nanotechnology for energy: fundamentals and applications
DESCRIPTION
Keith Johnston Research Group (5.414) Nanotechnology/Colloid Science/Interfaces [email protected]. Nanotechnology for Energy: Fundamentals and Applications Nanotechnology for CO 2 Sequestration and EOR (Bryant, Huh, Hirosaki , Milner, Nguyen, Prodanovic ) - PowerPoint PPT PresentationTRANSCRIPT
Keith Johnston Research Group (5.414)Nanotechnology/Colloid Science/Interfaces
[email protected] for Energy: Fundamentals and Applications
– Nanotechnology for CO2 Sequestration and EOR(Bryant, Huh, Hirosaki, Milner, Nguyen, Prodanovic)
• Nanoparticle adsorption and transport in porous med.• Electromagnetic imaging• Emulsions/foams for mobility control
– Nanomaterials for electrocatalysis(Stevenson)
• Catalysis- fuel cells, batteries• CO2 reduction to fuels
Pharmaceutical Imaging and Therapeutics– Magnetic/optical/therapeutic nanoparticles -cancer and atherosclerosis(Sokolov, Milner, Feldman (UTHSCSA), Emelianov, Zhang)– Protein drug delivery (subcutaneous delivery)(Jennifer Maynard, Tom Truskett)
Potent and Biodegradable Nanoclusters for Imaging/Therapy(Inorganic: Sokolov, Emelianov, Milner Proteins: Maynard, Truskett)
UT Southwestern, UTHSCSA, M.D. Anderson
Sub-5 nm gold particles
Clustering of gold nanoparticles
mediated by weakly adsorbing polymer
PLA-b-PEG-b-PLA
Gold nanoparticle bound together by
polymerSub-5 nm gold particles
Clustering of gold nanoparticles
mediated by weakly adsorbing polymer
PLA-b-PEG-b-PLA
Gold nanoparticle bound together by
polymer
Capsid dsRNA virus, PNAS, 106 (09)
Bryant, Huh, Nguyen (Petroleum, Geosyst.)Milner (BME), Bielawski (polymer org. chemist)
Polymer coatings: interfacial properties
CO2 sequestration and EORImage reservoirsElectrocatalysis: interactions with support
Nanoparticles at interfaces in porous media: nanomaterials synthesis, colloid/interface science with polymer science
q qwater
CO2
CO2
water
CO2
water
DOE Frontiers of Subsurface Energy Security (UT-Sandia)
v dWv dWS te ric
S te ric
Stable protein dispersions for protein drug delivery
4
0.00 100.00 200.00 300.00 400.000.00
20.00
40.00
60.00
80.00
100.00
120.00 mAb 220 mg/mLmAb 200 mg/mLmAb 150 mg/mL
0 0.1 0.2 0.3 0.4 0.5 0.60
0.05
0.1
0.15
0.2
0.25
0.3
0.35 20.4280683564.6581768120.0765141183.2172019239.1922003312.2682155380.0618024444.2031469
φC
φP
GEL PHASE
Colloid science
Protein processing/characteriz.
Fundamental protein interactions/stability
Nanomaterials for electrocatalysis (Fuel cells/rechargeable batteries, CO2 reduction) (Stevenson)
Amorphous alloy shell over corrugated crystalline alloy coreLow coordination sites and strain from wetting for high activity
(100)
(111)
0 400 800 1200 16000.0
0.2
0.4
0.6
0.8
1.0
1.2
Pot
entia
l [V
]
Current Density [mA/cm2]
0.0
0.1
0.2
0.3
0.4
0.5 Pt Pd
3Pt
2
Pow
er Density [W
/cm2]
O2 + 4H+ +4e- = 2H2O
Destination of PhD Students• Dixon S. Dakota
S. Mines • Gupta Auburn• Balbuena Texas A + M• Meredith Ga. Tech.• Yates U. Rochester• Da Rocha Wayne State U.• Lee U. S. California• Ziegler U. Florida• Lu Nat. Univ.
Singapore
• Young Dow • Psathas Schering-Plough• Rogers Dow • Sirard Lam Research• Shah Pfizer• Pham Sematech• Chen Abbott• DicksonExxon-Mobil• Smith Exxon-Mobil• Overhoff Schering-Plough• Engstrom Bristol-Meyers-
Squibb• Matteucci Dow• Gupta Exxon-Mobil• Tam Bristol-Meyers-
Squibb• Patel Lam Research• Ma Dupont• Miller Medimmune