norma fiat

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Page: Date: Change Date Description Edition normazione Code Ch. B 3 CMD --- 9.57513 04/04/2008 PROCUREMENT SPECIFICATION ALUMINIUM-- AND ZINC--LAMELLAR BASE ANTI--CORROSION COATING FOR FERROUS MATERIAL PARTS 1/12 ANY PRINTED COPY IS TO BE DEEMED AS UNCHECKED; THEREFORE THE UPDATED COPY MUST BE CHECKED IN THE APPROPRIATE WEB SITE PUBLISHED BY SATIZ --- NORMAZIONE CONFIDENTIAL THIS DOCUMENT MUST NOT BE REPRODUCED OR CIRCULATED TO THE THIRD PARTIES WITHOUT PRIOR WRITTEN CONSENT BY FIAT GROUP AUTOMOBILES S.p.A. IN CASE OF DISPUTE THE ONLY VALID REFERENCE IS THE ORIGINAL ITALIAN EDITION Fiat Group Automobiles SUPERVISING Dept. : E.D. -- Ingegneria dei Materiali MANAGING Dept. : E.D. -- Ingegneria dei Materiali PURPOSE To define thecharacteristics that the non--electrolytic anticorrosive coatings with thinzinc andalu- minum layer base must meet for parts made of ferrous material. To define the modalities to be followed and equipment to be utilized for the execution of the control tests of these characteristics. This Procurement Specification consists of No. 12 pages and 2 annexes . = 01/31/03 Edition1 -- New. (DA) = 05/08/06 Edition2 -- Completely revised. (FD) = 04/24/07 Edition3 -- Type V added.Type IV changed. (FD) A 10/03/07 Annex 2 : changed . (FD) B 04/04/08 Annex 2 : supplier name changed . (FD) Supervisor Department: Manager Department: Supervisor: Manager: MATERIALS ENGINEERING & SERVICES - ANTICORROSION & PAINTING MATERIALS ENGINEERING & SERVICES - ANTICORROSION & PAINTING GIANCARLO LUNAZZI MAURO ANTICO

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Page 1: norma fiat

Page:

Date:

Change Date Description

Edition

normazione

Code

Ch.

B3

CMD---

9.57513

04/04/2008

PROCUREMENTSPECIFICATIONALUMINIUM-- AND ZINC--LAMELLAR

BASE ANTI--CORROSION COATINGFOR FERROUS MATERIAL PARTS

1/12

ANY PRINTED COPY IS TO BE DEEMED AS UNCHECKED; THEREFORE THE UPDATED COPY MUST BE CHECKED IN THE APPROPRIATE WEB SITE

PUBLISHED BY SATIZ --- NORMAZIONE

CONFIDENTIAL

THISDOCUMENTMUSTNOTBEREPRODUCEDORCIRCULATEDTOTHETHIRDPARTIES

WITHOUTPRIORWRITTENCONSENTBYFIATGROUPAUTOMOBILESS.p.A.INCASEOFDISPUTE

THEONLYVALIDREFERENCEISTHEORIGINALITALIANEDITION

Fiat GroupAutomobiles

SUPERVISING Dept. : E.D. -- Ingegneria dei Materiali

MANAGING Dept. : E.D. -- Ingegneria dei Materiali

PURPOSETo define the characteristics that the non--electrolytic anticorrosive coatingswith thin zinc andalu-minum layer base must meet for parts made of ferrous material.To define the modalities to be followed and equipment to be utilized for the execution of the controltests of these characteristics.

This Procurement Specification consists of No. 12 pages and 2 annexes.

= 01/31/03 Edition1 -- New. (DA)

= 05/08/06 Edition2 -- Completely revised. (FD)

= 04/24/07 Edition3 -- Type V added.Type IV changed. (FD)

A 10/03/07 Annex 2 : changed . (FD)

B 04/04/08 Annex 2 : supplier name changed . (FD)

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| § ”A” : TEST EQUIPMENT

Equipment necessary for tests is the one specified in the Standards listed in § “B”.

| § ”B” : REFERENCED DOCUMENTS

|50180 | Corrosion tests. TMD

|50473 | Determination of the resistance to gasoline of paints, enamels, etc. TMD

|50473/01 | Determination of the resistance to chemical aggression of products. TMD

|50757 | Measurement of metal coating thickness by magnetic method. TMD

|50758 | Measurement of metal coating and protection oxide layer thickness (micrographic method). TMD

|7.G0114 | Measurement of bolt friction coefficient. PGE

|7.M5000 | Metal parts. Check of the absence of hexavalent chromium (Cr VI) in surface coatings.PMD

|9.01102 | Quality of FIAT AUTO S.p.A. supplies. CFO

|9.01102/01 | Requirements for the statistic check of supplies. CFO

|9.01103 | Product quality and conformity certificate. CFO

|9.52605/01 | Bolts for normal and special use. CFO

|9.55367 | Single–side layer adhesive tapes. CMD

|9.57511 | Corrosion–resistant zinc, aluminum and chromate base chemical coating for ferrous metal parts. CMD

|9.57512 | Corrosion–resistant zinc, aluminum and organic binder base chemical coating for ferrousmetal parts. CMD

|5541 | ISO metric threads with triangular profile, with pitch equal to or higher than 0.35 mm– Tolerance system for movable couplings. UNI

|B 487 | Standard test Method for Measurement of Metal and Oxide Coating Thickness by Microscopical Examination of a cross Section. ASTM

|B 568 | Standard test Method for Measurement of coating Thickness by X–Ray Spectrometry. ASTM

| § ‘‘C’’ : ANNEXES

| 1 | Specifications Data Sheet

| 2 | Correspondence between Fiat Auto designation and commercial denominations

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1

GENERAL

1.1This Procurement Specification covers non–electrolytic anticorrosive coatings derived from water orsolvent dispersions of zinc and aluminum flakes and following stoving, for ferrous material parts.Stoving temperatures can vary from about 180 C for solvent–based organic systems, to about 300 C forwater–based inorganic systems.Topcoat finishing additional treatments can be applied on the base coating to improve the corrosion andabrasion resistance, to give a particular color and/or to modify the friction coefficient by adding, in thiscase, special additives such as wax or PTFE.

1.2

PurposeMain purpose of the coating dealt with in this Procurement Specification is to give to treated parts a highresistance to corrosion and to ensure a controlled value of the friction coefficient.

Coatings covered in this Procurement Specification shall comply with prescriptions inAnnex CK of P.S. 9.01102 and shall be completely free from chromium compounds.

1.3

Field of applicationDepending on the type of parts to be treated, non–electrolytic coatings with zinc and aluminum flake basecan be applied following one of these procedures:

– bulk dip / spin;

– rack dip / spin;

– rack spray, bulk (volute) or on pallet.

As a general rule, bulk processes are suitable for small or medium–size parts, while rack processes aresuitable for medium–size or large parts.For parts with indents – blind holes, socket screw heads, nuts – and/or fine threads, it is necessary to usesystems and working cycles able to avoid product deposits in these areas or to guarantee their removal.

These coatings must not be utilized in the following cases:

– Self–locking nuts with polyamide core.

– Parts for which a good electrical conductivity is required (e.g. ground connections).

– Only as concerns the coatings obtained by water dispersions, for components made ofmaterials for which the temperatures of �300 C cause a decay of the mechanicalcharacteristics.

Furthermore they are not recommended for:

– Internal and external threads < M6.

– Parts for which welding operations are foreseen after the application of coating.

For parts to be used on exposed areas (e.g.: under floor, engine compartment, vehicle exterior),assembled with stainless steels, magnesium alloys copper alloys, rubber or other elements subject tocreate contact corrosion with zinc, it is necessary to use coatings with appropriate additional finishings,to specify on drawings.

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PIn these cases, it is always advisable to check the suitability of the solution chosen by means of targetedcorrosion tests, to be agreed upon between Customer and Supplier.

1.4

Flexibility and resistance to shocksThe coating must resist normal extensions and compressions required to springs, as well as normalbending stresses to which elastic washers and flat springs are subject during the assembly, withoutshowing scaling or loss of adhesion from the base metal.Moreover, it must resist the normal handling and storage conditions without showing scaling, detach-ment from the base metal or other important damages.

1.5

LookUnless otherwise specified on drawings, the coating shall present a uniform semi–opaque silver grey color(Silver).

A different color can be required (e.g. black), it is usually obtained by applying one or more additionalfinishing coats which can affect the thickness of the coating (indicatively greater than 15 �m total), makingit potentially critical for fine metric screw threads.

1.6

Classification, designation, indication on drawing and use

TYPEINDICATION

ON DRAWING�

DESCRIPTIONOLD

DESIGNATION

USE PROVISIONS CODENUMBER

I RIV/EC 5P.S. 9.57513

Two applicationsof base coating

RIV/DAC 5RIV/DAC 8

P.S. 9.57511

FAR/ZN/OR IP.S. 9.57512

Of general use, also fornon–threaded parts.As a replacement of RIV/DACand FAR/ZN/OR I coatings. Tobe prescribed for bolts and nutswhen the values of thecoefficient of friction (Cf)required are 0.12 to 0.30

I

IIRIV/EC 5 F

P.S. 9.57513�

Two applicationsof bulk lubricatedbase coating

–––

To be prescribed particularly forbolts and nuts when the valuesof the coefficient of friction (Cf)required are 0.12 to 0.18

II

IIIRIV/EC 5 LUBP.S. 9.57513

Two applicationsof base coating +one of lubricant

–––

To be prescribed for bolts andnuts when the values of thecoefficient of friction (Cf)required are 0.10 to 0.16, orlower. �

III

IVRIV/EC 8 PLP.S. 9.57513

One or twoapplications ofbase coating +one or twoapplications oforganic finishingor minerallubricant

RIV/DAC 5 PLP.S. 9.57511

FAR/ZN/OR IIP.S. 9.57512

To be used when a greaterresistance to abrasion, tochemical agents, and tocorrosion due to contact arerequired.As a replacement of RIV/DAC 5PL coatings.To be prescribed for bolts andnuts when the values of thecoefficient of friction (Cf)required are 0.10 to 0.16. �To be prescribed also when acolor different from silver grey(e.g. black) is required.

IV

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TYPEINDICATION

ON DRAWING�

DESCRIPTIONOLD

DESIGNATION

USE PROVISIONS CODENUMBER

VRIV/EC 5 PLCap. 9.57513

One or twoapplications ofbase coating +one or twoapplications oforganic finishingor minerallubricant

FAR/ZN/OR IIP.S. 9.57512

To be used for the same uses,but in less heavy expositionconditions than Type IV (e.g.inside vehicle). �As a replacement ofFAR/ZN/OR II coatings.To be prescribed also when acolor different from silver grey(e.g. black) is required.

884

� If the Designers think it is necessary to bind the use of a specific product/process, it is possible to indicate on the drawing the commercial name of the products used and of their Manufacturers (seeAnnex 2 and § 2.5.3)

� The application of the lubricants can be carried out also on Type II coatings.In this case, the drawing prescription of the coating shall be: RIV/EC 5 F LUB P.S. 9.57513 and shallcomplulsorily be followed by the indication of the dispersion limits of the Cf required.

� All colors different from silver grey shall be explicitly indicated on drawing, e.g.: RIV/EC 8 PL Black P.S.9.57513, or RIV/EC 5 LUB Green P.S. 9.57513 (see Annex 2).

� Cf dispersion limits different from 0.10 to 0.16 shall be specified on drawings (see § 2.5).

1.7

Dimensions and tolerances of the coated part

1.7.1

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1.7.1.1If not otherwise indicated, dimensions and tolerances indicated on the part drawing are considered asincluding the coating.

1.7.2

Coating thickness on bolts

1.7.2.1When applied on threaded elements, the coating must not affect the normal assembly and dismountingoperations. The measure of the coating thickness is defined as per the tolerance of the ISO metric thread,according to Standard UNI 5541, with tolerance classes:

– g, f and e for outer threads (screws);

– H and G for inner threads (nuts).

In case of outer threads, these tolerances are considered before applying the coating while, in case ofinner threads, they are considered after coating. After coating, the higher deviation must not exceed zero(nominal dimension) in case of outer threads and be lower than zero in case of inner threads.

a) Screws The thickness values of coatings for screws are defined in function of thread pitch andtolerance field of thread. Table 1 shows the maximum theoretical thickness values thatcan be required; they are obtained from the values of the main deviations from tolerancepositions g, f and e.

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Even thickness values higher or lower than the indicated ones can be required.Thicknesses higher than the indicated ones must be agreed upon by Purchaser and Supplier, for, inaddition to the main deviation, a part of the thread tolerance could be utilized and a decrease of somemicrometers could occur on the average diameter in position “h/H”; nevertheless, in any case the screw– nut coupling must not be compromised.

b) Nuts Differently from the electrolytic coatings, the coatings dealt with in this Procurement Specification tend to accumulate in inner threads too. Therefore the female threads must be suitably increased in order to ensure the meeting of tolerance 6H after applyingthe coating.

2

REQUIREMENTS FOR THE COATING QUALIFICATION

2.1

Submit the component to tests and checks indicated in the following paragraphs, checking the complianceof the test result with the values/limits indicated in the design and/or in the annexed “Specifications DataSheet”, concerning the specific type.

4�4

Test environment (unless otherwise specified)Temperature : 23 * 5 CAtmospheric pressure : 860 to 1060 mbarRelative humidity : 45 to 70 %

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4�5

Coating materials and processes

The material and coating processes that are approved by FIAT AUTO are listed in Annex 2 .

2.4

CharacteristicsThe characteristics indicated below refer to the significant surface of the part.The term significant surface means the surface part that is essential for the look and/or utilization of thetreated component.It can be indicated on drawing or agreed upon when ordering; otherwise the whole part surface isconsidered to be significant.In case of bolts, the significant surface includes head and stem of screws, operation slots, possibleinseparable washers and the outer surface of nuts.

2.4.1

Visual inspectionThe part surface must be free of defects such as porosity, inclusions, cracks, blisters, drops, etc. and ofzones without coating.The coating must have a look conforming with what required in § 1.5, it must be catalyzed perfectly, witha not greasy or sticky hand (for versions LUB too); it must resist normal handling, storage and installationoperations without flaking, scaling or, in any case, losing adhesion.No accumulation of product that can affect the tightening operations must occur on bolts, on threads andin operation slots.

2.4.2

Check the absence of hexavalent chromium compounds in the coating compositionAs per Standard 7.M5000.

2.4.3

Thickness

2.4.3.1

Coating thickness for components other than bolts and nuts

The minimum local thickness, measured in significant surface zones by one of the methods indicatedbelow, must result as indicated in § 2.4.3.6, for the various types of coating.

2.4.3.2

Magnetic method

As per Standard ASTM B 568 or FIAT Standard 50757, making use of Magne–Gage, Mikrotest or otherequivalent equipment that permits an accuracy of at least * 10 %.To be utilized in current checks.

2.4.3.3

X–ray fluorescence methodAs per Standard ASTM B 568.Of general use, to be utilized preferably in case of small–size parts.It requires a specific calibration for every type of coating.

2.4.3.4

Micrographic methodAs per Standard ASTM B 487 or FIAT Standard 50758.To be utilized in case of objection or when the methods indicated above cannot apply.

Page 8: norma fiat

Page

Change9.57513 8

PUBLISHED BY SATIZ --- NORMAZIONE

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THISDOCUMENTMUSTNOTBEREPRODUCEDORCIRCULATEDTOTHETHIRDPARTIES

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2.4.3.5

Bolt coating thicknessThecoating thickness on threadedelementsmust not compromise the normal tightening anddismountingoperations.In the meantime, it must meet the requirements indicated in §§ 2.4.5 to 2.4.7.Unless otherwise arranged, after coating, metric threaded parts shall be manually screwable on the testgauges, ring type or thread plug type, with tolerance position “h” for external threads and “H” for internalthreads.In this case the screwing operation, for the first 3 threads shall be done by exerting a max. torquecomplying with values in P.S 9.52605/01 both for screws and for nuts.

2.4.3.5.1

Zones for the measurement of the bolt coating thicknessAs a consequence of the variability of the coating thickness on screws and nuts, it is measured in pointssignificant from the point of view of anticorrosive protection.

In case of hexagonal or outward--torsion, these points lies approximately at the center of the head surfaceor of the stem end.In case of cylindrical screws with countersunk hexagonal head and of screws with cross cut, themeasuring points lies on the flat surface of the head, between edge and countersunk hexagon, betweenedge and cross cut, or on the side of the head. Countersunk and cut surfaces are excluded from themeasuring points.In case of nuts, thickness is measured on a side of the hexagon or on a support plane.

2.4.3.5.2

Coating thickness measurement on bolts and nuts and small itemsOn a minimum of 10 parts for each homogeneous lot, measure, with the methods described above, thecoating thickness performing at least 4 different measurements for each part.For each single part the arithmetical mean of measured values shall be within the limits indicated in§2.4.3.6 as a function of the prescription indicated in the drawings.Single measurements lower than 40% of the prescribed limit are not allowed.

2.4.3.6

Thickness limitsThickness values must range within the following limits:

-- RIV/EC 5 ≥ 5 mm

-- RIV/EC 5 F ≥ 5 mm

-- RIV/EC 5 LUB ≥ 5 mm

-- RIV/EC 8 PL ≥ 8 mm

-- RIV/EC 5 PL ≥ 5 mm

As far as screws are concerned, the max. thickness, measured under the head, shall not exceed 25 mm.

2.4.4

AdhesionThe assessment of the adhesion of coating to base metal must be carried out by the following methods:

2.4.4.1

Adhesion when new

2.4.4.1.1Take 3 samples for each type of part to be checked.

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2.4.4.1.2On the part, choose the flattest possible and not–threaded surface, of at least 1 cm2 as test surface.

2.4.4.1.3Degrease the surface to be tested by heptane.

2.4.4.1.4At environmental temperature, apply a plastic elastic adhesive vinyl tape strip on the surface(Procurement Specification 9.55367) with an even and light manual pressure; avoid to let air bubbles.

2.4.4.1.5Detach the tape from the part manually, pulling it rapidly from above downward, perpendicularly to thesurface to be tested.

2.4.4.1.6Consider the worst result obtained in the 3 measurements carried out on every part.The adhesion of coating to the base metal must be higher than the cohesion of the same coating.

2.4.4.1.7The presence of small–size coating particles (�3 mm2) is allowed on the tape; in total they can cover anarea lower than the 20 % of the surface to be tested.On the contrary, neither coating fragments having dimensions of �3 – 4 mm2, nor any detachment fromthe base metal are allowed on the tape.

2.4.4.2

Adhesion after aging

2.4.4.2.1Submit the parts to be checked to a salty fog test, as per Standard 50180, method B1 for a duration of96 h .

NOTA :In case of small–size elements, when incisions cannot be made (flat surfaces < 1 cm2), thetest can be carried out on samples having suitable dimensions and submitted to the treatmenttogether with the elements to be tested.

2.4.4.2.2After drying and conditioning at environmental temperature for 10 min, repeat the operations as perparagraphs 2.4.4.1.4 and 2.4.4.1.5.

2.4.4.2.3

Neither detachments �3 mm from the incision lines, nor the presence on the tape of coating frag-ments caused by detachment form the base metal are allowed.

2.4.5

Resistance to corrosion

2.4.5.1After at least 24 h from the coating baking operation end, take a number of parts so that the total of thesignificant surfaces is �1 dm2.

2.4.5.2Submit the parts to the corrosion test in salty fog as per Standard 50180 method A1.Unless otherwise indicated, the various types of coating must meet the requirements indicated in Table 2.

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TYPE OFCOATING

Minimum time (h) of exposition within which they must not beshown

COATINGZinc corrosion products Base metal corrosion products

I RIV/EC 5 ––– 480

II RIV/EC 5 F ––– 480

III RIV/EC 5 LUB ––– 480

IV RIV/EC 8 PL 144* 720

V RIV/EC 5 PL 144* 480

* Only for finishing with colors different from silver grey (Silver)

2.4.5.3If not otherwise specified, the assessment of the resistance to corrosion must be assessed with the nakedeye and at a normal reading distance. The presence of white zinc corrosion products, for an extension�5 % of the total exposed significant surface, is not a cause of reject.The quantity of ferrous corrosion points must be �1/ dm2 (higher values are considered to be causes forreject). The presence of corrosion products within zones that are not significant surfaces is not consideredto be a cause for reject.

2.4.6

Resistance to temperature

2.4.6.1Expose the parts to be tested in a constant temperature and humidity ventilated chamber for 3 h at150*3 C (temperature measured on the part) and then submit them to the corrosion test in salty fog, asper Standard 50180 method A1.

2.4.6.2According to the type of coating, duration of exposition and requirements shall be the ones indicated inTable 2.

2.4.7

Cathode protection of coating

2.4.7.1By means of a suitable point, cut the coating on the part to be tested or on the sample until reaching thebase metal. The incision must have a width not larger than 0.5 mm.

2.4.7.2Expose the sample to be tested in a salty fog chamber as per Standard 50180 method A1 for 96 h.

2.4.7.3No ferrous corrosion must appear on the incision surface at the end of the test.

2.4.8

Resistance to gasoline (Test to be carried out only during the qualification phase)

2.4.8.1Carry out the test as per the modalities and with the equipment described in Standard 50473.

Page 11: norma fiat

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2.4.8.2Dry up the part and condition it in test environment for a duration of 120 min, then assess the surfaceconditions.

2.4.8.3No surface defect is allowed (e.g. : spots, blisters, detachments) if compared to the unexposed part.

2.4.9

Resistance to the liquid window cleaner (Test to be carried out only during the qualification phase)

2.4.9.1Carry out the test as per the modalities and with the equipment described in Standard 50473/01 MethodB.

2.4.9.2Dry up the part and condition it in test environment for a duration of 120 min, then assess the surfaceconditions.

2.4.9.3No surface defect is allowed (e.g. : spots, blisters, detachments) if compared to the unexposed part.

4�6

Bolt friction coefficient

2.5.1Unless otherwise specified on drawings, coefficients of friction of bolts and nuts shall be within thedispersion limits Cf = 0.12 to 0.30, as prescribed by P.S. 9.52605/01.In case lower Cf values or narrower dispersion limits are required, e.g. Cf = 0.10 to 0.16, or Cf = 0.12 to0.18, it is necessary to use self–lubricated coatings (Type F), or to apply suitable lubricating products(Type LUB) or finishing products (Type PL) (See Annex 2).If no requirements are present on the drawings, the following dispersion values shall be applied:

– RIV/EC 5 Cf = 0.12 to 0.30– RIV/EC 5 F Cf = 0.12 to 0.18– RIV/EC 5 LUB Cf = 0.10 to 0.16– RIV/EC 8 PL Cf = 0.10 to 0.16– RIV/EC 5 PL Cf = 0,10�0,16.

2.5.2Friction conditioner application check shall be carried out through the measurement of the coefficient offriction as per Std. 7.G0114.Other checking methods shall be agreed upon in advance and approved by Fiat Auto appropriatedepartments (E.&D. /P.T.&S.).

2.5.3The correspondence between Fiat Auto designations and approved commercial names of coatings andfriction conditioners are shown in Annex 2.The use of products different from those indicated is allowed, as long as the requirements of thisProcurement Specification and of any specification indicated on the drawings are respected. Limitationson use of forbidden substances or substances to be monitored, as per Annex CK of P.S. 9.01102, shallbe respected too.The Specification Data Sheet of the product used, together with its application cycle parameters, shall beavailable on Fiat Auto’s demand.

Page 12: norma fiat

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3

REQUIREMENTS FOR THE SUPPLY CHECK.(by Qualità di Stabilimento)

3.1The supply check must be carried out as per requirements indicated in Procurement Specification9.01102/01 (Limited distribution).

4

REQUIREMENTS FOR THE SUPPLIER

4.1The Supplier must meet the general requirements indicated in Procurement Specification 9.01102‘‘SUPPLY QUALITY”.

4.2

Supplies for the product qualification

The Supplier must produce the product quantity required in the purchase order, attaching the relevantrequired Quality and Conformity Certificate (see Proc. Spec. 9.01103); all the characteristics indicatedin the attached “Specifications Data Sheet”, concerning the specific type, shall be checked. No“non–conformity” is allowed.

4.3

Supplies for the production

The supplied product must meet the requirements indicated on drawing and in this ProcurementSpecification. When defining the kind of production process to be followed and the severity of acceptancetests, the Supplier must consider the classes of importance that FIAT defined for each one of thecharacteristics to which requirements refer (see § 5).

NOTE: During both product qualification and supply control, checks can be carried out on componentsthat underwent non–destructive tests (indicated by NM in § 5); if the component underwentdestructive tests (M) it can be utilized no more for other tests or checks if not otherwise speci-fied every time.

5

TABLE OF THE CLASSIFICATION OF CHARACTERISTICS

CLASSIFICATION OF CHARACTERISTICS TEST TYPE

Visual inspection Minor NM

Check the absence of hexavalent chromiumcompounds in the coating composition Minor M

Thickness Minor NM/M

Adhesion when new Major M

Adhesion after aging Minor M

Resistance to corrosion Major M

Resistance to temperature Minor M

Cathode protection of coating Minor M

Resistance to gasoline Minor M

Resistance to the liquid window cleaner Minor M

Friction coefficient Major M

Page 13: norma fiat

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ALUMINIUM– AND ZINC–LAMELLARBASE ANTI–CORROSION COATING FOR

FERROUS MATERIAL PARTS

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Specifications Data Sheet

CHARACTERISTICS TestConditions LIMITS

Visual inspection –– § 2.4.1

Search of hexavalent chromiumin coating

§ 2.4.2Standard 7.M5000 § 2.4.2

RIV/EC 5 �5 �m

RIV/EC 5 F§ 2 4 3

�5 �m

Thickness RIV/EC 5 LUB§ 2.4.3

�5 �m

RIV/EC 8 PL �8 �m

RIV/EC 5 PL § 2.4.3 �5 �m

Adhesion

Adhesion when new § 2.4.4.1

Absence of detachments of basemetal.Allowed cohesion detachment�20 % of the test surface.Fragment dimension �3 mm2.Adhesion

Adhesion after aging

§ 2.4.4.2and Standard

50180method B1

Absence of detachments frombase metal.No detachment allowed �3 mmfrom incision lines.

RIV/EC 8 PLfor 144 h(only forcoatings of Product of zinc corrosion �5 % of

R i t

RIV/EC 5 PL

coatings ofa colorother thanSilver) § 2.4.5

d St d d

Product of zinc corrosion �5 % ofthe significant surface

Resistance to corrosion

RIV/EC 5

§and Standard

50180to corrosionRIV/EC 5 F

for 480 h

50180method A1

Th tit f ibl fRIV/EC 5 LUBfor 480 h The quantity of possible ferrous

corrosion points must be �1/dm2.RIV/EC 5 PL

corrosion points must be �1/dm .

RIV/EC 8 PL for 720 h

Resistance to temperature

§ 2.4.6and Standard

50180method A1

§ 2.4.5.2

Cathode protection of coating

§ 2.4.7and Standard

50180method A1

No ferrous corrosion must appearon the incision surface at the end ofthe test.

Resistance to gasoline§ 2.4.8

and Standard50473

No surface defect is allowed (e.g.:spots, blisters, detachments) ifcompared to the unexposed part.

Resistance to the liquid window cleaner

§ 2.4.9and Standard

50473/01Method B

No surface defect is allowed (e.g.:spots, blisters, detachments) ifcompared to the unexposed part.

Bolt friction coefficient § 2.5Standard 7.G0114 § 2.5

Page 14: norma fiat

Page:

Edition

normazione

Code

Ch.

3B

CMD

1/2

ALUMINIUM-- AND ZINC--LAMELLARBASE ANTI--CORROSION COATING FOR

FERROUS MATERIAL PARTS

9.57513ANNEX 2

PUBLISHED BY SATIZ --- NORMAZIONE

CONFIDENTIAL

THISDOCUMENTMUSTNOTBEREPRODUCEDORCIRCULATEDTOTHETHIRDPARTIES

WITHOUTPRIORWRITTENCONSENTBYFIATAUTOS.P.A.INCASEOFDISPUTE

THEONLYVALIDREFERENCEISTHEORIGINALITALIANEDITION

Fiat GroupAutomobiles

CORRESPONDENCE BETWEEN FIAT AUTO DESIGNATION AND COMMERCIAL DENOMINA-TIONS

Correspondence between FIAT Auto designation and commercial denomination of coating materials/processes qualified as per Procurement Specification 9.57513 and Experimentation Standard7.G0114.

TYPE DRAWING SUPPLIERCOMMERCIAL DENOMINATIONS

TYPE DRAWINGINDICATION SUPPLIER

Base coating Finishing

DACRAL S.A. GEOMET 321 ----

ATOTECH ZINTEK 200 ----

I RIV/EC 5 DOERKEN -- MKSDELTA TONE 9000DELTA PROTEKT KL

100----

MAGNI MAGNI FLAKE B46(Magni 565) ----

DACRAL S.A. GEOMET 500 ----

II RIV/EC 5 FDOERKEN -- MKS DELTA PROTEKT KL

105 ----

DACRAL S.A.GEOMET 321GEOMET 500

1186 Torque’N Tension Control

Fluid¡

ATOTECH ZINTEK 200 Gleitmo 605©

III RIV/EC 5 LUBDOERKEN -- MKS

DELTA TONE 9000DELTA PROTEKT KL

100

Merwin 65 Oil¢

Dacrolub 10 and Dacrolub 15£

Gardolube L 6255¤MAGNI MAGNI FLAKE B46

(Magni 565)

Gardolube L 6255¤

Gardolube 6255 T¥

DACRAL S.A. GEOMET 321PLUS L (Cf 0.08 to 0.14)PLUS ML (Cf 0.10 to 0.16)PLUS M (Cf 0.12 to 0.18)

IVV

RIV/EC 8 PLRIV/EC 5 PL

ATOTECH ZINTEK 200

TOP LG (Cf 0.10 to 0.16)TOP LF (Cf 0.12 to 0.18)TECHSEAL WL--14(Cf 0.10 to 0.16)TECHSEAL WL(Cf 0.12 to 0.18)

DOERKEN -- MKSDELTA TONE 9000DELTA PROTEKT KL

100

DELTA SEAL GZ(Cf 0.10 to 0.16)

DELTA PROTEKT VH 301 GZ(Cf 0.10 to 0.16)

MAGNI MAGNI FLAKE B46 MAGNI TOP B18(Cf 0.10 to 0.16)

Page 15: norma fiat

Page

Change9.57513 2

PUBLISHED BY SATIZ --- NORMAZIONE

CONFIDENTIAL

THISDOCUMENTMUSTNOTBEREPRODUCEDORCIRCULATEDTOTHETHIRDPARTIES

WITHOUTPRIORWRITTENCONSENTBYFIATAUTOS.P.A.INCASEOFDISPUTE

THEONLYVALIDREFERENCEISTHEORIGINALITALIANEDITION

TYPE DRAWING SUPPLIERCOMMERCIAL DENOMINATIONS

TYPE DRAWINGINDICATION SUPPLIER

Base coating Finishing

DACRAL S.A. GEOMET 321 PLUS ML BLACK (GEO-BLACK) (Cf 0.10 to 0.16)

IV

V

RIV/EC 8 PLNero

RIV/EC 5 PL

ATOTECH ZINTEK 200

TOP BLACK (Cf 0.10 to 0.16)TECHSEAL BLACK WL--14

(Cf 0.10 to 0.16)TECHSEAL BLACK WL

(Cf 0.12 to 0.18)V RIV/EC 5 PL

NeroDOERKEN -- MKS

DELTA TONE 9000DELTA PROTEKT KL

100

DELTA SEAL GZ BLACK(Cf 0.10÷0.16)

MAGNI MAGNI BASE D21 MAGNI TOP B37(Cf 0.10 to 0.16)

¡ Finishing 1186 Torque’N Tension Control Fluid by Mac Dermid(Reference dilutions = 3 : 7 in water)

© Finishing Gleitmo 605 by Gleitmolybdän Schmiermittel Gmbh(Reference dilutions = from 1 : 5 to 1 : 6 in water)

¢ Finishing Merwin 65 oil by Rods Oil Ltd(Reference dilutions = 1 : 2 in water)

£ Finishing Dacrolub 10 (for Cf 0.08 to 0.14) and Dacrolub 15 (for Cf 0.12 to 0.18) by DacralS.A.

¤ Finishing Gardolube L 6255 by Chemetall(Reference dilutions = 1 : 3 in water)

¥ Reference finishing Granolube 6352 T by Henkel(Reference dilutions = 1 : 3 in water)