next generation tank coatings: reducing opex, saving lives

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Next generation tank coatings: reducing opex, saving lives 13 September 2021 • 14:00-15:30 BST #tankers Part of Tanker Shipping & Trade Tech & Ops Webinar Day 13 September 2021 Supporting organisation Sponsored by Presentation & sponsor documents: Page 2: Captain Onur Yildirim, Advanced Polymer Coatings Page 12: Guy Johnson, L&I Maritime (UK) Ltd Page 44: D. Terry Greenfield, CONSULEX / Past Chairman AMPP (Formerly NACE International) 2020-2022 Page 49: Advanced Polymer Coatings company information

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Page 1: Next generation tank coatings: reducing opex, saving lives

Next generation tank coatings: reducing opex, saving lives13 September 2021 • 14:00-15:30 BST

#tankers

Part ofTanker Shipping

& Trade Tech & Ops Webinar Day

13 September 2021

Supporting organisationSponsored by

Presentation & sponsor documents:Page 2: Captain Onur Yildirim, Advanced Polymer CoatingsPage 12: Guy Johnson, L&I Maritime (UK) LtdPage 44: D. Terry Greenfield, CONSULEX / Past Chairman AMPP (Formerly NACE International) 2020-2022Page 49: Advanced Polymer Coatings company information

Page 2: Next generation tank coatings: reducing opex, saving lives

Thank you for the opportunity to meet!

Captain Onur YildirimGlobal Marine Manager,

Advanced Polymer Coatings

1

Page 3: Next generation tank coatings: reducing opex, saving lives

Can a tank coating be ‘green’ & save on Operational Cost?

2

What constitutes a Cargo Tank Coating to be ‘Green’, and to be beneficial for ‘OPEX’

Page 4: Next generation tank coatings: reducing opex, saving lives

Coating’s Properties

3

Cleaning Efficiency Turnaround Time

Recovery

Absorption

Desorption

What is Important and What to look for as Operator?

Page 5: Next generation tank coatings: reducing opex, saving lives

Coating’s Properties

4

High Absorption

Low DesorptionLong Recovery

High Absorption

High DesorptionRelatively shorter

Recovery

Virtually

Non-AbsorptionNon-Recovery

• Cross-Contamination• Longer Cleaning Period & Increased Slop• Slow Turnaround• Increased Fuel Consumption• Increased Chemical Cleaner Consumption

What is Important and What to look for as Operator?

Page 6: Next generation tank coatings: reducing opex, saving lives

Better Technology: Higher Cross -Linking

Microscopic coatingsurface images

High Functionality Polymer

Versus

Phenol Novolac Epoxy

x250 Magnification

x1000 Magnification

x250 Magnification

x1000 Magnification

Phenol Novolac EpoxyHigh Functionality Polymer

(Higher Cross-Linking)

5

Impermeable line of defense and easy to clean low energy & smooth surface

Comparison of Microscopic Coating Surface Images from Tubitak – The Scientific and Technological Research Council of Turkey, in Ankara, Turkey

Page 7: Next generation tank coatings: reducing opex, saving lives

Quantifying Savings

6

Reduction of Fuel Cost by 3%

• 3% fuel savings will generate operating cost savings of $600,000 to$1,200,000 per annum per tanker

• Annual fuel cost per ship ranges from$20,000,000 to $40,000,000 per annum

• Fleet size of (10) ships could achieve savings of $6,000,000 to $12,000,000 per annum

Fuel savings due to less tank cleaning

Source: Dr.Z. Bazari, Overview of ship energy management seminar

Page 8: Next generation tank coatings: reducing opex, saving lives

Quantifying Savings

7

• Fuel consumption per typical tanker 40,000to 50,000 MT per annum

• Average carbon content of marine fuels isabout 86%

• CO2 production per ship: 140,000 to 160,000MT per year

• 3% fuel saving = CO2 reduction of 4,500 MTper annum per ship

• 10 ship fleet equates 45,000 MT per annumof CO2 reduction

Source: Dr.Z. Bazari, Overview of ship energy management seminar

Reduced emissions due to less tank cleaning

Page 9: Next generation tank coatings: reducing opex, saving lives

Quantifying Savings

8

Source: Guy Johnson, Director, L&I Maritime, U.K. ‘Effects on your bottom line’

Reduced emissions due to less tank cleaning

• High Functionality Polymer coated vesselproduces 78.5% less CO2 emissions comparedto the zinc coated vessel for the same tankcleaning operation.

Zinc Coated Vessel

• 56 hours of hot water washing produces 106.4MT of CO2

High Functionality Polymer Coated Vessel

• 12 hours of hot water washing produces 22.8MT of CO2

Page 10: Next generation tank coatings: reducing opex, saving lives

Quantifying Savings

9

• A vessel “costs” $18,000 per day• A vessel has 16 cargo tanks.• 4 cargo tanks can be cleaned simultaneously.• Each cargo tank requires 200L of cleaning chemical(s) (where cleaning chemicals are required).• The typical cost of a regular cleaning chemical is $3 per litre

Zinc Coated Vessel High Functionality PolymerCoated Vessel

Total Cleaning Time 64 hours 16 hours

Hot Water Cleaning Time 56 hours 12 hours

Cleaning Chemical Consumption 3200L 0L

• The financial advantages of a High Functionality Polymer versus zinc silicate in this example can bequantified as follows:

Total time saving 48 hrs = $36,000Cleaning chemical saving 3200L = $9,600Hot water washing saving 44 hrs = 26.4MT of fuel**

(** On average a vessel consumes 0.6MT per hour of HFO / MGO in the boiler and A/E during tank cleaning).

Source: Guy Johnson, Director, L&I Maritime, U.K. ‘Effects on your bottom line’

Let’s assume the following…

Page 11: Next generation tank coatings: reducing opex, saving lives

Thank You

10

Questions?

Page 12: Next generation tank coatings: reducing opex, saving lives

How Clean is Clean?L&I

L&I Maritime (UK) LtdHall Farm Offices

West Markham

Newark

Nottinghamshire

NG22 0GU

UNITED KINGDOM

Tel: +44 (0) 1777 232 253

[email protected]

Page 13: Next generation tank coatings: reducing opex, saving lives

L&I

Page 14: Next generation tank coatings: reducing opex, saving lives

How Clean is Clean?L&I

• What makes a cargo tank clean, or not?

• The first point to consider is that the efficiency of all tank cleaning operations is determined by some kind of inspection

Visual

Wall Wash

Page 15: Next generation tank coatings: reducing opex, saving lives

How Clean is Clean?L&I

• Visually clean is fairly self explanatory

✓ CDOF – Clean Dry Odour Free

• But “wall wash” standard is less straightforward because there is no universal specification

✓ How Clean is Clean?

Page 16: Next generation tank coatings: reducing opex, saving lives

How Clean is Clean?L&I

• And who decides the wall wash specifications and what are they?

• Charterers and / or cargo Interests

Page 17: Next generation tank coatings: reducing opex, saving lives

How Clean is Clean?L&I

Dear Guy

Good day sir,

I have one question about WWT criteria.We would like to carry cargo of naphtha which product of GS Caltex Yeosu.For this cargo, charterer informed WWT requirement as bellows;--------------------------------------------------------------------------------------------------------------OWNERS CONFIRM VESSEL/MASTER WILL COMPLY WITH BELOW WALL WAST TEST CRITERIA PRIOR LOADING- APPEARANCE-VISUAL-PASS-CLEAR AND FREE OF SUSPENDED WATER- HYDROCARBONS – 125 PPM MAX- CHLORIDE – 0.5 PPM MAX- WATER MISCIBILITY – SPEC/RESULT : COMPLETE- NONVOLATILE MATTER – SPEC MAX 5 PPM GC- PT - CO COLOR METHOD D5386 MX 15- NITROGEN 1 MAX ASTM D6069- PERMANGANATE TIME TEST – MIN 30 MIN @ 15 DC

Page 18: Next generation tank coatings: reducing opex, saving lives

How Clean is Clean?L&I

Dear Julie,

Charterers have advised zero chlorides, I just asked them to reconfirm same and they replied;

That's correct. Zero.

Best regardsAsle JohansenITC / International Tanker Chartering AS

Phone : +47 55 90 28 00Direct : +47 55 90 28 06Mobile : +47 40 08 22 60

Page 19: Next generation tank coatings: reducing opex, saving lives

How Clean is Clean?L&I

Page 20: Next generation tank coatings: reducing opex, saving lives

What is the wall wash?L&I

• It is supposed to provide information to indicate whether a cargo tank is “clean” or not

• But what does it actually tell us?

Page 21: Next generation tank coatings: reducing opex, saving lives

How Clean is Clean?L&I

Page 22: Next generation tank coatings: reducing opex, saving lives

How Clean is Clean?L&I

Page 23: Next generation tank coatings: reducing opex, saving lives

How Clean is Clean?L&I

• Really only that the bottom 2 – 3M of the cargo tank is clean. Approximately 1% of the internal surface area of the tank?

• What about the remaining 99%?

• It is an “unknown” ..

Page 24: Next generation tank coatings: reducing opex, saving lives

How Clean is Clean?L&I

• And then we have to ask the most important question ..

• What are the wall wash specifications? How clean is clean?

• Blank canvas / no limitations for commercial interests

Page 25: Next generation tank coatings: reducing opex, saving lives

How Clean is Clean?L&I

• To one charterer a colour of 10 is acceptable, to others it is “dirty”

Page 26: Next generation tank coatings: reducing opex, saving lives

How Clean is Clean?L&I

• An inorganic chloride level higher than 0.5ppm is apparently evidence of “poor” tank cleaning.

• Really? 1 second in 23 days …

Page 27: Next generation tank coatings: reducing opex, saving lives

How Clean is Clean?L&I

• If a vessel does not pass the wall wash, it cannot load the next cargo

• Even though it represents less than 1% of the internal surface area of the cargo tank and perhaps more importantly none of the cargo lines.

Page 28: Next generation tank coatings: reducing opex, saving lives

How Clean is Clean?L&I

But if as much as 99% of the cargo tank is potentially un-clean at the start of cargo operations ..

Why do we not see more off-specification cargoes?

Page 29: Next generation tank coatings: reducing opex, saving lives

How Clean is Clean?L&I

• DILUTION EFFECTS

• Or .. what happens to the contaminants found in the wall wash sample when the tank is fully loaded

• Typically 3000 times dilution

Page 30: Next generation tank coatings: reducing opex, saving lives

How Clean is Clean?L&I

Page 31: Next generation tank coatings: reducing opex, saving lives

How Clean is Clean?L&I

• Wall wash inspections are imposed for one reason:

• To provide reassurance to cargo interests that any particular cargo tank is suitable to load the next nominated cargo

• But this is just not possible.

• All they do is contribute to unnecessary CSE and overcleaning (GHG emissions)

Page 32: Next generation tank coatings: reducing opex, saving lives

How Clean is Clean?L&I

• Each hour of hot water washing, consumes on average 0.6MT per hour of HFO / MGO in the boiler and A/E

• Burning 1MT of HFO produces approximately 3.2MT of CO2

• Meaning each hour of hot water washing liberates1.9MT of CO2 into the atmosphere

Page 33: Next generation tank coatings: reducing opex, saving lives

How Clean is Clean?L&I

• The dilution effect “allows” us to load chemical cargoes without them becoming contaminated.

• Not the wall wash specification.

• Focus on main area of concern, using techniques such as UV spectroscopy

Page 34: Next generation tank coatings: reducing opex, saving lives

How Clean is Clean?L&I

• Emerging trend for received cargoes to be tested for extremely low levels of previous cargo. WHY?

• Capability, bargaining tool and no faith in the wall wash.

• But what impact does this have on tank cleaning?

• And what about the influence of the cargo tank lining?

Page 35: Next generation tank coatings: reducing opex, saving lives

How Clean is Clean?L&I

• Stainless steel. Organic Coating. Inorganic Coating.

• If the coating / lining absorbs previous cargo residues, this needs to be recognised and understood. WHY?

• The wall wash generally does not pick these residues up. Contact time.

• Do not pretend that a “good” wall wash result means the cargo tank is suitable

Page 36: Next generation tank coatings: reducing opex, saving lives

How Clean is Clean?L&I

Page 37: Next generation tank coatings: reducing opex, saving lives

How Clean is Clean?L&I

Page 38: Next generation tank coatings: reducing opex, saving lives

How Clean is Clean?L&I

• Lab based project.

• Test panels immersed in different cargoes, cleaned until the wall wash passed, before being immersed in methanol.

• The methanol was tested for the presence of the previous cargo

Page 39: Next generation tank coatings: reducing opex, saving lives

L&I

0.0

5.0

10.0

15.0

20.0

25.0

30.0

premium epoxy phenolic zinc

gasoline in methanol (mg/kg)

gasoline inmethanol (mg/kg)

Page 40: Next generation tank coatings: reducing opex, saving lives

L&I

0.0

2.0

4.0

6.0

8.0

10.0

premium epoxy phenolic zinc

ulsd in methanol (mg/kg)

ulsd in methanol(mg/kg)

Page 41: Next generation tank coatings: reducing opex, saving lives

L&I

0.0

5.0

10.0

15.0

20.0

25.0

30.0

35.0

40.0

45.0

premium epoxy phenolic zinc

styrene monomer in methanol (mg/kg)

styrene monomerin methanol(mg/kg)

Page 42: Next generation tank coatings: reducing opex, saving lives

31

L&I

• Coatings that actively absorb certain cargo types should not be loaded directly afterwards with cargoes that are sensitive to the previous cargo.

• Commercial interests need to understand this as well.

• If the next cargo is high purity, choose a coating with a good prior cargo history, or a premium coating or stainless steel.

• Do not hide behind the wall wash

• Do not gamble safety/sustainability against cargo quality

Page 43: Next generation tank coatings: reducing opex, saving lives

Questions? L&I

Page 44: Next generation tank coatings: reducing opex, saving lives

No Magic Solution for Life-Cycle Longevity

D. TERRY GREENFIELD

P R I N C I PA L C O N S U LTA N T, C O N S U L E X

Page 45: Next generation tank coatings: reducing opex, saving lives

No Magic Solutions ▪ Its all in the process!

Page 46: Next generation tank coatings: reducing opex, saving lives

Life-Cycle Success

Material Selection

Installtion/Application

Integration of “Lessons

Learned”

Life Cycle Considerations and

Cost

Page 47: Next generation tank coatings: reducing opex, saving lives

Barriers to Extended Life-Cycle▪ Initial Costs vs. Life-Cycle Costs

▪ Initial Installation

▪ Inspection

▪ Initial Repairs

▪ Maintenance

Page 48: Next generation tank coatings: reducing opex, saving lives

Closing Thoughts Extended Life-Cycle is achievable

Success is in the process and isn’t magic!

Thanks!

Page 49: Next generation tank coatings: reducing opex, saving lives

The industry leading cargo tank coating for

chemical & product tankers, with superior chemical resistance.

Page 50: Next generation tank coatings: reducing opex, saving lives

Key Coatings Benefits

There's Only 1 MarineLINE®

3 Years 4 Years

5 Years 6 Years

11 Years

MarineLINE® cargo tank coating system offers long service lifepotential. See these photos of tanks at various inspection intervals.

For chemical and product carriers Strong Return on Investment (ROI) Virtually non-permeable for assurance of product purity Faster, easier cleaning and venting Maximum versatility to carry acids, alkalis, solvents, CPPs, PFADs, Bio-Fuels, and Methanol Excellent flex stressing GRAS - Generally recognized as safe for food grade cargoes FDA compliant Superior chemical resistance compared to stainless steel, phenolic epoxies, and zinc silicate coatings Field repairable Superior bond strength and adhesion Resistance to wear, abrasion, and impact Very low VOC - 130 grams/L (1.09 lbs./gal) Thermal shock resistance -40°C to +150°C (-40°F to +302°F ) ABS ISO 9001:2015 Certification Third party warranty through Helvetia Group, covering shipowners and operators for a specified warranty period up to 5 years.

Page 51: Next generation tank coatings: reducing opex, saving lives

Go Green:Easier Tank Cleaning Produces Additional Return On Investment (ROI)

Glossy, smooth surface Virtually non-absorbent lining Reduces cleaning time Reduces chemical cleaning use Reduces slops Reduces fuel burning (to heat hot water/steam) A wide range of approved cleaning detergents

and chemicals can be used for next cargoes Substantial savings in CO2, SOx, and NOx

reductions per voyage:• Tens of thousands of $USD savings

in bunker fuel• Tens of tons of SOx and NOx reductions• Hundreds of tons of CO2 reductions

MarineLINE® When Performance CountsGreater Versatility When Switching CargoesThese charts show how easily you can switch cargoes to take advantage of the greatest amount of sequencing possibilities and the opportunity to carry the most profitable

cargoes.

Page 52: Next generation tank coatings: reducing opex, saving lives

Why MarineLINE® Is BetterPatented Polymer Technology Delivers Results: Microscopic Crosslink Density

Phenol Novolac Epoxy MarineLINE®

x250 Magnification x250 Magnification

x1000 Magnification x1000 Magnification

Microscopic coating surface images taken at TUBITAK, in Ankara, Turkey, compare the differences of the APC's MarineLINE® versus standard Phenol Novolac epoxy coatings.

(LEFT) a Phenol Novolac Epoxy coating at various magnifications, compared to (RIGHT) the MarineLINE® cargo tank coating system.

Higher crosslinking leads to a denser structure that enhances high chemical and high temperature resistance.

The information provided by Advanced Polymer Coatings, Inc. (APC) for the application or repair of APC coatings is based upon protective coating industry standards and knowledge gained through observation of professional applicators throughout the world that have successfully applied APC coatings. APC does not exercise any control over selection of the applicator that applies or repairs APC coatings. By providing information APC is not representing, directly or by implication, that an applicator that is provided with this information will achieve a result that will pass without objection in the trade or industry, otherwise referred to as MERCHANTABILITY, or will meet the vessel owner’s protective coating requirements, otherwise referred to as FITNESS FOR A PARTICULAR PURPOSE. The only warranty provided by APC through its information and literature is that all APC products when delivered will have been manufactured in accordance with APC’s manufacturing procedures, will be accurately labeled, and when mixed, applied and cured in a controlled environment in accordance with APC’s current written application guidelines will withstand chemical corrosion as set forth in APC’s chemical compatibility reference

guide. The chemical compatibility reference guide and current application guidelines are available at www.adv-polymer.com. Any customer specific express warranty can only arise from a written warranty extended by APC to the specific customer identified in the writing. APC DISCLAIMS ALL OTHER WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION THE IMPLIED WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE THAT ARE CONTAINED IN ARTICLE 2 OF THE UNITED STATES UNIFORM COMMERCIAL CODE AND ANY SIMILAR WARRANTIES CONTAINED IN THE LAWS OF OTHER COUNTRIES WHERE APC PRODUCTS ARE DELIVERED OR APPLIED. ALL CONTRACTS FOR THE SALE OF APC PRODUCTS SHALL BE GOVERNED BY THE UNIFORM COMMERCIAL CODE WITHOUT REGARD TO ANY STATE VARIATIONS.

© Copyright 2020-03-20 APC2017

Advanced Polymer Coatings Avon, Ohio 44011 U.S.A. +1 440-937-6218 Phone+1 440-937-5046 Fax800-334-7193 Toll-Free USA & Canada

www.adv-polymer.com

T O M O R R O W ’ S S O L U T I O N S T O D AY