page 1/10 safety data sheet - weber singapore - e.mix tile... · 2020. 11. 10. · page 1/10 safety...

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Safety data sheetaccording to 1907/2006/EC, Article 31

8102.11.82 :noisiveR8102.11.82 etad gnitnirP Version number 1

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* SECTION 1: Identi�cation of the substance/mixture and of the c ompany/undertaking

1.1 Product identi�er

Safety data sheet no.: XXP0149441.2 Relevant identi�ed uses of the substance or mixture and us es advised againstNo further relevant information available.Application of the substance / the mixture Tile adhesive

1.3 Details of the supplier of the safety data sheetManufacturer/Supplier:Emix Industry (S) Pte Ltd2 Venture Drive, 09-10 Vision Exchange, Singapore 608526Phone: +65 6363 5340Fax: +65 6363 59881.4 Emergency telephone number: Phone: +65 6363 5340 (8.00 am - 5.30 pm)

SECTION 2: Hazards identi�cation

2.1 Classi�cation of the substance or mixtureClassi�cation according to R egulation (EC) No 1272/2008Results of in vitro- tests have shown that cement based mixture s with more than 1% of cement causeserious skin irritation and seriou s eye damage, therefore the c lassi�cation of these mixtures regardingH315 and H318 is not based on the calculation of the ingredien ts or the pH in this case.

GHS05 corrosion

Eye Dam. 1 H318 Causes serious eye damage.

GHS07

Skin Irrit. 2 H315 Causes skin irritation.Skin Sens. 1 H317 May cause an allergic skin reaction.STOT SE 3 H335 May cause respiratory irritation.

2.2 Label elementsLabelling according to Re gulation (EC) No 1272/2008The product is classi�ed and labe lled according to the CLP reg ulation.Hazard pictograms

GHS05 GHS07

Signal word Danger

Hazard-determining components of labelling:cement portland, greymilled �y ash

(Contd. on page 2) EUG

Trade name E.Mix Tile Fix 353

Version number 2 Revision: 01.09.2020

Saint-Gobain (Singapore) Pte Ltd

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Hazard statementsH315 Causes skin irritation.H318 Causes serious eye damage.H317 May cause an allergic skin reaction.H335 May cause respiratory irritation.Precautionary statementsP101 If medical advice is needed, have product container or labe l at hand.P102 Keep out of reach of children.P103 Read label before use.P280 Wear protective gloves/prote ctive clothing/ey e protection/face protection.P302+P352 IF ON SKIN: Wash with plenty of water.P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove c ontact

lenses, if present and easy to do. Continue rinsing.P310 Immediately call a POISON CENTER/doctor.P362 Take o� contaminated clothing.P501 Dispose of contents/container in accordance with local/regi onal/national/

international regulations.2.3 Other hazardsWhen the dry powder product comes in contact with water or beco mes wet, a strong alkaline solution isformed. Due to the high alkalinit y, moist/wet mortar can cause skin and eye irritation. There is a risk ofserious damage to health particu larly from prolonged contactThe product contains silica sand with less than 1% of �ne frac tion and therefore is not classi�ed ashazardous; however, pay attention when handling and follow the indications relating to personalprotective equipment.Results of PBT and vPvB assessmentPBT: Does not contain PBT substances.vPvB: Does not contain vPvB substances.

* SECTION 3: Composition/information on ingredients

3.2 Chemical characterisation: MixturesDescription: Mixture of substances listed below with non hazardous additions .Dangerous components:CAS: 14808-60-7EINECS: 238-878-4Index number: 002-315-45-4

Siliciumdioxide (Quartzsand)substance with a Community workplace exposure limit

25-50%

CAS: 65997-15-1EINECS: 266-043-4

cement portland, grey Eye Dam. 1, H318; Skin Irrit. 2, H315; Skin Sens. 1,

H317; STOT SE 3, H335

25-50%

CAS: 65996-69-2EINECS: 266-002-0Reg.nr.: 2119487456-25-0005

milled �y ash Skin Irrit. 2, H315; Eye I rrit. 2, H319; STOT SE 3, H335

5-10%

CAS: 471-34-1EINECS: 207-439-9Reg.nr.: 01-2119486795-18-xxxx

calcium carbonatesubstance with a Community workplace exposure limit

2-5%

SVHC VoidAdditional informationThe product contains silica sand composed of quartz (crystallin e silica) with a �ne fraction below 1%.The respirable fraction has an o ccupational exposure limit valu e (cf. section 8).




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For the wording of the listed haz ard phrases refer to section 1 6.

* SECTION 4: First aid measures

4.1 Description of �rst aid measuresGeneral informationImmediately remove any clo thing soiled by the product.Remove the victim immediately from the danger area. If the pati ent is unwell consult a doctor andpresent this data sheet.After inhalationSupply fresh air and to be sure call for a doctor.In case of unconsciousness place patient stably in side positio nfor transportation.After skin contactRemove contaminated gloves, cloth ing,footwear or other items an d wash thoroughly before re-use.Immediately wash with wate r and soap and rinse thoroughly.If skin irritation continues, consult a doctor.After eye contactRinse opened eye for several mi nutes under running water. Then consult doctor. Rinse liquid should betempered (20-30°C).After swallowingRinse out mouth with water. Do not induce vomiting. Seek medica l attention and present this datasheet.4.2 Most important symptoms and e�ects, both acute and delayedThis powder (wet or dry) may caus e irritation or potentially ir reversible serious inj ury on contact with theeyes. Prolonged contact with mois t skin (due to e.g. sweat or h umidity) can cause skin irritation4.3 Indication of any immediate medical attention and special t reatment neededNo further relevant information available.

SECTION 5: Fire�ghting measures

5.1 Extinguishing mediaSuitable extinguishing agentsUse �re extinguishing methods suitable to surroundingconditions.5.2 Special hazards arising from the substance or mixtureNo further relevant information available.5.3 Advice for �re�ghtersProtective equipment: Use methods suitable to surrounding conditions.

* SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency pr oceduresWear protective clothing.Avoid formation of dust.Ensure adequate ventilation.6.2 Environmental precautions: Do not allow product to reach sew age system or any water course .6.3 Methods and material for containment and cleaning up:Use neutralising agent.




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Dispose of contaminated material as waste according to item 13.Ensure adequate ventilation.6.4 Reference to other sectionsSee Section 7 for information on safe handlingSee Section 8 for information on personal protection equipment.See Section 13 for disposal information.

SECTION 7: Handling and storage

7.1 Precautions for safe handlingThorough dedusting.Keep receptacles tightly sealed.Provide suction extractors if dust is formed.Information about �re - and explosion protection: No special measures required.

7.2 Conditions for safe storag e, including any incompatibilitie sStorageRequirements to be met by storerooms and receptacles:Store only in unopened original receptacles.Information about storage in one common storage facility: Store away from foodstu�s.Further information about storage conditions:Store in cool, dry conditions i n well sealed receptacles.Protect from humidity and water.7.3 Speci�c end use(s) No further relevant information available.

SECTION 8: Exposure controls/personal protection

Additional information about d esign of technical facilities: No further data; see item 7.

8.1 Control parametersIngredients with limit values th at require monitoring at the wo rkplace:DNELsCAS: 471-34-1 calcium carbonateInhalative Derived No E�ect Level 6.36 mg/m³ (worker local long term value)

1.06 mg/m³ (consumer local long term value)

CAS No. Designation of mat erial % Type Value Uni tCAS: 14808-60-7 Siliciumdioxide (Quartzsand)TWA (Italy) Long-term value: 0.025 mg/m³

A2 (r)HTP (Finland) Long-term value: 0.05 mg/m³

alveolijaeCAS: 65997-15-1 cement portland, greyAGW (Germany) Long-term value: 5 E mg/m³

DFGLEP (Spain) Long-term value: 4 mg/m³

fracción respirable: e, d(Contd. on page 5)

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TWA (Italy) Long-term value: 1 mg/m³(e, j), A4

VLE (Portugal) Long-term value: 1 mg/m³Fração resp.;A4,função pulm.,sintomas resp.,asma

HTP (Finland) Long-term value: 5* 1** mg/m³*hengittyvä/inhalerbart, **alveolijae/respirabel

CAS: 471-34-1 calcium carbonateLEP (Spain) Long-term value: 10 mg/m³TWA (Italy) Long-term value: (10) mg/m³

(e)VLE (Portugal) Long-term value: (10) mg/m³

(Irritação)Additional Occupational Exposure Limit Values for possible haza rds during processing:Total inhalable dust: 10 mg/m³Respirable dust (< 5 μm): 4 mg/m³Quartz respirable dust (< 5 µm) : 0,15 mg/m³Additional information:The applicable TRGS 900 (MAK list) was used as the basis for th e preparation and/or revision of thissafety data sheet.

8.2 Exposure controlsPersonal protective equipment:General protective and hygienic measures:The usual precautionary meas ures are to be adhered to when hand ling chemicals.Keep away from foodstu�s, beverages and feed.Immediately remove all soil ed and contaminated clothing.Wash hands before brea ks and at the end of work.Avoid contact with the skin.Avoid contact with the eyes and skin.Use a moisturising skin cream after processing the product.Respiratory protection:In case of brief exposure or low pollution use respiratory �lt er device.In case of intensive or longer e xposure use self-contained resp iratory protective device.Protection of hands:Selection of the glove material on consideration of the penetra tion times, rates of di�usion and thedegradationThe glove material has to be impermeable and resistant to the p roduct/ the substance/ the preparation.Protective gloves.Material of glovesNitrile impregnated cotton gloves complying with the standard E N 374-1.The selection of the suitable gloves does not only depend on th e material, but also on further marks ofquality and varies from manufacturer to manufacturer. As the pr oduct is a preparation of severalsubstances, the resistance of the glove material can not be cal culated in advance and has therefore tobe checked prior to the application.Penetration time of glove materialThe exact break trough time has to be found out by the manufact urer of the protective gloves and hasto be observed.Eye protection: Tightly sealed goggles




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Body protection: Protective work clothing.

* SECTION 9: Physical and chemical properties

9.1 Information on basic physi cal and chemical propertiesGeneral InformationAppearance:

Form: PowderColour: According to product speci�cation

Odour: CharacteristicOdour threshold: Not determined.

pH-value: Alkaline

Change in conditionMelting point/freezing point: Undetermined.Initial boiling point and boiling range: Undetermined.

Flash point: Not applicable

Flammability (solid, gas): Product is not �ammable.

Ignition temperature: Not determined.

Decomposition temperature: Not determined.

Auto-ignition temperature: Product is not sel�gniting.

Explosive properties: Product does not presen t an explosion hazard.

Explosion limits:Lower: Not determined.Upper: Not determined.

Oxidising properties Not determined.

Vapour pressure: Not applicable.

Density at 20 °C: 1.4 g/cm³Relative density Not determined.Vapour density Not applicable.Evaporation rate Not applicable.

Solubility in / Miscibility withWater: Hardens when in contact with water.

Segregation coe�cient (n-octanol/water) logPow: Not determined.

Viscosity:dynamic: Not applicable.kinematic: Not applicable.

Solvent content:EU-VOC (%) 0.00 %EU-VOC (g/L) 0.0 g/lSolids content: 100.0 %




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9.2 Other information None.

* SECTION 10: Stability and reactivity

10.1 Reactivity Not reactive under normal conditions of use10.2 Chemical stability Stable at recommended storage conditionsThermal decomposition / Conditions to be avoided:No decomposition if used a ccording to speci�cations.10.3 Possibility of hazardous reactions Reacts with acids10.4 Conditions to avoidAvoid water ingress/moisture during storage (the product will r eact with moisture and harden).10.5 Incompatible materials: No further relevant information available.10.6 Hazardous decomposition products: No dangerous decomposition products known.

SECTION 11: Toxicological information

11.1 Information on toxicological e�ectsAcute toxicity Based on available data, the cla ssi�cation criteria are not me t.LD/LC50 values relevant for classi�cation:Components Type Value SpeciesCAS: 65997-15-1 cement portland, greyDermal LD50 >2,000 mg/kg (Rabbit)CAS: 471-34-1 calcium carbonateOral LD50 6,450 mg/kg (Rat)Dermal LD50 6,450 mg/kg (Rat)Copolymer of vinyl acetate and ethylene with mineral additives and protective colloidesOral LD50 >2,000 mg/kg (Rat)Primary irritant e�ect:Skin corrosion/irritationCauses skin irritation.Serious eye damage/irritationCauses serious eye damage.Respiratory or skin sensitisationMay cause an allergic skin reaction.CMR e�ects (carcinogenity, mutag enicity and toxicity for repro duction)Germ cell mutagenicity Based on available data, the cla ssi�cation criteria are not me t.Carcinogenicity Based on available data, the cla ssi�cation criteria are not me t.Reproductive toxicity Based on available data, the cla ssi�cation criteria are not me t.STOT-single exposureMay cause respiratory irritation.STOT-repeated exposure Based on available data, the cla ssi�cation criteria are not me t.Aspiration hazard Based on available data, the cla ssi�cation criteria are not me t.

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* SECTION 12: Ecological information

12.1 ToxicityAquatic toxicity: Not classi�ed as harmful to aquatic lifeType of test E�ective concentration Method AssessmentCAS: 65996-69-2 milled �y ashLC50/96h >100 mg/l (Leuciscus idus (Orfe))EC 0/48h >100 mg /l (Daphnia magna)CAS: 471-34-1 calcium carbonateEC50/72h 14 mg/l (Algae)Copolymer of vinyl acetate and ethylene with mineral additives and protective colloidesLC50/96h >100 mg/l (Cyprinus Carpio (common carp))12.2 Persistence and degradability No further relevant information available.12.3 Bioaccumulative potential No further relevant information available.Behaviour in environmental systems:12.4 Mobility in soil No further relevant information available.

Ecotoxical e�ects:Remark:The product contains s ubstances which caus es severe clouding in waterThe product contains substances w hich cause a local pH change a nd thus have a detrimental e�ect on�sh and bacteria.Additional ecological information:

General notes: Do not allow product to reach ground water, water course or sew age system.12.5 Results of PBT and vPvB assessmentPBT: Does not contain PBT substances.vPvB: Does not contain vPvB substances.12.6 Other adverse e�ects No further relevant information available.

* SECTION 13: Disposal considerations

13.1 Waste treatment methodsRecommendationDispose of the product in accor dance with national and local re gulations.Product hardens after adding wat er after 5 to 6 hours and can t hen be disposed of as building rubbish.Possible waste code 17 09 04.European waste cataloguePossible waste code. The concre te waste code depends on the sou rce of the waste.10 13 11 wastes from cement-based composite materials other than those mentioned in 10 13 09

and 10 13 1010 13 14 waste concrete and concrete sludgeHP 4 Irritant - skin irritation and eye damageHP 5 Speci�c Target Organ Toxici ty (STOT)/Aspiration ToxicityHP 13 Sensitising




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Uncleaned packaging:Recommendation: Disposal must be made according to o�cial regulations.Recommended cleaning agent: Thoroughly shake out sacks.

SECTION 14: Transport information

14.1 UN-NumberADR, ADN, IMDG, IATA Void

14.2 UN proper shipping nameADR, ADN, IMDG, IATA Void

14.3 Transport hazard class(es)

ADR, ADN, IMDG, IATAClass Void

14.4 Packing groupADR, IMDG, IATA Void

14.5 Environmental hazards: Not applicable.

14.6 Special precautions for user Not applicable.

14.7 Transport in bulk according to Annex II ofMarpol and the IBC Code Not applicable.

Transport/Additional information: N o t d a n g e r o u s a c c o r d i n g t o t h e a b o v especi�cations.

UN "Model Regulation": Void

* SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation s peci�c for the substance ormixtureRegulation (EC) No 1272/2008 (CLP)Regulation (EC) No 1907/2006 (REA CH) (Candidate List, Annexes X IV and XVII)Labelling according to Re gulation (EC) No 1272/2008 cf. section 2

Directive 2012/18/EUNamed dangerous substances - ANNEX I None of the ingredients is listed.REGULATION (EC) No 1907/2006 ANNEX XVIIThe marketing and use of cement is subject to a restriction on the content of soluble Cr (VI) (REACHAnnex XVII point 47 Chromium VI compounds)15.2 Chemical safety assessment: A Chemical Safety Assessm ent has not been carried out.

SECTION 16: Other informationThis information is based on our present knowledge. However,this shall not constitute a guar antee for any speci�c productfeatures and shall not establis h a legally valid contractualrelationship.




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Relevant phrasesH315 Causes skin irritation.H317 May cause an allergic skin reaction.H318 Causes serious eye damage.H319 Causes serious eye irritation.H335 May cause respiratory irritation.

Department issuing SDS: Technical DepartmentContact:Tan Kim SongPhone: +65 6363 [email protected] and acronyms:RID: Règlement international conc ernant le transport des marcha ndises dangereuses par chemin de fer (Regulations Concerningthe International Transport of Dangerous Goods by Rail)ADR: Accord européen sur le transport des marchandises dangereu ses par Route (European Agreement concerning theInternational Carriage of Dangerous Goods by Road)IMDG: International Maritime Code for Dangerous GoodsIATA: International Air Transport AssociationIATA-DGR: Dangerous Goods Regulati ons by the "International Air Transport Association" (IATA)ICAO: International Civil Aviation OrganisationGHS: Globally Harmonised System of Classi�cation and Labelling of ChemicalsEINECS: European Inventory of Exi sting Commercial Chemical Subs tancesELINCS: European List of Notif ied Chemical SubstancesCAS: Chemical Abstracts Service (division of the American Chemi cal Society)DNEL: Derived No-E�ect Level (REACH)LC50: Lethal concentration, 50 percentLD50: Lethal dose, 50 percentPBT: Persistent, Bioaccumulative and ToxicSVHC: Substances of Very High Concern (REACH regulation)vPvB: very Persistent and very BioaccumulativeSkin Irrit. 2: Skin corrosion/ irritation – Category 2Eye Dam. 1: Serious eye damage/eye irritation – Category 1Eye Irrit. 2: Serious eye damage/ eye irritation – Category 2Skin Sens. 1: Skin sensitisation – Category 1STOT SE 3: Speci�c target organ toxicity (single exposure) – C ategory 3* Data compared to the previous version altered.According to Annex II of the REAC H regulation, the modi�ed sec tions in this version of the Safety DataSheet in comparison with the prev ious one are marked with aster isks.

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