off-site disaster management plan...(like fire, explosion, gas leak) or may prolong for days (fire,...

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PREFACE

Management of risk due to industrial operations is one of the most complex issues facing the society today. In recent times accidents are becoming the focus of greater attention because of their increasing frequency and their huge impact on organization as well as the society. The risk from the industrial operation not only remain confirmed to the boundaries of the industrial premises, but have potential for impact on the areas well outside their perimeter. Transportation of hazardous material from the industry to various destinations by road, rail and pipelines poses yet another hazard enroute or in transit. In the light of accidents at Bhopal, Vizag, Mexico, Flixborough etc considerable public and governmental concern has been aroused for evolving appropriate strategy for identifying, assessing, controlling industrial risk and action plan for handling emergencies when it strikes.

A sincere effort has been made in this document for addressing the issues mentioned above. This valuable compilation would help government agencies and other concerned who are entrusted with handling of emergencies. The plan gives clear organizational structure for all agencies and elaborates the duties to be performed by each when situation demands, so as to reduce the probability / severity of community suffering and property damage. The activities among other things include providing help in arranging for food, shelter, clothing, medical attention and other life sustaining requirements.

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TABLE OF CONTENTS CHAPTER 1: INTRODUCTION ............................................................................ 4 CHAPTER 2 : OBJECTIVE, PURPOSE AND SCOPE .................................................. 5 CHAPTER 3 : ABBREVIATIONS AND DEFINITIONS ................................................ 6 CHAPTER 4: USER GUIDE ............................................................................... 10 CHAPTER 5: INITIAL NOTIFICATION AND EMERGENCY CONTROL CENTRES ............ 12 CHAPTER 6: RISK POTENTIAL AND GEOGRAPHICAL FEATURES OF DISTRICT .......... 15 CHAPTER 7 ORGANISATION FOR DISASTER MANAGEMENT ................................. 23 CHAPTER 8: ROLES & RESPONSIBILITIES OF EMERGENCY COORDINATORS ........... 40 CHAPTER 9 : WARNING SYSTEM ...................................................................... 50 CHAPTER 10: PERSONAL PROTECTION OF CITIZENS ........................................... 51 CHAPTER 11: EVACUATION PLAN ..................................................................... 52 CHAPTER 12 : CONTAINMENT AND CLEANUP ..................................................... 54 CHAPTER 13 : TRANSPORT EMERGENCY ........................................................... 55 CHAPTER 14 : TESTING AND UPDATING PLAN .................................................... 58 CHAPTER 15 : GENERAL GUIDELINES IN DISASTER ............................................ 61 CHAPTER 16 : SAFETY PRECAUTIONS (RESPONSE PERSONNEL SAFETY) ................ 62 CHAPTER 17 : GUIDE ON ANTIDOTES ............................................................... 63 Annexure : 1 : Chemical Fact Sheets (MAH Industries)

AEGIES CHEMICALS INDIA LTD ........................................................................... 67 BHARAT PETROLEUM CORP. LTD. – REFINERY DIVISION ............................................... 71 BHANDUP COMPLEX WATER TREATMENT PLANT ......................................................... 76 CHEMICAL TERMINAL TROMBAY LTD ...................................................................... 80 HINDUSTAN PETROLEUM CORP. LTD. REFINERY ......................................................... 84 HINDUSTAN PETROLEUM CORPORATION LTD. MAHUL TERMINAL ...................................... 88 HPCL MAHUL LPG FILLING PLANT ......................................................................... 92 MAHINDRA & MAHINDRA (TRACTOR DIVISION) ......................................................... 96 MAHINDRA & MAHINDRA LTD. (JEEP DIVISION) ...................................................... 100 PARLE PRODUCTS LIMITED. ............................................................................. 104 RASHTRIYA CHEMICALS AND FERTILIZERS LTD, TROMBAY UNIT ..................................... 109 SANUJ STEELS PVT LTD .................................................................................. 114 HINDUSTAN PETROLEUM CORP LTD : AVIATION FUEL STATION ...................................... 116 INDIAN OIL CORP LTD : AVIATION FUEL STATION .................................................... 118 SEA LORD CONTAINERS LIMITED ....................................................................... 120

Annexure : II : Chemical Fact Sheets (Hazardous pipelines) AEGIS CHEMICAL INDUSTRIES LTD ..................................................................... 125 AEGIS CHEMICAL INDUSTRIES LTD– LPG/PROPANE................................................... 127 BHARAT PETROLEUM CORPORATION LTD- HSD / MS /KERO .......................................... 130 GAS AUTHORITY OF INDIA (GAIL) : NATURAL GAS ................................................... 132 HINDUSTAN PETROLEUM CORPORATION (ATF) ........................................................ 134 HINDUSTAN PETROLEUM CORPORATION LTD : MS/HSD/KERO ...................................... 135 HINDUSTAN PETROLEUM CORPORATION LTD : FO / LDO ............................................. 136 INDIAN PETROCHEMICALS CORP. LTD : PROPANE (LIQUID) .......................................... 137 MAHANAGAR GAS LTD.: NATURAL GAS ................................................................ 138 RASHTRIYA CHEMICALS & FERTILIZERS LTD.: NATURAL GAS ........................................ 140 RELIANCE INDUSTRIAL INFRA LTD: NAPHTHA / KERO ................................................ 141 TATA POWER COMPANY LIMITED : NATURAL GAS ..................................................... 143

Annexure - III : Information on Chemicals at MAH Factories

Annexure - IV : Contact Information - Emergency Services

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CHAPTER 1: INTRODUCTION No Industrial plant, office, commercial, or mercantile organization is immune from catastrophe. Therefore, emergency action planning is not a luxury, it is good insurance. Today, the need for emergency action planning is intensified by the trend to build in the suburbs where professionally trained help may not be available.

Emergencies can arise at any time and do not have to be caused by a spectacular occurrences, such as nuclear attacks or tornadoes, in fact, serious personnel injuries and property losses can result from broken water and gas lines, exploding boilers and- explosion in neighboring plants. Injuries and property damage result form basic six causes : work accidents, fire & explosions, flood , earthquakes, hurricanes, tornadoes warfare or civil strife. Often when disaster strikes, all personnel are affected, their lives are in jeopardy and their jobs ate threatened. Major considerations in planning for disaster control must include 'provisions for protecting personnel, evacuating both injured and uninjured, and care of the incapacitated.

Regardless of the size and type of organization, management is responsible for developing and operating an emergency action Programme, which is designed to meet all eventualities. An effective emergency action plan requires the same good organization and administration as any business undertaking. There is no one emergency plan that will do all things for all organizations. Each company must therefore decide on a plan that fits its needs and can be afforded.

Emergency action plans include the organizing and training of small groups of people to perform specialized services, such as fire fighting or first aid, and to restore the organization to a productive unit. Small, well trained groups can. serve as a nucleus to be expanded to any size needed to meet ant kind of emergency. Even with outside help available, a self help plan is the best assurance that losses will be kept to a minimum. This precaution is particularly true in the case of warfare or civil strife because outside help may not be immediately available an the survival of the company will depend on its own ability to cope with its problem.

Ministry of Environment & Forest (MOEF) Government of India as the nodal ministry for management of chemical disasters, have as part of a programme avoid major accidents like Bhopal and restrict the loss of human beings, have decided to prepare a district disaster management plan, as per their guidelines. This plan is only a district management action plan for the Mumbai suburban district.

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CHAPTER 2 : OBJECTIVE, PURPOSE AND SCOPE

OBJECTIVE & PURPOSE The emergency Response Plan means a detailed programme of action to control and minimize the effect of an emergency, requiring prompt corrective measures beyond normal procedures to protect human life, minimize injuries, optimise loss control & reduce the exposure to physical assets & environment . in other words the emergency response plan is a process by which the response to an extra ordinary event is galvanised urgently through activation of functional components and assignment of responsibility for each component to an appropriate agencies. The action plan functions optimally only if undertaken and an institutional set-up responsible for the mitigation and response is understood clearly.

The purpose of this plan is to outline the procedures for immediate action, if major emergencies occur involving Major Hazard Units in the district.

Every Major Accident Hazard Unit has its Onsite Emergency Plan to deal with an emergency inside the premises of the factory. I fan emergency arises beyond the resources of the factory, they have an obligation to seek assistance from the Government. This plan comes into operation as soon as a responsible person of the Major Hazard Unit covered under this plan triggers the initial alert action regarding the Offsite emergency Plan as specified under this plan.

SCOPE The Major Accident Hazard Units in Mumbai Suburban district are covered under this plan. The plan will apply only to the following emergency scenario :

• Release of toxic / flammable material, both liquid & gases • Explosion / Fire

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CHAPTER 3 : ABBREVIATIONS AND DEFINITIONS

THE EMERGENCY RESPONSE PLAN The emergency Response Plan means a detailed programme of action to control and minimize the effect of an emergency, requiring prompt corrective measures beyond normal' procedures to protect human life, minimize injuries, optimize loss control & reduce the exposure to physical assets & environment.

In other words the emergency response plan is a process by which response to plan an extra ordinary event is galvanized urgently through activation of functional component and assignment of responsibility for each component to a appropriate agencies.

The object of an emergency plan is to intercept a developing disaster as quickly as possible so as to minimise its scale and consequences in terms of loss of life and property. It is oriented towards containment and extermination of the hazard. A Disaster Plan is pressed into service after the terminal event has occurred arid is oriented towards Salvage and Rescue Operations.

DISASTER An event, natural or manmade, sudden or progressive which impacts with such severity that the affected community must respond by taking exceptional measures It is a sudden or progressive occurrence of such magnitude as to affect normal pattern of life in an industry and/or vicinity causing extensive damage to life and/or property.

TYPES AND LIKELY CAUSES OF DISASTER TYPES OF DISASTER The types of disaster considered for this plan are limited to the following:

• Fire and explosion • Vapour cloud • Toxic Gas release • Large Oil Spills

These disaster may arise form an industrial activity with the industry or during transportation of hazardous material by pipeline, road or rail en route its destinations or in transit.

The other types of disaster mentioned below are not considered within the scope of this plan

• Hurricane, Flood, Cyclone

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• Strike and sabotage • Nuclear disaster

CAUSES OF DISASTER Various causes that can lead to the above referred types of disasters are as follows

a) In-plant emergencies due to

• deficiencies in system/ • malfunctioning/improper handling in operations or maintenance • Design or Equipment failure

b) Emergency during transportation of hazardous material by road, rail or by pipeline

The other causes of disaster mentioned below are not considered within the scope of this plan.

• Natural calamities like Cyclone/storm/gale/flood/Lightning/Earthquake • Deliberate acts of man like Sabotage, Riot, War Debris from a falling air

craft/rockets

PHASES OF DISASTER WARNING PHASE Many disasters are preceded by some sort of warning. For example with the aid of satellites and network of weather stations, many meteorological disasters like cyclones and hurricanes can be predicted and actions can be taken to eliminate/reduce their effect.

In an industrial unit the detection and alarm system can be used for timely detection of emergencies and alerting required personnel

PERIOD OF IMPACT PHASE This is the period when the disaster actually strikes and very little can be done to lessen the effects of disaster. The period of impact may last for a few seconds (like fire, explosion, gas leak) or may prolong for days (fire, leak, water pollution etc.)

RESCUE PHASE The rescue starts immediately after the impact phase and continues until necessary measures are taken to rush help and combat with the situation. The responsibilities assigned to each of the co-ordinators in organisation structure will be performed by them. Needless to emphasise that prompt and well organised rescue operations can save valuable lives.

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RELIEF PHASE In this phase, apart from organising relief measures internally, depending on severity of the disaster, external help should also be summoned to provide relief i measures (like evacuations to a safe place and providing medical help, food, clothing etc.). This phase will continue till normalcy is restored.

REHABILITATION PHASE This is the final and longest phase. It includes rebuilding damaged property, estimating the damages, payment of compensation, etc. Help from revenue/insurance authorities need to be obtained to assess the damage, quantum of compensation to be paid etc.

DISASTER MANAGEMENT An applied science consisting of a continuing process of systematic observation, analysis and dissemination that allows for the conscious structuring of a series of events or conditions, by the timely and informed application of resources.

PHASES OF DISASTER MANAGEMENT: Before the emergency : Preparatory action which include identification of specific hazards and area of vulnerability, adoption of mitigatory steps, setting up of response facilities education of communities, conducting of simulated training exercise etc.

During the emergency : It is the implementation of the operational plan to reduce casualties and damage to property.

After emergency: It is phase that involve restoring normalcy and assessing the damage. It is also necessary to carry out investigation of the causes of the accident to avoid repetition of similar occurrences.

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ABBREVIATIONS

CCG : Central Crisis Group

SCG : State Crisis Group

LCG : Local Crisis Group

MAH : Major Accident Hazard

MCL : Maximum Credible Loss

MSD : Mumbai Suburban District

MSDS : Material Safety Data Sheet

DCG : District Crisis Group

ECC : Emergency Control Center

CMG : Crisis Management Group

MARG : Mutual Aid Response Group

BMC : Brihanmumbai Municipal Corporation

MFB : Mumbai Fire Brigade

MTNL : Mahanagar Telephone Nigam Ltd.

MSRTC: Maharashtra State Road Trasport

MSEB : Maharashtra State Electricity Board

MPCB : Maharashtra Pollution Control Board

DISH : Directorate Industrial Safety & Health

PWD : Public Works Department

NGO : Non Governmental Organisation

RTO : Regional Transport Authority

DCP : Deputy Commissioner of Police

MECR : Main Emergency Control Room

SECR : Site Emergency Control Room

CEC : Chief Emergency Coordinator

OEC : Onsite Emergency Coordinator

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CHAPTER 4: USER GUIDE This manual is a documentation of various measures to be taken in case of a offsite major emergency or a disaster. This serves as a guideline for activities to be undertaken in case of a major emergency or a disaster in the Mumbai Suburban District.

The purpose of this plan is to describe the activities to be carried out in case of a major emergency or a disaster, assist concerned agencies in planning for hazardous materials incidents and to serve as a guide & training aid . This plan is developed for the Govt. agencies and the industries to help them in understanding their roles incase of an emergency.

This Manual details the responsibilities of various agencies, mobilisation of resources and emergency handling for offsite disaster. The emergencies arising out of industrial activities and emergencies while transporting of hazardous material by pipeline, road/ rail enroute / transit in Mumbai Suburban district only are considered for the purpose of this manual .

This plan will apply to only following emergency scenario.

• Release of toxic / flammable material, both liquid & gases • Explosion / Fire

WHO SHOULD READ THIS PLAN ? This plan is developed basically for the agencies under the Govt. to make them understand their roles incase of an emergency. Also the crisis groups and the industries are expected to be clear in their roles and relationship concerning Disaster.

WHEN THIS PLAN TO BE USED ? This plan should be used for pre-incident planning and disaster. It should be used for guidance and clarification, where particular agency has a responsibility. For the catastrophic emergency this plan shall be used in conjunction with City and state crisis management plan

ACTIVATION OF THE PLAN It is generally accepted that the "WORST CASE" scenario has the remotest of occurrence. Therefore, we need to direct resource towards the control of incidents, which could realistically occur. According, Maximum Credible Loss (MCL) scenarios can effectively manage lesser hazardous incidents. A~ soon as there is fire, explosion of toxic gas release, the incident will be handled by the industrial unit concerned in accordance with the "On-Site plan. In the event of the emergency escalating into a major incident extending beyond the unit premises,

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the offsite disaster management plan will come into effect. The plan comes into operation as soon as a responsible person of the Major Hazard Unit covered under the plan triggers the initial alert action regarding Offsite emergency plan when an emergency arises beyond the resource of the concerned unit.

DISTRIBUTION This plan shall be distributed to the concerned government agencies, members of the District Crisis Group, local Crisis Group and the concerned industries.

AMENDMENTS Any changes required to be incorporated shall be submitted in the given format. The suggested changes shall be incorporated in the manual upon approval.

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CHAPTER 5: INITIAL NOTIFICATION AND EMERGENCY

CONTROL CENTRES _______________________________________________________________________ The plan will be activated upon information of incidents of following nature:

• Fire and / or explosion • Release of hazardous material and / or waste • Any emergency situation that could impact human and safety and / and or

the environment.

INCIDENT DISCOVERY : IN CASE OF EMERGENCY

• Dial 100 / 101 immediately • Give you name, location, and concise description of the emergency (e.g.

fire, personal injury, toxic gas release etc.) • Notify / alert the personnel in the immediate area of danger. • If personal Safety and health is not assured, do not attempt to enter the

site • By this time the emergency response team will reach the site.

KEY CONTACT NUMBERS • Police Control Room 100 • Mumbai Fire Brigade 101 • DCG Control Room • MCGM Control Room 1916 • Municipal Commissioner's Office 2270 4403, 2269 4725 • Mumbai Suburban District Collector’s office 2655 6808 • SCG Control Room 2202 7990

NOTIFICATION : During an emergency, the command poster the first responder at site shall notify the emergency control center severity of incident. Accordingly the ECC shall deploy resource to manage the incident. After that ECC shall issue all the internal an external notification to various agencies and shall send the call out that are contingent on the nature of the incident.

EMERGENCY CONTROL CENTRES MAIN EMERGENCY CONTROL ROOM (MECR) The Main Emergency Control Room (MECR) will be located at Central Control Room, Municipal Corporation Office, VT area. It is from the MECR that all operations to handle emergency will directed and coordinated. The MECR is

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mobilized by the control room duty operator when required, by calling out the Chief Emergency Coordinator and Key Personnel

ACTION OF MECR 1. Chief Emergency Co-ordinator (CEC) to assume control. 2. Ensure that all information relating to situation is received .to ascertain

• What is the status of emergency • What action the factory management has taken • Is evacuation required If Yes how will this be carried out

3. Additionally alert as necessary • Hospital authorities Transport department • Railways • Electric Supply Authorities • Revenue Department • Telephone Department • Pollution control board • Bombay Port Trust • Any Other department

4. The group of key personnel to meet and evaluate the situation plan the phases of emergency procedure ie • Phase I Immediate Response Rescue of survivors and safety of

personnel is the primary' consideration. • Phase II Containment Mobilisation of resources to contain the situation

is the main concern. • Phase III Control and repair Plan to regain control of the situation.

5. Provide immediate advice to SCR as to how to tackle the situation what assistance is being mobilised what are the plans for evacuation, if any.

SITE EMERGENCY CONTROL ROOM (SECR) The Site Emergency Control Room (SCR) will be set up at any suitable point close to the scene of emergency assessment of the status of emergency steps required to fight the emergency and the type of assistance required will be the areas of primary concern.

ACTION AT SCR • OEC to assume command. • Ensure that all key agencies are called in. • Ensure that al information relating to situation is received . • Assess the type of assistance required and inform MECR. • Report to MECR the status of emergency at regular intervals. • Keep a running record of events major decisions and steps taken o meet

the emergency. ACTION AT SCENE

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• Respond to emergency in accordance with the Factory's own contingency plan.

• OEC Should ensure that the following are notified immediately o MECR o Police o Fire Brigade

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CHAPTER 6: RISK POTENTIAL AND GEOGRAPHICAL

FEATURES OF MUMBAI SUBURBAN

DISTRICT _______________________________________________________________________

ASESSMENT OF RISK: The potential for a major emergency as a result of fire, explosion and release of chemical substances and the possible consequences at each of the Major Accident Hazard Unit has been mentioned in the Chemical Fact Sheets as part of Annexure I. Also the details of offsite pipelines with these units carrying hazardous material is covered separately as part of Annexure II. The list of major accident hazard units and details of offsite pipelines passing through Mumbai Suburban Distrct carrying hazardous material is given below

LIST OF MAJOR ACCIDENT HAZARD UNIT FACTORIES IN MUMBAI

SUBURBAN DISTRICT SR. NO. NAME & ADDRESS OF FACTORY 1. Aegis Chemical Industries Ltd.,

Plot No. 72, Mahul Village, Trombay, Mumbai – 400 074.

2. Bharat Petroleum Corporation Ltd., (Mumbai Refinery) Mahul, Chembur, Mumbai – 400 704

3. Bhandup Complex water Treatment plant Brihan Mumbai Mahanagarpalika, Khindipada, Darag Raod, Mulund, (W), Mumbai-400082

4.

Chemical Terminal Trombay Ltd. Pirpau Installation, Near MbPT Pump House Behind Tata Electric Company Trombay, Mumhai 400 074

5.

Hindustan Petroleum Corporation Ltd., (Refinery) Corridor Rd., Mahul, Chembur, Mumbai - 400 074.

6. Hindustan Petroleum Corporation Ltd., Mahul Terminal Corridor road, Chembur, Mumbai - 400 074.

7. Hindustan Petroleum Corporation Ltd., Mahul LPG Filling Plant, L U Gadkari Marg, Chembur, Mumbai - 400 074

8. Mahindra & Mahindra Ltd., (Automotive division). Akurii Road, Kandivali. (E), Mumbai-400101.

9. Mahindra & Mahindra Ltd., (Tractor Division) Akurii Road, Kandivali (E),

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Mumbai-400101. 10. Parle Products Ltd.,

Vile Parle (E), Mumbai - 400 057. 11. Rashtriya Chemical and Fertilizers Ltd.,

Trombay Unit, Chembur, Mumbai - 400 074.

12. Sanuj Steels Private Limited, D R Container Yard, Jijamata Nagar, Mahul Road, Chembur, Mumbai – 74

13 Hindustan Petroleum Corporation Ltd., Aviation Fuel Station, Chchatrapati Shivaji International Airport, Sahar, Mumbai

14 Indian Oil Copr Ltd, Aviation Fuel Station, Chchatrapati Shivaji International Airport, Sahar, Mumbai

15 Sea Lord Containers Limited Ambapada, Mahul Village, near BPCL Refinery, Chembur, Mumbai -74

LIST OF OFFSITE PIPELINES CARRYING HAZARDOUS MATERIAL

IN MUMBAI SUBURBAN DISTRICT SR. No. NAME OF FACTORY

HAZARDOUS MATERIAL

1. Aegis Chemical Industries Ltd., Petrochemicals / POL Products LPG /Propane

2.

Bharat Petroleum Corporation Ltd., Refinery (MMPL)

High Speed Diesel Motor Spirit Superior Kerosene

3.

Gas Authority of India Ltd Natural Gas

4.

Hindustan Petroleum Corporation Ltd., Refinery (MPPL)

Aviation Turbine fuel High Speed Diesel Motor Spirit Superior Kerosene Furnace oil / Light diesel oil

5. Indian Petrochemicals Corpn. Ltd Propane

6. Mahanagar Gas Ltd Natural GAS

8.

Rashtriya Chemical and Fertilizers Ltd.,

Natural Gas

9.

Reliance Industrial Infrastructure Ltd

Naphtha / Kerosene

10. Tata Power Company Pvt. Ltd. Natural Gas

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GEOGRAPHICAL FEATURES Mumbai Suburban District which is one of the revenue district of Greater Mumbai Metropolitan area or BrihamnMumbai Municipal Corporation (BMC).lt covers an area of 370sqkm The district consist of one administrative subdivision comprising three tahsils ie Kurla.Borivaliand AndheriThe distrcit covers 14 municipal wards of BMC and is also referred as Eastern Suburbs and western suburbs .

SALIENT PHYSICAL FEATURES AND LAND USE PATTERNS Land Use Area in Sq km and Percentage

Inhabited area 277.5 (75%)

Agricultural area (5%)

Industrial area 41.0 (11.69%)

Forest Cover 33.0 (8.31%)

Waste Land Nil

Total 370 Sq km

CLIMATE & RAIN FALL The details about climate and rainfall in Mumbai Suburban District as recorded at Santacruz gauge station of India Meteorological Department are as under:

The climate of the Mumbai Suburban District is tropical maritime. The daily maximum temperature (mean) range from 29.1 c in August to 33.3 c in the month of April. Daily minimum temperature (mean) range from 16.3 c in January to 26.2 c in May. The average annual rainfall of this district based on last 30 years data is 2457.0 mts. The district receives an average seasonal rainfall of 2363.0 mm during June -September. The average monthly rainfall is highest in the month of July (945.4 mm) followed by August (660.4mm). The monthly rainfall in June is 647.5 mm and 309.2 mm in September.

TERRAIN AND CLIMATIC CHARACTERISTICS.: Terrain and climatic characteristic of the district are useful understand the precipitation and flood potential of the region. If the district exhibits varying oi differing terrain and collimation characteristics, the you make additional copies o1 the template and fill the requested information.

Area (in sq.Kms)

370

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Climate Temperature in Celsius Maximum Minimum

Tropical 31.7 22.1

Rainfall Total Annual Rainfall (mm) Maximum Rain fall (mm) Months during which maximum rainfall occurs. Months having maximum Continuous Rainfall (mm)

2422.1 201.8 3784.9 (1958 AD) June & July # June574.1 August 553.0 July 868.3 September

Predominant Soil Cover Whether. Sandy, alluvial loamy etc:

Alluvial & Loamy

Land Use Patterns-All in Sq. Kms. Inhabited area Agricultural area Industrial area Forest cover Wastelands Drought prone areas

370 277.5 75% 18.5 5% 41.0 11.69% 33. 8.31% Nil

FLOOD ASSESSMENT Sr. No.

Name of the River

Flooding frequency over years

Location and Extent of Area Inundated (worst case in Sq. Kms.

Corresponding Estimated Flood Damage in Rs.

1. Mithi River } Only in rainy 15 -

2. Dahisar River } Season 5 -

INDUSTRY RELATED INFORMATION Number of Industrial Estates

Types of Industries

Total work force in industries

Number of chemical industries / tank farms

Refineries, Chemicals & Fertilisers, Eletric companies Engg, printing, garments, plastic.etc 2,82,062

338

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Number of Pipelines carrying chemicals

Number of potentially hazardous locations

Number of potentially hazardous raw materials for industries (during a month)

Number of vehicles carrying hazardous finished products from industries (during a month)

Number of vehicles passing through the

industries (during a month)

Number of container terminals

29

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502

27,599

Information not received More details are given separately district carrying hazardous materials for as per comments.

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No. of Industries in the estate 336

No. of Major Hazardous and Polluting Industries

15

Total work force in industries 38,056

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POPULATION CHARACTERISTICS Sr. No.

Name of the Urban Center

Population Population Density

1. Nirmal Nagar 2,50,000 Mixed & Thickly populated

2. Kherwadi 3,50,000 -do-

3. Vakola 3,50,000 -do-

4. Vile-Parle 2,00,000 -do-

5. Kurla 7,00,000 -do-

6. Nehru Nagar 4,00,000 -do-

7. Tilak Nagar 3,13,440 -do-

8. Trombay 4,00,000 -do-

9. Deonar 2,50,000 -do-

10. Shivaji Nagar 4,00,000 -do-

11. Chembur 3,00,000 -do-

12. R.C.F. 3,50,000 -do-

13. Ghatkopar 9,00,000 -do-

14. Park Site 3,50,000 -do-

15. Vikhroli 4,00,000 -do-

16. Pant Nagar 6,00,000 -do-

17. Kanjur Marg 1,50,000 -do-

18. Mulund 3,87,000 -do-

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19. Bhandup 8,00,000 -do-

20. Sahar 75,000 -do-

21. Air Port 12,000 -do-

22. Bandra 2,05,000 -do-

23. Khar 5,30,000 -do-

24. Santacruz 7,17,765 -do-

25. Juhu 1,18,232 -do-

26. D. N. Nagar 4,00,000 -do-

27. Oshiwara 5,00,000 -do-

28. Andheri 3,75,000 -do-

29. Sakinaka 5,50,000 -do-

30. M.I.D.C. 2,50,000 -do-

31. Jogeshwari 1,25,000 -do-

32. Meghwadi 4,00,000 -do-

33. Goregaon 5,50,000 -do-

34. Aarey Sub. 80,000 -do-

35. Dindoshi 12,00,000 -do-

36. Malad 8,00,000 -do-

37. Malvani 5,00,000 -do-

38. Kandivli 3,57,000 -do-

39. Samta Nagar 5,50,000 -do-

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40. Borivli 6,00,000 -do-

41. Kastura Marg 4,00,000 -do-

42. Dahisar 6,00,000 -do-

SEASONAL MIGRATION Purpose Area (specify

Talukas) Period (Calendar Months)

Estimated population in/out migration

Salt Manufacture

Bhandup Taluka- Kurla Trombay }Trombay }

May 680

HISTORICAL AND RELIGIOUS CENTRES Name of the Historical and Religious centre and nearest Urban or Major Rural Centre listed above

Periods of Festive Occasions. Months

Estimated tourists or visiting population

1. Mount Mary Temple Bandra (West)

10 days in the month of September

8,00,000

2. Pandavkalin Gurnfa Majas Village, Jogeshwari (E)

1 Day for Mahashivratri

3,33,000

3. Madh Devi Festval Madh, Andheri (West)

1 day 50,000

4. Kaneri Caves Borivali (East) Daily

Daily 5,00,000 Yearly

5. National Park Borivli (East) Daily 10,00,000 Yearly

6. Mandpeshwar Gumfa Daily 36,500 Yearly

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CHAPTER 7 ORGANISATION FOR DISASTER

MANAGEMENT, VARIOUS AGENCIES REQUIRED

TO COMBAT A DISASTER A. MUNICIPAL CORPORATION OF GREATER MUMBAI

1. Mumbai Fire Brigade 2. Municipal Medical Services 3. Hydraulic / Water Department 4. Transport Department E. E. T. (City / Suburbs) 5. B.E.S.T 6. Conservancy Service 7. Municipal Security Service 8. Equipment Manufactures 9. Health Department

B. STATE GOVERNMENT SERVICE 1. Mumbai Police / Traffic Control 2. B. S. E. S. Co. Ltd. 3. Maharashtra State Road Transport Corporation 4. Public Health 5. State Civic Supply Department 6. Public Relations and Publicity 7. Communication Department 8. Public Works Department 9. Home Guards and Civil Defense 10. Equipment Manufacturers 11. Directorate of Industrial Safety & Health 12. Maharashtra Pollution Control Board

C. CENTRAL GOVERNMENT 1. Defence service (Army, Navy & Airforce) 2. Publicity & Public awareness (Doordarshan, Akashwani, Newspaper) 3. M. N. T. Ltd. / Telecommunication Department 4. Railways (Central / Western) 5. Aviation Department 6. Post & Telegraph 7. Mumbai Port Trust - Coastal Guard 8. Medical Aids 9. Equipment Manufacturers 10. Controller of Explosives

D. PRIVATE AGENCIES

1. Private Ambulance Service 2. Private Transport Organisations - Tankers / Trucks / Lorries/ Terr

Buses/Jeeps, etc.,

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3. Indian Oxygen Co., / Mumbai Oxygen for Medicated Oxygen. 4. Labour Contractors 5. Private suppliers of various materials 6. Tata Power House / Companies.

E. MUTUAL AID RESPONSE GROUPS (MARG)

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DISTRICT CRISIS GROUP- MUMBAI SUBURBAN DISTRICT.

District Collector

2589 6160 2655 6806

Prashasakiva Bhavan, 10'h Floor, Kala Nagar, Bandra (E)., Mumbai.

Directorate of Industrial Safety & Health

2265 2558 2265 2522 2265 2504 2655 2509

Jt Director, Directorate of Industrial Safety & Health, Kamgar Bhavan, Block E, Bandra Kurla Complex, Mumbai-51. Dy Director, Directorate of Industrial Safety & Health, Kamgar Bhavan, Block E, Bandra Kurla Complex, Mumbai-51.

District Energy Officer

2647 2131 2642 2211 2610 0505 3009 6999

Chief Engg. (Gen) Environment Health & safety, M.S.E.B. Parkash Gad, Plot No. G-9, Prof, Anant Kanekar Marg, Bandra (E), Mumbai – 55 Electricity House, Sanatacruz (E) Mumbai-55

4) Chief Fire Officer

2307 6111 / 3 23074923

Chief Fire Officer, Municipal E Ward Office Shaikh Haffijuddin Marg, Byculla, Mumbai-88

District Information Officer

2202 7956 2202 3472

Dy. Director (News) officer of director General of information & Public Relations, Got. Of Maharashtra Mantralya, Mumbai - 400 032

Controller of Explosives

2757 5946 Dy. Chief Controller of Explosives, West circle Mumbai A-1/A-2 wign, 5'h fir. C.G.O. Complex, CBD Belapur, Navi Mumbai-400 614

30

Chief of Civil Defense

2261 0088 2261 4092

Controller of Civil Defence, 3rd Flr, Shri Chatrapati Shivaji Maharaja Market, Mata Rarnab Ambedkar Marg, Mumhai — 400001

One Representative of Trade Unions

2418 1742 President Petroleum Workers Union, 773, Tel Rasayan Bhavan Tilak Road, Opp. BEST workshop, Dadar (East), Mumbai – 400 014

Deputy Superintendent of Police

2497 6960 C.P. Zone V, Tilak Nagar Police Station Bldg., 2nd Floor, Chembur, Mumbai – 400 089

Representative of Department of Public health Engg.

2262 0025 2262 0251 2300 4721 2306 1279

Chief Hydraulic Egnn. M. C.G. M. Head Quarter, Mahapalika, Marg, Mumbai Dy. Chief Engg. 2nd Floor Engg. Services & project Municipal Bldgs, Near Byculla Cement Godown Bldg., N. M. Joshi Marg, Mumbai – 400 011

Representative of pollution Controller Board.

2757 2740 2492 3462

Regional Officer MPCB Regional Office 7th floor Raigad Bhavan CBD Belapur, Navi Mumbai

Four Experts in Industrial Safety & health to be nominated by District Collector

Expert on LPG 922 322 2429 2554 2280 Experts on Ammonia RCF, Methyle amines etc. 2552 2347/ 2552 2265 9987036436 Experts on chlorine

Shri Rakesh Gupta Plant Manager. HPCL BDU Filling Plant,l Mumbai – 400 074 Shri P.B.Asai, DGM(Tech. Ser) Shri C.M.Bisen ,CE(Safety & Fire) R.C.F. Ltd. Chembur, Mumbai – 400 074 Shri Raghunanadan Singh

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922 336 9431 6717 5511 Expert of Chemicals. 25541463 986 702 6221

Dy G. M. - OPerations Tata Power Company Trombay Thermal Power Station, Chembur, Mumbai – 400 074 Shri Dilip Bheda M/s Aegis Chemicals Inds Ltd, Mahul, Mumbai – 400 074

Commissioner of Transport

2492 4734 Dy. Commissioner of Police (Traffic) Traffic Police

One Representative of Industry

2554 6434 Director (Refineries), BPCL Refinery, Mahul Road, Chembur, Mumbai – 400 074

Chairperson / Member Secretary of Local Crisis Group

2651 3744 2352 2230 / 1 / 2 2352 2230 / 1 / 2

Additional Collector & Chairperson Local Crisis Group, MMRDA Bldg, Bandra Kurla Complex, Bandra (E), Mumbai – 400 005 Dy. Collector & Chairperson M.S.D. 2nd Flr., MMRDA Bldg., Bandra Kurla Complex, Bandra (E), Mumbai – 400 005 Dy. Director & Member Secretary L.C.G. 5th flr. Commerce Center, Tardeo, Mumbai. Dy. Director & Member Secretary of Kurla Mulund Local Crisis Group 5th Flr., Commerce Center Tardeo, Mumbai

32

LOCAL CRISIS GROUP

TROMBAY – CHEMBUR AREA Sub Divisional Magistrate / District Emergency Authority

Chair Person Additional Collector, Mumbai Suburban District, Bandra, Mumbai

Inspector of Factories Member Secretary Dy. Director Industrial Safety & Health.

Industries in the District / Indurstrial area / industrial pocket

Member MAH Factories in Chembur Area

Transporters of hazardous chemicals (2 numbers)

Member K. Transports, 11 Majithia Ind. Estate, Near Dukes factory, Deonar, Chembur, Mumbai – 88

Pella Roadways, Opp. HPCL Refinery, Gowanpada Village, Chembur, Mumbai 74

Fire Officer Member Fire Officer Chembur, Mumbai – 74

Station house Officer (Police)

Member Assistant commissioner of Police Basant Park Chembur,Mumbai– 74

Block Development Officer

Member M – Ward Officer 12th Road, BMC Office, Mumbai-74

One Representative of Civil Defense

Member Area co-ordinator for chembur Civil Staff College. Dhobitalao, Nr. Metro Cinema, Mumbai – 01

33

Primary Health Officer Member Medical Officer, Sion Hospital, Mumbai

Editor of local news paper

Member Editor of Mid Day, tardeo, Mumbai – 34

Community leader / sarpanch / village pradhan nominated by Chair person

Member Municipal Corporator of Chembur

One representative of nos Government Organisation to be nominated by the chair person

Member Chairman, Mutual aid response Group

Two Doctors eminent in Member 1) Dr. S.V. Ingale, Chembur 2) Dr. V.C. Salvi, , Chambur

Two social workers to be nominated by the chair person

Member

34

LOCAL CRISIS GROUP

KURLA – MULUND AREA Sub Divisional Magistrate / District Emergency Authoriity

Chair Person Dy. Collector,

Mumbai Suburban District, Bandra (E), Mumbai

Inspector of Factories

Member Secretary Dy. Director,

Industrial Safety & Health, Mumbai

Industries in the District / Industrial area / industrial pocket

Member Brihanmumbai Mahanagarpalika, Bhandup Complex, Water Treatment Plant, Bhandup

Empire Industries Ltd., (Vitrum Glass), Vikhroli (W), L.B.S. Marg

Techno Product P. Ltd., Opp. Jari Mari Pipe Line, Near St. Jude’s School Andheri Kurla Rd.

Larsen & Tourbro Ltd. (West), Saki Vihar Road, Powai.

Transporters of hazardous Chemicals(2 numbers)

Member

Fire Officer Member Station Fire Officer, Mulund Fire Station, Mulund

Station fire Officer, Vikhroli, Fire Station, Vikhroli

Station House Officer (Police)

Member Dy. Commissioner of Police Parimandal – 6, Mulund

Dy. Commissioner of Police, Kurla

35


Member Ward Officer of Bhandup, Mulund, Vikhroli, Ghatkopar, Kurla

One Representative of Civil Defence

Minister Dy. Controller of Civil Defence, S. V. Road, Andheri (W)

Primary Health Officer Member Medical Superitendent of

Sarvodaya Hospital , Ghatkopar, Ph :

E.S.I.C. Hospital, Mulund

Mulund General Hospital, Mulund

Editor of Local News Paper

Member Editor – Mid Day, Tardeo, Mumbai – 34

Editor – Mahanagar, Mahim

Community leader / Sarpanch / Village Pradhan nominated by Chair-person

Member Corporators of Bhandup, Mulund, Vikhroli, Ghatkopar and Kurla area.

One Representative of Non-Government

Member Co-ordinator,

Bhandup Mulund Mutual Aid

Organisation to be nominated by the Chairperson

Response Group

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Two Doctors eminent in the Local Area, to be nominated by Chair-person

Member

Two Social Workers to be nominated by the Chairperson

Member

LOCAL CRISIS GROUP

BANDRA - DAHISAR AREA Sub Divisional Magistrate / District Emergency Authoriity

Chair Person Dy. Collector, Mumbai Suburban District, Bandra (E), Mumbai

Inspector of Factories

Member Secretary Dy. Director, Industrial Safety & Health, Kandivli

Industries in the District / Industrial area / industrial pocket

Member Director, Mahindra & Mahindra Ltd., (Jeep, Plant)

Director, Specials Steels Ltd., Borivali

Director, Parle Products Ltd., Vile Parle

Director, Borosil Glass Works, Marol Maroshi Road, Andheri (E)

Director, Mahindra & Mahindra Ltd., (Tractor Division)

Times of India Ltd., Suburban Press Kandivali

37

Transporters of hazardous Chemicals(2 numbers)

Member

Fire Officer Member Dy. Fire Officer, Western Zone, Marol, Andheri (East), Ph. : 821 0940

Station Officer S.V. Road, Kandivali (W)

Station House Officer (Police)

Member Asst. Commissioner of Police, S. V. Road, Kandivali (W)


Member Ward Officer Kandivali (East) & (West)

Ward Officer, Kandivali (East)

One Representative of Civil Defence

Minister Dy. Controller of Civil Defence, Area IV, Andheri Fire Station Compd, S. V. Road, Andheri (W)

Primary Health Officer Member Medical Superitendent of Cooper Hospital, Andheri, Ph. 6207254

Bhagawati Hospital, Borivali Ph : 8662461

ESIC Hospital, Kandivali Ph – 8877764

Editor of Local News Paper

Member Editor – Mid Day, Sarvoday Mill Compd., Tardeo, Mumbai – 34

Editor – Mahanagar, Mahim

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Community leader / Sarpanch / Village Pradhan nominated by Chair-person

Member Corporators, Borivali (E)

Corporators, kandivali (E)

Corporators, Andheri (E)

Corporators, Parle (E)

One Representative of Non-Government

Member Chairman, Mulund Aid Response Group

Organisation to be nominated by the Chairperson

Two Doctors eminent in the Local Area, to be nominated by Chair-person

Member Dr. Bodhankar A. N., Connected with Industrial Health. 701, Blue Bird, ‘C’, Opp. Rizvi College, Bandra (W), Ph 6494208

Dr. Yadav, Connected with Industrial health, Shree, 18/6, Pushtikar Society, Jogeshwari (W), Ph : 26247254

Two Social Workers to be nominated by the Chairperson

Member President, Lion Club of Marol, Andheri, Kurla Road, Andheri (E), Mumbai – 59 Ph : 8326435

President, Rotary Club of India, Andheri (E), Ph – 8360048

MUTUAL AID RESPONSE GROUPS IN MUMBAI SUBURBAN DISTRICT

39

1.

Mutual Aid Response Group

Trombay Chembur Area

2. Mutual Aid Response Group

Bhandup – Mulund Area


Kurla – Ghatkopar – Vikhroli Area


Bandra – Dahisar Area

40

CHAPTER 8: ROLES & RESPONSIBILITIES OF

EMERGENCY COORDINATORS AND KEY

AGENCIES _______________________________________________________________________________

CRISIS MANEGMENT GROUP (CMG) This is the apex body for crisis management

• Municipal Commissioner of Mumbai • Commissioner of Police • Chief Executive Health Dept, BMC • Joint Director, Industrial Safety & Health, • Chief Fire Officer, Mumbai Fire Brigade • Additional Controller, Civil Defense • Public Relations Officer • Member Secretary, Pollution Control Board • City Engineer of BMC • Co-ordinator Mutual Aid & Response Group, • RTO Mumbai

The chairman of CMG may co-opt any other officer depending upon the situation, for each member of the CMG there is an alternate member. The telephone number and address of each member are given in the list.

The tasks of the CMG are as under :

• To exercise board control over emergency operations • To give guidance on matter of basic policy • To provide official information and instruction to the public • During normal times review the operational preparedness and take

appropriate measures to rectify the defects • To co-ordinate inter zone emergency response

FIRST RESPONDER ON SCENE : The first senior official responding to an Emergency is the incident Controller and begins implementing the incident control system. All emergency responders and their communications are co-ordinated and controlled through the incident controller. As more senior official arrive the position of incident controller is passed up a previously established line of authority.

The first responder at the scene of a hazardous materials emergency should complete the task necessary to protect public health and responder safety, the environment, and the property. The order in which the following tasks are completed is incident priorities.

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• Evaluate potential hazards to determine if the release or threaten release is an emergency.

• Isolate the Scene and deny entry. • Establish control zones. • Identify spilled material or threatened release without subjecting

responders to contamination. • Look for any casualties and identify other essential site conditions. • Implement Incident Command System, establishes a command post, and

identifies a staging area for incoming resources. • Identify additional resources for operations beyond the capability of on-

scene units. • Notify appropriate response and reporting agencies. • Designate a knowledgeable safety officer prior to engaging in operational

activities. • Rescue victims from the hot zone using appropriate personal protective

equipment. • Provide emergency decontamination to victims exposed to material having

the potential for secondary contamination of emergency medical, personnel.

• Determine necessary public protection action (evacuation or sheltering in place)

• Initiate control and containment within capabilities of available resources and equipment

CHIEF EMERGENCY COORDINATOR (CEC) The Municipal Commissioner will be the Chief Emergency Coordinator (CEC) and will take over control room at MECR and will remain in command.

The first key person arriving at MECR will assume the responsibilities of the post till the arrival of the CEC. His responsibilities will be as follows :-

Immediately on being aware of the emergency the key person will proceed to MECR. On reaching he will, -

• Assume responsibilities of the post pending the arrival of CEC. • Ensure that key personnel have been called in. • Establish contact with SCR and assess the extent of emergency. • Keep a running record of development and information received from SCR. • Report all significant developments to the CEC on his arrival

Note : The above responsibilities will be discharged by the next senior key person on arrival at MECR and taking over charge so that pending the arrival of CEC the senior most key person present at MECR shoulders the responsibilities for overall main control.

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RESPONSIBILITIES OF CEC Immediately on being a ware of the emergency CEC will proceed to MECR. On reaching, he will-

• Assume full responsibility for overall control • Assess extent of the emergency and likely development organise action in the

following areas : • Immediate advise to OCE as to how to control the situation • Assistance in case of complete or partial evacuation if necessary. • Assistance in case of the evacuation if necessary. • Provision of equipment, material ad manpower etc tot control the situation. • Ensure that causalities and receiving adequate attention. • Ensure that all personnel at the factory are accounted for. • Arrange search and rescue of missing persons. • Arrange for a chronological record of the emergency to be maintained • Where the emergency is prolonged arrange for replacement of personnel and

provision of catering facilities. • Authorise information to be given to media. • Ensure that proper consideration is given to the preservation of evidence. • Control rehabilitation of affected areas on cessation of emergency.

ONSITE EMERGENCY COORDINATOR (OEC) : At the scene of emergency the person notified under the contingency plan of the affected factory will take up the responsibilities of Onsite Emergency Coordinator (OEC) and will remain in command at the site control room.

A Primary task of the OEC is to go to the scene of the emergency make an informal assessment of the situation and decide whether a major emergency exists or is likely to develop soon. On his decision he will inform the CEC and activate the emergency procedure

RESPONSIBILITIES OF OEC :

• Immediately on being aware that a major emergency exist at the factory :- • He should ensure that the concerned agencies are notified in the prescribed

manner • He will coordinate on scene emergency action as per in-house contingency

plan. • He will proceed to SCR and assume responsibilities of the post and remain

in command • He will keep MECR informed from time to time on – • Steps taken to fight the emergency. • Status of emergency at the time of reporting • Further actions necessary.

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ROLE OF DISTICT COLLECTOR MUMBAI SUBURBAN DISTRICT

• Exercise broad control on emergency operations • Give guidance / decision on measures of basic policy • Review operational preparedness of district emergency machinery • Hold periodic mock up / training exercise to ensure optimum operational

preparedness. If necessary, invoke help from the Army, the Air Force, the Government and any private industries in the are of MSD.

• Develop off-site scenarios based on-site Plans of the industries. • Relief Operation • o-ordination of all Local crisis Groups of the District • Act as Chief Controlling Authority of District Emergency plan. • Mobilise / Requisition / Pulling Together resources to Tackle emergencies. • Establish relationship between District Emergency plan (Crisis Group) and

State Crisis Group. • To requisite the resource available from the public works departments • Assessing the requirements for transit cams on the occurance of disaster. • Assisting the ward officer in requisitioning vehicles and temporary shelters. • Setting up of transit camps and pandals of temporary accommodation. • Arranging for food distribution. • Arrangement for clothing • Providing gratuitous relief. • Enlist support of NGOs and private sector for resources and manpower for

transit camps • Communicate to district control room details on the field activities including

development and reinforcement of staff and resourced of staff and resourced of staff and resources and communicate nature and additional requirements.

RESIDENT DEPUTY COLLECTOR – MUMBAI SUBURBAN DISTRICT

• Acts as an Alternate leader, Liaison Officer, Agency Chief, in disaster. • Check in at the incident command post. Ensure that all agency resources

have completed check-in. • Obtain briefing from liaison officer or incident controller. • Establish working location. Advise agency personnel on the incident that

the agency representative position has been filled. • Attend planning meeting as required • Provide input on use of agency resources if no resources use advisors are

assigned. • Co-operate fully with incident commander and general staff on agency’s

involvement at the incident. • Overseas the well being and Safety of agency personnel assigned

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• Advise liaison officer of any special agency need or requirements. • Determine, if any special reports or documents are require. • Report to agency dispatch or headquarters on prearranged. • Ensure that all agency personnel and / or equipment is properly accounted

for and released departure from the incident. • Give debriefing session with liaison officer commander prior to departure.

POLICE : LAW & ORDER

• Maintenance of Law and order and control of anti social element. • Cordoning off the area to restrict movement of onlookers, vehicular and

pedestrian traffic. • Shifting of injured to the hospitals on a priority and providing bandobast for

crowd control at the hospital. • Guarding of property / valuables in affected area • Providing easy access to rescue and relief personnel / vehicles • Ensuring proper identification, inquest procedure and corpse disposal • Panchanamas will be prepared as per procedure • Extensive mobile patrolling • Arrangement for transporting / shifting of standard or affected persons

through police vehicles and private vehicles • Use of public address system to provide information to the public Sign

boards may be used to provide information and declare areas out of bounds • Enlist support of Mohalla committees for maintaining peace and for rumour

control. • Information center to organize sharing of information with mass media and

community • Communicate to police control room details on the field activities including

deployment and reinforcement of staff and resources and communicate nature of additional requirements.

TRAFFIC • Control and monitor traffic • Diversion of traffic on alternate routes as and when necessary. • Provide information about traffic flow along various corridor especially

heavy traffic or congested roads. • Mobilisation towing cranes and towing of standard breakdown or those

vehicles obstructing movements. • Use PA system to provide information and direction to the public • Setting up of sign boards and display boards at strategic locations to give

information regarding traffic movement. • Enlist support of RSP, NCC, NSS, NGOs and voluntary organisations for

traffic management

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• Provide and coordinate arrangements for transporting shifting of stranded or affected persons through police vehicles and private vehicles

• Communicate to traffic control room details on the field activities including deployment and reinforcement of staff and resources and communicate nature of additional requirements.

• Assist emergency services in the performance of their duties.

RTO • Ensure strict enforcement of regulations laid down improve safety in

transportation of hazardous substances. • Organise Transportation, arrangement for evacuation. • Ensure TREMCARD is available in the tankers transporting hazardous

chemicals. • Divert tankers transporting hazardous chemicals in associating with traffic

police in case of disaster, Ganesh Chhaturthi / Chhaturdashi, any other festivals or Mass gathering to safer transport Route.

• Train tanker drivers in respect of the hazards during the chemicals transportation in consultation with MARG.

FIRE BRIGADE

• Fire fighting operations in the affected area. • Rescue and Salvage operations. • Transport of injured to the hospitals on priority. • Evacuation of persons from the affected area . • Neutralisation and dilution of toxic environment . • Mobilisation of all fire fighting units from various Source. • Training of fire service personnel in chemical disaster operations. • Stocking of special fire fighting agents and equipment for chemical

emergencies. • Adequacy of fire fighting / control measure at each industrial location. • Work out Mutual Aid Arrangement in the cluster. • Prepare Plan for Human Service required for the emergency response. • Formulate Chain of Command among the Fire Fighters. • Prepare Plan for Response Personal Safety. • Prepare Plan for Fire & Rescue. • List out of the Fire Fighters. • Communicate to fire brigade control room details on the field activities

including deployment and reinforcement of staff an resources and communicate nature of additional requirements.

MEDICAL SERVICES • First aid arrangement and availability of On-site requirements of industries. • Set up mobile First Aid Posts at Assembly points

46

• Mobilization of emergency medical and health service of Causality Clearance Centers and Base Hospital

• Public Health Service at. Reception Centres • Medical Supply of antidotes, special Medicine and life saving drugs. • Corpse disposal service. • Co-pt voluntary organization like Rotary Clubs and Lions Clubs • Prepare Plan for Health & medical • Training to Medical team Hospital staff for emergency response • Providing emergency treatment for the seriously injured at the hospital • Organising onsite treatment of injured with tagging and triage and transfer

of injured. • Emergency supplies of medicines and first aid • Post mortem and corpse disposal • Demarcate an area in the hospital for receiving patients tagging an triage • Coordinate with blood banks for emergency supply of blood • Setting up an information centre at the hospital • Communicate to BMC control room details on the field activities including

deployment and reinforcement of staff and resources and communicate nature of additional requirements.

BEST / MSTC/ RAILWAYS • Ensure availability of Buses / trains in case of evacuations. • Keep standby buses in readiness for deployment • Coordinate for transport arrangements of standard persons • Diversion of routes if necessary • Providing information to the public at bus depots regarding he cancellation

rerouting delays of buses, temporary shelter locations, of BMC and the aesures being undertaken

• Communicates to best control room details on the field activities including deployment and reinforcement o staff and resources and communicate nature of additional requirements.

TRANSPORT In case of Municipal Commissioner, Mumbai, takes the decision to evacuate persons of the nearby units and habitations to safer places, the services of the B.E.S.T. and M.S.R.T.C. in available number of buses at a short notice could be taken. The names and teleplone numbers are given with this note.

Vehicles can be mobilized by the Transport Commissioner, Government of Maharashtra on request.

BEST/BSES/TEC • Ensure electricity supply to all MAH units, streets, Police stations, Fire

brigades, Emergency Control Centre & Other Offices of emergency Response Personnel

47

• Cutting off power supply if necessary • Alternatives arrangements for power supply for lighting • Illumination of affected area as well as the periphery • Restoration of power supply • Keeping emergency gangs in readiness for repair work • Repairs to damaged power breakdown or short circuits • Coordinating with Fire brigade in case of fires or short-circuiting • Communicate with respective control rooms details on the field activities

including deployment and reinforcement of staff and resources and communicate nature of additional requirements.

EMERGENCY PLAN - COMMUNICATION SYSTEM If one were to examine closely and patiently the nature, variety and geographical sector of Chemical Industries in are in question, one would gradually perceive and visualise many problems that will simultaneously occur, should emergency arise inmost of these industrial units. Many incidents in the past 24 months have demonstrated these problems.

To meet an emergency, following a devastating fire, explosion, toxic release, corrosive spill, etc endangering community life and property, speedy response by emergency service authorities (i.e. Police, Fire, Brigade, Medical Services) is absolutely essential. Speedy emergency response by appropriate authority in good time and in correct sequence is often referred to as "first strike" is emergency parlance.

One single system on which speedy emergency response of "first strike" is critically dependent is communication.

In the area underquestion, the identified factories are communication with the Fire Brigade, Police and Medical Services by telephone system i.e. point - to - point voice communication. It is important to recognise a fundamental aspect right a t the outset that, fixed location office communication system cannot ensure speedy response by emergency services. However, we have to make optimum use oif the facilities available with us so as to reduce the time of "first Strike" as much as possible. It is seen that the hazardous factories are located in five Exchange areas i.e. Ghatkopar (2511, 512 and 513 ), Chembur (52); Powai, Vikhroli, Tagore Nagar and Kannamawar Nagar(58), Mankhurd (551, 555), Mulund (560, 561). In case of andy fault in the exchanges or instrument or any other urgent services required, the concerned Divisional Engineer can be directly contacted either at his office or at his residence at any time to seek his assistance.

In addition to the above, the important elephone Nos. Could also be identified as Emergency Numbers and the concerned Telephone Exchanges may be requested to consider the above numers as dedicated direct lines (DDL) so that, all such Telephone Numbers will be urgently tested regularly by the personnel in the Exchanges and maintained in working order at all time.

48

Considering the limitation of the point- to -point voice communication in the times of emergency, it is recommended as follows :-

• All the hazardous factories identified, should be connected by hot-line system with the concerned police stations, Fire Brigades and. Medical Institutions.

• The Control Room of the Mumbai Municipal Corporation – Control Panel consisting of 32 hot-line is should also be connected by hot-lines individually to each hazardous unit so that the red light in the Control Room will give an indication of any emergency in any connected unit.

• Control Room of the Mumbai Municipal Corporation should also be connected to the hot-line to police Authorities, Fire Bridge and Medical, Authorities, Evacuation agencies and various other concerned agencies so that first strike time can be reduced as much as possible.

• During the time of emergency, it may be necessary to communicate with various agencies, which may be fixes / fixed, fixed / mobile and mobile / mobile units. It is therefore, suggested that special frequency mobile communication system may be worked out in consultation with the Telephone Department.

CIVIL DEFENCE/HOME GUARDS To supplement the role of police and the salvage corps, additional man-power may be required and the same will be provided by Home guards Organisation There are 16 Offices of the honorary officers of the Home guards in Great Bombay. The services of the Home Guards can be utilised in case of an accident. Addresses and telephone numbers of various offices of the Horn Guards are given in this Note.

DISTRICT INFORMATION OFFICER The information officer, a member of the command staff is responsible for the formulation and release of information about the incident to the news media and other appropriate agencies and organizations.

• Obtain briefing from incident commander • Contact the jurisdiction agency to co-ordinate public information activities. • Establish single incident information center whenever possible • Arrange for necessary work space. Materials telephones, and staffing • Prepare initial information summary as soon as possible after arrival. • Obtain approval for release from incident commander • Obtain approval for release from incident commander • Release news to news media and post information in command post and other

appropriate locations. • Attend meetings to update information releases. • Arrange for meeting between media and incident personnel • Provide escort service to the media and VIPS • Provide fire retardant clothing for media and VIP’S • Respond to special requests for information • Maintain and submit all records and logs.

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DISTRICT SUPPLY OFFICER : He is responsible for detemining feeding requirements at all incident facilities, menu planning, determining cooking facilities required : and general maintenance of the food service areas.

CHIEF ENGINEER, BMC :

• Report to and obtain briefing and special instructions from RDC MSD. • Participate in the development of the Incident Action Plan, and review general control

objectives including alternative strategies presently in effect. • Collect and validate water resource information within the incident actions. • Prepare information on available water resources. • Establish water requirements needed to support fire suppression actions. • Compare incident control objectives as stated in the plan with available water

resources and report inadequancies or problems to RDC MSD. • Participate in the preparation of Incident Action Plan when requested. • Respond to requests for water Informations. • Collect & transmit records & logs to documentation unit at the end of each operational

period. • Maintain & Submit all records and logs.

CITY ENGINEER, BMC • Organise Reception Centers at Assembly points • Co-ordinate resource of voluntary organization • Prepare Plan for the public work • Assist to prepare Plan to Regional Officer MPCB of containment & Clean-up

DIRECTORATE OF INDUSTRIAL SAFETY & HEALTH (DISH) • Ensure On-Site plans of industries are vetted and approved as per Act. • Visit industries to see that safety norms are being followed. • Ensure development of On-Site Plans, • Examination of risk evaluation study and Safety Audit • Ensure frequency of Safety Audit and Mock Drills (Fire) • Assist the District Collector in developing Off-Site scenarios. • Ensure Safety Education, Safety awareness. Discussion along with MARG. • Pre-emergency & Post emergency Task. • Assistance in supplying information to service agencies from factory management • Making enquiries to find out case of disaster.

MAHARASHTRA POLLUTION CONTROL BOARD : • Monitor extent and quantum of pollution during the crisis • Declare hazardous area safe for re-occupation by population. • Prepare plan for the Containment & Clean-Up. • Prepare Plan for on-going incident assessment.

CONTROLLER OF EXPLSIVES (CCOE)

• Assistance in supplying information to service agencies from factory management • Making enquiries to find out cause of disaster.

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CHAPTER 9 : WARNING SYSTEM _______________________________________________________________________________ A good warning system is one of the most important pre-requisite of the emergency management system to save lives, prevent injuries and mitigate losses. As soon as incident controller determines that it is necessary to warn people of a threat to public safety, a strategy appropriate to the situation will be developed and immediately implemented to ensure coverage of the affected area. The dissemination of warning shall be effected by the MAH Factories.

TYPES OF WARNING :

Warning signal will be given as under :

DISASTER WARNING : The warning signal shall be high pitched long wailing siren followed by short wailing siren.

ALL CLEAR : Long continuous note

DISSEMINATION OF WARNING BY THE FACTORIES :

Depending on the nature of the hazard, the size of the population of the area threatened and the time available to react, one or more of the following methods would be used to warn the public.

• Outdoor warning siren • Public addressed system (Vehicle mounted) with the police • Remote public address system • Siren • Mass media i.e. Radio and Television • Door-to-door visits by Civil defence personnel using mask and relaying

prerecorded cassette messages.

Telephone calls to sensitive locations like schools, organizations and institutions having a large number of employees.

In case of a toxic gas emanating from present area on to the neighboring area due to prevailing wind direction, the information will be relayed to the district Collectorates for warning the likely affected population under their jurisdiction.

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CHAPTER 10: PERSONAL PROTECTION OF CITIZENS _______________________________________________________________________________

PLANNING TEAM :

• Deputy Collector - In-charge • Additional Controller of Civil Defence Mumbai • DCP • Chief Executive Health Dept BMC, • Education Officer BMC • City Engineer BMC • Executive Engineer PWD • RTO Mumbai • District Information Officer Mumbai • General Manager Central/Western Railway • Depot Manager MSRTC/BEST • General Manager MTNL

These team members shall prepare detailed contingency plan :

Factors:

a) Vulnerable zones where Evacuation could be necessary & method for notifying these places

b) Provisions for precautionary Evacuation c) Methods for controlling traffic flow and providing alternate traffic routes. d) Shelter location and other provisions for evacuations. e) Agreements with near by jurisdictions to receive evacuees. f) Agreements with Hospitals outside the local jurisdictions. g) Protective shelter for relocated populations. h) Reception and care of evacuates. i) Re-entry procedures. j) A system of working and advising the public protection and on

expedient means to reduce ventilator. k) Relocation l) Water supply protection- to avoid contamination m) Sewage system protection: to avoid public Health threat Environment

problems.

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CHAPTER 11: EVACUATION PLAN _______________________________________________________________________________

In a disaster situation, evacuation from hazardous areas may be the most effective way to obviate casualties. It is a complex exercise requiring multidisciplinary inputs. A comprehensive and co-ordinated preplanning is necessary to implement orderly evacuation of population. The weather conditions obtained through the meteorological department / Weather Monitoring Station would dictate to a large extent the area to be evacuated.

On hearing the disaster warning the population should quickly move to the assembly area as announced on the public address system and should wait for the transportation facility. If assembly area is not announced than they should move out of the threatened area at the right angle to the prevailing wind away from the industrial area. Those personnel who can move out of their homes are advised to stay indoors and cover their noses with the wet cloth.

Following steps would be taken before the crisis by the District Emergency Authority MSD :

• Public information and education on measures for chemical hazards. • Installations of siren or Remote public address system in likely affected

area. • Formulations of detailed contingency plan of evacuation. • Working out evacuation plan of sensitive areas like Jail prisoners,

Mental/other hospitals etc.

LIMITATIONS:

While in many cases evacuation is a needed life saving measure, it is not always necessary or practical. Lack of time is often the single most important limitation on the effectiveness. Large evacuation takes very long time to execute even if they are well planned in advance. The toxic cloud may pass through an area before everybody can get out when people are outside their homes, attempting to evacuate.

Keeping the area situation into account, it may be possible to stress more on the in Place Protection and attempting to reduce the airflow into their shelter. Public education on the protection provided by a structure should be a part of preparedness activities.

ASSEMBLY AREA:

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The assembly points shall be the big open spaces around the area identified well before the accident happens. The assembly area shall also act as a Reception Centres, as the population will be displaced temporarily for a short duration.

Arrangements for water, first aid, and possibly food (if duration of emergency is long) shall also be made. Lighting arrangements also will be provided.-

Resident District Collector (Administration) shall ensure that all the Emergency response Agencies knows address & locations of Ail MAH units.

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CHAPTER 12 : CONTAINMENT AND CLEANUP _______________________________________________________________________________

PLANNING TEAM • Regional Officer MPCB – Incharge • Dy. Municipal Commissioner. • Chief Fire Officer Mumbai. • RTO Mumbai. • Coast Guard: • Chairman MARG • Expert From MAH industries • NGO. • D.C.P Navi Mumbai. • Ref. Of Transport Contractor.

TECHNIQUES FOR SPILL CONTAINMENT AND CLEANUP. Factors Responsibilities

Containment and mitigation action. Mumbai Cooperation

Cleanup methods LCG

Restoration of the surrounding environment

District collector

Comment :- LCG will typically emphasize the containment and stabilisation of an incident state regularity agencies can focus on cleanup details. ECG can provide assistance during the cleanup process. It is the releaser legal and financial responsibility to clean up the minimize the risk to the health of the general public and workers that are involved. CCG and other government official should monitor the responsible party cleanup activities.

Workers that are involved. CCG and other government official should monitor the responsible party cleanup activities.

A clear and succinct list of containment and cleanup countermeasures should be prepared for each hazardous material present in the community in significant quantities. This section should coordinated with the section on "Response Personnel Safety" So that response team applicable to the hazardous material and terrain area. It may be helpful to include sketches an details on how cleanup should occur for certain area where spill are more likely.

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CHAPTER 13 : TRANSPORT EMERGENCY _______________________________________________________________________________ Maharashtra is the first State in India which has introduced certain regulations for the transportation of hazardous chemicals and goods by Road Transport. Since large number of tankers and vehicles have to carry hazardous substances, it is necessary to take special precautions to avoid loss if life and property. In view of this, additional permit conditions on the vehicles used for carrying hazardous substances have been incorporated. These vehicles are required to prominently display labels and information regarding the hazardous materials under transport. The additional permit conditions and the order under these permit conditions are based on the recommendations of the Committee of U. N. Experts and these recommendations are accepted by almost all developed countries. The additional conditions to permit transportation of hazardous substances are :-

No public or private carrier should carry hazardous chemicals unless the following conditions are followed :-

• Special labels or notices should be prominently affixed on packages or on vehicles, bearing 'Emblems' specified by the Transport Commissioner of Maharashtra State, Mumbai, pictorially representing particular danger arising out of any hazardous chemicals.

• Chemical names, descriptive names or prescribed 'correct technical names' should invariably be displayed on packages or vehicles carrying hazardous chemicals.

• The drivers of all road vehicles carrying hazardous chemicals must carry with term instructions in Writing' relating to each dangerous substances or to each class of dangerous substance whether covered in packed form (i.e.) in tins, drums, etc.) or in bulk road vehicles. The instruction including First-aid treatments and advice for dealing with fire, accident, spillage or leakage must be written in English, Hindi and Marathi and in the language of the state of transit and destination. These instructions in writing should be obtained from the Company which load a hazardous chemical for transportation.

• A Summary of these instructions in writing in a card from called 'A’ Transport Emergency Card (Tremcard)' should also be carried by the driver in his cabin. The tremcard should be provided by the party / supplier / chemical company loading the said material.

• Special signs or plates denoting that dangerous goods are being conveyed should be displayed which will identify the substance and also reveal its hazardous properties and indicate what action should be taken in emergencies.

EMERGENCY PROCEDURE

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The driver of the vehicles should be instructed that in the events of an emergency, prejudicing the safety of the load or of the public e.g. a traffic accident or a leaking tank, his first responsibility should be to arrange that the police and emergency services are alerted and that assistance is given to any person who is in immediate danger or who has suffered injury. Further action by the driver to tackle a fire or contain a spillage, should be undertaken only if it is considered safe to do so having regard to the circumstances of the emergency, the nature of the load being conveyed and the safety equipment available on the vehicle. The driver should also be instructed to carry out as appropriate and where safe to do so, the following procedures in such order as circumstances dictate :-

• Stop the engine; • Where fitted, turn off the battery isolating switch; • Operate the emergency warning flashing device, but only in such

circumstances where there is no likelihood of it igniting any flammable vapour which may have escaped;

• Move the vehicle to a place where any leakage would cause less harm or damage;

• Where carried, place a hazard warning device, e.g. a red triangle, in position to the rear of the vehicle and of only spillage:

• Wear appropriate protective clothing; • Keep people away form the same; • Prevent smoking and keep other vehicles out of any fire risk area; and • Remove the written information provided (i.e. the TREMCARD) from the cab

if it is likely to be damaged by fire or later become in accessible. When the police and fire brigade arrive at the scene of the Incident they will take charge and the driver should be instructed to –

• Show them the written information concerning the substance(s) being carried e.g. the TREM CARD;

• Tell them all he can that is helpful concerning the load. The driver should be acquaint the operator with particulars of the emergency at the earliest opportunity.

The drivers of road tankers and vehicles conveying tank containers should have sufficient knowledge of the properties and hazards of the dangerous substance(s) they are conveying to enable them to understand and appreciate the dangers and risk involved whilst undertaking the duties.

The Transport Department has also devised the various class labels to be provided on vehicles carrying hazardous chemical properties of the substances which are being transported.

These guidelines should be followed so as to avoid any mishap.

It is further suggested that in the events of any disaster during transportation of hazardous chemicals, a neutralisation squad should be established which would act immediately to minimise the consequences.

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There should also be an effective communication system established between the manufacturer, transport user, police, fire brigade and medical services.

Such neutralisation squad consisting of-experts and trained personnel should work under the control of Fire Brigade. Formation of such squad could be finalised with consultation with transport department, users of hazardous chemicals and transporters.

While preparing off-site disaster control plan for the area under question where hazardous industries are situated, it was thought fit to include this chapter. Thick population on both sides of roads in these area emphasis the need for such plan.

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CHAPTER 14 : TESTING AND UPDATING PLAN _______________________________________________________________________________

PLANNING TEAM :

• District Collector Mumbai Suburban District • Jt/Deputy Director Industrial Safety & Health & Member Secretary Local

Crisis Group • Chief Fire Officer Mumbai Fire Brigade • DCP Mumbai (Chembur / Mulund / Andheri / Borivali) • Additional Controller Civil Defence Mumbai • Member Secretory MPCB Mumbai • Chief Executive Health Dept BMC • District Health Officer MSD • Medical Superintendent BMC Hospitals • RTO Mumbai • All MAH Industries in the area • Commander, Coast Guard • Technical Experts in MSD • NGO's • District Information Officer MSD • Representative of TV/Radio • Editor of Prominent news Papers • Executive Engineer PWD • Co-ordinator MARG

TESTING THE PLAN Factors : Provision For Regular Table Top, Functional, Mock & Full Scale exercises Organisation In-charge Of the Exercise Types of the Exercise Frequency of Exercise DRILLS AND SIMULATION EXCERCISES : The regular drills and simulation exercises is a progressive commitment to ensuring that the personnel, Organisational structure, and resources identified in the area plan can function to achieve the most favourable outcome in the event of real accident. The terms used in this exercise are defined as: Orientation Seminars : The orientation seminar is an informal activity which focuses on training and familiarizations with roles, procedures, responsibilities, and personalities in the management plan. The general purpose is for participants to review plans and procedures in a low stress no "real-time environment with little or no attempt at any simulation.

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Table Top Exercise : The tabletop exercise provides a specific simulation exercise whose focus is on reviewing the plans and procedures unique to the situation. This exercise makes sure that all the participants have reviewed the plan details in an interactive fashion. Functional Exercise : The exercise is designed to taste or evaluate individual function. Each function is exercised separately. As far as possible the functional exercises should be held near the site. Full Scale Exercise : This is done by simulating an event. Exercise Cycle : The exercise cycle is a calendar of events reflecting a series of exercise that moves the area in the direction towards preparedness. A good exercise cycle is updated regularly to account for changes in the area plan. A recommended exercise cycle may look as below. Exercise Type

Purpose

Participants

Time

In-charge

Orientation

Review Plan

Planning Team Members

Half Yearly

District Collector MSD

Tabletop

Review Co-ordination

Emergency Management staff & Responders

Quarterly

Chief Fire Officer \ MFB

Orientation

Evacuation Procedures

Emergency Management Staff & responders, community leaders

Half yearly

Chief Fire Officer Addnll Controller Civil Defence & Police Authorities

Tabletop

Risk Communication

Emergency Management Staff, Information Officer, Media

Half Yearly


Functional Simulated Evacuation

Media

Yearly


Full Scale Simulated toxic gas release

All emergency response system personnel and volunteers

Half Yearly District Collector MSD

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To make any specific comments and / or suggestions for Plan improvement following format can be used. Format For Comments : Name of the Department/Agency : Address : Contact Name : Phone Number : Fax Number : Suggestions for Plan improvement : Errors or inaccuracies noted in this plan: Signature : Date :

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CHAPTER 15 : GENERAL GUIDELINES IN DISASTER

(PERSONAL PROTECTION OF CITIZENS) _______________________________________________________________________________

• Keep calm

• Don’t Panic

• Cover mouth and Nose with wet cloth

• Don't spread rumour

• Don't crowd at incident sight

• Walk fast at right angle to the wind direction

• Close doors and windows in case of toxic gas release

• Turn off LPG gas in case of inflammable Gas leakage

• Keep phone tines clear

• Inform Police & Fire brigade

• Follow direction from proper authority

• Keep the road clear

• Give way to Emergency vehicles immediately

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CHAPTER 16 : SAFETY PRECAUTIONS (RESPONSE

PERSONNEL SAFETY) _______________________________________________________________________________

APPROACH CAUTIOUSLY FROM UPWIND: Resist the urge to rush in; others cannot be helped until the situation has been fully assessed. SECURE THE SCENE: Without entering the immediate hazard area, isolate the area and assure the safety of people and the environment, keep people away from the scene and outside the safety perimeter. Allow enough room to move your own equipment. IDENTIFY THE HAZARDS : Placards, container labels, shipping documents and / or expert persons on the scene are valuable information sources. Evaluate all available information and consult the recommended MSDS to reduce immediate risks. ASSESS THE SITUATION : Consider the following:

• Is there a fire, a spill or a leak? • What are the weather conditions? • What is the terrain like ? • Who/what is at risk: people, property or the environment ? • What actions should be taken:, Is an evacuation necessary ? • Is diking necessary ? What resources(human and equipment) are required and are

readily Available ? • What can be done immediately ?

OBTAIN HELP : Advise your ECC notify responsible agencies and call for assistance from qualified personnel. DECIDE ON SITE ENTRY : Any efforts made to rescue persons, protect property or the environment must be weighed against the possibility that you could become part of the problem. Enter the area only when wearing appropriate protective gear (see the MSDS on protective clothing and equipment). RESPOND: Respond in an appropriate manner. Establish a command post and lines of communication. Rescue casualties where possible & evacuate if necessary. Maintain control of the site. Continually re-assess the situation & modify the response accordingly. The first duty is to consider the safety of the people in the immediate area, including your own. ABOVE ALL: Don't walk into or touch spilled materials. Avoid inhalation of fumes, smoke & vapours, even if no dangerous chemicals are known to the involved. Don't assume that the gases or vapours are harmless because of lack of smell odourless gases or vapours may be harmful.

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CHAPTER 17 : GUIDE ON ANTIDOTES _______________________________________________________________________________

Antidotes are therapeutic agents used to counteract the toxic effects of specific xenobiotics. These are heterogeneous group of substances consisting pharmaceuticals, biological agents and immunoglobulin fragments. Different mechanisms of action are involved. Some specifically act at the receptor sites while others exert their effect by changing the metabolism of the poison, counteracting the toxic injury or just forming the inert complex with the poison. Antidotes should be given in adequate doses as early as possible in case of poisoning. Some antidotes cause serious adverse reactions. Hence, both the risk and the benefits of the antidotal therapy must therefore be carefully evaluated and the patient must be monitored regularly. At times the half-life of some antidotes like naloxone, atropine is much shorter than the toxin, in which cases the antidotal therapy must be continued till symptoms of the poisoning subside. Thus knowledge and expertise on the proper use of antidotes is mandatory for controlling the effects of poisoning. Some common chemical antidotes:

- Common salt : it neutralizes silver nitrate to silver chloride. - Albumen : it precipitates mercuric chloride. - Dialysed Iron : it neutralizes arsenic. - Copper sulphate :precipitates phosphorous - Alkali : (alkaline hydroxide, milk of magnesia, ammonia) it neutralies acids. Do

not use bicarbonates to neutralize acids as carbon dioxide is liberated and accumulated in stomach which may rupture the stomach.

- Potassium permanganate (1:5000): at this concentration it loses its pink color. It oxidizes phosphorous strychnine, cyanide, atropine, barbituric acid.

- Tincture Iodine or Lugols (15 drops of iodine in glass of warm water): it precipitates lead, mercury, silver, quinine.

- Tannic acid (4% in water) of Tannin in strong tea : It precipitates nicotine, cocaine, aconite, lead, silver, cobalt, aluminum, copper, zink, mercury, nickel.

UNIVERSAL ANTIDOTE - 2 parts of charcoal powder plus 1 part of tannic acid plus 1 part of magnesium

oxide, mix 1 tablespoon in tumbleful of water and give to victim to drink, repeat 2-3 times.

CHELATING AGENTS - BAL (British Anti Lweisite, Dimercaprol) : it is an antidote for arsenic, lead,

bismuth, copper, mercury, gold and heavy metals. 3-4 mg/kg deep IM 4 hourly for first 2 days then BD for 10 days

- E.D.T.A. (Ethylene Diamine Tetra Acetic Acid) : It is used in lead, mercury, copper, cobalt, cadmium, iron and nickel poisoning. Use 25 mg/Kg in 500 ml of 5% glucose or saline twice a day for 5 days.

- Penicillamine : Give orally 0.5 mg/day for 4 times a day for 7 days (30 mg/kg) for heavy metal poisoning.

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ANTIDOTES COMMONLY USED AGAINST SPECIFIC AGENT

Specific Agents Symptoms requiring Treatment

Antidotes Dosages

Acetaminophen Hepatotoxicity N‐acetylcysteine Oral: 140 mg/kg initial dose following by (Tylenol, Nebs#) (hepatocellular necrosis) 70 mg/kg every 8 hours for 17 doses. Anticholinergic agents Central and/or peripheral Physostigmine Adults: 1 or 2 mg IV slowly (1 mg per min) Anticholinergic symptoms & Repeat in 20 minutes if no reversal Atleast one of the following Then 1 to 2 mg IV for recurrent symptoms. Hypertension Children: 0.5 mg IV (0.5 mg/min) Hallucinations Re‐administer at 5 minute intervals to Convulsions Maximum of 2 mg if symptoms persists. Coma Repeat with lowest effective trial dose if Arrhythmias Life threatening symptoms recur. Cholinergic agents Cholinergic crisis Atropine Sulphate Adults : 2 mg IV Physostigmine Diaphoresis Children : 0.05 mg/kg IV, repeat until Neostigmine Lacrimation cessation of secretions. Pyridostigmine Bronchial secretions Pilocarpine Excessive unination/defcat Bethanechol Convulsions Methacholine Fasciculations Cynide (potassium Cynosis Sodium nitrite Adults : 300 mg IV (10 ml of 3% solution) Cyanide Cardiopulmonary arrest Then Children : Dose based on serum Hydrocyanic acid Convulsions Sodium thiosulfate Hemoglobin. Laetrile Coma Adults: 12.5 grams IV (50 ml of 25% soln) Nitroposside sodium Cobalt E.D.T.A. Ethylene Glycol Acidosis Ethanol Loading dose: 600 mg/kg (1 ml absolute Oxalate crystals in urine Alcohol =790mg) IV in D W over 15 minute Maintenance dose : to maintain blood Level of 100mg% it varies depending on Drinking history of patient Neuroleptic agents Haloperidol Extrapyramidal symptoms Diphenhydramine 25 to 50 mg IV, IM (Haldo #1) Dystonia Or Or Loxapine succinate Dyskinesia Benztropine 1 to 2 mg IV, IM (Loxitane#) Oculogyric crisis Molindone Parkinsonian symptoms (Moban#) Phenothiazenis Chlorpromazine (thorazine#) Fluphenazine (Prolixin#) Thioridazine (Mellaril#)

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ANTIDOTES COMMONLY USED AGAINST SPECIFIC AGENT

Specific Agents Symptoms requiring Treatment

Antidotes Dosages

Iron salts (ferrous Hypotension Deferoxamine Shock and / or Coma : 15 mg/kg/hour IV Sulfate, ferrous Shock For 8 hours Gluconate) Coma Absence of shock or coma but SI TIBC: (free serum iron present) 90 mg/kg IM every 8 hours x 3 doses. Methanol Acidosis Ethanol Loading dose: 600 mg/kg (1 ml absolute Alcohol =790mg) IV in D W over 15 minute Maintenance dose : to maintain blood Level of 100mg % it varies depending on Drinking history of patient Methemoglobin ‐ Methemoglobinemia Methylene blue 1 to 2 mg/kg IV (0.1 to 0.2 ml/kg) of 1 Producing agents (30%) Percent solution. Nitrates / Nitrites Not: Contraindicated in Phenazopyridine Methemoglobinemia secondary to Phenocetin Sodium nitrite in cyanide poisoning. Narcotic analgesics Respiratory depression Naloxone Adults : 0.8 mg IV, IM, SC And related Hypotension Children : 0.01 mg/kg IV, IM, SC Coma Repeat at 10 x(times) origimal dose if no Response Organophosphate Cholinergic crisis Atropine Sulfate Adults : 2 to 4 mg IV slowly; repeat every Insecticides Diaphoresis 10 to 30 minutes to attain and maintain Malathion Lacrimation Stropinization (decreased bronchial Bronchial secretions Secretions Excessive unination/defcat Children : 0.05 mg/kg IV. Slowly repeat Convulsions Every 10 to 30 minutes at attain and Fasciculations Maintain atropinization. Profound weakness Pralidoxine After atropine Muscular twitching Adults : 1 g IV (500 mg/minutes) Repeat x 3 at 8‐12 hour intervals if Muscle weakness not relieved Children : 25 to 50 mg/kg IV Repeat x 3 at 8‐12 hour intervals if Muscle weakness not relieved

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ANNEXURE – I

CHEMICAL FACT SHEETS OF MAJOR HAZARD UNIT FACTTORIES MUMBAI

SUBURBAN DISTRICT

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AEGIES CHEMICALS INDIA LTD

1. FACTORY IDENTITY a) Name Aegies Chemicals Industries Ltd.

b) Address

Plot No. : 72, Mahul Village, Trombay, Mumbai - 400 074.

c) Telephone Nos. / Telex /Fax Nos. / E-mail Address.

Phone : 255448832, 2554163. Fax : 5541969 & 5541105. E-Mail: egiscd(5)bom3.vsnl.net.in

d) (Location) Railway Line / Highways, passing through / near the area. If so, details of rail / road, crossings / bridges and water way vicinity.

e) Details of Human habitation (village, City, Residential colony. Hospital etc. near the factory etc. near the factory within 1 Km.)

None within a Km

2. a) Contact personnel of the factory their Phone Nos., Designations, Mobile

D. K. Bheda, General Manger Office Phone: 25544975; Mobile: 9821038819 Residence Phone – 27801427 P. H. Darji, Mgr, Chemical Storage, Office Phone: 25541105; Mobile: 982118909 Residence Phone: 27824455.

b) Name of the technical experts designation & their phOone Nos.

Dr. S. K. Biswas, Group Advisor (Safety & Environment) Office Phone: 22057076 / 2082242. Residence Phone- 2183288 S. K. Hazra, Managing Director, Phone: 22057076 / 22082242 Mobile: 9821018104; Residence : 22185743 D. J. Kulkarni, Advisor Fire fighting, Office Phone :2 7241740 Residence Phone: 25153548.

c) Name & phone nos. of incident & Site Controller.

D. K. Bheda, (LPG), Office Phone: 25544975: Residence Phone: 27801427.

3. Principal Manufacturing Activities

It is not a manufacturing unit. It is a terminal for storing bulk liquidChemicals and liquefied petrochemical.

4. Total No. of workers employed 96 Nos.

5. Maximum No. of persons, who may be present in the factory at any one

70 Nos. (General Shift)

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time.

6. No. of workers directly involved with the hazardous chemicals / shift / total.

7 Nos.

7. Maximum quantity of hazardous chemicals stored and their mode of storage (Raw Materials, Intermediate products, bye-products, finished products).

Liquid Chemicals: Maximum quantity in storage at one time 40,000 T in atmospheric cone roof tanks with Nitrogen blanketing when required. LPG: Maximum Quantity 19,OOOT full containment, double wall atmospheric cryogenic storage tanks.

8. Maximum'Credible Loss Scenario:

a) TOXIC DISPERSION: Not Applicable.

Brief description of Maximum Credible Loss Scenario In case of:

i) Atmospheric Stability Stable Neutral Unstable

ii) Wind Velocity 2m/sec 4 m/sec 6 m/sec

b) IN CASE OF BLEVE, VCE, POOL FIRE AS APPLICABLE

Max. Credible Loss Scenario In case of BLEVE

VCE Pool Fire as applicable

Worst case scenario is fire in bund area due to LPG tank leak. It is a Non-Credible Scenario (Probability once in one billion years)

Heat Radiation

a) Severe Damage to life and property (within cloud)

None. b) 100% lethality (37.5 Kw/m2)

c) 50% Lethality (25 Kw/m2)

No credible off-site effect

d) 1% Lethalitv (12.5 Kw/m2)

e) First Deciree 4.5 Kw/m2

f) No discomfort 1.6 Kw/m2.

a) Damage distance due to 0.3 bar pressure

9. Consequences of Major Hazards that are likely to occur in case of process

No pressing activity involved. Fire inside the terminal because of spillage, even it occurs wilt

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upsets and storage.

be contained within the terminals.

10. Resources Available

Details of fire fighting equipments available in the factory

a) Fire tender / Trailer pump and its capacity

: TATA Model LPT 1612 / 42 FFC Water Tank Capacity : 3000 Litres. Foam tank capacity : 1000 Litres. 2270 lpm at 7 kg/cm2.

b) Maximum quantity of foam available.

: 1000 Litres.

c) Water storage tank and its capacity

: 7000 m3 per day municipal make up water.

d) No. of hose reels and total length

: 66Nos.X1bm.

h) No. of fire Suit

: 01 Nos

11. Details of communication available to contact Police and Fire brigade in case of emergency

a) Telephone

: 5544832 / 55040709 / 5541463 / 5546734 / 5541961

b) Hot Line 1 Hotline to IPCL

c) Wireless

Wireless connection with IPCL.

d)Walkie Talkies etc.

9 Nos. Walkie talkie.

12. Public Alert System and its procedure

Long distance Electrical Siren (5 Km).

13. List of protective equipments available in Factory

i) No. & type of emergency kit

First Aid Box -4 Nos.

ii) No. of Self contained breathing apparatus

1 Set.

iii) No. of air line respirators

1 Nos.

iv) No: of canister respirators : 10 Nos.

v) No. of acid suits.

: PVC suit.

vi) Any other personal protective equipments.

: Helmet, Face shield. Safety goggles, ear plugs, ear muffs, hand gloves, Safety shoes, blowman mask.

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14. Medical facility available in factory : N. A.

i) Equipments available in Ambulance room.

ii) Antidotes available : N. A.

iii) No. of first aiders available : 28 Nos.

iv) Ambulance Van or alternate arrangement

: Jeep – 2 Nos

v) Details of hospitals in the vicinity and any the up with them.

: Permanent arrangement with Inlaks Hospital, Chembur Colony.

15. Provision of emergency lighting : Yes.

16. Hazardous chemicals transported

a) Quantity (MT / day) 400 1600 120

b) Name of the Chemical LPG Naphtha LPG

c) Type of carrier Pipeline Pipeline Tanker

d) Principal destination IPCL NOCIL

17. Site plan of factory showing internal roads, location of storages of hazardous chemicals, buildings etc.

: Attached as Annexure.

22. Any other relevant information

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BHARAT PETROLEUM CORP. LTD. – REFINERY DIVISION

1. FACTORY IDENTITY

a) Name

BHARAT PETROLEUM CORP. LTD. REFINERY DIVISION

b) Address Mahul, Chembur

Mumbai – 400 074.

c) Telephone Nos. /

Telex / Fax Nos.

E-mail Address

Telephone : 2554 3151,

2554 2990, 55401

51, 25540390

Telex : 61058

Fax : 5542970

d)Details of Human habitation (Village, City Residential colony, Hospital etc. near the factory etc. near the factory within 1 km.)

East Side – HPCL, Gawanpada

West Side – Mahul Village

North Side – HP Nagar

South Side – Tata Electric Company Aegis Chemicals

2. a) Contact personnel of the factory their Phone Nos., Designations, Mobile Phone Nos.

b) KV Seshadri

GM (Process)

Off : 5540157 Resi : 5546069

c) CS Chakrabarti

DGM (Fire & Safety)

Off : 5543827 Resi : 3860751

3. Pricipal Manufacturing Activities : Processing of crude oil by various physical and chemical separation process to produce value added products

4. Total No. of workers employed : 3001

(Clerical – 235; Labour – 2099; Staff – 667)

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5. Maximum No. of persons, who may be present in the factory at any one time.

: 1272


: 1763

7. Maximum quantity of hazardous chemicals stored and their mode of storage (Raw Materials, Intermediate products, bye-poducts, finished products)

Maximum quantity of hazardous chemicals with a potential of causing Maximum Credible Loss Scenario

Chemical (MT) Type of Storage

Propylene 275 Horton sphere

LPG 1537 Horton here

8. Maximum Credible Loss Scenario:

a) Toxic Dispersion Not Applicable

b) In case of BLEVE, VCE, POOL FIRE as applicable

Brief Dscription

BLEVE :

The worst accident as assessed by M/s. NEERI is attributed to BLEVE of C3 sphere

VCE :

The worst accident situation on account of explosion is attributable to the vapor cloud explosion (VCE) of C3 sphere

POOL FIRE :

There is no scenario for pool fire which have impact outside the refinery


(Damage Distances in Meters)

Heat Radiation NA

a) 50% Lethality (25 Kw/m2) 669 mts

b) 1% Lethality (12.5 Kw/m2) 843 mts

c) First Degree 4.5 Kw/m2 of burns 1150 mts

d) Damage distance due to 0.3 bar pressure wave In case of VCE 91 mts

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9. Details of fire fighting equipments available in the factory

a) Fire tender / Trailor pump and its capacity Foam Tenders 5 Nos

3 Nos. 6000 LPM at 8-12 Kg/cm2

1 No. 4000 LPM at 7 kg/cm2

1 No. 3000 LPM at 7-12 kg/cm2

Dry Chemical Powder Tender 2 Nos.

1 Tender with two DCP vessel of 700 Kg Monnex DCP each.

1 Tender with two DCP vessel of 1000 Kg Monnex DCP each.

Foam Nurser 1 No 7600 Lits

Emergency Equipments Carrier 1 No.

b) Maximum quantity of foam available

95,500 Lit AFFF

(Aquenous Film forming Foam)

c) Water jet monitors Nos.

: 4 Nos. (2 Nos. HVLR & 2 Nos. Super Jet

d) Water storage tank and its capacity Raw water 2 X 12,000 KL Tanks at LPG FF Pump House

Sea water basin 13,000 KL at SWPH with facilities for continuous replenishment

e) No. of hose reels and total length 300 Nos. Hoses (300 X 15 mtr. ) = 4500 mtr.

f) No. of fire Suit : 8 Nos.

4 Nos. = Proximity

2 Nos = Fire Suit

2 Nos. = low temp. Suits

11. Details of communication available to contact Police and Fire Brigade in case of emergency

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a) Telephone

Crisis Control Room located near Fire Station having telephone facilities for communication during emergency to mutual aid members & out side agencies required as per Disaster Management Plan.

b) Hot Line

Mumbai Fire brigade – Chembur Fire Station

HPCL Refienry RCF Police Station

c) Wireless

VHF Network for internal communication and emergency handling:

VHF Hand Sets 65 Nos., Base Station 12 Nos., Mobile Vehicle Mounted 6 Nos.

12. Public Alert System and its procedure 1. PA System provided at security gates for. communication with out side public (Main Gate & North Gate). 2. Fire Siren: Fire sirens installed in Refinery & Staff Colony for alerting people during emergency. Refinery sirens can be sounded on Civil Defence mode as per requirement

13. List of protective equipments available in factory

i) No. & type of emergency kit emergency rescue tender having emergency kit of different types for handling emergency in refinery is available round the clock.

ii) No. of Self contained breathing apparatus : 40 BA Sets with spare cylinders (1200 Ltr. Capacity BA Sets 28 Nos. (600 Ltr. Capacity BA Sets 12 Nos.)

iii) No. of air line respirators : 22 Nos

iv) No. of canister respirators : 26 Nos and Canisters are regular stock items

v) No. of acid suits : 20

14. Medical facility available in factory

i) Equipments available in Ambulance room Oxygen cylinders, Resuscitator, Suction Machines, I.V. Sets, Suturing sets, special burn dressing etc. for handling any emergency. X-Ray Unit, Autoclave machines for sterilization of various surgical. 8 beds with on line oxygen facility.

ii) Antidotes available Injections Atropin, Adernalin, Soda-Bicarb, Abntisnake venom etc.

iii) No. of first aiders available 13 Para Medical / Nursing Staf. (Minimum 2 Male nurses in each shift)


75

1. Place of availability : 2 Ambulances available inside the refinery at fire station

2. Capacity : 3 Persons in each ambulance

3. Facilities available in the van : Oxygen Cylinders, Suction machine, First aid dressing materials, splints antiseptic lotions & ointments, IV Set, Water tank etc.

v) Details of hospitals in the vicinity and any tie up with them. 1.LTMG Hospital, Sion. 2. KEM Hospital, Parel. 3. Shatpadi Municipal Hospital, Govandi. 4. Rajawadi Municipal Gen. Hospital, Ghatkopar. 5. JJ Group of Hospital, Chembur. 6. Inlaks General Hospital, Chembur. 7. P. D. Hinduja Hospital, Mahim. 8. Diamond Poly Clinic and Nursing Home, Chembur. 9. Mangal Anand Hospital, Swastik Park, Chembur. 10. Dr. LCManek Hospital, Parvati Palace, Chembur. 11. Joy hospital, 1 'h Road, Chembur. 12. Hegade hospital, Sai Kripa, Road No. :1, Chembur. 13. Dr. Karmarkar Hospital, Dadar. 14. Lilavati Hospital, Bandra.

15. Provision of emergency lighting Normally emergency lighting is fed through, normal power supply sources (either Gas Turbine Generators (20 MW each) or Tata Electric Company). However, we have three separate emergency lighting viz. Emergency Diesel Generator (1250 KVA), TG Set (25 KVA) & New Diesel Generator Set (1250 KVA) as source to feed emergency lighting in refinery in case of GT & Tata grid failure.

16. What other facilities are available outside : the factory premises (Mutual Aid Scheme)

Mutual Aid Scheme in Trombay-Chembur area, 14 members including Mumbai Fire Brigade & Civil Defence.

18. Hazardous chemicals transported 1. Propylene 2.LPG 3. Crude oil 4. Motor Spirit 5. Naphtha 6. Benzene 7. Toluene 8.Hexane9.Xytol10.SBP(55-115) 11.MT012.ATF ,13. SK014. HSD

Principal destination Mumbai, Thane, Pune, Raigad, Nagpur, Nasik & other major towns in Maharashtra, States ofGoa (Panjim), Gujrat (Surat, Vapi, Vadodara, Amdavad), Madhya Pradesh (Bhopal, Indore), Andhra Pradesh (Secundrabad, Vizag), Rajasthan (Jaipur, Kota, Udaipur), Uttar Pradesh (Agra, Mathura, Lucknow, Kanpur), Bihar (Patna), Delhi, Tamilnadu (Chennai, Mahurai, Coimabtore), Kerala (Kochi), Kamataka (Banglore), West Bengal (Calcutta), Chandigarh etc.

19. Site plan of factory showing internal roads, location of storages of hazardous chemicals, buildings etc. (Attached )

76

BHANDUP COMPLEX WATER TREATMENT PLANT

1.

FACTORY IDENTITY

: Bhandup Complex Water Treatment Plant (Municipal corporation of Greater Mumbai)

a) Name : Khandipada, Darag Road, Mulund (W),Mumbai - 400 082.

b) Address

: Voice Mail: 25690703/25690704 Ext. 541,588. Direct No.:2 5616177. Fax No.: 25690702.

b) Telephone Nos. / Telex / Fax Nos. / E-mail Address.


e) Details of Human habitation (Village, City, Residential colony, Hospital etc. near the factory etc. near the factory within 1 Km.)


: Mr. T. R. Rane, Dy. Hydraulic Engineer, Direct: 225686154; Board : 5690703/04 Ext. : 551. Mr. U. R. Divekar, Executive Engr. (Treatment, Chemical & Instrument) Direct: 25690702 Board Ext: 512. Mr. D. R. Shejale, A. E. (Chemical) Direct: 25616179 Board Ext. : 541, 588. • Mr. S. P. Chavan, Division Labour & Welfare Officer. Board Ext.: 527.

b) Name of the technical experts designation & their phone Nos.

c) Name & phone nos. of incident & Site Controller


4. Total No. of workers employed

5. Maximum No. of persons, who may be present in the factory at any one time

6. No. of workers directly involved with inc

77

hazardous chemicals / shift / total.

7. Maximum quantity of hazardous chemicals stored and their mode of storage (Raw Materials, Intermediate products, bye products, finished products)

8. Maximum Credible Loss Scenario:

a) TOXIC DISPERSION

Brief description of Maximum Credible Loss Scenario

In case of


ii) Wind Velocity 2 m/sec. 4 m/sec. 6 m/sec.

Radial distance around factory which could be affected in metres

Toxicity

a) LC 50

b) STEL

c)TLV


Brief Description

Max. Credible Loss Scenario

In case of BLEVE


(Damage Distances in Metres)

Heat Radiation


b) 100% lethality (37.5 Kw/m2)


d) 1% Lethality (12.5 Kw/m2)

e) First Degree 4.5 Kw/m2 of bums

f) No discomfort 1.6 Kw/m2

9. a) Damage distance due to 0.3 bar pressure wave

b) Consequences of Major Hazards that are likely to occur in case of process upsets and storages.


a) No. of Fire fighting equipments and their capacity

i) Soda acid type

ii) C02 Type

iii) DCP Type

iv) Foam Type

78

b) Fire tender / Trailer pump and its capacity

c) Maximum quantity of foam available.

d) Water jet monitors Nos.

e) Water storage tank and its capacity

f) No. of Hydrant points

g) No. of hose reels, and total length

h) No. of fire Suit


a) Telephone

b) Hot Line

c) Wireless




ii) No. of Self contained breathing apparatus·


iv) No. of canister respirators


vi) Any other personal protective equipments

vii) Neutralisation facility provided for neutralising chemicals


i) Equipments available in Ambulance room

ii) Antidotes available

iii) No. of first aiders available


1. Place of availability

2. Capacity

3. Facilities available in the van


15. Provision of emergency lighting

16. What other facilities are available outside the factory premises (Mutual Aid Scheme)

17. Available Meteorological data

a) Wind Directions during part of the day

b) Wind speed (Monthly)

c) Rainfall (Average / Max. Record)

d) Floods Etc.

79


a) Quantity at a time

b) Name of the chemical

c) Type of carrier

d) Principal destination

19. Demographic segment map showing the area around factory within the physical range of worst scenario.

20. Whether separate are specially earmarked for parking of tankers in factory / in the vicinity of factory is provided to avoid traffic congestion, if so details of thereof

21. Site.. plan of factory showing internal roads, location of storages of hazardous chemicals, buildings etc


80

CHEMICAL TERMINAL TROMBAY LTD

S No

1 Factory Identity.

a) Name b) Address

c) Telephone No/ Telex No / Fax No/E-mail address.

d) Details of Human Habitation ( Village, city, residential colony, Hospitals etc near the factory within 1 Km

Chemical Terminal Trombay Limited Pir Pau Installation, Near MBPT pump house, Behind Tata Electric Company Trombay Mumbai 400074. Tel fax No 67030114 / 15 / 16 / 17 /18 E- mail [email protected] Village Mahul Taluke Kurla. Hospital Inlaks Hospital

2 a) Contact personnel of the factory their Phone Nos & Designations Mobile phones

b) Name of the Technical experts designation & their phone No

c) Name & phone No of incidental site controller

Mr. S.H.Bengali Terminal Manager Tel fax No 67030117 / 18 Mobile 9821349536. Residence 26372074 Mr. P.D.Sahani Health Safety & Environment Officer Tel fax No 67030114 / 15 / 16.. Mobile 9821336941 Residence 24370424 Mr.P.D.Sahani. Health Safety & Environment Officer

3 Principal Manufacturing activities(Plant wise)

Receiving, storage & redelivering of chemicals, presently we store chemicals i.e. Methanol, Ethyl Acetate, Toluene Acetone, IPA, Cumene & Lube base oil

4 Total No of workers employed 34

5 Maximum No of persons, who may be present in the factory at any one time

50

6 No of workers directly involved with the hazardous chemicals.

No manufacturing activity only storage of chemicals in tanks.

81

7 Maximum quantity of hazardous chemicals stored and their mode of storage (Raw materials, Intermediate products, bye products, finished products.)

Storage of A / B / C class products 42132 K lit

Stored in atmospheric tanksStock as on 10th May 2008 ( 14825 Kl )

8 Maximum credible loss scenario.

a) Toxic dispersion i) Atmospheric stability

ii)Wind velocity

iii)Toxicity LC50

b) In case of BLEVE, VCE, POOL FIRE as applicable Brief Description

Max Credible Loss scenario

Heat radiation

a)Severe damage to life and property

b)100% lethality (37.5Kw/m2)

c)50% lethality (25Kw/m2)

d)1% lethality (12.5Kw/m2)

e)First degree (4.5Kw/m2)

f)damage distance due to 0.3 bar pressure wave

Not applicable

Stable

2 to 4 m/sec

Non Toxic

Not applicable

As in case of fire the area effected will be within the factory premises only. i.e.

Chemical Name Methanol

Failure Bottom nozzle of the tank

Time 9062 seconds

Wind speed 1 m/sec

Pool fire distance in meters

37.5 Kw/m2 27 meter

12.5 Kw/m2 27 meter

4 Kw/m2 40 meter

9 Consequences of major hazards that are likely to occur in case of process upsets and storage.

Fire.

10

Details of Fire fighting equipments available in the factory.

a) Fire tender/ trailer pump and their capacity

Hydrant line diesel pump 615 m3/hr at 105 MWC head three numbers Hydrant line diesel pump 171 m3/hr at 75MWC head one number Hydrant line Jockey pump 40 m3/hr Foam Line diesel pump 110 m3/hr Fire tender pump 110m3/hr. Co2 in fire tender 6 X 22 Kg DCP in fire tender 2 X 68 Kg

82

c) Maximum quantity of foam available

d) Water storage tank and its capacity.

e) No of hose reels & total length

f) No of fire suit.

Foam in fire tender 500 Lit Water in fire tender 2750 Lit. AFFF Foam 5.5 m3 in SS foam tank 500 Lit in fire tender 30 Lit carboys 50 Nos. Hydrant system 2050 m3 two tanks & Foam system 600 m3 one tank 1 X 30 meter in fire tender 2 Nos

11 Details of communication available to contact police & fire bridge in case of emergency

Telephone lines

12 Public address system and its procedure

Portable public address system.

Installation of one solar booth with public address system

13 List of Protective equipments available in factory

a) No & type of emergency kit.

b) No of self contained breathing apparatus.

c) No of Air line respirators

d) No of Canister respirators

e) No of acid suits.

f) Any other personnel protective equipments

g) Ventilation facility for installation

First aid.

Two

Nil

Six

We do not handle acids hence not applicable.

Helmets, safety shoes, gloves, goggles, PVC apron, face shield. etc.

Material stored in fixed roof tanks in open space..

83

14 Medical facilities available in factory.

Equipment available in ambulance room

a) Antidotes available b) No of first aiders available

c) Ambulance van or alternate arrangement

d) Details of hospitals in the vicinity and any tie up with them

All equipments as listed in Factory rules

Antidotes mention in MSDS are available

All workers are trained in first Aid certificate course.

Tie up with Inlaks Hospital. & Mutual aid scheme members.

Inlaks Hospital Chembur colony Mumbai 400074. Tel No 25204160-64

Fax 25204141

15 Provision of emergency lighting High powered Torches available

One solar booth light at night time.

16 What other facilities are available outside the factory premises (Mutual aid scheme)

Member of mutual aid scheme.

17 Hazardous chemical transported Only storage facilities are available at terminal.

18 Site plan of the factory showing internal roads, locations of storages of hazardous chemicals.

Attached.

19 Any other relevant information. ---------

HINDUSTAN PETROLEUM CORP. LTD. REFINERY 1 FACTORY IDENTITY a) Name : Hindustan Petroleum Corpn. Ltd. b) Address : Mumbai Refinery Division,

Bhikaji Damaji Patil Marg, Mahul, Mumbai – 400 074.

c) Telephone Nos./ Telex / Fax Nos./ E-mail Address :

25076000 25542391 Fax 25542008

d) (Location) Railway Line / Highways, passing through / near the area. If

so, details of rail / road, crossings / bridges and water way vicinity.

: Old Corridor Road

e) Details of human habitation (Village, City, Residential colony, Hospital etc. near the factory etc. near the factory within 1 km.)

: North side : Calico Chemical South side : Tata Electric Co. West side : BPCL East Side : Container Yard/Apar

Ltd. 2. a) Contact personnel of the factory

their Phone Nos., Designations, Mobile

Phone Nos.

S C Mehta – ED,MR Office : 25545061 Residence : 23521583 M D Pawde – General Manager - Oprns Office : 2554 0675 Residence : 2403 6365 K V Singh : Ch Manager (F&S) Office : 2507 6600 Residence : 9769026290

b) Name of the technical experts, designation & their phone Nos.

V S Agashe -DGM (Opns..) –FR Office : 2554 1952 9819919330 V A Katne - DGM (Opns.) – LR Office : 25544258 9833268501

c) Name & Phone nos. of incident & Site Controller

S C Mehta – E D –MR Office : 25545061 Residence : 23521583

3. Principal Manufacturing Activities (Plant wise)

Manufacturing / Refining of Petroleum Products

4. Total No. of workers employed : 1850 5. Maximum No. of persons, who may be

present in the factory at any one time. : 1250

6. No. of workers directly involved with the hazardous chemicals/ shift/ total.

: Plant operators are not directly involved in Hazardous chemicals as the system has closed system.

7. Maximum quantity of hazardous chemicals stored and their mode of storage (raw Materials, Intermediate products, bye-products, finished

Crude : 267000 T (Tank) LPG : 3300 T (Sphere) Naphtha : 37900 T (Tank) Petrol : 35800 T (Tank)

85

products). Hexane: 4800 T (Tank) Solvent: 1800 T (Tank) LDO : 18000 T (Tank) IFO : 39800 T (Tank) MTO : 1800 T (Tank) ATF : 5190 T(Tank) HSD : 94600 T(Tank)

8. Maximum Credible Loss scenario ; a) TOXIC DISPERSION : Brief description of Maximum Credible

Loss Scenario:

In case of i) atmospheric Stability Stable Neutral Unstable ii) wind Velocity 2 m/sec. 4 m/sec. 6 m/sec. Redial distance around factory which

could be affected in meters. Toxicity Nil – Not applicable a) LC 50 b) STEL c) TLV d) In case of BLEVE, VCE, POOL FIRE as applicable Brief Description *As per DMI Risk Analysis study Max. Credible Loss the worst accident situation

or Maximum credible loss scenario is identified as Tk-253, the Naphtha tank fire and loss of containment leading to vapor cloud. Delayed ignition vapor cloud explosion and pool fire. Appropriate Onsite measures have been taken by HPCL to minimize the damage preventing such accidents.

In case of BLEVE


(Damage distances in meters) Heat Radiation a) Severe Damage to life and property

(within cloud)

b) 100% lethality (37.5 Kw/m2) Not reached c) 50% lethality (25 Kw/m2) 47 d) 10% lethality (12.5 Kw/m2) 105 e) first degree 4.5 Kw/m2 of burns f) no discomfort 1.6 Kw/m2 g)Damage distance due to 0.3 bar

pressure wave 80

9. b) Consequences of Major Hazards that are likely to occur in case of process upsets and storages.

Fire, Explosion



i) Soda acid type - ii) CO2 type 467

86

iii) DCP type 835 iv) Foam type - b) fire tender / Trailor pump and its

capacity 5 Fire / Foam tender, 4000 LPM, 3 Trailor pump 1800 LPM

c) Maximum quantity foam available. 90000 ltrs d) Water jet monitors Nos. : 20 jet/ 325 fix monitors. e) water storage tank and its capacity : 2 tanks, 18740 m3 f) No. of hydrant points : 824 g) No. of hose reels and total length : 100, Length -22.5 m each h) No. of Fire Suit : 02 & 10 Nos. of Water jel blanket 11. Details of communication available to

contact police and Fire brigade in case of emergency

: Telephone, pager system, hot line and Radio trunking.

a) Telephone : 3 b) Hot line : BPCL & Chembur fire brigade c) wireless : 65 Sets.. 12. Public Alert system and its procedure : Mike System 13. List of protective equipments available

in factory Fire Proximity, PVC suit, water jel

i) No. & Type of emergency kit : 2 Nos rescue tools. ii)No. of Self contained breathing

apparatus : 12

iii) No. of air line respirators : 02 iv) No. of canister respirators : 12 v) No. of acid suits : 10 vi) any other personal protective

equipments. : All PPE are available in Central

warehouse and given as and when required.

vii) Neutralization facility provided for neutralizing chemicals.

14. Medical facility available in factory i) Equipments available in Ambulance

room : Full fledged 2 Nos. of Medical centre

available with 2 nos. of ambulance. Medical centre is manned round the clock.

ii) Antidotes available : N/A iii) No. of First aiders available : First aiders are the medical staff,

also the employees have trained in First aid.

iv)Ambulance Van or alternate arrangement

: 2 Nos. ambulance van available alternate on call.

1. Place of availability : Ambulance are in the refinery 2. Capacity : A/C two beds. 3. Facilities available in the van : Oxygen sets. v) Details of hospitals in the vicinity and

any the up with them. : Inlak Hospital, Shushrut Hospital,

Mangal Anand, Sion Hospital 15. Provision of emergency lighting :Available in case of Tata Power

failure, we have power supply from Captive power plant. Also 2 emergency generator are available.

16. What other facilities are available : Mutual Aid Scheme is available

87

outside the factory premises (Mutual Aid scheme)

17. Available meteorological data a) wind Directions during part of the

day : N/W : September – March S/W : April – August

b) wind Speed (monthly) : Mean wind speed 6 knots. c) Rainfall (Average / Max. Record) 76 inch. d) Floods, Etc. : No. 18. Hazardous chemicals transported : No hazardous chemicals transported

from the Refinery. a) Quantity at a time b) Name of the chemical c) type of carrier d) principal destination 19. Demographic segment map showing the

area around factory within the physical range of worst scenario.

: Refer attachment.

20 Whether separate area are specially earmarked for parking of tankers in factory / in the vicinity of factory is provided to avoid traffic congestion, if so details of thereof.

: Traffic congestion is reduced in corridor road. Tanker have been issued token are removed by traffic police.

21. Site plan of factory showing internal roads, location of storages of hazardous chemicals, buildings, etc.

: Refer attachment

22. Any other relevant information.

88

HINDUSTAN PETROLEUM CORPORATION LTD. MAHUL TERMINAL

1.

FACTORY IDENTITY

a) Name : Hindustan Petroleum Corp. Ltd. b) Address Mahul Terminal, Old Corridor Road,

Chembur, Mumbai – 400 074 c) Telephone Nos. /

Telex / Fax Nos. / E-mail Address.

25543280/81/82/83 Fax : 25546665

d) (Location) Railway Line / Highways, passing through / never the area. If so, details of rail / road, crossings / bridges and water way vicinity

e) Details of human habitation (Village, City, Residential colony. Hospital etc. near the factory etc. near the factory within 1 Km.)

: Gawanpada Population – 9000

2. a) Contact personnel of the factory their phone Nos., Designations, Mobile Phone Nos.

: Shri B P Jaisawal, Sr. Instn. Manager Office : 25545168 25544323

b) Name of the technical experts destination & their phone nos.

: Shri S. V. Rane Manager Instruments Office : 25546530 Residence :27579694


3. Principal manufacturing Activities (Plant wise) : Products received from Refinery. Storage and distribution of finished petroleum

4. Total No. of workers employed : 155


: 120

6. No. of workers directly involved with the hazardous chemicals / shift / total

: Nil

7. Maximum quantity of hazardous chemicals stored and their mode of storage (Raw materials, Intermediate products, bye-products, finished products)

: Class – A : 6770 MT Class – B : 22320 MT Class – C : 13660 MT. LPG : 310 MT

8. Maximum Credible Loss Scenario :

a) TOXIC DISPERSION : Net applicable as we are not handling any toxic chemicals

Brief description of Maximum Credible Loss Scenario

In case of

i) Atmospheric Stability

Stable Neutral Unstable

ii) Wind Velocity 2m/sec 4m/sec. 6m/sec.


Toxicity

89

a) LC 50

b) STEL

c) TLV


Brief Description

Mx. Credible Loss Scenario In case of BLEVE


(Damage Distances in Metres)

Heat Radiation


Attachment

b) 100 % lethality (37.5 Kw/m2)

c) 50 % Lethality (25 Kw/m2) 23

d) 1 % Lethality (12.5 Kw/m2) 117

e) First Degree 4.5 Kw/m2 of burn 46

f) No discomfort 1.6 Kw/m2

g) Damage distance due to 0.3 bar pressure wave

Consequnces of Major Hazards that are likely to occur in case of process upsets and storages



: Nil; Assisted from HPFR

i) Soda acid type

ii) CO2 Type

iii) DCP type

iv) Foam Type

b) Fire tender / Trailor pump and its capacity : Nil; Assisted from HPFR

c) Maximum quantity of foam available : 2500 Ltd

d) Water jet monitors Nos.

e) Water storage tank and its capacity

f) No. of Hydrant points

g) No. of hose reels and total length : 100 nos. 150 Rm

h) No. of fire Suit

10. Details of communication available to contact Police and Firebrigade in case of emergency

a) Telephone :P & T Line – 10 Nos.

b) Hot line : 2 nos.

90

c) Wireless : Nos.

12. Public alert System and its procedure : Provided at main entry gate and 2 nos. Electrical siren having available range pf 2 km.


i) No. & type of emergency kit : 2 Nos.

ii) No. of Self contained breathing apparatus : 2 Nos.

iii) No. of air line respirators : Nil

iv) No. of canister respirators : N.A.

v) No. of acid suits : N.A.

vi) Any other personal protective equipments : Hand gloves, Safety Shoes, Safety Belts, Rubber Hand gloves, ear muff.

vii) Neutralisation facility provided for neutralizing chemicals

: Neutralisation facility is not available. However, hydrocarbon detectors with alarm system has been provided in LPG area.


i) Equipments available in Ambulance room : Assistance from HPFR.

ii) antidotes available



1. Place of availability : HPFR

2. Capacity : 2 Nos.

3. Facilities available in the van : With all necessary Equipments

v) Details of hospitalism the vicinity and any the up with them.

: Inlak / Sion Hospital

15. Provision of emergency lighting : 1. Tatal Electric 2. HPFR 3. BSEB


: We are member of Mutual Premises (Mutual Aid Scheme) Aid Scheme, Chembur – Trombay Area.

17. Available Meterological data

a) Wind direction during part of the day



d) Floods Etc.

18. Hazaradous chemicals transported

a) Quantity at a time : With varying capacity of 12 / 14 / 16 KLP per T.

b) name of the chemical : Naphtha, Hexane

c) Type of carrier : Tank truck

91

d) Principal destination : Industrial Customer and Upcountry location

19. Demographic segment map showing the area around factory within the physical range of worst scenario

20. Whether separate are specially earmarked for parking of tankers in factory / in the vicinity of factory is provided to avoid traffic congestion, if so details of thereof.

: Request for allotment of land west of BPCR Refinery to BPC & HPC for development of submitted to Municipal Commission on 06.11.1996


: Attached

22. Any other relevant information : Nil

92

HPCL MAHUL LPG FILLING PLANT 1 FACTORY IDENTITY a) Name : Hindustan Petroleum Corpn. Ltd. b) Address : Mahul LPG Filling Plant,

L U Gadkari Marg, Behind HPCL Refinery,Chemburl, Mumbai – 400 074.


2554 2280 25544159 Fax 25548677



: L U Gadkari Marg


: North side : Ganon Norton Co South side : Bombay Indl Corp. West side : L U Gadkari Marg East Side : BARC


Phone Nos.

K Subramaniam – CRM (Occupier) Office : 25548677 9920930963 R L Jadhav – Plant Manager Office : 2554 2280 9975255818 Shabbir Azam– Exe Opr Officer Office : 25544159 9619189944

b) Name of the technical experts, designation & their phone Nos.

Exe Opr Officer Office : 25544159


Site Controller Primary Plant Manager (2554 2280) Alternate – Safety Officer (25544159) Incident Controller Primary – Shift Incharge 2554 4159 Alternate Maintenance Officer 2554 4159


Bulk Storage, Bulk Dispatch in road tanker & packed cylinder dispatch in trucks




: Plant operators are not directly involved in Hazardous chemicals as the system has closed system.

93

7. Maximum quantity of hazardous chemicals stored and their mode of storage (raw Materials, Intermediate products, bye-products, finished products).

LPG – (3 x 200 MT) = 600 MT Mounded STorage

8. Maximum Credible Loss scenario ; a) TOXIC DISPERSION : Brief description of Maximum Credible

Loss Scenario:

In case of i) atmospheric Stability Stable Neutral Unstable ii) wind Velocity 2 m/sec. 4 m/sec. 6 m/sec. Redial distance around factory which

could be affected in meters. Toxicity Nil – Not applicable a) LC 50 b) STEL c) TLV d) In case of BLEVE, VCE, POOL FIRE as applicable Brief Description *As per As per ALARP Risk Analysis principle using PHAST software

(process Hazard Analysis Software) Max. credible Loss the worst accident situation is identified as Full Bore Rupture of LPG pipe line, Model (MAH-LPG-2) Distance of 89 Mtr shall be affected by heat radiation of 4.0 Kw/Sqm. The effect is minimized by green belt. We have mounded storage of LPG which has reduced the risk considerably. Appropriate Onsite measures have been taken by HPCL to minimize the damage preventing such accidents.

In case of BLEVE


(Damage distances in meters) Heat Radiation a) Severe Damage to life and property

(within cloud) N/A

b) 100% lethality (37.5 Kw/m2) 6.2 Mtr c) 50% lethality (25 Kw/m2) d) 10% lethality (12.5 Kw/m2) 44.7 Mtr e) first degree 4.5 Kw/m2 of burns 88.1 Mtr f) no discomfort 1.6 Kw/m2 g)Damage distance due to 0.3 bar

pressure wave

9. b) Consequences of Major Hazards that are likely to occur in case of process upsets and storages.

Fire, Explosion



i) Soda acid type -

94

ii) CO2 type 4 iii) DCP type 44 iv) Foam type - b) fire tender / Trailor pump and its

capacity Fixed type M V Sprinkler system is available from all LPG areas

c) Maximum quantity foam available. - d) Water jet monitors Nos. 19 DH Monitrs and 18 Jet monitors. e) water storage tank and its capacity : 2 x 2500 KL Tanks (5000 KL) f) No. of hydrant points :36 g) No. of hose reels and total length : 46, Length -15 m each h) No. of Fire Suit : 02 Low temp and 1 fire proximity 11. Details of communication available to


: Telephone, pager system, Walky Talky stets.

a) Telephone : 3 b) Hot line : c) wireless : 9 Walky talky 12. Public Alert system and its procedure Paging system with Amplispkers 13. List of protective equipments available

in factory Fire Proximity, Low temp suit & gloves, helmets, rescuciters, Breathing Appratus, stretcher, electrical gloves etc

i) No. & Type of emergency kit : 1 Nos rescue tools. ii)No. of Self contained breathing

apparatus : 1

iii) No. of air line respirators : iv) No. of canister respirators : v) No. of acid suits : N/A vi) any other personal protective

equipments. : All PPE are available in Central

warehouse and given as and when required.

vii) Neutralization facility provided for neutralizing chemicals.

14. Medical facility available in factory i) Equipments available in Ambulance

room : Have tie up with HP Refineries

medical group to handle medical emergency,. One jeep and a car is available for shifting casualty if any.

ii) Antidotes available : N/A iii) No. of First aiders available : Five employees have trained in First

aid. iv)Ambulance Van or alternate

arrangement : One jeep and a car is avalable for

shirting casualty if any. 1. Place of availability : In plant premises 2. Capacity : A/C two beds. 3. Facilities available in the van : stretchers. v) Details of hospitals in the vicinity and

any the up with them. : Inlak Hospital, Shushrut Hospital,

Mangal Anand, Sion Hospital 15. Provision of emergency lighting :One DG Set is available. 16. What other facilities are available

outside the factory premises (Mutual Aid : Mutual Aid Scheme is available

95

scheme) 17. Available meteorological data a) wind Directions during part of the

day : N/W : September – March S/W : April – August

b) wind Speed (monthly) : Mean wind speed 6 knots. c) Rainfall (Average / Max. Record) 76 inch. d) Floods, Etc. : No. 18. Hazardous chemicals transported : No hazardous chemicals transported

from the Refinery. a) Quantity at a time b) Name of the chemical c) type of carrier d) principal destination 19. Demographic segment map showing the


: Refer attachment.

20 Whether separate area are specially earmarked for parking of tankers in factory / in the vicinity of factory is provided to avoid traffic congestion, if so details of thereof.

: Parking space is available out side plant.

21. Site plan of factory showing internal roads, location of storages of hazardous chemicals, buildings, etc.

: Refer attachment


96

MAHINDRA & MAHINDRA (TRACTOR DIVISION) 1 FACTORY IDENTITY

a. Name Mahindra & Mahindra Ltd. Tractor Division, (Farm Equipment Sector)

b. Address Akurli Road, Kandivli (East). Mumbai – 400 101

c. Telephone / Telex / Fax Nos.

Tel: 2887 4651 to 2887 4670 Fax: 2886 4670

d. (Location) Railway Line / Highways, passing through / near the area. If so, details of Rail / Road, crossings / Bridges and water way vicinity

Kandivli Station Near NH-8 (Ahmedabad–Mumbai) Village Poinsar, Town- Kandivli

e. Details of Human Habitation (Village, City, Residential Colony, School, Public Place, Hospital etc.. near the Factory within 1 Km.

North-Samata Nagar South- Lokhandwala Complex Lokhandwala Foundation School Pvt. Garden of Lokhandwala Township Dr. Vasa’s Hospital & Shopping Arcade

2 a. Contact Personnel of the Factory their Phone Nos. and Designation.

Mr. Sudhir Gharat , Controller of Operations Phone:

b. Name of the Technical Experts, Designation and their Phone Nos. Residential No. Area of Specification.

Mr. Arun Joshi Manager- Safety & Env. Phone : 9867038073

3 Principal Manufacturing Activities Manufacturing of Agricultural Tractors & Equipments

4 Total No. of Workers Employed About, 5500

5 Maximum No. of persons, who may be present in the factory at any one time 2500

6 No. of workers directly involved with the hazardous chemicals/shift total 95

7

Maximum quantity of hazardous chemicals stored and their mode of storage (Raw Material, Intermediate Products, bye- Products, Finished products)

a) 32 tonnes of LPG in 3 bullets (10+10+12) b) 50 kg. of Ammonia stored in one cylinder.

8 A

Hazardous Analysis done Attach details with date

Hazardous analysis done, details attached.

8 B

Maximum Credible Loss Scenario a. TOXIC DISPERSION: Brief description of Maximum Credible Loss Scenario: Chemical (S) involved:- In Case of i) Atmospheric Stable Neutral Stability ii) Wind 2m/sec. Velocity Radial distance around factory which could be affected in meters. iii) Toxicity

a) DLH

Effect of Accident release of LPG will depend on quantity of LPG and nearest location of ignition source. Toxicity index is 3.9. i.e. within specified range of 6.oo. LPG ) ) Stable Ammonia ) -348 Metres LPG AMMONIA

97

b) STEL c) TLV

10% i.e.100000 PPM 5000 PPM 1000 PPM 35 PPM 5000 PPM 46.8 PPM

b.IN CASE OF BLEVE,VCE, POOL FIRE AS APPLICABLE Brief Description.

L.P.G. – Explosive. Ammonia – Difficult ignite. If LPG vessel is involved in a Fire, it may overheat and rupture violently giving out intensely hog fire ball and may project pieces of the vessel over considerable distance.

Max. credible Loss Scenario Heat Radiation a. Severe damage to life and property (within cloud) b. 100% Lethality (37.5 Kw/m2) c. 50 % Lethality (25 Kw/m2) d. 1% Lethality (12.5 Kw/m2) e. First Dogree 4.5 Kw/m2 f. No. discomfort 1.6 Kw/m2

BLEVE Fire Ball Radius - 53 Mtr. Duration (Damage Distance in Metres) IV VCE Extensive Damage Duration -3.75 Sec. 57 Metres 105.4 Metres 348 Metres 500 Metres 600 Metres 1000 Metres

9 Demographic segment map showing the area around factory within the physical range of worst scenario

Attached herewith

10

Details of Fire fighting equipments available in the factory a. No. of Fire equipments and their capacity 1. Soda Acid Type 2. Co2 Type 3. DCP Type 4. Foam Type

9 ltrs.– 106 Nos, 22,5 kg –15 Nos. 10 kg.–6 Nos. 7 Kg. –20 Nos. , 4.5 Kg. – 5 Nos. 6000 Lbs.–1 Nos., 45 Kg.–12 Nos. 10 Kg. – 62 Nos. 150 ltrs. – 15 Nos., 9 ltrs.- 135 Nos.

b. Fire Tender/Trailor pump and its capacity NIL (Exemption received)

c. Maximum quantity of FOAM available 100 Kg.

d. Water Jet Monitors Nos. 3 Nos. of Fixed Monitors on Hydrant System

e. Water Storage Tank and its capacity 1 Nos.-453000 lltrs.capacity f. No. of Hydrant Points 72 Nos. g. No. of hose reels and total length 72 Nos.

11 Details of Communication available to contact District Emergency Authority, Police & Fire Brigade and other agencies

98

in case of Emergency. a. Telephone b. Hot Line c. Wireless d. Mobile e. Walky Talky etc...

Yes - - - Yes

12 Public Alert System and its Procedures Yes speakers located on all the 5 Gates Operated from Emergency Control Central

13

List of Protective Equipment’s available in factory a. No. & Type of Emergency kit breathing apparatus b. No. of self contained breathing apparatus c. No. of Air Line respirators d. No. of Canister Respirators e. No. of Acid Suits f. Any other Personal Protective Equipment g. Neutralisation facility available to Neutralise Chemicals

Nil Nil Nil Nil Nil Hand gloves, Aprons, Shoes, Goggles required for routing work, Not Applicable (Aluminised Fire Suit available)

14

Medical Facility available in Factory a. Equipments available in Ambulance b. Antidotes available in c. No. of First aiders available d. Ambulance Van or alternative arrangement 1. Place of availability 2. Capacity 3. Facilities available in the Van e. Details of Hospitals in the vicinity and any tie up with them

As per rule e.g. Oxygen, Stretcher & medicines. Not Applicable 38 2 Nos. of Vans Near Factory Gate One injured each As above ESIS, Yashwant, Asha Parekh, Nanavati Hospital, with tie-up Dr. Vasa’s Hospital no tie-up.

15 Provision of Emergency Lighting Emergency lights in key location e.g. Dispensary, Emertgency Control of Centre.

16 What Others Facilities are available outside the factory premises (Mutual Aid Scheme)

Power driven Trailor Pump in Adjacent factory

17

Methods and Procedure to be followed by installation own, operators load emergency and Medical, Personnel to respond to release of Hazardous Chemical.

Prescribed in “On Site Emergency Plan” & Practiced in Emergency Drills.

18

Hazardous Chemicals Incorporated : a. Quantity at a time b. Name of the Chemical c. Type of carrier

L.P.G. 6 Tonnes is received in one trip L.P.G. Tanker

99

d. Principal Destination e. Transporter’s Name f. Contact Person

L.J.Transport, Tel. No.- 556 6166 M/s. Krishna Santosh & Tiwari

19 Demographic segment map showing the area around factory within the physical range of worst scenario.

Attached herewith

20

Whether separate area specially earmarked for parking of tankers in factory/ in the vicinity of factory is provided to avoid traffic, If so details thereof.

Suitable Area is earmarked outsid3e the gate.

21 Site Plan of the factory showing internal roads, location of storages of Hazardous chemicals, bldg. etc.

Attached.

22 Any other relevant information Member-Chief Co-ordinator Mutual Aid Scheme Western region, Mumbai.

100

MAHINDRA & MAHINDRA LTD. (JEEP DIVISION) 1 FACTORY IDENTITY

a. Name Mahindra & Mahindra Ltd., Central Jeep Plant, (Automotive Sector)

b. Address Akurli Road, Kandivli (East). Mumbai – 400 101

c. Telephone / Telex / Fax Nos.

Tel: 2887 4601 Fax: 2887 6739

d. (Location) Railway Line / Highways, passing through / near the area. If so, details of Rail / Road, crossings / Bridges and water way vicinity

Kandivli Station Near NH-8 (Ahmedabad–Mumbai) Village Poinsar, Town- Kandivli

e. Details of Human Habitation (Village, City, Residential Colony, School, Public Place, Hospital etc.. near the Factory within 1 Km.

North-Samata Nagar South- Hanumannagar

2 a. Contact Personnel of the Factory their Phone Nos. and Designation.

Mr. V.K. Tuli Vice President - Operations Phone: 022 28467156

b. Name of the Technical Experts, Designation and their Phone Nos. Residential No. Area of Specification.

Mr. G.M. Wagh Manager- Safety, Health & Env. Phone : 022 28467532 / 28467554

3 Principal Manufacturing Activities Manufacturing of Multi Utility Vehicles (Jeeps)

4 Total No. of Workers Employed Around 3,500

5 Maximum No. of persons, who may be present in the factory at any one time 2000

6 No. of workers directly involved with the hazardous chemicals/shift total 90

7

Maximum quantity of hazardous chemicals stored and their mode of storage (Raw Material, Intermediate Products, bye- Products, Finished products)

a) 40 tonnes of LPG in 2 bullets (10+30) b) 50 kg. of Ammonia stored in four cylinders.

8 A

Hazardous Analysis done Attach details with date

Hazardous analysis done, details attached.

8 B

Maximum Credible Loss Scenario a. TOXIC DISPERSION: Brief description of Maximum Credible Loss Scenario: Chemical (S) involved:- In Case of i) Atmospheric Stable Neutral Stability ii) Wind 2m/sec. Velocity Radial distance around factory which could be affected in meters. iii) Toxicity

d) DLH e) STEL f) TLV

Effect of Accident Leakage of LPG will depend on quantity of LPG and nearest location of ignition source. Toxicity index is 3.9. i.e. within specified range of 6.oo. LPG ) ) Stable Ammonia ) -348 Metres LPG AMMONIA 10% i.e.100000 PPM 5000 PPM 1000 PPM 35 PPM

101

5000 PPM 46.8 PPM

b.IN CASE OF BLEVE,VCE, POOL FIRE AS APPLICABLE Brief Description.

L.P.G. – Explosive. Ammonia – Difficult to ignite. If LPG vessel is involved in a Fire, it may overheat and rupture violently giving out intensely hog fire ball and may project pieces of the vessel over considerable distance.

Max. credible Loss Scenario Heat Radiation a. Severe damage to life and property (within cloud) b. 100% Lethality (37.5 Kw/m2) c. 50 % Lethality (25 Kw/m2) d. 1% Lethality (12.5 Kw/m2) e. First Degree 4.5 Kw/m2 f. No. discomfort 1.6 Kw/m2

BLEVE Fire Ball Radius - 50 Mtr. Duration (Damage Distance in Metres) IV VCE Extensive Damage Duration 8.00 Sec. 57 Metres 90 Metres 125 Metres 160 Metres 320 Metres 510 Metres

9 Demographic segment map showing the area around factory within the physical range of worst scenario

Attached herewith

10

Details of Fire fighting equipments available in the factory a. No. of Fire equipments and their capacity 1. Soda Acid Type 2. Co2 Water Type 3. Foam Chemical 4. Mechanical Foam 5.Dry Chemical Powder 6. Co2 Type

Nil. 90 (9) Nil 107 (9,45) 387 (5,10,22.5,70) 259 (2, 3.2, 4.5, 6.8, 9, 22.5)

b. Fire Tender/Trailor pump and its capacity One

c. Maximum quantity of FOAM available 107 Fire Extinguishers (Foam) d. Water Jet Monitors Nos. 4 Nos. of Water Monitors.

e. Water Storage Tank and its capacity 50,000 gallons of water Fire Tender 1250 Ltrs.

102

f. No. of Hydrant Points 66 Nos. g. No. of hose reels and total length 66 Nos., Length 7.5 Meter each

11

Details of Communication available to contact District Emergency Authority, Police & Fire Brigade and other agencies in case of Emergency.

f. Telephone g. Hot Line h. Wireless i. Mobile j. Walky Talky etc...

Yes - - Yes Yes

12 Public Alert System and its Procedures

Yes, Speakers located in the Product Units for internal communication and at 22KV substation for external communication and Emergency Control Central

13

List of Protective Equipment’s available in factory a. No. & Type of Emergency kit breathing apparatus b. No. of self contained breathing apparatus c. No. of Air Line respirators d. No. of Canister Respirators e. No. of Acid Suits f. Any other Personal Protective Equipment g. Neutralisation facility available to Neutralise Chemicals

1 Ammonia Kit 2 Nil Nil Nil Hand gloves, Aprons, Shoes, Goggles required for routing work, Not Applicable (Aluminized Fire Suit available)

14

Medical Facility available in Factory a. Equipments available in Ambulance b. Antidotes available in c. No. of First aiders available d. Ambulance Van or alternative arrangement 1. Place of availability 2. Capacity 3. Facilities available in the Van e. Details of Hospitals in the vicinity and any tie up with them

AS PER RULE E.G. OXYGEN CYLINDER WITH MASK, STRETCHER & MEDICINES. ANTI SNEAK VENOM. 129 2 NOS. OF VANS NEAR OCCUPATIONAL HEALTH CENTRE ONE INJURED EACH AS ABOVE ESIS HOSPITAL, SRI SAI HOSPITAL, SUCHAK HOSPITAL, BHAGWATI HOSPITAL NANAVATI HOSPITAL,

15 Provision of Emergency Lighting Emergency lights in key location e.g. OHC, Emergency Control Centre, HT Dept& other PU’s etc.

16 What Others Facilities are available outside the factory premises (Mutual Aid

Power driven Trailor Pump in Adjacent factory of M&M, FES, who is also

103

Scheme) member of MARG

17

Methods and Procedure to be followed by installation own, operators load emergency and Medical, Personnel to respond to release of Hazardous Chemical.

Prescribed in “On Site Emergency Plan” & Practiced in Emergency Mock Drills periodically.

18

Hazardous Chemicals Incorporated : g. Quantity at a time h. Name of the Chemical i. Type of carrier j. Principal Destination k. Transporter’s Name l. Contact Person

L.P.G. Around 12 Tonnes is received in one trip L.P.G.Tanker Mahul SPN Transport Tel. No.- 25066582 Mr. Y.A.Seth

19 Demographic segment map showing the area around factory within the physical range of worst scenario.

Attached herewith

20

Whether separate area specially earmarked for parking of tankers in factory/ in the vicinity of factory is provided to avoid traffic, If so details thereof.

Suitable Area is earmarked outside the gate.

21 Site Plan of the factory showing internal roads, location of storages of Hazardous chemicals, bldg. etc.

Attached.

22 Any other relevant information Chief Convener- (M&M, A.S.) Mutual Aid Response Group (MARG) Western region, Mumbai.

104

PARLE PRODUCTS LIMITED.

1.

FACTORY IDENTITY

a) Name : Parle Products Limited. b) Address Vile Parle (E), Mumbai - 400 057.

c) Telephone NOS./ Telex / Fax Nos. / E-mail Address.


Near Vile Parle north level crossing.

e) Details of Human habitation (Village, City, Residential colony. Hospital etc. near the factory etc. near the factory within 1 Km.)


: B. K. Kotwal, Factory Manager, Residence: 24361483 R. S. Nevatia, Chief Engineer, Residence: 28320076 A. K. Gadiwala, Dy. Engineer, Residence: 26491972 G. Scares, Plant Services & Safety Manager Residence: 26406458 R. D. Panchal, Safety Officer. C. D. Kamat, Residence B. K. Nair, Manager Ptg. Residence:2 6127591 N. B. Patel, Manager (Pers & Admin.) R. Gopalan, Prod. Manager Confectionery Residence: 26211130 D. N. Shah, Manager Electrical Residence: 28374539 K. C. Gupta, Standard Executive, Residence: 25512753 S. S. Vichare, Prod. Manager Biscuits Residence:2 8324178 Mrs. Shelar, Nurse Residence: 4921786 Mrs. D'Souza, Jr. Officer - Medical Services. Residence: 6464996. Azad Gholkar, Personnel Officer, Residence: 5362512. D. B. Jha, Maintenance engineer. Residence: 8830541,

105

b) Name of the technical experts designation & their phone Nos.


3. Principal Manufacturing Activities Making Biscuits, Confectionery, Candies , Lozenges and Toffees.

4. Total No. of workers employed



7. Maximum quantity of hazardous chemicals stored and their mode of storage (Raw Materials, Intermediate products, bye-products, finished products'

Name of chemical Quantity stored Storage method and mode

Quantity of chemical in the processing system

Ammonia 20 Lts. Bullet

LPG 81 Mt. Bullets

Ethyl / Butyl Acetate

2400 Lts. MS Drums

Toluene 20000 Lts. UG Tanks & drums

Petrol 13600 Lts UG Tanks

HSD 43600 Lts. UG Tank

Furnace Oil 76000 Lts. UG Tank

Caustic Soda 50 Kg. PVC Bag.

8. Maximum Credible Loss Scenario

a) TOXIC DESPERSION :

Brief description of Maximum Credible Loss Scenario :

In case of


ii) Wind Velocity 2 m/sec.

4 m/sec.

6 m/sec.


Toxicity

a) LC 50

b) STEL

c) TLV


Brief Description

106



(Damage distances in Metres)

Heat Radiation Jet Flame

The hazard is posed by storage of Liquefied Petroleum Gas (LPG) In case of leakage of LPG from the largest tank with a capacity of 30 Ton of LPG , the following scenarios are possible BLEVE VCE Jet Flame through the safety valve Pool fire is not considered as a possible event. A very preliminery step in any LPG storage is to have the ground below the tank slpoing so as to not to have any pool of LPG The following tables give the damage distance in case of different possibilities.


In case of BLEVE

In caseof

Jet flame

b) 100% lethality (37.5 Kw/m2) 135 Met 16.30

c) 50% Lethality (25 Kw/m2) 170 Met 17.00

d) 1% Lethality (12.5 Kw/m2) 290 Met 19.30

e) First Degree 4.5 Kw/m2 of bums 440 Met 25.65

f) No discomfort 1.6 Kw/m2. 725 Met 38.30

g) Damage distance due to 0.3 bar pressure wave

Over pressure bar Damage distance (M)

Effect

745 High concentration of people e.g. Schools, Hospitals.

0.04 454 Domestic Housing

0.05 327 Public Road

0.07 254 Ordinary Plant Building

0.10 200 Building with shelter resistant windows, fixed roof tanks containing highly flammable or toxic materials

0.20 136 Floating roof tanks, other fixed roof tank, cooling towers, utility areas site roads.

0.30 091 Plant with large atmospheric pressure vessels

0.40 080 Other hazardous plants

0.70 058 Non-hazardous plants control room designed for blast resistance


107


i) Soda acid type : 9 Litres : 5 Nos. 45 Litres : 40 Nos.

ii) CO2 Type : 2.0 Kg : 0.8 Kg : 10 Nos. 9.0 Kg : 20 Nos. 22.5 Kg. : 11 Nos.

iii) DCP Type : 2.0 Kg. 10 Kg. : 42 Nos.

iv) Foam Type : 9 Lts. : 20 Nos. 45 Lts. : 04 Nos.

b) Fire tender / Trailor pump and its capacity

: 1000 GPM

c) Maximum quantity of foam available : 400 Lts.

d) Water jet monitors Nos. : Fixed – 4 Nos. Mobile – 1 Nos.

e) Water storage tank and its capacity : 105000 Gallons

f) No. of Hydrant points : 37 Nos.

g) No. of hose reels and total length

h) No. of fire Suit : 02 Nos.

10. Details of communication available to contact Police and Firebrigade in case of emergency

a) Telephone

b) Hot Line

c) Wireless



i) No. & type of emergency kit : 2 Chemical Suits 1 Oxygen Kit

ii) No. of self contained breathing apparatus


iv) No. of canister respirators

v) No. of acid suits

vi) Any other personal protective equipments

: 20 Ear plugs, Safety Belts.

vii) Neutralisation facility provided for neutralizing chemicals

: 12 Goggkes, 14 Helmets


i) Equipments available in Ambulance room

ii) Antidotes available


108


1. Place of availability

2. Capacity

3. Facilities available in the van

v) Details of hospitalsin the vicinity and any the up with them

14. Provision of emergency lighting

15. What other facilities are a available outside the factory premises (Mutual Aid Scheme)

16. Available Meterological data

a) Wind Directions during part of the day



d) Floods Etc.


a) Quantity at a time

b) Name of the chemical

c) Type of carrier


18. Demographic segment map showing the area around factory within the physical range of worst scenario.

19. Whether separate are specially earmarked for parking of tankers in factory / in the vicinity of factory is provided to avoid traffic congestion, if so details of thereof.



109

RASHTRIYA CHEMICALS AND FERTILIZERS LTD, TROMBAY UNIT

1.

FACTORY IDENTITY

a) Name : Rashtriya Chemicals and Fertlisers Limited; Trombay Unit , Chembur.

b) Address : Marvali, Chembur, Mumbai – 400 074. c) Telephone Nos./ Telex / Fax Nos./

: Phone : 2552 2201 – 10 Telex No. : 011-61037, 71228, 72250 RCF B - 1N Fax No. : 022 – 2552 2231 Telegram : Fertilizer

d) (Location ) Railway Line / Highways, passing through / near the area. If so , details of rail / road, crossings / bridges and water way vicinity

: Eastern Express Highway to the North side RCF to Mahul Road to the South side R C Marg , Kurla - Goods railway line to the East Side, creek at the West Side

e) Details of Human Habitation (Village, City, Residential colony, Hospitals etc. near factory within 1 Km.)

SCHOOLS OTHERS POPULATION

Swami Vivekandanda Schools & College complex ( 3 school & 4 colleges) Mumbai Assembly of Good Day School,

Chembur Police Station

65,000

Sind Cosmopolitan High School, Marvali Matta Urdu School , Loreto Convent High School, R.C.F. Colony Municipal Primary School,

Municipal Primary School, Santan Dharma High School, National Sarvodaya High School and Jr. College, Sadhu Vasvan High School

Collector Colony,

Wadavali Village ,Golf Club, Ashish Theatre,

Chembur Colony, R.C.F. Colony, R.C.F. Hospital,

Inlak Hospital

85,000

Jawahar Vidya Bhavan School and Jr. College Complex,

St. Sebastian High School

R.C.F Hospital, RCF Police Station

35,000

Vashi Village , Vitta Sanchay Society

35,000

110

Vasant Dada Patil College of Engineering, Somaiya Trust Medical College

Stray Population 15,000

2. a) Contact Personnel of the factory, their Phone Nos., Designations, Mobile

: Shri R. K. Jain, Exe. Director - Technical ,Occupier Office : 2552 2245 , Residence : 2766 0029 Shri Manoj Priya Chief General Manager (C), Manager Office : 2552 2260 , Residence : 2556 5041

b) Name of the Technical Experts, Designation & their telephone Nos.

: Shri P.B.Asai, DGM(Tech. Services) Office : 2552 2347, Residence : 2558 3206 Shri C.M.Bisen ,CE(Safety & Fire) Office : 2552 2265 Residence : 2550 7624 Mobile : 9987036436

c) Name & phone nos. of Incident & Site Controller

Shri R. K. Jain, Exe. Director - Technical ,Occupier Office : 2552 2245, Residence : 2766 0029

3 Principal Manufacturing Activities : Chemicals and Fertilisers

4. Total number of workers employed : 3000 ( RCF + Contactor + Temporary Contractor)

5. Maximum number of persons, who may be present in factory at any one time

: 2000

6. No. of workers directly involved with the storage of hazardous chemicals/ shift.

: Atmospheric Ammonia storage : 03

Methyl amine storage : 05

111

7. Maximum quantity of hazardous chemicals stored and their mode of storage. (Raw materials, Intermediate products, By products, Finished products)

Chemical Storage

Ammonia Methanol Methyl amine (Anhydrous)

Max. Storage

(MT)

5000 X 2

4930 (539 X 2) (2660 X 1) (840 X 1) (260 X 1) (45 X 2)

247

(50.5 X 2) (61 X 2) (24 X 1)

Mode of Storage

Double wall double integrated, dyked, Atmospheric, refrigerated storage tanks. Fix Conical roof vertical Tanks Vertical Pressurized Storage Tanks with relief valves & header, connected to hot flare

8.

Maximum Credible Loss Scenario :

A) TOXIC DISPERSION :


: Release through 6" NB outlet of New

5000 X 2 nos Atm. Ammonia storage tanks.

In case of


ii) Wind velocity 2m/s 4m/s 6m/s

Radial distance and population around factory which could be affected in meters

Toxicity

a) LC 50 ( 4837 ppm ) 250 100 100

112

b) STEL -- -- --

c) TLV -- -- --

d) IDLH ( 300 ppm ) 1000 800 800


: Methylamine liquid leak from 1.5 “ pipeline from tank bottom..

In case of


ii) Wind velocity 2m/s 4m/s 6m/s

Radial distance and population around factory which could be affected in meters

Toxicity (Anhydrous Ammonia)

a) LC 50 : 4837 ppm ( mouse) 250 100 100

b) IDLH ( 500 ppm ) 1000 800 800

c) IDLH ( 100 ppm ) 663 573 NA

B) In Case of BLEVE, VCE, POOL FIRE as applicable

Brief Description

Maximum Credible Loss Scenario In Case of BLEVE

VCE POOL FIRE as

applicable (Damage Distances in Meters)

Heat Radiation

a) Severe Damage to life and property ( within cloud )

NA NA NA

b) 100% Lethality (37.5 Kw/m2) NA NA NA

c) 50% Lethality (25 Kw/m2) NA NA NA

d) 1% Lethality (12.5 Kw/m2) NA NA NA

e) First Degree 4.5 Kw/m2 of burns NA NA NA

f) No discomfort 1.6 Kw/m2. NA NA NA

113

9. a) Damage distance due to 0.3 bar pressure wave

Ammonia-V plant

Chemical Damage Distance in Meters(Pressure wave

0.3 ) Primary

Reformer Methane --

Secondary reformer

Hydrogen 216

Methanator Hydrogen 389

Synthesis Converter

Hydrogen 837

10

Consequences of Major Hazards that are likely to occur in case of process upsets and storage.

No off-site consequences

11


a) No. of fire fighting equipments and their

capacity

i) Soda acid type -- ii) CO2 type 500 iii) DCP type 600 iv) Foam type 050 b) Fire Tenders/Trailer pump with capacity

Foam Tenders - 2 Nos. with 1350 lts. Foam & 2250 lts. Water and 2000 lts. Foam and 200 lts. Water capacities respectively. DCP cum foam tender - One number with 1000 lts. Foam , 2000 lts. water and 1000 kgs. DCP capacity.

c) Max. Quantity of foam available : 3000 lts d) Water jet monitors nos. : 10 Nos. e) Water storage tank & its capacity

: 0.33 million gallons

f) No. of Hydrant points : 273 g) No. of hose reels & total length : 60 hoses of 75 ft. Each h) No. of fire suits : 10 nos.

114

SANUJ STEELS PVT LTD 1 FACTORY IDENTITY a) Name Sanuj Steels Pvt Ltd. b) Address D R Container Yard

Jeejamata Nagar Mahul Road, ,Chembur, Mumbai – 400 074.


2553 8325 9371160657 [email protected]



: Jeejamata Nagar


: North side : BPT Road South side : Mithul Enclave. West side : Jijamata Nagar East Side : BPCL Refinery


Phone Nos.

Nitin Kharg (Occupier) 9371432000 Dharmesh Sampat 9371160657 Sachin Nair 9967292194


Bottling LPG Cylinders




25.

7. Maximum quantity of hazardous chemicals stored and their mode of storage (raw Materials, Intermediate products, bye-products, finished products).

LPG – 20 MT

8. Maximum Credible Loss scenario ; Not Applicable a) TOXIC DISPERSION : 9. b) Consequences of Major Hazards that

are likely to occur in case of process upsets and storages.

Fire, Explosion


15 DCP Extingusiehes 15 CO2 Extinguishers

b) fire tender / Trailor pump and its capacity

Fixed type Sprinkler system in filling shed and storage of LPG

c) Maximum quantity foam available. - d) Water jet monitors Nos. Hosepipes. e) water storage tank and its capacity : 3 tanks 1 lac ltrs each

115

f) No. of hydrant points : g) No. of hose reels and total length : 6, hoses -15 m each h) No. of Fire Suit : to be procured 11. Details of communication available to


: Telephone, several mobiles

12. Public Alert system and its procedure Fire siren installed at main gate 13. List of protective equipments available

in factory No equipment

14. Medical facility available in factory A few wheeler in case of emergency A first aid kit Details of hospitals LTMG hospital sion KEM hospital, Satapdi Muni Hosp

15. Provision of emergency lighting :DG Set of 25 KV incase of power failure.

16. What other facilities are available outside the factory premises (Mutual Aid scheme)

: Mutual Aid Scheme in trombay, chembur 14 members in cluding Mumbai fire brigade

18. Hazardous chemicals transported : Not applicable. 19. Demographic segment map showing the


: Refer attachment.


116

HINDUSTAN PETROLEUM CORP LTD : AVIATION FUEL STATION

1. FACTORY IDENTITY

a) Name

Hindustan Petroleum Corpn Ltd

Aviation Fuel Station

b) Address Chatrapati Shivaji International Airport, Sahar, Mumbai

c) Telephone Nos. /

Telex / Fax Nos. /

E-mail Address

Phone : 26156284

Fax: 26156285

Email : [email protected]

d) (Location) Railway Line / Highways, passing through / near the area. Is so, details of rail / road, crossings / bridges and water way vicinity

Sahar International Airport.


Slum area, Airport activities.

2. a. Contact personnel of the Factory their phone Nos. and Designation

b) Name of the Technical Experts, Designation and their Phone Nos. Residential No. Area of Specification

Mr. Shamim Ahamad

O-26156285

9004870093

3. Principal manufacturing Activities Storage of ATF and Fueling of Aircrafts

4. Total no. of workers employed 55

5. Maximum no. of persons who may be present in the factory at any one time

25

6. No. of workers directly involved with the hazardous chemicals shift total

persons per shift

7. Maximum quantity of hazardous chemicals stored and their mode of storage (Raw material, intermediate

ATF in atmospheric storage tanks

17830KL

117

products, Bye products. Finished product)

8. Hazardous analysis done Yes/No Attach details with date

Yes, Consequences analysis of storage

8. Maximum Credible loss Scenario Tank fire

a) TOXIC DISPERSION Not applicable

b) Consequences of Major Hazards that are likely to occur in case of process upsets and storages

Not significant


Annexure 1 & Annexure – 1A

10 Details of fire fighting equipments available in the factory

Hydrants

11. Details of communication available to contact police and firebrigade in case of emergency

Telephone, walky talky

12. Public Alert System and its procedure Yes


SCBA, Suit

14 Medical facility available in factory

15. Provision of emergency lighting Yes


IOCL, Airport Fire Station

17. Methods and procedures to be followed by installation own, operators load emergency and medical personnel to respond to release of hazardous chemical.

18. Hazardous Chemicals Transported a) Quantity at a time b) Name of the chemical c) Type of carrier d) Principal destination

-


20. Whether separate area specially earmarked for parking of tankers in factory in the vicinity of factory is provided to avoid traffic. Is so details thereof.

21. Site plan of the factory showing internal roads, locations of storages of hazardous chemicals, bldg, etc.


118

INDIAN OIL CORP LTD : AVIATION FUEL STATION

1. FACTORY IDENTITY

a) Name

Indian Oil Corporation Ltd

Aviation Fuel Station

b) Address Chatrapati Shivaji International Airport, Sahar, Mumbai

c) Telephone Nos. /

Telex / Fax Nos. /

E-mail Address

Phone : 2682 8561

Fax: 2682 9301

Email : [email protected]

d) (Location) Railway Line / Highways, passing through / near the area. Is so, details of rail / road, crossings / bridges and water way vicinity

Sahar International Airport.


Slum area, Airport activities.

2. a. Contact personnel of the Factory their phone Nos. and Designation b) Name of the Technical Experts, Designation and their Phone Nos. Residential No. Area of Specification

Mr. Vinayak Mokashi O-2682 8561 98209 18187

3. Principal manufacturing Activities Storage of ATF and Fueling of Aircrafts

4. Total no. of workers employed 55

5. Maximum no. of persons who may be present in the factory at any one time

25

6. No. of workers directly involved with the hazardous chemicals shift total

persons per shift

7. Maximum quantity of hazardous chemicals stored and their mode of storage (Raw material, intermediate products, Bye products. Finished product)

ATF in atmospheric storage tanks

17830KL

8. Hazardous analysis done Yes/No Attach details with date

Yes, Consequences analysis of storage

119

8. Maximum Credible loss Scenario Tank fire

a) TOXIC DISPERSION Not applicable

b) Consequences of Major Hazards that are likely to occur in case of process upsets and storages

Not significant


Annexure 1 & Annexure – 1A

10 Details of fire fighting equipments available in the factory

Hydrants

11. Details of communication available to contact police and firebrigade in case of emergency

Telephone, walky talky

12. Public Alert System and its procedure Yes


SCBA, Suit

14 Medical facility available in factory

15. Provision of emergency lighting Yes


IOCL, Airport Fire Station

17. Methods and procedures to be followed by installation own, operators load emergency and medical personnel to respond to release of hazardous chemical.

18. Hazardous Chemicals Transported a) Quantity at a time b) Name of the chemical c) Type of carrier d) Principal destination

-


20. Whether separate area specially earmarked for parking of tankers in factory in the vicinity of factory is provided to avoid traffic. Is so details thereof.

21. Site plan of the factory showing internal roads, locations of storages of hazardous chemicals, bldg, etc.


120

SEA LORD CONTAINERS LIMITED

1. FACTORY IDENTITY a) Name Sea Lord Containers Ltd.

b) Address

Ambapada, Mahul Village, Near BPCL Refinery main gate, Chembur, Mumbai - 74

c) Telephone Nos. / Telex /Fax Nos. / E-mail Address.

Phone : 2553 5523, 2553 5524. Fax : 25546093.

d) (Location) Railway Line / Highways, passing through / near the area. If so, details of rail / road, crossings /bridges and water way vicinity.

e) Details of Human habitation (village, City, Residential colony. Hospital etc. near the factory etc. near the factory within 1 Km.)

None within a Km


P P Kudchadkar – Vice President Office Phone: 25535520; Mobile: 9821118907 M A Bohari, Office Phone: 25544832; Mobile: 9987273489 .

b) Name of the technical experts designation & their phOone Nos.

Dr. S. K. Biswas, Group Advisor (Safety & Environment) Office Phone : 2057076 / 2082242. Residence Phone- 2183288 S. K. Hazra, Managing Director, Phone: 2057076 / 2082242 Mobile: 9821018104; Residence : 2185743 D. J. Kulkarni, Advisor Fire fighting, Office Phone : 7241740 Residence Phone: 5153548.


D. K. Bheda, (LPG), Office Phone: 5544975: Residence Phone: 7801427.


It is not a manufacturing unit. It is a terminal for storing bulk liquid Chemicals and liquefied petrochemical.

121

4. Total No. of workers employed 50 Nos.


30 Nos. (General Shift)


7 Nos.

7. Maximum quantity of hazardous chemicals stored and their mode of storage (Raw Materials, Intermediate products, bye-products, finished products).

Liquid Chemicals: Methanol/Hexane Maximum quantity in storage at one time 75,000 T in atmospheric tanks.

8. Maximum'Credible Loss Scenario:

a) TOXIC DISPERSION: Not Applicable.

Brief description of Maximum Credible Loss Scenario In case of:


ii) Wind Velocity 2m/sec 4 m/sec 6 m/sec

b) IN CASE OF BLEVE, VCE, POOL FIRE AS APPLICABLE



Worst case scenario is fire in bund area due to LPG tank leak. It is a Non-Credible Scenario (Probability once in one billion years)

Heat Radiation


None. b) 100% lethality (37.5 Kw/m2)


No credible off-site effect

d) 1% Lethalitv (12.5 Kw/m2)

e) First Deciree 4.5 Kw/m2

f) No discomfort 1.6 Kw/m2.

a) Damage distance due to 0.3 bar pressure

122

9. Consequences of Major Hazards that are likely to occur in case of process upsets and storage.

No pressing activity involved. Fire inside the terminal because of spillage, even it occurs wilt be contained within the terminals.

10. Resources Available


a) Fire tender / Trailer pump and its capacity

Fire Tender Water Tank Capacity : 3000 Litres. Foam tank capacity : 1000 Litres. 2270 lpm at 7 kg/cm2.

b) Maximum quantity of foam available.

: 5000 Litres. ATC

c) Water storage tank and its capacity

: 8600 m3 non-saline water.

d) No. of hose reels and total length

: 66Nos.X1bm.

h) No. of fire Suit

: 01 Nos


a) Telephone

: 25535523/25535524/64506793

b) Hot Line

c) Wireless

d)Walkie Talkies etc.

9 Nos. Walkie talkie.


Long distance Electrical Siren (5 Km).



First Aid Box -4 Nos.

ii) No. of Self contained breathing apparatus

1 Set.


1 Nos.

iv) No: of canister respirators : 10 Nos.


: PVC suit.

123

vi) Any other personal protective equipments.

: Helmet, Face shield. Safety goggles, ear plugs, ear muffs, hand gloves, Safety shoes, blowman mask.

14. Medical facility available in factory : N. A.

i) Equipments available in Ambulance room.

ii) Antidotes available : N. A.

iii) No. of first aiders available : 28 Nos.


: Jeep – 2 Nos


: Permanent arrangement with Inlaks Hospital, Chembur Colony.

15. Provision of emergency lighting : Yes.


a) Quantity (MT / day) 400 1600

b) Name of the Chemical Methanol Hexane

c) Type of carrier Tanker tanker



.


124

ANNEXURE – II

OFFISTE PIPELINES CARRYING HAZARDOUS MAERIAL IN MUMBAI

SUBURBAN DISTRICT

125

AEGIS CHEMICAL INDUSTRIES LTD PETROCHEMICALS / POL PRODUCTS

S. No.

DESCRIPTION DETAILS

1. NAME OF FACTORY Aegis Chemical Industries Ltd., Mahul

2. MATERIAL BEING TRANSPORTED / RECEIVED Petrochemicals / POL Products

3. PIPELINE DETAILS :

a) Diameter

b) Length

(applicable to Mumbai Suburban District)

c) Operating Pressure

d) Flow/Hr

e) Above ground / Underground

12” -2 No’s (From new jetty) &

6” – 1 No. (from old jetty) in all three pipelines

4.6 Km 12” each & 22 Km 6”

5 Kg/cm2 g

300 MT/Hr for 12” & 120 MT/Hr for 6”

Above ground

4. ROUTE OF PIPELINE Schematic attached as annexure

5. TYPE OF EMERGENCY FIRE

6. POPULATION LIKELY TO BE AFFECTED None within one km.

7. SAFETY MEASURES TAKEN Continuous patrolling along the piping route is being down during ship unloading/loading to detect leakage. The following safety measures exists/undertaken :

a) Manually operated isolation valves provided on each lines in the jetties and at Terminal for stopping unloading/loading operation.

b) During ship unloading/loading of liquid cargoes, Security Personnel carry out patrolling of

126

pipeline.

8. EMERGENCY PREPAREDNESS In case any leakage is observed, patrolling personnel will inform Duty Officer at the Terminal promptly and also the officer at the jetty. Thereafter the following actions will be taken immediately.

a) Shutting of Manual valves at the jetty and terminal

b) Stop pumping from terminal or from the ship.

c) Cordon off the area. Avoid any spark/open flame. Restrict entry to people and vehicles engaged in controlling the situation.

d) Inform MBPT fire station. Rush aegis fire tender to affected area.

e) Spray Foam on the spilled product. Arrange for attending the leakage and collection of product.

9. CONTACT PERSONS AND THEIR PHONE NOS. :

Terminal Officer 5544832 Extn 19

Mr. S.K. Sawant, Vice President 5546721, 5544832 Extn : 10

Mr. D.K. Bheda, General Mgr. 5544975, 5544832 Extn : 11

Mr. P. H. Darji, Chief Term. Mgr. 5541105, 5544832 Extn. 14

Mr. R. M. Mahajan, Dy Mgr. Ops Security Officer 5544832

5544832 Extn. 31

127

AEGIS CHEMICAL INDUSTRIES LTD– LPG/PROPANE

S. No

DESCRIPTION DETAILS

1. NAME OF FACTORY Aegis Chemical Industries Ltd., Mahul

2. MATERIAL BEING TRANSPORTED / RECEIVED Petrochemicals / POL Products


a) Diameter

b) Length


c) Operating Pressure

d) Flow/Hr

e) Above ground / Underground

12” Main unloading line with 6” chaling line

4.6 Km each

5 Kg/cm2 g

400 MT/Hr. Maximum

Above ground

4. ROUTE OF PIPELINE Attached as annexure

5. TYPE OF EMERGENCY Fire / Explosion

6. POPULATION LIKELY TO BE AFFECTED None within one km.

7. SAFETY MEASURES TAKEN Continuous patrolling by Engineering personnel during ship loading to detect any leak. The following safety measures exists/undertaken :

a) Automatic emergency shutdown by immediate closing of SOV at the new pirpau jetty in case of failure of unloading pipeline.

b) Remote controlled system (ESD) located far away from the unloading arm at jetty for closing of emergency so for immediate stopping of unloading operation.

c) Gas detectors are provided along the pipeline at specific

128

location as well as jetties.

d) Automatic emergency closure of SOV in case of gas detection.

e) Automatic emergency closure of SOV on unloading arm envelop going in red zone.

f) Interlinking of ship shore ESD whenever ship has interlinking facility, on agreement with ship master

g) During ship unloading engineers carry out patrolling of pipeline with portable gas detectors & communication devices

h) 2 Nos manually operated isolation valves in the jetty for isolation

8. EMERGENCY PREPAREDNESS In case any leakage is observed, engineer on patrolling duty will immediately inform,

a) Terminal Officer in Ship

b) Operator at unloading jetty

c) Terminal Control room personnel Sinultaneously following actions will be initiated

a) Automatic / Remote control closure of SOV at Jetty

b) Automatic stoppage of ship pump

c) Shutting of manual valves at the jetty and valve manifold

d) Cordon off the area Avoid any spark / open flame Restrict entry to people &

129

vehicles engaged in controlling the emergency

e) Inform MbPT fire station Rush Aegis fire tender to affected area

f) Disperse gas leak with water spray from fire tender and other water source

9. CONTACT PERSONS AND THEIR PHONE NOS. :

Control Room Operator 2541514

25544832 Extn 30

Mr. S. K. Sawant, Vice President

25546721 25544832 Extn : 10

Mr. D. K. Bheda, General Mgr. 25544975, 25544832 Extn : 11

Security Officer 5544832 Extn 31

130

BHARAT PETROLEUM CORPORATION LTD- HSD / MS /KERO

S.NO. DESCRIPTION DETAILS

1. NAME OF FACTORY Bharat Petroleum Corporation Limited

2. MATERIALS BEING TRANSPORTED/RECEIVED

a. High Speed Diesel

b. Motor Spirit

c. Superior Kerosene


a. Diameter

b. Length

(Applicable to Mumbai suburban district)

c. Pressure

d. Flow/Hr

e. Above ground/below ground

18 inches

116 Km (Mumbai to Igatpuri taluka entry point)

57.5 – 10 kg/cm2

650 – 700 M3/Hr

Burried line

4. ROUTE OF PIPELINE Route along with topography of the line enclosed

5. TYPE OF EMERGENCY Fire/Hydrocarbon leak

6. POPULATION LIKELY TO BE AFFECTED

500 Hutment at Sathe nagar area in Mankhurd

7. SAFETY MEASURES TAKEN : a) Catholic protection and 3 ply extruded polyethylene coating upto first 47 km and coal tar enamel coating for the rest to avoid external corrosion

b) Pumping of corrosion inhabitor to protect inner surface

c) Supervisory control and data acquisition system (SCADA) for on line monitoring and control of pipeline and to detect the leaks.

d) Round the clock surveillance of P/L in city region and single shift surveillance for the rest of pipeline.

e) Provision of sectionalizing valves between sensitive sections for isolating a particular section in case of any

131

emergency.

f) Quarterly line inspections are carried out by all officers to familiarize the route as well as to check for leak/pilferage, encroachments etc.

8. EMERGENCY PREPAREDNES

a) Dedicated phones and hot lines between control rooms along the pipeline b) A dedicated emergency rescue vehicle with crew, kept at Mumbai control room round the clock. c) All engineers and selected higher officials of MMPL have been provided with pagers and mobile phones. Respectively to get them at short notice in the event of an emergency. d) All three control rooms are manned by engineers round the clock. e) Roles and responsibilities of each officers are laid down to tackle any emergency situation. f) All important Phone numbers such as Civil Police, Factories, Fire Brigade Authorities etc. are kept in all control rooms.

9. CONTACT PERSONS AND THEIR PHONE NOS. a) Mr.G.S.Wankhede Chief Operations Manager b) Mr. N. Manohar Rao Sr.Manager(M&C) c) Mr.V.B.Sharma Sr. Mgr. Operations d) Control Room, Mumbai e) Fire Station, BPCL(R) f) Asst. Commandant, CISF, BPCL (R)

25545540 (0) 25685363 (Resd.) 9820048707 9820039527 25543151 Extn. 3865 2554408 (Resd.) 25545540 (Office) 8402560 (Resd.) Extn 25545540 9820037151 25545480 25543175

132

GAS AUTHORITY OF INDIA (GAIL) : NATURAL GAS

S.NO. DESCRIPTION DETAILS

1. NAME OF FACTORY Gas Authority of India Limited

2. MATERIAL BEING TRANSPORTED/RECEIVED

Natural Gas

3. PIPELINE DETAILS

a) Diameter

b) Length

c) Pressure

d) Flow/Hour

e) Above ground (AG)/Underground (UG) (Kms.)

1. Trombay – RCF pipeline = 18”

2. Trombay – MGL pipeline = 18”

1. Trombay – RCF pipeline = 5.5 Kms

2. Trombay = MGL pipeline = 7.7 Kms.

Both 25 – 40 kg./Sq.cm

1. Trombay – RCF pipeline = 75000 SCM/Hr

2. Trombay – MGL pipeline = 16600 SCM/Hr.

3. Trombay – RCF pipeline U/G 2.7, A/G:2.8

1. Trombay – MGL pipeline U/G 7.1, A/G:0.6

4. ROUTER OF THE PIPELINE Both the pipelines are routed between ONGCL, Trombay near BARC through BPT/BPCL areas and RCF. Route sketch attached as Annexure

5. TYPE OF EMERGENCY Fire only


Both pipelines are routed through industrial premises of BPT/BPCL and RCF through non-residential areas.

7. SAFETY MEASURES TAKEN 1. Both the pipelines are designed as per the Industry Code ANSI B 31.8 with due allowances for class locations and isolation valves at vantage points

2. Pipeline is provided with anti-corrosion coatings and supplemented with Impressed current Catholic Protection system.

3. Dedicated communication network and SCADA (Supervisory Control and Data Acquisition) for monitoring the

133

various parameters on real time basis.

4. Remote operated isolation valves are provided on both the pipelines for isolation and safe evacuation of line contents in case of emergency.

5. Routine Patrolling of pipeline is carried out to monitor and control any activity in the pipeline route.

8. EMERGENCY PREPAREDNESS a) Control room manned round the clock is functioning from City Gate station Opp. Anik Bus Depot, Wadala. This center is provided with Supervisory Control and Data Acquisition System (SCADA) to monitor pipeline operation and safety. Vehicle is also available at this centre round the clock.

b) Emergency items such as leak champs hydrotested pipes, etc. are kept in stock to contain the leak online.

c) GAIL has no process plants in the area and hence no dedicated fire brigade is envisaged. However, GAIL has joined the Mutual Aid Scheme of Trombay area industries for aid at times of emergencies.

9. CONTACT PERSONS AND THEIR PHONE NUMBERS

Master Control Room 4070156 / 4070129 Mr. AK Purwaha General Manager 6542321 (O) 6542064 ® Mr. Shyam Sunder Sr Manager O & M 6541935 (O) 6508840 ® MBAA Sr Manager HR 6542373 (O) 6527464 ® Mr RK Kamra Manager Finance 6541731 (O) 6542385 ®

134

HINDUSTAN PETROLEUM CORPORATION (ATF) S NO DESCRIPTION DETAILS 1 NAME OF FACTORY Hindustan Petroleum Corporation Limited 2 MATERIAL BEING

TRANSPORTED / RECEIVED ATF (Aviation Turbine Fuel)

3 PIPELINE DETAILS a. Diameter b. Length


c. Pressure d. Flow/Hr

e. Above

ground/underground

10 inches O.D. 19.65 km 10 Kg.sq.cm. 250 KL/Hr Underground

4 ROUTE OF PIPELINE HPFR- BPCR-RCF-NERUNAGAR-KURLA – SANTACRUZ AIRPORT-SAHARAIRPORT Route sketch attached.

5. TYPE OF EMERGENCY Oil Spillage / Fire 6 POPULATION LIKELY TO BE

AFFECTED Line passes through non-population / non residential area

7 SAFETY MEASURES TAKEN a. Line walkers provided in three shifts b. Pressure/Flow rates closely

monitored during pumping at both the ends.

c. Line is inspected and tested as per statutory norms.

8 EMERGENCY PREPAREDNESS a. marketing group has an emergency crew which can attend all the pipeline emergencies.

b. Refinery also gives additional help as and when required

9 CONTACT PERSONS AND THEIR PHONE NOS.

1. Shift Terminal In-charge : 26156285/86/26156453/26156892 2. Dy Manager OM&S : 25544133

135

HINDUSTAN PETROLEUM CORPORATION LTD : MS/HSD/KERO

S NO DESCRIPTION DETAILS 1 NAME OF FACTORY 2 MATERIAL BEING

TRANSPORTED / RECEIVED MS/HSD/SKO

3 PIPELINE DETAILS f. Diameter g. Length


h. Pressure i. Flow/Hr

j. Above

ground/underground

14 inches O.D. 162.17 + 342 km 12 Km (refinery to vashi bridge toll naka) 58.0 Kg.sq.cm. 600 KL/Hr Underground

4 ROUTE OF PIPELINE Route sketch attached as annexure 5. TYPE OF EMERGENCY Fire / explosion 6 POPULATION LIKELY TO BE

AFFECTED MPSPL

7 SAFETY MEASURES TAKEN All MPPL locations are provided with adequate nos of DCP extinguishers, CO2 extinguishers, fire hydrant, monitors, sand buckets and fire hoses. To take care of offsite, foam tender, gully emptier, compressor truck are available

8 EMERGENCY PREPAREDNESS Disaster control plan for Onsite and Offsite is prepared and responsibilities are assigned to individuals

9 CONTACT PERSONS AND THEIR PHONE NOS. A B Thosar – Gen Mgr Suranjan Pal – Ch Mgr V K Singh – Manager S K Mohapatra – Mgr Maint

OFFICE 22614352 25542184 25544266 25540555

Residance 25306561 27530628

136

HINDUSTAN PETROLEUM CORPORATION LTD : FO / LDO

S NO DESCRIPTION DETAILS 1 NAME OF FACTORY Hindustan Petroleum Corporation Ltd 2 MATERIAL BEING

TRANSPORTED / RECEIVED FO / LDO (Fuel Oil / Light Diesl Oil)

3 PIPELINE DETAILS k. Diameter l. Length


m. Pressure n. Flow/Hr

o. Above

ground/underground

12 inches O.D. 21 km 20 Kg.sq.cm. 90 KL/Hr – 320 Kls/hr Underground

4 ROUTE OF PIPELINE BOPL line passes in the same alignment but on the other side of the road.

5. TYPE OF EMERGENCY Fire 6 POPULATION LIKELY TO BE

AFFECTED MPSPL

7 SAFETY MEASURES TAKEN All MPPL locations are provided with adequate nos of DCP extinguishers, CO2 extinguishers, fire hydrant, monitors, sand buckets and fire hoses. To take care of offsite, foam tender, gully emptier, compressor truck are available

8 EMERGENCY PREPAREDNESS Disaster control plan for Onsite and Offsite is prepared and responsibilities are assigned to individuals

9 CONTACT PERSONS AND THEIR PHONE NOS. A B Thosar – Gen Mgr Suranjan Pal – Ch Mgr V K Singh – Manager S K Mohapatra – Mgr Maint

OFFICE 22614352 25542184 25544266 25540555

Residance 25306561 27530628

137

INDIAN PETROCHEMICALS CORP. LTD : PROPANE (LIQUID) S. NO

DESCRIPTION DETAILS

1. NAME OF FACTORY M/s Indian Petrochemicals Corp. Ltd., Nagothane

2. MATERIAL BEING TRANSPORTED/ RECEIVED

Propane liquid

3. PIPELINE DETAILS a. Diametre b. Length c. Pressure d. Flow/Hr. e. Above ground/ Underground (Kms)

4” NB 2000 MTR Apprx. Upto Pirpau jetty and further 11.7 Km in Thane creek upto Shivaji Nagar Land fall point. 74.00 KG/CM2 15 T/HR. Above ground upto Pirpau jetty and sub sea in the Thane creek

4. ROUTE OF PIPELINE Route sketch attached as Annexure

5. TYPE OF EMERGENCY Fire / explosion


Within the vicinity of BPCL Refinery. Tata Electrical and Mumbai Port Trust area.

7. SAFETY MEASURES TAKEN

1. Catholic protection of the pipeline 2. Dedicated telecommunications system from HALPG to MGCC. Nagothane 3. Installation of sectuibalising valve at Shivajinagar to get the portion HALPG to thane creek isolated 4. Off-shore security for round the clock in thane creek.

8. EMERGENCY PREPAREDNESS

For any fire fighting requirements M/s BPCL, HALPG and Mumbai Port Trust can be requested as per mutual aid basis scheme of understanding

9. CONTACT PERSONSAND THEIR PHONENOS a. Mr. S. RAvikumar – ED (NC) b. Mr. J.L. Wazir – GM (O) c. Mr. M.A. Venkatraman – DGM (O) d. Mr. W.P. Vittal – Sr. Manager (GC) e. Mr. K.K. Jain – Mgr. Pipelines

021442 2280 2323 Extn. 2165 021442 2280 2317 Extn. 2301 021442 2280 2434 Extn. 2093 021441 2280 2431 Extn. 021442 2280 2424 Extn 2095

138

MAHANAGAR GAS LTD.: NATURAL GAS S. NO

DESCRIPTION

DETAILS

1. NAME OF FACTORY Mahanagar Gas Ltd.

2. ADDRESS Pay & Accounts Building Bandra Kurla Complex Bandra (East) Mumbai 400 051 Tel. : 6541708 / 6542675 / 6541705 Fax : 91-22-6542156


Natural Gas

4. PIPELINE DETAILS Diametre Length Pressure Flow/Hr. Above ground/ Underground

The steel Grid mains system is constructed to British Gas and internationally accepted standards and is fully welded system. To date approximately 58 kms are laid at a diameters between 3” – 18” The operating pressure of the steel Grid pipeline is 19 Bar All pipe is laid below ground at 1.2 m cover. For protection a sand surround is provided with protective marker tape above with warnings in two languages. The flow rate is dependent on the demand of the network and varies throughout the day and also day to day.


6. TYPE OF EMERGENCY The potential emergency situation from the 19 bar system is predominately i) release of natural gas ii) subsequent ignition fire To date no incidence of this nature has arisen


The population affected will be dependant on the type/location of any incident. Pipeline route planning takes considerations of dense population


Apart from the above safety precautions mentioned, the system is fully protected from corrosion by a PE coating and catholic protection system. Isolation valves are positioned at a strategic positions to unable specific sections to be isolated in case of emergency. Mahanagar Gas ltd employs pipeline patrolman who continually survey the route of our system to ensure no third party works are being undertaken nearby and to educate other utilities in awareness regarding our plant.

139

As natural gas is odourless odour is added at our supply point to the network. Weekly checks at various system points ensure that correct levels are present. Safety awareness programmes are carried out in each gas supply area to ensure that customers and members of the public are educated in our product.


Full emergency procedures are in place to deal with any potential scenario that may occur on our system MGL has an emergency control Centre with one telephone contact number (4012400). This control centre is linked by a communication system to 3 emergency response locations. These locations have fully mobile emergency crew led by trained technicians. This emergency source operates 24Hrs X 365 days.

10. CONTACT PERSONS AND THEIR PHONE NOS

A rota system exists for all levels of attendance at emergency situations, up to the Technical and Managing Director level. Again contact is through the one emergency telephone no 401 2400

140

RASHTRIYA CHEMICALS & FERTILIZERS LTD.: NATURAL GAS S. NO

DESCRIPTION DETAILS

1. NAME OF FACTORY Rashtriya Chemicals & Fertilizers Ltd., Trombay Unit

2. MATERIAL BEINGTRANSPORTED/RECEIVED

Natural Gas

3. PIPELINE DETAILS a. Length of pipeline b. Dia of pipe line c. Pressure d. Flow e. Above/Underground

5.5 Kms. (only 400 meters is along the Mahul road and remaining inside BPT/BPCL/Tata/RCF Trombay 18” 26 Kg/cm2 to 36 kg/cm2 2.5 MMCMD Line is above ground and under ground 400 meters outside R.C.F. is under ground

4. ROUTE OF PIPELINE Attached as Annexure

5. TYPE OF EMERGENCY Fire/Explosion


About 2500 people (Jeejamata Nagar and few hosuing societies adjacent to R.C.F.)


Inspection by gas detector. Under ground section has been protected by Catholic Protection


GAIL has no established Fire fighting department. GAIL and ONGC are members of Mutual aid scheme for Chembur – Trombay region. During emergency Mutual aid scheme will be activated. Identification of source of leakage and its control and then appropriate measures like isolation of gas supply from ONGC/GAIL, evacuation of population etc. will be taken. (depending upon the nature and severity)

9. NAME AND PHONE NOS. OF KEY PERSONS TO BE CONTACTED IN CASE OF EMERGENCY

From GAIL 1. Mr. Shyamsunder, Sr. O.M. Off. 654 1935 Res. 650 8840 2. Shift in Charge M.C.R. Phone No. 407 0156/407 0129 Shift In Charge R.C.F. Terminal Phone No. 5585067 From R.C.F. Ltd. Fire Station : 558 0387 Work Manager : 556 5879 / 556 1780

141

RELIANCE INDUSTRIAL INFRA LTD: NAPHTHA / KERO S. NO

DESCRIPTION

DETAILS

1. NAME OF FACTORY Reliance Industrial Infrastructure Limited


Naphtha / Kerosene

3. PIPELINE DETAILS a. Diametre b. Length (applicable to Mumbai Suburban District) c. Operating Pressure d. Flow/Hr. e. Above ground/ Underground

Between BPCL Mahul Refinery & RIL, PG 200 mm NB Twin Pipelines 10.5 KM (Total length 54 kms.) 55 Kg/cm2 200 M3/Hr Underground


5. TYPE OF EMERGENCY Fire


-


Periodical Check up and type of check up :- Our pipelines are coated with coal tar coating plus pipelines are provided with Impressed current catholic protection system. Reading of all the test points, where level of Cathodic Protection is reas, en route the pipeline and cathodic protection stations, are taken on every fortnight basis. The increase, decrease in current level, other steps are arranged on this feedback. In addition to this, physical surveillance of the pipeline route is carried out daily on round the clock basis through foot patrol. Detection of Leakage : Our pipelines are provided with Supervisory Control and Data Acquisition (SCADA) System, which shows the operating pressure, flow rate etc. Same is monitored in our Patalganga Control Room on 24 hrs.

142

Basis. The system gives alarm if the pressure loss is 0.05 kg/cm2/sec. Or the volume difference is 5 m3/hr or 2m3/30min. Or 1 m3/6min. Between despatch and receiving end.


Emergency Tool Kit with on-line high pressure leak arresting clamp is kept ready at our JNPT Terminal. In case of any abnormal pressure drop / volume loss, the pumping is stopped immediately. The pipelines are provided with isolation valves at intermediate stations which can be remotely operated from Control Room. During emergency, these valves will be closed to isolate the section and identify the exact location. Meantime, team will arrest the leakage with high pressure clamp. In addition to above, Fire Tenders, Ambulance are available with our Patalganga Plant for 24 hours.

9. CONTACT PERSONS AND THEIR PHONE NOS

Patalganga Control Room : 91450705 JNPT Terminal C/R : 7242145 JNPT Terminal Security : 7242143 BPCL C/R : 5540151 Extn.3491/3492/3497 Shri A.S. Desai, GM (B.M. & S) :- 7242141 (O), 6553461 ® Shri F.M.K. Gouda, Ops. Manager 91450705 (O), 7450016 ®

143

TATA POWER COMPANY LIMITED : NATURAL GAS S. NO

DESCRIPTION

DETAILS

1. NAME OF FACTORY Tata Power Company Ltd, Trombay Thermal

Generating Station, Mahul Road, Chembur, Mumbai – 400 074


Natural gas being received via off-site pipeline from Gas Authority of India No hazardous material being transported via offsite pipeline

3. PIPELINE DETAILS a. Diameter b. Length (applicable to Mumbai Suburban District) c. Pressure d. Flow per hour e. Above ground/ Underground

For units 4, 5, & 6 For unit 7 450 mm 300 mm 150 m 200 m Approx. Approx. 7 bar 30 to 40 bars 110 tons/hr 30 tons/hr Maximum Maximum Underground Abovegound

4. ROUTE OF PIPELINE This pipeline is location near drainage channel (along Mumbai Port Trust road) entering in Tata Electric premises. Route sketch attached as Annexure

5. TYPE OF EMERGENCY : TOXIC RELEASE / FIRE / EXPLOSION

Natural gas leak and subsequent fire


Since this pipeline is located near drainage channel (along Mumbai Port Trust road which lies within plots of Tata Electric Company, no external population is likely to be affected.


a. Relief valve and cold flare system b. External visual inspection per quarter c. Thickness measurement per annum as per statutory requirement d. Provision of remote operated valve on one line. For another line, this system in being installed.


a. Full fledged fire station with fire fighting crew exists. b. On-site emergency management plan is practiced periodically c. Mutual aid scheme (MAS) exists within

144

major industries in Chembur Trombay area. Interactive meetings are held by members regularly.

9. CONTACT PERSONS AND THEIR PHONE NOS a. Ashok Sethi – Vice President b. A P Wankhede – General Mgr.

OFFICE RESIDENCE 6717 5114 6717 4004 6717 5104 25542194

145

ROLE OF FIREBRIGADE PREAMBLE

Section 359 to 364 of B. M. C. Act 1888 provide for maintenance of Fire Brigade by the Municipal Corporation of Greater Mumbai. It also provides that all the Municipal Officers and Police Officers to assist Fire Brigade while dealing with the fire emergencies all kind of emergencies which include House Collapses, Chemical Leakage's, Gas Leakage's, Rail, Road and Air Accidents, Floods and Earthquakes, or in short, in addition to the fire fighting, the brigade offers the services on humanitarian grounds, whenever and wherever any human life is in distress, expect in the cases of epidemics.

Throughout the world, over the period of time, large scale chemical industries have been established which contain potential fire as well as chemical and gas leakage's risk. There have been number of serious disaster resulting in death of thousands of people and also destruction of properties. It has become necessary to prepare for the disasters in advance so that loss of life and property can be minimized.

As is know, the magnitude of disasters cannot be anticipated nor the resources can be separately created for management of disasters. It is also a common knowledge that there are number of Government, Semi-Government agencies who have requisite equipment and manpower to deal with routine or normal anticipated emergencies. For preparedness to a major disaster, it would be therefore, necessary to co-ordinate the services of all these agencies under one umbrella upgrade the same wherever necessary and see that all the services are available to deal with the disaster within a shortest possible time Annexure - 'A' shows the agencies which are available in the City of Mumbai whose works need to be co-ordinated for attendance to a disaster.

Depending upon the type and seriousness of emergency as a matter of routine the services of Hydraulic Department, Sewerage Department, Buildin Department, Ward Office, Municipal Labour Contractors, Police, Homeguards Civil Defense, B.E.S.T., B.S.E. S., Municipal and Government Hospitals, Bomba Port Trust, Private Ambulances, Mutual - Aid - Schemes, Air-Port Fire Service and also the Fire services from Thane, Vashi etc. Are requisitioned by Mumbai Fire Bridgade in the event of an emergency. The enclosed Annexures 'A', 'B', 'C 'D', 'E', and 'F' give details information regarding the location of Fire Stations availability of various type of Fire Appliances, Fire Engines etc., names an addresses of senior officers, manpower posted at each fire station.

CONTROL ROOM : The Mumbai Fire Brigade has its Control Room situated at Fire Brigade Headquaters, Byculla which is manned with adequate number of staff coatinuously

146

for 24 hours and headed by Divisional Officer (Mobilization assisted by Duty Officer of the rank of Sub-Officer in each shift. The Control Room can be contacted in case of emergency on Telephone Nos. 101, 3095191 3076111 and 3086171.

HEALTH SERVICES ORGANISATION Introduction Mumbai is a major financial commercial and industrial City of India. It is linked with the world through air, sea and road. The people from all over India come to this city in search of livelihood. It is estimated that about 300 families migrate to city of Mumbai every day. The land available is about 437.71 Square Kilometre and population is 99,26,000 as per 1991 census. The density of population is about 22,677 per Square Kilometer, which is very high. The cost of land and its development is exorbitant, which a common man cannot afford. Thus, slums have developed on almost all the available vacant lands including footpaths. Greater Mumbai is divided in 3 welt-defined areas, viz. City Western Suburbs and Eastern (Central) Suburbs on account of its peculiar geographical position. The city consists of A, B, C, D, E, F, and G administrative municipal wards. Western suburbs consists H, K, P and R Wards while the Eastern Suburbs, also called as Central Suburbs, has L, M., N., and T., Wards. 21 hazardous chemical factories are located in Mumbai Suburban District. Chemical factories in Belapur - Thane -Raigad are also within easy reach of Mumbai. The population in the Eastern Suburbs is about 24,70,476 lakhs as per 1991 census and the land available is 156.93 Square Kilometres. The population in the Western Suburbs us about 42,80,526 lakhs and the land available is 212.99 Square Kilometer. Hence density of population in this suburbs is 13,237 Square Kilometer. Thus, the calamities affecting Eastern Suburbs (or for that matter any part of Mumbai) may result into extensive damage to the life and property.

The Municipal Commissioner, heads the administration of the Corporation. In this, he is assisted by two additional Municipal Commissioner and Deputy Municipal Commissioners. Executive Health Office remains at the helm of Public Health matters. He is responsible to additional Municipal Commissioner. He is assisted in his day-today work by four Deputy Executive Health Officers, nine Assistant Health Officers and many other assistants. Since the disasters striking Mumbai - shall involve health and life of the public, Health Officer shall be in over all control of health management in case of disaster organisation Chart is put up at Annexure - 1. INFRASTRUCTURE

147

The Mumbai Municipal Corporation provides the most comprehensive Health services to citizens. There are 3 major Hospitals with medical colleges and one Dental College, each one is under the charge of a Dean. One infectious Diseases Hospital one Tuberculosis Hospital, one E. N. T. Hospital and One Eye Hospital, all these hospitals are located in city area. There are 13 General Hospitals located in suburbs (Eastern and Western). Each Hospital is managed by either Medical Superintendents or medical Officers. The Director of Peripheral (Suburban) Hospital is in over all control of these Hospitals Total number of above general hospital beds is 7,318. These Hospitals provide general, special and super-special services to citizens in all the fields of medicines, surgery, maternal and child health etc. Detection and diagnosis of diseases is done by qualified, experience and skilled medical and para-medical staff. Each Hospital has well equipped laboratory, X-ray machines and most modem other equipment's like Sonography - CAT Scan, etc. Intensive Care Units for all sorts of emergencies are also available in these Hospitals. Treatments is given with advanced new generations drugs which also include chemo-theraphy, Radio-theraphy, Pnysio-theraphy, Occupational Therapy is also given to the patients. The major hospitals in the city have their own blood banks while in suburbs most of them have to depend upon private blood banks, list of blood banks is attached. At least one ambulance appropriately equipped with emergency kit is attached to each Hospital and most of the Hospitals have mortuary and hearse-. There are two Coroner's Court, one in J. J. Hospital Compound and another in Cooper Hospital in K/West Ward of Western Suburbs have 7 general Hospitals, located in different wards with bed strength of 1,281 beds. Each Hospital is given number of direct telephone lines and department within the hospital are connected with Inter-com system. Residential Medical Officers are also provided with telephone connection. There are about 150 Municipal dispensaries in Greater Mumbai which work like Out Patient Departments, of these 33 are located in Eastern Suburbs. AMBULANCE SERVICE : The list of Ambulance services in Eastern Suburbs with location and telephone number is given in the list. Each ambulance shall be equipped with :-

• Stretcher • Blanket • Oxygen Cylinder • Incubation Kit • Pain Killers • V. Set • First Aid / Resuscitation Kit.

149

ANNEXURE – III

INFORMATION ON CHEMICALS AT THE MAJOR HAZRD UNIT FACTORIES IN

MUMBAI SUBURBAN DISTRICT

CHEMICALS AT THE MAH FACTORIES IN MUMBAI SUBURBAN DISTRICT NAME OF CHEMICAL

1. ACETONE

2. AMMONIA

3. ASPHALT

4. BENZENE

5. BUTADIENE

6. CHLORINE

7. DIESEL

8. DIMETHYLAMINE

9. GASOLENE

10. HEXANE

11. HYDROGEN

12. ISOPROPYL ALCOHOL

13. KEROSENE

14. LIQUEFIED PETROLEUM GAS

15. MONOMETHYLAMINE

16. METHANOL

17. NAPTHA, COAL TAR

18. NITRIC ACID

19. PARA-XYLENE

20. PROPANE

21. SULPHUR

22. STYRENE

23. SULPHURIC ACID

24. TURPENTINE OIL

25. TRIMETHYLAMINE

26. TOLUNE

27. XYLENE

Chemical Information Annexure - III : 1

Prepared in the context of cooperation between the InternationalProgramme on Chemical Safety and the European Commission ©

IPCS 2005

SEE IMPORTANT INFORMATION ON THE BACK.

IPCSInternationalProgramme onChemical Safety

ACETONE 0087April 1994

CAS No: 67-64-1RTECS No: AL3150000UN No: 1090EC No: 606-001-00-8

2-PropanoneDimethyl ketoneMethyl ketoneC3H6O / CH3-CO-CH3Molecular mass: 58.1

TYPES OFHAZARD/EXPOSURE

ACUTE HAZARDS/SYMPTOMS PREVENTION FIRST AID/FIRE FIGHTING

FIRE Highly flammable. NO open flames, NO sparks, and NOsmoking.

Powder, alcohol-resistant foam,water in large amounts, carbondioxide.

EXPLOSION Vapour/air mixtures are explosive. Closed system, ventilation,explosion-proof electrical equipmentand lighting. Do NOT usecompressed air for filling,discharging, or handling.

In case of fire: keep drums, etc., coolby spraying with water.

EXPOSURE

Inhalation Sore throat. Cough. Confusion.Headache. Dizziness. Drowsiness.Unconsciousness.

Ventilation, local exhaust, or breathingprotection.

Fresh air, rest. Refer for medicalattention.

Skin Dry skin. Protective gloves. Remove contaminated clothes.Rinse skin with plenty of water orshower.

Eyes Redness. Pain. Blurred vision.Possible corneal damage.

Safety spectacles or face shield.Contact lenses should not be worn.

First rinse with plenty of water forseveral minutes (remove contactlenses if easily possible), then take toa doctor.

Ingestion Nausea. Vomiting. (Further seeInhalation). (Further see Inhalation).

Do not eat, drink, or smoke duringwork.

Rinse mouth. Refer for medicalattention.

SPILLAGE DISPOSAL PACKAGING & LABELLING

Ventilation. Collect leaking liquid in sealablecontainers. Absorb remaining liquid in sand or inertabsorbent and remove to safe place. Do NOT washaway into sewer. Then wash away with plenty ofwater. Personal protection: self-contained breathingapparatus.

F SymbolXi SymbolR: 11-36-66-67S: (2-)9-16-26UN Hazard Class: 3UN Pack Group: II

EMERGENCY RESPONSE SAFE STORAGE

Transport Emergency Card: TEC (R)-30S1090NFPA Code: H 1; F 3; R 0

Fireproof. Separated from strong oxidants.


Boiling point: 56/CMelting point: -95/CRelative density (water = 1): 0.8Solubility in water: miscibleVapour pressure, kPa at 20/C: 24Relative vapour density (air = 1): 2.0

Relative density of the vapour/air-mixture at 20/C (air = 1): 1.2Flash point: -18/C c.c.Auto-ignition temperature: 465/CExplosive limits, vol% in air: 2.2-13Octanol/water partition coefficient as log Pow: -0.24

LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information

©IPCS 2005

0087 ACETONE

IMPORTANT DATA

Physical State; AppearanceCOLOURLESS LIQUID, WITH CHARACTERISTIC ODOUR.

Physical dangersThe vapour is heavier than air and may travel along the ground;distant ignition possible.

Chemical dangersThe substance can form explosive peroxides on contact withstrong oxidants such as acetic acid, nitric acid, hydrogenperoxide. Reacts with chloroform and bromoform under basicconditions, causing fire and explosion hazard. Attacks plastic.

Occupational exposure limitsTLV: 500 ppm as TWA, 750 ppm as STEL; A4 (not classifiable asa human carcinogen); BEI issued; (ACGIH 2004).MAK: 500 ppm 1200 mg/m3 Peak limitation category: I(2);Pregnancy risk group: IIc; (DFG 2004).

Routes of exposureThe substance can be absorbed into the body by inhalation andthrough the skin.

Inhalation riskA harmful contamination of the air can be reached rather quicklyon evaporation of this substance at 20/C ; on spraying ordispersing, however, much faster.

Effects of short-term exposureThe vapour irritates the eyes and the respiratory tract. Thesubstance may cause effects on the central nervous system,liver, kidneys and gastrointestinal tract.

Effects of long-term or repeated exposureRepeated or prolonged contact with skin may cause dermatitis.The substance may have effects on the blood and bone marrow.

PHYSICAL PROPERTIES

ENVIRONMENTAL DATA

NOTES

Use of alcoholic beverages enhances the harmful effect.Card has been partly updated in October 2005. See sections Occupational Exposure Limits, EU classification.

ADDITIONAL INFORMATION



IPCS 2005



AMMONIA (ANHYDROUS) 0414March 1998

CAS No: 7664-41-7RTECS No: BO0875000UN No: 1005EC No: 007-001-00-5

(cylinder)NH3Molecular mass: 17.03



FIRE Flammable. NO open flames, NO sparks, and NOsmoking.

In case of fire in the surroundings:use appropriate extinguishing media.

EXPLOSION Gas/air mixtures are explosive. Closed system, ventilation,explosion-proof electrical equipmentand lighting.

In case of fire: keep cylinder cool byspraying with water.

EXPOSURE AVOID ALL CONTACT!

Inhalation Burning sensation. Cough.Laboured breathing. Shortness ofbreath. Sore throat. Symptoms maybe delayed (see Notes).


Fresh air, rest. Half-upright position.Artificial respiration may be needed.Refer for medical attention.

Skin Redness. Skin burns. Pain. Blisters.ON CONTACT WITH LIQUID:FROSTBITE.

Cold-insulating gloves. Protectiveclothing.

ON FROSTBITE: rinse with plenty ofwater, do NOT remove clothes.Refer for medical attention.

Eyes Redness. Pain. Severe deep burns. Face shield or eye protection incombination with breathingprotection.


Ingestion


Evacuate danger area! Consult an expert! Ventilation.NEVER direct water jet on liquid. Remove gas withfine water spray. Personal protection: gas-tightchemical protection suit including self-containedbreathing apparatus.

T SymbolN SymbolR: 10-23-34-50S: (1/2-)9-16-26-36/37/39-45-61UN Hazard Class: 2.3UN Subsidiary Risks: 8


Transport Emergency Card: TEC (R)-20S1005 or20G2TCNFPA Code: H3; F1; R0

Fireproof. Separated from oxidants, acids, halogens. Cool. Keep in awell-ventilated room.


Boiling point: -33/CMelting point: -78/CRelative density (water = 1): 0.7 at -33/CSolubility in water, g/100 ml at 20/C: 54

Vapour pressure, kPa at 26/C: 1013Relative vapour density (air = 1): 0.59Auto-ignition temperature: 651/CExplosive limits, vol% in air: 15-28


©IPCS 2005

0414 AMMONIA (ANHYDROUS)

IMPORTANT DATA

Physical State; AppearanceCOLOURLESS COMPRESSED LIQUEFIED GAS, WITHPUNGENT ODOUR.

Physical dangersThe gas is lighter than air.

Chemical dangersShock-sensitive compounds are formed with mercury, silver andgold oxides. The substance is a strong base, it reacts violentlywith acid and is corrosive. Reacts violently with strong oxidantsand halogens. Attacks copper, aluminum, zinc and their alloys.Dissolves in water evolving heat.

Occupational exposure limitsTLV: 25 ppm as TWA; 35 ppm as STEL; (ACGIH 2004).MAK: 20 ppm, 14 mg/m3; Peak limitation category: I(2); Pregnancyrisk group: C; (DFG 2004).

Routes of exposureThe substance can be absorbed into the body by inhalation.

Inhalation riskA harmful concentration of this gas in the air will be reached veryquickly on loss of containment.

Effects of short-term exposureThe substance is corrosive to the eyes, the skin and therespiratory tract. Inhalation of high concentrations may cause lungoedema (see Notes). Rapid evaporation of the liquid may causefrostbite.

PHYSICAL PROPERTIES

ENVIRONMENTAL DATA

The substance is very toxic to aquatic organisms.

NOTES

The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort.Rest and medical observation is therefore essential.Immediate administration of an appropriate inhalation therapy by a doctor or a person authorized by him/her, should be considered.Turn leaking cylinder with the leak up to prevent escape of gas in liquid state.Card has been partly updated in October 2005. See sections Occupational Exposure Limits, Emergency Response.




IPCS 2005



ASPHALT 0612October 2004

CAS No: 8052-42-4RTECS No: CI9900000UN No: 1999

BitumenPetroleum bitumen



FIRE Combustible. Dry powder, carbon dioxide, foam.NO water.

EXPLOSION


Inhalation Cough. Shortness of breath. Ventilation. Local exhaust orbreathing protection.

Fresh air, rest.

Skin On contact with heated materialserious skin burns.

Heat-insulating gloves. Protectiveclothing.

Rinse with plenty of water, do NOTremove clothes. Refer for medicalattention.

Eyes Redness. Pain. Safety goggles. First rinse with plenty of water forseveral minutes (remove contactlenses if easily possible), then take toa doctor.

Ingestion Do not eat, drink, or smoke duringwork. Wash hands before eating.


Let solidify. Sweep spilled substance into containers. UN Hazard Class: 3UN Pack Group: III


Transport Emergency Card: TEC (R)-30GF1-III (onlyfor the hot product)


Boiling point: above 300/CMelting point: 54-173/CRelative density (water = 1): 1.0-1.18

Solubility in water: noneFlash point: above 200/C c.cAuto-ignition temperature: above 400/C


©IPCS 2005

0612 ASPHALT

IMPORTANT DATA

Physical State; AppearanceDARK BROWN OR BLACK SOLID.

Occupational exposure limitsTLV: asphalt (bitumen) fume as benzene-soluble aerosol, 0.5mg/m3 as TWA; A4 (not classifiable as a human carcinogen);(ACGIH 2004).MAK: (vapour and aerosol) skin absorption (H); Carcinogencategory: 2; (DFG 2004).

Routes of exposureThe substance can be absorbed into the body by inhalation offumes.

Inhalation riskEvaporation at 20/C is negligible; a harmful concentration ofairborne particles can, however, be reached quickly whendispersed or when heated.

Effects of short-term exposureThe substance is irritating to the eyes and the respiratory tract.The substance when heated causes burns on the skin.

Effects of long-term or repeated exposureFumes of this substance are possibly carcinogenic to humans.

PHYSICAL PROPERTIES

ENVIRONMENTAL DATA

NOTES

Do NOT take working clothes home.Card has been partly updated in October 2005. See section Occupational Exposure Limits.




IPCS 2004SEE IMPORTANT INFORMATION ON THE BACK.


BENZENE 0015May 2003

CAS No: 71-43-2RTECS No: CY1400000UN No: 1114EC No: 601-020-00-8

CyclohexatrieneBenzolC6H6Molecular mass: 78.1



FIRE Highly flammable. NO open flames, NO sparks, andNO smoking.

Powder, AFFF, foam, carbondioxide.

EXPLOSION Vapour/air mixtures are explosive.Risk of fire and explosion: seeChemical Dangers.

Closed system, ventilation,explosion-proof electrical equipmentand lighting. Do NOT usecompressed air for filling,discharging, or handling. Usenon-sparking handtools. Preventbuild-up of electrostatic charges(e.g., by grounding).

In case of fire: keep drums, etc.,cool by spraying with water.


Inhalation Dizziness. Drowsiness. Headache.Nausea. Shortness of breath.Convulsions. Unconsciousness.

Ventilation, local exhaust, orbreathing protection.


Skin MAY BE ABSORBED! Dry skin.Redness. Pain. (Further seeInhalation).

Protective gloves. Protectiveclothing.

Remove contaminated clothes.Rinse skin with plenty of water orshower. Refer for medical attention.

Eyes Redness. Pain. Face shield, or eye protection incombination with breathingprotection.

First rinse with plenty of water forseveral minutes (remove contactlenses if easily possible), then taketo a doctor.

Ingestion Abdominal pain. Sore throat.Vomiting. (Further see Inhalation).


Rinse mouth. Do NOT inducevomiting. Refer for medicalattention.


Remove all ignition sources. Collect leaking andspilled liquid in sealable containers as far aspossible. Absorb remaining liquid in sand or inertabsorbent and remove to safe place. Do NOT washaway into sewer. Do NOT let this chemical enter theenvironment. Personal protection: completeprotective clothing including self-contained breathingapparatus.

F SymbolT SymbolR: 45-46-11-36/38-48/23/24/25-65S: 53-45Note: EUN Hazard Class: 3UN Pack Group: II

Do not transport with food andfeedstuffs.


Transport Emergency Card: TEC (R)-30S1114 /30GF1-IINFPA Code: H2; F3; R0

Fireproof. Separated from food and feedstuffs oxidants and halogens.


Boiling point: 80/CMelting point: 6/CRelative density (water = 1): 0.88Solubility in water, g/100 ml at 25/C: 0.18Vapour pressure, kPa at 20/C: 10Relative vapour density (air = 1): 2.7

Relative density of the vapour/air-mixture at 20/C (air = 1): 1.2Flash point: -11/C c.c.Auto-ignition temperature: 498/CExplosive limits, vol% in air: 1.2-8.0Octanol/water partition coefficient as log Pow: 2.13

LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible

©IPCS 2004

0015 BENZENE

IMPORTANT DATAPhysical State; AppearanceCOLOURLESS LIQUID, WITH CHARACTERISTIC ODOUR.

Physical dangersThe vapour is heavier than air and may travel along the ground;distant ignition possible. As a result of flow, agitation, etc.,electrostatic charges can be generated.

Chemical dangersReacts violently with oxidants, nitric acid, sulfuric acid andhalogens causing fire and explosion hazard. Attacks plastic andrubber.

Occupational exposure limitsTLV: 0.5 ppm as TWA; 2.5 ppm as STEL; (skin); A1; BEI issued;(ACGIH 2004).MAK: H; Carcinogen category: 1; Germ cell mutagen group: 3A;(DFG 2004).

Routes of exposureThe substance can be absorbed into the body by inhalation,through the skin and by ingestion.

Inhalation riskA harmful contamination of the air can be reached very quicklyon evaporation of this substance at 20/C.

Effects of short-term exposureThe substance is irritating to the eyes, the skin and therespiratory tract. Swallowing the liquid may cause aspiration intothe lungs with the risk of chemical pneumonitis. The substancemay cause effects on the central nervous system, resulting inlowering of consciousness. Exposure far above the occupationalexposure limit value may result in unconsciousness and death.

Effects of long-term or repeated exposureThe liquid defats the skin. The substance may have effects onthe bone marrow and immune system, resulting in a decrease ofblood cells. This substance is carcinogenic to humans.

PHYSICAL PROPERTIES

ENVIRONMENTAL DATAThe substance is very toxic to aquatic organisms.

NOTESUse of alcoholic beverages enhances the harmful effect.Depending on the degree of exposure, periodic medical examination is indicated.The odour warning when the exposure limit value is exceeded is insufficient.Card has been partly updated in October 2004. See sections Occupational Exposure Limits, EU classification, EmergencyResponse.






1,3-BUTADIENE 0017April 2000

CAS No: 106-99-0RTECS No: EI9275000UN No: 1010 (stabilized)EC No: 601-013-00-X

DivinylVinylethyleneC4H6 / CH2=(CH)2=CH2Molecular mass: 54.1



FIRE Extremely flammable. NO open flames, NO sparks, andNO smoking.

Shut off supply; if not possible andno risk to surroundings, let the fireburn itself out; in other casesextinguish with water spray, powder,carbon dioxide.

EXPLOSION Gas/air mixtures are explosive. Closed system, ventilation,explosion-proof electrical equipmentand lighting. Prevent build-up ofelectrostatic charges (e.g., bygrounding) if in liquid state.

In case of fire: keep cylinder cool byspraying with water.

EXPOSURE AVOID ALL CONTACT! AVOIDEXPOSURE OF (PREGNANT)WOMEN!

Inhalation Cough. Sore throat. Dizziness.Headache. Drowsiness. Blurredvision. Nausea. Unconsciousness.



Skin ON CONTACT WITH LIQUID:FROSTBITE.

Cold-insulating gloves. ON FROSTBITE: rinse with plentyof water, do NOT remove clothes.Refer for medical attention.

Eyes Redness. Pain. Blurred vision. SeeSkin.

Safety goggles. First rinse with plenty of water forseveral minutes (remove contactlenses if easily possible), then taketo a doctor.

Ingestion Do not eat, drink, or smoke duringwork.


Evacuate danger area! Consult an expert!Ventilation. NEVER direct water jet on liquid.Remove all ignition sources. Chemical protectionsuit including self-contained breathing apparatus.

F+ SymbolT SymbolR: 45-46-12S: 53-45Note: DUN Hazard Class: 2.1



Transport Emergency Card: TEC (R)-20S1010NFPA Code: H2; F4; R2

Fireproof. Cool. Separated from food and feedstuffs.


Boiling point: -4/CMelting point: -109/CRelative density (water = 1): 0.6Solubility in water: none (0.1 g/100 ml)Vapour pressure, kPa at 20/C: 245

Relative vapour density (air = 1): 1.9Flash point: -76/CAuto-ignition temperature: 414/CExplosive limits, vol% in air: 1.1-16.3Octanol/water partition coefficient as log Pow: 1.99


©IPCS 2005

0017 1,3-BUTADIENE

IMPORTANT DATAPhysical State; AppearanceCOLOURLESS COMPRESSED LIQUEFIED GAS, WITHCHARACTERISTIC ODOUR.

Physical dangersThe gas is heavier than air and may travel along the ground;distant ignition possible. As a result of flow, agitation, etc.,electrostatic charges can be generated. The vapours areuninhibited and may form polymers in vents or flame arresters ofstorage tanks, resulting in blockage of vents.

Chemical dangersThe substance can under specific circumstances (exposure toair) form peroxides, initiating explosive polymerization. Thesubstance may polymerize due to warming with fire or explosionhazard. Shock-sensitive compounds are formed with copper andits alloys (see Notes). The substance decomposes explosivelyon rapid heating under pressure. Reacts vigorously with oxidantsand many other substances, causing fire and explosion hazard.

Occupational exposure limitsTLV: 2 ppm as TWA; A2 (suspected human carcinogen);(ACGIH 2004).MAK: Carcinogen category: 1; Germ cell mutagen group: 2;(DFG 2004).


Inhalation riskA harmful concentration of this gas in the air will be reachedvery quickly on loss of containment.

Effects of short-term exposureThe substance irritates the eyes and the respiratory tract. Rapidevaporation of the liquid may cause frostbite. The substancemay cause effects on the central nervous system, resulting inlowering of consciousness.

Effects of long-term or repeated exposureThe substance may have effects on the bone marrow, resultingin leukemia. This substance is probably carcinogenic tohumans. May cause heritable genetic damage in humans.Animal tests show that this substance possibly causes toxiceffects upon human reproduction.

PHYSICAL PROPERTIES

ENVIRONMENTAL DATA

NOTESPiping material for this gas must not contain over 63% of copper.Use of alcoholic beverages enhances the harmful effect.The odour warning when the exposure limit value is exceeded is insufficient.Card has been partly updated in October 2004 and April 2005. See sections Occupational Exposure Limits, EU classification,Emergency Response.






CHLORINE 0126April 2000

CAS No: 7782-50-5RTECS No: FO2100000UN No: 1017EC No: 017-001-00-7

(cylinder)Cl2Molecular mass: 70.9



FIRE Not combustible but enhancescombustion of other substances.Many reactions may cause fire orexplosion.

NO contact with combustibles,acetylene, ethylene, hydrogen,ammonia and finely divided metals.

In case of fire in the surroundings:use appropriate extinguishingmedia.

EXPLOSION Risk of fire and explosion oncontact with combustiblesubstances, ammonia and finelydivided metals.

In case of fire: keep cylinder cool byspraying with water but NO directcontact with water.

EXPOSURE AVOID ALL CONTACT! IN ALL CASES CONSULT ADOCTOR!

Inhalation Corrosive. Burning sensation.Shortness of breath. Cough.Headache. Nausea. Dizziness.Laboured breathing. Sore throat.Symptoms may be delayed (seeNotes).

Breathing protection. Closed systemand ventilation.


Skin ON CONTACT WITH LIQUID:FROSTBITE. Corrosive. Skinburns. Pain.


First rinse with plenty of water, thenremove contaminated clothes andrinse again. Refer for medicalattention.

Eyes Corrosive. Pain. Blurred vision.Severe deep burns.

Safety goggles or eye protection incombination with breathingprotection.


Ingestion


Evacuate danger area! Consult an expert!Ventilation. NEVER direct water jet on liquid.Remove gas with fine water spray. Personalprotection: complete protective clothing includingself-contained breathing apparatus. Do NOT let thischemical enter the environment.

T SymbolN SymbolR: 23-36/37/38-50S: (1/2-)9-45-61UN Hazard Class: 2.3UN Subsidiary Risks: 8

Special insulated cylinder. Marinepollutant.


Transport Emergency Card: TEC (R)-20S1017NFPA Code: H 4; F 0; R 0; OX

Separated from strong bases, combustible and reducing substances. Cool.Dry. Keep in a well-ventilated room.


Boiling point: -34/CMelting point: -101/CRelative density (water = 1): 1.4 at 20/C, 6.86 atm (liquid)

Solubility in water, g/100 ml at 20/C: 0.7Vapour pressure, kPa at 20/C: 673Relative vapour density (air = 1): 2.5


©IPCS 2005

0126 CHLORINE

IMPORTANT DATAPhysical State; AppearanceGREENISH-YELLOW GAS, WITH PUNGENT ODOUR.

Physical dangersThe gas is heavier than air.

Chemical dangersThe solution in water is a strong acid, it reacts violently withbases and is corrosive. Reacts violently with many organiccompounds, ammonia, hydrogen and finely divided metalscausing fire and explosion hazard. Attacks many metals inpresence of water. Attacks plastic, rubber and coatings.

Occupational exposure limitsTLV: 0.5 ppm as TWA; 1 ppm as STEL; A4 (not classifiable as ahuman carcinogen); (ACGIH 2004).MAK: 0.5 ppm, 1.5 mg/m3; Peak limitation category: I(1);Pregnancy risk group: C; (DFG 2004).


Inhalation riskA harmful concentration of this gas in the air will be reachedvery quickly on loss of containment.

Effects of short-term exposureTear drawing. The substance is corrosive to the eyes, the skinand the respiratory tract. Inhalation of gas may causepneumonitis and lung oedema, resulting in reactive airwaysdysfunction syndrome (RADS) (see Notes). Rapid evaporationof the liquid may cause frostbite. Exposure far above the OELmay result in death. The effects may be delayed. Medicalobservation is indicated.

Effects of long-term or repeated exposureThe substance may have effects on the lungs, resulting inchronic bronchitis. The substance may have effects on theteeth, resulting in erosion.

PHYSICAL PROPERTIES

ENVIRONMENTAL DATAThe substance is very toxic to aquatic organisms.

NOTESThe symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physicaleffort. Rest and medical observation are therefore essential.Immediate administration of an appropriate inhalation therapy by a doctor or a person authorized by him/her, should be considered.The odour warning when the exposure limit value is exceeded is insufficient.Do NOT use in the vicinity of a fire or a hot surface, or during welding.Do NOT spray water on leaking cylinder (to prevent corrosion of cylinder).Turn leaking cylinder with the leak up to prevent escape of gas in liquid state.Card has been partly updated in April 2005. See sections Occupational Exposure Limits, EU classification, Emergency Response.






DIESEL FUEL No. 2 1561October 2004

CAS No: 68476-34-6RTECS No: LS9142500UN No: 1202EC No: 649-227-00-2

Fuels, Diesel, No. 2Diesel oil No. 2Gasoil - unspecified



FIRE Flammable. Gives off irritating ortoxic fumes (or gases) in a fire.

NO open flames. Water spray, alcohol-resistant foam,dry powder, carbon dioxide.

EXPLOSION Above 52/C explosive vapour/airmixtures may be formed.

Above 52/C use a closed system,ventilation, and explosion-proofelectrical equipment.


EXPOSURE

Inhalation Dizziness. Headache. Nausea. Ventilation, local exhaust, orbreathing protection.


Skin Dry skin. Redness. Protective gloves. Rinse and then wash skin with waterand soap.

Eyes Redness. Pain. Safety goggles, or eye protection incombination with breathingprotection.


Ingestion (See Inhalation). Do not eat, drink, or smoke duringwork.



Collect leaking and spilled liquid in sealablecontainers as far as possible. Absorb remainingliquid in sand or inert absorbent and remove to safeplace. Personal protection: filter respirator fororganic gases and vapours.

Xn SymbolR: 40S: (2-)36/37Note: HUN Hazard Class: 3UN Pack Group: III



Well closed.


Boiling point: 282-338/CMelting point: -30 - -18/CDensity: 0.87 - 0.95 g/cm3

Solubility in water, g/100 ml at 20/C: 0.0005

Flash point: 52/C c.c.Auto-ignition temperature: 254-285/CExplosive limits, vol% in air: 0.6 - 6.5Octanol/water partition coefficient as log Pow: > 3.3


©IPCS 2004

1561 DIESEL FUEL No. 2

IMPORTANT DATAPhysical State; AppearanceBROWN SLIGHTLY VISCOUS LIQUID, WITHCHARACTERISTIC ODOUR.

Occupational exposure limitsTLV: 100 ppm as TWA; (skin); A3; (ACGIH 2004).

Routes of exposureThe substance can be absorbed into the body by inhalation ofits aerosol.

Inhalation riskA harmful contamination of the air will not or will only very slowlybe reached on evaporation of this substance at 20/C.

Effects of short-term exposureThe substance is irritating to the eyes, the skin and therespiratory tract. The substance may cause effects on thecentral nervous system. If this liquid is swallowed, aspiration intothe lungs may result in chemical pneumonitis.

Effects of long-term or repeated exposureThe liquid defats the skin.

PHYSICAL PROPERTIES

ENVIRONMENTAL DATAThe substance is harmful to aquatic organisms.

NOTESAdditives to Diesel fuel in winter may change physical and toxicological properties of the substance. This card does not addressDiesel exhaust.



Prepared in the context of cooperation between the InternationalProgramme on Chemical Safety and the European Commission

© IPCS 2002



DIMETHYLAMINE 0260May 2003

CAS No: 124-40-3RTECS No: IP8750000UN No: 1032EC No: 612-001-00-9

Methanamine, N-methylDMA(cylinder)(CH3)2NH / C2H7NMolecular mass: 45.1



FIRE Extremely flammable. Gives offirritating or toxic fumes (or gases)in a fire.

NO open flames, NO sparks, andNO smoking.

Shut off supply; if not possible andno risk to surroundings, let the fireburn itself out; in other casesextinguish with water spray,alcohol-resistant foam, dry powder,carbon dioxide.

EXPLOSION Gas/air mixtures are explosive. Closed system, ventilation,explosion-proof electrical equipmentand lighting. Use non-sparkinghandtools.

In case of fire: keep cylinder cool byspraying with water. Combat firefrom a sheltered position.

EXPOSURE STRICT HYGIENE!

Inhalation Burning sensation. Cough.Headache. Laboured breathing.Shortness of breath. Sore throat.Symptoms may be delayed (seeNotes).





ON FROSTBITE: rinse with plentyof water, do NOT remove clothes.Refer for medical attention.

Eyes Redness. Pain. Blurred vision. Safety goggles, or eye protection incombination with breathingprotection.




Evacuate danger area! Consult an expert!Ventilation. Remove all ignition sources. NEVERdirect water jet on liquid. Remove gas with finewater spray. Do NOT let this chemical enter theenvironment. (Extra personal protection: completeprotective clothing including self-containedbreathing apparatus.)

F+ SymbolXn SymbolR: 12-20-37/38-41S: (2-)16-26-39UN Hazard Class: 2.1

EMERGENCY RESPONSE STORAGE


Fireproof. Cool.


Boiling point: 7.0°CMelting point: -92.2°CRelative density (water = 1): 0.7Solubility in water: 354 g/100mlVapour pressure, kPa at 25°C: 203

Relative vapour density (air = 1): 1.6Flash point: Flammable GasAuto-ignition temperature: 400°CExplosive limits, vol% in air: 2.8-14.4Octanol/water partition coefficient as log Pow: -0.2


©IPCS 2002

0260 DIMETHYLAMINE

IMPORTANT DATA

Physical State; AppearanceCOLOURLESS COMPRESSED LIQUEFIED GAS, WITHPUNGENT ODOUR.

Physical dangersThe gas is heavier than air and may travel along the ground;distant ignition possible.

Chemical dangersThe substance decomposes on burning producing toxic fumesincluding nitrogen oxides. Reacts violently with strong oxidantsand mercury causing fire and explosion hazard. Attacks copper,zinc alloys, aluminium, galvanized surfaces, and plastic. Thesolution in water is a strong base, it reacts violently with acidand is corrosive, see ICSC 1485 Dimethylamine, aqueoussolution.

Occupational exposure limitsTLV: 5 ppm as TWA; 15 ppm as STEL; A4; (ACGIH 2003).EU OEL: 2 ppm, 3.8 mg/m3 as TWA; 5 ppm, 9.4 mg/m3 asSTEL; (EU 1998).


Inhalation riskOn loss of containment, a harmful concentration of this gas inthe air will be reached very quickly especially in confinedspaces.

Effects of short-term exposureThe substance is severely irritating to the eyes and therespiratory tract. Inhalation of the substance at high levels maycause lung oedema (see Notes). The effects may be delayed.Medical observation is indicated. Rapid evaporation of the liquidmay cause frostbite.

PHYSICAL PROPERTIES

ENVIRONMENTAL DATA

The substance is harmful to aquatic organisms.

NOTES

Turn leaking cylinder with the leak up to prevent escape of gas in liquid state.The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physicaleffort. Rest and medical observation is therefore essential.Immediate administration of an appropriate inhalation therapy by a doctor or a person authorized by him/her, should be considered.Do NOT spray water on leaking cylinder (to prevent corrosion of cylinder).See ICSC 1485 Dimethylamine, aqueous solution.






GASOLINE 1400October 2001

CAS No: 86290-81-5RTECS No: DE3550000UN No: 1203EC No: 649-378-00-4

Benzin





EXPLOSION Vapour/air mixtures are explosive. Closed system, ventilation,explosion-proof electrical equipmentand lighting. Prevent build-up ofelectrostatic charges (e.g., bygrounding).


EXPOSURE

Inhalation Confusion. Cough. Dizziness.Drowsiness. Dullness. Headache.



Skin MAY BE ABSORBED! Dry skin.Redness.


Remove contaminated clothes.Rinse and then wash skin with waterand soap.

Eyes Redness. Pain. Safety spectacles or eye protectionin combination with breathingprotection.


Ingestion Nausea. Vomiting. (SeeInhalation).


Rinse mouth. Do NOT inducevomiting. Give plenty of water todrink. Refer for medical attention.


Evacuate danger area! Consult an expert! Removeall ignition sources. Cover the spilled material withdry earth, sand or non-combustible material. DoNOT wash away into sewer. Do NOT let thischemical enter the environment. Personal protection:self-contained breathing apparatus.

T SymbolR: 45-65S: 53-45Note: H, PUN Hazard Class: 3UN Pack Group: I

Marine pollutant.


NFPA Code: H1; F3; R0;Transport Emergency Card: TEC (R)-30S1203

Fireproof.


Boiling point: 20-200/CRelative density (water = 1): 0.70 - 0.80Solubility in water, g/100 ml: noneRelative vapour density (air = 1): 3 - 4

Flash point: <-21/CAuto-ignition temperature: about 250/CExplosive limits, vol% in air: 1.3-7.1Octanol/water partition coefficient as log Pow: 2-7


©IPCS 2005

1400 GASOLINE

IMPORTANT DATAPhysical State; AppearanceMOBILE LIQUID

Physical dangersThe vapour is heavier than air and may travel along the ground;distant ignition possible. The vapour mixes well with air,explosive mixtures are easily formed. As a result of flow,agitation, etc., electrostatic charges can be generated.

Occupational exposure limitsTLV: 300 ppm as TWA, 500 ppm as STEL; A3 (confirmedanimal carcinogen with unknown relevance to humans); (ACGIH2004).

Routes of exposureThe substance can be absorbed into the body by inhalation ofits vapour, through the skin and by ingestion.


Effects of short-term exposureThe substance is irritating to the eyes, the skin and therespiratory tract. If this liquid is swallowed, aspiration into thelungs may result in chemical pneumonitis. The substance maycause effects on the central nervous system.

Effects of long-term or repeated exposureThe liquid defats the skin. The substance may have effects onthe central nervous system and liver. This substance is possiblycarcinogenic to humans.

PHYSICAL PROPERTIES

ENVIRONMENTAL DATAThe substance is harmful to aquatic organisms.

NOTESDepending on the degree of exposure, periodic medical examination is suggested.The product may contain additives which may alter the health and environmental effects. Card has been partly updated in April 2005.See section Physical properties.




IPCS 2005



n-HEXANE 0279April 2000

CAS No: 110-54-3RTECS No: MN9275000UN No: 1208EC No: 601-037-00-0

Hexyl hydrideC6H14Molecular mass: 86.2




Powder, AFFF, foam, carbon dioxide.

EXPLOSION Vapour/air mixtures are explosive. Closed system, ventilation,explosion-proof electrical equipmentand lighting. Do NOT usecompressed air for filling,discharging, or handling. Usenon-sparking handtools.


EXPOSURE

Inhalation Dizziness. Drowsiness. Dullness.Headache. Nausea. Weakness.Unconsciousness.



Skin Dry skin. Redness. Pain. Protective gloves. Remove contaminated clothes.Rinse and then wash skin with waterand soap. Refer for medicalattention.

Eyes Redness. Pain. Safety goggles, face shield or eyeprotection in combination withbreathing protection.


Ingestion Abdominal pain. (Further seeInhalation).


Rinse mouth. Do NOT inducevomiting. Rest. Refer for medicalattention.


Consult an expert! Remove all ignition sources.Collect leaking and spilled liquid in sealable containersas far as possible. Absorb remaining liquid in sand orinert absorbent and remove to safe place. Do NOTwash away into sewer. Do NOT let this chemicalenter the environment. Personal protection: filterrespirator for organic gases and vapours.

F SymbolXn SymbolN SymbolR: 11-38-48/20-62-65-67-51/53S: (2-)9-16-29-33-36/37-61-62UN Hazard Class: 3UN Pack Group: II



Fireproof. Separated from strong oxidants. Well closed.


Boiling point: 69/CMelting point: -95/CRelative density (water = 1): 0.7Solubility in water, g/100 ml at 20/C: 0.0013Vapour pressure, kPa at 20/C: 17Relative vapour density (air = 1): 3.0

Relative density of the vapour/air-mixture at 20/C (air = 1): 1.3Flash point: -22/C c.c.Auto-ignition temperature: 225/CExplosive limits, vol% in air: 1.1-7.5Octanol/water partition coefficient as log Pow: 3.9


©IPCS 2005

0279 n-HEXANE

IMPORTANT DATA

Physical State; AppearanceVOLATILE COLOURLESS LIQUID, WITH CHARACTERISTICODOUR.


Chemical dangersReacts with strong oxidants causing fire and explosion hazard.Attacks some plastics, rubber and coatings.

Occupational exposure limitsTLV: 50 ppm, 176 mg/m3 as TWA; (skin); BEI issued; (ACGIH2004).MAK: 50 ppm, 180 mg/m3; Peak limitation category: II(8);Pregnancy risk group: C; (DFG 2004).

Routes of exposureThe substance can be absorbed into the body by inhalation of itsvapour and by ingestion.

Inhalation riskA harmful contamination of the air can be reached rather quicklyon evaporation of this substance at 20/C.

Effects of short-term exposureThe substance irritates the skin. Swallowing the liquid may causeaspiration into the lungs with the risk of chemical pneumonitis.Exposure at high levels could cause lowering of consciousness.

Effects of long-term or repeated exposureRepeated or prolonged contact with skin may cause dermatitis.The substance may have effects on the central nervous systemand especially peripheral nervous system, resulting inpolyneuropathy. Animal tests show that this substance possiblycauses toxic effects upon human reproduction.

PHYSICAL PROPERTIES

ENVIRONMENTAL DATA

The substance is toxic to aquatic organisms.

NOTES

Depending on the degree of exposure, periodic medical examination is suggested.Card has been partly updated in October 2004. See sections Occupational Exposure Limits, EU classification, Emergency Response.




© IPCS 2002



HYDROGEN 0001March 2002

CAS No: 1333-74-0RTECS No: MW8900000UN No: 1049EC No: 001-001-00-9

H2

Molecular mass: 2.0



FIRE Extremely flammable. Manyreactions may cause fire orexplosion.


Shut off supply; if not possible andno risk to surroundings, let the fireburn itself out; in other casesextinguish with water spray, powder,carbon dioxide.

EXPLOSION Gas/air mixtures are explosive. Closed system, ventilation,explosion-proof electrical equipmentand lighting. Use non-sparkinghandtools. Do not handle cylinderswith oily hands.


EXPOSURE

Inhalation Suffocation. Closed system and ventilation. Fresh air, rest. Artificial respirationmay be needed. Refer for medicalattention.

Skin Serious frostbite. Cold-insulating gloves. Refer for medical attention.

Eyes Safety spectacles.

Ingestion


Remove all ignition sources. Evacuate danger area!Consult an expert! Ventilation. Remove vapour withfine water spray.

F+ SymbolR: 12S: (2-)9-16-33UN Hazard Class: 2.1



Fireproof. Cool.


Boiling point: -253°CRelative vapour density (air = 1): 0.07Flash point: flammable gas

Auto-ignition temperature: 500-571°CExplosive limits, vol% in air: 4-76


©IPCS 2002

0001 HYDROGEN

IMPORTANT DATA

Physical State; AppearanceODOURLESS, COLOURLESS COMPRESSED GAS

Physical dangersThe gas mixes well with air, explosive mixtures are easilyformed. The gas is lighter than air.

Chemical dangersHeating may cause violent combustion or explosion. Reactsviolently with air, oxygen, halogens and strong oxidants causingfire and explosion hazard. Metal catalysts, such as platinum andnickel, greatly enhance these reactions.

Occupational exposure limitsTLV: Simple asphyxiant (ACGIH 2002).


Inhalation riskOn loss of containment, a harmful concentration of this gas inthe air will be reached very quickly.

Effects of short-term exposureSimple asphyxiant. See Notes.

PHYSICAL PROPERTIES

ENVIRONMENTAL DATA

NOTES

High concentrations in the air cause a deficiency of oxygen with the risk of unconsciousness or death.Check oxygen content before entering area.No odour warning if toxic concentrations are present.Measure hydrogen concentrations with suitable gas detector (a normal flammable gas detector is not suited for the purpose).




IPCS 2005



ISOPROPYL ALCOHOL 0554March 1999

CAS No: 67-63-0RTECS No: NT8050000UN No: 1219EC No: 603-117-00-0

2-PropanolPropan-2-olIsopropanolDimethylcarbinolC3H8O / CH3CHOHCH3Molecular mass: 60.1





EXPLOSION Vapour/air mixtures are explosive. Closed system, ventilation,explosion-proof electrical equipmentand lighting.


EXPOSURE

Inhalation Cough. Dizziness. Drowsiness.Headache. Sore throat. (SeeIngestion).



Skin Dry skin. Protective gloves. Remove contaminated clothes.Rinse and then wash skin with waterand soap.

Eyes Redness. Safety spectacles or eye protection incombination with breathingprotection.


Ingestion Abdominal pain. Labouredbreathing. Nausea.Unconsciousness. Vomiting.(Further see Inhalation).


Rinse mouth. Do NOT inducevomiting. Rest. Refer for medicalattention.


Personal protection: filter respirator for organic gasesand vapours. Collect leaking liquid in sealablecontainers. Absorb remaining liquid in sand or inertabsorbent and remove to safe place.

F SymbolXi SymbolR: 11-36-67S: (2-)7-16-24/25-26Note: 6UN Hazard Class: 3UN Pack Group: II



Fireproof. Separated from strong oxidants. Cool. Well closed.


Boiling point: 83/CMelting point: -90/CRelative density (water = 1): 0.79Solubility in water: miscibleVapour pressure, kPa at 20/C: 4.4Relative vapour density (air = 1): 2.1

Relative density of the vapour/air-mixture at 20/C (air = 1): 1.05Flash point: 11.7/C c.c.Auto-ignition temperature: 456/CExplosive limits, vol% in air: 2-12Octanol/water partition coefficient as log Pow: 0.05


©IPCS 2005

0554 ISOPROPYL ALCOHOL

IMPORTANT DATA

Physical State; AppearanceCOLOURLESS LIQUID

Physical dangersThe vapour mixes well with air, explosive mixtures are easilyformed.

Chemical dangersReacts with strong oxidants. Attacks some plastic, rubber.

Occupational exposure limitsTLV: 200 ppm as TWA; 400 ppm as STEL; A4 (not classifiable asa human carcinogen); (ACGIH 2004).MAK: 200 ppm, 500 mg/m3; Peak limitation category: II(2);Pregnancy risk group: C; (DFG 2004).

Routes of exposureThe substance can be absorbed into the body by inhalation of itsvapour.

Inhalation riskA harmful contamination of the air will be reached rather slowly onevaporation of this substance at 20/C; on spraying or dispersing,however, much faster.

Effects of short-term exposureThe substance is irritating to the eyes and the respiratory tract.The substance may cause effects on the central nervous system,resulting in depression. Exposure far above the OEL may result inunconsciousness.

Effects of long-term or repeated exposureThe liquid defats the skin.

PHYSICAL PROPERTIES

ENVIRONMENTAL DATA

NOTES

Use of alcoholic beverages enhances the harmful effect.Card has been partly updated in October 2004 and 2005. See sections Occupational Exposure Limits, EU classification, EmergencyResponse.




© IPCS 1999



KEROSENE 0663November 1998

CAS No: 8008-20-6RTECS No: OA5500000UN No: 1223EC No: 649-404-00-4

KerosineLight petroleumLamp oilFuel oil no�1



FIRE Flammable. NO open flames, NO sparks, andNO smoking.


EXPLOSION Above 37�C explosive vapour/airmixtures may be formed.

Above 37�C use a closed system,ventilation, and explosion-proofelectrical equipment. Preventbuild-up of electrostatic charges(e.g., by grounding).


EXPOSURE PREVENT GENERATION OFMISTS!

Inhalation Confusion. Cough. Dizziness.Headache. Sore throat.Unconsciousness.

Ventilation. Fresh air, rest. Artificial respirationif indicated. Refer for medicalattention.

Skin Dry skin. Roughness. Protective gloves. Remove contaminated clothes.Rinse and then wash skin withwater and soap. Refer for medicalattention.

Eyes Redness. Safety spectacles. First rinse with plenty of water forseveral minutes (remove contactlenses if easily possible), then taketo a doctor.

Ingestion Diarrhoea. Nausea. Vomiting. Do not eat, drink, or smoke duringwork.

Do NOT induce vomiting. Rest.Refer for medical attention.


Collect leaking liquid in sealable containers. Absorbremaining liquid in sand or inert absorbent andremove to safe place. Do NOT let this chemicalenter the environment (extra personal protection:self-contained breathing apparatus).

Xn SymbolR: 65S: (2-)23-24-62Note: HUN Hazard Class: 3UN Pack Group: III


Transport Emergency Card: TEC (R)-551NFPA Code: H 0; F 2; R 0;

Fireproof. Separated from strong oxidants. Cool.


Boiling point: 150-300�CMelting point: -20�CRelative density (water = 1): 0.8Solubility in water: none

Relative vapour density (air = 1): 4.5Flash point: 37-65�CAuto-ignition temperature: 220�CExplosive limits, vol% in air: 0.7-5


© IPCS 1999

0663 KEROSENE

IMPORTANT DATA

Physical State; AppearanceLOW VISCOSITY LIQUID, WITH CHARACTERISTIC ODOUR.

Physical DangersAs a result of flow, agitation, etc., electrostatic charges can begenerated.

Chemical DangersReacts with oxidants.

Occupational Exposure LimitsTLV not established.

Routes of ExposureThe substance can be absorbed into the body by inhalation ofits vapour and by ingestion.

Inhalation RiskNo indication can be given about the rate in which a harmfulconcentration in the air is reached on evaporation of thissubstance at 20�C.

Effects of Short-term ExposureThe substance slightly irritates the skin and the respiratorytract. Swallowing the liquid may cause aspiration into the lungswith the risk of chemical pneumonitis. The substance maycause effects on the nervous system.

Effects of Long-term or Repeated ExposureThe liquid defats the skin.

PHYSICAL PROPERTIES

ENVIRONMENTAL DATA


NOTES

Physical properties vary, depending on the composition. Ingestion of kerosene (lamp oil) is a major cause of accidental poisoningin children.






METHANOL 0057April 2000

CAS No: 67-56-1RTECS No: PC1400000UN No: 1230EC No: 603-001-00-X

Methyl alcoholCarbinolWood alcoholCH4O / CH3OHMolecular mass: 32.0



FIRE Highly flammable. See Notes. NO open flames, NO sparks, andNO smoking. NO contact withoxidants.


EXPLOSION Vapour/air mixtures are explosive. Closed system, ventilation,explosion-proof electrical equipmentand lighting. Do NOT usecompressed air for filling,discharging, or handling. Usenon-sparking handtools.


EXPOSURE AVOID EXPOSURE OFADOLESCENTS AND CHILDREN!

Inhalation Cough. Dizziness. Headache.Nausea. Weakness. Visualdisturbance.

Ventilation. Local exhaust orbreathing protection.


Skin MAY BE ABSORBED! Dry skin.Redness.


Remove contaminated clothes.Rinse skin with plenty of water orshower. Refer for medical attention.

Eyes Redness. Pain. Safety goggles or eye protection incombination with breathingprotection.


Ingestion Abdominal pain. Shortness ofbreath. Vomiting. Convulsions.Unconsciousness. (Further seeInhalation).

Do not eat, drink, or smoke duringwork. Wash hands before eating.

Induce vomiting (ONLY INCONSCIOUS PERSONS!). Referfor medical attention.


Evacuate danger area! Ventilation. Collect leakingliquid in sealable containers. Wash away remainderwith plenty of water. Remove vapour with fine waterspray. Chemical protection suit includingself-contained breathing apparatus.

F SymbolT SymbolR: 11-23/24/25-39/23/24/25S: (1/2-)7-16-36/37-45UN Hazard Class: 3UN Subsidiary Risks: 6.1UN Pack Group: II




Fireproof. Separated from strong oxidants, food and feedstuffs. Cool.


Boiling point: 65/CMelting point: -98/CRelative density (water = 1): 0.79Solubility in water: miscibleVapour pressure, kPa at 20/C: 12.3Relative vapour density (air = 1): 1.1

Relative density of the vapour/air-mixture at 20/C (air = 1): 1.01Flash point: 12/C c.c.Auto-ignition temperature: 464/CExplosive limits, vol% in air: 5.5-44Octanol/water partition coefficient as log Pow: -0.82/-0.66


©IPCS 2005

0057 METHANOL


Physical dangersThe vapour mixes well with air, explosive mixtures are easilyformed.

Chemical dangersReacts violently with oxidants causing fire and explosion hazard.

Occupational exposure limitsTLV: 200 ppm as TWA, 250 ppm as STEL; (skin); BEI issued;(ACGIH 2004).MAK: 200 ppm, 270 mg/m3; Peak limitation category: II(4); skinabsorption (H); Pregnancy risk group: C (DFG 2004).

Routes of exposureThe substance can be absorbed into the body by inhalation andthrough the skin and by ingestion.


Effects of short-term exposureThe substance is irritating to the eyes, the skin and therespiratory tract. The substance may cause effects on thecentral nervous system, resulting in loss of consciousness.Exposure may result in blindness and death. The effects may bedelayed. Medical observation is indicated.

Effects of long-term or repeated exposureRepeated or prolonged contact with skin may cause dermatitis.The substance may have effects on the central nervous system,resulting in persistent or recurring headaches and impairedvision.

PHYSICAL PROPERTIES

ENVIRONMENTAL DATA

NOTESBurns with nonluminous bluish flame.Depending on the degree of exposure, periodic medical examination is suggested.Card has been partly updated in April 2005. See section Occupational Exposure Limits.




© IPCS 2002



METHYLAMINE 0178October 2002

CAS No: 74-89-5RTECS No: PF6300000UN No: 1061 (anhydrous)EC No: 612-001-00-9

MethanamineAminomethaneMonomethylamine(cylinder)CH5N / CH3NH2

Molecular mass: 31.1





Shut off supply; if not possible andno risk to surroundings, let the fireburn itself out; in other casesextinguish with powder, carbondioxide.




Inhalation Burning sensation. Cough.Headache. Laboured breathing.Shortness of breath. Sore throat.See Notes.






Eyes Redness. Pain. Blurred vision.Severe deep burns.

Safety goggles, or eye protection incombination with breathingprotection.




Evacuate danger area! Consult an expert!Ventilation. Remove all ignition sources. NEVERdirect water jet on liquid. Remove vapour with finewater spray. (Extra personal protection: completeprotective clothing including self-containedbreathing apparatus.)



Transport Emergency Card: TEC 20S1061NFPA Code: H3; F4; R0.

Fireproof. Cool.


Boiling point: -6°CMelting point: -93°CRelative density (water = 1): 0.7 (liquid)Solubility in water: at 25 °C very goodVapour pressure, kPa at 20°C: 304

Relative vapour density (air = 1): 1.07Flash point: Flammable GasAuto-ignition temperature: 430°CExplosive limits, vol% in air: 4.9-20.7Octanol/water partition coefficient as log Pow: -0.71


©IPCS 2002

0178 METHYLAMINE

IMPORTANT DATA

Physical State; AppearanceCOLOURLESS COMPRESSED LIQUEFIED GAS, WITHCHARACTERISTIC ODOUR.

Physical dangersThe gas mixes well with air, explosive mixtures are easilyformed.

Chemical dangersThe substance decomposes on burning producing toxic fumesincluding nitrogen oxides. The solution in water is a strong base,it reacts violently with acid and is corrosive. Reacts violentlywith strong oxidants. Attacks plastic, rubber and coatings.Attacks copper, zinc alloys, aluminium and galvanized surfaces.

Occupational exposure limitsTLV: (as TWA) 5 ppm; (as STEL) 15 ppm; (ACGIH 2002).MAK: 10 ppm, 13 mg/m3; (DFG 2002).MAK: class Peak limitation category: I (1) ceiling; Pregnancyrisk group: IIc; (2002)



Effects of short-term exposureThe substance is corrosive to the eyes and the respiratory tract.Inhalation of the substance at high levels may cause lungoedema (see Notes). The effects may be delayed. Medicalobservation is indicated. Rapid evaporation of the liquid maycause frostbite.

PHYSICAL PROPERTIES

ENVIRONMENTAL DATA

NOTES

Turn leaking cylinder with the leak up to prevent escape of gas in liquid state.The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physicaleffort. Rest and medical observation is therefore essential.Immediate administration of an appropriate inhalation therapy by a doctor or a person authorized by him/her, should be considered.




© IPCS 2000



NAPHTHA (PETROLEUM), HEAVY ALKYLATE 1382March 2001

CAS No: 64741-65-7RTECS No:UN No: 1268EC No: 649-275-00-4

Low boiling point modified naphthaAliphatic HC's, iso-paraffins




Water spray, alcohol-resistantfoam, powder, carbon dioxide.

EXPLOSION Above 44°C explosive vapour/airmixtures may be formed.

Above 44°C use a closed system,ventilation, and explosion-proofelectrical equipment.


EXPOSURE PREVENT GENERATION OFMISTS!

Inhalation Dizziness. Headache. Drowsiness.Nausea. Unconsciousness.



Skin Dry skin. Protective gloves. Remove contaminated clothes.Rinse skin with plenty of water orshower.

Eyes Redness. Safety goggles. First rinse with plenty of water forseveral minutes (remove contactlenses if easily possible), then taketo a doctor.

Ingestion Cough. Diarrhoea. Sore throat.Vomiting. (Further see Inhalation).


Do NOT induce vomiting. Refer formedical attention. See Notes.


Ventilation. Collect leaking and spilled liquid insealable containers as far as possible. Absorbremaining liquid in sand or inert absorbent andremove to safe place. Do NOT wash away intosewer. (Extra personal protection: filter respirator fororganic vapours of low boiling compounds.)

T SymbolR: 45-65S: 53-45Note: H, PUN Hazard Class: 3UN Pack Group: III


Transport Emergency Card: TEC (R)-30G35NFPA Code: H1; F3; R0

Fireproof. Separated from strong oxidants. Well closed.


Boiling point: 172-215°CMelting point: -30°CDensity: 0.75-0.79 g/cm3

Solubility in water: none

Vapour pressure, kPa at 20°C: 0.1-0.2Flash point: = 44°C c.c. Auto-ignition temperature: 355 °CExplosive limits, vol% in air: 0.6-8.0


©IPCS 2000

1382 NAPHTHA (PETROLEUM), HEAVY ALKYLATE

IMPORTANT DATA

Physical State; AppearanceCOLOURLESS LIQUID


Chemical dangersReacts with strong oxidants, causing fire and explosion hazard.

Occupational exposure limitsTLV not established. MAK not established.

Routes of exposureThe substance can be absorbed into the body by inhalation ofits vapour and by ingestion.

Inhalation riskNo indication can be given about the rate in which a harmfulconcentration in the air is reached on evaporation of thissubstance at 20°C.

Effects of short-term exposureThe vapour is slightly irritating to the eyes. The substance maycause effects on the central nervous system. Exposure to highconcentration of vapours may result in unconsciousness.Swallowing the liquid may cause aspiration into the lungs withthe risk of chemical pneumonitis.

Effects of long-term or repeated exposureThe liquid defats the skin. See Notes.

PHYSICAL PROPERTIES

ENVIRONMENTAL DATA


NOTES

This is a mixture of C9-C14 iso- and n-paraffins. Neither the concentration of aromatics nor of hexane is greater than 0.1 % byvolume. Note P: the EU classification as carcinogen (R45) does not apply if it can be shown that the benzene content is below 0.1%by volume. Depending on the raw material and the production processes, the composition and physical properties of this solventcan vary considerably. The symptoms of chemical pneumonitis do not become manifest until a few hours or even a few days havepassed. Isopar G / L / M, Shellsol T / TK / TD, Soltrol 100 / 130, among others, are trade names.






NITRIC ACID 0183April 1994

CAS No: 7697-37-2RTECS No: QU5775000UN No: 2031EC No: 007-004-00-1

Concentrated Nitric Acid (70%)HNO3Molecular mass: 63.0



FIRE Not combustible but enhancescombustion of other substances.Gives off irritating or toxic fumes(or gases) in a fire.

NO contact with flammablesubstances. NO contact withcombustibles or organic chemicals.

In case of fire in the surroundings:NO foam.

EXPLOSION Risk of fire and explosion oncontact with many common organiccompounds.



Inhalation Burning sensation. Cough.Laboured breathing.Unconsciousness. Symptoms maybe delayed (see Notes).



Skin Corrosive. Serious skin burns.Pain. Yellow discolouration.

Protective clothing. Remove contaminated clothes.Rinse skin with plenty of water orshower. Refer for medical attention.

Eyes Corrosive. Redness. Pain. Severedeep burns.

Face shield or eye protection incombination with breathingprotection.


Ingestion Corrosive. Abdominal pain.Burning sensation. Shock.


Do NOT induce vomiting. Giveplenty of water to drink. Rest. Referfor medical attention.


Evacuate danger area! Consult an expert!Ventilation. Collect leaking liquid in sealablecontainers. Cautiously neutralize remainder withsodium carbonate. Then wash away with plenty ofwater. Do NOT absorb in saw-dust or othercombustible absorbents. Personal protection:complete protective clothing including self-containedbreathing apparatus.

O SymbolC SymbolR: 8-35S: (1/2-)23-26-36-45Note: BUN Hazard Class: 8UN Pack Group: II

Unbreakable packaging; putbreakable packaging into closedunbreakable container. Do nottransport with food and feedstuffs.


Transport Emergency Card: TEC (R)-80S2031-II or80GO1-INFPA Code: H 3; F 0; R 0; OX

Separated from combustible and reducing substances, bases, food andfeedstuffs, organic chemicals. Cool. Dry. Keep in a well-ventilated room.


Boiling point: 121/CMelting point: -41.6/CRelative density (water = 1): 1.4Solubility in water: miscible

Vapour pressure, kPa at 20/C: 6.4Relative vapour density (air = 1): 2.2Relative density of the vapour/air-mixture at 20/C (air = 1): 1.07


©IPCS 2005

0183 NITRIC ACID

IMPORTANT DATAPhysical State; AppearanceCOLOURLESS TO YELLOW LIQUID, WITH PUNGENTODOUR.

Chemical dangersThe substance decomposes on warming producing nitrogenoxides. The substance is a strong oxidant and reacts violentlywith combustible and reducing materials, e.g., turpentine,charcoal, alcohol. The substance is a strong acid, it reactsviolently with bases and is corrosive to metals. Reacts veryviolently with organic chemicals (e.g., acetone, acetic acid,acetic anhydride), causing fire and explosion hazard. Attackssome plastics.

Occupational exposure limitsTLV: 2 ppm as TWA, 4 ppm as STEL; (ACGIH 2004).MAK: 2 ppm, 5.2 mg/m3; Peak limitation category: I(1);Pregnancy risk group: IIc; (DFG 2004).

Routes of exposureThe substance can be absorbed into the body by inhalation ofits vapour and by ingestion.


Effects of short-term exposureThe substance is very corrosive to the eyes, the skin and therespiratory tract. Corrosive on ingestion as well. Inhalation ofvapour may cause lung oedema (see Notes).

PHYSICAL PROPERTIES

ENVIRONMENTAL DATA

NOTESDepending on the degree of exposure, periodic medical examination is suggested.The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physicaleffort. Rest and medical observation are therefore essential.Rinse contaminated clothes (fire hazard) with plenty of water.Other UN 2031 classification with more than 70% nitric acid, hazard class 8, subsidiary hazard 5.1, packing group I.Card has been partly updated in April 2005. See sections Occupational Exposure Limits, Emergency Response, Notes.




© IPCS 2002



p-XYLENE 0086March 2002

CAS No: 106-42-3RTECS No: ZE2625000UN No: 1307EC No: 601-022-00-9

para-Xylene1,4-Dimethylbenzenep-XylolC6H4(CH3)2 / C8H10





Powder, water spray, foam, carbondioxide.


Above 27°C use a closed system,ventilation, and explosion-proofelectrical equipment. Preventbuild-up of electrostatic charges(e.g., by grounding).


EXPOSURE STRICT HYGIENE! AVOIDEXPOSURE OF (PREGNANT)WOMEN!

Inhalation Dizziness. Drowsiness. Headache.Nausea.



Skin Dry skin. Redness. Protective gloves. Remove contaminated clothes.Rinse and then wash skin withwater and soap.

Eyes Redness. Pain. Safety spectacles. First rinse with plenty of water forseveral minutes (remove contactlenses if easily possible), then taketo a doctor.

Ingestion Burning sensation. Abdominalpain. (Further see Inhalation).




Ventilation. Remove all ignition sources. Collectleaking and spilled liquid in sealable containers asfar as possible. Absorb remaining liquid in sand orinert absorbent and remove to safe place. Do NOTlet this chemical enter the environment. (Extrapersonal protection: filter respirator for organicgases and vapours.)

Xn SymbolR: 10-20/21-38S: (2-)25Note: CUN Hazard Class: 3UN Pack Group: III


Transport Emergency Card: TEC (R)-30S1307-IIINFPA Code: H 2; F 3; R 0

Fireproof. Separated from strong oxidants, and strong acids.


Boiling point: 138°CMelting point: 13°CRelative density (water = 1): 0.86Solubility in water: noneVapour pressure, kPa at 20°C: 0.9Relative vapour density (air = 1): 3.7

Relative density of the vapour/air-mixture at 20°C (air = 1): 1.02Flash point: 27°C c.c.Auto-ignition temperature: 528°CExplosive limits, vol% in air: 1.1-7.0Octanol/water partition coefficient as log Pow: 3.15


©IPCS 2002

0086 p-XYLENE

IMPORTANT DATA


Physical dangersAs a result of flow, agitation, etc., electrostatic charges can begenerated.

Chemical dangersReacts with strong acids and strong oxidants.

Occupational exposure limitsTLV: 100 ppm as TWA; 150 ppm as STEL A4 (ACGIH 2001).BEI specified by (ACGIH 2001).EU OEL: 50 ppm as TWA; 100 ppm as STEL (skin) (EU 2000).


Inhalation riskA harmful contamination of the air will be reached rather slowlyon evaporation of this substance at 20°C.

Effects of short-term exposureThe substance is irritating to the eyes and the skin. Thesubstance may cause effects on the central nervous system. Ifthis liquid is swallowed, aspiration into the lungs may result inchemical pneumonitis.

Effects of long-term or repeated exposureThe liquid defats the skin. The substance may have effects onthe central nervous system. Exposure to the substance mayenhance hearing damage caused by exposure to noise. Animaltests show that this substance possibly causes toxicity tohuman reproduction or development.

PHYSICAL PROPERTIES

ENVIRONMENTAL DATA


NOTES

Depending on the degree of exposure, periodic medical examination is indicated.The recommendations on this Card also apply to technical xylene.See ICSC 0084 o-Xylene and 0085 m-Xylene.




© IPCS 2003



PROPANE 0319November 2003

CAS No: 74-98-6RTECS No: TX2275000UN No: 1978EC No: 601-003-00-5

n-Propane(cylinder)C3H8 / CH3CH2CH3




FIRE Extremely flammable. NO open flames, NO sparks, andNO smoking.


EXPLOSION Gas/air mixtures are explosive. Closed system, ventilation,explosion-proof electrical equipmentand lighting. Prevent build-up ofelectrostatic charges (e.g., bygrounding) if in liquid state. Usenon-sparking handtools.


EXPOSURE

Inhalation Drowsiness. Unconsciousness. Closed system and ventilation. Fresh air, rest. Artificial respirationmay be needed. Refer for medicalattention.




Eyes ON CONTACT WITH LIQUID:FROSTBITE.

Face shield. First rinse with plenty of water forseveral minutes (remove contactlenses if easily possible), then taketo a doctor.

Ingestion


Evacuate danger area! Consult an expert! Removeall ignition sources. Ventilation. NEVER direct waterjet on liquid. (Extra personal protection:self-contained breathing apparatus.)

F+ SymbolR: 12S: (2-)9-16UN Hazard Class: 2.1



Fireproof. Cool.


Boiling point: -42°CMelting point: -189.7°CRelative density (water = 1): 0.5Solubility in water, g/100 ml at 20°C: 0.007Vapour pressure, kPa at 20°C: 840

Relative vapour density (air = 1): 1.6Flash point: -104°CAuto-ignition temperature: 450°CExplosive limits, vol% in air: 2.1-9.5Octanol/water partition coefficient as log Pow: 2.36


©IPCS 2003

0319 PROPANE

IMPORTANT DATA

Physical State; AppearanceODOURLESS, COLOURLESS COMPRESSED LIQUEFIEDGAS.

Physical dangersThe gas is heavier than air and may travel along the ground;distant ignition possible, and may accumulate in low ceilingspaces causing deficiency of oxygen. As a result of flow,agitation, etc., electrostatic charges can be generated.

Occupational exposure limitsTLV: 2500 ppm as TWA; (ACGIH 2003).MAK: 1000 ppm, 1800 mg/m3; Peak limitation category: II(2);Pregnancy risk group: IIc; (DFG 2003).


Inhalation riskOn loss of containment this liquid evaporates very quicklydisplacing the air and causing a serious risk of suffocationwhen in confined areas.

Effects of short-term exposureRapid evaporation of the liquid may cause frostbite. Thesubstance may cause effects on the central nervous system.

PHYSICAL PROPERTIES

ENVIRONMENTAL DATA

NOTES

Check oxygen content before entering area.Turn leaking cylinder with the leak up to prevent escape of gas in liquid state.High concentrations in the air cause a deficiency of oxygen with the risk of unconsciousness or death.




© IPCS 1999



STYRENE 0073April 1994

CAS No: 100-42-5RTECS No: WL3675000UN No: 2055 (styrene monomer, inhibited)EC No: 601-026-00-0

VinylbenzenePhenylethyleneEthenylbenzeneC8H8 / C6H5CH=CH2







EXPLOSION Above 31�C explosive vapour/airmixtures may be formed. SeeNotes.

Above 31�C use a closed system,ventilation, and explosion-proofelectrical equipment. Preventbuild-up of electrostatic charges(e.g., by grounding).



Inhalation Dizziness. Drowsiness. Headache.Nausea. Weakness.


Fresh air, rest.

Skin Redness. Protective clothing. Remove contaminated clothes.Rinse and then wash skin withwater and soap.

Eyes Redness. Pain. Safety goggles or eye protection incombination with breathingprotection.


Ingestion Abdominal pain (further seeInhalation).


Rinse mouth. Do NOT inducevomiting. Give plenty of water todrink. Rest.


Ventilation. Collect leaking and spilled liquid insealable containers as far as possible. Absorbremaining liquid in sand or inert absorbent andremove to safe place. Do NOT wash away intosewer. Do NOT let this chemical enter theenvironment (extra personal protection:self-contained breathing apparatus).

Xn SymbolR: 10-20-36/38S: (2-)23Note: DUN Hazard Class: 3UN Pack Group: III

Airtight. Marine pollutant.


Transport Emergency Card: TEC (R)-101(monomer, inhibited)NFPA Code: H 2; F 3; R 2;

Fireproof. Separated from incompatible materials (see Chemical Dangers).Cool. Keep in the dark. Store only if stabilized.


Boiling point: 145�CMelting point: -30.6�CRelative density (water = 1): 0.9Solubility in water, g/100 ml at 25�C: 0.03Vapour pressure, kPa at 20�C: 0.7Relative vapour density (air = 1): 3.6

Relative density of the vapour/air-mixture at 20�C (air = 1): 1.02Flash point: 31�C c.c. Auto-ignition temperature: 490�CExplosive limits, vol% in air: 0.9-6.8Octanol/water partition coefficient as log Pow: 3.2


© IPCS 1999

0073 STYRENE

IMPORTANT DATA

Physical State; AppearanceCOLOURLESS TO YELLOW, OILY LIQUID.

Physical DangersAs a result of flow, agitation, etc., electrostatic charges can begenerated.

Chemical DangersThe substance can form explosive peroxides. The substancemay polymerize due to warming, under the influence of lightand on contact with many compounds such as oxygen,oxidizing agents, peroxides and strong acids with fire orexplosion hazard. The substance decomposes on burningproducing toxic fumes, styrene oxide. Attacks copper andcopper alloys.

Occupational Exposure LimitsTLV: 50 ppm; 213 mg/m3 STEL: 100ppm; 426 mg/m3 (skin) (ACGIH 1993-1994).

Routes of ExposureThe substance can be absorbed into the body by inhalationand through the skin.

Inhalation RiskA harmful contamination of the air will be reached rather slowlyon evaporation of this substance at 20�C.

Effects of Short-term ExposureThe substance irritates the eyes, the skin and the respiratorytract. Swallowing the liquid may cause aspiration into the lungswith the risk of chemical pneumonitis. Exposure could causelowering of consciousness.

Effects of Long-term or Repeated ExposureRepeated or prolonged contact with skin may cause dermatitis.Repeated or prolonged contact may cause skin sensitization.Repeated or prolonged inhalation exposure may causeasthma. The substance may have effects on the centralnervous system. This substance is possibly carcinogenic tohumans. See Notes.

PHYSICAL PROPERTIES

ENVIRONMENTAL DATA

NOTES

Depending on the degree of exposure, periodic medical examination is indicated. The symptoms of asthma often do not becomemanifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation are thereforeessential. Anyone who has shown symptoms of asthma due to this substance should avoid all further contact with this substance.An added stabilizer or inhibitor can influence the toxicological properties of this substance, consult an expert. Check for peroxidesprior to distillation; eliminate if found. Styrene monomer vapours are uninhibited and may form polymers in vents or flamearresters of storage tanks, resulting in blockage of vents.




© IPCS 2000



SULFUR 1166April 2000

CAS No: 7704-34-9RTECS No: WS4250000UN No: 1350

Flowers of sulfurFlour sulfurBrimstoneS or S8

Molecular mass: 256.5 (S8); Atomic mass: 32.1



FIRE Combustible. NO open flames, NO sparks, andNO smoking.

Water spray. Foam. Powder. Drysand.

EXPLOSION Finely dispersed particles formexplosive mixtures in air.

Prevent deposition of dust; closedsystem, dust explosion-proofelectrical equipment and lighting.Prevent build-up of electrostaticcharges (e.g., by grounding).


EXPOSURE PREVENT DISPERSION OF DUST!

Inhalation Burning sensation. Cough. Sorethroat.

Local exhaust or breathingprotection.

Fresh air, rest. Half-upright position.Refer for medical attention.

Skin Redness. Protective gloves. Remove contaminated clothes.Rinse skin with plenty of water orshower.

Eyes Redness. Pain. Blurred vision. Safety goggles. First rinse with plenty of water forseveral minutes (remove contactlenses if easily possible), then taketo a doctor.

Ingestion Burning sensation. Diarrhoea. Do not eat, drink, or smoke duringwork.

Rinse mouth. Refer for medicalattention.


Sweep spilled substance into containers; ifappropriate, moisten first to prevent dusting. (Extrapersonal protection: P2 filter respirator for harmfulparticles).

UN Hazard Class: 4.1UN Pack Group: III


Transport Emergency Card: TEC (R)-115ANFPA Code: H 1; F 1; R 0



Boiling point: 445°CMelting point: (r-sulfur) 107°C, (beta-sulfur) 115°C, (amorphous) 120)°CDensity: 2.1 g/cm3

Solubility in water: noneFlash point: 160°C c.c.Auto-ignition temperature: 232°CExplosive limits, vol% in air: 35-1400 g/m3


©IPCS 2000

1166 SULFUR

IMPORTANT DATA

Physical State; AppearanceYELLOW SOLID IN VARIOUS FORMS

Physical dangersDust explosion possible if in powder or granular form, mixedwith air. If dry, it can be charged electrostatically by swirling,pneumatic transport, pouring, etc.

Chemical dangersOn combustion, forms toxic and corrosive gases of sulfur oxidesincluding sulfur dioxide (see ICSC 0074). Reacts violently withstrong oxidants causing fire and explosion hazard, especially ifpowdered.

Occupational exposure limitsTLV not established.

Routes of exposureThe substance can be absorbed into the body by inhalation andby ingestion.

Inhalation riskEvaporation at 20°C is negligible; a harmful concentration ofairborne particles can, however, be reached quickly whendispersed.

Effects of short-term exposureThe substance irritates the eyes, the skin and the respiratorytract. Inhalation of powder of this substance may causeinflammation of the nose and the respiratory tract.

Effects of long-term or repeated exposureRepeated or prolonged contact with skin may cause dermatitis.The substance may have effects on the respiratory tract,resulting in chronic bronchitis.

PHYSICAL PROPERTIES

ENVIRONMENTAL DATA

NOTES

Often transported in molten state (UN 2448; TEC(R)-115). Molten sulfur reacts with hydrocarbons to form toxic and flammablegases.Depending on the degree of exposure, periodic medical examination is indicated.




IPCS 2005



SULFURIC ACID 0362October 2000

CAS No: 7664-93-9RTECS No: WS5600000UN No: 1830EC No: 016-020-00-8

Sulfuric acid 100%Oil of vitriolH2SO4Molecular mass: 98.1



FIRE Not combustible. Many reactionsmay cause fire or explosion. Givesoff irritating or toxic fumes (orgases) in a fire.

NO contact with flammablesubstances. NO contact withcombustibles.

NO water. In case of fire in thesurroundings: powder, AFFF, foam,carbon dioxide.

EXPLOSION Risk of fire and explosion on contactwith base(s), combustiblesubstances, oxidants, reducingagents or water.

In case of fire: keep drums, etc., coolby spraying with water but NO directcontact with water.

EXPOSURE PREVENT GENERATION OFMISTS! AVOID ALL CONTACT!

IN ALL CASES CONSULT ADOCTOR!

Inhalation Corrosive. Burning sensation. Sorethroat. Cough. Laboured breathing.Shortness of breath. Symptomsmay be delayed (see Notes).



Skin Corrosive. Redness. Pain. Blisters.Serious skin burns.

Protective gloves. Protective clothing. Remove contaminated clothes.Rinse skin with plenty of water orshower. Refer for medical attention.

Eyes Corrosive. Redness. Pain. Severedeep burns.

Face shield or eye protection incombination with breathingprotection.


Ingestion Corrosive. Abdominal pain. Burningsensation. Shock or collapse.


Rinse mouth. Do NOT inducevomiting. Refer for medical attention.


Consult an expert! Evacuate danger area! Do NOTabsorb in saw-dust or other combustible absorbents.Personal protection: complete protective clothingincluding self-contained breathing apparatus. Do NOTlet this chemical enter the environment.

C SymbolR: 35S: (1/2-)26-30-45Note: BUN Hazard Class: 8UN Pack Group: II

Unbreakable packaging; putbreakable packaging into closedunbreakable container. Do nottransport with food and feedstuffs.


Transport Emergency Card: TEC (R)-80S1830 or80GC1-II+IIINFPA Code: H 3; F 0; R 2; W

Separated from combustible and reducing substances, strong oxidants,strong bases, food and feedstuffs, incompatible materials. See ChemicalDangers. May be stored in stainless steel containers. Store in an area havingcorrosion resistant concrete floor.


Boiling point (decomposes): 340/CMelting point: 10/CRelative density (water = 1): 1.8

Solubility in water: miscibleVapour pressure, kPa at 146/C: 0.13Relative vapour density (air = 1): 3.4


©IPCS 2005

0362 SULFURIC ACID

IMPORTANT DATA

Physical State; AppearanceCOLOURLESS, OILY, HYGROSCOPIC LIQUID, WITH NOODOUR.

Chemical dangersThe substance is a strong oxidant and reacts violently withcombustible and reducing materials. The substance is a strongacid, it reacts violently with bases and is corrosive to mostcommon metals forming a flammable/explosive gas (hydrogen -see ICSC 0001). Reacts violently with water and organic materialswith evolution of heat (see Notes). Upon heating, irritating or toxicfumes (or gases) (sulfur oxides) are formed.

Occupational exposure limitsTLV: 1 mg/m3 as TWA, 3 mg/m3 as STEL; sulfuric acid containedin strong inorganic acid mists A2 (suspected human carcinogen);(ACGIH 2004).MAK: (Inhalable fraction) 0.1 mg/m3; Peak limitation category: I(1);Carcinogen category: 4; Pregnancy risk group: C; (DFG 2004).

Routes of exposureThe substance can be absorbed into the body by inhalation of itsaerosol and by ingestion.

Inhalation riskEvaporation at 20/C is negligible; a harmful concentration ofairborne particles can, however, be reached quickly on spraying.

Effects of short-term exposureCorrosive. The substance is very corrosive to the eyes, the skinand the respiratory tract. Corrosive on ingestion. Inhalation of anaerosol of this substance may cause lung oedema (see Notes).

Effects of long-term or repeated exposureLungs may be affected by repeated or prolonged exposure to anaerosol of this substance. Risk of tooth erosion upon repeated orprolonged exposure to an aerosol of this substance. Stronginorganic acid mists containing this substance are carcinogenicto humans.

PHYSICAL PROPERTIES

ENVIRONMENTAL DATA


NOTES

The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort.Rest and medical observation are therefore essential.NEVER pour water into this substance; when dissolving or diluting always add it slowly to the water.Other UN numbers: UN1831 Sulfuric acid, fuming, hazard class 8, subsidiary hazard 6.1, pack group I; UN1832 Sulfuric acid, spent,Hazard class 8, Pack group II.Card has been partly updated in October 2005. See sections Occupational Exposure Limits, Emergency Response.






TOLUENE 0078October 2002

CAS No: 108-88-3RTECS No: XS5250000UN No: 1294EC No: 601-021-00-3

MethylbenzeneToluolPhenylmethaneC6H5CH3 / C7H8Molecular mass: 92.1





EXPLOSION Vapour/air mixtures are explosive. Closed system, ventilation,explosion-proof electrical equipmentand lighting. Prevent build-up ofelectrostatic charges (e.g., bygrounding). Do NOT usecompressed air for filling,discharging, or handling. Usenon-sparking handtools.


EXPOSURE STRICT HYGIENE! AVOIDEXPOSURE OF (PREGNANT)WOMEN!

Inhalation Cough. Sore throat. Dizziness.Drowsiness. Headache. Nausea.Unconsciousness.



Skin Dry skin. Redness. Protective gloves. Remove contaminated clothes.Rinse and then wash skin with waterand soap. Refer for medicalattention.

Eyes Redness. Pain. Safety goggles. First rinse with plenty of water forseveral minutes (remove contactlenses if easily possible), then taketo a doctor.





Evacuate danger area in large spill! Consult anexpert in large spill! Remove all ignition sources.Ventilation. Collect leaking liquid in sealablecontainers. Absorb remaining liquid in sand or inertabsorbent and remove to safe place. Do NOT washaway into sewer. Do NOT let this chemical enter theenvironment. Personal protection: self-containedbreathing apparatus in large spill.

F SymbolXn SymbolR: 11-38-48/20-63-65-67S: (2-)36/37-46-62UN Hazard Class: 3UN Pack Group: II





Boiling point: 111/CMelting point: -95/CRelative density (water = 1): 0.87Solubility in water: noneVapour pressure, kPa at 25/C: 3.8Relative vapour density (air = 1): 3.1

Relative density of the vapour/air-mixture at 20/C (air = 1): 1.01Flash point: 4/C c.c.Auto-ignition temperature: 480/CExplosive limits, vol% in air: 1.1-7.1Octanol/water partition coefficient as log Pow: 2.69


©IPCS 2004

0078 TOLUENE


Physical dangersThe vapour mixes well with air, explosive mixtures are formedeasily. As a result of flow, agitation, etc., electrostatic chargescan be generated.

Chemical dangersReacts violently with strong oxidants causing fire and explosionhazard.

Occupational exposure limitsTLV: 50 ppm as TWA; (skin); A4; BEI issued; (ACGIH 2004).MAK: 50 ppm, 190 mg/m3; H; Peak limitation category: II(4);Pregnancy risk group: C; (DFG 2004).



Effects of short-term exposureThe substance is irritating to the eyes and the respiratory tract.The substance may cause effects on the central nervoussystem. If this liquid is swallowed, aspiration into the lungs mayresult in chemical pneumonitis. Exposure at high levels mayresult in cardiac dysrhythmia and unconsciousness.

Effects of long-term or repeated exposureThe liquid defats the skin. The substance may have effects onthe central nervous system. Exposure to the substance mayenhance hearing damage caused by exposure to noise. Animaltests show that this substance possibly causes toxicity to humanreproduction or development.

PHYSICAL PROPERTIES

ENVIRONMENTAL DATAThe substance is toxic to aquatic organisms.

NOTESDepending on the degree of exposure, periodic medical examination is suggested.Use of alcoholic beverages enhances the harmful effect.Card has been partly updated in October 2004. See sections Occupational Exposure Limits, EU classification, EmergencyResponse.




© IPCS 2002



TRIMETHYLAMINE 0206October 2002

CAS No: 75-50-3RTECS No: PA0350000UN No: 1083 (anhydrous)EC No: 612-001-00-9

N,N-DimethylmethanamineTMA(cylinder)C3H9N / (CH3)3NMolecular mass: 59.1









Inhalation Burning sensation. Cough.Headache. Sore throat. Labouredbreathing. Shortness of breath.Symptoms may be delayed (seeNotes).






Eyes Redness. Pain. Blurred vision. Safety goggles, or eye protection incombination with breathingprotection.




Evacuate danger area! Consult an expert!Ventilation. Remove all ignition sources. NEVERdirect water jet on liquid. Remove vapour with finewater spray. (Extra personal protection: completeprotective clothing including self-containedbreathing apparatus.)



Transport Emergency Card: TEC (R)-20S1083NFPA Code: H3; F4; R0.

Fireproof. Cool.


Boiling point: 3°CMelting point: -117°CRelative density (water = 1): 0.6 (liquid)Solubility in water: very goodVapour pressure, kPa at 20°C: 187

Relative vapour density (air = 1): 2Flash point: Flammable GasAuto-ignition temperature: 190°CExplosive limits, vol% in air: 2.0-11.6Octanol/water partition coefficient as log Pow: 0.2


©IPCS 2002

0206 TRIMETHYLAMINE

IMPORTANT DATA

Physical State; AppearanceCOLOURLESS COMPRESSED LIQUEFIED GAS, WITHCHARACTERISTIC ODOUR.

Physical dangersThe gas is heavier than air and may travel along the ground;distant ignition possible.

Chemical dangersThe substance decomposes on burning producing toxic fumesincluding nitrogen oxides. The solution in water is a strong base,it reacts violently with acid and is corrosive. Reacts violentlywith oxidants, ethylene oxide. Attacks metal such as copper,zinc, aluminium, tin, and their alloys.

Occupational exposure limitsTLV: 5 ppm (as TWA); 15 ppm (as STEL); (ACGIH 2002).MAK: class IIb (see Notes) (2002)



Effects of short-term exposureThe substance is severely irritating to the eyes and therespiratory tract. Rapid evaporation of the liquid may causefrostbite. Inhalation of the substance may cause lung oedema(see Notes). The effects may be delayed. Medical observationis indicated.

PHYSICAL PROPERTIES

ENVIRONMENTAL DATA

NOTES

Turn leaking cylinder with the leak up to prevent escape of gas in liquid state.The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physicaleffort. Rest and medical observation is therefore essential.Immediate administration of an appropriate inhalation therapy by a doctor or a person authorized by him/her, should be considered.MAK value not established but full documentation is available (MAK IIb).




© IPCS 2002



TURPENTINE 1063March 2002

CAS No: 8006-64-2RTECS No: YO8400000UN No: 1299EC No: 650-002-00-6

Turpentine, oilSpirits of turpentineOil of turpentineSteam distilled turpentineGum spiritsWood turpentineC10H16 (approx)Molecular mass: 136 (approx)





Foam, dry powder, carbon dioxide.


Above 30°C use a closed system,ventilation, and explosion-proofelectrical equipment. Preventbuild-up of electrostatic charges(e.g., by grounding). Usenon-sparking handtools.


EXPOSURE PREVENT GENERATION OFMISTS! STRICT HYGIENE!

Inhalation Confusion. Cough. Headache.Sore throat. Shortness of breath.


Fresh air, rest. Artificial respirationmay be needed. Refer for medicalattention.

Skin Redness. Pain. Protective gloves. Protectiveclothing.

Remove contaminated clothes.Rinse and then wash skin withwater and soap.

Eyes Blurred vision. Pain. Redness. Safety spectacles, or eye protectionin combination with breathingprotection.


Ingestion Burning sensation. Abdominalpain. Nausea. Vomiting.Confusion. Convulsions.Diarrhoea. Unconsciousness.


Do NOT induce vomiting. Giveplenty of water to drink. Refer formedical attention.


Cover the spilled material with dry earth or sand orother non-combustible material. Ventilation.Remove all ignition sources. Do NOT wash awayinto sewer. Sweep spilled substance into containersand then remove to safe place. (Extra personalprotection: self-contained breathing apparatus.) DoNOT let this chemical enter the environment.

Xn SymbolN SymbolR: 10-20/21/22-36/38-43-51/53-65S: (2-)36/37-46-61-62UN Hazard Class: 3UN Pack Group: III

Marine pollutant.



Fireproof. Separated from strong oxidants, incompatible materials. SeeChemical Dangers. Cool. Keep in a well-ventilated room.


Boiling point: 149 to 180°CMelting point: -50 to -60°CRelative density (water = 1): 0.9Solubility in water: noneVapour pressure, kPa at 20°C: 0.25 to 0.67

Relative vapour density (air = 1): 4.6 to 4.8Relative density of the vapour/air-mixture at 20°C (air = 1): 1.01Flash point: 30 to 46°C c.c.Auto-ignition temperature: 220 to 255°CExplosive limits, vol% in air: 0.8-6


©IPCS 2002

1063 TURPENTINE

IMPORTANT DATA


Chemical dangersOn combustion, forms toxic fumes including carbon monoxide.The substance decomposes slowly under the influence of air orlight producing oxidation products that are more toxic orirritating than turpentine itself. Reacts violently with oxidants,halogens, combustible substances, mineral acids. Attacksplastic and rubber.

Occupational exposure limitsTLV: 100 ppm (as TWA); SEN Intended change; (ACGIH 2001).

Routes of exposureThe substance can be absorbed into the body by inhalation ofits vapour, through the skin and by ingestion.


Effects of short-term exposureThe vapour is irritating to the eyes, the skin and the respiratorytract. If this liquid is swallowed, aspiration into the lungs mayresult in chemical pneumonitis. The substance may causeeffects on the central nervous system, bladder and kidneys,resulting in irritability, convulsions and kidney impairment.Exposure at high levels may result in tachycardia,unconsciousness, respiratory failure, death.

Effects of long-term or repeated exposureRepeated or prolonged contact may cause skin sensitization.The liquid defats the skin.

PHYSICAL PROPERTIES

ENVIRONMENTAL DATA

The substance is harmful to aquatic organisms. The substance may cause long-term effects in the aquatic environment.

NOTES

The odour warning when the exposure limit value is exceeded is insufficient.Turpentine is obtained by distilling the gum from various species of pine. It is a mixture of isomeric terpene hydrocarbons.Composition varies with refining methods and the age, location and species of the softwood source.




© IPCS 2002



m-XYLENE 0085March 2002

CAS No: 108-38-3RTECS No: ZE2275000UN No: 1307EC No: 601-022-00-9

meta-Xylene1,3-Dimethylbenzenem-XylolC6H4(CH3)2 / C8H10





Powder, water spray, foam, carbondioxide.


Above 27°C use a closed system,ventilation, and explosion-proofelectrical equipment. Preventbuild-up of electrostatic charges(e.g., by grounding).



Inhalation Dizziness. Drowsiness. Headache.Nausea.



Skin Dry skin. Redness. Protective gloves. Remove contaminated clothes.Rinse and then wash skin withwater and soap.

Eyes Redness. Pain. Safety spectacles. First rinse with plenty of water forseveral minutes (remove contactlenses if easily possible), then taketo a doctor.





Ventilation. Remove all ignition sources. Collectleaking and spilled liquid in sealable containers asfar as possible. Absorb remaining liquid in sand orinert absorbent and remove to safe place. Do NOTlet this chemical enter the environment. (Extrapersonal protection: filter respirator for organicgases and vapours.)

Xn SymbolR: 10-20/21-38S: (2-)25Note: CUN Hazard Class: 3UN Pack Group: III


NFPA Code: H 2; F 3; R 0;Transport Emergency Card: TEC (R)-30S1307-III

Fireproof. Separated from strong oxidants and strong acids.


Boiling point: 139°CMelting point: -48°CRelative density (water = 1): 0.86Solubility in water: noneVapour pressure, kPa at 20°C: 0.8Relative vapour density (air = 1): 3.7

Relative density of the vapour/air-mixture at 20°C (air = 1): 1.02Flash point: 27°C c.c.Auto-ignition temperature: 527°CExplosive limits, vol% in air: 1.1-7.0Octanol/water partition coefficient as log Pow: 3.20


©IPCS 2002

0085 m-XYLENE

IMPORTANT DATA


Physical dangersAs a result of flow, agitation, etc., electrostatic charges can begenerated.

Chemical dangersReacts with strong acids and strong oxidants.

Occupational exposure limitsTLV: 100 ppm as TWA; 150 ppm as STEL A4 (ACGIH 2001).BEI specified by (ACGIH 2001).EU OEL: 50 ppm as TWA; 100 ppm as STEL (skin) (EU 2000).



Effects of short-term exposureThe substance is irritating to the eyes and the skin. Thesubstance may cause effects on the central nervous system. Ifthis liquid is swallowed, aspiration into the lungs may result inchemical pneumonitis.

Effects of long-term or repeated exposureThe liquid defats the skin. The substance may have effects onthe central nervous system. Exposure to the substance mayenhance hearing damage caused by exposure to noise. Animaltests show that this substance possibly causes toxicity tohuman reproduction or development.

PHYSICAL PROPERTIES

ENVIRONMENTAL DATA


NOTES

Depending on the degree of exposure, periodic medical examination is indicated.The recommendations on this Card also apply to technical xylene.See ICSC 0084 o-Xylene and 0086 p-Xylene.



150

ANNEXURE – IV

CONTACT INFORMATION EMERGENCY SERVICES

Telephone Nos. Of Control Rooms

Important Control Rooms Telephone nos. Fax No.

Dsaster Mangement Control Room22694725, 22694727 22694719

MCGM22620251 Ext

2062/2054 22704403

Disaster Helpline 108

Bus Running Control Officer 24146533, 24184489 24146532

(BEST Traffic Control)24137937,

24146262 Ext-801

BEST Traffic Control Room 24143611, 24136883

(Wadala)24137645, 24146162

BEST Bus Control 24137924, 24127244

(For BEST bus breakdowns) 24129651, 24111979

BEST Electric Supply -Dadar 24145888, 24124242

Control Room - Phathakwadi

22067893, 22082875 22085888

Weather Bureau 22150431 22160824

Mantralaya Control Room 22024243, 22854168

Traffic Police 24937746, 24937755 24927234

24937747

Mumbai Police Headquarters 10022625020, 22621983 22633319

22641440, 22623054

141

Fire Brigade Control Room 101 23076111/12/13 23085993

23086181/82

Reliance Energy - Special Officer/ 30094920

Shri V.B.Sharma 9323551665

Santacruz 30099999 30099776

Andheri/Jogeshwari30096999, 30094302

Goregaon/Kandivili30096999, 30094900 30094844

Borivili/Bhayander30094500, 30093070 30094633

Chembur/Kurla/Vikhroli30096999, 30092040 30092022

M.S.E.D.C.L. - Bandra26472131, 26474211 26476749

Bhandup25663408, 25664323 25643990

Mulund(West) 25686666,

25653408

Mulund(East) 21636945

Western Railway Churchgate22017420, 22084287

Control Room23070564, 23720505

Central Railway CST 22622685,

9821223724

Railway Police22620173, 22621695

Konkan Railway Control Room27579969, 27572015 27572420

MTNL - Head Office 24371900 24372033

142

CONTACT INFORMATION:

Fire Station:

FIRE STATION

NO.NAME & ADDRESS OF THE

FIRESTATIONSCONTACT NO.

1 COLABANARAYAN ATMARAM SAWANT MARG,COLABA,MUMBAI-400 005

22043603

2 FORTRUSTOM SINDHVA MARG,FORT,MUMBAI-400 001

22611942

3 MEMONWADAS.V.P.ROAD,MUMBAI-400 003

23478818

4 GOVALIYA TANKAGUST KRANTI MARG,NANA CHOWK,MUMBAI-400 007

223801118

5 BYCULLABAPURAO JAGTAP MARG,BYCULLA,MUMBAI-400 008

23086181

6 WARALIDR.ANNI BASANT ROAD,WARALI,MUMBAI-400 025

24300178

7 DADARDR.BABASAHEB AMBEDKAR MARG,DADAR,MUMBAI-400 008

224134200

8 SHIVAJII PARKPRAKASH KOTNIS MARG,MAHIM,MUMBAI-400 016

24457203

9 INDIRA DOCKP’DIMELO ROAD,KARNAK BUNDER,MUMBAI-400 038

22611589

10 MANDVIS.V.P.ROAD,WADIBUNDER,MUMBAI-400 009

23716694

11 SEWARIBARISTER NATH PAI MARG,COTTON GREEN MARG,MUMBAI-400 033

23775756

12 ANDHERIS.V.ROAD,IRLA BIDGE,ANDHERI(W)MUMBAI-400 058

26205301

13 VIKHROLIL.B.S.ROAD,VIKHROLI PARKSITE, VIKHROLI(W)MUMBAI-400 079

25170730

14 CEMBURV.N.PURAVMARG,CHEMBUR,MUMBAI-400 071

25224824

15 DHARAVI 24077868

87

RAJASHRI SHAHU NAGAR,MAHIM(E),MUMBAI-400 017

16 DEVNAR5/4 SECTOR,NEW MUNICIPAL COLONY,DEVNAR,MUMBAI-400 043

25563391

17 MULUNDL.B.S. MARG,MULUND(W)MUMBAI-400 080

25687637

18 RAVALI CAMPLEELABAI KASBE MARG,SARDAR NAGAR NO.4, MUMBAI-400 037

24077841

19 KANDIVLIS.V.ROAD,KANDIVLI(W)MUMBAI-400 067

28050101

20 MAROLAGNISHAMAN DAL MARG,MAROL NAKA,ANDHERI(E),MUMBAI-400 059

28210940/41

21 MALADMARVE ROAD,MALVANI,MALAD(W)MUMBAI-400 095

28071010

22 BANDRAKRSHNA CHANDRA MARG, RECLAMATION,BANDRA(W),MUMBAI-400 058

26435206

23 NARIMAN POINTV.V.RAO MARG,MUMBAI-400 020

22882787

24 WADALASHAIKH MISTRI DARGA ROAD,C.G.S.COLONY,SECTOR NO.7,ANTOP HILL,MUMBAI-400 037

24122255

25 GAVANPADASWATANRA VEER SAVARKAR MARG,MULUND(E),MUMBAI-400 081

25639191

26 BORIVLIGORAI ROAD ROAD,BORIVLI(W)MUMBAI-400 104

26112121

27 VILEPAELEAZAD ROAD,VILEPARLE(E)GOREGOAN,MUMBAI-400 057

28602848

28 KURLA KAMANIANDHERI KURLA RD. L.B.S. MARG JUNCTION, OPP MUCUND CO. LTD.MUMBAI

25039200

29 BANDRA KURLA COMPLEX,OPP MTNL OFFICE,KURLA -WMUMBAI

S.O. KAHRBADE26435260

30 CHINCHLILINK ROAD,MALAD(W,)MUMBAI

S.O. MHASKE9819751759

88

31 DINDOSHIARUN KUMAR VAIDYA MARG,GOREGOAN (E)MUMBAI

S.O. JADHAV9869331391

32 DAHISAR,SHAILENDRA NAGAR, NEAR DAHISAR POST OFFICE, DAHISAR -EMUMBAI

S.O. MAINKAR9869532248

33 GOREGOANBEST COLONY ROAD,GOREGOAN(W)MUMBAI-400 104

28712869

Brigade Senior Officers:

DISI NAME AND ADDRESS MOBILE NOS..C.F.O (i/c) P.D.KARGUPPIKAR

INDIRA DOCK FIRE STATION

9820702531

” U.K.TATKARENARIMAN POINT FIRE STATION

9930464805

” A.N.SHINDEKANDIWILI FIRE STATION

9930464806

” H.N.MUJAWARBYCULLA FIRE STATION

9930464807

” S.V.JOSHICOLABA FIRE STATION

9930464808

Dy. C.F.O.( i/c)

A.R.PATILBYCULLA FIRE STATION

9930464809

DFO R.B.KHOLKHUMBEIDOCK FIRE STATOPM

9930464810

” J.A.H. MALIKMEMONWADA FIRE

9930464811

D.F.O. (i/c) A.N.VARMACHEMBUR FIRE STATION

9930464812

A.D.F.O S.A.MALI.ANDHERI FIRE STATION

9930464813

” M.R.KADAMBYCULLA FIRE STATION

9930464814

” C.I.SHAIKHMULUND KAMANI

9930464815

” V.R.KUVESKARKANDIVALI FIRE STATION

9930464817

” V.V.NIKAM.BYCULLA FIRE STATION

9930464818

” S.K.RANE.MAROL FIRE STATION

9930464819

89

DISI NAME AND ADDRESS MOBILE NOS.” S.H.NESRIKAR

CHEMBER FIRE STATION

9930464823

” P.S. RAHANGDALENARIMAN POINT FIRE STATION

9930464820

” S.A.KALEWORLI FIRE STATION

9930464822

” S.G.AMIN.FORT FIRE STATION

9930464821

” V.N. PANIGRAHI

R.CAMP FIRE STATION

9930464824

” K.V. HIWARALE

M.WADA

9930464825

” H.D. PARAB

MAROL

9930464826

” A.V. KALE

BANDRA

9930464827

A.D.O. ( Tech) R.A. CHAUDHARY

BYCULLA

9930464828

90

Annexure – VIII

List of MCGM Hospitals

Municipal Hospitals:

Sr. No. Name Address Telephone

NumberNo. of Beds

Name of Police Station

1 A.K.J. Banke Bihari E.N.T. Hospital

7, Maharshi Dadhichi Marg, Flora Fountain, Fort, Mumbai – 01

2204 3322 2204 2526 2204 5996 2202 1191

100 Azad Maidan Police Station

2 Nair Hospital B.Y.L. Nair Charitable Hospital, Dr. Nair Road, Mumbai Central, Mumbai - 400 008

2308 1490 2309 8150 2308 1491 2308 1758 2385 5555

1229 Agripada Police Station

3 Municipal Eye Hospital

DO Tanki, Maulana Saukat Ali Road, Byculla (West) Mumbai - 400 008

2309 6361 2308 2632

80 Nagpada Police Station

4 Kasturba Hospital

Sane Guruji Marg, Chinch Pokli, Mumbai - 400 011

2308 3901 2308 3902 2300 4323 2308 3991 2309 2458

515 Byculla Police Station

5 K.E.M. Hospital Dr. E. Borges Road, Parel, Mumbai - 400 012

2413 4977 2413 1419 2413 6051 2413 1763

1800 Bhoiwada Police Station

6 Group of T.B. Hospitals

Jerbai Wadia Road, Sewree, Mumbai - 400 015

2414 6789 2414 6790 2414 6791 2414 6792

1000 Kidwai Nagar Police Station

7 Lokmanya Tilak Municipal General Hospital

Sion Hospital, Sion Road, Sion (West), Mumbai - 400 022

2407 6381 24081504 24072020

1422 Matunga Police Station

8 Ackworth Municipal Leprosy Hospital

Near St. Joseph Church, Wadala, Mumbai - 400 031

2414 7256 Wadala Police Station

9 Centenary Hospital

Vaman Tukaram Patil Marg, Near Dukes Company, Gowandi, Mumbai – 400 043

2556 4069 2556 4071

210 Gowandi Police Station

95

10 K.B. Bhabha Hospital

R.K. Patkar Road, Bandra (West), Mumbai - 400 050

2642 2541 2642 2542 2640 6787 2642 9828

Bandra Police Station

11 V.N. Desai Municipal General Hospital

Golibar Road, T.P. S. 3, 11th Road, Santacruze (East), Mumbai - 400 055

2618 3018 2615 1506 2618 2081

Vakola Police Station

12 Cooper Hospital Dr. R.N. Cooper Memorial General Hospital, Cooper Hospital Road, Juhu, Parle (West), Mumbai - 400 056

2620 7254 2620 5892 2620 7258 2620 7447

441 Juhu Police Station

13 B.S.E.S. M.G. Hospital

S.V. Road, Opp. Railway Station, Andheri (West) Mumbai - 400 058

5697 0707 5697 0288 5697 0289

Oshiwara Police Station

14 Mahanagar Palika Shatabdi General Hospital

Kandiwali (West) Mumbai - 400 067

2805 1509 2805 0882 2805 0105

Kandivali Police Station

15 K.B. Bhabha Hospital

Kurla Police Station Road, Takiyawad, Kurla (West), Mumbai – 400 071

2650 0144 2650 0241 2650 3145

320 Kurla Police Station

16 MAA Hospital Diwaliben Mafatlal Mehta Hospital, Sarvodaya Estate, R.C. Marg, Chembur, Mumbai - 400 071

2522 0333 2522 0334 2522 2084

75 Basant Park (Chembur) Police Station

17 Rajawadi Hospital

Vadilal Chatrabhuj Gandhi & Sheth M.A. Vora Municipal Gen. Hospital, Rajawadi, Ghatkopar (East), Mumbai - 400 077

2509 4149 2509 4150 2509 4153 2509 4151

700 Tilak Nagar Police Station

18 M.T. Agarwal Municipal General Hospital

Dr. R.P. Road, Mulund (West), Mumbai - 400 080

2564 0767 2560 5730 2560 5727 2560 5729

233 Mulund (W) Police Station

19 Vir Savarkar Municipal Hospital

Mahatma Phule Road, Mulund (East), Mumbai - 400 081

2561 6226 2568 6225

100 Navghar Police Station

20 Mahatma Phule Municipal General Hospital

Kannamvar Nagar 2, Vikroli (East), Mumbai - 400 083

2578 2283 2577 1292

148 Kannamwar Nagar Police Station

21 Sant Muktabai Municipal Gneral Hospital

Bhattwadi, S.G. Barve Nagar, Ghatkopar (West), Mumbai - 400 086

2512 6088 2515 3771

Ghatkopar Police Station

96

22 Municipal Centenary General Hospital

Vaman Tukaram Patil Marg, Near Dukes Company, Gowandi, Mumbai – 400 043

2556 4069 2556 4071

210 Trombe Police Station

23 Bhagwati Municipal General Hospital

S.V.Road, Tulsi Baug, Borivali (West), Mumbai - 400 092

2893 2461 2893 2462 2893 2463 2893 3740

375 M.H.B. Police Station

24 S.K. Patil Municipal General Hospital

Daftary Road, Malad (East), Mumbai - 400 097

2889 4381 2889 9447

50 Dindoshi Police Station

25 M.W. Desai Municipal General Hospital

Govindnagar Hospital, Govindnagar, Haji Badu Road, Malad (East), Mumbai - 400 097

2877 4215 2877 0007

162 Dindoshi Police Station

26 Siddharth Hospital

Siddharth Nagar, Goregaon (West), Mumbai - 400 104

2876 6885 2876 6886

100 Goregaon Police Station

97

Telephone Nos. Of Control Rooms

Important Control Rooms Telephone nos. Fax No.

Dsaster Mangement Control Room22694725, 22694727 22694719

MCGM22620251 Ext

2062/2054 22704403

Disaster Helpline 108

Bus Running Control Officer 24146533, 24184489 24146532

(BEST Traffic Control)24137937,

24146262 Ext-801

BEST Traffic Control Room 24143611, 24136883

(Wadala)24137645, 24146162

BEST Bus Control 24137924, 24127244

(For BEST bus breakdowns) 24129651, 24111979

BEST Electric Supply -Dadar 24145888, 24124242

Control Room - Phathakwadi

22067893, 22082875 22085888

Weather Bureau 22150431 22160824

Mantralaya Control Room 22024243, 22854168

Traffic Police 24937746, 24937755 24927234

24937747

Mumbai Police Headquarters 10022625020, 22621983 22633319

22641440, 22623054

141

Fire Brigade Control Room 101 23076111/12/13 23085993

23086181/82

Reliance Energy - Special Officer/ 30094920

Shri V.B.Sharma 9323551665

Santacruz 30099999 30099776

Andheri/Jogeshwari30096999, 30094302

Goregaon/Kandivili30096999, 30094900 30094844

Borivili/Bhayander30094500, 30093070 30094633

Chembur/Kurla/Vikhroli30096999, 30092040 30092022

M.S.E.D.C.L. - Bandra26472131, 26474211 26476749

Bhandup25663408, 25664323 25643990

Mulund(West) 25686666,

25653408

Mulund(East) 21636945

Western Railway Churchgate22017420, 22084287

Control Room23070564, 23720505

Central Railway CST 22622685,

9821223724

Railway Police22620173, 22621695

Konkan Railway Control Room27579969, 27572015 27572420

MTNL - Head Office 24371900 24372033

142

Annexure – XVI

Civil Defence Corps, Brihanmumbai

Nodal Officers

Area BMC Ward Nodal Officer Telephone No.

BrihanMumbai

All

Mr. Sanjeevan JoshiAddl. Controller

Off - 2261 0088Res - 2677 5090Fax - 2261 4092Cell - 9969 012427e-mail - [email protected]

Mr. P.V. SureshChief Warden

Res - 6573 6419Cell - 9323 199559

Mr. D.M. KhandareSr. Asstt. Dy. Controller

Off - 2261 1928Cell - 9969 504820

Area-I A, B, C, D, E & G (S)

Smt. S.G. Makandar,Dy. Controller

Off - 2261 1910Cell - 9819 917945

Mr.C.D. Kadam,Asstt. Dy. Controller

Off - 2261 1910Cell - 9869 954685

Area-IIG(N), F(S), F(N), L, H(E) & H(W)

Shri B.B. Kasbe,Dy. Controller

Off - 2308 5123 2309 8777Cell - 9224 401670

Mr. Anil Patil,Dy. Chief Warden

Cell - 9969 341823

Area-III M(E), M(W), N, S & T

Mr. V.R. Tehre,Dy. Controller

Off - 2561 5911Res - 2760 3831Cell - 9867 617800

Mr. A.H. Sonavane,Dy. Chief Warden

Cell - 9322 249430

Area-IV

K(E), K(W), P(S), P(N), R(S), R(C) & R(N)

Mr. V.H. Pawar,Dy. Controller

Off - 2620 6791Res - 2291 9495Cell - 9892 099535

Mr. V,V, Waghmare, Cell - 9869 308299

166

off-site disaster management plan...(like fire, explosion, gas leak) or may prolong for days (fire,...

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