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Narayana IIT Academy INDIA
Sec: Sr. IIT_IZ JEE-MAIN Date: 27-01-18 Time: 07:30 AM to 10:30 AM GTM-4 Max.Marks: 360
KEY SHEET
PHYSICS
1 1 2 2 3 3 4 2 5 4 6 3
7 4 8 4 9 3 10 3 11 2 12 3
13 4 14 2 15 2 16 2 17 2 18 4
19 1 20 3 21 2 22 2 23 2 24 3
25 1 26 2 27 3 28 4 29 1 30 4
CHEMISTRY
31 2 32 4 33 2 34 3 35 3 36 1
37 3 38 4 39 2 40 1 41 3 42 1
43 4 44 4 45 4 46 4 47 2 48 3
49 3 50 3 51 4 52 1 53 1 54 4
55 3 56 4 57 1 58 2 59 2 60 3
MATHS
61 4 62 3 63 1 64 1 65 2 66 1
67 3 68 3 69 4 70 2 71 2 72 1
73 2 74 2 75 3 76 4 77 4 78 2
79 1 80 2 81 1 82 4 83 3 84 2
85 3 86 2 87 2 88 4 89 3 90 1
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SOLUTIONS PHYSICS
1. At any instant let be the angle made by v with u and let they meet after line T
0
cos T
v dt uT and 0
cos T
v u dt l 0 0
cos T T
v dt u dt l 0
cos T
vT u dt l
uTvT u lv
2 2
2 2
v u lvT l Tv v u
2. 10 VSD=9MSD=9mm.
Least count =1MSD-1VSD=0.1mm.
Zero error= 0.1 10 8 0.2 mm.
Thickness= Main scale reading +L.CV.C+error.
i.e, Thickness=12 0.1 3 0.2 12.5mm
3.
4. The initial extension of spring is 0mgxk
. Just after collision of B and A the speed of
combined mass is 2v
( |2mv m v ). For spring to just attain natural length the combined mass must rise up
by 0mgxk
(see figure) and come to rest. Now applying conservation of energy
2
20 0
1 12 22 2 2
vm k x m gx
and 0mgxk
.
Narayana IIT Academy 27-01-18_Sr.IIT_IZ_Ph-I_JEE-MAIN_GTM-4_Key&Sol’s
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So get 6mv gk
.
5.
1) As mutual repulsive force between the particles is internal for the system and as there
is no other external force on the system ,linear momentum of the system is conserved in
any direction
2) As the forces on the particles due to one on the other are equal in magnitude,
opposite in direction and act along the line joining them always, net torque on the
system due to these forces about any point in space is zero. therefore angular
momentum of the system remains constant about any point in space
3) As center of mass of the system lies on the line joining the particles always and force
on any of them is passing through C.M always, torque due to this force on any particle
about C.M is zero. Hence angular momentum of any particle about C.M is conserved
individually.
4) About any other point except C.M, torque on any individual particle is not zero.
Hence angular momenta of individual particles change but total angular momentum of
the system remains constant.
6.
7. 0cos2L v and sin
2L v 0 tanv v
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8. From conservation of angular momentum of the mass about the centre of the black
hole, 0mv R mva and from conservation of energy 2 20
1 12 2
GMmmv mva
.
9.
sinF mg tanmg ( is small) . i.e, F 2
40dy xmg mgdx
2xa 1
2
10.
2g
g5g 2g
P0
5effg g . Therefore pressure at centre= 0 5P Rg 11. If is temperature of the body at any instant and 0 temperature of surroundings, from
Newton’s law of Cooling 30 04eAd
dt ms
. i ,e At any temperature 1ddt m as
, , , se A are same for both.
As area is same for both mass of cube is less than that of sphere. Slope of the curve
at any for cube is greater than that of sphere
12. At triple point substance exits is three states in equilibrium
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Keeping pressure constant if temperature is increased substance will be in vapour state
and if temperature is decreased substance will be solid state. Keeping temperature
constant if pressure increased substance will be in liquid state and pressure decreased
substance will be vapour state .
13. Internal energy 52
U nRT and PV nRT
52
U PV U P 1
2
1
2
i
i
U PU P
( V is
same for both) . As final pressures are equal 1 2f fU U
14. Let the wave equation is siny A t kx .
At the given instant particle at 0.09x m is moving towards mean position from
positive extreme.
i.e , 1 33 4sin sin 0.5894
t kx t kx
rad. its phase is 0.589 rad .
At the given instant particle at 0x is at mean position and is moving towards positive
extreme.
its phase is 0 or 2 rad or 4 rad etc. As wave is moving along positive x-direction
its phase is more than that at 0.09x m and as these are within one wave length range
phase of particle 0x should be 2 rad.
Phase difference between the particles 2 0.589 0.589 3.729 rad
3.7290.09
k x k . Wave velocity 12 6.28 0.04 3.793.729 0.09
Tv msk k
15. dVEdx
16. Potential at any point inside the shell=potential at any point on the surface
potential at A=potential at C due to ‘q’ and induced charges =
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0 0 0 0
1 1 1 14 4 4 4
q q q qr R R r
17. When the switches open charges on differtent plates are as shown
When all the switches are closed the two capacitors will be in parallel and net charge
on the isolated plates B and C together (-100+40=-60 c )is shared by them in the the
ratio of their capacities
final charges on different plates are as shown
80 C flows through s1 fromplate A to ground, 80 C charge flows through s2 from plate
C to B and 80 C charge flows through s3 from ground to plate D.
18. 0E DV V (as they are earthed )
2 , 10 2 12 , 12 6 6B C AV V V V V V
Current through 2 22
A BV V A
Current through 3 43
C DV V A
From Kirchhoff’s junction rule we can show that current through wire DE=0
19. Electric field is induced and is the form of concentric circles about centre of cylindrical
region.
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2 22 2 2
d dB r dB rE r r r Edt dt dt
. Consider a small path length dl along
path AB at distance r from the centre
tan 30 ABL
. cos2r Lde E dl Edl dl
r
2
2 2 2 3 2 3ABL L L L Le de dl AB
20. When the right wire starts moving, due to motional emf developed in it anti clock wise
current flows in the frame, due to this there is mutual attraction between the wires and
due to this the wires attain common velocity after some times. When they attain
common velocity there will be no net emf hence no current flow, hence wires continue
to move with the common velocity
00 2
2vmv mv v = common velocity. Loss in
22 200 0
1 1 122 2 2 4
vkE mv m mv
21. 0 0 0NiB niL
22. For permanent magnet we prefer a material with high retentivity (so as to make a
stronger magnet) and high coercivity (so that magnetization any not be wiped out
easily). For electromagnet we prefer high saturated magnetism low coercivity and least
possible area of hysteresis loop so that electromagnet develops high magnetization, is
easily demagnetized and energy loss in a magnetization cycle is least. Therefore, P is
suitable for making permanent magnets and Q for making electromagnets.
23. 0 sincJ E t kx and 0 0E
d
d dEi Adt dt
0 0 cosAE t kx
dJ 0 0 cosE t kx 0
c
d
JJ
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24. Replacing it with string block system
Let at initial position 2F force is a applied then
W.E.T. from A to B
0S FW W
3FXK
Net elongation in spring max3 3F Q CEK
25. 0
0
1e
v Dmu f
0 0
0 0
25 2525 15 6
v vu u
For eye lens 1 1 1 1 1 1 1 6 25 25 5 25 6e
e e e e e
u cmv u f u u
059146ev u and 0
06 5925 25vu cm .
For objective 00 0 0 0
1 1 1 6 25 1 59 59 59 31
f cmv u f f
.
26.
Due to total internal reflection light comes out through a cone of semi vertex angle
which is equal to critical angle. Total light energy is distributed over 4 solid angle.
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Solid angle made by cone at source 2 1 cos . 5 sin 14
053 .
02 1 cos53 1 2 14 2 5 5T
PP
27. For 1st minimum sin sin 30b b ……(1)
For 1st secondary maximum 3sin2
b ……..(2)
1 sin 30 sin 3 432 sin
2
1sin 3 4
28. Charge is conserved. In order to fully convert an electron into energy, a positron (the
electron’s antiparticle must be involved). That is, electron+positron energy , Not
electron positron+energy
29. For excitation with least KE of colliding particle the collision should be perfectly in
elastic and all the loss in KE is to be used for excitation.
0 ( ) mumu M M m v vM m
where v=common velocity after collision .
maximum loss in KE is
2 22 2
2
1 1 1( )2 2 2
m u M MK mu M m mu K KM m M mM m
4. 10.2 10.2 4 63.75
4 1i e K K eV
30. .y A B B CHEMISTRY
31. NCERT-XI, VOL-II, PAGE NO : 403, 404
32. NCERT-XII, VOL-II, PAGE NO : 452, 453
33. NCERT-XII, VOL-I, PAGE NO : 229
34. Cis - 3 24Co NH Cl - violet and trans- 3 24
Co NH Cl - green
35.
Ionization energy (in Kj/mol)
H 1312
2H 1488
N 1402
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2N 1503
O 1314
2O 1175
F 1681
2F 1515
If energy of electrons in HOMO of molecule is higher than energy of last election
in its atom then ionization energy of molecule will be less than its atom
36. NCERT-XII, VOL-I, PAGE NO : 203
37. NCERT-XII, VOL-I, PAGE NO : 250,251,252,254
In a group pairing energy of 3d elements greater than that of 4d and 5d series elements
because 3d-oribital is more compact ( small size) than 4d-and 5d
38. NCERT-XII, VOL-I, PAGE NO : 196
39. NCERT-XI, VOL-II, PAGE NO : 310
40. From Si to P to S to Cl, P d bond strength with oxygen increases due to decrease in
size(or energy) difference of 3d of central atom and 2p of oxygen. As a result
polymerization tendency decreases.
41. NCERT-XII, VOL-I, PAGE NO : 155
42. Weak base and strong nuclophiles like I and RS give best yield for substitution than
elimination
43. -I,+M groups 3 2 2 3 2 6 5, , , , , , ,OH OR OCOCH NH NR NHCOCH CH CH C H activates
– O and –p positions due to +M effect but deactivates m-position due to –I effect, But
+I –groups like alkyl groups activates all –O, m and –p positions.
44.
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45. Sucrose is non-reducing sugar, polysaccharides are non-reducing non-sugar
46.
2 4
2
,Conc H SO
E
eH H
Less stable alkenes rearrange to more stable alkene by acid calatyst but not by
base .
47. Molecule which is non superinposable on its mirror image is chiral molecule.
Structures I, II and IV are nonsuperinposable on their mirror images. But compound
one is optically inactive because its enantiomers are inter convertable ( conformers)
compound two is optically inactive due to pyramidal inversion .
48. NCERT-XII, VOL-II, PAGE NO : 129,130
49. NCERT-XII, PRACTICAL MANUAL , PAGE NO : 90
Compounds Phthalein dye test
OH3CH
Red
OH
3CH
Bluish purple
OH
3CH
No colour
OH
OH
Blue but takes longer time to
appear
OH
OH
Green fluorescent colour of
fluorescein
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Take 0.1g of organic compound and 0.1g of phthalic anhydride in a clean dry test tube
and add 1-2 drops of 2 4.Canc H SO heat the test tube for about 1 min in oil bath. Cool and
pour the reaction mixture carefully into a beaker containing 15 ml of dil. NaOH .
Appearance of pink, blue, green, red etc. Colour indicates the presence of phenol –OH
group in the compound
50. 0E
A B AG VdP , area of ABCA and CDEC are equal
51. In case of acetones at any concentration of it slow step is nucleophilic attack of
carbanion at carbonyl carbon because ketones are less reactive in nucleophilic addition
52. Number of milli moles of 3 50 0.1 5AgNO
Number of milli moles of 50 0.2 10NaCl
3 3
5 10 0 05 5 0 10 5 5 5 5
AgNO NaCl AgCl NaNO
25 /100 5 10Cl M
sAgCl Ag Cl
10 210 5 10Ag
92 10Ag M
53. NCERT-XI, VOL-I, PAGE NO : 48
54. NCERT-XI, VOL-I, PAGE NO : 150
55. I, II, III, IV
56. 22 4
0 0 01 , 1 , 2 2Na K C O
X X Y Y Z Z
2 4
0 02 42 , 2 / 2NaKC O X Y Z NaKC O X Y Z
57.
Number of atoms per unit cell= 1 1 2 14 4 1 1 1 26 12 3 3
X
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58. For inilial solution 0.53Tb
10000.53 0.5360 1060w
w
60ureaw g
For final solution left 2.12Tb
60 10002.12 0.5360 x
250x g
Weight of water vaporized =1000-250=750g
59. NCERT-XII, VOL-I, PAGE NO : 143
60. NCERT-XII, VOL-I, PAGE NO : 100, 102, 104
MATHS 61. (4) Since , are the roots of the equation
2x px q 0
p and a q.
Now, 1/4 1/4 4 1/4 1/4 2 2( ) [( ) ]
1/2 1/2 1/4 2[ 2( ) ]
2
1/42 2( )
2
1/4p 2 q 2(q)
1/4p 6 q 4q p 2 q
1/4
1/4 1/4 1/4p 6 q 4q p 2 q
62. (3)
The total numbers of factors of xnyz…. is equal to the number of ways of selecting one
or more out of n identical quantities of one type and remaining m distinct quantities.
Hence, the required numbers of factors = (n + 1)2m
63. (1) F(x) is defined for
2[x] [x] 6 0 ([x] 3)([x] 2) 0
[x] 2 or [x] 3
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But [x] 2 [x] 3, 4, 5,......
x 2
Domain of f ( , 2) [4, )
64. (1) Let the roots of the given equation be 1 + ip and 1 – ip, where p R
product of roots
2(1 ip)(1 ip) 1 p 1, p R
(1, )
65. (2) Given condition 2 2A B (A B)(A B)
2 2 2 2A B A AB BA B
AB BA .
66. (1) Since 1 1 1 2 2 2a b c , a b c and 3 3 3a b c are divisible by k, therefore
1 1 1 1
2 2 2 2
3 3 3 3
100a 10b c n k100a 10b c n k100a 10b c n k
where n1, n2, n3 are integers.
Now 1 1 1
2 2 2
3 3 3
a b ca b ca b c
1 1 1 1 1
2 2 2 2 2
3 3 3 3 3
a b 100a 10b ca b 100a 10b ca b 100a 10b c
(Applying 3 3 2 1C C 10C 100C )
1 1 1
2 2 2
3 3 3
a b n ka b n ka b n k
= k 1 1 1
2 2 2 1
3 3 3
a b na b n ka b n
is divisible by k
(Since elements of 1 are integers, 1 is an integer)
67. (3) The four digits 3, 3, 5, 5 can be arranged at four even places in 4! 62!2!
ways and the
remaining digits viz., 2, 2, 8, 8, 8 can be arranged at the five odd places in 5! 102!3!
ways. Thus, the number of possible arrangements is (6) (10) = 60.
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68. (3) term independent of x will be 10 5 55C (sin ) (cos )
10
555
C sin (2 )2
So maximum value will be 10
55
C2
69. (4) Given: 4 4 4
1 1 1....1 2 3
4 4 4 4i 1
1 1 1 1 .....(2i 1) 1 3 5
4 4 4 4 4 4
1 1 1 1 1 1... ...1 2 3 4 2 4
4 4 4 4
1 1 1 1 ...2 1 2 3
1 1516 16
70. (2) A.M. > G.M.
1/3
x y z x y z/ 3 . .y z x y z x
x y z 3y z x
71. (2)
x y is an integer
x x 0 is an integer A is Reflexive
x y is an integer y x is an integer A is symmetric x y, y z are integers
As sum of two integers is an integer.
(x y) (y z) x z is an integer
A is transitive. Hence statement 1 is true.
Also x 1x is a rational number B is reflexive
xx is rational y
x need not be rational
i.e., 01
is rational 10
is not rational
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Hence B is not symmetric
B is not an equivalence relation.
72. (1) Let Ei denote the event that Ai dies in a year, then iP(E ) p and 'iP(E ) 1 p for I = 1,
2, …..n P (none of A1, A2, …. A3 dies in a year)
' ' ' ' ' ' n1 2 n 1 2 nP(E E E ) P(E )P(E )....P(E ) (1 p)
Because E1, E2,……En are independent.
Let E denote the event that at least one of 1 2 nA , A ,.......A dies in a year, then ' ' ' n1 2 nP(E) 1 P(E E .... E ) 1 (1 p)
Let F denote the event that A1 is the first to die, then 1P(F / E) .Also,n
P(F) = P(E).P(F/E)
= n1 1 (1 p)n
73 (2) Since, 1P(A B)3
1 1P(A B) 1 P(A B)3 3
2 2P(A B) P(A) P(B) P(A B)3 3
1 2p 2p2 3
74 (2)
2 23
4x 0 3 2 3
x z (z x)lim8xz 4x 8xz
3 2
4x 0 3 33 3
x 2zx xlimx 8z 4x 8z x
4/3 3 3
4 4x 0 4/3 3 3 3
x 2z x 2zlimx 8z 4x 8z 2 8z
23/3
12 .z
75. (3) In the neighbourhood of x = 0, f(x) = log 2 – sin x
g(x) = f(f(x)) = log2 – sin (f(x))
log 2 – sin(log 2 – sin x)
Since g(x) is differentiable at x = 0,
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g ' (x) = – cos(log2 – sinx) (–cosx)
g '(0) cos(log 2)
76. (4) 3 2f (x) x x f '(1) xf "(2) f "'(3)
2f '(x) 3x 2xf '(1) f "(2)
f "(x) 6x 2f '(1)
f "'(x) 6
Now, f '(1) 3 2f '(1) f "(2)
f "(2) f '(1) 3 0 (1)
Again f "(2) 12 2f '(1)
f "(2) 2f '(1) 12 0 (2)
Again f "'(3) 6 (3)
From (1) and (2)
2f "(2) f "(2) 6 0 f "(2) 2 (4)
(1) gives f '(1) 2 3 0
f '(1) 5
3 2f (x) x 5x 2x 6 (5)
f (0) 6
f (1) 1 5 2 6 4
f (2) 8 20 4 6 2
f (3) 27 45 6 6 6
f (0) f (2) 6 2 f (1)
(a) is false f (0) f (3) 6 6 0
f (1) f (3) (1 5 2 6) 6
2 f (2)
f (1) f (3) 2 f (0) [ f (0) 6]
(4) is false
77. (4) Let, 3f (x) x 3x a
2f '(x) 3x 3 3(x 1)(x 1)
Now, f (1) a 2,f ( 1) a 2
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The roots would be real and distinct if, f (1)f ( 1) 0
(a 2) (a 2) 0 or
2 a 2
Thus the given equation would have real and distinct roots if a ( 2, 2)
78. (2) Let n 1 n n 1 2
0 1 2 n 1 nx x x xf (x) a a a ... a a xn 1 n n 1 2
Then f(x) is continuous and differentiable in [0, 1], as it is a polynomial function of x.
Also, f(0) = 0
and 0 1 2 n 1n
a a a af (1) ... a 0n 1 n n 1 2
. (Given)
Hence, by Rolle’s theorem, there exists atleast one real number c (0,1) such that
f '(c) 0 i.e., c is a root of the equation n n 10 1 n 1 na x a x ... a x a 0
.
79. (1) 2
2 1
11 dxxI
1 1(x ) 1 tan xx x
Put 1x tx
80. (2) Let 1100
r 1 0
I f (r 1 x)dx
1 1 1 1
0 0 0 0
I f (x)dx f (x 1)dx f (2 x)dx ... f (99 x)dx
1 2 3 100
0 1 2 99
I f (x)dx f (x)dx f (x)dx ... f (x)dx
100
0
I f (x)dx a(given)
81. (1) We have, sin x x for x 0
sin(cos x) cos x for 0 < x < / 2
/2 /2
0 0
sin(cos x) dx cos x dx
3 2I I (1)
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Now, x cos x cos and x, 0,2
x sin x
cos x cos(sin x)
/2 /2
0 0
cos x dx cos(sin x)dx
3 1I I (2)
from (1) and (2) 1 3 2I I I
82. (4) 2 1 1 2 2 2a and ah . .2 2 33 3 3
abc (2)(1)(1)(3) 3R4 3(4) 2 2 2
83. (3) 2 42
11 cos cos .... 4 41 cos
2cos ec 4
2 21sin sin4 6
n6
85. (3) Given equation of lines 2 23y 4xy 3x 0
2 23y 3xy xy 3x 0
( 3y x)(y 3x) 0
xy , y 3x3
oAPO 75
In AMP, o AMsin 753
oAM 3sin 75
Now, length of chord of contact AB = 2AM
o o2(3sin 75 ) 6sin 75
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3 1 ( 3 1)6 32 2 2
86. (2) 2 2y 4b(x (a 2b)) or y 4bX where x (2a b) X
2 2x 4a(y (a 2b)) or x 4aY where y (a 2b) Y
For 2y 4bX, extremities of latus rectum (b, 2b) and (b, –2b) w.r.t. X-Y axis.
i.e., (2a, 2b) and (2a, – 2b)w.r.t. x-y axis.
For 2x 4aY, extremities of latus rectum (2a, – a)
and (–2a, –a) w.r.t. X-Y axis.
i.e., (2a, 2b) and (–2a, 2b)
hence the common end of latus rectum (2a, 2b)
Now for 1st parabola
dy2y 4bdx
1
dy 2b 1dx y
at (2a, 2b)
Also for 2nd parabola
dy dy x2x 4a ordx dx 2a
Hence parabolas intersect orthogonally at (2a, 2b)
87. (2) 2 2 29(x 3) 9(y 4) y
2 29(x 3) 8y 72y 144 0
2 29(x 3) 8(y 9y) 144 0
2
2 9 819(x 3) 8 y 144 02 4
2
2 99(x 3) 8 y 162 144 182
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2
98 y9(x 3) 2 1
18 18
2
9y(x 3) 2 192
4
2 2.4 1e 19 9
1e3
88. (4) 2 2y x 11 1
16 9
Locus will be the auxiliary circle
2 2 1x y16
89. (3) Range of 1 2f (x) tan (3x bx c) is 0,2
if and only if range of 2g(x) 3x bx c is
[0, ) . This is possible only when discriminate of the equation 23x bx c 0 is equal to
zero.
i.e. b2 = 12c
90. (1) Vector ˆ ˆ ˆ ˆ ˆ ˆ((3i 2j 4k) (4i 3j 4k)) is perpendicular to ˆ ˆ ˆ2i j mk .
3 2 14 3 4 02 1 m