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ANALYTICAL REPORT

Job Number: 180-42982-1

Job Description: Sparrows Point Trust Offshore Investigat

For:EA Engineering, Science, and Technology

225 Schilling CircleHunt Valley, MD 21031

Attention: Sanita Corum

_____________________________________________

Approved for release.Carrie L GamberSenior Project Manager4/30/2015 1:45 PM

Carrie L Gamber, Senior Project Manager301 Alpha Drive, Pittsburgh, PA, 15238

(412)963-2428 [email protected]

04/30/2015

The test results in this report meet all NELAP requirements for parameters for which accreditation is required oravailable. Any exceptions to the NELAP requirements are noted in this report. Pursuant to NELAP, this report may notbe reproduced, except in full, without the written approval of the laboratory. This report is confidential and is intendedfor the sole use of TestAmerica and its client. All questions regarding this report should be directed to the TestAmericaProject Manager or designee who has signed this report.

TestAmerica Laboratories, Inc.

TestAmerica Pittsburgh 301 Alpha Drive, RIDC Park, Pittsburgh, PA 15238

Tel (412) 963-7058 Fax (412) 963-2468 www.testamericainc.com

Page 1 of 541

mailto:[email protected]://www.testamericainc.comhttp://

Table of ContentsCover Title Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1

Data Summaries . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5

Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5

Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6

Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7

Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8

Default Detection Limits . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21

Surrogate Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22

QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23

QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26

Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28

Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 30

Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31

Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32

Manual Integration Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33

Reagent Traceability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35

COAs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98

Organic Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 206

GC/MS Semi VOA . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 206

Method 8270D Low Level . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 206Method 8270D Low Level QC Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 207Method 8270D Low Level Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 214Standards Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 227

Method 8270D Low Level ICAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 227Method 8270D Low Level CCAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 291

Raw QC Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 298

Page 2 of 541

Table of ContentsMethod 8270D Low Level Tune Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 298Method 8270D Low Level Blank Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 314Method 8270D Low Level LCS/LCSD Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 321

Method 8270D Low Level Run Logs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 326Method 8270D Low Level Prep Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 328

Inorganic Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 329

Metals Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 329

Met Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 330

Met Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 331

Met QC Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 335Met ICV/CCV . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 335Met CRQL . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 339Met Blanks . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 341Met ICSA/ICSAB . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 347Met LCS/LCSD . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 349

Met MDL . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 351

Met Linear Ranges . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 355

Met Preparation Log . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 356

Met Analysis Run Log . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 358

Met ICP/MS Int Stds . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 366

Met Raw Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 368

Met Prep Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 494

General Chemistry Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 497

Gen Chem Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 498

Gen Chem Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 499

Gen Chem QC Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 505

Page 3 of 541

Table of ContentsGen Chem ICV/CCV . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 505Gen Chem Blanks . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 507Gen Chem LCS/LCSD . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 508

Gen Chem MDL . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 510

Gen Chem Analysis Run Log . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 514

Gen Chem Raw Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 516

Gen Chem Prep Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 535

Shipping and Receiving Documents . . . . . . . . . . . . . . . . . . . . . . . . . . . 538

Client Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 539

Sample Receipt Checklist . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 541

Page 4 of 541

Definitions/GlossaryTestAmerica Job ID: 180-42982-1Client: EA Engineering, Science, and Technology

Project/Site: Sparrows Point Trust Offshore Investigat

Qualifiers

GC/MS Semi VOA

Qualifier Description

J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.

Qualifier

Metals



Qualifier

General Chemistry



Qualifier

Glossary

These commonly used abbreviations may or may not be present in this report.

¤ Listed under the "D" column to designate that the result is reported on a dry weight basis

Abbreviation

%R Percent Recovery

CFL Contains Free Liquid

CNF Contains no Free Liquid

DER Duplicate error ratio (normalized absolute difference)

Dil Fac Dilution Factor

DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample

DLC Decision level concentration

MDA Minimum detectable activity

EDL Estimated Detection Limit

MDC Minimum detectable concentration

MDL Method Detection Limit

ML Minimum Level (Dioxin)

NC Not Calculated

ND Not detected at the reporting limit (or MDL or EDL if shown)

PQL Practical Quantitation Limit

QC Quality Control

RER Relative error ratio

RL Reporting Limit or Requested Limit (Radiochemistry)

RPD Relative Percent Difference, a measure of the relative difference between two points

TEF Toxicity Equivalent Factor (Dioxin)

TEQ Toxicity Equivalent Quotient (Dioxin)

TestAmerica Pittsburgh

Page 5 of 541

CASE NARRATIVE

Client: EA Engineering, Science, and Technology

Project: Sparrows Point Trust Offshore Investigation

Report Number: 180-42982-1

With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no

problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control

limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of

the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples,

the reporting limits are adjusted relative to the dilution required.

Calculations are performed before rounding to avoid round-off errors in calculated results.

All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the

individual sections below.

RECEIPT

The samples were received on 04/11/2015; the samples arrived in good condition, properly preserved and on ice. The temperature of the

coolers at receipt was 2.7 C.

SEMIVOLATILES

No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

METALS

The following samples were diluted due to the nature of the sample matrix: PW-C01 (180-42982-1), PW-B01 (180-42982-2) and PW-A01

(180-42982-3). Elevated reporting limits (RLs) are provided.

GENERAL CHEMISTRY

The following samples were diluted to bring the concentration of target analytes within the calibration range: PW-C01 (180-42982-1),

PW-B01 (180-42982-2) and PW-A01 (180-42982-3). Elevated reporting limits (RLs) are provided.

Batch# 140019 Method SM5310C DOC Insufficient sample to analyze TIC for this batch:PW-C01 (180-42982-1), PW-B01 (180-42982-2)

and PW-A01 (180-42982-3)

The presence of the '4' qualifier indicates analytes where the concentration in the unspiked sample exceeded four times the spiking

amount.

Page 6 of 541

Detection SummaryTestAmerica Job ID: 180-42982-1Client: EA Engineering, Science, and Technology


Client Sample ID: PW-C01 Lab Sample ID: 180-42982-1

Bis(2-ethylhexyl) phthalate

RL

1.9 ug/L

MDL

0.42

Analyte Result Qualifier Unit Dil Fac D Method Prep Type

Total/NA1J0.73 8270D LL

Arsenic 10 ug/L2.9 Total

Recoverable

106.8 J 6020A

Thallium 10 ug/L0.15 Total

Recoverable

100.26 J 6020A

Antimony 20 ug/L0.19 Total

Recoverable

100.66 J 6020A

Nickel 10 ug/L1.7 Total

Recoverable

102.1 J 6020A

Zinc 50 ug/L9.6 Total

Recoverable

1012 J 6020A

Hardness as calcium carbonate 25 mg/L7.7 Total/NA11300 SM 2340C

Dissolved Organic Carbon - Duplicate 1.0 mg/L0.14 Dissolved11.2 SM 5310C

Client Sample ID: PW-B01 Lab Sample ID: 180-42982-2

Arsenic

RL

10 ug/L

MDL

2.9


Total

Recoverable

10J7.2 6020A


Recoverable

100.17 J 6020A


Recoverable

102.0 J 6020A

Hardness as calcium carbonate 130 mg/L38 Total/NA12100 SM 2340C

Dissolved Organic Carbon - Duplicate 1.0 mg/L0.14 Dissolved11.0 SM 5310C

Client Sample ID: PW-A01 Lab Sample ID: 180-42982-3

Arsenic

RL

10 ug/L

MDL

2.9


Total

Recoverable

10J3.4 6020A

Lead 10 ug/L0.19 Total

Recoverable

100.19 J 6020A


Recoverable

100.17 J 6020A


Recoverable

102.9 J 6020A

Hardness as calcium carbonate 50 mg/L15 Total/NA11700 SM 2340C

Dissolved Organic Carbon - Duplicate 1.0 mg/L0.14 Dissolved10.96 J SM 5310C


This Detection Summary does not include radiochemical test results.

Page 7 of 541

Client Sample ResultsTestAmerica Job ID: 180-42982-1Client: EA Engineering, Science, and Technology


Method: 8270D LL - Semivolatile Organic Compounds by GC/MS - Low Level

Lab Sample ID: 180-42982-1Client Sample ID: PW-C01

Matrix: WaterDate Collected: 04/10/15 15:54

Date Received: 04/11/15 09:30RL MDL

Anthracene ND 0.19 0.018 ug/L 04/13/15 09:07 04/14/15 18:39 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

0.19 0.035 ug/L 04/13/15 09:07 04/14/15 18:39 1Benzo[a]anthracene ND

0.19 0.047 ug/L 04/13/15 09:07 04/14/15 18:39 1Benzo[b]fluoranthene ND

0.19 0.029 ug/L 04/13/15 09:07 04/14/15 18:39 1Benzo[k]fluoranthene ND

0.19 0.028 ug/L 04/13/15 09:07 04/14/15 18:39 1Benzo[g,h,i]perylene ND

0.19 0.027 ug/L 04/13/15 09:07 04/14/15 18:39 1Benzo[a]pyrene ND

0.19 0.030 ug/L 04/13/15 09:07 04/14/15 18:39 1Chrysene ND

0.19 0.026 ug/L 04/13/15 09:07 04/14/15 18:39 1Dibenz(a,h)anthracene ND

0.19 0.020 ug/L 04/13/15 09:07 04/14/15 18:39 1Fluoranthene ND

0.19 0.023 ug/L 04/13/15 09:07 04/14/15 18:39 1Fluorene ND

0.19 0.042 ug/L 04/13/15 09:07 04/14/15 18:39 1Indeno[1,2,3-cd]pyrene ND

0.19 0.040 ug/L 04/13/15 09:07 04/14/15 18:39 1Phenanthrene ND

0.19 0.022 ug/L 04/13/15 09:07 04/14/15 18:39 1Pyrene ND

0.19 0.028 ug/L 04/13/15 09:07 04/14/15 18:39 1Acenaphthene ND

0.19 0.021 ug/L 04/13/15 09:07 04/14/15 18:39 1Acenaphthylene ND

0.19 0.022 ug/L 04/13/15 09:07 04/14/15 18:39 1Naphthalene ND

1.9 0.42 ug/L 04/13/15 09:07 04/14/15 18:39 1Bis(2-ethylhexyl) phthalate 0.73 J

Nitrobenzene-d5 (Surr) 41 27 - 114 04/13/15 09:07 04/14/15 18:39 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

2-Fluorobiphenyl 41 04/13/15 09:07 04/14/15 18:39 128 - 109

Terphenyl-d14 (Surr) 45 04/13/15 09:07 04/14/15 18:39 120 - 118

2-Fluorophenol (Surr) 37 04/13/15 09:07 04/14/15 18:39 120 - 105

2,4,6-Tribromophenol (Surr) 45 04/13/15 09:07 04/14/15 18:39 130 - 118

Phenol-d5 (Surr) 43 04/13/15 09:07 04/14/15 18:39 125 - 105


Page 8 of 541




Lab Sample ID: 180-42982-2Client Sample ID: PW-B01










0.19 0.030 ug/L 04/13/15 09:07 04/14/15 19:06 1Chrysene ND



0.19 0.023 ug/L 04/13/15 09:07 04/14/15 19:06 1Fluorene ND



0.19 0.022 ug/L 04/13/15 09:07 04/14/15 19:06 1Pyrene ND




1.9 0.42 ug/L 04/13/15 09:07 04/14/15 19:06 1Bis(2-ethylhexyl) phthalate ND



2-Fluorobiphenyl 39 04/13/15 09:07 04/14/15 19:06 128 - 109

Terphenyl-d14 (Surr) 41 04/13/15 09:07 04/14/15 19:06 120 - 118



Phenol-d5 (Surr) 43 04/13/15 09:07 04/14/15 19:06 125 - 105


Page 9 of 541




Lab Sample ID: 180-42982-3Client Sample ID: PW-A01










0.20 0.031 ug/L 04/13/15 09:07 04/14/15 19:33 1Chrysene ND



0.20 0.024 ug/L 04/13/15 09:07 04/14/15 19:33 1Fluorene ND



0.20 0.023 ug/L 04/13/15 09:07 04/14/15 19:33 1Pyrene ND




2.0 0.44 ug/L 04/13/15 09:07 04/14/15 19:33 1Bis(2-ethylhexyl) phthalate ND



2-Fluorobiphenyl 35 04/13/15 09:07 04/14/15 19:33 128 - 109

Terphenyl-d14 (Surr) 45 04/13/15 09:07 04/14/15 19:33 120 - 118



Phenol-d5 (Surr) 38 04/13/15 09:07 04/14/15 19:33 125 - 105


Page 10 of 541



Method: 6020A - Metals (ICP/MS) - Total Recoverable




Arsenic 6.8 J 10 2.9 ug/L 04/27/15 11:43 04/28/15 00:32 10


10 1.1 ug/L 04/27/15 11:43 04/28/15 00:32 10Cadmium ND

20 5.4 ug/L 04/27/15 11:43 04/28/15 00:32 10Chromium ND

10 0.19 ug/L 04/27/15 11:43 04/28/15 00:32 10Lead ND

50 4.2 ug/L 04/27/15 11:43 04/28/15 00:32 10Selenium ND

10 0.36 ug/L 04/27/15 11:43 04/28/15 00:32 10Silver ND

10 0.37 ug/L 04/27/15 11:43 04/28/15 00:32 10Beryllium ND

10 0.15 ug/L 04/27/15 11:43 04/28/15 00:32 10Thallium 0.26 J

20 0.19 ug/L 04/27/15 11:43 04/28/15 00:32 10Antimony 0.66 J

10 1.7 ug/L 04/27/15 11:43 04/28/15 00:32 10Nickel 2.1 J

50 9.6 ug/L 04/27/15 11:43 04/28/15 00:32 10Zinc 12 J

20 2.4 ug/L 04/27/15 11:43 04/28/15 00:32 10Copper ND


Page 11 of 541







Arsenic 7.2 J 10 2.9 ug/L 04/27/15 11:43 04/28/15 00:36 10


10 1.1 ug/L 04/27/15 11:43 04/28/15 00:36 10Cadmium ND

20 5.4 ug/L 04/27/15 11:43 04/28/15 00:36 10Chromium ND

10 0.19 ug/L 04/27/15 11:43 04/28/15 00:36 10Lead ND

50 4.2 ug/L 04/27/15 11:43 04/28/15 00:36 10Selenium ND

10 0.36 ug/L 04/27/15 11:43 04/28/15 00:36 10Silver ND

10 0.37 ug/L 04/27/15 11:43 04/28/15 00:36 10Beryllium ND

10 0.15 ug/L 04/27/15 11:43 04/28/15 00:36 10Thallium 0.17 J

20 0.19 ug/L 04/27/15 11:43 04/28/15 00:36 10Antimony ND

10 1.7 ug/L 04/27/15 11:43 04/28/15 00:36 10Nickel 2.0 J

50 9.6 ug/L 04/27/15 11:43 04/28/15 00:36 10Zinc ND

20 2.4 ug/L 04/27/15 11:43 04/28/15 00:36 10Copper ND


Page 12 of 541







Arsenic 3.4 J 10 2.9 ug/L 04/27/15 11:43 04/28/15 00:40 10


10 1.1 ug/L 04/27/15 11:43 04/28/15 00:40 10Cadmium ND

20 5.4 ug/L 04/27/15 11:43 04/28/15 00:40 10Chromium ND

10 0.19 ug/L 04/27/15 11:43 04/28/15 00:40 10Lead 0.19 J

50 4.2 ug/L 04/27/15 11:43 04/28/15 00:40 10Selenium ND

10 0.36 ug/L 04/27/15 11:43 04/28/15 00:40 10Silver ND

10 0.37 ug/L 04/27/15 11:43 04/28/15 00:40 10Beryllium ND

10 0.15 ug/L 04/27/15 11:43 04/28/15 00:40 10Thallium 0.17 J

20 0.19 ug/L 04/27/15 11:43 04/28/15 00:40 10Antimony ND

10 1.7 ug/L 04/27/15 11:43 04/28/15 00:40 10Nickel 2.9 J

50 9.6 ug/L 04/27/15 11:43 04/28/15 00:40 10Zinc ND

20 2.4 ug/L 04/27/15 11:43 04/28/15 00:40 10Copper ND


Page 13 of 541



Method: 7470A - Mercury (CVAA)




Mercury ND 0.20 0.078 ug/L 04/27/15 09:38 04/27/15 18:29 1



Page 14 of 541



General Chemistry




Hardness as calcium carbonate 1300 25 7.7 mg/L 04/29/15 13:35 1



Page 15 of 541



General Chemistry




Hardness as calcium carbonate 2100 130 38 mg/L 04/29/15 13:38 1



Page 16 of 541



General Chemistry




Hardness as calcium carbonate 1700 50 15 mg/L 04/29/15 13:42 1



Page 17 of 541



General Chemistry - Dissolved




Dissolved Organic Carbon -

Duplicate

1.2 1.0 0.14 mg/L 04/29/15 08:01 1



Page 18 of 541








Duplicate

1.0 1.0 0.14 mg/L 04/29/15 08:20 1



Page 19 of 541








Duplicate

0.96 J 1.0 0.14 mg/L 04/29/15 08:38 1



Page 20 of 541

Default Detection LimitsClient: EA Engineering, Science, and Technology TestAmerica Job ID: 180-42982-1



0.20Acenaphthene ug/L

Analyte Units MethodMDLRL

0.029 8270D LL

0.20Acenaphthylene ug/L0.022 8270D LL

0.20Anthracene ug/L0.019 8270D LL

0.20Benzo[a]anthracene ug/L0.037 8270D LL

0.20Benzo[a]pyrene ug/L0.028 8270D LL

0.20Benzo[b]fluoranthene ug/L0.049 8270D LL

0.20Benzo[g,h,i]perylene ug/L0.029 8270D LL

0.20Benzo[k]fluoranthene ug/L0.030 8270D LL

2.0Bis(2-ethylhexyl) phthalate ug/L0.44 8270D LL

0.20Chrysene ug/L0.031 8270D LL

0.20Dibenz(a,h)anthracene ug/L0.027 8270D LL

0.20Fluoranthene ug/L0.021 8270D LL

0.20Fluorene ug/L0.024 8270D LL

0.20Indeno[1,2,3-cd]pyrene ug/L0.043 8270D LL

0.20Naphthalene ug/L0.023 8270D LL

0.20Phenanthrene ug/L0.042 8270D LL

0.20Pyrene ug/L0.023 8270D LL


2.0Antimony ug/L


0.019 6020A

1.0Arsenic ug/L0.29 6020A

1.0Beryllium ug/L0.037 6020A

1.0Cadmium ug/L0.11 6020A

2.0Chromium ug/L0.54 6020A

2.0Copper ug/L0.24 6020A

1.0Lead ug/L0.019 6020A

1.0Nickel ug/L0.17 6020A

5.0Selenium ug/L0.42 6020A

1.0Silver ug/L0.036 6020A

1.0Thallium ug/L0.015 6020A

5.0Zinc ug/L0.96 6020A


0.20Mercury ug/L


0.078 7470A

General Chemistry

5.0Hardness as calcium carbonate mg/L


1.5 SM 2340C


1.0Dissolved Organic Carbon - Duplicate mg/L


0.14 SM 5310C


Page 21 of 541

Surrogate SummaryTestAmerica Job ID: 180-42982-1Client: EA Engineering, Science, and Technology


Method: 8270D LL - Semivolatile Organic Compounds by GC/MS - Low LevelPrep Type: Total/NAMatrix: Water

Lab Sample ID Client Sample ID (27-114) (28-109) (20-118) (20-105) (30-118) (25-105)

NBZ FBP TPH 2FP TBP PHL

41 41 45 37 45 43180-42982-1

Percent Surrogate Recovery (Acceptance Limits)

PW-C01

40 39 41 4537 43180-42982-2 PW-B01

36 35 45 4834 38180-42982-3 PW-A01

57 55 60 6357 61LCS 180-138290/2-A Lab Control Sample

58 53 58 5557 60MB 180-138290/1-A Method Blank

Surrogate Legend

NBZ = Nitrobenzene-d5 (Surr)

FBP = 2-Fluorobiphenyl

TPH = Terphenyl-d14 (Surr)

2FP = 2-Fluorophenol (Surr)

TBP = 2,4,6-Tribromophenol (Surr)

PHL = Phenol-d5 (Surr)


Page 22 of 541

QC Sample ResultsTestAmerica Job ID: 180-42982-1Client: EA Engineering, Science, and Technology



Client Sample ID: Method BlankLab Sample ID: MB 180-138290/1-A

Matrix: Water Prep Type: Total/NA

Analysis Batch: 138398 Prep Batch: 138290

RL MDL


MB MB

Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier

ND 0.0370.20 ug/L 04/13/15 09:07 04/14/15 10:54 1Benzo[a]anthracene

ND 0.0490.20 ug/L 04/13/15 09:07 04/14/15 10:54 1Benzo[b]fluoranthene

ND 0.0300.20 ug/L 04/13/15 09:07 04/14/15 10:54 1Benzo[k]fluoranthene

ND 0.0290.20 ug/L 04/13/15 09:07 04/14/15 10:54 1Benzo[g,h,i]perylene

ND 0.0280.20 ug/L 04/13/15 09:07 04/14/15 10:54 1Benzo[a]pyrene

ND 0.0310.20 ug/L 04/13/15 09:07 04/14/15 10:54 1Chrysene

ND 0.0270.20 ug/L 04/13/15 09:07 04/14/15 10:54 1Dibenz(a,h)anthracene

ND 0.0210.20 ug/L 04/13/15 09:07 04/14/15 10:54 1Fluoranthene

ND 0.0240.20 ug/L 04/13/15 09:07 04/14/15 10:54 1Fluorene

ND 0.0430.20 ug/L 04/13/15 09:07 04/14/15 10:54 1Indeno[1,2,3-cd]pyrene

ND 0.0420.20 ug/L 04/13/15 09:07 04/14/15 10:54 1Phenanthrene

ND 0.0230.20 ug/L 04/13/15 09:07 04/14/15 10:54 1Pyrene

ND 0.0290.20 ug/L 04/13/15 09:07 04/14/15 10:54 1Acenaphthene

ND 0.0220.20 ug/L 04/13/15 09:07 04/14/15 10:54 1Acenaphthylene

ND 0.0230.20 ug/L 04/13/15 09:07 04/14/15 10:54 1Naphthalene

ND 0.442.0 ug/L 04/13/15 09:07 04/14/15 10:54 1Bis(2-ethylhexyl) phthalate

Nitrobenzene-d5 (Surr) 58 27 - 114 04/14/15 10:54 1

MB MB

Surrogate

04/13/15 09:07

Dil FacPrepared AnalyzedQualifier Limits%Recovery

53 04/13/15 09:07 04/14/15 10:54 12-Fluorobiphenyl 28 - 109

58 04/13/15 09:07 04/14/15 10:54 1Terphenyl-d14 (Surr) 20 - 118

57 04/13/15 09:07 04/14/15 10:54 12-Fluorophenol (Surr) 20 - 105

55 04/13/15 09:07 04/14/15 10:54 12,4,6-Tribromophenol (Surr) 30 - 118

60 04/13/15 09:07 04/14/15 10:54 1Phenol-d5 (Surr) 25 - 105

Client Sample ID: Lab Control SampleLab Sample ID: LCS 180-138290/2-A



Anthracene 20.0 12.4 ug/L 62 49 - 100

Analyte

LCS LCS

DUnitResult Qualifier %Rec

Spike

Added

%Rec.

Limits

Benzo[a]anthracene 20.0 12.5 ug/L 62 50 - 100

Benzo[b]fluoranthene 20.0 12.7 ug/L 64 43 - 100

Benzo[k]fluoranthene 20.0 12.6 ug/L 63 47 - 100

Benzo[g,h,i]perylene 20.0 13.5 ug/L 67 48 - 100

Benzo[a]pyrene 20.0 13.1 ug/L 66 47 - 100

Chrysene 20.0 12.5 ug/L 63 49 - 100

Dibenz(a,h)anthracene 20.0 13.5 ug/L 68 48 - 100

Fluoranthene 20.0 12.0 ug/L 60 48 - 100

Fluorene 20.0 12.3 ug/L 62 48 - 100

Indeno[1,2,3-cd]pyrene 20.0 13.6 ug/L 68 47 - 100

Phenanthrene 20.0 12.5 ug/L 63 48 - 100

Pyrene 20.0 13.6 ug/L 68 44 - 100

Acenaphthene 20.0 11.3 ug/L 57 47 - 100

Acenaphthylene 20.0 11.9 ug/L 60 47 - 100

Naphthalene 20.0 11.7 ug/L 59 44 - 100

Bis(2-ethylhexyl) phthalate 20.0 13.1 ug/L 66 35 - 118


Page 23 of 541



Method: 8270D LL - Semivolatile Organic Compounds by GC/MS - Low Level (Continued)




Nitrobenzene-d5 (Surr) 27 - 114

Surrogate

57

LCS LCS

Qualifier Limits%Recovery

552-Fluorobiphenyl 28 - 109

60Terphenyl-d14 (Surr) 20 - 118

572-Fluorophenol (Surr) 20 - 105

632,4,6-Tribromophenol (Surr) 30 - 118

61Phenol-d5 (Surr) 25 - 105

Method: 6020A - Metals (ICP/MS)


Matrix: Water Prep Type: Total Recoverable


RL MDL

Arsenic ND 1.0 0.29 ug/L 04/27/15 11:43 04/27/15 22:52 1

MB MB


ND 0.111.0 ug/L 04/27/15 11:43 04/27/15 22:52 1Cadmium

ND 0.542.0 ug/L 04/27/15 11:43 04/27/15 22:52 1Chromium

ND 0.0191.0 ug/L 04/27/15 11:43 04/27/15 22:52 1Lead

ND 0.425.0 ug/L 04/27/15 11:43 04/27/15 22:52 1Selenium

ND 0.0361.0 ug/L 04/27/15 11:43 04/27/15 22:52 1Silver

ND 0.0371.0 ug/L 04/27/15 11:43 04/27/15 22:52 1Beryllium

ND 0.0151.0 ug/L 04/27/15 11:43 04/27/15 22:52 1Thallium

ND 0.0192.0 ug/L 04/27/15 11:43 04/27/15 22:52 1Antimony

ND 0.171.0 ug/L 04/27/15 11:43 04/27/15 22:52 1Nickel

ND 0.965.0 ug/L 04/27/15 11:43 04/27/15 22:52 1Zinc

ND 0.242.0 ug/L 04/27/15 11:43 04/27/15 22:52 1Copper


Matrix: Water Prep Type: Total Recoverable


Arsenic 40.0 37.5 ug/L 94 80 - 120

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Cadmium 50.0 51.3 ug/L 103 80 - 120

Chromium 200 196 ug/L 98 80 - 120

Lead 20.0 21.4 ug/L 107 80 - 120

Selenium 10.0 9.81 ug/L 98 80 - 120

Silver 50.0 50.0 ug/L 100 80 - 120

Beryllium 50.0 47.5 ug/L 95 80 - 120

Thallium 50.0 52.2 ug/L 104 80 - 120

Antimony 500 518 ug/L 104 80 - 120

Nickel 500 472 ug/L 94 80 - 120

Zinc 500 492 ug/L 98 80 - 120

Copper 250 236 ug/L 94 80 - 120


Page 24 of 541







RL MDL

Mercury ND 0.20 0.078 ug/L 04/27/15 09:38 04/27/15 17:38 1

MB MB





Mercury 2.50 2.65 ug/L 106 80 - 120

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Method: SM 2340C - Hardness, Total (mg/l as CaC03)

Client Sample ID: Method BlankLab Sample ID: MB 180-140054/2


Analysis Batch: 140054

RL MDL

Hardness as calcium carbonate ND 5.0 1.5 mg/L 04/29/15 13:15 1

MB MB


Client Sample ID: Lab Control SampleLab Sample ID: LCS 180-140054/1



Hardness as calcium carbonate 50.0 50.0 mg/L 100 90 - 110

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Method: SM 5310C - Organic Carbon, Dissolved (DOC)

Client Sample ID: Method BlankLab Sample ID: MB 180-140019/6

Matrix: Water Prep Type: Dissolved


RL MDL

Dissolved Organic Carbon - Duplicate ND 1.0 0.14 mg/L 04/29/15 07:43 1

MB MB


Client Sample ID: Lab Control SampleLab Sample ID: LCS 180-140019/4




Duplicate

20.0 19.7 mg/L 99 80 - 120

Analyte

LCS LCS


Spike

Added

%Rec.

Limits

Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 180-140019/5




Duplicate

20.0 19.0 mg/L 95 80 - 120 4 20

Analyte

LCSD LCSD


Spike

Added

%Rec.

Limits LimitRPD

RPD


Page 25 of 541

QC Association SummaryTestAmerica Job ID: 180-42982-1Client: EA Engineering, Science, and Technology


GC/MS Semi VOA

Prep Batch: 138290

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

Water 3520C180-42982-1 PW-C01 Total/NA

Water 3520C180-42982-2 PW-B01 Total/NA

Water 3520C180-42982-3 PW-A01 Total/NA

Water 3520CLCS 180-138290/2-A Lab Control Sample Total/NA

Water 3520CMB 180-138290/1-A Method Blank Total/NA



Water 8270D LL 138290180-42982-1 PW-C01 Total/NA

Water 8270D LL 138290180-42982-2 PW-B01 Total/NA

Water 8270D LL 138290180-42982-3 PW-A01 Total/NA

Water 8270D LL 138290LCS 180-138290/2-A Lab Control Sample Total/NA

Water 8270D LL 138290MB 180-138290/1-A Method Blank Total/NA

Metals

Prep Batch: 139732


Water 7470A180-42982-1 PW-C01 Total/NA

Water 7470ALCS 180-139732/2-A Lab Control Sample Total/NA

Water 7470AMB 180-139732/1-A Method Blank Total/NA

Prep Batch: 139759


Water 3005A180-42982-1 PW-C01 Total Recoverable

Water 3005A180-42982-2 PW-B01 Total Recoverable

Water 3005A180-42982-3 PW-A01 Total Recoverable

Water 3005ALCS 180-139759/2-A Lab Control Sample Total Recoverable

Water 3005AMB 180-139759/1-A Method Blank Total Recoverable

Prep Batch: 139774


Water 7470ACRA 180-139774/9-A DL



Water 7470A 139732180-42982-1 PW-C01 Total/NA

Water 7470A 139774CRA 180-139774/9-A DL

Water 7470A 139732LCS 180-139732/2-A Lab Control Sample Total/NA

Water 7470A 139732MB 180-139732/1-A Method Blank Total/NA



Water 6020A 139759180-42982-1 PW-C01 Total Recoverable

Water 6020A 139759180-42982-2 PW-B01 Total Recoverable

Water 6020A 139759180-42982-3 PW-A01 Total Recoverable

Water 6020ACRI 180-139939/113 DL

Water 6020ACRI 180-139939/7 DL

Water 6020AICSA 180-139939/8 ICS

Water 6020AICSAB 180-139939/9 ICS


Page 26 of 541

QC Association SummaryTestAmerica Job ID: 180-42982-1Client: EA Engineering, Science, and Technology


Metals (Continued)

Analysis Batch: 139939 (Continued)


Water 6020A 139759LCS 180-139759/2-A Lab Control Sample Total Recoverable

Water 6020A 139759MB 180-139759/1-A Method Blank Total Recoverable

General Chemistry

Filtration Batch: 139876


Water FILTRATION180-42982-1 PW-C01 Dissolved

Water FILTRATION180-42982-2 PW-B01 Dissolved

Water FILTRATION180-42982-3 PW-A01 Dissolved



Water SM 5310C 139876180-42982-1 PW-C01 Dissolved

Water SM 5310C 139876180-42982-2 PW-B01 Dissolved

Water SM 5310C 139876180-42982-3 PW-A01 Dissolved

Water SM 5310CLCS 180-140019/4 Lab Control Sample Dissolved

Water SM 5310CLCSD 180-140019/5 Lab Control Sample Dup Dissolved

Water SM 5310CMB 180-140019/6 Method Blank Dissolved



Water SM 2340C180-42982-1 PW-C01 Total/NA

Water SM 2340C180-42982-2 PW-B01 Total/NA

Water SM 2340C180-42982-3 PW-A01 Total/NA

Water SM 2340CLCS 180-140054/1 Lab Control Sample Total/NA

Water SM 2340CMB 180-140054/2 Method Blank Total/NA


Page 27 of 541

Lab ChronicleClient: EA Engineering, Science, and Technology TestAmerica Job ID: 180-42982-1


Client Sample ID: PW-C01 Lab Sample ID: 180-42982-1Matrix: WaterDate Collected: 04/10/15 15:54

Date Received: 04/11/15 09:30

Prep 3520C BJT04/13/15 09:07 TAL PIT138290

Type

Batch

Method

Batch

Prep Type LabAnalystRun

Prepared

or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

Total/NA 260 mL 0.25 mL

Analysis 8270D LL 1 138398 04/14/15 18:39 VVP TAL PITTotal/NA 260 mL 0.25 mL

CH732Instrument ID:

Prep 3005A 139759 04/27/15 11:43 AB1 TAL PITTotal Recoverable 50 mL 50 mL

Analysis 6020A 10 139939 04/28/15 00:32 WTR TAL PITTotal Recoverable 50 mL 50 mL

MInstrument ID:

Prep 7470A 139732 04/27/15 09:38 MLF TAL PITTotal/NA 50 mL 50 mL

Analysis 7470A 1 139819 04/27/15 18:29 RJR TAL PITTotal/NA 50 mL 50 mL

KInstrument ID:

Analysis SM 2340C 1 140054 04/29/15 13:35 CAK TAL PITTotal/NA 10 mL 50 mL

NOEQUIPInstrument ID:

Filtration FILTRATION 139876 04/28/15 10:20 SLM TAL PITDissolved 1.0 mL 1.0 mL

Analysis SM 5310C 1 140019 04/29/15 08:01 CLL TAL PITDissolved

TOC1030Instrument ID:

Client Sample ID: PW-B01 Lab Sample ID: 180-42982-2Matrix: WaterDate Collected: 04/10/15 14:20


Prep 3520C BJT04/13/15 09:07 TAL PIT138290

Type

Batch

Method

Batch


Prepared

or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil



CH732Instrument ID:



MInstrument ID:

Analysis SM 2340C 1 140054 04/29/15 13:38 CAK TAL PITTotal/NA 2 mL 50 mL





Client Sample ID: PW-A01 Lab Sample ID: 180-42982-3Matrix: WaterDate Collected: 04/10/15 12:45


Prep 3520C BJT04/13/15 09:07 TAL PIT138290

Type

Batch

Method

Batch


Prepared

or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil



CH732Instrument ID:



MInstrument ID:


Page 28 of 541

Lab ChronicleClient: EA Engineering, Science, and Technology TestAmerica Job ID: 180-42982-1


Client Sample ID: PW-A01 Lab Sample ID: 180-42982-3Matrix: WaterDate Collected: 04/10/15 12:45


Analysis SM 2340C CAK04/29/15 13:421 TAL PIT140054

Type

Batch

Method

Batch


Prepared

or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

Total/NA 5 mL 50 mL





Laboratory References:

TAL PIT = TestAmerica Pittsburgh, 301 Alpha Drive, RIDC Park, Pittsburgh, PA 15238, TEL (412)963-7058

Analyst References:

Lab: TAL PIT

Batch Type: Filtration

SLM = Sarah McCann

Batch Type: Prep

AB1 = Ashwin Baikadi

BJT = Bill Trout

MLF = Michele Freeman

Batch Type: Analysis

CAK = Chuck Kieda

CLL = Cheryl Loheyde

RJR = Ron Rosenbaum

VVP = Vincent Piccolino

WTR = Bill Reinheimer


Page 29 of 541

Certification SummaryClient: EA Engineering, Science, and Technology TestAmerica Job ID: 180-42982-1


Laboratory: TestAmerica PittsburghAll certifications held by this laboratory are listed. Not all certifications are applicable to this report.

Authority Program EPA Region Certification ID Expiration Date

Arkansas DEQ 88-06906State Program 06-27-15

California State Program 9 2891 03-31-16

Connecticut State Program 1 PH-0688 09-30-16

Florida NELAP 4 E871008 06-30-15

Illinois NELAP 5 002602 06-30-15

Kansas NELAP 7 E-10350 04-30-15 *

Louisiana NELAP 6 04041 06-30-15

New Hampshire NELAP 1 203011 04-04-16

New Jersey NELAP 2 PA005 06-30-15

New York NELAP 2 11182 03-31-16

North Carolina (WW/SW) State Program 4 434 12-31-15

Pennsylvania NELAP 3 02-00416 04-30-15 *

South Carolina State Program 4 89014 04-30-15 *

Texas NELAP 6 T104704528 03-31-16

US Fish & Wildlife Federal LE94312A-1 11-30-15

USDA Federal P-Soil-01 05-23-16

Utah NELAP 8 STLP 05-31-15

Virginia NELAP 3 460189 09-14-15

West Virginia DEP State Program 3 142 01-31-16

Wisconsin State Program 5 998027800 08-31-15


* Certification renewal pending - certification considered valid.

Page 30 of 541

Method SummaryTestAmerica Job ID: 180-42982-1Client: EA Engineering, Science, and Technology


Method Method Description LaboratoryProtocol

SW8468270D LL Semivolatile Organic Compounds by GC/MS - Low Level TAL PIT

SW8466020A Metals (ICP/MS) TAL PIT

SW8467470A Mercury (CVAA) TAL PIT

SMSM 2340C Hardness, Total (mg/l as CaC03) TAL PIT

SMSM 5310C Organic Carbon, Dissolved (DOC) TAL PIT

Protocol References:

SM = "Standard Methods For The Examination Of Water And Wastewater",

SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.

Laboratory References:

TAL PIT = TestAmerica Pittsburgh, 301 Alpha Drive, RIDC Park, Pittsburgh, PA 15238, TEL (412)963-7058


Page 31 of 541

Sample SummaryTestAmerica Job ID: 180-42982-1Client: EA Engineering, Science, and Technology


Lab Sample ID Client Sample ID ReceivedCollectedMatrix

180-42982-1 PW-C01 Water 04/10/15 15:54 04/11/15 09:30

180-42982-2 PW-B01 Water 04/10/15 14:20 04/11/15 09:30

180-42982-3 PW-A01 Water 04/10/15 12:45 04/11/15 09:30


Page 32 of 541

Lab Name: Job No.:

SDG No.:

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-42982-1

Instrument ID: Analysis Batch Number:CH732 132436

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-132436/3

D0203003.D02/03/15 05:53 GC Column: Rxi-5SilMS ID: 0.32(mm)

1,4-Dioxane Poor chromatography piccolinov

02/03/15 08:471.55

N-Nitrosodimethylamine Poor chromatography piccolinov

02/03/15 08:472.14

Pyridine Poor chromatography piccolinov

02/03/15 08:472.24

Benzoic acid Poor chromatography piccolinov

02/03/15 08:477.15

Indeno[1,2,3-cd]pyrene Poor chromatography piccolinov

02/03/15 08:4719.79

Dibenz(a,h)anthracene Poor chromatography piccolinov

02/03/15 08:4719.85

Benzo[g,h,i]perylene Poor chromatography piccolinov

02/03/15 08:4720.50




TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-132436/4


Pyridine Poor chromatography piccolinov

02/03/15 08:482.22


02/03/15 08:487.16


02/03/15 08:4819.79


02/03/15 08:4819.84

Benzo[g,h,i]perylene Poor chromatography piccolinov

02/03/15 08:4820.50

8270D LL

Page 33 of 541

Lab Name: Job No.:

SDG No.:

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-42982-1

Instrument ID: Analysis Batch Number:CH732 132436




TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-132436/5



02/03/15 08:507.16


02/03/15 08:5019.84




TIME

MANUAL INTEGRATION

DATEANALYSTREASON

ICIS 180-132436/6



02/03/15 08:5119.82




TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-132436/8



02/03/15 08:5819.82




TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-132436/9



02/03/15 08:5919.81

8270D LL

Page 34 of 541

REAGENT TRACEABILITY SUMMARY

Lab Name:

SDG No.:

Job No.: 180-42982-1TestAmerica Pittsburgh

Reagent IDExpDate Date

Prep DilutantUsed

ReagentFinalVolume

Parent Reagent

Reagent IDVolumeAdded ConcentrationAnalyte

WTOC1000SP_00011 Dissolved Organic Carbon - Duplicate

10 mg/L200 mg/L 2 mL04/30/15 04/29/1510 PPM TOC/CC_00485 DI Water, Lot DI WATER

DOC Result 1 10 mg/LDOC Result 2 10 mg/L

12/31/15 (Purchased Reagent) Dissolved Organic Carbon - Duplicate

1000 mg/LRicca Chemical Co, Lot 2412908.WTOC1000SP_00011


WTOC1000SP_00011 Dissolved Organic Carbon - Duplicate

40 mg/L100 mg/L 4 mL04/30/15 04/29/15ICV 40 PPM_00618 DI Water, Lot DIWATER



1000 mg/LRicca Chemical Co, Lot 2412908.WTOC1000SP_00011


04/30/15 04/29/15 200 mg/L WTOC1000P_00022 4 mL Dissolved Organic Carbon - Duplicate

20 mg/LLCS 20 PPM_00614 DI Water, Lot DIWATER


1000 mg/LLab Chem, Lot E054-11.WTOC1000P_00022

MCALSPECAREV_00005 Arsenic 0.1 ppm500 mL 10 mL05/01/15 04/14/15MCCV1X_00074 2% Nitric Acid, Lot 1241747

Beryllium 0.1 ppmCadmium 0.1 ppmChromium 0.1 ppmCopper 0.1 ppmLead 0.1 ppmNickel 0.1 ppmSelenium 0.1 ppmSilver 0.1 ppmThallium 0.1 ppmZinc 0.1 ppm

MCALSPECB_00007 10 mL Antimony 0.1 ppm05/01/15 (Purchased Reagent) Arsenic 5 ppmInorganic Ventures, Lot F2-MEB524026.MCALSPECAREV_00005

Beryllium 5 ppmCadmium 5 ppmChromium 5 ppmCopper 5 ppmLead 5 ppmNickel 5 ppmSelenium 5 ppmSilver 5 ppmThallium 5 ppmZinc 5 ppm

05/01/15 (Purchased Reagent) Antimony 5 ppmInorganic Ventures, Lot F2-MEB524027.MCALSPECB_00007

MMSCRI-1B_00005 Arsenic 0.001 ppm250 mL 1 mL05/07/15 04/07/15MCRIX_00065 HNO3, Lot 1191081Beryllium 0.001 ppm

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Cadmium 0.001 ppmChromium 0.002 ppmCopper 0.002 ppmLead 0.001 ppmNickel 0.001 ppmSelenium 0.005 ppmSilver 0.001 ppmThallium 0.001 ppmZinc 0.005 ppm

MMSCRI-2_00007 1 mL Antimony 0.002 ppm04/01/16 (Purchased Reagent) Arsenic 0.25 ppmInorganic Ventures, Lot J2-MEB572092.MMSCRI-1B_00005

Beryllium 0.25 ppmCadmium 0.25 ppmChromium 0.5 ppmCopper 0.5 ppmLead 0.25 ppmNickel 0.25 ppmSelenium 1.25 ppmSilver 0.25 ppmThallium 0.25 ppmZinc 1.25 ppm

04/01/16 (Purchased Reagent) Antimony 0.5 ppmInorganic Ventures, Lot J2-MEB572093.MMSCRI-2_00007

04/28/15 04/27/15 100 mL MHgIntcal_00110 1 mL Mercury 100 ppbMHgworkingCal_01031 2% Nitric Acid, Lot 0000102057

04/28/15 04/27/15 100 mL MCGHG1-1_00009 1 mL Mercury 10 ppm.MHgIntcal_00110 2% Nitric Acid, Lot 0000102057

02/01/16 (Purchased Reagent) Mercury 1000 ppminorganic ventures, Lot H2-HG02128..MCGHG1-1_00009

04/28/15 04/27/15 100 mL MHgIntICV_00090 1 mL Mercury 100 ppbMHgWorkingicv_01002 2% Nitric Acid, Lot 0000102057

04/28/15 04/27/15 100 mL MHGICV-1_00005 1 mL Mercury 10 ppm.MHgIntICV_00090 2% Nitric Acid, Lot 0000102057

07/31/15 (Purchased Reagent) Mercury 1000 ppmULTRA SCIENTIFIC, Lot T00602..MHGICV-1_00005

M6020ICS-0A_00005 Al 100 ppm100 mL 10 mL05/01/15 04/14/15MICSABX_00069 2% Nitric Acid, Lot J38N82

Ca 100 ppmFe 100 ppmK 100 ppmMg 100 ppmMo 2 ppmNa 100 ppmTi 2 ppmArsenic 0.02 ppmM6020ICS-0B_00006 1 mLCadmium 0.02 ppmChromium 0.02 ppmCo 0.02 ppmCopper 0.02 ppmMn 0.0225 ppm

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Nickel 0.02 ppmSilver 0.02 ppmZinc 0.025 ppmBa 0.02 ppmMMSICSAB-1_00007 0.2 mLBeryllium 0.02 ppmLead 0.02 ppmSr 0.025 ppmThallium 0.02 ppmV 0.02 ppmAntimony 0.02 ppmMMSICSAB-2_00006 0.2 mLB 0.05 ppmSelenium 0.05 ppmSi 0.5 ppmSn 0.1 ppm

09/01/15 (Purchased Reagent) Al 1000 ppmInorganic Ventures, Lot G2-MEB476152MCA.M6020ICS-0A_00005Ca 1000 ppmFe 1000 ppmK 1000 ppmMg 1000 ppmMo 20 ppmNa 1000 ppmTi 20 ppm

09/01/15 (Purchased Reagent) Arsenic 2 ppmInorganic Ventures, Lot G2-MEB463151.M6020ICS-0B_00006Cadmium 2 ppmChromium 2 ppmCo 2 ppmCopper 2 ppmMn 2.25 ppmNickel 2 ppmSilver 2 ppmZinc 2.5 ppm

05/01/15 (Purchased Reagent) Ba 10 ppmInorganic Ventures, Lot F2-MEB524028.MMSICSAB-1_00007Beryllium 10 ppmLead 10 ppmSr 12.5 ppmThallium 10 ppmV 10 ppm

05/01/15 (Purchased Reagent) Antimony 10 ppmInorganic Ventures, Lot G2-MEB467043.MMSICSAB-2_00006B 25 ppmSelenium 25 ppmSi 250 ppmSn 50 ppm

M6020ICS-0A_00005 Al 100 ppm100 mL 10 mL05/14/15 04/14/15MICSAX_00065 DI Water, Lot J38N82Ca 100 ppmFe 100 ppmK 100 ppmMg 100 ppm

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Mo 2 ppmNa 100 ppmTi 2 ppm

09/01/15 (Purchased Reagent) Al 1000 ppmInorganic Ventures, Lot G2-MEB476152MCA.M6020ICS-0A_00005Ca 1000 ppmFe 1000 ppmK 1000 ppmMg 1000 ppmMo 20 ppmNa 1000 ppmTi 20 ppm

MICPMSICV_00018 Antimony 0.08 mg/L250 mg/L 10 mg/L05/09/15 04/09/15MICVX_00031 2% Nitric Acid, Lot 25106

Arsenic 0.08 mg/LBeryllium 0.08 mg/LCadmium 0.08 mg/LChromium 0.08 mg/LCopper 0.08 mg/LLead 0.08 mg/LNickel 0.08 mg/LSelenium 0.08 mg/LSilver 0.08 mg/LThallium 0.08 mg/LZinc 0.08 mg/L

11/30/15 (Purchased Reagent) Antimony 2 ppmSPEX CertiPrep, Lot 7-230WL.MICPMSICV_00018Arsenic 2 ppmBeryllium 2 ppmCadmium 2 ppmChromium 2 ppmCopper 2 ppmLead 2 ppmNickel 2 ppmSelenium 2 ppmSilver 2 ppmThallium 2 ppmZinc 2 ppm

MCALSPECAREV_00005 Arsenic 0.2 ppm250 mL 10 mg/L05/01/15 04/14/15MSTD2X_00043 DI Water, Lot 1241717Beryllium 0.2 ppmCadmium 0.2 ppmChromium 0.2 ppmCopper 0.2 ppmLead 0.2 ppmNickel 0.2 ppmSelenium 0.2 ppmSilver 0.2 ppmThallium 0.2 ppmZinc 0.2 ppm

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05/01/15 (Purchased Reagent) Arsenic 5 ppmInorganic Ventures, Lot F2-MEB524026.MCALSPECAREV_00005Beryllium 5 ppmCadmium 5 ppmChromium 5 ppmCopper 5 ppmLead 5 ppmNickel 5 ppmSelenium 5 ppmSilver 5 ppmThallium 5 ppmZinc 5 ppm

05/01/15 04/14/15 250 mL MCALSPECB_00007 10 mg/L Antimony 0.2 ppmMSTD3X_00044 2% Nitric Acid, Lot 1241747

05/01/15 (Purchased Reagent) Antimony 5 ppmInorganic Ventures, Lot F2-MEB524027.MCALSPECB_00007

07/01/15 (Purchased Reagent) Al 200 ug/mLINORGANIC VENTURES, Lot H2-MEB532047MTAPITTICPMS_00020Arsenic 4 ug/mLB 100 ug/mLBa 200 ug/mLBeryllium 5 ug/mLCadmium 5 ug/mLChromium 20 ug/mLCo 50 ug/mLCopper 25 ug/mLFe 100 ug/mLLead 2 ug/mLMn 50 ug/mLNickel 50 ug/mLSelenium 1 ug/mLSilver 5 ug/mLSr 100 ug/mLThallium 5 ug/mLV 50 ug/mLZinc 50 ug/mL

12/01/15 (Purchased Reagent) Ca 5000 ug/mLINORGANIC VENTURES, Lot H2-MEB532044MTAPITTMSA_00023K 5000 ug/mLMg 5000 ug/mLNa 5000 ug/mL

12/01/15 (Purchased Reagent) Antimony 50 ug/mLInorganic Ventures, Lot H2-MEB532046MTAPITTMSC_00029Mo 100 ug/mLSi 1000 ug/mLSiO2 2140 ug/mLSn 200 ug/mLTi 100 ug/mL

SVLVstd1_00030 1,1'-Biphenyl 200 ug/mL100 mL 20 mL09/10/15 03/10/15OPLVISPKMIX1i_00037 Methanol, Lot 0000082533

1,2,4,5-Tetrachlorobenzene 200 ug/mL

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1,2,4-Trichlorobenzene 200 ug/mL1,2-Dichlorobenzene 200 ug/mL1,2-Diphenylhydrazine 200 ug/mL1,3-Dichlorobenzene 200 ug/mL1,3-Dinitrobenzene 200 ug/mL1,4-Dichlorobenzene 200 ug/mL1,4-Dioxane 200 ug/mL1-Methylnaphthalene 200 ug/mL2,2'-oxybis[1-chloropropane] 200 ug/mL2,3,4,6-Tetrachlorophenol 200 ug/mL2,4,5-Trichlorophenol 200 ug/mL2,4,6-Trichlorophenol 200 ug/mL2,4-Dichlorophenol 200 ug/mL2,4-Dimethylphenol 200 ug/mL2,4-Dinitrophenol 400 ug/mL2,4-Dinitrotoluene 200 ug/mL2,6-Dichlorophenol 200 ug/mL2,6-Dinitrotoluene 200 ug/mL2-Chloronaphthalene 200 ug/mL2-Chlorophenol 200 ug/mL2-Methylnaphthalene 200 ug/mL2-Methylphenol 200 ug/mL2-Nitroaniline 200 ug/mL2-Nitrophenol 200 ug/mL3 & 4 Methylphenol 200 ug/mL3-Nitroaniline 200 ug/mL4,6-Dinitro-2-methylphenol 400 ug/mL4-Bromophenyl phenyl ether 200 ug/mL4-Chloro-3-methylphenol 200 ug/mL4-Chloroaniline 200 ug/mL4-Chlorophenyl phenyl ether 200 ug/mL4-Methylphenol 200 ug/mL4-Nitroaniline 200 ug/mL4-Nitrophenol 400 ug/mLAcenaphthene 200 ug/mLAcenaphthylene 200 ug/mLAcetophenone 200 ug/mLAniline 200 ug/mLAnthracene 200 ug/mLAzobenzene 200 ug/mLBenzo[a]anthracene 200 ug/mLBenzo[a]pyrene 200 ug/mLBenzo[b]fluoranthene 200 ug/mLBenzo[g,h,i]perylene 200 ug/mLBenzo[k]fluoranthene 200 ug/mLBenzyl alcohol 200 ug/mLBis(2-chloroethoxy)methane 200 ug/mLBis(2-chloroethyl)ether 200 ug/mL

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Bis(2-ethylhexyl) phthalate 200 ug/mLButyl benzyl phthalate 200 ug/mLCarbazole 200 ug/mLChrysene 200 ug/mLDi-n-butyl phthalate 200 ug/mLDi-n-octyl phthalate 200 ug/mLDibenz(a,h)anthracene 200 ug/mLDibenzofuran 200 ug/mLDiethyl phthalate 200 ug/mLDimethyl phthalate 200 ug/mLFluoranthene 200 ug/mLFluorene 200 ug/mLHexachlorobenzene 200 ug/mLHexachlorobutadiene 200 ug/mLHexachlorocyclopentadiene 200 ug/mLHexachloroethane 200 ug/mLHexadecane 200 ug/mLIndeno[1,2,3-cd]pyrene 200 ug/mLIsophorone 200 ug/mLMethyl Phenols,Total 400 ug/mLn-Decane 200 ug/mLN-Nitrosodi-n-propylamine 200 ug/mLN-Nitrosodimethylamine 200 ug/mLN-Nitrosodiphenylamine 400 ug/mLn-Octadecane 200 ug/mLNaphthalene 200 ug/mLNitrobenzene 200 ug/mLPentachlorophenol 400 ug/mLPhenanthrene 200 ug/mLPhenol 200 ug/mLPyrene 200 ug/mLPyridine 200 ug/mLTotal Cresols 400 ug/mLBenzoic acid 200 ug/mLSVLVstd10_00001 10 mLIndene 200 ug/mLAtrazine 200 ug/mLSVLVstd11_00001 10 mLBenzaldehyde 200 ug/mLCaprolactam 200 ug/mL3,3'-Dichlorobenzidine 200 ug/mLSVLVstd9_00001 10 mLBenzidine 200 ug/mL

05/31/16 (Purchased Reagent) 1,1'-Biphenyl 1000 ug/mLRestek, Lot A0107399.SVLVstd1_000301,2,4,5-Tetrachlorobenzene 1000 ug/mL1,2,4-Trichlorobenzene 1000 ug/mL1,2-Dichlorobenzene 1000 ug/mL1,2-Diphenylhydrazine 1000 ug/mL1,3-Dichlorobenzene 1000 ug/mL1,3-Dinitrobenzene 1000 ug/mL1,4-Dichlorobenzene 1000 ug/mL

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1,4-Dioxane 1000 ug/mL1-Methylnaphthalene 1000 ug/mL2,2'-oxybis[1-chloropropane] 1000 ug/mL2,3,4,6-Tetrachlorophenol 1000 ug/mL2,4,5-Trichlorophenol 1000 ug/mL2,4,6-Trichlorophenol 1000 ug/mL2,4-Dichlorophenol 1000 ug/mL2,4-Dimethylphenol 1000 ug/mL2,4-Dinitrophenol 2000 ug/mL2,4-Dinitrotoluene 1000 ug/mL2,6-Dichlorophenol 1000 ug/mL2,6-Dinitrotoluene 1000 ug/mL2-Chloronaphthalene 1000 ug/mL2-Chlorophenol 1000 ug/mL2-Methylnaphthalene 1000 ug/mL2-Methylphenol 1000 ug/mL2-Nitroaniline 1000 ug/mL2-Nitrophenol 1000 ug/mL3 & 4 Methylphenol 1000 ug/mL3-Nitroaniline 1000 ug/mL4,6-Dinitro-2-methylphenol 2000 ug/mL4-Bromophenyl phenyl ether 1000 ug/mL4-Chloro-3-methylphenol 1000 ug/mL4-Chloroaniline 1000 ug/mL4-Chlorophenyl phenyl ether 1000 ug/mL4-Methylphenol 1000 ug/mL4-Nitroaniline 1000 ug/mL4-Nitrophenol 2000 ug/mLAcenaphthene 1000 ug/mLAcenaphthylene 1000 ug/mLAcetophenone 1000 ug/mLAniline 1000 ug/mLAnthracene 1000 ug/mLAzobenzene 1000 ug/mLBenzo[a]anthracene 1000 ug/mLBenzo[a]pyrene 1000 ug/mLBenzo[b]fluoranthene 1000 ug/mLBenzo[g,h,i]perylene 1000 ug/mLBenzo[k]fluoranthene 1000 ug/mLBenzyl alcohol 1000 ug/mLBis(2-chloroethoxy)methane 1000 ug/mLBis(2-chloroethyl)ether 1000 ug/mLBis(2-ethylhexyl) phthalate 1000 ug/mLButyl benzyl phthalate 1000 ug/mLCarbazole 1000 ug/mLChrysene 1000 ug/mLDi-n-butyl phthalate 1000 ug/mLDi-n-octyl phthalate 1000 ug/mL

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Dibenz(a,h)anthracene 1000 ug/mLDibenzofuran 1000 ug/mLDiethyl phthalate 1000 ug/mLDimethyl phthalate 1000 ug/mLFluoranthene 1000 ug/mLFluorene 1000 ug/mLHexachlorobenzene 1000 ug/mLHexachlorobutadiene 1000 ug/mLHexachlorocyclopentadiene 1000 ug/mLHexachloroethane 1000 ug/mLHexadecane 1000 ug/mLIndeno[1,2,3-cd]pyrene 1000 ug/mLIsophorone 1000 ug/mLMethyl Phenols,Total 2000 ug/mLn-Decane 1000 ug/mLN-Nitrosodi-n-propylamine 1000 ug/mLN-Nitrosodimethylamine 1000 ug/mLN-Nitrosodiphenylamine 2000 ug/mLn-Octadecane 1000 ug/mLNaphthalene 1000 ug/mLNitrobenzene 1000 ug/mLPentachlorophenol 2000 ug/mLPhenanthrene 1000 ug/mLPhenol 1000 ug/mLPyrene 1000 ug/mLPyridine 1000 ug/mLTotal Cresols 2000 ug/mL

06/30/16 (Purchased Reagent) Benzoic acid 2000 ug/mLRestek, Lot A0107943.SVLVstd10_00001Indene 2000 ug/mL

06/30/16 (Purchased Reagent) Atrazine 2000 ug/mLRestek, Lot A0108035.SVLVstd11_00001Benzaldehyde 2000 ug/mLCaprolactam 2000 ug/mL

07/31/16 (Purchased Reagent) 3,3'-Dichlorobenzidine 2000 ug/mLRestek, Lot A0108709.SVLVstd9_00001Benzidine 2000 ug/mL

SVLVSURRSPK_00006 2,4,6-Tribromophenol (Surr) 200 ug/mL500 mL 20 mL08/26/15 02/26/15OPQL8270SURi_00028 Methanol, Lot b#0000049909

2-Fluorobiphenyl 200 ug/mL2-Fluorophenol (Surr) 200 ug/mLNitrobenzene-d5 (Surr) 200 ug/mLPhenol-d5 (Surr) 200 ug/mLTerphenyl-d14 (Surr) 200 ug/mL

02/28/18 (Purchased Reagent) 2,4,6-Tribromophenol (Surr) 5000 ug/mLRestek, Lot A093638.SVLVSURRSPK_000062-Fluorobiphenyl 5000 ug/mL2-Fluorophenol (Surr) 5000 ug/mLNitrobenzene-d5 (Surr) 5000 ug/mLPhenol-d5 (Surr) 5000 ug/mLTerphenyl-d14 (Surr) 5000 ug/mL

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SVTAPITINTRNi_00005 1,4-Dichlorobenzene-d4 4 ug/mL1 mL 10 uL02/21/15 07/21/14SVTAPSTD0.4i_00007 MeCl2, Lot 1053215Acenaphthene-d10 4 ug/mLChrysene-d12 4 ug/mLNaphthalene-d8 4 ug/mLPerylene-d12 4 ug/mLPhenanthrene-d10 4 ug/mLBenzo[e]pyrene 0.2 ug/mLSVTAPITSTCKi_00004 5 uL2-Naphthylamine 0.2 ug/mL2,3,5,6-Tetrachlorophenol 0.2 ug/mL2,6-Dichlorophenol 0.2 ug/mL7,12-Dimethylbenz(a)anthracene 0.2 ug/mLMethyl methanesulfonate 0.2 ug/mL1,1'-Biphenyl 0.2 ug/mL1,2,4,5-Tetrachlorobenzene 0.2 ug/mL1,2,4-Trichlorobenzene 0.2 ug/mL1,2-Dichlorobenzene 0.2 ug/mL1,2-Diphenylhydrazine 0.2 ug/mL1,3-Dichlorobenzene 0.2 ug/mL1,3-Dinitrobenzene 0.2 ug/mL1,4-Dichlorobenzene 0.2 ug/mL1,4-Dioxane 0.2 ug/mL1-Methylnaphthalene 0.2 ug/mL2,2'-oxybis[1-chloropropane] 0.2 ug/mL2,3,4,6-Tetrachlorophenol 0.2 ug/mL2,4,5-Trichlorophenol 0.2 ug/mL2,4,6-Trichlorophenol 0.2 ug/mL2,4-Dichlorophenol 0.2 ug/mL2,4-Dimethylphenol 0.2 ug/mL2,4-Dinitrophenol 0.4 ug/mL2,4-Dinitrotoluene 0.2 ug/mL2,6-Dinitrotoluene 0.2 ug/mL2-Chloronaphthalene 0.2 ug/mL2-Chlorophenol 0.2 ug/mL2-Methylnaphthalene 0.2 ug/mL2-Methylphenol 0.2 ug/mL2-Nitroaniline 0.2 ug/mL2-Nitrophenol 0.2 ug/mL3-Nitroaniline 0.2 ug/mL4,6-Dinitro-2-methylphenol 0.4 ug/mL4-Bromophenyl phenyl ether 0.2 ug/mL4-Chloro-3-methylphenol 0.2 ug/mL4-Chloroaniline 0.2 ug/mL4-Chlorophenyl phenyl ether 0.2 ug/mL4-Methylphenol 0.2 ug/mL4-Nitroaniline 0.2 ug/mL4-Nitrophenol 0.4 ug/mLAcenaphthene 0.2 ug/mLAcenaphthylene 0.2 ug/mL

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Acetophenone 0.2 ug/mLAniline 0.2 ug/mLAnthracene 0.2 ug/mLBenzo[a]anthracene 0.2 ug/mLBenzo[a]pyrene 0.2 ug/mLBenzo[b]fluoranthene 0.2 ug/mLBenzo[g,h,i]perylene 0.2 ug/mLBenzo[k]fluoranthene 0.2 ug/mLBenzyl alcohol 0.2 ug/mLBis(2-chloroethoxy)methane 0.2 ug/mLBis(2-chloroethyl)ether 0.2 ug/mLBis(2-ethylhexyl) phthalate 0.2 ug/mLButyl benzyl phthalate 0.2 ug/mLCarbazole 0.2 ug/mLChrysene 0.2 ug/mLDi-n-butyl phthalate 0.2 ug/mLDi-n-octyl phthalate 0.2 ug/mLDibenz(a,h)anthracene 0.2 ug/mLDibenzofuran 0.2 ug/mLDiethyl phthalate 0.2 ug/mLDimethyl phthalate 0.2 ug/mLFluoranthene 0.2 ug/mLFluorene 0.2 ug/mLHexachlorobenzene 0.2 ug/mLHexachlorobutadiene 0.2 ug/mLHexachlorocyclopentadiene 0.2 ug/mLHexachloroethane 0.2 ug/mLHexadecane 0.2 ug/mLIndeno[1,2,3-cd]pyrene 0.2 ug/mLIsophorone 0.2 ug/mLn-Decane 0.2 ug/mLN-Nitrosodi-n-propylamine 0.2 ug/mLN-Nitrosodimethylamine 0.2 ug/mLn-Octadecane 0.2 ug/mLNaphthalene 0.2 ug/mLNitrobenzene 0.2 ug/mLPentachlorophenol 0.4 ug/mLPhenanthrene 0.2 ug/mLPhenol 0.2 ug/mLPyrene 0.2 ug/mLPyridine 0.2 ug/mL3,3'-Dichlorobenzidine 0.2 ug/mLAtrazine 0.2 ug/mLBenzidine 0.2 ug/mLCaprolactam 0.2 ug/mLN-Nitrosodiphenylamine 0.2 ug/mLBenzaldehyde 0.2 ug/mLBenzoic acid 0.2 ug/mL

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Indene 0.2 ug/mL2,4,6-Tribromophenol (Surr) 0.2 ug/mL2-Fluorobiphenyl 0.2 ug/mL2-Fluorophenol (Surr) 0.2 ug/mLNitrobenzene-d5 (Surr) 0.2 ug/mLPhenol-d5 (Surr) 0.2 ug/mLTerphenyl-d14 (Surr) 0.2 ug/mLN-Nitrosopyrrolidine 0.2 ug/mL

SVLVIntstd_00007 1,4-Dichlorobenzene-d4 400 ug/mL25 mL 5000 uL05/07/15 05/07/14.SVTAPITINTRNi_00005 MeCl2, Lot 1000447Acenaphthene-d10 400 ug/mLChrysene-d12 400 ug/mLNaphthalene-d8 400 ug/mLPerylene-d12 400 ug/mLPhenanthrene-d10 400 ug/mL

02/28/18 (Purchased Reagent) 1,4-Dichlorobenzene-d4 2000 ug/mLRestek, Lot A093676..SVLVIntstd_00007Acenaphthene-d10 2000 ug/mLChrysene-d12 2000 ug/mLNaphthalene-d8 2000 ug/mLPerylene-d12 2000 ug/mLPhenanthrene-d10 2000 ug/mL

sv benzoepyre_00001 Benzo[e]pyrene 40 ug/mL20 mL 800 uL02/21/15 07/21/14.SVTAPITSTCKi_00004 MeCl2, Lot 10532152-Naphthylamine 40 ug/mLSV2NAPAMINEs_00002 800 uL2,3,5,6-Tetrachlorophenol 40 ug/mLSVLVlist12_00002 800 uL2,6-Dichlorophenol 40 ug/mL7,12-Dimethylbenz(a)anthracene 40 ug/mLMethyl methanesulfonate 40 ug/mL1,1'-Biphenyl 40 ug/mLSVLVstd1_00026 800 uL1,2,4,5-Tetrachlorobenzene 40 ug/mL1,2,4-Trichlorobenzene 40 ug/mL1,2-Dichlorobenzene 40 ug/mL1,2-Diphenylhydrazine 40 ug/mL1,3-Dichlorobenzene 40 ug/mL1,3-Dinitrobenzene 40 ug/mL1,4-Dichlorobenzene 40 ug/mL1,4-Dioxane 40 ug/mL1-Methylnaphthalene 40 ug/mL2,2'-oxybis[1-chloropropane] 40 ug/mL2,3,4,6-Tetrachlorophenol 40 ug/mL2,4,5-Trichlorophenol 40 ug/mL2,4,6-Trichlorophenol 40 ug/mL2,4-Dichlorophenol 40 ug/mL2,4-Dimethylphenol 40 ug/mL2,4-Dinitrophenol 80 ug/mL2,4-Dinitrotoluene 40 ug/mL2,6-Dinitrotoluene 40 ug/mL2-Chloronaphthalene 40 ug/mL2-Chlorophenol 40 ug/mL2-Methylnaphthalene 40 ug/mL

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2-Methylphenol 40 ug/mL2-Nitroaniline 40 ug/mL2-Nitrophenol 40 ug/mL3-Nitroaniline 40 ug/mL4,6-Dinitro-2-methylphenol 80 ug/mL4-Bromophenyl phenyl ether 40 ug/mL4-Chloro-3-methylphenol 40 ug/mL4-Chloroaniline 40 ug/mL4-Chlorophenyl phenyl ether 40 ug/mL4-Methylphenol 40 ug/mL4-Nitroaniline 40 ug/mL4-Nitrophenol 80 ug/mLAcenaphthene 40 ug/mLAcenaphthylene 40 ug/mLAcetophenone 40 ug/mLAniline 40 ug/mLAnthracene 40 ug/mLBenzo[a]anthracene 40 ug/mLBenzo[a]pyrene 40 ug/mLBenzo[b]fluoranthene 40 ug/mLBenzo[g,h,i]perylene 40 ug/mLBenzo[k]fluoranthene 40 ug/mLBenzyl alcohol 40 ug/mLBis(2-chloroethoxy)methane 40 ug/mLBis(2-chloroethyl)ether 40 ug/mLBis(2-ethylhexyl) phthalate 40 ug/mLButyl benzyl phthalate 40 ug/mLCarbazole 40 ug/mLChrysene 40 ug/mLDi-n-butyl phthalate 40 ug/mLDi-n-octyl phthalate 40 ug/mLDibenz(a,h)anthracene 40 ug/mLDibenzofuran 40 ug/mLDiethyl phthalate 40 ug/mLDimethyl phthalate 40 ug/mLFluoranthene 40 ug/mLFluorene 40 ug/mLHexachlorobenzene 40 ug/mLHexachlorobutadiene 40 ug/mLHexachlorocyclopentadiene 40 ug/mLHexachloroethane 40 ug/mLHexadecane 40 ug/mLIndeno[1,2,3-cd]pyrene 40 ug/mLIsophorone 40 ug/mLn-Decane 40 ug/mLN-Nitrosodi-n-propylamine 40 ug/mLN-Nitrosodimethylamine 40 ug/mLn-Octadecane 40 ug/mL

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Naphthalene 40 ug/mLNitrobenzene 40 ug/mLPentachlorophenol 80 ug/mLPhenanthrene 40 ug/mLPhenol 40 ug/mLPyrene 40 ug/mLPyridine 40 ug/mL3,3'-Dichlorobenzidine 40 ug/mLSVLVstd2_00012 400 uLAtrazine 40 ug/mLBenzidine 40 ug/mLCaprolactam 40 ug/mLN-Nitrosodiphenylamine 40 ug/mLSVLVstd5(7)_00001 400 uLBenzaldehyde 40 ug/mLSVLVstd8_00003 400 uLBenzoic acid 40 ug/mLIndene 40 ug/mL2,4,6-Tribromophenol (Surr) 40 ug/mLSVLVSURRSPK_00003 160 uL2-Fluorobiphenyl 40 ug/mL2-Fluorophenol (Surr) 40 ug/mLNitrobenzene-d5 (Surr) 40 ug/mLPhenol-d5 (Surr) 40 ug/mLTerphenyl-d14 (Surr) 40 ug/mL

SVNNITROPYROs_00015 800 uL N-Nitrosopyrrolidine 40 ug/mL10/03/18 (Purchased Reagent) Benzo[e]pyrene 1000 ug/mLAbsolute, Lot 100313..sv benzoepyre_0000106/30/17 (Purchased Reagent) 2-Naphthylamine 1000 ug/mLUltra Scientific, Lot Ck-1617..SV2NAPAMINEs_0000204/30/15 (Purchased Reagent) 2,3,5,6-Tetrachlorophenol 1000 ug/mLRestek, Lot A0102912..SVLVlist12_00002

2,6-Dichlorophenol 1000 ug/mL7,12-Dimethylbenz(a)anthracene 1000 ug/mLMethyl methanesulfonate 1000 ug/mL

08/31/15 (Purchased Reagent) 1,1'-Biphenyl 1000 ug/mLRestek, Lot A0101615..SVLVstd1_000261,2,4,5-Tetrachlorobenzene 1000 ug/mL1,2,4-Trichlorobenzene 1000 ug/mL1,2-Dichlorobenzene 1000 ug/mL1,2-Diphenylhydrazine 1000 ug/mL1,3-Dichlorobenzene 1000 ug/mL1,3-Dinitrobenzene 1000 ug/mL1,4-Dichlorobenzene 1000 ug/mL1,4-Dioxane 1000 ug/mL1-Methylnaphthalene 1000 ug/mL2,2'-oxybis[1-chloropropane] 1000 ug/mL2,3,4,6-Tetrachlorophenol 1000 ug/mL2,4,5-Trichlorophenol 1000 ug/mL2,4,6-Trichlorophenol 1000 ug/mL2,4-Dichlorophenol 1000 ug/mL2,4-Dimethylphenol 1000 ug/mL2,4-Dinitrophenol 2000 ug/mL2,4-Dinitrotoluene 1000 ug/mL2,6-Dinitrotoluene 1000 ug/mL2-Chloronaphthalene 1000 ug/mL

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2-Chlorophenol 1000 ug/mL2-Methylnaphthalene 1000 ug/mL2-Methylphenol 1000 ug/mL2-Nitroaniline 1000 ug/mL2-Nitrophenol 1000 ug/mL3-Nitroaniline 1000 ug/mL4,6-Dinitro-2-methylphenol 2000 ug/mL4-Bromophenyl phenyl ether 1000 ug/mL4-Chloro-3-methylphenol 1000 ug/mL4-Chloroaniline 1000 ug/mL4-Chlorophenyl phenyl ether 1000 ug/mL4-Methylphenol 1000 ug/mL4-Nitroaniline 1000 ug/mL4-Nitrophenol 2000 ug/mLAcenaphthene 1000 ug/mLAcenaphthylene 1000 ug/mLAcetophenone 1000 ug/mLAniline 1000 ug/mLAnthracene 1000 ug/mLBenzo[a]anthracene 1000 ug/mLBenzo[a]pyrene 1000 ug/mLBenzo[b]fluoranthene 1000 ug/mLBenzo[g,h,i]perylene 1000 ug/mLBenzo[k]fluoranthene 1000 ug/mLBenzyl alcohol 1000 ug/mLBis(2-chloroethoxy)methane 1000 ug/mLBis(2-chloroethyl)ether 1000 ug/mLBis(2-ethylhexyl) phthalate 1000 ug/mLButyl benzyl phthalate 1000 ug/mLCarbazole 1000 ug/mLChrysene 1000 ug/mLDi-n-butyl phthalate 1000 ug/mLDi-n-octyl phthalate 1000 ug/mLDibenz(a,h)anthracene 1000 ug/mLDibenzofuran 1000 ug/mLDiethyl phthalate 1000 ug/mLDimethyl phthalate 1000 ug/mLFluoranthene 1000 ug/mLFluorene 1000 ug/mLHexachlorobenzene 1000 ug/mLHexachlorobutadiene 1000 ug/mLHexachlorocyclopentadiene 1000 ug/mLHexachloroethane 1000 ug/mLHexadecane 1000 ug/mLIndeno[1,2,3-cd]pyrene 1000 ug/mLIsophorone 1000 ug/mLn-Decane 1000 ug/mLN-Nitrosodi-n-propylamine 1000 ug/mL

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N-Nitrosodimethylamine 1000 ug/mLn-Octadecane 1000 ug/mLNaphthalene 1000 ug/mLNitrobenzene 1000 ug/mLPentachlorophenol 2000 ug/mLPhenanthrene 1000 ug/mLPhenol 1000 ug/mLPyrene 1000 ug/mLPyridine 1000 ug/mL

07/31/15 (Purchased Reagent) 3,3'-Dichlorobenzidine 2000 ug/mLRestek, Lot A0100824..SVLVstd2_00012Atrazine 2000 ug/mLBenzidine 2000 ug/mLCaprolactam 2000 ug/mL

02/28/17 (Purchased Reagent) N-Nitrosodiphenylamine 2000 ug/mLRestek, Lot A0101573..SVLVstd5(7)_0000105/31/15 (Purchased Reagent) Benzaldehyde 2000 ug/mLRestek, Lot A0103145..SVLVstd8_00003

Benzoic acid 2000 ug/mLIndene 2000 ug/mL

02/28/18 (Purchased Reagent) 2,4,6-Tribromophenol (Surr) 5000 ug/mLRestek, Lot A093638..SVLVSURRSPK_000032-Fluorobiphenyl 5000 ug/mL2-Fluorophenol (Surr) 5000 ug/mLNitrobenzene-d5 (Surr) 5000 ug/mLPhenol-d5 (Surr) 5000 ug/mLTerphenyl-d14 (Surr) 5000 ug/mL

06/05/17 (Purchased Reagent) N-Nitrosopyrrolidine 1000 ug/mLabsolute, Lot 060514..SVNNITROPYROs_00015

SVTAPITINTRNi_00005 1,4-Dichlorobenzene-d4 4 ug/mL1 mL 10 uL02/06/15 01/31/15SVTAPSTD10i_00088 MeCl2, Lot 1417620Acenaphthene-d10 4 ug/mLChrysene-d12 4 ug/mLNaphthalene-d8 4 ug/mLPerylene-d12 4 ug/mLPhenanthrene-d10 4 ug/mLBenzo[e]pyrene 5 ug/mLSVTAPITSTCKi_00004 125 uL2-Naphthylamine 5 ug/mL2,3,5,6-Tetrachlorophenol 5 ug/mL2,6-Dichlorophenol 5 ug/mL7,12-Dimethylbenz(a)anthracene 5 ug/mLMethyl methanesulfonate 5 ug/mL1,1'-Biphenyl 5 ug/mL1,2,4,5-Tetrachlorobenzene 5 ug/mL1,2,4-Trichlorobenzene 5 ug/mL1,2-Dichlorobenzene 5 ug/mL1,2-Diphenylhydrazine 5 ug/mL1,3-Dichlorobenzene 5 ug/mL1,3-Dinitrobenzene 5 ug/mL1,4-Dichlorobenzene 5 ug/mL1,4-Dioxane 5 ug/mL1-Methylnaphthalene 5 ug/mL2,2'-oxybis[1-chloropropane] 5 ug/mL

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2,3,4,6-Tetrachlorophenol 5 ug/mL2,4,5-Trichlorophenol 5 ug/mL2,4,6-Trichlorophenol 5 ug/mL2,4-Dichlorophenol 5 ug/mL2,4-Dimethylphenol 5 ug/mL2,4-Dinitrophenol 10 ug/mL2,4-Dinitrotoluene 5 ug/mL2,6-Dinitrotoluene 5 ug/mL2-Chloronaphthalene 5 ug/mL2-Chlorophenol 5 ug/mL2-Methylnaphthalene 5 ug/mL2-Methylphenol 5 ug/mL2-Nitroaniline 5 ug/mL2-Nitrophenol 5 ug/mL3-Nitroaniline 5 ug/mL4,6-Dinitro-2-methylphenol 10 ug/mL4-Bromophenyl phenyl ether 5 ug/mL4-Chloro-3-methylphenol 5 ug/mL4-Chloroaniline 5 ug/mL4-Chlorophenyl phenyl ether 5 ug/mL4-Methylphenol 5 ug/mL4-Nitroaniline 5 ug/mL4-Nitrophenol 10 ug/mLAcenaphthene 5 ug/mLAcenaphthylene 5 ug/mLAcetophenone 5 ug/mLAniline 5 ug/mLAnthracene 5 ug/mLBenzo[a]anthracene 5 ug/mLBenzo[a]pyrene 5 ug/mLBenzo[b]fluoranthene 5 ug/mLBenzo[g,h,i]perylene 5 ug/mLBenzo[k]fluoranthene 5 ug/mLBenzyl alcohol 5 ug/mLBis(2-chloroethoxy)methane 5 ug/mLBis(2-chloroethyl)ether 5 ug/mLBis(2-ethylhexyl) phthalate 5 ug/mLButyl benzyl phthalate 5 ug/mLCarbazole 5 ug/mLChrysene 5 ug/mLDi-n-butyl phthalate 5 ug/mLDi-n-octyl phthalate 5 ug/mLDibenz(a,h)anthracene 5 ug/mLDibenzofuran 5 ug/mLDiethyl phthalate 5 ug/mLDimethyl phthalate 5 ug/mLFluoranthene 5 ug/mLFluorene 5 ug/mL

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Hexachlorobenzene 5 ug/mLHexachlorobutadiene 5 ug/mLHexachlorocyclopentadiene 5 ug/mLHexachloroethane 5 ug/mLHexadecane 5 ug/mLIndeno[1,2,3-cd]pyrene 5 ug/mLIsophorone 5 ug/mLn-Decane 5 ug/mLN-Nitrosodi-n-propylamine 5 ug/mLN-Nitrosodimethylamine 5 ug/mLn-Octadecane 5 ug/mLNaphthalene 5 ug/mLNitrobenzene 5 ug/mLPentachlorophenol 10 ug/mLPhenanthrene 5 ug/mLPhenol 5 ug/mLPyrene 5 ug/mLPyridine 5 ug/mL3,3'-Dichlorobenzidine 5 ug/mLAtrazine 5 ug/mLBenzidine 5 ug/mLCaprolactam 5 ug/mLN-Nitrosodiphenylamine 5 ug/mLBenzaldehyde 5 ug/mLBenzoic acid 5 ug/mLIndene 5 ug/mL2,4,6-Tribromophenol (Surr) 5 ug/mL2-Fluorobiphenyl 5 ug/mL2-Fluorophenol (Surr) 5 ug/mLNitrobenzene-d5 (Surr) 5 ug/mLPhenol-d5 (Surr) 5 ug/mLTerphenyl-d14 (Surr) 5 ug/mLN-Nitrosopyrrolidine 5 ug/mL

SVLVIntstd_00007 1,4-Dichlorobenzene-d4 400 ug/mL25 mL 5000 uL05/07/15 05/07/14.SVTAPITINTRNi_00005 MeCl2, Lot 1000447Acenaphthene-d10 400 ug/mLChrysene-d12 400 ug/mLNaphthalene-d8 400 ug/mLPerylene-d12 400 ug/mLPhenanthrene-d10 400 ug/mL

02/28/18 (Purchased Reagent) 1,4-Dichlorobenzene-d4 2000 ug/mLRestek, Lot A093676..SVLVIntstd_00007Acenaphthene-d10 2000 ug/mLChrysene-d12 2000 ug/mLNaphthalene-d8 2000 ug/mLPerylene-d12 2000 ug/mLPhenanthrene-d10 2000 ug/mL

sv benzoepyre_00001 Benzo[e]pyrene 40 ug/mL20 mL 800 uL02/21/15 07/21/14.SVTAPITSTCKi_00004 MeCl2, Lot 10532152-Naphthylamine 40 ug/mLSV2NAPAMINEs_00002 800 uL2,3,5,6-Tetrachlorophenol 40 ug/mLSVLVlist12_00002 800 uL

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2,6-Dichlorophenol 40 ug/mL7,12-Dimethylbenz(a)anthracene 40 ug/mLMethyl methanesulfonate 40 ug/mL1,1'-Biphenyl 40 ug/mLSVLVstd1_00026 800 uL1,2,4,5-Tetrachlorobenzene 40 ug/mL1,2,4-Trichlorobenzene 40 ug/mL1,2-Dichlorobenzene 40 ug/mL1,2-Diphenylhydrazine 40 ug/mL1,3-Dichlorobenzene 40 ug/mL1,3-Dinitrobenzene 40 ug/mL1,4-Dichlorobenzene 40 ug/mL1,4-Dioxane 40 ug/mL1-Methylnaphthalene 40 ug/mL2,2'-oxybis[1-chloropropane] 40 ug/mL2,3,4,6-Tetrachlorophenol 40 ug/mL2,4,5-Trichlorophenol 40 ug/mL2,4,6-Trichlorophenol 40 ug/mL2,4-Dichlorophenol 40 ug/mL2,4-Dimethylphenol 40 ug/mL2,4-Dinitrophenol 80 ug/mL2,4-Dinitrotoluene 40 ug/mL2,6-Dinitrotoluene 40 ug/mL2-Chloronaphthalene 40 ug/mL2-Chlorophenol 40 ug/mL2-Methylnaphthalene 40 ug/mL2-Methylphenol 40 ug/mL2-Nitroaniline 40 ug/mL2-Nitrophenol 40 ug/mL3-Nitroaniline 40 ug/mL4,6-Dinitro-2-methylphenol 80 ug/mL4-Bromophenyl phenyl ether 40 ug/mL4-Chloro-3-methylphenol 40 ug/mL4-Chloroaniline 40 ug/mL4-Chlorophenyl phenyl ether 40 ug/mL4-Methylphenol 40 ug/mL4-Nitroaniline 40 ug/mL4-Nitrophenol 80 ug/mLAcenaphthene 40 ug/mLAcenaphthylene 40 ug/mLAcetophenone 40 ug/mLAniline 40 ug/mLAnthracene 40 ug/mLBenzo[a]anthracene 40 ug/mLBenzo[a]pyrene 40 ug/mLBenzo[b]fluoranthene 40 ug/mLBenzo[g,h,i]perylene 40 ug/mLBenzo[k]fluoranthene 40 ug/mLBenzyl alcohol 40 ug/mL

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Bis(2-chloroethoxy)methane 40 ug/mLBis(2-chloroethyl)ether 40 ug/mLBis(2-ethylhexyl) phthalate 40 ug/mLButyl benzyl phthalate 40 ug/mLCarbazole 40 ug/mLChrysene 40 ug/mLDi-n-butyl phthalate 40 ug/mLDi-n-octyl phthalate 40 ug/mLDibenz(a,h)anthracene 40 ug/mLDibenzofuran 40 ug/mLDiethyl phthalate 40 ug/mLDimethyl phthalate 40 ug/mLFluoranthene 40 ug/mLFluorene 40 ug/mLHexachlorobenzene 40 ug/mLHexachlorobutadiene 40 ug/mLHe