nitrogen oxides sensor

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Patents inert gas. The ionic movement under the influence of an electric current is modified by the magnetic field: hydrated ions move along the ring channel containing the test solution. The advantage of the cell design is in improved determination of membrane characteristics due to a reduction in concentration polarization and more uniform flow. Patent number: SU 1789253 Date: 23 January 1993 Inventors: V.I. Baglai, I.M Tseiflln, V.G. Stepanov Applicant: Soyuzgiprovodkhoz Inst. (Ship Mechanical Engineering Research Institute) Fluorinated polymer This patent, one of the first to be granted under Russian rather than Soviet law, covers the surface modification of polytrimethylsilyl propyne membranes. The chosen method uses gas plasma: the source gas can be a fluorocarbon, sulphur hexafluoride or nitrogen trifluoride, either neat or diluted with nitrogen, oxygen or an inert gas. The reason for the treatment is to increase the selectivity of the membrane when used in industrial gas separation. Patent number: RU 2001665 Date: 30 October 1993 Inventors: E.G. Litvinova, N.N. Fateev, V.S. Khotimskii et al Applicant: Petrochemical Synthesis Institute Nitrogen oxides sensor The sensor detects nitrogen oxides by their effect on the conductivity of a membrane connected between two electrodes. The composite membrane contains a silicon toroidal chamber / N , electromag - membrane J r ----~---~-3 I. L~ [----'J L ~ d.c.source Membrane testing cell substrate and a thin upper layer of a phthalocyanine coordination compound, in which the transition metal can be copper, nickel, lead, iron, zinc or cobalt, and magnesium is also proposed. Substituents on the benzene ring of the phthalocyanine are also necessary, although their nature is specified only in that the volume that they occupy must be greater than that of hydrogen. Patent number: JP 6063414 Date: 8 March 1994 Inventor: K. Moriya Applicant: Osaka Gas Co. Ltd Electrophoretic separator for proteins Classical electrophoresis techniques are widely used in research work on proteins and peptides, but suffer from the defects of slowness and the need to operate in batch mode. The device patented here is capable of continuous-flow separations. It is tubular, with a stator and rotor which together form the processing chamber. The rotor is designed to produce toroidal vortices in the chamber, which create secondary flows or material and increase the separation capacity. Membranes are here fitted adjacent to the two electrodes and are used to isolate electrolyte from the working fluid held in the processing chamber. Continuous zone electrophoresis, Isoelectrlc focusing separations and zone electric field gradient focusing are possible in this apparatus. Previous preparative-scale electrophoresis equipment has been commercialized but this can only operate in batch mode, and its construction, which entails 20 discrete compartments separated by membrane screens, is expensive to maintain. Patent number: US 5298143 Date: 29 March 1994 Inventors: C.F. Ivory, W.A. Goble Applicant: Washington State University Research Foundation Membrane Technology No. 54 11

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Patents

iner t gas. The ionic movement unde r the influence of an electric cur ren t is modified by the magnet ic field: h y d r a t e d ions move along the r ing channe l conta in ing the tes t solution. The advan tage of the cell des ign is in improved de te rmina t ion of m e m b r a n e charac te r i s t i c s due to a reduc t ion in concent ra t ion polar izat ion and more uniform flow.

Patent number: SU 1789253 Date: 23 J a n u a r y 1993 Inventors: V.I. Baglai, I.M Tseiflln, V.G. S tepanov Applicant: Soyuzgiprovodkhoz Inst. (Ship Mechanical Engineer ing Research Inst i tute)

Fluorinated polymer This pa ten t , one of the first to be gran ted unde r Russ i an ra the r than Soviet law, covers the surface modificat ion of

polytr imethylsi lyl propyne membranes . The chosen me thod uses gas p lasma: the source gas can be a f luorocarbon, s u l phu r hexafluoride or ni trogen trifluoride, ei ther nea t or di luted with nitrogen, oxygen or an iner t gas. The r eason for the t r ea tmen t is to increase the selectivity of the m e m b r a n e when used in indus t r ia l gas separat ion.

Patent number: RU 2001665 Date: 30 October 1993 Inventors: E.G. Litvinova, N.N. Fateev, V.S. Khotimskii et al Applicant: Petrochemical Synthes is Inst i tute

Nitrogen oxides sensor The sensor detects ni trogen oxides by their effect on the conduct ivi ty of a m e m b r a n e connected between two electrodes. The composi te membrane conta ins a silicon

toroidal chamber / N

, electromag

- membrane

J

r - - - -~---~-3 I . L ~

[----'J L ~ d.c. source

Membrane testing cell

s u b s t r a t e and a th in upper layer of a ph tha locyan ine coordinat ion compound, in which the t rans i t ion meta l can be copper, nickel, lead, iron, zinc or cobalt, and magnes ium is also proposed. S u b s t i t u e n t s on the benzene ring of the ph tha locyan ine are a lso necessary , a l though their na tu re is specified only in tha t the volume tha t they occupy mus t be greater t h a n tha t of hydrogen.

Patent number: JP 6063414 Date: 8 March 1994 Inventor: K. Moriya Applicant: Osaka Gas Co. Ltd

Electrophoretic separator for proteins Classical e lec t rophores is t echniques are widely used in r e sea rch work on prote ins and pept ides , bu t suffer from the defects of s lowness and the need to opera te in ba tch mode.

The device pa t en ted here is capable of cont inuous-f low separa t ions . It is tubular , with a s ta tor and rotor which together form the process ing chamber . The rotor is des igned to p roduce toroidal vort ices in the chamber, which create secondary flows or mater ia l and increase the separa t ion capaci ty.

Membranes are here fitted ad jacen t to the two electrodes and are used to isolate electrolyte from the working fluid held in the process ing chamber . Con t inuous zone electrophoresis , Isoelectrlc focusing separa t ions and zone electric field grad ien t focusing are poss ible in th is a ppa r a t u s .

Previous prepara t ive-sca le e lec t rophores is equ ipment h a s been commercia l ized bu t this can only operate in ba t ch mode, and its const ruct ion , which entai ls 20 discre te c om pa r t m e n t s s epa ra t ed by m e m b r a n e screens, is expensive to mainta in .

Patent number: US 5298143 Date: 29 March 1994 Inventors: C.F. Ivory, W.A. Goble Applicant: Washington Sta te Universi ty Research Founda t ion

M e m b r a n e T e c h n o l o g y No. 5 4 11