mutineer exeter crude oil - santos - home · water by distillation astm d4006 %volume 0.00 wax...
TRANSCRIPT
on behalf of
Accreditation No. 13658
0.038 %m Sulphur
11.8 K Factor
Santos Limited
Crude Assay Job Number 2014-PTAD-000139
08-January-2015
MUTINEER EXETER CRUDE OIL
43.1 °API
0.10 mgKOH/g TAN
Joshua Camens ________________ Lab. Supervisor Jhonas Fernandez Lab. Manager ________________ Intertek - Commodities Port Adelaide Laboratory Australia NATA accredited lab for ASTM D2892 Full accreditation details available at http://www.nata.com.au/index.php/scopeinfo/?key=13651
Report By:
Approved By:
Date:
Santos Limited
60 Flinders Street
Adelaide SA 5001
Australia
For the Attention of : Cathy Frost
Sample(s) received from : Santos Limited
Sample(s) submitted as : Mutineer Exeter Crude Oil
2 x 20 L epoxy lined cans
5 x 20 mL VOA vials
2 x 1 L glass bottle
Sample description : Mutineer Exeter Crude oil dated 21-11-14
ex FPSO Modec, Venture 11
Seals on Sample(s) : Sealed: 0066772,0066762,0066795,0066770
Crude Assay Job Number 2014-PTAD-000139
January 8, 2015
2014-PTAD-000139
Page No.
Sample Details
1
2
3
4
5
Graph of Cumulative % Middle Volume vs API Gravity 6
7
8
9
10
11
appendix i
appendix iiDetailed Hydrocarbon Analysis, Full Report (70-140°C)
Component List. Total by group type & Carbon number.
Front End Overview
TABLE OF CONTENTS
Report ID:
Description
MUTINEER EXETER CRUDE OIL
Assay Slate Summary
Properties of Naphtha
Detailed Hydrocarbon Analysis, Full report (C5-70°C)
Component List. Total by group type & Carbon number.
Properties of Kerosene
Properties of Whole Crude Oil
Properties of Gas Oil
Properties of Residue
Distillation Overview
Graph of True Boiling Point vs Simulated Distillation
Graph of True Boiling Point (Cumulative % mass and % volume)
Report ID
Crude IDClient IDDate
Test Method Unit
mass% 0.1 4.0 22.9 26.2 32.7 14.1
vol% (note 1) 0.1 4.9 25.2 27.0 30.6 12.3
Density @15°C kg/L (note 6) 0.8098 0.5600 0.6556 0.7331 0.7879 0.8663 0.9297
Specific Gravity @60/60°F - 0.8102 0.5600 0.6558 0.7333 0.7883 0.8668 0.9303
API Gravity °API 43.1 121.2 84.3 61.5 48.0 31.7 20.6
Rapid Yield SIMDIS ASTM D7169+LE °C See page 3
Aromatics - FIA ASTM D1319 %volume 7.5
Aniline Point ASTM D611 °C 61.15
Aniline Gravity Product ASTM D611, Calc - 6819
Arsenic (Note 3) ICP-MS wt ppb <10
Lead (Note 3) ICP-MS wt ppb <10
Ash Content ASTM D482 %mass 0.012
Asphaltenes IP143 %mass 1.3
Carbon Residue - Micro ASTM D4530 %mass 5.9
Characterisation Factor UOP375 - 11.8
Colour Saybolt ASTM D6045 - +30
Copper Strip Corrosion ASTM D130 - 1A 1A 1A
Cetane Index ASTM D4737(proc. A) - 47.0
Cloud Point ASTM D2500 °C -13
Colour - ASTM ASTM D6045 - <0.5
DHA ASTM D6730 %volume/%mass See appendix i See appendix ii
Distillation ASTM D86 °C See page 10
Freeze Point ASTM D2386 °C -58.5
Kinematic viscosity @ -20°C 3.130
Kinematic viscosity @ 20°C 2.199 1.435 6.317
Kinematic viscosity @ 40°C 1.574 1.084 3.761
Kinematic viscosity @ 50°C 1.384 3.045 66.80
Metal - Nickel <1 1
Metal - Copper <1 <1
Metal - Iron <1 1
Metal - Sodium <1 3
Metal - Vanadium <1 <1
Metal - Mercury (Note 3) UOP938 wt ppb <1
Naphthalenes ASTM D1840 %volume 0.14
Nitrogen - Basic UOP269 wt ppm 355
Nitrogen - Total ASTM D4629 wt ppm 107 787
RON (Note 4) DHA Calc - 68.3 55.1
Pour Point - Upper ASTM D5853 °C <-36
Pour Point ASTM D97 °C -12 +33
Reid Vapour Pressure (Note 5) ASTM D323 psi 2.61
Salt Content ASTM D3230 PTB <1
Sediment by Extraction ASTM D473 %mass 0.04
Smoke Point ASTM D1322 mm 29.5
Sulphur - Mercaptan UOP163 wt ppm 2 1 <1 1
Sulphur - Total ASTM D5453 wt ppm 6.8 <1.0 17 273
Sulphur - Total IP 336 %mass 0.038 0.17
Total Acid Number ASTM D664 mg KOH/g 0.10 <0.10 0.46
Water by Distillation ASTM D4006 %volume 0.00
Wax Content UOP46 %mass <5.0 18.2
NOTES:(1) Volumes are expressed as per ASTM D2892 which stipulates volumetric expansion normalisation among fractions boiling below 150°C in proportion to their yields.
(2) Aniline point not possible on the residue as sample matrix outside of instrument's scope.
(3) Arsenic, Lead and Mercury values were determined on separate acid washed VOA vial samples supplied by the client.
(4) Calculated DHA properties are indicative only and are not meant to replace values derived by relevant physical testing methods.
(5) RVP was tested on a separate 1L bottle sample supplied by client.
(6) LPG density is estimated and for indicative purpose only. Unable to perform actual analysis due to insuficient amount of fraction.
ICPES wt ppm
ASTM D445 cSt
(note 2)
ASTM D5002/ASTM
D4052/ IP 365
Ga
s O
il 2
30
-36
0C
Re
sid
ue
36
0C
+
Santos Limited08-January-2015
LP
G
Na
pth
a C
5-7
0C
ASSAY SLATE SUMMARY
Wh
ole
Cru
de
Fractional Distillation ASTM D2892
2014-PTAD-000139
MUTINEER EXETER CRUDE OIL
Cut Range
Na
pth
a 7
0-1
40
C
Ke
ros
en
e 1
40
-23
0C
Santos Mutineer Exeter Crude oil 2014-PTAD-000139 - Final Report.xls Page 1 of 11
Report ID
Crude ID
Client ID
Date
Test Method Unit
Simulated Distillation ASTM D7169 + LE - See page 3
Density @15°C kg/L 0.8098
Specific Gravity @60/60°F - 0.8102
API Gravity °API 43.1
Arsenic (Note 3) ICP-MS wt ppb <10
Lead (Note 3) ICP-MS wt ppb <10
Characterisation Factor UOP375 - 11.8
Kinematic viscosity @20°C 2.199
Kinematic viscosity @40°C 1.574
Kinematic viscosity @50°C 1.384
Metal - Nickel <1
Metal - Copper <1
Metal - Iron <1
Metal - Sodium <1
Metal - Vanadium <1
Metal - Mercury (Note 3) UOP938 wt ppb <1
Nitrogen - Total ASTM D4629 wt ppm 107
Pour Point - Upper ASTM D5853 °C <-36
Reid Vapour Presure (Note 5) ASTM D323 psi 2.61
Salt Content ASTM D3230 PTB <1
Sediment by Extraction ASTM D473 %mass 0.04
Sulphur - Mercaptan UOP163 wt ppm 2
Sulphur - Total IP336 %mass 0.038
Total Acid Number ASTM D664 mg KOH/g 0.10
Water by Distillation ASTM D4006 %volume 0.00
Wax Content UOP46 %mass <5.0
NOTES:(3) Arsenic, Lead and Mercury values were determined on separate
acid washed VOA vial samples supplied by the client.
(5) RVP was tested on a separate 1L bottle sample supplied by client.
Wh
ole
ASTM D5002
ASTM D445 cSt
ICPES wt ppm
Properties of Crude Oil
08-January-2015
2014-PTAD-000139
MUTINEER EXETER CRUDE OIL
Santos Limited
Santos Mutineer Exeter Crude oil 2014-PTAD-000139 - Final Report.xls Page 2 of 11
Crude Name:
Report ID:
Sample Number: 2014-PTAD-0001390-001
Temp C % mass
Cumulative %
mass
Density
(kg/L) SG 60/60F
API
Gravity %volume
Cum. %
volume Mid %vol
Cum. Mid.
%vol
15.0 0.1 0.1 0.5600 0.5600 121.2 0.1 0.1 0.1 0.1
70.0 4.0 4.1 0.6556 0.6558 84.3 4.9 5.0 2.5 2.5
110.0 11.6 15.7 0.7218 0.7220 64.5 13.0 17.9 9.0 11.4
140.0 11.3 27.0 0.7449 0.7453 58.4 12.2 30.2 15.1 24.0
170.0 9.7 36.7 0.7645 0.7649 53.5 10.3 40.5 20.2 35.3
200.0 8.3 45.0 0.7880 0.7884 48.0 8.5 49.0 24.5 44.7
230.0 8.2 53.2 0.8166 0.8171 41.7 8.2 57.1 28.6 53.1
250.0 6.0 59.2 0.8374 0.8379 37.4 5.8 62.9 31.5 60.0
280.0 8.7 67.9 0.8594 0.8599 33.1 8.2 71.2 35.6 67.0
310.0 6.7 74.6 0.8759 0.8764 30.0 6.2 77.4 38.7 74.3
330.0 5.9 80.5 0.8788 0.8793 29.4 5.4 82.8 41.4 80.1
360.0 5.4 85.9 0.8861 0.8866 28.1 4.9 87.7 43.9 85.3
360+ 14.1 100.0 0.9297 0.9303 20.6 12.3 100.0 50.0 93.9
SIMDIS DATAtemp C mass% temp C mass% temp C mass%
27.8 0.5 164.8 34 277.1 68
36.1 1 168.0 35 281.6 69
60.3 2 170.7 36 285.5 70
63.3 3 173.1 37 287.7 71
68.7 4 178.4 38 292.9 72
71.8 5 181.9 39 297.6 73
80.7 6 185.5 40 301.2 74
89.8 7 188.8 41 304.3 75
91.8 8 192.5 42 309.5 76
91.9 9 194.4 43 313.6 77
98.4 10 198.2 44 316.5 78
98.4 11 202.3 45 322.9 79
100.9 12 206.4 46 328.7 80
100.9 13 209.8 47 332.8 81
100.9 14 213.1 48 340.3 82
100.9 15 214.6 49 345.2 83
104.9 16 218.1 50 352.7 84
117.5 17 221.7 51 358.1 85
117.5 18 225.6 52 366.9 86
117.6 19 228.7 53 373.7 87
118.5 20 231.9 54 381.4 88
121.2 21 233.5 55 391.5 89
125.7 22 236.5 56 402.2 90
125.7 23 240.3 57 413.1 91
125.7 24 243.8 58 424.6 92
132.9 25 247.0 59 439.1 93
135.2 26 250.1 60 457.0 94
144.0 27 252.3 61 486.1 95
144.9 28 255.0 62 538.4 96
148.0 29 259.3 63 650.7 97
150.8 30 263.4 64 719.9 97.4
156.4 31 266.7 65
159.5 32 269.5 66
161.9 33 272.0 67
DISTILLATION OVERVIEW
(6) LPG density is estimated and for indicative purpose only. Unable to perform actual analysis due to insuficient amount of fraction.
MUTINEER EXETER CRUDE OIL
ASTM D2892
TBP DATA
Volumes are expressed as per ASTM D2892 which stipulates volumetric expansion normalisation among fractions boiling below
150°C in proportion to their yields.
MUTINEER EXETER CRUDE OIL
2014-PTAD-000139
Santos Mutineer Exeter Crude oil 2014-PTAD-000139 - Final Report.xls Page 3 of 11
Front End Overview
REPORT ID:
ASSET ID:
Boiling Range °C
mass%
vol %
Density @15°C (Note 6) kg/L 0.5600
Specific Gravity @60/60°F - 0.5600
API Gravity °API 121.2
Boiling Range °C
mass%
vol %
Density @15°C kg/L 0.6556
Specific Gravity @60/60°F - 0.6558
API Gravity °API 84.3
Summary mass% vol%
n-Paraffins 46.290 47.356
Iso-Paraffins 44.826 45.032
Naphthenes 8.884 7.612
Aromatics <0.010 <0.010
Olefins <0.010 <0.010
Unidentified <0.010 <0.010
DHA CALCULATED PROPERTIES**Average Molecular Weight :
Relative Density:
Octane Number:
Boiling Range °C
mass%
vol %
Density @15°C kg/L 0.7331
Specific Gravity @60/60°F - 0.7333
API Gravity °API 61.5
Summary mass% vol%
n-Paraffins 25.645 27.043
Iso-Paraffins 29.177 30.285
Naphthenes 44.897 42.437
Aromatics 0.282 0.236
Olefins <0.010 <0.010
Unidentified <0.010 <0.010
DHA CALCULATED PROPERTIES**Average Molecular Weight :
Relative Density:
Octane Number:
**Calculated DHA properties are indicative only and are not
meant to replace values derived by relevant physical testing methods
(6) LPG density is estimated and for indicative purpose only.
Unable to perform actual analysis due to insuficient amount of fraction.
105.0
Yield 0.1
0.1
4.0
ISO8973
C5-70C
Yield
D4052
55.1
Yield 22.9
25.2
0.7259
MUTINEER EXETER CRUDE OIL
2014-PTAD-000139
70-140C
D4052
68.3
0.6494
79.3
4.9
LPG (C1-C5)
Santos Mutineer Exeter Crude oil 2014-PTAD-000139 - Final Report.xls Page 4 of 11
Santos Mutineer Exeter Crude oil 2014-PTAD-000139 - Final Report.xls Page 5 of 11
0.0
20.0
40.0
60.0
80.0
100.0
120.0
140.0
160.0
180.0
200.0
220.0
240.0
260.0
280.0
300.0
320.0
340.0
360.0
380.0
0.0 10.0 20.0 30.0 40.0 50.0 60.0 70.0 80.0 90.0 100.0
Te
mp
era
ture
, oC
Cumulative % Recovered
TRUE BOILING POINT CURVE MUTINEER EXETER CRUDE OIL
2014-PTAD-000139 NOVEMBER 2014
Vol%-TBP
Mass%-TBP
Santos Mutineer Exeter Crude oil 2014-PTAD-000139 - Final Report.xls Page 6 of 11
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0
90.0
100.0
110.0
120.0
0.0 10.0 20.0 30.0 40.0 50.0 60.0 70.0 80.0 90.0 100.0
AP
I G
ravit
y
Cumulative Middle % Volume
Graph of API vs Mid Volume
MUTINEER EXETER CRUDE OIL 2014-PTAD-000139 NOVEMBER 2014
Santos Mutineer Exeter Crude oil 2014-PTAD-000139 - Final Report.xls Page 7 of 11
0
20
40
60
80
100
120
140
160
180
200
220
240
260
280
300
320
340
360
380
400
420
440
460
480
500
520
540
560
580
600
620
640
660
680
700
720
740
760
0 10 20 30 40 50 60 70 80 90 100
Tem
pe
ratu
re, o
C
Cumulative % Recovered
Graph of True Boiling Point vs Simdis
MUTINEER EXETER CRUDE OIL 2014-PTAD-000139 NOVEMBER 2014
mass%-TBP
mass%-HT Simdis
Report ID
Crude ID
Client ID
Date
Test Method Unit
mass% 4.0 22.9
vol% (Note 1) 4.9 25.2
Density @15°C kg/L 0.6556 0.7331
Specific Gravity @60/60°F - 0.6558 0.7333
API Gravity °API 84.3 61.5
Copper Strip Corrosion, 3H @ 50°C ASTM D130 - 1A
RON (Note 4) Calc - 68.3 55.1
Sulphur - Mercaptan UOP 163 wt ppm 1 <1
Sulphur - Total ASTM D5453 wt ppm 6.8 <1.0
NOTES:
(1) Volumes are expressed as per ASTM D2892 which stipulates volumetric expansion
normalisation among fractions boiling below 150°C in proportion to their yields.
(4) Calculated DHA properties are indicative only and are not meant to replace
values derived by relevant physical testing methods.
ASTM D4052
2014-PTAD-000139
MUTINEER EXETER CRUDE OIL
Santos Limited
08-January-2015
Properties of Naphtha
Fractional Distillation ASTM D2892
70
-14
0C
C5
-70
C
NAPHTHA
Santos Mutineer Exeter Crude oil 2014-PTAD-000139 - Final Report.xls Page 8 of 11
Report ID
Crude ID
Client ID
Date
Test Method Unitmass% 26.2
vol% (Note 1) 27.0
Density @15°C kg/L 0.7879
Specific Gravity @60/60°F - 0.7883
API Gravity °API 48.0
Aromatics - FIA ASTM D1319 %volume 7.5
Aniline Point ASTM D611 °C 61.15
Aniline Gravity Product ASTM D611, Calc - 6819
Colour Saybolt ASTM D6045 - +30
Copper Strip Corrosion, 2H @ 100°C ASTM D130 - 1A
Freeze Point ASTM D2386 °C -58.5
Kinematic viscosity @ -20°C 3.130
Kinematic viscosity @ 20°C 1.435
Kinematic viscosity @ 40°C 1.084
Naphthalenes ASTM D1840 %volume 0.14
Smoke Point ASTM D1322 mm 29.5
Sulphur - Mercaptan UOP 163 wt ppm 1
Sulphur - Total ASTM D5453 wt ppm 17
Total Acid Number ASTM D664 mg KOH/g <0.10
Notes:
(1) Volumes are expressed as per ASTM D2892 which stipulates volumetric expansion
normalisation among fractions boiling below 150°C in proportion to their yields.
Properties of Kerosene
2014-PTAD-000139
MUTINEER EXETER CRUDE OIL
Santos Limited
Kerosene
cSt
14
0-2
30
C08-January-2015
Fractional Distillation ASTM D2892
ASTM D4052
ASTM D445
Santos Mutineer Exeter Crude oil 2014-PTAD-000139 - Final Report.xls Page 9 of 11
Report ID
Crude ID
Client ID
Date
Test Method Unitmass% 32.7
vol% (note 1) 30.6
Density @15°C kg/L 0.8663
Specific Gravity @60/60°F - 0.8668
API Gravity °API 31.7
Copper Strip Corrosion, 3H @ 50°C ASTM D130 - 1A
Cetane Index ASTM D4737(proc. A) - 47.0
Cloud Point ASTM D2500 °C -13
Colour - ASTM ASTM D6045 - <0.5
Kinematic viscosity @ 20°C 6.317
Kinematic viscosity @ 40°C 3.761
Kinematic viscosity @ 50°C 3.045
Pour Point ASTM D97 °C -12
Sulphur - Total ASTM D5453 wt ppm 273
Notes:
(1) Volumes are expressed as per ASTM D2892 which stipulates volumetric expansion
normalisation among fractions boiling below 150°C in proportion to their yields.
Test - LV% Method Unit 230-360C
Distillation - IBP 249.5
Distillation - 5% 258.6
Distillation - 10% 261.0
Distillation - 20% 264.9
Distillation - 30% 269.1
Distillation - 40% 274.1
Distillation - 50% 280.4
Distillation - 60% 287.7
Distillation - 70% 296.8
Distillation - 80% 307.7
Distillation - 90% 320.4
Distillation - 95% 329.6
Distillation - FBP 333.7
Distillation - Recovery 98.2
Distillation - Residue 1.4
Distillation - Loss 0.4
Fractional Distillation ASTM D2892
MUTINEER EXETER CRUDE OIL
Santos Limited
08-January-2015
Properties of Gas Oil
Gas Oil
230 -
360C
ASTM D86
°C
%volume
ASTM D445 cSt
ASTM D4052
2014-PTAD-000139
Santos Mutineer Exeter Crude oil 2014-PTAD-000139 - Final Report.xls Page 10 of 11
Report ID
Crude IDClient IDDate
Test Method Unitmass% 14.1
vol% (note 1) 12.3
Density @15°C kg/L 0.9297
Specific Gravity @60/60°F - 0.9303
API Gravity °API 20.6
Aniline Point ASTM D611 °C
Aniline Gravity Product ASTM D611, Calc -
Ash ASTM D482 %mass 0.012
Asphaltenes IP143 %mass 1.3
Carbon Residue - Micro ASTM D4530 %mass 5.9
Kinematic Viscosity @ 50°C ASTM D445 cSt 66.80
Metal - Nickel 1
Metal - Copper <1
Metal - Iron 1
Metal - Sodium 3
Metal - Vanadium <1
Nitrogen - Basic UOP269 wt ppm 355
Nitrogen - Total ASTM D4629 wt ppm 787
Pour Point ASTM D97 °C +33
Sulphur - Total IP336 %mass 0.17
Total Acid Number ASTM D664 mg KOH/g 0.46
Wax Content UOP46 %mass 18.2
NOTES:
(1) Volumes are expressed as per ASTM D2892 which stipulates volumetric expansion
normalisation among fractions boiling below 150°C in proportion to their yields.
(2) Aniline point not possible on residue as sample matrix outside of instrument's scope.
Properties of Residue
2014-PTAD-000139
MUTINEER EXETER CRUDE OIL
Santos Limited
Residue
ICPES wt ppm
36
0C
+
Note 2
Fractional Distillation ASTM D2892
IP 365
08-January-2015
Santos Mutineer Exeter Crude oil 2014-PTAD-000139 - Final Report.xls Page 11 of 11
Detailed Hydrocarbon Analysis
CRUDE ID:
REPORT ID:
Boiling Range °C
mass%
vol %
Component mass% vol%
ethane 0.076 0.146
propane 1.018 1.320
n-butane 3.297 3.699
2,2-dimethylpropane 0.219 0.241
i-pentane 12.854 13.471
n-pentane 17.862 18.522
2,2-dimethylbutane 1.491 1.491
cyclopentane 0.351 0.306
2,3-dimethylbutane 2.769 2.717
2-methylpentane 16.485 16.391
3-methylpentane 9.093 8.889
n-hexane 23.978 23.613
2,2-dimethylpentane 0.409 0.394
methylcyclopentane 5.283 4.582
2,4-dimethylpentane 0.597 0.576
2,2,3-trimethylbutane 0.096 0.091
3,3-dimethylpentane 0.066 0.062
cyclohexane 2.814 2.347
2-methylhexane 0.394 0.377
2,3-dimethylpentane 0.122 0.114
1,1-dimethylcyclopentane 0.097 0.084
3-methylhexane 0.231 0.218
1c,3-dimethylcyclopentane 0.109 0.095
1t,3-dimethylcyclopentane 0.075 0.065
1t,2-dimethylcyclopentane 0.109 0.095
n-heptane 0.060 0.057
methylcyclohexane 0.046 0.039
MUTINEER EXETER CRUDE OIL
2014-PTAD-000139
C5-70C4.0
Yield4.9
Santos Mutineer Exeter Crude oil 2014-PTAD-000139 - Final Report.xls appendix i
CRUDE ID:
REPORT ID:
Boiling Range °C
mass%
vol %
Class Summary mass% vol%
n-Paraffins 46.290 47.356
Iso-Paraffins 44.826 45.032
Naphthenes 8.884 7.612
Aromatics <0.010 <0.010
Olefins <0.010 <0.010
Unidentified <0.010 <0.010
DHA CALCULATED PROPERTIES**
Average Molecular Weight :
Relative Density:
Octane Number:
**Calculated DHA properties are indicative only and are not meant to replace values derived by
relevant physical testing methods
C5-70C
68.3
Yield
79.3
0.6494
2014-PTAD-000139
4.0
4.9
MUTINEER EXETER CRUDE OIL
Santos Mutineer Exeter Crude oil 2014-PTAD-000139 - Final Report.xls appendix i
Detailed Hydrocarbon Analysis (continued)
Boiling Range C5-70C
CRUDE ID: Yield, mass% 4.0
REPORT ID: Yield, vol % 4.9
Totals by Group Type & Carbon Number (in Mass Percent)
n-Paraffins: I-paraffins: Olefins: Naphthenes: Aromatics: Total:
C1:
C2: 0.076 0.000 0.000 0.000 0.000 0.076
C3: 1.018 0.000 0.000 0.000 0.000 1.018
C4: 3.297 0.000 0.000 0.000 0.000 3.297
C5: 17.862 13.073 0.000 0.351 0.000 31.285
C6: 23.978 29.838 0.000 8.097 0.000 61.913
C7: 0.060 1.915 0.000 0.437 0.000 2.411
C8:
C9:
C10:
C11:
C12:
Total : 46.290 44.826 0.000 8.884 0.000 100.000
Oxygenates: Total Heavies: Total Unknowns: Grand Total:
0.000 0.000 0.000 100.000
Totals by Group Type & Carbon Number (in Volume Percent)
n-Paraffins: I-paraffins: Olefins: Naphthenes: Aromatics: Total:
C1:
C2: 0.146 0.000 0.000 0.000 0.000 0.146
C3: 1.320 0.000 0.000 0.000 0.000 1.320
C4: 3.698 0.000 0.000 0.000 0.000 3.698
C5: 18.522 13.712 0.000 0.306 0.000 32.539
C6: 23.613 29.488 0.000 6.930 0.000 60.031
C7: 0.057 1.832 0.000 0.377 0.000 2.266
C8:
C9:
C10:
C11:
C12:
Total : 47.356 45.032 0.000 7.612 0.000 100.000
Oxygenates: Total Heavies: Total Unknowns: Grand Total:
0.000 0.000 0.000 100.000
2014-PTAD-000139
MUTINEER EXETER CRUDE OIL
Santos Mutineer Exeter Crude oil 2014-PTAD-000139 - Final Report.xls appendix i
Detailed Hydrocarbon Analysis
CRUDE ID:
REPORT ID:
Boiling Range °C
mass%
vol %
Component mass% vol%
i-pentane 0.089 0.104
n-pentane 0.206 0.239
2,2-dimethylbutane 0.048 0.054
2,3-dimethylbutane 0.163 0.178
2-methylpentane 1.059 1.177
3-methylpentane 0.795 0.869
n-hexane 3.448 3.796
2,2-dimethylpentane 0.251 0.270
methylcyclopentane 1.257 1.219
2,4-dimethylpentane 0.467 0.504
2,2,3-trimethylbutane 0.085 0.089
3,3-dimethylpentane 0.182 0.190
cyclohexane 2.380 2.219
2-methylhexane 3.458 3.699
2,3-dimethylpentane 0.946 0.988
1,1-dimethylcyclopentane 0.453 0.436
3-methylhexane 3.570 3.772
1c,3-dimethylcyclopentane 1.220 1.189
1t,3-dimethylcyclopentane 1.125 1.091
3-ethylpentane 0.257 0.267
1t,2-dimethylcyclopentane 1.761 1.701
n-heptane 10.672 11.330
methylcyclohexane 17.840 16.831
1,1,3-trimethylcyclopentane 0.805 0.781
ethylcyclopentane 0.907 0.859
2,5-dimethylhexane 0.562 0.589
2,4-dimethylhexane 0.665 0.689
1c,2t,4-trimethylcyclopentane 0.766 0.728
3,3-dimethylhexane 0.206 0.211
1t,2c,3-trimethylcyclopentane 0.630 0.593
2,3,4-trimethylpentane 0.042 0.043
2,3,3-trimethylpentane 0.048 0.048
toluene 0.053 0.045
2,3-dimethylhexane 0.669 0.682
2-methyl-3-ethylpentane 0.117 0.120
2-methylheptane 3.191 3.319
Yield22.9
25.2
MUTINEER EXETER CRUDE OIL
2014-PTAD-000139
70 - 140C
Santos Mutineer Exeter Crude oil 2014-PTAD-000139 - Final Report.xls appendix ii
Detailed Hydrocarbon Analysis (continued)
CRUDE ID:
REPORT ID:
Boiling Range °C
mass%
vol %
Component mass% vol%
4-methylheptane 1.270 1.308
3,4-dimethylhexane 0.133 0.134
1c,2c,4-trimethylcyclopentane 0.051 0.048
1c,3-dimethylcyclohexane 0.049 0.047
3-methylheptane 2.516 2.587
1c,2t,3-trimethylcyclopentane 6.525 6.148
3-ethylhexane 2.593 2.638
1,1-dimethylcyclohexane 0.700 0.651
2,2,5-trimethylhexane 0.057 0.058
3c-ethylmethylcyclopentane 0.362 0.343
3t-ethylmethylcyclopentane 0.323 0.306
2t-ethylmethylcyclopentane 0.574 0.542
1,1-methylethylcyclopentane 0.098 0.091
2,2,4-trimethylhexane 2.384 2.341
n-octane 10.486 10.836
2,4,4-trimethylhexane 0.139 0.136
N1 0.137 0.127
1c,2-dimethylcyclohexane 0.357 0.326
2,3,5-trimethylhexane 0.334 0.336
1,1,4-trimethylcyclohexane 4.142 3.894
2,4-dimethylheptane 0.491 0.498
ethylcyclohexane 0.510 0.472
*1c,3c,5-trimethylcyclohexane 0.162 0.153
3,3-dimethylheptane 0.531 0.531
3,5-dimethylheptane 0.199 0.200
1,1,3-trimethylcyclohexane 0.110 0.101
ethylbenzene 0.090 0.075
Ethybenzene 2 0.036 0.030
1c,2t,4t-trimethylcyclohexane 0.368 0.342
I3 0.112 0.111
1,3-dimethylbenzene 0.103 0.086
3,4-dimethylheptane* 0.301 0.299
N14 0.159 0.148
4-ethylheptane 0.085 0.086
1c,2t,3-trimethylcyclohexane 0.482 0.462
3-ethylheptane 0.588 0.588
Yield22.9
25.2
MUTINEER EXETER CRUDE OIL
2014-PTAD-000139
70 - 140C
Santos Mutineer Exeter Crude oil 2014-PTAD-000139 - Final Report.xls appendix ii
Detailed Hydrocarbon Analysis (continued)
CRUDE ID:
REPORT ID:
Boiling Range °C
mass%
vol %
Component mass% vol%
1c,2t,4c-trimethylcyclohexane 0.122 0.114
1,1,2-trimethylcyclohexane 0.524 0.475
I8 0.396 0.394
I9 0.132 0.131
n-nonane 0.833 0.843
2,6-dimethyloctane 0.050 0.050
Boiling Range °C
mass%
vol %
Class Summary mass% vol%
n-Paraffins 25.645 27.043
Iso-Paraffins 29.177 30.285
Naphthenes 44.897 42.437
Aromatics 0.282 0.236
Olefins <0.010 <0.010
Unidentified <0.010 <0.010
DHA CALCULATED PROPERTIES**
Average Molecular Weight :
Relative Density:
Octane Number:
70 - 140C
**Calculated DHA properties are indicative only and are not meant to replace values derived by
relevant physical testing methods
Yield22.9
25.2
105.0
0.7259
70 - 140CYield
22.9
25.2
55.1
MUTINEER EXETER CRUDE OIL
2014-PTAD-000139
Santos Mutineer Exeter Crude oil 2014-PTAD-000139 - Final Report.xls appendix ii
Boiling Range 70 - 140C
CRUDE ID: Yield, mass% 22.9
REPORT ID: Yield, vol % 25.2
Totals by Group Type & Carbon Number (in Mass Percent)
n-Paraffins: I-paraffins: Olefins: Naphthenes: Aromatics: Total:
C1:
C2:
C3:
C4:
C5: 0.206 0.089 0.000 0.000 0.000 0.295
C6: 3.448 2.064 0.000 3.637 0.000 9.149
C7: 10.671 9.215 0.000 23.306 0.053 43.246
C8: 10.486 12.012 0.000 11.886 0.228 34.613
C9: 0.833 5.747 0.000 6.068 0.000 12.648
C10: 0.000 0.050 0.000 0.000 0.000 0.050
C11:
C12:
Total : 25.645 29.177 0.000 44.897 0.282 100.000
Oxygenates: Total Heavies: Total Unknowns: Grand Total:
0.000 0.000 0.000 100.000
Totals by Group Type & Carbon Number (in Volume Percent)
n-Paraffins: I-paraffins: Olefins: Naphthenes: Aromatics: Total:
C1:
C2:
C3:
C4:
C5: 0.239 0.104 0.000 0.000 0.000 0.343
C6: 3.796 2.277 0.000 3.438 0.000 9.511
C7: 11.330 9.779 0.000 22.107 0.045 43.261
C8: 10.836 12.367 0.000 11.203 0.191 34.596
C9: 0.843 5.708 0.000 5.689 0.000 12.240
C10: 0.000 0.049 0.000 0.000 0.000 0.049
C11:
C12:
Total : 27.043 30.285 0.000 42.437 0.236 100.000
Oxygenates: Total Heavies: Total Unknowns: Grand Total:
0.000 0.000 0.000 100.000
2014-PTAD-000139
MUTINEER EXETER CRUDE OIL
Santos Mutineer Exeter Crude oil 2014-PTAD-000139 - Final Report.xls appendix ii