pg degree course in m.sc....

SYLLABUS AND REGULATIONS

UNDER CHOICE BASED CREDIT SYSTEM (CBCS) (Those who joined in 2018-2019 and after)

PG Degree Course

in M.Sc. (Chemistry)

Regulations 2018

SRI S. RAMASAMY NAIDU MEMORIAL COLLEGE SATTUR- 626 203 (An Autonomous Institution Affiliated to Madurai Kamaraj University, Madurai)

(Re-Accredited with Grade ‘A’ by NAAC)

Placed at the meeting of Academic

Council held on 17.04.2018

SRNMC Regulations-2018 Syllabus

1

OBJECTIVES To enable the students

1. To gain knowledge on the basic and advanced level aspects in the different disciplines of

chemistry.

2. To get an exposure to the basics in nano chemistry and biochemistry.

3. To gain knowledge on the basic and advanced level experimental techniques.

4. To get an exposure on some current trends in chemistry.

ELIGIBILITY FOR ADMISSION

B.Sc. degree with chemistry as the core subject and physics as one of the allied subjects; the

other allied subject may be any one of the following: Mathematics, Botany and Zoology.

DURATION OF THE COURSE

The duration of the course shall be two academic years comprising four semesters with two

semesters in each academic year.

COURSES OF STUDY

1. Core subjects

2. Major elective subjects

.

CREDITS

The term ‘credit’ refers to the weight age given to the course, usually in relation to the instructional

hours assigned to it. The total credits required for completing Master of Science in Chemistry is 90.

The particulars of the credits for individual components and courses are placed on Table-1.

EXTRA CREDITS PAPER

1. This paper is optional. Students may or may not select this paper. If he/she selects

this paper and if he/she passes the paper, then 3 extra credits will be added in his/her total

credit to the degree, even otherwise, it won’t affect the completion of degree.

2. Though this paper is common to all PG programmes, the syllabus varies according to

the subject selected by the department.

3. The title of this paper is ―Model Paper for NET/ SET Examinations- Chemical sciences

4. Examination for this paper will be held at the end of the 4th

semester examinations.

5. There is no internal examination and only external examination for this paper.

6 . Maximum marks for this paper is 100.


2

SCHEME OF EXAMINATION

It is presented on Table-2

PATTERN OF THE QUESTION PAPER

THEORY

Part A

Ten questions (Multiple choice) 10 x 1 = 10 marks

Two questions from each Unit

Part B

Five questions (either or type) 5 x 7 = 35 marks

One question from each Unit

Part C

Three questions (out of five) 3 x 10 = 30 marks

One question from each unit

---------------

Total 75 Marks

---------------

EVALUATION

The performance of the student is evaluated in terms of percentage of marks with a

provision for conversion to grade points. Evaluation for each course shall be done by a

continuous internal assessment by the concerned course teacher as well as by an end semester

examination which will be written type examination of 3 hours duration and will be

consolidated at the end of the course. The ratio of marks to be allotted to continuous internal

assessment and to end semester examination is 25:75 (i.e. Internal 25 Marks and external 75

Marks)


3

The components of continuous internal assessment are

Two tests and their average 15 Marks

Seminar/Group Discussion 5 Marks

Assignment 5 Marks

Total 25 Marks

PASSING MINIMUM

A) Theory

1. 50% of the aggregate (External+ Internal)

2. No separate pass minimum for Internal

3. 34 Marks out of 75 is the pass minimum for the External.

B) Practical

1. 50% of the aggregate (External+ Internal)

2. No separate pass minimum for Internal

3. 27 Marks out of 60 is the pass minimum for the External.

C) Project

1. 50% of the aggregate (Project Evaluation + Viva Voce+ Internal)

2. No separate pass minimum for internal.

3. 27 marks out of 60 is the pass minimum for the External.


4

M.Sc (CHEMISTRY)

Table -1: Course pattern

(For those who joining in 2018-2019 and after)

Extra Credit paper : 3 credits

Grand Total : 93

S.No

Semester

I

II

III

IV

V

Total

Hours

Total

Credits

1

I

Core

5(5)

Core

5(5)

Core

5(4)

Elective

5(4)

Practical

10(4)

30

22

2

II

Core

5(5)

Core

5(4)

Core

5(5)

Elective

5(4)

Practical

10(4)

30

22

3

III

Core

5(5)

Core

5(5)

Core

5(5)

Elective

5(4)

Practical

10(4)

30

23

4

IV

Core

5(5)

Core

5(5)

Core

5(5)

Elective

5(4)

Project

10(4)

30

23

TOTAL

120

90


5

M.Sc (CHEMISTRY)

Table -2: Course details and scheme of examinations


Semester Title of the Paper Subject Code

Hrs

per

week

Credit

Exam

hrs.

Marks Total

Marks Int Ext

I

Organic chemistry- I

Stereochemistry and reaction

mechanism–I

P18CHC11 5 5 3 25 75 100

Inorganic Chemistry -I

Atomic properties,

coordination and solid state

chemistry- I

P18CHC12 5 5 3 25 75 100

Physical Chemistry -I

Thermodynamics and

electrochemistry

P18CHC13 5 4 3 25 75 100

Major elective: (Any one)

1) Environmental chemistry

2) Biochemistry

P18CHE11

P18CHE12

5

4

3

25

75

100

Practical–I Inorganic

chemistry P18CHPC1P1 10 4 6 40 60 100

II

Organic Chemistry –II

Natural products,

conformational analysis and

reaction mechanism– II

P18CHC21 5 5 3 25 75 100

Inorganic Chemistry -II

Bioinorganic and solid state

chemistry -II

P18CHC22 5 4 3 25 75 100

Physical Chemistry -II

Quantum, catalysis and

molecular spectroscopy-I

P18CHC23 5 5 3 25 75 100

Major Elective: (Any one)

1) Analytical chemistry

2) Industrial chemistry

P18CHE21

P18CHE22

5 4 3 25 75 100

Practical – II

Organic chemistry P18CHC2P1 10 4 6 40 60 100


6

III

Organic Chemistry -III

Reactions , reagents and

spectroscopy

P18CHC31 5 5 3 25 75 100

Inorganic Chemistry -III

Inorganic spectroscopy and

Nano Chemistry

P18CHC32 5 5 3 25 75 100

Physical Chemistry-III

Group theory and molecular

spectroscopy-II

P18CHC33 5 5 3 25 75 100

Major elective: (Any one)

1) Computer applications

2) Pharmaceutical chemistry

P18CHE31

P18CHE32

5 4

3

25

75

100

Practical- III

Physical chemistry P18CHC3P1 10 4 6 40 60 100

IV

Organic chemistry -IV

Molecular rearrangements and

synthetic methods

P18CHC41 5 5 3 25 75 100

Inorganic Chemistry -IV

Nuclear and organometallic

Chemistry.

P18CHC42 5 5 3 25 75 100

Physical Chemistry IV -

Chemical Kinetics , surface,

biophysical and photo chemistry

P18CHC43 5 5 3 25 75 100

Major Elective: (Any one)

1) Introduction to Nano science

2) Polymer chemistry

P18CHE41

P18CHE42

5 4 3 25 75 100

Project / Review of recent

aspects of Chemistry

Viva Voce

P18CHPT41 10 4 6 40 40

20 100

Extra credit paper

Model paper for NET/SET

examination- Chemical sciences

P18CHX41 3 2 100


7

SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE (An Autonomous Institution Re-accredited with ‘A’ Grade by NAAC)

SATTUR-626 203.

Department of Chemistry


Programme : M.Sc. Chemistry Subject Code : P18CHC11

Semester : I No. of Hours allotted : 5 / week

Subject : Core Paper I No of Credits : 5

Title of the Paper : ORGANIC CHEMISTRY - I

STEREOCHEMISTRY AND REACTION MECHANISM- I

Objectives :

To enable the learners

to learn the basic concepts of organic chemistry

to know about the basic concept of stereochemistry in detail

to understand the aromatic character of organic compounds.

to learn the fundamentals of reaction mechanism.

UNIT-I ELECTRON DISPLACEMENT AND STRUCTURE-REACTIVITY

CORRELATION

Inductive and field effects – bond distances - bond energies – delocalised bonds -

cross conjugation– rules of resonance effect -steric inhibition of resonance–hyper conjugation

- hydrogen bonding–addition compound–EDA complexes -inclusion compounds. Quantitative

treatment of the effect of structure on reactivity – The Hammett relationship - significance of

reaction and substituent constants - application of the Hammett equation in reaction

mechanism – limitations and deviation.

UNIT- II STEREOCHEMISTRY –I

Symmetry elements - Concept of chirality , necessary and sufficient conditions for

chirality–Relationship between substrate symmetry and chirality-Projection formulae– Wedge,

Fischer, Sawhorse and Newmann - Optical isomerism due to centre of chirality - Molecules

with one stereogenic centre (chiral centre) and molecules with more than one chiral centr –

properties of enantiomers and diastereoisomers–erythro and threo nomenclature – Cahn-

Ingold - Prelog system of designation of configuration .


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Geometrical isomerism: E-Z nomenclature-determination of configuration of geometrical

isomers using physical and chemical methods–stereoisomerism in monocyclic compounds

(upto six membered ring).

UNIT -III STEREOCHEMISTRY II

Prochirality and prosteroisomerism, enantiotopic and diastereotopic ligands and

faces and their nomenclature - pro-R and pro-S and Re and Si faces - Stereospecfic and

stereoselective reactions - Asymmetric synthesis; Cram and Prelog rule - Optical isomerism

due to axial chirality - biphenyl, Allenes and spiranes - Molecules with planar chirality –

paracyclophanes, trans-cyclooctene and ansa compounds.

UNIT –IV AROMATIC CHARACTER

Aromatic character in benzene, six membered rings, five, seven and eight

membered rings – other systems with aromatic sextets–Huckel’s rule–Craigs rule–concept of

homoaromaticity and antiaromaticity-systems with 2,4,8 and 10 electrons – systems with

more than 10electrons– Alternant and nonalternant hydrocarbons-Chemistry of

cyclopentadienyl anion– Fulvene, Azulene, Tropolones, Sydnones and Annulenes .

Novel ring system: Nomenclature of bicyclic and tricyclic systems- chemistry of adamantane,

diamantane (congressane), cubane and catenanes.

UNIT–V INTRODUCTION TO REACTION MECHANISM

Reaction intermediates–free radicals, carbenes, nitrenes, carbanions, carbocations

formation and stability of reaction intermediates–methods of determination of reaction

mechanism-kinetic and thermodynamic control of chemical reaction - Kinetic and non kinetic

methods for determining organic reaction mechanism–principle of microscopic reversibility –

Hammond postulate-Partial rate factors - ortho/para ratio .

Text books

Text book-1

Title of the book : Reaction mechanism and reagents in organic chemistry

Names of the Author : G.R. Chatwal

Publisher : Himalaya publishing house,

Edition/Year : 5/2012


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Text book-2

Title of the book : Stereochemistry of Organic compounds, Principles and

Application,

Name of the Author : D.Nasipuri

Publisher : Wiley eastern Ltd

Edition/Year : 2 /2006

Text book-3

Title of the book : Stereochemistry conformation and Mechanism

Name of the Author : P.S.Kalsi

Publisher : New age international publishers


Text book-4

Title of the book : Organic chemistry Vol-II

Name of the Author : I.L.Finar

Publisher : ELBS Longmann


Text book-5

Title of the book : Organic reaction mechanism

Name of the Author : V.K Ahluwalia

Publisher : Narosa publishing House New Delhi


Unit –I (From text book 1)

Chapter –2 (Page No.2.1- 2.46)

Unit –II (From text book –2) Chapter – 2 (Page No.15-20)

Chapter – 3 (PageNo.27-36)

Chapter – 5 (Page No. 43-67)

(From text book –4) Chapter – 4 (Page No.170-200)

Unit –III (From text book –3)

Chapter – 1 (Page No.84-130)

Unit –IV (From text book –1)

Chapter –13 (Page No.13.1-13.37)

Unit –V (From text book –5) Chapter –2 (Page No.78-118)

Reference books

Reference Book-1

Title of the book : Guide book to Mechanism in Organic chemistry

Name of the Author : Peter Sykes

Publisher : Orient longmann Ltd., New Delhi,1998,

Edition/Year : 6 / 1984

Reference Book-2

Title of the book : Organic chemistry,

Name of the Author : R.T.Morrison and R.N. Boyd,

Publisher : Prentice, Hall,

Edition/Year : 6/ 1995,


10

Reference Book-3

Title of the book : Mechanism and Structure of Organic Chemistry,

Name of the Author : E.S. Gould,

Publisher : Holt, Rinehart and Winston Inc, New York,


Reference Book-4

Title of the book : Stereo chemistry of carbon compounds,

Name of the Author : E.l.Eliel

Publisher : Mc Graw Hill

Edition/Year : Reprint 2008 Edition / 1975

Reference Book- 5

Title of the book : Advanced Organic Chemistry,

Name of the Author : Jerry March,

Publisher : John Wiley and Sons,

Edition/Year : 4/ 2004.

Prepared by : 1. Ms. V. SOUNDARANAYAKI

2. Ms. K. RAJASULOCHANA

Signature :


11


SATTUR-626 203.



SYLLABUS

Programme : M.Sc Chemistry Subject Code : P18CHC12

Semester : I No. of Hours allotted: 5 / week

Subject : Core - Paper II No. of Credits : 5

Title of the Paper : INORGANIC CHEMISTRY – I

ATOMIC PROPERTIES, COORDINATION AND SOLID

STATE CHEMISTRY -I

Objectives :


to apply molecular orbital theory to the poly atomic molecules

to study the application of redox potential.

to know about bond properties , Ionic bonding and the concepts of solid chemistry

to interrelate the structure of inorganic cages, chains and poly-acids.

UNIT- I ATOMIC PROPERTIES

Bond length- bond order- bond energy, bond polarity – partial ionic character of

covalent bond- covalent character in ionic compounds (Fajan’s rule) - different types of

electrostatic interactions-hydrogenbonding.-Electron affinity-electronegativity- determination

of electronegativity by pauling’s mulliken’s and Allred Rochow methods-factors

determining electronegativity–Lattice energy - Born-Lande equation -Kapustinski’s equation-

Born-Haber cycle.

UNIT- II CHEMICAL BONDING AND REDOX POTENTIAL

Covalent bond: Hybridisation – Calculation of S and P characters – Bent’s rule –

VSEPR theory - M.O.theory- LCAO approximation – application of MOT to heteronuclear

diatomic molecules like NO, CO and triatomic molecule BeH2.

Oxidation and reduction: Concept of oxidation and reduction potentials-periodic

trends- Application of electrode potentials- electrode potential diagrams- Latimer diagram-

Frost diagram –Pourbaix diagram- Ellingham diagram.


12

UNIT -III CO-ORDINATION CHEMISTRY-I

Basics of co-ordination compounds-IUPAC nomenclature of co-ordination

compounds–isomerism in co-ordination compounds–types of ligand monodentate,

ambidentate and macrocyclic ligands–chelate and its applications–detection of complex

formation in solution–stepwise stability constant-overall stability constant-factors affecting

stability constant in solution–determination of stability constant by spectrophotometric,

polorographic and potentiometric and Job’s method.

UNIT –IV SOLID STATE CHEMISTRY – I

Elements of crystallography-space lattice - unit cell-crystal system - X ray

diffraction - Bragg’s equation-Bragg’s method-Rotating crystal method and powder method

of x-ray diffraction - evaluation of unit cell parameters- structure of typical lattice

such as cesium chloride, zinc blende, wurzite, rutile, fluorite, antifluorite, perovskite,

covalent crystal as diamond and graphite.

UNIT -V INORGANIC CHAINS, RINGS AND CAGES

Preparation and structure of polyacids: Classification – isopoly acids like

polymolybdate, polyvanadate and polytungstate ,heteropolyacids 6, 9 and 12 heteropolyacids.

Silicates-classification of silicates - Silicones- Phosphazenes and their polymers – S4N4 –

polymeric sulphur nitride (polythiazyl). Cage compounds:–Nomenclature of boranes and

carboranes –Wade’ rules – Styx number – Multicentered bond in diborane- preparation and

structures of, B4H10, and C2B10H12.- Borazine

Text books

Text Book-1

Title of the book : Inorganic Chemistry- principles of structure and reactivity.

Name of the Author : James E. Huheey , Ellen A. Keitler and Richard L. Keitler,

Publisher : Harper Collins College Publishers


Text Book- 2 Title of the book : Fundamental concepts of inorganic chemistry

Name of the Author : Asim k Das & mahuda Das

Publisher : CBS Publishers & Distributors pvt Ltd, New Delhi.

Edition/Year : 1/ 2014


13

Text Book- 3 Title of the book : Concise Inorganic Chemistry

Name of the Author : J. D Lee

Publisher : Blackwell Science Ltd


Text Book- 4 Title of the book : Text book of Inorganic Chemistry

Name of the Author : G. S Sodhi

Publisher : Viva books Pvt Ltd

Edition/Year : Reprint2013

Text Book- 5 Title of the book : Inorganic Chemistry.

Name of the Author : P.W.Atkins, Overton,Rourke, weller , Armstrong

Publisher : oxford - - ELBS

Edition/Year : 4/2006, reprint 2011

Unit-I (From Text Book-1) Chapter – 4 (Page No 99 to105,129)

Chapter – 5 (Page No 182 to183,194)

Chapter – 8 (Page No296 to 303)

(From Text Book-3)

Chapter – 6(Page No 153 to 161)

(From Text Book-4)


Unit II (From Text Book-1&5)

Chapter –6 (Page No201 to 229)

Chapter –5 (Page No 153 to 157,167to177)

(From Text Book-3)

Chapter – 3,4 (Page No 54- 57, 74-97 107 to 110)

(From Text Book-5) Chapter – 5 (Page141 to 159)

Unit III (From Text Book-2) Chapter – 1(Page No 28 to 39,56 to 61,145 to 156)

Chapter – 4(Page No538 to 548 )

Unit IV (From Text Book-5)



Unit V (From Text Book-1)

Chapter – 16 (Page No 752 to 775, 779 to 802)

Reference Books

Reference Book-1

Title of the book : Fundamental concepts of Inorganic Chemistry(volume 2)

Name of the Author : Asim K Das & Mahua Das

Publisher : CBS publishers& Distributors Pvt Ltd, New Delhi.



14

Reference Book-2

Title of the book : Advanced Inorganic Chemistry

Name of the Author : F.A Cotton and G. Wilkinson

Publisher : John Wiley & Sons Singapore


Reference Book-3

Title of the book : Inorganic Chemistry.

Name of the Author : Alan G Sharpe

Publisher : Pearson education Ltd ,Singapore.

Edition/Year : 3/ reprint 2005

Reference Book-4

Title of the book : Modern Inorganic Chemistry.

Name of the Author : R.D Madan

Publisher : S. Chand &company Ltd.

Edition/Year : 2/ reprinted 2002.

Prepared by : 1. Ms. K. BUVANESWARI

2. Ms. V. SOUNDARANAYAKI

Signature :


15

SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE

(An Autonomous Institution Re-accredited with ‘A’ Grade by NAAC)

SATTUR-626 203.



SYLLABUS

Programme : M.Sc .Chemistry Subject Code : P18CHC13


Subject : Core - Paper III No. of Credits : 4

Title of the Paper : PHYSICAL CHEMISTRY – I

THERMODYNAMICS AND ELECTROCHEMISTRY

Objectives :

To enable the students

to understand the importance and significance of thermodynamics and the principle

of chemical equilibrium.

to acquire an insight into phase rule.

to understand the principles of quantum chemistry.

to know about the importance and significance of electrochemistry and its

applications.

UNIT-I CHEMICAL THERMODYNAMICS

Second law of thermodynamics, concept of entropy. Gibbs-Helmholtz equation,

Maxwell relations and thermodynamic equation of state. Partial molar quantities - Chemical

potential, its variation with temperature and pressure, Gibbs Duhem equation. Experimental

determinations of fugacity of real gases (Graphical, from state equation, approximate and

generalized methods).Third law of thermodynamics – Nernst theorem, absolute entropies,

determinations of absolute entropies, exception to third law and unattainability of absolute

zero.

UNIT-II CHEMICAL AND PHASE EQUILIBRIA

Spontaneous reactions, free energy of a spontaneous reaction, role of temperature,

standard free energy change of a reaction. Thermodynamic derivation for the law of chemical

equilibrium, Van’t Hoff’s reaction isotherm. Temperature dependence of equilibrium

constant, Integrated form of the Van’t Hoff equation. Relation between Kp and Kc. De

Donder’s concept of degree of advancement of a reaction.


16

Gibbs phase rule - its thermodynamic derivation. Application of phase rule to

three component systems - systems composed of two solids and a liquid ( crystallization of

pure components only, hydrate and double salt formation ). Formation of one pair, two pairs

and three pairs of partially miscible liquids.

UNIT–III BASIC PRINCIPLES OF QUANTUM MECHANICS

Planck’s explanation about black- body radiation, de-Broglie’s concept of matter

waves ( Experimental technique and verification), Compton effect, Heisenberg’s uncertainty

principle, Postulates of quantum mechanics, Operators (addition, subtraction, multiplication,

commutator, Hermitian, Hamiltonian and linear operators), Rules for setting up the following

quantum mechanical operators - position, momentum, kinetic energy, potential energy, total

energy, angular momentum, raising and lowering of spin angular momentum. Orthogonality

and normalization of wave functions. Problems on evaluation of commutators and find

expressions of some operators. Simple problems based on to find out the eigen values and

eigen functions.

UNIT-IV ELECTROCHEMISTRY - I

Theory of electrolytic conductance – inter ionic attraction, ionic atmosphere,

thickness of ionic atmosphere. Debye Huckel - Onsager conductance equation – its derivation

and experimental verification, deviations and modifications-Debye Falkenhagen and Wein

effects. Mean ionic activity and activity coefficients of strong electrolytes. Liquid junction

potential and membrane potential. Construction and working of metal-metal ion electrode,

hydrogen electrode, calomel electrode and oxidation-reduction electrode. Types of cells -

Electrochemical cells –primary cells, secondary cells and fuel cells. Experimental

determination of EMF of cells. Nernst equation. Applications of EMF measurements-

determination of equilibrium constant, pH and solubility product.

UNIT-V ELECTROCHEMISTRY - II

The electrical double layer and zeta potential. Perrin, Gouy-Chapmen and Stern

models. Butler-Volmer equation - Tafel equation. Over voltage, Hydrogen over voltage.

current-potential curves , Potentiometric titrations – principles and types (acid- base, redox

and precipitation).Conductometric titrations – principles and types ( acid – base and

precipitation )


17

Text books

Text book-1

Title of the book : Principles of Physical chemistry

Name of the Author : B.R.Puri, L.R.Sharma,M.S.Pathania

Publication : Vishal publishing Co,New Delhi.

Edition/ year : 45 /2012

Text Book- 2

Title of the book : Advanced Physical chemistry

Name of the Author : Gurdeep Raj

Publisher : Goel Publishing Co.Meerut.


Text Book- 3

Title of the book : Quantum chemistry

Name of the Author : R.K Prasad

Publisher : New Age International publishers


Text Book- 4

Title of the book : An Introduction to Electrochemistry

Name of the Author : S.Glasstone

Publisher : East West Press (P) Ltd.


Unit-I (From Text Book-1) Chapter – 14 (Page No.517-541,546-549)

Unit-II (From Text Book-1) Chapter – 16 (Page No.564-573,581-582)

(From Text Book-2)

Chapter – 18 (Page No.1050-1052, 1054-1056, 1079-1083, 1085-1088)

Unit- III (From Text Book-1) Chapter -1(Page No.23-25, 32-39, 43, 44)

(From Text Book-3)

Chapter -2(Page No.32, 33)

Chapter -3(Page No. 34-55)

Unit-IV (From Text Book-1)

Chapter – 22 (Page No.770-829,845-850,867-887)

(From Text Book-4)


Unit-V (From Text Book-1)

Chapter – 24 (Page No.845-851,867-873)

Reference Books

Reference Book-1

Title of the book : Thermodynamics for chemists

Name of the Author : S.Glasstone

Publisher : East West Press (P) Ltd,New Delhi.



18

Reference Book-2

Title of the book : Thermodynamics

Name of the Author : J.Rajaram and J.C. Kuriakose

Publisher : Shoban Lal Nagin, Chand & Co, New Delhi.


Reference Book-3


Name of the Author : D.N. Bajpai

Publisher : S.Chand &Company Ltd, New Delhi.


Reference Book-4

Title of the book : Electrochemistry

Name of the Author : B.K. Sharma

Publisher : Goel Publishing House,Meerut.


Prepared by : 1. Ms. M. SELVAMARIAMMAL

2. Ms. K. BUVANESWARI

Signature :


19



SATTUR- 626 203.



SYLLABUS

Programme : M.Sc., Chemistry Subject Code : P18CHE11


Subject : Paper IV Major Elective I- (a) No. of Credits : 4

Title of the Paper : ENVIRONMENTAL CHEMISTRY

Objectives:


to learn about pollutions and its types.

to know the sources and control measures of various pollution.

UNIT- I INTRODUCTION AND CLASSIFICATION OF POLLUTION

Introduction, definitions – environment, environmental science, environmental

education. Types of environment and its components. Definitions- ecology, ecosystem. Types

and components of ecosystem. Cycling of minerals, elements and gases –Phosphate cycle-

Carbon cycle- Nitrogen Cycle- Hydrological cycle. Sources, effects and control measures of

various pollution - air pollution-water pollution- soil pollution- radioactive pollution- thermal

pollution- noise pollution- marine pollution.

UNIT-II ANALYSIS OF POLLUTANT

Neutron activation analysis-Anodic stripping voltametry-Atomic absorption

spectrophotometry - X-RayFlorescence - non-dispersive infrared spectrometry -Fourier

transform infrared spectroscopy- chemiluminescence-gas chromatography-High performance

liquid chromatography-Ion selective electrode.

UNIT-III AIR POLLUTION

Introduction – sources of air pollution – air pollutants – classification and effects of air

pollutants – oxides of nitrogen, sulphur and carbon- acid rain-effects and control-hydrogen

sulphide – effects and control- carbon mono oxide – effects and control- photochemical smog

– effects and control – fly ash – effects and control – green house effect – global warming –

effects and control – ozone layer – ozone depletion – choloro fluoro carbons – effects and

control.


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UNIT- IV SOIL POLLUTION

Introduction- types of soil on the basis of its texture- sources of soil pollution-

fertilizers and pesticides- radioactive pollutants- soil sediments as pollutant. Soil erosion –

types- harmful effects-causes and its control measures. Solid waste management-types,

sources and effect of improper solid wastes. Process of solid waste management- disposal

methods- sanitary land filling - incineration and composting methods. Control measures of

soil pollution.

UNIT- V INDUSTRIAL POLLUTION & CHEMICAL TOXICOLOGY

Introduction-causes of industrial pollution–thermal power plants-nuclear power

reactors-fertilizers and chemical industry-pulp and paper industries – agro based industries-

cement industry. Toxic chemicals in the environment –biochemical effects of arsenic,

cadmium, lead, mercury and cyanide- bio-ware agents.

Text books

Text Book- 1

Title of the book : Environmental Chemistry,

Name of the Author : A.K De,

Publisher : New Age International Publishers, Delhi

Edition/Year : 7 /2010 (Reprint)

Text Book- 2

Title of the book : Environmental chemistry

Name of the Author : B.K.Sharma

Publisher : Goel Publishing House


Unit I (From Text Book-1)

Chapter 1 (Page No 1 to 12)

Chapter 6 (Page No 85, 86)

Unit II (From Text book -1)

Chapter 14(Page No 295 to 313)

Unit III (From Text book -2)


Chapter 4 &5 (Page No 157 to163, 181)




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Unit IV (From Text Book-2)

Chapter -1(Page No. 33 to 34)

Chapter -2(Page No 47-55, 62-64)

Chapter-3(Page No 75-80)

Unit V (From Text book -1)



Reference Books

Reference Book-1

Title of the book : Environmental Chemistry,

Name of the Author : B.K Sharma and H.Kaur,

Publisher : Krishna Prakashan, Meerut


Prepared by : Ms. V. SOUNDARANAYAKI

Signature :


22



SATTUR-626 203.



SYLLABUS

Programme : M.Sc ., Chemistry Subject Code : P18CHE12


Subject : Paper V- Major Elective – I (b) No. of Credits : 4

Title of the Paper: BIO CHEMISTRY

Objectives:


to understand the biological role of enzymes in living organisms

to get a knowledge about the metabolism and genetic information.

UNIT-I ENZYMES

Classifications, nomenclature, properties of enzymes, some features of active sites of

enzymes, enzyme kinetics-Michaelis-Menton model-significance of Km and Vmax Values,

Enzyme inhibition-competitive and non-competitive. Allosteric interaction-Mechanism of

enzyme action .Lysozyme and carboxypeptidase.

UNIT-II GENERATION AND STORAGE OF METABOLIC ENERGY

Metabolism-basic concepts and design: glycolysis-citric acid cycle-oxidative

phosphorylation-pentose pathway and gluoneogenesis. Glycogen and disaccharide

metabolism, fatty acid metabolism –amino acid degradation and urea cycle-photosynthesis.

UNIT-III INFORMATION, STORAGE, TRANSMISSION OF GENETIC

INFORMATION

DNA-Genetic role structure and replication: messenger RNA and transcription

genetic code and gene protein relationship-protein synthesis, control of gene expression -

Eukaryotic chromosomes, Recombinant DNA technology and viruses.


23

UNIT-IV BIO-INORGANIC CHEMISTRY

Metalloproteins and enzymes- Blue copper proteins-copper proteins as

oxidases/reductases-Nickel containing enzymes-structure of DNA-types of nucleic acid

interactions-coordination, intercalation and hydrogen bonding-interactions of metal ions with

nucleic acid-redox chemistry. Hydrolytic chemistry- monitoring the DNA binding by UV, IR,

NMR and CV spectral techniques.

UNIT-V BIOPHYSICAL ASPECTS

Electron transport and oxidative phosphorylation - Thermodynamic and kinetic

aspects-Photosynthesis-An overview- Photo system II-The light harvesting chlorophyll -

protein complexes of photo system II-Role of carotenoids in photosynthesis-The primary

electron donor of photo system II, P680 - The stable primary electron acceptor QA and the

secondary electron acceptor QB–The transient intermediate electron acceptor of photo

system II, pheophytin-Oxygen evolution-The role of manganese-The electron donor to P680+

- Charge recombination in photo system II-Photo system I-Light-harvesting chlorophyll -

protein complexes of photo system I - The primary electron donor of photo system I ,P700-

The primary electron acceptor Ao of photo system I- The intermediate electron acceptor A1

of photo system I-Mobile electron carriers plastocynanin and ferredoxin NADP+ - reductase.

Text books

Text Book- 1

Title of the book : Fundamentals of Biochemistry

Name of the Author : J.L Jain

Publisher : S.Chand & company Limited


Text Book- 2

Title of the book : Bioinorganic Chemistry

Name of the Author : I.Bertini, H.B.Gray S.J.Leppard and J.S Valentine

Publisher : Viva Books Pvt Ltd..


Text Book- 3

Title of the book : Biochemistry

Name of the Author : A.L.Lehninger,

Publisher : CBS publishers



24

Text Book -4 Title of the book : An Introduction to Inorganic Chemistry

Name of the Author : K.F. Purcell and J.C. Koltz,

Publisher : W.B. Saunders Company, Philadelpha 1980

Edition/Year : 1/19

Unit-I (From Text Book-1)

Chapter 16 (Page No. 277-286,309-331)

Unit-II (From Text Book-1)

Chapter 21(Page No 367-412,420-422)

Unit-III (From Text Book-3 )

Chapter 4 (Page No 791-913)

Unit IV (From Text Book -2)

Chapter 6 (page No 315-346)

Unit-V (From Text Book -4) Study materials will be provided

Reference Books

Reference Book-1

Title of the book : Biochemistry

Name of the Author : B.D.Hames and N.M.Hooper

Publisher : Viva Books Ltd


Reference Book-2

Title of the book : Biochemistry,

Name of the Author : J.M. Berg, J.L.Tymoczko and L.Stryer,

Publisher : W.H.Freeman and company, New York


Reference Book-3

Title of the book : Bio-inorganic Chemistry.

Name of the Author : Asim.K.Das

Publisher : Books&Allied Pvt Ltd, Kolkata

Edition/Year : 1/Reprinted 2013


Signature :


25



SATTUR-626 203.



SYLLABUS

Programme : M.Sc ., Chemistry Subject Code : P18CHC1P1


Subject : Paper V Practical - I No. of Credits : 4

Title of the Paper : INORGANIC CHEMISTRY PRACTICAL

Objectives:


to understand the principle for the estimation of binary mixture.

to apply the principle in the semi-micro analysis of an inorganic salt mixture.

to prepare the inorganic complexes

1. SEMI-MICRO QUALITATIVE ANALYSIS: Analysis of mixtures containing one

familiar and one less familiar cations from the following W, Pb, Se, Mo, Cu, Cd,

Bi,V,Ce, Th,Zr Mn, Ni, Co, Zn, Ca, Ba, Sr, Li, Mg (insoluble and interfering an ion

may be avoided).

2. INORGANIC PREPARATIONS: preparation of at least 5 inorganic complexes.

3. QUANTITATIVE ANALYSIS: separation and estimation of mixtures by volumetric

and gravimetric methods, some recommended mixtures are

i) Cu and Ni

ii) Fe and Ni

iii) Ca and Ba

iv) Cu and Zn

v) Fe and Cu

4. ESTIMATIONS: Estimation of Cu & Mg by EDTA Method (class work only)


26

References

Reference Book-1

Title of the book : Vogel’s Text Book of Quantitative Chemical Analysis

Name of the Author : J. Bassett et al

Publisher : ELBS, Longmann, U.K


Reference Book-2

Title of the book : Inorganic Semi micro Qualitative Analysis

Name of the Author : V.V. Ramanujam

Publisher : The National Publishing Co, Chennai


Prepared by : Ms. K. BUVANESWARI

Signature :


27


SATTUR-626 203.



Programme : M.Sc ., Chemistry Subject Code : P18CHC21

Semester : II No. of Hours allotted : 5 / week

Subject : Core Paper VI No of Credits : 5

Title of the Paper : ORGANIC CHEMISTRY – II

NATURAL PRODUCTS, CONFORMATIONAL ANALYSIS

AND REACTION MECHANISM – II

Objectives:


to know the concept of aliphatic nucleophilic and electrophilic substitution and

elimination.

to learn the concept of addition to multiple bonds.

to understand the principle of UV, IR and Mass spectroscopy and their application in

organic chemistry.

to know about the chemistry of carbohydrates and terpenoids.

to understand the concept of conformational analysis.

UNIT- I ALIPHATIC NUCLEOPHILIC SUBSTITUTION

Nucleophilicity and basicity – SN1and SN2 mechanisms – Effect of substrate structure

- Effect of the attacking nucleophile–Effect of the leaving group –Effect of the reaction

medium – ambident nucleophiles – ambident substrates– neighbouring group participation by

n, π and σ bonds–SNi mechanism- nucleophilic substitution at an allylic and a vinylic carbon.

Aliphatic electrophilic substitution: Electrophilic substitution at saturated carbon – SE1,SE2

and SEi mechanism.

Elimination: Elimination - E1, E2 and E1CB mechanism – stereochemistry of

Elimination – orientation of the double bond– Effect of changes in the substrates base,

leaving group and medium on E1, E2, and E1CB reactions – elimination Vs substitution –

pyrolytic cis eliminations – Bredts rule .


28

UNIT- II ADDITION TO MULTIPLE BONDS

Electrophilic, nucleophilic and free radical additions - addition to conjugated systems

– orientation of the addendum - stereochemical factors in reactions like addition of hydrogen,

halogens, hydrogen halides and hypohalous acids, hydroboration and hydroxylation -

epoxidation. Addition to carbonyl groups – mechanism - Aldol condensation – Perkin

reaction - Knoevenagel reaction - Mannich reaction - Cannizaro reaction – Benzoin

condensation - Claisen ester condensation –Darzen’s reaction - Reformatsky reaction - Wittig

reaction – Grignard reactions.

Addition to α,β -Unsaturated carbonyl groups : Addition of Grignard reagents to α,β-

unsaturated carbonyl compounds – Michael addition – Diels-Alder reaction .

UNIT- III SPECTROSCOPY I

UV Spectroscopy: Principle-absorption spectra of conjugated dienes–α,β -

unsaturated carbonyl compounds–Woodward-Fieser rules-Scott’s rules for aromatic

carbonyls.

IR Spectroscopy : Principle- Molecular vibrations – vibrational frequency - factors

influencing group frequencies – quantitative studies.

Mass Spectrometry: Principle – type of ions – base peak – parent ion, meta stable and

isotopic peaks – nitrogen rule – fragmentation - general rules - pattern of fragmentation for

compounds such as hydrocarbons, amines, alcohols, ketones, acids, phenols and nitro

compounds – McLafferty rearrangement – Retro Diels-Alder reaction.

UNIT- IV CARBOHYDRATES , AMINOACIDS, PROTEINS AND TERPENOIDS

Carbohydrates: Methods used for determination of ring size – structure elucidation

of maltose, lactose and cellobiose - a brief study of starch and cellulose (structure only).

Terpenoids: Classification of terpenoids – structural elucidation of Camphor,

α-pinene, zingiberene , lanosterol and squalene.

Aminoacids and Proteins: General structure of amino acids - peptides –representation

of peptide bond-determination of the amino acid sequence of a polypeptide chain-

Classification of proteins – structure of (primary, secondary, tertiary and quaternary) peptides

- structural elucidation of glutathione and oxytocin


29

UNIT -V CONFORMATIONAL ANALYSIS

Configuration and Conformation – Conformation of ethane, 1,2-dicholoroethane and

n-butane-conformational analysis–stereoelectronic and steric factors - conformation of simple

acyclic compounds-conformation of monosubtituted and disubstituted cyclohexanes –

conformation of acyclic and cyclic systems with their physical and chemical properties –

conformational free energy – Curtin- Hammett principle - Quantitative treatment of Mobile

system - Eliel-Ro equation – conformations and reactivity of cyclohexanones.

Text books

Text book-1


Name of the Author : G.R. Chatwal



Text book-2





Text Book- 3

Title of the book : Reactions, Rearrangements and Reagents

Name of the Author : Somorendra Nath Sanyal

Publisher : Bharati Bhawan Publishers


Text Book- 4

Title of the book : Elementary organic spectroscopy principles and chemical

applications

Name of the Author : Y.R.Sharma

Publisher : S.Chand and company Ltd, New Delhi

Edition/Year : Reprint /2012

Text book-5

Title of the book : Stereochemistry conformation and Mechanism

Name of the Author : P.S.Kalsi



Text book-6

Title of the book : Organic chemistry of natural products

Name of the Author : G.R. Chatwal


Edition/Year 4/2007


30

Unit-I (From Text Book-2) Chapter-1(page No 12-33, 50-59)


Chapter -7 (Page No 7.1-7.61)

(From Text Book-3) Chapter-2(PageNo77-83,97-107,117-121,141-146,148-152,154-158,161-164,182-185)

Unit-III (From Text Book-4) Chapter-2 (Page No.9-12, 15-33, 34-42, 44-54)

Chapter-3 (Page No.69-82, 89-140)

Chapter-7 (Page No.280-328)


Chapter-1 (Page No.1.46-53, 1.115-123, 1.132-144)

Chapter-2 (Page No.2.62-93, 2.98-101)



Reference Books

Reference Book-1

Title of the book : Stereochemistry of Organic Compounds, Principles and

Applications Name of the Author : D.Nasipuri,

Publisher : New Age International (P) Ltd.,

Edition/Year : 2 / 1994.

Reference Book-2

Title of the book : Mechanism and Structure in Organic Chemistry,

Name of the Author : E.S. Gould,

Publisher : Henry Holt& Co.,New York ,


Reference Book-3

Title of the book : Organic Spectroscopy,

Name of the Author : William Kemp,

Publisher : ELBS,


Reference Book-4

Title of the book : Spectrometric Identification of Organic Compounds,

Name of the Author : Robert M.Silverstein, Francis X. Webster,

Publisher : John Wiley and Sons Inc.,


Reference Book-5

Title of the book : Spectroscopy of Organic Compounds,

Name of the Author : P.S.Kalsi,

Publisher : New Age International Publishers,



31

Reference Book-6

Title of the book : Advanced Organic Chemistry,

Name of the Author : Jerry March,



Reference Book-7

Title of the book : Stereo chemistry of carbon compounds,

Name of the Author : E.l.Eliel

Publisher : Mc Graw Hill

Edition/Year : Reprint 2008


2. Ms. K. RAJASULOCHANA

Signature :


32



SATTUR-626 203.



SYLLABUS

Programme : M.Sc., Chemistry Subject Code : P18CHC22

Semester : II No. of Hours allotted: 5 / week

Subject : Core Paper VII No. of Credits : 4

Title of the Paper : INORGANIC CHEMISTRY – II

BIOINORGANIC AND SOILD STATE CHEMISTRY- II

Objectives:


To have an insight into study of coordination compounds and their reactions

To have an understanding of role of inorganic metal complexes in living systems

UNIT -I CO-ORDINATION CHEMISTRY-II

Theories of bonding: VB theory and CFT theory – splitting of d-orbitals in Oh, Td,

square planar and tetragonal distortion –Jahn-Teller distortions – CFSE calculation in terms

of Dq – factors affecting crystal field splitting energy– spectrochemical series – applications

of CFSE – MOT diagram of octahedral, Td and square planar complexes – effect of π-donor

and π-acceptor ligands – magnetic properties of transition metal complexes – calculation of

spin-only magnetic moments –orbital contribution to the magnetic moment – spin orbit

coupling.

UNIT -II BIO – INORGANIC CHEMISTRY–I

Porphyrin ring system – metalloporphyrins – hemogolobin and myoglobin

structures and work functions – synthetic oxygen carriers – cytochromes and its types –

structure and work functions in respiration – chlorophyll – structure – photosynthetic

sequence – iron sulphur proteins [ non – heme iron protein] – copper containing proteins –

classification – blue copper proteins – structure of blue copper electron transferases, copper

proteins as Oxidases .


33

UNIT -III BIO – INORGANIC CHEMISTRY – II

Structure and function of enzyme: carboxypeptidase A–carbonic anhydrase –

inhibition and poisoning – corin ring system – vitamin B12 and B12 Coenzymes – in – vivo

and in – vitro nitrogen fixation – essential and trace elements in biological systems- metal ion

toxicity(Cu, Cd Fe, Pb, Hg, Cr) and its detoxification -sodium and potassium ions pumps –

chelate therapy – cis platin

UNIT -IV ACID – BASE SYSTEMS AND NON AQUEOUS SOLVENTS

Acid –base definition: Bronsted–Lowry, Lux–flood, Solvent system , Lewis concept

Usanovich concept , generalized acid – base concept – steric effect on the strength of acids

and bases – HSAB concept – Symbiosis.

Non Aqueous Solvents: Classification of solvents- A general study of typical reactions in

non aqueous media like liquid NH3, H2SO4 , liquid N2O4 , liquid SO2 and molten salts as non

aqueous solvents.

UNIT- V SOLID STATE CHEMISTRY II

Dislocation in solids- point defects-stoichiometric-schottky defect and frenkel defect

and non stoichiometric defects-metal excess defect and metal deficiency defect-color centers

–free electron theory (Drude Lorentz model) merits and demerits – Band theory - types of

solids – super conductivity – high temperature super conductors – types of semiconductors –

Hall effect - photo voltaic effect – Semi conductors in solar energy conversion-solar cell.

Text books

Text Book- 1

Title of the book : Inorganic Chemistry-principles of structure and reactivity




Text Book-2


Name of the Author : P.W.Atkins, Overton,Rourke, weller , Armstrong

Publisher : oxford university press

Edition/Year : 4/2006, reprinted 2011

Unit-I - V (From Text Book-1) Chapter 11( page No 391to 393, 394-424,459-464)

Chapter 19(Page No 891 to 936,941-947,956-958)

Chapter 9 (Page No 318 to 330,341to 355)

Chapter 10 (Page No 360 to 366,375-376)

Chapter 7 (Page No 263- 275, 285-288)


34

Unit-I - V (From Text Book-2)

Chapter 3 (Page No102-106)

Chapter 26 (Page No719-720,727-730,761-762)

Reference Books

Reference Book-1

Title of the book : An Introduction to Inorganic Chemistry

Name of the Author : K.F. Purcell and J.C. Koltz,

Publisher : W.B. Saunders Company, Philadelpha 1980


Reference Book-2

Title of the book : Bio-inorganic Chemistry.

Name of the Author : Asim.K.Das

Publisher : Books&Allied Pvt Ltd, Kolkata

Edition/Year : 1/Reprinted 2013

Reference Book-3


Name of the Author : Alan G Sharpe

Publisher : Pearson education Ltd ,Singapore.

Edition/Year : 3/ reprint 2005

Reference Book-3

Title of the book : Introduction to solids

Name of the Author : L.V.Azaroff

Publisher : Tata Mc Graw Hill Publishing House


Reference Book-4

Title of the book : Coordination Chemistry- An approach

Name of the Author : S.F.A Kettle

Publisher : SpectrumAcademic publishers,




Signature :


35


SATTUR-626 203.



SYLLABUS



Subject : Core Paper VIII No. of Credits : 5

Title of the Paper : PHYSICAL CHEMISTRY - II

QUANTUM, CATALYSIS AND MOLECULAR SPECTROSCOPY-I

Objectives:


to apply the principles of quantum chemistry to simple systems, atomic and molecular

systems and to obtain their energies.

to understand the theory and applications of catalysis.

to get an insight into the principles of molecular spectroscopy.

UNIT- I APPLICATION OF QUANTUM MECHANICS TO SIMPLE SYSTEMS

Derivation of Schrodinger wave equation (SWE). Application of SWE to simple

systems - particle moving in one dimensional box, particle moving in a 3-D box- degeneracy

– distortion, particle moving in a ring, rigid rotator, simple harmonic oscillator. Radial

wave function and radial probability distribution function. Shapes of various atomic orbitals.

UNIT- II APPROXIMATION METHODS IN QUANTUM MECHANICS

Need for approximation methods (variation and Perturbation methods). Perturbation

corrections-first order correction. Schrodinger equation for He atom. Variation theorem-

application to hydrogen and He atoms. Hartee - Fock Self Consistent Field (HFSCF) theory-

application to He atom, HFSCF method of many electron system. Electron spin and Pauli

principle, anti symmetric nature of the wave functions, Slater rules and Born-Oppenheimer

approximation.

UNIT- III STATISTICAL THERMODYNAMICS-I

Aims of statistical thermodynamics, definitions of state of a system, ensembles and

their types, micro and macro states, thermodynamic probability. Derivation of Boltzmann

distribution law. Quantum statistics – derivation of Fermi-Dirac and Bose-Einstein statistics.

Comparison of Maxwell-Boltzmann, Bose-Einstein and Fermi-Dirac statistics, bosons and

fermions. Problems on distribution laws-photon gas and electron gas. Boltzmann-Planck

equation


36

UNIT- IV CATALYSIS

Catalysis - Types, characteristics and theory of catalysis. Heterogeneous catalysis-

kinetics, retardation and effect of temperature. Mechanism of Heterogeneous catalysis-

Langmuir – Heinshelwood and Langmuir – Rideal- mechanism- Classification of catalysis.

Enzyme catalysis – -characteristics- factors governing the rate of enzyme reaction-

Mechanism and its kinetics (Michaelis Menten equation), Line weaver - Burk plot and

Eadie’s plot. Acid–Base catalysis –Mechanism and its kinetics. Hammett and Bronsted

equation, Acidity function. .

UNIT-V MOLECULAR SPECTROSCOPY-I

Electromagnetic spectrum. Types of molecular energies. Absorption and emission of

radiation. Einstein’s coefficient-induced emission and absorption. Rotational spectra of rigid

diatomic molecules-isotope effect in rotational spectra. Microwave spectrometer.

Informations derived from rotational spectra.

Infrared spectroscopy: Vibrational energy of diatomic molecule-infrared selection

rules-diatomic vibrating rotator. Vibrations of polyatomic molecules - overtone, combination

and difference bands. Concept of group frequencies - coupling interaction. Fermi resonance-

FT-IR.

Text books

Text Book- 1

Title of the book : Introductory Quantum chemistry

Name of the Author : A.K.Chandra

Publisher : Tata McGraw –Hill Publishing Company Limited,New Delhi.


Text book-2





Text Book- 3



Publisher : Goel Publishing Co,Meerut.



37

Text Book- 4

Title of the book : Fundamentals of molecular spectroscopy

Name of the Author : Colin N. Banwell and Elaine M.McCash

Publisher : Tata McGraw- Hill Publishing Company Limited


Unit- I & II (From Text Book-1)

Chapter -3(Page No.39-55)





Unit-III (From Text Book-3) Chapter – 3 (Page No.254-262,281-293)

Unit -IV (From text book 3)

Chapter-15(Page No.841-872)

Unit- V (From Text book-2 & 4) Chapter-2&3(Page No. 31-98)

Chapter-4(Page No. 100-126)

Reference Books

Reference Book-1

Title of the book : Quantum chemistry

Name of the Author : R.K.Prasad

Publisher : New Age International Publishers, New Delhi


Reference Book-2

Title of the book : Molecular structure and spectroscopy

Name of the Author : G.Aruldhas

Publisher : PHI Learning (P) Limited, New Delhi


Reference Book-3

Title of the book : Physical chemistry of surfaces

Name of the Author : A.W.Adamson,

Publisher : John Wiley&sons,New York


Prepared by : 1. Ms. M. SELVAMARIAMMAL


Signature :


38


SATTUR-626 203.



SYLLABUS


Semester : II No. of Hours allotted: 5/ week

Subject : Paper IX Major Elective –II (a) No. of Credits : 4

Title of the Paper : ANALYTICAL CHEMISTRY

Objectives:


to learn the principle of electro analytical methods & spectro analytical methods.

to gain knowledge on the basic concepts of error analysis

UNIT-I PRECIPITATION TECHNIQUES

Introduction-properties of precipitates and precipitating reagents –colloidal

precipitates, Coprecipitation-post precipitation –precipitates from homogeneous solution –

surface adsorption –drying and ignition of precipitates –application of gravimetric methods

UNIT-II ERROR ANALYSIS

Error analysis: Classification of errors-accuracy and precision-minimization of errors-

significant figures-significant figures in computation-statistical treatment of data: mean,

median, standard deviations, variance, relative standard deviation –spread, errors-standard

deviation of computed results-Student’s t-test, F-test-comparison of the means of two

samples-Q test- correlation and regression: linear regression (least square analysis).

UNIT-III ELECTRO ANALYTICAL METHODS

Electro analytical techniques: Electrogravimetry, theory of eletrogravimetric analysis-

electrolytic separation and determination of metal ions.Coulometry: Electrolytic cell-working

electrodes-auxiliary electrode and reference electrode- coulometric titrations Voltammetry:

Cyclic voltammetry – stripping voltammetry - chronopoteniometry. Amperometry:

Amperometric titrations.


39

UNIT-IV THERMOANALYTICAL METHODS

Thermal analysis, theory and principles of DTA and TGA- factors affecting the

position of DT and TG traces-application of DTA and TGA to the thermal behavior of the

following compounds-crystalline coppersulphate, calcium oxalate monohydrate, calcium

acetate monohydrate, zinc hexafluosilicate-complementary nature of DTA and TGA-

principle and application of DSC-determination of degree of conversion of high alumina

cement-purity determination-phase transition study –in forensic laboratory.

UNIT-V SPECTROANALYTICAL METHODS

Colorimetry: Beer and Lambert’s law-terminology-condition for a satisfactory

colorimetric analysis-method of colour measurement or comparison-principles of

colorimetric determinations of NH3, Cr, Cu, Fe, Mn-simultaneous spectrophotometer

determination of Cr and Mn.

Nephelometry and turbidimetry:principle-determination of sulphate and phosphate-

fluorimetry: principle-application of fluorimetry in the determination of Cd,Ca,and Zn and

determination of codeine and morphine in a mixture-flame spectrometry: theory-

interferences-AAS-applications in the determination of Mg+2

and Ca+2

in tap water ,V in

lubricating oil, trace lead in a ferrous alloy and trace elements in contaminated soil.

Text books

Text Book- 1

Title of the book : Elements of analytical chemistry

Name of the Author : R.Gopalan

Publisher : Sultan Chand & sons, New Delhi


Text Book- 2

Title of the book : Instrumental method of chemical analysis

Name of the Author : Gurdeep chatwal

Publisher : Himalaya publishing House



Chapter 9(Page No 121 to134)



Unit-III (From Text Book-1)

Chapter 10(Page No 139 to 145,148 to 150)

(From Text Book-2)

Chapter 28(Page No 2.541 to 2.545)


40





Chapter 13 to 16(Page No 2.389 to 2.398, 2.349 to 2.416, 2.367)

Reference Books

Reference Book-1,

Title of the book : Fundamentals of Analytical Chemistry,

Name of the Author : D.A.Skoog, D.M.West and F.J.Hollar

Publisher : Harcourt College Publishers,


Reference Book-2

Title of the book : Instrumental Methods of Analysis

Name of the Author : H.H.Williard,L.L.Merritt and J.A.Dean

Publisher : East-West press New Delhi


Reference Book- 3

Title of the book : Analytical chemistry

Name of the Author : U.N Dash

Publisher : Sultan Chand & sons, New Delhi


Reference Book-4

Title of the book : Vogel’s Text Book of Quantitative Chemical Analysis

Name of the Author : J. Bassett et al

Publisher : ELBS, Longmann, U.K


Reference Book-4

Title of the book : Analytical chemistry

Name of the Author : J. G.Dick

Publisher : Tata-McGraw Hill



Signature :


41


SATTUR-626 203.


(For those who joining in 2018 -2019 and after)

SYLLABUS



Subject : Paper IX-Major Elective –II (b) No. of Credits : 4

Title of the Paper : INDUSTRIAL CHEMISTRY

Objectives:


To understand the principle and importance of chemical technology

To utilize the raw materials in chemical industry

To get the awareness about the pollution and its control

UNIT-I PRINCIPLES AND IMPORTANCE OF CHEMICAL PROCESS INDUSTRY

Introduction – importance of chemical industry – new developments in chemical

technology – classification of technological processes – unit process and unit operation –

batch and continuous process – Indian chemical industry today – basic principles of

homogeneous and heterogeneous non catalytic processes.

UNIT-II RAW MATERIALS AND ENERGY FOR CHEMICAL INDUSTRY

Raw materials-Characteristics of raw materials and their resources- methods of raw

material concentration –integral utilization of raw materials

Energy for chemical industry-power and fuels-classification of fuels, coal, fuel gases

and liquid fuels-petroleum-cracking-chemical corrosion-types of corrosion and preventive

measures

UNIT-III Water Pollution and its Control

Introduction – types of water –soft and hard water-softening of water– water

pollution – sources of water pollution – water pollutants – classification – physical, chemical

and biological – inorganic pollutants and toxic metals – organic pollutants – -pesticides and

fertilizers – suspended particles – water quality – ill effects of water pollutants – water

pollution control – water treatment – primary, secondary and tertiary treatment – desalination

– reverse osmosis – sewage and industrial waste water treatment.


42

UNIT-IV SMALL SCALE CHEMICAL INDUSTRIES

Electro-thermal and electro-chemical industries: Electric furnace – classification -

manufacture of calcium carbide- Electrolytic manufacturing and refining of aluminium -

process and theory of electroplating.

Oils, fats and waxes: Manufacturing of soyabean oil-Analysis of oils,fats and waxes-

manufacture of soap by batch process - detergent (cationic ,anionic and non-ionic) –

preparation, properties and uses of potassium chlorate . .

UNIT-V LARGE SCALE CHEMICAL INDUSTRIES

Manufacturing process - raw materials - composition and uses of products in Portland

cement – ceramics - plastics(Polyethylene, PVC) -- synthetic fibres (Nylon66, Nylon 6,

Terylene) - natural Rubber- Refining of crude rubber - Vulcanization of rubber and Synthetic

rubbers (BunaS, Neoprene) - fertilizers(Nitrogen and phosphate)- Organic insecticides

(DDT,BHC)

Text Book- 1

Title of the book : ChemicalTechnology,Vol.1.

Name of the Author : I.Mukhlyonov(ed.),

Publisher : Mir publication, Moscow


Text Book- 2

Title of the book : Enviromental Chemistry

Name of the Author : A.K.De

Publisher : New age International (P) Limited


Text book-3

Title of the book : Industrial chemistry

Name of the Author : B.K Sharma

Publisher : Goel publishing house.


Text book-4

Title of the book : Outlines of Chemical Technology

Name of the Author : M.Gopala Rao Drydens

Publisher : East-West Press


Text Book- 5

Title of the book : Polymer Science

Name of the Author : V.R.Gowarikar, N.V.Viswanathan and Jayadev Sreedher,

Publisher : Wiley Eastern Ltd., New Delhi



43


Chapter 2(Page No 20-25,68-89)

Chapter 3(Page No90-118)

Chapter 4(Page No 136-158)

Chapter 5(Page No159-230)

(From textbook -4)

Chapter 1(Page No.)


Chapter 7(page no.287-307,316-320)

(From Text Book-2)

Chapter 12(page no292-295)

Unit-III (From Text Book-2) Chapter -12 &13 (Page No. 197-292)

Unit-IV (From Text Book-1) Chapter -7 (Page No. 245 to 285)

Unit-V (From Text Book- 5 &3 ) Chapter 9 (Page No 215 to 220)

Reference Books

Reference Book-1

Title of the book : Chemical process industries

Name of the Author : R.Norris shreve & J.A.Brink

Publisher : McGraw Hill


Reference Book-3

Title of the book : Hand book of industrial Chemistry

Name of the Author : James A.Kent

Publisher : CBS Publishers & Distributors PVT. Ltd.



Signature :


44



SATTUR-626 203.



SYLLABUS



Subject : Paper X Practical - II No. of Credits : 4

Title of the Paper : ORGANIC CHEMISTRY PRACTICAL

Objectives :


to estimate the organic compounds quantitatively

to prepare organic compounds by two stage preparation

to separate and analyze the given organic mixture into two different components

QUALITATIVE ANALYSIS

Separation and analysis of two component mixtures. Identification of the

components and preparation of solid derivative.

QUANTITATIVE ANALYSIS

a. Estimation of glucose by Lane and Eynon method

b. Estimation of glucose by Bertrand method

c. Estimation of glycine.

d. Estimation of formaldehyde.

e. Estimation of ethylmethyl ketone

f. Estimation of acetone

g. Estimation of ascorbic acid

ORGANIC PREPARATIONS: (ONLY FOR CLASS WORK)

About 5 (five) two stage preparations:

a. p-Nitroaniline from acetanilide

b. Anthranilic acid from phthalimide

c. m-Nitrobenzoic acid from methyl benzoate

d. Benzanilide from benzophenone.

e. Acetylsalicylic acid from salicylic acid


45

Reference books

Reference book-1:

Title of the book : Small Scale Preparations

Name of the Author : A.I. Vogel

Publisher : ELSB


Reference book -2

Title of the book : Basic principles of practical Chemistry

Name of the Author : V.Venkateswaran, R.Veerasamy, A.R Kulandaivelu

Publisher : Sultan chand & sons Publishers, New Delhi


Reference book -3

Title of the book : A Laboratory Manual of Organic Chemistry

Name of the Author : S. Murugan

Publisher : Bharathi Press


Reference book -4

Title of the book : Advanced experimental Chemistry

Name of the Author : J.N Gurtu and R.Kapoor

Publisher : S.Chand and company limited


Prepared by: Ms. K. RAJASULOCHANA

Signature :


46


SATTUR-626 203.




Semester : III No.of Hours alloted : 5 / week

Subject : Core Paper No of Credits : 5

Title of the Paper : ORGANIC CHEMISTRY - III

REACTIONS, REAGENTS AND SPECTROSCOPY

Objectives:


to understand the concept of Oxidation and reduction

to know the application of reagents in organic synthesis

to apply 1H NMR and

13C NMR technique in elucidating the structure and

identification of organic molecules.

to apply the principle of ORD and CD in elucidating the structure of organic

molecules.

to know the chemistry of vitamins.

UNIT-I OXIDATION AND REDUCTION

Elimination of hydrogen and aromatization reactions – catalytic dehydrogenation –

mechanism and application of stereochemical aspect of the following oxidation – reduction

reactions : Oxidation reaction involving CrO3, SeO2, OsO4, lead tetra acetate, periodic acid,

N- bromosuccinimide, H2O2 - Oppenauer oxidation.

Catalytic hydrogenation – reaction involving lithium aluminium hydride, tri

isobutoxy aluminium hydride - DIBAL and sodium borohydride - Birch reduction –

Meerwein-Pondorf-Verley reduction – Wolff-Kishner reduction — Hydroboration.

UNIT -II REAGENTS IN ORGANIC SYNTHESIS AND FREE RADICALS

Gilman’s reagent (lithium dimethylcuprate), lithium diisopropylamide(LDA),

Dicyclohexylcarbodiimide, 1,3-dithiane,Woodward and Prevost hydroxylation, Merrifield

resin, phase transfer catalysts, Peterson’s synthesis and Baker’s yeast.


47

Free radicals: Free radical reactions – halogenations, addition, oxidation, reduction

and rearrangement reactions – Barton, Sandmeyer, Gomberg, Bachmann, Ullmann, Pschorr

and Hundsdiecker reactions.

UNIT- III 1H NMR SPECTROSCOPY

1H NMR spectroscopy: Origin of NMR spectra – chemical shift, chemical shift

parameters – internal standards – factors affecting chemical shift, anisotropic effect, – NMR

concept of aromaticity – spin-spin coupling – coupling constant – first and second order

spectra– influence of stereochemical factors on chemical shift of protons – simplification of

complex spectra – deuterium substitution – spin decoupling and spin tickling – double

resonance – shift reagents – lanthanide shift reagents, chiral resolving reagents – Nuclear

overhauser effect – CIDNP.

UNIT -IV 13

C NMR SPECTROSCOPY

Natural abundance – H decoupling - Off-resonance decoupling – line intensities –

chemical shift equivalence - elementary study of alpha, beta and gamma effects -

hybridization of carbon - calculation of chemical shifts for aromatic and aliphatic

compounds , DEPT 13

C spectra - 13

C correlation spectroscopy - COSY, HETCOR, NOESY

and Inadequate.

Application: Application of spectral studies to characterize the organic compounds

UNIT- V CHIRO- OPTICAL TECHNIQUES AND VITAMINS

ORD and CD – principle - Cotton effect - type of ORD curves - α-haloketone rule -

octant rule - applications to determine the configuration and conformation of simple

monocyclic and bicyclic ketones-comparison of ORD and CD.

Vitamins : Introduction, classification, Structural elucidation of vitamin A, B1, B2, B6,

C, D2 and H

Text Books

Text book-1


Name of the Author : G.R.Chatwal



Text Book- 2




Edition/Year : reprint / 2000


48

Text Book- 3

Title of the book : Elementary organic spectroscopy principles and chemical

applications Name of the Author : Y.R.Sharma


Edition/Year : Reprint / 2012

Text Book- 4 Title of the book : Organic spectroscopy – principles and applications

Name of the Author : Jag Mohan,

Publisher : Narosa Publishing House,

Edition/Year : 2/ 2003.

Unit-I (From Text Book-1) Chapter-17 (Page No.17.12-17, 27-48,56-70,91)

(From Text Book-2)

Chapter-2 (Page No.96-97, 146-148, 152-154)

Chapter-3 (Page No.199-202, 210-234, 237-246).


Chapter-17 (Page No.17.23-26)

(From Text Book-2)

Chapter-2 (Page No.91-94, 167-170, 177-180)


Unit-III (From Text Book-3) Chapter-5 (Page No.182-221,230-233)

(From Text Book-4)

Chapter-4 (Page No.187-197,203-256,269-288,296-306)

Unit-IV (From Text Book-4) Chapter-4 (Page No.307-326)

Unit-V (From Text Book-4) Chapter-5 (Page No.440-445,457-460)


Reference books

Reference book1





Reference Book-2

Title of the book : Organic Spectroscopy,

Name of the Author : William Kemp,

Publisher : ELBS,

Edition/Year : 3 /2008,

Reference Book-3

Title of the book : Spectrometric Identification of Organic Compounds,

Name of the Author : Robert M.Silverstein, Francis X. Webster,

Publisher : John Wiley and Sons Inc.,



49

Reference Book-4

Title of the book : Spectroscopy of Organic Compounds,

Name of the Author : P.S.Kalsi,

Publisher : New Age International Publishers,


Reference Book-5

Title of the book : Organic Chemistry of Natural Products volume I ,

Name of the Author : Gurdeep R. Chatwal,

Publisher : Himalaya PublishingHouse.


Reference Book-6

Title of the book : Organic Chemistry of Natural Products volume II,

Name of the Author : Gurdeep R. Chatwal



Reference Book-7

Title of the book : ORD and CD in Chemistry and Biochemistry

Name of the Author : P. Crabbe

Publisher : Academic Press,



Signature :


50



SATTUR-626 203.



SYLLABUS


Semester : III No. of Hours allotted: 5 / week

Subject : Core -Paper - XII No. of Credits : 5

Title of the Paper : INORGANIC CHEMISTRY III

INORGANIC SPECTROSCOPY AND NANO CHEMISTRY

Objectives:


to have an indepth study of spectral applications to the structural elucidation of

inorganic compounds.

to have an exposure to the nano technology

to understand the concept of molecular rearrangements reaction in coordination

Complexes.

UNIT- I ELECTRONIC SPECTRA OF TRANSITION METAL COMPLEXES

Types of electronic transition- d-d transition- charge transfer transition.- L-S

coupling- Microstates –Term symbol-selection rules – mechanism of breakdown of selection

rules- bandwidths and shapes- Jahn Teller effect –Orgel diagram --Tanabo-sugano diagram

for various dn

configuration-Racah parameter- evaluation of 10Dq -Nephelauxetic ratio( β)

for Co(III)and Cr(III) complexes.

UNIT- II APPLICATION OF SPECTROSCOPY TO THE STUDY OF INORGANIC

COMPOUNDS

Mossbauer spectroscopy

Mossbauer effect- resonance absorption-Doppler effect- Doppler velocity –isomer

shift-magnetic hyperfine splitting-application of Mossbauer spectroscopy in the study of iron

and tin complexes.

NMR Spectroscopy: Multinuclear NMR- 31

P, 19

F and 15

N NMR – introduction –

application in structural problem-(ClF3, SF4, PF5, BrF5, P4S3, PF3 (NH2)2 )- evaluation of rate

constants –NMR of fluxional molecules –NMR of paramagnetic molecules- contact shifts

and shift reagents.


51

ESR Spectroscopy: Principle –presentation of the spectrum –hyperfine splitting-

evaluation of g values –factors affecting the magnitude of g- values-zero field splitting –

Kramer's degeneracy---application of ESR in the study of transition of metal complex (bis

salicylaldiamine)copper(II), Mn2+

complex.

UNIT-III NANOCHEMISTRY

Basic idea of nanoscience–dimensional in nano structures-,0D,1D,2D and 3D ,

synthesis of nano materials -chemical method, sol gel , chemical vapour deposition- ball

milling-plasma arcing- electrodeposition- thermolysis

Carbon nanotubes: Types of carbon nano tubes- structure, properties and applications of

single walled carbon nano tubes.

Nano Shells: Introduction-types- properties and applications in Ion selective film, gold

nanoshell for blood Immunoassay - cancer detection and therapy.

Nano polymers: Conductive polymer and block copolymer.

Applications of nano materials- Insulation material-machine tools-high power magnets-motor

vehicle and aircrafts.

UNIT– IV REACTION MECHANISM OF COORDINATION COMPOUNDS

Substitution reactions of octahedral complexes- factors affecting reactivity octahedral

of complexes–labile–inert complexes–mechanism of acid hydrolysis, base hydrolysis and

anation reactions. substitution reactions in square planar complexes–factors affecting

reactivity of square planar complexes – The trans effect and its applications– electron transfer

reactions–outer sphere and inner sphere electron transfer mechanisms- complementary and

non complementary reactions.

UNIT-V MOLECULAR REARRANGEMENTS AND METAL CLUSTERS

Molecular rearrangement of four coordinated complex- six coordinated

complexes- -hydrolysis of amino acid ester, - Aldol condensation-imine formation, hydrolysis

and substituent exchange – the template effect and macro cyclic ligands.

Metal clusters: Structure and bonding of dinuclear clusters [Re2Cl8]4-

, trinuclear

clusters [Fe3(CO)12] tetranuclear clusters [Fe4(CO)12], hexanuclear clusters [Os6(CO)18] 2-


52

Text books

Text Book- 1

Title of the book : Inorganic Chemistry-principles of structure and reactivity




Text Book-2

Title of the book : Concise inorganic chemistry

Name of the Author : J. D Lee

Publisher : Black well science Ltd


Text Book-3

Title of the book : .Spectroscopy

Name of the Author : B.K Sharma

Publisher : Geol Publishing House,Meerut


Text Book- 4

Title of the book : NanoTechnology

Name of the Author : Mick Wilson

Publisher : Overseas Press India Private Limited


Text Book-5

Title of the book : An Introduction to Inorganic Chemistry.

Name of the Author : K.F. Purcell and J.C Koltz ,

Publisher : W.B Saunders company,




(From Text Book-2)

Chapter 32 (Page No 938 to 970 )


Chapter 14 (Page No 737 to760)




Chapter 13 (page No 538 to 555, 558-559)

Unit V (From Text Book -5)

Chapter (Page No 757 to 762, 783 to 791)

(From Text Book-1)



53

Reference Books

Reference Book-1

Title of the book : Physical Methods in Inorganic Chemistry

Name of the Author : R.S.Drago

Publisher : W.B.Saunder company, London


Reference Book -2

Title of the book : Introduction to Nanotechnology

Name of the Author : Charles P.Poolee Jr. and Franck Owens,

Publisher : John-Wiley and Sons


Reference Book -3

Title of the book : Nano: the Essentials

Name of the Author : T.Pradeep

Publisher : Mc Graw-Hill Education,Delhi.


Reference Book-4

Title of the book : Advanced Inorganic chemistry

Name of the Author : F. A Cotton and Wilkinson

Publisher : John Wiley and sons


Reference Book-5

Title of the book : Concepts and Model of Inorganic chemistry

Name of the Author : B. Dougles,D.H. Daniel and J.J Alexander

Publisher : John Wiley & Sons




Signature :


54



SATTUR-626 203.


(For those who joining in 2018-2019 and after )

SYLLABUS



Subject : Core Paper VIII No. of Credits : 5

Title of the Paper : PHYSICAL CHEMISTRY – III

GROUP THEORY AND MOLECULAR SPECTROSCOPY-II

Objectives:

To enable the learners to

to have an idea of symmetries of molecules and their fundamental concepts.

to apply the group theory to spectroscopy and molecular problems.

to have an insight into the principles of molecular spectroscopy.

to get a clear idea about various spectroscopic technique and their applications.

to learn the concept of partition functions and theories of heat capacities of solids.

UNIT-I GROUP THEORY

Molecular symmetry elements and symmetry operations. Matrix algebra- types of

matrices, matrix representation for symmetry operations (E,Cn,Sn,i, σ) and transformatuon

matrices. Group-definition and properties of a group, subgroup, isomorphic group and

classes. Group multiplication table for C2Vand C3V point groups. Representation of a group

- reducible and irreducible representations.

Great Orthogonality theorem. Construction of a character tables- C2V, C3V, C2h and

D2d. Standard reduction formula. Direct product – definition and its applications.

UNIT-II APPLICATION OF GROUP THEORY TO SPECTROSCOPY AND

MOLECULAR PROBLEMS

Definition of molecular vibration, symmetry of normal mode analysis to water,

formaldehyde, ammonia, trans-N2F2 and ethylene molecule. Selection rules for IR and Raman

spectra. Selection rules for electronic transition in simple molecules like ethylene,

formaldehyde and benzene.


55

Group theory applied to hybridization (BCl3, PCl5, XeF4, SF6 and CH4). Simplication

for molecular orbital calculation- SALC procedure - HMO theory and delocalization energy

for cyclopropenyl cation ,butadiene and benzene systems.

UNIT-III MOLECULAR SPECTROSCOPY-II

Raman spectroscopy: Theories of Raman scattering, Rotational and vibrational

Raman spectra. Mutual exclusion principle- Laser Raman spectra. Electronic spectra of

diatomic and polyatomic molecules. Intensity of vibrational electronic spectra - Franck

Condon principle -rotational fine structure of electronic vibrational spectra. Fortrat parabola.

Dissociation and predissociation spectra.

NQR : Principles and applications –quadruple moment and electrical field, nuclear

quadruple resonance, nuclear quadruple coupling in atoms and molecules. Identification of

ionic character and hybridization.

UNIT-IV SPIN RESONANCE SPECTROSCOPY

NMR: Magnetic properties of nuclei, resonance condition, NMR instrumentation.

Chemical shift, spin-spin splitting, relaxation processes, line shape and line width. Double

resonance technique, ENDOR, Nuclear overhauser effect, FT-NMR spectroscopy and

lanthanide shift reagents.

Photo electron spectroscopy – principle, XPS of elements, chemical shift, Koopman’s

theorem, XPS of O2 molecule, valence electron photoelectron spectroscopy. UPS spectrum

of N2 and O2 molecule. Application of photoelectron spectroscopy.

UNIT- V STATISTICAL THERMODYNAMICS-II

Partition functions: Translational, rotational, vibrational and electronic partition

functions of a diatomic molecule. Relationship between partition function and

thermodynamic function: internal energy, pressure, enthalpy, entropy, heat capacity,

Helmholtz free energy, Gibbs free energy and equilibrium constant. Sackur –Tetrode

equation. Population inversion. Einstein’s and Debye’s theories of heat capacities of solids.

Text books

Text Book- 1

Title of the book : Symmetry and spectroscopy of molecules

Name of the Author : K. Veera Reeddy

Publisher : New Age International Publishers



56

Text Book- 2

Title of the book : Group Theory in Chemistry

Name of the Author : V.Ramakrishnan and M.S. Gopinathan

Publisher : Vishal Publications


Text Book- 3

Title of the book : Fundamentals of molecular spectroscopy

Name of the Author : Colin N. Banwell and Elaine M.McCash

Publisher : Tata McGraw- Hill Publishing Company Limited


Text book-4





Text Book- 5





Unit I (From Text book 1)





Unit II (From Text book 1)


(From Text book 2)


Unit III (From Text book 4)

Chapter-4(Page No. 2.83-2.99)

Unit IV (From Text book 3)

Chapter-7 (Page No. 199-219)

(From Text book-4)

Chapter-7 (page No. 416-420)

(From Text book 4)



Unit V (From text book 5)

Chapter -3 (Page No.262-271)

Chapter -4 (Page No. 304-311)


57

Reference Books

Reference Book-1

Title of the book : Group Theory and its applications to chemistry

Name of the Author : K.V.Raman

Publisher : Tata McGraw- Hill Publishing company limited


Reference Book-2

Title of the book : Chemical applications of Group Theory

Name of the Author : F.A. Cotton

Publisher : John Wiley & Sons,New york


Reference Book-3

Title of the book : A Simple approach to group theory in chemistry

Name of the Author : S. Swarnalakshmi,T. Saroja,R.M.Ezhilarasi

Publisher : Universities Press Private Ltd


Reference Book-4

Title of the book : Molecular structure and spectroscopy

Name of the Author : G.Aruldhas

Publisher : PHI Learning (P) Limited, New Delhi


Prepared by : Ms. M. SELVAMARIAMMAL

Signature


58


SATTUR-626 203.



SYLLABUS



Subject : Paper XIV - Major Elective III (a) No. of Credits : 4

Title of the Paper : COMPUTER APPLICATIONS

Objectives:

To enable the learners to

to study the basic concepts of VB and its application in chemistry.

to know about basic concepts of internet.

UNIT-1 BASIC CONCEPT OF VB

Introduction to visual basic-the integrated development environment-the menu bar,tool

bar,the project explorer,the tool box,the properties of window,the form designer,the form lay

out,the immediate window,the elements of the interface-programming an application

common properties,common methods and common events-customising the environment.

Working with Forms: The appearance of form – the start up form – loading,

showing and hiding forms – elementary concepts of drag and drop operations.

Variables – declaring variables – variable types – strings, numeric and data

variables- scope and life forms of variables – constants.

UNIT- II THE LANGUAGE FORMS AND BASIC ACTIVE CONTROLS

Control flow statements: If… Then and If… Then…Else. Loop statements : DO…

Loop,For…Next and While – Wend – nested control statement – the Exit statement.

Arrays: Declaring arrays – specifying arrays – multi dimensional arrays.

Procedures: Subroutines, functions, calling procedures – arrangements – arguments passing

mechanism – using optional arguments – functions returning arrays.


59

UNIT-III APPLICATIONS OF VB IN CHEMISTRY

Writing Simple programs in Chemistry:

1. Calculation of molecular weight of organic compound,

2. Ionic strength of an electrolyte,

3. Different velocities of a gas,

4. NMR frequency values of nuclei,

5. Average rate constant,

6. Unit cell dimensions,

7. Thermodynamic parameters,

8. Reduced mass,

9. Empirical formula of an organic compound containing C,H and O,

10. Normality, molality and molarity of a solution,

11. Half life period of a radioactive material,

12. Surface tension and

13. Temperature in Kelvin scale into Celsius and vice-versa.

Practical : (Class work only)

Construcion of programs in VB language, compiling, debugging and making

executive files, printing the output.

Running Simple VB programs in Chemistry to calculate/ determine the above

problems.

UNIT- IV BASIC CONCEPTS OF COMMUNICATION SYSTEMS

Communication systems: Satellites – RADAR – optical fibers – advantages and

disadvantages – ISDN – distributed systems – advantages and disadvantages.

Telecommunications: analog and digital signals – types and needs of modulations –

MODEMS – Telecommunication software.

Computer networks: An overview – communication processors – protocols – network

architecture.

Practicals (Class work only)

1. Salient features of Windows and MS Word for typing texts and equations in

Chemistry – tabular columns – advanced concepts.

2. Basic concept of creating and accessing databases using MS Access.

3. Significance of Chemdraw – drawing chemical structures and pasting them in the

text.


60

UNIT- V BASIC CONCEPTS OF INTERNET AND APPLICATIONS IN

CHEMISTRY

Internet: History of internet – the working way of internet – getting connected to

internet, internet protocols – internet addressing –domain names- internet services. Internet:

characterization – advantages – drawbacks – need for internet – extranet.

www: Web Pages–homepages –web browsers –search engines –internet chat –

chatting on web.

E-mail : Introduction – working way – mailing basics – e-mail ethics – advantages

and disadvantages – creating e-mail – receiving and sending e-mails.

.Applications of internet in Chemistry: Websites in Literature survey in chemistry –

popular websites in chemistry – data bases in chemistry - URLS – WAIS – downloading the

attachment / PDF files – opening ,browsing and searching a website literature searching

online.

Practicals (Class work only)

Creating e-mail id, sending and receiving e- mail, attachment files, PDF files.Opening,

browsing and searching a website – down loading– literature survey in chemistry – online

searching.

Unit I to V Study material will be provided

Reference Book-1

Title of the book : Mastering Visual Basic 6

Name of the Author : Evangelos Petroutsos

Publisher : BPB Publication


Reference Book-2

Title of the book : Visual Basic 6 Super Bible

Name of the Author : David Jung, Pierre Boutqukin, John D. Conley III, Loren Eidahl

Publisher : First Indian Edition, Techmedia, New Delhi, 1999.


Reference Book-3

Title of the book : Visual Basic 6.

Name of the Author : Gary Cornell,

Publisher : Tata-McGraw Hill, New Delhi



Signature :


61


SATTUR- 626 203.



SYLLABUS


Semester : III No. of Hours allotted : 5 / week

Subject : Paper XIV Major Elective – III (b) No. of Credits : 4

Title of the Paper : PHARMACEUTICAL CHEMISTRY

Objectives:


to know the fundamentals of medicinal chemistry.

to learn uses of antibiotics and steroids.

to understand the concept of chemotherapy and its agents.

UNIT-I FUNDAMENTALS OF MEDICINAL CHEMISTRY

Definitions of Medicinal Chemistry, Pharmacology and molecular pharmacology,

pharmacodynamics, pharmacophore, pharmacodynamics agents - Structure Activity

Relationship (QSAR) – Hansch approach – account of physiological effects by hydroxyl,

aldehyde, ketone, acidic, nitro, nitrite, nitrile groups and unsaturation - drug receptors ,

mechanism of drug action on enzymes, gene function, biological membranes.

UNIT-II MEDICINALLY USEFUL ANTIBIOTICS AND ANTIMALARIALS

Classification of antibiotics - Structural features and SAR of the following

antibiotics - penicillin G, cephalosphorin and their semisynthetic analogs (β-lactam),

streptomycin (amino glycoside), terramycin (tetracycline), erythromycin(macrolide) ,

chloramphenicol and Rifamycin.

UNIT-III CHEMOTHERAPEUTIC AGENTS

Antineoplasticagents: Classification and synthesis of Cyclophosphamide,

Clorambucil, Busulfan, Decarbazine, Methotrexate, 6-Mercaptopurine, 5-fluorouracil and

cisplatin, Antitubercular drugs: Classification and Synthesis of Isoniazid, Rifampicin,

Pyrazinamine, Ethambutol and Ethionamide.Anti malarial drugs: Classification and synthesis

of Chloroquin, Primaquine, Amaodiaquine. Diuretics: Classification and Synthesis of

Fursemide, Acetazolamide, Chlorothiazide.


62

UNIT-IV SYNTHESIS AND THERAPEUTIC ACTION OF CERTAIN DRUGS

Antihypertensive drugs: Nifedipine, Captopril, Sodiumnitroprusside, clonidine,

methyldopa and guanothidine. Antihistamines: H1-Antagonists: Pheniramine, Mepyramine,

Promethazine, H2- Antagonists: Cimetidine, Ranitidine and fomotidine.

UNIT- V SYNTHESIS AND THERAPEUTIC ACTION OF DRUGS

Anti-inflammatory drugs: Antipyratics & Non-narcotic analgesics: Aspirin, sodium

salicylate, paracetamol, phenylbutazone, oxyphenylbutazone, ibuprofen, Mephenamicacid,

Diclofenac sodium (preparation,structure and therapeutic uses only).CNS Stimulant drugs:

Amphetamine, Caffeine, Theobromine, Theophylline (structure and therapeutic uses only).

CNS Depressent drugs: Phenelazine, Imipramine, Amitriptyline, Desipramine (structure and

therapeutic uses only).

Text books

Text Book- 1

Title of the book : Pharmaceutical chemistry-organic


Publisher : Himalaya Publishing House


Text Book- 2

Title of the book : A Textbook of Pharmaceutical Chemistry

Name of the Author : Jayashree Ghosh

Publisher : S.Chand& Company Ltd


Text Book- 3

Title of the book : Medicinal chemistry




Text Book- 4

Title of the book : Text book of Pharmaceutical Organic chemistry

Name of the Author : Mohammad Ali

Publisher : CBS Publishers & distributors




Chapter – 3 (Page No. 41-45, 50-56, 62,63)



63



Unit-III (From Text Book- 3)

Chapter – 31 (Page No 316-333, 283 to291, 264 to271)

Chapter – 25 (Page No 250 to 257)

Unit-IV (From Text Book- 3)

Chapter – 19 (Page No 214 to224)



(From Text Book-4)


Reference Books

Reference Book-1

Title of the book : Medicinal Chemistry

Name of the Author : Sriram.D,Yogeeswari

Publisher : PESL


Reference Book-2

Title of the book : Medicinal Chemistry

Name of the Author : Kar.Ashutosh

Publisher : New age International Publishing House


Reference Book-3

Title of the book : Introductory Medicinal Chemistry..

Name of the Author : J.B Taylor and P.D Kennewell

Publisher : Ellisworth publishers



Signature :


64



SATTUR-626 203.


(For those who joining in 2018--2019 and after)

SYLLABUS


Semester : III No. of Hours allotted : 10 / week

Subject : Paper XV PRACTICAL III No. of Credits : 4

Title of the Paper: PHYSICAL CHEMISTRY PRACTICAL

Objectives:


To know about the practical applications of conductometry.

To appreciate the application of potentiometric technique in the quantitative analysis.

To understand the concepts of adsorption and Chemical kinetics by carrying out

experiments.

I. CONDUCTOMETRIC EXPERIMENTS

i. Double displacement & acid base titrations

a) NH4Cl-NaOH-Mixture of CH3COOH &HCl.

b) NH4Cl- NaOH- Mixture of NH4Cl &HCl.

ii. Precipitation titration

a) Na2CO3-Pb (NO3)2 – Na2CO3

b) K2SO4 – BaCl2 – K2SO4.

iii. Determination of dissociation constant of weak acids.

II ADSORPTION EXPERIMENTS

i. Adsorption of oxalic acid/ Acetic acid on charcoal.

III KINETIC EXPERIMENTS

i. Perdisulphate and iodide ion reaction: Study of primary salt effect and

determination of concentration of given KNO3.

ii. Kinetics of alkaline hydrolysis of ester by conductometric method.


65

IV POTENTIOMETRIC EXPERIMENTS

i. Precipitation titration : Ag vs. halide mixture

ii. Redox titrations : a) permanganate vs iodide ion

b) ceric ammonium sulphate vs. ferrous ion

iii. Determination of dissociation constant of weak acids and pH of

Buffer solutions

iv Determination of solubility product of sparingly soluble salts.

V Titrations using pH meter

Determination of first, second and third dissociation constants of phosphoric acid.

References:

Reference Book-1

Title of the book : Advanced Practical Physical Chemistry

Name of the Author : J.B. Yadav

Publisher : Goel Publications, Meerut


Reference Book-2

Title of the book : Practical physical Chemistry

Name of the Author : B.Viswanathan

Publisher : Vivas Book private limited



Signature :


66


SATTUR-626 203.



Programme : M.Sc . Chemistry Subject Code : P18CHC41

Semester : IV No.of Hours alloted : 5 / week

Subject : Paper XVI -Core Paper No of Credits : 5

Title of the Paper: ORGANIC CHEMISTRY -IV

MOLECULAR REARRANGEMENTS AND SYNTHETIC METHODS

Objectives:


to know about the various types of molecular rearrangements.

to understanding the fundamental concept of photochemistry and pericyclic reactions

to know about alkaloids and steroids.

to get insight into the principle of green chemistry.

to know the synthetic utility of reagents.

UNIT-I MOLECULAR REARRANGEMENTS

Mechanism of the following rearrangement reactions: Wagner – Meerwein, Pinacol-

pinacolone, Demjanov, Beckmann, Hofmann, Curtius, Wolff, Baeyer-Villeger, Stevens,

Sommelet-Hauser, Favorskii, Benzil-benzilic acid, Claisen, Cope, Fries, Dienone-phenol and

Benzidine rearrangement – photo Fries rearrangements.

UNIT-II PHOTOCHEMISTRY AND PERICYCLIC REACTIONS

Basic principles of photochemistry - Jablonskii diagram – Norrish type-I and

Norrish type-II reactions – Paternò–Büchi reaction – photochemistry of olefins and dienes ,

cis, trans isomerisation - photosensitization - photoreduction .

Pericyclic reactions: Types of pericyclic reactions-– electrocyclic reactions – cyclo addition

reactions and sigmatropic rearrangements –applications of conservation of orbital symmetry-

correlation diagram approach (butadiene and hexatriene), Frontier molecular approach,

Huckel-Mobius approach to the above reactions.


67

UNIT- III STEROIDS,HARMONES AND ALKALOIDS

Steroids and Harmones: Classification – structural elucidation of cholesterol,– male

sex harmones – androsterone and testosterone – female sex harmones – oestrone, equilenin

and progesterone

Alkaloids: General methods of structural determination – Hofmann, Emde and Von

Braun degradations. Structural elucidation of quinine, reserpine, morphine (synthesis not

required) and lysergic acid

UNIT- IV GREEN CHEMISTRY

Twelve basic principles of green chemistry, green starting materials, green catalyst

(zeolites as solid acid catalyst)and reagents (molecular oxygen ,tetrabutylammonium

tribromide), green solvents – applications of supercritical fluids, ionic liquids and water –

solvent free techniques.

Non-conventional microwave heating - interaction of microwave radiation with the

material-difference between conventional heating and microwave heating. Dielectric

polarization-dipolar polarization-applications and advantages of microwave heating over

conventional heating.

UNIT-V SYNTHETIC METHODS

Planning a synthesis- molecular history- starting materials-Relay approach and

convergent approach to total synthesis- Retro synthetic analysis of simple organic compounds

- functional group inter conversions -use of activating and blocking groups in synthesis -

stereo selective problems of geometrical and optical isomerism- steric crowding–

Regioselectivity – Diastereoselectivity – Enantioselectivity - Umpolung synthesis - Robinson

annelation – A schematic analysis of the total synthesis of the following compounds:, trans-

9-methyl -1-decalone and 2,4-dimethyl-2-hydroxy pentanoic acid, Isonootkatone.

Text books

Text book-1





Text Book- 2






68

Text Book- 3

Title of the book : Photochemistry and Pericyclic Reactions

Name of the Author : Jagdamba Singh and Jayasingh

Publisher : New age international (p) limited, New Delhi.


Text Book- 4

Title of the book : New trends in Green chemistry

Name of the Author : V.K Ahluwalia and Kidwai ,

Publisher : Anamaya publishing house, New Delhi.


Text Book- 5

Title of the book : Organic Synthesis,.

Name of the Author : R.E. Ireland,

Publisher : prentice-Hall of India Pvt. Ltd ,

Edition/Year : 2 reprint /1998

Text book-6

Title of the book : Organic chemistry of natural products Vol-I&vol-II

Name of the Author : G.R.Chatwal,

Publisher : Himalaya publishing House New Delhi,

Edition/Year : 4 & 5 /2007, 2009


Chapter 6 (Page No.398-413, 415-424, 434-440,454-460)

(From Text Book-2)

Chapter 2 (Page No.89-94, 107-109,121-133, 172-174, 180-187)


Chapter 6 (Page No.160-183)

Chapter 7 (Page No.184-212, 218-223)








Chapter 4 (Page No.4.1-4.25,4.59-4.68,4.76-4.82,4.90-4.92,4.95-4.96)

Chapter 3 (Page No.3.6-3.19, 3.66-76, 3.109-117, 3.123-137, )

Unit-IV (From Text Book-4) Chapter 1&2 (Page No.1-4)



Chapter 7(Page No.27-28)



Unit-V (From Text Book-5) Chapter 2(Page No.17-52)

Chapter 3 (Page No.55-56,81-87)


69

Reference Books

Reference Book-1

Title of the book : Organic Chemistry,Vol II ,

Name of the Author : I.L.Finar

Publisher : ELBS Longmann


Reference Book-2

Title of the book : Advanced Organic Chemistry,.

Name of the Author : Jerry March



Reference Book-3

Title of the book : Green chemistry (Environmental Benign Reactions)

Name of the Autho : V.K Ahluwalia ,

Publisher : Aru Books India. New Delhi.


Reference Book-4

Title of the book : Green Chemistry (Environmental Friendly Alternatives)

Name of the Author : R.Sanghi and M.M. Srivastava,

Publisher : Narosa publishing House, New Delhi.


Reference Book-5

Title of the book : Reaction Mechanism in Organic Chemistry,

Name of the Author : S.M .Mukherji and Singh

Publisher : Macmillan India Ltd


Reference Book-6

Title of the book : Pericyclic Reactions,

Name of the Author : Sankarraman ,

Publisher : Wiley VCH.


Reference Book-8

Title of the book : Organic Chemistry of Natural Products volume II,

Name of the Author : Gurdeep R. Chatwal



Reference Book-9

Title of the book : The Chemistry of Steroids,

Name of the Author : W.Klyne

Publisher : Reinhold



Signature :


70


SATTUR-626 203.



SYLLABUS


Semester : IV No. of hours allotted: 5 / week

Subject : Core Paper XVII No. of Credits : 5

Title of the Paper : INORGANIC CHEMISTRY -IV

NUCLEAR AND ORGANOMETALLIC CHEMISTRY

Objectives:


To have a complete study of f-block elements.

To have an idea about various analytical techniques.

To learn principles and applications in nuclear chemistry.

UNIT- I STRUCTURE OF NUCLEUS AND RADIOACTIVE DECAY

Composition of the nucleus –nuclear Size, shape and density-principle, radial

and magnetic quantum numbers n/p ratio- stability of nucleus packing fraction--mass defect

and binding energy.Radioactive decay: Group displacement law – decay series – rate of

disintegration -half life period -average life period – secular and transient equilibria -

theories of alpha decay, beta decay, gamma emission, internal conversion and electron

capture - Auger effect.

UNIT- II NUCLEAR FISSION AND FUSION AND APPLICATION RADIOACTIVE

ISOTOPES

Bethe's notation of nuclear process - nuclear reaction energies (Q-values) – fission

-energy release in nuclear fission-mass distribution of fission products-theory of nuclear

fission -fissile and fertile isotopes – energy from nuclear fusion-thermonuclear reaction in

stars - nuclear reactor--breeder reactor- waste disposal management.Applications of

radioactive isotopes: - chemical investigations-age determination-medical field-agriculture

and analytical techniques.


71

UNIT-III CHEMISTRY OF LANTHANIDES AND ACTINIDES

Position of lanthanides and actinides in periodic table – occurrence, extraction of

lanthanides from monazite sand -ion exchange and solvent extraction method. -Electronic

configuration-properties of lanthanides-oxidation state-lanthanide contraction and its

consequences-color of lanthanides ions- magnetic properties of lanthanides. Actinides:

separation of actinide elements-separation of Pu from fission products-electronic

configuration- oxidation state-comparison of lanthanides and actinides.

UNIT- IV ANALYTICAL METHODS

Electro analytical Techniques: Electrogravimetry, Theory of electro gravimetric

analysis - electrolytic separation and determination of metal ions. Coulometry - Coulometric

titrations. Voltametry: Cyclic voltammetry.Amperometry: Amperometric titrations. Thermo

analytical Methods: Principle and applications of TGA and DTA. Spectro analytical

Methods: principle and applications of – Fluorimetry , Nepheometry , Turbidimetry - Flame

photometry and Atomic absorptions spectroscopy .

UNIT – V COMPLEXES OF П- ACCEPTOR LIGANDS

Synthesis, structure and bonding in metal carbonyls and nitrosyls – Applications of

IR spectroscopy in metal carbonyls - EAN rule.Isolobal relationship. Synthesis, properties,

structure and bonding in ferrocene- olefin and acetylene complexes.

Catalysis using organometallic compounds: Oxidative addition – reductive elimination –

insertion reaction Catalytic mechanism in the following Reactions: hydrogenation of olefins

(Wilkinson catalyst) - hydroformylation (Oxoprocess) – acetic acid from methanol –

oxidation of alkenes to aldehydes and Ketones (Wacker process) – olefin polymerization

(Ziegler – Natta) – Cyclo oligomerisation of acetylenes (Reppe’s or Wilke’s catalysts).

Text books

Text Book- 1

Title of the book : Essential of Nuclear Chemistry

Name of the Author : H.I .Arnikar

Publisher : Wiley Eastern Ltd.,New Delhi



72

Text Book- 2

Title of the book : Nuclear Chemistry

Name of the Author : U.N.Dash

Publisher : Sultan Chand and Sons, New Delhi


Text Book- 3

Title of the book : Selected Topics in Inorganic Chemistry

Name of the Author : Wahid U.Malik et al

Publisher : S.Chand and Company Ltd.


Text Book- 4

Title of the book : Instrumental Methods of chemical Analysis

Name of the Author : Gurdeep R.Chatwal



Text Book- 5

Title of the book : Advanced Inorganic Chemistry Vol II

Name of the Author : Satya Prakash

Publisher : S.Chand & Company LTD


Text Book- 6





Unit I (From Text book-2)

Chapter - 1 (section 1.5 to 1.6.4, 1.8.1, 1.8.2)

Chapter - 3 (section 3.2 to3.3, 3.6.1, 3.6.2,)

Chapter - 5 (Page no 195 to 201, 214 to 227)

Unit II (From Text book -1)

Chapter 5(section 5.1 to 5.2.6, 5.7 to 5.7.3, 5.9, 5.10)

Chapter 6 (section6.2, 6.3 6.9)

Chapter 7 (section 7.8.1, 7.11)

Chapter 10 (section 10.7.1.10.7.3 to 10.7.6)


Chapter 9 and 10 (274 to 331)


Chapter 26 to29 (Page No 2.523 to 2.549)

Chapter 41 (Page No 2.701, 2.719 to 2.738)

Chapter 13 to 16 (Page No 2.340 to 2.415)


73



(From Text Book-6)

Chapter 15(Page No 630-639,647-653,662-665,669-673, 706-712, 714-715,718)

Reference Books

Reference Book-1

Title of the book : Source Book on Atomic Energy

Name of the Author : S.Glasstone,

Publisher : Van Nostrand Reinhold Company, New York


Reference Book-2

Title of the book : Fundamentals of Analytical Chemistry,

Name of the Author : D.A .Skoog and D.M. Weat

Publisher : Saunders college Puplishing co Philadelphia


Reference Book-2

Title of the book : Instrumental Methods of Analysis

Name of the Author : H.H..Willard, LL.Merritt and J.A.Dean,

Publisher : East- West press., New Delhi


Reference Book-4

Title of the book : Concepts and Model of Inorganic chemistry

Name of the Author : B.E Dougles,D.H. Daniel and J.J Alexander



Reference Book-5

Title of the book : Organometallic Chemistry

Name of the Author : R.C Mehrotra& Animgh singh



Reference Book-5 Title of the book : Advanced Inorganic chemistry

Name of the Author : F. A cotton & G. Wilkinson



Reference Book-5 Title of the book : Analytical Chemistry

Name of the Author : U.N.Dash

Publisher : Sultan Chand and Sons, New Delhi




Signature :


74


SATTUR-626 203.



SYLLABUS


Semester : IV No. of Hours allotted: 5 /week

Subject : Core Paper XVIII No. of Credits : 5

Title of the Paper : PHYSICAL CHEMISTRY -IV

CHEMICAL KINETICS, SURFACE, BIOPHYSICAL AND

PHOTOCHEMISTRY

Objectives:


to get themselves exposed to kinetics and mechanisms of chemical reactions.

to derive advance knowledge on solids and surface phenomena.

to learn concepts of non-equilibrium thermodynamics and bio-energetics.

to understand the fundamental concepts of photochemistry and radiation chemistry

UNIT - I CHEMICAL KINETICS I

Chain reactions and its general characteristics. Study of kinetics of chain reactions

like H2-Br2 reaction, decomposition of acetaldehyde and N2O5. Study of H2-O2 explosive

reactions.Unimolecular reaction rate theories – the simple Lindemann treatment,

Hishelwood’s theory, Rice, Ramsperger and Kassel(RRK) theory, Marcus theory or Rice,

Ramsperger, Kassel and Marcus (RRKM) theory and Slater’s theory. Principle of

microscopic reversibility and detailed balancing, Kinetic isotope effect. Reactions in solution

– influence of solvent dielectric constant, ionic strength (Bronsted- Bjerrum equation –

primary and secondary salt effects).

UNIT- II CHEMICAL KINETICS II

Fast reactions techniques – chemical relaxation methods, temperature and pressure

jump methods, ultrasonic absorption technique, reactions in flow system, continuous and

stopped flow, shock wave tube methods; chemical kinetics in crossed molecular beams and

Flash photolysis.


75

UNIT - III SURFACE CHEMISTRY

Introduction- adsorption of gases on solids- physisorption and chemisorptions –

adsorption isotherms- Freundlich-Langmuir, BET and Temkin adsorption isotherms – surface

tension-Gibbs adsorption isotherm-surface area determination–monolayer-preparation of LB

films – micelles - critical micellar concentration (CMC)-structure- reverse micelles-micro

emulsion.

UNIT - IV BIOPHYSICAL AND SUPRAMOLECULAR CHEMISTRY

Basic concept of non-equilibrium thermodynamics- Phenomenological Laws-

Onsager reciprocal relations – transformation properties of fluxes and forces.Its application to

biological systems.- entropy production due to heat flow- High energy metabolites – ATP

and its role in bioenergetics, -coupled reaction. Biophysical applications of Mossbauer Effect,

NMR imaging.– Enzyme models- molecular asymmetry- Molecular recognition. .

UNIT - V PHOTO CHEMISTRY AND RADIATION CHEMISTRY

Physical properties of the electronically excited molecules – excited state dipole

moments, pKa and redox potentials –photo physical processes in electronically excited

molecules – Fluorescence, phosphorescence and other deactivating processes. Stern - Volmer

equation and its applications – electronic energy transfer mechanisms – photosensitization

and chemiluminescence, Experimental techniques in photochemistry – light sources –

chemical actinometry – elementary aspects of photosynthesis, photochemical conversion and

storage of solar energy. Radiation chemistry : source of high energy – interaction of high

energy radiation with matter – radiolysis of water. Experimental techniques of radiation

chemistry- Dosimeter .

Text Book- 1

Title of the book : Chemical Kinetics

Name of the Author : K.J.Laidler

Publisher : Pearson Education Private Ltd, Delhi


Text Book- 2

Title of the book : Fast Reactions

Name of the Author : J.N.Bradley

Publisher : Clarendon Press Oxford



76

Text Book- 3





Text Book- 4

Title of the book : Fundamentals of Biochemistry

Name of the Author : J.N.Jain

Publisher : S.Chand & Company Ltd, New Delhi

Edition/year : 6 / 2005

Text Book- 5

Title of the book : Fundamentals of Photochemisty

Name of the Author : K.K. Rohatgi Mukherjee

Publisher : New Age International (P) Limited


Text Book- 6

Title of the book : Essential of Nuclear chemistry

Name of the Author : H.J.Arnikar

Publisher : New Age International Publishers







Unit-II (From Text book-2)






Unit-III (From Text book-3)

Chapter-16(Page No. 873-880, 882-894. 905-909)

Chapter-17(Page No. 952-954, 1017-1021, 1028-1030)

Unit-IV (From Text book-4)


Unit- V (From text book -5)

Chapter - 4 (Section 4.7 to 4.9)

Chapter - 5 (section 5.1)

Chapter - 9 (section 9.5)

Chapter -10 (section 10.1)

(From text book -6)

Chapter -11 (section 11.1 to 11.7.5)


77

Reference Book-1





Reference Book-2





Reference Book-3

Title of the book : Physical chemistry on Surfaces

Name of the Author : A.W.Adamson

Publisher : John Wiley &Sons, New York


Reference Book-4

Title of the book : Principles of Biochemistry

Name of the Author : A.L.Lehninger

Publisher : CBS Publication,New Delhi

Edition/year : 1 /1984

Reference Book-5





Reference Book-6

Title of the book : Bioorganic,bioinorganicand supramolecular chemistry

Name of the Author : P.S. Kalsi & J.P.Kalsi


Edition/Year : 2 /Reprinted 2011.


Signature :


78



SATTUR- 626 203.



SYLLABUS


Semester : IV No. of Hours allotted: 5 / week

Subject : paper XIX Major Elective IV (a) No. of Credits : 4

Title of the Paper : INTRODUCTION TO NANOSCIENCE

Objectives:

to understand the basic concept of nano science.

to study the synthesis and applications of nano chemistry.

to know about the characterization of nano materials.

UNIT- I GENERAL INTRODUCTION

Forms of Matter –Crystal structures –electronic properties of atoms and solids –

surface energy and surface tension – defining nanodimensional materials – 0D, 1D and 2D

nanostructures – size dependence of properties – special properties resulting from

nanodimensionality – potential use of nanomaterials.

UNIT- II SYNTHESIS OF NANOMATERIALS

General approaches – nucleation process – sizes of the crystal – influence of

nucleation rate on the size of the crystal – chemical methods – Sol-gel techniques – control of

grain size – Coprecipitation - hydrolysis – sonochemical method – colloidal precipitation –

bottom up and top down approaches – kinetically confined synthesis of nanoparticles.

UNIT- III PRINCIPLE AND INSTRUMENTATION

Spectrophotometry,XRD, EXAFS, XPS, SEM, TEM, AFM –application to

nanomaterials characterization.

UNIT- IV OPTICAL PROPERTIES OF NANOMATERIALS

UV-Vis, IR absorption – photoluminescence and stimulated emission – nonlinear

optical mixing – photo conductivity Magnetic properties: concepts of dia-, para-, and ferro-

magnetism – exchange correlation – exchange interaction. Electrical properties: electrical

conductivity – Hall effect – charge carrier density – activation energy; electronic properties –

field emission properties.


79

UNIT- V BIOLOGICAL NANOMATERIALS

Sizes of building blocks – proteins – DNA double nanowire – enzymes – protein

synthesis – Micelles and vesicles – Biomimetic nanostructures – Worm micelles and Vesicles

from block copolymers.

Text books

Text Book- 1

Title of the book : Introduction to Nanotechnology

Name of the Author : C.P. Poole

Publisher : John Wiley & Sons, INC.


Text Book- 2

Title of the book : Nano: the Essentials

Name of the Author : T. Pradeep

Publisher : Mc Grow-Hill Education, Delhi.


Text Book- 3

Title of the book : Nanotechnology

Name of the Author : Mick Wilson

Publisher : Overseas India pvt Ltd






Unit-III (From Text Book-2) Chapter – 2 (Page No. 15-75)

Unit-IV&V (From Text Book-1)



Reference Book-1

Title of the book : The Chemistry of Nano Materials

Name of the Author : C.N.R.Rao

Publisher : Wiley-VCH –Verlag Gmoh and co

Edition/Year : volumes 1 and 2 /1980

Reference Book-2 Title of the book : NanoTechnology

Name of the Author : S.Shanmugam

Publisher : NJP Publisher



Signature :


80



SATTUR- 626 203.



SYLLABUS

Programme : M.Sc., Chemistry Subject Code : P18CHE42


Subject : paper XIX Major Elective IV (b) No. of Credits : 4

Title of the Paper : POLYMER CHEMISTRY

Objectives:


To understand the chemistry of polymerization.

To study about the utility of polymers in various field.

To know about the processing of polymers.

UNIT- I CLASSIFICATION OF POLYMERS AND CHEMISTRY OF

POLYMERISATION

Classification of polymers: linear polymers, non-linear or branched polymers,

cross - linked polymers, homo chain hetero chain, homopolymers co-polymers block

polymers and graft polymers. Chemistry of polymerisation: Types of polymerization –

mechanism of chain growth, free radical, ionic, co-ordination, ring opening, metathetical and

group transfer polymerization, polyaddition and polycondensation polymerisations.

UNIT- II INDIVIDUAL POLYMERS

Individual polymers: Monomers required general methods of preparation,

repeating units and uses of the following polymers and resins- polyethylene, polystyrene,

polyacryloniltrile-polymethylmethacrylate-polyvinylchloride-polytetrafluoroethylene

polybutadienes-polychloroprene-polyesters-polycarbonates-polyimides-polyamides (Kevlar)-

polyurethanes- polyethylene glycols, Resins: phenol - formaldehyde, urea- formaldehyde,

melamine – formaldehyde and epoxy resins.

UNIT- III PROPERTIES OF POLYMERS

Intrinsic properties – processing properties – basic idea of isomerism of polymers –

configuration of polymer chain – geometrical structure - syndiotatic, isotatic and atatic

polymers.Glass transition temperature: Definition –factors affecting glass transition


81

temperature – relationships between glass transition temperature and (a) molecular weight,

(b) meltingpoint and (c) plasticizer – importance of glass transition temperature – heat

distortion temperature.Molecular weight and size of polymers: Number average, weight

average, sedimentation and viscosity average molecular weights – molecular weights and

degree of polymerisation– poly dispersity – molecular weight distribution in polymers – size

of polymer molecules – kinetics of polymerization.

UNIT- IV POLYMERISATION TECHNIQUES, DEGRADATION AND USES OF

POLYMERS

Polymerisation Techniques: Bulk, solution, suspension, emulsion, melt

condensation and interfacial polycondensation polymerizations. Degradation: Types of

degradation – thermal, mechanical, ultrasonic and photodegradation – photo stabilizers –

oxidative degradation – antioxidants – hydrolytic degradation. Uses of polymers in

electronics and biomedicine.

UNIT -V POLYMER PROCESSING

Polymer processing: plastics (thermo and thermosetting), elastomers, fibres,

compounding, plasticizers, colorants, flame retardants. Compression and injection mouldings

– film extrusion and calendaring – die casting and rotational casting- thermo forming –

reinforcing.

Text Book- 1

Title of the book : Polymer Science

Name of the Author : V.R.Gowarikar, N.V.Viswanathan and Jayadev Sreedher,

Publisher : Wiley Eastern Ltd., New Delhi


Text Book- 2

Title of the book : Principles of Polymer science

Name of the Author : N.V.Sastry

Publisher : Narosa Publishing House


Text Book- 3

Title of the book : Polymer chemistry

Name of the Author : Alka.l.Gupta

Publisher : Pragati Prakashan educational Publishers.



82

Unit-I (From Text Book - 1) Chapter – 1 (Page No 12-14)

Chapter – 2 (Page No 15-71)


Chapter – 9 (Page No 215-257)

Unit-III (From Text Book-1&2)

Chapter – 3 (Page no 86 to 97)

Chapter – 6 (Page No150 to172)

Unit-IV (From Text Book-1& 3)

Chapter – 1 (Page no 61 to 67)

Chapter – 10 (Page no 263 to289)

Unit-V (From Text Book -2)

Chapter 4– (Page No.140 to 161)

Chapter 6– (Page No.238)

Reference Books

Reference Book-1

Title of the book : Text book of polymer science

Name of the Author : F.W.Billmeyer

Publisher : JohnWiley and sons,New York


Reference Book-2

Title of the book : Text book of polymer chemistry

Name of the Author : B.K.Sharma

Publisher : Goel pub,House, Meerut.


Reference Book-3

Title of the book : Text book of introductory polymer chemistry

Name of the Author : G.S.Mistra

Publisher : New Age International pub, New Delhi



Signature :


83



SATTUR-626 203.



SYLLABUS

Programme : M.Sc .,Chemistry Subject Code : P18CHPT41


Subject : Paper XX No. of Credits : 4

Title of the Paper : PROJECT WORK AND VIVA-VOCE

Objectives:


To develop the ability of the students to prepare a project.

To get clear idea about the new concepts in our field apart from the syllabus.

REGULATIONS FOR THE PROJECT REPORT

Evaluation method for project:

Max. Marks Credits

Internal External

Project Evaluation 40 40

Viva Voce 20

Total 100 4

1. 50% of the aggregate (Project Evaluation + Viva Voce+ Internal)

2. No separate pass minimum for internal.

3. 27 marks out of 60 is the pass minimum for the External.

Internal examiners are the respective supervisors.

Viva voce examination to be evaluated by the external examiner.

The report of the project must be in the prescribed form. It should be typed neatly in

MS word. The font size of the letter should be 13 points with double space.


84

The format of the project should have the following components.

First page should contain:

Title of the project report.

Name of the candidate

Register number.

Name of the supervisor.

Address of the institution

Month and year of submission.

1. Contents.

2. Declaration by candidate

3. Certificate by supervisor

4. Acknowledgement

5. Preface

6. Chapter 1 – Preliminaries.

7. Other chapters

8. References

The number of pages in the project may be 40 to 50

Each page should contain at least 18 lines.

Two copies of the project report should be submitted.


Signature :


85



SATTUR-626 203.



SYLLABUS

Programme : M.Sc .,Chemistry Subject Code : P18CHX41

Semester : IV No. of Credits : 3

Subject : Paper XX

Title of the Paper : MODEL PAPER FOR NET/SET EXAMINATION- CHEMICAL

SCIENCES

Objectives:


to create an awareness of the NET/SET Examination

to make the students prepared for NET / SET Examinations

UNIT-I

i) Periodic properties – Atomic radius – ionic radius, ionization potential, electron

affinity and electronegativity – Their significance in chemical bonding.

ii) VB theory, MO theory – applications – Comparision of VB and MO theories –

VSEPR theory –Bond order – Bond energy – Bond length Bond polarity – Partial

ionic character of bonds – The conceptof multi-centre bond – Electron deficient

compounds – Hydrogen bond – Its influences.

iii) Non aqueous solvents – A general study of typical reactions in non aqueous

media – comparison with reactions in aqueous media.

iv) Nuclear – chemistry – Nuclear structure – Nuclear forces –Nuclear stability –

Nuclear modes – Modes of Radioactivity decay. Nuclear Reaction- fission and

fusion

v) Orgnometallic compounds – Metallecences – Arene complexes – Non aromatic

olefins and acetylenes complexes – catalysis by organometallic compounds

Wilkinson’s catalyst – Oxoprocess –wacker process – Ziegler – Natta catalysis.


86

UNIT- II

i) Optical activity and concept of chirality – Different kinds of optically active

compounds – Absolute configuration - R and S Notations– Methods with more

than one chiral center – Asymmetric synthesis.

ii) Geometrical isomerism resulting from double bonds – The E.Z. system of

nomenclature –Geometrical isomerism of monocyclic compounds and fused ring

systems – Stereospecific and stereo selective reactions with examples.

iii) Organic reaction mechanisms – Aliphatic nucleophilic substituion SN1 and SN2

– stereo chemistry of nucleophilic reaction –Elimination reactions E1, E2, E1cB

Mechanism – dehydration of alcohols – dehydro halogenation – cope

elemination.

iv) Reagents in organic synthesis - DCC, DDQ ,selenium dioxide ,phase transfer

catalyst, LDA – Rearrangements:- Lossen, Schmitts, Baeyer – Villiger, Pinacol –

Pinacolene, Benzoil –Benzilic acid, Benzidine, Favorski and fries rearrangements

– sigmatropic rearragements – claisen and cope rearragements. Pericyclic

reactions, selection rules – orbital symmetry – Electrocyclic reactions – cyclic

additions - sigmatropic reactions.

UNIT-III

i) The old quantum theory – black body radiation – Photo electric effect –

Hydrogen spectrum – Compton effect- de Broglie equation – Heisenberg’s

uncertainty principle – Postulates of quantum mechanics – Schrödinger

equation – Operator algebra – Linear and Hermitian operators –Eigen

functions and Eigen values – Hamiltonian operators – Angular momentum.

ii) Symmetry elements and symmetry operations – Point groups – reducible and

irreducible representations, characters tables – Orthogonality theorem and its

consequences. Symmetry selection rule for IR and Raman spectra -

symmetries of normal modes of vibration – symmetry applied to MO theory

and orbital hybridization.


87

iii) Thermodynamic equations of state – closed and open systems – partial molar

quantities –chemical potential with temperature and pressure – third law of

thermodynamics. Fugacity – methods of determination – activity and activity

co-efficient – Maxwell’s distribution of molecular velocities – derivation of

expression for average, most probable and root mean square velocities –

Microstates Macro states – partial functions – Sacker tetrode equation.

iv) Hammett acidity function –Acid base catalysis Bronsted relation- Enzyme

catalysis – Michaelis Menton Law – influence of PH and temperature. Surface

phenomenon – Heterogeneous catalysis – Adsorption isotherms.

v) Electrolytic conductance – applications – solubility product – Inter ionic

attraction theory – Debye- Huckel – Onsager equation – equivalent

conductivity of electrolytes. Electrode potentials – Electrochemical cells –

electrode – electrolyte interface – electrical double layer electro capillary

phenomena – electro kinetic Phenomena – Membrane potential – Polarisation

–Butler-Volmer equation.

UNIT-IV

i) UV Spectroscopy: Principle - absorption spectra of conjugated dienes – α,β -

unsaturated carbonyl compounds – Woodward- Fieser rules - Scott’s rules for

aromatic carbonyls.

ii) IR Spectroscopy: Molecular vibrations – vibrational frequency - factors

influencing group frequencies – quantitative studies.

iii) 1H NMR spectroscopy: Theory of NMR – chemical shift- factors affecting

chemical shift, spin-spin coupling – coupling constant – spin-spin splitting –

simplification of complex spectra –double resonance – lanthanide shift reagents,

chiral resolving reagents – nuclear overhauser effect – NMR concept of

aromaticity.

iv) Mossbauer Spectroscopy: Mossbauer effect- resonance absorption-Doppler effect-

Doppler velocity –isomer shift-magnetic hyperfine splitting-application of

Mossbauer spectroscopy in the study of iron and tin complexes.

v) ESR Spectroscopy: Principle –presentation of the spectrum –hyperfine splitting-

evaluation of g values –factors affecting the magnitude of g –values-Zero field

splitting –Kramer's degeneracy---application of ESR in the study of transition of

metal complex


88

UNIT- V

i) Basic idea of nanoscience–Dimensional control in nano structures-,1D,2D and 3D

nano structures , synthesis of nano materials -chemical method, sol gel -Chemical

vapour deposition- Ball milling-plasma Arcing- electrodeposition- Thermolysis

ii) Carbon nanotubes: structure and characterization of single walled carbon nano

tubes-properties and applications of nano tubes.

iii) Nano polymers:Conductive polymer and Block copolymer.

iv) Twelve basic principles of green chemistry, green starting materials, green catalyst

and reagents -green solvents –applications of supercritical fluids, ionic liquids and

water – solvent free techniques- Non-conventional microwave heating - interaction

of microwave radiation with the material-difference between conventional heating

and microwave heating.

Text Book:1





Text book-2





Text book-3





Text Book- 4

Title of the book : Elementary organic spectroscopy principles and

chemical applications Name of the Author : Y.R.Sharma




89

Reference Book:1

CSIR-UGC NET/JRF/SET Chemical sciences - Hemant Kulshrestha, Ajay Taneja,

2010,Upkar’s Publication.

Reference Book:2

CSIR-UGC NET/JRF/SET Chemical sciences - Helder, Trueman’s Specific series(2012)


Signature :

CHAIRMAN DEAN

pg degree course in m.sc....

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