perkinelmer arnelturnkey gc systems

PerkinElmer Arnel Turnkey GC Systems

Petrochemical & Natural Gas Applications

1

Introduction The measurement of semivolatile and volatile compounds in petrochemical feeds, processes and products can be easily accomplished with turnkey analyzers and systems designed to meet accepted standard methods. PerkinElmer has a long-standing relationship with Arnel™, a market leader in customized chromatography solutions, to provide, install, and support a full range of guaranteed analyzers, systems and accessories. This Applications booklet summarizes the features and benefits of individual Clarus™ Arnel GC analyzers that are available for a variety of petrochemical laboratory and process applications, from hydrogen to asphalt analysis. More details and specifications are available for each model by obtaining the referenced companion literature for each product. Almost 100 turnkey analyzers are presented, ensuring that consultation with a PerkinElmer representative will deliver the analyzer that will meet your needs. Tables 1, 2 and 3 below show industry-standard methods compliance for standard model Refinery Gas Analyzers (RGA), Natural Gas Analyzers (NGA) and Trace Sulfur Analyzer Systems. Other standard model analyzers for light gas, chlorine, transformer oil gas, LPG and simulated distillation through detailed hydrocarbon analyses that are compliant with ASTM and various industry standard methods are also summarized in this applications booklet. Table 1. Methods Compliance for RGA Systems

PerkinElmer Arnel RGA Model ASTM Method UOP Method 1001 D1945, D1946, D2597 539 1101 D1945, D1946, D2597 539 1201 D1945, D1946, D2597 539 1301 D1945, D1946, D2597 539 1015, 1016 D1945, D1946, D2597 539, 709 1115, 1116 D1945, D1946, D2597 539, 709 1215, 1216 D1945, D1946, D2597 539, 709 1315, 1316 D1945, D1946, D2597 539, 709

Table 2. Methods Compliance for NGA Systems

PerkinElmer Arnel NGA Model ASTM Methods GPA Methods ISO Methods IP Methods 2001, 2101 D1945, D1946, D2597 2261 6568, 6974-5 None 2201, 2301 D1945 2177, 2261 6568, 6974-5 None 2002, 2102, 2202, 2302 D1945 2261 6974-5 None

2003, 2103, 2203, 2303 D1945, D1946 2261 None None

2206, 2306 None 2165, 2177, 2186 None None 2008 D1946 2286 6975 345 2108 D1946 2286 6974E, 6974-3, 6975 345 2208 D1946 2165, 2186, 2286 6974E, 6974-3, 6975 345 2009, 2109, 2209 D1946 2286 6975 345 2000, 2100, 2200, 2300, D1945, D1946 None None None

2006, 2106 D1945, D1946 None None None 2010, 2110, 2210 D1945 2261 6974-5 None

Table 3. Methods Compliance for Sulfur Analyzer Systems

PerkinElmer Arnel Sulfur Analyzer Model ASTM Methods 4025, 4026, 4027, 4028, 4029, 4227, 4229, 4425, 4428, 4429, 4629 D5504, D5623, D6021

2

Table of Contents Refinery Gas Analyzers Model 1001…………………………………………………………………………………….….5 Model 1015………………………………………………………………………………….…….6 Model 1016………………………………………………………………………………….…….7 Model 1101……………………………………………………………………………….……….8 Model 1115……………………………………………………………………………….……….9 Model 1116………………………………………………………………………………………10 Model 1201……………………………………………………………………………………....11 Model 1215.......................................................................................................................12 Model 1216.......................................................................................................................13 Model 1301.......................................................................................................................14 Model 1315.......................................................................................................................15 Model 1316.......................................................................................................................16 Natural Gas Analyzers Model 2000......................................................................................................................18 Model 2001......................................................................................................................19 Model 2002......................................................................................................................20 Model 2003......................................................................................................................21 Model 2006………………………………………………………………………………...……22 Model 2008......................................................................................................................23 Model 2009......................................................................................................................24 Model 2010......................................................................................................................25 Model 2100......................................................................................................................26 Model 2101......................................................................................................................27 Model 2102......................................................................................................................28 Model 2103......................................................................................................................29 Model 2106......................................................................................................................30 Model 2108......................................................................................................................31 Model 2109......................................................................................................................32 Model 2110......................................................................................................................33 Model 2200………………………………………………………………………………………34 Model 2201………………………………………………………………………………………35 Model 2202………………………………………………………………………………………36 Model 2203………………………………………………………………………………………37 Model 2206………………………………………………………………………………………38 Model 2208………………………………………………………………………………………39 Model 2209………………………………………………………………………………………40 Model 2210………………………………………………………………………………………41 Model 2300………………………………………………………………………………………42 Model 2301………………………………………………………………………………...…….43 Model 2302.......................................................................................................................44 Model 2303.......................................................................................................................45 Model 2306.......................................................................................................................46 Model 2310.......................................................................................................................47 Simulated Distillation Software and Software Enhancements Model 3012.......................................................................................................................49 Model 3013.......................................................................................................................50 Model 3062.......................................................................................................................51

3

Trace Sulfur Analyzers Model 4025.......................................................................................................................53 Model 4026.......................................................................................................................54 Model 4027.......................................................................................................................55 Model 4028.......................................................................................................................56 Model 4029.......................................................................................................................57 Model 4227.......................................................................................................................58 Model 4229.......................................................................................................................59 Model 4425.......................................................................................................................60 Model 4428.......................................................................................................................60 Model 4429.......................................................................................................................60 Model 4629.......................................................................................................................60 Other Analyzers (For light gas, chlorine, transformer oil gas, LPG and simulated distillation through detailed hydrocarbon analyses) Model 4001……………………………………………………………………………………….62 Model 4002……………………………………………………………………………………….62 Model 4003……………………………………………………………………………………….63 Model 4004……………………………………………………………………………………….64 Model 4005……………………………………………………………………………………….65 Model 4006……………………………………………………………………………………….66 Model 4007……………………………………………………………………………………….67 Model 4008……………………………………………………………………………………….67 Model 4009……………………………………………………………………………………….68 Model 4010……………………………………………………………………………………….68 Model 4011……………………………………………………………………………………….69 Model 4012……………………………………………………………………………………….69 Model 4013……………………………………………………………………………………….70 Model 4014……………………………………………………………………………………….71 Model 4015……………………………………………………………………………………….72 Model 4016……………………………………………………………………………………….73 Model 4017……………………………………………………………………………………….74 Model 4018……………………………………………………………………………………….75 Model 4019……………………………………………………………………………………….76 Model 4020……………………………………………………………………………………….77 Model 4021……………………………………………………………………………………….78 Model 4022……………………………………………………………………………………….79 Model 4023……………………………………………………………………………………….80 Model 4024……………………………………………………………………………………….81 Model 4032……………………………………………………………………………………….82 Model 4033……………………………………………………………………………………….82 Model 4034……………………………………………………………………………………….82 Model 4035……………………………………………………………………………………….83 Model 4036……………………………………………………………………………………….84 Model 4037……………………………………………………………………………………….85 Model 4080……………………………………………………………………………………….86 Model 4081……………………………………………………………………………………….63 Model 4082……………………………………………………………………………………….87 Model 4083……………………………………………………………………………………….88 Model 4086……………………………………………………………………………………….89 C5=: Pentenes C6+: C6 hydrocarbons and higher

Refine Model 1001

Model 1015

Model 1016

Model 1101

Model 1115

Model 1116

Model 1201

Model 1215

Model 1216

Model 1301

Model 1315

Model 1316

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Refinery Gas Analyzers

5

Analyzer Description

Typical Chromatogram

Major Features and Benefits

Refinery Gas Analyzers

Refinery Gas Analyzer Model 1001

Published methods met: ASTM D1945, ASTM D1946, ASTM D2597, UOP 539-73, DIN 51872-4 Types of sample analyzed: Gas Compounds separated: H2; O2; N2; CO2; CO; H2S; C1 through C5; C5=, C6+, H2O, NH3 composite peak Guaranteed detection ranges/concentration levels: H2 - 1 to 10%; H2S - 0.1 to 25%; all other components - 0.01 to 100% except the C5=, C6+, H2O, NH3 composite peak - 0.01 to 40% Application note reference number with technical details: D-6620

• Simple, lowest-cost refinery/light hydrocarbon gas analysis solution • Single channel/single thermal conductivity detector (TCD) • Rugged packed columns, no degradation from H2O, NH3 or other common

contaminants • Limited hydrogen detection range (see Model 1101 for full range capability) • 35 - 40 minute analysis time (see Model 1015 for faster analysis time) • Plumbed in sulfur-resistant materials to enhance H2S detection

6


Typical Chromatograms



Published methods met: ASTM D1945, ASTM D1946, ASTM D2597, UOP 539-73, UOP 709, DIN 51872-4 Types of sample analyzed: Gas Compounds separated: H2; O2; N2; CO2; CO; H2S; C1 through C5; C5=, C6+ composite peak Guaranteed detection ranges/concentration levels: H2 - 1 to 10%; H2S - 0.02 to 100%; C1 through C5 - 0.001 to 100% on FID; C5=, C6+ composite peak - 0.002 to 40%; O2, N2, CO2, CO, C1 and C2 hydrocarbons on TCD - 0.01 to 100% Application note reference number with technical details: D-6621

• Rapid, 15-minute analysis time • Dual channel/thermal conductivity detector and flame ionization detector (TCD/FID) • Rugged packed columns, no degradation from H2O, NH3 or other common contaminants • Limited hydrogen detection range (see Model 1115 for full range capability) • Critical 1-butene/isobutylene separation • Includes Model 3062 Software, which contains a merge program to combine multichannel data into one report • Plumbed in sulfur-resistant materials to enhance H2S detection

C5=

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Channel two - FIDChannel one - TCD

7




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H2S


Published methods met: ASTM D1945, ASTM D1946, ASTM D2597, UOP 539-73, UOP 709, DIN 51872-4 Types of sample analyzed: Gas Compounds separated: H2; O2; N2; CO2; CO; H2S; C1 through C5; C5=, C6+, H2O, NH3 composite peak Guaranteed detection ranges/concentration levels: H2 - 1 to 10%; H2S - 0.02 to 100%; C5=, C6+, H2O, NH3 composite peak - 0.2 to 40%; all other components - 0.01 to 100% Application note reference number with technical details: D-6621

• Rapid, 15-minute analysis time • Dual channel/dual thermal conductivity detector (TCD/TCD) • Rugged packed columns, no degradation from H2O, NH3 or other common contaminants • Limited hydrogen detection range (see Model 1116 for full range capability) • Critical butane-1/isobutylene separation • Includes Model 3062 Software, which contains a merge program to combine multichannel data into one report • Plumbed in sulfur-resistant materials to enhance H2S detection

Channel two - TCD Channel one - TCD

8




• Full-range hydrogen detection using separate channel with nitrogen carrier gas • Dual channel/dual thermal conductivity detector (TCD/TCD) • Includes Model 3062 Software, which contains a merge program to combine

multichannel data into one report • Rugged packed columns, no degradation from H2O, NH3 or other common

contaminants • 35 - 40 minute analysis time (see Model 1015 for faster analysis time) • Plumbed in sulfur-resistant materials to enhance H2S detection


Published methods met: ASTM D1945, ASTM D1946, ASTM D2597, UOP 539-73, UOP 539-86, DIN 51872-4 Types of sample analyzed: Gas Compounds separated: He; H2; O2; N2; CO2; CO; H2S; C1 through C5; C5=, C6+, H2O, NH3 composite peak Guaranteed detection ranges/concentration levels: H2S - 0.1 to 25%; all other components - 0.01 to 100% except the C5=, C6+, H2O, NH3 composite peak - 0.01 to 40% Application note reference number with technical details: D-6620, D-6651, D-6653

9





Published methods met: ASTM D1945, ASTM D1946, ASTM D2597, UOP 539-73, UOP 539-86, UOP 709, DIN 51872-4 Types of sample analyzed: Gas Compounds separated: He; H2; O2; N2; CO2; CO; H2S; C1 through C5; C5=, C6+ composite peak Guaranteed detection ranges/concentration levels: H2S - 0.02 to 100%; C1 through C5 - 0.001 to 100% on FID; C5=, C6+ composite peak - 0.002 to 40%; He, H2, O2, N2, CO2, CO, C1, C2 hydrocarbons on TCD - 0.01 to 100% Application note reference number with technical details: D-6621, D-6651, D-6653

• Rapid, 15-minute analysis time • Full-range hydrogen detection using separate channel with nitrogen carrier gas • Three channel/dual thermal conductivity detector and flame ionization detector

(TCD/TCD/FID) • Rugged packed columns, no degradation from H2O, NH3 or other common contaminants • Critical 1-butene/isobutylene separation • Includes Model 3062 Software, which contains a merge program to combine multichannel data into one report • Plumbed in sulfur-resistant materials to enhance H2S detection

C5=

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Channel three - FID Channel one and two - TCD/TCD

(electronically combined into one output )

10




Prop

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H2S


Published methods met: ASTM D1945, ASTM D1946, ASTM D2597, UOP 539-73, UOP 539-86, UOP 709, DIN 51872-4 Types of sample analyzed: Gas Compounds separated: He; H2; O2; N2; CO2; CO; H2S; C1 through C5; C5=, C6+, H2O, NH3 composite peak Guaranteed detection ranges/concentration levels: H2S - 0.02 to 100%; C5=, C6+, H2O, NH3 composite peak - 0.2 to 40%; all other components - 0.01 to 100% Application note reference number with technical details: D-6621, D-6651, D-6653

• Rapid, 15-minute analysis time • Full-range hydrogen detection using separate channel with nitrogen carrier gas • Three channel/three thermal conductivity detector (TCD/TCD/TCD) • Rugged packed columns, no degradation from H2O, NH3 or other common contaminants • Critical 1-butene (butene-1)/isobutylene separation • Includes Model 3062 Software, which contains a merge program to combine multichannel data into one report • Plumbed in sulfur-resistant materials to enhance H2S detection

Hyd

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Etha

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Acet

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H2S

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Met

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Min

utes

Channel three - TCD Channel one and two - TCD/TCD (electronically combined into one output)

11




• Added liquid-sampling capability to Model 1001 • Includes sample-loop purge feature that prevents contamination when changing

sample types, a secondary filter and back pressure regulation for proper liquid sample introduction, plus a vaporization zone for proper liquid sample injection • Single channel/single thermal conductivity detector (TCD) • Rugged packed columns, no degradation from H2O, NH3 or other common

contaminants • Limited hydrogen detection range (see Model 1101 for full-range capability) • 35 - 40 minute analysis time (see Model 1015 for faster analysis time) • Plumbed in sulfur-resistant materials to enhance H2S detection


Published methods met: ASTM D1945, ASTM D1946, ASTM D2597, UOP 539-73, DIN 51872-4 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: H2; O2; N2; CO2; CO; H2S; C1 through C5; C5=, C6+, H2O, NH3 composite peak Guaranteed detection ranges/concentration levels: H2 - 1 to 10%; H2S - 0.1 to 25%; all other components - 0.01 to 100% except the C5=, C6+, H2O, NH3 composite peak - 0.01 to 40% Application note reference number with technical details: D-6620, D-6652, D-6653

12




• Rapid, 15-minute analysis time • Added liquid-sampling capability to FID channel of Model 1015 • Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid

sample introduction, plus a vaporization zone for proper liquid sample injection • Dual channel/thermal conductivity detector and flame ionization detector (TCD/FID) • Rugged packed columns, no degradation from H2O, NH3 or other common contaminants • Limited hydrogen detection range (see Model 1315 for full-range capability) • Critical 1-butene/isobutylene separation • Includes Model 3062 Software, which contains a merge program to combine multichannel data into one report • Plumbed in sulfur-resistant materials to enhance H2S detection


Published methods met: ASTM D1945, ASTM D1946, ASTM D2597, UOP 539-73, UOP 709, DIN 51872-4 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: H2; O2; N2; CO2; CO; H2S; C1 through C5; C5=, C6+ composite peak Guaranteed detection ranges/concentration levels: H2 - 1 to 10%; H2S - 0.02 to 100%; C1 through C5 - 0.001 to 100% on FID; C5=, C6+ composite peak - 0.002 to 40%; O2, N2, CO2, CO, C1, C2s on TCD - 0.01 to 100% Application note reference number with technical details: D-6621, D-6652, D-6653

C5=

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Met

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Prop

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Channel two - FID Channel one - TCD

13




• Rapid, 15-minute analysis time • Added liquid-sampling capability to hydrocarbon channel of Model 1016 • Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid

sample introduction, plus a vaporization zone for proper liquid sample injection • Dual channel/dual thermal conductivity detector (TCD/TCD) • Rugged packed columns, no degradation from H2O, NH3 or other common contaminants • Limited hydrogen detection range (see Model 1316 for full-range capability) • Critical butene – 1/isobutylene separation • Includes Model 3062 Software, which contains a merge program to combine multichannel data into one report • Plumbed in sulfur-resistant materials to enhance H2S detection

Prop

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H2S


Published methods met: ASTM D1945, ASTM D1946, ASTM D2597, UOP 539-73, UOP 709, DIN 51872-4 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: H2; O2; N2; CO2; CO; H2S; C1 through C5; C5=, C6+, H2O, NH3 composite peak Guaranteed detection ranges/concentration levels: H2 - 1 to 10%; H2S - 0.02 to 100%; C5=, C6+, H2O, NH3 composite peak - 0.2 to 40%; all other components - 0.01 to 100% Application note reference number with technical details: D-6621, D-6652, D-6653

Channel two - TCD Channel one - TCD

14





Published methods met: ASTM D1945, ASTM D1946, ASTM D2597, UOP 539-73, UOP 539-86, DIN 51872-4 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: He; H2; O2; N2; CO2; CO; H2S; C1 through C5; C5=, C6+, H2O, NH3 composite peak Guaranteed detection ranges/concentration levels: H2S - 0.1 to 25%; all other components - 0.01 to 100% except the C5=, C6+, H2O, NH3 composite peak - 0.01 to 40% Application note reference number with technical details: D-6620, D-6651, D-6652, D-6653

• Full-range hydrogen detection using separate channel with nitrogen carrier gas • Added liquid-sampling capability to Model 1101 • Includes sample-loop purge feature that prevents contamination when changing

sample types, a secondary filter and back pressure regulation for proper liquid sample introduction, plus a vaporization zone for proper liquid sample injection • Dual channel/dual thermal conductivity detector (TCD/TCD) • Includes Model 3062 Software, which contains a merge program to combine

multichannel data into one report • Rugged packed columns, no degradation from H2O, NH3 or other common

contaminants • 35 - 40 minute analysis time (see Model 1015 for faster analysis time) • Plumbed in sulfur-resistant materials to enhance H2S detection

15




• Rapid, 15-minute analysis time • Full-range hydrogen detection using separate channel with nitrogen carrier gas • Three channel / dual thermal conductivity detector and flame ionization detector

(TCD/TCD/FID) • Added liquid-sampling capability to FID channel of Model 1115 • Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid

sample introduction, plus a vaporization zone for proper liquid sample injection • Rugged packed columns, no degradation from H2O, NH3 or other common

contaminants • Critical 1-butene/isobutylene separation • Includes Model 3062 Software, which contains a merge program to combine multichannel data into one report • Plumbed in sulfur-resistant materials to enhance H2S detection


Published methods met: ASTM D1945, ASTM D1946, ASTM D2597, UOP 539-73, UOP 539-86, UOP 709, DIN 51872-4 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: He; H2; O2; N2; CO2; CO; H2S; C1 through C5; C5=, C6+ composite peak Guaranteed detection ranges/concentration levels: H2S - 0.02 to 100%; C1 through C5 - 0.001 to 100% on FID; C5=, C6+ composite peak - 0.002 to 40%; He, H2, O2, N2, CO2, CO, C1 and C2 hydrocarbons on TCD - 0.01 to 100% Application note reference number with technical details: D-6621, D-6651, D-6652, D-6653

C5=

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Channel three - FID Channel one and two - TCD/TCD (electronically combined into one output)

16




• Rapid, 15-minute analysis time • Full-range hydrogen detection using separate channel with nitrogen carrier gas • Three channel/three thermal conductivity detector (TCD/TCD/TCD) • Added liquid-sampling capability to FID channel of Model 1116 • Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid

sample introduction, plus a vaporization zone for proper liquid sample injection • Rugged packed columns, no degradation from H2O, NH3 or other common contaminants • Critical butane-1/isobutylene separation • Includes Model 3062 Software, which contains a merge program to combine multichannel data into one report • Plumbed in sulfur-resistant materials to enhance H2S detection

Prop

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H2S


Published methods met: ASTM D1945, ASTM D1946, ASTM D2597, UOP 539-73, UOP 539-86, UOP 709, DIN 51872-4 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: He; H2; O2; N2; CO2; CO; H2S; C1 through C5; C5=, C6+, H2O, NH3 composite peak Guaranteed detection ranges/concentration levels: H2S - 0.02 to 100%; C5=, C6+, H2O, NH3 composite peak - 0.2 to 40%; all other components - 0.01 to 100% Application note reference number with technical details: D-6621, D-6651, D-6652, D-6653

Hyd

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Etha

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Acet

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H2S

Oxy

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Nitr

ogen

Met

hane

CO 15

Min

utes

Channel three - TCD Channel one and two - TCD/TCD (electronically combined into one output )

Natural Model 2000

Model 2001

Model 2002

Model 2003

Model 2006

Model 2008

Model 2009

Model 2010

Model 2100

Model 2101

Model 2102

Model 2103

Model 2106

Model 2108

Model 2109

Model 2110

Model 2200

Model 2201

Model 2202

Model 2203

Model 2206

Model 2208

Model 2209

Model 2210

Model 2300

Model 2301

Model 2302

Model 2303

Model 2306

Model 2310

Na

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Natural Gas Analyzers

18




• Simple, low-cost solution • Single channel/single FID • Only hydrocarbons detected and measured, no interference from air or CO2 • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software available containing template for heating value calculation and other sample specifications • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon

unsaturates. LPG samples can not be analyzed on this analyzer without modification. See Model 4036 or Model 4037, which meets ASTM D2163 methodology for LPG.

Natural Gas Analyzer Model 2000

2 4 6 8 10 12 14Time (min)

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ane

Etha

ne

C6+

Met

hane

Published methods met: ASTM D1945 (precision statement only) Types of sample analyzed: Gas Compounds separated: C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: All components except C6+ - 0.005 to 100%, C6+ - 0.005 to 10% Application note reference number with technical details: D-6622, D-6623

All compounds measured by FID

19




• Simple, low-cost solution • Single channel/single thermal conductivity detector (TCD) • No separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon

unsaturates. LPG samples can not be analyzed on this analyzer without modification. See Model 4036 or Model 4037, which meets ASTM D2163 methodology for LPG analysis


Published methods met: ASTM D1945, GPA 2261, ISO 6568, ISO 6974-5, DIN 51872-5 Types of sample analyzed: Gas Compounds separated: O2, N2 composite; CO2; H2S; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: O2, N2 composite and CO2 – 0.01 to 20%, C1 through C5 - 0.01 to 100%, H2S - 0.1 to 25%, C6+ composite - 0.01 to 10% Application note reference number with technical details: D-6622, D-6624

0 2 4 6 8 10 12 14Time (min)

i - P

enta

ne

n - P

enta

ne

i - B

utan

e

n - B

utan

e

Prop

ane

Etha

neC

O2

C6+

O2/N

2

Met

hane

H2S

20




• Baseline separation of O2, N2 composite and methane, argon measurement • Single channel/single thermal conductivity detector (TCD) • No separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon

unsaturates. LPG samples can not be analyzed on this analyzer without modification. See Model 4036 or Model 4037, which meets ASTM D2163 methodology for LPG analysis.


Published methods met: ASTM D1945, GPA 2261, ISO 6974-5, DIN 51872-5 Types of sample analyzed: Gas Compounds separated: Ar; O2, N2 composite; CO2; H2S; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: Ar – 0.01 to 4%, H2S - 0.1 to 5%, C6+ composite - 0.01 to 10%, all other components - 0.01 to 100%, Application note reference number with technical details: D-6622, D-6625

10 20Time (min)

Prop

ane

C6+ i -

But

ane

n - B

utan

e

i - P

enta

ne

n - P

enta

ne

O2 /

N2

Met

hane

Argo

n

CO

2

Etha

ne

H2S

21




• Single channel/single thermal conductivity detector (TCD) • Separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon



Published methods met: ASTM D1945, ASTM D1946, GPA 2261, DIN 51872-5 Types of sample analyzed: Gas Compounds separated: O2; N2; CO2; H2S; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: O2 and C6+ composite - 0.01 to 10%, N2 – 0.01 to 20%, H2S - 0.1 to 5%, CO2 and C1 through C5 - 0.01 to 100%, Application note reference number with technical details: D-6622, D-6626

2 4 6 8 10 12 14Time (min)

C6+

H2S

Prop

ane

i-But

ane

n-Bu

tane

i-Pen

tane

n-Pe

ntan

e

CO

2Et

hane

Oxy

gen

Nitr

ogen

Met

hane

22




Published methods met: None Types of sample analyzed: Gas Compounds separated: O2, N2 composite; CO2; H2S; C1 through C10; C6+ composite Guaranteed detection ranges/concentration levels: Channel one (TCD): O2, N2 composite and CO2 – 0.01 to 20%, C1 through C5 - 0.01 to 100%, H2S - 0.1 to 25%, C6+ composite - 0.01 to 10%, Channel two (FID): C4 to C10 - 0.005 to 100% (depends upon split ratio) Application note reference number with technical details: D-6622, D-6627

• Capillary channel added to Model 2001 • Dual channel/thermal conductivity detector (TCD), flame ionization detector (FID) • No separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush on TCD channel. • Packed and capillary columns, extended hydrocarbon analysis to C10 • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon



0 2 4 6 8 10 12 14Time (min)

i - P

enta

ne

n - P

enta

ne

i - B

utan

e

n - B

utan

e

Prop

ane

Etha

neC

O2

C6+

O2/N

2

Met

hane

H2S

Buta

nes

Pent

anes

Hex

ane

Hep

tane

Oct

ane

p-Xy

lene

n-Pr

opyl

benz

ene

Dec

ane

n-Bu

tylb

enze

ne

Time (min)2010

Channel one - TCD Channel two - FID

23




Published methods met: ASTM D1946, GPA 2286, IP 345, ISO 6975 Types of sample analyzed: Gas Compounds separated: O2; N2; CO2; H2S; C1 through C10; C6+ composite Guaranteed detection ranges/concentration levels: Channel one (TCD): O2 and C6+ composite - 0.01 to 10%, N2 – 0.01 to 20%, H2S - 0.1 to 5%, CO2 and C1 through C5 - 0.01 to 100% Channel two (FID): C4 to C10 - 0.005 to 100% (depends upon split ratio) Application note reference number with technical details: D-6622, D-6628

• Capillary channel added to Model 2003 • Dual channel/thermal conductivity detector (TCD), flame ionization detector (FID) • Separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush on TCD channel. • Packed and capillary columns, extended hydrocarbon analysis to C10 • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon



2 4 6 8 10 12 14Time (min)

C6+

H2S

Prop

ane

i-But

ane

n-Bu

tane

i-Pen

tane

n-Pe

ntan

e

CO

2Et

hane

Oxy

gen

Nitr

ogen

Met

hane

Channel one - TCD

Buta

nes

Pent

anes

Hex

ane

Hep

tane

Oct

ane

p-Xy

lene

n-Pr

opyl

benz

ene

Dec

ane

n-Bu

tylb

enze

ne

Time (min)2010

Channel two - FID

24




Published methods met: ASTM D1946, GPA 2286, IP 345, ISO 6975 Types of sample analyzed: Gas Compounds separated: O2; N2; CO2; H2S; C1 through C10 Guaranteed detection ranges/concentration levels: Channel one (TCD): O2 - 0.01 to 10%, N2 – 0.01 to 20%, H2S - 0.1 to 5%, CO2 and C1 through C4 - 0.01 to 100% Channel two (FID): C4 to C10 - 0.005 to 100% (depends upon split ratio) Application note reference number with technical details: D-6622, D-6629

• “Fast Model 2008” – C4 + compounds backflushed to vent on TCD channel • Dual channel/thermal conductivity detector (TCD), flame ionization detector (FID) • Separation and measurement of O2 and N2 individually • Packed and capillary columns, extended hydrocarbon analysis to C10 • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon



Channel one - TCD

Buta

nes

Pent

anes

Hex

ane

Hep

tane

Oct

ane

p-Xy

lene

n-Pr

opyl

benz

ene

Dec

ane

n-Bu

tylb

enze

ne

Time (min)2010

Channel two - FID

25




• Model 2001 with C6+ backflush to FID channel (no water interference/better sensitivity) • Full-range hydrogen detection using separate channel with nitrogen carrier gas • Three channel (TCD/TCD/FID) • No separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon



Published methods met: ASTM D1945, GPA 2261, ISO 6974-5 Types of sample analyzed: Gas Compounds separated: O2, N2 composite; CO2; H2S; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: Channel one (TCD): O2, N2 composite and CO2 – 0.01 to 20%; He, H2, C1 through C5 - 0.01 to 100%; H2S - 0.1 to 25% Channel two (FID): C6+ composite - 0.001 to 100% Application note reference number with technical details: D-6622, D-6630

i-But

ane

N-Bu

tane

Prop

ane

I-Pen

tane

Met

hane

n-Pe

ntan

e

Etha

ne

Air

Carb

on D

ioxi

de

H 2S

TCD channel – C6+ backflushed to FID

26




• Full-range hydrogen detection using separate channel with nitrogen carrier gas • Dual channel/thermal conductivity detector, flame ionization detector (TCD/FID) • Hydrocarbons detected and measured, no interference from air or CO2 • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software included containing template for heating value calculation and other sample specifications, plus merge and custom report formatting • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon



Published methods met: ASTM D1945 (precision statement only) Types of sample analyzed: Gas Compounds separated: He; H2; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: He, H2 – 0.01 to 100%; all other components except C6+ composite - 0.005 to 100%; C6+ - 0.005 to 10% Application note reference number with technical details: D-6622, D-6623, D-6651

H2 measured by TCD and the remaining compounds measured by FID

27




• Full-range hydrogen detection using separate channel with nitrogen carrier gas • Dual channel/dual thermal conductivity detector (TCD/TCD) • No separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon



Published methods met: ASTM D1945, GPA 2261, ISO 6568, ISO 6974-5, DIN 51872-5 Types of sample analyzed: Gas Compounds separated: He; H2; O2, N2 composite; CO2; H2S; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: He, H2, C1 through C5 – 0.01 to 100%; O2, N2 composite and CO2 – 0.01 to 20%, H2S - 0.1 to 25%, C6+ composite - 0.01 to 10% Application note reference number with technical details: D-6622, D-6624, D-6651

H2 measured in one TCD utilizing a nitrogen carrier gas and the remaining compounds measured in a second TCD utilizing a helium carrier gas.

28




• Baseline separation of O2, N2 composite and methane, argon measurement • Full-range hydrogen detection using separate channel with nitrogen carrier gas • Dual channel/dual thermal conductivity detector (TCD/TCD) • No separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon



Published methods met: ASTM D1945, GPA 2261, ISO 6974-5, DIN 51872-5 Types of sample analyzed: Gas Compounds separated: He; H2; Ar; O2, N2 composite; CO2; H2S; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: Ar – 0.01 to 4%, H2S - 0.1 to 5%, C6+ composite - 0.01 to 10%, all other components - 0.01 to 100%, Application note reference number with technical details: D-6622, D-6625, D-6651


29




• Full-range hydrogen detection using separate channel with nitrogen carrier gas • Dual channel/dual thermal conductivity detector (TCD/TCD) • Separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon



Published methods met: ASTM D1945, ASTM D1946, GPA 2261, DIN 51872-5 Types of sample analyzed: Gas Compounds separated: He; H2; O2; N2; CO2; H2S; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: O2 and C6+ composite - 0.01 to 10%; N2 – 0.01 to 20%; H2S - 0.1 to 5%; He, H2, CO2 and C1 through C5 - 0.01 to 100%, Application note reference number with technical details: D-6622, D-6626, D-6651


30




Published methods met: None Types of sample analyzed: Gas Compounds separated: He; H2; O2, N2 composite; CO2; H2S; C1 through C10; C6+ composite Guaranteed detection ranges/concentration levels: Channel one (TCD): O2, N2 composite and CO2 – 0.01 to 20%; He, H2, C1 through C5 - 0.01 to 100%; H2S - 0.1 to 25%; C6+ composite - 0.01 to 10%; Channel two (FID): C4 to C10 - 0.005 to 100% (depends upon split ratio) Application note reference number with technical details: D-6622, D-6627, D-6651

• Capillary channel added to Model 2101 • Full-range hydrogen detection using separate channel with nitrogen carrier gas • Three channel/ two thermal conductivity detector, flame ionization detector (TCD/TCD/FID) • No separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush on TCD channel. • Packed and capillary columns, extended hydrocarbon analysis to C10 • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon



Buta

nes

Pent

anes

Hex

ane

Hep

tane

Oct

ane

p-Xy

lene

n-Pr

opyl

benz

ene

Dec

ane

n-Bu

tylb

enze

ne

Time (min)2010

Channel one and two – TCD/TCD Channel two - FID

31




Published methods met: ASTM D1946, GPA 2286, IP 345, ISO 6974E, ISO 6974-3, ISO 6975 Types of sample analyzed: Gas Compounds separated: He; H2; O2; N2; CO2; H2S; C1 through C10; C6+ composite Guaranteed detection ranges/concentration levels: Channel one (TCD): He, H2, O2 and C6+ composite - 0.01 to 10%; N2 – 0.01 to 20%; H2S - 0.1 to 5%; CO2 and C1 through C5 - 0.01 to 100% Channel two (FID): C4 to C10 - 0.005 to 100% (depends upon split ratio) Application note reference number with technical details: D-6622, D-6628, D-6651

• Capillary channel added to Model 2103 • Full-range hydrogen detection using separate channel with nitrogen carrier gas • Three channel (TCD/TCD/FID) • Separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush on TCD channel. • Packed and capillary columns, extended hydrocarbon analysis to C10 • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon



Channel one and two - TCD

Buta

nes

Pent

anes

Hex

ane

Hep

tane

Oct

ane

p-Xy

lene

n-Pr

opyl

benz

ene

Dec

ane

n-Bu

tylb

enze

ne

Time (min)2010

Channel three - FID

32




Published methods met: ASTM D1946, GPA 2286, IP 345, ISO 6975 Types of sample analyzed: Gas Compounds separated: He; H2; O2; N2; CO2; H2S; C1 through C10 Guaranteed detection ranges/concentration levels: Channel one (TCD): O2 - 0.01 to 10%; N2 – 0.01 to 20%; H2S - 0.1 to 5%; He, H2, CO2 and C1 through C4 - 0.01 to 100% Channel two (FID): C4 to C10 - 0.005 to 100% (depends upon split ratio) Application note reference number with technical details: D-6622, D-6629, D-6651

• “Fast Model 2008” – C4 + compounds backflushed to vent on main TCD channel • Full-range hydrogen detection using separate channel with nitrogen carrier gas • Three channel (TCD/TCD/FID) • Separation and measurement of O2 and N2 individually • Packed and capillary columns, extended hydrocarbon analysis to C10 • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon



Channel one and two – TCD/TCD

Buta

nes

Pent

anes

Hex

ane

Hep

tane

Oct

ane

p-Xy

lene

n-Pr

opyl

benz

ene

Dec

ane

n-Bu

tylb

enze

ne

Time (min)2010

Channel two - FID

33




• Model 2101 with C6+ backflush to FID channel (no water interference/better sensitivity) • Full-range hydrogen detection using separate channel with nitrogen carrier gas • Three channel (TCD/TCD/FID) • No separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon



Published methods met: ASTM D1945, GPA 2261, ISO 6974-5 Types of sample analyzed: Gas Compounds separated: He; H2; O2, N2 composite; CO2; H2S; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: Channel one (TCD): O2, N2 composite and CO2 – 0.01 to 20%; He, H2, C1 through C5 - 0.01 to 100%; H2S - 0.1 to 25% Channel two (FID): C6+ composite - 0.001 to 100% Application note reference number with technical details: D-6622, D-6630, D-6651

i-But

ane

N-Bu

tane

Prop

ane

I-Pen

tane

Met

hane

n-Pe

ntan

e

Etha

ne

Air

Carb

on D

ioxi

de

H 2S

He, H2 measured by TCD using Nitrogen carrier gas. C6+ backflushed to FID, all other compounds measured using TCD with Helium carrier gas.

34





2 4 6 8 10 12 14Time (min)

i - P

enta

ne

n - P

enta

ne

i - B

utan

e

n - B

utan

e

Prop

ane

Etha

ne

C6+

Met

hane

Published methods met: ASTM D1945 (precision statement only) Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: All components except C6+ - 0.005 to 100%, C6+ - 0.005 to 10% Application note reference number with technical details: D-6622, D-6623, D-6652

• Added liquid-sampling capability to Model 2000 • Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid

sample introduction, plus a vaporization zone for proper liquid sample injection • Only hydrocarbons detected and measured, no interference from air or CO2 • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software available containing template for heating value calculation and other sample specifications • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon


All compounds measured by FID

35




Published methods met: ASTM D1945, GPA 2177, GPA 2261, ISO 6568, ISO 6974-5, DIN 51872-5 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: O2, N2 composite; CO2; H2S; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: O2, N2 composite and CO2 – 0.01 to 20%, C1 through C5 - 0.01 to 100%, H2S - 0.1 to 25%, C6+ composite - 0.01 to 10% Application note reference number with technical details: D-6622, D-6624, D-6652

• Added liquid-sampling capability to Model 2001 • Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid

sample introduction, plus a vaporization zone for proper liquid sample injection • Single channel/single TCD • No separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon



0 2 4 6 8 10 12 14Time (min)

i - P

enta

ne

n - P

enta

ne

i - B

utan

e

n - B

utan

e

Prop

ane

Etha

neC

O2

C6+

O2/N

2

Met

hane

H2S

36




• Baseline separation of O2, N2 composite and methane, argon measurement • Added liquid-sampling capability to Model 2002 • Single channel/single thermal conductivity detector (TCD) • Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid

sample introduction, plus a vaporization zone for proper liquid sample injection • No separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon



Published methods met: ASTM D1945, GPA 2261, ISO 6974-5, DIN 51872-5 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: Ar; O2, N2 composite; CO2; H2S; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: Ar – 0.01 to 4%, H2S - 0.1 to 5%, C6+ composite - 0.01 to 10%, all other components - 0.01 to 100%, Application note reference number with technical details: D-6622, D-6625, D-6652

10 20Time (min)

Prop

ane

C6+ i -

But

ane

n - B

utan

e

i - P

enta

ne

n - P

enta

ne

O2 /

N2

Met

hane

Argo

n

CO

2

Etha

ne

H2S

37




• Single channel/single thermal conductivity detector (TCD) • Separation and measurement of O2 and N2 individually • Added liquid-sampling capability to Model 2003 • Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid

sample introduction, plus a vaporization zone for proper liquid sample injection • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon



Published methods met: ASTM D1945, ASTM D1946, GPA 2261, DIN 51872-5 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: O2; N2; CO2; H2S; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: O2 and C6+ composite - 0.01 to 10%, N2 – 0.01 to 20%, H2S - 0.1 to 5%, CO2 and C1 through C5 - 0.01 to 100%, Application note reference number with technical details: D-6622, D-6626, D-6652

2 4 6 8 10 12 14Time (min)

C6+

H2S

Prop

ane

i-But

ane

n-Bu

tane

i-Pen

tane

n-Pe

ntan

e

CO

2Et

hane

Oxy

gen

Nitr

ogen

Met

hane

38




Published methods met: None Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: O2, N2 composite; CO2; H2S; C1 through C10; C6+ composite Guaranteed detection ranges/concentration levels: Channel one (TCD): O2, N2 composite and CO2 – 0.01 to 20%, C1 through C5 - 0.01 to 100%, H2S - 0.1 to 25%, C6+ composite - 0.01 to 10%, Channel two (FID): C4 to C10 - 0.005 to 100% (depends upon split ratio) Application note reference number with technical details: D-6622, D-6627, D-6652

• Capillary channel added to Model 2001 • Added liquid sampling capability to Model 2006 • Dual channel/thermal conductivity detector (TCD), flame ionization detector (FID) • Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid

sample introduction, plus a vaporization zone for proper liquid sample injection • No separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush on TCD channel. • Packed and capillary columns, extended hydrocarbon analysis to C10 • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon


Channel two - FID


0 2 4 6 8 10 12 14Time (min)

i - P

enta

ne

n - P

enta

ne

i - B

utan

e

n - B

utan

e

Prop

ane

Etha

neC

O2

C6+

O2/N

2

Met

hane

H2S

Buta

nes

Pent

anes

Hex

ane

Hep

tane

Oct

ane

p-Xy

lene

n-Pr

opyl

benz

ene

Dec

ane

n-Bu

tylb

enze

ne

Time (min)2010

Channel one - TCD

39




Published methods met: ASTM D1946, GPA 2165, GPA 2186, GPA 2286, IP 345, ISO 6975 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: O2; N2; CO2; H2S; C1 through C10; C6+ composite Guaranteed detection ranges/concentration levels: Channel one (TCD): O2 and C6+ composite - 0.01 to 10%, N2 – 0.01 to 20%, H2S - 0.1 to 5%, CO2 and C1 through C5 - 0.01 to 100% Channel two (FID): C4 to C10 - 0.005 to 100% (depends upon split ratio) Application note reference number with technical details: D-6622, D-6628, D-6652

• Capillary channel added to Model 2003 • Added liquid-sampling capability to Model 2008 • Dual channel/thermal conductivity detector (TCD), flame ionization detector (FID) • Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid

sample introduction, plus a vaporization zone for proper liquid sample injection • Separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush on TCD channel. • Packed and capillary columns, extended hydrocarbon analysis to C10 • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon



2 4 6 8 10 12 14Time (min)

C6+

H2S

Prop

ane

i-But

ane

n-Bu

tane

i-Pen

tane

n-Pe

ntan

e

CO

2Et

hane

Oxy

gen

Nitr

ogen

Met

hane

Channel one - TCD

Buta

nes

Pent

anes

Hex

ane

Hep

tane

Oct

ane

p-Xy

lene

n-Pr

opyl

benz

ene

Dec

ane

n-Bu

tylb

enze

ne

Time (min)2010

Channel two - FID

40




Published methods met: ASTM D1946, GPA 2286, IP 345, ISO 6975 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: O2; N2; CO2; H2S; C1 through C10 Guaranteed detection ranges/concentration levels: Channel one (TCD): O2 - 0.01 to 10%; N2 – 0.01 to 20%; H2S - 0.1 to 5%; CO2 and C1 through C4 - 0.01 to 100% Channel two (FID): C4 to C10 - 0.005 to 100% (depends upon split ratio) Application note reference number with technical details: D-6622, D-6629, D-6652

• “Fast Model 2008” – C4 + compounds backflushed to vent on TCD channel • Added liquid-sampling capability to Model 2009 • Dual channel/thermal conductivity detector (TCD), flame ionization detector (FID) • Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid

sample introduction, plus a vaporization zone for proper liquid sample injection • Separation and measurement of O2 and N2 individually • Packed and capillary columns, extended hydrocarbon analysis to C10 • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon



Channel one – TCD

Buta

nes

Pent

anes

Hex

ane

Hep

tane

Oct

ane

p-Xy

lene

n-Pr

opyl

benz

ene

Dec

ane

n-Bu

tylb

enze

ne

Time (min)2010

Channel two - FID

41




• Model 2201 with C6+ backflush to FID channel (no water interference, better sensitivity) • Added liquid-sampling capability to Model 2010 • Dual channel/thermal conductivity detector (TCD), flame ionization detector (FID) • Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid sample introduction, plus a vaporization zone for proper liquid sample injection • No separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon



Published methods met: ASTM D1945, GPA 2261, ISO 6974-5 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: O2, N2 composite; CO2; H2S; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: Channel one (TCD): O2, N2 composite and CO2 – 0.01 to 20%, C1 through C5 - 0.01 to 100%, H2S - 0.1 to 25%, Channel two (FID): C6+ composite - 0.001 to 100% Application note reference number with technical details: D-6622, D-6630, D-6652

TCD channel – C6+ backflushed to FID

42



Published methods met: ASTM D1945 (precision statement only) Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: He; H2; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: He, H2 – 0.01 to 100%; all other components except C6+ - 0.005 to 100%; C6+ - 0.005 to 10% Application note reference number with technical details: D-6622, D-6623, D-6651, D-6652

• Full-range hydrogen detection using separate channel with nitrogen carrier gas • Added liquid-sampling capability on FID channel of Model 2100 • Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid

sample introduction, plus a vaporization zone for proper liquid sample injection • Dual channel/thermal conductivity detector, flame ionization detector (TCD/FID) • Hydrocarbons detected and measured, no interference from air or CO2 • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software included containing template for heating value calculation and other sample specifications, plus merge and custom report formatting • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon




H2 measured by TCD and the remaining compounds measured by FID

43




Published methods met: ASTM D1945, GPA 2177, GPA 2261, ISO 6568, ISO 6974-5, DIN 51872-5 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: He; H2; O2, N2 composite; CO2; H2S; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: He, H2, C1 through C5 - 0.01 to 100%, O2, N2 composite and CO2 – 0.01 to 20%, H2S - 0.1 to 25%, C6+ composite - 0.01 to 10% Application note reference number with technical details: D-6622, D-6624, D-6651, D-6652

• Full-range hydrogen detection using separate channel with nitrogen carrier gas • Added liquid-sampling capability to Model 2101 • Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid

sample introduction, plus a vaporization zone for proper liquid sample injection • Dual channel/dual thermal conductivity detector (TCD/TCD) • No separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon




44




• Baseline separation of O2, N2 composite and methane, argon measurement • Full-range hydrogen detection using separate channel with nitrogen carrier gas • Added liquid-sampling capability to Model 2102 • Dual channel/dual thermal conductivity detector (TCD/TCD) • Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid




Published methods met: ASTM D1945, GPA 2261, ISO 6974-5, DIN 51872-5 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: He; H2; Ar; O2, N2 composite; CO2; H2S; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: Ar – 0.01 to 4%, H2S - 0.1 to 5%, C6+ composite - 0.01 to 10%, all other components - 0.01 to 100%, Application note reference number with technical details: D-6622, D-6625, D-6651, D-6652


45




• Full-range hydrogen detection using separate channel with nitrogen carrier gas • Dual channel/dual thermal conductivity detector (TCD/TCD) • Added liquid-sampling capability to Model 2103 • Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid

sample introduction, plus a vaporization zone for proper liquid sample injection • Separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush. • Rugged packed columns, no degradation from common contaminants • Model 3062 Software available containing template for heating value calculation and other sample specifications • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon



Published methods met: ASTM D1945, ASTM D1946, GPA 2261, DIN 51872-5 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: He; H2; O2; N2; CO2; H2S; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: O2 and C6+ composite - 0.01 to 10%; N2 – 0.01 to 20%; H2S - 0.1 to 5%; He, H2, CO2 and C1 through C5 - 0.01 to 100%, Application note reference number with technical details: D-6622, D-6626, D-6651, D-6652


46




Published methods met: None Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: He; H2; O2, N2 composite; CO2; H2S; C1 through C10; C6+ composite Guaranteed detection ranges/concentration levels: Channel one (TCD): O2, N2 composite and CO2 – 0.01 to 20%; He, H2, C1 through C5 - 0.01 to 100%; H2S - 0.1 to 25%; C6+ composite - 0.01 to 10%; Channel two (FID): C4 to C10 - 0.005 to 100% (depends upon split ratio) Application note reference number with technical details: D-6622, D-6627, D-6651, D-6652

• Capillary channel added to Model 2301 • Added liquid-sampling capability to Model 2106 • Full-range hydrogen detection using separate channel with nitrogen carrier gas • Three channel (TCD/TCD/FID) • Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid

sample introduction, plus a vaporization zone for proper liquid sample injection • No separation and measurement of O2 and N2 individually • Designed so that the lowest boiling C6 (2,2-dimethylbutane) is included in the backflush on TCD channel. • Packed and capillary columns, extended hydrocarbon analysis to C10 • Model 3062 Software available containing template for heating value calculation • Plumbed in sulfur-resistant materials to enhance H2S detection • This analyzer is for natural gas. Natural gas does not contain light hydrocarbon



Buta

nes

Pent

anes

Hex

ane

Hep

tane

Oct

ane

p-Xy

lene

n-Pr

opyl

benz

ene

Dec

ane

n-Bu

tylb

enze

ne

Time (min)2010

Channel one and two – TCD/TCD Channel three - FID

47




Published methods met: ASTM D1945, GPA 2261, ISO 6974-5 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: He; H2; O2, N2 composite; CO2; H2S; C1 through C5; C6+ composite Guaranteed detection ranges/concentration levels: Channel one (TCD): O2, N2 composite and CO2 – 0.01 to 20%; He, H2, C1 through C5 - 0.01 to 100%; H2S - 0.1 to 25% Channel two (FID): C6+ composite - 0.001 to 100% Application note reference number with technical details: D-6622, D-6630, D-6651, D-6652

• Model 2301 with C6+ backflush to FID channel (no water interference, better sensitivity) • Added liquid-sampling capability to Model 2110 • Full-range hydrogen detection using separate channel with nitrogen carrier gas • Three channel (TCD/TCD/FID) • Includes sample-loop purge feature that prevents contamination when changing sample types, a secondary filter and back pressure regulation for proper liquid




He, H2 measured by TCD using Nitrogen carrier gas. C6+ backflushed to FID, all other compounds measured using TCD using Helium carrier gas.

Simulat Model 3012

Model 3013

Model 3062

Sim

ula

ted

Dis

tilla

tio

n S

oft

wa

re

Simulated Distillation Softwareand Software Enhancements

49

Software Description

Typical Chromatogram and Report


Chromatogram of Reference Gas Oil (RGO) standard for ASTM D2887

Simulated Distillation Software Model 3012

Published methods met: ASTM D2887, ASTM D3710, ASTM D5307 Types of sample analyzed: Liquid Compounds analyzed: C4 through C110, depending upon method Application note reference number with technical details: D-6631

• Runs with PerkinElmer TotalChrom and Turbochrom Workstation or Client Server software

• Up to eight Sim Dis analyzers per each software license

• Step-by-step instruction manual

• Long and short reporting formats

• Cut point reports

• Setup templates for each Sim Dis Method

• Auto sequence multiple methods

• Batch reprocessing

• Reports to printer, disk or screen

10 20 30 40 50 60 70 80 90

100 110 120 130

ASTM D2887 report for the RGO sample

50


Typical Chromatogram and Report


Chromatogram of Reference Gas Oil (RGO) standard for ASTM D2887

Simulated Distillation Software Model 3013

Published methods met: ASTM D2887, ASTM D3710, ASTM D5307 Types of sample analyzed: Liquid Compounds analyzed: C4 through C110, depending upon method Application note reference number with technical details: D-6631

• Model 3013 includes method development, using Model 3012 Software

• Customer purchases total system specified for their desired methodology

• Sampling procedure and report format developed

• Chromatographic parameters established for the method

• Column identified

• Operating conditions identified

• Calibration material chosen

• Calibration and actual customer sample run, if supplied

• Sample interpreted

• Sample run at on-site installation by PerkinElmer

10 20 30 40 50 60 70 80 90

100 110 120 130

ASTM D2887 report for the RGO sample

51

Software Description

Typical Heating Calculation Report


Software Enhancements Model 3062

Published methods met: ASTM D3588 Types of sample analyzed: All Application note reference number with technical details: D-6632

• Combine two Turbochrom or TotalChrom reports into a single report

• Full computational power of Excel™

• Full reporting power of Excel

• Translation of report into local language

• Automatic output to paper and/or computer file path

• Typical uses include Natural gas computations using the supplied template and multiple detector analyzers report merge

• Changing the Turbochrom or TotalChrom report to match a company format

• Special calculations based upon measured concentrations

• Examples supplied include two detector-bridged Natural Gas Analyzer heat calculation and Refinery Gas Analyzer two-integrator channel merge

Sample Name: 3062 Demo Time: 08/07/98 12:05:42 PMOperator: M. Taylor Study: Default SequenceInstrument: TABLE_2_________(2B) Data Acquisition Time: 06/06/97 01:50:24 PM

Compressibility: 0.9977Heat (Saturated): 1045.63Heat (Dry): 1064.15 Specific Gravity (R 0.6484

Sequence File: C:\Userprog\Tc6demo\Nga\Nga32.seqInst Method: C:\TC4\1METHOD\2306F from c:\userprog\tc6demo\nga\pack.rst

Channel:BRaw Data File: c:\userprog\tc6demo\nga\pack.rawResult File: c:\userprog\tc6demo\nga\pack.rstProc Method: C:\USERPROG\tc6DEMO\NGA\PACKED.mthCalib Method: C:\USERPROG\tc6DEMO\NGA\PACKED.mth

Channel:ARaw Data File: c:\userprog\tc6demo\nga\cap.rawResult File: c:\userprog\tc6demo\nga\cap.rstProc Method: C:\USERPROG\tc6DEMO\NGA\CAP.mthCalib Method: C:\USERPROG\tc6DEMO\NGA\CAP.mth

A/B Component Mol % Mol Fraction Mol FractioSpecific GrCalorific Compressibilty Rleative Density Calorific Value CompressibilityName Bridged Normalizedfraction Fraction Fraction Btu/ft3 sqr rt (b)

B Hydrogen 5 0.05001 0.05 0.00348 16.25 0.0696 324.9B Air 3.85 0.03849 0.03848 0.03848 0 0.00078 1 0.0202B Argon 0.99 0.00995 0.00994 0.01372 0 0.00027 1.3792 0.0276B Methane 81.52 0.81524 0.81502 0.45144 824.8 0.03553 0.5539 1012 0.0436B CO2 0.41 0.00408 0.00407 0.00619 0 0.00026 1.5194 0.064B Ethane 3 0.03002 0.03001 0.03116 53.21 0.00275 1.0382 1772.9 0.0917B Propane 2.02 0.02021 0.0202 0.03075 50.96 0.00271 1.5224 2523 0.1342B i-Butane 1.01 0.01011 0.01011 0.02029 32.96 0.00185 2.0067 3260.1 0.1825B n-Butane 0.99 0.00989 0.00989 0.01984 32.32 0.00176 2.0067 3269.6 0.178B i-Pentane 0.49 0.00493 0.00493 0.01228 19.76 0.00117 2.491 4009.4 0.2376B n-Pentane 0.48 0.00479 0.00478 0.01192 19.22 0.00114 2.491 4018.5 0.2377A i-Pentane 0.49A n-Pentane 0.48A 2,2-dimethylButane 0.26 0.00256 0.00256 0.00761 12.16 0.00072 2.9753 4758 0.283

1.00028 1 0.64715 1061.65 0.04895

Trace S Model 4025

Model 4026

Model 4027

Model 4028

Model 4029

Model 4227

Model 4229

Model 4425

Model 4428

Model 4429

Model 4629

Tra

ce

Su

lfu

r A

na

lyze

rs

Trace Sulfur Analyzers

53




Trace Sulfur Components Analyzer Model 4025

H2S

CO

SSO

2

Met

hylm

erca

ptan

Ethy

lmer

capt

an

Dim

ethy

lsul

fide

t-But

ylm

erca

ptan

Prop

ylm

erca

ptan

Published methods met: ASTM D5504, ASTM D5623, ASTM D6021 Types of sample analyzed: Gas Compounds separated: H2S, SO2, COS, mercaptans, aromatic sulfur compounds, sulfides Guaranteed detection levels: less than 10 ppb Application note reference number with technical details: D-6643

• Analyzes samples such as refinery gas, natural gas, process gas, and Kraft gas • Uses a Sievers Sulfur Chemiluminescence Detector (SCD)

• The SCD has an equimolar response to sulfur compounds, lack of carbon

interference and requires simple calibration

• Capillary column solution

• Can be modified with a second or third channel to perform additional analyses

• Can be modified to analyze liquid and pressurized liquid samples (Model 4028)

• Can be designed to be on-line and/or a multistream system

54





H2S

CO

SSO

2

Met

hylm

erca

ptan

Ethy

lmer

capt

an

Dim

ethy

lsul

fide

t-But

ylm

erca

ptan

Prop

ylm

erca

ptan

Published methods met: ASTM D5504, ASTM D5623, ASTM D6021 Types of sample analyzed: Liquid, pressurized liquid (valve injection) Compounds separated: H2S, SO2, COS, mercaptans, aromatic sulfur compounds, sulfides Guaranteed detection levels: less than 10 ppb Application note reference number with technical details: D-6643

• Analyzes samples such as LPG, naphtha, gasoline and other liquid petroleum products • Uses a Sievers Sulfur Chemiluminescence Detector (SCD)

• The SCD has an equimolar response to sulfur compounds, lack of carbon interference

and requires simple calibration


• Can be modified with a second or third channel to perform additional analyzes

• Can be modified to analyze gas samples (Model 4028)


55




• Analyzes samples such as naphtha, gasoline and other liquid petroleum products that can be syringe injected

• Uses a Sievers Sulfur Chemiluminescence Detector (SCD)








H2S

CO

SSO

2

Met

hylm

erca

ptan

Ethy

lmer

capt

an

Dim

ethy

lsul

fide

t-But

ylm

erca

ptan

Prop

ylm

erca

ptan

Published methods met: ASTM D5504, ASTM D5623, ASTM D6021 Types of sample analyzed: Liquid (syringe injection) Compounds separated: H2S, SO2, COS, mercaptans, aromatic sulfur compounds, sulfides Guaranteed detection levels: less than 10 ppb Application note reference number with technical details: D-6643

56





H2S

CO

SSO

2

Met

hylm

erca

ptan

Ethy

lmer

capt

an

Dim

ethy

lsul

fide

t-But

ylm

erca

ptan

Prop

ylm

erca

ptan

Published methods met: ASTM D5504, ASTM D5623, ASTM D6021 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: H2S, SO2, COS, mercaptans, aromatic sulfur compounds, sulfides Guaranteed detection levels: less than 10 ppb Application note reference number with technical details: D-6643

• Analyzes samples such as refinery gas, natural gas, process gas, Kraft gas, LPG, naphtha, gasoline and other gaseous and liquid petroleum products




• Dual-capillary column solution

• Can be modified with a second or third channel to perform additional analyzes


57




• Analyzes samples such as refinery gas, natural gas, process gas, Kraft gas, naphtha, gasoline and other liquid petroleum products that can be syringe injected






• Can be modified to analyze pressurized liquid samples by adding a liquid sampling valve (Model 4229)



H2S

CO

SSO

2

Met

hylm

erca

ptan

Ethy

lmer

capt

an

Dim

ethy

lsul

fide

t-But

ylm

erca

ptan

Prop

ylm

erca

ptan

Published methods met: ASTM D5504, ASTM D5623, ASTM D6021 Types of sample analyzed: Gas, liquid Compounds separated: H2S, SO2, COS, mercaptans, aromatic sulfur compounds, sulfides Guaranteed detection levels: less than 10 ppb Application note reference number with technical details: D-6643

58




• Analyzes samples like naphtha, gasoline and other liquid petroleum products that can be syringe injected




• Includes a secondary filter and back-pressure regulation for proper liquid sample introduction





H2S

CO

SSO

2

Met

hylm

erca

ptan

Ethy

lmer

capt

an

Dim

ethy

lsul

fide

t-But

ylm

erca

ptan

Prop

ylm

erca

ptan

Published methods met: ASTM D5504, ASTM D5623, ASTM D6021 Types of sample analyzed: Liquid (syringe injection), liquid and pressurized liquid (valve injection Compounds separated: H2S, SO2, COS, mercaptans, aromatic sulfur compounds, sulfides Guaranteed detection levels: less than 10 ppb Application note reference number with technical details: D-6643

59




• Analyzes samples like refinery gas, natural gas, process gas, Kraft gas, LPG, naphtha, gasoline and other liquid petroleum products

• Uses a Sievers Sulfur Chemiluminescence Detector (SCD). The SCD has an

equimolar response to sulfur compounds, lack of carbon interference and requires simple calibration

• Includes a secondary filter and back-pressure regulation for proper liquid sample introduction, plus a vaporization zone for proper liquid sample injection





H2S

CO

SSO

2

Met

hylm

erca

ptan

Ethy

lmer

capt

an

Dim

ethy

lsul

fide

t-But

ylm

erca

ptan

Prop

ylm

erca

ptan

Published methods met: ASTM D5504, ASTM D5623, ASTM D6021 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: H2S, SO2, COS, mercaptans, aromatic sulfur compounds, sulfides Guaranteed detection levels: less than 10 ppb Application note reference number with technical details: D-6643, D-6652

60


Chamber Schematic


Trace Sulfur Components Analyzer Models 4425, 4428, 4429 and 4629

Published methods met: ASTM D5504, ASTM D5623, ASTM D6021 Types of sample analyzed: Gas Compounds separated: H2S, SO2, COS, mercaptans, aromatic sulfur compounds, sulfides Guaranteed detection levels: less than 10 ppb Application note reference number with technical details: D-6643

• Adds an integrated permeation tube chamber for calibration option to Trace Sulfur Components Analyzer Models 4025, 4028, 4029 and 4229

• Saves both space and cost

• Mounts on top of the analyzer for easy access

• Manual valve is used to select the calibration chamber or the sample input • Permeation tube chamber can accommodate up to four permeation tubes or wafers

for calibration of other non sulfur compounds

• Includes certified dimethyl-sulfide permeation tube

• Permeation tube shipped with the product is tested with the analyzer, against an NBS traceable calibrator for accuracy

Model 4001 Model 4002 Model 4003 Model 4081 Model 4004 Model 4005 Model 4006 Model 4007 Model 4008 Model 4009 Model 4010 Model 4011 Model 4012 Model 4013 Model 4014 Model 4015 Model 4016 Model 4017

Model 4018 Model 4019 Model 4020 Model 4021 Model 4022 Model 4023 Model 4024 Model 4032 Model 4033 Model 4034 Model 4035 Model 4036 Model 4037 Model 4080 Model 4082 Model 4083 Model 4086

Oth

er

An

aly

ze

rs

Other Analyzers

Analyzers for Light Gas, Chlorine, Transformer Oil Gas,LPG and Simulated Distillation through DetailedHydrocarbon Analyses

62




Published methods met: ASTM D4815-99 Types of sample analyzed: liquid Compounds separated: Methanol, ethanol, isopropanol, tert-butanol, n-propanol, MTBE, sec-butanol, DIPE, isobutanol, ETBE, tert-pentanol, n-butanol, benzene, TAME, heavy hydrocarbons Guaranteed detection ranges/concentration levels: MTBE, DIPE, ETBE, TAME – 0.1 to 20%; all other components – 0.1 to 12% Application note reference number with technical details: D-6633

Standard Method (ASTM D4815) Analyzers Model 4001/4002

• Guaranteed to meet the scope of ASTM D4815-99 methodology

• Fully automated

• Low cost of operation

• Available with thermal conductivity detector (Model 4001) or flame ionization detector (Model 4002)

• The determination of benzene, separated by this valve/column system, is not

qualified by this method. To analyze benzene, refer to Model 4013 (ASTM D3606) or Model 4006 (ASTM D4420). Model 4013 or Model 4006 can be incorporated as a second channel in the Model 4001/4002 (see Models 4009, 4010 or 4007, 4008).

63



Major Features and Benefits • Model 4081 Transformer Oil Gas Extraction Apparatus and Model 4003 Analyzer meets

the scope of ASTM D3612-01, Method A • Dual detector (TCD/FID) • Model 4003 can be connected to a Headspace Sampler to meet ASTM D3612-01,

Method C • Purged sampling valve housing on Model 4003 Analyzer • Passivated tubing for optimum CO response

• Injection port and gas sampling valve for various sample introductions

• High capacity methanizer

Transformer Oil Gas Analyzer Model 4003/4081

Hyd

roge

n

Car

bon

Dio

xide

Ethy

lene

Etha

ne

Acet

ylen

e

Oxy

gen

Nitr

ogen

Met

hane

Car

bon

Mon

oxid

e

Published methods met: ASTM D3612-01 Types of sample analyzed: Gas Compounds separated: H2, O2, N2, CO2, CO, CH4, C2H6, C2H4, C2H2, C3 and C4 hydrocarbons Guaranteed detection ranges/concentration levels: CO2, CO, CH4, C2H6, C2H4 – 1.0 ppm; C2H2 - 2.0 ppm; C3s, C4s – 3.0 ppm; H2 – 50 ppm; O2, N2 – 500 ppm Application note reference number with technical details: D-6634

64




• Analyzer has the capability to determine the ether and alcohol additives (see Model 4001/4002), as well as the benzene, toluene, ethylbenzene and other aromatics, as required, (see Model 4005) in gasoline

• The same column system is utilized for both methods

• ASTM D5580 requires a flame ionization detector (FID). For this reason and since the

same column system is utilized for both methods, only the FID performing ASTM D4815 is appropriate for this analyzer

• See Models 4002 and 4005 for more details

Standard Method (ASTM D4815/D5580) Analyzer Model 4004

Published methods met: ASTM D4815, ASTM D5580 Types of sample analyzed: Finished gasoline Compounds separated: (ASTM D4815): Methanol, ethanol, isopropanol, tert-butanol, n-propanol, MTBE, sec-butanol, DIPE, isobutanol, ETBE, tert-pentanol, n-butanol, benzene, TAME, heavy hydrocarbons; (ASTM D5580): Benzene, toluene, ethylbenzene, p/m-xylene, o-xylene, C9 and heavier aromatics, total aromatics Guaranteed detection ranges/concentration levels: (ASTM D4815): MTBE, DIPE, ETBE, TAME – 0.1 to 20%; all other components – 0.1 to 12%; (ASTM D5580): (all v%) Benzene – 0.1 to 5%, toluene – 1 to 15%, individual C8 aromatics – 0.5 to 10%, total C9 and heavier aromatics – 5 to 30%, total aromatics – 10 to 80% Application note reference number with technical details: D-6633, D-6635

ASTM D4815 analysis ASTM D5580 analysis 1 ASTM D5580 analysis 2

65




• Aromatic hydrocarbons are separated without interferences from other hydrocarbons in the sample

• Nonaromatic hydrocarbons having a boiling point greater than n-dodecane may cause interferences with the C9 and heavier aromatics

• For the C8 aromatics, p-xylene and m-xylene coelute, ethylbenzene and o-xylene separate

• The C9 and heavier aromatics are measured as a single group • Two separate analyses are performed. The first, the quantitation of benzene and

toluene. The second, the quantitation of ethylbenzene, p/m-xylene, o-xylene, and the C9 and heavier aromatics. The results are summed to determine total aromatic content.

• Alcohols and ethers added to gasoline do not interfere with the analysis

Standard Method (ASTM D5580) Analyzer Model 4005

Published methods met: ASTM D5580 Types of sample analyzed: Finished Gasoline Compounds separated: Benzene, toluene, ethylbenzene, p/m-xylene, o-xylene, C9 and heavier aromatics, total aromatics Guaranteed detection ranges/concentration levels: (all v%) Benzene – 0.1 to 5%, toluene – 1 to 15%, individual C8 aromatics – 0.5 to 10%, total C9 and heavier aromatics – 5 to 30%, total aromatics – 10 to 80% Application note reference number with technical details: D-6635

Analysis 1 Analysis 2

66




Published methods met: ASTM D4420 Types of sample analyzed: Finished Gasoline Compounds separated: Benzene; toluene; C8, C9 and heavier aromatics, total aromatics Guaranteed detection ranges/concentration levels: Benzene - 0.1 to 5V%, toluene – 1 to 20V%, C8 aromatics – 3 to 25V%, C9 and heavier aromatics – 5 to 30V%, total aromatics – 10 to 80V% Application note reference number with technical details: D-6636


• A sample is injected by syringe into a two column/valve system. Nonaromatics are vented as they elute column one. Before benzene elutes, the aromatics are backflushed from column one to column two. Aromatics elute from column two to the thermal conductivity detector (TCD) in boiling point order. After C8 aromatics have eluted, column two is backflushed to the TCD to obtain the C9 and heavier aromatics. Sample results are compared to the analysis of a blend of known aromatic content.

• A knowledge of aromatics in gasolines is needed to access sample results

• This single channel analyzer can have a second channel added, performing another

method or application. The column oven temperature requirement of the second channel cannot operate above the maximum temperature allowed by Model 4006 (200 oC).

67




• Analyzer has the capability to determine the ether and alcohol additives (see Model 4001/4002), as well as the benzene, toluene, ethylbenzene, C8 and other heavier aromatics, as required, (see Model 4006) in gasoline

• Two separate column systems are utilized for these methods

• See Models 4001/4002 and 4006 for more details

Standard Method (ASTM D4815/D4420) Analyzer Model 4007/4008

Published methods met: ASTM D4815, ASTM D4420 Types of sample analyzed: Finished gasoline Compounds separated: (ASTM D4815): Methanol, ethanol, isopropanol, tert-butanol, n-propanol, MTBE, sec-butanol, DIPE, isobutanol, ETBE, tert-pentanol, n-butanol, benzene, TAME, heavy hydrocarbons; (ASTM D4420): Benzene; toluene; C8, C9 and heavier aromatics, total aromatics Guaranteed detection ranges/concentration levels: (ASTM D4815): MTBE, DIPE, ETBE, TAME – 0.1 to 20%; all other components – 0.1 to 12%; (ASTM D4420): Benzene - 0.1 to 5V%, toluene – 1 to 20V%, C8 aromatics – 3 to 25V%, C9 and heavier aromatics – 5 to 30V%, total aromatics – 10 to 80V% Application note reference number with technical details: D-6633, D-6636

ASTM D4815 analysis ASTM D4420 analysis

68




• Analyzer has the capability to determine the ether and alcohol additives (see Model 4001/4002), as well as the benzene and toluene, as required, (see Model 4013) in gasoline



Standard Method (ASTM D4815/D3606) Analyzer Model 4009/4010

Published methods met: ASTM D4815, ASTM D3606 Types of sample analyzed: Finished gasoline Compounds separated: (ASTM D4815): Methanol, ethanol, isopropanol, tert-butanol, n-propanol, MTBE, sec-butanol, DIPE, isobutanol, ETBE, tert-pentanol, n-butanol, benzene, TAME, heavy hydrocarbons; (ASTM D3606): Benzene, toluene Guaranteed detection ranges/concentration levels: (ASTM D4815): MTBE, DIPE, ETBE, TAME – 0.1 to 20%; all other components – 0.1 to 12%; (ASTM D3606): Benzene - 0.1 to 5V%, toluene – 2 to 20V% Application note reference number with technical details: D-6633, D-6637

ASTM D4815 analysis ASTM D3606 analysis

69




• Analyzer has the capability to determine the ether and alcohol additives (see Model 4001/4002), as well as the benzene and toluene, as required, (see Model 4014) in gasoline

• EPA modification of ASTM D3606 adds additional column for enhanced benzene –

ethanol (if present) separation. All other specifications and method intent remain unchanged.



Standard Method (ASTM D4815/D3606- EPA modified) Analyzer Model 4011/4012

Published methods met: ASTM D4815, ASTM D3606 (EPA modification) Types of sample analyzed: Finished gasoline Compounds separated: (ASTM D4815): Methanol, ethanol, isopropanol, tert-butanol, n-propanol, MTBE, sec-butanol, DIPE, isobutanol, ETBE, tert-pentanol, n-butanol, benzene, TAME, heavy hydrocarbons; (ASTM D3606-EPA modified): Benzene, toluene Guaranteed detection ranges/concentration levels: (ASTM D4815): MTBE, DIPE, ETBE, TAME – 0.1 to 20%; all other components – 0.1 to 12%; (ASTM D3606-EPA modified): Benzene - 0.1 to 5V%, toluene – 2 to 20V% Application note reference number with technical details: D-6633, D-6637

ASTM D4815 analysis ASTM D3606 (EPA modified) analysis

70





Published methods met: ASTM D3606 Types of sample analyzed: Finished Motor and Aviation Gasoline Compounds separated: Benzene, toluene Guaranteed detection ranges/concentration levels: Benzene – 0.1 to 5V%, toluene – 2 to 20V% Application note reference number with technical details: D-6637

• A sample, containing methyl ethyl ketone (MEK) as an internal standard, is injected by syringe into two columns in series. The first column separates components by boiling point. After octane elutes from column one into column two, carrier flow is reversed in column one. Hydrocarbons heavier than octane are vented. Column two then separates the octane and lighter components. Aromatic and nonaromatic compounds are measured with reference to the MEK by thermal conductivity detector (TCD).

• Knowledge of benzene concentration may be an aid in evaluating the toxicity of the

gasoline being analyzed. This method is not intended to evaluate that toxicity, however.

• This single-channel analyzer can have a second channel added, performing another


71




Standard Method (ASTM D3606-EPA modified) Analyzer Model 4014

Published methods met: ASTM D3606 (EPA modification) Types of sample analyzed: Finished Motor and Aviation Gasoline Compounds separated: Benzene, toluene Guaranteed detection ranges/concentration levels: Benzene – 0.1 to 5V%, toluene – 2 to 20V% Application note reference number with technical details: D-6637

• EPA modification of ASTM D3606 adds additional column for enhanced benzene – ethanol (if present) separation

• All other specifications and method intent remain unchanged. See Model 4013 for

details • This single channel analyzer can have a second channel added, performing another


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Page One of Typical Report


• Detailed analysis of gasolines, naphthas and similar samples that boil below 250 oC • Software is mated to capillary-column output to obtain detailed hydrocarbon

characteristics • Reports include individual components, key boiling point data, oxygenates and oxygen

content and multisubstituted aromatics • Calculated values include percent carbon and hydrogen, vapor pressure, average

molecular weight and density by carbon number, octane rating and bromine number • Key separated compounds include methylcyclopentene-1/benzene; 2,3,3-

trimethylpentane/toluene and 1,4-dimethylbenzene (p-xylene)/2,3-dimethylheptane

Detailed Hydrocarbon Analyzer Model 4015

Published methods met: ASTM D5443, ASTM D6623, ASTM D6730, ASTM D6733 Types of sample analyzed: liquid Compounds separated: Paraffins, Isoparaffins, Naphthenes, Olefins, Aromatics and Oxygenates (reported by carbon number) through C13 Guaranteed detection ranges/concentration levels: All components – 10 ppm Application note reference number with technical details: D-6638

Detailed Hydrocarbon Analysis (DHAX)Neil G. Johansen, Inc.

Raw File: 0928001002.raw Analyzed: 28 Sep 1999 01:33PMSample: Reported: 01 Oct 1999 02:32PM Method: DHA Initial Gasoline.mth DHA DBase File: 5987A.csv Processed 445 peaks Normalized to 100.00%

Summary Report

Group Type: Total (mass%) Total (vol%) Paraffins: 9.471 10.564 I-paraffins: 30.320 33.370 Olefins: 8.131 8.733 Naphthenes: 9.807 9.439 Aromatics: 24.981 20.917 Total C14+: 0.436 0.421 Total Unknowns: 1.384 1.171 Grand Total 100.000 100.000

Oxygenates: Total: 15.471 (mass%) 15.385 (vol%) Total Oxygen Content: 2.808 (mass%)

Multisubstituted Aromatics: 18.161 (mass%) 15.313 (vol%)

Average Molecular Weight: 80.291

Relative Density: 0.609

Vapor Pressure calc RVP (EPA method): 3.42 (psi @ 100°F)

Calculated Octane Number: 87.08

73




Light Gas Analyzer Model 4016

Published methods met: ASTM D1946 Types of sample analyzed: Gas Compounds separated: Ar - O2 composite; N2; CH4; CO; CO2; Ethylene; Ethane; Acetylene; H2S Guaranteed detection ranges/concentration levels: H2S – 0.02 to 100%, all other components – 0.01 to 100%

• Typical analyses are light gases, furnace gases, stack gases, combustion gases, decoking gases, mine gases

• Packed columns/single thermal conductivity detector (TCD)

• Often used as one channel of an analyzer – very versatile

• Some common added channels are:

- Flame ionization detector (FID) for better hydrocarbon detection - Methanizer/FID and purged-valve housings for trace CO and CO2 analysis - Flame photometric detector (FPD) or a Sievers Sulfur Chemiluminescence

Detector (SCD) for trace levels of the light sulfur gases

74





• Full-range hydrogen detection using separate channel with nitrogen carrier gas added to Model 4016

• Packed columns/dual Arnel thermal conductivity detector (TCD/TCD)

• Arnel dual TCD allows analyzer to have an added third channel

• Some common added channels are:

- Flame ionization detector (FID) for better hydrocarbon detection - Methanizer/FID and purged valve housings for trace CO and CO2 analysis - Flame photometric detector (FPD) or a Sievers Sulfur Chemiluminescence

Detector (SCD) for trace levels of the light sulfur gases


Published methods met: ASTM D1946 Types of sample analyzed: Gas Compounds separated: He; H2; Ar - O2 composite; N2; CH4; CO; CO2; Ethylene; Ethane; Acetylene; H2S Guaranteed detection ranges/concentration levels: H2S – 0.02 to 100%, all other components – 0.01 to 100%

Hyd

roge

n

CO

2

Ethy

lene

Etha

ne

Acet

ylen

e H2S

Oxy

gen

Nitr

ogen

Met

hane

CO

75





• Packed columns/dual thermal conductivity detector (TCD/TCD)

• Third channel added to Model 4016 for Ar – O2 separation and measurement

Channel one – TCD Channel two - TCD


Published methods met: ASTM D1946 Types of sample analyzed: Gas Compounds separated: Ar; O2; N2; CH4; CO; CO2; Ethylene; Ethane; Acetylene; H2S Guaranteed detection ranges/concentration levels: H2S – 0.02 to 100%, all other components – 0.01 to 100% Application note reference number with technical details: D-6639

Argo

n

Nitr

ogen

Oxy

gen

13 M

inut

es

76





Published methods met: ASTM D1946 Types of sample analyzed: Gas Compounds separated: He; H2; Ar; O2; N2; CH4; CO; CO2; Ethylene; Ethane; Acetylene; H2S Guaranteed detection ranges/concentration levels: H2S – 0.02 to 100%, all other components – 0.01 to 100% Application note reference number with technical details: D-6639


• Packed columns/dual Arnel thermal conductivity detector and PerkinElmer thermal

conductivity detector (TCD/TCD/TCD) • Third channel added to Model 4017 for Ar – O2 separation and measurement

• Arnel dual TCD allows analyzer to have added third channel

Hyd

roge

n

CO

2

Ethy

lene

Etha

ne

Acet

ylen

e H2S

Oxy

gen

Nitr

ogen

Met

hane

CO

Channel one and two – TCD/TCD

Argo

n

Nitr

ogen

Oxy

gen

13 M

inut

es

Channel three - TCD

77




Light Gases in Chlorine Model 4020

Published methods met: ASTM E1746 Types of sample analyzed: Gas Compounds separated: He, H2, O2, N2, CH4, CO2, CO Guaranteed detection ranges/concentration levels: He, H2 - 0.001 to 100%; all other components - .01 to 100% Application note reference number with technical details: D-6640

• All tubing and valves in contact with the samples are constructed of chlorine-resistant material

• Dual packed column channels/dual thermal conductivity detector (TCD/TCD)

• An important feature is the use of proprietary packing materials as the first column in

both channels • Samples containing water do not interfere with the analysis or create hardware

problems • Chlorine is backflushed to vent and does not enter the detector

78




Trace CO, CH4 and CO2 Analyzer Model 4021

Published methods met: ASTM D3416, ISO 6381 Types of sample analyzed: Gas Compounds separated: CO, CO2, CH4, ethylene – ethane composite, acetylene Guaranteed detection ranges/concentration levels: All components – 0.1 ppm Application note reference number with technical details: D-6641

• Single channel/methanizer/flame ionization detector (FID) • One valve and one column

• Can handle large methane concentrations

• Acetylene elutes after ethylene – trace acetylene can not be analyzed in large

quantities of ethylene • Purged valve housings and passivated tubing are used to enhance sensitivity

• In practical use, the sample must be free of oxygen

Car

bon

Mon

oxid

e

Met

hane

Car

bon

Dio

xide

8 M

inut

es

79





Published methods met: ASTM D3416, ISO 6381 Types of sample analyzed: Gas Compounds separated: CO, CO2, CH4, ethylene, ethane, acetylene Guaranteed detection ranges/concentration levels: All components – 0.1 ppm Application note reference number with technical details: D-6641

• Single channel/methanizer/flame ionization detector (FID) • One valve and one column

• Can not handle large methane concentrations

• Acetylene elutes before ethylene – trace acetylene, CO, CO2, CH4 can be analyzed in

large quantities of ethylene • Purged valve housings and passivated tubing are used to enhance sensitivity


Car

bon

Mon

oxid

eM

etha

ne

Car

bon

Dio

xide

Acet

ylen

e Ethy

lene

Etha

ne

4 M

inut

es

80


Product Schematic


• Compliments analyzers for a fully tested complete system or sold as a stand-alone product

• If purchased with an analyzer, it will be additionally tested using an actual sample supplied by the customer or supplied by Arnel

• Designed to vaporize liquefied light hydrocarbons such as propylene • Incorporates design improvements to meet the requirements for trace hydrocarbons,

as well as trace CO and CO2 analysis in liquefied light hydrocarbon gases • The output of the Apparatus is connected directly to the analyzer to insure no air will

be added to the expanded sample • The Apparatus includes a metering valve for the sample flow, a metering valve for

calibration gases, a clear plastic graduated cylinder for use as a manometer and a burst disk located in the “liquid sample in” system, which relieves a high-pressure (above 500 psi) sample to vent, if introduced into the product

Liquid Sample Expansion Apparatus Model 4023

Published methods met: ASTM D2712 Types of sample analyzed: Pressurized liquid Compounds separated: N/A Guaranteed detection ranges/concentration levels: N/A Application note reference number with technical details: D-6642

81





Car

bon

Mon

oxid

e

Met

hane Car

bon

Din

oxid

e

Published methods met: UOP 603 Types of sample analyzed: Gas Compounds separated: CO, CO2, CH4 Guaranteed detection ranges/concentration levels: All components – 0.5 ppm Application note reference number with technical details: D-6641

• Single channel/methanizer/flame ionization detector (FID) • Valving and columns meet UOP 603 methodology

• Can handle large methane concentrations

• Does not include any C2 analysis (Acetylene and ethylene coelute off of the primary

column) • Purged valve housings and passivated tubing are used to enhance sensitivity


82




Full Range H2, He, O2 and N2 Analysis Model 4032/4033/4034

Published methods met: ASTM D1945, ASTM D1946 Types of sample analyzed: Gas Compounds separated: Model 4032- He, H2; Model 4033- O2, N2; Model 4034- He, H2, O2, N2 Guaranteed detection ranges/concentration levels: All components – 10 ppm to 100% Application note reference number with technical details: D-6645

• Rugged and simple packed-column technology • Models 4032 and 4033 are single channel, thermal conductivity detector analyzers.

Model 4034 is a dual-channel, dual-thermal conductivity detector analyzer. • Better detection and measurement than 10 ppm can be achieved, with modification, in

some cases. Some limitations are present, however, with certain combinations of compound levels present. Information on the complete sample matrix is required to determine true detection and measurement ranges.

• Model 4032 and 4033 have the ability to be combined with other application channels

for cost savings

Model 4032 and Model 4034 analysis one Model 4033 and Model 4034 analysis two

83



Light Hydrocarbon Analyzer Model 4035


Published methods met: ASTM D2163, ASTM D2593, ASTM D2712, ASTM D2820, ASTM D4424, ISO 7941 Types of sample analyzed: Gas Compounds separated: All hydrocarbons from methane through hexane Guaranteed detection ranges/concentration levels: All components - 0.1 ppm Application note reference number with technical details: D-6663

• Used to analyze a wide range of gaseous light hydrocarbon samples such as LPG • Fully automatic operation • All hydrocarbons from methane to hexane are analyzed. Complete separations of all

possible compounds are obtained in approximately 20 minutes. The analysis usually includes a column temperature program.

• This analyzer cannot be used for all samples. Two very good applications are for propylene/butylenes manufacturing and analysis of butane streams, which are free of compounds that irreversibly poison the Alumina PLOT column (NH3, H2S).

• External valve oven design allows for full range temperature programming for column reconditioning (removing CO2 and H2O)

• The valve oven assures that no sample condensation occurs in the sample loop • Possible to add second channel for another application

84




• Used to analyze a wide range of liquid light hydrocarbon samples such as LPG • Fully automatic operation • All hydrocarbons from methane to hexane are analyzed. Complete separations of all



• Liquid sampling valve mounted at ambient temperature allows for full range temperature programming for column reconditioning (removing CO2 and H2O)

• Includes a secondary filter and back pressure regulation for proper liquid sample introduction, plus a vaporization zone for proper liquid sample injection • Possible to add second channel for another application


Published methods met: ASTM D2163, ASTM D2593, ASTM D2712, ASTM D2820, ASTM D4424, ISO 7941 Types of sample analyzed: Liquid, pressurized liquid Compounds separated: All hydrocarbons from methane through hexane Guaranteed detection ranges/concentration levels: All components - 0.1 ppm Application note reference number with technical details: D-6663

85




• Analyzes a wide range of gaseous and liquid light hydrocarbon samples such as LPG • Fully automatic operation • All hydrocarbons from methane to hexane are analyzed. Complete separations of all



• Liquid sampling valve mounted at ambient temperature and external valve oven design for the gas sampling valve allows for full range temperature programming for column reconditioning (removing CO2 and H2O)

• Includes a secondary filter and back-pressure regulation for proper liquid sample introduction, plus a vaporization zone for proper liquid sample injection


Published methods met: ASTM D2163, ASTM D2593, ASTM D2712, ASTM D2820, ASTM D4424, ISO 7941 Types of sample analyzed: Gas, liquid, pressurized liquid Compounds separated: All hydrocarbons from methane through hexane Guaranteed detection ranges/concentration levels: All components - 0.1 ppm Application note reference number with technical details: D-6663

86




Published methods met: EN 12177, EN 13132, IP 425/96 Types of sample analyzed: Unleaded petrol (gasoline) with a boiling point not to exceed 220 oCCompounds separated: Benzene, aromatics, MTBE, ethanol, oxygenates Guaranteed detection ranges/concentration levels: Benzene - 0.05 to 6 % (V/V), individual organic oxygenate compounds - 0.17% to 15 % (m/m), total organically bound oxygen - up to 3.7% (m/m) Application note reference number with technical details: D-6647

Benzene and Oxygenates Analyzer Model 4080

MTB

E

Benz

ene

Tolu

ene

i-But

yl-m

ethy

l-ket

one

• Pressure switched (PreVent), “heartcut” instrument configuration • The analyzer features a capillary injection port, PreVent and three capillary columns (a

liquid-sampling valve can also be used) • Total flexibility - Choosing the correct internal standard and varying the “heartcut”

times, it is possible to determine any oxygenate or aromatic found in petrol. • The same sample can be run twice with different “heartcut” times. By spreading the

components into two analyses, the interferences found with a large number of components are eliminated.

Petrol with heartcuts

Measured MTBE, benzene

87


Schematic of Mounted Model 4082


• Apparatus is designed to introduce pressurized liquid samples precisely, without sample vaporization before sample injection

• This product is normally sold as an “add on” to liquid sampling valved analyzers

• OPERATION OF THE MODEL 4082: Connect the filtered sample to the sample inlet and

start the liquid flow. There may be bubbles passing through the sight glass. Gently close the valve at the top of the sight glass until the bubbles stop. This will provide a slight backpressure in order to prevent the vaporizing of the liquid sample. Upon minimizing the vaporization (bubbles) of the sample and obtaining a desired liquid flow rate, close the toggle valve to stop the flow and make your injection. Once the run has commenced, open the toggle valve and the backpressure valve to vent the remaining liquid.

Liquid Sampling Apparatus Model 4082

Published methods met: UOP 911 Types of sample analyzed: Pressurized liquid Compounds separated: N/A Guaranteed detection ranges/concentration levels: N/A Application note reference number with technical details: None

88




Published methods met: ASTM D2504 Types of sample analyzed: Gas Compounds separated: Hydrogen, oxygen /argon coelution, nitrogen, methane, carbon monoxide Guaranteed detection ranges/concentration levels: CO – 100 ppb, all other components – 50 ppb Application note reference number with technical details: D-6648

Trace H2, O2, Ar, N2, CH4 and CO in Light Hydrocarbons Analyzer Model 4083

• Trace level detection and measurement of components by Discharge Ionization Detector (DID)

• To maximize performance, all features of the system’s valving, fittings, tubing and columns are designed to be inert and leak tight. Key components are located in a carrier gas purged enclosure.

• If any of the target compounds are in % level concentrations in your sample, this analyzer may not be appropriate for your samples

• Extreme care must be taken in providing sample to the analyzer. Sample connections and carrier gas connections to the analyzer must be leak free.

• The analyzer includes a carrier gas purifier to ensure carrier gas quality • Can be combined with other applications or a second channel of trace level analysis

89




Trace Methanol and MTBE in Liquid Hydrocarbons Analyzer Model 4086

Published methods met: None Types of sample analyzed: Liquid Compounds separated: Acetaldehyde, MTBE, methanol, acetone, 2-propanol, others Guaranteed detection ranges/concentration levels: Acetaldehyde, MTBE, methanol – 0.5 V ppm to 1V%; all other components – 1 V ppm to 1V% Application note reference number with technical details: None

• Split/splitless injector, dual capillary column, PreVent and flame ionization detector (FID)

• An autosampler should be included for precision • Optional gas-sampling or liquid-sampling valves can be added • Capillary non-polar precolumn for separation of light non-polar compounds and

backflushing heavies. The use of a precolumn and backflushing keeps high boiling material from contaminating the main column. Backflushing of the precolumn is provided by PreVent hardware and a mid-point pressure switch time programmed from the Clarus Interface or TotalChrom.

• Capillary PLOT silica main column for separation of oxygenated compounds

90

Related Industries Also Benefit The dedicated and guaranteed PerkinElmer Arnel Analyzers and Systems in this booklet specifically address the petrochemical laboratory and process industry. Many other standard and custom Analyzers, Systems and Accessories are available for other industries such as pharmaceutical, food & beverage, and specialty gases for QC, general testing and environmental - occupational safety monitoring applications. Examples of other guaranteed products are:

• Model 4438 and 4046 Trace Impurities in Beverage CO2 Analyzers • Series 5100 Acetaldehyde in PET Bottles Analyzer • Series 5200 Workspace Air Quality Monitor

Explore both the PerkinElmer web site (www.perkinelmer.com) and the Arnel Inc. web site (www.arnelinc.com) for other products, plus contact your local PerkinElmer sales engineer or email Arnel at [email protected] for more details, literature and a quotation.

© 2003 PerkinElmer, Inc. All rights reserved. PerkinElmer is a registered trademark of PerkinElmer, Inc. Arnel is a trademark of Arnel Inc.PerkinElmer reserves the right to change this document at any time and disclaims liability for editorial, pictorial or typographical errors.

006808_02 KG060303 Printed in USA

PerkinElmer Life and Analytical Sciences710 Bridgeport Avenue Shelton, CT 06484-4794 USAPhone: 800-762-4000 or(+1) 203-925-4602www.perkinelmer.com

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