münster symposium on cooperative effects · münster symposium on cooperative effects münster,...

Münster Symposium on

Cooperative Effects

Münster, Germany

May 4th 2012

The Collaborative Research Center(Sonderforschungsbereich) 858“Synergetic Effects in Chemistry - From Additivity towards Cooperativity“

ContactSonderforschungsbereich 858Corrensstraße 40D-48149 Münster, Germanyhttp://www.wwu.de/sfb858

Book of Abstracts

[email protected]/sfb858

Synergetische Effektein der Chemie - von der

Additivität zur Kooperativität

SFB858

Symposium Schedule Fri May 4th 2012, Aula Schloss of the WWU Münster

Opening Adress

9:55 am Armido Studer Speaker of the SFB 858

10:00 am Shie-Ming Peng Chair: F. Ekkehardt Hahn

National Taiwan University, Taiwan

“Molecular Metal Wires and Related Molecular Materials”

11:00 am Krzysztof Matyjaszewski Chair: N. Seda Kehr

Carnegie Mellon University, Pittsburgh, USA

“Atom Transfer Radical Polymerization - From Mechanism and Synthesis to Materials and Applications”

12:00 am

Postersession

Lunch (~ 12:30 pm) Coffee Break (~ 2:00 pm)

2:30 pm Christopher A. Hunter Chair: Mark P. Waller The University of Sheffield, UK

“The Anatomy of Complex Recognition Interfaces”

3:30 pm David W. C. MacMillan Chair: Ulrich Hennecke Princeton University, USA

“Multi Catalysis in Chemical Synthesis”

4:30 pm Poster Prize Awards Closing Remarks

Poster Contributions in alphabetical order (presenting author’s surname)

Authors Institution Title

1. Jens Antony, Stefan Grimme* WWU Münster / SFB 858 Fully ab initio protein-ligand interaction energies

with dispersion corrected density functional theory

2. Lukas M. Artner, Nina Bohlke, Jens

Dernedde, Nediljko Budisa,

Christian P. R. Hackenberger*

Freie Universität Berlin Multivalent Protein Scaffolds for Lectin Binding

Studies

3. Stephan Beckendorf, Sören Asmus,

Christian Mück-Lichtenfeld, Olga

García Mancheño*

WWU Münster / SFB 858 Cooperation as key to success:

Now weak C–H∙∙∙Anion interactions can catalyze!

4. Anup Biswas, Suman De Sarkar,

Ludger Tebben, Armido Studer*

WWU Münster Enantioselective cyclopropanation of enals by

oxidative N-heterocyclic carbene catalysis

5. Roberto Blanco-Trillo, Mattias

Leven, Bernd Goldfuss*

Universität Köln Electronegativity governs enantioselectivity: Alkyl-

aryl-cross coupling with fenchol-based Palladium-

Phosphorus-Halide catalysts

6. Teerawut Bootwicha, Erli Sugiono,

Magnus Rueping*

RWTH Aachen Continuous-flow Organocatalytic Asymmetric

Hydrogenations using FTIR Inline Analysis

7. Hannah Schuster, Hanna Bruss, Rémi

Martinez, Andrey P. Antonchick,

Herbert Waldmann*

Max-Planck-Institut für

Molekulare Physiologie

Dortmund

Synthesis of the B-seco Limonoid Scaffold

8. Mark Busch, Sefer Ay, Adam Kubas,

Karin Fink, Stefan Bräse*

Karlsruhe Institute of

Technology (KIT)

Multimetallic Complexes with [2.2]Paracyclophanes

Backbone: Cooperative Effects in Catalysis

9. C. Cebrián, M. Mauro, D.

Kourkoulos, P. Mercandelli, D.

Hertel, K. Meerholz, C. A. Strassert,

L. De Cola*

WWU Münster Luminescent neutral Platinum Complexes Bearing an

asymmetric N^N^N Ligand for High-Performance

Solution-processed OLEDs

10. Xiao Yun Chen, Helmut Buschmann,

Carsten Bolm*

RWTH Aachen Bioactive Sulfoximines:

Synthesis and Properties of Dapsone analogues

11. Christian A. Citron, Nelson L. Brock,

Patrick Rabe, Jeroen S. Dickschat*

Technische Universität

Braunschweig

The Stereochemical Course and Mechanism of the

IspH Reaction

12. Soumen De, Susnata Pramanik,

Michael Schmittel*

Universität Siegen Reversible ON/OFF Nanoswitch for Organocatalysis:

Mimicking the Locking and Unlocking Operation of

CaMKII

13. Julia V. Dickschat, Slawomir Urban,

Frank Glorius*, F. Ekkehardt Hahn*

WWU Münster / SFB 858 Novel Amphiphilic Germylenes and Stannylenes and

their Reactivity

14. Arne Dickschat, Jinjun Ren, Frederik

Behrends, Wilma Pröbsting, Hellmut Eckert*, Armido Studer*

WWU Münster / SFB 858 Bifunctional Mesoporous Silica Nanoparticals utilizing

click-chemistry: A route to cooperativity

15. Hussein Ali El-Damarany,

Soumen De, Michael Schmittel*

Universität Siegen Synthesis of Molecular Tweezers as Receptors



16. Christina Eller, Birgit Wibbeling,

Roland Fröhlich, Gerald Kehr,

Gerhard Erker*

WWU Münster Newly Developed Sulfur-Boron Systems

17. Hugo Fanlo, Sijbren Otto* University of Groningen,

Niederlande

Substrate-Induced Catalyst Formation in Dynamic

Molecular Networks

18. Yingsheng Zhao, Siong Wan Foo,

Susumu Saito*

Nagoya University, Japan Iron/Amino Acid Catalyzed Direct N-Alkylation of

Amines with Alcohols

19. Sabrina Freye, Jakob Hey, Anna

Torras-Galán, Michael John,

Guido H. Clever*

Georg-August Universität

Göttingen

Positive Cooperativity and Allosteric Halide Binding

by an Interpenetrated Double Cage

20. Silke Frömel, Roland Fröhlich,

Constantin G. Daniliuc,

Gerald Kehr, Gerhard Erker*

WWU Münster Application of Halogenating Reagents

in FLP Chemistry

21. Daniela Fuchs, Géraldine Rousseau,

Lisa Diab, Urs Gellrich and Bernhard

Breit*

Albert-Ludwigs-Universität

Freiburg

Cooperative Supramolecular Ligand Catalysis:

Tandem Hydroformylation-Hydrogenation of

terminal Alkenes

22. Takuya Fujimoto, Michio M.

Matsushita, Kunio Awaga*

Nagoya University, Japan Octathio[8]circulene Thin-Film Transistors in Ionic

Liquids

23. Agneyo Ganguly, Yoandris del Toro

Duany, Dagmar Klostermeier*

WWU Münster / SFB 858 Selective and co-operative binding of nucleotide and

DNA co-ordinated by the latch domain guides DNA

processing by T.maritima reverse gyrase

24. Sabrina Gatzweiler, Katharina Graf,

Verena Göker, A. Stephen K.

Hashmi*

Ruprecht-Karls-Universität

Heidelberg

Dual Activation: a New Concept in Homogeneous

Gold Catalysis

25. Christoph Glotzbach, Roland

Fröhlich, Ernst-Ulrich Würthwein*,

Shohei Saito, Shigehiro Yamaguchi

WWU Münster Oxa-/Aza-Boraphenalenes A Modular Fluorescent

Oligonitrile-Boron System

26. Muxin Han, Bice He,

Guido H. Clever*

Georg-August Universität

Göttingen

Control over the Shape of Coordination Cages by

Ligand Design and Dynamics

27. Johannes Hepperle, Anna Katharina

Bier, Armido Studer*,

Anreas Greiner*

WWU Münster,

Philipps-Universität

Marburg

A New Immobilization Concept For Organocatalysts

By Functionalization Of Polymeric Nanotubes

28. Christine Hofmann,

Peter R. Schreiner*

Justus-Liebig Universität

Giessen

Stereoselective Oxidation of Alcohols using TEMPO-

Peptide catalysts

29. Waldemar Hujo, Stefan Grimme* WWU Münster / SFB 858,

Rheinische Friedrich-

Wilhelms-Universität Bonn

Accurate description of ionic liquids, weak hydrogen

bonds and thermochemistry by dispersion-corrected

density functional theory

30. Yuki Iijima, Ryo Kitaura, Katsuaki

Kawasumi, Kenichiro Itami,

Hisanori Shinohara*

Nagoya University, Japan Bottom-up Fabrication of Graphene Nanoribbons

from Halogenated Aromatic Precursors with

Dnh Symmetry



31. Katsuaki Kawasumi, Tomonori

Kajino, Kenji Mochida, Yasutomo

Segawa, Lawrence T. Scott,

Kenichiro Itami*

Nagoya University, Japan Direct π-extension of Polycyclic Aromatic

Hydrocarbons by C–H Functionalization

32. Kathrin Benson, J. El-Gindi, Luisa De

Cola, Hans-Joachim Galla*, Nermin

Seda Kehr*

WWU Münster / SFB 858 Cell Adhesion Behaviour on Enantiomerically

Functionalized Zeolite L Monolayers

33. Jennifer Antonia Krings, Bart Jan

Ravoo*

WWU Münster / SFB 858 Light-Responsive Self-Assembly of Silica-

Nanoparticles

34. Sadhana Kumbhar, Frank D. Fischer,

Mark P. Waller*

WWU Münster / SFB 858 Assessment of weak intermolecular interactions

across QM/MM noncovalent boundaries

35. Manik Lal Saha, Jian Fan,

Michael Schmittel*

Universität Siegen Post-Self-Assembly Functionalization of a Trigonal

Nanoprism: Construction of a Cage-like 3D

Framework and Poly-Nanocage Metallodynamer with

Three Correlated Strands

36. Stefanie C. Lange, Bart Jan Ravoo* WWU Münster / SFB 858 Dynamic and Switchable Receptors in Water

37. Matthias Leiendecker, Mahmud

Hussain, Ke Liu, Jason Law, Daisuke

Ito, Stephanie Wang, Andrew Stern,

Stephen Johnston, Gavin Dunn, Yan-

Ling Zhang, Ben Munoz, Stuart L.

Schreiber*, Alykhan Shamji

Broad Institute of

Harvard and MIT

Identification of an allele-selective, small-molecule

inhibitor of the oncogenic ketoreductase activity of

isocitrate dehydrogenase

38. Pavel Lulchev, Agneyo Ganguly,

Dagmar Klostermeier*

WWU Münster / SFB 858 Identifying key residues of functional inter-domain

interfaces and DNA-binding sites in T. maritima

reverse gyrase.

39. M. Mauro, Luisa De Cola* WWU Münster Luminescent Molecular Assemblies Based on Pt(II)

and Ir(III) Complexes

40. Stefan Minkler, Bruce Lipshutz,

Norbert Krause*


Dortmund

Gold Catalysis in Micellar Systems:

Application in Natural Product Synthesis

41. Kazuhiro Mouri, Shohei Saito,

Shigehiro Yamaguchi*

Nagoya University, Japan Head-to-Tail Cyclic Thiazole Tetramers: Synthesis,

Structures, and Properties

42. Christian Mück-Lichtenfeld*,

Stefan Grimme*

WWU Münster / SFB 858,

Rheinische Friedrich-

Wilhelms-Universität Bonn

Many-body Deformation Densities provide Insight

into Cooperative Non-Covalent Binding

43. Michael E. Muratore, Masaki

Nakajima, Quentin Lefebvre,

Magnus Rueping*

RWTH Aachen Organocatalytic Carbanion Chemistry – Potassium

tert-Butoxide initiated additions of dithianes and

sulfonyl derivatives to styrenes

44. Kristine Müther, Roland Fröhlich,

Christian Mück-Lichtenfeld, Stefan

Grimme, Martin Oestreich*


Berlin

Characterization of a Ferrocene-Stabilized Silicon

Cation

45. Nicole Nischan, Wiebke

Stahlschmidt, Volker Haucke,

Christian P. R. Hackenberger*

Freie Universität Berlin Chemoselective Lipidation of Azido-Polypeptides by

the Staudinger-Phosphite-Reaction: Inhibition of

Clathrin-Mediated Endocytosis



46. Pascal Nösel, Max M. Hansmann,

A. Stephen K. Hashmi*


Heidelberg

Dual Activation: Gem-Diaurated Species as

“Instant Dual- Activation” Precatalyts

47. Nuria Ortega, Slawomir Urban,

Bernhard Beiring, Frank Glorius*

WWU Münster Ruthenium-NHC Catalyzed Highly Asymmetric

Hydrogenation of Benzofurans

48. Peter Persich, Kévin Micoine,

Alois Fürstner*


Kohlenforschung Mülheim

The Total Synthesis of Isomigrastatin

49. Markus Plois, Robert Wolf* Universität Regensburg,

WWU Münster / SFB 858

C-H Activation and H2 Fixation by Ruthenium(II)

NHC Complexes

50. Marco Potowski, Markus Schürmann,

Hans Preut, Andrey P. Antonchick,

Herbert Waldmann*



Dortmund

Selective Programmed One-pot Synthesis of

Complex Molecules Bearing Eight Stereocenters

51. Helene Reeker, Norbert Krause* Technische Universität

Dortmund

Coinage Metal Catalysis in Target-Oriented

Synthesis Illustrated by the Example of a

C-Glycopyranoside

52. Matti Reißmann, André Schäfer,

Thomas Müller*

Carl von Ossietzky Universität

Oldenburg

Silyl Cationic Frustrated Lewis Pairs –

A Progress Report

53. S.B. Riese, M. Weinhart, D. Gröger,

R. Tauber, R. Haag, J. Dernedde*

Charité-Universitäts-medizin

Berlin

Modulation of L-selectin–ligand interaction via

multivalent inhibitors under flow

54. Christian Rösener, Thorsten

Holtrichter-Rößmann, Johannes

Hellmann, Roland Fröhlich, Birgit

Wibbeling, Werner Uhl*,

Ernst-Ulrich Würthwein*

WWU Münster / SFB 858 Generation of Weakly Bound Al−N Lewis Pairs

by Hydroalumination of Ynamines and the

Activation of Small Molecules:

Phenylethyne and Dicyclohexylcarbodiimide

55. Christian Rösner, Katrin

Schünemann, Carl Deutsch,

Norbert Krause*


Dortmund

Towards the Total Synthesis of

(+)-Goniothalesdiol

56. Rajarshi Samanta, Jonas Lategahn,

Katharina Kulikov,

Andrey P. Antonchick*



Dortmund

Organocatalytic and Metal Free Oxidative

C-H Bond Amination at Ambient Temperature

57. Soumen Kumar Samanta,

Michael Schmittel*

Universität Siegen DABCO as a Dynamic Hinge Between Cofacial

Porphyrin Panels and its Tumbling Inside a

Supramolecular Cavity

58. André Schäfer, Thomas Müller* Carl von Ossietzky Universität

Oldenburg

Silyl Cation Mediated Conversion of CO2 into

Benzoic Acid, Formic Acid and Methanol

59. P. Scharf, F. Winckler, J. Müller* WWU Münster / SFB 858 A metal-mediated base pair with a phenanthroline-

derived ligand

60. Stefanie S. Schilson, Petra Keul,

Michael Schäfers, Bodo Levkau,

Günter Haufe*

WWU Münster New Ligands for Sphingolipid Receptor Imaging



61. Benjamin Schinor, Günter Haufe* WWU Münster Fluorinated Tranylcypromine Analogues as New

Monoamine Oxidase Inhibitors

62. Birgitta Schirmer, Muhammad Sajid,

Annika Klose, Timothy H. Warren,

Gerhard Erker, Stefan Grimme*

WWU Münster A new persistent N-Oxyl Radical and the

Activation of SO2 – New Activation Reactions

with Frustrated Lewis Pairs

63. Ruth K. Schmidt, K. Müther, C.

Mück-Lichtenfeld, S. Grimme, M.

Oestreich*

Technische Universität Berlin The Danger of Hidden Proton Catalysis with

Strong Lewis Acids in Silylium Ion-Catalyzed

Challenging Diels-Alder Reactions

64. Markus Schmidtendorf,

F. Ekkehardt Hahn*

WWU Münster / SFB 858 Synthesis of Supramolecular Structures containing

NR,NR- and NH,Osubstituted Dicarbene Building

Blocks

65. Nils Schröder, Joanna Wencel-

Delord, Frank Glorius*

WWU Münster High Yielding, Versatile and Practical

[Rh(III)Cp*]-catalyzed ortho-bromination and

iodination of arenes

66. Sören M. M. Schuler,

Peter R. Schreiner*


Giessen

In situ generated dioxirane organocatalysts in

enantioselective epoxidation reactions

67. Zhanhu Sun, Markus Albrecht*,

Roland Fröhlich

RWTH Aachen Amide-functionalized1Quinoline Derivatives as

Receptors for Anions

68. Daniel Thiel, Jan Deska* Universität Köln A Desymmetrization/ Ring Expansion Strategy

Towards Substituted Pipecolic Acids

69. Carlos Vila, Uxue Uria,

Magnus Rueping*

RWTH Aachen Direct azidation of allylic alcohols with TMSN3

70. Raffael C. Wende, Christian E.

Müller, Radim Hrdina,

Peter R. Schreiner*


Giessen

Evolution of Asymmetric Organocatalysis –

Retrocatalysis and the Multicatalyst Approach

71. Thomas Wiegand, Hellmut Eckert*,

Olga Ekkert, Annika Klose,

Muhammad Sajid, Gerald Kehr,

Roland Fröhlich, Gerhard Erker,

Stefan Grimme

WWU Münster / SFB 858 New Insights into Frustrated Lewis Pairs by

Modern Solid-State NMR Techniques and DFT

calculations

72. Marcel Wieteck, Tobias Lauterbach,



Heidelberg

Dual Activation: Gold-Catalyzed Synthesis of

Dibenzopentalenes

73. Nathalie E. Wurz, Frank Glorius* WWU Münster Highly enantioselective intermolecular Stetter

reaction of simple α,β-unsaturated esters –

synthesis of α-chiral γ-ketoesters

74. Weibo Yang, Yang Yu,



Heidelberg

Gold(I)-Catalyzed Novel Rearrangement of 3-

Silyloxy-1,5-enynes: Synthesis of

Benzo[b]furanandBenzo[b]thiophene Derivatives

münster symposium on cooperative effects · münster symposium on cooperative effects münster,...

Documents