ncsu [110] [001] [110] si gaas 2 nm. ncsu the world of atoms instructor: dr. gerd duscher http://...
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NCSUNCSU
[110]
[001]
[110]
SiSi
GaAsGaAs
2 nm2 nm
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NCSU
The World of Atoms
Instructor: Dr. Gerd Duscher http://www4.ncsu.edu/~gjdusche
email: [email protected]
Office: 2156 Burlington Nuclear Lab.
Office Hours: Tuesday: 10-12pm
NCSU
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NCSU
The World of Atoms
ObjectiveJohann Wolfgang von Goethe (1749-1832): Faust
Faust is searching for the first principles, for "that inner force which holds the world together," “was die Welt im Innersten zusammenhält”.
So do we, in this lecture
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NCSU
Atomic Structure
Bohr Model
that is too simple
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NCSU
Atomic Structure
pro
bab
ilit
y1
Bohr Model
Nucleus
distance
Wavemechanic Model
Nucleus
electrons
pro
bab
ilit
y
1
radial distanceEnergy
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NCSU
Some Links
Bonding :http://info.lu.farmingdale.edu/depts/met/met205/atomicbonds.html (pictures of different kinds of bonding)
Orbitals : http://web.mit.edu/3.091/www/orbs/ (computer simulation of electron positiond for certain orbitals)
Crystal Structure : http://web.mit.edu/3.091/www/cryst/(Pictures of several crystal structures)
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NCSU
• have discrete energy states• tend to occupy lowest available energy state.
3
Electrons...
Adapted from Fig. 2.5, Callister 6e.
Electron Energy States
incr
easi
ng
en
erg
y
n=1
n=2
n=3
n=4
1s2s
3s2p
3p
4s4p
3d
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NCSU
• have complete s and p subshells• tend to be unreactive.
Adapted from Table 2.2, Callister 6e.
Stable Energy Configurations
Z Element Configuration
2 He 1s2
10 Ne 1s22s22p6
18 Ar 1s22s22p63s23p6
36 Kr 1s22s22p63s23p63d104s24p6
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NCSU
• Why? Valence (outer) shell usually not filled completely.
• Most elements: Electron configuration not stable.
Adapted from Table 2.2, Callister 6e.
Survey of Elements
Element Hydrogen Helium Lithium Beryllium Boron Carbon ... Neon Sodium Magnesium Aluminum ... Argon ... Krypton
Electron configuration 1s 1
1s 2 (stable) 1s 22s 1 1s 22s 2 1s 22s 22p 1 1s 22s 22p 2 ...
1s 22s 22p 6 (stable) 1s 22s 22p 63s 1 1s 22s 22p 63s 2 1s 22s 22p 63s 23p 1 ...
1s 22s 22p 63s 23p 6 (stable) ...
1s 22s 22p 63s 23p 63d 10 4s 24p 6 (stable)
Atomic # 1 2 3 4 5 6
10 11 12 13
18 ... 36
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NCSU
• Columns: Similar Valence Structure
Electropositive elements:Readily give up electronsto become + ions.
Electronegative elements:Readily acquire electronsto become - ions.
Adapted from Fig. 2.6, Callister 6e.
The Periodic Table
He
Ne
Ar
Kr
Xe
Rn
iner
t gas
es
acce
pt 1
e-
acce
pt 2
e-
give
up
1e-
give
up
2e-
gi
ve u
p 3e
-
F Li Be
Metal
Nonmetal
Intermediate
H
Na Cl
Br
I
At
O
S Mg
Ca
Sr
Ba
Ra
K
Rb
Cs
Fr
Sc
Y
Se
Te
Po
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NCSU
Bondingattractive force FA
repulsive force FR
Net force FNre
pu
lsio
nat
trac
tion
0fo
rce F
repulsive energy ER
attractive energy EA
net energy EN
rep
uls
ion
attr
acti
on
0
pot
enti
al e
ner
gy E
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NCSU
• bond length, r
• bond energy, Eo
• melting temperature, Tm
Tm is larger if Eo is larger.
Properties from Bonding: Tm
F F
r
r
larger T m
smaller T m
Energy (r)
r o
Eo=
“bond energy”
Energy (r)
r o r
unstretched length
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NCSU
16
• Elastic modulus, E
• E ~ curvature at ro
Properties from Bonding: E
cross sectional area A o
DL
length, Lo
F
undeformed
deformed
r
larger Elastic Modulus
smaller Elastic Modulus
ener
gy
r o unstretched length
E is larger if E0 is more negative.
• coefficient of thermal expansion,
• ~ symmetry at ro
smaller
larger
r o
DL
length, Lo
unheated, T 1
heated, T 2
ren
ergy
is smaller if Eo is more negative
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NCSU
• Occurs between + and - ions.
• Requires electron transfer.
• Large difference in electronegativity required.
• Example: NaCl
Ionic Bonding
Na (metal) unstable
Cl (nonmetal) unstable
electron
+ - Coulomb attraction
Na (cation) stable
Cl (anion) stable
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NCSU
Ionic Bonding
+ -
Electron density difference
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NCSU
• predominant bonding in ceramics
give up electrons acquire electrons
Examples: Ionic Bondings
He -
Ne -
Ar -
Kr -
Xe -
Rn -
F 4.0
Cl 3.0
Br 2.8
I 2.5
At 2.2
Li 1.0
Na 0.9
K 0.8
Rb 0.8
Cs 0.7
Fr 0.7
H 2.1
Be 1.5
Mg 1.2
Ca 1.0
Sr 1.0
Ba 0.9
Ra 0.9
Ti 1.5
Cr 1.6
Fe 1.8
Ni 1.8
Zn 1.8
As 2.0
Cs Cl
MgO
CaF 2
NaCl
O 3.5
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NCSU
• requires shared electrons
• example: CH4
C: has 4 valence e, needs 4 more
H: has 1 valence e, needs 1 more
Electronegativities are comparable.
Covalent Bonding
shared electrons from carbon atom
shared electrons from hydrogen atoms
H
H
H
H
C
CH4
H
H
H
H
Cenhanced electrondensity
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NCSU
Ni3Al–Superalloy Bonds Covalently
Ni
Al
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NCSU
11
• Molecules with nonmetals• Molecules with metals and nonmetals• Elemental solids (RHS of Periodic Table)• Compound solids (about column IVA)
Examples: Covalent Bonding
He -
Ne -
Ar -
Kr -
Xe -
Rn -
F 4.0
Cl 3.0
Br 2.8
I 2.5
At 2.2
Li 1.0
Na 0.9
K 0.8
Rb 0.8
Cs 0.7
Fr 0.7
H 2.1
Be 1.5
Mg 1.2
Ca 1.0
Sr 1.0
Ba 0.9
Ra 0.9
Ti 1.5
Cr 1.6
Fe 1.8
Ni 1.8
Zn 1.8
As 2.0
Si C
C(diamond)
H2O
C 2.5
H2
Cl2
F2
Si 1.8
Ga 1.6
GaAs
Ge 1.8
O 2.0
colu
mn
IVA
Sn 1.8Pb 1.8
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NCSU
• Arises from a sea of donated valence electrons (1, 2, or 3 from each atom).
• Primary bond for metals and their alloys
Metallic Bonding
+ + +
+ + +
+ + +
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NCSU
arises from interaction between dipoles
• permanent dipoles-molecule induced
• fluctuating dipoles
-general case:
-ex: liquid HCl
-ex: polymer
Van Der Waals Bonding
secondary bonding
HH HH
H2 H2
van der Waals bonding
ex: liquid H2asymmetric electron clouds
+ - + -van der Waals
bonding
+ -van der Waals
bonding + -
H Cl H Clvan der Waals
bonding
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NCSU
Van Der Waals Bonding
permanent dipolsfluctuating (Induced) dipols
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NCSU
Ceramics(Ionic & covalent bonding):
Metals(Metallic bonding):
Polymers(Covalent & Secondary):
large bond energylarge Tm
large Esmall
variable bond energymoderate Tm
moderate Emoderate
directional Propertiesvan der Waals bonding dominates
small Tsmall Elarge
Summary: Primary Bonds
secondary bonding
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NCSU
• Non dense, random packing
• Dense, regular packing
Dense, regular-packed structures tend to have lower energy.
Energy And Packing
r
typical neighbor bond length
typical neighbor bond energy
ener
gy
r
typical neighbor bond length
typical neighbor bond energy
ener
gy
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NCSU
• atoms pack in periodic, 3D arrays• typical of:
Crystalline materials...
-metals-many ceramics-some polymers
• atoms have no periodic packing• occurs for:
Noncrystalline materials...
-complex structures-rapid cooling
Si Oxygen
crystalline SiO2
noncrystalline SiO2"Amorphous" = Noncrystalline
Materials And Packing
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NCSU
• tend to be densely packed.
• have several reasons for dense packing:-Typically, only one element is present, so all atomic radii are the same.-Metallic bonding is not directional.-Nearest neighbor distances tend to be small in order to lower bond energy.
• have the simplest crystal structures.
We will look at three such structures...
Metallic Crystals
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NCSU
• rare due to poor packing (only Po has this structure)• close-packed directions are cube edges.
• Coordination # = 6 (# nearest neighbors)
Simple Cubic Structure (sc)
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NCSU
• Coordination # = 8
• Close packed directions are cube diagonals.--Note: All atoms are identical; the center atom is shaded differently only for ease of viewing.
Body Centered Cubic Structure (bcc)
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NCSU
• Coordination # = 12
• Close packed directions are face diagonals.--Note: All atoms are identical; the face-centered atoms are shaded differently only for ease of viewing.
Face Centered Cubic Structure (fcc)
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NCSU
Perovskite Strucutre
SrTiO3
Applications: non-linear resistors (PTC), SMD capacitors, piezoelectric sensors and actuators, ferroelectric memory.
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NCSU
• Some engineering applications require single crystals:
• Crystal properties reveal features of atomic structure.
--Ex: Certain crystal planes in quartz fracture more easily than others.
--diamond single crystals for abrasives
--turbine blades
Crystals as Building Blocks
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NCSU
• Most engineering materials are polycrystals.
• Nb-Hf-W plate with an electron beam weld.• Each "grain" is a single crystal.• If crystals are randomly oriented, overall component properties are not directional.• Crystal sizes typ. range from 1 nm to 2 cm (i.e., from a few to millions of atomic layers).
1 mm
POLYCRYSTALS
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NCSU
• Single Crystals-properties vary with direction: anisotropic.
-example: the modulus of elasticity (E) in bcc iron:
• Polycrystals
-properties may/may not vary with direction.-if grains are randomly oriented: isotropic. (Epoly iron = 210 GPa)-if grains are textured, anisotropic.
200 mm
Single vs Polycrystals
E (diagonal) = 273 GPa
E (edge) = 125 GPa
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NCSU
TEMs at NCSUThe NEW JEOL 2010F
This is a TEM/STEM, which can do everything
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NCSU
TEMs at NCSUTEM Lab Course at the OLD TEM: Topcon
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NCSU
STEM at ORNL
This STEM provides the smallest beam in the world.
It uses the brightest sourcein the universe,1000 times brighter thana supernova.