november 14, 2014 - recasting the smelter · 630 plaza drive #100 highland ranch, co 80129 dhl...

November 14, 2014

Arcadis - USKyrie Jeffery

Dear Kyrie Jeffery:

RE: ASARCO-El Paso Cemetery Fines Pile

Order No.: 1411076FAX (720) 344-3535

TEL: (720) 344-3851

630 Plaza Drive #100Highland Ranch, CO 80129

DHL Analytical, Inc. received 3 sample(s) on 11/11/2014 for the analyses presented in the following report.

There were no problems with the analyses and all data met requirements of NELAC except where noted in the Case Narrative. All non-NELAC methods will be identified accordingly in the case narrative and all estimated uncertainties of test results are within method or EPA specifications.

If you have any questions regarding these tests results, please feel free to call. Thank you for using DHL Analytical.

Sincerely,

John DuPontGeneral Manager

This report was performed under the accreditation of the State of Texas Laboratory Certification Number: T104704211-14-13

2300 Double Creek Drive • Round Rock, TX 78664 • Phone (512) 388-8222 • FAX (512) 388-8229

www.dhlanalytical.com

1

Table of Contents

.............................................................................. 3Miscellaneous Documents

.................................................................................. 9CaseNarrative 1411076

....................................................... 10WorkOrderSampleSummary 1411076

........................................................................... 11PrepDatesReport 1411076

.................................................................. 12AnalyticalDatesReport 1411076

.......................................................................... 13Analytical Report 1411076

.................................................... 16AnalyticalQCSummaryReport 1411076

.................................................................. 28MQLSummaryReport 1411076

2

1 Items identified by the letter “R” should be included in the laboratory data package submitted to the TCEQ in the TRRP-required report(s). Items identified by the letter “S” should be retained and made available upon request for the appropriate retention period.

2 O = organic analyses; I = inorganic analyses (and general chemistry, when applicable). 3 NA = Not applicable. 4 NR = Not Reviewed. 5 ER# = Exception Report identification number (an Exception Report should be completed for an item if “NR” or “No” is checked).

DHL Analytical, Inc. Laboratory Review Checklist: Reportable Data Project Name: ASARCO-El Paso Cemetery Fines Pile Date: 11/14/14

Reviewer Name: Carlos Castro Laboratory Work Order: 1411076

Prep Batch Number(s): See Prep Dates Report Run Batch: See Analytical Dates Report

#1 A2 Description Yes No NA3 NR4 ER#5

R1 OI Chain-of-Custody (C-O-C) 1) Did samples meet the laboratory’s standard conditions of sample acceptability upon receipt? X R1-01 2) Were all departures from standard conditions described in an exception report? X

R2 OI Sample and Quality Control (QC) Identification 1) Are all field sample ID numbers cross-referenced to the laboratory ID numbers? X 2) Are all laboratory ID numbers cross-referenced to the corresponding QC data? X

R3 OI Test Reports 1) Were all samples prepared and analyzed within holding times? X 2) Other than those results < MQL, were all other raw values bracketed by calibration standards? X 3) Were calculations checked by a peer or supervisor? X 4) Were all analyte identifications checked by a peer or supervisor? X 5) Were sample detection limits reported for all analytes not detected? X 6) Were all results for soil and sediment samples reported on a dry weight basis? X 7) Were % moisture (or solids) reported for all soil and sediment samples? X 8) Were bulk soils/solids samples for volatile analysis extracted with methanol per EPA Method 5035? X 9) If required for the project, TICs reported? X

R4 O Surrogate Recovery Data 1) Were surrogates added prior to extraction? X 2) Were surrogate percent recoveries in all samples within the laboratory QC limits? X

R5 OI Test Reports/Summary Forms for Blank Samples 1) Were appropriate type(s) of blanks analyzed? X 2) Were blanks analyzed at the appropriate frequency? X 3) Where method blanks taken through the entire analytical process, including preparation and, if

applicable, cleanup procedures? X

4) Were blank concentrations < MQL? X R5-04 R6 OI Laboratory Control Samples (LCS):

1) Were all COCs included in the LCS? X 2) Was each LCS taken through the entire analytical procedure, including prep and cleanup steps? X 3) Were LCSs analyzed at the required frequency? X 4) Were LCS (and LCSD, if applicable) %Rs within the laboratory QC limits? X 5) Does the detectability data document the laboratory’s capability to detect the COCs at the MDL used

to calculate the SDLs? X

6) Was the LCSD RPD within QC limits (if applicable)? X R7 OI Matrix Spike (MS) and Matrix Spike Duplicate (MSD) Data

1) Were the project/method specified analytes included in the MS and MSD? X 2) Were MS/MSD analyzed at the appropriate frequency? X 3) Were MS (and MSD, if applicable) %Rs within the laboratory QC limits? X R7-03 4) Were MS/MSD RPDs within laboratory QC limits? X

R8 OI Analytical Duplicate Data 1) Were appropriate analytical duplicates analyzed for each matrix? X 2) Were analytical duplicates analyzed at the appropriate frequency? X 3) Were RPDs or relative standard deviations within the laboratory QC limits? X

R9 OI Method Quantitation Limits (MQLs): 1) Are the MQLs for each method analyte included in the laboratory data package? X 2) Do the MQLs correspond to the concentration of the lowest non-zero calibration standard? X 3) Are unadjusted MQLs and DCSs included in the laboratory data package? X

R10 OI Other Problems/Anomalies

1) Are all known problems/anomalies/special conditions noted in this LRC and ER? X 2) Was applicable and available technology used to lower the SDL to minimize the matrix interference

affects on the sample results? X

3) Is the laboratory NELAC-accredited under the Texas Laboratory Accreditation Program for the analytes, matrices and methods associated with this laboratory data package? X

6



DHL Analytical, Inc. Laboratory Review Checklist (continued): Supporting Data

Project Name: ASARCO-El Paso Cemetery Fines Pile Date: 11/14/14



S1 OI Initial Calibration (ICAL)

1) Were response factors and/or relative response factors for each analyte within QC limits? X

2) Were percent RSDs or correlation coefficient criteria met? X 3) Was the number of standards recommended in the method used for all analytes? X 4) Were all points generated between the lowest and highest standard used to calculate the curve? X 5) Are ICAL data available for all instruments used? X 6) Has the initial calibration curve been verified using an appropriate second source standard? X

S2 OI Initial and Continuing calibration Verification (IC CV and CCV) and Continuing Calibration blank (CCB):

1) Was the CCV analyzed at the method-required frequency? X

2) Were percent differences for each analyte within the method-required QC limits? X 3) Was the ICAL curve verified for each analyte? X 4) Was the absolute value of the analyte concentration in the inorganic CCB < MDL? X

S3 O Mass Spectral Tuning:

1) Was the appropriate compound for the method used for tuning? X

2) Were ion abundance data within the method-required QC limits? X S4 O Internal Standards (IS):

1) Were IS area counts and retention times within the method-required QC limits? X S5 OI Raw Data (NELAC Section 5.5.10)

1) Were the raw data (for example, chromatograms, spectral data) reviewed by an analyst? X

2) Were data associated with manual integrations flagged on the raw data? X S6 O Dual Column Confirmation

1) Did dual column confirmation results meet the method-required QC? X S7 O Tentatively Identified Compounds (TICs):

1) If TICs were requested, were the mass spectra and TIC data subject to appropriate checks? X S8 I Interference Check Sample (ICS) Results:

1) Were percent recoveries within method QC limits? X S9 I Serial Dilutions, Post Digestion Spikes, and Method of Standard Additions

1) Were percent differences, recoveries, and the linearity within the QC limits specified in the

method? X

S10 OI Method Detection Limit (MDL) Studies 1) Was a MDL study performed for each reported analyte? X 2) Is the MDL either adjusted or supported by the analysis of DCSs? X

S11 OI Proficiency Test Reports: 1) Was the lab's performance acceptable on the applicable proficiency tests or evaluation studies? X

S12 OI Standards Documentation 1) Are all standards used in the analyses NIST-traceable or obtained from other appropriate sources? X

S13 OI Compound/Analyte Identification Procedures 1) Are the procedures for compound/analyte identification documented? X

S14 OI Demonstration of Analyst Competency (DOC)

1) Was DOC conducted consistent with NELAC Chapter 5 – Appendix C? X

2) Is documentation of the analyst’s competency up-to-date and on file? X S15 OI Verification/Validation Documentation for Methods (NELAC Chapter 5)

1) Are all the methods used to generate the data documented, verified, and validated, where

applicable? X

S16 OI Laboratory Standard Operating Procedures (SOPs):

1) Are laboratory SOPs current and on file for each method performed?

X

7

RG-366/TRRP-13 May 2010

Laboratory Data Package Signature Page – RG-366/TRRP-13

This data package consists of:

This signature page, the laboratory review checklist, and the following reportable data:

R1 Field chain-of-custody documentation; R2 Sample identification cross-reference; R3 Test reports (analytical data sheets) for each environmental sample that includes:

a) Items consistent with NELAC Chapter 5, b) dilution factors, c) preparation methods, d) cleanup methods, and e) if required for the project, tentatively identified compounds (TICs).

R4 Surrogate recovery data including: a) Calculated recovery (%R), and

b) The laboratory’s surrogate QC limits. R5 Test reports/summary forms for blank samples; R6 Test reports/summary forms for laboratory control samples (LCSs) including:

a) LCS spiking amounts, b) Calculated %R for each analyte, and c) The laboratory’s LCS QC limits.

R7 Test reports for project matrix spike/matrix spike duplicates (MS/MSDs) including: a) Samples associated with the MS/MSD clearly identified, b) MS/MSD spiking amounts, c) Concentration of each MS/MSD analyte measured in the parent and spiked samples, d) Calculated %Rs and relative percent differences (RPDs), and e) The laboratory’s MS/MSD QC limits

R8 Laboratory analytical duplicate (if applicable) recovery and precision: a) The amount of analyte measured in the duplicate, b) The calculated RPD, and c) The laboratory’s QC limits for analytical duplicates.

R9 List of method quantitation limits (MQLs) and detectability check sample results for each analyte for each method and matrix;

R10 Other problems or anomalies.

The Exception Report for every “No” or “Not Reviewed (NR)” item in Laboratory Review checklist and for each analyte, matrix, and method for which the laboratory does not hold NELAC accreditation under the Texas Laboratory Accreditation Program.

Release Statement: I am responsible for the release of this laboratory data package. This laboratory is NELAC accredited under the Texas Laboratory Accreditation Program for all the methods, analytes, and matrices reported in this data package except as noted in the Exception Reports. The data have been reviewed and are technically compliant with the requirements of the methods used, except where noted by the laboratory in the Exception Reports. By my signature below, I affirm to the best of my knowledge that all problems/anomalies observed by the laboratory have been identified in the Laboratory Review Checklist, and no information or data affecting the quality of the data has been knowingly withheld.

This laboratory was last inspected by TCEQ on May 6-10, 2013. Any findings affecting the data in this laboratory data package are noted in the Exception Reports herein. The official signing the cover page of the report in which these data are used is responsible for releasing this data package and is by signature affirming the above release statement is true.

John DuPont – General Manager

________________________

_______________ Scott Schroeder – Technical Director Signature Date

11/14/14

8

14-Nov-14Date:DHL Analytical, Inc.

Project: ASARCO-El Paso Cemetery Fines Pile

CLIENT: Arcadis - US

Lab Order: 1411076CASE NARRATIVE

Samples were analyzed using the methods outlined in the following references:

Method SW6020A - Metals Analysis

Method SW7471B - Mercury Analysis

Method D2216 - Percent Moisture

Exception Report R1-01

The samples were received on and log-in performed on 11/11/14. A total of 2 samples were received.

The samples arrived in good condition and were properly packaged.


For Metals analysis performed on 11/12/14 Zinc was detected below the reporting limit in the method

blank (MB-66494). The associated samples were detected greater than 10 times the amount in the

blank for this analyte. No further corrective actions were taken.


For Metals analysis performed on 11/12/14 the matrix spike and matrix spike duplicate recoveries were

above control limits for three analytes. These are flagged accordingly in the QC summary report. The

sample selected for the matrix spike and matrix spike duplicate was from this work order. The LCS

was within control limits for these analytes. No further corrective actions were taken.

Page 1 of 1

9




Lab Order: 1411076Work Order Sample Summary

Lab Smp ID Client Sample ID Tag Number Date RecvedDate Collected

1411076-01 R23-110714 11/07/14 03:27 PM 11/11/2014

1411076-02 R22-110714 11/07/14 03:27 PM 11/11/2014

1411076-03 O26-111014 11/10/14 03:20 PM 11/11/2014

Page 1 of 1

10

Sample ID Client Sample ID Collection Date Matrix Batch ID

PREP DATES REPORT

14-Nov-14

Lab Order: 1411076

Client: Arcadis - US

Project: ASARCO-El Paso Cemetery Fines

DHL Analytical, Inc.

Test Name Prep DateTest Number

1411076-01A R23-110714 11/07/14 03:27 PM Soil Mercury Soil Prep, Total 11/11/14 09:16 AMSW7471A 66489

R23-110714 11/07/14 03:27 PM Soil Moisture Preparation 11/12/14 10:52 AMD2216 66516

R23-110714 11/07/14 03:27 PM Soil Soil Prep Total Metals: ICP-MS 11/11/14 12:38 PMSW3050B 66494



R22-110714 11/07/14 03:27 PM Soil Moisture Preparation 11/12/14 10:52 AMD2216 66516



1411076-03A O26-111014 11/10/14 03:20 PM Soil Mercury Soil Prep, Total 11/11/14 09:16 AMSW7471A 66489

O26-111014 11/10/14 03:20 PM Soil Moisture Preparation 11/12/14 10:52 AMD2216 66516

O26-111014 11/10/14 03:20 PM Soil Soil Prep Total Metals: ICP-MS 11/11/14 12:38 PMSW3050B 66494


Page 1 of 1

11

Sample ID Client Sample ID Test NumberMatrix Analysis Date

ANALYTICAL DATES REPORT

14-Nov-14

Lab Order: 1411076




Test Name DilutionBatch ID Run ID

1411076-01A R23-110714 D2216Soil Percent Moisture 11/13/14 10:31 AM66516 1 PMOIST_141112A

R23-110714 SW7471BSoil Total Mercury: Soil/Solid 11/12/14 12:12 PM66489 1 CETAC2_HG_141112

D

R23-110714 SW6020ASoil Trace Metals: ICP-MS - Solid 11/13/14 11:35 AM66494 50 ICP-MS4_141113B

R23-110714 SW6020ASoil Trace Metals: ICP-MS - Solid 11/12/14 02:00 PM66494 5 ICP-MS4_141112C

1411076-02A R22-110714 D2216Soil Percent Moisture 11/13/14 10:31 AM66516 1 PMOIST_141112A


D

R22-110714 SW6020ASoil Trace Metals: ICP-MS - Solid 11/13/14 11:39 AM66494 50 ICP-MS4_141113B

R22-110714 SW6020ASoil Trace Metals: ICP-MS - Solid 11/12/14 02:06 PM66494 5 ICP-MS4_141112C

1411076-03A O26-111014 D2216Soil Percent Moisture 11/13/14 10:31 AM66516 1 PMOIST_141112A

O26-111014 SW7471BSoil Total Mercury: Soil/Solid 11/12/14 12:37 PM66489 1 CETAC2_HG_141112

D

O26-111014 SW6020ASoil Trace Metals: ICP-MS - Solid 11/13/14 11:41 AM66494 50 ICP-MS4_141113B

O26-111014 SW6020ASoil Trace Metals: ICP-MS - Solid 11/12/14 02:08 PM66494 5 ICP-MS4_141112C

Page 1 of 1

12


Client Sample ID: R23-110714

Collection Date: 11/07/14 03:27 PM

Matrix: SOIL

Analyses Result Qual Units Date Analyzed


Lab Order: 1411076

DF

Lab ID: 1411076-01

DHL Analytical, Inc. Date: 14-Nov-14

RL

Project No: 6835001.2014.49DM3

SDL

TOTAL MERCURY: SOIL/SOLID SW7471B Analyst: SMMercury 11/12/14 12:12 PM0.0380 mg/Kg-dry 1<0.0152 0.0152

TRACE METALS: ICP-MS - SOLID SW6020A Analyst: ROArsenic 11/12/14 02:00 PM0.999 mg/Kg-dry 510.3 0.500

Cadmium 11/12/14 02:00 PM0.300 mg/Kg-dry 50.428 0.0999

Chromium 11/12/14 02:00 PM2.00 mg/Kg-dry 511.9 0.500

Copper 11/12/14 02:00 PM2.00 mg/Kg-dry 580.6 0.500

Iron 11/13/14 11:35 AM125 mg/Kg-dry 5012600 125

Lead 11/12/14 02:00 PM0.300 mg/Kg-dry 534.5 0.0999

Selenium 11/12/14 02:00 PM0.500 mg/Kg-dry 50.962 0.150

Zinc 11/12/14 02:00 PM2.50 mg/Kg-dry 5293 0.999

PERCENT MOISTURE D2216 Analyst: JLPercent Moisture 11/13/14 10:31 AM0 WT% 13.78 0

Qualifiers:

Page 1 of 3

J - Analyte detected between SDL and RL

B - Analyte detected in the associated Method Blank

S - Spike Recovery outside control limits

C - Sample Result or QC discussed in Case Narrative

ND - Not Detected at the SDL

E - TPH pattern not Gas or Diesel Range Pattern

RL - Reporting Limit (MQL adjusted for moisture and sample size)

DF- Dilution Factor

See Final Page of Report for MQLs and MDLs

SDL - Sample Detection Limit

N - Parameter not NELAC certified

13




Matrix: SOIL



Lab Order: 1411076

DF

Lab ID: 1411076-02


RL

Project No: 6835001.2014.49DM3

SDL



Cadmium J 11/12/14 02:06 PM0.292 mg/Kg-dry 50.118 0.0974



Iron 11/13/14 11:39 AM122 mg/Kg-dry 5013100 122

Lead 11/12/14 02:06 PM0.292 mg/Kg-dry 58.24 0.0974


Zinc 11/12/14 02:06 PM2.44 mg/Kg-dry 542.4 0.974


Qualifiers:

Page 2 of 3








DF- Dilution Factor




14


Client Sample ID: O26-111014


Matrix: SOIL



Lab Order: 1411076

DF

Lab ID: 1411076-03


RL

Project No: 6835001.2014.49DM3

SDL

TOTAL MERCURY: SOIL/SOLID SW7471B Analyst: SMMercury J 11/12/14 12:37 PM0.0412 mg/Kg-dry 10.0227 0.0165





Iron 11/13/14 11:41 AM123 mg/Kg-dry 5010400 123

Lead 11/12/14 02:08 PM0.294 mg/Kg-dry 57.19 0.0981


Zinc 11/12/14 02:08 PM2.45 mg/Kg-dry 533.6 0.981


Qualifiers:

Page 3 of 3








DF- Dilution Factor




15




Work Order: 1411076ANALYTICAL QC SUMMARY REPORT

RunID: CETAC2_HG_141112DThe QC data in batch 66489 applies to the following samples: 1411076-01A, 1411076-02A, 1411076-03A

Sample ID MB-66489 Batch ID: 66489 TestNo: SW7471B

Analysis Date: 11/12/2014 12:03:24 P

Analyte Result SPK value Ref Val %REC %RPDLowLimit HighLimit RPDLimit Qual

Units: mg/Kg

RL

MBLKSampType: Run ID: CETAC2_HG_141112D Prep Date: 11/11/2014

Mercury 0.0400<0.0160

Sample ID LCS-66489 Batch ID: 66489 TestNo: SW7471B

Analysis Date: 11/12/2014 12:05:40 P


Units: mg/Kg

RL

LCSSampType: Run ID: CETAC2_HG_141112D Prep Date: 11/11/2014

Mercury 0.2000 110 85 1150.0400 00.221

Sample ID LCSD-66489 Batch ID: 66489 TestNo: SW7471B

Analysis Date: 11/12/2014 12:07:56 P


Units: mg/Kg

RL

LCSDSampType: Run ID: CETAC2_HG_141112D Prep Date: 11/11/2014

Mercury 0.2000 111 85 115 250.0400 0 0.4510.222

Sample ID DCS-66489 Batch ID: 66489 TestNo: SW7471B

Analysis Date: 11/12/2014 12:10:13 P


Units: mg/Kg

RL

DCSSampType: Run ID: CETAC2_HG_141112D Prep Date: 11/11/2014

Mercury 0.02000 112 60 1400.0400 00.0223

Sample ID 1411076-01A SD Batch ID: 66489 TestNo: SW7471B

Analysis Date: 11/12/2014 12:14:46 P


Units: mg/Kg-dry

RL

SDSampType: Run ID: CETAC2_HG_141112D Prep Date: 11/11/2014

Mercury 0 100.190 0 0<0.0761

Sample ID 1411076-01A PDS Batch ID: 66489 TestNo: SW7471B

Analysis Date: 11/12/2014 12:17:01 P


Units: mg/Kg-dry

RL

PDSSampType: Run ID: CETAC2_HG_141112D Prep Date: 11/11/2014

Mercury 0.2377 108 85 1150.0380 00.256

Sample ID 1411076-01A MS Batch ID: 66489 TestNo: SW7471B

Analysis Date: 11/12/2014 12:19:16 P


Units: mg/Kg-dry

RL

MSSampType: Run ID: CETAC2_HG_141112D Prep Date: 11/11/2014

Mercury 0.1999 114 80 1200.0400 00.229

Qualifiers:

Page 1 of 12B Analyte detected in the associated Method Blank DF Dilution Factor

J Analyte detected between MDL and RL MDL Method Detection Limit

ND Not Detected at the Method Detection Limit R RPD outside accepted control limits

RL Reporting Limit S Spike Recovery outside control limits

J Analyte detected between SDL and RL N Parameter not NELAC certified

16




RunID: CETAC2_HG_141112D

Sample ID 1411076-01A MSD Batch ID: 66489 TestNo: SW7471B

Analysis Date: 11/12/2014 12:21:32 P


Units: mg/Kg-dry

RL

MSDSampType: Run ID: CETAC2_HG_141112D Prep Date: 11/11/2014

Mercury 0.1851 115 80 120 250.0370 0 7.260.213

Qualifiers:






17





Sample ID ICV-141112 Batch ID: R76309 TestNo: SW7471B

Analysis Date: 11/12/2014 11:58:50 A


Units: mg/Kg

RL

ICVSampType: Run ID: CETAC2_HG_141112D Prep Date:

Mercury 0.004000 105 90 1100.0400 00.00420

Sample ID CCV1-141112 Batch ID: R76309 TestNo: SW7471B

Analysis Date: 11/12/2014 12:28:22 P


Units: mg/Kg

RL

CCVSampType: Run ID: CETAC2_HG_141112D Prep Date:

Mercury 0.002000 102 90 1100.0400 00.00203


Analysis Date: 11/12/2014 12:39:46 P


Units: mg/Kg

RL

CCVSampType: Run ID: CETAC2_HG_141112D Prep Date:

Mercury 0.002000 103 90 1100.0400 00.00205

Qualifiers:






18




RunID: ICP-MS4_141110A

Sample ID DCS1-66455 Batch ID: 66455 TestNo: SW6020A

Analysis Date: 11/10/2014 11:31:00 A


Units: mg/Kg

RL

DCSSampType: Run ID: ICP-MS4_141110A Prep Date: 11/7/2014

Arsenic 0.1500 113 80 120 01.00 0 00.169

Cadmium 0.1500 99.7 80 120 00.300 0 00.150

Chromium 0.1500 116 80 120 02.00 0 00.174

Copper 0.1500 97.0 80 120 02.00 0 00.146

Iron 6.250 106 80 120 012.5 0 06.64

Lead 0.1500 102 80 120 00.300 0 00.152

Selenium 0.1500 118 80 120 00.500 0 00.178


Analysis Date: 11/10/2014 11:35:00 A


Units: mg/Kg

RL


Zinc 5.000 106 80 120 02.50 0 05.31

Qualifiers:






19




RunID: ICP-MS4_141112CThe QC data in batch 66494 applies to the following samples: 1411076-01A, 1411076-02A, 1411076-03A

Sample ID MB-66494 Batch ID: 66494 TestNo: SW6020A

Analysis Date: 11/12/2014 1:52:00 PM


Units: mg/Kg

RL

MBLKSampType: Run ID: ICP-MS4_141112C Prep Date: 11/11/2014

Arsenic 1.00<0.500

Cadmium 0.300<0.100

Chromium 2.00<0.500

Copper 2.00<0.500

Iron 12.5<12.5

Lead 0.300<0.100

Selenium 0.500<0.150

Zinc 2.501.17

Sample ID LCS-66494 Batch ID: 66494 TestNo: SW6020A

Analysis Date: 11/12/2014 1:54:00 PM


Units: mg/Kg

RL

LCSSampType: Run ID: ICP-MS4_141112C Prep Date: 11/11/2014

Arsenic 50.00 104 80 1201.00 051.8

Cadmium 50.00 103 80 1200.300 051.5

Chromium 50.00 108 80 1202.00 054.0

Copper 50.00 108 80 1202.00 054.0

Iron 250.0 102 80 12012.5 0255

Lead 50.00 101 80 1200.300 050.3

Selenium 50.00 103 80 1200.500 051.6

Zinc 50.00 110 80 1202.50 054.8

Sample ID LCSD-66494 Batch ID: 66494 TestNo: SW6020A

Analysis Date: 11/12/2014 1:56:00 PM


Units: mg/Kg

RL

LCSDSampType: Run ID: ICP-MS4_141112C Prep Date: 11/11/2014

Arsenic 50.00 102 80 120 201.00 0 1.1751.2

Cadmium 50.00 102 80 120 200.300 0 1.2750.8

Chromium 50.00 107 80 120 202.00 0 1.1453.4

Copper 50.00 106 80 120 202.00 0 1.8153.0

Iron 250.0 101 80 120 2012.5 0 0.606254

Lead 50.00 100 80 120 200.300 0 0.38250.1

Selenium 50.00 102 80 120 200.500 0 0.98451.1

Zinc 50.00 106 80 120 202.50 0 3.2953.0

Sample ID 1411076-01A SD Batch ID: 66494 TestNo: SW6020A

Analysis Date: 11/12/2014 2:02:00 PM


Units: mg/Kg-dry

RL

SDSampType: Run ID: ICP-MS4_141112C Prep Date: 11/11/2014

Arsenic 0 105.00 10.30 0.17010.3

Qualifiers:






20




RunID: ICP-MS4_141112C


Analysis Date: 11/12/2014 2:02:00 PM


Units: mg/Kg-dry

RL

SDSampType: Run ID: ICP-MS4_141112C Prep Date: 11/11/2014

Cadmium 0 101.50 0.4280 0<0.500

Chromium 0 109.99 11.89 1.6112.1

Copper 0 109.99 80.56 1.9582.1

Lead 0 101.50 34.47 1.6035.0

Selenium 0 102.50 0.9616 5.580.909

Zinc 0 1012.5 292.5 3.05302

Sample ID 1411076-01A PDS Batch ID: 66494 TestNo: SW6020A

Analysis Date: 11/12/2014 2:10:00 PM


Units: mg/Kg-dry

RL

PDSSampType: Run ID: ICP-MS4_141112C Prep Date: 11/11/2014

Arsenic 49.97 103 80 1200.999 10.3061.8

Cadmium 49.97 102 80 1200.300 0.428051.6

Chromium 49.97 107 80 1202.00 11.8965.1

Copper 49.97 106 80 1202.00 80.56134

Lead 49.97 104 80 1200.300 34.4786.6

Selenium 49.97 103 80 1200.500 0.961652.3

Zinc 49.97 106 80 1202.50 292.5345

Sample ID 1411076-01A MS Batch ID: 66494 TestNo: SW6020A

Analysis Date: 11/12/2014 2:12:00 PM


Units: mg/Kg-dry

RL

MSSampType: Run ID: ICP-MS4_141112C Prep Date: 11/11/2014

Arsenic 49.49 105 80 1200.990 10.3062.2

Cadmium 49.49 103 80 1200.297 0.428051.5

Chromium 49.49 109 80 1201.98 11.8965.7

Copper 49.49 148 80 120 S1.98 80.56154

Iron 247.5 818 80 120 S12.4 1272014700

Lead 49.49 110 80 1200.297 34.4788.8

Selenium 49.49 100 80 1200.495 0.961650.7

Zinc 49.49 140 80 120 S2.47 292.5362

Sample ID 1411076-01A MSD Batch ID: 66494 TestNo: SW6020A

Analysis Date: 11/12/2014 2:14:00 PM


Units: mg/Kg-dry

RL

MSDSampType: Run ID: ICP-MS4_141112C Prep Date: 11/11/2014

Arsenic 47.67 104 80 120 200.953 10.30 3.8759.8

Cadmium 47.67 99.9 80 120 200.286 0.4280 6.8748.1

Chromium 47.67 106 80 120 201.91 11.89 5.4562.2

Copper 47.67 140 80 120 20 S1.91 80.56 4.30147

Iron 238.4 226 80 120 20 S11.9 12720 10.613300

Qualifiers:






21






Analysis Date: 11/12/2014 2:14:00 PM


Units: mg/Kg-dry

RL

MSDSampType: Run ID: ICP-MS4_141112C Prep Date: 11/11/2014

Lead 47.67 104 80 120 200.286 34.47 5.2784.3

Selenium 47.67 101 80 120 200.477 0.9616 3.4949.0

Zinc 47.67 141 80 120 20 S2.38 292.5 0.497360

Qualifiers:






22





Sample ID ICV-141112 Batch ID: R76322 TestNo: SW6020A

Analysis Date: 11/12/2014 10:35:00 A


Units: mg/L

RL

ICVSampType: Run ID: ICP-MS4_141112C Prep Date:

Arsenic 0.100 97.9 90 1100.00500 00.0979

Cadmium 0.100 99.4 90 1100.00100 00.0994

Chromium 0.100 103 90 1100.00500 00.103

Copper 0.100 101 90 1100.0100 00.101

Iron 2.50 101 90 1100.100 02.52

Lead 0.100 98.0 90 1100.00100 00.0980

Selenium 0.100 96.8 90 1100.00500 00.0968

Zinc 0.100 101 90 1100.00500 00.101

Sample ID LCVL-141112 Batch ID: R76322 TestNo: SW6020A

Analysis Date: 11/12/2014 10:41:00 A


Units: mg/L

RL

LCVLSampType: Run ID: ICP-MS4_141112C Prep Date:

Arsenic 0.00500 101 70 1300.00500 00.00505

Cadmium 0.00100 107 70 1300.00100 00.00107

Chromium 0.00500 108 70 1300.00500 00.00541

Copper 0.00500 99.4 70 1300.0100 00.00497

Iron 0.100 100 70 1300.100 00.100

Lead 0.00100 99.0 70 1300.00100 00.000990

Selenium 0.00500 105 70 1300.00500 00.00523

Zinc 0.00500 104 70 1300.00500 00.00519

Sample ID CCV4-141112 Batch ID: R76322 TestNo: SW6020A

Analysis Date: 11/12/2014 1:38:00 PM


Units: mg/L

RL

CCVSampType: Run ID: ICP-MS4_141112C Prep Date:

Arsenic 0.200 99.0 90 1100.00500 00.198

Cadmium 0.200 99.0 90 1100.00100 00.198

Chromium 0.200 105 90 1100.00500 00.210

Copper 0.200 102 90 1100.0100 00.204

Iron 5.00 104 90 1100.100 05.22

Lead 0.200 98.3 90 1100.00100 00.197

Selenium 0.200 98.8 90 1100.00500 00.198

Zinc 0.200 102 90 1100.00500 00.204

Sample ID LCVL4-141112 Batch ID: R76322 TestNo: SW6020A

Analysis Date: 11/12/2014 1:46:00 PM


Units: mg/L

RL


Arsenic 0.00500 103 70 1300.00500 00.00515

Cadmium 0.00100 104 70 1300.00100 00.00104

Qualifiers:






23






Analysis Date: 11/12/2014 1:46:00 PM


Units: mg/L

RL


Chromium 0.00500 109 70 1300.00500 00.00545

Copper 0.00500 99.7 70 1300.0100 00.00499

Iron 0.100 102 70 1300.100 00.102

Lead 0.00100 97.4 70 1300.00100 00.000974

Selenium 0.00500 99.7 70 1300.00500 00.00499

Zinc 0.00500 105 70 1300.00500 00.00524


Analysis Date: 11/12/2014 2:27:00 PM


Units: mg/L

RL

CCVSampType: Run ID: ICP-MS4_141112C Prep Date:

Arsenic 0.200 98.9 90 1100.00500 00.198

Cadmium 0.200 99.2 90 1100.00100 00.198

Chromium 0.200 103 90 1100.00500 00.207

Copper 0.200 102 90 1100.0100 00.204

Iron 5.00 102 90 1100.100 05.12

Lead 0.200 98.1 90 1100.00100 00.196

Selenium 0.200 99.4 90 1100.00500 00.199

Zinc 0.200 101 90 1100.00500 00.202


Analysis Date: 11/12/2014 2:32:00 PM


Units: mg/L

RL


Arsenic 0.00500 100 70 1300.00500 00.00501

Cadmium 0.00100 106 70 1300.00100 00.00106

Chromium 0.00500 109 70 1300.00500 00.00545

Copper 0.00500 97.2 70 1300.0100 00.00486

Iron 0.100 99.5 70 1300.100 00.0995

Lead 0.00100 99.2 70 1300.00100 00.000992

Selenium 0.00500 105 70 1300.00500 00.00523

Zinc 0.00500 104 70 1300.00500 00.00520

Qualifiers:






24




RunID: ICP-MS4_141113BThe QC data in batch 66494 applies to the following samples: 1411076-01A, 1411076-02A, 1411076-03A


Analysis Date: 11/13/2014 11:37:00 A


Units: mg/Kg-dry

RL

SDSampType: Run ID: ICP-MS4_141113B Prep Date: 11/11/2014

Iron 0 10625 12600 0.62612500


Analysis Date: 11/13/2014 11:43:00 A


Units: mg/Kg-dry

RL

PDSSampType: Run ID: ICP-MS4_141113B Prep Date: 11/11/2014

Iron 12490 108 80 120125 1260026100

Qualifiers:






25




RunID: ICP-MS4_141113B


Analysis Date: 11/13/2014 11:23:00 A


Units: mg/L

RL

ICVSampType: Run ID: ICP-MS4_141113B Prep Date:

Iron 2.50 98.5 90 1100.100 02.46


Analysis Date: 11/13/2014 11:28:00 A


Units: mg/L

RL

LCVLSampType: Run ID: ICP-MS4_141113B Prep Date:

Iron 0.100 100 70 1300.100 00.100


Analysis Date: 11/13/2014 11:44:00 A


Units: mg/L

RL

CCVSampType: Run ID: ICP-MS4_141113B Prep Date:

Iron 5.00 103 90 1100.100 05.16


Analysis Date: 11/13/2014 11:53:00 A


Units: mg/L

RL


Iron 0.100 101 70 1300.100 00.101

Qualifiers:






26




RunID: PMOIST_141112AThe QC data in batch 66516 applies to the following samples: 1411076-01A, 1411076-02A, 1411076-03A

Sample ID 1411073-02A-DUP Batch ID: 66516 TestNo: D2216

Analysis Date: 11/13/2014 10:31:00 A


Units: WT%

RL

DUPSampType: Run ID: PMOIST_141112A Prep Date: 11/12/2014

Percent Moisture 0 300 22.48 5.0021.4

Qualifiers:






27




Work Order: 1411076MQL SUMMARY REPORT

TestNo: SW7471B

mg/KgAnalyte

MQL

mg/Kg

MDL

Mercury 0.04000.0160

TestNo: SW6020A

mg/KgAnalyte

MQL

mg/Kg

MDL

Arsenic 1.000.500

Cadmium 0.3000.100

Chromium 2.000.500

Copper 2.000.500

Iron 12.512.5

Lead 0.3000.100

Selenium 0.5000.150

Zinc 2.501.00

Qualifiers:

Page 1 of 1

MQL -Method Quantitation Limit as defined by TRRP

MDL -Method Detection Limit as defined by TRRP

28

November 17, 2014


Dear Kyrie Jeffery:


Order No.: 1411094FAX (720) 344-3535

TEL: (720) 344-3851





Sincerely,





1

Table of Contents


.................................................................................. 9CaseNarrative 1411094







2




Reviewer Name: Angie O’Donnell Laboratory Work Order: 1411094









4) Were blank concentrations < MQL? X R6 OI Laboratory Control Samples (LCS):







R10 OI Other Problems/Anomalies 1) Are all known problems/anomalies/special conditions noted in this LRC and ER? X

2) Was applicable and available technology used to lower the SDL to minimize the matrix interference affects on the sample results? X


6























method? X









applicable? X



X

7

RG-366/TRRP-13 May 2010

















________________________


11/17/14

8





The samples were analyzed using the methods outlined in the following references:



Method D2216 - Percent Moisture Analysis


The samples were received and log-in performed on 11/12/2014. A total of 2 samples were received

and analyzed. The samples arrived in good condition and were properly packaged.


For Metals Analysis, the recoveries of three analytes for the Matrix Spike and Matrix Spike Duplicate

(1411094-01 MS/MSD) were outside of the method control limits. These are flagged accordingly in

the QC Summary Report. These analytes were within method control limits in the associated LCS. No

further corrective action was taken.

Page 1 of 1

9






1411094-01 O27-111114 11/11/14 01:00 PM 11/12/2014

1411094-02 N27-111114 11/11/14 01:05 PM 11/12/2014

Page 1 of 1

10


PREP DATES REPORT

17-Nov-14

Lab Order: 1411094





1411094-01A O27-111114 11/11/14 01:00 PM Soil Mercury Soil Prep, Total 11/13/14 09:36 AMSW7471A 66526


O27-111114 11/11/14 01:00 PM Soil Soil Prep Total Metals: ICP-MS 11/13/14 09:36 AMSW3050B 66525




1411094-02A N27-111114 11/11/14 01:05 PM Soil Mercury Soil Prep, Total 11/13/14 09:36 AMSW7471A 66526

N27-111114 11/11/14 01:05 PM Soil Moisture Preparation 11/12/14 10:52 AMD2216 66516

N27-111114 11/11/14 01:05 PM Soil Soil Prep Total Metals: ICP-MS 11/13/14 09:36 AMSW3050B 66525




Page 1 of 1

11



17-Nov-14

Lab Order: 1411094







B

O27-111114 SW6020ASoil Trace Metals: ICP-MS - Solid 11/14/14 11:24 AM66525 5 ICP-MS4_141114A

O27-111114 SW6020ASoil Trace Metals: ICP-MS - Solid 11/14/14 11:16 AM66525 50 ICP-MS4_141114A

O27-111114 SW6020ASoil Trace Metals: ICP-MS - Solid 11/13/14 04:33 PM66525 50 ICP-MS4_141113B


1411094-02A N27-111114 D2216Soil Percent Moisture 11/13/14 10:31 AM66516 1 PMOIST_141112A

N27-111114 SW7471BSoil Total Mercury: Soil/Solid 11/14/14 12:20 PM66526 1 CETAC2_HG_141114

B

N27-111114 SW6020ASoil Trace Metals: ICP-MS - Solid 11/14/14 11:28 AM66525 5 ICP-MS4_141114A

N27-111114 SW6020ASoil Trace Metals: ICP-MS - Solid 11/14/14 11:20 AM66525 50 ICP-MS4_141114A

N27-111114 SW6020ASoil Trace Metals: ICP-MS - Solid 11/13/14 04:39 PM66525 50 ICP-MS4_141113B


Page 1 of 1

12




Matrix: SOIL



Lab Order: 1411094

DF

Lab ID: 1411094-01


RL

Project No: 6835001.2014.49DM3

SDL




Chromium 11/14/14 11:24 AM1.86 mg/Kg-dry 59.09 0.466

Copper 11/13/14 04:20 PM1.86 mg/Kg-dry 5106 0.466

Iron 11/14/14 11:16 AM117 mg/Kg-dry 5011000 117

Lead 11/13/14 04:20 PM0.280 mg/Kg-dry 525.5 0.0932


Zinc 11/13/14 04:20 PM2.33 mg/Kg-dry 5207 0.932


Qualifiers:

Page 1 of 2








DF- Dilution Factor




13


Client Sample ID: N27-111114


Matrix: SOIL



Lab Order: 1411094

DF

Lab ID: 1411094-02


RL

Project No: 6835001.2014.49DM3

SDL

TOTAL MERCURY: SOIL/SOLID SW7471B Analyst: SMMercury 11/14/14 12:20 PM0.0428 mg/Kg-dry 10.0495 0.0171





Iron 11/14/14 11:20 AM127 mg/Kg-dry 5014100 127

Lead 11/13/14 04:26 PM0.304 mg/Kg-dry 595.3 0.101


Zinc 11/13/14 04:39 PM25.3 mg/Kg-dry 50738 10.1


Qualifiers:

Page 2 of 2








DF- Dilution Factor




14







Analysis Date: 11/12/2014 12:10:13 P


Units: mg/Kg

RL


Mercury 0.02000 112 60 140 00.0400 0 00.0223

Qualifiers:






15




RunID: CETAC2_HG_141114BThe QC data in batch 66526 applies to the following samples: 1411094-01A, 1411094-02A


Analysis Date: 11/14/2014 11:58:33 A


Units: mg/Kg

RL

MBLKSampType: Run ID: CETAC2_HG_141114B Prep Date: 11/13/2014

Mercury 0.0400<0.0160


Analysis Date: 11/14/2014 12:00:48 P


Units: mg/Kg

RL

LCSSampType: Run ID: CETAC2_HG_141114B Prep Date: 11/13/2014

Mercury 0.2000 114 85 1150.0400 00.228


Analysis Date: 11/14/2014 12:07:37 P


Units: mg/Kg-dry

RL

SDSampType: Run ID: CETAC2_HG_141114B Prep Date: 11/13/2014

Mercury 0 100.178 0 0<0.0711


Analysis Date: 11/14/2014 12:09:52 P


Units: mg/Kg-dry

RL

PDSSampType: Run ID: CETAC2_HG_141114B Prep Date: 11/13/2014

Mercury 0.2221 90.4 85 1150.0355 00.201


Analysis Date: 11/14/2014 12:12:07 P


Units: mg/Kg-dry

RL

MSSampType: Run ID: CETAC2_HG_141114B Prep Date: 11/13/2014

Mercury 0.1774 114 80 1200.0355 00.201


Analysis Date: 11/14/2014 12:14:23 P


Units: mg/Kg-dry

RL

MSDSampType: Run ID: CETAC2_HG_141114B Prep Date: 11/13/2014

Mercury 0.1940 115 80 120 250.0388 0 9.770.222


Analysis Date: 11/14/2014 12:18:15 P


Units: mg/Kg

RL

LCSDSampType: Run ID: CETAC2_HG_141114B Prep Date: 11/13/2014

Mercury 0.2000 112 85 115 250.0400 0 1.320.225

Qualifiers:






16




RunID: CETAC2_HG_141114B


Analysis Date: 11/14/2014 11:53:59 A


Units: mg/Kg

RL

ICVSampType: Run ID: CETAC2_HG_141114B Prep Date:

Mercury 0.004000 101 90 1100.0400 00.00403


Analysis Date: 11/14/2014 12:25:06 P


Units: mg/Kg

RL

CCVSampType: Run ID: CETAC2_HG_141114B Prep Date:

Mercury 0.002000 104 90 1100.0400 00.00209

Qualifiers:






17






Analysis Date: 11/10/2014 11:31:00 A


Units: mg/Kg

RL


Arsenic 0.1500 113 80 120 01.00 0 00.169

Cadmium 0.1500 99.7 80 120 00.300 0 00.150

Chromium 0.1500 116 80 120 02.00 0 00.174

Copper 0.1500 97.0 80 120 02.00 0 00.146

Iron 6.250 106 80 120 012.5 0 06.64

Lead 0.1500 102 80 120 00.300 0 00.152

Selenium 0.1500 118 80 120 00.500 0 00.178


Analysis Date: 11/10/2014 11:35:00 A


Units: mg/Kg

RL


Zinc 5.000 106 80 120 02.50 0 05.31

Qualifiers:






18




RunID: ICP-MS4_141113AThe QC data in batch 66525 applies to the following samples: 1411094-01A, 1411094-02A


Analysis Date: 11/13/2014 4:12:00 PM


Units: mg/Kg

RL

MBLKSampType: Run ID: ICP-MS4_141113A Prep Date: 11/13/2014

Arsenic 1.00<0.500


Analysis Date: 11/13/2014 4:14:00 PM


Units: mg/Kg

RL

LCSSampType: Run ID: ICP-MS4_141113A Prep Date: 11/13/2014

Arsenic 50.00 101 80 1201.00 050.4


Analysis Date: 11/13/2014 4:16:00 PM


Units: mg/Kg

RL

LCSDSampType: Run ID: ICP-MS4_141113A Prep Date: 11/13/2014

Arsenic 50.00 100 80 1201.00 050.1


Analysis Date: 11/13/2014 4:22:00 PM


Units: mg/Kg-dry

RL

SDSampType: Run ID: ICP-MS4_141113A Prep Date: 11/13/2014

Arsenic 0 104.66 7.274 1.177.36


Analysis Date: 11/13/2014 4:28:00 PM


Units: mg/Kg-dry

RL

PDSSampType: Run ID: ICP-MS4_141113A Prep Date: 11/13/2014

Arsenic 46.62 103 80 1200.932 7.27455.3


Analysis Date: 11/13/2014 4:30:00 PM


Units: mg/Kg-dry

RL

MSSampType: Run ID: ICP-MS4_141113A Prep Date: 11/13/2014

Arsenic 44.61 98.6 80 1200.892 7.27451.3


Analysis Date: 11/13/2014 4:31:00 PM


Units: mg/Kg-dry

RL

MSDSampType: Run ID: ICP-MS4_141113A Prep Date: 11/13/2014

Arsenic 46.21 94.7 80 120 250.924 7.274 0.45751.0

Qualifiers:






19






Analysis Date: 11/13/2014 11:23:00 A


Units: mg/L

RL

ICVSampType: Run ID: ICP-MS4_141113A Prep Date:

Arsenic 0.100 98.5 90 1100.00500 00.0985


Analysis Date: 11/13/2014 11:28:00 A


Units: mg/L

RL

LCVLSampType: Run ID: ICP-MS4_141113A Prep Date:

Arsenic 0.00500 102 70 1300.00500 00.00512


Analysis Date: 11/13/2014 4:00:00 PM


Units: mg/L

RL

CCVSampType: Run ID: ICP-MS4_141113A Prep Date:

Arsenic 0.200 99.8 90 1100.00500 00.200


Analysis Date: 11/13/2014 4:08:00 PM


Units: mg/L

RL


Arsenic 0.00500 95.7 70 1300.00500 00.00478


Analysis Date: 11/13/2014 5:06:00 PM


Units: mg/L

RL


Arsenic 0.200 103 90 1100.00500 00.206


Analysis Date: 11/13/2014 5:10:00 PM


Units: mg/L

RL


Arsenic 0.00500 99.0 70 1300.00500 00.00495

Qualifiers:






20




RunID: ICP-MS4_141113BThe QC data in batch 66525 applies to the following samples: 1411094-01A, 1411094-02A


Analysis Date: 11/13/2014 4:12:00 PM


Units: mg/Kg

RL

MBLKSampType: Run ID: ICP-MS4_141113B Prep Date: 11/13/2014

Arsenic 1.00<0.500

Cadmium 0.300<0.100

Copper 2.00<0.500

Lead 0.300<0.100


Zinc 2.50<1.00


Analysis Date: 11/13/2014 4:14:00 PM


Units: mg/Kg

RL

LCSSampType: Run ID: ICP-MS4_141113B Prep Date: 11/13/2014

Arsenic 50.00 101 80 1201.00 050.4

Cadmium 50.00 104 80 1200.300 051.9

Copper 50.00 105 80 1202.00 052.7

Lead 50.00 99.6 80 1200.300 049.8

Selenium 50.00 94.5 80 1200.500 047.2

Zinc 50.00 105 80 1202.50 052.4


Analysis Date: 11/13/2014 4:16:00 PM


Units: mg/Kg

RL

LCSDSampType: Run ID: ICP-MS4_141113B Prep Date: 11/13/2014

Arsenic 50.00 100 80 120 201.00 0 0.46050.1

Cadmium 50.00 104 80 120 200.300 0 0.48852.2

Copper 50.00 105 80 120 202.00 0 0.02052.7

Lead 50.00 99.9 80 120 200.300 0 0.27349.9

Selenium 50.00 95.2 80 120 200.500 0 0.80347.6

Zinc 50.00 104 80 120 202.50 0 0.43352.2


Analysis Date: 11/13/2014 4:22:00 PM


Units: mg/Kg-dry

RL


Arsenic 0 104.66 7.274 1.177.36

Cadmium 0 101.40 0.3194 0<0.466

Copper 0 109.32 106.4 4.09111

Lead 0 101.40 25.50 0.83025.3

Selenium 0 102.33 0.6194 0<0.699

Zinc 0 1011.7 206.7 3.13213

Qualifiers:






21






Analysis Date: 11/13/2014 4:28:00 PM


Units: mg/Kg-dry

RL


Arsenic 46.62 103 80 1200.932 7.27455.3

Cadmium 46.62 107 80 1200.280 0.319450.1

Copper 46.62 113 80 1201.86 106.4159

Lead 46.62 105 80 1200.280 25.5074.6

Selenium 46.62 98.5 80 1200.466 0.619446.5

Zinc 46.62 118 80 1202.33 206.7262


Analysis Date: 11/13/2014 4:30:00 PM


Units: mg/Kg-dry

RL

MSSampType: Run ID: ICP-MS4_141113B Prep Date: 11/13/2014

Arsenic 44.61 98.6 80 1200.892 7.27451.3

Cadmium 44.61 102 80 1200.268 0.319445.8

Copper 44.61 82.5 80 1201.78 106.4143

Lead 44.61 96.3 80 1200.268 25.5068.5

Selenium 44.61 94.3 80 1200.446 0.619442.7

Zinc 44.61 -2.87 80 120 S2.23 206.7205


Analysis Date: 11/13/2014 4:31:00 PM


Units: mg/Kg-dry

RL

MSDSampType: Run ID: ICP-MS4_141113B Prep Date: 11/13/2014

Arsenic 46.21 94.7 80 120 200.924 7.274 0.45751.0

Cadmium 46.21 101 80 120 200.277 0.3194 2.5947.0

Copper 46.21 35.0 80 120 20 S1.85 106.4 15.5123

Lead 46.21 86.8 80 120 200.277 25.50 4.2565.6

Selenium 46.21 92.4 80 120 200.462 0.6194 1.5243.3

Zinc 46.21 70.2 80 120 20 S2.31 206.7 15.2239

Qualifiers:






22






Analysis Date: 11/13/2014 11:23:00 A


Units: mg/L

RL


Arsenic 0.100 98.5 90 1100.00500 00.0985

Cadmium 0.100 99.9 90 1100.00100 00.0999

Copper 0.100 102 90 1100.0100 00.102

Iron 2.50 98.5 90 1100.100 02.46

Lead 0.100 97.5 90 1100.00100 00.0975

Selenium 0.100 96.9 90 1100.00500 00.0969

Zinc 0.100 101 90 1100.00500 00.101


Analysis Date: 11/13/2014 11:28:00 A


Units: mg/L

RL


Arsenic 0.00500 102 70 1300.00500 00.00512

Cadmium 0.00100 104 70 1300.00100 00.00105

Copper 0.00500 107 70 1300.0100 00.00533

Iron 0.100 100 70 1300.100 00.100

Lead 0.00100 99.8 70 1300.00100 00.000998

Selenium 0.00500 103 70 1300.00500 00.00513

Zinc 0.00500 101 70 1300.00500 00.00505


Analysis Date: 11/13/2014 11:44:00 A


Units: mg/L

RL


Copper 0.200 106 90 1100.0100 00.211

Iron 5.00 103 90 1100.100 05.16


Analysis Date: 11/13/2014 11:53:00 A


Units: mg/L

RL


Copper 0.00500 107 70 1300.0100 00.00535

Iron 0.100 101 70 1300.100 00.101


Analysis Date: 11/13/2014 4:00:00 PM


Units: mg/L

RL


Arsenic 0.200 99.8 90 1100.00500 00.200

Cadmium 0.200 103 90 1100.00100 00.207

Copper 0.200 103 90 1100.0100 00.206

Qualifiers:






23






Analysis Date: 11/13/2014 4:00:00 PM


Units: mg/L

RL


Lead 0.200 97.2 90 1100.00100 00.194

Selenium 0.200 95.2 90 1100.00500 00.190

Zinc 0.200 103 90 1100.00500 00.205


Analysis Date: 11/13/2014 4:08:00 PM


Units: mg/L

RL


Arsenic 0.00500 95.7 70 1300.00500 00.00478

Cadmium 0.00100 98.2 70 1300.00100 00.000982

Copper 0.00500 102 70 1300.0100 00.00510

Lead 0.00100 92.0 70 1300.00100 00.000920

Selenium 0.00500 89.5 70 1300.00500 00.00448

Zinc 0.00500 104 70 1300.00500 00.00522


Analysis Date: 11/13/2014 5:06:00 PM


Units: mg/L

RL


Arsenic 0.200 103 90 1100.00500 00.206

Cadmium 0.200 106 90 1100.00100 00.213

Copper 0.200 107 90 1100.0100 00.214

Lead 0.200 102 90 1100.00100 00.203

Selenium 0.200 98.6 90 1100.00500 00.197

Zinc 0.200 107 90 1100.00500 00.213


Analysis Date: 11/13/2014 5:10:00 PM


Units: mg/L

RL


Arsenic 0.00500 99.0 70 1300.00500 00.00495

Cadmium 0.00100 109 70 1300.00100 00.00109

Copper 0.00500 106 70 1300.0100 00.00530

Lead 0.00100 99.6 70 1300.00100 00.000996

Selenium 0.00500 103 70 1300.00500 00.00517

Zinc 0.00500 106 70 1300.00500 00.00528

Qualifiers:






24




RunID: ICP-MS4_141114AThe QC data in batch 66525 applies to the following samples: 1411094-01A, 1411094-02A


Analysis Date: 11/14/2014 11:08:00 A


Units: mg/Kg

RL


Chromium 2.00<0.500

Iron 12.5<12.5


Analysis Date: 11/14/2014 11:10:00 A


Units: mg/Kg

RL


Chromium 50.00 107 80 1202.00 053.7

Iron 250.0 101 80 12012.5 0252


Analysis Date: 11/14/2014 11:12:00 A


Units: mg/Kg

RL


Chromium 50.00 108 80 120 202.00 0 0.77054.1

Iron 250.0 102 80 120 2012.5 0 1.67256


Analysis Date: 11/14/2014 11:18:00 A


Units: mg/Kg-dry

RL


Iron 0 10583 11050 3.5710700


Analysis Date: 11/14/2014 11:22:00 A


Units: mg/Kg-dry

RL


Iron 11660 104 80 120117 1105023100


Analysis Date: 11/14/2014 11:26:00 A


Units: mg/Kg-dry

RL


Chromium 0 109.32 9.087 0.6659.15


Analysis Date: 11/14/2014 11:30:00 A


Units: mg/Kg-dry

RL


Chromium 46.62 110 80 1201.86 9.08760.3

Qualifiers:






25






Analysis Date: 11/14/2014 11:32:00 A


Units: mg/Kg-dry

RL


Chromium 44.61 105 80 1201.78 9.08756.1

Iron 223.1 -119 80 120 S11.2 1094010700


Analysis Date: 11/14/2014 11:34:00 A


Units: mg/Kg-dry

RL


Chromium 46.21 110 80 120 201.85 9.087 6.6559.9

Iron 231.0 -294 80 120 20 S11.6 10940 3.9710300

Qualifiers:






26






Analysis Date: 11/14/2014 10:29:00 A


Units: mg/L

RL


Chromium 0.100 103 90 1100.00500 00.103

Iron 2.50 99.2 90 1100.100 02.48


Analysis Date: 11/14/2014 10:33:00 A


Units: mg/L

RL


Chromium 0.00500 111 70 1300.00500 00.00556

Iron 0.100 101 70 1300.100 00.101


Analysis Date: 11/14/2014 10:56:00 A


Units: mg/L

RL


Chromium 0.200 106 90 1100.00500 00.213

Iron 5.00 104 90 1100.100 05.19


Analysis Date: 11/14/2014 11:02:00 A


Units: mg/L

RL


Chromium 0.00500 111 70 1300.00500 00.00557

Iron 0.100 106 70 1300.100 00.106


Analysis Date: 11/14/2014 11:36:00 A


Units: mg/L

RL


Chromium 0.200 107 90 1100.00500 00.215

Iron 5.00 105 90 1100.100 05.23


Analysis Date: 11/14/2014 11:41:00 A


Units: mg/L

RL


Chromium 0.00500 109 70 1300.00500 00.00543

Iron 0.100 102 70 1300.100 00.102

Qualifiers:






27




RunID: PMOIST_141112AThe QC data in batch 66516 applies to the following samples: 1411094-01A, 1411094-02A


Analysis Date: 11/13/2014 10:31:00 A


Units: WT%

RL



Qualifiers:






28





TestNo: SW6020A

mg/KgAnalyte

MQL

mg/Kg

MDL

Arsenic 1.000.500

TestNo: SW7471B

mg/KgAnalyte

MQL

mg/Kg

MDL

Mercury 0.04000.0160

TestNo: SW6020A

mg/KgAnalyte

MQL

mg/Kg

MDL

Arsenic 1.000.500

Cadmium 0.3000.100

Chromium 2.000.500

Copper 2.000.500

Iron 12.512.5

Lead 0.3000.100

Selenium 0.5000.150

Zinc 2.501.00

Qualifiers:

Page 1 of 1



29

November 18, 2014


Dear Kyrie Jeffery:


Order No.: 1411118FAX (720) 344-3535

TEL: (720) 344-3851





Sincerely,





1

Table of Contents


................................................................................ 11CaseNarrative 1411118







2























8























method? X









applicable? X



X

9

RG-366/TRRP-13 May 2010

















________________________


11/18/14

10













For Metals Analysis, the recovery of Iron for the Matrix Spike and Matrix Spike Duplicate (1411104-

01 MS/MSD) was above the method control limits. These are flagged accordingly in the QC Summary

Report. This analyte was within method control limits in the associated LCS. No further corrective

action was taken.

Page 1 of 1

11






1411118-01 N28-111214 11/12/14 01:45 PM 11/14/2014

1411118-02 M28-111214 11/12/14 01:50 PM 11/14/2014

1411118-03 P24-111314 11/13/14 03:10 PM 11/14/2014

1411118-04 M27-111314 11/13/14 02:03 PM 11/14/2014

1411118-05 Q24-111314 11/13/14 03:05 PM 11/14/2014

Page 1 of 1

12


PREP DATES REPORT

18-Nov-14

Lab Order: 1411118





1411118-01A N28-111214 11/12/14 01:45 PM Soil Mercury Soil Prep, Total 11/16/14 06:20 PMSW7471A 66554

N28-111214 11/12/14 01:45 PM Soil Moisture Preparation 11/17/14 09:07 AMD2216 66562

N28-111214 11/12/14 01:45 PM Soil Soil Prep Total Metals: ICP-MS 11/16/14 06:16 PMSW3050B 66553

N28-111214 11/12/14 01:45 PM Soil Soil Prep Total Metals: ICP-MS 11/16/14 06:16 PMSW3050B 66553

1411118-02A M28-111214 11/12/14 01:50 PM Soil Mercury Soil Prep, Total 11/16/14 06:20 PMSW7471A 66554

M28-111214 11/12/14 01:50 PM Soil Moisture Preparation 11/17/14 09:07 AMD2216 66562

M28-111214 11/12/14 01:50 PM Soil Soil Prep Total Metals: ICP-MS 11/16/14 06:16 PMSW3050B 66553


1411118-03A P24-111314 11/13/14 03:10 PM Soil Mercury Soil Prep, Total 11/16/14 06:20 PMSW7471A 66554

P24-111314 11/13/14 03:10 PM Soil Moisture Preparation 11/17/14 09:07 AMD2216 66562

P24-111314 11/13/14 03:10 PM Soil Soil Prep Total Metals: ICP-MS 11/16/14 06:16 PMSW3050B 66553



M27-111314 11/13/14 02:03 PM Soil Moisture Preparation 11/17/14 09:07 AMD2216 66562



1411118-05A Q24-111314 11/13/14 03:05 PM Soil Mercury Soil Prep, Total 11/16/14 06:20 PMSW7471A 66554

Q24-111314 11/13/14 03:05 PM Soil Moisture Preparation 11/17/14 09:09 AMD2216 66563

Q24-111314 11/13/14 03:05 PM Soil Soil Prep Total Metals: ICP-MS 11/16/14 06:16 PMSW3050B 66553


Page 1 of 1

13



18-Nov-14

Lab Order: 1411118






N28-111214 SW7471BSoil Total Mercury: Soil/Solid 11/17/14 11:02 AM66554 1 CETAC2_HG_141117

A

N28-111214 SW6020ASoil Trace Metals: ICP-MS - Solid 11/17/14 11:29 AM66553 5 ICP-MS4_141117B


1411118-02A M28-111214 D2216Soil Percent Moisture 11/18/14 11:23 AM66562 1 PMOIST_141117A

M28-111214 SW7471BSoil Total Mercury: Soil/Solid 11/17/14 11:04 AM66554 1 CETAC2_HG_141117

A

M28-111214 SW6020ASoil Trace Metals: ICP-MS - Solid 11/17/14 11:31 AM66553 5 ICP-MS4_141117B


1411118-03A P24-111314 D2216Soil Percent Moisture 11/18/14 11:23 AM66562 1 PMOIST_141117A

P24-111314 SW7471BSoil Total Mercury: Soil/Solid 11/17/14 11:07 AM66554 1 CETAC2_HG_141117

A

P24-111314 SW6020ASoil Trace Metals: ICP-MS - Solid 11/17/14 11:52 AM66553 50 ICP-MS4_141117B




A



1411118-05A Q24-111314 D2216Soil Percent Moisture 11/18/14 11:26 AM66563 1 PMOIST_141117B

Q24-111314 SW7471BSoil Total Mercury: Soil/Solid 11/17/14 11:11 AM66554 1 CETAC2_HG_141117

A

Q24-111314 SW6020ASoil Trace Metals: ICP-MS - Solid 11/17/14 11:56 AM66553 50 ICP-MS4_141117B


Page 1 of 1

14




Matrix: SOIL



Lab Order: 1411118

DF

Lab ID: 1411118-01


RL

Project No: 6835001.2014.47SR2

SDL

TOTAL MERCURY: SOIL/SOLID SW7471B Analyst: SMMercury J 11/17/14 11:02 AM0.0366 mg/Kg-dry 10.0242 0.0147

TRACE METALS: ICP-MS - SOLID SW6020A Analyst: ROArsenic 11/17/14 11:29 AM1.01 mg/Kg-dry 525.0 0.507

Cadmium 11/17/14 11:29 AM0.304 mg/Kg-dry 50.452 0.101


Copper 11/17/14 11:29 AM2.03 mg/Kg-dry 579.1 0.507

Iron 11/17/14 11:48 AM127 mg/Kg-dry 5012200 127

Lead 11/17/14 11:29 AM0.304 mg/Kg-dry 526.9 0.101

Selenium 11/17/14 11:29 AM0.507 mg/Kg-dry 50.980 0.152

Zinc 11/17/14 11:29 AM2.54 mg/Kg-dry 5193 1.01


Qualifiers:

Page 1 of 5








DF- Dilution Factor




15


Client Sample ID: M28-111214


Matrix: SOIL



Lab Order: 1411118

DF

Lab ID: 1411118-02


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/17/14 11:50 AM123 mg/Kg-dry 5012400 123

Lead 11/17/14 11:31 AM0.295 mg/Kg-dry 549.1 0.0984


Zinc 11/17/14 11:31 AM2.46 mg/Kg-dry 5153 0.984


Qualifiers:

Page 2 of 5








DF- Dilution Factor




16


Client Sample ID: P24-111314


Matrix: SOIL



Lab Order: 1411118

DF

Lab ID: 1411118-03


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/17/14 11:52 AM118 mg/Kg-dry 5011400 118

Lead 11/17/14 11:33 AM0.283 mg/Kg-dry 533.4 0.0942


Zinc 11/17/14 11:33 AM2.36 mg/Kg-dry 5133 0.942


Qualifiers:

Page 3 of 5








DF- Dilution Factor




17




Matrix: SOIL



Lab Order: 1411118

DF

Lab ID: 1411118-04


RL

Project No: 6835001.2014.47SR2

SDL





Copper 11/17/14 11:35 AM1.89 mg/Kg-dry 5114 0.472

Iron 11/17/14 11:54 AM118 mg/Kg-dry 5010500 118

Lead 11/17/14 11:35 AM0.283 mg/Kg-dry 534.9 0.0945


Zinc 11/17/14 11:35 AM2.36 mg/Kg-dry 5232 0.945


Qualifiers:

Page 4 of 5








DF- Dilution Factor




18


Client Sample ID: Q24-111314


Matrix: SOIL



Lab Order: 1411118

DF

Lab ID: 1411118-05


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/17/14 11:56 AM114 mg/Kg-dry 509670 114

Lead 11/17/14 11:37 AM0.274 mg/Kg-dry 561.4 0.0912


Zinc 11/17/14 11:37 AM2.28 mg/Kg-dry 5102 0.912


Qualifiers:

Page 5 of 5








DF- Dilution Factor




19







Analysis Date: 11/12/2014 12:10:13 P


Units: mg/Kg

RL


Mercury 0.02000 112 60 140 00.0400 0 00.0223

Qualifiers:






20




RunID: CETAC2_HG_141117AThe QC data in batch 66554 applies to the following samples: 1411118-01A, 1411118-02A, 1411118-03A, 1411118-04A, 1411118-05A


Analysis Date: 11/17/2014 10:12:40 A


Units: mg/Kg

RL

MBLKSampType: Run ID: CETAC2_HG_141117A Prep Date: 11/16/2014

Mercury 0.0400<0.0160


Analysis Date: 11/17/2014 10:14:56 A


Units: mg/Kg

RL

LCSSampType: Run ID: CETAC2_HG_141117A Prep Date: 11/16/2014

Mercury 0.2000 111 85 1150.0400 00.222


Analysis Date: 11/17/2014 10:17:12 A


Units: mg/Kg

RL

LCSDSampType: Run ID: CETAC2_HG_141117A Prep Date: 11/16/2014

Mercury 0.2000 112 85 115 250.0400 0 1.340.225

Sample ID 1411104-01C SD Batch ID: 66554 TestNo: SW7471B

Analysis Date: 11/17/2014 10:21:45 A


Units: mg/Kg-dry

RL

SDSampType: Run ID: CETAC2_HG_141117A Prep Date: 11/16/2014

Mercury 0 100.210 0.02287 0<0.0839

Sample ID 1411104-01C PDS Batch ID: 66554 TestNo: SW7471B

Analysis Date: 11/17/2014 10:24:00 A


Units: mg/Kg-dry

RL

PDSSampType: Run ID: CETAC2_HG_141117A Prep Date: 11/16/2014

Mercury 0.2623 103 85 1150.0420 0.022870.293

Sample ID 1411104-01C MS Batch ID: 66554 TestNo: SW7471B

Analysis Date: 11/17/2014 10:26:15 A


Units: mg/Kg-dry

RL

MSSampType: Run ID: CETAC2_HG_141117A Prep Date: 11/16/2014

Mercury 0.2012 108 80 1200.0402 0.022870.240

Sample ID 1411104-01C MSD Batch ID: 66554 TestNo: SW7471B

Analysis Date: 11/17/2014 10:28:31 A


Units: mg/Kg-dry

RL

MSDSampType: Run ID: CETAC2_HG_141117A Prep Date: 11/16/2014

Mercury 0.2178 109 80 120 250.0436 0.02287 7.540.259

Qualifiers:






21




RunID: CETAC2_HG_141117A


Analysis Date: 11/17/2014 10:08:06 A


Units: mg/Kg

RL

ICVSampType: Run ID: CETAC2_HG_141117A Prep Date:

Mercury 0.004000 101 90 1100.0400 00.00403


Analysis Date: 11/17/2014 10:51:12 A


Units: mg/Kg

RL

CCVSampType: Run ID: CETAC2_HG_141117A Prep Date:

Mercury 0.002000 102 90 1100.0400 00.00204


Analysis Date: 11/17/2014 11:13:59 A


Units: mg/Kg

RL


Mercury 0.002000 102 90 1100.0400 00.00203

Qualifiers:






22






Analysis Date: 11/10/2014 11:31:00 A


Units: mg/Kg

RL


Arsenic 0.1500 113 80 120 01.00 0 00.169

Cadmium 0.1500 99.7 80 120 00.300 0 00.150

Chromium 0.1500 116 80 120 02.00 0 00.174

Copper 0.1500 97.0 80 120 02.00 0 00.146

Iron 6.250 106 80 120 012.5 0 06.64

Lead 0.1500 102 80 120 00.300 0 00.152

Selenium 0.1500 118 80 120 00.500 0 00.178


Analysis Date: 11/10/2014 11:35:00 A


Units: mg/Kg

RL


Zinc 5.000 106 80 120 02.50 0 05.31

Qualifiers:






23




RunID: ICP-MS4_141117BThe QC data in batch 66553 applies to the following samples: 1411118-01A, 1411118-02A, 1411118-03A, 1411118-04A, 1411118-05A


Analysis Date: 11/17/2014 10:30:00 A


Units: mg/Kg

RL


Arsenic 1.00<0.500

Cadmium 0.300<0.100

Chromium 2.00<0.500

Copper 2.00<0.500

Iron 12.5<12.5

Lead 0.300<0.100


Zinc 2.50<1.00


Analysis Date: 11/17/2014 10:32:00 A


Units: mg/Kg

RL


Arsenic 50.00 98.7 80 1201.00 049.4

Cadmium 50.00 100 80 1200.300 050.2

Chromium 50.00 102 80 1202.00 051.2

Copper 50.00 104 80 1202.00 052.2

Iron 250.0 102 80 12012.5 0255

Lead 50.00 99.2 80 1200.300 049.6

Selenium 50.00 96.7 80 1200.500 048.3

Zinc 50.00 102 80 1202.50 051.2


Analysis Date: 11/17/2014 10:34:00 A


Units: mg/Kg

RL


Arsenic 50.00 101 80 120 201.00 0 1.7950.3

Cadmium 50.00 101 80 120 200.300 0 0.52350.5

Chromium 50.00 105 80 120 202.00 0 2.6552.6

Copper 50.00 105 80 120 202.00 0 0.83552.6

Iron 250.0 105 80 120 2012.5 0 2.57262

Lead 50.00 101 80 120 200.300 0 2.1850.7

Selenium 50.00 99.4 80 120 200.500 0 2.7549.7

Zinc 50.00 103 80 120 202.50 0 0.70651.6

Sample ID 1411104-01C SD Batch ID: 66553 TestNo: SW6020A

Analysis Date: 11/17/2014 10:40:00 A


Units: mg/Kg-dry

RL


Arsenic 0 105.12 1.757 0<2.56

Qualifiers:






24






Analysis Date: 11/17/2014 10:40:00 A


Units: mg/Kg-dry

RL


Cadmium 0 101.54 0.4019 0<0.512

Chromium 0 1010.2 9.864 1.4810.0

Copper 0 1010.2 4.946 1.764.86

Lead 0 101.54 6.622 0.1666.63

Selenium 0 102.56 0.5135 0<0.768

Zinc 0 1012.8 14.89 0.88515.0

Sample ID 1411104-01C PDS Batch ID: 66553 TestNo: SW6020A

Analysis Date: 11/17/2014 10:59:00 A


Units: mg/Kg-dry

RL


Arsenic 51.20 105 80 1201.02 1.75755.4

Cadmium 51.20 106 80 1200.307 0.401954.6

Chromium 51.20 110 80 1202.05 9.86466.2

Copper 51.20 109 80 1202.05 4.94660.8

Lead 51.20 107 80 1200.307 6.62261.4

Selenium 51.20 103 80 1200.512 0.513553.5

Zinc 51.20 107 80 1202.56 14.8969.8

Sample ID 1411104-01C MS Batch ID: 66553 TestNo: SW6020A

Analysis Date: 11/17/2014 11:01:00 A


Units: mg/Kg-dry

RL


Arsenic 52.18 94.6 80 1201.04 1.75751.1

Cadmium 52.18 97.2 80 1200.313 0.401951.1

Chromium 52.18 104 80 1202.09 9.86463.9

Copper 52.18 100 80 1202.09 4.94657.4

Iron 260.9 588 80 120 S13.0 49666500

Lead 52.18 97.2 80 1200.313 6.62257.4

Selenium 52.18 90.7 80 1200.522 0.513547.8

Zinc 52.18 102 80 1202.61 14.8968.1

Sample ID 1411104-01C MSD Batch ID: 66553 TestNo: SW6020A

Analysis Date: 11/17/2014 11:03:00 A


Units: mg/Kg-dry

RL


Arsenic 47.64 93.4 80 120 200.953 1.757 9.9446.3

Cadmium 47.64 98.7 80 120 200.286 0.4019 7.4447.4

Chromium 47.64 105 80 120 201.91 9.864 6.1960.1

Copper 47.64 103 80 120 201.91 4.946 5.9154.1

Iron 238.2 318 80 120 20 S11.9 4966 12.75720

Qualifiers:






25





Sample ID 1411104-01C MSD Batch ID: 66553 TestNo: SW6020A

Analysis Date: 11/17/2014 11:03:00 A


Units: mg/Kg-dry

RL


Lead 47.64 97.9 80 120 200.286 6.622 7.3953.3

Selenium 47.64 90.4 80 120 200.476 0.5135 9.2543.6

Zinc 47.64 107 80 120 202.38 14.89 3.0666.1


Analysis Date: 11/17/2014 11:17:00 A


Units: mg/Kg-dry

RL


Iron 0 10640 5153 4.954900

Sample ID 1411104-01C PDS Batch ID: 66553 TestNo: SW6020A

Analysis Date: 11/17/2014 11:19:00 A


Units: mg/Kg-dry

RL


Iron 12800 109 80 120128 515319100

Qualifiers:






26






Analysis Date: 11/17/2014 10:17:00 A


Units: mg/L

RL


Arsenic 0.100 101 90 1100.00500 00.101

Cadmium 0.100 103 90 1100.00100 00.103

Chromium 0.100 104 90 1100.00500 00.104

Copper 0.100 105 90 1100.0100 00.105

Iron 2.50 100 90 1100.100 02.51

Lead 0.100 103 90 1100.00100 00.103

Selenium 0.100 99.7 90 1100.00500 00.0997

Zinc 0.100 105 90 1100.00500 00.105


Analysis Date: 11/17/2014 10:24:00 A


Units: mg/L

RL


Arsenic 0.00500 98.4 70 1300.00500 00.00492

Cadmium 0.00100 104 70 1300.00100 00.00104

Chromium 0.00500 107 70 1300.00500 00.00533

Copper 0.00500 103 70 1300.0100 00.00516

Iron 0.100 101 70 1300.100 00.101

Lead 0.00100 103 70 1300.00100 00.00103

Selenium 0.00500 93.8 70 1300.00500 00.00469

Zinc 0.00500 100 70 1300.00500 00.00500


Analysis Date: 11/17/2014 11:05:00 A


Units: mg/L

RL


Arsenic 0.200 99.8 90 1100.00500 00.200

Cadmium 0.200 101 90 1100.00100 00.202

Chromium 0.200 104 90 1100.00500 00.208

Copper 0.200 105 90 1100.0100 00.210

Iron 5.00 104 90 1100.100 05.22

Lead 0.200 99.6 90 1100.00100 00.199

Selenium 0.200 98.0 90 1100.00500 00.196

Zinc 0.200 102 90 1100.00500 00.203


Analysis Date: 11/17/2014 11:11:00 A


Units: mg/L

RL


Arsenic 0.00500 99.1 70 1300.00500 00.00495

Cadmium 0.00100 98.4 70 1300.00100 00.000984

Qualifiers:






27






Analysis Date: 11/17/2014 11:11:00 A


Units: mg/L

RL


Chromium 0.00500 111 70 1300.00500 00.00555

Copper 0.00500 105 70 1300.0100 00.00526

Iron 0.100 103 70 1300.100 00.103

Lead 0.00100 104 70 1300.00100 00.00105

Selenium 0.00500 103 70 1300.00500 00.00513

Zinc 0.00500 99.3 70 1300.00500 00.00496


Analysis Date: 11/17/2014 11:39:00 A


Units: mg/L

RL


Arsenic 0.200 100 90 1100.00500 00.200

Cadmium 0.200 100 90 1100.00100 00.201

Chromium 0.200 104 90 1100.00500 00.209

Copper 0.200 104 90 1100.0100 00.208

Iron 5.00 106 90 1100.100 05.28

Lead 0.200 98.6 90 1100.00100 00.197

Selenium 0.200 98.4 90 1100.00500 00.197

Zinc 0.200 102 90 1100.00500 00.203


Analysis Date: 11/17/2014 11:43:00 A


Units: mg/L

RL


Arsenic 0.00500 102 70 1300.00500 00.00510

Cadmium 0.00100 105 70 1300.00100 00.00105

Chromium 0.00500 111 70 1300.00500 00.00554

Copper 0.00500 104 70 1300.0100 00.00521

Iron 0.100 104 70 1300.100 00.104

Lead 0.00100 104 70 1300.00100 00.00105

Selenium 0.00500 98.8 70 1300.00500 00.00494

Zinc 0.00500 97.4 70 1300.00500 00.00487


Analysis Date: 11/17/2014 12:22:00 P


Units: mg/L

RL


Iron 5.00 106 90 1100.100 05.31

Qualifiers:






28






Analysis Date: 11/17/2014 12:37:00 P


Units: mg/L

RL


Iron 0.100 102 70 1300.100 00.102

Qualifiers:






29




RunID: PMOIST_141117AThe QC data in batch 66562 applies to the following samples: 1411118-01A, 1411118-02A, 1411118-03A, 1411118-04A


Analysis Date: 11/18/2014 11:23:00 A


Units: WT%

RL



Qualifiers:






30




RunID: PMOIST_141117BThe QC data in batch 66563 applies to the following samples: 1411118-05A


Analysis Date: 11/18/2014 11:26:00 A


Units: WT%

RL

DUPSampType: Run ID: PMOIST_141117B Prep Date: 11/17/2014


Qualifiers:






31





TestNo: SW7471B

mg/KgAnalyte

MQL

mg/Kg

MDL

Mercury 0.04000.0160

TestNo: SW6020A

mg/KgAnalyte

MQL

mg/Kg

MDL

Arsenic 1.000.500

Cadmium 0.3000.100

Chromium 2.000.500

Copper 2.000.500

Iron 12.512.5

Lead 0.3000.100

Selenium 0.5000.150

Zinc 2.501.00

Qualifiers:

Page 1 of 1



32

November 21, 2014


Dear Kyrie Jeffery:


Order No.: 1411137FAX (720) 344-3535

TEL: (720) 344-3851





Sincerely,





11

Table of Contents


.................................................................................. 9CaseNarrative 1411137






............................................................................ 46Sequence Report 1411137


22

















1) Were the project/method specified analytes included in the MS and MSD? X 2) Were MS/MSD analyzed at the appropriate frequency? X 3) Were MS (and MSD, if applicable) %Rs within the laboratory QC limits? X R7-03 4) Were MS/MSD RPDs within laboratory QC limits? X R7-04






66























method? X S9-01









applicable? X



X

77

RG-366/TRRP-13 May 2010

















________________________


11/21/14

88












Exception Report R7-03 and R7-04

For Metals Analysis, the recoveries of two analytes for the Matrix Spike and Matrix Spike Duplicate

(1411137-01 MS/MSD) were above the method control limits. Additionally, the RPD of Copper for

the Matrix Spike Duplicate (1411137-01 MSD) was above the method control limit. These are flagged

accordingly in the QC Summary Report. These analytes were within method control limits in the

associated LCS. No further corrective action was taken.

Exception Report S9-01

For Metals Analysis, the RPD of Selenium for the Serial Dilution (1411137-01 SD) was above the

method control limit. This is flagged accordingly in the QC Summary Report. This analyte was within

method control limits in the associated Post Digestion Spike. No further corrective action was taken.

Page 1 of 1

99






1411137-01 Q23-111314 11/13/14 03:10 PM 11/18/2014

1411137-02 Q22-111314 11/13/14 02:15 PM 11/18/2014

1411137-03 E04-111314 11/13/14 02:55 PM 11/18/2014

1411137-04 E03-111414 11/14/14 09:15 AM 11/18/2014

1411137-05 E05-111314 11/13/14 02:45 PM 11/18/2014

1411137-06 E06-111414 11/14/14 09:22 AM 11/18/2014

1411137-07 F03-111414 11/14/14 09:12 AM 11/18/2014

1411137-08 F04-111414 11/14/14 09:10 AM 11/18/2014

1411137-09 F05-111414 11/14/14 09:18 AM 11/18/2014

1411137-10 P21-111714 11/17/14 02:03 PM 11/18/2014

1411137-11 P19-111714 11/17/14 02:10 PM 11/18/2014

1411137-12 P20-111714 11/17/14 02:06 PM 11/18/2014

1411137-13 P22-111714 11/17/14 02:00 PM 11/18/2014

1411137-14 O20-111714 11/17/14 02:10 PM 11/18/2014

1411137-15 P23-111714 11/17/14 01:55 PM 11/18/2014

Page 1 of 1

1010


PREP DATES REPORT

21-Nov-14

Lab Order: 1411137













1411137-03A E04-111314 11/13/14 02:55 PM Soil Mercury Soil Prep, Total 11/18/14 03:45 PMSW7471A 66601

E04-111314 11/13/14 02:55 PM Soil Moisture Preparation 11/19/14 11:43 AMD2216 66613

E04-111314 11/13/14 02:55 PM Soil Soil Prep Total Metals: ICP-MS 11/18/14 03:45 PMSW3050B 66602


1411137-04A E03-111414 11/14/14 09:15 AM Soil Mercury Soil Prep, Total 11/18/14 03:45 PMSW7471A 66601

E03-111414 11/14/14 09:15 AM Soil Moisture Preparation 11/19/14 11:43 AMD2216 66613

E03-111414 11/14/14 09:15 AM Soil Soil Prep Total Metals: ICP-MS 11/18/14 03:45 PMSW3050B 66602


1411137-05A E05-111314 11/13/14 02:45 PM Soil Mercury Soil Prep, Total 11/18/14 03:45 PMSW7471A 66601

E05-111314 11/13/14 02:45 PM Soil Moisture Preparation 11/19/14 11:43 AMD2216 66613







1411137-07A F03-111414 11/14/14 09:12 AM Soil Mercury Soil Prep, Total 11/18/14 03:45 PMSW7471A 66601

F03-111414 11/14/14 09:12 AM Soil Moisture Preparation 11/19/14 11:43 AMD2216 66613

F03-111414 11/14/14 09:12 AM Soil Soil Prep Total Metals: ICP-MS 11/18/14 03:45 PMSW3050B 66602


Page 1 of 3

1111


PREP DATES REPORT

21-Nov-14

Lab Order: 1411137





























1411137-14A O20-111714 11/17/14 02:10 PM Soil Mercury Soil Prep, Total 11/18/14 03:45 PMSW7471A 66601




Page 2 of 3

1212


PREP DATES REPORT

21-Nov-14

Lab Order: 1411137









Page 3 of 3

1313



21-Nov-14

Lab Order: 1411137





1411137-01A Q23-111314 D2216Soil Percent Moisture 11/20/14 10:52 AM66613 1 PMOIST_141119A

Q23-111314 SW7471BSoil Total Mercury: Soil/Solid 11/20/14 01:44 PM66601 1 CETAC2_HG_141120

C

Q23-111314 SW6020ASoil Trace Metals: ICP-MS - Solid 11/19/14 04:01 PM66602 5 ICP-MS4_141119A


1411137-02A Q22-111314 D2216Soil Percent Moisture 11/20/14 10:52 AM66613 1 PMOIST_141119A


C

Q22-111314 SW6020ASoil Trace Metals: ICP-MS - Solid 11/19/14 04:05 PM66602 5 ICP-MS4_141119A


1411137-03A E04-111314 D2216Soil Percent Moisture 11/20/14 10:52 AM66613 1 PMOIST_141119A

E04-111314 SW7471BSoil Total Mercury: Soil/Solid 11/20/14 01:58 PM66601 1 CETAC2_HG_141120

C

E04-111314 SW6020ASoil Trace Metals: ICP-MS - Solid 11/19/14 04:07 PM66602 5 ICP-MS4_141119A

E04-111314 SW6020ASoil Trace Metals: ICP-MS - Solid 11/20/14 11:41 AM66602 50 ICP-MS4_141120B



C





C





C



1411137-07A F03-111414 D2216Soil Percent Moisture 11/20/14 10:52 AM66613 1 PMOIST_141119A

Page 1 of 3

1414



21-Nov-14

Lab Order: 1411137





1411137-07A F03-111414 SW7471BSoil Total Mercury: Soil/Solid 11/20/14 02:07 PM66601 1 CETAC2_HG_141120

C

F03-111414 SW6020ASoil Trace Metals: ICP-MS - Solid 11/19/14 04:14 PM66602 5 ICP-MS4_141119A

F03-111414 SW6020ASoil Trace Metals: ICP-MS - Solid 11/20/14 11:49 AM66602 50 ICP-MS4_141120B


F04-111414 SW7471BSoil Total Mercury: Soil/Solid 11/20/14 02:09 PM66601 1 CETAC2_HG_141120

C





C




P21-111714 SW7471BSoil Total Mercury: Soil/Solid 11/20/14 02:14 PM66601 1 CETAC2_HG_141120

C

P21-111714 SW6020ASoil Trace Metals: ICP-MS - Solid 11/19/14 04:20 PM66602 5 ICP-MS4_141119A




C


P19-111714 SW6020ASoil Trace Metals: ICP-MS - Solid 11/20/14 12:10 PM66602 50 ICP-MS4_141120B



C





C

Page 2 of 3

1515



21-Nov-14

Lab Order: 1411137





1411137-13A P22-111714 SW6020ASoil Trace Metals: ICP-MS - Solid 11/19/14 05:00 PM66602 5 ICP-MS4_141119A




C

O20-111714 SW6020ASoil Trace Metals: ICP-MS - Solid 11/19/14 05:02 PM66602 5 ICP-MS4_141119A




C



Page 3 of 3

1616




Matrix: SOIL



Lab Order: 1411137

DF

Lab ID: 1411137-01


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/20/14 11:35 AM122 mg/Kg-dry 5013700 122

Lead 11/19/14 04:01 PM0.293 mg/Kg-dry 531.5 0.0977


Zinc 11/19/14 04:01 PM2.44 mg/Kg-dry 5286 0.977


Qualifiers:

Page 1 of 15








DF- Dilution Factor




1717




Matrix: SOIL



Lab Order: 1411137

DF

Lab ID: 1411137-02


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/20/14 11:39 AM114 mg/Kg-dry 5013700 114

Lead 11/19/14 04:05 PM0.273 mg/Kg-dry 560.3 0.0911


Zinc 11/19/14 04:05 PM2.28 mg/Kg-dry 5454 0.911


Qualifiers:

Page 2 of 15








DF- Dilution Factor




1818


Client Sample ID: E04-111314


Matrix: SOIL



Lab Order: 1411137

DF

Lab ID: 1411137-03


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/20/14 11:41 AM130 mg/Kg-dry 5011100 130

Lead 11/19/14 04:07 PM0.312 mg/Kg-dry 5109 0.104


Zinc 11/19/14 04:07 PM2.60 mg/Kg-dry 5240 1.04


Qualifiers:

Page 3 of 15








DF- Dilution Factor




1919



Collection Date: 11/14/14 09:15 AM

Matrix: SOIL



Lab Order: 1411137

DF

Lab ID: 1411137-04


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/20/14 11:43 AM121 mg/Kg-dry 5010100 121

Lead 11/19/14 04:09 PM0.290 mg/Kg-dry 5352 0.0966


Zinc 11/19/14 04:09 PM2.41 mg/Kg-dry 5306 0.966


Qualifiers:

Page 4 of 15








DF- Dilution Factor




2020




Matrix: SOIL



Lab Order: 1411137

DF

Lab ID: 1411137-05


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/20/14 11:45 AM124 mg/Kg-dry 5022000 124

Lead 11/19/14 04:11 PM0.297 mg/Kg-dry 5333 0.0990


Zinc 11/20/14 11:45 AM24.7 mg/Kg-dry 501290 9.90


Qualifiers:

Page 5 of 15








DF- Dilution Factor




2121




Matrix: SOIL



Lab Order: 1411137

DF

Lab ID: 1411137-06


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/20/14 11:47 AM130 mg/Kg-dry 509600 130

Lead 11/19/14 04:12 PM0.311 mg/Kg-dry 5106 0.104


Zinc 11/19/14 04:12 PM2.59 mg/Kg-dry 5143 1.04


Qualifiers:

Page 6 of 15








DF- Dilution Factor




2222


Client Sample ID: F03-111414


Matrix: SOIL



Lab Order: 1411137

DF

Lab ID: 1411137-07


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/20/14 11:49 AM121 mg/Kg-dry 5011100 121

Lead 11/19/14 04:14 PM0.291 mg/Kg-dry 5213 0.0970


Zinc 11/19/14 04:14 PM2.42 mg/Kg-dry 5321 0.970


Qualifiers:

Page 7 of 15








DF- Dilution Factor




2323




Matrix: SOIL



Lab Order: 1411137

DF

Lab ID: 1411137-08


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/20/14 11:51 AM127 mg/Kg-dry 509200 127

Lead 11/19/14 04:16 PM0.305 mg/Kg-dry 544.2 0.102


Zinc 11/19/14 04:16 PM2.54 mg/Kg-dry 5135 1.02


Qualifiers:

Page 8 of 15








DF- Dilution Factor




2424




Matrix: SOIL



Lab Order: 1411137

DF

Lab ID: 1411137-09


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/20/14 11:53 AM127 mg/Kg-dry 5016500 127

Lead 11/19/14 04:18 PM0.304 mg/Kg-dry 5152 0.101


Zinc 11/20/14 11:53 AM25.3 mg/Kg-dry 50842 10.1


Qualifiers:

Page 9 of 15








DF- Dilution Factor




2525




Matrix: SOIL



Lab Order: 1411137

DF

Lab ID: 1411137-10


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/20/14 11:55 AM129 mg/Kg-dry 5011500 129

Lead 11/19/14 04:20 PM0.309 mg/Kg-dry 537.1 0.103


Zinc 11/19/14 04:20 PM2.58 mg/Kg-dry 5111 1.03


Qualifiers:

Page 10 of 15








DF- Dilution Factor




2626




Matrix: SOIL



Lab Order: 1411137

DF

Lab ID: 1411137-11


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/20/14 12:10 PM131 mg/Kg-dry 5014700 131

Lead 11/19/14 04:57 PM0.314 mg/Kg-dry 5109 0.105


Zinc 11/19/14 04:57 PM2.62 mg/Kg-dry 5475 1.05


Qualifiers:

Page 11 of 15








DF- Dilution Factor




2727




Matrix: SOIL



Lab Order: 1411137

DF

Lab ID: 1411137-12


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/20/14 12:12 PM121 mg/Kg-dry 5011400 121

Lead 11/19/14 04:58 PM0.289 mg/Kg-dry 571.0 0.0964


Zinc 11/19/14 04:58 PM2.41 mg/Kg-dry 5246 0.964


Qualifiers:

Page 12 of 15








DF- Dilution Factor




2828




Matrix: SOIL



Lab Order: 1411137

DF

Lab ID: 1411137-13


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/20/14 12:14 PM118 mg/Kg-dry 509920 118

Lead 11/19/14 05:00 PM0.282 mg/Kg-dry 535.4 0.0941


Zinc 11/19/14 05:00 PM2.35 mg/Kg-dry 5110 0.941


Qualifiers:

Page 13 of 15








DF- Dilution Factor




2929




Matrix: SOIL



Lab Order: 1411137

DF

Lab ID: 1411137-14


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/20/14 12:16 PM124 mg/Kg-dry 5014500 124

Lead 11/19/14 05:02 PM0.297 mg/Kg-dry 5223 0.0990


Zinc 11/20/14 12:16 PM24.8 mg/Kg-dry 50593 9.90


Qualifiers:

Page 14 of 15








DF- Dilution Factor




3030




Matrix: SOIL



Lab Order: 1411137

DF

Lab ID: 1411137-15


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/20/14 12:18 PM118 mg/Kg-dry 5016600 118

Lead 11/19/14 05:04 PM0.283 mg/Kg-dry 5108 0.0943


Zinc 11/20/14 12:18 PM23.6 mg/Kg-dry 50808 9.43


Qualifiers:

Page 15 of 15








DF- Dilution Factor




3131







Analysis Date: 11/12/2014 12:10:13 P


Units: mg/Kg

RL


Mercury 0.02000 112 60 140 00.0400 0 00.0223

Qualifiers:






3232




RunID: CETAC2_HG_141120CThe QC data in batch 66601 applies to the following samples: 1411137-01A, 1411137-02A, 1411137-03A, 1411137-04A, 1411137-05A, 1411137-06A, 1411137-07A, 1411137-08A, 1411137-09A, 1411137-10A, 1411137-11A, 1411137-12A, 1411137-13A, 1411137-14A, 1411137-15A


Analysis Date: 11/20/2014 1:38:10 PM


Units: mg/Kg

RL

MBLKSampType: Run ID: CETAC2_HG_141120C Prep Date: 11/18/2014

Mercury 0.0400<0.0160


Analysis Date: 11/20/2014 1:40:26 PM


Units: mg/Kg

RL

LCSSampType: Run ID: CETAC2_HG_141120C Prep Date: 11/18/2014

Mercury 0.2000 104 85 1150.0400 00.208


Analysis Date: 11/20/2014 1:42:42 PM


Units: mg/Kg

RL

LCSDSampType: Run ID: CETAC2_HG_141120C Prep Date: 11/18/2014

Mercury 0.2000 104 85 115 250.0400 0 0.4820.207


Analysis Date: 11/20/2014 1:47:15 PM


Units: mg/Kg-dry

RL

SDSampType: Run ID: CETAC2_HG_141120C Prep Date: 11/18/2014

Mercury 0 100.204 0 0<0.0816


Analysis Date: 11/20/2014 1:49:31 PM


Units: mg/Kg-dry

RL

PDSSampType: Run ID: CETAC2_HG_141120C Prep Date: 11/18/2014

Mercury 0.2550 102 85 1150.0408 00.261


Analysis Date: 11/20/2014 1:51:46 PM


Units: mg/Kg-dry

RL

MSSampType: Run ID: CETAC2_HG_141120C Prep Date: 11/18/2014

Mercury 0.1996 109 80 1200.0399 00.218


Analysis Date: 11/20/2014 1:54:02 PM


Units: mg/Kg-dry

RL

MSDSampType: Run ID: CETAC2_HG_141120C Prep Date: 11/18/2014

Mercury 0.2049 108 80 120 250.0410 0 1.710.221

Qualifiers:






3333




RunID: CETAC2_HG_141120C


Analysis Date: 11/20/2014 1:33:36 PM


Units: mg/Kg

RL

ICVSampType: Run ID: CETAC2_HG_141120C Prep Date:

Mercury 0.004000 99.2 90 1100.0400 00.00397


Analysis Date: 11/20/2014 2:16:43 PM


Units: mg/Kg

RL

CCVSampType: Run ID: CETAC2_HG_141120C Prep Date:

Mercury 0.002000 98.0 90 1100.0400 00.00196


Analysis Date: 11/20/2014 2:32:40 PM


Units: mg/Kg

RL


Mercury 0.002000 98.5 90 1100.0400 00.00197

Qualifiers:






3434






Analysis Date: 11/10/2014 11:31:00 A


Units: mg/Kg

RL


Arsenic 0.1500 113 80 120 01.00 0 00.169

Cadmium 0.1500 99.7 80 120 00.300 0 00.150

Chromium 0.1500 116 80 120 02.00 0 00.174

Copper 0.1500 97.0 80 120 02.00 0 00.146

Iron 6.250 106 80 120 012.5 0 06.64

Lead 0.1500 102 80 120 00.300 0 00.152

Selenium 0.1500 118 80 120 00.500 0 00.178


Analysis Date: 11/10/2014 11:35:00 A


Units: mg/Kg

RL


Zinc 5.000 106 80 120 02.50 0 05.31

Qualifiers:






3535




RunID: ICP-MS4_141119AThe QC data in batch 66602 applies to the following samples: 1411137-01A, 1411137-02A, 1411137-03A, 1411137-04A, 1411137-05A, 1411137-06A, 1411137-07A, 1411137-08A, 1411137-09A, 1411137-10A, 1411137-11A, 1411137-12A, 1411137-13A, 1411137-14A, 1411137-15A


Analysis Date: 11/19/2014 3:53:00 PM


Units: mg/Kg

RL


Arsenic 1.00<0.500

Cadmium 0.300<0.100

Chromium 2.00<0.500

Copper 2.00<0.500

Iron 12.5<12.5

Lead 0.300<0.100


Zinc 2.50<1.00


Analysis Date: 11/19/2014 3:55:00 PM


Units: mg/Kg

RL


Arsenic 50.00 98.1 80 1201.00 049.1

Cadmium 50.00 94.4 80 1200.300 047.2

Chromium 50.00 97.0 80 1202.00 048.5

Copper 50.00 100 80 1202.00 050.1

Iron 250.0 96.8 80 12012.5 0242

Lead 50.00 101 80 1200.300 050.2

Selenium 50.00 100 80 1200.500 050.2

Zinc 50.00 98.7 80 1202.50 049.4


Analysis Date: 11/19/2014 3:57:00 PM


Units: mg/Kg

RL


Arsenic 50.00 98.5 80 120 201.00 0 0.40549.3

Cadmium 50.00 94.7 80 120 200.300 0 0.29947.3

Chromium 50.00 96.1 80 120 202.00 0 0.92848.1

Copper 50.00 99.7 80 120 202.00 0 0.57549.9

Iron 250.0 96.6 80 120 2012.5 0 0.120242

Lead 50.00 100 80 120 200.300 0 0.40450.0

Selenium 50.00 102 80 120 200.500 0 1.2450.9

Zinc 50.00 98.3 80 120 202.50 0 0.45149.1


Analysis Date: 11/19/2014 4:03:00 PM


Units: mg/Kg-dry

RL


Qualifiers:






3636






Analysis Date: 11/19/2014 4:03:00 PM


Units: mg/Kg-dry

RL


Arsenic 0 104.88 11.75 0.45811.7

Cadmium 0 101.47 0.3351 0<0.488

Chromium 0 109.77 10.75 0.39210.7

Copper 0 109.77 93.42 5.1198.3

Lead 0 101.47 31.51 0.57531.3

Selenium 0 10 R2.44 1.038 27.11.36

Zinc 0 1012.2 285.5 4.52299


Analysis Date: 11/19/2014 4:22:00 PM


Units: mg/Kg-dry

RL


Arsenic 48.85 102 80 1200.977 11.7561.6

Cadmium 48.85 101 80 1200.293 0.335149.6

Chromium 48.85 103 80 1201.95 10.7560.8

Copper 48.85 103 80 1201.95 93.42144

Lead 48.85 106 80 1200.293 31.5183.4

Selenium 48.85 104 80 1200.488 1.03851.9

Zinc 48.85 102 80 1202.44 285.5335


Analysis Date: 11/19/2014 4:24:00 PM


Units: mg/Kg-dry

RL


Arsenic 47.50 97.2 80 1200.950 11.7557.9

Cadmium 47.50 91.7 80 1200.285 0.335143.9

Chromium 47.50 93.5 80 1201.90 10.7555.2

Copper 47.50 167 80 120 S1.90 93.42173

Iron 237.5 131 80 120 S11.9 1268013000

Lead 47.50 106 80 1200.285 31.5181.8

Selenium 47.50 97.7 80 1200.475 1.03847.4

Zinc 47.50 113 80 1202.38 285.5339


Analysis Date: 11/19/2014 4:26:00 PM


Units: mg/Kg-dry

RL


Arsenic 48.85 94.2 80 120 200.977 11.75 0.26157.8

Cadmium 48.85 92.6 80 120 200.293 0.3351 3.7345.5

Chromium 48.85 93.2 80 120 201.95 10.75 2.0156.3

Copper 48.85 83.9 80 120 20 R1.95 93.42 24.9134

Qualifiers:






3737






Analysis Date: 11/19/2014 4:26:00 PM


Units: mg/Kg-dry

RL


Iron 244.2 121 80 120 20 S12.2 12680 0.11913000

Lead 48.85 96.3 80 120 200.293 31.51 4.0978.5

Selenium 48.85 95.7 80 120 200.488 1.038 0.73147.8

Zinc 48.85 84.9 80 120 202.44 285.5 3.69327

Qualifiers:






3838






Analysis Date: 11/19/2014 1:37:00 PM


Units: mg/L

RL


Arsenic 0.100 100 90 1100.00500 00.100

Cadmium 0.100 102 90 1100.00100 00.102

Chromium 0.100 107 90 1100.00500 00.107

Copper 0.100 109 90 1100.0100 00.109

Iron 2.50 103 90 1100.100 02.59

Lead 0.100 104 90 1100.00100 00.104

Selenium 0.100 100 90 1100.00500 00.100

Zinc 0.100 104 90 1100.00500 00.104


Analysis Date: 11/19/2014 1:43:00 PM


Units: mg/L

RL


Arsenic 0.00500 103 70 1300.00500 00.00513

Cadmium 0.00100 109 70 1300.00100 00.00109

Chromium 0.00500 113 70 1300.00500 00.00567

Copper 0.00500 108 70 1300.0100 00.00542

Iron 0.100 103 70 1300.100 00.103

Lead 0.00100 108 70 1300.00100 00.00108

Selenium 0.00500 107 70 1300.00500 00.00534

Zinc 0.00500 97.2 70 1300.00500 00.00486


Analysis Date: 11/19/2014 3:16:00 PM


Units: mg/L

RL


Arsenic 0.200 98.6 90 1100.00500 00.197

Cadmium 0.200 96.6 90 1100.00100 00.193

Chromium 0.200 96.5 90 1100.00500 00.193

Copper 0.200 100 90 1100.0100 00.200

Iron 5.00 96.2 90 1100.100 04.81

Lead 0.200 102 90 1100.00100 00.204

Selenium 0.200 102 90 1100.00500 00.203

Zinc 0.200 101 90 1100.00500 00.202


Analysis Date: 11/19/2014 3:26:00 PM


Units: mg/L

RL


Arsenic 0.00500 101 70 1300.00500 00.00503

Cadmium 0.00100 98.2 70 1300.00100 00.000982

Qualifiers:






3939






Analysis Date: 11/19/2014 3:26:00 PM


Units: mg/L

RL


Chromium 0.00500 95.1 70 1300.00500 00.00476

Copper 0.00500 97.5 70 1300.0100 00.00487

Iron 0.100 93.5 70 1300.100 00.0935

Lead 0.00100 101 70 1300.00100 00.00101

Selenium 0.00500 110 70 1300.00500 00.00549

Zinc 0.00500 90.2 70 1300.00500 00.00451


Analysis Date: 11/19/2014 4:28:00 PM


Units: mg/L

RL


Arsenic 0.200 98.7 90 1100.00500 00.197

Cadmium 0.200 97.2 90 1100.00100 00.194

Chromium 0.200 98.3 90 1100.00500 00.197

Copper 0.200 100 90 1100.0100 00.200

Iron 5.00 99.0 90 1100.100 04.95

Lead 0.200 101 90 1100.00100 00.202

Selenium 0.200 101 90 1100.00500 00.203

Zinc 0.200 101 90 1100.00500 00.201


Analysis Date: 11/19/2014 4:48:00 PM


Units: mg/L

RL


Arsenic 0.00500 99.5 70 1300.00500 00.00497

Cadmium 0.00100 102 70 1300.00100 00.00102

Chromium 0.00500 98.7 70 1300.00500 00.00493

Copper 0.00500 101 70 1300.0100 00.00503

Iron 0.100 94.9 70 1300.100 00.0949

Lead 0.00100 106 70 1300.00100 00.00106

Selenium 0.00500 115 70 1300.00500 00.00574

Zinc 0.00500 93.0 70 1300.00500 00.00465


Analysis Date: 11/19/2014 5:06:00 PM


Units: mg/L

RL


Arsenic 0.200 99.1 90 1100.00500 00.198

Cadmium 0.200 96.9 90 1100.00100 00.194

Chromium 0.200 99.3 90 1100.00500 00.199

Copper 0.200 99.3 90 1100.0100 00.199

Qualifiers:






4040






Analysis Date: 11/19/2014 5:06:00 PM


Units: mg/L

RL


Lead 0.200 100 90 1100.00100 00.201

Selenium 0.200 101 90 1100.00500 00.202

Zinc 0.200 100 90 1100.00500 00.201


Analysis Date: 11/19/2014 5:12:00 PM


Units: mg/L

RL


Arsenic 0.00500 102 70 1300.00500 00.00510

Cadmium 0.00100 102 70 1300.00100 00.00102

Chromium 0.00500 99.4 70 1300.00500 00.00497

Copper 0.00500 101 70 1300.0100 00.00503

Lead 0.00100 112 70 1300.00100 00.00112

Selenium 0.00500 109 70 1300.00500 00.00546

Zinc 0.00500 101 70 1300.00500 00.00504

Qualifiers:






4141




RunID: ICP-MS4_141120BThe QC data in batch 66602 applies to the following samples: 1411137-01A, 1411137-02A, 1411137-03A, 1411137-04A, 1411137-05A, 1411137-06A, 1411137-07A, 1411137-08A, 1411137-09A, 1411137-10A, 1411137-11A, 1411137-12A, 1411137-13A, 1411137-14A, 1411137-15A


Analysis Date: 11/20/2014 11:37:00 A


Units: mg/Kg-dry

RL


Iron 0 10611 13720 0.30713800


Analysis Date: 11/20/2014 11:57:00 A


Units: mg/Kg-dry

RL


Iron 12210 108 80 120122 1372026900

Qualifiers:






4242






Analysis Date: 11/20/2014 10:53:00 A


Units: mg/L

RL


Iron 2.50 103 90 1100.100 02.59

Zinc 0.100 104 90 1100.00500 00.104


Analysis Date: 11/20/2014 10:58:00 A


Units: mg/L

RL


Iron 0.100 100 70 1300.100 00.100

Zinc 0.00500 97.1 70 1300.00500 00.00485


Analysis Date: 11/20/2014 11:26:00 A


Units: mg/L

RL


Iron 5.00 103 90 1100.100 05.14

Zinc 0.200 103 90 1100.00500 00.206


Analysis Date: 11/20/2014 11:31:00 A


Units: mg/L

RL


Iron 0.100 102 70 1300.100 00.102

Zinc 0.00500 92.4 70 1300.00500 00.00462


Analysis Date: 11/20/2014 11:59:00 A


Units: mg/L

RL


Iron 5.00 101 90 1100.100 05.05

Zinc 0.200 103 90 1100.00500 00.206


Analysis Date: 11/20/2014 12:04:00 P


Units: mg/L

RL


Iron 0.100 100 70 1300.100 00.100

Zinc 0.00500 91.1 70 1300.00500 00.00455

Qualifiers:






4343






Analysis Date: 11/20/2014 12:28:00 P


Units: mg/L

RL


Iron 5.00 99.4 90 1100.100 04.97

Zinc 0.200 102 90 1100.00500 00.204


Analysis Date: 11/20/2014 12:33:00 P


Units: mg/L

RL


Iron 0.100 98.6 70 1300.100 00.0986

Zinc 0.00500 90.7 70 1300.00500 00.00454

Qualifiers:






4444




RunID: PMOIST_141119AThe QC data in batch 66613 applies to the following samples: 1411137-01A, 1411137-02A, 1411137-03A, 1411137-04A, 1411137-05A, 1411137-06A, 1411137-07A, 1411137-08A, 1411137-09A, 1411137-10A, 1411137-11A, 1411137-12A, 1411137-13A, 1411137-14A, 1411137-15A


Analysis Date: 11/20/2014 10:52:00 A


Units: WT%

RL



Qualifiers:






4545

Sequence Report

21-Nov-14

Lab Order: 1411137




Sample ID Client Sample ID Test Number Dilution Analysis DateBatch ID Prep Date

CETAC2_HG_141112DRun ID:

Matrix

DCS-66489 ----- SW7471B 11/12/2014 12:10:13 PM 11/11/2014 9:16:22 AM166489 S


CETAC2_HG_141120CRun ID:

Matrix

ICV-141120 ----- SW7471B 11/20/2014 1:33:36 PM1R76448 S

ICB-141120 ----- SW7471B 11/20/2014 1:35:55 PM1R76448 S

MB-66601 ----- SW7471B 11/20/2014 1:38:10 PM 11/18/2014 3:45:31 PM166601 S

LCS-66601 ----- SW7471B 11/20/2014 1:40:26 PM 11/18/2014 3:45:31 PM166601 S

LCSD-66601 ----- SW7471B 11/20/2014 1:42:42 PM 11/18/2014 3:45:31 PM166601 S

1411137-01A Q23-111314 SW7471B 11/20/2014 1:44:58 PM 11/18/2014 3:45:31 PM166601 S

1411137-01A SD Q23-111314 SW7471B 11/20/2014 1:47:15 PM 11/18/2014 3:45:31 PM566601 S

1411137-01A PDS Q23-111314 SW7471B 11/20/2014 1:49:31 PM 11/18/2014 3:45:31 PM166601 S

1411137-01A MS Q23-111314MS SW7471B 11/20/2014 1:51:46 PM 11/18/2014 3:45:31 PM166601 S

1411137-01A MSD Q23-111314MSD SW7471B 11/20/2014 1:54:02 PM 11/18/2014 3:45:31 PM166601 S

1411137-02A Q22-111314 SW7471B 11/20/2014 1:56:18 PM 11/18/2014 3:45:31 PM166601 S

1411137-03A E04-111314 SW7471B 11/20/2014 1:58:34 PM 11/18/2014 3:45:31 PM166601 S

1411137-04A E03-111414 SW7471B 11/20/2014 2:00:50 PM 11/18/2014 3:45:31 PM166601 S

1411137-05A E05-111314 SW7471B 11/20/2014 2:03:05 PM 11/18/2014 3:45:31 PM166601 S

1411137-06A E06-111414 SW7471B 11/20/2014 2:05:21 PM 11/18/2014 3:45:31 PM166601 S

1411137-07A F03-111414 SW7471B 11/20/2014 2:07:37 PM 11/18/2014 3:45:31 PM166601 S

1411137-08A F04-111414 SW7471B 11/20/2014 2:09:53 PM 11/18/2014 3:45:31 PM166601 S

1411137-09A F05-111414 SW7471B 11/20/2014 2:12:09 PM 11/18/2014 3:45:31 PM166601 S

1411137-10A P21-111714 SW7471B 11/20/2014 2:14:25 PM 11/18/2014 3:45:31 PM166601 S

CCV1-141120 ----- SW7471B 11/20/2014 2:16:43 PM1R76448 S

CCB1-141120 ----- SW7471B 11/20/2014 2:19:02 PM1R76448 S

1411137-11A P19-111714 SW7471B 11/20/2014 2:21:17 PM 11/18/2014 3:45:31 PM166601 S

1411137-12A P20-111714 SW7471B 11/20/2014 2:23:33 PM 11/18/2014 3:45:31 PM166601 S

1411137-13A P22-111714 SW7471B 11/20/2014 2:25:50 PM 11/18/2014 3:45:31 PM166601 S

1411137-14A O20-111714 SW7471B 11/20/2014 2:28:06 PM 11/18/2014 3:45:31 PM166601 S

1411137-15A P23-111714 SW7471B 11/20/2014 2:30:22 PM 11/18/2014 3:45:31 PM166601 S

CCV2-141120 ----- SW7471B 11/20/2014 2:32:40 PM1R76448 S

CCB2-141120 ----- SW7471B 11/20/2014 2:34:59 PM1R76448 S


ICP-MS4_140724ARun ID:

Matrix

DCS-63705-1 ----- SW6020A 7/24/2014 2:00:00 PM 5/22/2014 8:00:00 AM163705 A

DCS-63705-2 ----- SW6020A 7/24/2014 2:02:00 PM 5/22/2014 8:00:00 AM163705 A

DCS-63705-3 ----- SW6020A 7/24/2014 2:04:00 PM 5/22/2014 8:00:00 AM163705 A

Page 1 of 6

4646

Sequence Report

21-Nov-14

Lab Order: 1411137






Matrix

DCS1-65515 ----- SW6020A 9/9/2014 10:37:00 AM 9/8/2014 12:54:21 PM165515 A

DCS2-65515 ----- SW6020A 9/9/2014 10:39:00 AM 9/8/2014 12:54:21 PM165515 A

DCS3-65515 ----- SW6020A 9/9/2014 10:41:00 AM 9/8/2014 12:54:21 PM165515 A

DCS1-65518 ----- SW6020A 9/9/2014 10:43:00 AM 9/8/2014 1:09:30 PM565518 S

DCS2-65518 ----- SW6020A 9/9/2014 10:45:00 AM 9/8/2014 1:09:30 PM565518 S

DCS3-65518 ----- SW6020A 9/9/2014 10:47:00 AM 9/8/2014 1:09:30 PM565518 S

DCS1-65684 ----- SW6020A 9/22/2014 10:47:00 AM 9/19/2014 9:21:55 AM565684 S

DCS2-65684 ----- SW6020A 9/22/2014 10:49:00 AM565684 S


ICP-MS4_141013CRun ID:

Matrix

DCS1-66041 ----- SW6020A 10/13/2014 12:11:00 PM166041 A

DCS2-66041 ----- SW6020A 10/13/2014 12:13:00 PM166041 A

DCS3-66041 ----- SW6020A 10/13/2014 12:15:00 PM166041 A



Matrix

DCS1-66455 ----- SW6020A 11/10/2014 11:31:00 AM 11/7/2014 11:09:54 AM566455 S

DCS2-66455 ----- SW6020A 11/10/2014 11:33:00 AM 11/7/2014 11:09:54 AM566455 S

DCS3-66455 ----- SW6020A 11/10/2014 11:35:00 AM 11/7/2014 11:09:54 AM566455 S

Page 2 of 6

4747

Sequence Report

21-Nov-14

Lab Order: 1411137






Matrix

BLANK STD 1 ----- SW6020A 11/19/2014 1:10:00 PM1R76426 A

Cal01 ----- SW6020A 11/19/2014 1:12:00 PM1R76426 A

Cal02 ----- SW6020A 11/19/2014 1:14:00 PM1R76426 A

Cal03 ----- SW6020A 11/19/2014 1:16:00 PM1R76426 A

Cal04 ----- SW6020A 11/19/2014 1:18:00 PM1R76426 A

Cal05 ----- SW6020A 11/19/2014 1:20:00 PM1R76426 A

Cal06 ----- SW6020A 11/19/2014 1:22:00 PM1R76426 A

Cal07 ----- SW6020A 11/19/2014 1:24:00 PM1R76426 A

ICSA-141119 ----- SW6020A 11/19/2014 1:30:00 PM1R76426 A

ICSAB-141119 ----- SW6020A 11/19/2014 1:31:00 PM1R76426 A

ICV-141119 ----- SW6020A 11/19/2014 1:37:00 PM1R76426 A

ICB-141119 ----- SW6020A 11/19/2014 1:48:00 PM1R76426 A

CCV2-141119 ----- SW6020A 11/19/2014 3:16:00 PM1R76426 A

LCVL2-141119 ----- SW6020A 11/19/2014 3:26:00 PM1R76426 A

CCB2-141119 ----- SW6020A 11/19/2014 3:31:00 PM1R76426 A

MB-66602 ----- SW6020A 11/19/2014 3:53:00 PM 11/18/2014 3:45:59 PM566602 S

LCS-66602 ----- SW6020A 11/19/2014 3:55:00 PM 11/18/2014 3:45:59 PM566602 S

LCSD-66602 ----- SW6020A 11/19/2014 3:57:00 PM 11/18/2014 3:45:59 PM566602 S

1411137-01A Q23-111314 SW6020A 11/19/2014 4:01:00 PM 11/18/2014 3:45:59 PM566602 S

1411137-01A SD Q23-111314 SW6020A 11/19/2014 4:03:00 PM 11/18/2014 3:45:59 PM2566602 S

1411137-02A Q22-111314 SW6020A 11/19/2014 4:05:00 PM 11/18/2014 3:45:59 PM566602 S

1411137-03A E04-111314 SW6020A 11/19/2014 4:07:00 PM 11/18/2014 3:45:59 PM566602 S

1411137-04A E03-111414 SW6020A 11/19/2014 4:09:00 PM 11/18/2014 3:45:59 PM566602 S

1411137-05A E05-111314 SW6020A 11/19/2014 4:11:00 PM 11/18/2014 3:45:59 PM566602 S

1411137-06A E06-111414 SW6020A 11/19/2014 4:12:00 PM 11/18/2014 3:45:59 PM566602 S

1411137-07A F03-111414 SW6020A 11/19/2014 4:14:00 PM 11/18/2014 3:45:59 PM566602 S

1411137-08A F04-111414 SW6020A 11/19/2014 4:16:00 PM 11/18/2014 3:45:59 PM566602 S

1411137-09A F05-111414 SW6020A 11/19/2014 4:18:00 PM 11/18/2014 3:45:59 PM566602 S

1411137-10A P21-111714 SW6020A 11/19/2014 4:20:00 PM 11/18/2014 3:45:59 PM566602 S

1411137-01A PDS Q23-111314 SW6020A 11/19/2014 4:22:00 PM 11/18/2014 3:45:59 PM566602 S

1411137-01A MS Q23-111314MS SW6020A 11/19/2014 4:24:00 PM 11/18/2014 3:45:59 PM566602 S

1411137-01A MSD Q23-111314MSD SW6020A 11/19/2014 4:26:00 PM 11/18/2014 3:45:59 PM566602 S

CCV3-141119 ----- SW6020A 11/19/2014 4:28:00 PM1R76426 A

LCVL3-141119 ----- SW6020A 11/19/2014 4:48:00 PM1R76426 A

CCB3-141119 ----- SW6020A 11/19/2014 4:51:00 PM1R76426 A

1411137-11A P19-111714 SW6020A 11/19/2014 4:57:00 PM 11/18/2014 3:45:59 PM566602 S

1411137-12A P20-111714 SW6020A 11/19/2014 4:58:00 PM 11/18/2014 3:45:59 PM566602 S

1411137-13A P22-111714 SW6020A 11/19/2014 5:00:00 PM 11/18/2014 3:45:59 PM566602 S

Page 3 of 6

4848

Sequence Report

21-Nov-14

Lab Order: 1411137




1411137-14A O20-111714 SW6020A 11/19/2014 5:02:00 PM 11/18/2014 3:45:59 PM566602 S

1411137-15A P23-111714 SW6020A 11/19/2014 5:04:00 PM 11/18/2014 3:45:59 PM566602 S

CCV4-141119 ----- SW6020A 11/19/2014 5:06:00 PM1R76426 A

CCB4-141119 ----- SW6020A 11/19/2014 5:10:00 PM1R76426 A

LCVL4-141119 ----- SW6020A 11/19/2014 5:12:00 PM1R76426 A

Page 4 of 6

4949

Sequence Report

21-Nov-14

Lab Order: 1411137





ICP-MS4_141120BRun ID:

Matrix

BLANK STD 1 ----- SW6020A 11/20/2014 10:19:00 AM1R76452 A

Cal01 ----- SW6020A 11/20/2014 10:21:00 AM1R76452 A

Cal02 ----- SW6020A 11/20/2014 10:23:00 AM1R76452 A

Cal03 ----- SW6020A 11/20/2014 10:25:00 AM1R76452 A

Cal04 ----- SW6020A 11/20/2014 10:27:00 AM1R76452 A

Cal05 ----- SW6020A 11/20/2014 10:29:00 AM1R76452 A

Cal06 ----- SW6020A 11/20/2014 10:31:00 AM1R76452 A

Cal07 ----- SW6020A 11/20/2014 10:33:00 AM1R76452 A

ICSA-141120 ----- SW6020A 11/20/2014 10:39:00 AM1R76452 A

ICSAB-141120 ----- SW6020A 11/20/2014 10:40:00 AM1R76452 A

ICV-141120 ----- SW6020A 11/20/2014 10:53:00 AM1R76452 A

LCVL-141120 ----- SW6020A 11/20/2014 10:58:00 AM1R76452 A

ICB-141120 ----- SW6020A 11/20/2014 11:02:00 AM1R76452 A

CCV1-141120 ----- SW6020A 11/20/2014 11:26:00 AM1R76452 A

LCVL1-141120 ----- SW6020A 11/20/2014 11:31:00 AM1R76452 A

CCB1-141120 ----- SW6020A 11/20/2014 11:33:00 AM1R76452 A

1411137-01A Q23-111314 SW6020A 11/20/2014 11:35:00 AM 11/18/2014 3:45:59 PM5066602 S

1411137-01A SD Q23-111314 SW6020A 11/20/2014 11:37:00 AM 11/18/2014 3:45:59 PM25066602 S

1411137-02A Q22-111314 SW6020A 11/20/2014 11:39:00 AM 11/18/2014 3:45:59 PM5066602 S

1411137-03A E04-111314 SW6020A 11/20/2014 11:41:00 AM 11/18/2014 3:45:59 PM5066602 S

1411137-04A E03-111414 SW6020A 11/20/2014 11:43:00 AM 11/18/2014 3:45:59 PM5066602 S

1411137-05A E05-111314 SW6020A 11/20/2014 11:45:00 AM 11/18/2014 3:45:59 PM5066602 S

1411137-06A E06-111414 SW6020A 11/20/2014 11:47:00 AM 11/18/2014 3:45:59 PM5066602 S

1411137-07A F03-111414 SW6020A 11/20/2014 11:49:00 AM 11/18/2014 3:45:59 PM5066602 S

1411137-08A F04-111414 SW6020A 11/20/2014 11:51:00 AM 11/18/2014 3:45:59 PM5066602 S

1411137-09A F05-111414 SW6020A 11/20/2014 11:53:00 AM 11/18/2014 3:45:59 PM5066602 S

1411137-10A P21-111714 SW6020A 11/20/2014 11:55:00 AM 11/18/2014 3:45:59 PM5066602 S

1411137-01A PDS Q23-111314 SW6020A 11/20/2014 11:57:00 AM 11/18/2014 3:45:59 PM5066602 S

CCV2-141120 ----- SW6020A 11/20/2014 11:59:00 AM1R76452 A

LCVL2-141120 ----- SW6020A 11/20/2014 12:04:00 PM1R76452 A

CCB2-141120 ----- SW6020A 11/20/2014 12:09:00 PM1R76452 A

1411137-11A P19-111714 SW6020A 11/20/2014 12:10:00 PM 11/18/2014 3:45:59 PM5066602 S

1411137-12A P20-111714 SW6020A 11/20/2014 12:12:00 PM 11/18/2014 3:45:59 PM5066602 S

1411137-13A P22-111714 SW6020A 11/20/2014 12:14:00 PM 11/18/2014 3:45:59 PM5066602 S

1411137-14A O20-111714 SW6020A 11/20/2014 12:16:00 PM 11/18/2014 3:45:59 PM5066602 S

1411137-15A P23-111714 SW6020A 11/20/2014 12:18:00 PM 11/18/2014 3:45:59 PM5066602 S

CCV8-141120 ----- SW6020A 11/20/2014 3:07:00 PM1R76452 A

LCVL8-141120 ----- SW6020A 11/20/2014 3:13:00 PM1R76452 A

Page 5 of 6

5050

Sequence Report

21-Nov-14

Lab Order: 1411137




CCB8-141120 ----- SW6020A 11/20/2014 3:16:00 PM1R76452 A


PMOIST_141119ARun ID:

Matrix

1411137-01A Q23-111314 D2216 11/20/2014 10:52:00 AM 11/19/2014 11:43:15 AM166613 S

1411137-02A Q22-111314 D2216 11/20/2014 10:52:00 AM 11/19/2014 11:43:15 AM166613 S

1411137-03A E04-111314 D2216 11/20/2014 10:52:00 AM 11/19/2014 11:43:15 AM166613 S

1411137-04A E03-111414 D2216 11/20/2014 10:52:00 AM 11/19/2014 11:43:15 AM166613 S

1411137-05A E05-111314 D2216 11/20/2014 10:52:00 AM 11/19/2014 11:43:15 AM166613 S

1411137-06A E06-111414 D2216 11/20/2014 10:52:00 AM 11/19/2014 11:43:15 AM166613 S

1411137-07A F03-111414 D2216 11/20/2014 10:52:00 AM 11/19/2014 11:43:15 AM166613 S

1411137-08A F04-111414 D2216 11/20/2014 10:52:00 AM 11/19/2014 11:43:15 AM166613 S

1411137-09A F05-111414 D2216 11/20/2014 10:52:00 AM 11/19/2014 11:43:15 AM166613 S

1411137-10A P21-111714 D2216 11/20/2014 10:52:00 AM 11/19/2014 11:43:15 AM166613 S

1411137-11A P19-111714 D2216 11/20/2014 10:52:00 AM 11/19/2014 11:43:15 AM166613 S

1411137-12A P20-111714 D2216 11/20/2014 10:52:00 AM 11/19/2014 11:43:15 AM166613 S

1411137-13A P22-111714 D2216 11/20/2014 10:52:00 AM 11/19/2014 11:43:15 AM166613 S

1411137-14A O20-111714 D2216 11/20/2014 10:52:00 AM 11/19/2014 11:43:15 AM166613 S

1411137-15A P23-111714 D2216 11/20/2014 10:52:00 AM 11/19/2014 11:43:15 AM166613 S

1411160-01A-DUP ----- D2216 11/20/2014 10:52:00 AM 11/19/2014 11:43:15 AM166613 S

Page 6 of 6

5151





TestNo: SW7471B

mg/KgAnalyte

MQL

mg/Kg

MDL

Mercury 0.04000.0160

TestNo: SW6020A

mg/KgAnalyte

MQL

mg/Kg

MDL

Arsenic 1.000.500

Cadmium 0.3000.100

Chromium 2.000.500

Copper 2.000.500

Iron 12.512.5

Lead 0.3000.100

Selenium 0.5000.150

Zinc 2.501.00

Qualifiers:

Page 1 of 1



5252

November 24, 2014


Dear Kyrie Jeffery:


Order No.: 1411161FAX (720) 344-3535

TEL: (720) 344-3851





Sincerely,





1

Table of Contents


.................................................................................. 9CaseNarrative 1411161







2























6












2) Were percent differences for each analyte within the method-required QC limits? X S2-02 3) Was the ICAL curve verified for each analyte? X 4) Was the absolute value of the analyte concentration in the inorganic CCB < MDL? X











method? X S9-01









applicable? X



X

7

RG-366/TRRP-13 May 2010

















________________________


11/24/14

8













For Metals Analysis, the recoveries of two analytes for the Matrix Spike and Matrix Spike Duplicate

(1411116-01 MS/MSD) were outside of the method control limits. These are flagged accordingly in

the QC Summary Report. These analytes were within method control limits in the associated LCS. No

further corrective action was taken.


For Metals Analysis, performed on 11/20/2014, the recovery of Copper for the Low Level Calibration

Verification (LCVL7-141120) was marginally below the method control limits. This analyte was within

method control limits in the associated bracketing QC. No further corrective action was taken.


For Metals Analysis, the RPD of Selenium for the Serial Dilution (1411116-01 SD) was above the

method control limit. This is flagged accordingly in the QC Summary Report. This analyte was within

method control limits in the associated Post Digestion Spike. No further corrective action was taken.

For Mercury Analysis, the RPD of the Serial Dilution (1411116-01 SD) was above the method control

limit. This is flagged accordingly in the QC Summary Report. The associated Post Digestion Spike was

within method control limits. No further corrective action was taken.

Page 1 of 1

9






1411161-01 P18-111814 11/18/14 11:08 AM 11/19/2014

1411161-02 M17-111814 11/18/14 10:55 AM 11/19/2014

1411161-03 N17-111814 11/18/14 11:00 AM 11/19/2014

1411161-04 P17-111814 11/18/14 11:05 AM 11/19/2014

1411161-05 O18-111814 11/18/14 11:18 AM 11/19/2014

1411161-06 O17-111814 11/18/14 11:03 AM 11/19/2014

1411161-07 O19-111814 11/18/14 11:13 AM 11/19/2014

1411161-08 L29-111814 11/18/14 03:45 PM 11/19/2014

1411161-09 L28-111814 11/18/14 03:42 PM 11/19/2014

1411161-10 K29-111814 11/18/14 03:40 PM 11/19/2014

Page 1 of 1

10


PREP DATES REPORT

24-Nov-14

Lab Order: 1411161





1411161-01A P18-111814 11/18/14 11:08 AM Soil Mercury Soil Prep, Total 11/19/14 11:34 AMSW7471A 66578

P18-111814 11/18/14 11:08 AM Soil Moisture Preparation 11/19/14 11:46 AMD2216 66614

P18-111814 11/18/14 11:08 AM Soil Soil Prep Total Metals: ICP-MS 11/19/14 08:30 AMSW3050B 66577


1411161-02A M17-111814 11/18/14 10:55 AM Soil Mercury Soil Prep, Total 11/19/14 11:34 AMSW7471A 66578

M17-111814 11/18/14 10:55 AM Soil Moisture Preparation 11/19/14 11:46 AMD2216 66614

M17-111814 11/18/14 10:55 AM Soil Soil Prep Total Metals: ICP-MS 11/19/14 08:30 AMSW3050B 66577

M17-111814 11/18/14 10:55 AM Soil Soil Prep Total Metals: ICP-MS 11/19/14 08:30 AMSW3050B 66577

1411161-03A N17-111814 11/18/14 11:00 AM Soil Mercury Soil Prep, Total 11/19/14 11:34 AMSW7471A 66578

N17-111814 11/18/14 11:00 AM Soil Moisture Preparation 11/19/14 11:46 AMD2216 66614

N17-111814 11/18/14 11:00 AM Soil Soil Prep Total Metals: ICP-MS 11/19/14 08:30 AMSW3050B 66577

N17-111814 11/18/14 11:00 AM Soil Soil Prep Total Metals: ICP-MS 11/19/14 08:30 AMSW3050B 66577

1411161-04A P17-111814 11/18/14 11:05 AM Soil Mercury Soil Prep, Total 11/19/14 11:34 AMSW7471A 66578

P17-111814 11/18/14 11:05 AM Soil Moisture Preparation 11/19/14 11:46 AMD2216 66614



1411161-05A O18-111814 11/18/14 11:18 AM Soil Mercury Soil Prep, Total 11/19/14 11:34 AMSW7471A 66578

O18-111814 11/18/14 11:18 AM Soil Moisture Preparation 11/19/14 11:46 AMD2216 66614

O18-111814 11/18/14 11:18 AM Soil Soil Prep Total Metals: ICP-MS 11/19/14 08:30 AMSW3050B 66577










Page 1 of 2

11


PREP DATES REPORT

24-Nov-14

Lab Order: 1411161





1411161-08A L29-111814 11/18/14 03:45 PM Soil Mercury Soil Prep, Total 11/19/14 11:34 AMSW7471A 66578

L29-111814 11/18/14 03:45 PM Soil Moisture Preparation 11/19/14 11:46 AMD2216 66614

L29-111814 11/18/14 03:45 PM Soil Soil Prep Total Metals: ICP-MS 11/19/14 08:30 AMSW3050B 66577


1411161-09A L28-111814 11/18/14 03:42 PM Soil Mercury Soil Prep, Total 11/19/14 11:34 AMSW7471A 66578

L28-111814 11/18/14 03:42 PM Soil Moisture Preparation 11/19/14 11:46 AMD2216 66614



1411161-10A K29-111814 11/18/14 03:40 PM Soil Mercury Soil Prep, Total 11/19/14 11:34 AMSW7471A 66578

K29-111814 11/18/14 03:40 PM Soil Mercury Soil Prep, Total 11/19/14 11:34 AMSW7471A 66578

K29-111814 11/18/14 03:40 PM Soil Moisture Preparation 11/19/14 11:46 AMD2216 66614

K29-111814 11/18/14 03:40 PM Soil Soil Prep Total Metals: ICP-MS 11/19/14 08:30 AMSW3050B 66577


Page 2 of 2

12



24-Nov-14

Lab Order: 1411161





1411161-01A P18-111814 D2216Soil Percent Moisture 11/20/14 10:59 AM66614 1 PMOIST_141119B


B



1411161-02A M17-111814 D2216Soil Percent Moisture 11/20/14 10:59 AM66614 1 PMOIST_141119B

M17-111814 SW7471BSoil Total Mercury: Soil/Solid 11/21/14 12:23 PM66578 1 CETAC2_HG_141121

B

M17-111814 SW6020ASoil Trace Metals: ICP-MS - Solid 11/20/14 01:14 PM66577 5 ICP-MS4_141120B


1411161-03A N17-111814 D2216Soil Percent Moisture 11/20/14 10:59 AM66614 1 PMOIST_141119B


B





B



1411161-05A O18-111814 D2216Soil Percent Moisture 11/20/14 10:59 AM66614 1 PMOIST_141119B


B





B




Page 1 of 2

13



24-Nov-14

Lab Order: 1411161





1411161-07A O19-111814 SW7471BSoil Total Mercury: Soil/Solid 11/21/14 12:39 PM66578 1 CETAC2_HG_141121

B



1411161-08A L29-111814 D2216Soil Percent Moisture 11/20/14 10:59 AM66614 1 PMOIST_141119B

L29-111814 SW7471BSoil Total Mercury: Soil/Solid 11/21/14 12:41 PM66578 1 CETAC2_HG_141121

B

L29-111814 SW6020ASoil Trace Metals: ICP-MS - Solid 11/20/14 01:36 PM66577 5 ICP-MS4_141120B


1411161-09A L28-111814 D2216Soil Percent Moisture 11/20/14 10:59 AM66614 1 PMOIST_141119B

L28-111814 SW7471BSoil Total Mercury: Soil/Solid 11/21/14 12:43 PM66578 1 CETAC2_HG_141121

B



1411161-10A K29-111814 D2216Soil Percent Moisture 11/20/14 10:59 AM66614 1 PMOIST_141119B

K29-111814 SW7471BSoil Total Mercury: Soil/Solid 11/21/14 12:46 PM66578 1 CETAC2_HG_141121

B


B

K29-111814 SW6020ASoil Trace Metals: ICP-MS - Solid 11/20/14 02:16 PM66577 100 ICP-MS4_141120B


Page 2 of 2

14




Matrix: SOIL



Lab Order: 1411161

DF

Lab ID: 1411161-01


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/20/14 01:58 PM126 mg/Kg-dry 5010400 126

Lead 11/20/14 01:12 PM0.302 mg/Kg-dry 591.9 0.101


Zinc 11/20/14 01:12 PM2.52 mg/Kg-dry 5152 1.01


Qualifiers:

Page 1 of 10








DF- Dilution Factor




15




Matrix: SOIL



Lab Order: 1411161

DF

Lab ID: 1411161-02


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/20/14 02:00 PM129 mg/Kg-dry 508210 129

Lead 11/20/14 01:14 PM0.311 mg/Kg-dry 551.9 0.104


Zinc 11/20/14 01:14 PM2.59 mg/Kg-dry 587.2 1.04


Qualifiers:

Page 2 of 10








DF- Dilution Factor




16




Matrix: SOIL



Lab Order: 1411161

DF

Lab ID: 1411161-03


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/20/14 02:02 PM129 mg/Kg-dry 508480 129

Lead 11/20/14 01:15 PM0.310 mg/Kg-dry 513.5 0.103


Zinc 11/20/14 01:15 PM2.58 mg/Kg-dry 589.4 1.03


Qualifiers:

Page 3 of 10








DF- Dilution Factor




17




Matrix: SOIL



Lab Order: 1411161

DF

Lab ID: 1411161-04


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/20/14 02:04 PM122 mg/Kg-dry 509520 122

Lead 11/20/14 01:17 PM0.292 mg/Kg-dry 5127 0.0973


Zinc 11/20/14 01:17 PM2.43 mg/Kg-dry 5175 0.973


Qualifiers:

Page 4 of 10








DF- Dilution Factor




18




Matrix: SOIL



Lab Order: 1411161

DF

Lab ID: 1411161-05


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/20/14 02:06 PM128 mg/Kg-dry 5012900 128

Lead 11/20/14 01:19 PM0.308 mg/Kg-dry 5130 0.103


Zinc 11/20/14 01:19 PM2.57 mg/Kg-dry 5490 1.03


Qualifiers:

Page 5 of 10








DF- Dilution Factor




19




Matrix: SOIL



Lab Order: 1411161

DF

Lab ID: 1411161-06


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/20/14 02:08 PM128 mg/Kg-dry 509800 128

Lead 11/20/14 01:33 PM0.308 mg/Kg-dry 529.3 0.103


Zinc 11/20/14 01:33 PM2.57 mg/Kg-dry 5166 1.03


Qualifiers:

Page 6 of 10








DF- Dilution Factor




20




Matrix: SOIL



Lab Order: 1411161

DF

Lab ID: 1411161-07


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/20/14 02:10 PM128 mg/Kg-dry 5013900 128

Lead 11/20/14 01:35 PM0.308 mg/Kg-dry 5213 0.103


Zinc 11/20/14 01:35 PM2.56 mg/Kg-dry 5471 1.03


Qualifiers:

Page 7 of 10








DF- Dilution Factor




21


Client Sample ID: L29-111814


Matrix: SOIL



Lab Order: 1411161

DF

Lab ID: 1411161-08


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/20/14 02:12 PM114 mg/Kg-dry 5017100 114

Lead 11/20/14 01:36 PM0.274 mg/Kg-dry 5223 0.0912


Zinc 11/20/14 02:12 PM22.8 mg/Kg-dry 50934 9.12


Qualifiers:

Page 8 of 10








DF- Dilution Factor




22




Matrix: SOIL



Lab Order: 1411161

DF

Lab ID: 1411161-09


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/20/14 02:14 PM126 mg/Kg-dry 509290 126

Lead 11/20/14 01:38 PM0.302 mg/Kg-dry 553.1 0.101


Zinc 11/20/14 01:38 PM2.52 mg/Kg-dry 578.1 1.01


Qualifiers:

Page 9 of 10








DF- Dilution Factor




23


Client Sample ID: K29-111814


Matrix: SOIL



Lab Order: 1411161

DF

Lab ID: 1411161-10


RL

Project No: 6835001.2014.47SR2

SDL


TRACE METALS: ICP-MS - SOLID SW6020A Analyst: ROArsenic 11/20/14 01:40 PM1.05 mg/Kg-dry 5126 0.524




Iron 11/20/14 02:16 PM262 mg/Kg-dry 10031400 262

Lead 11/20/14 01:40 PM0.315 mg/Kg-dry 5476 0.105


Zinc 11/20/14 02:16 PM52.4 mg/Kg-dry 1002190 21.0


Qualifiers:

Page 10 of 10








DF- Dilution Factor




24







Analysis Date: 11/12/2014 12:10:13 P


Units: mg/Kg

RL


Mercury 0.02000 112 60 140 00.0400 0 00.0223

Qualifiers:






25




RunID: CETAC2_HG_141121BThe QC data in batch 66578 applies to the following samples: 1411161-01A, 1411161-02A, 1411161-03A, 1411161-04A, 1411161-05A, 1411161-06A, 1411161-07A, 1411161-08A, 1411161-09A, 1411161-10A


Analysis Date: 11/21/2014 11:50:59 A


Units: mg/Kg

RL


Mercury 0.0400<0.0160


Analysis Date: 11/21/2014 11:53:15 A


Units: mg/Kg

RL


Mercury 0.2000 106 85 1150.0400 00.213


Analysis Date: 11/21/2014 11:55:31 A


Units: mg/Kg

RL


Mercury 0.2000 107 85 115 250.0400 0 0.4680.214


Analysis Date: 11/21/2014 12:00:04 P


Units: mg/Kg-dry

RL


Mercury 0 10 R0.259 0.1863 14.50.215


Analysis Date: 11/21/2014 12:02:19 P


Units: mg/Kg-dry

RL


Mercury 0.3234 96.4 85 1150.0517 0.18630.498


Analysis Date: 11/21/2014 12:04:34 P


Units: mg/Kg-dry

RL


Mercury 0.2556 117 80 1200.0511 0.18630.486


Analysis Date: 11/21/2014 12:06:50 P


Units: mg/Kg-dry

RL


Mercury 0.2607 115 80 120 250.0521 0.1863 0.0920.486

Qualifiers:






26






Analysis Date: 11/21/2014 11:46:25 A


Units: mg/Kg

RL


Mercury 0.004000 101 90 1100.0400 00.00402


Analysis Date: 11/21/2014 12:30:14 P


Units: mg/Kg

RL


Mercury 0.002000 101 90 1100.0400 00.00202


Analysis Date: 11/21/2014 1:14:17 PM


Units: mg/Kg

RL


Mercury 0.002000 101 90 1100.0400 00.00202


Analysis Date: 11/21/2014 1:41:49 PM


Units: mg/Kg

RL


Mercury 0.002000 99.5 90 1100.0400 00.00199


Analysis Date: 11/21/2014 3:01:46 PM


Units: mg/Kg

RL


Mercury 0.002000 102 90 1100.0400 00.00203

Qualifiers:






27






Analysis Date: 11/10/2014 11:31:00 A


Units: mg/Kg

RL


Arsenic 0.1500 113 80 120 01.00 0 00.169

Cadmium 0.1500 99.7 80 120 00.300 0 00.150

Chromium 0.1500 116 80 120 02.00 0 00.174

Copper 0.1500 97.0 80 120 02.00 0 00.146

Iron 6.250 106 80 120 012.5 0 06.64

Lead 0.1500 102 80 120 00.300 0 00.152

Selenium 0.1500 118 80 120 00.500 0 00.178


Analysis Date: 11/10/2014 11:35:00 A


Units: mg/Kg

RL


Zinc 5.000 106 80 120 02.50 0 05.31

Qualifiers:






28




RunID: ICP-MS4_141120BThe QC data in batch 66577 applies to the following samples: 1411161-01A, 1411161-02A, 1411161-03A, 1411161-04A, 1411161-05A, 1411161-06A, 1411161-07A, 1411161-08A, 1411161-09A, 1411161-10A


Analysis Date: 11/20/2014 11:04:00 A


Units: mg/Kg

RL


Arsenic 1.00<0.500

Cadmium 0.300<0.100

Chromium 2.00<0.500

Copper 2.00<0.500

Iron 12.5<12.5

Lead 0.300<0.100


Zinc 2.50<1.00


Analysis Date: 11/20/2014 11:06:00 A


Units: mg/Kg

RL


Arsenic 50.00 102 80 1201.00 050.9

Cadmium 50.00 102 80 1200.300 051.2

Chromium 50.00 104 80 1202.00 051.9

Copper 50.00 105 80 1202.00 052.5

Iron 250.0 107 80 12012.5 0268

Lead 50.00 102 80 1200.300 051.1

Selenium 50.00 100 80 1200.500 050.1

Zinc 50.00 105 80 1202.50 052.3


Analysis Date: 11/20/2014 11:07:00 A


Units: mg/Kg

RL


Arsenic 50.00 101 80 120 201.00 0 0.63150.5

Cadmium 50.00 104 80 120 200.300 0 1.2951.9

Chromium 50.00 104 80 120 202.00 0 0.09551.9

Copper 50.00 104 80 120 202.00 0 0.64252.2

Iron 250.0 106 80 120 2012.5 0 1.25264

Lead 50.00 102 80 120 200.300 0 0.45150.9

Selenium 50.00 99.3 80 120 200.500 0 0.88949.6

Zinc 50.00 104 80 120 202.50 0 0.88051.9


Analysis Date: 11/20/2014 11:13:00 A


Units: mg/Kg-dry

RL


Qualifiers:






29






Analysis Date: 11/20/2014 11:13:00 A


Units: mg/Kg-dry

RL


Arsenic 0 106.55 8.721 0.8108.65

Cadmium 0 101.96 0.4629 0<0.655

Chromium 0 1013.1 20.84 3.4121.6

Copper 0 1013.1 17.58 3.2417.0

Lead 0 101.96 57.74 0.22357.9

Selenium 0 10 R3.27 1.481 23.61.88

Zinc 0 1016.4 120.9 4.69127


Analysis Date: 11/20/2014 11:20:00 A


Units: mg/Kg-dry

RL


Arsenic 65.47 106 80 1201.31 8.72178.1

Cadmium 65.47 104 80 1200.393 0.462968.6

Chromium 65.47 104 80 1202.62 20.8488.7

Copper 65.47 101 80 1202.62 17.5883.5

Lead 65.47 108 80 1200.393 57.74129

Selenium 65.47 105 80 1200.655 1.48169.9

Zinc 65.47 104 80 1203.27 120.9189


Analysis Date: 11/20/2014 11:22:00 A


Units: mg/Kg-dry

RL


Arsenic 59.10 98.1 80 1201.18 8.72166.7

Cadmium 59.10 97.2 80 1200.355 0.462957.9

Chromium 59.10 96.0 80 1202.36 20.8477.6

Copper 59.10 91.4 80 1202.36 17.5871.6

Iron 295.5 14.5 80 120 S14.8 1314013200

Lead 59.10 83.8 80 1200.355 57.74107

Selenium 59.10 98.9 80 1200.591 1.48159.9

Zinc 59.10 61.0 80 120 S2.96 120.9157


Analysis Date: 11/20/2014 11:24:00 A


Units: mg/Kg-dry

RL


Arsenic 58.58 101 80 120 201.17 8.721 1.4667.7

Cadmium 58.58 97.7 80 120 200.351 0.4629 0.31657.7

Chromium 58.58 100 80 120 202.34 20.84 2.4779.5

Copper 58.58 94.7 80 120 202.34 17.58 2.0573.1

Qualifiers:






30






Analysis Date: 11/20/2014 11:24:00 A


Units: mg/Kg-dry

RL


Iron 292.9 155 80 120 20 S14.6 13140 3.0713600

Lead 58.58 97.9 80 120 200.351 57.74 7.02115

Selenium 58.58 102 80 120 200.586 1.481 2.2561.3

Zinc 58.58 64.6 80 120 20 S2.93 120.9 1.15159


Analysis Date: 11/20/2014 1:56:00 PM


Units: mg/Kg-dry

RL


Iron 0 10818 13750 4.4413100


Analysis Date: 11/20/2014 2:29:00 PM


Units: mg/Kg-dry

RL


Iron 16370 105 80 120164 1375030900

Qualifiers:






31






Analysis Date: 11/20/2014 10:53:00 A


Units: mg/L

RL


Arsenic 0.100 101 90 1100.00500 00.101

Cadmium 0.100 101 90 1100.00100 00.101

Chromium 0.100 104 90 1100.00500 00.104

Copper 0.100 104 90 1100.0100 00.104

Iron 2.50 103 90 1100.100 02.59

Lead 0.100 101 90 1100.00100 00.101

Selenium 0.100 101 90 1100.00500 00.101

Zinc 0.100 104 90 1100.00500 00.104


Analysis Date: 11/20/2014 10:58:00 A


Units: mg/L

RL


Arsenic 0.00500 104 70 1300.00500 00.00522

Cadmium 0.00100 106 70 1300.00100 00.00106

Chromium 0.00500 107 70 1300.00500 00.00533

Copper 0.00500 86.6 70 1300.0100 00.00433

Iron 0.100 100 70 1300.100 00.100

Lead 0.00100 109 70 1300.00100 00.00109

Selenium 0.00500 106 70 1300.00500 00.00531

Zinc 0.00500 97.1 70 1300.00500 00.00485


Analysis Date: 11/20/2014 11:26:00 A


Units: mg/L

RL


Arsenic 0.200 100 90 1100.00500 00.200

Cadmium 0.200 101 90 1100.00100 00.201

Chromium 0.200 101 90 1100.00500 00.202

Copper 0.200 102 90 1100.0100 00.204

Iron 5.00 103 90 1100.100 05.14

Lead 0.200 99.5 90 1100.00100 00.199

Selenium 0.200 99.2 90 1100.00500 00.198

Zinc 0.200 103 90 1100.00500 00.206


Analysis Date: 11/20/2014 11:31:00 A


Units: mg/L

RL


Arsenic 0.00500 101 70 1300.00500 00.00507

Cadmium 0.00100 106 70 1300.00100 00.00106

Qualifiers:






32






Analysis Date: 11/20/2014 11:31:00 A


Units: mg/L

RL


Chromium 0.00500 107 70 1300.00500 00.00534

Copper 0.00500 77.4 70 1300.0100 00.00387

Iron 0.100 102 70 1300.100 00.102

Lead 0.00100 113 70 1300.00100 00.00113

Selenium 0.00500 108 70 1300.00500 00.00539

Zinc 0.00500 92.4 70 1300.00500 00.00462


Analysis Date: 11/20/2014 12:54:00 P


Units: mg/L

RL


Arsenic 0.200 99.7 90 1100.00500 00.199

Cadmium 0.200 99.6 90 1100.00100 00.199

Chromium 0.200 98.6 90 1100.00500 00.197

Copper 0.200 101 90 1100.0100 00.201

Lead 0.200 96.9 90 1100.00100 00.194

Selenium 0.200 101 90 1100.00500 00.201

Zinc 0.200 103 90 1100.00500 00.206


Analysis Date: 11/20/2014 12:58:00 P


Units: mg/L

RL


Arsenic 0.00500 101 70 1300.00500 00.00506

Cadmium 0.00100 108 70 1300.00100 00.00108

Chromium 0.00500 103 70 1300.00500 00.00517

Copper 0.00500 72.8 70 1300.0100 00.00364

Lead 0.00100 100 70 1300.00100 00.00100

Selenium 0.00500 115 70 1300.00500 00.00573

Zinc 0.00500 93.5 70 1300.00500 00.00468


Analysis Date: 11/20/2014 1:21:00 PM


Units: mg/L

RL


Arsenic 0.200 101 90 1100.00500 00.202

Cadmium 0.200 98.1 90 1100.00100 00.196

Chromium 0.200 99.2 90 1100.00500 00.198

Copper 0.200 99.9 90 1100.0100 00.200

Lead 0.200 96.4 90 1100.00100 00.193

Selenium 0.200 101 90 1100.00500 00.202

Qualifiers:






33






Analysis Date: 11/20/2014 1:21:00 PM


Units: mg/L

RL


Zinc 0.200 103 90 1100.00500 00.206


Analysis Date: 11/20/2014 1:25:00 PM


Units: mg/L

RL


Arsenic 0.00500 104 70 1300.00500 00.00518

Cadmium 0.00100 102 70 1300.00100 00.00102

Chromium 0.00500 104 70 1300.00500 00.00518

Copper 0.00500 71.1 70 1300.0100 00.00355

Lead 0.00100 106 70 1300.00100 00.00106

Selenium 0.00500 107 70 1300.00500 00.00534

Zinc 0.00500 92.4 70 1300.00500 00.00462


Analysis Date: 11/20/2014 1:44:00 PM


Units: mg/L

RL


Arsenic 0.200 101 90 1100.00500 00.202

Cadmium 0.200 99.0 90 1100.00100 00.198

Chromium 0.200 98.8 90 1100.00500 00.198

Copper 0.200 99.2 90 1100.0100 00.198

Iron 5.00 103 90 1100.100 05.15

Lead 0.200 97.3 90 1100.00100 00.195

Selenium 0.200 101 90 1100.00500 00.202

Zinc 0.200 103 90 1100.00500 00.206


Analysis Date: 11/20/2014 1:50:00 PM


Units: mg/L

RL


Arsenic 0.00500 101 70 1300.00500 00.00506

Cadmium 0.00100 105 70 1300.00100 00.00105

Chromium 0.00500 104 70 1300.00500 00.00520

Copper 0.00500 74.0 70 1300.0100 00.00370

Iron 0.100 102 70 1300.100 00.102

Lead 0.00100 110 70 1300.00100 00.00110

Selenium 0.00500 103 70 1300.00500 00.00513

Zinc 0.00500 94.7 70 1300.00500 00.00474

Qualifiers:






34






Analysis Date: 11/20/2014 2:31:00 PM


Units: mg/L

RL


Copper 0.200 100 90 1100.0100 00.200

Iron 5.00 103 90 1100.100 05.17

Zinc 0.200 103 90 1100.00500 00.205


Analysis Date: 11/20/2014 2:35:00 PM


Units: mg/L

RL


Copper 0.00500 68.9 70 130 S0.0100 00.00345

Iron 0.100 100 70 1300.100 00.100

Zinc 0.00500 91.3 70 1300.00500 00.00457

Qualifiers:






35




RunID: PMOIST_141119BThe QC data in batch 66614 applies to the following samples: 1411161-01A, 1411161-02A, 1411161-03A, 1411161-04A, 1411161-05A, 1411161-06A, 1411161-07A, 1411161-08A, 1411161-09A, 1411161-10A


Analysis Date: 11/20/2014 10:59:00 A


Units: WT%

RL



Qualifiers:






36





TestNo: SW7471B

mg/KgAnalyte

MQL

mg/Kg

MDL

Mercury 0.04000.0160

TestNo: SW6020A

mg/KgAnalyte

MQL

mg/Kg

MDL

Arsenic 1.000.500

Cadmium 0.3000.100

Chromium 2.000.500

Copper 2.000.500

Iron 12.512.5

Lead 0.3000.100

Selenium 0.5000.150

Zinc 2.501.00

Qualifiers:

Page 1 of 1



37

November 25, 2014


Dear Kyrie Jeffery:


Order No.: 1411174FAX (720) 344-3535

TEL: (720) 344-3851





Sincerely,





1

Table of Contents


.................................................................................. 9CaseNarrative 1411174







2
























6























method? X









applicable? X



X

7

RG-366/TRRP-13 May 2010

















________________________


11/25/14

8










The samples were received and log-in performed on 11/20/14. A total of 12 samples were received.


Exception Report R7-03 & R7-04


above control limits for three analytes. In addition, the matrix spike and matrix spike duplicate had the

RPD above control limits for Chromium and Iron. These are flagged accordingly in the QC summary

report. The reference sample selected for the matrix spike and matrix spike duplicate was not from this

work order. The LCS was within control limits for these analytes. No further corrective actions were

taken.

For Mercury analysis performed on 11/25/14 the matrix spike duplicate recovery was above control

limits. This is flagged accordingly. The reference sample selected for the matrix spike and matrix

spike duplicate was from this work order. The LCS was within control limits. No further corrective

actions were taken.

Page 1 of 1

9






1411174-01 J29-111914 11/19/14 03:05 PM 11/20/2014

1411174-02 L28-111914 11/19/14 03:13 PM 11/20/2014

1411174-03 M27-111914 11/19/14 03:20 PM 11/20/2014

1411174-04 N26-111914 11/19/14 03:28 PM 11/20/2014

1411174-05 L27-111914 11/19/14 03:14 PM 11/20/2014

1411174-06 K17-111914 11/19/14 02:24 PM 11/20/2014

1411174-07 J17-111914 11/19/14 02:26 PM 11/20/2014

1411174-08 I17-111914 11/19/14 02:30 PM 11/20/2014

1411174-09 N27-111914 11/19/14 03:23 PM 11/20/2014

1411174-10 L17-111914 11/19/14 02:20 PM 11/20/2014

1411174-11 J28-111914 11/19/14 03:08 PM 11/20/2014

1411174-12 K28-111914 11/19/14 03:11 PM 11/20/2014

Page 1 of 1

10


PREP DATES REPORT

25-Nov-14

Lab Order: 1411174





1411174-01A J29-111914 11/19/14 03:05 PM Soil Mercury Soil Prep, Total 11/24/14 02:07 PMSW7471A 66711

J29-111914 11/19/14 03:05 PM Soil Mercury Soil Prep, Total 11/24/14 02:07 PMSW7471A 66711

J29-111914 11/19/14 03:05 PM Soil Moisture Preparation 11/20/14 03:57 PMD2216 66652

J29-111914 11/19/14 03:05 PM Soil Soil Prep Total Metals: ICP-MS 11/20/14 08:30 AMSW3050B 66625


1411174-02A L28-111914 11/19/14 03:13 PM Soil Mercury Soil Prep, Total 11/24/14 02:07 PMSW7471A 66711

L28-111914 11/19/14 03:13 PM Soil Moisture Preparation 11/20/14 03:57 PMD2216 66652




M27-111914 11/19/14 03:20 PM Soil Moisture Preparation 11/20/14 03:57 PMD2216 66652

M27-111914 11/19/14 03:20 PM Soil Soil Prep Total Metals: ICP-MS 11/20/14 08:30 AMSW3050B 66625

M27-111914 11/19/14 03:20 PM Soil Soil Prep Total Metals: ICP-MS 11/20/14 08:30 AMSW3050B 66625


N26-111914 11/19/14 03:28 PM Soil Moisture Preparation 11/20/14 03:57 PMD2216 66652







1411174-06A K17-111914 11/19/14 02:24 PM Soil Mercury Soil Prep, Total 11/24/14 02:07 PMSW7471A 66711

K17-111914 11/19/14 02:24 PM Soil Moisture Preparation 11/20/14 03:57 PMD2216 66652






Page 1 of 2

11


PREP DATES REPORT

25-Nov-14

Lab Order: 1411174





1411174-07A J17-111914 11/19/14 02:26 PM Soil Soil Prep Total Metals: ICP-MS 11/20/14 08:30 AMSW3050B 66625

1411174-08A I17-111914 11/19/14 02:30 PM Soil Mercury Soil Prep, Total 11/24/14 02:07 PMSW7471A 66711

I17-111914 11/19/14 02:30 PM Soil Moisture Preparation 11/20/14 03:57 PMD2216 66652

I17-111914 11/19/14 02:30 PM Soil Soil Prep Total Metals: ICP-MS 11/20/14 08:30 AMSW3050B 66625

I17-111914 11/19/14 02:30 PM Soil Soil Prep Total Metals: ICP-MS 11/20/14 08:30 AMSW3050B 66625


N27-111914 11/19/14 03:23 PM Soil Moisture Preparation 11/20/14 03:57 PMD2216 66652












K28-111914 11/19/14 03:11 PM Soil Moisture Preparation 11/20/14 03:57 PMD2216 66652



Page 2 of 2

12



25-Nov-14

Lab Order: 1411174





1411174-01A J29-111914 D2216Soil Percent Moisture 11/21/14 11:01 AM66652 1 PMOIST_141120A

J29-111914 SW7471BSoil Total Mercury: Soil/Solid 11/25/14 10:49 AM66711 1 CETAC2_HG_141125

A


A

J29-111914 SW6020ASoil Trace Metals: ICP-MS - Solid 11/21/14 11:26 AM66625 5 ICP-MS4_141121B

J29-111914 SW6020ASoil Trace Metals: ICP-MS - Solid 11/21/14 02:04 PM66625 500 ICP-MS4_141121B

1411174-02A L28-111914 D2216Soil Percent Moisture 11/21/14 11:01 AM66652 1 PMOIST_141120A

L28-111914 SW7471BSoil Total Mercury: Soil/Solid 11/25/14 11:01 AM66711 1 CETAC2_HG_141125

A

L28-111914 SW6020ASoil Trace Metals: ICP-MS - Solid 11/21/14 11:27 AM66625 5 ICP-MS4_141121B




A





A





A



1411174-06A K17-111914 D2216Soil Percent Moisture 11/21/14 11:01 AM66652 1 PMOIST_141120A

K17-111914 SW7471BSoil Total Mercury: Soil/Solid 11/25/14 11:10 AM66711 1 CETAC2_HG_141125

A


K17-111914 SW6020ASoil Trace Metals: ICP-MS - Solid 11/21/14 11:35 AM66625 5 ICP-MS4_141121B

Page 1 of 2

13



25-Nov-14

Lab Order: 1411174







A

J17-111914 SW6020ASoil Trace Metals: ICP-MS - Solid 11/21/14 11:37 AM66625 5 ICP-MS4_141121B


1411174-08A I17-111914 D2216Soil Percent Moisture 11/21/14 11:01 AM66652 1 PMOIST_141120A

I17-111914 SW7471BSoil Total Mercury: Soil/Solid 11/25/14 11:14 AM66711 1 CETAC2_HG_141125

A

I17-111914 SW6020ASoil Trace Metals: ICP-MS - Solid 11/21/14 11:39 AM66625 5 ICP-MS4_141121B

I17-111914 SW6020ASoil Trace Metals: ICP-MS - Solid 11/21/14 02:21 PM66625 50 ICP-MS4_141121B



A





A





A



1411174-12A K28-111914 D2216Soil Percent Moisture 11/21/14 11:01 AM66652 1 PMOIST_141120A

K28-111914 SW7471BSoil Total Mercury: Soil/Solid 11/25/14 11:31 AM66711 1 CETAC2_HG_141125

A



Page 2 of 2

14


Client Sample ID: J29-111914


Matrix: SOIL



Lab Order: 1411174

DF

Lab ID: 1411174-01


RL

Project No: 6835001.2014.47SR2

SDL

TOTAL MERCURY: SOIL/SOLID SW7471B Analyst: SMMercury 11/25/14 11:35 AM0.201 mg/Kg-dry 50.276 0.0803

TRACE METALS: ICP-MS - SOLID SW6020A Analyst: ROArsenic 11/21/14 11:26 AM1.02 mg/Kg-dry 5308 0.511



Copper 11/21/14 02:04 PM204 mg/Kg-dry 5003710 51.1

Iron 11/21/14 02:04 PM1280 mg/Kg-dry 500126000 1280

Lead 11/21/14 02:04 PM30.6 mg/Kg-dry 5001340 10.2


Zinc 11/21/14 02:04 PM255 mg/Kg-dry 50011200 102


Qualifiers:

Page 1 of 12








DF- Dilution Factor




15




Matrix: SOIL



Lab Order: 1411174

DF

Lab ID: 1411174-02


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/21/14 02:05 PM128 mg/Kg-dry 5010800 128

Lead 11/21/14 11:27 AM0.306 mg/Kg-dry 5247 0.102


Zinc 11/21/14 02:05 PM25.5 mg/Kg-dry 50611 10.2


Qualifiers:

Page 2 of 12








DF- Dilution Factor




16




Matrix: SOIL



Lab Order: 1411174

DF

Lab ID: 1411174-03


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/21/14 02:07 PM128 mg/Kg-dry 509860 128

Lead 11/21/14 11:29 AM0.307 mg/Kg-dry 542.8 0.102


Zinc 11/21/14 11:29 AM2.56 mg/Kg-dry 5175 1.02


Qualifiers:

Page 3 of 12








DF- Dilution Factor




17




Matrix: SOIL



Lab Order: 1411174

DF

Lab ID: 1411174-04


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/21/14 02:09 PM124 mg/Kg-dry 509560 124

Lead 11/21/14 11:31 AM0.297 mg/Kg-dry 527.6 0.0990


Zinc 11/21/14 11:31 AM2.47 mg/Kg-dry 591.6 0.990


Qualifiers:

Page 4 of 12








DF- Dilution Factor




18




Matrix: SOIL



Lab Order: 1411174

DF

Lab ID: 1411174-05


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/21/14 02:11 PM118 mg/Kg-dry 5013700 118

Lead 11/21/14 11:33 AM0.284 mg/Kg-dry 5179 0.0946


Zinc 11/21/14 11:33 AM2.36 mg/Kg-dry 5451 0.946


Qualifiers:

Page 5 of 12








DF- Dilution Factor




19




Matrix: SOIL



Lab Order: 1411174

DF

Lab ID: 1411174-06


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/21/14 02:13 PM261 mg/Kg-dry 10033800 261

Lead 11/21/14 11:35 AM0.313 mg/Kg-dry 5381 0.104


Zinc 11/21/14 02:13 PM52.1 mg/Kg-dry 1002440 20.8


Qualifiers:

Page 6 of 12








DF- Dilution Factor




20




Matrix: SOIL



Lab Order: 1411174

DF

Lab ID: 1411174-07


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/21/14 02:20 PM129 mg/Kg-dry 5012700 129

Lead 11/21/14 11:37 AM0.311 mg/Kg-dry 5127 0.104


Zinc 11/21/14 11:37 AM2.59 mg/Kg-dry 5469 1.04


Qualifiers:

Page 7 of 12








DF- Dilution Factor




21


Client Sample ID: I17-111914


Matrix: SOIL



Lab Order: 1411174

DF

Lab ID: 1411174-08


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/21/14 02:21 PM133 mg/Kg-dry 5018700 133

Lead 11/21/14 11:39 AM0.320 mg/Kg-dry 5203 0.107


Zinc 11/21/14 02:21 PM26.7 mg/Kg-dry 50915 10.7


Qualifiers:

Page 8 of 12








DF- Dilution Factor




22




Matrix: SOIL



Lab Order: 1411174

DF

Lab ID: 1411174-09


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/21/14 02:23 PM123 mg/Kg-dry 5010500 123

Lead 11/21/14 11:41 AM0.296 mg/Kg-dry 550.4 0.0985


Zinc 11/21/14 11:41 AM2.46 mg/Kg-dry 5212 0.985


Qualifiers:

Page 9 of 12








DF- Dilution Factor




23




Matrix: SOIL



Lab Order: 1411174

DF

Lab ID: 1411174-10


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/21/14 12:57 PM114 mg/Kg-dry 5019100 114

Lead 11/21/14 11:43 AM0.273 mg/Kg-dry 5426 0.0910


Zinc 11/21/14 12:57 PM22.8 mg/Kg-dry 501180 9.10


Qualifiers:

Page 10 of 12








DF- Dilution Factor




24




Matrix: SOIL



Lab Order: 1411174

DF

Lab ID: 1411174-11


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/21/14 12:59 PM247 mg/Kg-dry 10032000 247

Lead 11/21/14 12:59 PM5.92 mg/Kg-dry 100751 1.97


Zinc 11/21/14 12:59 PM49.4 mg/Kg-dry 1002900 19.7


Qualifiers:

Page 11 of 12








DF- Dilution Factor




25




Matrix: SOIL



Lab Order: 1411174

DF

Lab ID: 1411174-12


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/21/14 02:36 PM1210 mg/Kg-dry 50060900 1210

Lead 11/21/14 02:36 PM29.1 mg/Kg-dry 5001370 9.70


Zinc 11/21/14 02:36 PM242 mg/Kg-dry 5004720 97.0


Qualifiers:

Page 12 of 12








DF- Dilution Factor




26







Analysis Date: 11/12/2014 12:10:13 P


Units: mg/Kg

RL


Mercury 0.02000 112 60 140 00.0400 0 00.0223

Qualifiers:






27




RunID: CETAC2_HG_141125AThe QC data in batch 66711 applies to the following samples: 1411174-01A, 1411174-02A, 1411174-03A, 1411174-04A, 1411174-05A, 1411174-06A, 1411174-07A, 1411174-08A, 1411174-09A, 1411174-10A, 1411174-11A, 1411174-12A


Analysis Date: 11/25/2014 10:42:54 A


Units: mg/Kg

RL


Mercury 0.0400<0.0160


Analysis Date: 11/25/2014 10:45:11 A


Units: mg/Kg

RL


Mercury 0.2000 108 85 1150.0400 00.215


Analysis Date: 11/25/2014 10:47:28 A


Units: mg/Kg

RL


Mercury 0.2000 110 85 115 250.0400 0 2.750.221


Analysis Date: 11/25/2014 11:38:03 A


Units: mg/Kg-dry

RL


Mercury 0 101.00 0.2762 0<0.402


Analysis Date: 11/25/2014 11:40:20 A


Units: mg/Kg-dry

RL


Mercury 1.255 104 85 1150.201 0.27621.59


Analysis Date: 11/25/2014 11:42:37 A


Units: mg/Kg-dry

RL


Mercury 0.2087 114 80 1200.209 0.27620.514


Analysis Date: 11/25/2014 11:44:54 A


Units: mg/Kg-dry

RL


Mercury 0.2039 170 80 120 25 S0.204 0.2762 18.90.622

Qualifiers:






28






Analysis Date: 11/25/2014 9:27:53 AM


Units: mg/Kg

RL


Mercury 0.004000 102 90 1100.0400 00.00406


Analysis Date: 11/25/2014 10:38:19 A


Units: mg/Kg

RL


Mercury 0.002000 99.5 90 1100.0400 00.00199


Analysis Date: 11/25/2014 11:24:18 A


Units: mg/Kg

RL


Mercury 0.002000 101 90 1100.0400 00.00201


Analysis Date: 11/25/2014 11:47:12 A


Units: mg/Kg

RL


Mercury 0.002000 101 90 1100.0400 00.00201

Qualifiers:






29






Analysis Date: 11/10/2014 11:31:00 A


Units: mg/Kg

RL


Arsenic 0.1500 113 80 120 01.00 0 00.169

Cadmium 0.1500 99.7 80 120 00.300 0 00.150

Chromium 0.1500 116 80 120 02.00 0 00.174

Copper 0.1500 97.0 80 120 02.00 0 00.146

Iron 6.250 106 80 120 012.5 0 06.64

Lead 0.1500 102 80 120 00.300 0 00.152

Selenium 0.1500 118 80 120 00.500 0 00.178


Analysis Date: 11/10/2014 11:35:00 A


Units: mg/Kg

RL


Zinc 5.000 106 80 120 02.50 0 05.31

Qualifiers:






30




RunID: ICP-MS4_141121BThe QC data in batch 66625 applies to the following samples: 1411174-01A, 1411174-02A, 1411174-03A, 1411174-04A, 1411174-05A, 1411174-06A, 1411174-07A, 1411174-08A, 1411174-09A, 1411174-10A, 1411174-11A, 1411174-12A


Analysis Date: 11/21/2014 10:59:00 A


Units: mg/Kg

RL


Arsenic 1.00<0.500

Cadmium 0.300<0.100

Chromium 2.00<0.500

Copper 2.00<0.500

Iron 12.5<12.5

Lead 0.300<0.100


Zinc 2.50<1.00


Analysis Date: 11/21/2014 11:01:00 A


Units: mg/Kg

RL


Arsenic 50.00 100 80 1201.00 050.1

Cadmium 50.00 99.4 80 1200.300 049.7

Chromium 50.00 103 80 1202.00 051.3

Copper 50.00 106 80 1202.00 053.1

Iron 250.0 98.8 80 12012.5 0247

Lead 50.00 98.3 80 1200.300 049.1

Selenium 50.00 99.1 80 1200.500 049.6

Zinc 50.00 103 80 1202.50 051.4


Analysis Date: 11/21/2014 11:02:00 A


Units: mg/Kg

RL


Arsenic 50.00 103 80 120 201.00 0 2.7951.5

Cadmium 50.00 101 80 120 200.300 0 1.8150.6

Chromium 50.00 105 80 120 202.00 0 2.4052.5

Copper 50.00 110 80 120 202.00 0 3.2754.8

Iron 250.0 101 80 120 2012.5 0 1.97252

Lead 50.00 99.4 80 120 200.300 0 1.1649.7

Selenium 50.00 102 80 120 200.500 0 3.2351.2

Zinc 50.00 105 80 120 202.50 0 1.7752.3


Analysis Date: 11/21/2014 11:08:00 A


Units: mg/Kg-dry

RL


Qualifiers:






31






Analysis Date: 11/21/2014 11:08:00 A


Units: mg/Kg-dry

RL


Arsenic 0 105.03 4.800 0.6994.77

Cadmium 0 101.51 0 0<0.503

Chromium 0 1010.1 25.28 0.59325.4

Copper 0 1010.1 4.017 4.113.86

Lead 0 101.51 9.901 2.439.66

Selenium 0 102.51 1.557 0.4351.56

Zinc 0 1012.6 25.06 0.95525.3


Analysis Date: 11/21/2014 11:10:00 A


Units: mg/Kg-dry

RL


Arsenic 50.29 107 80 1201.01 4.80058.6

Cadmium 50.29 107 80 1200.302 053.9

Chromium 50.29 107 80 1202.01 25.2879.2

Copper 50.29 111 80 1202.01 4.01759.7

Lead 50.29 107 80 1200.302 9.90163.8

Selenium 50.29 105 80 1200.503 1.55754.6

Zinc 50.29 108 80 1202.51 25.0679.3


Analysis Date: 11/21/2014 11:12:00 A


Units: mg/Kg-dry

RL


Arsenic 53.44 112 80 1201.07 4.80064.5

Cadmium 53.44 101 80 1200.321 053.9

Chromium 53.44 152 80 120 S2.14 25.28107

Copper 53.44 107 80 1202.14 4.01761.3

Iron 267.2 6700 80 120 S13.4 2393041800

Lead 53.44 106 80 1200.321 9.90166.5

Selenium 53.44 99.5 80 1200.534 1.55754.7

Zinc 53.44 127 80 120 S2.67 25.0693.0


Analysis Date: 11/21/2014 11:14:00 A


Units: mg/Kg-dry

RL


Arsenic 52.97 98.5 80 120 201.06 4.800 12.357.0

Cadmium 52.97 102 80 120 200.318 0 0.07654.0

Chromium 52.97 105 80 120 20 R2.12 25.28 27.580.8

Copper 52.97 106 80 120 202.12 4.017 1.6360.3

Qualifiers:






32






Analysis Date: 11/21/2014 11:14:00 A


Units: mg/Kg-dry

RL


Iron 264.8 466 80 120 20 SR13.2 23930 49.825200

Lead 52.97 98.5 80 120 200.318 9.901 6.9262.1

Selenium 52.97 98.3 80 120 200.530 1.557 2.0853.6

Zinc 52.97 107 80 120 202.65 25.06 12.681.9


Analysis Date: 11/21/2014 2:02:00 PM


Units: mg/Kg-dry

RL


Iron 0 101260 24530 2.1324000


Analysis Date: 11/21/2014 2:25:00 PM


Units: mg/Kg-dry

RL


Iron 25150 109 80 120251 2453052000

Qualifiers:






33






Analysis Date: 11/21/2014 10:18:00 A


Units: mg/L

RL


Arsenic 0.100 101 90 1100.00500 00.101

Cadmium 0.100 105 90 1100.00100 00.105

Chromium 0.100 108 90 1100.00500 00.108

Copper 0.100 110 90 1100.0100 00.110

Iron 2.50 103 90 1100.100 02.58

Lead 0.100 101 90 1100.00100 00.101

Selenium 0.100 103 90 1100.00500 00.103

Zinc 0.100 105 90 1100.00500 00.105


Analysis Date: 11/21/2014 10:23:00 A


Units: mg/L

RL


Arsenic 0.00500 102 70 1300.00500 00.00508

Cadmium 0.00100 113 70 1300.00100 00.00113

Chromium 0.00500 112 70 1300.00500 00.00562

Copper 0.00500 108 70 1300.0100 00.00538

Iron 0.100 104 70 1300.100 00.104

Lead 0.00100 111 70 1300.00100 00.00111

Selenium 0.00500 94.6 70 1300.00500 00.00473

Zinc 0.00500 105 70 1300.00500 00.00524


Analysis Date: 11/21/2014 10:51:00 A


Units: mg/L

RL


Arsenic 0.200 99.5 90 1100.00500 00.199

Cadmium 0.200 103 90 1100.00100 00.206

Chromium 0.200 103 90 1100.00500 00.205

Copper 0.200 104 90 1100.0100 00.209

Iron 5.00 102 90 1100.100 05.09

Lead 0.200 98.7 90 1100.00100 00.197

Selenium 0.200 98.9 90 1100.00500 00.198

Zinc 0.200 102 90 1100.00500 00.204


Analysis Date: 11/21/2014 10:55:00 A


Units: mg/L

RL


Arsenic 0.00500 106 70 1300.00500 00.00530

Cadmium 0.00100 106 70 1300.00100 00.00106

Qualifiers:






34






Analysis Date: 11/21/2014 10:55:00 A


Units: mg/L

RL


Chromium 0.00500 108 70 1300.00500 00.00541

Copper 0.00500 104 70 1300.0100 00.00518

Iron 0.100 102 70 1300.100 00.102

Lead 0.00100 103 70 1300.00100 00.00103

Selenium 0.00500 97.2 70 1300.00500 00.00486

Zinc 0.00500 106 70 1300.00500 00.00529


Analysis Date: 11/21/2014 11:16:00 A


Units: mg/L

RL


Arsenic 0.200 102 90 1100.00500 00.203

Cadmium 0.200 101 90 1100.00100 00.203

Chromium 0.200 103 90 1100.00500 00.206

Copper 0.200 107 90 1100.0100 00.213

Iron 5.00 102 90 1100.100 05.11

Lead 0.200 97.5 90 1100.00100 00.195

Selenium 0.200 101 90 1100.00500 00.201

Zinc 0.200 104 90 1100.00500 00.208


Analysis Date: 11/21/2014 11:20:00 A


Units: mg/L

RL


Arsenic 0.00500 102 70 1300.00500 00.00512

Cadmium 0.00100 108 70 1300.00100 00.00108

Chromium 0.00500 107 70 1300.00500 00.00537

Copper 0.00500 102 70 1300.0100 00.00511

Iron 0.100 105 70 1300.100 00.105

Lead 0.00100 101 70 1300.00100 00.00101

Selenium 0.00500 110 70 1300.00500 00.00550

Zinc 0.00500 105 70 1300.00500 00.00524


Analysis Date: 11/21/2014 11:45:00 A


Units: mg/L

RL


Arsenic 0.200 102 90 1100.00500 00.203

Cadmium 0.200 99.6 90 1100.00100 00.199

Chromium 0.200 104 90 1100.00500 00.208

Copper 0.200 107 90 1100.0100 00.214

Qualifiers:






35






Analysis Date: 11/21/2014 11:45:00 A


Units: mg/L

RL


Lead 0.200 97.9 90 1100.00100 00.196

Selenium 0.200 101 90 1100.00500 00.201

Zinc 0.200 105 90 1100.00500 00.209


Analysis Date: 11/21/2014 11:53:00 A


Units: mg/L

RL


Arsenic 0.00500 105 70 1300.00500 00.00523

Cadmium 0.00100 108 70 1300.00100 00.00108

Chromium 0.00500 110 70 1300.00500 00.00552

Copper 0.00500 107 70 1300.0100 00.00536

Lead 0.00100 116 70 1300.00100 00.00116

Selenium 0.00500 102 70 1300.00500 00.00511

Zinc 0.00500 119 70 1300.00500 00.00597


Analysis Date: 11/21/2014 12:29:00 P


Units: mg/L

RL


Arsenic 0.200 102 90 1100.00500 00.203

Cadmium 0.200 100 90 1100.00100 00.200

Chromium 0.200 103 90 1100.00500 00.206

Copper 0.200 106 90 1100.0100 00.213

Iron 5.00 104 90 1100.100 05.18

Lead 0.200 96.1 90 1100.00100 00.192

Selenium 0.200 101 90 1100.00500 00.203

Zinc 0.200 104 90 1100.00500 00.208


Analysis Date: 11/21/2014 12:53:00 P


Units: mg/L

RL


Arsenic 0.00500 103 70 1300.00500 00.00517

Cadmium 0.00100 107 70 1300.00100 00.00107

Chromium 0.00500 108 70 1300.00500 00.00539

Copper 0.00500 103 70 1300.0100 00.00517

Iron 0.100 101 70 1300.100 00.101

Lead 0.00100 105 70 1300.00100 00.00105

Selenium 0.00500 110 70 1300.00500 00.00551

Zinc 0.00500 108 70 1300.00500 00.00542

Qualifiers:






36






Analysis Date: 11/21/2014 1:32:00 PM


Units: mg/L

RL


Copper 0.200 106 90 1100.0100 00.212

Iron 5.00 103 90 1100.100 05.14

Lead 0.200 96.8 90 1100.00100 00.194

Zinc 0.200 103 90 1100.00500 00.206


Analysis Date: 11/21/2014 1:56:00 PM


Units: mg/L

RL


Copper 0.00500 100 70 1300.0100 00.00502

Iron 0.100 100 70 1300.100 00.100

Lead 0.00100 101 70 1300.00100 00.00101

Zinc 0.00500 108 70 1300.00500 00.00538


Analysis Date: 11/21/2014 2:27:00 PM


Units: mg/L

RL


Copper 0.200 106 90 1100.0100 00.212

Iron 5.00 104 90 1100.100 05.18

Lead 0.200 96.3 90 1100.00100 00.193

Zinc 0.200 102 90 1100.00500 00.204


Analysis Date: 11/21/2014 2:31:00 PM


Units: mg/L

RL


Copper 0.00500 101 70 1300.0100 00.00506

Iron 0.100 103 70 1300.100 00.103

Lead 0.00100 102 70 1300.00100 00.00102

Zinc 0.00500 106 70 1300.00500 00.00532


Analysis Date: 11/21/2014 2:47:00 PM


Units: mg/L

RL


Copper 0.200 106 90 1100.0100 00.212

Iron 5.00 104 90 1100.100 05.19

Lead 0.200 95.9 90 1100.00100 00.192

Zinc 0.200 103 90 1100.00500 00.206

Qualifiers:






37






Analysis Date: 11/21/2014 2:56:00 PM


Units: mg/L

RL


Copper 0.00500 101 70 1300.0100 00.00503

Iron 0.100 100 70 1300.100 00.100

Lead 0.00100 101 70 1300.00100 00.00101

Zinc 0.00500 104 70 1300.00500 00.00520

Qualifiers:






38




RunID: PMOIST_141120AThe QC data in batch 66652 applies to the following samples: 1411174-01A, 1411174-02A, 1411174-03A, 1411174-04A, 1411174-05A, 1411174-06A, 1411174-07A, 1411174-08A, 1411174-09A, 1411174-10A, 1411174-11A, 1411174-12A


Analysis Date: 11/21/2014 11:01:00 A


Units: WT%

RL



Qualifiers:






39





TestNo: SW7471B

mg/KgAnalyte

MQL

mg/Kg

MDL

Mercury 0.04000.0160

TestNo: SW6020A

mg/KgAnalyte

MQL

mg/Kg

MDL

Arsenic 1.000.500

Cadmium 0.3000.100

Chromium 2.000.500

Copper 2.000.500

Iron 12.512.5

Lead 0.3000.100

Selenium 0.5000.150

Zinc 2.501.00

Qualifiers:

Page 1 of 1



40

November 26, 2014


Dear Kyrie Jeffery:


Order No.: 1411191FAX (720) 344-3535

TEL: (720) 344-3851





Sincerely,





1

Table of Contents


.................................................................................. 9CaseNarrative 1411191







2



DHL Analytical, Inc. Laboratory Review Checklist: Reportable Data Project Name: ASARCO-El Paso Cemetery Fines Pole Date: 11/26/14





















6




Project Name: ASARCO-El Paso Cemetery Fines Pole Date: 11/26/14



















method? X S9-01









applicable? X



X

7

RG-366/TRRP-13 May 2010

















________________________


11/26/14

8







MethodSW7471B - Mercury Analysis







above control limits for Iron. These are flagged accordingly in the QC summary report. The reference

sample selected for the matrix spike and matrix spike duplicate was not from this work order. The LCS

was within control limits for this analyte. No further corrective actions were taken.

For Mercury analysis performed on 11/25/14 the matrix spike duplicate recovery was slightly above

control limits. This is flagged accordingly. The reference sample selected for the matrix spike and

matrix spike duplicate was from this work order. The LCS was within control limits. No further

corrective actions were taken.


For Mercury analysis performed on 11/25/14 the PDS recovery was below control limits. This is

flagged accordingly in the QC summary report. The serial dilution was within control limits. No

further corrective actions were taken.

Page 1 of 1

9






1411191-01 K28-112014 11/20/14 03:11 PM 11/21/2014

1411191-02 F06-112014 11/20/14 11:00 AM 11/21/2014

1411191-03 D05-112014 11/20/14 11:30 AM 11/21/2014

1411191-04 E08-112014 11/20/14 11:20 AM 11/21/2014

1411191-05 N18-112014 11/20/14 10:45 AM 11/21/2014

1411191-06 F08-112014 11/20/14 11:06 AM 11/21/2014

1411191-07 F07-112014 11/20/14 11:03 AM 11/21/2014

1411191-08 E07-112014 11/20/14 11:23 AM 11/21/2014

1411191-09 D04-112014 11/20/14 11:30 AM 11/21/2014

1411191-10 E09-112014 11/20/14 11:15 AM 11/21/2014

Page 1 of 1

10


PREP DATES REPORT

26-Nov-14

Lab Order: 1411191






K28-112014 11/20/14 03:11 PM Soil Mercury Soil Prep, Total 11/24/14 02:06 PMSW7471A 66710

K28-112014 11/20/14 03:11 PM Soil Moisture Preparation 11/21/14 11:37 AMD2216 66677

K28-112014 11/20/14 03:11 PM Soil Soil Prep Total Metals: ICP-MS 11/24/14 02:02 PMSW3050B 66709

K28-112014 11/20/14 03:11 PM Soil Soil Prep Total Metals: ICP-MS 11/24/14 02:02 PMSW3050B 66709





1411191-03A D05-112014 11/20/14 11:30 AM Soil Mercury Soil Prep, Total 11/24/14 02:06 PMSW7471A 66710

D05-112014 11/20/14 11:30 AM Soil Moisture Preparation 11/21/14 11:37 AMD2216 66677

D05-112014 11/20/14 11:30 AM Soil Soil Prep Total Metals: ICP-MS 11/24/14 02:02 PMSW3050B 66709



E08-112014 11/20/14 11:20 AM Soil Mercury Soil Prep, Total 11/24/14 02:06 PMSW7471A 66710




1411191-05A N18-112014 11/20/14 10:45 AM Soil Mercury Soil Prep, Total 11/24/14 02:06 PMSW7471A 66710

N18-112014 11/20/14 10:45 AM Soil Moisture Preparation 11/21/14 11:37 AMD2216 66677

N18-112014 11/20/14 10:45 AM Soil Soil Prep Total Metals: ICP-MS 11/24/14 02:02 PMSW3050B 66709

N18-112014 11/20/14 10:45 AM Soil Soil Prep Total Metals: ICP-MS 11/24/14 02:02 PMSW3050B 66709


F08-112014 11/20/14 11:06 AM Soil Mercury Soil Prep, Total 11/24/14 02:06 PMSW7471A 66710





Page 1 of 2

11


PREP DATES REPORT

26-Nov-14

Lab Order: 1411191













1411191-09A D04-112014 11/20/14 11:30 AM Soil Mercury Soil Prep, Total 11/24/14 02:06 PMSW7471A 66710

D04-112014 11/20/14 11:30 AM Soil Moisture Preparation 11/21/14 11:37 AMD2216 66677







Page 2 of 2

12



26-Nov-14

Lab Order: 1411191





1411191-01A K28-112014 D2216Soil Percent Moisture 11/24/14 12:21 PM66677 1 PMOIST_141121D


B


B

K28-112014 SW6020ASoil Trace Metals: ICP-MS - Solid 11/25/14 04:40 PM66709 5 ICP-MS3_141125A

K28-112014 SW6020ASoil Trace Metals: ICP-MS - Solid 11/25/14 07:10 PM66709 100 ICP-MS3_141125A

1411191-02A F06-112014 D2216Soil Percent Moisture 11/24/14 12:21 PM66677 1 PMOIST_141121D


B



1411191-03A D05-112014 D2216Soil Percent Moisture 11/24/14 12:21 PM66677 1 PMOIST_141121D

D05-112014 SW7471BSoil Total Mercury: Soil/Solid 11/25/14 01:40 PM66710 1 CETAC2_HG_141125

B

D05-112014 SW6020ASoil Trace Metals: ICP-MS - Solid 11/25/14 04:52 PM66709 5 ICP-MS3_141125A


1411191-04A E08-112014 D2216Soil Percent Moisture 11/24/14 12:21 PM66677 1 PMOIST_141121D


B


B



1411191-05A N18-112014 D2216Soil Percent Moisture 11/24/14 12:21 PM66677 1 PMOIST_141121D


B

N18-112014 SW6020ASoil Trace Metals: ICP-MS - Solid 11/25/14 05:04 PM66709 5 ICP-MS3_141125A

N18-112014 SW6020ASoil Trace Metals: ICP-MS - Solid 11/25/14 07:34 PM66709 50 ICP-MS3_141125A



B

Page 1 of 2

13



26-Nov-14

Lab Order: 1411191





1411191-06A F08-112014 SW7471BSoil Total Mercury: Soil/Solid 11/25/14 02:32 PM66710 5 CETAC2_HG_141125

B





B


B





B



1411191-09A D04-112014 D2216Soil Percent Moisture 11/24/14 12:21 PM66677 1 PMOIST_141121D

D04-112014 SW7471BSoil Total Mercury: Soil/Solid 11/25/14 01:56 PM66710 1 CETAC2_HG_141125

B





B



Page 2 of 2

14




Matrix: SOIL



Lab Order: 1411191

DF

Lab ID: 1411191-01


RL

Project No: 6835001.2014.47SR2

SDL


TRACE METALS: ICP-MS - SOLID SW6020A Analyst: KLArsenic 11/25/14 04:40 PM0.949 mg/Kg-dry 5175 0.475




Iron 11/25/14 07:10 PM237 mg/Kg-dry 10045900 237

Lead 11/25/14 07:10 PM5.70 mg/Kg-dry 1001260 1.90


Zinc 11/25/14 07:10 PM47.5 mg/Kg-dry 1004600 19.0

PERCENT MOISTURE D2216 Analyst: JLPercent Moisture 11/24/14 12:21 PM0 WT% 12.54 0

Qualifiers:

Page 1 of 10








DF- Dilution Factor




15




Matrix: SOIL



Lab Order: 1411191

DF

Lab ID: 1411191-02


RL

Project No: 6835001.2014.47SR2

SDL


TRACE METALS: ICP-MS - SOLID SW6020A Analyst: KLArsenic 11/25/14 04:46 PM1.00 mg/Kg-dry 532.2 0.502




Iron 11/25/14 07:16 PM125 mg/Kg-dry 5015100 125

Lead 11/25/14 04:46 PM0.301 mg/Kg-dry 5118 0.100


Zinc 11/25/14 07:16 PM25.1 mg/Kg-dry 50582 10.0


Qualifiers:

Page 2 of 10








DF- Dilution Factor




16


Client Sample ID: D05-112014


Matrix: SOIL



Lab Order: 1411191

DF

Lab ID: 1411191-03


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/25/14 07:22 PM127 mg/Kg-dry 5013500 127

Lead 11/25/14 04:52 PM0.304 mg/Kg-dry 5191 0.101


Zinc 11/25/14 04:52 PM2.54 mg/Kg-dry 5428 1.01


Qualifiers:

Page 3 of 10








DF- Dilution Factor




17




Matrix: SOIL



Lab Order: 1411191

DF

Lab ID: 1411191-04


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/25/14 07:28 PM268 mg/Kg-dry 10020500 268

Lead 11/25/14 07:28 PM6.44 mg/Kg-dry 100628 2.15


Zinc 11/25/14 07:28 PM53.6 mg/Kg-dry 1001440 21.5


Qualifiers:

Page 4 of 10








DF- Dilution Factor




18




Matrix: SOIL



Lab Order: 1411191

DF

Lab ID: 1411191-05


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/25/14 07:34 PM132 mg/Kg-dry 5012200 132

Lead 11/25/14 05:04 PM0.318 mg/Kg-dry 532.5 0.106


Zinc 11/25/14 05:04 PM2.65 mg/Kg-dry 5215 1.06


Qualifiers:

Page 5 of 10








DF- Dilution Factor




19




Matrix: SOIL



Lab Order: 1411191

DF

Lab ID: 1411191-06


RL

Project No: 6835001.2014.47SR2

SDL


TRACE METALS: ICP-MS - SOLID SW6020A Analyst: KLArsenic 11/25/14 05:10 PM1.00 mg/Kg-dry 5118 0.501




Iron 11/25/14 07:40 PM250 mg/Kg-dry 10025400 250

Lead 11/25/14 07:40 PM6.01 mg/Kg-dry 100760 2.00


Zinc 11/25/14 07:40 PM50.1 mg/Kg-dry 1001740 20.0


Qualifiers:

Page 6 of 10








DF- Dilution Factor




20




Matrix: SOIL



Lab Order: 1411191

DF

Lab ID: 1411191-07


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/25/14 07:46 PM123 mg/Kg-dry 5015000 123

Lead 11/25/14 07:46 PM2.94 mg/Kg-dry 50611 0.981


Zinc 11/25/14 07:46 PM24.5 mg/Kg-dry 50864 9.81


Qualifiers:

Page 7 of 10








DF- Dilution Factor




21




Matrix: SOIL



Lab Order: 1411191

DF

Lab ID: 1411191-08


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/25/14 07:52 PM129 mg/Kg-dry 509480 129

Lead 11/25/14 06:22 PM0.310 mg/Kg-dry 536.8 0.103


Zinc 11/25/14 06:22 PM2.58 mg/Kg-dry 5102 1.03


Qualifiers:

Page 8 of 10








DF- Dilution Factor




22


Client Sample ID: D04-112014


Matrix: SOIL



Lab Order: 1411191

DF

Lab ID: 1411191-09


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/25/14 07:58 PM131 mg/Kg-dry 5010500 131

Lead 11/25/14 06:28 PM0.314 mg/Kg-dry 5132 0.105


Zinc 11/25/14 06:28 PM2.62 mg/Kg-dry 5248 1.05


Qualifiers:

Page 9 of 10








DF- Dilution Factor




23




Matrix: SOIL



Lab Order: 1411191

DF

Lab ID: 1411191-10


RL

Project No: 6835001.2014.47SR2

SDL






Iron 11/25/14 08:04 PM133 mg/Kg-dry 5016700 133

Lead 11/25/14 06:34 PM0.319 mg/Kg-dry 5516 0.106


Zinc 11/25/14 08:04 PM26.6 mg/Kg-dry 501150 10.6


Qualifiers:

Page 10 of 10








DF- Dilution Factor




24







Analysis Date: 11/12/2014 12:10:13 P


Units: mg/Kg

RL


Mercury 0.02000 112 60 140 00.0400 0 00.0223

Qualifiers:






25




RunID: CETAC2_HG_141125BThe QC data in batch 66710 applies to the following samples: 1411191-01A, 1411191-02A, 1411191-03A, 1411191-04A, 1411191-05A, 1411191-06A, 1411191-07A, 1411191-08A, 1411191-09A, 1411191-10A


Analysis Date: 11/25/2014 1:20:08 PM


Units: mg/Kg

RL


Mercury 0.0400<0.0160


Analysis Date: 11/25/2014 1:22:24 PM


Units: mg/Kg

RL


Mercury 0.2000 109 85 1150.0400 00.218


Analysis Date: 11/25/2014 1:24:40 PM


Units: mg/Kg

RL


Mercury 0.2000 110 85 115 250.0400 0 0.4580.219


Analysis Date: 11/25/2014 2:21:30 PM


Units: mg/Kg-dry

RL


Mercury 0 100.913 0.3430 0<0.365


Analysis Date: 11/25/2014 2:23:45 PM


Units: mg/Kg-dry

RL


Mercury 1.142 0.640 85 115 S0.183 0.34300.350


Analysis Date: 11/25/2014 2:26:01 PM


Units: mg/Kg-dry

RL


Mercury 0.1867 104 80 1200.187 0.34300.537


Analysis Date: 11/25/2014 2:28:16 PM


Units: mg/Kg-dry

RL


Mercury 0.1888 128 80 120 25 S0.189 0.3430 8.680.585

Qualifiers:






26






Analysis Date: 11/25/2014 9:27:53 AM


Units: mg/Kg

RL


Mercury 0.004000 102 90 1100.0400 00.00406


Analysis Date: 11/25/2014 11:47:12 A


Units: mg/Kg

RL


Mercury 0.002000 101 90 1100.0400 00.00201


Analysis Date: 11/25/2014 2:14:03 PM


Units: mg/Kg

RL


Mercury 0.002000 102 90 1100.0400 00.00203


Analysis Date: 11/25/2014 2:37:22 PM


Units: mg/Kg

RL


Mercury 0.002000 101 90 1100.0400 00.00201

Qualifiers:






27






Analysis Date: 10/17/2014 6:13:00 PM


Units: mg/Kg

RL

DCS2SampType: Run ID: ICP-MS3_141017C Prep Date: 10/17/2014

Arsenic 1.000 94.8 80 120 01.00 0 00.948

Chromium 1.000 102 80 120 02.00 0 01.02

Copper 1.000 103 80 120 02.00 0 01.03

Iron 12.50 104 80 120 012.5 0 013.1


Analysis Date: 10/20/2014 1:11:00 PM


Units: mg/Kg

RL

DCSSampType: Run ID: ICP-MS3_141017C Prep Date: 10/17/2014

Cadmium 0.1500 103 80 120 00.300 0 00.154

Selenium 0.1500 120 80 120 00.500 0 00.180


Analysis Date: 10/20/2014 1:24:00 PM


Units: mg/Kg

RL

DCS3SampType: Run ID: ICP-MS3_141017C Prep Date: 10/17/2014

Zinc 5.000 119 80 120 02.50 0 05.97


Analysis Date: 10/22/2014 5:52:00 PM


Units: mg/Kg

RL

DCSSampType: Run ID: ICP-MS3_141017C Prep Date: 10/17/2014

Lead 0.1500 106 80 120 00.300 0 00.160

Qualifiers:






28




RunID: ICP-MS3_141125AThe QC data in batch 66709 applies to the following samples: 1411191-01A, 1411191-02A, 1411191-03A, 1411191-04A, 1411191-05A, 1411191-06A, 1411191-07A, 1411191-08A, 1411191-09A, 1411191-10A


Analysis Date: 11/25/2014 3:39:00 PM


Units: mg/Kg

RL


Arsenic 1.00<0.500

Cadmium 0.300<0.100

Chromium 2.00<0.500

Copper 2.00<0.500

Iron 12.5<12.5

Lead 0.3000.290


Zinc 2.50<1.00


Analysis Date: 11/25/2014 3:52:00 PM


Units: mg/Kg

RL


Arsenic 50.00 94.0 80 1201.00 047.0

Cadmium 50.00 92.8 80 1200.300 046.4

Chromium 50.00 94.0 80 1202.00 047.0

Copper 50.00 95.2 80 1202.00 047.6

Iron 250.0 99.6 80 12012.5 0249

Lead 50.00 92.8 80 1200.300 046.4

Selenium 50.00 93.8 80 1200.500 046.9

Zinc 50.00 95.7 80 1202.50 047.8


Analysis Date: 11/25/2014 3:58:00 PM


Units: mg/Kg

RL


Arsenic 50.00 97.0 80 120 201.00 0 3.2548.5

Cadmium 50.00 95.0 80 120 200.300 0 2.2947.5

Chromium 50.00 96.6 80 120 202.00 0 2.7348.3

Copper 50.00 97.9 80 120 202.00 0 2.8549.0

Iron 250.0 101 80 120 2012.5 0 1.55253

Lead 50.00 94.4 80 120 200.300 0 1.7647.2

Selenium 50.00 95.3 80 120 200.500 0 1.5947.6

Zinc 50.00 97.0 80 120 202.50 0 1.3548.5


Analysis Date: 11/25/2014 4:16:00 PM


Units: mg/Kg

RL


Qualifiers:






29






Analysis Date: 11/25/2014 4:16:00 PM


Units: mg/Kg

RL


Arsenic 0 104.97 2.083 0<2.49

Cadmium 0 101.49 0.1439 0<0.497

Chromium 0 109.95 8.706 3.008.97

Copper 0 109.95 6.728 5.947.14

Lead 0 101.49 4.002 1.854.08

Selenium 0 102.49 2.334 0.5632.35

Zinc 0 10 R12.4 16.26 12.418.4


Analysis Date: 11/25/2014 5:16:00 PM


Units: mg/Kg

RL


Arsenic 49.75 102 80 1200.995 2.08353.0

Cadmium 49.75 102 80 1200.298 0.143951.1

Chromium 49.75 103 80 1201.99 8.70660.0

Copper 49.75 103 80 1201.99 6.72857.8

Lead 49.75 105 80 1200.298 4.00256.3

Selenium 49.75 99.9 80 1200.497 2.33452.0

Zinc 49.75 105 80 1202.49 16.2668.5


Analysis Date: 11/25/2014 5:21:00 PM


Units: mg/Kg

RL


Arsenic 49.86 97.1 80 1200.997 2.08350.5

Cadmium 49.86 93.0 80 1200.299 0.143946.5

Chromium 49.86 99.6 80 1201.99 8.70658.4

Copper 49.86 98.2 80 1201.99 6.72855.7

Iron 249.3 815 80 120 S12.5 74159450

Lead 49.86 95.1 80 1200.299 4.00251.4

Selenium 49.86 91.8 80 1200.499 2.33448.1

Zinc 49.86 103 80 1202.49 16.2667.6


Analysis Date: 11/25/2014 5:27:00 PM


Units: mg/Kg

RL


Arsenic 49.70 95.3 80 120 200.994 2.083 2.0649.4

Cadmium 49.70 91.8 80 120 200.298 0.1439 1.5645.8

Chromium 49.70 94.8 80 120 201.99 8.706 4.4655.8

Copper 49.70 93.0 80 120 201.99 6.728 5.0452.9

Qualifiers:






30






Analysis Date: 11/25/2014 5:27:00 PM


Units: mg/Kg

RL


Iron 248.5 472 80 120 20 S12.4 7415 9.518590

Lead 49.70 94.1 80 120 200.298 4.002 1.2050.8

Selenium 49.70 93.2 80 120 200.497 2.334 1.0748.6

Zinc 49.70 98.5 80 120 202.48 16.26 3.5465.2


Analysis Date: 11/25/2014 6:04:00 PM


Units: mg/Kg

RL


Iron 0 10622 7758 2.297580


Analysis Date: 11/25/2014 6:40:00 PM


Units: mg/Kg

RL


Iron 12440 112 80 120124 775821700

Qualifiers:






31





Sample ID ILCVL-141125 Batch ID: R76552 TestNo: SW6020A

Analysis Date: 11/25/2014 3:33:00 PM


Units: mg/L

RL


Arsenic 0.00500 103 70 1300.00500 00.00513

Cadmium 0.00100 91.9 70 1300.00100 00.000919

Chromium 0.00500 103 70 1300.00500 00.00515

Copper 0.00500 96.8 70 1300.0100 00.00484

Iron 0.100 97.2 70 1300.100 00.0972

Lead 0.00100 103 70 1300.00100 00.00103

Selenium 0.00500 96.2 70 1300.00500 00.00481

Zinc 0.00500 83.8 70 1300.00500 00.00419


Analysis Date: 11/25/2014 5:52:00 PM


Units: mg/L

RL


Arsenic 0.00500 104 70 1300.00500 00.00522

Cadmium 0.00100 103 70 1300.00100 00.00103

Chromium 0.00500 101 70 1300.00500 00.00503

Copper 0.00500 96.6 70 1300.0100 00.00483

Iron 0.100 97.6 70 1300.100 00.0976

Lead 0.00100 112 70 1300.00100 00.00112

Selenium 0.00500 103 70 1300.00500 00.00514

Zinc 0.00500 89.3 70 1300.00500 00.00447


Analysis Date: 11/25/2014 6:58:00 PM


Units: mg/L

RL


Arsenic 0.00500 106 70 1300.00500 00.00531

Cadmium 0.00100 112 70 1300.00100 00.00112

Chromium 0.00500 103 70 1300.00500 00.00513

Copper 0.00500 99.6 70 1300.0100 00.00498

Iron 0.100 98.3 70 1300.100 00.0983

Lead 0.00100 124 70 1300.00100 00.00124

Selenium 0.00500 104 70 1300.00500 00.00519

Zinc 0.00500 89.8 70 1300.00500 00.00449


Analysis Date: 11/25/2014 8:41:00 PM


Units: mg/L

RL


Copper 0.00500 94.0 70 1300.0100 00.00470

Iron 0.100 96.5 70 1300.100 00.0965

Qualifiers:






32






Analysis Date: 11/25/2014 8:41:00 PM


Units: mg/L

RL


Lead 0.00100 105 70 1300.00100 00.00105

Zinc 0.00500 86.5 70 1300.00500 00.00433

Sample ID ICV1-141125 Batch ID: R76552 TestNo: SW6020A

Analysis Date: 11/25/2014 3:21:00 PM


Units: mg/L

RL


Arsenic 0.100 102 90 1100.00500 00.102

Cadmium 0.100 98.9 90 1100.00100 00.0989

Chromium 0.100 102 90 1100.00500 00.102

Copper 0.100 103 90 1100.0100 00.103

Iron 2.50 102 90 1100.100 02.56

Lead 0.100 99.5 90 1100.00100 00.0995

Selenium 0.100 99.1 90 1100.00500 00.0991

Zinc 0.100 102 90 1100.00500 00.102


Analysis Date: 11/25/2014 5:40:00 PM


Units: mg/L

RL


Arsenic 0.200 102 90 1100.00500 00.204

Cadmium 0.200 99.1 90 1100.00100 00.198

Chromium 0.200 98.5 90 1100.00500 00.197

Copper 0.200 102 90 1100.0100 00.203

Iron 5.00 102 90 1100.100 05.12

Lead 0.200 99.6 90 1100.00100 00.199

Selenium 0.200 102 90 1100.00500 00.203

Zinc 0.200 102 90 1100.00500 00.203


Analysis Date: 11/25/2014 6:46:00 PM


Units: mg/L

RL


Arsenic 0.200 102 90 1100.00500 00.203

Cadmium 0.200 100 90 1100.00100 00.200

Chromium 0.200 96.7 90 1100.00500 00.193

Copper 0.200 98.6 90 1100.0100 00.197

Iron 5.00 100 90 1100.100 05.02

Lead 0.200 99.0 90 1100.00100 00.198

Selenium 0.200 104 90 1100.00500 00.208

Zinc 0.200 100 90 1100.00500 00.200

Qualifiers:






33






Analysis Date: 11/25/2014 8:10:00 PM


Units: mg/L

RL


Copper 0.200 99.2 90 1100.0100 00.198

Iron 5.00 101 90 1100.100 05.06

Lead 0.200 98.2 90 1100.00100 00.196

Zinc 0.200 101 90 1100.00500 00.202

Qualifiers:






34




RunID: PMOIST_141121DThe QC data in batch 66677 applies to the following samples: 1411191-01A, 1411191-02A, 1411191-03A, 1411191-04A, 1411191-05A, 1411191-06A, 1411191-07A, 1411191-08A, 1411191-09A, 1411191-10A


Analysis Date: 11/24/2014 12:21:00 P


Units: WT%

RL

DUPSampType: Run ID: PMOIST_141121D Prep Date: 11/21/2014


Qualifiers:






35





TestNo: SW7471B

mg/KgAnalyte

MQL

mg/Kg

MDL

Mercury 0.04000.0160

TestNo: SW6020A

mg/KgAnalyte

MQL

mg/Kg

MDL

Arsenic 1.000.500

Cadmium 0.3000.100

Chromium 2.000.500

Copper 2.000.500

Iron 12.512.5

Lead 0.3000.100

Selenium 0.5000.150

Zinc 2.501.00

Qualifiers:

Page 1 of 1



36

December 02, 2014


Dear Kyrie Jeffery:


Order No.: 1411228FAX (720) 344-3535

TEL: (720) 344-3851





Sincerely,





1

Table of Contents


.................................................................................. 9CaseNarrative 1411228







2
























6























method? X S9-01









applicable? X



X

7

RG-366/TRRP-13 May 2010

















________________________


12/02/14

8

02-Dec-14Date:DHL Analytical, Inc.









The samples were received and log-in performed on 11/25/14. A total of 6 samples were received. The

samples arrived in good condition and were properly packaged.



above control limits for three analytes. These are flagged accordingly in the QC summary report. The

reference sample selected for the matrix spike and matrix spike duplicate was from this work order.

The LCS was within control limits for these analytes. No further corrective actions were taken.


For Metals analysis performed on 12/1/14 the RPD for the serial dilution was slightly above control

limits for Selenium. This is flagged accordingly in the QC summary report. The PDS was within

control limits for this analyte. No further corrective actions were taken.

Page 1 of 1

9






1411228-01 P26-112414 11/24/14 12:48 PM 11/25/2014

1411228-02 H17-112114 11/21/14 09:45 AM 11/25/2014

1411228-03 Q26-112414 11/24/14 01:00 PM 11/25/2014

1411228-04 S23-112414 11/24/14 12:45 PM 11/25/2014

1411228-05 Q25-112414 11/24/14 03:00 PM 11/25/2014

1411228-06 R24-112414 11/24/14 02:55 PM 11/25/2014

Page 1 of 1

10


PREP DATES REPORT

02-Dec-14

Lab Order: 1411228





1411228-01A P26-112414 11/24/14 12:48 PM Soil Mercury Soil Prep, Total 11/26/14 09:37 AMSW7471A 66757

P26-112414 11/24/14 12:48 PM Soil Moisture Preparation 11/26/14 03:40 PMD2216 66771

P26-112414 11/24/14 12:48 PM Soil Soil Prep Total Metals: ICP-MS 11/26/14 09:36 AMSW3050B 66756


1411228-02A H17-112114 11/21/14 09:45 AM Soil Mercury Soil Prep, Total 11/26/14 09:37 AMSW7471A 66757

H17-112114 11/21/14 09:45 AM Soil Moisture Preparation 11/26/14 03:40 PMD2216 66771

H17-112114 11/21/14 09:45 AM Soil Soil Prep Total Metals: ICP-MS 11/26/14 09:36 AMSW3050B 66756

H17-112114 11/21/14 09:45 AM Soil Soil Prep Total Metals: ICP-MS 11/26/14 09:36 AMSW3050B 66756

1411228-03A Q26-112414 11/24/14 01:00 PM Soil Mercury Soil Prep, Total 11/26/14 09:37 AMSW7471A 66757

Q26-112414 11/24/14 01:00 PM Soil Moisture Preparation 11/26/14 03:40 PMD2216 66771

Q26-112414 11/24/14 01:00 PM Soil Soil Prep Total Metals: ICP-MS 11/26/14 09:36 AMSW3050B 66756


1411228-04A S23-112414 11/24/14 12:45 PM Soil Mercury Soil Prep, Total 11/26/14 09:37 AMSW7471A 66757

S23-112414 11/24/14 12:45 PM Soil Moisture Preparation 11/26/14 03:40 PMD2216 66771

S23-112414 11/24/14 12:45 PM Soil Soil Prep Total Metals: ICP-MS 11/26/14 09:36 AMSW3050B 66756

S23-112414 11/24/14 12:45 PM Soil Soil Prep Total Metals: ICP-MS 11/26/14 09:36 AMSW3050B 66756

1411228-05A Q25-112414 11/24/14 03:00 PM Soil Mercury Soil Prep, Total 11/26/14 09:37 AMSW7471A 66757

Q25-112414 11/24/14 03:00 PM Soil Moisture Preparation 11/26/14 03:40 PMD2216 66771




R24-112414 11/24/14 02:55 PM Soil Moisture Preparation 11/26/14 03:40 PMD2216 66771

R24-112414 11/24/14 02:55 PM Soil Soil Prep Total Metals: ICP-MS 11/26/14 09:36 AMSW3050B 66756

R24-112414 11/24/14 02:55 PM Soil Soil Prep Total Metals: ICP-MS 11/26/14 09:36 AMSW3050B 66756

Page 1 of 1

11



02-Dec-14

Lab Order: 1411228







C



1411228-02A H17-112114 D2216Soil Percent Moisture 12/01/14 10:59 AM66771 1 PMOIST_141126B

H17-112114 SW7471BSoil Total Mercury: Soil/Solid 12/01/14 01:45 PM66757 1 CETAC2_HG_141201

C

H17-112114 SW6020ASoil Trace Metals: ICP-MS - Solid 12/01/14 11:52 AM66756 5 ICP-MS4_141201B

H17-112114 SW6020ASoil Trace Metals: ICP-MS - Solid 12/01/14 12:26 PM66756 50 ICP-MS4_141201B



C

Q26-112414 SW6020ASoil Trace Metals: ICP-MS - Solid 12/01/14 12:28 PM66756 50 ICP-MS4_141201B


1411228-04A S23-112414 D2216Soil Percent Moisture 12/01/14 10:59 AM66771 1 PMOIST_141126B

S23-112414 SW7471BSoil Total Mercury: Soil/Solid 12/01/14 01:49 PM66757 1 CETAC2_HG_141201

C

S23-112414 SW6020ASoil Trace Metals: ICP-MS - Solid 12/01/14 11:56 AM66756 5 ICP-MS4_141201B

S23-112414 SW6020ASoil Trace Metals: ICP-MS - Solid 12/01/14 12:30 PM66756 50 ICP-MS4_141201B



C


Q25-112414 SW6020ASoil Trace Metals: ICP-MS - Solid 12/01/14 12:32 PM66756 50 ICP-MS4_141201B

1411228-06A R24-112414 D2216Soil Percent Moisture 12/01/14 10:59 AM66771 1 PMOIST_141126B


C

R24-112414 SW6020ASoil Trace Metals: ICP-MS - Solid 12/01/14 12:34 PM66756 500 ICP-MS4_141201B

R24-112414 SW6020ASoil Trace Metals: ICP-MS - Solid 12/01/14 12:00 PM66756 5 ICP-MS4_141201B

Page 1 of 1

12




Matrix: SOIL



Lab Order: 1411228

DF

Lab ID: 1411228-01

DHL Analytical, Inc. Date: 02-Dec-14

RL

Project No: 6835001.2014.47SR2

SDL






Iron 12/01/14 12:22 PM1240 mg/Kg-dry 50026500 1240

Lead 12/01/14 11:49 AM0.299 mg/Kg-dry 5168 0.0996


Zinc 12/01/14 12:22 PM249 mg/Kg-dry 5001590 99.6


Qualifiers:

Page 1 of 6








DF- Dilution Factor




13


Client Sample ID: H17-112114


Matrix: SOIL



Lab Order: 1411228

DF

Lab ID: 1411228-02


RL

Project No: 6835001.2014.47SR2

SDL






Iron 12/01/14 12:26 PM125 mg/Kg-dry 5012100 125

Lead 12/01/14 11:52 AM0.300 mg/Kg-dry 598.2 0.100


Zinc 12/01/14 11:52 AM2.50 mg/Kg-dry 5206 1.00


Qualifiers:

Page 2 of 6








DF- Dilution Factor




14




Matrix: SOIL



Lab Order: 1411228

DF

Lab ID: 1411228-03


RL

Project No: 6835001.2014.47SR2

SDL






Iron 12/01/14 12:28 PM126 mg/Kg-dry 5012200 126

Lead 12/01/14 11:54 AM0.303 mg/Kg-dry 558.0 0.101


Zinc 12/01/14 11:54 AM2.52 mg/Kg-dry 5345 1.01


Qualifiers:

Page 3 of 6








DF- Dilution Factor




15


Client Sample ID: S23-112414


Matrix: SOIL



Lab Order: 1411228

DF

Lab ID: 1411228-04


RL

Project No: 6835001.2014.47SR2

SDL






Iron 12/01/14 12:30 PM124 mg/Kg-dry 5015600 124

Lead 12/01/14 11:56 AM0.299 mg/Kg-dry 591.6 0.0996


Zinc 12/01/14 11:56 AM2.49 mg/Kg-dry 5427 0.996


Qualifiers:

Page 4 of 6








DF- Dilution Factor




16




Matrix: SOIL



Lab Order: 1411228

DF

Lab ID: 1411228-05


RL

Project No: 6835001.2014.47SR2

SDL






Iron 12/01/14 12:32 PM120 mg/Kg-dry 5012700 120

Lead 12/01/14 11:58 AM0.288 mg/Kg-dry 569.2 0.0960


Zinc 12/01/14 11:58 AM2.40 mg/Kg-dry 5372 0.960


Qualifiers:

Page 5 of 6








DF- Dilution Factor




17




Matrix: SOIL



Lab Order: 1411228

DF

Lab ID: 1411228-06


RL

Project No: 6835001.2014.47SR2

SDL






Iron 12/01/14 12:34 PM1190 mg/Kg-dry 50026400 1190

Lead 12/01/14 12:00 PM0.286 mg/Kg-dry 5159 0.0953


Zinc 12/01/14 12:34 PM238 mg/Kg-dry 5001460 95.3


Qualifiers:

Page 6 of 6








DF- Dilution Factor




18







Analysis Date: 11/12/2014 12:10:13 P


Units: mg/Kg

RL


Mercury 0.02000 112 60 140 00.0400 0 00.0223

Qualifiers:






19




RunID: CETAC2_HG_141201CThe QC data in batch 66757 applies to the following samples: 1411228-01A, 1411228-02A, 1411228-03A, 1411228-04A, 1411228-05A, 1411228-06A


Analysis Date: 12/1/2014 1:23:19 PM


Units: mg/Kg

RL

MBLKSampType: Run ID: CETAC2_HG_141201C Prep Date: 11/26/2014

Mercury 0.0400<0.0160




Units: mg/Kg

RL

LCSSampType: Run ID: CETAC2_HG_141201C Prep Date: 11/26/2014

Mercury 0.2000 114 85 1150.0400 00.229




Units: mg/Kg

RL

LCSDSampType: Run ID: CETAC2_HG_141201C Prep Date: 11/26/2014

Mercury 0.2000 114 85 115 250.0400 0 0.8770.227




Units: mg/Kg-dry

RL

SDSampType: Run ID: CETAC2_HG_141201C Prep Date: 11/26/2014

Mercury 0 100.201 0.02704 0<0.0804




Units: mg/Kg-dry

RL

PDSSampType: Run ID: CETAC2_HG_141201C Prep Date: 11/26/2014

Mercury 0.2513 103 85 1150.0402 0.027040.286




Units: mg/Kg-dry

RL

MSSampType: Run ID: CETAC2_HG_141201C Prep Date: 11/26/2014

Mercury 0.1919 111 80 1200.0384 0.027040.240




Units: mg/Kg-dry

RL

MSDSampType: Run ID: CETAC2_HG_141201C Prep Date: 11/26/2014

Mercury 0.1956 109 80 120 250.0391 0.02704 0.1150.240

Qualifiers:






20




RunID: CETAC2_HG_141201C




Units: mg/Kg

RL

ICVSampType: Run ID: CETAC2_HG_141201C Prep Date:

Mercury 0.004000 103 90 1100.0400 00.00411




Units: mg/Kg

RL


Mercury 0.002000 104 90 1100.0400 00.00208

Qualifiers:






21






Analysis Date: 11/10/2014 11:31:00 A


Units: mg/Kg

RL


Arsenic 0.1500 113 80 120 01.00 0 00.169

Cadmium 0.1500 99.7 80 120 00.300 0 00.150

Chromium 0.1500 116 80 120 02.00 0 00.174

Copper 0.1500 97.0 80 120 02.00 0 00.146

Iron 6.250 106 80 120 012.5 0 06.64

Lead 0.1500 102 80 120 00.300 0 00.152

Selenium 0.1500 118 80 120 00.500 0 00.178


Analysis Date: 11/10/2014 11:35:00 A


Units: mg/Kg

RL


Zinc 5.000 106 80 120 02.50 0 05.31

Qualifiers:






22




RunID: ICP-MS4_141201BThe QC data in batch 66756 applies to the following samples: 1411228-01A, 1411228-02A, 1411228-03A, 1411228-04A, 1411228-05A, 1411228-06A


Analysis Date: 12/1/2014 11:39:00 AM


Units: mg/Kg

RL


Arsenic 1.00<0.500

Cadmium 0.300<0.100

Chromium 2.00<0.500

Copper 2.00<0.500

Iron 12.5<12.5

Lead 0.300<0.100


Zinc 2.50<1.00


Analysis Date: 12/1/2014 11:43:00 AM


Units: mg/Kg

RL


Arsenic 50.00 94.9 80 1201.00 047.5

Cadmium 50.00 95.6 80 1200.300 047.8

Chromium 50.00 99.3 80 1202.00 049.7

Copper 50.00 96.2 80 1202.00 048.1

Iron 250.0 105 80 12012.5 0263

Lead 50.00 95.5 80 1200.300 047.7

Selenium 50.00 91.1 80 1200.500 045.5

Zinc 50.00 95.4 80 1202.50 047.7


Analysis Date: 12/1/2014 11:45:00 AM


Units: mg/Kg

RL


Arsenic 50.00 94.8 80 1201.00 047.4

Cadmium 50.00 96.7 80 1200.300 048.4

Chromium 50.00 99.7 80 1202.00 049.9

Copper 50.00 95.3 80 1202.00 047.7

Iron 250.0 106 80 12012.5 0264

Lead 50.00 94.0 80 1200.300 047.0

Selenium 50.00 92.0 80 1200.500 046.0

Zinc 50.00 96.1 80 1202.50 048.1


Analysis Date: 12/1/2014 11:50:00 AM


Units: mg/Kg-dry

RL


Arsenic 0 104.98 39.53 1.6740.2

Qualifiers:






23






Analysis Date: 12/1/2014 11:50:00 AM


Units: mg/Kg-dry

RL


Cadmium 0 101.49 1.595 4.471.67

Chromium 0 109.96 22.40 2.1522.9

Lead 0 101.49 168.5 2.21165

Selenium 0 10 R2.49 1.576 11.81.77


Analysis Date: 12/1/2014 12:02:00 PM


Units: mg/Kg-dry

RL


Arsenic 49.78 98.7 80 1200.996 39.5388.7

Cadmium 49.78 97.2 80 1200.299 1.59550.0

Chromium 49.78 102 80 1201.99 22.4073.3

Lead 49.78 103 80 1200.299 168.5220

Selenium 49.78 93.3 80 1200.498 1.57648.0


Analysis Date: 12/1/2014 12:04:00 PM


Units: mg/Kg-dry

RL


Arsenic 49.89 97.9 80 1200.998 39.5388.4

Cadmium 49.89 92.3 80 1200.299 1.59547.6

Chromium 49.89 97.9 80 1202.00 22.4071.2

Copper 49.89 130 80 120 S2.00 551.8617

Iron 249.5 173 80 120 S12.5 2624026700

Lead 49.89 116 80 1200.299 168.5226

Selenium 49.89 89.3 80 1200.499 1.57646.1

Zinc 49.89 141 80 120 S2.49 15731640


Analysis Date: 12/1/2014 12:06:00 PM


Units: mg/Kg-dry

RL


Arsenic 49.80 95.3 80 120 200.996 39.53 1.6087.0

Cadmium 49.80 95.3 80 120 200.299 1.595 2.9649.1

Chromium 49.80 98.7 80 120 201.99 22.40 0.45171.6

Copper 49.80 104 80 120 201.99 551.8 2.12604

Iron 249.0 536 80 120 20 S12.4 26240 3.3327600

Lead 49.80 88.9 80 120 200.299 168.5 6.12213

Selenium 49.80 93.1 80 120 200.498 1.576 3.8648.0

Zinc 49.80 163 80 120 20 S2.49 1573 0.6451650

Qualifiers:






24






Analysis Date: 12/1/2014 12:24:00 PM


Units: mg/Kg-dry

RL


Copper 0 10996 562.1 1.22555

Iron 0 106220 26490 3.5625600

Zinc 0 101240 1593 1.211570


Analysis Date: 12/1/2014 12:38:00 PM


Units: mg/Kg-dry

RL


Copper 4978 95.0 80 120199 562.15290

Iron 124500 99.6 80 1201240 26490150000

Zinc 4978 94.9 80 120249 15936320

Qualifiers:






25






Analysis Date: 12/1/2014 9:58:00 AM


Units: mg/L

RL


Arsenic 0.100 97.8 90 1100.00500 00.0978

Cadmium 0.100 102 90 1100.00100 00.102

Chromium 0.100 103 90 1100.00500 00.103

Copper 0.100 100 90 1100.0100 00.100

Iron 2.50 101 90 1100.100 02.52

Lead 0.100 101 90 1100.00100 00.101

Selenium 0.100 95.8 90 1100.00500 00.0958

Zinc 0.100 99.3 90 1100.00500 00.0993


Analysis Date: 12/1/2014 10:05:00 AM


Units: mg/L

RL


Arsenic 0.00500 101 70 1300.00500 00.00504

Cadmium 0.00100 102 70 1300.00100 00.00102

Chromium 0.00500 107 70 1300.00500 00.00536

Copper 0.00500 102 70 1300.0100 00.00511

Iron 0.100 99.3 70 1300.100 00.0993

Lead 0.00100 109 70 1300.00100 00.00109

Selenium 0.00500 97.4 70 1300.00500 00.00487

Zinc 0.00500 93.6 70 1300.00500 00.00468


Analysis Date: 12/1/2014 11:23:00 AM


Units: mg/L

RL


Arsenic 0.200 99.6 90 1100.00500 00.199

Cadmium 0.200 98.7 90 1100.00100 00.197

Chromium 0.200 98.3 90 1100.00500 00.197

Copper 0.200 98.7 90 1100.0100 00.197

Iron 5.00 98.6 90 1100.100 04.93

Lead 0.200 98.8 90 1100.00100 00.198

Selenium 0.200 100 90 1100.00500 00.201

Zinc 0.200 98.5 90 1100.00500 00.197


Analysis Date: 12/1/2014 11:26:00 AM


Units: mg/L

RL


Arsenic 0.00500 102 70 1300.00500 00.00512

Cadmium 0.00100 104 70 1300.00100 00.00105

Qualifiers:






26






Analysis Date: 12/1/2014 11:26:00 AM


Units: mg/L

RL


Chromium 0.00500 100 70 1300.00500 00.00502

Copper 0.00500 102 70 1300.0100 00.00511

Iron 0.100 95.8 70 1300.100 00.0959

Lead 0.00100 99.8 70 1300.00100 00.000998

Selenium 0.00500 100 70 1300.00500 00.00502

Zinc 0.00500 94.7 70 1300.00500 00.00473


Analysis Date: 12/1/2014 12:08:00 PM


Units: mg/L

RL


Arsenic 0.200 98.5 90 1100.00500 00.197

Cadmium 0.200 99.5 90 1100.00100 00.199

Chromium 0.200 103 90 1100.00500 00.206

Copper 0.200 98.8 90 1100.0100 00.198

Iron 5.00 106 90 1100.100 05.28

Lead 0.200 98.0 90 1100.00100 00.196

Selenium 0.200 96.1 90 1100.00500 00.192

Zinc 0.200 105 90 1100.00500 00.211


Analysis Date: 12/1/2014 12:14:00 PM


Units: mg/L

RL


Arsenic 0.00500 100 70 1300.00500 00.00501

Cadmium 0.00100 108 70 1300.00100 00.00108

Chromium 0.00500 109 70 1300.00500 00.00547

Copper 0.00500 101 70 1300.0100 00.00506

Iron 0.100 103 70 1300.100 00.103

Lead 0.00100 112 70 1300.00100 00.00112

Selenium 0.00500 95.1 70 1300.00500 00.00476

Zinc 0.00500 98.9 70 1300.00500 00.00494


Analysis Date: 12/1/2014 12:40:00 PM


Units: mg/L

RL


Copper 0.200 99.3 90 1100.0100 00.199

Iron 5.00 103 90 1100.100 05.17

Zinc 0.200 107 90 1100.00500 00.214

Qualifiers:






27






Analysis Date: 12/1/2014 12:44:00 PM


Units: mg/L

RL


Copper 0.00500 99.2 70 1300.0100 00.00496

Iron 0.100 97.8 70 1300.100 00.0978

Zinc 0.00500 93.6 70 1300.00500 00.00468

Qualifiers:






28




RunID: PMOIST_141126BThe QC data in batch 66771 applies to the following samples: 1411228-01A, 1411228-02A, 1411228-03A, 1411228-04A, 1411228-05A, 1411228-06A


Analysis Date: 12/1/2014 10:59:00 AM


Units: WT%

RL



Qualifiers:






29





TestNo: SW7471B

mg/KgAnalyte

MQL

mg/Kg

MDL

Mercury 0.04000.0160

TestNo: SW6020A

mg/KgAnalyte

MQL

mg/Kg

MDL

Arsenic 1.000.500

Cadmium 0.3000.100

Chromium 2.000.500

Copper 2.000.500

Iron 12.512.5

Lead 0.3000.100

Selenium 0.5000.150

Zinc 2.501.00

Qualifiers:

Page 1 of 1



30

December 23, 2014


Dear Kyrie Jeffery:


Order No.: 1412152FAX (720) 344-3535

TEL: (720) 344-3851





Sincerely,





1

Table of Contents


.................................................................................. 9CaseNarrative 1412152







2













4) Were blank concentrations < MQL? X R5-04 R6 OI Laboratory Control Samples (LCS):











6
















1) Were IS area counts and retention times within the method-required QC limits? X S4-01 S5 OI Raw Data (NELAC Section 5.5.10)







method? X S9-01









applicable? X



X

7

RG-366/TRRP-13 May 2010

















________________________


12/23/14

8













For Metals analysis performed on 12/22/14 Zinc was detected below the reporting limit in the method

blank (MB-67276). All samples wree detected greater than 10 times the amount in the blank for this

analyte. No further corrective actions were taken.

Exception Report R7-03 & R7-04


out of control limits for five analytes. In addition, the matrix spike and matrix spike duplicate had the

RPD above control limits for Arsenic and Copper. These are flagged accordingly in the QC summary

report. The reference sample selected for the matrix spike and matrix spike duplicate was from this

work order. The LCS was within control limits for these analytes. No further corrective actions were

taken.

For Mercury analysis performed on 12/22/14 the matrix spike duplicate recovery was slightly below

control limits. This is flagged accordingly. The reference sample selected for the matrix spike and

matrix spike duplicate was from this work order. The LCS was within control limits. No further



For Metals analysis CCV3-141222 and CCV4-141222 had low responses for the internal standard

Scandium(1). The associated analytes (Copper, Iron and Zinc) were within control limits. No further



Page 1 of 2

9




For Metals analysis performed on 12/22/14 the RPD for the serial dilution was slightly above control

limits for Selenium. This is flagged accordingly in the QC summary report. The PDS was within

control limits for this analyte. No further corrective actions were taken.

For Metals analysis performed on 12/22/14 the PDS recovery was slightly below control limits for

Zinc. This is flagged accordingly. The serial dilution was within control limits for this analyte. No

further corrective actions were taken.

Page 2 of 2

10






1412152-01 G06-120814 12/08/14 03:10 PM 12/11/2014

1412152-02 G07-120814 12/08/14 03:15 PM 12/11/2014

1412152-03 G08-120814 12/08/14 03:20 PM 12/11/2014

1412152-04 G14-120914 12/09/14 02:50 PM 12/11/2014

1412152-05 G15-120914 12/09/14 02:55 PM 12/11/2014

1412152-06 G16-120914 12/09/14 03:00 PM 12/11/2014

1412152-07 G09-121014 12/10/14 01:25 PM 12/11/2014

1412152-08 G10-121014 12/10/14 01:22 PM 12/11/2014

1412152-09 G11-121014 12/10/14 01:20 PM 12/11/2014

1412152-10 G12-121014 12/10/14 01:30 PM 12/11/2014

1412152-11 G13-121014 12/10/14 01:35 PM 12/11/2014

1412152-12 P25-121014 12/10/14 04:15 PM 12/11/2014

1412152-13 FD-12102014-1 12/10/14 02:30 PM 12/11/2014

1412152-14 FD-12102014-2 12/10/14 02:35 PM 12/11/2014

1412152-15 FD-12102014-3 12/10/14 02:40 PM 12/11/2014

1412152-16 FD-12102014-4 12/10/14 02:45 PM 12/11/2014

Page 1 of 1

11


PREP DATES REPORT

23-Dec-14

Lab Order: 1412152





1412152-01A G06-120814 12/08/14 03:10 PM Soil Mercury Soil Prep, Total 12/19/14 10:33 AMSW7471A 67275

G06-120814 12/08/14 03:10 PM Soil Moisture Preparation 12/19/14 11:42 AMD2216 67278

G06-120814 12/08/14 03:10 PM Soil Soil Prep Total Metals: ICP-MS 12/19/14 10:33 AMSW3050B 67276


























Page 1 of 3

12


PREP DATES REPORT

23-Dec-14

Lab Order: 1412152


















G13-121014 12/10/14 01:35 PM Soil Mercury Soil Prep, Total 12/19/14 10:33 AMSW7471A 67275




1412152-12A P25-121014 12/10/14 04:15 PM Soil Mercury Soil Prep, Total 12/19/14 10:33 AMSW7471A 67275




1412152-13A FD-12102014-1 12/10/14 02:30 PM Soil Mercury Soil Prep, Total 12/19/14 10:33 AMSW7471A 67275

FD-12102014-1 12/10/14 02:30 PM Soil Mercury Soil Prep, Total 12/19/14 10:33 AMSW7471A 67275

FD-12102014-1 12/10/14 02:30 PM Soil Moisture Preparation 12/19/14 11:42 AMD2216 67278

FD-12102014-1 12/10/14 02:30 PM Soil Soil Prep Total Metals: ICP-MS 12/19/14 10:33 AMSW3050B 67276




Page 2 of 3

13


PREP DATES REPORT

23-Dec-14

Lab Order: 1412152





1412152-14A FD-12102014-2 12/10/14 02:35 PM Soil Soil Prep Total Metals: ICP-MS 12/19/14 10:33 AMSW3050B 67276










Page 3 of 3

14



23-Dec-14

Lab Order: 1412152





1412152-01A G06-120814 D2216Soil Percent Moisture 12/23/14 09:24 AM67278 1 PMOIST_141222A

G06-120814 SW7471BSoil Total Mercury: Soil/Solid 12/22/14 02:59 PM67275 1 CETAC2_HG_141222

A

G06-120814 SW6020ASoil Trace Metals: ICP-MS - Solid 12/22/14 02:30 PM67276 5 ICP-MS2_141222A




A





A





A





A





A




Page 1 of 3

15



23-Dec-14

Lab Order: 1412152





1412152-07A G09-121014 SW7471BSoil Total Mercury: Soil/Solid 12/22/14 03:10 PM67275 1 CETAC2_HG_141222

A





A





A





A





A


A





A



1412152-13A FD-12102014-1 D2216Soil Percent Moisture 12/23/14 09:24 AM67278 1 PMOIST_141222A

Page 2 of 3

16



23-Dec-14

Lab Order: 1412152





1412152-13A FD-12102014-1 SW7471BSoil Total Mercury: Soil/Solid 12/22/14 03:29 PM67275 1 CETAC2_HG_141222

A

FD-12102014-1 SW7471BSoil Total Mercury: Soil/Solid 12/22/14 03:49 PM67275 5 CETAC2_HG_141222

A

FD-12102014-1 SW6020ASoil Trace Metals: ICP-MS - Solid 12/22/14 06:25 PM67276 5 ICP-MS2_141222A




A





A





A



Page 3 of 3

17


Client Sample ID: G06-120814


Matrix: SOIL



Lab Order: 1412152

DF

Lab ID: 1412152-01


RL

Project No: 6835001.2014.47SR2

SDL






Iron 12/22/14 07:59 PM119 mg/Kg-dry 5012200 119

Lead 12/22/14 02:30 PM0.286 mg/Kg-dry 5121 0.0954


Zinc 12/22/14 02:30 PM2.39 mg/Kg-dry 5383 0.954


Qualifiers:

Page 1 of 16








DF- Dilution Factor




18




Matrix: SOIL



Lab Order: 1412152

DF

Lab ID: 1412152-02


RL

Project No: 6835001.2014.47SR2

SDL






Iron 12/22/14 07:42 PM115 mg/Kg-dry 5014900 115

Lead 12/22/14 01:55 PM0.276 mg/Kg-dry 5136 0.0921


Zinc 12/22/14 01:55 PM2.30 mg/Kg-dry 5360 0.921


Qualifiers:

Page 2 of 16








DF- Dilution Factor




19




Matrix: SOIL



Lab Order: 1412152

DF

Lab ID: 1412152-03


RL

Project No: 6835001.2014.47SR2

SDL






Iron 12/22/14 08:05 PM231 mg/Kg-dry 10020500 231

Lead 12/22/14 02:36 PM0.278 mg/Kg-dry 5149 0.0925


Zinc 12/22/14 08:05 PM46.3 mg/Kg-dry 100770 18.5


Qualifiers:

Page 3 of 16








DF- Dilution Factor




20




Matrix: SOIL



Lab Order: 1412152

DF

Lab ID: 1412152-04


RL

Project No: 6835001.2014.47SR2

SDL






Iron 12/22/14 08:11 PM120 mg/Kg-dry 5014800 120

Lead 12/22/14 02:41 PM0.289 mg/Kg-dry 5267 0.0963


Zinc 12/22/14 08:11 PM24.1 mg/Kg-dry 50730 9.63


Qualifiers:

Page 4 of 16








DF- Dilution Factor




21




Matrix: SOIL



Lab Order: 1412152

DF

Lab ID: 1412152-05


RL

Project No: 6835001.2014.47SR2

SDL






Iron 12/22/14 08:17 PM121 mg/Kg-dry 5017700 121

Lead 12/22/14 02:47 PM0.291 mg/Kg-dry 5211 0.0969


Zinc 12/22/14 08:17 PM24.2 mg/Kg-dry 50966 9.69


Qualifiers:

Page 5 of 16








DF- Dilution Factor




22




Matrix: SOIL



Lab Order: 1412152

DF

Lab ID: 1412152-06


RL

Project No: 6835001.2014.47SR2

SDL






Iron 12/22/14 08:23 PM114 mg/Kg-dry 5011100 114

Lead 12/22/14 02:53 PM0.273 mg/Kg-dry 5294 0.0911


Zinc 12/22/14 02:53 PM2.28 mg/Kg-dry 5443 0.911


Qualifiers:

Page 6 of 16








DF- Dilution Factor




23




Matrix: SOIL



Lab Order: 1412152

DF

Lab ID: 1412152-07


RL

Project No: 6835001.2014.47SR2

SDL






Iron 12/22/14 08:29 PM116 mg/Kg-dry 5017700 116

Lead 12/22/14 05:50 PM0.278 mg/Kg-dry 563.6 0.0928


Zinc 12/22/14 05:50 PM2.32 mg/Kg-dry 5252 0.928


Qualifiers:

Page 7 of 16








DF- Dilution Factor




24




Matrix: SOIL



Lab Order: 1412152

DF

Lab ID: 1412152-08


RL

Project No: 6835001.2014.47SR2

SDL






Iron 12/22/14 08:35 PM114 mg/Kg-dry 5013800 114

Lead 12/22/14 05:56 PM0.274 mg/Kg-dry 549.2 0.0914


Zinc 12/22/14 05:56 PM2.29 mg/Kg-dry 5157 0.914


Qualifiers:

Page 8 of 16








DF- Dilution Factor




25




Matrix: SOIL



Lab Order: 1412152

DF

Lab ID: 1412152-09


RL

Project No: 6835001.2014.47SR2

SDL






Iron 12/22/14 08:41 PM236 mg/Kg-dry 10020400 236

Lead 12/22/14 06:02 PM0.283 mg/Kg-dry 5114 0.0944


Zinc 12/22/14 08:41 PM47.2 mg/Kg-dry 100635 18.9


Qualifiers:

Page 9 of 16








DF- Dilution Factor




26




Matrix: SOIL



Lab Order: 1412152

DF

Lab ID: 1412152-10


RL

Project No: 6835001.2014.47SR2

SDL






Iron 12/22/14 09:52 PM119 mg/Kg-dry 5013800 119

Lead 12/22/14 06:08 PM0.285 mg/Kg-dry 5148 0.0951


Zinc 12/22/14 09:52 PM23.8 mg/Kg-dry 50476 9.51


Qualifiers:

Page 10 of 16








DF- Dilution Factor




27




Matrix: SOIL



Lab Order: 1412152

DF

Lab ID: 1412152-11


RL

Project No: 6835001.2014.47SR2

SDL






Iron 12/22/14 09:58 PM121 mg/Kg-dry 5012000 121

Lead 12/22/14 06:13 PM0.290 mg/Kg-dry 5411 0.0966


Zinc 12/22/14 09:58 PM24.2 mg/Kg-dry 50821 9.66


Qualifiers:

Page 11 of 16








DF- Dilution Factor




28




Matrix: SOIL



Lab Order: 1412152

DF

Lab ID: 1412152-12


RL

Project No: 6835001.2014.47SR2

SDL






Iron 12/22/14 10:04 PM113 mg/Kg-dry 508120 113

Lead 12/22/14 06:19 PM0.272 mg/Kg-dry 553.1 0.0908


Zinc 12/22/14 06:19 PM2.27 mg/Kg-dry 597.1 0.908


Qualifiers:

Page 12 of 16








DF- Dilution Factor




29


Client Sample ID: FD-12102014-1


Matrix: SOIL



Lab Order: 1412152

DF

Lab ID: 1412152-13


RL

Project No: 6835001.2014.47SR2

SDL






Iron 12/22/14 10:10 PM117 mg/Kg-dry 5011800 117

Lead 12/22/14 06:25 PM0.282 mg/Kg-dry 5362 0.0938


Zinc 12/22/14 10:10 PM23.5 mg/Kg-dry 50671 9.38


Qualifiers:

Page 13 of 16








DF- Dilution Factor




30




Matrix: SOIL



Lab Order: 1412152

DF

Lab ID: 1412152-14


RL

Project No: 6835001.2014.47SR2

SDL






Iron 12/22/14 10:16 PM222 mg/Kg-dry 10029500 222

Lead 12/22/14 06:31 PM0.267 mg/Kg-dry 5242 0.0890


Zinc 12/22/14 10:16 PM44.5 mg/Kg-dry 1002060 17.8


Qualifiers:

Page 14 of 16








DF- Dilution Factor




31




Matrix: SOIL



Lab Order: 1412152

DF

Lab ID: 1412152-15


RL

Project No: 6835001.2014.47SR2

SDL






Iron 12/22/14 10:21 PM225 mg/Kg-dry 10023300 225

Lead 12/22/14 06:37 PM0.270 mg/Kg-dry 5168 0.0902


Zinc 12/22/14 10:21 PM45.1 mg/Kg-dry 1001470 18.0


Qualifiers:

Page 15 of 16








DF- Dilution Factor




32




Matrix: SOIL



Lab Order: 1412152

DF

Lab ID: 1412152-16


RL

Project No: 6835001.2014.47SR2

SDL






Iron 12/22/14 10:27 PM238 mg/Kg-dry 10019700 238

Lead 12/22/14 06:42 PM0.285 mg/Kg-dry 5208 0.0950


Zinc 12/22/14 10:27 PM47.5 mg/Kg-dry 1001100 19.0


Qualifiers:

Page 16 of 16








DF- Dilution Factor




33







Analysis Date: 11/12/2014 12:10:13 P


Units: mg/Kg

RL


Mercury 0.02000 112 60 140 00.0400 0 00.0223

Qualifiers:






34




RunID: CETAC2_HG_141222AThe QC data in batch 67275 applies to the following samples: 1412152-01A, 1412152-02A, 1412152-03A, 1412152-04A, 1412152-05A, 1412152-06A, 1412152-07A, 1412152-08A, 1412152-09A, 1412152-10A, 1412152-11A, 1412152-12A, 1412152-13A, 1412152-14A, 1412152-15A, 1412152-16A


Analysis Date: 12/22/2014 2:32:06 PM


Units: mg/Kg

RL


Mercury 0.0400<0.0160


Analysis Date: 12/22/2014 2:41:14 PM


Units: mg/Kg-dry

RL


Mercury 0 100.200 0.3476 4.090.362


Analysis Date: 12/22/2014 2:43:31 PM


Units: mg/Kg-dry

RL


Mercury 0.2504 94.4 85 1150.0401 0.34760.584


Analysis Date: 12/23/2014 11:01:05 A


Units: mg/Kg

RL


Mercury 0.2000 110 85 1150.0400 00.219


Analysis Date: 12/23/2014 11:03:22 A


Units: mg/Kg

RL


Mercury 0.2000 112 85 115 250.0400 0 2.700.225


Analysis Date: 12/23/2014 11:05:39 A


Units: mg/Kg-dry

RL


Mercury 0.1773 102 80 1200.0355 0.34760.529


Analysis Date: 12/23/2014 11:07:55 A


Units: mg/Kg-dry

RL


Mercury 0.1807 76.7 80 120 25 S0.0361 0.3476 2.430.486

Qualifiers:






35






Analysis Date: 12/22/2014 10:02:07 A


Units: mg/Kg

RL


Mercury 0.004000 108 90 1100.0400 00.00433


Analysis Date: 12/22/2014 1:48:57 PM


Units: mg/Kg

RL


Mercury 0.002000 101 90 1100.0400 00.00202


Analysis Date: 12/22/2014 3:15:26 PM


Units: mg/Kg

RL


Mercury 0.002000 106 90 1100.0400 00.00212


Analysis Date: 12/22/2014 3:42:40 PM


Units: mg/Kg

RL


Mercury 0.002000 106 90 1100.0400 00.00213


Analysis Date: 12/22/2014 4:32:46 PM


Units: mg/Kg

RL


Mercury 0.002000 108 90 1100.0400 00.00217


Analysis Date: 12/23/2014 10:17:18 A


Units: mg/Kg

RL


Mercury 0.004000 101 90 1100.0400 00.00405


Analysis Date: 12/23/2014 10:47:25 A


Units: mg/Kg

RL


Mercury 0.002000 94.0 90 1100.0400 00.00188

Qualifiers:






36






Analysis Date: 12/23/2014 11:12:30 A


Units: mg/Kg

RL


Mercury 0.002000 95.5 90 1100.0400 00.00191

Qualifiers:






37






Analysis Date: 11/24/2014 6:10:00 PM


Units: mg/Kg

RL

DCS2SampType: Run ID: ICP-MS2_141124A Prep Date: 11/7/2014

Arsenic 1.000 100 80 120 01.00 0 01.00

Chromium 1.000 107 80 120 02.00 0 01.07

Copper 1.000 110 80 120 02.00 0 01.10

Iron 12.50 120 80 120 012.5 0 015.0


Analysis Date: 11/24/2014 6:16:00 PM


Units: mg/Kg

RL

DCS3SampType: Run ID: ICP-MS2_141124A Prep Date: 11/7/2014

Zinc 5.000 105 80 120 02.50 0 05.27


Analysis Date: 11/24/2014 6:45:00 PM


Units: mg/Kg

RL


Cadmium 0.1500 105 80 120 00.300 0 00.158

Lead 0.1500 98.3 80 120 00.300 0 00.147

Selenium 0.1500 103 80 120 00.500 0 00.155

Qualifiers:






38




RunID: ICP-MS2_141222AThe QC data in batch 67276 applies to the following samples: 1412152-01A, 1412152-02A, 1412152-03A, 1412152-04A, 1412152-05A, 1412152-06A, 1412152-07A, 1412152-08A, 1412152-09A, 1412152-10A, 1412152-11A, 1412152-12A, 1412152-13A, 1412152-14A, 1412152-15A, 1412152-16A


Analysis Date: 12/22/2014 1:25:00 PM


Units: mg/Kg

RL


Arsenic 1.00<0.500

Cadmium 0.300<0.100

Chromium 2.00<0.500

Copper 2.00<0.500

Iron 12.5<12.5

Lead 0.300<0.100


Zinc 2.501.09


Analysis Date: 12/22/2014 1:37:00 PM


Units: mg/Kg

RL


Arsenic 50.00 91.7 80 1201.00 045.8

Cadmium 50.00 92.9 80 1200.300 046.4

Chromium 50.00 91.2 80 1202.00 045.6

Copper 50.00 94.0 80 1202.00 047.0

Iron 250.0 97.0 80 12012.5 0242

Lead 50.00 91.9 80 1200.300 046.0

Selenium 50.00 90.6 80 1200.500 045.3

Zinc 50.00 91.4 80 1202.50 045.7


Analysis Date: 12/22/2014 1:43:00 PM


Units: mg/Kg

RL


Arsenic 50.00 94.6 80 120 201.00 0 3.1147.3

Cadmium 50.00 95.9 80 120 200.300 0 3.1347.9

Chromium 50.00 95.8 80 120 202.00 0 4.8147.9

Copper 50.00 97.1 80 120 202.00 0 3.1948.6

Iron 250.0 100 80 120 2012.5 0 3.40251

Lead 50.00 95.0 80 120 200.300 0 3.3247.5

Selenium 50.00 95.4 80 120 200.500 0 5.2747.7

Zinc 50.00 96.0 80 120 202.50 0 4.8548.0


Analysis Date: 12/22/2014 2:01:00 PM


Units: mg/Kg-dry

RL


Qualifiers:






39






Analysis Date: 12/22/2014 2:01:00 PM


Units: mg/Kg-dry

RL


Arsenic 0 104.61 62.59 3.6864.9

Cadmium 0 101.38 4.371 4.134.55

Chromium 0 109.21 9.453 5.6810.0

Copper 0 109.21 186.9 7.45201

Lead 0 101.38 136.0 8.25148

Selenium 0 10 R2.30 2.644 15.13.08

Zinc 0 1011.5 359.7 8.34391


Analysis Date: 12/22/2014 2:59:00 PM


Units: mg/Kg-dry

RL


Arsenic 46.05 88.9 80 1200.921 62.59104

Cadmium 46.05 92.8 80 1200.276 4.37147.1

Chromium 46.05 87.8 80 1201.84 9.45349.9

Copper 46.05 84.0 80 1201.84 186.9226

Lead 46.05 105 80 1200.276 136.0184

Selenium 46.05 87.0 80 1200.461 2.64442.7

Zinc 46.05 72.5 80 120 S2.30 359.7393


Analysis Date: 12/22/2014 3:04:00 PM


Units: mg/Kg-dry

RL


Arsenic 45.13 702 80 120 S0.903 62.59379

Cadmium 45.13 91.7 80 1200.271 4.37145.7

Chromium 45.13 89.2 80 1201.81 9.45349.7

Copper 45.13 1900 80 120 S1.81 186.91040

Iron 225.6 -7.94 80 120 S11.3 1537015400

Lead 45.13 286 80 120 S0.271 136.0265

Selenium 45.13 89.8 80 1200.451 2.64443.2

Zinc 45.13 109 80 1202.26 359.7409


Analysis Date: 12/22/2014 3:10:00 PM


Units: mg/Kg-dry

RL


Arsenic 45.96 105 80 120 20 R0.919 62.59 109111

Cadmium 45.96 98.7 80 120 200.276 4.371 8.3649.7

Chromium 45.96 94.1 80 120 201.84 9.453 5.8752.7

Copper 45.96 114 80 120 20 R1.84 186.9 125239

Qualifiers:






40






Analysis Date: 12/22/2014 3:10:00 PM


Units: mg/Kg-dry

RL


Iron 229.8 842 80 120 20 S11.5 15370 12.017300

Lead 45.96 240 80 120 20 S0.276 136.0 7.44246

Selenium 45.96 92.8 80 120 200.460 2.644 4.7545.3

Zinc 45.96 256 80 120 20 S2.30 359.7 15.4477


Analysis Date: 12/22/2014 7:47:00 PM


Units: mg/Kg-dry

RL


Iron 0 10576 14940 4.9015700


Analysis Date: 12/22/2014 8:47:00 PM


Units: mg/Kg-dry

RL


Iron 11510 90.8 80 120115 1494025400

Qualifiers:






41





Sample ID ILCVL-141222 Batch ID: R77115 TestNo: SW6020A

Analysis Date: 12/22/2014 1:19:00 PM


Units: mg/L

RL


Arsenic 0.00500 92.0 70 1300.00500 00.00460

Cadmium 0.00100 111 70 1300.00100 00.00111

Chromium 0.00500 92.0 70 1300.00500 00.00460

Copper 0.00500 91.8 70 1300.0100 00.00459

Iron 0.100 98.1 70 1300.100 00.0981

Lead 0.00100 114 70 1300.00100 00.00114

Selenium 0.00500 98.1 70 1300.00500 00.00490

Zinc 0.00500 85.4 70 1300.00500 00.00427


Analysis Date: 12/22/2014 5:43:00 PM


Units: mg/L

RL


Arsenic 0.00500 96.2 70 1300.00500 00.00481

Cadmium 0.00100 109 70 1300.00100 00.00109

Chromium 0.00500 98.2 70 1300.00500 00.00491

Copper 0.00500 99.3 70 1300.0100 00.00496

Iron 0.100 110 70 1300.100 00.110

Lead 0.00100 127 70 1300.00100 00.00127

Selenium 0.00500 110 70 1300.00500 00.00548

Zinc 0.00500 99.9 70 1300.00500 00.00500


Analysis Date: 12/22/2014 7:24:00 PM


Units: mg/L

RL


Arsenic 0.00500 89.0 70 1300.00500 00.00445

Cadmium 0.00100 93.5 70 1300.00100 00.000935

Chromium 0.00500 86.7 70 1300.00500 00.00433

Copper 0.00500 97.2 70 1300.0100 00.00486

Iron 0.100 116 70 1300.100 00.116

Lead 0.00100 125 70 1300.00100 00.00125

Selenium 0.00500 93.8 70 1300.00500 00.00469

Zinc 0.00500 109 70 1300.00500 00.00544


Analysis Date: 12/22/2014 9:34:00 PM


Units: mg/L

RL


Copper 0.00500 105 70 1300.0100 00.00523

Iron 0.100 121 70 1300.100 00.121

Qualifiers:






42






Analysis Date: 12/22/2014 9:34:00 PM


Units: mg/L

RL


Zinc 0.00500 120 70 1300.00500 00.00601


Analysis Date: 12/22/2014 11:03:00 P


Units: mg/L

RL


Copper 0.00500 85.6 70 1300.0100 00.00428

Iron 0.100 90.0 70 1300.100 00.0900

Zinc 0.00500 92.2 70 1300.00500 00.00461

Sample ID ICV1-141222 Batch ID: R77115 TestNo: SW6020A

Analysis Date: 12/22/2014 1:08:00 PM


Units: mg/L

RL


Arsenic 0.100 99.7 90 1100.00500 00.0997

Cadmium 0.100 104 90 1100.00100 00.104

Chromium 0.100 103 90 1100.00500 00.103

Copper 0.100 102 90 1100.0100 00.102

Iron 2.50 104 90 1100.100 02.61

Lead 0.100 102 90 1100.00100 00.102

Selenium 0.100 99.5 90 1100.00500 00.0995

Zinc 0.100 102 90 1100.00500 00.102


Analysis Date: 12/22/2014 3:16:00 PM


Units: mg/L

RL


Arsenic 0.200 102 90 1100.00500 00.205

Cadmium 0.200 101 90 1100.00100 00.203

Chromium 0.200 105 90 1100.00500 00.211

Copper 0.200 106 90 1100.0100 00.212

Iron 5.00 106 90 1100.100 05.32

Lead 0.200 100 90 1100.00100 00.200

Selenium 0.200 103 90 1100.00500 00.205

Zinc 0.200 104 90 1100.00500 00.209


Analysis Date: 12/22/2014 6:48:00 PM


Units: mg/L

RL


Arsenic 0.200 102 90 1100.00500 00.204

Qualifiers:






43






Analysis Date: 12/22/2014 6:48:00 PM


Units: mg/L

RL


Cadmium 0.200 102 90 1100.00100 00.204

Chromium 0.200 103 90 1100.00500 00.207

Copper 0.200 105 90 1100.0100 00.210

Iron 5.00 107 90 1100.100 05.36

Lead 0.200 101 90 1100.00100 00.201

Selenium 0.200 102 90 1100.00500 00.203

Zinc 0.200 105 90 1100.00500 00.210


Analysis Date: 12/22/2014 8:53:00 PM


Units: mg/L

RL


Copper 0.200 103 90 1100.0100 00.207

Iron 5.00 106 90 1100.100 05.30

Zinc 0.200 103 90 1100.00500 00.206


Analysis Date: 12/22/2014 10:33:00 P


Units: mg/L

RL


Copper 0.200 106 90 1100.0100 00.211

Iron 5.00 109 90 1100.100 05.46

Zinc 0.200 105 90 1100.00500 00.210

Qualifiers:






44




RunID: PMOIST_141222AThe QC data in batch 67278 applies to the following samples: 1412152-01A, 1412152-02A, 1412152-03A, 1412152-04A, 1412152-05A, 1412152-06A, 1412152-07A, 1412152-08A, 1412152-09A, 1412152-10A, 1412152-11A, 1412152-12A, 1412152-13A, 1412152-14A, 1412152-15A, 1412152-16A


Analysis Date: 12/23/2014 9:24:00 AM


Units: WT%

RL



Qualifiers:






45





TestNo: SW7471B

mg/KgAnalyte

MQL

mg/Kg

MDL

Mercury 0.04000.0160

TestNo: SW6020A

mg/KgAnalyte

MQL

mg/Kg

MDL

Arsenic 1.000.500

Cadmium 0.3000.100

Chromium 2.000.500

Copper 2.000.500

Iron 12.512.5

Lead 0.3000.100

Selenium 0.5000.150

Zinc 2.501.00

Qualifiers:

Page 1 of 1



46

ANALYTICAL REPORTTestAmerica Laboratories, Inc.TestAmerica Corpus Christi1733 N. Padre Island DriveCorpus Christi, TX 78408Tel: (361)289-2673

TestAmerica Job ID: 560-45526-1Client Project/Site: 06835001/Frmr ASARCO SiteRevision: 1

For:Malcolm Pirnie, Inc. Invoice to Arcadis211 North Florence StreetSuite 202El Paso, Texas 79901

Attn: Ms. Marla Miller

Authorized for release by:6/26/2014 5:28:44 PMJohn Cady, Manager of Project [email protected]

Designee for

Neal Salcher, Senior Project [email protected]

The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accreditedparameters, exceptions are noted in this report. This report may not be reproduced except in full,and with written approval from the laboratory. For questions please contact the Project Managerat the e-mail address or telephone number listed on this page.

This report has been electronically signed and authorized by the signatory. Electronic signature isintended to be the legally binding equivalent of a traditionally handwritten signature.

Results relate only to the items tested and the sample(s) as received by the laboratory.

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mailto:[email protected]

mailto:[email protected]

Definitions/GlossaryTestAmerica Job ID: 560-45526-1Client: Malcolm Pirnie, Inc. Invoice to Arcadis

Project/Site: 06835001/Frmr ASARCO Site

Qualifiers

Metals

Qualifier Description

U Analyte was not detected at or above the SDL.

Qualifier

J Result is less than the MQL but greater than or equal to the SDL and the concentration is an estimated value.

N MS, MSD: Spike recovery exceeds upper or lower control limits.

4 MS, MSD: The analyte present in the original sample is greater than 4 times the matrix spike concentration; therefore, control limits are not

applicable.

General Chemistry

Qualifier Description

H Sample was prepped or analyzed beyond the specified holding time

Qualifier

Glossary

These commonly used abbreviations may or may not be present in this report.

¤ Listed under the "D" column to designate that the result is reported on a dry weight basis

Abbreviation

%R Percent Recovery

CFL Contains Free Liquid

CNF Contains no Free Liquid

DER Duplicate error ratio (normalized absolute difference)

Dil Fac Dilution Factor

DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample

DLC Decision level concentration

MDA Minimum detectable activity

EDL Estimated Detection Limit

MDC Minimum detectable concentration

MDL Method Detection Limit

ML Minimum Level (Dioxin)

NC Not Calculated

ND Not detected at the reporting limit (or MDL or EDL if shown)

PQL Practical Quantitation Limit

QC Quality Control

RER Relative error ratio

RL Reporting Limit or Requested Limit (Radiochemistry)

RPD Relative Percent Difference, a measure of the relative difference between two points

TEF Toxicity Equivalent Factor (Dioxin)

TEQ Toxicity Equivalent Quotient (Dioxin)

TestAmerica Corpus Christi

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Appendix A

This data package is for TestAmerica Corpus Christi job number 560-45526-1 and consists of:

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Release Statement: I am responsible for the release of this laboratory data package. This laboratory isNELAC accredited under the Texas Laboratory Accreditation Program for all the methods, analytes, andmatrices reported in this data package except as noted in the Exception Reports. The data have beenreviewed and are technically compliant with the requirements of the methods used, except where notedby the laboratory in the Exception Reports. By my signature below, I affirm to the best of my knowledgeall problems/anomalies observed by the laboratory have been identified in the Laboratory Review Checklist,and no information affecting the quality of the data has been knowingly withheld.

a. Calculated recovery (%R), and

b. The laboratory’s surrogate QC limits.

R5 - Test reports/summary forms for blank samples;

R6 - Test reports/summary forms for laboratory control samples (LCSs) including:

The Exception Report for each “No” or “Not Reviewed (NR)” item in Laboratory Review Checklist and for each

a. LCS spiking amounts,

b. Calculated %R for each analyte, and

c. The laboratory’s LCS QC limits.

R7 - Test reports for project matrix spike/matrix spike duplicates (MS/MSDs) including:

a. Samples associated with the MS/MSD clearly identified,

b. MS/MSD spiking amounts,

c. Concentration of each MS/MSD analyte measured in the parent and spiked samples,

d. Calculated %Rs and relative percent differences (RPDs), and

e. The laboratory’s MS/MSD QC limits

Date6/26/2014John Cady

Laboratory Accreditation Program.

each method and matrix.

Laboratory Data Package Cover Page - Page 1 of 4

R8 - Laboratory analytical duplicate (if applicable) recovery and precision:

a. The amount of analyte measured in the duplicate,

b. The calculated RPD, and

c. The laboratory’s QC limits for analytical duplicates.

R9 - List of method quantitation limits (MQLs) and detectability check sample results for each analyte for

R10 - Other problems or anomalies.

analyte, matrix, and method for which the laboratory does not hold NELAC accreditation under the Texas

Name (printed)

R1 - Field chain-of-custody documentation;

R2 - Sample identification cross-reference;

R3 - Test reports (analytical data sheets) for each environmental sample that includes:

a. Items consistent with NELAC Chapter 5,

b. dilution factors,

c. preparation methods,

d. cleanup methods, and

e. if required for the project, tentatively identified compounds (TICs).

R4 - Surrogate recovery data including:

Signature

Manager of Project ManagementOfficial Title (printed)

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LRC Date:Laboratory Job Number:

#1 A2 Yes No NA3 NR4 ER#5

R1 OIXX

R2 OIXX

R3 OIXXXXXXX

XX

R4 OXX

R5 OIXX

XX

R6 OIXXXX

XX

R7 OIXX

X R07CX

R8 OIXXX

R9 OIXXX

R10 OIX

X

X1.

2.3.4.5.

Chain-of-custody (C-O-C)Did samples meet the laboratory’s standard conditions of sample acceptability upon receipt?Were all departures from standard conditions described in an exception report?Sample and quality control (QC) identification

6/26/2014Laboratory Name:

If required for the project, are TICs reported?Surrogate recovery data

Were bulk soils/solids samples for volatile analysis extracted with methanol per SW846 Method 5035?

Are all field sample ID numbers cross-referenced to the laboratory ID numbers?Are all laboratory ID numbers cross-referenced to the corresponding QC data?Test reportsWere all samples prepared and analyzed within holding times?

Reviewer Name:Project Name:

Were appropriate analytical duplicates analyzed for each matrix?Were analytical duplicates analyzed at the appropriate frequency?

TestAmerica Corpus Christi06835001/Frmr ASARCO Site

Other than those results < MQL, were all other raw values bracketed by calibration standards?Were calculations checked by a peer or supervisor?Were all analyte identifications checked by a peer or supervisor?Were sample detection limits reported for all analytes not detected?Were all results for soil and sediment samples reported on a dry weight basis?

Were RPDs or relative standard deviations within the laboratory QC limits?

Do the MQLs correspond to the concentration of the lowest non-zero calibration standard?

Matrix spike (MS) and matrix spike duplicate (MSD) data

Were blanks analyzed at the appropriate frequency?Were method blanks taken through the entire analytical process, including preparation and, if applicable, cleanup procedures?Were blank concentrations < MQL?Laboratory control samples (LCS):Were all COCs included in the LCS?Was each LCS taken through the entire analytical procedure, including prep and cleanup steps?Were LCSs analyzed at the required frequency?

Were % moisture (or solids) reported for all soil and sediment samples?

Were surrogates added prior to extraction?Were surrogate percent recoveries in all samples within the laboratory QC limits?Test reports/summary forms for blank samplesWere appropriate type(s) of blanks analyzed?

Were LCS (and LCSD, if applicable) %Rs within the laboratory QC limits?Does the detectability check sample data document the laboratory’s capability to detect the COCs at the MDL used to calculate the SDLs?

560-45526-1

Were the project/method specified analytes included in the MS and MSD?Were MS/MSD analyzed at the appropriate frequency?Were MS (and MSD, if applicable) %Rs within the laboratory QC limits?Were MS/MSD RPDs within laboratory QC limits?Analytical duplicate data

Items identified by the letter “R” must be included in the laboratory data package submitted in the TRRP-required report(s). Items

Are all known problems/anomalies/special conditions noted in this LRC and ER?

Was applicable and available technology used to lower the SDL to minimize the matrix interference effects on the sample results?Is the laboratory NELAC-accredited under the Texas Laboratory Accreditation Program for the analytes, matrices and methods associated with this laboratory data package?

Method quantitation limits (MQLs):Are the MQLs for each method analyte included in the laboratory data package?

Are unadjusted MQLs and DCSs included in the laboratory data package?Other problems/anomalies

Neal Salcher

Description

Laboratory Review Checklist: Reportable Data - Page 2 of 4

Was the LCSD RPD within QC limits?

identified by the letter “S” should be retained and made available upon request for the appropriate retention period.O = organic analyses; I = inorganic analyses (and general chemistry, when applicable);NA = Not applicable;NR = Not reviewed;ER# = Exception Report identification number (an Exception Report should be completed for an item if “NR” or “No” is checked).

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#1 A2 Yes No NA3 NR4 ER#5

S1 OIXXXXXX

S2 OIXXXX

S3 OXX

S4 OX

S5 OIXX

S6 OX

S7 OX

S8 IX

S9 IX

S10 OIXX

S11 OIX

S12 OIX

S13 OIX

S14 OIXX

S15 OI

XS16 OI

X1.

2.3.4.5.

6/26/2014560-45526-1

Has the initial calibration curve been verified using an appropriate second source standard?

Were percent RSDs or correlation coefficient criteria met?Was the number of standards recommended in the method used for all analytes?

Were response factors and/or relative response factors for each analyte within QC limits?

Were all points generated between the lowest and highest standard used to calculate the curve?Are ICAL data available for all instruments used?

Initial calibration (ICAL)

Laboratory Name: TestAmerica Corpus ChristiProject Name:

Initial and continuing calibration verification (ICV and CCV) and continuing calibration blank (CCB):

Were percent differences for each analyte within the method-required QC limits?Was the ICAL curve verified for each analyte?

Description

Was the CCV analyzed at the method-required frequency?

Were the raw data (for example, chromatograms, spectral data) reviewed by an analyst?Were data associated with manual integrations flagged on the raw data?

Was the absolute value of the analyte concentration in the inorganic CCB < MDL?Mass spectral tuningWas the appropriate compound for the method used for tuning?Were ion abundance data within the method-required QC limits?Internal standards (IS)Were IS area counts and retention times within the method-required QC limits?Raw data (NELAC Section 5.5.10)

Dual column confirmationDid dual column confirmation results meet the method-required QC?Tentatively identified compounds (TICs)If TICs were requested, were the mass spectra and TIC data subject to appropriate checks?Interference Check Sample (ICS) resultsWere percent recoveries within method QC limits?

Verification/validation documentation for methods (NELAC Chapter 5)

Are all the methods used to generate the data documented, verified, and validated, where applicable?

Serial dilutions, post digestion spikes, and method of standard additions

Method detection limit (MDL) studiesWas a MDL study performed for each reported analyte?Is the MDL either adjusted or supported by the analysis of DCSs?Proficiency test reports

Standards documentationAre all standards used in the analyses NIST-traceable or obtained from other appropriate sources?Compound/analyte identification proceduresAre the procedures for compound/analyte identification documented?

Laboratory Review checklist: Supporting Data - Page 3 of 4

Items identified by the letter “R” must be included in the laboratory data package submitted in the TRRP-required report(s). Itemsidentified by the letter “S” should be retained and made available upon request for the appropriate retention period.O = organic analyses; I = inorganic analyses (and general chemistry, when applicable);NA = Not applicable;NR = Not reviewed;

Laboratory standard operating procedures (SOPs)Are laboratory SOPs current and on file for each method performed?

Demonstration of analyst competency (DOC)

06835001/Frmr ASARCO SiteReviewer Name: Neal Salcher

ER# = Exception Report identification number (an Exception Report should be completed for an item if “NR” or “No” is checked).

Was the laboratory's performance acceptable on the applicable proficiency tests or evaluation studies?

Were percent differences, recoveries, and the linearity within the QC limits specified in the method?

Was DOC conducted consistent with NELAC Chapter 5?Is documentation of the analyst’s competency up-to-date and on file?

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1.

2.3.4.5.

NA = Not applicable;

ER# = Exception Report identification number (an Exception Report should be completed for an item if “NR” or “No” is checked).

Laboratory Review Checklist: Exception Reports - Page 4 of 4

R07C

Neal Salcher

Items identified by the letter “R” must be included in the laboratory data package submitted in the TRRP-required report(s). Itemsidentified by the letter “S” should be retained and made available upon request for the appropriate retention period.O = organic analyses; I = inorganic analyses (and general chemistry, when applicable);

Method 6010B: 560-45526-1 MS and MSD failed the recovery criteria for the following analyte(s): Antimony. Matrix interference is suspected.

Method 6010B: 560-45526-21 MS and MSDfailed the recovery criteria for the following analyte(s): Antimony, Copper. Matrix interference is suspected.

Method 6010B: 560-45526-41 MS and MSD failed the recovery criteria for the following analyte(s): Antimony, Arsenic, Barium, Cobalt, Copper, Lead, Molybdenum, Nickel, Selenium, Zinc. Matrix interference is suspected.

Method 7471A: The matrix spike / matrix spike duplicate (MS/MSD) recoveries for batch98751 were outside control limits. Sample matrix interference and/or non-homogeneity are suspected because the associated laboratory control sample (LCS) recovery was within acceptance limits.

ER #1

Reviewer Name:

Description

Laboratory Name: TestAmerica Corpus Christi

NR = Not reviewed;

6/26/2014Project Name: 06835001/Frmr ASARCO Site 560-45526-1

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Detection Check Standard

Matrix: SoilMethod: 6020Preparation: per methodDate Analyzed: 1/6/2014Date Prepared: 12/10/2014TALs Batches: 560-44003-1Units: mg/Kg

Analyte MDL DCS Spike Measured Result MQLAntimony 0.0961 0.313 0.230 0.25Arsenic 0.0499 0.313 0.207 0.25Barium 0.109 0.313 0.297 0.25Cadmium 0.0721 0.313 0.234 0.25Chromium 0.112 0.313 0.257 0.25Cobalt 0.0525 0.313 0.299 0.25Copper 0.177 0.313 1.75 0.5Iron 5.53 31.3 32.2 25Lead 0.205 0.313 0.300 0.5Molybdenum 0.106 0.313 0.127 0.25Nickel 0.133 0.313 0.307 0.25Selenium 0.0435 0.313 0.281 0.25Silver 0.0686 0.313 0.219 0.25Zinc 0.768 0.625 1.18 1.25

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Detection Check Standard

Matrix: SoilMethod: 7471APreparation: per methodDate Analyzed: 11/27/2013Date Prepared: 11/27/2013TALs Batches: 560-43975-3Units: mg/Kg

Analyte MDL DCS Spike Measured Result MQLMercury 0.018 0.25 0.2505 0.2

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Case NarrativeClient: Malcolm Pirnie, Inc. Invoice to Arcadis TestAmerica Job ID: 560-45526-1


Job ID: 560-45526-1

Laboratory: TestAmerica Corpus Christi

Narrative

Job Narrative

560-45526-1

Comments

This is a revised report replacing the original report generated on 3/4/2014, adjusting date and time per clients request.

Receipt

The samples were received on 2/18/2014 9:30 AM; the samples arrived in good condition, properly preserved and, where required, on ice.

The temperatures of the 2 coolers at receipt time were 5.8º C and 6.0º C.

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Detection SummaryTestAmerica Job ID: 560-45526-1Client: Malcolm Pirnie, Inc. Invoice to Arcadis


Client Sample ID: A12-A5 Lab Sample ID: 560-45526-1

☼Arsenic

MQL (Adj)

1.74 mg/Kg

SDL

0.126

Analyte Result Qualifier Unit Dil Fac D Method Prep Type

Total/NA14.96 6010B

☼Barium 0.870 mg/Kg0.164 Total/NA161.7 6010B

☼Cadmium 0.435 mg/Kg0.0313 Total/NA10.902 6010B

☼Chromium 0.870 mg/Kg0.117 Total/NA12.07 6010B

☼Cobalt 0.870 mg/Kg0.0244 Total/NA11.67 6010B

☼Copper 1.74 mg/Kg0.175 Total/NA122.3 6010B

☼Iron 17.4 mg/Kg10.3 Total/NA13120 6010B

☼Lead 0.435 mg/Kg0.132 Total/NA120.4 6010B

☼Molybdenum 1.74 mg/Kg0.109 Total/NA10.396 J 6010B

☼Nickel 1.74 mg/Kg0.108 Total/NA12.49 6010B

☼Selenium 0.870 mg/Kg0.172 Total/NA10.241 J 6010B

☼Zinc 2.18 mg/Kg0.496 Total/NA130.8 6010B

☼Mercury 0.108 mg/Kg0.00973 Total/NA10.0312 J 7471A


☼Arsenic

MQL (Adj)

1.53 mg/Kg

SDL

0.111


Total/NA14.49 6010B













☼Arsenic

MQL (Adj)

1.91 mg/Kg

SDL

0.138


Total/NA13.21 6010B


☼Cadmium 0.477 mg/Kg0.0344 Total/NA10.296 J 6010B










Client Sample ID: A12-B5 Lab Sample ID: 560-45526-4

☼Arsenic

MQL (Adj)

1.91 mg/Kg

SDL

0.138


Total/NA12.99 6010B


This Detection Summary does not include radiochemical test results.

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Client Sample ID: A12-B5 (Continued) Lab Sample ID: 560-45526-4

☼Barium

MQL (Adj)

0.953 mg/Kg

SDL

0.180


Total/NA184.7 6010B













☼Arsenic

MQL (Adj)

1.91 mg/Kg

SDL

0.139


Total/NA1J1.59 6010B








☼Nickel 1.91 mg/Kg0.118 Total/NA11.70 J 6010B




☼Arsenic

MQL (Adj)

1.60 mg/Kg

SDL

0.116













Client Sample ID: A12-C4 Lab Sample ID: 560-45526-7

☼Arsenic

MQL (Adj)

1.57 mg/Kg

SDL

0.114


Total/NA12.69 6010B

☼Barium 0.786 mg/Kg0.148 Total/NA1152 6010B





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Client Sample ID: A12-C4 (Continued) Lab Sample ID: 560-45526-7

☼Cobalt

MQL (Adj)

0.786 mg/Kg

SDL

0.0220


Total/NA12.38 6010B










☼Arsenic

MQL (Adj)

1.89 mg/Kg

SDL

0.137


Total/NA15.29 6010B














☼Arsenic

MQL (Adj)

0.186 mg/Kg

SDL

0.0135


Total/NA10.624 6010B














☼Antimony

MQL (Adj)

1.78 mg/Kg

SDL

0.238



☼Arsenic 1.78 mg/Kg0.129 Total/NA131.1 6010B




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Client Sample ID: A12-C7 (Continued) Lab Sample ID: 560-45526-10

☼Cadmium

MQL (Adj)

0.445 mg/Kg

SDL

0.0320


Total/NA16.10 6010B










☼Mercury 0.108 mg/Kg0.00970 Total/NA10.146 7471A

Client Sample ID: A12-D3 Lab Sample ID: 560-45526-11

☼Arsenic

MQL (Adj)

1.57 mg/Kg

SDL

0.114


Total/NA110.5 6010B














☼Antimony

MQL (Adj)

1.60 mg/Kg

SDL

0.213



















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Client Sample ID: A12-D5 (Continued) Lab Sample ID: 560-45526-13

☼Arsenic

MQL (Adj)

2.04 mg/Kg

SDL

0.148


Total/NA15.03 6010B














☼Arsenic

MQL (Adj)

1.95 mg/Kg

SDL

0.141


Total/NA114.5 6010B













Client Sample ID: A12-F2 Lab Sample ID: 560-45526-15

☼Arsenic

MQL (Adj)

1.98 mg/Kg

SDL

0.144


Total/NA18.16 6010B
















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Client Sample ID: A12-F3 (Continued) Lab Sample ID: 560-45526-16

☼Antimony

MQL (Adj)

1.75 mg/Kg

SDL

0.233

















☼Antimony

MQL (Adj)

1.78 mg/Kg

SDL

0.238

















☼Arsenic

MQL (Adj)

1.99 mg/Kg

SDL

0.144


Total/NA18.21 6010B















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Client Sample ID: A12-F6 (Continued) Lab Sample ID: 560-45526-19

☼Antimony

MQL (Adj)

1.71 mg/Kg

SDL

0.229

















☼Arsenic

MQL (Adj)

1.68 mg/Kg

SDL

0.122


Total/NA15.84 6010B













☼Antimony

MQL (Adj)

1.99 mg/Kg

SDL

0.266
















Client Sample ID: A12-G3 Lab Sample ID: 560-45526-22



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Client Sample ID: A12-G3 (Continued) Lab Sample ID: 560-45526-22

☼Antimony

MQL (Adj)

1.85 mg/Kg

SDL

0.247










☼Lead 0.463 mg/Kg0.141 Total/NA1325 6010B






☼Antimony

MQL (Adj)

1.89 mg/Kg

SDL

0.252

















☼Antimony

MQL (Adj)

1.97 mg/Kg

SDL

0.263








☼Copper 1.97 mg/Kg0.198 Total/NA1103 6010B










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☼Antimony

MQL (Adj)

1.70 mg/Kg

SDL

0.226

















☼Arsenic

MQL (Adj)

1.76 mg/Kg

SDL

0.128


Total/NA16.01 6010B













☼Antimony

MQL (Adj)

1.79 mg/Kg

SDL

0.239














☼Zinc 2.23 mg/Kg0.509 Total/NA1173 6010B


Client Sample ID: A12-H4 Lab Sample ID: 560-45526-28



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Client Sample ID: A12-H4 (Continued) Lab Sample ID: 560-45526-28

☼Antimony

MQL (Adj)

1.91 mg/Kg

SDL

0.255

















☼Antimony

MQL (Adj)

1.90 mg/Kg

SDL

0.253

















☼Arsenic

MQL (Adj)

1.73 mg/Kg

SDL

0.125


Total/NA112.8 6010B















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Client Sample ID: A12-H7 (Continued) Lab Sample ID: 560-45526-31

☼Antimony

MQL (Adj)

1.95 mg/Kg

SDL

0.261

















☼Arsenic

MQL (Adj)

1.55 mg/Kg

SDL

0.112


Total/NA13.64 6010B












Client Sample ID: A12-I5 Lab Sample ID: 560-45526-33

☼Arsenic

MQL (Adj)

1.76 mg/Kg

SDL

0.128


Total/NA17.66 6010B
















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Client Sample ID: A12-I6 (Continued) Lab Sample ID: 560-45526-34

☼Arsenic

MQL (Adj)

1.83 mg/Kg

SDL

0.133


Total/NA15.01 6010B













☼Arsenic

MQL (Adj)

1.88 mg/Kg

SDL

0.136


Total/NA18.17 6010B














☼Arsenic

MQL (Adj)

1.80 mg/Kg

SDL

0.130


Total/NA14.07 6010B
















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Client Sample ID: A12-I9 (Continued) Lab Sample ID: 560-45526-37

☼Arsenic

MQL (Adj)

1.94 mg/Kg

SDL

0.141


Total/NA15.54 6010B












Client Sample ID: A12-J6 Lab Sample ID: 560-45526-38

☼Antimony

MQL (Adj)

1.86 mg/Kg

SDL

0.249
















☼Antimony

MQL (Adj)

2.03 mg/Kg

SDL

0.271



















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Client Sample ID: A12-J8 (Continued) Lab Sample ID: 560-45526-40

☼Antimony

MQL (Adj)

1.62 mg/Kg

SDL

0.216

















☼Arsenic

MQL (Adj)

1.76 mg/Kg

SDL

0.127


Total/NA12.75 6010B












☼Antimony

MQL (Adj)

2.08 mg/Kg

SDL

0.278
















Client Sample ID: A12-K7 Lab Sample ID: 560-45526-43



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Client Sample ID: A12-K7 (Continued) Lab Sample ID: 560-45526-43

☼Antimony

MQL (Adj)

1.92 mg/Kg

SDL

0.257

















☼Arsenic

MQL (Adj)

1.80 mg/Kg

SDL

0.130


Total/NA13.91 6010B














☼Antimony

MQL (Adj)

2.11 mg/Kg

SDL

0.282


















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Client Sample ID: A12-K10 (Continued) Lab Sample ID: 560-45526-46

☼Antimony

MQL (Adj)

2.07 mg/Kg

SDL

0.277














☼Zinc 2.59 mg/Kg0.591 Total/NA1116 6010B




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Client Sample ResultsTestAmerica Job ID: 560-45526-1Client: Malcolm Pirnie, Inc. Invoice to Arcadis


Lab Sample ID: 560-45526-1Client Sample ID: A12-A5Matrix: SolidDate Collected: 01/29/14 13:10

Percent Solids: 99.1Date Received: 02/18/14 09:30

Method: 6010B - Metals (ICP)MQL (Adj) SDL

Antimony 0.232 U 1.74 0.232 mg/Kg ☼ 02/20/14 08:30 02/20/14 12:44 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

1.74 0.126 mg/Kg 02/20/14 08:30 02/20/14 12:44 1☼Arsenic 4.96

0.870 0.164 mg/Kg 02/20/14 08:30 02/20/14 12:44 1☼Barium 61.7

0.435 0.0313 mg/Kg 02/20/14 08:30 02/20/14 12:44 1☼Cadmium 0.902

0.870 0.117 mg/Kg 02/20/14 08:30 02/20/14 12:44 1☼Chromium 2.07

0.870 0.0244 mg/Kg 02/20/14 08:30 02/20/14 12:44 1☼Cobalt 1.67

1.74 0.175 mg/Kg 02/20/14 08:30 02/20/14 12:44 1☼Copper 22.3

17.4 10.3 mg/Kg 02/20/14 08:30 02/20/14 12:44 1☼Iron 3120

0.435 0.132 mg/Kg 02/20/14 08:30 02/20/14 12:44 1☼Lead 20.4

1.74 0.109 mg/Kg 02/20/14 08:30 02/20/14 12:44 1☼Molybdenum 0.396 J

1.74 0.108 mg/Kg 02/20/14 08:30 02/20/14 12:44 1☼Nickel 2.49

0.870 0.172 mg/Kg 02/20/14 08:30 02/20/14 12:44 1☼Selenium 0.241 J

0.435 0.0957 mg/Kg 02/20/14 08:30 02/20/14 12:44 1☼Silver 0.0957 U

2.18 0.496 mg/Kg 02/20/14 08:30 02/20/14 12:44 1☼Zinc 30.8

Method: 7471A - Mercury (CVAA)MQL (Adj) SDL

Mercury 0.0312 J 0.108 0.00973 mg/Kg ☼ 02/20/14 10:00 02/20/14 18:25 1


General ChemistryMQL (Adj) SDL

Percent Moisture 0.93 0.10 0.10 % 02/19/14 14:59 1


0.10 0.10 % 02/19/14 14:59 1Percent Solids 99




Antimony 0.205 U 1.53 0.205 mg/Kg ☼ 02/20/14 08:30 02/20/14 13:00 1


1.53 0.111 mg/Kg 02/20/14 08:30 02/20/14 13:00 1☼Arsenic 4.49

0.767 0.145 mg/Kg 02/20/14 08:30 02/20/14 13:00 1☼Barium 59.7

0.384 0.0276 mg/Kg 02/20/14 08:30 02/20/14 13:00 1☼Cadmium 0.516

0.767 0.103 mg/Kg 02/20/14 08:30 02/20/14 13:00 1☼Chromium 1.58

0.767 0.0215 mg/Kg 02/20/14 08:30 02/20/14 13:00 1☼Cobalt 1.43

1.53 0.154 mg/Kg 02/20/14 08:30 02/20/14 13:00 1☼Copper 10.7

15.3 9.05 mg/Kg 02/20/14 08:30 02/20/14 13:00 1☼Iron 2490

0.384 0.117 mg/Kg 02/20/14 08:30 02/20/14 13:00 1☼Lead 11.8


1.53 0.0951 mg/Kg 02/20/14 08:30 02/20/14 13:00 1☼Nickel 1.98

0.767 0.152 mg/Kg 02/20/14 08:30 02/20/14 13:00 1☼Selenium 0.152 U

0.384 0.0844 mg/Kg 02/20/14 08:30 02/20/14 13:00 1☼Silver 0.0844 U

1.92 0.437 mg/Kg 02/20/14 08:30 02/20/14 13:00 1☼Zinc 17.1


Mercury 0.0217 J 0.115 0.0103 mg/Kg ☼ 02/20/14 10:00 02/20/14 18:33 1



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Date Received: 02/18/14 09:30




0.10 0.10 % 02/19/14 14:59 1Percent Solids 99




Antimony 0.255 U 1.91 0.255 mg/Kg ☼ 02/20/14 08:30 02/20/14 13:04 1


1.91 0.138 mg/Kg 02/20/14 08:30 02/20/14 13:04 1☼Arsenic 3.21

0.954 0.180 mg/Kg 02/20/14 08:30 02/20/14 13:04 1☼Barium 36.4

0.477 0.0344 mg/Kg 02/20/14 08:30 02/20/14 13:04 1☼Cadmium 0.296 J

0.954 0.128 mg/Kg 02/20/14 08:30 02/20/14 13:04 1☼Chromium 1.83

0.954 0.0267 mg/Kg 02/20/14 08:30 02/20/14 13:04 1☼Cobalt 1.21

1.91 0.192 mg/Kg 02/20/14 08:30 02/20/14 13:04 1☼Copper 3.78

19.1 11.3 mg/Kg 02/20/14 08:30 02/20/14 13:04 1☼Iron 2500

0.477 0.145 mg/Kg 02/20/14 08:30 02/20/14 13:04 1☼Lead 4.46


1.91 0.118 mg/Kg 02/20/14 08:30 02/20/14 13:04 1☼Nickel 1.91

0.954 0.189 mg/Kg 02/20/14 08:30 02/20/14 13:04 1☼Selenium 0.189 U

0.477 0.105 mg/Kg 02/20/14 08:30 02/20/14 13:04 1☼Silver 0.105 U

2.39 0.544 mg/Kg 02/20/14 08:30 02/20/14 13:04 1☼Zinc 11.4


Mercury 0.0235 J 0.113 0.0102 mg/Kg ☼ 02/20/14 10:00 02/20/14 18:35 1



Percent Moisture 2.1 H 0.10 0.10 % 02/19/14 14:59 1


0.10 0.10 % 02/19/14 14:59 1Percent Solids 98 H

Lab Sample ID: 560-45526-4Client Sample ID: A12-B5Matrix: SolidDate Collected: 01/14/14 08:25



Antimony 0.255 U 1.91 0.255 mg/Kg ☼ 02/20/14 08:30 02/20/14 13:20 1


1.91 0.138 mg/Kg 02/20/14 08:30 02/20/14 13:20 1☼Arsenic 2.99

0.953 0.180 mg/Kg 02/20/14 08:30 02/20/14 13:20 1☼Barium 84.7

0.477 0.0343 mg/Kg 02/20/14 08:30 02/20/14 13:20 1☼Cadmium 0.436 J

0.953 0.128 mg/Kg 02/20/14 08:30 02/20/14 13:20 1☼Chromium 2.60

0.953 0.0267 mg/Kg 02/20/14 08:30 02/20/14 13:20 1☼Cobalt 1.77

1.91 0.192 mg/Kg 02/20/14 08:30 02/20/14 13:20 1☼Copper 9.89

19.1 11.3 mg/Kg 02/20/14 08:30 02/20/14 13:20 1☼Iron 3210

0.477 0.145 mg/Kg 02/20/14 08:30 02/20/14 13:20 1☼Lead 7.59


1.91 0.118 mg/Kg 02/20/14 08:30 02/20/14 13:20 1☼Nickel 2.69


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Method: 6010B - Metals (ICP) (Continued)MQL (Adj) SDL

Selenium 0.236 J 0.953 0.189 mg/Kg ☼ 02/20/14 08:30 02/20/14 13:20 1


0.477 0.105 mg/Kg 02/20/14 08:30 02/20/14 13:20 1☼Silver 0.105 U

2.38 0.543 mg/Kg 02/20/14 08:30 02/20/14 13:20 1☼Zinc 17.5


Mercury 0.0289 J 0.107 0.00966 mg/Kg ☼ 02/20/14 10:00 02/20/14 18:38 1





0.10 0.10 % 02/19/14 14:59 1Percent Solids 98 H




Antimony 0.255 U 1.91 0.255 mg/Kg ☼ 02/20/14 08:30 02/20/14 13:25 1


1.91 0.139 mg/Kg 02/20/14 08:30 02/20/14 13:25 1☼Arsenic 1.59 J

0.955 0.181 mg/Kg 02/20/14 08:30 02/20/14 13:25 1☼Barium 31.4

0.478 0.0344 mg/Kg 02/20/14 08:30 02/20/14 13:25 1☼Cadmium 0.212 J

0.955 0.128 mg/Kg 02/20/14 08:30 02/20/14 13:25 1☼Chromium 1.45

0.955 0.0268 mg/Kg 02/20/14 08:30 02/20/14 13:25 1☼Cobalt 1.27

1.91 0.192 mg/Kg 02/20/14 08:30 02/20/14 13:25 1☼Copper 2.97

19.1 11.3 mg/Kg 02/20/14 08:30 02/20/14 13:25 1☼Iron 2570

0.478 0.145 mg/Kg 02/20/14 08:30 02/20/14 13:25 1☼Lead 3.31

1.91 0.119 mg/Kg 02/20/14 08:30 02/20/14 13:25 1☼Molybdenum 0.119 U

1.91 0.118 mg/Kg 02/20/14 08:30 02/20/14 13:25 1☼Nickel 1.70 J

0.955 0.189 mg/Kg 02/20/14 08:30 02/20/14 13:25 1☼Selenium 0.189 U

0.478 0.105 mg/Kg 02/20/14 08:30 02/20/14 13:25 1☼Silver 0.105 U

2.39 0.545 mg/Kg 02/20/14 08:30 02/20/14 13:25 1☼Zinc 9.57


Mercury 0.0139 J 0.106 0.00951 mg/Kg ☼ 02/20/14 10:00 02/20/14 18:40 1





0.10 0.10 % 02/19/14 14:59 1Percent Solids 99 H




Antimony 0.213 U 1.60 0.213 mg/Kg ☼ 02/20/14 08:30 02/20/14 13:29 1


1.60 0.116 mg/Kg 02/20/14 08:30 02/20/14 13:29 1☼Arsenic 1.54 J


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Barium 23.0 0.799 0.151 mg/Kg ☼ 02/20/14 08:30 02/20/14 13:29 1


0.400 0.0288 mg/Kg 02/20/14 08:30 02/20/14 13:29 1☼Cadmium 0.208 J

0.799 0.107 mg/Kg 02/20/14 08:30 02/20/14 13:29 1☼Chromium 1.50

0.799 0.0224 mg/Kg 02/20/14 08:30 02/20/14 13:29 1☼Cobalt 1.30

1.60 0.161 mg/Kg 02/20/14 08:30 02/20/14 13:29 1☼Copper 1.79

16.0 9.43 mg/Kg 02/20/14 08:30 02/20/14 13:29 1☼Iron 2490

0.400 0.122 mg/Kg 02/20/14 08:30 02/20/14 13:29 1☼Lead 2.63

1.60 0.0999 mg/Kg 02/20/14 08:30 02/20/14 13:29 1☼Molybdenum 0.0999 U

1.60 0.0991 mg/Kg 02/20/14 08:30 02/20/14 13:29 1☼Nickel 1.86

0.799 0.158 mg/Kg 02/20/14 08:30 02/20/14 13:29 1☼Selenium 0.170 J

0.400 0.0879 mg/Kg 02/20/14 08:30 02/20/14 13:29 1☼Silver 0.0879 U

2.00 0.455 mg/Kg 02/20/14 08:30 02/20/14 13:29 1☼Zinc 7.62


Mercury 0.0104 U 0.116 0.0104 mg/Kg ☼ 02/20/14 10:00 02/20/14 18:42 1





0.10 0.10 % 02/19/14 14:59 1Percent Solids 99 H

Lab Sample ID: 560-45526-7Client Sample ID: A12-C4Matrix: SolidDate Collected: 01/14/14 08:10



Antimony 0.210 U 1.57 0.210 mg/Kg ☼ 02/20/14 08:30 02/20/14 13:33 1


1.57 0.114 mg/Kg 02/20/14 08:30 02/20/14 13:33 1☼Arsenic 2.69

0.786 0.148 mg/Kg 02/20/14 08:30 02/20/14 13:33 1☼Barium 152

0.393 0.0283 mg/Kg 02/20/14 08:30 02/20/14 13:33 1☼Cadmium 0.346 J

0.786 0.105 mg/Kg 02/20/14 08:30 02/20/14 13:33 1☼Chromium 3.66

0.786 0.0220 mg/Kg 02/20/14 08:30 02/20/14 13:33 1☼Cobalt 2.38

1.57 0.158 mg/Kg 02/20/14 08:30 02/20/14 13:33 1☼Copper 4.95

15.7 9.27 mg/Kg 02/20/14 08:30 02/20/14 13:33 1☼Iron 4140

0.393 0.120 mg/Kg 02/20/14 08:30 02/20/14 13:33 1☼Lead 4.67


1.57 0.0974 mg/Kg 02/20/14 08:30 02/20/14 13:33 1☼Nickel 4.01

0.786 0.156 mg/Kg 02/20/14 08:30 02/20/14 13:33 1☼Selenium 0.341 J

0.393 0.0864 mg/Kg 02/20/14 08:30 02/20/14 13:33 1☼Silver 0.0864 U

1.96 0.448 mg/Kg 02/20/14 08:30 02/20/14 13:33 1☼Zinc 15.1


Mercury 0.0270 J 0.101 0.00912 mg/Kg ☼ 02/20/14 10:00 02/20/14 18:45 1





0.10 0.10 % 02/19/14 14:59 1Percent Solids 98 H


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Antimony 0.253 U 1.89 0.253 mg/Kg ☼ 02/20/14 08:30 02/20/14 13:37 1


1.89 0.137 mg/Kg 02/20/14 08:30 02/20/14 13:37 1☼Arsenic 5.29

0.947 0.179 mg/Kg 02/20/14 08:30 02/20/14 13:37 1☼Barium 113

0.474 0.0341 mg/Kg 02/20/14 08:30 02/20/14 13:37 1☼Cadmium 0.555

0.947 0.127 mg/Kg 02/20/14 08:30 02/20/14 13:37 1☼Chromium 3.01

0.947 0.0265 mg/Kg 02/20/14 08:30 02/20/14 13:37 1☼Cobalt 2.16

1.89 0.190 mg/Kg 02/20/14 08:30 02/20/14 13:37 1☼Copper 7.49

18.9 11.2 mg/Kg 02/20/14 08:30 02/20/14 13:37 1☼Iron 3710

0.474 0.144 mg/Kg 02/20/14 08:30 02/20/14 13:37 1☼Lead 9.08


1.89 0.117 mg/Kg 02/20/14 08:30 02/20/14 13:37 1☼Nickel 3.50

0.947 0.188 mg/Kg 02/20/14 08:30 02/20/14 13:37 1☼Selenium 0.524 J

0.474 0.104 mg/Kg 02/20/14 08:30 02/20/14 13:37 1☼Silver 0.104 U

2.37 0.540 mg/Kg 02/20/14 08:30 02/20/14 13:37 1☼Zinc 17.2


Mercury 0.102 J 0.119 0.0107 mg/Kg ☼ 02/20/14 10:00 02/20/14 18:47 1





0.10 0.10 % 02/19/14 14:59 1Percent Solids 97 H




Antimony 0.0249 U 0.186 0.0249 mg/Kg ☼ 02/20/14 08:30 02/20/14 13:41 1


0.186 0.0135 mg/Kg 02/20/14 08:30 02/20/14 13:41 1☼Arsenic 0.624

0.0932 0.0176 mg/Kg 02/20/14 08:30 02/20/14 13:41 1☼Barium 4.35

0.0466 0.00335 mg/Kg 02/20/14 08:30 02/20/14 13:41 1☼Cadmium 0.0902

0.0932 0.0125 mg/Kg 02/20/14 08:30 02/20/14 13:41 1☼Chromium 0.183

0.0932 0.00261 mg/Kg 02/20/14 08:30 02/20/14 13:41 1☼Cobalt 0.140

0.186 0.0187 mg/Kg 02/20/14 08:30 02/20/14 13:41 1☼Copper 1.00

1.86 1.10 mg/Kg 02/20/14 08:30 02/20/14 13:41 1☼Iron 272

0.0466 0.0142 mg/Kg 02/20/14 08:30 02/20/14 13:41 1☼Lead 1.16


0.186 0.0116 mg/Kg 02/20/14 08:30 02/20/14 13:41 1☼Nickel 0.196

0.0932 0.0184 mg/Kg 02/20/14 08:30 02/20/14 13:41 1☼Selenium 0.0376 J

0.0466 0.0102 mg/Kg 02/20/14 08:30 02/20/14 13:41 1☼Silver 0.0102 U

0.233 0.0531 mg/Kg 02/20/14 08:30 02/20/14 13:41 1☼Zinc 1.75


Mercury 0.0315 J 0.117 0.0105 mg/Kg ☼ 02/20/14 10:00 02/20/14 18:50 1



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0.10 0.10 % 02/19/14 14:59 1Percent Solids 97 H




Antimony 0.653 J 1.78 0.238 mg/Kg ☼ 02/20/14 08:30 02/20/14 13:45 1


1.78 0.129 mg/Kg 02/20/14 08:30 02/20/14 13:45 1☼Arsenic 31.1

0.890 0.168 mg/Kg 02/20/14 08:30 02/20/14 13:45 1☼Barium 45.2

0.445 0.0320 mg/Kg 02/20/14 08:30 02/20/14 13:45 1☼Cadmium 6.10

0.890 0.119 mg/Kg 02/20/14 08:30 02/20/14 13:45 1☼Chromium 1.71

0.890 0.0249 mg/Kg 02/20/14 08:30 02/20/14 13:45 1☼Cobalt 1.90

1.78 0.179 mg/Kg 02/20/14 08:30 02/20/14 13:45 1☼Copper 46.5

17.8 10.5 mg/Kg 02/20/14 08:30 02/20/14 13:45 1☼Iron 2750

0.445 0.135 mg/Kg 02/20/14 08:30 02/20/14 13:45 1☼Lead 62.9


1.78 0.110 mg/Kg 02/20/14 08:30 02/20/14 13:45 1☼Nickel 2.51

0.890 0.176 mg/Kg 02/20/14 08:30 02/20/14 13:45 1☼Selenium 0.717 J

0.445 0.0979 mg/Kg 02/20/14 08:30 02/20/14 13:45 1☼Silver 0.0979 U

2.22 0.507 mg/Kg 02/20/14 08:30 02/20/14 13:45 1☼Zinc 78.8


Mercury 0.146 0.108 0.00970 mg/Kg ☼ 02/20/14 10:00 02/20/14 18:53 1





0.10 0.10 % 02/19/14 15:18 1Percent Solids 98 H

Lab Sample ID: 560-45526-11Client Sample ID: A12-D3Matrix: SolidDate Collected: 01/21/14 10:20



Antimony 0.210 U 1.57 0.210 mg/Kg ☼ 02/20/14 08:30 02/20/14 13:49 1


1.57 0.114 mg/Kg 02/20/14 08:30 02/20/14 13:49 1☼Arsenic 10.5

0.787 0.149 mg/Kg 02/20/14 08:30 02/20/14 13:49 1☼Barium 93.9

0.393 0.0283 mg/Kg 02/20/14 08:30 02/20/14 13:49 1☼Cadmium 1.01

0.787 0.105 mg/Kg 02/20/14 08:30 02/20/14 13:49 1☼Chromium 2.89

0.787 0.0220 mg/Kg 02/20/14 08:30 02/20/14 13:49 1☼Cobalt 2.63

1.57 0.158 mg/Kg 02/20/14 08:30 02/20/14 13:49 1☼Copper 19.0

15.7 9.28 mg/Kg 02/20/14 08:30 02/20/14 13:49 1☼Iron 3590

0.393 0.120 mg/Kg 02/20/14 08:30 02/20/14 13:49 1☼Lead 20.3


1.57 0.0975 mg/Kg 02/20/14 08:30 02/20/14 13:49 1☼Nickel 3.76


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Selenium 0.322 J 0.787 0.156 mg/Kg ☼ 02/20/14 08:30 02/20/14 13:49 1


0.393 0.0865 mg/Kg 02/20/14 08:30 02/20/14 13:49 1☼Silver 0.0865 U

1.97 0.448 mg/Kg 02/20/14 08:30 02/20/14 13:49 1☼Zinc 36.1


Mercury 0.0633 J 0.113 0.0101 mg/Kg ☼ 02/20/14 10:00 02/20/14 19:11 1





0.10 0.10 % 02/19/14 14:59 1Percent Solids 98 H




Antimony 0.334 J 1.60 0.213 mg/Kg ☼ 02/20/14 08:30 02/20/14 13:53 1


1.60 0.116 mg/Kg 02/20/14 08:30 02/20/14 13:53 1☼Arsenic 6.13

0.799 0.151 mg/Kg 02/20/14 08:30 02/20/14 13:53 1☼Barium 124

0.399 0.0287 mg/Kg 02/20/14 08:30 02/20/14 13:53 1☼Cadmium 0.289 J

0.799 0.107 mg/Kg 02/20/14 08:30 02/20/14 13:53 1☼Chromium 3.51

0.799 0.0224 mg/Kg 02/20/14 08:30 02/20/14 13:53 1☼Cobalt 2.22

1.60 0.161 mg/Kg 02/20/14 08:30 02/20/14 13:53 1☼Copper 3.99

16.0 9.42 mg/Kg 02/20/14 08:30 02/20/14 13:53 1☼Iron 3470

0.399 0.121 mg/Kg 02/20/14 08:30 02/20/14 13:53 1☼Lead 3.71


1.60 0.0990 mg/Kg 02/20/14 08:30 02/20/14 13:53 1☼Nickel 3.65

0.799 0.158 mg/Kg 02/20/14 08:30 02/20/14 13:53 1☼Selenium 0.460 J

0.399 0.0878 mg/Kg 02/20/14 08:30 02/20/14 13:53 1☼Silver 0.0878 U

2.00 0.455 mg/Kg 02/20/14 08:30 02/20/14 13:53 1☼Zinc 11.6


Mercury 0.0169 J 0.102 0.00919 mg/Kg ☼ 02/20/14 10:00 02/20/14 19:13 1





0.10 0.10 % 02/19/14 14:59 1Percent Solids 96 H




Antimony 0.272 U 2.04 0.272 mg/Kg ☼ 02/20/14 08:30 02/20/14 13:57 1


2.04 0.148 mg/Kg 02/20/14 08:30 02/20/14 13:57 1☼Arsenic 5.03


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Barium 83.2 1.02 0.193 mg/Kg ☼ 02/20/14 08:30 02/20/14 13:57 1


0.510 0.0367 mg/Kg 02/20/14 08:30 02/20/14 13:57 1☼Cadmium 0.711

1.02 0.137 mg/Kg 02/20/14 08:30 02/20/14 13:57 1☼Chromium 2.74

1.02 0.0286 mg/Kg 02/20/14 08:30 02/20/14 13:57 1☼Cobalt 1.91

2.04 0.205 mg/Kg 02/20/14 08:30 02/20/14 13:57 1☼Copper 10.1

20.4 12.0 mg/Kg 02/20/14 08:30 02/20/14 13:57 1☼Iron 3490

0.510 0.155 mg/Kg 02/20/14 08:30 02/20/14 13:57 1☼Lead 11.4


2.04 0.127 mg/Kg 02/20/14 08:30 02/20/14 13:57 1☼Nickel 2.81

1.02 0.202 mg/Kg 02/20/14 08:30 02/20/14 13:57 1☼Selenium 0.273 J

0.510 0.112 mg/Kg 02/20/14 08:30 02/20/14 13:57 1☼Silver 0.112 U

2.55 0.582 mg/Kg 02/20/14 08:30 02/20/14 13:57 1☼Zinc 19.8


Mercury 0.0476 J 0.115 0.0103 mg/Kg ☼ 02/20/14 10:00 02/20/14 19:15 1





0.10 0.10 % 02/19/14 14:59 1Percent Solids 97 H




Antimony 0.260 U 1.95 0.260 mg/Kg ☼ 02/20/14 08:30 02/20/14 14:14 1


1.95 0.141 mg/Kg 02/20/14 08:30 02/20/14 14:14 1☼Arsenic 14.5

0.974 0.184 mg/Kg 02/20/14 08:30 02/20/14 14:14 1☼Barium 140

0.487 0.0351 mg/Kg 02/20/14 08:30 02/20/14 14:14 1☼Cadmium 2.54

0.974 0.131 mg/Kg 02/20/14 08:30 02/20/14 14:14 1☼Chromium 4.39

0.974 0.0273 mg/Kg 02/20/14 08:30 02/20/14 14:14 1☼Cobalt 2.29

1.95 0.196 mg/Kg 02/20/14 08:30 02/20/14 14:14 1☼Copper 67.9

19.5 11.5 mg/Kg 02/20/14 08:30 02/20/14 14:14 1☼Iron 5600

0.487 0.148 mg/Kg 02/20/14 08:30 02/20/14 14:14 1☼Lead 53.5


1.95 0.121 mg/Kg 02/20/14 08:30 02/20/14 14:14 1☼Nickel 2.58

0.974 0.193 mg/Kg 02/20/14 08:30 02/20/14 14:14 1☼Selenium 0.371 J

0.487 0.107 mg/Kg 02/20/14 08:30 02/20/14 14:14 1☼Silver 0.107 U

2.44 0.555 mg/Kg 02/20/14 08:30 02/20/14 14:14 1☼Zinc 60.8


Mercury 0.0826 J 0.118 0.0106 mg/Kg ☼ 02/20/14 10:00 02/20/14 19:18 1





0.10 0.10 % 02/19/14 14:59 1Percent Solids 98 H


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Lab Sample ID: 560-45526-15Client Sample ID: A12-F2Matrix: SolidDate Collected: 01/20/14 10:50



Antimony 0.265 U 1.98 0.265 mg/Kg ☼ 02/20/14 08:30 02/20/14 14:18 1


1.98 0.144 mg/Kg 02/20/14 08:30 02/20/14 14:18 1☼Arsenic 8.16

0.992 0.187 mg/Kg 02/20/14 08:30 02/20/14 14:18 1☼Barium 156

0.496 0.0357 mg/Kg 02/20/14 08:30 02/20/14 14:18 1☼Cadmium 1.00

0.992 0.133 mg/Kg 02/20/14 08:30 02/20/14 14:18 1☼Chromium 3.08

0.992 0.0278 mg/Kg 02/20/14 08:30 02/20/14 14:18 1☼Cobalt 2.39

1.98 0.199 mg/Kg 02/20/14 08:30 02/20/14 14:18 1☼Copper 33.1

19.8 11.7 mg/Kg 02/20/14 08:30 02/20/14 14:18 1☼Iron 3510

0.496 0.151 mg/Kg 02/20/14 08:30 02/20/14 14:18 1☼Lead 25.3


1.98 0.123 mg/Kg 02/20/14 08:30 02/20/14 14:18 1☼Nickel 3.72

0.992 0.196 mg/Kg 02/20/14 08:30 02/20/14 14:18 1☼Selenium 0.364 J

0.496 0.109 mg/Kg 02/20/14 08:30 02/20/14 14:18 1☼Silver 0.109 U

2.48 0.565 mg/Kg 02/20/14 08:30 02/20/14 14:18 1☼Zinc 50.3


Mercury 0.179 0.113 0.0101 mg/Kg ☼ 02/20/14 10:00 02/20/14 19:20 1





0.10 0.10 % 02/19/14 14:59 1Percent Solids 97 H




Antimony 0.292 J 1.75 0.233 mg/Kg ☼ 02/20/14 08:30 02/20/14 14:22 1


1.75 0.127 mg/Kg 02/20/14 08:30 02/20/14 14:22 1☼Arsenic 4.01

0.874 0.165 mg/Kg 02/20/14 08:30 02/20/14 14:22 1☼Barium 91.7

0.437 0.0315 mg/Kg 02/20/14 08:30 02/20/14 14:22 1☼Cadmium 0.537

0.874 0.117 mg/Kg 02/20/14 08:30 02/20/14 14:22 1☼Chromium 2.67

0.874 0.0245 mg/Kg 02/20/14 08:30 02/20/14 14:22 1☼Cobalt 2.27

1.75 0.176 mg/Kg 02/20/14 08:30 02/20/14 14:22 1☼Copper 16.8

17.5 10.3 mg/Kg 02/20/14 08:30 02/20/14 14:22 1☼Iron 3090

0.437 0.133 mg/Kg 02/20/14 08:30 02/20/14 14:22 1☼Lead 9.43


1.75 0.108 mg/Kg 02/20/14 08:30 02/20/14 14:22 1☼Nickel 3.24

0.874 0.173 mg/Kg 02/20/14 08:30 02/20/14 14:22 1☼Selenium 0.501 J

0.437 0.0962 mg/Kg 02/20/14 08:30 02/20/14 14:22 1☼Silver 0.0962 U

2.19 0.498 mg/Kg 02/20/14 08:30 02/20/14 14:22 1☼Zinc 16.7


Mercury 0.0226 J 0.108 0.00969 mg/Kg ☼ 02/20/14 10:00 02/20/14 19:23 1



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0.10 0.10 % 02/19/14 14:59 1Percent Solids 98 H




Antimony 0.306 J 1.78 0.238 mg/Kg ☼ 02/20/14 08:30 02/20/14 14:26 1


1.78 0.129 mg/Kg 02/20/14 08:30 02/20/14 14:26 1☼Arsenic 14.4

0.892 0.169 mg/Kg 02/20/14 08:30 02/20/14 14:26 1☼Barium 221

0.446 0.0321 mg/Kg 02/20/14 08:30 02/20/14 14:26 1☼Cadmium 1.66

0.892 0.120 mg/Kg 02/20/14 08:30 02/20/14 14:26 1☼Chromium 4.72

0.892 0.0250 mg/Kg 02/20/14 08:30 02/20/14 14:26 1☼Cobalt 3.46

1.78 0.179 mg/Kg 02/20/14 08:30 02/20/14 14:26 1☼Copper 36.8

17.8 10.5 mg/Kg 02/20/14 08:30 02/20/14 14:26 1☼Iron 7360

0.446 0.136 mg/Kg 02/20/14 08:30 02/20/14 14:26 1☼Lead 31.6


1.78 0.111 mg/Kg 02/20/14 08:30 02/20/14 14:26 1☼Nickel 5.11

0.892 0.177 mg/Kg 02/20/14 08:30 02/20/14 14:26 1☼Selenium 0.687 J

0.446 0.0982 mg/Kg 02/20/14 08:30 02/20/14 14:26 1☼Silver 0.0982 U

2.23 0.509 mg/Kg 02/20/14 08:30 02/20/14 14:26 1☼Zinc 46.4


Mercury 0.0621 J 0.104 0.00932 mg/Kg ☼ 02/20/14 10:00 02/20/14 19:25 1





0.10 0.10 % 02/19/14 14:59 1Percent Solids 95




Antimony 0.266 U 1.99 0.266 mg/Kg ☼ 02/20/14 08:30 02/20/14 14:30 1


1.99 0.144 mg/Kg 02/20/14 08:30 02/20/14 14:30 1☼Arsenic 8.21

0.996 0.188 mg/Kg 02/20/14 08:30 02/20/14 14:30 1☼Barium 156

0.498 0.0359 mg/Kg 02/20/14 08:30 02/20/14 14:30 1☼Cadmium 1.23

0.996 0.133 mg/Kg 02/20/14 08:30 02/20/14 14:30 1☼Chromium 2.42

0.996 0.0279 mg/Kg 02/20/14 08:30 02/20/14 14:30 1☼Cobalt 2.57

1.99 0.200 mg/Kg 02/20/14 08:30 02/20/14 14:30 1☼Copper 35.4

19.9 11.8 mg/Kg 02/20/14 08:30 02/20/14 14:30 1☼Iron 7190

0.498 0.152 mg/Kg 02/20/14 08:30 02/20/14 14:30 1☼Lead 28.4


1.99 0.124 mg/Kg 02/20/14 08:30 02/20/14 14:30 1☼Nickel 2.59


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Selenium 0.197 U 0.996 0.197 mg/Kg ☼ 02/20/14 08:30 02/20/14 14:30 1


0.498 0.110 mg/Kg 02/20/14 08:30 02/20/14 14:30 1☼Silver 0.110 U

2.49 0.568 mg/Kg 02/20/14 08:30 02/20/14 14:30 1☼Zinc 42.2


Mercury 0.0499 J 0.112 0.0101 mg/Kg ☼ 02/20/14 10:00 02/20/14 19:27 1





0.10 0.10 % 02/19/14 14:59 1Percent Solids 97 H




Antimony 0.311 J 1.71 0.229 mg/Kg ☼ 02/20/14 08:30 02/20/14 14:34 1


1.71 0.124 mg/Kg 02/20/14 08:30 02/20/14 14:34 1☼Arsenic 28.5

0.857 0.162 mg/Kg 02/20/14 08:30 02/20/14 14:34 1☼Barium 105

0.429 0.0309 mg/Kg 02/20/14 08:30 02/20/14 14:34 1☼Cadmium 2.82

0.857 0.115 mg/Kg 02/20/14 08:30 02/20/14 14:34 1☼Chromium 2.04

0.857 0.0240 mg/Kg 02/20/14 08:30 02/20/14 14:34 1☼Cobalt 1.97

1.71 0.172 mg/Kg 02/20/14 08:30 02/20/14 14:34 1☼Copper 50.2

17.1 10.1 mg/Kg 02/20/14 08:30 02/20/14 14:34 1☼Iron 4360

0.429 0.130 mg/Kg 02/20/14 08:30 02/20/14 14:34 1☼Lead 46.7


1.71 0.106 mg/Kg 02/20/14 08:30 02/20/14 14:34 1☼Nickel 2.50

0.857 0.170 mg/Kg 02/20/14 08:30 02/20/14 14:34 1☼Selenium 0.481 J

0.429 0.0943 mg/Kg 02/20/14 08:30 02/20/14 14:34 1☼Silver 0.0943 U

2.14 0.489 mg/Kg 02/20/14 08:30 02/20/14 14:34 1☼Zinc 65.5


Mercury 0.133 0.112 0.0101 mg/Kg ☼ 02/20/14 10:00 02/20/14 19:30 1





0.10 0.10 % 02/19/14 14:59 1Percent Solids 97




Antimony 0.225 U 1.68 0.225 mg/Kg ☼ 02/20/14 08:30 02/20/14 14:38 1


1.68 0.122 mg/Kg 02/20/14 08:30 02/20/14 14:38 1☼Arsenic 5.84


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Barium 38.5 0.841 0.159 mg/Kg ☼ 02/20/14 08:30 02/20/14 14:38 1


0.421 0.0303 mg/Kg 02/20/14 08:30 02/20/14 14:38 1☼Cadmium 1.17

0.841 0.113 mg/Kg 02/20/14 08:30 02/20/14 14:38 1☼Chromium 1.44

0.841 0.0236 mg/Kg 02/20/14 08:30 02/20/14 14:38 1☼Cobalt 1.39

1.68 0.169 mg/Kg 02/20/14 08:30 02/20/14 14:38 1☼Copper 6.03

16.8 9.93 mg/Kg 02/20/14 08:30 02/20/14 14:38 1☼Iron 3140

0.421 0.128 mg/Kg 02/20/14 08:30 02/20/14 14:38 1☼Lead 5.62


1.68 0.104 mg/Kg 02/20/14 08:30 02/20/14 14:38 1☼Nickel 1.81

0.841 0.167 mg/Kg 02/20/14 08:30 02/20/14 14:38 1☼Selenium 0.288 J

0.421 0.0925 mg/Kg 02/20/14 08:30 02/20/14 14:38 1☼Silver 0.0925 U

2.10 0.480 mg/Kg 02/20/14 08:30 02/20/14 14:38 1☼Zinc 12.1


Mercury 0.0102 U 0.113 0.0102 mg/Kg ☼ 02/20/14 10:00 02/20/14 19:32 1





0.10 0.10 % 02/19/14 14:59 1Percent Solids 98 H




Antimony 0.722 J 1.99 0.266 mg/Kg ☼ 02/20/14 10:30 02/21/14 12:23 1


1.99 0.145 mg/Kg 02/20/14 10:30 02/21/14 12:23 1☼Arsenic 17.9

0.997 0.189 mg/Kg 02/20/14 10:30 02/21/14 12:23 1☼Barium 53.2

0.499 0.0359 mg/Kg 02/20/14 10:30 02/21/14 12:23 1☼Cadmium 2.45

0.997 0.134 mg/Kg 02/20/14 10:30 02/21/14 12:23 1☼Chromium 1.79

0.997 0.0279 mg/Kg 02/20/14 10:30 02/21/14 12:23 1☼Cobalt 1.86

1.99 0.200 mg/Kg 02/20/14 10:30 02/21/14 12:23 1☼Copper 51.7

19.9 11.8 mg/Kg 02/20/14 10:30 02/21/14 12:23 1☼Iron 2960

0.499 0.152 mg/Kg 02/20/14 10:30 02/21/14 12:23 1☼Lead 52.2


1.99 0.124 mg/Kg 02/20/14 10:30 02/21/14 12:23 1☼Nickel 2.35

0.997 0.197 mg/Kg 02/20/14 10:30 02/21/14 12:23 1☼Selenium 0.353 J

0.499 0.110 mg/Kg 02/20/14 10:30 02/21/14 12:23 1☼Silver 0.110 U

2.49 0.569 mg/Kg 02/20/14 10:30 02/21/14 12:23 1☼Zinc 88.1


Mercury 0.124 0.101 0.00908 mg/Kg ☼ 02/20/14 10:00 02/20/14 19:44 1





0.10 0.10 % 02/19/14 14:59 1Percent Solids 98


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Lab Sample ID: 560-45526-22Client Sample ID: A12-G3Matrix: SolidDate Collected: 01/21/14 10:55



Antimony 0.614 J 1.85 0.247 mg/Kg ☼ 02/20/14 10:30 02/21/14 12:52 1


1.85 0.134 mg/Kg 02/20/14 10:30 02/21/14 12:52 1☼Arsenic 18.4

0.925 0.175 mg/Kg 02/20/14 10:30 02/21/14 12:52 1☼Barium 145

0.463 0.0333 mg/Kg 02/20/14 10:30 02/21/14 12:52 1☼Cadmium 2.16

0.925 0.124 mg/Kg 02/20/14 10:30 02/21/14 12:52 1☼Chromium 2.89

0.925 0.0259 mg/Kg 02/20/14 10:30 02/21/14 12:52 1☼Cobalt 2.67

1.85 0.186 mg/Kg 02/20/14 10:30 02/21/14 12:52 1☼Copper 99.0

18.5 10.9 mg/Kg 02/20/14 10:30 02/21/14 12:52 1☼Iron 5680

0.463 0.141 mg/Kg 02/20/14 10:30 02/21/14 12:52 1☼Lead 325


1.85 0.115 mg/Kg 02/20/14 10:30 02/21/14 12:52 1☼Nickel 3.72

0.925 0.183 mg/Kg 02/20/14 10:30 02/21/14 12:52 1☼Selenium 0.183 U

0.463 0.102 mg/Kg 02/20/14 10:30 02/21/14 12:52 1☼Silver 0.102 U

2.31 0.527 mg/Kg 02/20/14 10:30 02/21/14 12:52 1☼Zinc 77.3


Mercury 0.228 0.100 0.00902 mg/Kg ☼ 02/20/14 10:00 02/20/14 19:52 1





0.10 0.10 % 02/19/14 15:18 1Percent Solids 97 H




Antimony 0.791 J 1.89 0.252 mg/Kg ☼ 02/20/14 10:30 02/21/14 12:56 1


1.89 0.137 mg/Kg 02/20/14 10:30 02/21/14 12:56 1☼Arsenic 34.8

0.943 0.178 mg/Kg 02/20/14 10:30 02/21/14 12:56 1☼Barium 153

0.472 0.0340 mg/Kg 02/20/14 10:30 02/21/14 12:56 1☼Cadmium 2.78

0.943 0.126 mg/Kg 02/20/14 10:30 02/21/14 12:56 1☼Chromium 3.30

0.943 0.0264 mg/Kg 02/20/14 10:30 02/21/14 12:56 1☼Cobalt 2.81

1.89 0.190 mg/Kg 02/20/14 10:30 02/21/14 12:56 1☼Copper 63.4

18.9 11.1 mg/Kg 02/20/14 10:30 02/21/14 12:56 1☼Iron 5030

0.472 0.143 mg/Kg 02/20/14 10:30 02/21/14 12:56 1☼Lead 60.4


1.89 0.117 mg/Kg 02/20/14 10:30 02/21/14 12:56 1☼Nickel 4.17

0.943 0.187 mg/Kg 02/20/14 10:30 02/21/14 12:56 1☼Selenium 0.563 J

0.472 0.104 mg/Kg 02/20/14 10:30 02/21/14 12:56 1☼Silver 0.104 U

2.36 0.538 mg/Kg 02/20/14 10:30 02/21/14 12:56 1☼Zinc 78.8


Mercury 0.170 0.114 0.0103 mg/Kg ☼ 02/20/14 10:00 02/20/14 19:55 1



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Percent Moisture 15 H 0.10 0.10 % 02/19/14 15:18 1


0.10 0.10 % 02/19/14 15:18 1Percent Solids 85 H




Antimony 0.493 J 1.97 0.263 mg/Kg ☼ 02/20/14 10:30 02/21/14 13:00 1


1.97 0.143 mg/Kg 02/20/14 10:30 02/21/14 13:00 1☼Arsenic 29.4

0.984 0.186 mg/Kg 02/20/14 10:30 02/21/14 13:00 1☼Barium 114

0.492 0.0354 mg/Kg 02/20/14 10:30 02/21/14 13:00 1☼Cadmium 2.68

0.984 0.132 mg/Kg 02/20/14 10:30 02/21/14 13:00 1☼Chromium 2.57

0.984 0.0275 mg/Kg 02/20/14 10:30 02/21/14 13:00 1☼Cobalt 2.21

1.97 0.198 mg/Kg 02/20/14 10:30 02/21/14 13:00 1☼Copper 103

19.7 11.6 mg/Kg 02/20/14 10:30 02/21/14 13:00 1☼Iron 4990

0.492 0.150 mg/Kg 02/20/14 10:30 02/21/14 13:00 1☼Lead 52.8


1.97 0.122 mg/Kg 02/20/14 10:30 02/21/14 13:00 1☼Nickel 3.20

0.984 0.195 mg/Kg 02/20/14 10:30 02/21/14 13:00 1☼Selenium 0.361 J

0.492 0.108 mg/Kg 02/20/14 10:30 02/21/14 13:00 1☼Silver 0.108 U

2.46 0.561 mg/Kg 02/20/14 10:30 02/21/14 13:00 1☼Zinc 69.9


Mercury 0.137 0.104 0.00940 mg/Kg ☼ 02/20/14 10:00 02/20/14 19:57 1





0.10 0.10 % 02/19/14 15:18 1Percent Solids 95




Antimony 0.436 J 1.70 0.226 mg/Kg ☼ 02/20/14 10:30 02/21/14 13:04 1


1.70 0.123 mg/Kg 02/20/14 10:30 02/21/14 13:04 1☼Arsenic 16.5

0.848 0.160 mg/Kg 02/20/14 10:30 02/21/14 13:04 1☼Barium 107

0.424 0.0305 mg/Kg 02/20/14 10:30 02/21/14 13:04 1☼Cadmium 1.52

0.848 0.114 mg/Kg 02/20/14 10:30 02/21/14 13:04 1☼Chromium 3.08

0.848 0.0237 mg/Kg 02/20/14 10:30 02/21/14 13:04 1☼Cobalt 2.16

1.70 0.170 mg/Kg 02/20/14 10:30 02/21/14 13:04 1☼Copper 22.5

17.0 10.0 mg/Kg 02/20/14 10:30 02/21/14 13:04 1☼Iron 4070

0.424 0.129 mg/Kg 02/20/14 10:30 02/21/14 13:04 1☼Lead 31.8


1.70 0.105 mg/Kg 02/20/14 10:30 02/21/14 13:04 1☼Nickel 3.44


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Selenium 0.396 J 0.848 0.168 mg/Kg ☼ 02/20/14 10:30 02/21/14 13:04 1


0.424 0.0932 mg/Kg 02/20/14 10:30 02/21/14 13:04 1☼Silver 0.0932 U

2.12 0.483 mg/Kg 02/20/14 10:30 02/21/14 13:04 1☼Zinc 40.4


Mercury 0.0209 J 0.108 0.00971 mg/Kg ☼ 02/20/14 10:00 02/20/14 20:00 1





0.10 0.10 % 02/19/14 15:18 1Percent Solids 96 H




Antimony 0.235 U 1.76 0.235 mg/Kg ☼ 02/20/14 10:30 02/21/14 13:08 1


1.76 0.128 mg/Kg 02/20/14 10:30 02/21/14 13:08 1☼Arsenic 6.01

0.880 0.166 mg/Kg 02/20/14 10:30 02/21/14 13:08 1☼Barium 73.1

0.440 0.0317 mg/Kg 02/20/14 10:30 02/21/14 13:08 1☼Cadmium 0.472

0.880 0.118 mg/Kg 02/20/14 10:30 02/21/14 13:08 1☼Chromium 1.44

0.880 0.0246 mg/Kg 02/20/14 10:30 02/21/14 13:08 1☼Cobalt 1.32

1.76 0.177 mg/Kg 02/20/14 10:30 02/21/14 13:08 1☼Copper 10.8

17.6 10.4 mg/Kg 02/20/14 10:30 02/21/14 13:08 1☼Iron 2390

0.440 0.134 mg/Kg 02/20/14 10:30 02/21/14 13:08 1☼Lead 11.5


1.76 0.109 mg/Kg 02/20/14 10:30 02/21/14 13:08 1☼Nickel 1.88

0.880 0.174 mg/Kg 02/20/14 10:30 02/21/14 13:08 1☼Selenium 0.174 U

0.440 0.0968 mg/Kg 02/20/14 10:30 02/21/14 13:08 1☼Silver 0.0968 U

2.20 0.502 mg/Kg 02/20/14 10:30 02/21/14 13:08 1☼Zinc 24.3


Mercury 0.104 0.100 0.00904 mg/Kg ☼ 02/20/14 10:00 02/20/14 20:04 1





0.10 0.10 % 02/19/14 15:18 1Percent Solids 98 H




Antimony 1.16 J 1.79 0.239 mg/Kg ☼ 02/20/14 10:30 02/21/14 13:12 1


1.79 0.130 mg/Kg 02/20/14 10:30 02/21/14 13:12 1☼Arsenic 31.8


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Barium 60.2 0.894 0.169 mg/Kg ☼ 02/20/14 10:30 02/21/14 13:12 1


0.447 0.0322 mg/Kg 02/20/14 10:30 02/21/14 13:12 1☼Cadmium 4.18

0.894 0.120 mg/Kg 02/20/14 10:30 02/21/14 13:12 1☼Chromium 1.72

0.894 0.0250 mg/Kg 02/20/14 10:30 02/21/14 13:12 1☼Cobalt 1.80

1.79 0.180 mg/Kg 02/20/14 10:30 02/21/14 13:12 1☼Copper 67.9

17.9 10.5 mg/Kg 02/20/14 10:30 02/21/14 13:12 1☼Iron 2710

0.447 0.136 mg/Kg 02/20/14 10:30 02/21/14 13:12 1☼Lead 82.7


1.79 0.111 mg/Kg 02/20/14 10:30 02/21/14 13:12 1☼Nickel 2.42

0.894 0.177 mg/Kg 02/20/14 10:30 02/21/14 13:12 1☼Selenium 0.853 J

0.447 0.0983 mg/Kg 02/20/14 10:30 02/21/14 13:12 1☼Silver 0.0983 U

2.23 0.509 mg/Kg 02/20/14 10:30 02/21/14 13:12 1☼Zinc 173


Mercury 0.0299 J 0.106 0.00957 mg/Kg ☼ 02/20/14 10:00 02/20/14 20:07 1





0.10 0.10 % 02/19/14 15:18 1Percent Solids 96 H

Lab Sample ID: 560-45526-28Client Sample ID: A12-H4Matrix: SolidDate Collected: 01/21/14 11:30



Antimony 0.557 J 1.91 0.255 mg/Kg ☼ 02/20/14 10:30 02/21/14 13:16 1


1.91 0.138 mg/Kg 02/20/14 10:30 02/21/14 13:16 1☼Arsenic 10.3

0.954 0.180 mg/Kg 02/20/14 10:30 02/21/14 13:16 1☼Barium 173

0.477 0.0344 mg/Kg 02/20/14 10:30 02/21/14 13:16 1☼Cadmium 0.595

0.954 0.128 mg/Kg 02/20/14 10:30 02/21/14 13:16 1☼Chromium 2.55

0.954 0.0267 mg/Kg 02/20/14 10:30 02/21/14 13:16 1☼Cobalt 2.32

1.91 0.192 mg/Kg 02/20/14 10:30 02/21/14 13:16 1☼Copper 27.3

19.1 11.3 mg/Kg 02/20/14 10:30 02/21/14 13:16 1☼Iron 3730

0.477 0.145 mg/Kg 02/20/14 10:30 02/21/14 13:16 1☼Lead 21.8


1.91 0.118 mg/Kg 02/20/14 10:30 02/21/14 13:16 1☼Nickel 3.41

0.954 0.189 mg/Kg 02/20/14 10:30 02/21/14 13:16 1☼Selenium 0.331 J

0.477 0.105 mg/Kg 02/20/14 10:30 02/21/14 13:16 1☼Silver 0.105 U

2.39 0.544 mg/Kg 02/20/14 10:30 02/21/14 13:16 1☼Zinc 41.6


Mercury 0.0262 J 0.113 0.0102 mg/Kg ☼ 02/20/14 10:00 02/20/14 20:09 1





0.10 0.10 % 02/19/14 15:18 1Percent Solids 96 H


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Antimony 0.309 J 1.90 0.253 mg/Kg ☼ 02/20/14 10:30 02/21/14 13:20 1


1.90 0.137 mg/Kg 02/20/14 10:30 02/21/14 13:20 1☼Arsenic 9.81

0.948 0.179 mg/Kg 02/20/14 10:30 02/21/14 13:20 1☼Barium 110

0.474 0.0341 mg/Kg 02/20/14 10:30 02/21/14 13:20 1☼Cadmium 0.712

0.948 0.127 mg/Kg 02/20/14 10:30 02/21/14 13:20 1☼Chromium 1.73

0.948 0.0265 mg/Kg 02/20/14 10:30 02/21/14 13:20 1☼Cobalt 1.74

1.90 0.191 mg/Kg 02/20/14 10:30 02/21/14 13:20 1☼Copper 12.5

19.0 11.2 mg/Kg 02/20/14 10:30 02/21/14 13:20 1☼Iron 3140

0.474 0.144 mg/Kg 02/20/14 10:30 02/21/14 13:20 1☼Lead 23.6


1.90 0.118 mg/Kg 02/20/14 10:30 02/21/14 13:20 1☼Nickel 2.49

0.948 0.188 mg/Kg 02/20/14 10:30 02/21/14 13:20 1☼Selenium 0.239 J

0.474 0.104 mg/Kg 02/20/14 10:30 02/21/14 13:20 1☼Silver 0.104 U

2.37 0.540 mg/Kg 02/20/14 10:30 02/21/14 13:20 1☼Zinc 46.1


Mercury 0.0702 J 0.114 0.0102 mg/Kg ☼ 02/20/14 10:00 02/20/14 20:12 1





0.10 0.10 % 02/19/14 15:18 1Percent Solids 96 H




Antimony 0.231 U 1.73 0.231 mg/Kg ☼ 02/20/14 10:30 02/21/14 13:24 1


1.73 0.125 mg/Kg 02/20/14 10:30 02/21/14 13:24 1☼Arsenic 12.8

0.865 0.163 mg/Kg 02/20/14 10:30 02/21/14 13:24 1☼Barium 51.2

0.432 0.0311 mg/Kg 02/20/14 10:30 02/21/14 13:24 1☼Cadmium 1.02

0.865 0.116 mg/Kg 02/20/14 10:30 02/21/14 13:24 1☼Chromium 1.66

0.865 0.0242 mg/Kg 02/20/14 10:30 02/21/14 13:24 1☼Cobalt 1.41

1.73 0.174 mg/Kg 02/20/14 10:30 02/21/14 13:24 1☼Copper 11.9

17.3 10.2 mg/Kg 02/20/14 10:30 02/21/14 13:24 1☼Iron 4110

0.432 0.132 mg/Kg 02/20/14 10:30 02/21/14 13:24 1☼Lead 17.8


1.73 0.107 mg/Kg 02/20/14 10:30 02/21/14 13:24 1☼Nickel 2.14

0.865 0.171 mg/Kg 02/20/14 10:30 02/21/14 13:24 1☼Selenium 0.240 J

0.432 0.0951 mg/Kg 02/20/14 10:30 02/21/14 13:24 1☼Silver 0.0951 U

2.16 0.493 mg/Kg 02/20/14 10:30 02/21/14 13:24 1☼Zinc 22.6


Mercury 0.00984 U 0.109 0.00984 mg/Kg ☼ 02/20/14 10:00 02/20/14 20:14 1



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0.10 0.10 % 02/19/14 15:18 1Percent Solids 98 H




Antimony 0.348 J 1.95 0.261 mg/Kg ☼ 02/20/14 10:30 02/21/14 13:41 1


1.95 0.142 mg/Kg 02/20/14 10:30 02/21/14 13:41 1☼Arsenic 11.6

0.976 0.185 mg/Kg 02/20/14 10:30 02/21/14 13:41 1☼Barium 131

0.488 0.0351 mg/Kg 02/20/14 10:30 02/21/14 13:41 1☼Cadmium 0.863

0.976 0.131 mg/Kg 02/20/14 10:30 02/21/14 13:41 1☼Chromium 2.76

0.976 0.0273 mg/Kg 02/20/14 10:30 02/21/14 13:41 1☼Cobalt 2.21

1.95 0.196 mg/Kg 02/20/14 10:30 02/21/14 13:41 1☼Copper 19.5

19.5 11.5 mg/Kg 02/20/14 10:30 02/21/14 13:41 1☼Iron 4460

0.488 0.149 mg/Kg 02/20/14 10:30 02/21/14 13:41 1☼Lead 21.8


1.95 0.121 mg/Kg 02/20/14 10:30 02/21/14 13:41 1☼Nickel 3.34

0.976 0.193 mg/Kg 02/20/14 10:30 02/21/14 13:41 1☼Selenium 0.251 J

0.488 0.107 mg/Kg 02/20/14 10:30 02/21/14 13:41 1☼Silver 0.107 U

2.44 0.557 mg/Kg 02/20/14 10:30 02/21/14 13:41 1☼Zinc 41.2


Mercury 0.0317 J 0.105 0.00947 mg/Kg ☼ 02/21/14 09:30 02/21/14 14:29 1





0.10 0.10 % 02/19/14 15:18 1Percent Solids 97 H




Antimony 0.206 U 1.55 0.206 mg/Kg ☼ 02/20/14 10:30 02/21/14 13:45 1


1.55 0.112 mg/Kg 02/20/14 10:30 02/21/14 13:45 1☼Arsenic 3.64

0.773 0.146 mg/Kg 02/20/14 10:30 02/21/14 13:45 1☼Barium 33.5

0.386 0.0278 mg/Kg 02/20/14 10:30 02/21/14 13:45 1☼Cadmium 0.411

0.773 0.104 mg/Kg 02/20/14 10:30 02/21/14 13:45 1☼Chromium 1.56

0.773 0.0216 mg/Kg 02/20/14 10:30 02/21/14 13:45 1☼Cobalt 1.35

1.55 0.155 mg/Kg 02/20/14 10:30 02/21/14 13:45 1☼Copper 7.83

15.5 9.12 mg/Kg 02/20/14 10:30 02/21/14 13:45 1☼Iron 2740

0.386 0.118 mg/Kg 02/20/14 10:30 02/21/14 13:45 1☼Lead 7.23


1.55 0.0958 mg/Kg 02/20/14 10:30 02/21/14 13:45 1☼Nickel 2.04


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Selenium 0.270 J 0.773 0.153 mg/Kg ☼ 02/20/14 10:30 02/21/14 13:45 1


0.386 0.0850 mg/Kg 02/20/14 10:30 02/21/14 13:45 1☼Silver 0.0850 U

1.93 0.440 mg/Kg 02/20/14 10:30 02/21/14 13:45 1☼Zinc 16.1


Mercury 0.0105 U 0.117 0.0105 mg/Kg ☼ 02/21/14 09:30 02/21/14 14:38 1





0.10 0.10 % 02/19/14 15:18 1Percent Solids 95 H

Lab Sample ID: 560-45526-33Client Sample ID: A12-I5Matrix: SolidDate Collected: 01/29/14 11:35



Antimony 0.235 U 1.76 0.235 mg/Kg ☼ 02/20/14 10:30 02/21/14 13:49 1


1.76 0.128 mg/Kg 02/20/14 10:30 02/21/14 13:49 1☼Arsenic 7.66

0.880 0.166 mg/Kg 02/20/14 10:30 02/21/14 13:49 1☼Barium 73.2

0.440 0.0317 mg/Kg 02/20/14 10:30 02/21/14 13:49 1☼Cadmium 0.566

0.880 0.118 mg/Kg 02/20/14 10:30 02/21/14 13:49 1☼Chromium 1.93

0.880 0.0246 mg/Kg 02/20/14 10:30 02/21/14 13:49 1☼Cobalt 1.75

1.76 0.177 mg/Kg 02/20/14 10:30 02/21/14 13:49 1☼Copper 21.5

17.6 10.4 mg/Kg 02/20/14 10:30 02/21/14 13:49 1☼Iron 3010

0.440 0.134 mg/Kg 02/20/14 10:30 02/21/14 13:49 1☼Lead 21.4


1.76 0.109 mg/Kg 02/20/14 10:30 02/21/14 13:49 1☼Nickel 2.62

0.880 0.174 mg/Kg 02/20/14 10:30 02/21/14 13:49 1☼Selenium 0.425 J

0.440 0.0968 mg/Kg 02/20/14 10:30 02/21/14 13:49 1☼Silver 0.0968 U

2.20 0.501 mg/Kg 02/20/14 10:30 02/21/14 13:49 1☼Zinc 27.6


Mercury 0.0177 J 0.106 0.00958 mg/Kg ☼ 02/21/14 09:30 02/21/14 14:40 1





0.10 0.10 % 02/19/14 15:18 1Percent Solids 98 H




Antimony 0.244 U 1.83 0.244 mg/Kg ☼ 02/20/14 10:30 02/21/14 13:53 1


1.83 0.133 mg/Kg 02/20/14 10:30 02/21/14 13:53 1☼Arsenic 5.01


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Barium 85.7 0.914 0.173 mg/Kg ☼ 02/20/14 10:30 02/21/14 13:53 1


0.457 0.0329 mg/Kg 02/20/14 10:30 02/21/14 13:53 1☼Cadmium 0.425 J

0.914 0.123 mg/Kg 02/20/14 10:30 02/21/14 13:53 1☼Chromium 2.51

0.914 0.0256 mg/Kg 02/20/14 10:30 02/21/14 13:53 1☼Cobalt 1.93

1.83 0.184 mg/Kg 02/20/14 10:30 02/21/14 13:53 1☼Copper 11.3

18.3 10.8 mg/Kg 02/20/14 10:30 02/21/14 13:53 1☼Iron 3510

0.457 0.139 mg/Kg 02/20/14 10:30 02/21/14 13:53 1☼Lead 13.9


1.83 0.113 mg/Kg 02/20/14 10:30 02/21/14 13:53 1☼Nickel 2.94

0.914 0.181 mg/Kg 02/20/14 10:30 02/21/14 13:53 1☼Selenium 0.301 J

0.457 0.101 mg/Kg 02/20/14 10:30 02/21/14 13:53 1☼Silver 0.101 U

2.29 0.521 mg/Kg 02/20/14 10:30 02/21/14 13:53 1☼Zinc 18.8


Mercury 0.0104 U 0.116 0.0104 mg/Kg ☼ 02/21/14 09:30 02/21/14 14:42 1





0.10 0.10 % 02/19/14 15:18 1Percent Solids 98 H




Antimony 0.250 U 1.88 0.250 mg/Kg ☼ 02/20/14 10:30 02/21/14 13:57 1


1.88 0.136 mg/Kg 02/20/14 10:30 02/21/14 13:57 1☼Arsenic 8.17

0.938 0.177 mg/Kg 02/20/14 10:30 02/21/14 13:57 1☼Barium 96.6

0.469 0.0338 mg/Kg 02/20/14 10:30 02/21/14 13:57 1☼Cadmium 0.671

0.938 0.126 mg/Kg 02/20/14 10:30 02/21/14 13:57 1☼Chromium 4.51

0.938 0.0263 mg/Kg 02/20/14 10:30 02/21/14 13:57 1☼Cobalt 3.20

1.88 0.189 mg/Kg 02/20/14 10:30 02/21/14 13:57 1☼Copper 10.1

18.8 11.1 mg/Kg 02/20/14 10:30 02/21/14 13:57 1☼Iron 5740

0.469 0.143 mg/Kg 02/20/14 10:30 02/21/14 13:57 1☼Lead 15.3


1.88 0.116 mg/Kg 02/20/14 10:30 02/21/14 13:57 1☼Nickel 5.69

0.938 0.186 mg/Kg 02/20/14 10:30 02/21/14 13:57 1☼Selenium 0.311 J

0.469 0.103 mg/Kg 02/20/14 10:30 02/21/14 13:57 1☼Silver 0.103 U

2.34 0.535 mg/Kg 02/20/14 10:30 02/21/14 13:57 1☼Zinc 26.8


Mercury 0.0313 J 0.117 0.0105 mg/Kg ☼ 02/21/14 09:30 02/21/14 14:45 1





0.10 0.10 % 02/19/14 15:18 1Percent Solids 97 H


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Antimony 0.240 U 1.80 0.240 mg/Kg ☼ 02/20/14 10:30 02/21/14 14:01 1


1.80 0.130 mg/Kg 02/20/14 10:30 02/21/14 14:01 1☼Arsenic 4.07

0.899 0.170 mg/Kg 02/20/14 10:30 02/21/14 14:01 1☼Barium 140

0.449 0.0324 mg/Kg 02/20/14 10:30 02/21/14 14:01 1☼Cadmium 0.399 J

0.899 0.120 mg/Kg 02/20/14 10:30 02/21/14 14:01 1☼Chromium 4.47

0.899 0.0252 mg/Kg 02/20/14 10:30 02/21/14 14:01 1☼Cobalt 3.13

1.80 0.181 mg/Kg 02/20/14 10:30 02/21/14 14:01 1☼Copper 5.77

18.0 10.6 mg/Kg 02/20/14 10:30 02/21/14 14:01 1☼Iron 5350

0.449 0.137 mg/Kg 02/20/14 10:30 02/21/14 14:01 1☼Lead 7.19


1.80 0.111 mg/Kg 02/20/14 10:30 02/21/14 14:01 1☼Nickel 5.21

0.899 0.178 mg/Kg 02/20/14 10:30 02/21/14 14:01 1☼Selenium 0.276 J

0.449 0.0988 mg/Kg 02/20/14 10:30 02/21/14 14:01 1☼Silver 0.0988 U

2.25 0.512 mg/Kg 02/20/14 10:30 02/21/14 14:01 1☼Zinc 18.6


Mercury 0.0112 J 0.105 0.00946 mg/Kg ☼ 02/21/14 09:30 02/21/14 14:47 1





0.10 0.10 % 02/19/14 15:18 1Percent Solids 97 H




Antimony 0.259 U 1.94 0.259 mg/Kg ☼ 02/20/14 10:30 02/21/14 14:05 1


1.94 0.141 mg/Kg 02/20/14 10:30 02/21/14 14:05 1☼Arsenic 5.54

0.970 0.183 mg/Kg 02/20/14 10:30 02/21/14 14:05 1☼Barium 216

0.485 0.0349 mg/Kg 02/20/14 10:30 02/21/14 14:05 1☼Cadmium 0.495

0.970 0.130 mg/Kg 02/20/14 10:30 02/21/14 14:05 1☼Chromium 5.02

0.970 0.0272 mg/Kg 02/20/14 10:30 02/21/14 14:05 1☼Cobalt 3.22

1.94 0.195 mg/Kg 02/20/14 10:30 02/21/14 14:05 1☼Copper 6.90

19.4 11.5 mg/Kg 02/20/14 10:30 02/21/14 14:05 1☼Iron 5960

0.485 0.148 mg/Kg 02/20/14 10:30 02/21/14 14:05 1☼Lead 8.23


1.94 0.120 mg/Kg 02/20/14 10:30 02/21/14 14:05 1☼Nickel 5.41

0.970 0.192 mg/Kg 02/20/14 10:30 02/21/14 14:05 1☼Selenium 0.254 J

0.485 0.107 mg/Kg 02/20/14 10:30 02/21/14 14:05 1☼Silver 0.107 U

2.43 0.553 mg/Kg 02/20/14 10:30 02/21/14 14:05 1☼Zinc 22.2


Mercury 0.0103 U 0.114 0.0103 mg/Kg ☼ 02/21/14 09:30 02/21/14 14:50 1



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0.10 0.10 % 02/19/14 15:18 1Percent Solids 96

Lab Sample ID: 560-45526-38Client Sample ID: A12-J6Matrix: SolidDate Collected: 01/29/14 13:20



Antimony 0.333 J 1.86 0.249 mg/Kg ☼ 02/20/14 10:30 02/21/14 14:09 1


1.86 0.135 mg/Kg 02/20/14 10:30 02/21/14 14:09 1☼Arsenic 6.22

0.932 0.176 mg/Kg 02/20/14 10:30 02/21/14 14:09 1☼Barium 104

0.466 0.0336 mg/Kg 02/20/14 10:30 02/21/14 14:09 1☼Cadmium 0.353 J

0.932 0.125 mg/Kg 02/20/14 10:30 02/21/14 14:09 1☼Chromium 4.20

0.932 0.0261 mg/Kg 02/20/14 10:30 02/21/14 14:09 1☼Cobalt 2.93

1.86 0.187 mg/Kg 02/20/14 10:30 02/21/14 14:09 1☼Copper 9.63

18.6 11.0 mg/Kg 02/20/14 10:30 02/21/14 14:09 1☼Iron 5080

0.466 0.142 mg/Kg 02/20/14 10:30 02/21/14 14:09 1☼Lead 9.74


1.86 0.116 mg/Kg 02/20/14 10:30 02/21/14 14:09 1☼Nickel 5.28

0.932 0.185 mg/Kg 02/20/14 10:30 02/21/14 14:09 1☼Selenium 0.402 J

0.466 0.103 mg/Kg 02/20/14 10:30 02/21/14 14:09 1☼Silver 0.103 U

2.33 0.531 mg/Kg 02/20/14 10:30 02/21/14 14:09 1☼Zinc 20.4


Mercury 0.0105 U 0.117 0.0105 mg/Kg ☼ 02/21/14 09:30 02/21/14 14:52 1





0.10 0.10 % 02/19/14 15:35 1Percent Solids 97




Antimony 0.358 J 2.03 0.271 mg/Kg ☼ 02/20/14 10:30 02/21/14 14:14 1


2.03 0.147 mg/Kg 02/20/14 10:30 02/21/14 14:14 1☼Arsenic 17.6

1.01 0.192 mg/Kg 02/20/14 10:30 02/21/14 14:14 1☼Barium 138

0.507 0.0365 mg/Kg 02/20/14 10:30 02/21/14 14:14 1☼Cadmium 0.625

1.01 0.136 mg/Kg 02/20/14 10:30 02/21/14 14:14 1☼Chromium 4.58

1.01 0.0284 mg/Kg 02/20/14 10:30 02/21/14 14:14 1☼Cobalt 3.32

2.03 0.204 mg/Kg 02/20/14 10:30 02/21/14 14:14 1☼Copper 8.38

20.3 12.0 mg/Kg 02/20/14 10:30 02/21/14 14:14 1☼Iron 5710

0.507 0.154 mg/Kg 02/20/14 10:30 02/21/14 14:14 1☼Lead 12.8


2.03 0.126 mg/Kg 02/20/14 10:30 02/21/14 14:14 1☼Nickel 6.01


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Selenium 0.368 J 1.01 0.201 mg/Kg ☼ 02/20/14 10:30 02/21/14 14:14 1


0.507 0.112 mg/Kg 02/20/14 10:30 02/21/14 14:14 1☼Silver 0.112 U

2.54 0.579 mg/Kg 02/20/14 10:30 02/21/14 14:14 1☼Zinc 28.5


Mercury 0.0513 J 0.118 0.0107 mg/Kg ☼ 02/21/14 09:30 02/21/14 14:55 1





0.10 0.10 % 02/19/14 15:35 1Percent Solids 96 H




Antimony 0.371 J 1.62 0.216 mg/Kg ☼ 02/20/14 10:30 02/21/14 14:18 1


1.62 0.118 mg/Kg 02/20/14 10:30 02/21/14 14:18 1☼Arsenic 23.4

0.811 0.153 mg/Kg 02/20/14 10:30 02/21/14 14:18 1☼Barium 111

0.405 0.0292 mg/Kg 02/20/14 10:30 02/21/14 14:18 1☼Cadmium 1.85

0.811 0.109 mg/Kg 02/20/14 10:30 02/21/14 14:18 1☼Chromium 4.75

0.811 0.0227 mg/Kg 02/20/14 10:30 02/21/14 14:18 1☼Cobalt 3.47

1.62 0.163 mg/Kg 02/20/14 10:30 02/21/14 14:18 1☼Copper 16.3

16.2 9.57 mg/Kg 02/20/14 10:30 02/21/14 14:18 1☼Iron 6400

0.405 0.123 mg/Kg 02/20/14 10:30 02/21/14 14:18 1☼Lead 33.7


1.62 0.101 mg/Kg 02/20/14 10:30 02/21/14 14:18 1☼Nickel 6.49

0.811 0.161 mg/Kg 02/20/14 10:30 02/21/14 14:18 1☼Selenium 0.303 J

0.405 0.0892 mg/Kg 02/20/14 10:30 02/21/14 14:18 1☼Silver 0.0892 U

2.03 0.462 mg/Kg 02/20/14 10:30 02/21/14 14:18 1☼Zinc 51.2


Mercury 0.201 0.110 0.00991 mg/Kg ☼ 02/21/14 09:30 02/21/14 14:57 1





0.10 0.10 % 02/19/14 15:18 1Percent Solids 96 H




Antimony 0.235 U 1.76 0.235 mg/Kg ☼ 02/28/14 11:00 03/03/14 16:59 1


1.76 0.127 mg/Kg 02/28/14 11:00 03/03/14 16:59 1☼Arsenic 2.75


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Barium 159 0.878 0.166 mg/Kg ☼ 02/28/14 11:00 03/03/14 16:59 1


0.439 0.0316 mg/Kg 02/28/14 11:00 03/03/14 16:59 1☼Cadmium 0.375 J

0.878 0.118 mg/Kg 02/28/14 11:00 03/03/14 16:59 1☼Chromium 5.59

0.878 0.0246 mg/Kg 02/28/14 11:00 03/03/14 16:59 1☼Cobalt 3.57

1.76 0.177 mg/Kg 02/28/14 11:00 03/03/14 16:59 1☼Copper 5.23

17.6 10.4 mg/Kg 02/28/14 11:00 03/03/14 16:59 1☼Iron 7060

0.439 0.134 mg/Kg 02/28/14 11:00 03/03/14 16:59 1☼Lead 5.58


1.76 0.109 mg/Kg 02/28/14 11:00 03/03/14 16:59 1☼Nickel 6.37

0.878 0.174 mg/Kg 02/28/14 11:00 03/03/14 16:59 1☼Selenium 0.174 U

0.439 0.0966 mg/Kg 02/28/14 11:00 03/03/14 16:59 1☼Silver 0.0966 U

2.20 0.501 mg/Kg 02/28/14 11:00 03/03/14 16:59 1☼Zinc 20.6


Mercury 0.00957 U 0.106 0.00957 mg/Kg ☼ 02/21/14 09:30 02/21/14 15:04 1





0.10 0.10 % 02/19/14 15:18 1Percent Solids 96 H




Antimony 0.735 J 2.08 0.278 mg/Kg ☼ 02/28/14 11:00 03/03/14 17:28 1


2.08 0.151 mg/Kg 02/28/14 11:00 03/03/14 17:28 1☼Arsenic 11.3

1.04 0.197 mg/Kg 02/28/14 11:00 03/03/14 17:28 1☼Barium 190

0.521 0.0375 mg/Kg 02/28/14 11:00 03/03/14 17:28 1☼Cadmium 1.07

1.04 0.140 mg/Kg 02/28/14 11:00 03/03/14 17:28 1☼Chromium 5.38

1.04 0.0292 mg/Kg 02/28/14 11:00 03/03/14 17:28 1☼Cobalt 3.52

2.08 0.209 mg/Kg 02/28/14 11:00 03/03/14 17:28 1☼Copper 32.8

20.8 12.3 mg/Kg 02/28/14 11:00 03/03/14 17:28 1☼Iron 6320

0.521 0.159 mg/Kg 02/28/14 11:00 03/03/14 17:28 1☼Lead 34.2


2.08 0.129 mg/Kg 02/28/14 11:00 03/03/14 17:28 1☼Nickel 6.24

1.04 0.206 mg/Kg 02/28/14 11:00 03/03/14 17:28 1☼Selenium 0.620 J

0.521 0.115 mg/Kg 02/28/14 11:00 03/03/14 17:28 1☼Silver 0.115 U

2.61 0.594 mg/Kg 02/28/14 11:00 03/03/14 17:28 1☼Zinc 54.6


Mercury 0.0247 J 0.120 0.0108 mg/Kg ☼ 02/21/14 09:30 02/21/14 15:07 1





0.10 0.10 % 02/19/14 15:18 1Percent Solids 94 H


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Lab Sample ID: 560-45526-43Client Sample ID: A12-K7Matrix: SolidDate Collected: 01/16/14 10:05



Antimony 0.380 J 1.92 0.257 mg/Kg ☼ 02/28/14 11:00 03/03/14 17:32 1


1.92 0.139 mg/Kg 02/28/14 11:00 03/03/14 17:32 1☼Arsenic 6.01

0.962 0.182 mg/Kg 02/28/14 11:00 03/03/14 17:32 1☼Barium 124

0.481 0.0346 mg/Kg 02/28/14 11:00 03/03/14 17:32 1☼Cadmium 0.539

0.962 0.129 mg/Kg 02/28/14 11:00 03/03/14 17:32 1☼Chromium 5.16

0.962 0.0269 mg/Kg 02/28/14 11:00 03/03/14 17:32 1☼Cobalt 3.34

1.92 0.193 mg/Kg 02/28/14 11:00 03/03/14 17:32 1☼Copper 8.69

19.2 11.3 mg/Kg 02/28/14 11:00 03/03/14 17:32 1☼Iron 6120

0.481 0.146 mg/Kg 02/28/14 11:00 03/03/14 17:32 1☼Lead 9.22


1.92 0.119 mg/Kg 02/28/14 11:00 03/03/14 17:32 1☼Nickel 6.10

0.962 0.190 mg/Kg 02/28/14 11:00 03/03/14 17:32 1☼Selenium 0.260 J

0.481 0.106 mg/Kg 02/28/14 11:00 03/03/14 17:32 1☼Silver 0.106 U

2.40 0.548 mg/Kg 02/28/14 11:00 03/03/14 17:32 1☼Zinc 25.3


Mercury 0.0163 J 0.114 0.0103 mg/Kg ☼ 02/21/14 09:30 02/21/14 15:09 1





0.10 0.10 % 02/19/14 15:35 1Percent Solids 95 H




Antimony 0.240 U 1.80 0.240 mg/Kg ☼ 02/28/14 11:00 03/03/14 17:36 1


1.80 0.130 mg/Kg 02/28/14 11:00 03/03/14 17:36 1☼Arsenic 3.91

0.898 0.170 mg/Kg 02/28/14 11:00 03/03/14 17:36 1☼Barium 90.7

0.449 0.0323 mg/Kg 02/28/14 11:00 03/03/14 17:36 1☼Cadmium 0.439 J

0.898 0.120 mg/Kg 02/28/14 11:00 03/03/14 17:36 1☼Chromium 5.22

0.898 0.0251 mg/Kg 02/28/14 11:00 03/03/14 17:36 1☼Cobalt 3.49

1.80 0.180 mg/Kg 02/28/14 11:00 03/03/14 17:36 1☼Copper 6.48

18.0 10.6 mg/Kg 02/28/14 11:00 03/03/14 17:36 1☼Iron 6920

0.449 0.137 mg/Kg 02/28/14 11:00 03/03/14 17:36 1☼Lead 7.56


1.80 0.111 mg/Kg 02/28/14 11:00 03/03/14 17:36 1☼Nickel 6.13

0.898 0.178 mg/Kg 02/28/14 11:00 03/03/14 17:36 1☼Selenium 0.391 J

0.449 0.0988 mg/Kg 02/28/14 11:00 03/03/14 17:36 1☼Silver 0.0988 U

2.24 0.512 mg/Kg 02/28/14 11:00 03/03/14 17:36 1☼Zinc 24.4


Mercury 0.476 0.231 0.0208 mg/Kg ☼ 02/21/14 09:30 02/21/14 15:39 2



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0.10 0.10 % 02/19/14 15:35 1Percent Solids 96 H




Antimony 0.447 J 2.11 0.282 mg/Kg ☼ 02/28/14 11:00 03/03/14 17:40 1


2.11 0.153 mg/Kg 02/28/14 11:00 03/03/14 17:40 1☼Arsenic 11.2

1.06 0.200 mg/Kg 02/28/14 11:00 03/03/14 17:40 1☼Barium 308

0.528 0.0380 mg/Kg 02/28/14 11:00 03/03/14 17:40 1☼Cadmium 0.537

1.06 0.141 mg/Kg 02/28/14 11:00 03/03/14 17:40 1☼Chromium 5.58

1.06 0.0296 mg/Kg 02/28/14 11:00 03/03/14 17:40 1☼Cobalt 3.75

2.11 0.212 mg/Kg 02/28/14 11:00 03/03/14 17:40 1☼Copper 12.8

21.1 12.5 mg/Kg 02/28/14 11:00 03/03/14 17:40 1☼Iron 6830

0.528 0.161 mg/Kg 02/28/14 11:00 03/03/14 17:40 1☼Lead 11.6


2.11 0.131 mg/Kg 02/28/14 11:00 03/03/14 17:40 1☼Nickel 6.63

1.06 0.209 mg/Kg 02/28/14 11:00 03/03/14 17:40 1☼Selenium 0.292 J

0.528 0.116 mg/Kg 02/28/14 11:00 03/03/14 17:40 1☼Silver 0.116 U

2.64 0.602 mg/Kg 02/28/14 11:00 03/03/14 17:40 1☼Zinc 30.4


Mercury 0.0101 U 0.112 0.0101 mg/Kg ☼ 02/21/14 09:30 02/21/14 15:15 1





0.10 0.10 % 02/19/14 15:35 1Percent Solids 93 H




Antimony 0.928 J 2.07 0.277 mg/Kg ☼ 02/28/14 11:00 03/03/14 17:44 1


2.07 0.150 mg/Kg 02/28/14 11:00 03/03/14 17:44 1☼Arsenic 22.3

1.04 0.196 mg/Kg 02/28/14 11:00 03/03/14 17:44 1☼Barium 182

0.518 0.0373 mg/Kg 02/28/14 11:00 03/03/14 17:44 1☼Cadmium 2.41

1.04 0.139 mg/Kg 02/28/14 11:00 03/03/14 17:44 1☼Chromium 5.55

1.04 0.0290 mg/Kg 02/28/14 11:00 03/03/14 17:44 1☼Cobalt 3.70

2.07 0.208 mg/Kg 02/28/14 11:00 03/03/14 17:44 1☼Copper 83.5

20.7 12.2 mg/Kg 02/28/14 11:00 03/03/14 17:44 1☼Iron 6210

0.518 0.158 mg/Kg 02/28/14 11:00 03/03/14 17:44 1☼Lead 83.6


2.07 0.128 mg/Kg 02/28/14 11:00 03/03/14 17:44 1☼Nickel 6.22


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Selenium 0.676 J 1.04 0.205 mg/Kg ☼ 02/28/14 11:00 03/03/14 17:44 1


0.518 0.114 mg/Kg 02/28/14 11:00 03/03/14 17:44 1☼Silver 0.114 U

2.59 0.591 mg/Kg 02/28/14 11:00 03/03/14 17:44 1☼Zinc 116


Mercury 0.0890 J 0.110 0.00991 mg/Kg ☼ 02/21/14 09:30 02/21/14 15:17 1





0.10 0.10 % 02/19/14 15:35 1Percent Solids 96 H


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QC Sample ResultsTestAmerica Job ID: 560-45526-1Client: Malcolm Pirnie, Inc. Invoice to Arcadis


Method: 6010B - Metals (ICP)

Client Sample ID: Method BlankLab Sample ID: MB 560-98720/1-A

Matrix: Solid Prep Type: Total/NA

Analysis Batch: 98743 Prep Batch: 98720

MQL (Adj) SDL

Antimony 0.267 U 2.00 0.267 mg/Kg 02/20/14 08:30 02/20/14 12:35 1

MB MB

Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier

0.145 U 0.1452.00 mg/Kg 02/20/14 08:30 02/20/14 12:35 1Arsenic

0.189 U 0.1891.00 mg/Kg 02/20/14 08:30 02/20/14 12:35 1Barium

0.0360 U 0.03600.500 mg/Kg 02/20/14 08:30 02/20/14 12:35 1Cadmium

0.134 U 0.1341.00 mg/Kg 02/20/14 08:30 02/20/14 12:35 1Chromium

0.0280 U 0.02801.00 mg/Kg 02/20/14 08:30 02/20/14 12:35 1Cobalt

0.201 U 0.2012.00 mg/Kg 02/20/14 08:30 02/20/14 12:35 1Copper

11.8 U 11.820.0 mg/Kg 02/20/14 08:30 02/20/14 12:35 1Iron

0.152 U 0.1520.500 mg/Kg 02/20/14 08:30 02/20/14 12:35 1Lead

0.125 U 0.1252.00 mg/Kg 02/20/14 08:30 02/20/14 12:35 1Molybdenum

0.124 U 0.1242.00 mg/Kg 02/20/14 08:30 02/20/14 12:35 1Nickel

0.2475 J 0.1981.00 mg/Kg 02/20/14 08:30 02/20/14 12:35 1Selenium

0.110 U 0.1100.500 mg/Kg 02/20/14 08:30 02/20/14 12:35 1Silver

0.570 U 0.5702.50 mg/Kg 02/20/14 08:30 02/20/14 12:35 1Zinc

Client Sample ID: Lab Control SampleLab Sample ID: LCS 560-98720/2-A



Antimony 25.0 23.65 mg/Kg 95 80 - 120

Analyte

LCS LCS

DUnitResult Qualifier %Rec

Spike

Added

%Rec.

Limits

Arsenic 25.0 23.44 mg/Kg 94 80 - 120

Barium 25.0 24.67 mg/Kg 99 80 - 120

Cadmium 25.0 25.55 mg/Kg 102 80 - 120

Chromium 25.0 24.08 mg/Kg 96 80 - 120

Cobalt 25.0 24.32 mg/Kg 97 80 - 120

Copper 25.0 23.33 mg/Kg 93 80 - 120

Iron 2500 2531 mg/Kg 101 80 - 120

Lead 25.0 24.14 mg/Kg 97 80 - 120

Molybdenum 25.0 23.85 mg/Kg 95 80 - 120

Nickel 25.0 24.36 mg/Kg 97 80 - 120

Selenium 25.0 22.37 mg/Kg 89 80 - 120

Silver 25.0 24.10 mg/Kg 96 80 - 120

Zinc 25.0 26.30 mg/Kg 105 80 - 120

Client Sample ID: A12-A5Lab Sample ID: 560-45526-1 MS



Antimony 0.232 U 19.3 10.26 N mg/Kg 53 75 - 125☼

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits

Arsenic 4.96 19.3 22.32 mg/Kg 90 75 - 125☼

Barium 61.7 19.3 79.30 mg/Kg 91 75 - 125☼

Cadmium 0.902 19.3 19.58 mg/Kg 97 75 - 125☼

Chromium 2.07 19.3 19.36 mg/Kg 90 75 - 125☼

Cobalt 1.67 19.3 18.52 mg/Kg 87 75 - 125☼

Copper 22.3 19.3 38.21 mg/Kg 83 75 - 125☼

Iron 3120 1930 5397 mg/Kg 118 75 - 125☼


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Method: 6010B - Metals (ICP) (Continued)




Lead 20.4 19.3 36.26 mg/Kg 82 75 - 125☼

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits

Molybdenum 0.396 J 19.3 15.72 mg/Kg 80 75 - 125☼

Nickel 2.49 19.3 19.52 mg/Kg 88 75 - 125☼

Selenium 0.241 J 19.3 16.03 mg/Kg 82 75 - 125☼

Silver 0.0957 U 19.3 17.09 mg/Kg 89 75 - 125☼

Zinc 30.8 19.3 45.66 mg/Kg 77 75 - 125☼

Client Sample ID: A12-A5Lab Sample ID: 560-45526-1 MSD



Antimony 0.232 U 20.0 10.38 N mg/Kg 52 75 - 125 1 20☼

Analyte

MSD MSD


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits LimitRPD

RPD

Arsenic 4.96 20.0 22.51 mg/Kg 88 75 - 125 1 20☼

Barium 61.7 20.0 83.74 mg/Kg 110 75 - 125 5 20☼

Cadmium 0.902 20.0 20.05 mg/Kg 96 75 - 125 2 20☼

Chromium 2.07 20.0 20.01 mg/Kg 90 75 - 125 3 20☼

Cobalt 1.67 20.0 19.02 mg/Kg 87 75 - 125 3 20☼

Copper 22.3 20.0 39.39 mg/Kg 85 75 - 125 3 20☼

Iron 3120 2000 5434 mg/Kg 115 75 - 125 1 20☼

Lead 20.4 20.0 36.93 mg/Kg 82 75 - 125 2 20☼

Molybdenum 0.396 J 20.0 16.18 mg/Kg 79 75 - 125 3 20☼

Nickel 2.49 20.0 20.06 mg/Kg 88 75 - 125 3 20☼

Selenium 0.241 J 20.0 16.26 mg/Kg 80 75 - 125 1 20☼

Silver 0.0957 U 20.0 18.04 mg/Kg 90 75 - 125 5 20☼

Zinc 30.8 20.0 48.17 mg/Kg 87 75 - 125 5 20☼




MQL (Adj) SDL

Antimony 0.267 U 2.00 0.267 mg/Kg 02/20/14 10:30 02/21/14 12:15 1

MB MB


0.1530 J 0.1452.00 mg/Kg 02/20/14 10:30 02/21/14 12:15 1Arsenic

0.189 U 0.1891.00 mg/Kg 02/20/14 10:30 02/21/14 12:15 1Barium

0.0360 U 0.03600.500 mg/Kg 02/20/14 10:30 02/21/14 12:15 1Cadmium

0.2995 J 0.1341.00 mg/Kg 02/20/14 10:30 02/21/14 12:15 1Chromium

0.0280 U 0.02801.00 mg/Kg 02/20/14 10:30 02/21/14 12:15 1Cobalt

0.201 U 0.2012.00 mg/Kg 02/20/14 10:30 02/21/14 12:15 1Copper

11.8 U 11.820.0 mg/Kg 02/20/14 10:30 02/21/14 12:15 1Iron

0.152 U 0.1520.500 mg/Kg 02/20/14 10:30 02/21/14 12:15 1Lead


0.124 U 0.1242.00 mg/Kg 02/20/14 10:30 02/21/14 12:15 1Nickel

0.2545 J 0.1981.00 mg/Kg 02/20/14 10:30 02/21/14 12:15 1Selenium

0.110 U 0.1100.500 mg/Kg 02/20/14 10:30 02/21/14 12:15 1Silver

0.570 U 0.5702.50 mg/Kg 02/20/14 10:30 02/21/14 12:15 1Zinc


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Antimony 25.0 24.12 mg/Kg 96 80 - 120

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Arsenic 25.0 24.05 mg/Kg 96 80 - 120

Barium 25.0 24.68 mg/Kg 99 80 - 120

Cadmium 25.0 24.71 mg/Kg 99 80 - 120

Chromium 25.0 25.21 mg/Kg 101 80 - 120

Cobalt 25.0 24.56 mg/Kg 98 80 - 120

Copper 25.0 24.69 mg/Kg 99 80 - 120

Iron 2500 2527 mg/Kg 101 80 - 120

Lead 25.0 24.78 mg/Kg 99 80 - 120

Molybdenum 25.0 24.56 mg/Kg 98 80 - 120

Nickel 25.0 24.64 mg/Kg 99 80 - 120

Selenium 25.0 23.46 mg/Kg 94 80 - 120

Silver 25.0 25.36 mg/Kg 101 80 - 120

Zinc 25.0 26.04 mg/Kg 104 80 - 120

Client Sample ID: A12-F8Lab Sample ID: 560-45526-21 MS



Antimony 0.722 J 22.5 15.58 N mg/Kg 66 75 - 125☼

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits

Arsenic 17.9 22.5 38.64 mg/Kg 92 75 - 125☼

Barium 53.2 22.5 74.32 mg/Kg 94 75 - 125☼

Cadmium 2.45 22.5 23.52 mg/Kg 94 75 - 125☼

Chromium 1.79 22.5 21.83 mg/Kg 89 75 - 125☼

Cobalt 1.86 22.5 21.07 mg/Kg 85 75 - 125☼

Copper 51.7 22.5 80.31 N mg/Kg 127 75 - 125☼

Iron 2960 2250 5155 mg/Kg 98 75 - 125☼

Lead 52.2 22.5 73.26 mg/Kg 93 75 - 125☼

Molybdenum 1.14 J 22.5 20.35 mg/Kg 85 75 - 125☼

Nickel 2.35 22.5 21.82 mg/Kg 87 75 - 125☼

Selenium 0.353 J 22.5 19.17 mg/Kg 84 75 - 125☼

Silver 0.110 U 22.5 21.73 mg/Kg 97 75 - 125☼

Zinc 88.1 22.5 110.6 mg/Kg 100 75 - 125☼

Client Sample ID: A12-F8Lab Sample ID: 560-45526-21 MSD



Antimony 0.722 J 24.9 18.16 N mg/Kg 70 75 - 125 15 20☼

Analyte

MSD MSD


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits LimitRPD

RPD

Arsenic 17.9 24.9 41.81 mg/Kg 96 75 - 125 8 20☼

Barium 53.2 24.9 78.34 mg/Kg 101 75 - 125 5 20☼

Cadmium 2.45 24.9 25.37 mg/Kg 92 75 - 125 8 20☼

Chromium 1.79 24.9 24.46 mg/Kg 91 75 - 125 11 20☼

Cobalt 1.86 24.9 23.80 mg/Kg 88 75 - 125 12 20☼

Copper 51.7 24.9 74.16 mg/Kg 90 75 - 125 8 20☼

Iron 2960 2490 5620 mg/Kg 107 75 - 125 9 20☼


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Lead 52.2 24.9 88.01 N mg/Kg 143 75 - 125 18 20☼

Analyte

MSD MSD


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits LimitRPD

RPD

Molybdenum 1.14 J 24.9 23.02 mg/Kg 88 75 - 125 12 20☼

Nickel 2.35 24.9 24.43 mg/Kg 89 75 - 125 11 20☼

Selenium 0.353 J 24.9 21.80 mg/Kg 86 75 - 125 13 20☼

Silver 0.110 U 24.9 23.59 mg/Kg 95 75 - 125 8 20☼

Zinc 88.1 24.9 124.9 N mg/Kg 148 75 - 125 12 20☼




MQL (Adj) SDL

Antimony 0.267 U 2.00 0.267 mg/Kg 02/28/14 11:00 03/03/14 16:51 1

MB MB


0.145 U 0.1452.00 mg/Kg 02/28/14 11:00 03/03/14 16:51 1Arsenic

0.189 U 0.1891.00 mg/Kg 02/28/14 11:00 03/03/14 16:51 1Barium

0.0360 U 0.03600.500 mg/Kg 02/28/14 11:00 03/03/14 16:51 1Cadmium

0.134 U 0.1341.00 mg/Kg 02/28/14 11:00 03/03/14 16:51 1Chromium

0.0280 U 0.02801.00 mg/Kg 02/28/14 11:00 03/03/14 16:51 1Cobalt

0.201 U 0.2012.00 mg/Kg 02/28/14 11:00 03/03/14 16:51 1Copper

11.8 U 11.820.0 mg/Kg 02/28/14 11:00 03/03/14 16:51 1Iron

0.152 U 0.1520.500 mg/Kg 02/28/14 11:00 03/03/14 16:51 1Lead


0.124 U 0.1242.00 mg/Kg 02/28/14 11:00 03/03/14 16:51 1Nickel

0.198 U 0.1981.00 mg/Kg 02/28/14 11:00 03/03/14 16:51 1Selenium

0.110 U 0.1100.500 mg/Kg 02/28/14 11:00 03/03/14 16:51 1Silver

0.570 U 0.5702.50 mg/Kg 02/28/14 11:00 03/03/14 16:51 1Zinc




Antimony 25.0 24.43 mg/Kg 98 80 - 120

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Arsenic 25.0 24.39 mg/Kg 98 80 - 120

Barium 25.0 24.41 mg/Kg 98 80 - 120

Cadmium 25.0 24.57 mg/Kg 98 80 - 120

Chromium 25.0 24.85 mg/Kg 99 80 - 120

Cobalt 25.0 24.21 mg/Kg 97 80 - 120

Copper 25.0 23.21 mg/Kg 93 80 - 120

Iron 2500 2562 mg/Kg 102 80 - 120

Lead 25.0 24.25 mg/Kg 97 80 - 120

Molybdenum 25.0 24.79 mg/Kg 99 80 - 120

Nickel 25.0 24.32 mg/Kg 97 80 - 120

Selenium 25.0 22.77 mg/Kg 91 80 - 120

Silver 25.0 24.36 mg/Kg 97 80 - 120

Zinc 25.0 25.19 mg/Kg 101 80 - 120


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Client Sample ID: A12-J9Lab Sample ID: 560-45526-41 MS



Antimony 0.235 U 23.3 7.686 N mg/Kg 33 75 - 125☼

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits

Arsenic 2.75 23.3 20.01 N mg/Kg 74 75 - 125☼

Barium 159 23.3 169.2 4 mg/Kg 43 75 - 125☼

Cadmium 0.375 J 23.3 18.94 mg/Kg 80 75 - 125☼

Chromium 5.59 23.3 23.71 mg/Kg 78 75 - 125☼

Cobalt 3.57 23.3 20.45 N mg/Kg 72 75 - 125☼

Copper 5.23 23.3 21.85 N mg/Kg 71 75 - 125☼

Iron 7060 2330 9052 mg/Kg 85 75 - 125☼

Lead 5.58 23.3 22.06 N mg/Kg 71 75 - 125☼

Molybdenum 0.269 J 23.3 16.22 N mg/Kg 68 75 - 125☼

Nickel 6.37 23.3 23.22 N mg/Kg 72 75 - 125☼

Selenium 0.174 U 23.3 15.69 N mg/Kg 67 75 - 125☼

Silver 0.0966 U 23.3 20.46 mg/Kg 88 75 - 125☼

Zinc 20.6 23.3 36.44 N mg/Kg 68 75 - 125☼

Client Sample ID: A12-J9Lab Sample ID: 560-45526-41 MSD



Antimony 0.235 U 24.4 9.026 N mg/Kg 37 75 - 125 16 20☼

Analyte

MSD MSD


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits LimitRPD

RPD

Arsenic 2.75 24.4 22.09 mg/Kg 79 75 - 125 10 20☼

Barium 159 24.4 164.5 4 mg/Kg 22 75 - 125 3 20☼

Cadmium 0.375 J 24.4 21.09 mg/Kg 85 75 - 125 11 20☼

Chromium 5.59 24.4 25.76 mg/Kg 83 75 - 125 8 20☼

Cobalt 3.57 24.4 22.36 mg/Kg 77 75 - 125 9 20☼

Copper 5.23 24.4 23.99 mg/Kg 77 75 - 125 9 20☼

Iron 7060 2440 9615 mg/Kg 105 75 - 125 6 20☼

Lead 5.58 24.4 24.25 mg/Kg 76 75 - 125 9 20☼

Molybdenum 0.269 J 24.4 17.48 N mg/Kg 70 75 - 125 7 20☼

Nickel 6.37 24.4 25.33 mg/Kg 78 75 - 125 9 20☼

Selenium 0.174 U 24.4 17.30 N mg/Kg 71 75 - 125 10 20☼

Silver 0.0966 U 24.4 19.54 mg/Kg 80 75 - 125 5 20☼

Zinc 20.6 24.4 39.78 mg/Kg 79 75 - 125 9 20☼

Method: 7471A - Mercury (CVAA)




MQL (Adj) SDL

Mercury 0.01820 J 0.120 0.0108 mg/Kg 02/20/14 10:00 02/20/14 19:34 1

MB MB



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Method: 7471A - Mercury (CVAA) (Continued)




MQL (Adj) SDL

Mercury 0.01885 J 0.120 0.0108 mg/Kg 02/20/14 10:00 02/20/14 18:07 1

MB MB





Mercury 0.250 0.2965 mg/Kg 119 80 - 120

Analyte

LCS LCS


Spike

Added

%Rec.

Limits




Mercury 0.250 0.2735 mg/Kg 109 80 - 120

Analyte

LCS LCS


Spike

Added

%Rec.

Limits




Mercury 0.0312 J 0.221 0.3090 N mg/Kg 126 75 - 125☼

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits

Client Sample ID: A12-A5Lab Sample ID: 560-45526-1 MSD



Mercury 0.0312 J 0.219 0.2958 mg/Kg 121 75 - 125 4 30☼

Analyte

MSD MSD


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits LimitRPD

RPD

Client Sample ID: A12-F8Lab Sample ID: 560-45526-21 MS



Mercury 0.124 0.236 0.4065 mg/Kg 120 75 - 125☼

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits




Mercury 0.124 0.231 0.3880 mg/Kg 114 75 - 125 5 30☼

Analyte

MSD MSD


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits LimitRPD

RPD




MQL (Adj) SDL

Mercury 0.0108 U 0.120 0.0108 mg/Kg 02/21/14 09:30 02/21/14 14:25 1

MB MB



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Mercury 0.250 0.2635 mg/Kg 105 80 - 120

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Client Sample ID: A12-H7Lab Sample ID: 560-45526-31 MS



Mercury 0.0317 J 0.216 0.2911 mg/Kg 120 75 - 125☼

Analyte

MS MS


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits

Client Sample ID: A12-H7Lab Sample ID: 560-45526-31 MSD



Mercury 0.0317 J 0.214 0.2673 mg/Kg 110 75 - 125 9 30☼

Analyte

MSD MSD


Spike

Added

Sample

Result

Sample

Qualifier

%Rec.

Limits LimitRPD

RPD

Method: Moisture - Percent Moisture

Client Sample ID: A12-D3Lab Sample ID: 560-45526-11 DU


Analysis Batch: 98678

Percent Moisture 2.2 H 2.3 % 6 40

Analyte

DU DU

DUnitResult Qualifier

Sample

Result

Sample

Qualifier LimitRPD

RPD

Percent Solids 98 H 98 % 0.1 40

Client Sample ID: A12-I6Lab Sample ID: 560-45526-34 DU



Percent Moisture 2.3 H 2.3 % 0.5 40

Analyte

DU DU


Sample

Result

Sample

Qualifier LimitRPD

RPD


Client Sample ID: A12-K7Lab Sample ID: 560-45526-43 DU



Percent Moisture 5.5 H 5.6 % 3 40

Analyte

DU DU


Sample

Result

Sample

Qualifier LimitRPD

RPD



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QC Association SummaryTestAmerica Job ID: 560-45526-1Client: Malcolm Pirnie, Inc. Invoice to Arcadis


Metals

Prep Batch: 98720

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

Solid 3050B560-45526-1 A12-A5 Total/NA

Solid 3050B560-45526-1 MS A12-A5 Total/NA

Solid 3050B560-45526-1 MSD A12-A5 Total/NA



Solid 3050B560-45526-4 A12-B5 Total/NA



Solid 3050B560-45526-7 A12-C4 Total/NA




Solid 3050B560-45526-11 A12-D3 Total/NA




Solid 3050B560-45526-15 A12-F2 Total/NA






Solid 3050BLCS 560-98720/2-A Lab Control Sample Total/NA

Solid 3050BMB 560-98720/1-A Method Blank Total/NA

Prep Batch: 98722



Solid 3050B560-45526-21 MS A12-F8 Total/NA

Solid 3050B560-45526-21 MSD A12-F8 Total/NA

Solid 3050B560-45526-22 A12-G3 Total/NA






Solid 3050B560-45526-28 A12-H4 Total/NA





Solid 3050B560-45526-33 A12-I5 Total/NA





Solid 3050B560-45526-38 A12-J6 Total/NA






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Metals (Continued)



Solid 6010B 98720560-45526-1 A12-A5 Total/NA

Solid 6010B 98720560-45526-1 MS A12-A5 Total/NA

Solid 6010B 98720560-45526-1 MSD A12-A5 Total/NA



Solid 6010B 98720560-45526-4 A12-B5 Total/NA



Solid 6010B 98720560-45526-7 A12-C4 Total/NA




Solid 6010B 98720560-45526-11 A12-D3 Total/NA




Solid 6010B 98720560-45526-15 A12-F2 Total/NA






Solid 6010B 98720LCS 560-98720/2-A Lab Control Sample Total/NA

Solid 6010B 98720MB 560-98720/1-A Method Blank Total/NA



Solid 7471A 98764560-45526-1 A12-A5 Total/NA

Solid 7471A 98764560-45526-1 MS A12-A5 Total/NA

Solid 7471A 98764560-45526-1 MSD A12-A5 Total/NA



Solid 7471A 98764560-45526-4 A12-B5 Total/NA



Solid 7471A 98764560-45526-7 A12-C4 Total/NA




Solid 7471A 98764560-45526-11 A12-D3 Total/NA




Solid 7471A 98764560-45526-15 A12-F2 Total/NA







Solid 7471A 98764560-45526-21 MS A12-F8 Total/NA


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Metals (Continued)

Analysis Batch: 98751 (Continued)


Solid 7471A 98764560-45526-21 MSD A12-F8 Total/NA

Solid 7471A 98764560-45526-22 A12-G3 Total/NA






Solid 7471A 98764560-45526-28 A12-H4 Total/NA



Solid 7471A 98764LCS 560-98764/29-A Lab Control Sample Total/NA


Solid 7471A 98764MB 560-98764/28-A Method Blank Total/NA


Prep Batch: 98764


Solid 7471A560-45526-1 A12-A5 Total/NA

Solid 7471A560-45526-1 MS A12-A5 Total/NA

Solid 7471A560-45526-1 MSD A12-A5 Total/NA



Solid 7471A560-45526-4 A12-B5 Total/NA



Solid 7471A560-45526-7 A12-C4 Total/NA




Solid 7471A560-45526-11 A12-D3 Total/NA




Solid 7471A560-45526-15 A12-F2 Total/NA







Solid 7471A560-45526-21 MS A12-F8 Total/NA

Solid 7471A560-45526-21 MSD A12-F8 Total/NA

Solid 7471A560-45526-22 A12-G3 Total/NA






Solid 7471A560-45526-28 A12-H4 Total/NA




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Metals (Continued)

Prep Batch: 98764 (Continued)


Solid 7471ALCS 560-98764/29-A Lab Control Sample Total/NA


Solid 7471AMB 560-98764/28-A Method Blank Total/NA





Solid 7471A 98798560-45526-31 MS A12-H7 Total/NA

Solid 7471A 98798560-45526-31 MSD A12-H7 Total/NA


Solid 7471A 98798560-45526-33 A12-I5 Total/NA





Solid 7471A 98798560-45526-38 A12-J6 Total/NA





Solid 7471A 98798560-45526-43 A12-K7 Total/NA






Prep Batch: 98798



Solid 7471A560-45526-31 MS A12-H7 Total/NA

Solid 7471A560-45526-31 MSD A12-H7 Total/NA


Solid 7471A560-45526-33 A12-I5 Total/NA





Solid 7471A560-45526-38 A12-J6 Total/NA





Solid 7471A560-45526-43 A12-K7 Total/NA







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Metals (Continued)




Solid 6010B 98722560-45526-21 MS A12-F8 Total/NA

Solid 6010B 98722560-45526-21 MSD A12-F8 Total/NA

Solid 6010B 98722560-45526-22 A12-G3 Total/NA






Solid 6010B 98722560-45526-28 A12-H4 Total/NA





Solid 6010B 98722560-45526-33 A12-I5 Total/NA





Solid 6010B 98722560-45526-38 A12-J6 Total/NA





Prep Batch: 99032



Solid 3050B560-45526-41 MS A12-J9 Total/NA

Solid 3050B560-45526-41 MSD A12-J9 Total/NA


Solid 3050B560-45526-43 A12-K7 Total/NA









Solid 6010B 99032560-45526-41 MS A12-J9 Total/NA

Solid 6010B 99032560-45526-41 MSD A12-J9 Total/NA


Solid 6010B 99032560-45526-43 A12-K7 Total/NA







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General Chemistry



Solid Moisture560-45526-1 A12-A5 Total/NA



Solid Moisture560-45526-4 A12-B5 Total/NA



Solid Moisture560-45526-7 A12-C4 Total/NA



Solid Moisture560-45526-11 A12-D3 Total/NA

Solid Moisture560-45526-11 DU A12-D3 Total/NA




Solid Moisture560-45526-15 A12-F2 Total/NA










Solid Moisture560-45526-22 A12-G3 Total/NA






Solid Moisture560-45526-28 A12-H4 Total/NA





Solid Moisture560-45526-33 A12-I5 Total/NA


Solid Moisture560-45526-34 DU A12-I6 Total/NA




Solid Moisture560-45526-40 A12-J8 Total/NA







Solid Moisture560-45526-43 A12-K7 Total/NA


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General Chemistry (Continued)

Analysis Batch: 98684 (Continued)


Solid Moisture560-45526-43 DU A12-K7 Total/NA





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Lab ChronicleClient: Malcolm Pirnie, Inc. Invoice to Arcadis TestAmerica Job ID: 560-45526-1


Client Sample ID: A12-A5 Lab Sample ID: 560-45526-1Matrix: SolidDate Collected: 01/29/14 13:10


Prep 3050B 02/20/14 08:30 RLM98720 TAL CC

Type

Batch Batch

MethodPrep Type LabAnalystRun

Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA

Analysis 6010B 1 98743 02/20/14 12:44 EDR TAL CCTotal/NA

Prep 7471A 98764 02/20/14 10:00 JEM TAL CCTotal/NA

Analysis 7471A 1 98751 02/20/14 18:25 JEM TAL CCTotal/NA

Analysis Moisture 1 98678 02/19/14 14:59 DRB TAL CCTotal/NA



Prep 3050B 02/20/14 08:30 RLM98720 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA







Prep 3050B 02/20/14 08:30 RLM98720 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA





Client Sample ID: A12-B5 Lab Sample ID: 560-45526-4Matrix: SolidDate Collected: 01/14/14 08:25


Prep 3050B 02/20/14 08:30 RLM98720 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA






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Prep 3050B 02/20/14 08:30 RLM98720 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA







Prep 3050B 02/20/14 08:30 RLM98720 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA





Client Sample ID: A12-C4 Lab Sample ID: 560-45526-7Matrix: SolidDate Collected: 01/14/14 08:10


Prep 3050B 02/20/14 08:30 RLM98720 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA







Prep 3050B 02/20/14 08:30 RLM98720 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA






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Prep 3050B 02/20/14 08:30 RLM98720 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA







Prep 3050B 02/20/14 08:30 RLM98720 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA





Client Sample ID: A12-D3 Lab Sample ID: 560-45526-11Matrix: SolidDate Collected: 01/21/14 10:20


Prep 3050B 02/20/14 08:30 RLM98720 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA







Prep 3050B 02/20/14 08:30 RLM98720 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA






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Prep 3050B 02/20/14 08:30 RLM98720 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA







Prep 3050B 02/20/14 08:30 RLM98720 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA





Client Sample ID: A12-F2 Lab Sample ID: 560-45526-15Matrix: SolidDate Collected: 01/20/14 10:50


Prep 3050B 02/20/14 08:30 RLM98720 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA







Prep 3050B 02/20/14 08:30 RLM98720 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA






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Prep 3050B 02/20/14 08:30 RLM98720 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA







Prep 3050B 02/20/14 08:30 RLM98720 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA







Prep 3050B 02/20/14 08:30 RLM98720 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA







Prep 3050B 02/20/14 08:30 RLM98720 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA






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Prep 3050B 02/20/14 10:30 RLM98722 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA





Client Sample ID: A12-G3 Lab Sample ID: 560-45526-22Matrix: SolidDate Collected: 01/21/14 10:55


Prep 3050B 02/20/14 10:30 RLM98722 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA







Prep 3050B 02/20/14 10:30 RLM98722 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA







Prep 3050B 02/20/14 10:30 RLM98722 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA






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Prep 3050B 02/20/14 10:30 RLM98722 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA







Prep 3050B 02/20/14 10:30 RLM98722 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA







Prep 3050B 02/20/14 10:30 RLM98722 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA





Client Sample ID: A12-H4 Lab Sample ID: 560-45526-28Matrix: SolidDate Collected: 01/21/14 11:30


Prep 3050B 02/20/14 10:30 RLM98722 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA






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Prep 3050B 02/20/14 10:30 RLM98722 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA







Prep 3050B 02/20/14 10:30 RLM98722 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA







Prep 3050B 02/20/14 10:30 RLM98722 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA







Prep 3050B 02/20/14 10:30 RLM98722 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA






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Client Sample ID: A12-I5 Lab Sample ID: 560-45526-33Matrix: SolidDate Collected: 01/29/14 11:35


Prep 3050B 02/20/14 10:30 RLM98722 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA







Prep 3050B 02/20/14 10:30 RLM98722 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA







Prep 3050B 02/20/14 10:30 RLM98722 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA







Prep 3050B 02/20/14 10:30 RLM98722 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA






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Prep 3050B 02/20/14 10:30 RLM98722 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA





Client Sample ID: A12-J6 Lab Sample ID: 560-45526-38Matrix: SolidDate Collected: 01/29/14 13:20


Prep 3050B 02/20/14 10:30 RLM98722 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA







Prep 3050B 02/20/14 10:30 RLM98722 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA







Prep 3050B 02/20/14 10:30 RLM98722 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA






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Prep 3050B 02/28/14 11:00 RLM99032 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA







Prep 3050B 02/28/14 11:00 RLM99032 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA





Client Sample ID: A12-K7 Lab Sample ID: 560-45526-43Matrix: SolidDate Collected: 01/16/14 10:05


Prep 3050B 02/28/14 11:00 RLM99032 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA







Prep 3050B 02/28/14 11:00 RLM99032 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA






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Prep 3050B 02/28/14 11:00 RLM99032 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA







Prep 3050B 02/28/14 11:00 RLM99032 TAL CC

Type

Batch Batch


Prepared

or Analyzed

Batch

Number

Dilution

Factor

Total/NA





Laboratory References:

TAL CC = TestAmerica Corpus Christi, 1733 N. Padre Island Drive, Corpus Christi, TX 78408, TEL (361)289-2673


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Certification SummaryClient: Malcolm Pirnie, Inc. Invoice to Arcadis TestAmerica Job ID: 560-45526-1


Laboratory: TestAmerica Corpus ChristiAll certifications held by this laboratory are listed. Not all certifications are applicable to this report.

Authority Program EPA Region Certification ID Expiration Date

Kansas E-103627NELAP 10-31-14

Oklahoma State Program 6 9968 08-31-14

Texas NELAP 6 T104704210 03-31-15


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Method SummaryTestAmerica Job ID: 560-45526-1Client: Malcolm Pirnie, Inc. Invoice to Arcadis


Method Method Description LaboratoryProtocol

SW8466010B Metals (ICP) TAL CC

SW8467471A Mercury (CVAA) TAL CC

EPAMoisture Percent Moisture TAL CC

Protocol References:

EPA = US Environmental Protection Agency

SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.

Laboratory References:

TAL CC = TestAmerica Corpus Christi, 1733 N. Padre Island Drive, Corpus Christi, TX 78408, TEL (361)289-2673


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Sample SummaryTestAmerica Job ID: 560-45526-1Client: Malcolm Pirnie, Inc. Invoice to Arcadis


Lab Sample ID Client Sample ID ReceivedCollectedMatrix

560-45526-1 A12-A5 Solid 01/29/14 13:10 02/18/14 09:30

560-45526-2 A12-A6 Solid 01/21/14 10:45 02/18/14 09:30

560-45526-3 A12-A7 Solid 01/21/14 10:25 02/18/14 09:30

560-45526-4 A12-B5 Solid 01/14/14 08:25 02/18/14 09:30

560-45526-5 A12-B6 Solid 01/21/14 10:35 02/18/14 09:30

560-45526-6 A12-B7 Solid 01/21/14 10:30 02/18/14 09:30

560-45526-7 A12-C4 Solid 01/14/14 08:10 02/18/14 09:30

560-45526-8 A12-C5 Solid 01/21/14 10:40 02/18/14 09:30

560-45526-9 A12-C6 Solid 01/14/14 08:15 02/18/14 09:30

560-45526-10 A12-C7 Solid 01/14/14 08:20 02/18/14 09:30

560-45526-11 A12-D3 Solid 01/21/14 10:20 02/18/14 09:30

560-45526-12 A12-D4 Solid 01/21/14 11:25 02/18/14 09:30

560-45526-13 A12-D5 Solid 01/21/14 11:15 02/18/14 09:30

560-45526-14 A12-D6 Solid 01/14/14 08:14 02/18/14 09:30

560-45526-15 A12-F2 Solid 01/20/14 10:50 02/18/14 09:30

560-45526-16 A12-F3 Solid 01/14/14 08:30 02/18/14 09:30

560-45526-17 A12-F4 Solid 01/14/14 08:35 02/18/14 09:30

560-45526-18 A12-F5 Solid 01/21/14 11:10 02/18/14 09:30

560-45526-19 A12-F6 Solid 01/21/14 11:05 02/18/14 09:30

560-45526-20 A12-F7 Solid 01/16/14 09:30 02/18/14 09:30

560-45526-21 A12-F8 Solid 01/29/14 13:15 02/18/14 09:30

560-45526-22 A12-G3 Solid 01/21/14 10:55 02/18/14 09:30

560-45526-23 A12-G4 Solid 01/21/14 11:55 02/18/14 09:30

560-45526-24 A12-G5 Solid 01/21/14 11:50 02/18/14 09:30

560-45526-25 A12-G6 Solid 01/16/14 09:55 02/18/14 09:30

560-45526-26 A12-G7 Solid 01/17/14 08:35 02/18/14 09:30

560-45526-27 A12-G8 Solid 01/16/14 09:50 02/18/14 09:30

560-45526-28 A12-H4 Solid 01/21/14 11:30 02/18/14 09:30

560-45526-29 A12-H5 Solid 01/21/14 11:40 02/18/14 09:30

560-45526-30 A12-H6 Solid 01/16/14 09:40 02/18/14 09:30

560-45526-31 A12-H7 Solid 01/21/14 09:45 02/18/14 09:30

560-45526-32 A12-H8 Solid 01/21/14 09:35 02/18/14 09:30

560-45526-33 A12-I5 Solid 01/29/14 11:35 02/18/14 09:30

560-45526-34 A12-I6 Solid 01/16/14 10:20 02/18/14 09:30

560-45526-35 A12-I7 Solid 01/21/14 12:10 02/18/14 09:30

560-45526-36 A12-I8 Solid 01/29/14 12:05 02/18/14 09:30

560-45526-37 A12-I9 Solid 01/29/14 13:25 02/18/14 09:30

560-45526-38 A12-J6 Solid 01/29/14 13:20 02/18/14 09:30

560-45526-39 A12-J7 Solid 01/21/14 12:00 02/18/14 09:30

560-45526-40 A12-J8 Solid 01/16/14 10:00 02/18/14 09:30

560-45526-41 A12-J9 Solid 01/21/14 10:10 02/18/14 09:30

560-45526-42 A12-J10 Solid 01/16/14 10:15 02/18/14 09:30

560-45526-43 A12-K7 Solid 01/16/14 10:05 02/18/14 09:30

560-45526-44 A12-K8 Solid 01/17/14 08:40 02/18/14 09:30

560-45526-45 A12-K9 Solid 01/17/14 08:50 02/18/14 09:30

560-45526-46 A12-K10 Solid 01/17/14 08:45 02/18/14 09:30


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Login Sample Receipt Checklist

Client: Malcolm Pirnie, Inc. Invoice to Arcadis Job Number: 560-45526-1

Login Number: 45526

Question Answer Comment

Creator: Rood, Vivian R

List Source: TestAmerica Corpus Christi

List Number: 1

N/ARadioactivity wasn't checked or is </= background as measured by a survey

meter.

TrueThe cooler's custody seal, if present, is intact.

TrueSample custody seals, if present, are intact.

TrueThe cooler or samples do not appear to have been compromised or

tampered with.

TrueSamples were received on ice.

TrueCooler Temperature is acceptable.

TrueCooler Temperature is recorded.

TrueCOC is present.

TrueCOC is filled out in ink and legible.

FalseCOC is filled out with all pertinent information. No sample date and/or time on COC, logged in

per container labels.

TrueIs the Field Sampler's name present on COC?

TrueThere are no discrepancies between the containers received and the COC.

TrueSamples are received within Holding Time.

TrueSample containers have legible labels.

TrueContainers are not broken or leaking.

TrueSample collection date/times are provided. No date or time on COC, logged in per container

labels.

TrueAppropriate sample containers are used.

TrueSample bottles are completely filled.

TrueSample Preservation Verified.

TrueThere is sufficient vol. for all requested analyses, incl. any requested

MS/MSDs

N/AContainers requiring zero headspace have no headspace or bubble is

<6mm (1/4").

TrueMultiphasic samples are not present.

TrueSamples do not require splitting or compositing.

N/AResidual Chlorine Checked.

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Unadjusted Detection LimitsClient: Malcolm Pirnie, Inc. Invoice to Arcadis TestAmerica Job ID: 560-45526-1


Method: 6010B - Metals (ICP)

2.00Antimony mg/Kg

Analyte Units MethodMDLMQL

0.267 6010B

2.00Arsenic mg/Kg0.145 6010B

1.00Barium mg/Kg0.189 6010B

0.500Cadmium mg/Kg0.0360 6010B

1.00Chromium mg/Kg0.134 6010B

1.00Cobalt mg/Kg0.0280 6010B

2.00Copper mg/Kg0.201 6010B

20.0Iron mg/Kg11.8 6010B

0.500Lead mg/Kg0.152 6010B

2.00Molybdenum mg/Kg0.125 6010B

2.00Nickel mg/Kg0.124 6010B

1.00Selenium mg/Kg0.198 6010B

0.500Silver mg/Kg0.110 6010B

2.50Zinc mg/Kg0.570 6010B

Method: 7471A - Mercury (CVAA)

0.200Mercury mg/Kg


0.0180 7471A

General Chemistry

0.10Percent Moisture %


0.10 Moisture

0.10Percent Solids %0.10 Moisture


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