phase behavior of liquids - ksu facultyfac.ksu.edu.sa/sites/default/files/pge_362_lecture7_2.pdf ·...
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Properties of Reservoir Fluids (PGE 362)
Phase Behavior of Liquids BY
DR. MOHAMMED A. KHAMIS 1-11-2016
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Pressure-Temperature Diagram for Multicomponent Systems
Reserv
oir
Pre
ssu
re
Reservoir Temperature
60%
20% 0%
2-Phase
1-Phase 1-Phase
CP
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Importance of Pressure-Temperature Diagram
Temperature
t 1
Pre
ssu
re
t 3
t 2
Gas
Injection
Production t
t 3
2
Gas
Injection
Production
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Terminologies
• Phase
• A portion of the system which has homogeneous intensive properties and it is bounded by a physical surface.
• Interface • Separates two or more phases. These phases are solid, liquid(s), and gas
• Intensive Properties • Independent of system mass (i.e density)
• Extensive Properties • Dependent of system mass (i.e volume)
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Terminologies
• System • A body of matter with finite boundaries (physical or virtual)
• Closed system • Does not exchange matter with surroundings but may exchange energy (heat).
• Open system • Does exchange matter and energy with surroundings.
• Homogenous system • Intensive properties change continuously and uniformly (smoothly)
• Heterogeneous system • System made up of two or more phases in which the intensive properties
change abruptly at phase-contact surfaces
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Terminologies
• Properties
•Characteristics of a system (phase) that may be evaluated quantitatively. These are, Phase density (liquid, gas, solid)
Compressibility
Surface tension
Viscosity
Heat capacity
Thermal conductivity
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Phase Diagram
• Types of phase diagrams for a single component (pure substance)
Pressure-Temperature (PT)
Pressure-Volume (PV) or (P𝜌)
Temperature-Volume (TV) or (T 𝜌)
Pre
ssu
re
P c
Temperature T c
Liquid (1 phase)
Vapor (1 phase)
Solid (1 phase)
Sublimation Curve (2 phases)
Triple Point (3 phases)
Vapor Pressure Curve (2 phases)
Critical Point
Fusion Curve 2 phases
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Phase Diagram
• Interesting videos
Phase Diagrams and the States of Matter
http://www.youtube.com/watch?v=gbUTffUsXOM
Triple Point
http://www.youtube.com/watch?v=BLRqpJN9zeA
What is Supercritical fluid
http://www.youtube.com/watch?v=QHcqyFm0i9M#aid=P8sRLIeLU1Q
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Pressure-Volume-Temperature
• Temperature-Volume (TV) • At constant pressure the volume of a liquid at any temperature can be
estimated using the formula:
• 𝑉 = 𝑉𝑜 1 + 𝛼 𝑇 − 𝑇𝑜
• Vo : initial volume at To
• 𝛼 : average coefficient of thermal expansion (different for different liquids)
• At constant pressure the volume of a liquid at any temperature cab be estimated using the formula:
• 𝑉 = 𝑉𝑜 1 − 𝐶 𝑃 − 𝑃𝑜
• C: average coefficient of compression (different for different liquids)