omki - us environmental protection agency · b4s(2-clilotoe1hoxy)melhan e * a § 0, o 2, 1...

\oMki! UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

REGION IIICENTRAL REGIONAL LABORATORY

839 BESTGATE ROADANNAPOLIS, MARYLAND 21401

(301) 266-9180

DATE : May 17, 1989

SUBJECT- Organic Data Validation for the Mid-Atlantic Wood PreserversSite - Case 11488

FROM ' Theresa A. SimpsonRegion III Acting ESAT DPO (3ES23)

TO : Eric NewmanRegional Project Manager (3HW16)

THRU : Patricia J. Kran tzChief, QA Section (3ES23)

Attached is the organic data review for the Mid-Atlantic WoodPreservers Site (Case 11488) completed by the Region IIIEnvironmental Services Assistance Team (ESAT) contractor underthe direction of Region III ESD.

If you have any questions regarding this review, please callme .

Attachment

cc: Freda Griffis, LEE WAN ASSOC.Karen Kihlstadius, MD DOEElaine Spiewak (3HW10) (w/o attachments)

TID File: 03890511 Task 1651

_ __ _ __________ • Task

DATA VALIDATION EVALUATION CHECKLIST

Case/SAS Number; IdS'S' _____ Sice Name: Nlitl - Atl**1'i< IjJotJAssignment £; -»•?>•> ?~ // Revision Number; O^ Analysis Type; Fu// a *«?

'^

Reviewer! 0 O'^v '• /"> _______ Contractor; frS'flT SOW #;Information • . Informationrequest date: ________ __ _______ received date:Date submitted to EPA;E2A DPO; T?*rt^ o/'»«Ofj* Cdc?''*-;'' ____ Number of hours spentZ?A RPM; ?/t>c ' J*?~JfV/**\__________1___________ on review: Jr"____

cc:_______________________________ Number of______________________________ samples: ^_____

CRITERIA TS5 NO COMMENTS

Format according toRegion III protocol __ __ ______________________________

Clarity of report " __ __

Qualifiers appliedcorrectly . __ __

Consistency between---- . .--•.. - — -narrative, data summaryfora(s), and DPO report __ __

Error-free transcription __.--___— -

ErTICIZNCY £? • TSS H2 COtlZNTSCOSTRACTOR _ ''

Approval recommendedfor current submission __ __

Time spent on reviewis reasonable __ __ ___________________________

ESP OVERSIGHT

MONITOR/DATES AFC/DPO EVALUATOR __________ ESAI

Received at EPA _________Oversight assigned _________Oversight rec'd by TM __________________Oversight complete . __________________Feedback given ' -Mailed to RPM _________ ? J^)

Attachment(s), check if applicable: cover memo ___ phone log ___ comments ___

~ cc: Patricia" J.--Krant2 — - — — -—• •- - ———- -— —• - ... -. •-.. . _......revised 08/88

Task #:_/£5V_ESAT DATA VALIDATION EVALUATION CHECKLIST

Case/SAS Ntaber; //VJfrf_____ Site Naae: Mid- Pi£ZD # :__2JL£±_L_L_________ Analysis Type: fu M

Techsical Quality

(i) WHO___________________ INTO. R2Q. DATE___________ 52ASGNA3L2VSS________________________ EErO. REC»D DATS__________ REQUEST (Y/N).phone log______

(2) ISO_______________________ INTO. SEQ. DATS___________ SZASONA3LSKHZ____________________ INTO. REC'D DATE__________ REQUEST (Y/N).phone log______

(3) WHO_____________________• INFO. REQ. DATE___________ REASON-ASLE 'WHT___________________ INFO. REC'D DATE__________ REQUEST (Y/N).phone.log_____

(4) WHO___________________ INFO. REQ. DATS______|_____ 3CASONA3LEWHY___________________ INFO. REC'D DATS__________ REQUEST (Y/N).phone log___"... •

TASrC MONITOR _ _ _ _ _ .....,__ ...____.. __SIGNATURE ____________________________. DATE

L IXFO. DELAY DAYS

TOTAL OVERS I GET DELAY DAIS _______ . • ' •

DAYS LATE ________•

ACTUAL t.a.t'. _______ Compliance with Schedule

Estimated Actual hourshours for spent onreview: _____ review: _____ ' Compliance with Budget

Management(optional)

OPTIONAL COMMENTS RELATING TO SCORES:

300550SECTION CHIEF ' . •-SIGNATURE -r~-~t —• • •' *-"-~- -^- '•••-—————"————i——'-DATE *——-*-"»-«.".•. --.•-.—.-«.»--«

revised 08/88

(») UNITED STATES ENVIRONMENTAL PROTECTION AGENCY. REGION n

S- __«i^ CENTRAL REGIONAL LABORATORY839 BESTGATE ROAD

ANNAPOUS. MARYLAND 21401(301) 2604180

DATE : .

SUBJECT: Region III CLP Data QA Review

FROM : Patricia J. Krantz (3ES23)cnief, Quality Assurance, Region III

TO : carla Dempsey (OS-230)QAO, AOB

Attached is a Region III CLP Data Review done by Weston reviewersunder the ESAT contract:

Case No.:

Sitename: Mid- fit !&*+>< (//Odd

Laboratory: T C M _________

Reviewer: 0 3 # 'J ' S f9. '

"R30055I

Attachment

cc: EPA Site RPMGareth Pearson, EMSL-LV .Regional DPO; C&AAfts S/*»cS_______ Region m \

ESAT PROJECT2568A RIVA RD., SUITE 300ANNAPOUS. MO 21401PHONE (301) 266-9887

MANAGERS \ ^ OeSeNERS/CONSULTANTS

DATE: May 15, 1989

SUBJECT: ORGANIC DATA VALIDATION FOR CASE 11488Site: Mid-Atlantic Wood

FROM: DON O'BRIEN SUDABEH ROWSHAN-KOLARORGANIC DATA REVIEWER SR. ORGANIC CHEMIST

TO: TERRY SIMPSONACTING ESAT DEPUTY PROJECT OFFICER

THRU: CHARLES MATKOVICH; ESAT TEAM MANAGER

OVERVIEW

Case 11488 consisted of four (4) water samples for volatile,semi-volatile and pesticide/PCB analyses. One trip blank wasincluded in the case, which was analyzed for volatiles only. Thesamples were analyzed as a Contract Laboratory Program (CLP)Routine Analytical Service (RAS) .

SUMMARY

All samples were successfully analyzed for all target compounds.All instrument and method sensitivities were according to theContract Laboratory Program (CLP) Routine Analytical Service(RAS) protocol.

MINOR

Several compounds failed precision criteria for initial and/orcontinuing calibrations. The quantitation limits werequalified "UJ" for the affected samples. (See Table 1 inAppendix F) .

The extractions of the semi-volatile and pesticide fractionsin all samples were performed one (1) day in excess of thetechnical holding time. The quantitation limits for thesesamples were qualified "UJ", and positive results werequalified "J".

of 2WX.KJ

NOTEi

o The maximum concentrations of all compounds found in the fieldor method blanks are listed below. All samples with theconcentrations of common laboratory contaminants less than tentimes (<10X) the blank level, or uncommon laboratorycontaminants less than five times (<5X) the blank level, havebeen qualified "B" on the data summary.

Compound Concentration fug/L)

acetone * 18chloroform 2

* common laboratory contaminant

o The reported tentatively identified compounds (TICs) ofAppendix D have been reviewed and corrected during datavalidation.

All data for Case 11488 were reviewed in accordance with theFunctional Guidelines for Evaluating Organic Analyses withModifications for use within Region III. The text of this reportaddresses only those problems affecting usability.

ATTACHMENTS

1) Appendix A - Glossary of Data Qualifiers2) Appendix B - Data Summary. These include:

(a) All positive results for target compoundswith qualifier codes where applicable.

(b) All unusable detection limits (qualified "R").3) Appendix C - Results as Reported by the Laboratory for All

Target Compounds4) Appendix D - Reviewed and Corrected Tentatively Identified

Compounds5) Appendix E - DPO Report for Contractual Compliance6) Appendix F - Support Documentation

Appendix A

Glossary of Data Qualifiers

^30055^

GLOSSARY OF DATA QUALIFIER CODES (ORGANIC)

CODES RELATING TjQ IDENTIFICATION(confidence concerning presence or absence of compounds):

U = Not detected. The associated number indicatesapproximate sample concentration necessary to bedetected.

(NO CODE) = Confirmed identification.

B * Not detected substantially above the level reportedin laboratory or field blanks.

R = Unreliable result. Analyte may or may not bepresent in the sample. Supporting data necessary toconfirm result.

N = Tentative identification. Consider present.Special methods may be needed to confirm itspresence or absence in future sampling efforts.

CODES RELATED 2P_ OUANTITATION 4fc\(can be used for both positive results and sample quantitation /limits) :

J = Analyte present. Reported value may not be accurateor precise.

K = Analyte present. Reported value may be biased high.Actual value is expected to be lower.

L = Analyte present. Reported value may be biased low.Actual value is expected to be higher.

UJ = Not detected, quantitation limit may be inaccurateor imprecise.

UL = Not detected, quantitation limit is probably higher.

OTHER CJ2JQES

Q =~ No analytical result.

ft

Appendix B

Data Summary Forms

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Appendix C

Results as Reported by the Laboratory" for All Target Compounds

. flR300563

1A ERA SAMPLE NO.VOLATILE ORSANICS ANALYSIS DATA SHEET

_ CY975;• _ab Name: ICM ' Contract: 6S-W8-0046 _____________

Lab Code: ICM Case No.: 11438 SAS No.: SDG No.: CY975

U-latrix: Csoi 1/water >. WATER Lab Sample ID:

rSample wt/vol: 5.0 Cg/mL) ML Lab File ID: A0859

Level: Clow/mecD LOW Date Received: 3/ 2/S9

j '. Moisture: not dec. 100. Date Analysed: 3/ 6/89

^Column: (pack/cap!) PACK Dilution Factor: 1.00

CONCENTRATION UNITS:CAS NO. COMPOUND <ug/L or ug/Kg) UG/L Q

""* -1 C"}"~* "

75-01-4 ——7=* »*. t~*. <••*75-09-2 ——67-64-1 ——75-15-0 ——75-35-4 ——— 'C1 *"! .1 •-*

S4O =;ci o\_V "T \_' wJ — • •_'

C "T — C C T

107-06-2 ——*? Q —. Ci T* —/ O ^O O

71-55-5 ——

108-05-4 ——7 •!'••"» <5— -Ll7— 4 ——7Q — Q"7 — =: _

10061-01-5 ——79-01-6 ——124-4S-1 ——79-00-5 ——71-43-2 ——

10061-02-6 ——TCT * g~ k75—25—2 ——

1 AQ 1 f\ 1 _«?O 1 ^Q C _

1 7 1 Q jl —T-Q 04 =r/ *-» f w

1 AD QD O _< (•if5_Q/-i -7_ __

1 (*>("> 41 4 ——X V V,' 1 i f

100-42-5 ——1 ooo— f*)— 7 _1 W W I J -»i. *,' /

———— Chl or omethane———— Br omomet han e———— Vinyl Chloride———— Chl or oethane

i i c: '^ i i / ._ e_ i i u. l— -r i _. '_' r j, LJ cr

———— Acetone- ——— Carbon Disul fide

f i u A '- n i '-' r '-' s v 1 1 s n e- ——— 1 , 1-Di chl oroethane- ——— 1 , 2- Die hi oroethene (total ) _— —— Chl or of or m——— 1 , 2-Di chl oroethane

__ _.' Ul U CX 1 i '-.' 1 1 C

———— 1 , 1 , 1-Tr i chl oroethane- ——— Carbon Tetrachl or ide———— Vinyl Acetate- ——— Bromodi chl or omethane———— 1 , 2-Di chloropropane- ——— cis-1 , 3-Dichloropropene ___———— Tr i chl oroethene———— Dibromochl ore-methane- ——— 1,1, 2-Tr i ch 1 or oethane

——— trans-1 , 3-Dichloropropene _— — Bromoform• ——— 4-Methyl-2-Pentanone• ——— 2-He.xanone• ——— Tetrachl oroethene• ——— 1 ,1,2, 2-Tetrachl oroethane _• — T-Toluene _ _ JB_p.A a.• ——— Chlorobenzene HTtJlJ• ——— Ethyl benzene——— Styrene

/^ Y _> €? 1 1 C? V ^ '«' \t CT\ _> J

10.10.10.10.6.S.5.5.5.5.5.5.10.5 .5 .10.5.5.5.5.5.5.5.5.5.10.10.5.5.

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1 1FORM I VOA ' 1/87 Rev.

rIB EPA SAMPLE NO.

SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

CY975Lab Name: ICM Contract: 63-W3-0046

; Lab Code: ICM Case No.: 11433 SAS No.: SDG No.: CY975

i-jMatrix: <soi 1 /water) WATER Lab Sample ID:

^Sample wt/vol: 1000.0 Cg/mL) ML Lab File ID: F0138

["Level: Clow/med) LOW Date Received: 3/ 2/89

'/. Moisture: not dec. 100. -dec. 0. Date Extracted: 3/ 8/89n••Extraction: C£epF/Cont/Scnc) SERF Date Analyzed: 4/ 6/89

-.GPC Cleanup: CY/N) N pH: 4.6 Dilution Factor: 1.00

CONCENTRATION UNITS:CAS NO. COMPOUND Cug/L or ug/Kg) UG/L D

f:Lr •

103-95-2111-4-^—4

.__ cr __ cr —» _ c?c- i -i •~"~v__ -f_j*~" _. / -j j.

106-46-7100-51-695-50-1y u — ^-r t_p — /

4 ••jO_j:, ;", _ *

— .-, J f- 4 T

^ -^ _ T •"' _ •*

co / <_• vj105-67-9c >=; o=; AO<J OO \J

111-91-1_ . u o o —120-32-191-20-3106-47-S

/ ™» ?• r*> **\

59-50-791-57-677-47-4OO '.'O _L

91-58-783-74-4

208-96-8606-20-2

—————— b i = C 2-Ch 1 or ost hy 1 ) et her— ———— 2— Thl or op hen ol—————— 1 , 3-Di chl or obenzene—————— 1 . ~-Di chl or obenzene——————— Benzvl alcohol—————— 1 , 2-Di ch 1 or obenzene—————— 2— Methvl shenol—————— '- i 3 (2— Chl cr oi socr opyl ') ether

IIIIIIlL;r":-Ju?; "-i~:zrc'pylamins""si ; j_ . _ i_ _ _ _i ij -. vi '_• u.1 e n *. n t?

—————— I soph or one—————— 2-tNi trophenol—————— 2, 4-Di methyl phenol— . . ,j?en_,i_>i>_ a>_ i Q—————— bi s <. 2— Uhl or oethoxy.) methane _—————— 2, 4-Di chlorochenol—————— 1 , 2, 4— Tr i chl or obenzene—————— Naohthal ene—————— 4— Ch I or oan i 1 i ne—————— Hexachl or obutadiene—————— 4-Chl or o-3-methyl phenol ___————— 2 -Methyl naphtha! ene—————— Kexachl or ocyc 1 opentadi ene _—————— 2, 4, 6— Tr ichlorophenol—————— 2, 4, 5— Tr ichlorophenol—————— 2— Chloronaphthal ene

.. ^ Nitroani line /|PQnr——————— Di methyl phthalate^Ji_?_U|j_5.^C—————— Acenaphthyl ene

-i',6 Di ni trotol uene

1 0 .10.1 0 .10.10.10.1 0 .10.1 0 .

10.10.10.10.50.10.10.10.10.1 0 .10.10.10.10.10.50.10.50.10.

' 10.10.

11

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FORM I SV-1 1/87 Rev.

1 01

1C EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

II

! CY375I ab Name: ICM Contract: S8-W8-0046 !

_._ Code: ICM Case No.: 11433 SAS No.: SDG No.: CY975

Matrix: Csoi1/water 3 WATER Lab Sample ID:

DSample wt/vol: 1000.0 Cg/mL> ML Lab File ID: F0133

Level: Qow/.-ned? LOW Date Received: 3/ 2/8'3

J/J Moisture: not dec. 100. dec. 0. Date Extracted: 3/ S/S9

— Extraction: CSepF/Cont/Sonc) SERF Date Analyzed: 4./ £/S9

GPC Cleanup: CY/N3 N pH: 4.S Dilution Factor: 1.00

CONCENTRATION UNITS:CAS NO. COMPOUND • Cug/L or'ug/Kg!' UG/L Q

O Q __ ("j 'Zj _-, •"

100-02-7132-5 -94 .•". 4 4 .4 •— ,j. .__. J. J. *~f -i_

S4-5S-2

S6-73-7

101-55-3•i 4 —j___ — T •• _ •*

37-36-585-01-8

* ••*! f "< 4/ •~>t "7

O .< T .* *-•OH1 /-T __

__,\.- L_« ' T*T v

129-00-085-6S-791-94-1er _- ercr iw C? -J -' O

. 4 Q /'\ 4. ,-_j

_i J. C3 VI -7

117-81-7117-84-0205-99-2207-08-950-32-8

1 QC* TO «T1 7O -1 3 wJG" *n -y /•* *io_v — /O o191-24-2

—————— 3-Ni tr oani line—— — — —Ac snasht !'"er, s—————— 2, --Dini trophenol—————— 4-Ni troohsnol_ _ _ _ _ _ _ ~\ »--._ — .- r,,^. -^«*-• J. w e : i . •_' T LI i dti

—————— 2, 4-Dini trotol-uehe • "ij* S T v i l V u. t^il '^. »C\J. CV W S

——— —— 4— Chl orophenyl — phenyl ether_

— . ———— -i-^itroanil ine—————— 4, £-Oinitrc.-2-T,ethyl phenol _—————— rJ-Mitro=cdi phenyl ami ne <i)~_------- 4-Eromophenyl -phenyl ether _—————— Hex ac h 1 or ob en z er, e—————— Pent ac h 1 or op h en o 1—————— Phenanthr ene—————— Anthracene—————— Di -n-b ut ylph thai ate—————— Fl uor anthene—————— pyr ene—————— Butyl benzyl ohthalate—————— 3, 3' -Di chi orobenzidine—————— Benzo (a) anthracene—————— Chrvsene—————— bis(2-Ethylhexyl)phthalate _—————— Di-n-octvlph thai ate—————— Benzo <b) f 1 uor anthene—————— BenzoCk) fluor anthene—————— Benzo (a) pyr ene—————— Indeno (1,2, 3-cd) pyrene., _———— . — Dibenz (a, h 3 anthracene K3-Q———— Benzo Cq, h, i Jperylene

50.10.50 .50.1 0 .

r • " :" 10.10.1 0 .1 0 .50 .50 .4 **\-> *_•' •

•* ''",J. '•-' •

1 0 .50.10.10.10.1 0 .10.10.20.10.10.10.10.10.10.10.10.

556 l°l

11

;u:u:u!U!U!U:u:u:u!U:u' i lI W

!U!U!U!USU:u

. !USL-ID;u:u!U:u!U!U!U!U!U!U!U11

(1) - Cannot be separated from diphenylamine


1 0 2-

ID EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET ______________

! CY375 JLab Name: ICM Contract: 68-W8-004S !_____________I

- Lab Code: ICM Case No.: 11488 SAS No.: SDG No.: CY975

Matrix: Csoi1/water> WATER Lab Sample ID:

i' Sample wt/vol: 1000. Cg/mL)ML Lab File ID: D0941

Level: Clow/med) LOW Date Received: 3/ 2/89

1 '/. Moisture: not dec. 100. dec. 0. Date Extracted: 3/ 8/89

•->. Extraction: CSepF/Cont/Sonc!) SEPF Date Analyzed: 3/20/89

' GPC Cleanup: CY/N3 N pH: 4.6 Dilution Factor: l.OO

CONCENTRATION DNITS:CAS NO. COMPOUND Cug/L or ug/Kg) UG/L Q

D

319-84-6 — -319-85-7 — -T 1 -a ac Qera OCj Q

76-44-8 — -

6O-57-1 — -72-55-9 — -

7'""' ^ -i O.—54 81 no 1 r\~! — p

7«~» A r*i c*._:— 43— 5 ——ww^ 3 r * v w

- i i r - i i - i — .r*/L-i~*—— al pha— BnCI—, 1-1 4- -i TJ L_t I~"

—— delta-BHC—— gamma— BHC (Lindane)—— Hept achl or—— Aldrin—— Heptachlor epoxide—— Endosul fan I—— Di eldr in—— 4. 4 '-DDE—— tndr i n—— Endosul fan II—— 4, 4 '-ODD—— Endosul fan sul fate—— 4, 4 '-DOT—— Methoxychlor—— Endrin ketone—— al pha-Chlordane

SOO 1-35-2 ———— toxaphene1 "t"C ~f J._ 1 1 _'~<__.- A — ._ - 1 .-.— < f\ < C

11141-16-5 — •W — J —— D •/ ^ X mi

1 •T'C.7-">_--.'Cl — C_ ._ ..

1-1 /*\&T ^0 1

M r i_"_ i '-' r - >.' _ o—— Ar oc 1 or - 1 22 1—— Ar odor -1232—— Ar oc 1 or - 1 242—— Ar oc 1 or - 1 248

1 1 096-82-5 ———— Ar oc 1 or - 1 260

; :.050 !U.050 !U. 050 ! U. 050 ! U. 050 : u.050 !U. 05O ! U. 050 ! U. 1 0 i U.10 ! U. 1 0 ! U.10 : u.10 ! U.10 ! U.10 :u.50 i U. 10 !U.50 !U.50 ! U1.0 !U.50 !U.50 !U. 50 ! U,.50 ! U.50 ! U1.0 !D1.0 !U

: i

*R30G567FORM I PEST 1/87 Rev^ ,i

1 8 2

r •1A EPA SAMPLE NO.

: VOLATILE ORGANICS ANALYSIS DATA SHEET| , ——————————————,

! CY97SName: ICM Contract: 68-W8-OO46 !_____________!

1 Lab Code: ICM Case No.: 11433 SAS No.: . SDG No.: CY975.

[""Matrix: C soil/water 3 WATER Lab Sample ID:USample wt/vol: 5.0 Cg/mL3 ML Lab File ID: A0876

[Level: Clow/med.') LOW Date Received: 3/ 2/89

7. Moisture: not dec. 100. Date Analyzed: 3/ 7/S9nf ii-Col umn: C pack /cap 3 PACK Dilution Factor: 1. OO

CONCENTRATION UNITS:CAS NO.' COMPOUND Cug/L or ug/Kg) UG/L Q

1

74-S7-3-"T .< f *~\ r-l.' -T Ow _— cr f\ < _ .</ W V i *T

— =;— I'ti'i— o75-09-2-67-64-1-"" ~ c* 1 cr f'\/ 5— 15— cj—/ %_• W I-/ S-

75—34—3—54Q-59-O-C' /' ~ t_> C- "~" •__• "~

— • 4 C"CT ^

--,. ..-,.., ^\_H__1 __.-_* i_*

108-05-4-~7t=i—~*~7 4/ W ii^ / t

-7Q_O"7_=' _/ a— H / .j —10061-01-5-

79-01-6-X •_,"•? lirD X

/ I? l J *.J O71—4^ •'•—/ X r *— * ^v

10061-02-6-75-25-2-

1 AQ— 1 A 1 —X VO— X U Xj y x / o oX i./ X D •*71.) 04 =;/ j w/'-r j

1 AQ — QQ T>X UO C5_3 O

1OS-90-7-100-41-4-100-42-5-

1 T"T>A — T'A 7X dCil-'— iV /

————— Chl or omethane————— Br omomet hane————— Vinvl Chloride

U- n _ >-! r '-' & u 1 1 o n s———— Methyl ene Lhloride————— Acetone————— Carbon Disulfide————— 1 , i-Di chl oroethene————— 1 , 1 -Di chl oroethane—————— 1 , 2-Di chl oroethene (total 3 _————— Ch Icr o f or .n————— 1 , 2-Di .-hi ,-r i-.>=th<?ns

*_ _.• ui v e^i i <— -i J cr

————— 1, 1, 1— Tr i chl or oethane————— Carbon Tetrachl or i de————— Vinyl Acetate————— Br omodi chl or omethane————— 1 , 2-Di ch lor op r op an e————— ci s-1 , 3-Dichl or op r op ene ___————— Tr ichl oroethene————— Di bromochl oromethane————— 1 , 1 . 2-Tr i chl or oethane————— Benzene————— trans-1 , 3-Di chl oropropene _————— Br omo for m————— 4-Methyl-2-Pentanone————— 2-Hexanone————— Tetrachl oroethene————— 1, 1,2, 2-Tetrachl oroethane _————— Tol uene————— Chl or obenzene _fl P Q D nv - — ... .,,_t.|,.(..y ,1.1————— Ethylbenzene v————— Styr ene————— Xylene (total)

10.1 0 .10.10.cr!_> *

/-*.-,

5.5.crw •cr

cr-

10.er

5.10.C~v_» *

5.5.5.5.5.5.5 .5.10.10.5.5.

563 1:5.5.

1t

!U!U:u;u:u:Bi J!U!U:u:u:u:u:u!U!U!U!U:u:u!U:u!U,'U!U:u!U!U!U!U!UIU!U:u11

FORM I VOA 1/87 Rev.1 9

rIB EPA SAMPLE NO.

SEMI VOLATILE ORGAN I CS ANALYSIS DATA SHEET _____-

I CY976Lab Name: ICM Contract: 6S-W8-OO46 !

. Lab Code: ICM Case No.: 11438 SAS No.: SD6 No.: CY975

rrlatrix: (soi 1 /water 3 WATER Lab Sample ID:

Sample wt/vol: 1000.0 Cg/mL3 ML Lab File ID: F0139

["Level : Clow/med3 LOW . Date Received: 3/ 2/89

7.. Moisture: not dec. 100. 'dec. 0. Date Extracted: 3/ 8/S9r*~*I

' "Extraction: (SepF/Cont/3onc3 SERF Date Analyzed: 4/ 6/89

GPC Cleanup: CY/N3 N pH: 4.1 Dilution Factor: 1.00

1 CONCENTRATION UNITS:CAS NO. COMPOUND Cug/L or uc/Kg) UG/L Q

i

C

_J

!J

i v 0 r <_' —1* ^ ,-« .* •»j_ A— -r~ — -- ——— — —

^ .* 4 ~T^ 4

106-46-7 ———100-51-6 -——95-50-1 —— -;? tj •-!•!_< J

103-60-rl ———106-44-5 --—

—— Phenol—— b i s C2— Ch 1 or oet hy 1 3 et her ___—— 2— Ch 1 or ophenol—— 1 . 3-Di chl or obenzene—— 1 . --Di chl or obenzene—— rienzvl alcohol—— 1 , 2-Di chl or obenzene—— 2-Methyl phenol—— bi s (2— Chl oroi scpr opyl 3 ether—— 4— Methyl phenol

E 2 1-64-7 —————— N-Ni tr oso-di -r,-propyi amine _£7-72-1 —————— HcrX-BC .-i 1 or oet ha.ne.-. .-3 •— i c- "2 U.- 5 w> — /

TO ="Cj 1 _/ w J - X —

83-75-5 ———105-67-9 ———65-85-0 — —111-91-1 ———

120-32-1 ——— :

106-47-S ———O"7 *" <"» ^O / OO wJ

59-50-7 ———91-57-6 ———/ / T- / ^

95-95-4 ———

88-74-4 ———1 •? 1 11 *? —208-96-S ———CAC ""'A •">

—— N i t r ob enz en e—— I s op h or on e—— 2-Ni tr ophenol—— 2, 4-Di methyl phenol—— Benzoic acid—— bi s <!2— Chl or oethoxy 3 methane _—— 2, 4-Di chl or ophenol—— 1 , 2, 4— Tr i chl or obenzene—— Naphtha! ene—— 4-Chloroani 1 ine- — Hexachl orobutadi ene—— 4-Chl or o-3-methyl phenol ___—— 2-Methyl naphthal ene—— Hexachlorocyclopentadi ene _—— 2, 4, 6-Tr i chl orophenol—— 2, 4, 5— Tr ichlorophenol—— 2-Chloronaphthalene—— 2-Ni t r oan i 1 i n e __ fl R"3 Q~Q $ g'f1—— Dimethylphthalate •—— Acenaphthylene—— 2, £-Di nitre-toluene

10.1 0 .1 0 .10.10.10.10.10.1 0 .10.10.1 0 .10.1 0 .10.10.50.10.10.10.10.10.10.10.10.10.10.50.10.

S 50.' 10.

10.10.

1t

:u:ut 1 11 1—':uiU!U:u:u!U!U!UID!D:u! U!U!U:u!U!U!U!UID:u;D!U!D:uID!UIDIDID•i

FORM I SV-1 1/87 Rev.1 0 9

! 1C EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET __ __ __ _

I " ~ " "l. ! CY976 !

1 ^»p Name: ICM Contract: SS-W8-OO46 !______________f

• Hro Code: ICM Case No.: 11483 SAS No.: SDG No. s CY975

Matrix: (soil/water) WATER Lab Sample ID:

Msample wt/vol: 1000.0 (g/mL3 ML Lab File ID: F0139

Level: (Iow/med3 LOW Date Received: 3/ 2/S9

U% Moisture: not dec. 100. dec. 0. Date Extracted: 3/ 8/89

[""Extraction: (SepF/Cont/Sonc 3 SERF Date Analyzed: 4/ S/39

"GPC Cleanup: CY/N) N pH: 4.1 Dilution Factor: 1.00

CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q

i^

99—09—2 ——————— 3-Ni troani line

51-23-5 —————— 2,-J— Dinitroohenol100-02-7 —————— •-•- Nitrochenol132- 4-9 —————— Dibi=nzofuran121 — 14—2 —————— 2, 4-Di ni tr otol uene34-66-2 —————— Diethvlph thai ate

70O5-72-3 —————— 4-Chl or ophenyi -phenyl ether _3S-73-7 —————— Fluor ene

1 OO-0 1 -S —————— •-•- Ni t r oar, i 1 i ne324-32-1 —————— -, £-Dini tr o-2-methyl phenol _E5-30— 5 —————— N-Nii tr osoci phenyl ami ne (13 _

1 0 1 —53— 3— — — — — — "— sr omopheny 1 —phenyl et her1 19-74-1 —————— Hexachlorobenzene37-36-5 —————— Pen tac hi or ophenol85-01-3 —————— Phenanthrene120-12-7 —————— Anthracene34-74-2 —————— Di-n-butylphthalate2O6-44-O —————— Fluor anthene1 29-OO-0 —————— Pyr en e35-63-7 —————— Butyl benzylph thai ate9 1 -94- 1 —————— 3 , 3 ' -Di c h 1 or obenz i dine36-55— 3 —————— Benzo (a3 anthracene213-0 1 -9 —————— Chr ysene117-31-7 —————— bis<2-Ethylhexyl)phthalate _117-84-0 —————— Di-n-octylphthalate205-99-2 —————— Benzo (b) fl uor anthene207-08-9 —————— Benzo (k) fl uor anthene50-32-3 —————— Benzo (a) pyr ene193-39-5 —————— Indeno (1,2, 3-cd)pyrene _ ._53-70-3 ———— ' — Dibenz <a, h) anthracene _ 9~-LJ191-24-2 —————— BenzoCq, h, i )peryl ene

50.10.50.50.10.10.1 0 .10.10.50 .50 .10.1 0 .1 0 .50.10.1 0 .10.10.10.10.20 .10.10.10.10.10.10.10.10.

00570 £

t

iUIDID:u:u!U:uID:uID!U ,I L'IDIDIDIDID!U!UID:uIUID,'UIDID!DIDIDIDIDIDI I

(1) — Cannot be separated from diphenylamine


1 1 0

r

ID EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET ___ _

I " JI CY976 J

Lab Name: ICM Contract: S8-W8-0046 S

.' Lab Code: ICM Case No.: 11488 SAS No.: SDG No.: CY975L


M Sample wt/vol: 1000. Cg/mL)ML Lab File ID: D0946

Level: (low/med) LOW Date Received: 3/ 2/89

LJ% Moisture: not dec.100. dec. 0. Date Extracted: 3/ 8/89

f~ Extraction: CSepF/Cont/Sonc3 SEPF Date Analyzed: 3/21/89

' GPC Cleanup: CY/N3 N pH: 4.1 Dilution Factor: 1.00

CONCENTRATION UNITS:- CAS NO. COMPOUND <ug/L or ug/Kg) UG/L Q 1

D

o i y OH- o0 1 *rj O c", ~7

wJO O 3 3

76-44-8 — -

1024-57-3 — -

6O-57-1 — -— _j_j ~

•_> wj .». X hj C/ *J *,72-54-3 — -

1A O 1 t~\ "7 QU«I> X V / O

7T-- 4*5 S— -f ^_ i *_ < ^/53494-70-5 — -•SSIAO 71— QCT4AO 7«t — O _____%J X <J*J / *T __

12674-11-2 — -11104-28-2 — -11141-16-5 — -BT'-\ -1 £*i__t__ *—.< _.O _.

1 •C.~7*"l> *~*O C

11097-69-1 — -11096-82-5 — -

—— alpha-BHCt_ 4_ _^ r*/t j,— *

,-J t 1 i. _ C* LJ i-'

—— gamma— BHC (Lindane3—— Hep t ac h 1 or—— Al dr i n—— Heptachlor epoxide—— Endosul fan I—— Dieldr in—— 4, 4 '-DDE—— Endr in—— Endosul fan II- — 4,4'-DDD—— Endosul fan sul fate

^ , *T U LJ 1

—— Met ho xyc hi or—— Endrin ketone—— al pha-Chl or dane—— gamma-Ch 1 or dane—— toxaphene—— Aroclor-1016—— Aroc lor -1221—— Ar oc 1 or - 1 232- — Aroclor-1242* A v _-i .- T i-iv *- 1 OM Qr\r w*- A Or JL .-ro

rnr OC JL Or i u*r- — Aroc lor -1260

.050

.050

. 050

.050, 050.050. 050. 050. 10. 10. 1O. 10. 10. 10. 10.50. 10.50.501.0.50.50.50.50.50l.O1.0

: ::u!U!U!U:u!U!U:u!U!U;u!U!U!U!UIDIDIDIDIDIDIDIDIDIDIDIDii

AR30057IFORM I PEST 1/87 Rev.

1 8 7

il^N

1A EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET

CY977lame: ICM Contract: 6S-W8-0046 I

.ab Code: ICM Case No.: 11488 SAS No.: SDG No.: CY975

Matrix: (soil/water 3 WATER Lab Sample ID:

Sample wt/vol: 5.0 (g/mL) ML Lab File ID: A0877

-evel: Clow/med) LOW Date Received: 3/ 2/89

•'. 'Moisture: not dec. 100. Date Analyzed: 3/ 7/89

ol Limn: (pac k /c ap 3 PACK Di 1 ut i on Fac t or: 1. 00

CONCENTRATION UNITS:CAS NO.' COMPOUND (ug/L or ug/Kg) UG/L Q

74 go Q75-01-4 —75-00-3 —/ wi O 3 —57-64- 1 —75-15-0 —75-35-4 —75-34-3 —540-39-0 —£— C C T'

107-06-2 —

71-55-S —

103-O5-4 —75-27-4 —"7Q O"7 er

10061-01-5 —79-01-6 —

. 124-43-1 —/ 5 UU o

10061-02-6 —

108-10-1 —*?ci 1 -70 e

79-34-5 —

1 A Q OA "7 —

100-41-4 —100-42-5 —1330-20-7 —

———— Chl or omethane———— 3r omomethane———— Vinvl Chloride———— Chl oroethane———— Methvlene Chloride

———— Carbon Bisulfide———— 1 , 1-Di chl oroethene———— 1, 1-Dichl or oethane———— 1 , 2-Di chl oroethene (total ) _

i~*-i« * _ ,_- — J: •. .— — .

——— i , 2-Di chl oroethane———— 2— But an one———— 1 , 1 , 1-Tr i chl oroethane———— Carbon Tetrachl or i de————— Vinyl Acetate———— Br omod i c h 1 or omet hane———— 1 , 2-Dichloropropane———— cis-1, 3-Dichloropropene ___———— Tri chl oroethene———— Di br omochl or omethane———— 1 , 1 . 2-Tr i chl or oethane

-_• -: 1 i «_> f 1 i tr

———— trans-l , 3-Di chl or opropene _———— Bromoform———— 4-Methyl-2-Pentanone———— 2-Hexanone———— Tetrachl oroethene———— 1, 1 , 2, 2-Tetrachloroethane _———— Toluene—— --Chl or obenzene . JD o r> .-. -^———— Ethylbenzene ""^UU^y———— Styrene———— Xylene (total)

10.10.10.10.5.3.10.=•cri-i .5.5.5.10.5.5.10.5.5.5.5.5.5.5 .5.5.10.10.5.5.5.5.

2 5--— •

iID!USUID!U!BJ11

:uIDID!U:uiUIDIDIDiUIDIDIDID!U!U!UiUIDIDIDIDIDIDIDID! J

FORM I VGA _ 1/87 Rev.2 7

13 ERA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET _______________

! ' I CY977 ILab Name: ICM Contract: 68-W8-OO46 !_____________!


pMatrix: (soil/water 3 WATER. Lab Sample ID:

Sample wt/vol: 1000.0 (g/mL3 ML Lab File ID: F013O

["Level : (Iow/med3 LOW Date Received: 3/ 2/89

'/. Moisture: not dec. 100. dec. 0. Date Extracted: 3/ 8/89j

"Extraction: (SepF/Cont/Sonc3 SERF Date Analyzed: 4/ 5/89

—GPC Cleanup: CY/N) N pH: 3.S Dilution Factor: 1.00

- CONCENTRATION UNITS:CAS NO. COMPOUND Cug/L or ug/Kg) UG/L Q

103-93-2111-44-495-57-S

E1 « •) — 7 ~". -twM- 1 / O

106-46-7100-51-695-50— 1— W " W f

J ,".. l „ £ ••, _ '.

r— —"-•

/ C? W * A

wO / w w

105-67-965-85-0111-91-1120-83-2120-32-191-20-3106-47-88-7 a a o/ DO Cr

59-50-791-57-6/ / ^ / *T

OO AC •""»

G=;_Cier 4.~/<-j -r *»j iy x %jo /DO 7.4 .4OH / *r *»

1O 1 11 OO X — X 1 O208-96-8CAC_"~.-A 'ow'b jiw,'

—————— Phenol—————— b i s ( 2-Ch 1 or oet hy 1 3 et her ___——————— 2— Ch 1 or ophenol

^ . \— • LJ *, i— i t j. '— ' '— ' l— ' c> i i c> i i cr

—————— 1 , 4-Di chl or obenzene—————— r'enzvl alcohol—————— 1 , 2-Di chl or obenzene—————— 2-iv1ethyl pher.oi—————— z i. = /2-Chl or oi sop ropy 1 3 ether

. J. M = •)- L, , , t ,-, I- — — .- . 1

—————— X-:-ii t rose— di — n— pr opyl ami ne _———— - — Hex .3 chl or o=t han<=—————— Ni troSenzene—— ——— I soohor one—————— 2-Ni tr ophenol—————— 2, 4-Di methyl phenol—————— Benzoic acid—————— bi s ( 2-Ch lor oet hoxy 3 methane _—————— 2, 4-Di chl or ophenol—————— 1 , 2, 4-Tri chl or obenzene—————— Nashthal ene—————— 4-Chxoroani 1 ine—————— Hexachlorobutadi ene—————— 4-Chl or o-3-methyl phenol ___—————— 2-Methyl naphthalene—————— Hexachl or ocyc 1 opentadi ene _—————— 2,4, 6— Tr i chl or ophenol—————— 2 . 4 , 5— Tr i c h 1 or ophenol—————— 2-Chloronaohthalene———— , — 2-Ni troani line _______ *-o-->-r———— --Di methyl phthal ate ATTJi—————— Acenaphthylene—————— 2, 6-Di ni t rotol uene

10.10.10.10.10.10.10.1 0 .4 ,'~

1 ''"> .1 f™'

1 0 .1 0 .1 0 .10.10.50.10.10.10.10.10.10.10.10.10.10.50.10.50.

0573 10.10.10.

ft

ID!U:uIDIDIUIUIDID:u1 I 11 '—'

:uIU!UID:uIDIDIDID!UIDIDIDIDIDIDIDIDIDIDIDID11

FORM I SV-1 1/87 Rev

1 1 7

EPA SAMPLE NO.ri 1C

SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

' Lab Name: ICM Contract: S8-W8-OO46

Code: ICM Case No.: 11433 SAS No.: SDG No.: CY975


Sample wt/vol: 1000.0 (g/mL3 ML Lab File ID: F0130


"/. Moisture: not dec. 100. dec. 0. Date Extracted: 3/ 8/89

Extraction: (SepF/Cont/Sonc3 SEPF Date Analyzed: 4/ 5/39

GPC Cleanup: CY/N3 N pH: 5.3 Dilution Factor: 1.00

CONCENTRATION UNITS:CAS NO. COMPOUND Cug/L or ug/Kg) UG/L Q

D

1

99-09-2 ——O T> _ T1 •"' _ C) _ _ _

100—02—7 — — —1 32—54—9 — — —1 •"> 1 1 j. •'••34-56-2 ——

100-01-S ——324-32-1 ——

101-33-2 ——113-74-1 ——37-35-5 ——Q nr /-, aC vJ U J. U

120-12-7 ——O*T / *"T .__.

206-44-0 ——129-00-0 ——OCT C Q T

91-94-1 ——ET £ CTCr ~1v. '—• <—' _J -_J

•~l 4 O !*"> 1 '*"'

117-31-7 ——117-84-0 ——•7'A=% oo -f _«.IJ J ../ .7 _.

207-08-9 ——=" t~\ '-i n

x i? *j *j y «->^O TA OOO /U O —

1 O 1 • 'il_'~'_ _.

——— 3-Ni t r oani line——— Ac er.ao h t h en e——— 2, 4-Di ni tr och<=nol——— 4-Ni tr ophenol——— Dibenzofuran——— 2, 4-Di ni trotol uene——— Di s^hyl ph thai ate——— 4-Chl or op hen y I -phenyl ether _——— Fl Ltor ene_ _ _ — ^1 _ N ' - •*- -v — — — . -j i— _

— — — — , E— Dinitro— 2— met hvl chenol——— /J-Ni trcscdi phenyl amine (1 3 _——— 4-=r cmophenyi -phenyl ether _——— Hex ac h 1 or obsn z an e——— Per, t ac h 1 or ophenol——— Phenanthr ene——— An t hr ac ene——— Di-n-bLitylphthal ate——— Fluor anthene——— Pyr sne——— Butyl benzyl phthal ate— — 3,3' — D i c h 1 or ob «n z i d i n e——— Benzo (a 3 anthracene——— Chrysene——— bis(2-Ethylhexyl 3 phthal ate _——— Di -n-oc tyl phthal ate——— Benzo (b) fl uor anthene——— Benzo (k) fl uor anthene——— Benzo (a 3 pyr ene——— Indeno(l,2, 3-cd)pyrene——— Di benz (a,h) anthracene— "i — Benzo (q, h, i 3 per yl ene j

rl i

50 .10.5O .50 .10.10.1 0 .10.1 0 -50 .50 .1 0 .10.10.50.10.10.10.1 0 .10.10.20 .10.10.12.10.10.10.10.10.10.

R300571?-

11

IDIUIUID!UID!D!DIDIDl l il '— /

IU -IU!UIDID!U!UIUIDIDIDIDIDiIDIDIDIDIDIDID1f

(i) — Cannot be separated from diphenylamine


1 1 8

ID EPA SAMPLE NO.PESTICIDE ORGANICS ANALYSIS DATA SHEET ___ _

Ij I CY377• Lab Name: ICM Contract: S8-WS-OO46 I__

I.Lab Code: ICM Case No.: 11488 SAS No.: SDG No.: CY975


j~J Sample wt/vol: 1000. (g/mL)ML Lab File ID: D0942


[]'/. Moisture: not dec. 100. dec. 0. Date Extracted: 3/ 8/89

!-: Extraction: (SepF/Cont/Sonc3 SEPF Date Analyzed: 3/2O/89: •/GPC Cleanup: (Y/N3 N pH: 5.8 Dilution Factor: 1.00

~~ CONCENTRATION UNITS:CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q

O 1 w O*+ O319-85-7 ———^1O Q C. Qox y oo o

•7C-J.il Q _

1 A">il ."7 O

60-57-1 ———7'~.' =" =; Q/ — — '-' o

^~>--i « *— t i- C1 Oww.£-x*^ o*j y*L. wJ-T O

*j*.' 4. y j7O J.O cr- H-O *J

-alpha-BHC(-. r-, 4- -. C1 LJ !-"•

-delta-BHC-gamma-BHC (Lindane)— Heptachl or-Aldr in-Heptachl or ep oxide—Endosul fan I-Di eldr i n4 4' DHFF f /l lw

-Endr i n-Endosul fan II-4, 4' -ODD-Endosul fan sul fate

t f JL/i 1

— Methoxychl or

5103-71-9 ———— alpha-Chlordane«JXV.J^J /••+ .DAA 1 — 0*% — O —

11 1 A *1 -""lO >

11141-16-5 ———<=:o.ieo 01 o— — __4 fc. "7 "- * O C.

-Toxaphene-Aroclor-1016-Aroc lor -1221-Aroclor-1232n i w <« 4> *— • * A -&. — L*,

1 1 097-69- 1 ———— Ar oc 1 or - 1 2541 1 096-82-5 ———— Ar oc 1 or - 1 260

.050

.050

.050

.050

. 050

.050

. 050

.050. 10. 10. 10. 10. 10. 10. 10.50. 10.50.501.0.50.50.50.50.50l.O1.0

I

1

ID!UID!UIDIU:u:uID!U:u:uIUID:uIDIDIDIDIDIDIDIDIDID:u i:u ii I

AR300575

FORM I PEST 1/87 Rev.

192

1A EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET ______________

CY978iName: ICM Contract: 68-W8-0046 ____________.

; uab Code: ICM Case No.: 11488 SAS No.: SDG No.: CY975

Hlatrix: (soil/water) WATER Lab Sample ID:

Sample wt/vol: 5.0 (g/mL) ML Lab File ID: AOS78

[Juevel : (low/med) LOW Date Received: 3/ 2/89

_% Moisture: not dec. 10O. Date Analyzed: 3/ 7/89

"olumn: (pack/cap3 PACK Dilution Factor: 1.00

CONCENTRATION UNITS:CAS NO.' , COMPOUND (ug/L or ug/Kg) UG/L Q

74-37-3 ——————

•7="— O 1 4/ W •-' J, 1

7~ ,--% /-i <-\

~T~r ,'*vO •*"'

67-64-1 ——————T*":-- «. ~r_.--*cr -?cr _ .•* ____ _, __t — ,__f_j — *-*. — — — — — —T-T — i ,-t *-*/ _> "~ .2 *r "•" >1 "~ ——— — ——

/ L_flw •_/

107-05-2 ——————T r~ Q *-> «— i

71-55-6 —————56-23-5 — — —103-05-4 —————7S— 7 4 — —"7Q — Q~7 =" —

10061-01-5 —————

1^™« -1 -1O 1•*-•-*• "-rO A •—-•"

79-00-5 —————

1 006 1 -02-6- —— —75 ••'5 •"*— —/ te' rfMW^ A.

108-10-1 —————^Ql— 7O— C— —

1 AQ— OO— O_____XVO OO""'fcj"""™"~ — 1 AO — OA "^

100-41-4 ———— -L100-42-5 —————

1 1 O"?A_OA "7

— Ch 1 or omet hane-Bromome thane

V JL 1 t jf j. •— •( 1 .L '— t A Ul

—Chl oroethane—Methyl ene Chloride

'_ _? v '— ' 1 I *™

—Carbon Disulfide-1 , 1-Di chl oroethene—1, 1-Di chl or oethane-1, 2-Di chl oroethene (total 3 _

•_• 1 1 i '_' r >_! j '_• r iTl-1 , 2-2ichloroethane-2-Butanone-1,1,1 -Tr i c h 1 or oet hane—Carbon Tetrachl or i de-Vinyl Acetate— Br omod i c h 1 or omet h an e— 1 , 2-Di chl or opr opane— ci s-1 , 3— Di chl or opropene ___-Tri chl oroethene— Di bromochl or omethane-1,1, 2-Tr i chl or oet haneBenzene-trans-1 , 3-Di chl or opropene _— Br omof orm-4-Methyl -2-Pentanone-2-Hexanone

J Gwr«L_fi.LQrL,'Guritrrie

-1 f 1 , 2, 2-Tetrachloroethane _i c* i u* e n cr

-Chlorobenzene _ ___ , D-Ethyl benzene HnjJjQ-Styrene _-Xylene (total 3

10.10.10.10.5.

1 0 .5.cr

—J •

5.1 0 -5.,_; .

1 0 .5.5 .5.5.5.5.5 .5.5.10.10.5.5.5.

)76 ="•5.5.

FORM I VOA- 36

11

!UIUIU!UIUIUIU!UIUIU: j:u!U!UIU!U:uID:uID;iuID!U:uIUIDIDIDID,'DIDIDIDID!

1/87

Appendix D

Reviewed and CorrectedTentatively Identified Compounds

IE EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET _ _TENTATIVELY IDENTIFIED COMPODNDS I

\ CY975Name: ICM Contract: S3-WS-0046 !—_——.———— ._—___

''Lab Code: ICM Case No.: 11483 SAS No.: SDG No.: CY975

Hlatrix: (soil/water!) WATER Lab Sample ID:

Sample wt/vol : 5.0 (g/mL> ML Lab File ID: A0859*jLevel: (low/med) LOW Date Received: 3/ 2/89

!-?/. "Moisture: not dec. 100. Date Analyzed: 3/ S/S9

•Column: Cpack/cap3 PACK Dilution Factor: 1.00

CONCENTRATION UNITS:_ Number TICs found: 0 (ug/L or ug/Kg3 UG/L ,

CA5 NUMBER

1.v_ 9

W •

4.5.

-- -- --B •

^ ^ f

3.9.

1 0 .11.12.13.14.15.16.17.IS.19.20 .21.•—>•"»-U-- *

23.24.25.26.27.28.29.''O.—————— ———

COMPOUND NAME RT

::?K2D

EST. CONC.

•

SS.7D _ ._W^. —>-/. Q--" ---••• ——

'Q

FORM I VOA-TIC 1/87 Rev.

i IF ERA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

TENTATIVELY IDENTIFIED COMPOUNDSCY975

Lab Name: ICM Contract: S3-WS-0046

Lab Code: ICM Case No.: 11488 SAS No.: SDG No.: CY975iMatrix: (sc.il/water3 WATER Lab Sample ID:

Hsample wt/vol: 1000.O (g/mL3 ML Lab File ID: F0133

Level: (Iow/med3 LOW Date Received: 3/ 2/89nL.:: Moisture: not dec. 100. dec. 0. Date Extracted: 3/ 8/89

fExtraction: (SepF/Cont/Sonc3 SERF Date Analyzed: 4/ 6/89

GFC Cleanup: (Y/N3 N pH: 4.6 Dilution Factor: 1.00

CONCENTRATION UNITS:- Number TICs found: 1 (ug/L or ug/Kg) L'G/L

C

c

CA3 NUMBER

1. 105-50-2.-,—

4.cr

6.-_8.o_

1 C .•1 -r

•* •"".'

13.14.15-16.17.13.19.20 .•".•122 .•"V*?

24.25.26.27.23.29.30.

I1

COMPOUND NAME

Capr ol act am

-

RT

13.73

1

! H7TOUt1

EST. CONC.

55Z2

Q

T

1

I _J

FORM I SV-TIC 1/87 Rev.

103

IE EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEETTENTATIVELY IDENTIFIED COMPOUNDS

CY976ICM Contract: 68-W8-OO46


ix: (soil/water 3 WATER Lab Sample ID:

':le wt/vol: • 5.0 (g/mL3 ML Lab File ID: A0876

'al: (low/med) LOW Date Received: 3/ 2/89

oisture: not dec. 10O. Date Analyzed: 3/ 7/89

umn: (pack/cap) PACK. Dilution Factor: 1.00

CONCENTRATION UNITS:Limber TICs found: 0 (ug/L or ug/Kg) UG/L

1 CAS NUMBER

h: ::::::::::::• — - -1 3.1 4-1 **V - -77S.9.1O.11.4 »~>A, *. •

13., 14.15.16.17.18.19.20 .21.22.23.24.25.26.27.28.29.

••""i.

COMPOUND NAME

1

V

RT E3T. CONC.

'

1

C

FORM I VOA-TIC -. 1/37 Rev.

20

IF EPA SAMPLE NO,SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

TENTATIVELY IDENTIFIED COMPOUNDS ICY976 !

Lab Name: ICM Contract: 6S-W8-0046 ___________



[Sample wt/vol: 1000.0 (g/mL3 ML Lab File ID: F0139

Level: (Iow/med3 LOW Date Received: 3/ 2/89

JV. Moisture: not dec. 100. dec. 0. Date Extracted: 3/ 8/89

"Extraction: (SepF/Cont/Sonc3 SEPF Date Analyzed: 4/ 6/89

QPC Cleanup: (Y/N3 N pH: 4.1 Dilution Factor: 1.00

CONCENTRATION UNITS:— Number TICs found: 1 (ug/L or ug/Kg3 UG/L

[{

nL

r

L

D

CAS NUMBER

4 1 i'\ cr £ ,-' •->»JL • J. V -V ~~ '—1 l-- --

•-,

3.4.C*_J •

6.7.E.o

"• '••''• .1 1.1 _ .1 '"I

13.14.15.16.17.13.19.20..", 4^~ *

jj. f

23.24.25.26.27.28.29.30.

COMPOUND NAME

Caprol act am

RT

1 "7°AW- / U.'

•>

*

— frfr3-Q

EST. CONC.

30.

j_5J*Ll

Q

J

~~ (

.

— "A


1 1 1

IE EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET __ ___________TENTATIVELY IDENTIFIED COMPOUNDS

CY377Name: ICM Contract: 6S-W8-OO46

.ab Code: ICM Case No.: 11488 SAS No.: SDG No.:: CY975iMatrix: (soil/water3 WATER Lab Sample ID:

Lsample wt/vol : ,- 5.0 (g/mL) ML Lab File ID: A0877

evel: (low/med) LOW Date Received: 3/ 2/89

7. Moisture: not dec. 100. Date Analyzed: 3/ 7/89n•••Column: (pack/cap3 PACK Dilution Factor: l.OO

CONCENTRATION UNITS:Number TICs found: 0 (ug/L or ug/Kg) UG/L

! CAS NUMBER

' ; i.i _-. •

3.4.

. e;1 w «

~: &.j ~ ,! 3.'. 9.1 1 0 .; 11.; 12.13.

; 14.! 15.

-; 16..: 17.~i is.

I 19."; 20 ., 21.1 •— 1 '-.1 ___- -

""" '_^ta«r 1*

_: 24.I 25.

-I 26.. 27.

— ; 28.• 29.: 30 .

COMPOUND NAME

„_,

--. «.—.-_, — — — . •. ,_._-.____

•*» —-

RT

-i<Lt

EST. CONC.

—

)jT]LrfC

Q i

'


28

i IF EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

TENTATIVELY IDENTIFIED COMPOUNDSCY977

Lab Name: ICM Contract: S3-WS-0046

," Lab Code: ICM Case No.: 11488 SAS No.: SDG No.: CY975\Matrix: (soil/water) WATER Lab Sample ID:

["Sample wt/vol: 1000.0 Cg/mL) ML Lab File ID: F013O

Level: (low/med) LOW Date Received: 3/ 2/89nl//. Moisture: not dec. 100. dec. 0. Date Extracted: 3/ 8/89

("Extraction: (SepF/Cont/Sonc3 SEPF Date Analyzed: 4/ 5/89

"GPC Cleanup: (Y/N) N pH: 5.3 Dilution Factor: 1.00

'. . CONCENTRATION UNITS::- Number TICs found: 1 (uq/L or uq/Kq) U6/L

L.

/

CAS NUMBER

1. , 105-5O-2*"!'

*•— ,w •.4*T m

trwJ •

S.7.3."-<

4 .-.

11.12.13.14.15.16.17.13.19.20. •.— , 4

+-:-———— •

•,———

Ikll •

24.25.26.27.28.29.30.

COMPOUND NAME

Caprol act am

—

RT

1 T> ~r*~I O . / w

EST. CONC.

10.

/Lfi_lon.E_3.2__

Q

J

_

I!i

__.__(*FORM I SV-TIC 1/87 Rev.

1 1 9

-iIE EPA SAMPLE NO.

VOLATILE ORGANICS ANALYSIS DATA SHEET _TENTATIVELY IDENTIFIED COMPOUNDS ! ~~ 5

: CY978 :Name: ICM Contract: 68-W8-OO4S !_____________I


Matrix: (soi1/water 3 WATER Lab Sample ID:

LJSample wt/vol : .• 5.0 (g/mL3 ML Lab File ID: AOS7S

pLevel: (Iow/med3 LOW Date Received: 3/ 2/89I.Iy. Moisture: not dec. 100. Date Analyzed: 3/ 7/S9

,i Column: (pack/cap) PACK Dilution Factor: 1.00

CONCENTRATION UNITS:Number TICs found: 0 (ug/L or ug/Kg) UG/L

—

'

— •

.

•

~~-ii

f i

CAS NUMBER

•fJ. •

2.— W •

4.E|

6.• .

.

1 0 .11.12.13.14.15.16.17.IS.19.•20.•7*1__. J. «.— , .—,._— •23.24.25.26.27.28.29.30.

COMPOUND NAME

•

»

RT

_______ 0

EST. CONC.

D o n n c; o f.

Q


Appendix E

DPO Report for Contractual Compliance

flR300585

of 2

ORGANIC DATA VALIDATION SUMMARY

Date Review Completed: 5/10/89 Contract Lab.: Id-Case No.: 11488 Contract No.: 68-W8-0046Site Name: Mid-Atlantic Wood Lab DPO: Charles SandsSample Nos.: CY975 thru CY978 Reviewer: Don O'Brien

From: Region III/ESATPhone: (301) 266-9887

CONCENTRA-1ATRIXsoil/solidaqueousother

low

4

medFIONhicrh MATRIX RELATED COMMENTS

VOLATILESGC/MS TUNINTG — BFBInitial CalibrationContinuincr CalibrationSurrogate RecoveryMatrix SpikesReagent BlanksHoldincr times

OKX

XX

X

FYI

XX

X

Action COMMENT

See note 1See note 1

See note 2

SEMI-VOLATILESGC/MS tunina — DFTPPInitial CalibrationContinuing CalibrationSurrogate RecoveryMatrix SpikesReacrent BlanksHolding Times

X

XX

XXXX

See note 1See note 1See note 3See note 4

-

PESTICIDESInstrument PerformanceInitial CalibrationContinuincr CalibrationSurrogate RecoveryMatrix SpikesReagent BlanksHolding Times

X

XXXX

XX

See note 5See note 6

3VERALL CASECompound IdentificationData Completeness

OKXX

FYI Action

REVIEWER'S COMMENTS:

DOCUMENTATION ATTACHED (see following pages) R 3 Q D S p c

Case 11488 Page 2 of 2

ORGANIC DATA VALIDATION SUMMARY

Note 1 - The %RSD and %D values for several compounds exceededprecision criteria in the initial and/or continuingcalibration. (See Table 1 of Appendix F).

Note 2 - The maximum concentrations of the following compoundswere found in the laboratory method blanks.

Compound Concentration fug/L)

acetone * 18

* Common Laboratory Contaminant

Note 3 - The semi-volatile analyses of samples CY975, CY975MS,CY975MSD, and CY977 each had one B/N surrogate recoveryoutside the QC limits. (See Form II of Appendix F).

Note 4 - The semi-volatile MS/MSD analysis of sample CY975 hadthree (3) out of twenty-two (22) recoveries outside theQC limits. (See Form III of Appendix F). 4M

Note 5 - For the pesticide evaluation check standards run on theconfirmation column, the percent RSD for 4,4'-DOT andendrin were outside the QC limits. No positives weredetermined for either compound. (See Form VIII ofAppendix F).

Note 6 - For the pesticide individual B standard run on theconfirmation column, the percent difference for endrinwas outside the QC limits. No positives weredetermined for this compound. (See Form IX of AppendixF).

AR300587

Appendix F

Support Documentation

^300588

P-9«_J_OfE N V I R O N M E N T A L PROTECTION AGENCY R E G I O N I I I

CALIBRATION OUTLIERSVOLATILE HSL COMPOUNDS

CASE/SAS No. // *•/ O ff____________CONTRACTOR __________ T C TA ___

| Instrument* 5" 3 J S '' t t n HI O A T 5 / T ! i « _ : 1 3/3/\ I9F! Ch 1 o r sme t h an« 11 3 rsmome thane II V i n vl Ch I or ide !1 Ch I oroethane 11 M e t hvlen* C h l o r i d e 11 Acetone 11 Carbon 0 ? sul f ?de 1| 1 . 1 - 9 ' e h l o r o « t h e n e II 1 . 1 - O i c h l o r o e t h a n e 11 T o t a l - 1 . 2-9 i e h l o r o e t h e n e 11 Ch t o r o f o r-n1 1 . 2 > 0 i c h l o r o e t h a n e1 2 • 3u t a none 1| 1 . 1 . 1 - T r i e S l o r o e t h a n eI C a rbon T e t - a c h l o r i d eI V i n y l A c e t a t e II S - omod i e h t o r ame t h a n eI 1 , 2 - 0 i c h l o r o o r o 3 a n e II C i s - 1 . 3 - 0 i c h l o r o o r o o e n eI T r i c h l o r o e r h e n eI D i D r o m o c h l o r o m e t h a n eI 1 . 1 . 2 - T r ? c h l o r o e t h a n eI 3 en z e n •I T r a n s - 1 . 3 - D i c h l o r o o t - 3 o e n e1 3 r omo f o r m 1I 4 - M e t h v l - 2 - o e n t a n o n e 1| 2 - H e x a n o n e 1] T e t r a ch I o r oe t h ene1 1 . 1 . 2 . 2 • T e t r aeh 1 oroeth ane !I To 1 uene Ii C h l o r o b e n z e n e Il E t h v l b e n z e n e II S ty r ene II T otal Xvl enes t

Reviewer f^ ••—•I n i t i a l s / D a t e : _$/ • •?/ <r9

:. C a l . ICont. C a l . l C o n t . C a t . l C o n t . Ca?? 2/.."1?'*/'3;».3»'| T/ 'P-V icIX a S D l f l »F 1X0 10 IRF 1 XD IQ |RF I SO

1 1 1 t ! I I I-:•_>.-?! I I I I I^.Vi C 1 1

! 1 I 1 1 ! 1 1! 1 1 1 1 1 1 11 I I I !"?.»! C 1 1I L \~:.?\ ; ? ! 1 I I 11 1 1 1 1 1 1 11 1 1 1 ! 1 1 11 ! 1 1 ! ! I I 1! ! 1 1 1 l 1 ! I1 1 1 1 1 1 1 1 11 1 1 1 1 1 1 1 1

o'.2. ! I I 153.? 1 _ 1 ! l| !1 1 1 1 1 1 1 1 11 1 1 1 1 1 1 1 l1 1 ! 1 1 1 1 1 11 1 1 | I 1 1 i1 1 1 1 1 1 1 ! 11 I ! 1 l l | ll 1 1 1 ! 1 1 1 11 ! 1 1 I 1 ! 1 l1 L ! I I I I I 11 1 1 1 I 1 1 1 11 1 I I I ' l l l1 ! 1 1 1 1 1 1 11 ITV.-'i 1 \ { I I 11 1 1 1 1 1 1 1 1! ! 1 1 1 1 1 I 11 1 1 1 1 1 1 1 11 1 ! 1 1 1 1 I 11 1 1 1 1 1 1 1 1

L 1 1 1 1 I I 1 1 11 1 i 1 1 1 1 1 1

L 1 1 1 1 1 1 1 1 11 1 1! CV97o I CY'~o I| | £ V 1 -7 "7 |I I .-V^Tx^ |I I !I I II I I

t . I Con t . CilI

a IRF iso laI I !I I II I II I !I I !I I iI I II I II I II I If I II I II I II I II I II I II I iI I iI I

I I ^k'I i PI !I II II II II !I II II I1 11 11 11111111

See A t t a c h m e n t s A for glossary of data q u a l i f i e r codes.

AR300589

- ofE.1VIIIONMEMTAL PROTECTION AGENCY REGION tit

CALIBRATION OUTLIERS__ SeXIVOLATILS HSL COMPOUNDS (Part 1 of 2)

CASS/SAS Mo. //'^drj>______________CONTRACTOR _______JfC M______________________

1 f1 .I1 9

1 bI 21 1l i1 ?••1 •

1 2 •1 bi1 4-! *•1 H(1 M i

1 t S

1 2-1 2 ,1 3-1 bi1 2,1 1 ,I S aI 4 •

I MeI 4 -

! 2-I **! 2,I 2,I 2-I 2-! OfI ACI 3-! ACI 2,I 4-! of

RevlIni:

is?-um«nti C ^ - 2 1 ! n t t . Cal.J T S / T J M C . l"/ O*/' •?"*'

* F X3S3 0' e n a '. 1•sf2-Chlor9ethvl).tHer ICh I 3 r aoh eno I 13-9'"e,hloroben_«ne 14-9 f en '. or'jbenzsne 1"izvi A l c a n a ! 1 12-Oi=.bilor-3benjene 1 1 1H e t h v l a n - n o t ' ' 1s ( 2 • e H '. or.isooraovl)-fher 1 1M _ t h v l a h « n o t 1 1 1f i t r a s a - d i - n - s r a o v l a m i n e 1 1 1x a c ^ l a r o e t h a n e 1 1 1rra3*.nz*ne 1 1oohorone 1 1W i - r a s h e n o l 1 14 - 3''-i.thvlah«not 1 1 1n : g ; e A e : d 1 'S f 2 - C . h l o r 9 e t h o x v ) m e t h a n « I '6 - 0 ' C h l a r o o h e n o t 1 12 , 4 - T r i e h t o r a b e n s e n e 1 1a h r S a t - n * 1C h l a r a a n i l i n e 1x a r h '. o r • a b u t a c i e n • 1 1 1C h l a r a - 3 - M e t h v l a h e n o l 1 1" e f w l n a a h t h a l s n e I [x a c h l o r o c v e l o o e n t a d i e n e 1 *^ » -^ 1 _4 . 6 - T r i c h l o r o o h e n o l 1 1 14 . 5 - T r i e h l o r o o h e n o t 1 1 1Chloronaohthalene f ! 1M i t r o a n i 1 i n e ( 1 !m e t h v t P h t h a t a t * 1 1 1•naahthvlene 1 1>4 i t r a a n i 1 i n e 1 I•naahthene . | 14 - O i n i t r o a h e n o l 1 1M i t r o o h e n o l 1benjofuran I

AFFECTEDSAMPLES: CV977

(, ^._.»J - ———— - —ewer ' J ____la Is/Oat*: J/'V-??

••

leant. Cal. leant. C a l . l C a n t . CallV/4/ */'-5 f3 | |f«F 1X3 10 I»F 1X0 10 I?F 1X3 IQ1 ! 1 I 1 1 1 f 11 1 1 1 1 1 1 1 11 I 1 1 1 t 1 1 11 1 1 1 1 1 t 1 11 1 1 1 1 1 1 1 11 1 1 1 1 1 1 1 11 1 1 1 1 1 1 1 11 1 1 1 1 1 1 1 11 1 1 1 1 1 1 1 11 1 1 1 1 1 1 1 11 I 1 1 1 1 1 1 11 1 1 1 t 1 1 1 11 1 1 ! 1 1 ! 1 11 1 I 1 ! 1 1 1 11 1 1 1 1 1 1 1 t1 1 1 1 1 I 1 1 11 1 1 1 1 1 1 1 11 1 1 1 1 1 1 1 11 1 1 1 1 1 1 1 11 1 1 I ! 1 1 1 11 1 1 1 1 1 1 I 11 1 1 1 1 1 1 1 11 1 1 1 1 1 1 I I1 1 1 1 1 1 1 1 'I1 1 1 1 1 1 1 1 11 i-s.5i C i i i l i ii i 1 I i i 1 i 1t i i l i l l I 11 1 t 1 1 I 1 1 1l i l i l i l l lr i i i i i i i ii i i i i i i i ii i i i i i i i ii i i i i t i i i1 £«.?! C 1 1 II 1 I1 1 1 1 1 1 1 1 1! 1 1 1 1 1 1 1 11 1 1I C. Vf 7S i ll rynz l lf ' l il 1 ll l ll i fltf.pnnr-0-1 l ,U^^U1 1 f

1 Can|UF1111111I111111111111!

111

11

111

1!11l111111111111

•. Cal

S3 101tll11l111l1»ll111

1 11t

l 11l

1 11 l

11111

L 11f

L 11r

See A t t a c h m e n t s A for glossary ef data q u a l i f i e r cedes,

P« a •____«'E N V I R O N M E N T A L PROTECTION AGENCY REGION III

CALIBRATION OUTLIERSSEMIVOLATILE 'NSL COMPOUNDS (Part 2 of 2)

CASE/SAS Ha. / / */ 00___________CONTRACTOR

111111111

1111111111111I111111

s«In

t-.r-.j-.e-,.* £ 91 7 d V3 A r 5 /"• I « . : "

2,4-3;nttr3tolueneO i t t i v l a h t h a t a t *4-eh I araehenvl - g h e n v t e t h e r* I uo r ene<<-<»'t'"3*odi'ahenvlamine4.6-?''->.-t-3-2-'<ethvl -ahenol4-3"3'"oenenvi. •ane«v?«therH e x ash I orabenzene» en t aeh loraohenol9h en a r) t h r en eAnthraceneD f - n - b u t v l a h t h a l a t eF t u o r s n t h e n e9 y r • n e3 u t v ' b e n i v l a n t h a l a t e3.3-9 'ehlor-benz'd'ne3 • " j 3 ' j > anthr a c e n eC^. rvsen*b i s ( 2 - _ t h v l h 9 x v l ) s h : h a l a t sO i - n - a c t v ' . a h t h a l a t e3 - » n _ o f b 1 M u o r a n t h e n e3eiz3('<}^'. u o r a n t h e n e3 e n I 3 ' §^ a v " » n *t nd « n 3 f ' , 2 , 3 - C d ) 3 v r « n e

O i b e n i f j h ^ a n t h r a e s n e3«n:3/>" h, ')aervlene

A F F E C T E DSAMPLES:

v i e w e r Ptf>i t i a I s / 0 a t e : 5/U/s 1

1 t n 5 t . C a l . 1I V/ff/*-' 1in* ix*S3 to ii l i li t t li l I Ii t i li l I Ii i 1 11 1 i iI I l i1 1 i iI I I Ii i I ii i i ii i 1 1t i 1 1i t i ii i i ii i i ii i ii t i 'i i ii i ii i ii i ll i ii l li i3?o i 'I1 C/9771111I111

Cont. Ca l . l e a n t . C a l .V/_./.??/_>'_2i»F 1X3 IQ IRF 1X3 10

1 1 1 1 11 1 1 1 11 1 1 1 11 1 1 1 1I I I I !l 1 1 1 1l l 1 1 l1 t l 1 11 1 l l 11 1 1 1 11 ( 1 1 1

1 l l 1 1 1I I I I !

! 1 I 1 1 11 1 1 1 1 11 1 1 1 1 11 1 1 1 1 11 1 1 1 1 11 1 1 1 1 11 1 1 1 1 11 1 1 1 1 11 1 1 1 1 11 1 1 1 1 1I i -rl J 1 1 l1 1.24.51 C I 1 I1 ifa.ol C 1 1 11 Ii (TV'975 i1 r"9Y£ it iL 1L 11 |1 1[ 1{ \

. I C o n t . C a l . l C a n t , C»!\ 1IRF 1 XO 10 \*f IXD 1C1 t t i l l1 1 I I I I1 1 ( 1 1 11 1 l i f t1 1 I I I II 1 1 1 t 11 1 l i l t1 1 I I I I1 1 I I I I1 1 ( 1 1 11 1 ( I I I1 1 l i l t1 1 1 1 1 11 1 1 1 1 11 1 I I I I1 1 I I I I1 1 I I I I1 1 I I I I1 I ( I I II I I I « ^ S1 1 1 1 li B'i l l l l ^ Wl i t i l ll l I l l ll l l l 1 ii l t i l ll 11 t1 11 11 1t f1 11 11 1I 1

See A t t a c h m e n t s A for glossary of data q u a l i f i e r codes.

3005

Attachment A

Q u a l i f i e r s

0 * The following qualifiers should be applied to the applicablecompounds in the affected samples on the data summary forms.

I * X RSO exceeded 30X in the i n i t i a l c a l i b r a t i o n , positiveresults are qualified "J", and quantitation limits arequali f i ed "UJ".

C * XD exceeded 25X in the continuing calibration. Positiveresults are q u a l i f i e d " J " and quantitation l i m i t s are q u a l i f i e d"UJ".

R - RF less than 0.05 in all calibrations. All quantitation l i m i t sare quali f i ed "R".

* * The "3" q u a l i f i e r denoting blank c o n t a m i n a t i o n supersedes thequalifier issued in this table.

^300532

r

&Ai VOLATILE ORGANICS INITIAL CALIBRATION DATA

_ab Name: ICM Contract: 63-W8-0046

_Lab Code: ICM Case No.: 11433 SAS No.: SDG No.: CY975

nstrument ID: 59951 Calibration Date(s): 3/ 3/89 3/ 3/89

Patrix:(soil/water) WATER Level:(low/med): LOW Column:(pack/cap) PACK__

Min RRF for SPCCCS) = .300 C0.25O for Bromoform) Max 7.RSD for CCCC*) - 30.0'/.r"""1 ^ ___| ii |__ ___ ___ ___ ___ ___ ___ __n ^ ___ ___ ___ __| __ ^^ B__ ___ llm_ ^ ___ ___ ___ __L ___ __L _l_l j . _ ___ u ^ ___ ___ ___——— ——— ——— -TIT '-• - —J_ ___ ___ __L, ___ ___ ___ —L —-I ——J __ -_ ___ ___ ___ —I- -LIB ITT' TTT ___ -n~T __I Fl_

!LAB~FILE ID: RRF02O= A082£ RRF05O= A0827 I!RRF100= A082S RRF150= A0829 RRF200= A0830 !

COMPOUND

r

I I I I I I •/ II I I I I _w__. > »• •

RRF020!RRF050:RRF100!RRF150!RRF200: RRF ! RSD !

!Chloromethane ____________#!Bromomethane_____! Vinyl Chl or i de____________*•Chloroethane______iMethylene Chloride

• !Acetone __________[Carbon D i s u l f i d e _ _ _ _

f~J 1. 1-Di chl oroethene________*|_! 1, 1-Di chl oroethane________#\1f2-Dichloroethene (total)

, !Chloroform________________; !1,2-Dichloroethane________' !2—Butanone________________i1.1,1—Trichloroethane ____•! Carbon Tetrachl or i de______

! !Vinyl Acetate ____________!Bromodichloromethane______

[ I 1,2-Dichloropropane ______*i J c i s-1,3-Di chloropropene __fTrichloroethene ___________

, IDibromochi oromethane_______i •1,1,2-Trichloroethane _____1 !Benzene ___________________trans-1,3-Di chloropropene _Bromoform _______________= =j4-Methyl-2-Pentanone_______!2-Hexanone_________________

CTetrachloroethene _________1,1- 2,2—Tetrachloroethane _#•Toluene ___________________*!Chlorobenzene ____________#

i ! Ethyl benzene————IM-D.^-^Z*'. IStyrene _________,'Xylene C total )__

. !Toluene-d8________________! 1.1S5! 1.152!! Bromof luorobenzene________J .848! .810!

,!l,2-Dichloroethane-d4 { 2.742! 2.619!

U:

FORM VI VOA 1/37 Rev.

7AVOLATILE CONTINUING CALIBRATION CHECK

(Name: ICM Contract: S8-W8-0046

Lab Code: ICM Case No.: 11488 SAS No.: SDG No.: CY975linstrument ID: 59951 Calibration Date: 3/ 6/89 Time: 8:37

Lab File ID: A0356 Init. Calib. DateCs): 3/ 3/89 3/ 3/S91Wlatrix:(soil/water) WATER Level:(low/med): LOW Column:(pack/cap) PACK

RRF50 for SPCC<#) = .300 (0.250 for Bromoform) Max '/.D for CCCC*) = 25.0%11

: COMPOUND! Chl or omet hane :i Br omomethane! Vinyl Chloride *1 Ch 1 or oet h an e[Methvlene Chloride! Acetone! Carbon Disulfide! 1 , 1 -D i c h 1 or oet h ene •»! 1 , 1 — Di chl oroethane :! 1 , 2-Di chl oroethene (total ) _[Chloroform J1 1 , 2-D i c h 1 or oet h an e1 2— Butanone1 i , 1 , 1 -Tr i c h 1 or oet h an s[Carbon Tetr achlor i de[Vinyl Acetate! Br omod i c h 1 or omet hane! 1 , 2-Di chl oropropane •*! c i s- 1 , 3-D i c h 1 or op r op en e ___I Tr ichl oroethene! Di bromochl oromethane• 1,1, 2-Tr i chl oroethane ____! Benzene! t r ans— 1 , 3-Di chl or opropene _[Bromoform 4! 4-Methyl -2-Pentanone! 2— Hex anon e! Tetrachl oroethene! 1 , 1 -2,2-Tetrachloroethane _*! Toluene 4i Chl or obenzene *! Ethylbenzene •»• Styrene,'Xylene (total)

!Toluene-d8! Bromof 1 uor obenzene! 1 , 2-Di chloroethane-d4it

iRRF !

=— =— =s= |

* 1.543!.776!

<• ..903!1 . O06 !1 . 792 !.425!4.597!

* 1.334!* • 3 . 046 !

1 . 520 [* 3.237!2.745!. O55 !. 700 !.516!tr^o i

• W%_IW 1

. 679 !(• . 436 !

. 827 !

.389!

.517!

. 299 !1. 171 !

4OC *-li-D i

*• .-374;OOA '• WW*.' 1

•TOCl '. .o y i•?i=:ts; '. WtJtaJ I

* . 450 !«• . 855 !* .943!t .515!1. 138!.643!

====== = =:

1.208!~7C ""> '* / G.L. f

2.482!11

RRF50

1 . 260. 906.812.988

1.666. 565

4. 60S1.3273.0751.5223. 1762.603. 074• &3o.612. 575.661.454.362.412.540.315

1. 187. 440. 420.421.299.398. 536.872.960.515

1. 134.649

1 . 330.7572.392

1

! %DI — — — -« —

! 13.4! 16.8! 10.0! 1.7! 7.0i r --I*; o~~i \»3*i • *3ji — ^*^i • *jI . 5

.9! . 1i -$ -7> -U • t

I 5.2i {*-**—* """"li s*i o "jsi ji 2.4! .8I 8.0: 2.7! 4. 1! 4.2! 5.8! 4.6! 5.3! 1.4l « *"•.1 w> • 1

! 12.2! 7. 4 )! 25.01 12.2! 19.2! 2.0! 1.8

.0! .4! .9

! 10.2i .6! 3.7j

ti

*fl

*

*

*

***4

. ot 3 i . -y a n _ _============= flfi30059/*•( 4 f «•» I 4 _•»_. ^ ^ "

FORM VII VOA 1/87 Rev.• 5 Q

7AVOLATILE CONTINUING CALIBRATION CHECK

Lab Name: ICM Contract: 63-W3-0046

f- Lab Code: ICM Case No.: 11483 SAS No.: SDG No.: CY975

Instrument ID: 59951 Calibration Date: 3/ 7/89 Time: 9:25

LJ-ab File ID: AOS74 Init. Calib. DataCs): 3/ 3/39 3/ 3/S9

D Matrix:(soil/water). WATER Level:(low/med): LOW Column:(pack/cap) PACK

Min RRF50 for SFCC(4*> = .300 C0.25O for Bromoform) Max /'.D for CCC(*) - 25.0%,

11

COMPOUND

Chl or omethane *Br omomethaneVinyl Chloride _ __ •>Chl or oet hane _ _Methyl ene ChlorideAce ten aCarbon Distil fide-1 . 1 -Di c h 1 or oet hen 1 . 1-Dichloroethane _________1 . l-~i chl .r oethene (total ) _C 1 1 o r o form1 2-Di chl or oethane2-Butanone1 1 , i— Tr i chl or .ret hana _____Carbon Tetrachl or i de _______V nvl Ac a tat •=3 • o.TiOd i c h I c-r c met hane _______1 2-Di c h 1 c r - pr c-o an s _______c s— 1 , 3— Di chlor oprooene __Tr i c h 1 or oet heneD i b r omoc h 1 or omet h an e _______1 , 1 , 2-Tr i c h 1 or oet h an eBenzenetr ans-1 , 3-Di chl or opropene _Bromoform4-Methvl -2-Pentanone2— Hex an oneTst r ac h 1 or cet hena1, 1 , 2. 2— Tetr achlor oethane _:Toluene •>Chl orobenzene \EthvlbenzeneStyrene _Xylens (total)

Toluene-d8 _Eromofl uor obenzene1 , 2-Dic"hloroethane-d4 _____

iiRRF '

* 1.543.776

<• . 9031 . 0061J7S2.'4254.597

f- 1.334* 3 . 0^£

*• 2 . 2972.745. 055. 700.SIS

. P7°

. 42£

.527f-\l-\f-,- —> cr _er •« -7

• w* J. /

. 2991. 171.426

* .374oor.• WwfV.'

.239*-\crer• w «*_%_'

S 1 450* .855ft .943* .515

1.133.643

== = = = = = :

1 . 208.7622.4S2

RRF50

1 . 3051 . 1 04.931.984

.-. *_V"V"V

.d'? 1• . w 1

4.2121 . 2773.049* .J.'O

o. . 43•"• c:d.-i. . G) ^ u-;. OS5. SSO.621

£

. 427Cf)"7. *—• * j /. 3SO.512.295

1. 119.430*T*"7 1• o / Aicr i

• W^JU.

: . 244. 353

! ' .475.826

! .948t cr 1 r?i * *J X j

! 1.160! .658

! 1 . 294t "TC *_>1 • / &^»

! 2.543Il

•/.D

15.4 *2 ."5*53.1 *•"> •"!•

•a _ 5*s1.28.44.3 *. 1 tt

4.0A . C? ^

3. 917.22. 9

a /

•1 t™ .4

* /"s

2.2 -<2.4dL. • -h_

1 . 01.24.4.8.9

6.6~t t>-- . «J

.S5.5 *3.4 *.6 4.4 *2.0'"! O-1. O=======7.2.2

2.4i

^300595

FORM VII VOA 1/87 Rev.

e 3

•-.

*

63SEMI VOLATILE ORGAN I CS INITIAL CALIBRATION DATA

Name: ICM Contract: 63-W8-0046


Instrument ID: 59704 Calibration Dats(s): 4/ 5/89 4/ 5/39

lin RRF for SPCC (#),' = .050 Max 3CRSD for CCC(*) = 30. 0%

0

j '

L<• 1I 1'• 1

1t1r

i ttii

i

L-J •iii— i

i i1 i' ii

Lii

n'1LJ!i»

ii

i

LAB FILE ID: RRF020= F0124 RRF050= F0123 !RRF080= F0122 RRF 120= F0121 RRF 160= F0120 !

1

COMPOUND

Phenolb i s ( 2-Ch 1 or oet h y 1 !' et her ___2— Ch 1 or op h en o 11 , 3-Di chl or obenzene1 , 4-Di chl or obenzene *Benzyl alcohol _____________1 . 2— Di chl or obenzene2— Methyl phenol ________ _ _____bis (2-Ch I croi scsr ocyl ) ether<i-Methyl phenol _, __ __ ________N— Ni tr cso— di — n — or opyl ami ns_-Hex ac h 1 or oet h an e»trober,zsne

0 oh or one2 - N i t r o o h e n o 1U » 4 — D .1 ~. s t ••" v 1 3 h >=r n o 1Bsnzoic acidbis ( 2 — C h I c r o e t h c x v ) m e t h a n e2, 4-Di c h 1 or ophsnol _______ ~-1,2, 4-Tr i chl or obenzeneNaphthalene4— Ch 1 or oan i 1 i neHexac h 1 or obut ad i an e •»4-Chl or o-3-methyl phenol __ J2-Methyl naphthsl ene

RRF020

* 1.8201.4751 . 5301.743

* 1.743m -Tw *,

1.-7321 . 2£2•* O€;£-. * iT1 ZTO•f O •""• T

* i . i 92. 662.21-4. 805

**t' O' *""**

o ••• o

. 480«• . 409

. 4501. 141.463

t . 296(• .415

.793Hexachlor ocyc 1 opentadiens _# .0512,4, 5-Tr i c h 1 cr cchenol * . 5002 , 4 . 5-Tr i c h 1 or op he- o 12-Ch 1 or on ac h thai en e2-Ni t r oan i 1 i n eDimethyl oh thai ateAcenaohthyl ene2, 6-Dini trotoluene3-Ni troani 1 ine

er •« o« %w** O

1 . 343.4231.7372.011.407.376

Acenaphthene * 1.4122,4-Dinitrophenol # .1344-Ni trophenol -" # .2924fe :

i

RRF050 ! RRF0801

1 . 746 ! 1 . 6391 . 450 ! 1 . 3351 . 464 ! 1 . 4021 . 720 ! 1 . 5761 . 720 ! 1 . 575. 904 ! . 397

4 ~7'~>O ' 1 *=!CiCJL • / .iLW 1 1 • \_JGO4 •—> .— , . t i 4 < KT "~*J, . . ^ i 1 . 1 ,3/1 O '"' ' ' •» /"•*•-. •".1 • cfîc i ~ • cr *.u1 . 330 ! 1 . 29 11. 148! 1.055. 6^9 ! . 624. 2'->u I . 203.747! .757, 225 ! . 24STiTV> i OOT

• v-" / •-' ! * __/ U. -^

•-; - .-> r --i r-- "i« *- — C* i • jL C- w

H .•"• •"• t .-i e* i. *Ôi < - 4w *oc "7 ' oc cr• ij c« / i •__/.;•«_.•.401! .412

1.061 ! 1.075. 422 ! . 432. 280 ! . 270. 393 ! .413.729! .719.110! . 1 72.453! .444. 493 I . 4991.249! 1.1 SS. 393 ! . 406

1.631! 1.4901 . 323 ! 1 . 659

OÔ i *?QO• O / O t . O 3*-,

. 362 ! . 3361.248! 1.160!.166! .242. 230 ! . 289 !

11 1

RRF 120

1 «r-»eri . wl J W

1.3121 . 42O1 =TQO.i. . »— ' W W

1.613.375.541. 1 74. 1=l 1 7. 22 1

1. 106, 646.201TTC. .• •«/ •-.

TC'T

. 446Ti~7T'. w / j

. 396O!="">. w »JO

.413•":•=: 1. jiwJ 1

. 335

.661

.219

.•444

.4731. 159. 4 1 3

1 . 4221 . 550. w->3o.367

1 . 092. 269.279

RRF 150

1.4441. 1371 . 2921 J.OCTA • *-r*ww

1.435.870

1 . 0421.7851. 1781 . 034. 502. 190. 706. 1_'34TC •*

•-' C- =•

. 430

. S- -S

. 375

.342• +-i? Z7O

. 232

.373

.625

.245

.431

.4431 . 082. 400

1.3601.377.360.347

1.007. 269.272flf?,?

! '/. IRRF ! RSD f

====== | ssBsaes |1.545! 8.9*1 O=;-T> ' o c 'JL . wO*- l O . D i1.1 *-.«-'» i c *•» *. 'Tj-ji 1 D. .». 1

1.622! 16.7!1.62S! £. 5*.396! 2.Sf

1 £T •• A ' *7 <• *J. « & a. V t / • . i4 .» .* i | •«» fJ. ._./,_. 1 /.11

•* r tr.-"» » *5 /*. *i . C? w v i C * •-• i

1.230! 4.8,'1.107! 5.SS.637! 3.7!.202! 4.3f.750! 4.81.-r*-*m i *"i "7j£.

. is-rfO 1 O*/^^

OTf'i i t> O '• O / U i *i « C5 !.-i * i ^ *n c i« *_ _--u/ i A ^ • D t

.454! 4.1!

.372! ;6.3*

.407! 6.3!1.014! ll.Sf.427! 5.6f..266! 9.3*.398! . 4. 1*.706! 9.4?. 159!C$973.455! ,5.9*.490! >7.5J1.206! 8.1!.410! 3.1!1.538! 11.2!1.S85! 14. BI.384! 4.5!.368! 4.0!1.134! 13.1*>.216! 29. 0#.282! 2.3#

Q.d£LQJ3 __ ?

FORM VI SV-1 1/87 Rev.

rSEMIVOLATILE ORGANICS INITIAL CALIBRATION DATA

r

• Lab Name: ICM Contract: 63-W8-OO46

' Lab Code: ICM Case'No.: 11433 SAS No.: SDG No.: CY975

Instrument ID: 59704 Calibration Data(s): 4/ 5/39 4/ 5/39

j Mir. RRF for SPCC(#) = .050 Max V.RSD for CCC(*) * 30.0V.

SLAB FILE ID: RRF020= F0124 RRF050= F0123 !n!RRFOSO= F0122 RRF 120= TO 121 RRF 160= F0120 !

• •> _ ___ _ «. _ _ '•p ' COMPOUND

! Di benzof uranr- ! 2 , *t- D i n i t r ot o 1 uen e. ! Diethvlohthal ate•— ! 4-Chiorophenyl -phenyl ether _! "luorsne

I ! 4-Ni troani 1 inei ! 47 S— Di ni tro— 2— methyl phenol_! N-Ni tr osodi phenyl ami ne ( 1 ) _-

r •! 4— Bromophenyl —phenyl ether _! Hex ac hi or obenzene! Pen" ach 1 or oohenol •>! Ph en an t h r en e

E! Anthracene! Di -;-— butyl phthal ate! F 1 uor ant h er. e

r I r-'vr sr. ei ! Butyl i=n- vl ch-, 'lal a b =

•. •— i *-• ' — — •' - >t i'" i o r c c s~. z r. c i ~ 5 ___ _. iSe-.z-^aNar.thr =.csr,e! Chr ••-•_; ene

1 ! b i s ( 2-Et h y 1 h e x y 1 ) p h t h a 1 at e_! Di -n-octyl phthal ate

j ! Benzo (b) fl uor antheneL! Benzo(k) fl uor anthene! Bsnzo(a) pyr ene •>

',-', Indeno( 1 , 2, 3-cd ) pyrenej'!Dibenz(a,h) anthracene"! BenzoCc, h, i )peryleneL, _ _ _ _ — _ .! Ni trobenzene-d5! 2-F1 uor obi phenyl! Terphenyl-d 14

0! Phenol -d5! 2-F1 uor ophenol! 2, 4, £-Tr i bromophenol

[ ! — - - -

RRF020

2.092.613

1 . 935.337

1 . 699.379.155

* . 626O'-'C. w j .O

. 40 1<• .232

* J~% A4. • O %w *-t

•» •-• £ fJ. • .___&.-'4 * ,- Ji . Sc *

<• 1 . 750"* T O "*j. * • _i _

.975

1.4S74 f-. :f-,X • k__' •— ' W

* 2.6721 . 9231 . 952

* 1.6381.015. 960.328

==zss====

.4271. 1321.3671.7571.445. 204

RRF050

1 . 3-4Ser*-r,-,

1 .757.735

4 ET .••» Q1 . w-Ooo=ro

• wW%-/

. 162

.545

.275

.34-1

.219^ 4 ,-%.-,J. . J. O -L.

1 . 1 7S1.713- cr --•'*".i . ._ C1 0

1 ,S2SC'Cr ;

uiT*Pi • 'Z?w'_T1 O c- (-)j. a —'•—,' •->

1.222^ m CfW /

2 . O4 11 . 7901.6031.017.955. 305

.403

. 9951.2341.7691.413. 182

RRFOSO

< 7~"?J. . / / W

. 59 11 . 539.715

1 . 390.379. 135. -494*-<"7 i* i. / i

* O i- j .

1 ?"* 1 f1 . OcS1 . OS64. • \_J / O

1 . 299j. . v-/ C- O

. EE5

.452JL * w/ / C4 ^* cr 1 * OOO•t 1 OOJ. . I _ W

2.3532 . 0 1 41 . 7221.563. 802. 303.562

4T"_>*-w

.9531. 1691.6741 . 39 1. 180

i

1

RRF 120!

•• C '• •-t IJL • OO.iU t

. 530 !1 . 509 !. 640 '

1 . 307 !•_>Ci— ' '. w y^.. 1 92 :. 490• -.-"DO i

. O 1 b

.-, .-• ._- -Jj_-

1 . 005. 9S5

1.1 241 . 26 11 &CT-'A • W x_- d_

Ci " • _

, J.-3P

i. . ~Zj*~J _

•t OCOj. . «_ — •— '•* •* C 'J. • J, u/ \-J•T' OCT.::*. • WwJO

2. 1741 . 9201.643.632.651.423

. 403

. 9081 . 2591.6591 . 404. 185

RRF ISO======1.525.564

•t rsoTJ. m Wi_f^

.5971 . 252.339.191.424. 249. 297

o— o. w / j.352. 952

4 H O.C-L - 4. -—.'W

* OT'.J.

'•* *IT ,•*

1 . 4591.2161 . 0722 . 1 792.047

, 1.3371.553.435.511

i jtt>— 'i . O*-O=======! .336

.855! 1.115! 1.554! 1 . 394

. 17111

1

RRF !

1 . 304 [errjer i• «JO*_t i

1.651 !.715!

1.431 !.373!. 177!.516!. U / / i.335!. 227 1

1 . 097 !1 . 075 !1.4H'1.415!i CO ^.k . wfW Jt.

.-..-.<- i. r'.'o i. 479

•< e •":• *?J. . O—— vl'

* T QX . ^ JO

1. 1992.4402.0401.8541.613.791.776.583

========.409.9691.2291.6821.410. 184

•

y. !RSD !

_--_ — .— »

4 **. *3 11*1. -J 1

3.S!15.1!13.9!12.5!4. 1!9.5!14. S*10.6!12.0!2.3*15.9!14.3!27 -.gfc16-W9.5!5. 1 !•-• -r >j_ . i7. 1 !7. 1!7.9!S.S*4.4!5. 1!3.4*29.7!

1 C~*5O 5\> ww . " Jr====== j

! 4.0!• 10.9!! 7.8!! 5.2!! 1.5!! 6.5!! !

(1) Cannot be separated from Diphenylamine

FORM VI SV-2 1/37 Rev.1 27

r 7BSEMIVOLATILE CONTINUING CALIBRATION CHECK

r—

L'Mfeb Name: ICM Contract: 63-WS-0046

Lab Code: ICM Case No.: 114SS SAS No.: SDG No.: CY975


Lab File ID: F0134 .. Init. Calib. Date(s): 4/ 5/S3 4/ 5/S9 ... ._

Min RRF50 for SPCCC#) = .050 Max 7.D for CCC(*) = 25.0%

n11

OMPOUND

'. Phenol ____________________*Ibis(2-Chloroethyl)ether _,' 2-Ch i or ophenol ____________• 1.3-Dichlorobenzene _______

'— ! 1 , 4-Dichlorobenzene ._______! Benzyl alcohol_____________

•; I 1 , 2-Di chl orobenzene _______i ! 2-Methyl phenol _____.______

[bi s(2-Chloroi sopropyl )etherC ! 4 — M e t h y l phenol _____________

.' M-Ni trosc-di-n-prcpyi ami r.e_!Hexachloroethane___________! .Nitrobenzene_______________! Isochcrone________________! 2-Ni tr ophenol ___~~____I_!2.4-Dimethvlshenol

szoic acid______________j (2—C h 1 o r o = t h o x y) m e t h s. n e

2, 4-Dichlorochenol________•*i,2,~-7richicrobenzeneNJir-Uf-h = 1thalene

RRF

!4-Chloroani1i ne ___________!Hexachlorobutadiene ______*!4-Chloro-3-methylphenol __*!2—Methylnaphthalene ______!!Hexachlorocyclopentadi ene _#!2,4,6-Trichlorophenol ____*!2,4,5—Tr i c h1 or op h enol ____! 2-Ch lor on aph thai ene ______i.!2—Ni troani1i ne____________[Dimethylphthalate __•____.! Acenaphthylene__________.! 2, 6—Di ni trotoluene_______.!3-Nitroani1ine

635!384!363!

! Acenaphthene__________ * 1.184!!2,4-Dinitrophenol _ _I# .216!!4-Nitrophenol ____~"~__~~# .282!

FORM VII SV-1 1/87 P j

•! Jl A

7CSEMIVOLATILE CONTINUING CALIBRATION CHECK

'•Lab Name: ICM Contract: 6S-WS-OO46

:~Lab Code: ICM Case No.: 11433 SAS No.: SDG No.: CY975


9 Lab File ID: F0134 . Init. Calib. Date(s): 4/ 5/S9 4/ 5/89

Min RRF50 for SPCC(#) = .050 Max V.D for CCC(*) - 25.0V.

i

Dn

COMPOUND

Di benzof ur an2. 4-Di ni trotol ueneDi ethyl ohthal ate4-Ch i or ophenyl -phenyl ether_Fl uor ene4-Ni troani 1 ine4, S-Dinitro-2-methylphenol_!M— Ni tr osod i phenyl ami ne (!)_•»4— Br omophenyl -phenyl ether _Hexachl or obenzeneP sn t ac h 1 or oc h sn o 1 -1P h e r. a n t h r s n eAnthraceneDi -r, -butyl phthal ate _______Fl uor ant her. e -1Pyrsnerut y 1 b sn z y 1 p h t h al at a _______'~ , "•• J — Di chl .-robsr.z i di neB e r. z c '•'. -3 ) a r. ~ ;i *• a c an eChr vseneb i s ( 2 - E t h y 1 h s x y 1 ) p h t h a 1 a t s _Di -n-octyl phthal ateBenzoCb) fluor antheneBenzo (k) fluor antheneBenzo(a)oyrene •*Indeno (1,2, 3-cd)pyr ene _____Dibenz (a, h) anthraceneBenzo (g , h, i )perylene ______

Ni trobenzene-dS2-F1 uorobiohenylTer phenyl— d 14Phenol -dG2— Fl uorophenol2,4, 6— Tr ibromophenol

_

RRF

1.304. 535

1.651.715

1.431.373. 177

«• .516

• O w \->

«• .2271 . 0971 . 0751.411

- 1.^161.531. 902. 479

1 . 5221.2531 . 1 99

* 2.4402.0401.S54

«• 1.613.791.775.583

. 409

.9691.2291.6321.410.184

-

RRF50 !

1.335. 556

1.326.7931.544. 302. 156

. 290

. 250

. 2031. 14S1. 1441.7141.5571 . 603. 9 «":•!";

Jt, m \Zf %J- w

1 . 2791.2122.5311 . 9091.8311.5631. 1021 . 059.921

. 4001 . 0231.2071.7601.414. 137

V.D

4.53.29.910.97.820 . 012. 13. 14.84.4S. 54.76.5

21.51 0 . 01.7

1 ,•••. ••. 71.61.25.36.41.2*•* *1 «

sjrp2.35. 61.74.6• O

1.6

(1) Cannpt be separated from DiphenylamineAR300599

FORM VII SV-2 . 1/87 Rev.

r 3DPESTICIDE EVALUATION STANDARDS SUMMARY

b Name: ICM Contract: 6S-W8-0046I

_ab Code: ICM Case No.: 11488 SAS No.: SDG No.: CY975

Instrument ID: 58903 GC Column ID: OV-1DnDates of Analyses: •'• 4/ 4/89 to 4/ 6/89

Evaluation Check for Linearity

PESTICIDE

AldrinEndri n4,4'-DDT __DEC

1

CALIBRATIONFACTOREVAL MIX A

31320720.20426190.24902320.35990600.

CALIBRATIONFACTOREVAL MIX B

34301920.26610570.17186440.35389810.

CALIBRATIONFACTOREVAL MIX C

=============35827060.27736400.18534840.36724360.

%RSD(</=10. 0V.)======

6.8(gug±

SrP(1)

.. j../ j. i -> XU.U7. RSD, plot a standard curve and determine the ngfor each sample in that set from the curve.

Evaluation Check for 4,4'-DDT/Endrin Breakdown(percent breakdown expressed as total degradation)

tIf1

INITIAL1 ! EVAL MIX B2! EVAL MIX B3!4!5!6!7!8!9!10!11 I12!13!14!

ii

DATEANALYZED

4/ 4/894/ 4/89

TIMEANALYZED

1:4712:17

ENDRIN

'

— —

4,4'-DDT COMBINED(2)

6.718.45

!

(2) See Form instructions.

AR300600

FORM VIII PEST-1 1/b/ Kev.1 8 9

9PESTICIDE/PCB STANDARDS SUMMARY



Instrument ID: 58903 GC Column ID: OV-1

! COMPOUND•, — i —— ; — ,—-i--i =-.. alpha-SHC __!beta-BHC _____idelta-BHC __igamma-BHC (Li! Heptachl or __! AldrinJHept. Epoxide! Endosul fan I_iDieldrin14, 4' -DDE! Endrin! Endosul fan I I!4,4'-DDD! Endo. sul fate!4,4'-DDT! Met hoxyc h 1 or _! Endrin ketone!a. Chl or dane!g. Chlordane! Toxaphene! Aroclor-1016_• ArociO* — Il2.i_• Ar-ocior-i__32_! Aroc lor -1242! Aroclor-1248_!Aroclor-1254_! Aroclor-1260l

DATE(S) OF FROM: 4/ 4/89ANALYSIS TO: 4/ 4/89TIME(S) OF FROM: 4:46ANALYSIS TO: 5:33

RT

2.232.422.75

'2.674*?o. *_.*.tr OQ*J . OOD . «_l /

8 . 20It • O^l

9 . 6O1 0 . 721 1 . OO12.1214. 1715. 00•—< 1 cr.i-4 . 1 51O OA1 O . O'.'S'-ic-. sll j

y^T1. >JO

i \

Fwir

FROM

2.222.372.692.624.23=; — 'C*J . i_O

£.438.039.41O '""'O- . OO

10.4810.7411.3613.3315.6723 . 7 117.90S. 16"7 o=:/ * W*J

?T^DOW

TO

2.342.482.812.734.415.496.718.379.339 . 32

1 0 . 961 1 . 2612.3314.461 C *~tJ. O • •*-><-J

24.5913.703.547.70

CALIBRATIONFACTOR

30070160.22567920.33613620.26648920.33434560.36411880.38111260.37370660 .32701920.23556130.21685720.33020670.2125334O.32195110.13777950.11552330.39154060.42396500.28940830.

DATE OF ANALYSIS 4/ 6/89 !TIME OF ANALYSIS 0:55 !EPA SAMPLE NO. !(STANDARD) INDB I

!

RT

= = == = ====

2.282.422.75

«=: OQu. oo

9 . 6010.7

12. 1214. 17

18.278. 357.53

CALIBRATIONFACTOR

24256840.20321100.28422220 .

33662020.

2432666O.17094760.

17968730.26292470 .

31752850.35749780.25 1 07300 .

QNTY/N

NNNNNNNNNNNNNNNNNNNNNNNNNNN

V.D

19.310. 015.4

7.6

14.8r 21.21's->~ — -""""I"i7g18.

!1

18.9!15.713.21

!; Under DNT Y/N: enter Y if quantitation was performed, N if not performed.l-/CD must be less than or equal to 15.0V. for quantitation, and less thanor equal to 2O.OV. for confirmation.nL_ Note: Determining that no compounds were found above the CRQL is a form ofquantitation, and therefore at least one column must meet the 15.0V. criteria.

I For multicomponent analytes, the largest single peak that is characteristic

; • "R30060I

L " 20e

WATER SEMIVOLATILE SURROGATE RECOVERY

Lab Name: ICM Contract: 6S-W8-0046


i <U

n 1•-. I

4!5!s:73!910!1

14!

151

IS191

•~«Q t-L.O i

EPASAMPLE NO-

CY975MSCY377S3LK10 6CY975MSDCY375CY976

C 1

CNBZ)#======878573sa .-74TO/ *»*

S2<F3P)#======137 *141 *105126 *117 *114

S3CTPH)#

44494543SO44

S4CPHL)#

3736'Q33ooooocwO

S5C2FP3#

*~tWOC"?ww43595256

SS(TBP)#

8010174793296

OTHER TOTOUT===110110

—

QC LIMITSSI (NBZ) = Nitrobenzene-d5 (35-114)S2 (F3P) = 2-Fluorobiphenyl ( (43-115)S3 (TPH) = Terphenyl-dl4 (23-141)S4 (PHD = Phenol -dS , (10- 94)S5 (2FP) = 2-F1 uor ophenol ' (21-100)56 (TBP) = 2,4,6-Tribromophenol (10-123)

# Column to be used to flag recovery values

* Values outside of contract required QC limits

D Surrogates diluted out

page 1 of 1FORM II SV-1 1/87 Rev,

96

3CWATER SEMIVCLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY


Lab Cede: ICM Case No,: 11433 SAS No.: SDG No.: CY975

atrix Spike - EPA Sample No.: CY975

D COMPOUND=:===:===========:=========

•Phenol2-ChloroDhenol1 , •--Di chl or obenzene ___N-Nitroso-di-n-prop. (1)1,2, 4-Tr ichlorobenzene_4-Chl or o-3-met hy i phenol.Acenaphthene4-Mi troohenol2, 4— Di ni tr otol uene?=n t ac h 1 or ooh en o 1Pyr ene

SPIKEADDED(UG/L )

=========•-•'1C'

235.113.113.113.•-««-i erj_.Wi— ' •

113.235.113..._- J_» .-» •

1 -f CJ. A '— -• •

SAMPLECONCENTRATION

(UG/L )=============

.0.0.0.0.0.0.0.0.0.0.

MSCONCENTRATION

(UG/L )=============

105.213.106.113.117.234.121.121.112.44.100.

MS7.REC #

======4er

w>

909010099 *100 *103 i^o i-9erw19 .35

QC ;LIMITS:REC. •:====== 1

1 *•* QO

27-123'36- 9741-116!39- 9823- 97!46-118,10- 80!24- 969-103.25-127

li

! Err I KE! ADDED

COMPOUND ; (L'G/L )

Phenol ! 225.2-Ch 1 or oo h en o 1 . ! 225 .1. 4-Di chl or obenzene ! 118.N-N i t r oso-d i .-n -p r op . ( 1 ) ! 113.1,2,4-Tr ichlorobenzene_ ! 113.4-Chl oro-3-methyl phenol ! 235.Acenaphthene ! 113.4-Nitrophenol ! 235.2, 4-Di ni trotol Liene ! US.Pen t ac h 1 or op h sn o 1 ____ ! 235 .Pyrane [ 113.

!

MSDCONCENTRATION

(UG/L )

10-i.•-••-•a _1 00 .111.107.244.11 *>i ..110.103.31.S3.

MCp1 1 1— • lw

*,',

REC ^r

4497859591104 *u47921375

7.f C' t J*

1756S4

1033512

QC L

424023332342O J.

503850*"V 4 tO JL .

vEMITSREC . '

12- 39'27-123136- 97!41-116'39- 98!23- 97;*rO 1 IQ <10- SO:24- 96!9-103:26-1271

!

v A y i

L# Coli

(1) N-Nitroso-di—n-propylamine

.umn to be used to flag recovery and RPD values with an asterisk

j * Values outside of QC limits

•RPD: 0 out of ,11 outside limits AR300603Spike Recovery: 3 out of 22 outside limits

i COMMENTS:

i!L.

FORM III SV'9_7 1/87 Rev.


! " :! VBLK B !

Name: ICM Contract: 6S-WS-0046 !___________

ab Code: ICM Case No.: 11433 SAS No.: SDG No.: CY975

atrix: (soi 1/water )• WATER Lab Sample ID:

r~5ample wt/vol: 5.0 (g/mL) ML Lab File ID: A0853

Level: (low/med) LOW Date Received: O/ O/ 0

'. Moisture: not dec. 100. Date Analyzed: 3/ 6/89

.Column: (pack/cap) PACK Dilution Factor: l.OO

CONCENTRATION UNITS:! CAS NO. COMPOUND (ug/L or ug/Kg) UG/L Q

74-37-3 ——

75-01-4 ——

67-64-1 ——75-15-0 ——

54O-59-O —— -

107-06-2 ——

— r 4 e'er £/I— 0»J fa

56—^3—51VO VwJ "T

73-37-5 ——10061-01-5 ——

79-01-6 ——1 '4 4S t_ .L- r w x79-00-5 ——71-43-2 ——

10061-02-6 ——

108-10-1 ——f o 1 ~ro c _i * >~7— 1 a .±i___

1 r\o cir-i_~7-._-_100-41-4 ——100-42-5 ——

- ——— Chl or omethane———— Br omomethane———— Vinyl Chloride———— Chl oroethane- ——— Methyl ene Chloride———— Acetone- ——— Carbon Disulfide- ——— 1, 1-Di chl oroethene———— 1, 1-Di chl or oethane———— 1 , 2-Di ch lor oet hen e (total ) _———— Ch 1 or o f or m———— 1 , 2-Di chl oroethane- ——— 2-Butanone———— 1 , 1 , 1-Tr i chl or oet hane• ——— Carbon Tetrachl or ide... . . _ , .-~-— •—•— v i ny i r^uet/a'ce• ——— Bromodi chl or omet hane———— 1 , 2-Dichloropropane- ——— ci s-1 , 3-Di chl or opropene ____- ——— Tr i c h 1 or oet h ene- ——— Dibromochl or omethane———— 1 , 1 , 2-Tri chl or oethane———— Benzene———— trans-1 , 3-Di chl or opropene _- ——— Bromoform- ——— 4-Methyl -2-Pentanone• ——— 2-Hexanone- ——— Tetrachl oroethene• ——— 1, 1, 2, 2-Tetrachl or oethane _• ——— Toluene• —— :-Chlorobenzene _____ fl R3~Q ---Q-f

——— Styrene. ——— Xylene (total)

10.10.10.1 0 .5.10.5.5.5.5.5.^J m

10.

5.10.5.5.5.5.5.5.5.5.5.10.10.5.5.5

5.5.

- 1 5FORM I VOA

!

!U!U!U!U!U!U!U!U!U!U!U!U!U!U!U!U!U!U!U!U!U!U!U!U!U!UIU!U!U!U!U!U!U!Ui

1/87 Rev.

rIE EPA SAMPLE NO.

VOLATILE ORGANICS ANALYSIS DATA SHEETTENTATIVELY IDENTIFIED COMPOUNDS

VBLK B !•'_ab Name: ICM Contract: 68-WS-0046

I


Hlatrix:, (soil/water) WATER Lab Sample ID:

Sample wt/vol: ' 5.0 (g/mL) ML Lab File ID: A0858


r-'-C Moisture: not dec. 100. Date Analyzed: 3/ 6/89

Column: (pack/cap) PACK Dilution Factor: 1.00

~ .. CONCENTRATION UNITS:_ Number TICs found: 0 (ug/L or ug/Kg) UG/L

C

CAS NUMBER

1.ji 9

O *

4.5.6.7.S.9.

1 0 .11.12.13.14.15.16.17.IS.19.20.21.22.23.24.25.26.27.28.29.30.

COMPOUND NAME

-.

RT

_ _ JLD— — — — H n

EST. CONC.

to n n C-n r ,,

sQ

_f

! !

FORM I VOA-TIC 1/87 Rev.- 7 6


VBLK CName: ICM Contract: 63-WS-0046 __________

'; Cab Code: ICM . Casa No.: 11433 SAS No.: SDG No.: CY975

rjMatrix: (soi 1 /water) WATER Lab Sample ID:

Sample wt/vol : '' 5.0 (g/mL) ML Lab File ID: AOS75

: (low/med> LOW Date Received: O/ O/ 0

%.Moisture: not dec. 100. Date Analysed: 3/ 7/S9nij'Column: (pack/cap) PACK Dilution Factor: 1.00

CONCENTRATION UNITS:CAS NC. COMPOUND Cug/L or ug/Kg) UG/L Q

f,

74-87-3 ————/ •H'—'CO :?

/ W .-' '--' •«,

C "? — C •« -tO / •— ' -T _

•?=:.__. -t =:_,- _____/ W —— X -_' •_•

"?c=;_Ot=p_ci._ __/ O WM —«-.-"— ——»,=• *-* .4 ^/' w wr"?1 w ~~"

5 -0-59-0 ———,= 7_S,=._^ ———107-05-2 —— -

n:-: _••:•«_=•_ ___w o . i_' _ri -JO U>_' — *r"7=;_-~'-/' ji __7Q_OT =:

10061-01-5 ————79-01-5 ————124-43-1 ———79-00-5 ———T ^ -•« •*"•

1 005 1 -02-6 — —7=- -r> c; t

103-10-1 ———591-78-6 ———1 '"•''7 1 Q fl _

TO "» •< c?

108-90-7 ———100-41-4 ————

1*"V V"\ ^ r"l "7

—— i_:h 1 or omethane—— Bromomethane—— V i n v 1 Ch 1 o r i d e—— Ch 1 or oet h an s—— p^et hyl ene Ch 1 or i de

—— Carbon Disulfide—— 1 , 1-Di chl or oethene—— 1. 1-Di chl or oet hane—— 1 , 2-Dichloroethene (total ) ___ j--,. ~. _„.._, * ,_ ._. _,•-• i . « _• . •_•.'_' i 1.1—— 1 , l-I'i : h 1 or oet hane—— 2-5 ut an one—— 1 , i , 1 -Tr i c h 1 or oet h an e—— Carbon TstrachI or i de—— Vinyl Acetate—— Br omodi chl or omethane—— 1 , 2-Di chl or opropane—— cis-1 , 3-Di chl or opropene ___—— Tr i chl or oethene—— Di br omochl or omethane—— 1,1. 2-Tr i c h 1 or oet h ane—— Benzene—— t rans-1 , 3-Di chl or opropene _—— 3r omo for m— 4-Methyl-2-Pentanone—— 2-Hexanone—— Tetrachl or oethene—— 1 ,1,2, 2-Tetr achl oroethane _—— Toluene—— Ch 1 or obenz ene—— Ethylbenzene • r> -, n --— Styrene ' " flH 3 QffKD—— Xylene (total)

10.10.10.10.RxJ •IS.nr*_f -

5.C1-j *

cr'-.- •

O «

•* i'"« '-• •crc--— i .

10.5.5.5.w *

5.5.

• 5.e*O .

, 5.*10.10.5.5.5 .5.5.

6 5-5-

1

!U!U!U!U> ' t1 UJ1i

!U!U!U!U!U! U!U.!U!U!U!U!U!U!U!U!U!U

' !U!U!U!U!U!U!U!U!U!U!U11

FORM I VGA . Q i 1/87 Rev.

IE EPA SAMPLE NO.VOLATILE ORGANICS ANALYSIS DATA SHEET _______ _TENTATIVELY IDENTIFIED COMPOUNDS ! ~~

; ! VBLK CLab Name: ICM Contract: 63-W8-0046 !_____________

"Lab Code: ICM Case No.: 11433 SAS No.: SDG No.: CY975i .Matrix: (soil/water) WATER Lab Sample ID:

[(Sample wt/vol: 5.0 (g/mL) ML Lab File ID: AOS75


UV. Moisture: not dec. 10O. Date Analyzed: 3/ 7/89

r-Column: (pack/can) PACK Dilution Factor: 1.00i 4 •-

CONCENTRATION UNITS:_ Number TICs found: 0 (ug/L or ug/Kg) UG/L

—

i1 ,

riL_

,'j

1

'•

!,! '

••

!ni. '!| !1 ii

iCAS NUMBER

1.*i •w •

4.cr*.; .6 .T

8.9.

•* »••»

•* 1

1 '~

12.14.15.IS.17.13.19.20.!__.!»22.22.*"?• ••*

25.26.27.28.29.30.

COMPOUND NAME

•

RT EST. CONC. Q

_:_:j—

s

FORM I VOA-TIC .' 1/87

82

__rat

IB EPA SAMPLE NO.SEMI VOLATILE ORGAN I CS ANALYSIS DATA SHEET

; 7•'! SBLK10O {b Name: ICM Contract: 6S-W8-0046 ! _ _!

•

"

•

J

31



Sample wt/vol: 1OOO.O (g/mL) ML Lab File ID: F0136


%.Moisture: not dec. 100. dec. 0. Date Extracted: 3/ 8/S9

Extraction: (SepF/Cont/Sonc) SEPF Date Analyzed: 4/ 6/39

GPC Cleanup: (Y/N) N pH: .0 Dilution Factor: 1.00

, CONCENTRATION UNITS:CAS NO. ' COMPOUND (ug/L or ug/Kg) UG/L Q

1 OS-95-2-— ———— Phenol11 1-44-4 —————— bis(2-Chloroethyl ) ether95-57-S —————— 2-Chiorochenol541-72-1 —————— 1 , 2-Di chl ore-benzene106-45-7 —————— 1 , 4-Di chl or obenzenej. •„' .-• w .k •_ w G7 1 l *. f 4. <=l -i '— •_' 1 t — .' j.

.. • w \_ '-' a. _ . - *y J. U. i } _ '— ' f '.,' !_' ti? ! l - '« . i '._

95-43-7 —————— 2-Mcthviph<=nol103-.5O-1 —————— bi 2 (2-Chloroisopropyl ) ether106-44-5 —————— •i-Methyl'ahsnol£2i— 54 — 7— ————— N-N'i tr o=o-di — n— pr opy 1 ami ne _57—72— 1 —————— He x sc h 1 or oet h an •=:93-95-3 —————— Nitrobenzene73-59-1 —————— Isoshorone33-75-5 —————— 2-Ni troohenol105-67-9 —————— 2. 4-Di methvl phenol65-35-0 —————— Benzoic acid

1 1 1-91-1 —————— bis(2-Chloroethoxy)methane _120-33-2 —————— 2,4-Dichloroohenol120-32-1 —————— 1. 2, 4-Tri chl or obenzene91-20-3 —————— Naphthalene

1 06-47-S —————— 4-Ch 1 or oan i 1 i ne37-63-3 ———— : — Hexachl orobutadi ene59-50-7 —————— 4-Chl or o-3-methyl phenol91-57-6 —————— 2-Methyl naphthalene77-47-4 —————— Hexac h 1 or oc yc 1 open t adi ene _83-06-2 —————— 2, 4, 6-Tr ichlorophenol95-95-4 —————— 2, 4, 5-Tr i chl or ophenol91-53-7 —————— 2-Ch 1 or onaph thai ene88-74-4 —————— 2-Ni troani line fl D on n /-.131-11-3 ———— * — Dimethylphthalate AtTr "0 D~0208-96-S —————— Acenaphthylene606-20-2 —————— 2 , 6-Di nitrotol uene

1O.10.1 0 .10.10.10.10.10.10.1 0 .1 0 .1 0 .10.10.10.10.50.10.10.10.10.10.10.10.10.10.10.50.10.

os ?S:10.10.

11

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FORM I SV-1 1 5 2 1/87

1C EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

~• ' % ! SBLK106Lab Name: ICM Contract: 63-W8-0046 !_____________S

""Lab Code: ICM Case No.: 11483 SAS No.: SDG No.: CY975

"" Matrix: (soil/water) WATER Lab Sample ID:

nSample wt/vol: 1OOO.O (g/mL) ML Lab File ID: F0136

Level: (low/med) LOW Date Received: O/ O/ 0a '

7. Moisture: not dec. 10O. dec. 0. Date Extracted: 3/ 8/89

HExtract ion: (SepF/Cont/Sonc) SEPF Date Analyzed: 4/ 6/89


\J • CONCENTRATION UNITS:L-* CAS NO. COMPOUND (ug/L| or ug/Kg) UG/L Q

99-09-2 ———W W w-rX- -?

cr 4 -~'C crW -i *_w3 i_l

1-~*i •. H .H •"•__i _L "™ J. *T~.*L.

34-55-2 -——7C05-72-3 ———

C3 O / _• i

100-O1-5 ———•_j O- *~»* ~~ — ' j'- ~ -. ~" ~~* ~~ ~"

86-2O-5 ————4 f"\ 4 CTCT *-•i *•.' J. -_J •-. •— '•!•*'—» ™r .4 -t1 1 Q—— / *+—— 1 ——————————

r-. -7 Q c crO / O O vJQC" f"> 1 OOwl l«/ 1 O

120-12-7 ———O --f "7-1 •" •34— /4 z.206-44-0 ————

pier CO ~*

y 1 3T i!=•£ ir-er »_ti_>O i O *_•

. O V.J JL 1711 T Q 1 "7

•tx C" CiO O ___

£.\J / \J<3 3 — .——Glf") "-" ..Ca __

1 Ci*? O -i «r

c;o VO^T>^ _

191-24-2 ————

—— 2-Ni troani 1 i ne—— Acenaohthene—— 2, 4-Dinitr ophenol—— 4-Ni tr oohenol—— Di benz o f ur an—— 2. 4-Di ni tr otol uene—— Di ethyl phthal ate—— 4-Chl or ophenyl -phenyl ether _—— Fi uor ene—— 4-Ni troani 1 i ne— — — '-r f ™ — tj i n i v r o — — m _; 'v n y ,- p i T e n G j. _ _—— W-Ni _ rosc-di phenyl ami ne ( 1 ) _—— 4-Br omophenyl -phenyl ether _—— He x ac h 1 or ob en z en e—— Pen t ac h 1 or op hen o 1—— Phenanthr ene—— Anthracene—— Di-n-butyl phthal ate—— Fluor anthene

pyr ene—— Butylbenzylphthalate—— 3, 3' -Di chl orobenzi di ne—— Benzo (a) anthracene—— Chrysene _,—— bis(2-Ethylhexyl) phthal ate _—— Di -n-oc tyl phthal ate—— Benzo(b) fluor anthene—— Benzo(k) fluor anthene—— Benzo(a)pyrene—— Indeno (1,2, 3-cd) pyrene—— Dibenz (a, h)anthracene ___ «-" — Benzo (q, h, i ) per yl ene ' "1

50.10.50.50.10.1 0 .10.10.1 0 .50 .50.10.10.10.50.10.10.10.10.10.10.20.10.10.10.10.10.10.10.10.

530060$.'1

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(1) — Cannot be separated from diphenylamine


1 6 3

IF EPA SAMPLE NO.SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

TENTATIVELY IDENTIFIED COMPOUNDSI SBLK106Lab Name: ICM Contract: 63-W3-0046 _____________

.'tffc:; Code: ICM Case No.: 11483 SAS No.: SDG No.: CY975i ^i_<Matrix: (soil/water) WATER Lab Sample ID:

Sample wt/vol: 1000.0 (g/mL) ML Lab File ID: F0136


7. Moisture: not dec. 100. dec. 0. Date Extracted: 3/ 8/S9

MExtract ion: (SepF/Cont/Sonc) SEPF Date Analyzed: 4/ 6/89


•. CONCENTRATION UNITS:Number TICs found: 0 (ug/L or ug/Kg) UG/L

i

y]i-(—••ii

i

jj!

J

tiCAS NUMBER

1 . _

! 1.1 *~»I _^. -1 *~)l O •

! 4.i rr;*_• •

A- I- -I " "V?.8.Q

1 0 .J. * •

1 '"'J. *_ «

•t 4, W1 •

14.15.16.17.13.19.20 .•TH

.—, .—,1 -. -

23.24.25.26.27.23.29.30.

COMPOUND NAME

A

RT

-fr TO

EST. COIMC.

dSZB I~I~~^** i o

Q

V

_

*

i

\


1 6 4

r -w EPA SAMPLE NO.PC.OI Ai_it/i_ utMji-ii -.. ww n«ti-it. t aia UH l A SHEET __

ij ! PBLK105' Lab Name: ICM Contract: 68-WS-0046 !_________

r Lab Code: ICM Case No.: 11488 SAS No.: SDG No.: CY975

'"Matrix: (soil/water) WATER Lab Sample ID:

f~j Sample wt/vol: 1000. (g/mL)ML Lab File ID: D094O


|J% Moisture: not dec. 100. dec. 0. Date Extracted: 3/ 8/89

p Extraction: (SepF/Cont /Sonc ) SEPF Date Analyzed: 3/20/89

l- GPC Cleanup: (Y/N) N pH: .0 Dilution Factor: 1.00

H CONCENTRATION UNITS:L2 QAS NO. COMPOUND <ug/L or ug/ Kg) UG/L Q

n

T> 1 O £3<i_C •» 1 nL* -> QUIP-

31 9-85-7 ———— bet a-BHC

58-39-9 ———— gamma-BHC (Li ndane)76-44-8 ———— Hep t ac h 1 or3O9-OO-2 ———— Al dr i n1024-57-3 ———— Heptachl or epoxideO K" O O O O r— '«-..-) (— 1 I 1 -P -1 1-1 T

60-57-1 ———— Di el dr i n72-55-9 ———— 4, 4' -DDE

-o*.a.o-ac,— •=• ———— Endosul fan II7'"' ei4 (S 4. 4.' HDD

1031-O7-B ———— Endosul fan sul fate

72-42-5 ———— Met hoxyc h 1 or53434-7 -5 ———— Endrin ketone5103—71- 9 ———— alpha-Chlordane

1 5103-74\ - ——— gamma-Ch lor dane8001-35-,2-rr —— foxaphene

v 1 2674- 1 1 -2\-Xr-Ar oc 1 or - 1 0 1 6>lllO4-28-2 —— -^-Aroc lor -1221ll 1141-16-5 ———— Aroc lor -1232

12672-29-6- - -Aroc lor 124811097-63-1 ———— Aroclor-12541 1 096-82-5 ———— Ar oc 1 or - 1 260

•H

.050

.050

.050

.050

. 050

.050

.050

.050. 10. 10. 1O. 10. 10. 10. 10.50. 10.50.501.0.50.SO.50.50.501.0

! 1.0,

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BR3006I I

FORM I PEST 1/87 Rev.

259

omki - us environmental protection agency · b4s(2-clilotoe1hoxy)melhan e * a § 0, o 2, 1...

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