north maharashtra university, jalgaonapps.nmu.ac.in/syllab/science and technology/science/2018-19...

NORTH MAHARASHTRA UNIVERSITY,

JALGAON

M.Sc. (Part II) Inorganic Chemistry

SEMESTER – III AND IV

PROPOSED SYLLABUS

Revised Syllabus

From June- 2018

NORTH MAHARASHTRA UNIVERSITY, JALGAON

M.Sc. (Part II) SEMESTER – III AND IV

Inorganic Chemistry Revised Syllabus From June 2018

PROPOSED SYLLABUS COURSE STRUCTURE

SEMESTER III

CH-330:-Co-ordination Chemistry (I) CH-331:-Inorganic Polymer Chemistry CH-332:- Physical Methods in Inorganic Chemistry CH-333:-Some Selected Topics in Inorganic Chemistry

SEMESTER - IV

CH-430: Applications of Group theory and Co-ordination Chemistry (II) CH-431:- Solid State Chemistry CH432:-Organo metallic Chemistry and catalysis.

Practical Courses

CH-I-2:-Inorganic Chemistry Practical Annual CH-I-3:-Inorganic Chemistry Practical Annual CH-I-4:- A Short Research Project Annual Note:

1. There are in all four theory courses for Third Semester and three theory courses for fourth semester and Three annual practical courses including one short research project.

2. Each theory course should be covered in 6 periods each of 60 minutes per week. 4 periods for lectures and two periods for tutorials, seminars etc .to be completed in 60 lectures of 60 min duration each.

3. The marks for each paper (theory and practical) are distributed as external (60 marks) and internal (40 marks) examinations. For internal assessment of each theory course two written test /tutorial will be taken.

4. Each practical course requires 6 hours of laboratory work per week and course will be extended over two semesters and the candidate will be examined at the end of the year.

5. There should not be more than 10 students in a batch of a practical course. Each practical course is having weightage of six hours per week.

6. Students have to submit journal duly certified by the Head of the Department /Head of the Institution. If the journal is lost ,the student should produce a certificate from Head of the department / Head of the Institution stating that he /she has satisfactorily completed the practical work.

The students pursuing this course would have to develop in depth understanding of various aspects of the subject. The conceptual understanding, development of experimental skills, designing and implementation of novel synthetic methods, developing the aptitude for academic and professional skills, acquiring basic concepts for structural elucidation with hyphenated techniques, understanding the

fundamental biological processes and rationale towards computer assisted drug designing are among such important aspects. Instructions for the students : The students seeking admission to M.Sc. II Inorganic Chemistry course is hereby informed that they are supposed to adhere to the following rules

1. A minimum of 75 % attendance for lectures / practical is the pre-requisite for grant of term.

2. There shall be tutorial / practical / surprise test / home assignment / referencing of research papers / seminar / industrial visits / as a part of internal assessment in each semester. The students are supposed to attend all the tests. The students should note that retest will not be conducted for the student absent for the test/s.

3. Theory Courses: Written tests will be conducted for each theory course. However focus may be given on non-written tests. Students should be encouraged for various academic activities like a) Open book test (concerned teacher will decide the allowed books) b) Tutorial c) Surprise test d) Oral e) Assignments f) Review of research paper g) Seminar presentation h) Journal/Lecture/Library notes .

4. Practical Courses: It is a continuous evaluation process. Practical courses will be evaluated on the basis of the following: a. Performance assessment of each experiment on the basis of attendance, punctuality,

journal completion, practical skills, results, oral and analysis. b. Test on practical may be conducted at the end of the year.

5. Project Course: Project will be evaluated by In-Charge of project batch in concern with project guide. Evaluation will be on the basis of weekly progress of project work, progress report, referencing, oral, results and documentation.

SEMESTER III CH-330:-Co-ordination Chemistry (I)

Chapter No.

Name of the chapter/topic No.of periods

Weightage without option(60)

Weightage with option(90)

1 Inorganic Reaction Mechanism 20 20 30

2 Photochemistry 10 10 15

3 Biological role of 'S' block elements 04 04 06

4 Oxygen, electron, iron transport systems and storage proteins

12 12 18

5 Mn in photosynthesis 03 04 06

6 Metalloenzymes 07 06 10

7 Metals in Medicine 04 04 05

CH-331:- Inorganic Polymer Chemistry

Chapter No.

Name of the chapter/topic No. of periods Weightage without option(60)


1 Zeolites 24 24 36

2 Macrocyclic complexes 06 06 09

3 Non-Transition Metal Chemistry 08 08 12

4 Non-Transition Metal Chemistry And Transition Metal Clusters

18 18 27

5 Supramolecular Chemisrty 04 04 06 CH-332:- Physical Methods In Inorganic Chemistry

Chapter No.




1 Electron Spin Resonance Spectroscopy 11 12 16

2 Nuclear Magnetic Resonance spectroscopy(NMR) 16 15 20

3 Nuclear Quadrupole Resonance (NQR) 03 04 07

4 Mossbauer spectroscopy 08 05 10

5 Thermal Methods 18 20 30

6 Cyclic Voltammetry (CV) 04 04 07

CH-333:- Some Selected Topics In Inorganic Chemistry

Chapter No.




1 Multiplication table 10 15 22

2 Reducible and irreducible representations 20 15 23

3 The chloro alkali industry 06 12 15

4 Noble gases 16 10 15

5 Metal – ligand equillibria in solution 08 08 15

SEMESTER IV CH-430:-Co-ordination Chemistry (II)

Chapter No.




1 Molecular orbital theory of metal complexes 10 10 15

2 Transition metal complexes 07 07 12

3 Symmetry adapted linear combination 03 03 08

4 Transformation properties 10 10 15

5 Electronic spectra of metal complexes 15 15 20

6 Ligand field theory of coordination compounds 15 15 20

CH-431:- Solid State Chemistry

Chapter No.




1 Crystal defects and Non stoichiometry 10 10 15

2 Composite materials 04 04 07

3 Ceramic materials 06 06 12

4 Superconducting Materials 12 12 18

5 Magnetic materials and magnetic properties 28 28 42

CH-432:- Organo metallic Chemistry and catalysis.

Chapter No.




1 Transition metals Carbon monoxide compounds

12 12 18

2 Transition metal compounds with bonds to hydrogen

12 12 18

3 Compounds of transition metals with single, double and triple bonds to carbon.

10 10 15

4 Compounds of transition metals with alkenes, alkynes and delocalize hydrogen system.

10 10 15

5 Metallocenes and bent-metallocenes. 08 08 12

6 Catalysis and Heterogeneous catalysis 08 08 12

SEMESTER III CH-330 Coordination Compounds I Chapter 1:- Inorganic Reaction Mechanism: (20L)

• Type of Mechanisms: Basic concepts of Liability and inertness of complexes, stability of complexes,

HSAB concept.

• Substitution Reaction of Octahedral Complexes: The types of Substitution Reaction, Theoretical

approach to Substitution mechanism, Nucleophilic reactivity, Nature of central atom, factors affecting

the rate of substitution reaction Replacement of co-ordinated water, acid catalysis. Substitution in

octahedral complexes: SN1, SN

2 SN1CB mechanisms. The rates of water exchange in high-spin hexa-

aqua ions.

• Stereochemical changes in Octahedral Complexes: Molecular rearrangement of complexes, Reactions

of geometrical and optical isomers, isomerisation and recemisation reactions of octahedral complex,

Ligand stereo specificity.

• Substitution Reaction of Square-Planer Complexes: Trans effect and its theories, Mechanism of

Substitution reaction of Platinum (II) complexes.

The classification of redox reactions: The inner-sphere mechanism & the outer-sphere mechanism,

Bridging Ligand Effects in Inner-Sphere Reactions. One and two electron transfer reactions.

Chapter 2:- Photochemistry: (10L)

Photochemical reactions, Prompt and delayed reactions, quantum yield, recapitulation of

fluorescence & phosphorescence, photochemical reactions irradiating at d-d transition and charge-

transfer reactions, Transitions in metal-metal bonded systems, photochemical reactions involving

chlorophyll Kinetics of excited state, processes

Chapter 3:- Biological role of 'S' block elements (04 L)

As electrolytes (Na, K, Mg and Ca), Channels & Pumps, Charge carriers.

Chapter 4:- Oxygen, electron, iron transport systems and storage proteins (12 L)

Essential and trace metal ions in biology and their distribution ; special ligands - porphyrins, chlorin

and corrin. O2 binding properties of heme (haemoglobin and myoglobin) and non-heme proteins

hemocynin & hemerythrin), their coordination geometry and electronic structure, co-operativity

effect, Hill coefficient and Bohr Effect; characterization of O2 bound species by Raman and infrared

spectroscopic methods; representative synthetic models of heme and non-heme systems.

Active site structure and functions of ferredoxin, rubridoxin and cytochromes, and their

comparisons. Vitamin B12 and cytochrome P450 and their mechanisms of action. Iron transport and

storage proteins in bacterial and mammalian systems – siderophores, transferrin, ferritin.

Chapter 5:- Mn in photosynthesis (03 L)

Photosystem I and II – chlorophyll.

Chapter 6:- Metalloenzymes (07 L)

Structural and functional relationships and mechanisms of enzymatic reaction in the following

metalloenzymes.

Urease, peptidases and phosphatases and their structure and function.

Carbonic anhydrase and carboxypeptidases,

Super oxide dismutases

Catalase and peroxidases,

Nitrogenase and xanthanineoxidase, P and M- clusters in nitrogenase, transition-metal

dinitrogen complexes and insights into N2 binding, reduction to ammonia.

B-12 Actions of Cobalamines

Chapter 7:- Metals in Medicine (04 L)

Application of metal in medicine, physiological effect of metals in medicine, Deficiency & over dose

of metal disease, metal in drug (anticancer drugs eg. Pt complexes, antiarthritis drugs e.g., Au).

Suggested Reference Books: 1. Mechanism of Inorganic Reactions, by Basalo & pearson(1977), Wiley Eastern Ltd. 2. Inorganic Reaction Mechanism by M. L. Tobe (1972), Thomas Nelson & Sons.

3. Inorganic Chemistry by Shriver and Atkins, Oxford University Press. 4. Biological Chemistry of Elements. J. J. R. Frausto da Silva, R. J. P. Williams, 5. Principles of Bioinorganic chemistry by S. J. Lippard and J. M. Berg, (I1994) University Science Books(USA) 6. Bioinorganic chemistry: inorganic elements in the chemistry of life, An Introduction And Guide by Wolfgang Kaim, Brigille Schwederski91994) John Wiley and Sons. 7. Bioinorganic chemistry, Bestini, Gray, Lippard, Vlentine, 1st South asian Edn.(1980) Viva books pvt.ltd. 8. Bio-organic chemistry: a Chemical approach to enzyme action 3rd edition.

9. F. A. Cotton and G. Wilkinson, Advanced Inorganic Chemistry, 5th Edn. (1999), John-Wiley & Sons, New York. 10. Inorganic Chemistry by Catherine E. Housecroft and Alan Sharpe Pearson Education Limited

11. Inorganic Chemistry: Principles of Structure and Reactivity, by J. H. Huheey, E.A. Keiter and

R.L.Keiter Pearson Education India.

12. Inorganic Chemistry, by Shriver and Atkins, Oxford University Press

13. Inorganic Chemistry, by Gary L. Miessler and Donald A. Tarr Pearson Education.

14. B. R. Puri, L. R. Sharma and K. C. Kalia, Principles of Inorganic Chemistry, Milestone

publishers,

15. Concise Coordination Chemistry, by R Gopalan and V Ramalingam Vikas Publishing House

Pvt Ltd.

CH-331:- Inorganic Polymers Chemistry and Molecular Clusters Chapter 1:- Zeolites: (24L)

Basic concept of Zeolites:Introduction, definition, natural and synthetic Zeolites or aluminosilicates, the primary and secondary building blocks, final framework structures.

Synthesis of Zeolites: Hydrothermal synthesis of zeolites Hydrothermal synthetic techniques, Examples of zeolite synthesis, Important factors affecting the synthesis batch composition,Si and Al sources , Si/Al ratio,alkalinity,H2O content,Inorganic cations,Organic templates, solvents, Crystallization temperature and time ,aging, stirring,seeding. Solvothermal synthetic route,

Ionothermal synthetic route, Microwave-assisted hydrothermal synthetic route, F−

synthetic route, Dry-gel conversion synthetic route.

Characterization of zeolites using : XRD, FTIR, Solid state NMR techniques

Applications of Zeolites: Softening of water, agriculture applications in organic synthesis with at least five reactions.

Metal organic framework: Introduction, methods of synthesis, Structure and properties

Chapter 2:- Macrocyclic complexes: (06L)

Types of macrocyclic ligands,design and synthesis by co-ordination template effect, di and polynuclear macrocyclc complexes,applications of macrocyclc complexes.

Chapter 3:- Non-Transition Metal Chemistry: (08 L)

Synthesis, Properties, Structure and reactions of Borazines, Silicates and silicones polysilicates and aluminosilicates, Phosphazenes, P-Ncompounds, cyclophosphazenes and phosphazene polymers. Structural features and reactivity Sulfur-Nitrogen compounds and S-N heterocycles, S4N4,(SN)x. Iso- and Hetero-poly anions.

Chapter 4:- Non-Transition Metal Chemistry And Transition Metal Clusters: (18L)

Synthesis, Properties, Structure & Bonding of: Boranes, Carboranes, Metallocarboranes, Main-group clusters: Geometric and electronic structure, styx notation; three-, four- and higher connect clusters, the closo-, nido-, arachno-borane structural paradigm, Wade-Mingos and Cluster Valence Electron Theory. Clusters with nuclearity 4-12 and beyond 12. Structure, synthesis and reactivity. Naked or Zintl clusters.

Metal carbonyl and halide clusters, low nuclearity clusters and High nuclearity carbonyl clusters-synthesis and structural pattern. 14n+2 rule, high nuclearity metal-carbonyl clusters with internal atoms. Structure, synthesis and reactivity. Capping rules, isoelectronic and isolobal relationships between main-group and transition metal fragments, metal-ligand complexes vs heteronuclear cluster. Metal-metal bonding in carbonyl and halide clusters.

Heteroatomes in clusters carbides, nitrides. Electron counting in high nuclear carbonyl clusters. High nuclear carbonyl clusters of Ge,Ru,Os,Co,Rh,Ir,Ni,Pd and Pt. Halide and chalcogenide clusters. Cheveral phases, triangular clusters. Solid state extended arrays.

Chapter 5:- Supramolecular Chemisrty: (04L)

Concept of supramolecular Chemistry chemistry, molecular recognition, nomenclature, design of supramolecule through non covalent interactions and their applications in transport processes.

Recommended Reference Books and Text books : 1. Introduction to Zeolite Science and Practice,H.Van Bekkum, E.M.Flanigen,P.A.Jacobs and J.C.Jansen(Elsevier pub. Amsterdam,2001) 2. Verified Synthesis of Zeolite material, (Elsevier science pub,2001) 3. Atlas of Zeolite framework types 5th edn.,Ch.Bbaerlocher,W.M.Meier and D.H.Olson. 4. Jean-Marie Lehn ,Supramolecular Chemistry, (1995) VCH, Weinheim. 5. Introduction to Zeolite Science and Practice, Jiri Cejka , Herman Van Bekkum, Avelino, Ferdi Schuth

6. F. A. Cotton and G. Wilkinson, Advanced Inorganic Chemistry, 5th Edn. (1999), John-Wiley & Sons, New York. 7. Inorganic Chemistry by Catherine E. Housecroft and Alan Sharpe Pearson Education Limited

8. Inorganic Chemistry: Principles of Structure and Reactivity, by J. H. Huheey, E.A. Keiter and R.L.Keiter

Pearson Education India.



11. B. R. Puri, L. R. Sharma and K. C. Kalia, Principles of Inorganic Chemistry, Milestone Publishers,

12. Supramolecular Chemistry, 2nd edition J. W. Steed and J. L. Atwood © 2009 John Wiley & Sons, Ltd 13. Supramolecular Chemistry (Concepts and Perspectives) - Jean Marie Lehn(VCH-1995).

CH-332 Physical methods in Inorganic Chemistry Chapter 1. Electron Spin Resonance Spectroscopy: 11 L Introduction, principle of ESR spectroscopy, presentation of spectrum, hyperfine splitting in various structures, hyperfine splitting diagram of representative examples, factors affecting the magnitude of ‘g’ values, Zero field splitting, Kramer’s degeneracy, Anisotropy in the hyperfine coupling constant, electron delocalization, instrumentation and applications. . Chapter 2. Nuclear Magnetic Resonance Spectroscopy (NMR) 16L Principal of NMR spectroscopy. Chemical shift, mechanism of electron shielding and factors affecting the magnitude of chemical shift. Volume diamagnetic susceptibility, Chemical shifts for which the local diamagnetic term does not predominate, spin-spin splitting, spin-spin coupling mechanism for transmitting nuclear spins, applications of spin-spin coupling to structure determination, applications involving magnitude of coupling constants, complex spectra, chemical exchange and the factors affecting line width, effect of chemical exchange on spectra and the evaluation of reaction rates for fast reactions, study of exchange reactions between ligands and metal ions. the double resonance technique, NMR of paramagnetic complexes –contact shift. applications of NMR to Inorganic problems. Chapter 3. Nuclear Quadrupole Resonance (NQR) 3L Principle selection rule for NQR, Factors for splitting of quadruple energy levels in NQR, Application of NQR: Structural information from NQR Chapter 4.Mossbauer spectroscopy: 8 L Principle, factors affecting the line position and shape, isomer effect and Quadrupole splitting iron salt like compounds, complexes, carbonyl compounds (temperature dependence of isomer shift and quadrupole splitting in simple compound and coordination, polynuclear complexes), Numericals. Chapter 5. Thermal Methods 18L a) Thermogravmetry (TGA): Definition, Types of TGA, Instrumentation, Information from TGA Curve; Factors affecting TGA curves (instrumental as well as characteristics of sample factors); Application of thermogravimetry; Calculation of percent decomposition and composition of compounds; Limitation and Advantages of TGA. b) Derivative thermogravimetry(DTG) and its advantages c) Differential Thermal Analysis (DTA) : Definition; Theoretical Basis of DTA; Instrumentation for DTA apparatus; Factors affecting the DTA curve; Application of DTA; Advantages and disadvantages of DTA. d) Differential Scanning Calorimetry (DSC) : Definition ; Comparison of DTA and DSC techniques; Istrumentation of DSC, Factors affecting DSC curves.

Chapter 6.Cyclic Voltammetry (CV) 4 L Principle of Cyclic Voltammetry, typical features of CV curve, CV advantages and disadvantages. Instrumentation Electrolytes Application of CV technique Inorganic Compounds Suggested Reference Books: 1. Physical methods in Inorganic Chemistry, R.S.Drago, Renhold Publishing Corporation 2. Instrumental Methods of Analysis,6thedition, Willard,Merit,Dean. 3. Instrumental Methods of Chemical Analysis,5thedition, GoldenW.Ewing 4. Principals of Instrumental Analysis,3rdedition, DouglasA.Skoog

5. Instrumental Methods of Chemical Analysis, Anand,hatwal 6. Quantitative Inorganic Analysis, A.I. Vogel

7. Spectroscopy of Compounds: V. M. Parikh 8. Coordination Chemistry by Experimental Methods: K. Barger 9. Coordination Chemistry vol. I: E. Martell 10. Physical Methods for Chemistry: R. S. Drago 11. Structural Methods in Inorganic Chemistry: E. A. V. Ebsworth & D. W. H. Rankin

CH-333:-Some Selected Topics in Inorganic Chemistry

(A) – Basic principles of Group theory: 1) Products of symmetry operations, Group multiplication table: C2V, C2h, C3V, C4V, D2h, D3h, D2d, D3d Matrices notations for geometric transformations,, law of reciprocal Proportion, classes for C2V, C2h, C3V, C4V and D2h, D3h, D2d, D3d point groups (10 L) REF: 1, 2, 3 2) Reducible and irreducible representations, The Great orthogonality theorem, rules derived from Great Orthogonality Theorem, rotational vectors, construction of character table; Mullikan’s symbolism for irreducible representations, character tables for C2,C3,C4,D2,D3,D4,C2V,C3V,C4V, C6V,C2h,C4h,D2h,D3h,D2d,D3d. Reducible representations and their reduction: C2V, C3V, C4V. (20L) REF: 1, 2,3,10.

B) Basic & applied Chemistry: 1) The chloro alkali industry: Introduction, LeBlanc process, Weldon and Deacon processes, electrolytic process, diaphragm cell, Mercury cathode cell, Solvay (ammonia soda) process (6L) REF: 7 2) Noble gases: Introduction, compounds of noble gases: Hydrates of noble gases, clatherate Of noble gases, Fluorides, oxy fluorides and oxides of xenon(XeF2,XeF4,XeOF2,,XeF6,XeOF4,XeO2F2,XeO3),Fluorides of Krypton. (16L) REF: 7, 8 3) Metal – ligand equillibria in solution. Stepwise and overall formation constants and their interaction, trends in Stepwise constants, Factors affecting the stability of metal complexes with Reference to nature of metal ion and ligand, chelate effect and its thermodynamic Origin, (8L)

REF : 8,9,10,11 Reference Books: 1. Chemical applications of Group theory by F-Albert cotton second edition, willey Eastern limited New Delhi. 2. Group theory and its chemical applications by P.K. Bhattacharya Himalaya Publishing House. 3. Concept and application of Group theory by Kishor Arrora Anmol publications Pvt.Ltd., New Delhi 4. Concise Inorganic Chemistry fifth edition, J.D.Lee 5.Principles of Inorganic Chemistry by Sharma,Puri,Kalia 6. Inorganic Chemistry by A.G. Sharpe third edition. 7. Advanced Inorganic Chemistry Fifth edition by F.A. Cotton and Wilkinson. 8. Inorganic Chemistry by J.E. Huhey 9. Electrons & Chemicals bonding by H.B. Gray. *****************

SEMESTER – IV

CH-430: Applications of Group theory and Coordination chemistry II

1) Molecular orbital theory of metal complexes (10 L) Hybrid orbitals for sigma (σ) bonding: Tetrahedral (Td) geometry, trigonal planerD3h geometry, square planarD4h geometry, square pyramidal C4V geometry. Hybrid orbitals for pi (Π) bonding: Trigonal planar complex D3h, square planar complex D4h point groups 2) Transition metal complexes:, Sigma bonding in octahedral complexes, sigma bonding in tetrahedral complexes, sigma bonding square planer Complexes. Molecular Terms symbols. (10L) 3) Symmetry adapted inear combination: Constructing symmetry adapted for linear combination (SALC) for C2V and C3V point groups. Molecular orbital approach to analyze bonding in H2O, NH3 and BF3 molecules. (7L) 4) Transformation properties: H2O molecule C2V, NH3 molecule C3V, BF3 molecule D3h (3L) REF: 1, 2,3,11. REF: 1, 2, 3 5) Electronic Spectra of metal complexes: Strong ligand field configurations:, splitting Pattern of co-ordination no. 2 to 9 metal complexes, , Jahn- Teller effect, spectrochemical series, Naphelauxetic series, Racah parameters (B), classification of electronic spectra, specific examples from d2,d3,d7 and d8 complexes ( T1 and A1 ground states, charge transfer spectra. (15L) REF: 1,2 ,3 6) Ligand field theory of coordination compounds: Crystal field theory, octahedral complexes, tetrahedral complexes, tetragonal distortion distorted octahedral complexes, square planar complexes, The method of descending symmetry square pyramidal complexes, trigonal bipyramidal complexes, the effect of weak crystal fields on S,P,D,F terms, Ligand field term diagrams :Orgal diagram for d1,d2,d3,d4,d6,d7,d8 configurations, excited electronic transitions, Tanabe Sugano (T.S) diagrams for d2and d8 configurations. (15 L) REF: 1. Reference Books: 1. Symmetry and Spectroscopy of molecules K. Veera Reddy, second edition, New age international P Limited publishers (2009) 2. Electronic Spectroscopy by A.B.P Lever 3. Intoduction to ligand fields by B .N.Figgis.. 4. Infrared and Raman Spectroscopy of Inorganic and co-ordination compounds, K. Nakamoto. 5. Infrared Spectroscopy of Inorganic Compound Bellamy. 6. Ligand Field theory and its application by B.N.Figgis and M.A.Hitchman Wiely VCH publication (2000) 7. Inorganic Chemistry D.F.Shriver and P.W.Atkins Oxford (1999) 8. Inorganic Electronic Spectroscopy: A.B.P Lever 2nd Edition Elsevier science Publishers, New York (1984) 9. Advanced Inorganic Chemistry by Cotton and Wilkinson (3rd, 4th ,5th edition) 10. Theoretic al Inorganic Chemistry by Day and Selbin. 11. Group theory and its applications in chemistry A.Salahuddin Kanju.G.Krishan. -----------------------------------------------------------------------------------------------

CH-431 Solid State Chemistry Chapter 1. Crystal defects and Non stoichiometry 10 L Crystal defects and Non stoichiometry, Diffusion in solids, phase transformation in solids, solid state reactions and crystal growth. Preparation methods of solids . Chapter 2. Composite materials 4 L Definition, glass transition temperature, fibers, concrete and asphalt materials, polymer composites, application Chapter 3. Ceramic materials 6 L Classification, dielectric properties, polarization properties, piezo, pyro and ferroelectric properties, sol-gel process, examples and applications, oxide, carbide, boride, nitride Chapter 4. Superconducting Materials 12 L Definition of superconductivity, Critical temperature (Tc), Critical field, Bardeen – Cooper - Schrieffer(BCS) theory, properties and classification of superconducting compounds, High Tc superconductivity, Examples of superconducting materials: Structure of YBa2Cu3O7-d oxide, Fullerenes, intermetallic superconductors, synthesis of superconductors. Application of superconducting materials . Chapter 5. Magnetic materials and magnetic properties 28 L Atomic magnetism and solids, type of magnetic materials(Diamagnetism,Paramagnetism.,Antiferromagnetism,ferrimagnetism,Variation of magnetic susceptibility with temperature ,Curie temperature (TC),Neel temperature (TN) Quenching of magnetic moments, Recapitulation of determination of R-S terms of d2& p2 transition metal ,Quantization of orbital contribution in d1 ion &quenching in cubic crystal field , Magnetic moments based on crystal field ground term, spin orbit coupling operator for magnetic susceptibility and magnetic moments of T terms &A,E terms. Magnetic moment & structure, exchange interactions, Lanthanides magnetic moment, Spin‐cross over region and effect of temperature, hysteresis loop and their classification, calculation of magnetic moment from saturation magnetization, magnetic domains, examples of magnetic materials, soft & hard ferrites, structure& magnetic interactions in spinel, garnet hexagonal ferrites, application of magnetic materials Suggested Reference Books : 1. A. F. Wells, Structural Inorganic Chemistry – 5th edition (1984) 2. J H Huheey, Inorganic Chemisry - Principles, structure and reactivity, Harper and Row Publisher, Inc. New York (1972) 3. J. D. Lee, Concise Inorganic Chemistry, Elbs with Chapman and Hall, London 4. A. R. West, Plenum, Solid State Chemistry and its applications 5. N. B. Hanney, Solid State Physics 6. H. V. Keer, Principles of Solid State 7. S. O. Pillai, Solid State Physics 8. W. D. Callister, Wiley, Material Science and Engineering: An Introduction 9. R. Raghwan, First Course in Material Science 10. R. W. Cahan, The coming of Material Science 11. A. R. West, Basic Solid State Chemistry, 2nd edition 12. U. Schubest and N. Husing, Synthesis of Inorganic Materials, Wiley VCH (2000)

13. M. C. Day and J. Selbin, Theoretical Inorganic Chemistry, Reinhold, EWAP 14. A. H. Hanney, Solid State Chemistry, A. H. Publications 15. O. A. Phiops, Metals and Metabolism 16. John Wulff, The structure an properties of materials 17. L. V. Azoroff, J. J. Brophy, Electronic processes in materials, Mc Craw Hill 18. F. A. Cotton, R. G. Wilkinson. Advanced Inorganic chemistry 19. Willam L. Jooly, Modern Inorganic Chemistry 20. ManasChanda, Atomic Structure and Chemical bonding

21. “Magnetism and Transition Metal Complexes”, F. E. Mabbs and D. J. Machin (Chapman and Hall)London(1973). 22. “Introduction to Magnetochemistry”, A. Earnshaw, Academic Press, (1968). 23.Elements of Magnetochemistry, R. L. Dutta and A. Syamal, Affiliated East/West Press Pvt. Ltd. 2007. 24. “Electrochemistry for Chemists”, D. T. Sawyer, A. Sobkowak, J. L. Roberts Jr. 2nd Edition, John Wiley, Inc.New York, 1995)

CH432:-Organo metallic Chemistry and catalysis.

Chapter 1:- Transition metals Carbon monoxide compounds: (12 L)

Stable electron configurations, 16 and 18-electron rule, concept of hapticity; & Recapitulation d-block metal carbonyls. Determining the structure of a carbonyl from IR data. Metal-Metal bonding in metal carbonyl. Synthesis, structure and bonding and reactions of homo and heteroleptic metal-carbonyls and Carbonylate anions.

Chapter 2:- Transition metal compounds with bonds to hydrogen (12 L)

Transition metal Compounds with M-H bonds: Metal hydrides (classical and non-classical). Agostic interaction. Application of NMR in studying hydrido complexes

Chapter 3:- Compounds of transition metals with single, double and triple bonds to carbon. (10 L)

Reactions of organometallic complexes and factors affecting in: Substitution, oxidative addition,

reductive elimination, insertion and deinsertion α-,γ- and δ-Hydride eliminations and

cyclometallations.

Transition metal of nitrosyls, tertiary phosphines, alkenyls, alkynyls, carbenes, N-heterocyclic carbenes and carbines. Synthesis, reactivity and reaction of Fischer and Schrock carbenes.

Chapter 4:- Compounds of transition metals with alkenes, alkynes and delocalize hydrogen system. (10 L)

Preparation, bonding and structure of allyl, dienyl and trienyl complexes; reactions with special reference to organic synthesis.

Hydrides and dihydrogen complexes.

Carbocyclic polyenes: Synthesis, bonding, vproperties and applications: Allyls, Pentadienyls, Cyclobutadienes, Cyclopentadienyls, Cycloheptetrienyls and Arenes.

Chapter 5:- Metallocenes and bent-metallocenes. (08 L)

Synthesis, reactions and reactivity of cyclopentadienyl compounds. The MO picture of bonding

and magnetic properties in bis (cyclopentadienyl) metal complexes. Fluxional behaviour of

metallocenes.

Chapter 6:- Catalysis and Heterogeneous catalysis: (08 L)

Organometallic catalysts, theories of adsorption. Terminology in catalysis: Turnover, turnover

number (TON), turnover frequency (TOF). Introduction, the water-gas-shift reaction, Concepts

of heterogeneous catalysis, CO and CO2 hydrogenation and Fischer-Tropsch processs,

Transformation of hydrocarbons, Metathesis of alkanes, alkenes and alkynes, Oxidation of

hydrocarbons.

Suggested Reference Books: 1. F. A. Cotton and G. Wilkinson, Advanced Inorganic Chemistry, 5th Edn. (1999), John-Wiley & Sons, New York. 2. Organometallic chemistry by R. C. Mehrotra and A. Singh, 1992, Wiley Eastern Ltd.

3. Inorganic chemistry by Butler, Harrod, 1989, Benjamin / Cummins Pub. Co.

4. Principles of organometallic chemistry 2nd Edn. P. Powell, 1988, Chapman and Hall.

5. The organometallic chemistry of the transition metals, fourth edition by Robert H. Crabtree Yale

University, New Haven, Connecticut, A John Wiley & Sons, Inc., Publication

6. Organometallic Chemistry And Catalysis by Didier Astruc Member Of The Institute Universities De

France, Springer Berlin Heidelberg New York

7. Organometallic compounds –Morries sijlirn. IVY Publication house

8. Organometallics in Organic Synthesis – Swan & Black

9. Organometallic Chemistry - E.J. Elias and Gupta

10. Inorganic Chemistry by Catherine E. Housecroft and Alan Sharpe Pearson Education Limited

11. Inorganic Chemistry: Principles of Structure and Reactivity, by J. H. Huheey, E.A. Keiter and R.L.Keiter

Pearson Education India.



M.Sc.(Part II) Inorganic Chemistry Practical Courses Practical Course - CH-I-2 1.Analysis of ore/alloy (any two)

i) Analysis of Cement ii) Analysis of Elmenite iii) Analysis of Steel Fe, Cr – alloy. iv) Analysis of Bronze – alloy.

2. Vitamin ‘C’ from Lemon juice. 3. Estimation of Fe from Soap Bar. 4. Analysis of pigment.(Zn & Cr) 5. Analysis of Plaster of Paris 6. Soil analysis: pH, conductivity, organic carbon and calcium carbonate 7. Copper from fungicide 8. Complexometric determination of bismuth by EDTA titration. 9. To study rate of aquation of 1,10Phenanthroline Fe (II) in acid solution by spectrophotometry. 10 Determination of N,P and K in a fertilizer sample 11. To study the current –potential characteristics of Cd+2 ions using DC polarography, sampled DC, cyclic voltammetry & pulse polarographic techniques. 12. Cyclic Voltametric study of i)Potassium ferricyanide ii) Ferrocene 13. Determine the redox potential of Fe(II)/Fe(III) system and hence determine the number of electron involved in the system using K2Cr2O7 by potentiometric method. 14. Stability constant of metal complex by Bjerrum (potentiometry) method/pHmetry

15.Flame Photomeric Determenation: Sodium and Potassium in fruit juice

Practical Course : CH-I-3

1.Synthesis, purification , analysis of co-ordination complexes of simple &chelating ligands and structure determination (UV,IR,TGA, Magnetic, Conductivity). ( M= Cr, Fe, Mn, Cu, Co) (Any-4)

i) Bis (acetylacetonato complex of Cu (II), Co(II) & V (IV) (any-1) ii) [Cr(NH3 )6] Cl3 iii) Thiourea

iv) Salicyladoxime (Fe or Cu) v) 8-hydroxy quinoline 2. Solid State Materials: Preparation, characterization and activity: (any- 3) Preparation of solid-state materials:

a. NiO, b. ZnO, c. ZnFe2O4 or NiFe2O4, d. Fe3O4, e. BaZrO3 or SrZrO3

3.Magneto Chemistry :Magnetic susceptibility measurements of the synthesised complexes. 4. TGA (Thermogravimetric analysis) two samples. 5.Kinetic masking.: Determination of Cr(III) & Fe(III) in a mixture. 6. Spectrophotometer: Estimate the amount of copper and bismuth ions using EDTA photometric titration method 7.Interpretation and spectral analysis.

a) To interpret IR spectra of acetylacetone and its complex. (1d) i) To determine force constant of -C=O bond. ii) To determine bond lengths of -C=O bond. iii) To identify coordination site & type of coordination.

b) To interpret ESR spectrum of Mn+2(Oh) / Co+2(Oh) / Cu+2 (D4h) etc. To calculate magnetic parameters isotropic, anisotropic viz. g-factor, hyperfine coupling constant etc. c). To interpret electronic spectra of coordination compounds.

i) To determine interelectronic repulsion parameter (B cm-1) & crystal field parameter (10 Dq) using numerical fitting procedure. ii) To calculate bonding parameters.

Practical Course : CH-I-4

A short Research Project The course includes: Literature survey, Research methodology and Industrial tour. Practical AND/ OR Oral Presentation. Dissertation Report – 10 marks. Presentation – 25 marks. Practical – 25 marks Industrial Visit Reference Books 1. Systematic experimental physical chemistry – T. K. Chondhekar& S.W. Rajbhoj 2. Experiments in chemistry – D.V. Jahagirdar 3. Textbook of quantitative Inorganic Analysis – IV Edn. J. Bassett, R. C. Denny, G.H.Gefery and J. Mendham 5. Chemical Curiosites, H. Denny and W. Roesky, WILEY VCH, Ed. 1996. 6. Practical Inorganic Chemistry, G. Marr and B. W. Rocket, University Science Books, Ed. 1999 7. Practical Inorganic Chemistry, G. Pass and H. Sutcliffe, Chapman and Hall, London, Ed. 1968. 8. Vogel’s Textbook of Quantitative Analysis, J. Mendham, R. C. Denney, J. D. 9. Barnes and M. Thomas, Pearson, Ed. 2006. 10. Vogel’s Textbook of Quantitative Analysis, G. Svehla, Pearson, Ed. 2006. 11. A Collection of Interesting General Chemistry Experiments, Anil J. Elias, University Press, Ed. 2002. 12.Thermal Analysis-Wendland 13.Instrumental Methods of Analysis-G-Chatwal and S. Anand( Himalaya Publication;1988) 14. Catalysis: Principles & Applications-B.Viswanathan, S.Savasankar and A.V.Ramaswamy ( Narosa Publication; 2004).( For XRD part) 15. Solid State Chemistry: An Introduction-Lesley Smart and Elaine Moore (2nd Edition, Chapman and hall, 1996).

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