polyaspartics –on the way to new markets - pda...
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Business Unit Coatings Adhesives & Specialties
Polyaspartics – On the way to new markets
Thomas Bäker
Brühl, November 17th – 18th 2009
-Conference
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Business Unit Coatings Adhesives & Specialties
Agenda
1. Basic chemistry and benefits of Polyaspartics
2. Case study protective coatings ‚Bayer Media Facade‘
3. Polyaspartic coatings for wind turbines
4. Recent developments
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Business Unit Coatings Adhesives & Specialties
O
O
O
O
R'
R'O
O
O
O
R'
R'
NH
XNH
Structure of aspartics (generic)
Basic chemistry of aspartics
- Aspartics are sterically hindered, secondary diamines
- The reactivity of the amine group towards polyisocyanates can be
controlled by the variation of the rest X
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Business Unit Coatings Adhesives & Specialties
Product Solid content
Equivalent weight
Viscosity mPas
Reactivity
Desmophen NH 1520 100% 290 1500 low Desmophen NH 1420 100% 276 1500 mid Desmophen NH 1220 100% 234 100 high
Aspartics with different reactivity
- Main difference of the products is the reactivity towards polyisocyanates
- A wide range of drying time and potlife is possible
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Business Unit Coatings Adhesives & Specialties
Adjustment of reactivity by blending of aspartics
0
1
2
3
4
5
6
7
8
9
0,001 0,01 0,1 1 10
Potlife / h
Dry-
to-h
andl
e* /
h
* at 20°C / 50% rel. humidity
NH 1220
NH 1220NH 1420 (1:1) NH 1420
NH 1520NH 1420 (1:1)
NH 1520
crosslinked with Desmodur N 3600
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Business Unit Coatings Adhesives & Specialties
Reaction of aspartic with aliphatic polyisocyanate
OO
O
O
N
R1
R2+ R3
N C O R3OO
O
O
R1 NC
NH
R2
O
H
Aspartic ‘Polyaspartic’
R1
R1
Aliphatic polyisocyanate
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Business Unit Coatings Adhesives & Specialties
Suitable aliphatic polyisocyanates (examples)
Polyisocyanate Solid content [%] Viscosity @ 23°C NCO- content [%] Functionality
100 700 23,7 3,1
100 1200 23 3,1
90 / BA 500 19,6 3,5
Desmodur N 75 75 / BA 170 16,5 3,8
[mPas]
Desmodur N 3900
Desmodur N 3600
Desmodur N 3390
Functionality of the polyisocyanate should be > 3
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Business Unit Coatings Adhesives & Specialties
Advantages of polyaspartics
- Fast cure even at ambient temperature translates into a faster painting process and / or to faster return to service
- High film build makes it possible to reduce the number of coats in a paint system while maintaining the same overall thickness
- The improved productivity helps to reduce the overall cost of the painting process
- Ultra high solids to No-VOC possible
- Durability on the high level of aliphatic 2K-PUR topcoats
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Business Unit Coatings Adhesives & Specialties
Case Study Protective Coatings
Bayer Media Facade
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Business Unit Coatings Adhesives & Specialties
• Substrate: Steel with rust or old coating, about 30.000 m³
• Surface preparation with shot blasting, Sa 2 ½
• Primer: MC PUR zinc-rich, 80 µm
• Topcoat: Polyaspartic, 140 µm
Case Study Protective Coatings
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Business Unit Coatings Adhesives & Specialties
Case Study Protective Coatings
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Business Unit Coatings Adhesives & Specialties
Polyaspartic Coatings for wind turbines
1. Tubular metal steel base tower
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Business Unit Coatings Adhesives & Specialties
Polyaspartic Coatings for wind turbines
Depending on the WPG location different corrosion categories* are required:
Category C3: Urban and industrial atmospherewith moderate pollution.
Category C5: Coastal and offshore areas with high salinity.
* according to ISO 12944
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Business Unit Coatings Adhesives & Specialties
Productivity and cost efficiency
*DTM = direct to metal
2K PUR topcoat
Primer
DTM polyaspartic
coating
Industrial coating: Substitution of the primer by a DTM-polyaspartic Category C3 coating
Corrosion protection: Substitution of the intermediate coat by polyaspartic Category C5 coating
2K PUR topcoat
Intermediate
Primer Primer
Polyaspartic
topcoat
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Business Unit Coatings Adhesives & Specialties
Polyaspartic Coatings for wind turbines
2. Wind turbine blades 1. Tubular metal steel base tower
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Business Unit Coatings Adhesives & Specialties
Polyaspartic coatings for wind turbine blades
Polyaspartic gelcoat
Polyaspartic putty/pore filler, primer and topcoat
GFR EP- composite
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Business Unit Coatings Adhesives & Specialties
Polyaspartic coatings for wind turbines
Main Driving Force: Increased application efficiency
Benefits for blade production:
Example: Polyaspartic putty and pore filler
Properties:
• Ultra high solid / solvent free
• Fast drying time Sandability: after 3-4 h @RT, Overcoatibility with topcoat: after 1-2 h @RT
• Consistency :Adjustable from low viscous for paint brush application up to liquid putty- or high viscous filler consistency
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Business Unit Coatings Adhesives & Specialties
Recent developments for DTM- applications
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Business Unit Coatings Adhesives & Specialties
Recent developments for DTM applications
- DTM (direct-to-metal) applications are ideal for polyaspartics
2K PUR topcoat
Primer
DTM polyaspartic
coating
- Adhesion on pretreated metals (e.g. shot blasted) is typically excellent
- Adhesion on substrates like cold rolled steel or aluminum is often poor and
has been a limitation so far
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Business Unit Coatings Adhesives & Specialties
Ways to improve adhesion
- Adhesion to metals can be improved by silanes
- First approach has been to use commercial silanes as an additive
together with polyaspartics, but no improvement in adhesion has been
found
- Second approach has been to find a way to incorporate the silane
functionality into the polymer matrix
- As a result a polyisocyanate with silane functionality has been developed
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Business Unit Coatings Adhesives & Specialties
Polyisocyanate with improved DTM-adhesion
- HDI-based polyisocyanate with allophanate structure
- Solids 100%, NCO-content approx. 16%, viscosity approx. 1300mPas
- Every molecule has beside the isocyantegroups a silane functionality
Desmodur XP 2714 (Idealized structure)
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Business Unit Coatings Adhesives & Specialties
Adhesion testing
- Adhesion on shot blasted steel (reference), cold rolled steel, aluminum and
phosphated steel has been tested
- A cross-cut test according to ISO 2409 test has been used to test the
adhesion, Ranking from 0 = no delamination to 5 = complete delamination
- The adhesion testing has been distinguished between ‚dry‘ and ‚wet‘
adhesion
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Business Unit Coatings Adhesives & Specialties
Dry adhesion on various substrates
‚Dry adhesion‘ = Adhesion test after storage of the coated
substrates for 7d at 23°C/50% r.H.
Cross-cut test according to ISO 2409 with 0 = no delamination,
5 = complete delamination
0
1
2
3
4
5
Cla
ssifi
catio
n
Shot blastedsteel
Cold rolledsteel
Aluminium Phosphatedsteel
Standard PIC Silanemodified PIC
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Business Unit Coatings Adhesives & Specialties
Wet adhesion on various substrates
‚Wet adhesion‘ = adhesion test after 7d at 23°C / 50% r.H. +
additional 14 d at 40°C 100% r.H. + 24h recovery
Cross-cut test according to ISO 2409 with 0 = no delamination,
5 = complete delamination
0
1
2
3
4
5
Cla
ssifi
catio
n
Shot blastedsteel
Cold rolledsteel
Aluminium Phosphatedsteel
Standard PIC Silanemodified PIC
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Business Unit Coatings Adhesives & Specialties
Drying profile silane modified polyisocyanate
141s148 sPendulum hardness (Koenig) after 7d
approx.4h 30minapprox.2hDry-to-handle at 23°C / 50% r.H.
approx.60minapprox.50minDrying time tack free at 23°C / 50% r.H..
approx. 2happrox.2h 30minPotlife
Desmodur XP 2714 (silane modified)
Desmodur N 3600(Standard)
- Dry-to-handle time becomes longer with the silane modified polyisocyanate
- Can be adjusted by the use of a higher reactive aspartic type or suitable catalyst
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Business Unit Coatings Adhesives & Specialties
Summary
Polyaspartics are characterized by:
§ Ultra low VOC
§ Fast drying
§ High film build
§ Increased productivity
Recent developments have shown that the direct-to-metal adhesion
can be improved by a silane modified polyisocyanate
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Business Unit Coatings Adhesives & Specialties