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    SPE Distinguished Lecturer Program

    The SPE Distinguished Lecturer Program is funded principally through a

    grant from the SPE Foundation.

    The society gratefully acknowledges the companies that support thisprogram by allowing their professionals to participate as lecturers.

    Special thanks to the American Institute of Mining, Metallurgical, andPetroleum Engineers (AIME) for its contribution to the program.

    Society of Petroleum EngineersDistinguished Lecturer Programwww.spe.org/dl

    Cement and Cementing:

    An Old Technique With a Future?

    Bernard PiotSchlumberger

    Society of Petroleum EngineersDistinguished Lecturer Programwww.spe.org/dl

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    Outline

    Cement

    Cementing: a necessary evil?

    Alternative isolation techniques

    Todays well challenges

    Cement versatility

    Well architecture tool for the future

    4

    Cement

    Material and Regulations

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    0:00 0:30 1:00 1:30 2:00Time(HH:MM)

    0

    20

    40

    60

    80

    100

    Viscosite(Bc)

    Thickening time test (neat class G)

    0:00 0:30 1:00 1:30 2:000

    20

    40

    60

    80

    100

    Consistency,

    Bc

    Time, h

    Portland Cement

    Hydraulic binder

    Suspension (paste or

    slurry) for placement

    Controllable setting

    Solid

    Strong

    Impermeable

    Inexpensive

    Available everywhere

    0 15 30 45 60 75Time (HH)

    0

    500

    1000

    1500

    2000

    2500

    3000

    3500

    4000

    Compressive

    StrengthType

    B

    (psi)

    Strength development test (neat class G)

    Time, h0 15 30 45 60 75

    Compressivestrength,

    psi

    1,000

    500

    1,500

    2,000

    2,500

    3,000

    3,500

    4,000

    0

    6

    History of Oilfield Cement

    Before our era

    Clay, lime

    Ca(OH)2 + CO2 CaCO3

    Roman times

    Pozzolanic cements

    1824: Portland cement

    Selected raw materials

    1903: Portland cement in oil wells

    1917: Oilfield cements

    API created 20 Mar 1919

    1940: ASTM Types 1 to 5

    1948: API Code 32 released

    Became API RP10B in 52

    1952: 6 classes of cement

    1953: API Std 10A

    API Spec 10A in 72 ISO 10426 since 2000

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    Cement Types

    Construction cements

    Common cement

    API classes A, B, C

    Retarded cements

    Deeper wells

    Classes D, E, F

    Pressurized consistometer

    Cementing companies

    Abandoned early 80s

    Plain Portland cement

    Classes G, H

    Quality control, reproducibility

    More universal

    Class J cement

    Replaced by G/H + Silica

    Slag cement

    ~80s Brine resistance

    ~90s Mud compatibility Others

    8

    Use of Cement

    USA

    ~ 80% class H and G

    ~ 10% class A, ~ 10% Class C

    Rest of the world (international service companies)

    >95% class G (often imported)

    Class A or C; or local common cement: preferentially

    Type V (ASTM), or CEM-I 42.5 or 52.5 (EN 197-1) Logistics allowing

    If good and even quality

    If adequate quality control

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    From API to ISO (since 1998)

    API Committee 10

    ISO TC 67 /SC 3/WG 2

    ISO 10426 well cements ISO 10426-1 (ANSI/API 10A) - specification

    ISO 10426-2 (ANSI/API RP 10B-2) - testing

    ISO 10426-3 (ANSI/API RP 10B-3) deepwater wells

    ISO 10426-4 (ANSI/API RP 10B-4) - foam cement

    ISO 10426-5 (ANSI/API RP 10B-5) shrinkage/expansion

    ISO 10426-6 (ANSI/API RP 10B-6) static gel strength

    Other work groups: Evaluation (logs), High Temperature, Deepwater

    10

    Cementing: A Necessary Evil?

    Evolution of Equipment and Technology,

    and an Outline of Their Shortcomings

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    Technology Older Than a Century

    First well cementing ~ 1903

    Perkins Oil Well Cementing Co., Calif.

    Shovel/cement mixer

    First use of an eductor

    Jet mixer invented 1921

    High pressure mixing

    In use till the 1970s

    Still used by some Gravity cement feed

    12

    Primary Cementing Objectives

    Casing anchor (axialsupport)

    Protection against corrosionand erosion

    Support of borehole walls

    Zonal isolation

    Hole

    Casing

    Cement

    Gas zone

    Oil zone

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    Unsuccessful Zonal Isolation

    Risk toHSE

    ACP/SCP Remedialwork

    Early

    water

    prodn

    Loss of

    prodnInterzonalfluid flow

    NPV

    Loss ofLoss of

    wellwell

    14

    Cementing Process at Surface

    Additives

    Water

    Slurry

    Homogenizing/

    ControlPumpingWell

    Dosing and

    Mixing

    Dry Additives

    Cement Bulk

    Blend

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    Handling Dry Cement

    From cutting sacks to

    pneumatic handling

    Storage

    Transport

    Blending

    Typical problems

    Contamination

    Humidity (air)

    Deliverability Homogeneity

    Fully automated blender

    16

    Control of Mixing

    SG -1.0

    +SLURRY SG ~ 1.9

    CEMENT

    SG -3.2=

    Density Control

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    Cement Quality = Slurry Performance

    0

    0.2

    0.4

    0.6

    0.8

    1

    Density

    Viscosity

    Gelation

    Free Fluid

    Stability

    Dehydration

    Pump Time

    Early Strength

    W/C ratio; extender;weighting agent

    Fluid loss agent

    Anti-settling agent

    Dispersant / viscosifier

    Retarder/accelerator

    Viscosity

    GelationPump time

    Free fluidDehydration

    Stability

    Early strength

    Density

    18

    Cementing Additives Key Milestones

    Lignosulphonates and cellulosics

    Sugars and superplasticizing agents (~ 1960s)

    Polyamine/imine ( ~1970s)

    SB Latex ( ~ 1980s)

    Co/ter-polymers AMPS (~ 1980s)

    Temperature stability

    Biopolymers (~ 1990s) Not based on Xanthan gum

    Environmentally friendly additives (end 1990s)

    OSPAR (OSlo-PARis) convention 1998

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    Cementing Process Downhole

    Failures identified 30-40s

    Field practices

    Turbulent displacement

    High Reynolds ~50s

    10 min contact ~60s

    SloFlo / Plug Flow ~70s

    Fluid with yield stress

    Displacement studies

    Yield stress fluids ~end 60s

    Mobility ratio/differentialvelocity ~70s

    Pump as fast as you can

    All semi-empirical

    Very mixed results

    Even in vertical wells

    DIRECTION OF FLOWV = 0

    V = 0

    V max

    20

    Mud Removal Modeling

    More complex wells

    Deviated, horizontal

    & extended reach

    More critical wells

    Deepwater, high-pressure

    high-temperature

    Importance for Zonal Isolation

    Very difficult modeling Computational Fluid Dynamics

    (CFD) tools not applicable

    Eccentricity effects

    Modeling ~ end 80s

    Turbulent/Effective Laminar Flow

    Rheology/Density contrast

    Erodability / PDGM concept

    Polymer muds

    Numerical 2D Modeling (2002)

    Lubrication analytical model (2003)

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    Cement Evaluation Logs

    Sonic logs

    CBL ~60s

    Compensated CBL ~80s

    Segmented Compensated

    Ultrasonic logs

    8 sensors ~80s

    1 rotating sensor ~90s

    Limitation of cement logs

    Strength or Impedance ~80s

    Microannulus/Isolation???

    Microdebonding ~mid-90 s

    Casing interface exclusively

    Flexural Attenuation (2006)

    1 + 3 sensors

    Full cemented annulus width

    3rd interface

    Differentiate lightweight

    cements from liquids Confirm hydraulic isolation

    Visualize casing in borehole

    22

    Alternative Isolation Techniques

    Other Fluids and Mechanical Means

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    Organic Resins

    Very limited applications

    Cost

    Shelf-life

    Sensitivity

    Health, safety, and environment

    Compatibility (water, mud)

    Placement

    24

    Mechanical Systems Complementary to cement

    Casing drilling, expandable casing (EC)

    Swellable elastomer layer

    Exclusive of cement

    EC/Casing with (oil or water) swellable

    packer

    Another form of completion

    May still require cement for most othercasings

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    Todays Well Challenges and

    Versatility of Cement

    26

    New Reservoir Isolation Challenges

    Aging and depleting fields

    Completions at lower pressures

    Steam injection, stimulation

    Workovers and repairs

    Plugging and abandonment

    Exploration and new developments Isolation under higher pressure and temperature Very narrow pore/frac pressures margin

    In deeper water and at colder temperatures

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    Need for Ultra-Low Density

    Conventional CementSlurries

    Directly linked to W/C ratio

    Slurry

    Very low rheology

    Stability

    Set cement

    Very low strength, high

    permeability, very longsetting times

    High performance/high solidcements

    Adapted from concrete industry

    Same water/solid ratio at alldensities

    From 900 to 2800 kg/m3

    Similar rheology

    High strength, low permeability

    28

    Slurry Quality Control?

    Solid Fraction Monitoring

    SG - 1.0

    + CEMENTSG - 3.2 Slurry Density - 1.0 ??

    =

    What if density 1.0?

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    Well Architecture and Logistics

    Lighter isolation-quality cements

    Depleted reservoirs

    Single-stage cementing

    Production liner instead of casing

    Light cements that set faster at

    low temperatures

    Deepwater conductors,

    surface casings

    30

    Cement A

    Cement B

    Is Isolation Durable?Cement is strong, but fragile

    Understanding failures

    P or T increases

    Drilling, milling, repairs

    P or T decreases

    Modeling capability Parameter sensitivity

    rock

    cement

    casing

    P,T

    rock

    cement

    casing

    rock

    cement

    casing

    P,T

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    Isolation Made Durable

    Controlled flexibilityand expansion

    Isolation maintainedduring P, T changes

    From construction toabandonment

    32

    A Tool in Well ArchitectureSummary

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    Cement in the Past

    A necessary evil?

    Commodity?

    34

    Cementing Today

    0

    0.2

    0.4

    0.6

    0.8

    1

    Early strength

    Final strength

    Permeability

    Shrinkage

    Bonding

    Flexibility

    Durability

    Toughness

    Solutions portfolio

    Not only slurryperformance

    Set material properties

    Short/long-term well

    requirements

    Modeling tools Fit-for-purpose,

    cost-effective system

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    Cementing Tomorrow:

    A Technology for the Future

    Oilwell cementing has evolved considerably

    Oilwell cementing will continue to quickly adapt

    New cements from cement manufacturers

    New tools from cementing service industry

    Physically active, chemically re-active or inert materials

    Process design/simulation means

    A true well engineering technology

    An interesting future

    Evolving cement industry

    Still considerable academicresearch

    CO2 emissions

    Important engineeringdevelopment

    Oilfield cementing industry More tools in the toolbox

    Materials, simulators

    Adapt to tomorrows wellrequirements

    A true well engineeringtechnology

    36

    Thank you for your attention