livingstone/ELBS 14. Watson, J. D., J. Tooze and D. T. Kurtz, Recombinant DNA, Scientific American

Books

34




Course Title: Bio Chemistry Paper-II No. of Credit Hours _______03___



Detail of New Course Contents 1. Metabolism of Proteins Protein metabolism and biosynthesis of amino acids. deamination and transamination, urea cycle, metabolic disorders, creatine & creatinine synthesis. 2. Metabolism of Nucleic acids Metabolism of nucleic acids biosynthesis and degredation of purines, pyrimidines, nucleosides and nucleotides. RECOMMENDED BOOKS

1. Lehninger, A. L. Principles of Biochemistry, Worth Publisher, New York (2001). 2. Voet, D. and J. G. Voet,. Biochemistry, John Wiley & Sons, New York. (2000) 3. Murray, R. K., P. A. Mayes, D. K. Granner and V. W. Rodwell, Harper’s .

Biochemistry, Appleton and Lange(2000). 4. Robert, Harper’s Biochemistry, 25th Edition. (2000) 5. West, Text Book of Biochemistry 4th Edition. (2000) 6. Zubay, G. Biochemistry, 4th Edition Macmillan Publishing Co.(1999) 7. Stryer, L. Biochemistry, Freeman & Co.( 1994) 8. Alberts, B., D. Bray, J. Lewis, M. Raff, K. Roberts and J. D. Watson, Molecular Biology of Cell, McGraw Hill Book Co., New York. 9. Watson, J. D., N. H. Hopkins, J. W. Roberts, J. A. Steitz and A. M. Weiner, Molecular






Books

35




Course Title: Bio Chemistry Paper-III No. of Credit Hours _______03___



Detail of New Course Contents 1. Physical techniques in biochemistry Physical techniques in biochemistry, gel filtration, ion-exchange and affinity chromatography, isoelectric focussing, centrifugation, ultrafiltration Isotopic labelling, Immunoblotting, ELISA and spectrometry. 2. Chemotherapy Chemotherapy antimalarials, sulfonamides and some commonly used antibiotics. Mechanism of drug resistance RECOMMENDED BOOKS








Books

36




Course Title: Bio Chemistry (Practical) No. of Credit Hours _______02___



Detail of New Course Contents 1. Analysis of normal and abnormal constituents in urine. 2. Analysis of organic and inorganic constituents of blood. 3. Estimation of different vitamins. 4. Separation of sub-cellular fractions in cells. 5. Gel filtration, ion-exchange, paper and thin layer chromatography of

proteins. 6. Gel filtration, ion-exchange chromatography and HPLC. 7. Enzymes: Purification and kinetic studies of invertase, lactic dehydrogenase and peroxidase. 8. Electrophoresis of plasma proteins, polyacrylamide gel electrophoresis. 9. Agarose electrophoresis of DNA. RECOMMENDED BOOKS

1. Wilson, A. Practical Biochemistry: Principle and techniques (2000). 2. Swotzer, Experimental Biochemistry theory and exercises in fundamental method

(2000) 3. Dryer, R. L. and G. F. Lata, Experimental Biochemistry, Oxford University Press. 4. Plummer, D. T.,Introduction to Practical Biochemisry, McGraw Hill Book Co., New

York (1986). 5. Alexander, R. R., J. M. Griggiths and M. L. Wilkinson, Basic Biochemical Methods,

John Wiley & Sons 6. Wooton, I. D. P., Microanalysis in Medical Biochemistry, J&A Churchill 7. Gowenlock, A.H., Varley’s Practical Clinical Biochemistry, 6th ed., Heinemann

Professional Publishing, Oxford (1988). 8. T. N. Pattabiraman. Laboratory Manual in biochemistry. All India Publishers(1998) 9. Gosling, J. P. Immunoassay: Laboratory Analysis and Clinical application (1994). 10. Sauhney, Introductory Practical Biochemistry (1998)

37




Course Title: Textile Chemistry Paper-I No. of Credit Hours _______03___



Detail of New Course Contents Introduction

Introduction to textile chemical processing, Chemical processing flow chart.

Shearing & Singeing Fundamentals

Shearing & Singeing processes, Shearing Machine and its description, Singeing Machine and its description, Evaluation of singed fabric.

Bleaching & Mercerizing Fundamentals

Bleaching Chemicals and auxiliaries, Bleaching chemistry, Effect of Mercerization on cotton fibre, Evaluation of Bleaching & Mercerizing.

RECOMMENDED BOOKS

1. Cellulosic Dyeing by John Shore, Society of Dyers and Colorists, 1995 2. Dyeing of Textile Materials by Jose Cegarra, Textilia, 1992 3. Textile Printing by W.C. Miles, Society of Dyers & Colorists, 2003 4. Textile Finishing by Derek Heywood, Society of Dyers & Colorists, 2003

38




Course Title: Textile Chemistry Paper-II No. of Credit Hours _______03___



Detail of New Course Contents Overview of characteristics, technology, processes, and research in apparel manufacturing industries including study of government statistics, material utilization and fabrication, mechanization, management and production engineering. The properties, characterization, and performance evaluation of clothing materials and structures for specific functional applications. Principles and methods related to wetting and transport properties, fabric hand and aesthetic properties, clothing comfort, and material and assembly technology. RECOMMENDED BOOKS

1. Gowrikar V. R. , Viswanathan N.V. and Jayadev Sreedhar, “Polymer Science”, New Age Publication, New Delhi 2003. 2. Gupta V. B. and Kothari V. K. , “Manufacture Fibre Technology”, Chapman and Hall Publication, UK 1997. 3. Billmayer F. M., “Text Book of Polymer science”, Wiley Inter Science, New York, 2002. 4. Trotman, E.R., Textile Scouring and Bleaching, Charless Griffins, Com. Ltd., London 1990. 5. Shenai V.A., Technology of Bleaching and Mercerizing, Sevak Publications, Wadala, Chennai, 1991. 6. Charles Tomasno, Chemistry and Technology of fabric Preparation and Finishing, North Carolina State University, USA,1992

39




Course Title: Textile Chemistry Paper-III No. of Credit Hours _______03___



Detail of New Course Contents Dyeing Fundamentals

Introduction to dyes, Dyeing of cellulosics with direct, reactive, sulphur and vat dyes, Dyeing of polyester, nylon, acrylic, wool and silk, Important characteristics of dyed fabrics.

Demonstration of various aspects of dyeing, printing, and finishing of textile substrates including the effect of fiber and finish type, and physical and chemical variables on dyeing and finishing processes and on the properties of the resultant textile. RECOMMENDED BOOKS

1. Morrison R.T. and Boyd R.N., “Organic chemistry”, 6th Edition, Prentice Hall of India (P) Ltd., 2003. 2. Arun Bahl and Bahl B.S., “Advanced Organic Chemistry”, 16th Edition, S.Chand and Company Ltd., 2002. 3. March J., “March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure”, 5th Edition, John Wiley, 2001. 4. Finar I.L., “Organic chemistry” Vol-I, 6th Edition, Pearson Education, 2002. 5. Sharma B.K., “Industrial Chemistry”, 12th Edition, Goel Publishing house, 2001. 6. Shenai,.V.A., “Introduction to the Chemistry of Dyestuffs”, Sevak Publications, Mumbai 199544 7. Shore,J. (Ed)., “Colorants and auxiliaries, Volume 1,:Colorants”, SDC, Blackwells, Leeds, 1990, 8. Shore,J. (Ed)., “Colorants and auxiliaries, Volume 2: Auxiliaries”, SDC, Blackwells, Leeds, 1990,

40




Course Title: Textile Chemistry (Practical) No. of Credit Hours _______02___



Detail of New Course Contents To demonstrate a simple laboratory colour matching exercise. Determination of the strength of H2O2. Determination of DO content of water sample by Winkler’s method. Determination of chloride content of water sample by argentometric method. Determination of strength of given hydrochloric acid using pH meter. Determination of strength of acids in a mixture using conductivity meter. Estimation of iron content of the water sample using spectrophotometer. (1,10- phenanthroline / thiocyanate method). Determination of molecular weight of polyvinylalcohol using Ostwald viscometer. Conductometric titration of strong acid vs strong base RECOMMENDED BOOKS

1. Daniel R. Palleros, “Experimental organic chemistry” John Wiley & Sons, Inc., New York 2001. 2. Furniss B.S. Hannaford A.J, Smith P.W.G and Tatchel A.R., “Vogel’s Textbook of practical organic chemistry”, LBS Singapore 1994. 3. Jeffery G.H., Bassett J., Mendham J.and Denny vogel’s R.C, “Text book of quantitative analysis chemical analysis”, ELBS 5th Edn. Longman, Singapore publishers, Singapore, 1996. 4. Kolthoff I.M., Sandell E.B. et al. “Quantitative chemical analysis”, Mcmillan, Madras 1980.

41




Course Title: Applied Chemistry Paper-I No. of Credit Hours _______03___



Detail of New Course Contents 1. Processing of Crude Oils Brief description of origin of petroleum Migration, reservoir, exploration and drilling of crude petroleum; Various unit processes involved petroleum processing like surface operation, fractional distillation; refining, cracking; reforming, isomerization; Polymerization, alkylation and finishing processes. 2. (a) Oils and Fats Classification of oils and fats, vegetable oils, essential oils, various methods of extraction of oils, refining and hydrogenation of oils. Industrial applications of oils in resins, surfactants, lubricants and paints. (b) Petrochemicals Chemistry and importance of the following petrochemicals; Acetylene; ethylene; propylene, benzene, toluene, xylene and naphthalene. Oxidation halogenations and nitration of petrochemicals of industrial significance. 3. Leather Tanning Industries Introduction, important steps in leather manufacturing, theory of leather tanning, waste disposal and pollution aspects involved in tanning industries. 4. Fertilizer industries

(a) Nitrogenous Fertilizers: Raw materials, various sources of hydrogen and nitrogen, manufacture of ammonia (Habber’s process), its use as fertilizer and other applications.

(b) Urea: Raw materials, manufacture of urea, assimilation in soil. Calcium ammonium nitrate

(c) Phosphatic Fertilizers: Calcium super phosphate, diammonium phosphate and triple super phosphate.

RECOMMENDED BOOKS

1. Arovan Singh “Industrial Chemistry” Vol. I & II, Anmd. Publishers. New Dehli 2. Buchel, Moretto & Wodith , Industrial Inorganic Chemistry, John Wiley & Sons. 3. Crogsins “ Unit Operation in Oganic Synthesis” McGraw Hill. 4. Pandey Vikas, “Text Book of Chemical Technology, Vol. 1 & II” Publishing Co. New

Dehli 5. Streven & Brink “Chemical Process Industries, McGraw Hill 6. Weissermel & Ape “Industrial Organic Chemistry” Verlag Chemie. 7. R. Norris Shreve, “The chemical process Industries” Second edition, McGraw-Hill Book company, Inc 8. Chemistry of pulp and Paper making, Edwin Sutermeister, Ed-3rd (1946).

42




Course Title: Applied Chemistry Paper-II No. of Credit Hours _______03___



Detail of New Course Contents 1. Sugar Industry Raw material, Extraction of juice from sugar cane, purification of juice, clarification, concentration, refining and crystallization. 2. Coal Chemicals and fuel Gases The destructive distillation of coal, coking of coal distillation of coal tar; Liquid Fuels: Hydrogenelysis Natural gas; Water Gas; Liquefied Petroleum Gases. 3. Textile Dyeing Color and chemical constitution, Important classes of chromogens, Classification and nomenclature of dyes, manufacturing of dye intermediates and dyes, Selection of dyes for wool, cellulosic and synthetic fibers, Theory of coloration, coloration of wool, cellulosic and synthetic fibers. 4. Textile Fibers Classification of synthetic fibers, chemistry and manufacturing of viscose rayon, true synthetic fibers including nylons and polyester fibers. Finishing processes for 100% cotton fibrics such as singeing, desizing, scouring, mercerizing and bleaching. RECOMMENDED BOOKS

1. R. Norris Shreve, “The chemical process Industries” Second edition, McGraw-Hill Book company, Inc.

2. T.B. of Quantitative Inorganic Analysis, Vogal’s Ed-4th, Longman Group Limited (1978).

3. Dyes and Dyeing, C.E. Pellow, Abhishek Publishers, (1998) 4. Textile Dyes and Pigments, H,. Panda, NIIR Publishers. 5. The Chemistry of Synthetic Dyes and Pigments, H.A. Lubs, Reinhold Publishing

Corporation, 1955.

43




Course Title: Applied Chemistry Paper-III No. of Credit Hours _______03___



Detail of New Course Contents 1. Soap Industry Processes involved in soap manufacturing, methods used for manufacturing laundry detergents. Recovery of glycerin. Detergent or surface active agents, cationic anionic and non-ionic agents. 2. Water Softening and Scale Removing Water hardness, its measurement and removal, methods used for water softening including ion-exchange, distillation and precipitation 3.Paper and Pulp Industries History and back ground, survey of raw materials, production of pulp by soda process, sulphite process and Kraft (sulphate) process, Manufacture of paper environmental aspects of paper industry. 4. Glass industry Chemistry of glass, raw materials, methods of manufacturing, various types of furnaces and crucible used for manufacturing of glass, special types of glass, their manufacturing and properties.

5. Leather industry Environmental aspects of leather industry, raw materials, steps involved in the manufacturing of leather, types of tanning, chrome tanning process and finishing operations.

RECOMMENDED BOOKS

1. Water supply and sewerage, T.J.McGhee, McGraw Hill Co. New York (1991). 2. Buchel, Moretto & Wodith , Industrial Inorganic Chemistry, John Wiley & Sons. 3. Unit operations in Chemical Engineering, Chattopadhyay, Khanna Publishers, Delhi 4. Pandey Vikas, “Text Book of Chemical Technology, Vol. 1 & II” Publishing Co. New

Dehli-6 (1993). 5. Hand Book of Industrial Chemicals, by SIRI Board of Consultants and Engineers, Small IndustriesResearch Institute, New Delhi (1995). 6. Industrial Chemistry, B.K. Sharma, Krishna Prakashan Media (P) Ltd., Ed-15 (2006). 7. R. Norris Shreve, “The chemical process Industries” Second edition, McGraw-Hill Book company, Inc

44




Course Title: Applied Chemistry (Practical) No. of Credit Hours _______02__



Detail of New Course Contents 1. Determination of magnesium and aluminum by EDTA titration. 2. Estimation of potassium in the tap water. 3. Analysis of caustic soda and soda ash in mixtures. 4. Determination of acidity of sulphuric acid and its normality. 5. Soap Analysis for free and combined alkali. 6. Preparations: Detergents, cosmetics, perfumes and vanishing creams. 7. Preparation and Testing of: Varnish and Enamel Paints. Adhesives. Emulsion Paints. 8. Purification and analysis of waste lubricating oils. RECOMMENDED BOOKS

1. Perfumes, Cosmetics and Soaps, W.A. Poucher, Chapmann and Hall 7th Ed. (1974). 2. Practical Statistics for Analytical Scientist, A Bench Guide, RSC Publishing LGC

Ltd (2009). 3. T.B. of Quantitative InorganicAnalysis, Vogal’s 4th Ed, Longman Group Limited

(1978). 4. Applied Chemistry Theory and Practice, O.P. Vermani &A.K. Narula, Wiley

Eastern Limited (1989).

45




Course Title: Analytical Chemistry Paper-I No. of Credit Hours _______03___



Detail of New Course Contents SYLLABUS OUTLINE: 1. FTIR / Raman Spectroscopy: Origin of infra red spectra; Different vibrational modes, Normal coordinate and normal vibrations, Symmetry of normal vibrations and selection rule, Raman spectroscopy, Metal-isotope spectroscopy, Vibrational spectra in gaseous phase and inert gas matrices; Comparison of raman with infra red spectroscopy; Applications for qualitative and quantitative chemical analysis; Instrumentation details and their function. 2. UV / Vis Spectroscopy: The Nature of electromagnetic radiation, The electromagnetic spectrum, Atomic energy levels, molecular electronic energy levels, Vibrational energy levels, Raman effect, Lasers, Radiation sources, Wavelength selection, Cells and sampling devices, detectors, readout modules, Instruments for absorption photometry 3. Atomic / Molecular Fluorescence: Atomic fluorescence spectroscopy; Instrumentation, applications and limitations of these techniques Plasma Source Inductively coupled plasma sources, special detection systems and read out devices used for ICPES; multielement analysis with plasma devices. 4. Laser Spectroscopy: Principle of laser operation; Stimulated emission population inversion, Single level and multi-level laser systems, Properties of laser light and its general and analytical applications; ruby laser, nitrogen laser, dye laser, Use of laser radiation in absorption and fluorescence spectroscopic methods. 5. Nuclear Magnetic Resonance Spectroscopy: Basic principles; properties of nuclei, Chemical shifts; spin-spin coupling; Pulsed fourier transform, NMR spectrometry; Identification of structural features; Use of NMR imaging in medicine; Analytical applications of NMR spectroscopy. 6. Mass Spectrometry: Principle of mass spectrometry; Intel system, ionization, acceleration, Drift chamber, Detection systems; Advancements in equipment; Analytical uses of mass spectrometry, Quadrupole mass spectrometry; Interpretation of mass spectra. Correlation of mass spectra with molecular structure RECOMMENDED BOOKS 1. Mass Spectrometry textbook by Jurgen H Gross, Springer-Verlag Berlin Heidelberg. 2. Nuclear Magnetic Resonance Spectroscopy by G.A Webb, RSC publishing. 3. Chemical Application of Spectroscopy by West, Inter Science Publisher Inc. N.Y. London. 4. Kinetics in Analytical Chemistry by H.B. Mark Jr. & G.A. Rechnitz, Interscience N.Y. (1968). 5. Analytical Chemistry by Gary D. Christian, John Wiley and Sons (1977). 6. Automated Chemical Analysis by J.K. Forman Stockwell, John Wiley and Sons, N.Y. (1975). 7. Advances in Infrared Group Frequencies by L.J. Bellacy, Mathuen& Col. Amsterdam (1968). 8. Laser spectroscopy by Wolfgang Demtroder, springerlink

46




Course Title: Analytical Chemistry Paper-II No. of Credit Hours _______03___



Detail of New Course Contents 1. Potentiometry: Nernst equation; Electrode potentials; different reference electrodes including glass and calomel electrode. Working of a potentiometer and its applications including pH measurements and potentiometric titrations. Ion-selective electrode systems; ion-exchange membrane electrode; gas-sensinig electrode; solid-state membrane electrode and bio-membrane electrode. 2. Thermo gravimetric Analysis / Differential Thermal Analysis: General principle of thermal, instrumentation, types of measurements; TGA (thermogravimetric analysis), DTA (differential thermal analysis), DSC (differential scanning calorimetry), TT (thermometric titrations) and EGD (evolved gas detection), Principles, instrumentation and applications of these techniques. 3. Voltrametry: Principle and applications of anodic stripping voltametry 4. Polarography: Introduction and principle of polarography, basic instrumentation, working and advantages of DME (dropping mercury electrode); limiting and residual current; half-wave potential; qualitative and quantitative aspects of polarographical analysis 5. Conductometry: Conductance in Solutions; Specific conductance; molar conductance; factors upon which the conductance of solution depends; Measurement of conductance; cell constant; Analytical applications of conductance measurement. RECOMMENDED BOOKS

1.Vogels, s text book of quantitative inorganic analysis by J. Bassett. The English language book Society and Longman. 2.Vogels, text book of Quantitative chemical analysis byJ.mendham, RCDenny, JDBarnes, MJ KTHomas, Pearson education Ltd. 3. Advances in electrophoresis by Andrea Chrmambach, Wiiley- VCH. 4. Chromatographic Methods of Analysis by Stock & Rice, Elsevier Co. Amsterdam. 5. Electro Analytical Chemistry by J.J. Longane, Inter Science Publisher Inc. N.Y. London. 6. Analytical Chemistry by Gary D. Christian, John Wiley and Sons (1977). 7. Principles of Polarography by J. Herosky& J. Kuta, Academic Press N.Y. (1968).

47




Course Title: Analytical Chemistry Paper-III No. of Credit Hours _______3___




(1) Introduction of Chromatography:

Classifications of chromatographic techniques, the chromatographic processes, rate theory of chromatography, Van-Deemter equation and its significance in evaluating column efficiency.

(2) Gas Liquid Chromatography:

General principle, sample preparation/derivatization, separation process, and instrumental aspects and its applications.

(3) HPLC:

General principle, sample preparation, separation process (normal phase and reverse phase separation), instrumentation, method development and applications.

(4) Capillary Electrophoresis:

Theory and principle of CE, mobility, electro-osmotic flow separation by CE, instrumentation, modes of operation, applications.

RECOMMENDED BOOKS

1. Skoog, D. A., West, P. M., Holler, F. J. and Crouch, S. R., Fundamentals of Analytical Chemistry, 9th ed., Cengage Learning, (2013).

2. Christian, G. D., Analytical Chemistry, 6th ed., John-Wiley & Sons, New York, (2004).

3. Kealey, D. and Haines, P. J., BIOS Instant Notes in Analytical Chemistry, 1st ed., Taylor & Francis, (2002).

4. Sharma, B.K. Instrumental Methods of Chemical Analysis, 24th ed., Goel Publishing House, Meerut, India, (2005).

5. Grob, R. L., Eugene, F. Barry, Modern Practice of Gas Chromatography, 4th ed., John-Wiley & Sons, USA, (2004).

6. Kellner, R., Mermet, J-. M., Otto, M., Valcarcel, M. and Widmer, H. M., Analytical Chemistry: A Modern Approach to Analytical Science, Wiley-VCH, (2004).

7. Meyer, V. R., Practical High-Performance Liquid Chromatography, 5th ed., John-Wiley & Sons, Ltd., (2010).

8. Lindsay, S., High Performance Liquid Chromatography, 2nd ed., John-Wiley & Sons, Ltd., (1992).

9. Braitwaite, A. and Smith, F. J., Chromatographic Methods, 5th ed., Kluwer Academic Publishers, (1999).

10. Miller, J. M., Chromatography: Concepts and Contrasts, 2nd ed., John-Wiley & Sons, Inc., (2005).

11. Camilleri, P., Capillary Electrophoresis: Theory and Practice, 2nd ed., CRC Press, (1998).

48




Course Title: Analytical Chemistry (Practical) No. of Credit Hours ______02___



Detail of New Course Contents 1. Molecular Spectrophotometry: Determination of Iron (II) using 1, 10-phenanthroline method. Determination of Iron (III) using thiocyanate method. Determination of chromium by diphenylcarbazide method. Determination of Fe, Pb, Cd, Zn and Cu in soil samples by AAS technique. Simple acid base titrations using potentiometer. Determination of “F” in water by using ion selective electrodes. Preparation of standard calibration graphs of Pb, Cd, Zn and Fe by AAS. Determination of Ni by DMG method spectrophotometrically. Determination of mixtures of complexes of Iron with Thiocyanide and 1, 10, pheranthroline. Determination of λmax of Cr complex with diphenylcarbazide. Infrared Determination of a Mixture of Xylene Spectrophotmetric determination of Lead or Leaves using Solvent Extraction. 2. Conductometry: Determine the amount of HClconductometrically by using strong base NaOH. Determine the amount of base NH4OH conductometrically by using strong acid. Determine the amount of NH4OH by using weak acid CH3COOH conductometrically. Determine the amount of NaOHconductometrically by using weak acid CH3COOH. 3. Potentiometry: Determine the amount of HCl by using strong base (NaOH) potentiometrically. Determine the amount of HCl by using weak base (NH4OH) potentiometrically. Determine the amount of CH3COOH by using strong base (NaOH). Determine the amount of HCl& CH3COOHconductometrically by using strong base NaOH. RECOMMENDED BOOKS: 1.Vogels, s text book of quantitative inorganic analysis by J. Bassett. The English language book Society and Longman. 2. Atomic and molecular spectroscopy. Basic concepts and practical application by SuneSvanberg, springerlink Berlin Heidelberg.

49




Course Title: Physical Chemistry Paper-IV No. of Credit Hours _______03___

Course Code ______CHEM-451 ___ Semester-IV Implementation Date September 2015


Detail of New Course Contents 1. Surface and Catalytic Chemistry Solids surfaces. Gas solid interface. Thermodynamics of adsorption. Heterogeneous catalysis. Kinetics and mechanisms of catalyzed reactions. Adsorption at liquid surfaces. Enzymatic catalysis. Organized molecular assemblies. Colloidal solutions. Catalyst preparation methods. Industrial catalysts. 2. Advance approach to homogenous and heterogeneous kinetics: Adsorption isotherms, single system, double system, study of gas reactions on solid surfaces, retardation, the Eley-Rideal mechanism and the Langmuir-Hinshelwood mechanism to study some organic and inorganic reactions, Catalysis, Autocatalysis, enzyme catalysis and enzyme inhibition. RECOMMENDED BOOKS

1. Albery J., Electrode Kinetics, Clarendon, Oxford, 1975. 2. Asperger S., “Chemical Kinetics and Inorganic Reaction Mechanisms” 2nd Ed.,

Springer Verlag (2003). 3. Bond G.C “Heterogeneous Catalysis” 2nd Ed., , Clarendon Press. Oxford (1987).

50




Course Title: Physical Chemistry Paper-V No. of Credit Hours _______03___



Detail of New Course Contents 1. Advanced Treatment of Solutions: The thermodynamic properties of solution. The solution process. Conditions of equilibrium between phases. Theoretical basis of Raoults equation. Deviation from ideal behavior. Compound formation and association. Separation of solid solutions. 2. Electronic and Raman Spectroscopy: Principles of electronic transition. Types of electronic transition. Energies of atomic orbital-with reference of H-atom spectrum electronic angular momentum fine structure of H-atom spectrum. Raman Spectra-idea of Raman scattering, Rayleigh scattering Molecular poparazability. Rotational Raman Spectra of linear Molecules. Symmetric top molecules and spherical top molecules Vibrational Raman spectra. RECOMMENDED BOOKS

1. Espenson, J. H. Chemical Kinetics and Reaction Mechanism “2nd Ed., McGraw Hill London (2002)

2. Hill T.L., “Statistical Mechanics, , New York, McGraw-Hill (1956). 3. House, James E., “Fundamentals of Quantum Mechanics” 2nd Ed., Elsevier-

Academic Press (2003) 4. J.H Espenson “Chemical Kinetics and Reaction Mechanisms”, 2nd Ed. McGraw Hill,

New York (1995) 5. Micheal, J. P., “Reaction Kinetics” Oxford University Press (2005). 6. ‘Principles of Electrode Kinetics” Roohi Printers, Lahore. 7. N. Davidson “Statistical Mechanics, New York, McGraw-Hill (1962).

51




Course Title: Physical Chemistry Paper-VI No. of Credit Hours _______03___



Detail of New Course Contents 1. The Atomic Nucleus and Its Properties: Atomic nucleus and its composition, nuclear radius and nuclear density, nuclear force, mass defect, packing fraction, binding energy, nuclear spin and moments, nuclear potential, concepts of nuclear structure – shell model, nuclear statistics, nuclear stability, nuclidic mass and atomic mass, nuclear mass and energy correlation, classification of nuclides. 2. Radioactivity and Radioactive Decay Laws: Radioactivity, units of radioactivity, natural and artificial radioactivity, radioactive decay, radioactive decay constant, kinetics of radioactive decay, half-life and average life, radioactive decay series, radioactive equilibria, comparison between radioactive equilibrium and chemical equilibrium. 3. Nuclear Reactions and Fission: Nuclear reactions and their comparison with chemical reactions, types of nuclear-reactions, conservation laws, energetics of nuclear reactions, nuclear reaction cross-section, excitation function, nuclear reactions mechanisms, liquid drop model of nuclear fission and fissionability parameters, general features of mass, charge and kinetic energy distributions in thermal neutron induced fission of 235U and 239PU. 4. Interaction of Radiation with Matter and Detection of Nuclear Radiation: Introduction, modes of interactions, interactions of gamma radiations with matters, interactions of charged particles with matters, Bremsstrahlung radiation, Cerenkov radiation, beta backscatter, the Auger process, radiation detection, measurements of radiations with ionization chambers, proportional counter, Geiger Müller counter, NaI(TI) scintillation detectors, solid state semiconductor detector. 5. Nuclear Reactors and Accelerators: Nuclear reactors -principles, major components of reactors, types of reactors, application of reactors; working principles, basic components and utilization of Van de graaff, tandem, Vande graaff and cyclotron accelerators. 6. Production and Uses of Radioisotopes: General principles of production of radioisotopes. Radio chemical separation and purification of isotopes, uses of radioisotopes in chemical, physical, and biological sciences, medicine, agriculture and industry citing illustrations of current interests. 7. Nuclear, Nuclear-relaled and Radiochemical Methods of Analysis and Their Applications: Radiotracer, geochronology and radioactive dating, isotope dilution method in chemical analysis, neutron activation analysis of trace elements, PIXE analysis of trace elements, energy dispersive X-ray fluorescence analysis. 8. Safety: Radiation exposure, radiation dose, dose equivalent, quality factor, simple calculation of radiation exposure and radiation dose for y- and ~-rays, radiation hazards, radioactive wastes and their management. RECOMMENDED BOOKS

1. Radiochemistry and Nuclear Methods of Analysis, W. D.Ehmann and D. E. Vance, John Wiley & Sons, Inc.

2. Nuclear and Radiochemistry, G.Friedlander, J.W.Kennedy, E.S.Macias and J. M. Miller, John Wiley & Sons.

3. Introduction to Nuclear Physics and Chemistry, B. G. Harvey, Prentice-Hall Inc.

4. Essentials of Nuclear Chemistry, H. J. Amikar, Wiley Eastern Ltd.

S. Nuclear Chemistry and its Applications, G. R. Choppin and J. Rydberg, Oxford: Pergamon.

52




Course Title: Physical Chemistry (Practical) No. of Credit Hours _______02___

Course Code ______CHEM-454P ___ Semester-IV Implementation Date September 2015


Detail of New Course Contents 1. Molecular Mass Determination of different Polymers by Viscosity measurement. 2. Thermo-chemical measurements (i) Heat of solution of a salt by solubility methods. (ii) Heat of precipitation. 3. Colloidal State: Preparation of As2S3 sol, and comparison of precipitating powers of different cations.

4. Spectrophotometry: (i) Determination of percentage composition of two coloured components in solution. (ii) Study of kinetics of iodination of acetone and decomposition of benzene diazonium chloride. (iii) Predicting normal modes of vibration for simple molecules and interpretation of their IR spectra. 5. Polarimetric Study of Reaction Kinetics: Inversion of cane sugar; salt effects on inversion of cane sugar. 6. Equilibrium constant for the reaction: I2 + I

I3

Calculation of ∆G for the formation of I3

reaction. 7. Adsorption measurements: Verification of Freundlich and Langmuir adsorption isotherms for adsorption of acetic acid on active charcoal. 8. Potentiometric measurements: A. Potentiometric titrations (i) Acid base (ii) Oxidation-reduction B. Equilibrium constant determination.

RECOMMENDED BOOKS

1. Advanced Experimental Physical Chemistry by Ayodhya Sing. 2. Experimental Physical Chemistry by Daniel 3. Experimental Physical Chemistry by G.Peter Mattews. 4. Experiments in Physical Chemistry by Shoemake

53




Course Title: Organic Chemistry Paper-IV No. of Credit Hours _______03___



Detail of New Course Contents 1. Introduction to natural products Introduction of primary and secondary metabolites and their varied sources, General classification of natural products, Historical and recent use of natural products in medicines. 2. Alkaloids Introduction, classification, isolation and general methods of structure determination. Chemistry of Conine, Nicotine and Morphine. 3. Terpenoids Introduction, classification, isolation and general methods of structure determination. Chemistry of Citral, -Pinene, Camphor and their biosynthesis. 4. Steroids Introduction, sterochemistry of Steroids, Chemistry of Cholesterol and Bile Acids. Biosynthesis of cholesterol. 5. Flavonoids Structure and synthesis of Flavones, Flavonol, Quercetin. Biosynthesis of Falvonoids. RECOMMENDED BOOKS

1. McMurry.J, “Organic Chemistry” Thomson Asia Pte Ltd, Singapore, Fifth Edition (2000).

2. Morrison.R.T, Boyd.R.N, “Organic Chemistry” Prentice-Hall, Inc; Sixth Edition (1992).

3. Solomons.T.W.G, Fryhle.C.B, Johnson.R.G, “Study Guide and Solutions Manual to Accompany Organic Chemistry” John Wiley & Sons, Inc; Seventh Edition (2000).

4. March.J, “Advanced Organic Chemistry Reactions, Mechanisms and Structure” John Wiley & Sons, Inc; Fourth Edition (1992)

5. Hornback.J.M, “Organic Chemistry” Brooks/Cole Publishing Company (1998). 6. Pine.S.H, Hendrickson.J.B, Cram.D.J, Hammond.G.S, “Organic Chemistry”

McGraw-Hill, Inc; Fourth Edition (1980). 7. Finar.I.L, “Fundamental Principles of Organic Chemistry”Longman, Third Edition,

Vol.I (1959). 8. Finar.I.L, “Stereochemistry and the Chemistry of Natural Products, “English

Language book Society and Longman Group Ltd; Fifth Edition, Vol.II (1975). 9. Cordell.G.A, “Introduction to Alkaloids”, John Wiley & Sons,Inc.(1981). 10. Craig.C.R., Stitzel.R.E., “Modern Pharmacology with Clinical Application”, 5th

Edition, Morgantown (2005). 11. Mann.J., “Secondary Metabolism”, 2nd Edition, Oxford University Press, New Yark.

(1987), 12. Bhat.S.V., Nagasampagi B. A., Sivakumar M., “Chemistry of Natural Products”,

Narosa Publishing House, New Delhi (2005).

54




Course Title: Organic Chemistry Paper-V No. of Credit Hours _______03___



Detail of New Course Contents 1. Modern Organic Synthesis Introduction to organic synthesis. Target selection, Retrosythesis, strategies, Reconnection approach- the synthon method and disconnection technique. Strategic bond approach, strategic bonds in rings. Biomimetic approach to retrosynthesis. The Chiron approach. Computer generated strategies. Formation of carbon-carbon single and double bonds. 2. Reactive Intermediates: Carbenes, nitrenes, and arynes. Structure and evidence for formation, general reactions and synthetic applications. 3. Free radical Reactions: Introduction, generation methods, relative stability, structure, free radical reactions and industrial applications. RECOMMENDED BOOKS

4. Cleyden.J, Greeves.N, Warren.S and Wothers.P, “Organic Chemistry” Oxford University Press (2001).

3. Nizami.S.S, “Reterosynthetic Approach to Organic Synthesis”, Higher Education Commission (2003).

2. Burger. A, “Medicinal Chemistry”, John Wiley & Sons, Inc; Third Edition, Part-I (1970).

1. Warren.S, “Organic Synthesis: The Disconnection Approach”, John Wiley & Sons Ltd (1982).

10. Reactive Intermediates in Organic chemistry, N. S. Isaac, John Willey and Sons, 1974. 10. Warren.S, “Designing Organic Syntheses A Programmed Introduction to the Synthon

Approach” John Wiley & Sons,Inc(1980). 11. Norman.R.O.C, “Principles of Organic Synthesis” Chapman and Hall Ltd, Second

Edition (1978). 12. Corey.E.J, Cheng.X.M, “The Logical of Chemical Synthesis” Wiley Interscience(1989).

55




Course Title: Organic Chemistry Paper-VI No. of Credit Hours _______03___



Detail of New Course Contents Proposed New Topics 1. Pericyclic reactions: Introduction, Wood-ward-Hoffmann rules and molecular orbital theory; cycloaddition, electrocyclic and sigmatropic rearrangement and group transfer reactions. 2. Protective Group Introduction to protective groups, protection of hydroxyl, amino, carbonyl and carboxylic groups, reactions involving the introduction and removal of some common protective groups and synthetic applications. Introduction to disconnection approach. RECOMMENDED BOOKS

1. Vogel.A.I, “Elementary Practical Organic Chemistry Part III: Quantitative Organic Analysis”, Longman Group Ltd (1958).

31. Mohan.J., “Organic Analytical Chemistry” Theory and Practice, Narosa Publishing

House, New Delhi (2003). 2. Greene.T.W, Nuts.P.G, “Protecting Groups in Organic Synthesis” John Wiley &

Sons, Second Edition (1991). 3. March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure, 6th ed. by Michael B. Smith, Jerry March, Wiley, 2007. 4. Organic Chemistry 6th ed. by Francis A. Carey, McGraw Hill, 2005. 5. Principles in Organic Synthesis by R.O.C Norman & J. M. Coxon, Chapman and Hall, 1993.

56




Course Title: Organic Chemistry (Practical) No. of Credit Hours _______02___



Detail of New Course Contents 1. Isolation of Natural Products

Isolation of Natural Products from the following;

1. Red Pepper 2. Turmeric 3. Piperine from Black Pepper 4. Caffeine from tea 5. Separation of plant pigments by TLC 6. Separation of plant pigments by paper chromatography 7. Cholesterol from gall stone, brain and egg 8. Lactose from milk 9. Oil from orange peels

2. Analysis of Commercial Drugs

Analysis of the following commercial drugs using HPLC and Titration methods:

i). Penicillin ii). Tetracycline iii). Chloroquine

iv). Brufen v). Valium vi). Paracetamol

vii). Neomycin viii). Chloropromazine RECOMMENDED BOOKS

1. Bender.G.T, “Principles of Chemical Instrumentation”, W.B.Saunders Company (1987). 2. Akitt.J.W, “NMR and Chemistry an Introduction to the Fourier transform multinuclear

era”, J.W.Arrowsmith Ltd, Bristol, Second Edition (1983). 3. Macomber.R.S, “NMR Spectroscopy Basic Principles and Applications”, Books for

Professionals, Inc (1988). 4. Kemp.W, “NMR in Chemistry A multinuclear Introduction”, The Macmillan Press Ltd.

(1986). 5. Silverstein.R.M, Bassler.G.C, Morrill.T.C, “Spectrometric Identification of Organic

Compounds”, John Wiley & Sons; Inc; Fourth Edition (1981). 6. Kemp.W, “Organic Spectroscopy”, Macmillan Education Ltd; Third Edition (1991). 7. Budzikiewicz.H, Djerass.C, Williams.D.H, “Mass Spectrometry of Organic

Compounds”, Holden-Day, Inc (1967).

57




Course Title: Inorganic Chemistry Paper-IV No. of Credit Hours _______03___




Non-aqueous solvents: Properties of ionizing solvents, classification, types of reactions, chemistry in non-aqueous solvents such as NH3, HF, CH3COOH, H2SO4, SO2, BrF3, N2O4 etc.

Fused salts systems: Reactions in molten salt systems (high temperature and low temperature molten salts.

Inorganic rings and cages: Clatherates, inorganic rings, chains, cages of B, Si, N, P, S.

RECOMMENDED BOOKS:

1. A.K. Holliday and A.G. Massey, Inorganic Chemistry in non-aqueous solvents, Pergamon Press Ltd. (1965).

2. H.H. Sisler, Chemistry in Non-aqueous solvents, Chapman & Hall Ltd. (1965).

3. J.E. Huheey, Inorganic Chemistry, Principles of Structures and Reactivity, 4th ed., Addison Wesley, Reading (1993).

58




Course Title: Inorganic Chemistry Paper-V No. of Credit Hours _______03___



Detail of New Course Contents Symmetry and symmetry operations. Point groups. Properties of group, Non-degenerate

representation, matrices, transformation of matrices, Degenerate representation , character

tables and their applications in chemical bonding and molecular vibration.

RECOMMENDED BOOKS:

Douglas, B., McDaniel, D., Alexander, J., Concepts and Models of Inorganic Chemistry, 3rd ed., John-Wiley & Sons Inc., (1997). 2. Huheey, J. E, Keiter, E. A., Keiter, R. L., Inorganic Chemistry: Principles of Structure and Reactivity”, 4th ed., Prentice Hall, (1997). 3. Mackay, K. M., Mackay, R. A. and Henderson, W., Introduction to Modern Inorganic Chemistry, 6th ed., CRC Press, (2002). 4. Miessler, G. L., Fisher, P. J. and Tar, D, A., Inorganic Chemistry, 5th ed., Prentice Hall, (2013). 5. Purcell, K. F., Kotz, J. C., An Introduction to Inorganic Chemistry, W. B. Saunders, Company Holt-Saunders, International ed., (1980). 6. Cotton, F. A., Wilkinson, G., Murillo, C. A., Bochmann, M., Advanced Inorganic Chemistry, 6th ed., Wiley-Intersceince, New York, (1999). 7. Jolly, W. L., Modern Inorganic Chemistry, 2nd ed., McGraw-Hill Company, (1991). 8. Carter, R. L., Molecular Symmetry and Group Theory, 1st ed., John-Wiley & Sons, Inc., New York, (1997). 9. Orchin, M., Jaffe, H. H., Symmetry, Orbitals, and Spectra, John-Wiley & Sons, Inc., New York, (1971). 10. McWeeny, R., Symmetry: An Introduction to Group Theory and its Applications, Dover

59




Course Title: Inorganic Chemistry Paper-VI No. of Credit Hours _______03___



Detail of New Course Contents Radioactivity And Nuclear Chemistry

This topic needs a balanced arrangement of articles to cover the inorganic chemistry. Types

and characteristics of nuclear radiation. Structure of nucleus, Radioactive decay, decay

constant half life, average life, radioactive equilibrium. Packing fraction stability belt,

Nuclear binding energy, Artificial radioactivity, fission and fusion reactions, Acceleration

of charged particles, Application of radioisotopes in various fields.

Recommended Books 1. Friedlander, G., Kennedy, J. W., Miller, J. M. and Maciuas, E. S., Nuclear and Radiochemistry, 3rd ed., John-Wiley & Sons, Inc., (1981). 2. Choppin, G. R., Rydberg, J., Liljenzin, J., Radiochemistry and Nuclear Chemistry, 3rd ed., Butterworth-Heinemann Ltd., (2002). 3. Arnikar, H. J., Essentials of Nuclear Chemistry, 4th ed., New Age International Pvt. Ltd. Publishers, (1996). 4. Naqvi, I. I. and Farrukh, M. A., Radiotracers in Chemical Applications VDM Verlag Dr. Müller, Germany, (2010). 5. Loveland,W., Morrissey, D. J. and Seaborg, J. T., Modern Nuclear Chemistry, John Wiley and Sons, Inc.,(2006)

60




Course Title: Inorganic Chemistry (Practical) No. of Credit Hours _______02___



Detail of New Course Contents 1.Use of organic reagents for the estimation of various metal ions 2. Preparation of Zinc-porphyrine complexes 3. Synthesis of Zinc-Phthalocyanine 4. Synthesis of ferrocene and acetyl ferrocene 5. Spectrophotometric determination of Nickel. 6. Spectrophotometric determination of Iron. 7 Spectrophotometric determination of Lead in leaves 8. Synthesis of coordination polymers of transition metals. RECOMMENDED BOOKS: 1. Angelici, R. J. (1977). Synthesis and technique in inorganic chemistry, pp. 157-168. Philadelphia: W. B. Saunders Company. 2. Elschenbroich, Ch., & Salzer, A. (1992). Organometallics. VCH Weinheim. 3. Hartley, F. R. (1974). Elements of organometallic Chemistry. London 4. Lucas, C. R., & Walsh, K. A. (1987). Organometallic chemistry of molybdenum. Journal of Chemical Education, 64, 265–266. 5. McNeese, T. J., & Ezbiansky, K. A. (1996). Photochemical preparation and reactivity of cis- Cr(CO)4(CH3CN)2. Journal of Chemical Education, 73, 548–550. 6. Miessler, G. L., & Spessard, G. O. (1991). Organometallic chemistry – A course designed for sophomore chemistry students. Journal of Chemical Education, 68, 16–18. 7. Rabideau, P. W. (1989). The metal–ammonia reduction of aromatic compounds. Tetrahedron, 45, 1579–1603. 8. Spessard, G. O., & Miessler, G. L. (1996). Organometallic chemistry. Upper Saddle River, New Jersey: Prentice Hall. 9. Szafran, Z., Pike, R. M., & Singh, M. M. (1991). Microscale inorganic chemistry. New York: John Wiley & Sons. 10. ZAVIX Holzbecher and other, Hand Book of Organic reagents in Inorganic Analysis Ellis Hurwod Limited, London. (1976) 11. J. Bassett, R. C. Denny, G. H. Jeffery and J. Mendham, Vogel’s Text Book of qualitative Inorganic Analysis, the English Language Book Society and Longman, New York, (2008) 12. James S. Pritz, George H. Sehenk, Quantitative Analysis Chemistry, Alby and Becon Inc. London. (2001) 13. Pass, G., Sutcliffe, H., Practical Inorganic Chemistry: Preparation Reactions and Instrumental Methods, 2nd ed., Chapman and Hall, (1974)

61




Course Title: Biochemistry Paper-IV No. of Credit Hours _______03___



Detail of New Course Contents 1. Immunology Chemistry of immunoglobulins, myeloma and hybridoma immunoglobulins. Immune system and its abnormalities, allergy and inflammation, complement system, peripheral leucocytes and macrophages. 2. Microbiology Microbiology microbial cultivation, metabolism and genetics. Bacteria, fungi, protozoa and algae. Medical and industrial microbiology. 3. Molecular biology Molecular biology Replication, transcription and translation. Regulation of gene expression. DNA synthesis and sequencing. Genetic code. plasmids, bacteriophages and cosmids. Mutagenesis, Methods and applications of recombinant DNA. RECOMMENDED BOOKS








Books

62




Course Title: Biochemistry Paper-V No. of Credit Hours _______03___



Detail of New Course Contents 1. Composition of blood Composition of blood plasma, serum proteins, red blood cells, white blood cells, platelets, structure and function of haemoglobin. Coagulation and its mechanism. 2. Body Fluids Biochemistry of urine and lymphatic fluids. 3. Physiological Chemistry Structure and functions of liver lungs, muscle, connective tissue, kidney, heart, nerve conduction and sensory systems. 4. Hormones Chemistry, functions and metabolism of thyroid, adrenal, pancreatic, steroid and growth hormones, hormonal regulation of metabolism. RECOMMENDED BOOKS








Books

63




Course Title: Biochemistry Paper-VI No. of Credit Hours _______03___



Detail of New Course Contents 1. Enzymes Kinetics Kinetic of single substrate reactions, substrate specify enzyme inhibition, multi-substrate reactions, multi-enzyme systems. 2. Vitamins: structure, physiological functions, deficiency diseases and recommended dietary allowances of vitamin A, D, E, K, B complex and C. 3. Nutrition Nutritional importance of carbohydrates, fats and proteins. Balance diet. micro-nutrients and their functions. Role of nutrition in growth, development and disease. RECOMMENDED BOOKS







Livingstone / ELBS 14. Watson, J. D., J. Tooze and D. T. Kurtz, Recombinant DNA, Scientific American

Books

64




Course Title: Biochemistry (Practical) No. of Credit Hours _______02___



Detail of New Course Contents 1. Dialysis, ultra filtration and lyophilization. 2. Cultivation of microorganisms in laboratory using solid and liquid culture media, test

tube, petri plate and shake flask cultures, isoletia of pure culture, study of physical characteristics of microorganism, bacterial growth curve, preservation of microbial strains

3. Enzymes, including preparation and kinetic studies of Invertase, Lactic dehydrogenase and peroxidases.

4. Estimation of different Vitamins, isolation and characterization of proteins in food materials.

RECOMMENDED BOOKS

11. Wilson, A. Practical Biochemistry: Principle and techniques (2000). 12. Swotzer, Experimental Biochemistry theory and exercises in fundamental method

(2000) 13. Dryer, R. L. and G. F. Lata, Experimental Biochemistry, Oxford University Press. 14. Plummer, D. T.,Introduction to Practical Biochemisry, McGraw Hill Book Co., New

York (1986). 15. Alexander, R. R., J. M. Griggiths and M. L. Wilkinson, Basic Biochemical Methods,

John Wiley & Sons 16. Wooton, I. D. P., Microanalysis in Medical Biochemistry, J&A Churchill 17. Gowenlock, A.H., Varley’s Practical Clinical Biochemistry, 6th ed., Heinemann

Professional Publishing, Oxford (1988). 18. T. N. Pattabiraman. Laboratory Manual in biochemistry. All India Publishers(1998) 19. Gosling, J. P. Immunoassay: Laboratory Analysis and Clinical application (1994). 20. Sauhney, Introductory Practical Biochemistry (1998)

65




Course Title: Textile Chemistry Paper-IV No. of Credit Hours _______03___




Impact of Industry on the Environment and Society

Relationship of society to safety and environmental aspects of manufactured products.

Quantifying manufacturing risks. Protective methods, e.g. administrative, engineering,

personal, treatment, pollution prevention. Social factors, e.g. political, regulatory, legal,

consumer attitudes, public policy, perceptions. Understanding complex social issues,

especially situations with conflicting goals. Critical comparison of options for risk

reduction, and selecting reasonable (hopefully optimal) courses of action in complex and

uncertain situations. Unsolved problems of industry and society (e.g. greenhouse effect).

Relationships of ethics, laws and regulations to manufacturing. RECOMMENDED BOOKS

1. A. Kumar, Environmental Chemistry, Wiley Eastern, New Delhi. 2. Baird, C. Environmental Chemistry, Freeman, New York. 3. J. W. Moore & E.M. Moore, Environmental Chemistry, Academic Press, New York. 4. Neil, P.O. Environmental Chemistry, Chapmann, London. 5. Pakistan Environmental Pollution Act 1997. 6. S. K. Banerji, Environmental Chemistry, Prentice Hall, Delhi. 7. S. K. Banerji, Environmental Chemistry, Tata Publisher, Delhi. 8. Staneley E. Manahan, Environmental Chemistry, Brooks, California.

66




Course Title: Textile Chemistry Paper-V No. of Credit Hours _______03___



Detail of New Course Contents POLYMER CHEMISTRY Introduction: Classification of polymers – Natural and synthetic; Thermoplastic and Thermosetting. Functionality – Degree of polymerization. Types and mechanism of polymerization: Addition (Free Radical, cationic and anionic); condensation and copolymerization. Properties of polymers, Techniques of polymerization: Bulk, emulsion, solution and suspension. Preparation, properties and uses of Nylon 6, 6, and Epoxy resin. CHEMICAL THERMODYNAMICS: Terminology of thermodynamics - Second law: Entropy - entropy change for an ideal gas, reversible and irreversible processes; entropy of phase transitions; Clausius inequality. Free energy and work function: Helmholtz and Gibbs free energy functions (problems); Criteria of spontaneity; Gibbs-Helmholtz equation (problems); Clausius-Clapeyron equation; Maxwell relations – Van’t Hoff isotherm and isochore(problems). PHOTOCHEMISTRY AND SPECTROSCOPY Photochemistry: Laws of photochemistry - Grotthuss–Draper law, Stark–Einstein law and LambertBeer Law. Quantum efficiency – determination- Photo processes - Internal Conversion, Intersystem crossing, Fluorescence, Phosphorescence, Chemiluminescence and Photo-sensitization. Spectroscopy: Electromagnetic spectrum - Absorption of radiation – Electronic, Vibrational and rotational transitions. UV-visible and IR spectroscopy – principles, instrumentation (Block diagram only). NANOCHEMISTRY - Distinction between molecules, nanoparticles and bulk materials; size-dependent properties. Nanoparticles: nano cluster, nano rod, nanotube(CNT) and nanowire. Synthesis: precipitation, thermolysis, hydrothermal, solvothermal, electrode position, chemical vapour deposition, laser ablation; Properties and applications TOTAL :45 PERIODS RECOMMENDED BOOKS

1. Dara S.S, Umare S.S, “Engineering Chemistry”, S. Chand & Company Ltd., New Delhi 2010 2. Sivasankar B., “Engineering Chemistry”, Tata McGraw-Hill Publishing Company, Ltd., New Delhi, 2008. 3. Gowariker V.R. , Viswanathan N.V. and JayadevSreedhar, “Polymer Science”, New Age International P (Ltd.,), Chennai, 2006. 4. Ozin G. A. and Arsenault A. C., “Nanochemistry: A Chemical Approach to Nanomaterials”, RSC Publishing, 2005.

67




Course Title: Textile Chemistry Paper-VI No. of Credit Hours _______03___



Detail of New Course Contents General introduction about Acids- Hydrochloric Acid, Sulphuric Acid, Acetic Acid, Formic Acid, Alcohols, Aldehydes, and Ketones. General methods of preparation and properties of Monohydric alcohols, polyhydric alcohols e.g. Glycol and glycerol, aldehydes-formaldehyde and ketonesacetone, oxalic acid, DMF. Introduction of Solution, saturated and unsaturated, ideal and non ideal solution. Different type of concentration units. Effect of temperature on concentration Fractional distillation of coal tar and its products, and their use in textile industry. RECOMMENDED BOOKS

1. Industrial Chemistry by B.K.Sharma. 2. Synthetic Organic Chemistry by Chatwal and Gurdeep. 3. Chemistry of Dyes and Principles of Dying by V.A.Shenai. 4. Physical Chemistry of Surfaces by A.W.Adamson. 5. Chemical Principles of Synthetic Fibre Dying by S.M.Burkinshaw. 6. Physical Chemistry of Dying by Vickerstaff.

68




Course Title: Textile Chemistry (Practical) No. of Credit Hours _______02___



Detail of New Course Contents 1. To apply a vat dye dispersion to a fabric by padding.

2. To apply a vat dye to cotton fabric using a pre-pigmentation method.

3. To observe the changes a vat dye undergoes during application to a fabric.

4. To determine the effect of soaping on a vat dye.

5. To practice pad-bath calculations.

RECOMMENDED BOOKS

1. Giles, C. H., A Laboratory Course in Dyeing, 2nd Ed., 1971. 2. Trotman, E. R., Dyeing and Chemical Technology of Textile Fibers, fourth edition,

1970 3. Arthur D. Broadbent, The Basic Principles of Textile Coloration. Society of Dyers &

Colourists, 2001

69




Course Title: Applied Chemistry Paper-IV No. of Credit Hours _______03___



Detail of New Course Contents 1. Synthetic Fibers Introduction and classification. Preparation properties and application of Nylon, Dacron, Polyesters, Rayon and Cuprammonium Rayon.

2. Polymers General classification of polymers, characteristics and significance of polymers, various mechanisms of polymerization process, Polymer processing like extrusion, injection, modeling and blow molding of plastics.

Brief description and uses of the following polymers:

Polyethylene, polystyrene, epoxy resins, polyethylene tetrapthalate.

3. Adhesives Introduction, Preparation and applications of Amino plasts. Polyesters, cellulosic, silicones, Polyurethanes.

RECOMMENDED BOOKS

1. Principles of polymer systems, Radri-Guez, McGraw Hill Book Co. New York. 2. Fibre to fabric, 4th Ed, Potter & Corba, McGraw Hill Book Company, 1959. 3. Industrial Chemistry, B.K. Sharma, Krishna Prakashan Media (P) Ltd., Ed-15 (2006). 4. Shereve’s Chemical Process Industries, 5th Ed. 1975, G.T. Austin, McGraw Hill Book.

Co. New York.

5. Board.B, Paint, Pigment, Solvent, Coating, Emulsion, Paint additives and formulations, Engineers India Research Incorporation, (2008).

70




Course Title: Applied Chemistry Paper-V No. of Credit Hours _______03___



Detail of New Course Contents Quality Control in Industries: Different methods for quality control in industries. Milk composition and different types of milk, butter, cheese etc.

Petroleum and Petrochemicals:

Origin of petroleum, constituents and classification of petroleum, cracking and distillation of various fractions in distillation towers, control of distillation tower in refinery, manufacture of monomers such as acetylene, ethylene, propylene, separation and purification of benzene, toluene and xylene.

Paints:

Raw materials for paints and pigments, classification and properties of surface-coating constituents, classification and manufacture of pigments, production of paints, varnishes, distempers, enamels and lacquers, chemistry involved in the drying phenomena of paints, drying oils for paint and classification of drying oils.

RECOMMENDED BOOKS


Dehli 5. Streven & Brink “Chemical Process Industries, McGraw Hill 6. Weissermel & Ape “Industrial Organic Chemistry” Verlag Chemie. 7. R. Norris Shreve, “The chemical process Industries” Second edition, McGraw-Hill Book company, Inc.

8. Manahan, S. E., Fundamentals of Environmental Chemistry, 2nd ed., CRC Press, (2001). 9. Austin, G. T., Nelson, W. L., Petroleum Refinery Engineering, 4th ed.,

Aukland. Mcgraw Hill, (1985).

71




Course Title: Applied Chemistry Paper-VI No. of Credit Hours _______03___



Detail of New Course Contents Insecticides Preparation and properties of insecticides. Applications for plant protection. Their side-effects and poisoning effects. Explosives Classification, Various types and their composition. Preparation of TNT, Trinitroglycerine, cellulose trinitrate, Smokeless powder and Black powder.

Cement: Definition, Various types and their composition. Preparation of Cement, Working of Ball mills, Setting Properties, Modern trends in Cement Industry, Environmental Impacts.

Industrial Pollution and Its Abatement:

Sources of air, water and soil pollution, Industrial waste control for the protection of environment, modern trends of waste management.

RECOMMENDED BOOKS


Dehli 5. Streven & Brink “Chemical Process Industries, McGraw Hill 6. Weissermel & Ape “Industrial Organic Chemistry” Verlag Chemie. 7. R. Norris Shreve, “The chemical process Industries” Second edition, McGraw-Hill Book company, Inc

72




Course Title: Applied Chemistry (Practical) No. of Credit Hours _______02__



Detail of New Course Contents 1. Evaluation of edible and industrial oils. Determination of acid value. Saponification

value and Iodine value. 2. Extraction and characterization of essential oils from fragrant plants. 3. Preparation and characterization of Nylon. 4. Analysis of effluent form industrial wastes. 5. Analysis of effluents from tanneries. 6. Recovery of chromium from tannery effluents. 7. Analysis of dolomite. 8. Loss on Ignition. 9. Assay of calcium by EDTA and Gravimetrically. 10. Assay of Aspirin and vitamin C. RECOMMENDED BOOKS


Dehli 5. Streven & Brink “Chemical Process Industries, McGraw Hill 6. Weissermel & Ape “Industrial Organic Chemistry” Verlag Chemie. 7. R. Norris Shreve, “The chemical process Industries” Second edition, McGraw-Hill Book company, Inc

73




Course Title: Analytical Chemistry Paper-IV No. of Credit Hours _______03___



Detail of New Course Contents Course Contents:

Radiotracer techniques, choice of radiotracers, factors affecting choice of radiotracers, isotope dilution analysis (IDA), principle and equation, instrumentation, applications, advantages and limitations, sub-stoichiometric isotope dilution analysis (SIDA), activation analysis (AA), principle of NAA, neutron sources, interferences, sensitivity and detection limits, classification, instrumentation, applications, advantages and limitations, comparison of NAA and IDA with other methods, radiometric titrations (RT), procedure, advantages and limitations, radio chromatography and radioimmunoassay.

RECOMMENDED BOOKS

1. Friedlander, G., Kennedy, J. W., Macias, E. S. and Miller. M. J., Nuclear and Radiochemistry, 3rd ed., Wiley, New York, (1981).

2. Arnikan, H. J., Essentials of Nuclear Chemistry, 4th ed., New Age International Pvt. Ltd.(1995)

3. Harvey, B. G., Nuclear Physics and Chemistry, 2nd ed., Prentice Hall Inc., (1969).

4. Naqvi, I. I., Farrukh,M.A, Radiotracers in Chemical Applications: Radiochemistry, VDM Verlog Dr. Muller, (2010).

74




Course Title: Analytical Chemistry Paper-V No. of Credit Hours _______03___



Detail of New Course Contents Food Products:

Introduction to food analysis, sampling of food, general methods of analysis. Analysis of milk, butter, wheat flour, meat, beverages, tea, coca, honey and soft drinks.

Pharmaceuticals:

Classification of drugs, tests for analysis of different pharmaceuticals, introduction to US and British pharmacopeia.

Forensics:

History and scope of forensic science, Forensic ethics, Forensic toxicology. Classification and analysis of narcotics and dangerous drugs. Examination of crime scene evidences, fingerprinting, skeletal material to provide scientific opinion for legal.

RECOMMENDED BOOKS

Recommended Books

1. Skoog, D. A., West, D. M. and Holler, F. J., Fundamentals of Analytical Chemistry, 7th ed., Saunders College Publishing, (1995).

2. Christian, G. D., Analytical Chemistry, John-Wiley & Sons, Inc., 6th ed., (2004). 3. Eckert, W. G., Introduction to Forensic Science, 2nd ed., CRC Press, (1997). 4. Nielsen, S. S., Food Analysis, 4th ed., Springer, (2010). 5. Thomas, G., Medicinal Chemistry: An Introduction, 2nd ed., John-Wiley & Sons,

(2007). 6. Kobilinsky, L. F., Forensic Chemistry Handbook, 1st ed., John-Wiley & Sons,

USA, (2012). 7. Watson, D. G., Pharmaceutical Analysis: A Textbook for Pharmacy Students and

Pharmaceutical Chemists, Elsevier, (2012). 8. Stuart H. Barbara, “Forensic Analytical Techniques”, 1st ed., John-Wiley & Sons,

(2013). 9. Jackson, A. R. W. and Jackson, J. M., Forensic Science, 2nd ed., Pearson Education,

(2008).

75




Course Title: Analytical Chemistry Paper-VI No. of Credit Hours _______3___



Detail of New Course Contents 1. Solvent Extraction: Basic principle of solvent extraction, The Distribution coefficient, The Distribution ratio, The Percent extracted Solvent extraction of metals, Analytical separations, Multiple batch extractions, Countercurrent distribution, Solid-phase extraction, Solvent extraction by flow injection analysis. 2. Electrophoresis: Capillary zone electrophoresis, Application of traditional electrophoresis Gel chromatography. 3. Flame Emission: Basic principle of atomic spectroscopy; Use of atomic spectra for detection and determination of elements; flame as a source of atomization and excitation; Instrumentation involved in FES; applications and limitations. 4. Atomic Absorption Spectroscopy: Basic principles of AAS; Flameless AA spectroscopy including graphite furnace and hydride generation. RECOMMENDED BOOKS: 1. Analytical Chemistry by J.D. Dick, McGraw Hill, 1973, N.Y. also available in International students edition McGraw Hill, Mogakusha, 1973. 2. Instrumental Methods by W.Ewing, McGraw Hill Book Co. N.Y. (Third/Fourth Edition) also available in International students edition. 3. Chromatography by R.K Sharma , Gogel publishing home meerret. 4. Introduction to chromatography by Nasir-ud-din, Published by author. 5. Paper chromatography by Dr.Friedrich Cramer, London Macmillan and Co Ltd. 6. Thin- layer chromatography by Marini, Elservier publisher. 7. Modern analytical chemistry by David Harvey, Roohani-art press, Islamabad. 8. Principle and Practice of analytical chemistry by Fillfield, Blackwell Science Ltd. 9. Spectroscopy by Browing, Mcgram Hill London. 10. Fundamentals of Chromatography by H.G. Cassidy, Inter Science Publisher, London, N.Y. 11. Fundamentals of Analytical Chemistry by Doughlas Skoog and Donals M. W. West, Holt Reinchart and Inc, London.

76




Course Title: Analytical Chemistry (Practical) No. of Credit Hours ______02___



Detail of New Course Contents 1. Flame Emission / Spectrophotometry: Determination of sodium in tap water by using flame photometer. Determination of potassium in tap water by using flame photometer. Find out the calcium in chalk sample by flame photometry. Determination of Ba by flame photometry. Estimation of purity of various compounds on the base of flame emission spectrophotometry. Indirect determination of various compounds by flame photometric techniques. Determination of λmax of KMnO4 and K2Cr2O7 by using spectrophotometer. Verification of Beer and Lambert Law. Ultraviolet spectrophotometric determination of aspirin, phenacetion and caffeine in APC tablet using solvent extraction. RECOMMENDED BOOKS

1. Vogels, s text book of quantitative inorganic analysis by J. Bassett. The English language book Society and Longman. 2. Introduction to chromatography by Nasir-ud-din, Published by author. 3. Paper chromatography by Dr.Friedrich Cramer, London Macmillan and Co Ltd. 4. Thin- layer chromatography by Marini, Elsrvier publisher

m.sc. chemistry (two years) evening programmeeveningprogram).pdf · 16 chem-354 inorganic chemistry...

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