operating_manual_thu9-tmu9-2109.9110.02-04

R&STHU9/TMU9Transmitter SystemOperating Manual

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wikowskiTextfeldFor information only!This manual, dated June 19, 2013, reflects the technical status as of that date. There may have been technical changes since that time.

2013 Rohde & Schwarz GmbH & Co. KGMhldorfstr. 15, 81671 Mnchen, GermanyPhone: +49 89 41 29 - 0Fax: +49 89 41 29 12 164E-mail: [email protected]: www.rohde-schwarz.comSubject to change Data without tolerance limits is not binding.R&S is a registered trademark of Rohde & Schwarz GmbH & Co. KG.Trade names are trademarks of the owners.

The following abbreviations are used throughout this manual: R&SXYZ1234 is abbreviated as R&S XYZ1234.

Sehr geehrter Kunde,Sie haben sich fr den Kauf eines Rohde & Schwarz Produk-tes entschieden. Sie erhalten damit ein nach modernsten Fer-tigungsmethoden hergestelltes Produkt. Es wurde nach den Regeln unserer Qualitts- und Umweltmanagementsysteme entwickelt, gefertigt und geprft. Rohde & Schwarz ist unter ande-rem nach den Managementsys-temen ISO 9001 und ISO 14001 zertifiziert.

Der Umwelt verpflichtet Energie-effiziente, RoHS-konforme Produkte

Kontinuierliche Weiterentwicklung nachhaltiger Umweltkonzepte

ISO 14001-zertifiziertes Umweltmanagementsystem

Dear customer,You have decided to buy a Rohde & Schwarz product. This product has been manufactured using the most advanced meth-ods. It was developed, manufac-tured and tested in compliance with our quality management and environmental manage-ment systems. Rohde & Schwarz has been certified, for exam-ple, according to the ISO 9001 and ISO 14001 management systems.

Environmental commitment Energy-efficient products Continuous improvement in environmental sustainability

ISO 14001-certified environmental management system

Cher client,Vous avez choisi dacheter un produit Rohde & Schwarz. Vous disposez donc dun produit fabriqu daprs les mthodes les plus avances. Le dvelop-pement, la fabrication et les tests de ce produit ont t effec-tus selon nos systmes de management de qualit et de management environnemental. La socit Rohde & Schwarz a t homologue, entre autres, conformment aux systmes de management ISO 9001 et ISO 14001.

Engagement cologique Produits efficience nergtique

Amlioration continue de la durabilit environnementale

Systme de management environnemental certifi selon ISO 14001

Certified Environmental System

ISO 14001

Certified Quality System

ISO 9001Quality management and environmental management

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ISO-Qualitaets-Zertifikat_1171-0200-11_A4.indd 1 28.09.2012 10:25:08

1171.0200.22-06.00

Customer Support

Technical support where and when you need it For quick, expert help with any Rohde & Schwarz equipment, contact one of our Customer Support Centers. A team of highly qualified engineers provides telephone support and will work with you to find a solution to your query on any aspect of the operation, programming or applications of Rohde & Schwarz equipment.

Up-to-date information and upgrades To keep your instrument up-to-date and to be informed about new application notes related to your instrument, please send an e-mail to the Customer Support Center stating your instrument and your wish. We will take care that you will get the right information.

Europe, Africa, Middle East Phone +49 89 4129 12345 [email protected]

North America Phone 1-888-TEST-RSA (1-888-837-8772) [email protected]

Latin America Phone +1-410-910-7988 [email protected]

Asia/Pacific Phone +65 65 13 04 88 [email protected]

China Phone +86-800-810-8228 / +86-400-650-5896 [email protected]

ContentsR&STHU9/TMU9

3Operating Manual 2109.9110.02 04

Contents1 Information about this Manual..............................................................72 Safety Instructions.................................................................................9

2.1 Safety Instructions for Transmitter Systems and Equipment..................................92.2 General Safety Instructions.......................................................................................10

2.2.1 Safety Instructions.........................................................................................................102.3 Special Hazard Information........................................................................................17

2.3.1 Hazards from AC Supply Voltage.................................................................................172.3.1.1 AC Power Supply..........................................................................................................172.3.1.2 Changing Fuses............................................................................................................17

2.3.2 Hazards from HighEnergy Electric Circuits..................................................................172.3.3 Hazards from RF Radiation...........................................................................................18

2.3.3.1 Obligation to Instruct Personnel....................................................................................182.3.3.2 RF Shielding..................................................................................................................182.3.3.3 Rules When Operating an Amplifier..............................................................................182.3.3.4 Rules When Working on an Open Amplifier..................................................................19

2.3.4 Conditions for Assembly Work on Cooling System.......................................................192.3.5 Safety Data Sheets for Hazardous Substances............................................................20

3 Operation..............................................................................................213.1 Operation using the TDU900......................................................................................21

3.1.1 Opening the Display......................................................................................................213.1.2 Closing the Display.......................................................................................................213.1.3 Using the Touchscreen Function..................................................................................21

3.2 Operation via a Web Browser....................................................................................223.2.1 Network Connection Process and Login.......................................................................22

3.3 Design of the User Interface......................................................................................233.3.1 Elements of the User Interface......................................................................................233.3.2 Views.............................................................................................................................233.3.3 Basic Menu Bar Functions............................................................................................24

3.3.3.1 Logbook........................................................................................................................253.3.3.2 Help...............................................................................................................................253.3.3.3 Local/Remote................................................................................................................25



3.3.3.4 Login/Logout.................................................................................................................253.3.3.5 Device View..................................................................................................................253.3.3.6 Task View......................................................................................................................26

3.3.4 Navigation.....................................................................................................................263.3.5 Input fields.....................................................................................................................263.3.6 Editors...........................................................................................................................26

3.3.6.1 Numeric editor...............................................................................................................273.3.6.2 Text editor.....................................................................................................................27

3.3.7 Special tasks.................................................................................................................273.3.7.1 Finding an Error............................................................................................................273.3.7.2 Managing Users............................................................................................................28

3.3.8 Logbook........................................................................................................................283.3.8.1 Chronological View.......................................................................................................283.3.8.2 Filter (filter/options).......................................................................................................313.3.8.3 Scroll function................................................................................................................31

4 Device View Description......................................................................334.1 System Overview........................................................................................................33

4.1.1 Device View Home........................................................................................................334.1.1.1 Forward Power..............................................................................................................334.1.1.2 Reflected Power............................................................................................................344.1.1.3 Transmitter....................................................................................................................344.1.1.4 N+1 Redundancy..........................................................................................................35

4.2 Transmitter..................................................................................................................374.2.1 Automatic Switchover Functions...................................................................................37

4.2.1.1 Automatic Input Signal Switchover................................................................................374.2.1.2 Automatic Exciter Switchover........................................................................................40

4.2.2 Transmitter Status.........................................................................................................414.2.3 Amplifiers......................................................................................................................424.2.4 Rack..............................................................................................................................51

4.2.4.1 Status Parameters Rack............................................................................................514.2.5 Output Stage.................................................................................................................51

4.2.5.1 Startup Parameters Output Stage..............................................................................514.3 Exciter..........................................................................................................................52



4.3.1 Coders (Standards).......................................................................................................524.3.1.1 DVBT2..........................................................................................................................524.3.1.2 DVB-T...........................................................................................................................604.3.1.3 ISDB-T..........................................................................................................................634.3.1.4 ATSC.............................................................................................................................684.3.1.5 DAB...............................................................................................................................704.3.1.6 ATV...............................................................................................................................72

4.3.2 Setting Transmit Frequency and Output Power............................................................814.3.3 Signal Feed...................................................................................................................81

4.3.3.1 Configuring Physical Inputs...........................................................................................824.3.3.2 Input Signal Switchover.................................................................................................85

4.3.4 Controlling Time of Transmission in Single-Frequency Networks (SFN)......................884.3.4.1 Settings.........................................................................................................................91

4.3.5 Using Frequency Control..............................................................................................934.3.6 Precorrection.................................................................................................................96

4.4 Cooling.......................................................................................................................1014.4.1 Configuring Switching Thresholds (Pressure) and Flow Volumes..............................1014.4.2 Configuring Pumps and Fans......................................................................................1044.4.3 Status of Cooling System............................................................................................105

5 Task View Description.......................................................................1075.1 Basic Settings...........................................................................................................1075.2 Parameters: Input Configuration.............................................................................1155.3 System Control..........................................................................................................117

5.3.1 Simple Network Management Protocol (SNMP).........................................................1175.3.1.1 General.......................................................................................................................1175.3.1.2 Settings on Transmitter Side.......................................................................................1175.3.1.3 Settings on Manager Side...........................................................................................1185.3.1.4 Which MIBs Must be Used?........................................................................................1205.3.1.5 Which OIDs from a MIB Must be Used?.....................................................................1215.3.1.6 Setting Alarms.............................................................................................................1225.3.1.7 Testing the SNMP Communication.............................................................................1235.3.1.8 Setting Alarms Using SNMP.......................................................................................1245.3.1.9 Type plates - the ENTITY MIB....................................................................................126



5.4 Maintenance..............................................................................................................1285.4.1 Backup / Restore.........................................................................................................1285.4.2 Software Update.........................................................................................................1295.4.3 Maintenance................................................................................................................1305.4.4 Options........................................................................................................................130

6 Operating the Device Manager.........................................................1336.1 Basic Settings...........................................................................................................133

7 User Administration...........................................................................1437.1 Creating New User Profiles......................................................................................1437.2 Modifying User Profiles (Users and Access Rights).............................................1437.3 Deleting User Profiles...............................................................................................1447.4 Closing Active Sessions..........................................................................................144

Information about this ManualR&STHU9/TMU9


1 Information about this ManualThis manual is part of the documentation for the R&S THU9 transmitter family fromRohde & Schwarz. The individual manuals for the transmitter family have a modularstructure and complement each other.

StructureThe system manual, which is the central and overarching part of the overall documen-tation, describes all the steps involved in installing a transmitter.Operation of the transmitter system after installation and the steps required to put thesystem into operation are described in the operating manual.The service manual describes all maintenance, troubleshooting and service tasks thatcustomers can carry out themselves. At certain points in the transmitter manual, thereader is referred to the appropriate operating manual or service manual.

ContentsThe manuals for the transmitter family describe all activities required for installation,startup, operation, maintenance, troubleshooting and servicing of the transmitter and itscomponent parts. The appendix contains the interface descriptions and the technicaldocumentation.

SafetyAll skilled personnel working with a transmitter or its components have a duty to read theassociated manuals and to follow the safety measures described in the section "Safety"and given at appropriate points in the manual. It must be ensured that the transmitter andthe individual components of the transmitter are used only for their intended use. Allactivities connected with the transmitter or individual transmitter components must becarried out by skilled personnel. If activities require additional skills and qualifications,this is indicated at the appropriate points in the manual.

Symbols and notationThe "warning triangle" symbol refers the reader to potential hazards. The degree of dan-ger is indicated by different signal words next to the warning symbol.Instructions are given in numbered steps. All other formatting options are intended toimprove clarity and are selfexplanatory.

Information about this ManualR&STHU9/TMU9


Safety InstructionsR&STHU9/TMU9


2 Safety Instructions2.1 Safety Instructions for Transmitter Systems and Equip-

ment

Compliance with safety regulationsThe safety regulations specified in this manual must always be complied with.

The following points require special attention: Only qualified technicians are allowed to install and wire the electrical equipment. National and international safety rules and regulations must be observed when

equipping operating facilities and during the assembly and operation of electricalsystems.These include, for example: Protective measures to prevent accidents Protection against overvoltage Isolation of electrical systems Grounding of electrical systems Physical properties and laying of electrical lines and cables Regulations that apply to factories, work areas and special systems

When installing transmitter racks, it is important to observe national accident pre-vention regulations, for example, with regard to: Crushing hazard when working beneath suspended loads Fall hazards when working on ladders Risk of injury when lifting heavy loads

Personal protective equipment (PPE) must be used when installation or repair workis being carried out. Depending on the type of work, it may be necessary to wearprotective clothing such as hard hats, safety gloves, eye protection, etc.

Instruments and systems must not be operated unless their cabinets are closed.Observe the appropriate safety instructions when opening cabinets for maintenanceor repair work.

Isolate all poles when disconnecting instruments and systems from the AC supply.In addition, disconnect all external sources of power, i.e. all measuring cables, exten-sion cables and multipoint connectors (except for special service connectors). Thenwait approx. 5 minutes to ensure that the capacitors in the system are sufficientlydischarged.

Additional information on liquidcooled transmitters: When installing the cooling sys-tem and filling it with coolant (pump and heat exchanger), the applicable regulations

Safety Instructions for Transmitter Systems and Equipment



on working with hazardous products (coolant) must be observed; see the section"Material Safety Data Sheets" under "EC Safety Data Sheet Antifrogen".

2.2 General Safety InstructionsThis section contains general safety instructions applying to all products manufacturedor sold by Rohde & Schwarz.In accordance with IEC215 or EN60215, transmitter systems and their add-on equipmentmust be operated under the responsibility of qualified technicians only. The minimumrequirements for qualified electricians are also defined in the standard "Safety require-ments for radio transmitting equipment".Compliance with all legal and regulatory requirements is a precondition for operating radioequipment and systems. The operator or the operator's authorized representative isresponsible for ensuring compliance with these requirements. They must additionallyensure that the training of the operating personnel satisfies the country-specific require-ments. This includes any periodic training that is necessary.

2.2.1 Safety Instructions

It is essential to read and observe the following instructions and safety informa-tion.All factories and sites of the Rohde & Schwarz company group continuously strive toensure that our products meet the very latest safety standards and that our customersare provided with the highest possible degree of safety. Our products and any additionalequipment that they require are manufactured and tested in accordance with the appli-cable safety regulations. Our quality assurance department regularly checks if thesestandards are met. This product has been manufactured and tested in accordance withthe enclosed EC Certificate of Conformity and left the factory in a condition fully complyingwith the relevant safety standards. In order to keep the product in this condition and toensure that it operates safely, the user must observe all information, warnings andinstructions. Please do not hesitate to contact the Rohde & Schwarz company group ifyou have any queries regarding these safety instructions.Additionally, it is the responsibility of the user to ensure that the product is operated inthe appropriate manner. The product is intended for industrial and laboratory use onlyand, if expressly authorized, also for use in the field, and must never be used in such away that may result in injury to personnel or damage to property. The user shall be heldresponsible if the product is used for purposes other than those specified or in such away that disregards the instructions from the manufacturer. The manufacturer shall notbe liable for any consequences resulting from the product being used for purposes otherthan those for which it is intended.Use of the product for its intended purpose is assumed if the product is used in accord-ance with the specifications given in the associated product documentation and within itsperformance limits (see the data sheet, documentation and the following safety instruc-

General Safety Instructions



tions). Use of the product requires specialist knowledge and, in part, knowledge of theEnglish language. It is therefore important to ensure that the product is operated only byspecialist personnel and persons with the appropriate skills who have received detailedinstruction in how to operate the product. If personnel protective equipment is requiredfor the operation of Rohde & Schwarz products, this is indicated at the appropriate pointin the product documentation. Keep the basic safety instructions and product documen-tation in a safe place and pass them on to subsequent users of the product.Observance of the safety instructions is intended to prevent injury or damage resultingfrom hazards of all types. It is therefore necessary that intended users carefully read andunderstand the following safety instructions before and during use of the product. It isalso essential to observe all other safety instructions (e.g. relating to personnel protection)which are given at appropriate points in the product documentation. In these safetyinstructions, the term "product" refers to all articles sold and marketed by theRohde & Schwarz company group; these include instruments, installations and all acces-sory items.

Signal words and their meaningThe following signal words are used in the product documentation to warn of risks andhazards.

indicates an immediate high-risk hazard which will result in death or serious injury if it isnot avoided.

indicates a potential medium-risk hazard which can result in death or (serious) injury if itis not avoided.

indicates a low-risk hazard which could result in minor or medium injury if it is not avoided.

indicates possible incorrect operation which could result in damage to the product.

These signal words correspond to the definitions customary in the European EconomicArea for civil applications. In addition to this definition, there may also be varying defini-tions used in other economic areas or for military applications. It is therefore important tonote that the signal words described here are used only in connection with the associatedproduct documentation and the associated product. The use of signal words in connection




with non-associated products or non-associated documentation can lead to incorrectinterpretation and thus result in injury and damage.

Operating conditions, positions and locationsThe product should only be operated in the operating conditions, positions and locationsspecified by the manufacturer such that ventilation is not obstructed. Non-observance ofthe manufacturer specifications can result in electric shock, fire and/or serious or (undercertain circumstances) fatal injury. All work must be performed in compliance with thelocal or country-specific safety and accident prevention regulations.

1. Unless otherwise agreed, the following points apply for Rohde & Schwarz products:a) Operating position: housing base at bottomb) IP degree of protection: 2Xc) Degree of soiling: 2d) Overvoltage category: 2e) For indoor use onlyf) Operation up to 2000 m above sea levelg) Transport up to 4500 m above sea levelh) Tolerance for nominal voltage: 10 %i) Tolerance for nominal frequency: 5 %

2. Do not stand the product on surfaces, vehicles, shelves or tables that are not suitablefor weight or stability reasons. When mounting and securing the product on/to objectsor structures (e.g. walls and shelves), always follow the installation instructions fromthe manufacturer. Persons can be injured or even killed if installation is not performedin the way described in the product documentation.

3. Do not place the product on appliances that generate heat (e.g. radiators and fanheaters). The ambient temperature must not exceed the maximum temperaturespecified in the product documentation or in the data sheet. Overheating of the prod-uct can result in electric shock, fire and/or serious or (under certain circumstances)fatal injury.

Electrical safetyNon-observance or inadequate observance of the instructions concerning electricalsafety can result in electric shock, fire and/or serious or (under certain circumstances)fatal injury.

1. Before switching on the product, always make sure that the nominal voltage set atthe product matches the nominal AC voltage of power supply network. If it is neces-sary to change the voltage setting, it may also be necessary to change the associatedAC supply fuse of the product.

2. In the case of products of protection class I with movable power supply line and plugconnector, operation is only permitted at sockets with protective contact and con-nected PE conductor.




3. Any deliberate interruption of the PE conductor (both along the feed line and at theproduct itself) is not permitted. This can result in a potential shock hazard at theproduct. If extension cables or multipoint connectors are used, it must be ensuredthat their safety is checked at regular intervals.

4. If the product is not equipped with a power switch to disconnect it from the powersupply, the plug on the connecting cable must be used to disconnect the power sup-ply. In such cases, it must be ensured that the power plug is easily reachable andaccessible at all times (length of connecting cable approx. 2 m). Function switchesor electronic switches are not suitable for disconnecting the product from the powersupply. If products without power switch are integrated in racks or systems, the dis-connecting device must be provided at system level.

5. Never use the product if the power cable is damaged. Check at regular intervals thatthe power cable is in perfect condition. Take suitable precautions and use suitablecable installation methods to ensure that the power cable cannot be damaged andpersonnel cannot be injured (e.g. as a result of electric shock or tripping over cables).

6. Operation is only permitted in TN/TT supply networks which are fuse-protected withmax. 16 A (higher fuse ratings should only be used after consultation with theRohde & Schwarz company group).

7. Do not insert the plug into dusty or dirty sockets. Insert the plug firmly and completelyinto the sockets provided. Disregard of these points can lead to sparks, fire and/orinjury.

8. Do not overload the sockets, extension cables or multipoint connectors as this cancause fire or electric shocks.

9. In the case of measurements in electrical circuits with voltages Urms > 30 V, appro-priate measures must be taken to avoid all hazards (e.g. suitable measuring equip-ment, fuse protection, current limiting, electrical separation, insulation, etc.).

10. In the case of connections to IT equipment (e.g. PCs or industrial computers), it mustbe ensured that such connections satisfy the applicable IEC609501/EN609501 orIEC610101/EN610101.

11. Unless explicitly permitted, never remove the cover or any part of the housing whilethe product is in operation. Electrical lines and components will otherwise beexposed, which can lead to injury, fire or damage to the product.

12. If the product is connected at a fixed location, the connection between the onsite PEconductor connection and the instrument PE conductor must be set up before anyother connections are made. Installation and connection should only be performedby an electrician.

13. In the case of permanently installed equipment without builtin fuses, circuit breakersor similar protective devices, the supply circuit must be fused in such a way thatpersonnel who have access to the product, as well as the product itself, are ade-quately protected.




14. Every product must be protected against overvoltage (e.g. as a result of a lightningstrike) by means of appropriate overvoltage protection. The operating personnel areotherwise at risk of electric shock.

15. Foreign objects must not be inserted into the openings of the housing. This can causeshort circuits in the product and/or electric shocks, fire or injury.

16. Unless otherwise specified, products are not protected against the penetration offluids; see also the section "Operating conditions, positions and locations", point 1.The instruments must therefore be protected against the penetration of fluids. If thispoint is disregarded, there is a risk of electric shock for the user or of damage to theproduct, which in turn can also endanger personnel.

17. Do not use the product under conditions in which condensation could occur (or mayalready have occurred) in or on the product, e.g. if the product has been moved froma cold environment into a warm environment. Water penetration increases the risk ofelectric shock.

18. Before cleaning the product, fully disconnect it from the power supply (e.g. powersupply network or battery). Clean instruments using a soft, lint-free dust cloth. Neveruse chemical cleaning agents such as alcohol, acetone or cellulose thinner.

Operation

1. Use of the product requires special instruction and full concentration during use. Itmust be ensured that persons who operate the product are fit to do so from a physical,intellectual and mental viewpoint, otherwise there is a risk of injury or damage. It isthe responsibility of the employer/operator to select suitable personnel to use theproduct.

2. Before moving or transporting the product, read and observe the information in thesection "Transport" on page 16.

3. As with all industrially manufactured goods, it is not possible to completely rule outthe use of materials which cause allergies, i.e. "allergens" (e.g. nickel). If, when usingRohde & Schwarz products, allergic reactions occur (e.g. skin rash, frequent sneez-ing, red eyes or respiratory problems), consult a doctor immediately in order to deter-mine the cause and to prevent health problems.

4. Before mechanically and/or thermally processing or dismantling the product, it isessential to refer to the section "Disposal" on page 16, point 1.

5. Owing to the inherent functional design of certain products (e.g. RF radio systems),increased electromagnetic radiation may be produced. In order to protect unborn life,pregnant women must be protected by means of suitable measures. Electromagneticradiation also poses a risk to persons with pacemakers. The employer/operator isobliged to assess and identify workplaces where there is a particular risk of exposureto radiation, and to take precautions to prevent potential hazards.




6. In the event of fire, toxic substances (gases, fluids, etc.) can be discharged from theproduct and damage the health of personnel. If a fire occurs, appropriate measuresmust therefore be taken (e.g. breathing masks and protective clothing).

7. If a laser product is integrated in an Rohde & Schwarz product (e.g. CD/DVD drive),no settings or functions other than those described in the product documentationshould be used in order to prevent injury (e.g. from the laser beam).

Repair and servicing

1. The product should be opened by authorized specialist personnel only. Before anywork is performed on the product or before the product is opened, it must be discon-nected from the supply voltage, otherwise there is a risk of electric shock.

2. Any adjustments, part replacements, maintenance or repairs should be carried outonly by authorized Rohde & Schwarz electricians. If safetyrelevant parts (e.g. powerswitches, power transformers or fuses) are to be changed, they must always bereplaced with original parts. A safety check must be performed after safetyrelevantparts have been replaced (visual inspection, PE conductor test, insulation resistancemeasurement, leaking current measurement, functional check). This ensures that theproduct remains safe to use.

Batteries and rechargeable batteries/cellsNon-observance or inadequate observance of the instructions concerning electricalsafety can result in electric shock, fire and/or serious or (under certain circumstances)fatal injury.Batteries and rechargeable batteries with alkaline electrolyte (e.g. lithiumcells) must be handled in line with EN62133.

1. Cells must not be disassembled, opened or crushed.2. Lithium batteries must not be exposed to high temperatures or fire. Do not store or

place batteries in direct sunlight. Keep cells and batteries clean and dry. Clean dirtyterminals using a dry, clean cloth.

3. Cells and batteries must not be short-circuited. Cells and batteries must not be storedin a potentially hazardous manner in a box or drawer where they can short-circuiteach other or can be short-circuited by other conductive materials. A cell or batteryshould only be taken out of its original packaging when it is to be used.

4. Keep cells and batteries out of the reach of children. If a cell or battery has beenswallowed, seek medical assistance immediately.

5. Do not subject cells and batteries to severe mechanical jolts or impacts.6. If a cell is leaking, do not allow the fluid to come into contact with the skin or eyes. If

the fluid does come into contact with the skin or eyes, wash the affected area withplenty of water and seek medical assistance.

7. There is a risk of explosion if cells or batteries containing alkaline electrolyte (e.g.lithium cells) are replaced or charged incorrectly. To ensure that the product remains




safe to use, always replace cells or batteries with the appropriate R&S type (see thereplacement parts list).

8. Cells or batteries must be recycled and must not be disposed of with residual waste.Rechargeable batteries or batteries containing lead, mercury or cadmium must bedisposed of as special waste. Observe the countryspecific disposal and recyclingregulations.

Transport

1. The product can be extremely heavy. It must therefore be moved and transportedcarefully and, if necessary, using suitable lifting gear (e.g. lift truck) in order to preventinjuries to the back and other parts of the body.

2. Handles on the products are handling aids which are only intended for persons trans-porting the product. The handles are not to be used for securing the product to or ontransport equipment (e.g. cranes, forklift trucks, carts, etc.). It is your responsibility toensure that the products are attached securely to or on suitable transport or liftingequipment. Observe the safety regulations from the manufacturer of the used trans-port or lifting equipment in order prevent injury to personnel and damage to the prod-uct.

3. If you use the product in a vehicle, it is the responsibility of the driver to drive thevehicle in a safe and appropriate manner. The manufacturer shall not be liable foraccidents or collisions. Never use the product in moving vehicle if there is a risk thatthis could distract the vehicle driver. Make sure that the product is adequately securedin order to prevent injury or further damage in the event of an accident.

Disposal

1. If products or their components are processed mechanically and/or thermally beyondthe scope of the operating conditions for which they were intended, hazardous mate-rials (dust containing heavy metals such as lead, beryllium, nickel) can be released.The product should therefore be dismantled by specially trained personnel only.Incorrect dismantling can cause damage to health. The national regulations con-cerning disposal must be observed.

2. If, when handling the product, hazardous materials or operating fluids are encoun-tered which must be disposed of separately (e.g. coolant or engine oils that have tobe changed at regular intervals), the safety instructions from the manufacturer ofthese hazardous materials and operating fluids, and the applicable local disposalregulations must be observed. Also observe any additional relevant safety instruc-tions in the product documentation. Incorrect disposal of hazardous materials oroperating fluids can result in damage to health and the environment.




2.3 Special Hazard Information

2.3.1 Hazards from AC Supply VoltageAll voltages of Urms > 30 V AC or U > 60 V DC must be regarded as constituting a shockhazard. When working with voltages that constitute a shock hazard, appropriate meas-ures must be taken to prevent exposure to danger. Never work on live components. Workon live parts should only be performed in exceptional cases and only if special safetyprecautions are taken.

2.3.1.1 AC Power Supply

Before connecting the AC power supply, it is important to ensure that the power sup-ply specifications given for the system or instruments match the nominal specifica-tions for the local power supply network. The power supply circuit must be protectedby means of fuses in order to prevent overloads and short circuits.

Miniature modules have neutral conductor fuses. As a result, the power supply maystill be connected even after interruption of the circuit by a fuse.

2.3.1.2 Changing Fuses

Fuses which are accessible to the operator should only be changed after the instru-ments have been disconnected from the power supply. They must always be replacedwith fuses that have the same electrical rating, tripping characteristics and breakingcapacity.

Motor protection switches and automatic line fuses in those parts of a transmittersystem that can be accessed by users must be tripped. If their response range isadjustable, the exfactory setting must not be altered. If settings are changed inad-vertently, the correct values specified in this documentation must be set.

2.3.2 Hazards from HighEnergy Electric CircuitsThe instruments contain low-voltage circuits that can be fed from a voltage source withan extremely low impedance (e.g. amplifier operating voltage). These circuits carry dan-gerously high levels of energy. At Rohde & Schwarz, we treat these circuits in the sameway as circuits with hazardous contact voltages. Normally, these circuits are protectedby covers to prevent unintentional contact. The cover has a warning label.In practice it has been repeatedly shown that short circuits caused by small metallic toolsresult in severe burns. For safety reasons, any highenergy electric circuits in areas ofthe equipment that can be accessed by users are concealed by protective covers. Exercise the same amount of caution for measurements on lowimpedance voltages

(e.g. for repair purposes) that you would when performing measurements on oper-ating voltages which constitute a shock hazard.Wear suitable protective gear when necessary.

Special Hazard Information



Before opening any equipment or removing a particular cover, turn off the powersupply and wait 5 minutes to ensure that capacitors have discharged sufficiently.

Do not discharge capacitors by shortcircuiting them.

2.3.3 Hazards from RF Radiation

2.3.3.1 Obligation to Instruct Personnel

The operator must train all personnel in the operation of this transmitter or instrumentin line with EN60215 and/or IEC215. It is essential that these regular training sessionsemphasize the dangers related to high frequency that exist at the respective trans-mitter or instrument. Operating personnel are only authorized to adjust and operatethe equipment after they have completed the respective training sessions and theirparticipation has been documented.

Highenergy RF circuits inside the transmitter or instrument are routed via conventionalremovable RF connectors (e.g. type N). Depending on the output power, the output portsof the transmitter and instrument are equipped with screw-type or plug-in RF lines orducts.If RF lines or modules carry high power, the connection point or the entire module istagged with the general danger warning label (yellow triangle with a black exclamationmark).

2.3.3.2 RF Shielding

Transmitters and instruments from Rohde & Schwarz are shielded so that even in theimmediate vicinity there is no danger from RF radiation when all RF lines are connected.This applies to statutory provisions in Germany, i.e. the regulation concerning electro-magnetic fields:Limits for electrical and magnetic field strengths of highfrequency installations aredefined in the 26th ordinance of the German Federal Government's Emission Control Actof December 16, 1996 (26. BImSchV).

2.3.3.3 Rules When Operating an Amplifier

Disconnecting RF lines that are in operation can result in arcs. These can cause burnsand eye injuries. Operation of the amplifier is only permitted if a main or dummy antenna is connected Never disconnect RF lines when the amplifier is in operation Never open the amplifier or modules when the amplifier is in operation Never operate the amplifier if RF lines are exposed




2.3.3.4 Rules When Working on an Open Amplifier

Operation with RF power is not permitted if the instrument has been opened or covershave been removed.

2.3.4 Conditions for Assembly Work on Cooling SystemThe operator has to ensure that all installation, inspection and assembly work is per-formed by authorized and qualified personnel who have read and understood the oper-ating instructions. Work on the system may be performed only with the system at restand deenergized, i.e. with all electric power supplies disconnected and switched off.All operating and safety instructions must be observed when working on the cooling sys-tem. Nonobservance of the safety instructions can result in injury to personnel, damageto the equipment and forfeiture of all claims for damages.Applicable accident prevention regulations must be observed. Precautions to preventhazards resulting from electrical energy must be taken. Relevant VDE and IEC/IEEEregulations as well as the regulations of local power companies must be observed.When performing installation and assembly work, use only the original parts supplied.Any modifications to the system require the prior agreement of the manufacturer. Toensure the safety of the system, it is important to use only original spare parts and acces-sories approved by the manufacturer. If parts other than the original ones are used oralterations are made to the system, all claims for damages against the manufacturer shallbe forfeited. In such cases, the manufacturer shall not be liable for any consequential orindirect damage.Safe and reliable operation of the system can only be ensured if the system is used forthe intended purpose and the operating instructions are observed. Limit values specifiedin the operating manual must never be exceeded. Elements or subassemblies of thepump unit may be heated by the coolant, especially after extended periods of use underunfavorable conditions.Depending on the coolant return temperature, direct contact with the elements and sub-assemblies of the pump unit (pipes, tubes, reservoirs, etc.) should therefore be avoidedwherever possible.For safety reasons, the coolant should be allowed to cool down to between 5 C and30 C before the system is drained.Inappropriate handling of the coolant may be harmful to your health. For this reason, wearwaterproof gloves and safety goggles during all maintenance and service work involvingdirect contact with the coolant.If your eyes or skin have come into contact with coolant, use tap water to wash it outimmediately and thoroughly. Consult a doctor if necessary. If you have swallowed cool-ant, consult a doctor immediately in all cases. The coolant may contain an antifreezingagent which contains glycol.




2.3.5 Safety Data Sheets for Hazardous SubstancesThis section contains the following safety data sheets in accordance with the directive91/155/ EEC: EC safety data sheet for coolant (Antifrogen N/ water mixture) WOLFRASYN ULAF grease GLT heat sink compoundNote regarding coolantOwing to legal provisions and typeapproval regulations, transmitter systems may insome countries have a different coolant to Antifrogen N. Please contact your localRohde & Schwarz representative for further information.


Safety data sheet in accordance with 2001/58/EC ANTIFROGEN N WATER-MIXTURE 39% Page 1 Substance key: SXR089061 Revision Date: 24.03.2004 Version : 2 - 26 / EU Date of printing : 03.03.2008 1. Identification of the substance/preparation and company

Trade name ANTIFROGEN N WATER-MIXTURE 39%

Use of the substance/preparation. Industry sector : Functional Fluids Type of use : Brine for refrigeration

Identification of the company Clariant Produkte (Deutschland) GmbH 65926 Frankfurt am Main Telephone no. : +49 69 305 18000

Information about the substance/preparation

Div. Functional Chemicals/PRODUCT SAFETY ++49(0)69-305-2092/15315/32251

Emergency telephone number : +49 69 305 6418

2. Composition/information on ingredients

Chemical characterization Monoethylene glycol (1,2-ethane diol) and inhibitors in aqueous solution (39% active)

Hazardous ingredients Ethanediol Concentration : 39 % CAS number : 107-21-1 EINECS number : 203-473-3 Hazard symbols Xn R phrases 22

Sodium nitrite Concentration : < 0,15 % CAS number : 7632-00-0 EINECS number : 231-555-9 Hazard symbols O T N R phrases 8 25 50

3. Hazards identification

Harmful if swallowed. 4. First aid measures

General information Remove soiled or soaked clothing immediately

After inhalation When inhaled remove to fresh air and seek medical aid.

wikowskiTextfeld

wikowskiTextfeld2093.8451.72 1 E-1

Safety data sheet in accordance with 2001/58/EC ANTIFROGEN N WATER-MIXTURE 39% Page 2 Substance key: SXR089061 Revision Date: 24.03.2004 Version : 2 - 26 / EU Date of printing : 03.03.2008

After contact with skin In case of contact with skin wash off immediately with plenty of water

After contact with eyes In case of contact with eyes rinse thoroughly with plenty of water and seek medical advice

After ingestion Summon a doctor immediately.

5. Fire-fighting measures

Suitable extinguishing media Product itself is non-combustible; Fire extinguishing method of surrounding areas must be discussed.

Special hazards from the substance itself, its combustion products or from its vapours In case of fires, hazardous combustion gases are formed: Carbon monoxide (CO)

Special protective equipment for firefighting Use self-contained breathing apparatus

6. Accidental release measures

Personal precautions Ensure adequate ventilation. Wear suitable personal protective equipment.

Environmental precautions Do not allow to enter drains or waterways

Methods for cleaning up/taking up Pick up with absorbent material (eg sand, kieselgur, acid binder, universal binder, sawdust). Dispose of as prescribed

7. Handling and storage

Advice on safe handling Open and handle container with care. Ensure adequate ventilation.

Advice on protection against fire and explosion The product is not combustible

Storage stability

Storage time: > 24 months 8. Exposure controls/personal protection

Ingredients with occupational exposure limits to be monitored



ETHYLENE GLYCOL CAS number : 107-21-1 EU. Indicative Exposure and Directives relating to the protection of risks related to work exposure to chemical, physical, and biological agents. EU Exposure Limit Values Data Revision : 07 2000 Time Weighted Average (TWA):

Values: 52 mg/m3 20 ppm

ETHYLENE GLYCOL CAS number : 107-21-1 EU. Indicative Exposure and Directives relating to the protection of risks related to work exposure to chemical, physical, and biological agents. EU Exposure Limit Values Data Revision : 07 2000 Skin designation: Can be absorbed through the skin.

ETHYLENE GLYCOL CAS number : 107-21-1 EU. Indicative Exposure and Directives relating to the protection of risks related to work exposure to chemical, physical, and biological agents. EU Exposure Limit Values Data Revision : 07 2000 Short Term Exposure Limit (STEL):

Values: 104 mg/m3 40 ppm

General protective measures Do not inhale vapours

Hygiene measures Keep away from foodstuffs and beverages.

Respiratory protection : Use respiratory protection in case of insufficient exhaust ventilation or prolonged exposure Full mask to standard DIN EN 136 Filter A (organic gases and vapours) to standard DIN EN 141 The use of filter apparatus presupposes that the environment atmosphere contains at least 17% oxygen by volume, and does not exceed the maximum gas concentration, usually 0.5% by volume. Relevant guidelines to be considered include EN 136/141/143/371/372 as well as other national regulations.

Hand protection : For long-term exposure:

Butyl rubber gloves Minimum breakthrough time / gloves : 480 min Minimum thickness / gloves 0,7 mm

For short-term exposure (splash protection):

Nitrile rubber gloves. Minimum breakthrough time / gloves : 30 min Minimum thickness / gloves 0,4 mm



These types of protective gloves are offered by various manufacturers. Please note the manufacturers detailed statements, especially about the minimum thickness and the minimum breakthrough time. Consider also the particular working conditions under which the gloves are being used.

Eye protection : safety glasses

9. Physical and chemical properties

Form : Liquid

Colour : light yellow

Odour : perceptible

Freezing point : approx. -25 C Method : ASTM D 1177

Boiling temperature : approx. 106 C ( 1.013 mbar) Method : ASTM D 1120

Flash point : None

Ignition temperature : None

Oxidizing properties : Not applicable

Self-ignition temperature : Not applicable

Lower explosion limit : not determined

Upper explosion limit : not determined

Evaporation rate : not determined

Vapour pressure : < 0,1 mbar (20 C) Method : Calculated by Syracuse.

Density : approx. 1,07 g/cm3 (20 C) Method : DIN 51757

Bulk density : Not applicable

Vapour density in relation to air :

not determined

Solubility in water : (20 C) miscible in all proportions

Soluble in ... : fat not determined

pH value : 7,8 - 8,3 (20 C) Method : DIN EN 1262

Octanol/water partition coefficient (log Pow) :

not determined

Viscosity (kinematic) : approx. 3,1 mm2/s ( 20 C) Method : DIN 51562



Combustion number : Not applicable 10. Stability and reactivity

Thermal decomposition : > 200 C Method : DSC Source : Analogy

Hazardous reactions Incompatible with oxidizing materials.

11. Toxicological information

Acute oral toxicity : LD50 4.000 mg/kg (rat) Source : IUCLID Information based on the main component.

Acute inhalation toxicity : not determined

Acute dermal toxicity : not determined

Irritant effect on skin : non-irritant

Irritant effect on eyes : slightly irritant

Sensitization : not determined

Mutagenicity : not determined

Remarks Vapours and mists cause irritation/burns to eyes and the respiratory tract There is a possibility of kidney damage Poisoning affects the central nervous system The data on toxicology refer to the active ingredient.

12. Ecological information

Biodegradability : 90 % good degradability Method : Zahn-Wellens test

Fish toxicity : LC50 1.500 mg/l (golden orfe)

Remarks If handled correctly it causes no disturbance in treatment plants. The ecological number information is based on the undiluted product.

13. Disposal considerations

Product In accordance with local authority regulations, take to special waste incineration plant


Safety data sheet in accordance with 2001/58/EC ANTIFROGEN N WATER-MIXTURE 39% Page 6 Substance key: SXR089061 Revision Date: 24.03.2004 Version : 2 - 26 / EU Date of printing : 03.03.2008 14. Transport information

ADR not restricted

ADNR not restricted

RID not restricted

IATA not restricted

IMDG not restricted 15. Regulatory information

Labelling in accordance with EC-Directives hazard warning labelling compulsory Classification according to the calculation procedure of the Dangerous Preparations Directive (1999/45/EC).

Hazard symbols Xn Harmful

Hazardous component(s) to be indicated on label Ethanediol

R phrases 22 Harmful if swallowed.

S phrases 26 In case of contact with eyes, rinse immediately with plenty of water and

seek medical advice. 28.2 After contact with skin, wash immediately with water and soap. 37/39 Wear suitable gloves and eye/face protection.

16. Other information

Text of the R-phrases which are allocated to the ingredients/components mentioned in section 2 of this Safety Data Sheet.

22 Harmful if swallowed. 25 Toxic if swallowed. 50 Very toxic to aquatic organisms. 8 Contact with combustible material may cause fire.

The data are based on the current state of our knowledge, and are intended to describe the product with regard to the requirements of safety. The data should not be taken to imply any guarantee of a particular or general specification. It is the responsibility of the user of the product to ensure to his satisfaction that the product is suitable for the intended purpose and method of use. We do not accept responsibility for any harm caused by the use of this information. In all cases, our general conditions of sale apply.


WOLFRASYN ULAF

SAFETY DATA SHEET

Product name

WOLFRASYN ULAF

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

:1.1 Product identifier

1.3 Details of the supplier of the safety data sheet

e-mail address of personresponsible for this SDS

: Material Compliance Management E-Mail: [email protected]

1.2 Relevant identified uses of the substance or mixture and uses advised against

SECTION 1: Identification of the substance/mixture and of the company/undertaking

National contact

1.4 Emergency telephone numberSupplier

Emergency telephonenumber (with hours ofoperation)

: 0049 (0) 897876-700 (24hrs)

KLBER LUBRICATION MNCHEN KGGeisenhausenerstrasse 7D-81379 MnchenTel: +49 (0) 897876-0Fax: +49 (0) 897876-333

Not applicable.

Product code : 003001Product description : Grease

Date of printing : 2011-09-16. Date of issue2011-09-16

Classification R43R52/53

:

:Human health hazards May cause sensitisation by skin contact.:Environmental hazards Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic

environment.

See Section 11 for more detailed information on health effects and symptoms.

Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 97.7%

Percentage of the mixture consisting of ingredient(s) of unknown hazards to theaquatic environment: 97.7%

SECTION 2: Hazards identification

2.1 Classification of the substance or mixtureProduct definition : Mixture

See Section 16 for the full text of the R phrases or H statements declared above.

Classification according to Directive 1999/45/EC [DPD]The product is classified as dangerous according to Directive 1999/45/EC and its amendments.

Ingredients of unknowntoxicity

:

Ingredients of unknownecotoxicity

:

2.2 Label elementsHazard pictograms :

Skin Sens. 1, H317Aquatic Chronic 3, H412

2093.8474.72: - 1 - E-2

WOLFRASYN ULAFConforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

SECTION 2: Hazards identification

:Other hazards which donot result in classification

Not available.

Signal word :Hazard statements :

Prevention :Precautionary statements

Response :

Storage :Disposal :

WarningMay cause an allergic skin reaction.Harmful to aquatic life with long lasting effects.

Wear protective gloves. Avoid release to the environment. Avoid breathing vapour.IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs:Get medical attention.Not applicable.Not applicable.

Supplemental labelelements

Containers to be fittedwith child-resistantfastenings

Not applicable.

Tactile warning of danger Not applicable.

:

:

: Not applicable.

Special packaging requirements

Hazardous ingredients : N-1-naphthylaniline

2.3 Other hazards

Additional warning phrases : Not available.

Substance/mixture Mixture

Occupational exposure limits, if available, are listed in Section 8.

:

Identifiers 67/548/EECProduct/ingredientname

There are no additional ingredients present which, within the current knowledge of the supplier and in theconcentrations applicable, are classified as hazardous to health or the environment and hence require reporting in thissection.

SECTION 3: Composition/information on ingredients

N-1-naphthylaniline EC: 201-983-0CAS: 90-30-2

1-2.5 Xn; R22R43N; R50/53

Acute Tox. 4, H302Skin Sens. 1, H317STOT RE 2, H373oAquatic Acute 1, H400Aquatic Chronic 1,H410

[1]

See Section 16 forthe full text of the R-phrases declaredabove.

%

Type

Regulation (EC) No.1272/2008 [CLP]

Classification

See Section 16 for thefull text of the Hstatements declaredabove.

[1] Substance classified with a health or environmental hazard[2] Substance with a workplace exposure limit[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII

Type

Description polyalkylene glycol oil solid lubricant:

2093.8474.72: - 2 - E-2


Wash out mouth with water. Remove dentures if any. Remove victim to fresh airand keep at rest in a position comfortable for breathing. If material has beenswallowed and the exposed person is conscious, give small quantities of water todrink. Stop if the exposed person feels sick as vomiting may be dangerous. Do notinduce vomiting unless directed to do so by medical personnel. If vomiting occurs,the head should be kept low so that vomit does not enter the lungs. Get medicalattention if adverse health effects persist or are severe. Never give anything bymouth to an unconscious person. If unconscious, place in recovery position and getmedical attention immediately. Maintain an open airway. Loosen tight clothing suchas a collar, tie, belt or waistband.

Skin contact

Immediately flush eyes with plenty of water, occasionally lifting the upper and lowereyelids. Check for and remove any contact lenses. Continue to rinse for at least 10minutes. Get medical attention if irritation occurs.

Wash with plenty of soap and water. Remove contaminated clothing and shoes.Wash contaminated clothing thoroughly with water before removing it, or weargloves. Continue to rinse for at least 10 minutes. Get medical attention. In theevent of any complaints or symptoms, avoid further exposure. Wash clothing beforereuse. Clean shoes thoroughly before reuse.

4.1 Description of first aid measures

Remove victim to fresh air and keep at rest in a position comfortable for breathing. Ifnot breathing, if breathing is irregular or if respiratory arrest occurs, provide artificialrespiration or oxygen by trained personnel. It may be dangerous to the personproviding aid to give mouth-to-mouth resuscitation. Get medical attention if adversehealth effects persist or are severe. If unconscious, place in recovery position andget medical attention immediately. Maintain an open airway. Loosen tight clothingsuch as a collar, tie, belt or waistband. In case of inhalation of decompositionproducts in a fire, symptoms may be delayed. The exposed person may need to bekept under medical surveillance for 48 hours.

Notes to physician In case of inhalation of decomposition products in a fire, symptoms may be delayed.The exposed person may need to be kept under medical surveillance for 48 hours.

Ingestion

Inhalation

Eye contact

:

:

:

:

:

Specific treatments

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. Itmay be dangerous to the person providing aid to give mouth-to-mouth resuscitation.Wash contaminated clothing thoroughly with water before removing it, or weargloves.

SECTION 4: First aid measures

4.2 Most important symptoms and effects, both acute and delayedPotential acute health effects

Inhalation : Exposure to decomposition products may cause a health hazard. Serious effectsmay be delayed following exposure.

No known significant effects or critical hazards.:IngestionSkin contact : May cause an allergic skin reaction.

No known significant effects or critical hazards.:Eye contact

Over-exposure signs/symptoms

Skin contact

Ingestion

Inhalation No specific data.

No specific data.

Adverse symptoms may include the following:irritationredness

:

::

Eye contact : No specific data.

4.3 Indication of any immediate medical attention and special treatment needed

No specific treatment.:

2093.8474.72: - 3 - E-2


Promptly isolate the scene by removing all persons from the vicinity of the incident ifthere is a fire. No action shall be taken involving any personal risk or without suitabletraining.

Hazardous combustionproducts

Hazards from thesubstance or mixture

Decomposition products may include the following materials:carbon dioxidecarbon monoxidenitrogen oxides

In a fire or if heated, a pressure increase will occur and the container may burst.This material is harmful to aquatic life with long lasting effects. Fire watercontaminated with this material must be contained and prevented from beingdischarged to any waterway, sewer or drain.

Fire-fighters should wear appropriate protective equipment and self-containedbreathing apparatus (SCBA) with a full face-piece operated in positive pressuremode. Clothing for fire-fighters (including helmets, protective boots and gloves)conforming to European standard EN 469 will provide a basic level of protection forchemical incidents.

Special protectiveequipment for fire-fighters

Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media

:

:

:

None known.

Suitable extinguishingmedia

:

Unsuitable extinguishingmedia

:

SECTION 5: Firefighting measures

5.2 Special hazards arising from the substance or mixture

5.3 Advice for firefightersSpecial precautions forfire-fighters

:

6.2 Environmentalprecautions

Stop leak if without risk. Move containers from spill area. Approach the releasefrom upwind. Prevent entry into sewers, water courses, basements or confinedareas. Wash spillages into an effluent treatment plant or proceed as follows.Contain and collect spillage with non-combustible, absorbent material e.g. sand,earth, vermiculite or diatomaceous earth and place in container for disposalaccording to local regulations (see section 13). Dispose of via a licensed wastedisposal contractor. Contaminated absorbent material may pose the same hazardas the spilt product. Note: see section 1 for emergency contact information andsection 13 for waste disposal.

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drainsand sewers. Inform the relevant authorities if the product has caused environmentalpollution (sewers, waterways, soil or air). Water polluting material. May be harmfulto the environment if released in large quantities.

Large spill :

Stop leak if without risk. Move containers from spill area. Dilute with water and mopup if water-soluble. Alternatively, or if water-insoluble, absorb with an inert drymaterial and place in an appropriate waste disposal container. Dispose of via alicensed waste disposal contractor.

Small spill :6.3 Methods and materials for containment and cleaning up

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency proceduresFor non-emergencypersonnel

:

For emergency responders :

6.4 Reference to othersections

See Section 1 for emergency contact information.See Section 8 for information on appropriate personal protective equipment.See Section 13 for additional waste treatment information.

No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel fromentering. Do not touch or walk through spilt material. Avoid breathing vapour ormist. Provide adequate ventilation. Wear appropriate respirator when ventilation isinadequate. Put on appropriate personal protective equipment.

If specialised clothing is required to deal with the spillage, take note of anyinformation in Section 8 on suitable and unsuitable materials. See also theinformation in "For non-emergency personnel".

:

:

2093.8474.72: - 4 - E-2


Store in accordance with local regulations. Store in original container protected fromdirect sunlight in a dry, cool and well-ventilated area, away from incompatiblematerials (see section 10) and food and drink. Keep container tightly closed andsealed until ready for use. Containers that have been opened must be carefullyresealed and kept upright to prevent leakage. Do not store in unlabelled containers.Use appropriate containment to avoid environmental contamination.

SECTION 7: Handling and storage

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should beconsulted for any available use-specific information provided in the Exposure Scenario(s).

7.1 Precautions for safe handlingProtective measures :

Advice on generaloccupational hygiene

:

7.2 Conditions for safestorage, including anyincompatibilities

7.3 Specific end use(s)Recommendations :

:Industrial sector specificsolutions

Not available.Not available.

Put on appropriate personal protective equipment (see Section 8). Persons with ahistory of skin sensitization problems should not be employed in any process inwhich this product is used. Do not get in eyes or on skin or clothing. Do not ingest.Avoid breathing vapour or mist. Avoid release to the environment. Keep in theoriginal container or an approved alternative made from a compatible material, kepttightly closed when not in use. Empty containers retain product residue and can behazardous. Do not reuse container.

Eating, drinking and smoking should be prohibited in areas where this material ishandled, stored and processed. Workers should wash hands and face beforeeating, drinking and smoking. Remove contaminated clothing and protectiveequipment before entering eating areas. See also Section 8 for additionalinformation on hygiene measures.

:

Recommended monitoringprocedures

Occupational exposure limits

If this product contains ingredients with exposure limits, personal, workplaceatmosphere or biological monitoring may be required to determine the effectivenessof the ventilation or other control measures and/or the necessity to use respiratoryprotective equipment. Reference should be made to European Standard EN 689 formethods for the assessment of exposure by inhalation to chemical agents andnational guidance documents for methods for the determination of hazardoussubstances.

:

No exposure limit value known.

Appropriate engineeringcontrols

: No special ventilation requirements. Good general ventilation should be sufficient tocontrol worker exposure to airborne contaminants. If this product containsingredients with exposure limits, use process enclosures, local exhaust ventilation orother engineering controls to keep worker exposure below any recommended orstatutory limits.

8.2 Exposure controls

No DELs available.

Predicted effect concentrationsNo PECs available.

SECTION 8: Exposure controls/personal protection


8.1 Control parameters

Derived effect levels

Individual protection measures

2093.8474.72: - 5 - E-2


SECTION 8: Exposure controls/personal protection

Hand protection

Use a properly fitted, air-purifying or air-fed respirator complying with an approvedstandard if a risk assessment indicates this is necessary. Respirator selection mustbe based on known or anticipated exposure levels, the hazards of the product andthe safe working limits of the selected respirator.

Chemical-resistant, impervious gloves complying with an approved standard shouldbe worn at all times when handling chemical products if a risk assessment indicatesthis is necessary.

Safety eyewear complying with an approved standard should be used when a riskassessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts.

Eye/face protection

Respiratory protection :

:

:

Skin protection

Personal protective equipment for the body should be selected based on the taskbeing performed and the risks involved and should be approved by a specialistbefore handling this product.

:

Environmental exposurecontrols

: Emissions from ventilation or work process equipment should be checked to ensurethey comply with the requirements of environmental protection legislation. In somecases, fume scrubbers, filters or engineering modifications to the processequipment will be necessary to reduce emissions to acceptable levels.

Wash hands, forearms and face thoroughly after handling chemical products, beforeeating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Contaminated work clothing should not be allowed out of the workplace. Washcontaminated clothing before reusing. Ensure that eyewash stations and safetyshowers are close to the workstation location.

Hygiene measures :

Body protection :

Other skin protection Appropriate footwear and any additional skin protection measures should beselected based on the task being performed and the risks involved and should beapproved by a specialist before handling this product.

Not available.Melting point/freezing pointInitial boiling point and boilingrange

Vapour pressure

Solubility(ies)

Not available.

Not available.

Insoluble in the following materials: cold water and hot water.

Characteristic.OdourpH

Black.Colour

Auto-ignition temperature

Flash point

Not available.

Not applicable.

Not available.

Not available.

Not available.

Not available.

Viscosity Not available.

Partition coefficient: n-octanol/water

Upper/lower flammability orexplosive limits

Explosive properties

::

::

:

::

:

:

:

:

::

Not available.Oxidising properties :

9.1 Information on basic physical and chemical propertiesAppearance

9.2 Other information

Burning time Not applicable.Burning rate Not applicable.

::

Decomposition temperature : Not available.

SECTION 9: Physical and chemical properties

Flammability (solid, gas) : Not available.

Density : 1.3 g/cm3 [20C]Bulk Density : Not available.

Paste.:Physical state

2093.8474.72: - 6 - E-2


SECTION 9: Physical and chemical properties

No additional information.

10.6 Hazardousdecomposition products

10.4 Conditions to avoid No specific data.

Under normal conditions of storage and use, hazardous decomposition productsshould not be produced.

The product is stable.10.2 Chemical stability

No specific data.

:

:

:

10.5 Incompatible materials :

10.3 Possibility ofhazardous reactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

SECTION 10: Stability and reactivity

10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Potential acute health effects

Acute toxicity

N-1-naphthylaniline LD50 Dermal Rabbit >5000 mg/kg -LD50 Oral Rat 1625 mg/kg -

Product/ingredient name Result Species Dose Exposure

Conclusion/Summary : Not available.

CarcinogenicityConclusion/Summary : Not available.

MutagenicityConclusion/Summary : Not available.

TeratogenicityConclusion/Summary : Not available.

Reproductive toxicityConclusion/Summary : Not available.

Irritation/CorrosionConclusion/Summary : Not available.

SensitiserConclusion/Summary : Not available.

Not available.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity estimates

Oral 2894.5 mg/kg

Route ATE value

Specific target organ toxicity (single exposure)

Specific target organ toxicity (repeated exposure)

Product/ingredient name Category

Aspiration hazard

Route ofexposure

Target organs

Information on the likelyroutes of exposure

:

Not available.

Not available.

N-1-naphthylaniline Category 2 Oral Not determined

2093.8474.72: - 7 - E-2


SECTION 11: Toxicological information

Potential chronic health effects

Inhalation : Exposure to decomposition products may cause a health hazard. Serious effectsmay be delayed following exposure.No known significant effects or critical hazards.:Ingestion

Skin contact : May cause an allergic skin reaction.No known significant effects or critical hazards.:Eye contact

Once sensitized, a severe allergic reaction may occur when subsequently exposedto very low levels.

General :

No known significant effects or critical hazards.Carcinogenicity :No known significant effects or critical hazards.Mutagenicity :No known significant effects or critical hazards.Teratogenicity :

Not available.


Developmental effects : No known significant effects or critical hazards.Fertility effects : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics

Skin contactIngestionInhalation No specific data.

No specific data.Adverse symptoms may include the following:irritationredness

::

:

Eye contact : No specific data.Delayed and immediate effects and also chronic effects from short and long term exposure

Short term exposure

Long term exposure

Potential immediateeffects

Potential delayed effects :

:

Potential immediateeffects

Potential delayed effects :

:

Other information :

Not available.

Not available.

Not available.

Not available.

Not available.

12.3 Bioaccumulative potentialNot available.

Product/ingredient name Aquatic half-life Photolysis Biodegradability

N-1-naphthylaniline - - Not readily

12.1 Toxicity

N-1-naphthylaniline Acute EC50 0.32 mg/l Daphnia 48 hoursAcute LC50 0.44 mg/l Fish - Oncorhynchus mykiss 96 hoursChronic NOEC 0.02 mg/l Daphnia - Daphnia Magna 21 days

Product/ingredient name SpeciesResult Exposure


12.2 Persistence and degradability

N-1-naphthylaniline OECD 301C 0 % - Not readily - 28 days - -

Product/ingredient name Test DoseResult Inoculum


SECTION 12: Ecological information

2093.8474.72: - 8 - E-2


SECTION 12: Ecological information

Mobility Not available.:

12.6 Other adverse effects No known significant effects or critical hazards.

PBT : Not applicable.vPvB : Not applicable.

12.4 Mobility in soilSoil/water partitioncoefficient (KOC)

Not available.:

12.5 Results of PBT and vPvB assessment

:

The classification of the product may meet the criteria for a hazardous waste.Hazardous waste :

The generation of waste should be avoided or minimised wherever possible.Significant quantities of waste product residues should not be disposed of via thefoul sewer but processed in a suitable effluent treatment plant. Dispose of surplusand non-recyclable products via a licensed waste disposal contractor. Disposal ofthis product, solutions and any by-products should at all times comply with therequirements of environmental protection and waste disposal legislation and anyregional local authority requirements.

:Methods of disposal

SECTION 13: Disposal considerations


13.1 Waste treatment methodsProduct

PackagingMethods of disposal :

Special precautions :

The generation of waste should be avoided or minimised wherever possible. Wastepackaging should be recycled. Incineration or landfill should only be consideredwhen recycling is not feasible.This material and its container must be disposed of in a safe way. Care should betaken when handling emptied containers that have not been cleaned or rinsed out.Empty containers or liners may retain some product residues. Avoid dispersal ofspilt material and runoff and contact with soil, waterways, drains and sewers.

-

-

-

-

Not regulated.

-

-

Not regulated. Not regulated.

- - -

SECTION 14: Transport information

ADR/RID IMDG IATA

14.1 UN number

14.2 UN propershipping name

14.3 Transporthazard class(es)

14.4 Packinggroup

Additionalinformation

14.5Environmentalhazards

14.6 Specialprecautions foruser

No. No. No.

Not available. Not available. Not available.

- - -

2093.8474.72: - 9 - E-2


SECTION 14: Transport information

14.7 Transport in bulkaccording to Annex II ofMARPOL 73/78 and the IBCCode

: Not available.

Other EU regulations

Not applicable.Annex XVII - Restrictionson the manufacture,placing on the market anduse of certain dangeroussubstances, mixtures andarticles

:

Europe inventory : All compone

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