polycarbonate-blends in...
TRANSCRIPT
![Page 1: Polycarbonate-Blends in Automotivefiles.buyplas.com/content/plaslib/2017-04/14921421945812.pdfGreater Noida, India Guangzhou, China BMS facilities Global: 7 sites Page 6. Product overview](https://reader033.vdocuments.net/reader033/viewer/2022050117/5f4df316ddfacb07185f8280/html5/thumbnails/1.jpg)
Polycarbonate-Blends in Automotive
![Page 2: Polycarbonate-Blends in Automotivefiles.buyplas.com/content/plaslib/2017-04/14921421945812.pdfGreater Noida, India Guangzhou, China BMS facilities Global: 7 sites Page 6. Product overview](https://reader033.vdocuments.net/reader033/viewer/2022050117/5f4df316ddfacb07185f8280/html5/thumbnails/2.jpg)
Agenda Product Portfolio
Color Competence
Interior Application
Exterior Application
Lighting Application
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Polycarbonate and its Blends Outstanding Combination of Properties
TransparencyGlass like: 88-90 % in 2 mm thickness
Heat resistantTg ~ 150 °C (DSC)Vicat (ISO 306) ~ 145 °C
Toughnessnotched impact resistance: (IZOD ISO180A, 23 °C, 3.2 mm)60-90 kJ/m²
High flame retardanceUL94 V-0,V2, HB …Glow wire ≥ 850 °C
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Products
PC/ABS-BlendsPolycarbonate / Acrylonitrile-Butadiene-Styrene copolymer
PC/Polyester-BlendsPBT – Polybutylene terephthalatePET – Polyethylene terephthalate
PCPolycarbonate
PCHigh Heat Polycarbonate
high transparency, high toughness, high heat resistance, high flame retardance, good electrical properties
high transparency, high toughness, tailor-made Vicat up to 205 °C, good electrical properties
high toughness even at low temperatures, high heat resistance, good paint ability, good flowability / good processing behavior
good resistance to chemicals, high toughness even at low temperatures, high heat resistance, good paint ability
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Makrolon®
Nameplate Capacity Year End 2010
Antwerp, Belgium 240 kt
Uerdingen, Germany 330 kt
Shanghai, China 200 kt
(+ 300 kt 2014 – 2016)
Map Ta Phut,Thailand 270 kt
Baytown, USA 260 kt
BMS facilitiesTotal: 1,300 kt
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Polycarbonates and BlendsCompounding Network & Plant Overview 2010
Newark (OH), USA
Uerdingen, Germany
Map Ta Phut, Thailand
Caojing, ChinaFilago, Italy
Greater Noida, IndiaGuangzhou, China
BMS facilitiesGlobal: 7 sites
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Product overview Makrolon® automotive
Standardgrades
LEDgrades
Translucentcolors
M 2207M 2407M 2607M 2807
M LED2245M LED2445
Bezelgrades
ALgrades
M AL2447M AL2647
M1260M2205M2405
Opaque gradesTransparent grades
Signalcolors
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Automotive Glazing
AX2675AG2677
Reflective White
RW2405RW2407
ThermalConductive
TC8010TC8030
Automotive eXterior
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Product overview Apec® automotive
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Easy flow, easy release 1795 18951695 2095 1)
173 183158 203Vicat – Softening Temp. [°C]
1) Not available in crystal clear (551022)
2) AMECA approval
Easy flow, easy release + UV stabilized 1897 2) 20971697 1797
Basic grade + UV stabilized 1703 2) 1803 2)1603 2)
RW1795RW1697Easy flow, reflective white
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Product OverviewStandard Grades – Bayblend® T
MFgrades
GFgrades
T95 MFT90 MF-20
T88 GF-10T88 GF-20T88 GF-30
Specialgrades
XFgrades
T50 XF T65 XFT85 XF
FR gradesStandard grades
* New development
HGgrades
T65HG*T85HG*
PGgrades
T45PG
Weatherablegrades
W85HIW85XF
LGX300
XGgrades
T80XGT90XG*
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Product OverviewMakroblend® automotive
PC/PBT PC/PET
KU2-7912KU2-7912/4KU2-7915S 7916
AR205
Mineral ReinforcedStandard grades
UT 3905 / 07UT 6005 / 07UT 6405 SG
KU2-7609
PC/PBT PC/PET
UT 235MGR 235M
GF
UT4045 G
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Agenda Product Portfolio
Color Competence
Interior Application
Exterior Application
Lighting Application
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Color Competence World Map: Colors can be developed in several sites close to customers
Newark (OH), USA
Map Ta Phut, Thailand
Caojing, ChinaFilago, Italy
Greater Noida, India Guangzhou, China
Once a color is developed, it can be transferred in all the regions within a shorttime
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Classic Colors: ROYGBV
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Classic Colors: Translucency
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Color effects: Absorbing and Reemitting Light
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Color effects: Metallic and Sparkle
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Beyond visible propertiesRole of UV : Light fastness
ASTM G26ASTM G151ASTM G155DIN EN ISO 4892 - 2SAE J2412 (J1885)SAE J2527 (J1960)VDA 75202
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Beyond visible properties: Role of UV and IR
Absorption optimization
Heat reduction & protection: for glazing and safety goggle/shield
Heat generating:for laser marking/welding
Transmission optimization
Free transmission IR wavelenght: for data transfer and night vision
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Agenda Product Portfolio
Color Competence
Interior Application
Exterior Application
Lighting Application
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Bayblend® T grades, non-reinforced
Basic Properties
• Excellent notched and multiaxial impact strength, even at low temperatures
• Excellent processing behavior and finished part accuracy
• Amorphous material, nearly constant E-modulus over relevant temperature range � excellent dimensional stability
• Excellent surface finishing properties for painting, foaming and skinning, typically without surface activation or primering
• Low quantitative emissions (VOC) and very competitive odor level
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Emission and Smell Behavior
Emissions according to VDA 277Automotive Grades: Bayblend®
Test plates molded under recommended conditions
µg C/g
Bayblend ® T65 XF < 20(Vicat B/120: 120 °C)
Bayblend ® T85 XF < 20(Vicat B/120: 131 °C)
Limit max. 50 (30)VW (Audi, Volvo)
Smell behavior ≤ 3 (VDA 270)
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Bayblend® T65 XF / T85 XF
Interior trim parts, e.g.• Safety parts• Painted parts• Skinned parts
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Bayblend® HG Generation
� New specialty product generation (T65 HG and T85 HG) with the same overall property profile compared to Bayblend XF, including in particular low-temperature ductility, low-emission behavior and paintability.
� New products are especially designed to add value by
� Processing-stable high gloss on unpainted surfaces
� Improved colorability (particularly suitable for dark and brilliant colors)
� Suitable for unpainted combined high-gloss / low-gloss parts due toexcellent reproduction of micro-textured injection molding tools
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Bayblend® HG vs. XF
T85 XF
ak Izod ISO 180A RT [ kJ/m² ]
Vicat B/120 [ °C ]
Shear viscosity 260°C/1000 s -1 [ Pa*s ]
Tensile modulus [ MPa ]
48
130
250
2300
T65 HG*
50
120
210
2300
T65 XF
45
120
200
2400
MVR 260°C/5 kg [ cm 3/10 min ] 1718 19
T85 HG*
50
130
260
2250
17
Gloss level @ 20°(260°C/80°C)
*preliminary product description; data are based on limited production statistics and thus shall not be interpreted to anticipate any future product specification
909790 100
Gloss level @ 20°(300°C/80°C) 509770 100
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Individual designs and colors, easy and costefficient realized
Molding of 3D LaserEngraving structures with cyclic mold temperature
• High gloss and matt on one surface• Natural scratch protection by structures• Reproducible design and mapping towards close parts using
Laser Engraving technology
Partner:,
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Bayblend HG:� good flowability and high mold temperature
enable good casting of mold� Good thermostability� high impact strength at lower temperatures� High gloss level using PC, PC+ABS
Individual designs and colors, easy and costefficient realized
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Bayblend® W
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Interior light stability testse.g. DIN EN ISO 105-B06, VDA 75202, PV 1303, SAE J1885, TSL0601 G Method E
PC/ASA blend tailored for non-paintedexterior and interior automotive applicationsrequiring superior light aging stability orweatherability
� High heat resistance
� melt flow comparable to Bayblend® T
� High impact strength
� enhanced tensile modulus
� compliant with European automotive OEMs‘ low-emission standards
� good surface cosmetics
� customer specific color developments on request
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Bayblend® W85 XFlight fastness (interior)
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Exposition of Bayblend according to VDA 75202 (smooth surface), determination of the change of the color as deltaE unit
0,0
1,0
2,0
3,0
4,0
5,0
6,0
7,0
1st cycle 2nd cycle 3rd cycle 4th cycle 5th cycle
delta
E u
nit
Bayblend T85 BBS910Bayblend W85 XFMakrolon 2407
Color white
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Electroplating applications
Bayblend® T45 PG
door handle front grille frame
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Chrom- and Strukturchrom® -Versions on Bayblend® T45 PG
Bayblend PG for diverse Galvano solutions
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Bayblend® GF Grades
� Melt viscosities reduced by 30-40 % vs. conventional Bayblend® GF grades; T88 GF-10 is successor of T88-2N; T88 GF-20 is successor of T88-4N
� Inreased long term heat aging reasistance
� Tensile modulus increased by 25 %; ~ 50 % increase in tensile strength
� Excellent color stability when exposed to (UV) light
� Improved surface cosmetics – benchmark in PC/ABS GF
� Very good adhesion to PU foams / TPU´s – even after aging
� Excellent performance in backmolding of interior wooden trim parts
� Part production with reduced wall thickness - utilizing full potential of new grades
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Bayblend® GF
T88 GF-30
an Izod ISO 180/U RT [ kJ/m² ]
Vicat B/120 [ °C ]
Tensile modulus [ MPa ]
Glass fibre content [ % ]
35
134
10000
31
T88 GF-20
38
130
7500
20
T88 GF-10
35
134
5100
10
Shear viscosity 260 °C/1000 s -1 [ Pa*s ] 210205 250
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E-modulus over Temperature
Temperature [ °C ]
E-M
odul
us [
Mpa
]
ABS (PC+ABS)
0
1000
2000
3000
4000
5000
-40 -20 0 20 40 60 80 100 120
PP
PP-GF
(PC+ABS)-GF
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Bayblend T88 GF-10 / 20 / 30
Backmoulding ofwooden trim parts• Low CLTE• High heat resistance• Excellent flowability
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T88 GF-10 for IP-Carrier
Advantage:
• High flowability results in faster cycle times/ better profitability
• Thermoageing stable
• Applications: Ford Focus C-Max
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2K centre console Bayblend® T88 GF-10 + TPU
Bayblend® T88 GF-10 Centre console (VW Golf)
Advantages:
• Good flowability
• high stiffness
• good warpage behavior
• excellent retention of ductility upon long-term exposure to (humid) heat
• Low wall thicknesses possible
• Minimized warpage
• Good adhesion of both components
• High dimensions stability, comfortable haptics, good scratch resistant, good light fastness, matt finish
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Bayblend® LGX300
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A1 polish texture
20° 60° 60° 85°
LGX300 ASTM D523
(GU)32 83 1.8 2.6
T85XF 98 100 3.1 5.8
• Inherent low gloss
• High stiffness, high impact High heat resistance
• Good weatherability
• Low emission
• Good flowability
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Agenda Product Portfolio
Color Competence
Interior Application
Exterior Application
Lighting Application
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Automotive Glazing
Roofs, side and rear windows1st transparent component:
• Makrolon AG 2677, • IR absorbing colors available
2nd black component: • Bayblend T95 MF• Makroblend UT 235 M
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Horizontal Parts ApplicationsRoof Bezels
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OEM: VW/Audi/Skoda/Seat/Lancia…Application : 1-Piece U-TrimMaterial : MK 2605 MAS083 black (=>AX2675)coated with AS 4700 &SHP470FT 2050
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Bayblend® W85 XF
PC + ASA blend tailored for non-paintedexterior and interior automotive applica-tions requiring superior light aging stability or weatherability
• heat distortion temperature superior to competition
• melt flow comparable to Bayblend® T65
• multiaxial ductility down to -20 °C
• enhanced tensile modulus
• compliant with European automotive OEMs’ low-emission standards
• good surface cosmetics
• customer specific color developments on request
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Bayblend® Mineral filled Grades
Mineral-reinforced PC/ABS injection molding grade with outstanding heat distortion temperature
• improved balance of ductility and stiffness vs. GF grades
• heat distortion temperature similar to pure PC
• reduced CLTE and molding shrinkage vs. non-reinforced PC/ABS blends
• isotropic molding shrinkage behavior
• nearly isotropic CLTE
• high dimensional stability
• superior melt flow vs. comparable Makroblend® grades
• high energy uptake capacity under multi-axial impact load down to temperatures as low as -30 °C
• class A, low gloss surface appearance
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Bayblend® Mineral Grades
an Izod ISO 180/U RT [ kJ/m² ]
Vicat B/120 [ °C ]
Shear viscosity 260 °C/1000 s -1 [ Pa*s ]
Tensile modulus [ MPa ]
T90 MF-20
33
130
230
5200
T95 MF
≥ 150
142
410
3350
MVR 260 °C/5 kg [ cm 3/10 min ] 1218
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Roof Spoiler
� 20 % mineral filled grade, low CLTE, isotropic behavior
� Class-A-surface� Excellent paint adhesion� Fully amorphous material, high
modulus up to > 100°C
� Excellent Flowability� Target: Metal- and SMC-
replacement
Bayblend® T90 MF-20
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Bayblend® T85 XF Rear Spoiler
� Class-A-surface� Excellent paint adhesion� High heat resistance and for large
horizontal parts� Excellent Flowability, 15-20 %
improved to Bayblend T85� Metal- and SMC-replacement in
large horizontal body panelapplications
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SGM 258 MPV spoiler T85XF
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Front and Rear BumperMakroblend PC+PBT KU2-7912
Weight per
part 5.2 kg
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OEM: VWType : Phaeton
OEM: BentleyType : Continental Flying Spur
The three bumper elements of lower section, protective strip and cover are injection molded by system suppliers, and then painted without plasma pretreatment or flame treatment.
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� Improved weatherability� High impact strength� Excellent chemical resistance
� Target: truck exteriorinluding non-painted mudguards
� Non-painted front grille
Makroblend® UT 6007 (PC/PBT)
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Makroblend® AR 205 (PC+PET)
New easy flowing PC+PET - Blend for Automotive Radiator grills
Outstanding properties:• Easy flowing• Excellent processing stability• Good surface quality• High heat resistance• Easy release• Excellent paintable (single layer
coating systems or high glosspiano black systems working well)
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Comparison AR 205 vs DP7645
DP7645AR 205
Tensile modulus [ MPa ] 21002200
an IZOD ISO 180U -30 °C [ kJ/m 2 ] n.b.n.b.
Vicat B/120 [ °C ] 133137
ak IZOD ISO 180A -20 °C [ kJ/m 2 ] 2318
0.6 – 0.80.6 – 0.8Shrinkage [ % ]
120125HDT-B [ °C ]
ak IZOD ISO 180A 23 °C [ kJ/m 2 ] 5039
MVR 270°C / 5 kg 2440
Melt viscosity 270 °C / 1000 s -1 240220
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PC+PBT / PC+PET mineral filled
GR235MUT235MKU 2-7609
MVR 260°C/5 kg [ cm 3/10 min ] 18*16*11
Shear viscosity [Pa*s] 260 °C /1000 s -1 280*230*370
ak IZOD ISO 180A 23 °C [ kJ/m² ] 8820
an IZOD ISO 180U 23 °C [ kJ/m² ] 110160 100
-130106HDT-B [ °C ]
Shrinkage [ % ] 0.5 - 0.60.5 - 0.60.4 - 0.6
CLTE [10-4/K] 0.460.450.7
142140120Vicat B/120 [ °C ]
Tensile modulus [ MPa ] 42003400 4600
* at 270 °C
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Makroblend® UT235M (15% mineral filled PC/PET)
• Prefered grade for horizontal exterior parts with low CLTE
• Much better flowability than DP7665
• Less mineral streaks
• Coefficient of linear thermal expansion < 0.5 [10-4/K]
• Low isotropic shrinkage (nearly same than DP7665)
• Good paint adhesion
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OEM: Audi A7Part: Cover and structural part
for tailgate
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Makroblend® UT235M (15% mineral filled PC/PET)
Structural part:− unpainted, partly visible− UV-protection needed > adjusted
AUDI specification− chemical resistance to gazoline / − cleaning agents− gluing behavior to cover
Cover:- painted (primer, base coat, clear coat)- class A surface- gluing behavior to structural part
sheet metal
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Makroblend® UT235M (15% mineral filled PC/PET)
• Opel Insignia Sports Tourer
• Rear spoiler
• Audi A5 cabriolet
• Cover for the convertible top box
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Mercedes SLK (R172): Pillar and roof trim
Makroblend® UT235M (15% mineral filled PC/PET)
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+
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Makroblend® GR235M (PC/PET)(15% mineral filled PC/PET)
Makroblend® GreenGR 235MMakroblend® GreenGR 235M
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Agenda Product Portfolio
Color Competence
Interior Application
Exterior Application
Lighting Application
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PCS automotive lighting applications
� Head lamp lens and fog lamp lens covers
� Bezels and reflectors
� Indicator and break lights:signal colors
� Rear Lamps
� LED
� Collimator lenses
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Head Lamp Lens and Fog Lamp Lens
� UV stabilized
� High impact strength
� Optical quality / High transparence
� Easy-moldability
� SAE/ECE approvals
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Material grades:
Makrolon: M. AL2447; M. AL2647 (550396)
Apec: A.1603; A.1703; A.1803; A.1897
Resistance to UV light, chemical attack and scratches by special hard coat
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Head Lamp Lens and Fog Lamp Lens
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Apec 1603 551022 for fog lamps
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Bezels/Reflectors
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* Please take the UL RTI temperature into account
Vicat (VST B120)100°C 120°C 140°C 160°C 180°C 200°C
*
�Tailor-made materials for a broad range
MaterialBayblend®
T80XGBayblend®
T90XG
Makrolon® 1260, 2205, 2405
Apec® 1695
Apec® 1795
Apec® 1895
Apec® 2095
Vicat Temperature* 50 N, 120K/h
127°C 130°C 143°C 158°C 173°C 183°C 203°C
Typical Application
Bezel for rear lamps
Bezel for rear lamps
Bezel for forward
lighting and rear lamps
Bezel for forward lighting
Bezel for forward lighting
Bezel for forward lighting
Bezel for forward lighting
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Bayblend® T80 XG
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Automotive light reflector applicationsrequiring class-A, high-gloss appearance after metallization
� excellent processing behavior
� homogenous high-gloss surface appearance
� good metallization behavior
� high heat distortion temperature
� welding ability with PC and PMMA
� high ductility at application temperatures
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Indicator and break lights: Signal Colors
� Special colors within the defined signal colorrange
� AMECA approval for signal colors
� High purity and tight color specifications
� High variety of signal colors to fulfill individual needs
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Material grades:
� Makrolon: M.2207; M.2407; M.2607; M.2807
� Apec: A.1697; A.1797; A.1897
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Rear Lamps
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Translucent
Cover
Light guide Structured surface
Sophisticated effects
Light guide
Many rear lamp components are made of Makrolon!
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LED Auto lighting Motivation for OEMs and Tier1:
� Energy saving
� Weight saving
� Design freedom
� Longer lifetime
BMS perspective:
� Makrolon for light guides, collimator optics, reflectors and other parts
� Development activities BMS:
o Makrolon LED2245/LED2445
o Molding technology
Lamp cover made in glass
Lamp covers made in PCLenses made in glass
Lamp covers made in PCLenses made in PC
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Makrolon® Grades for Optical Lens Applications
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Makrolongrade
Makrolon OD2015
MakrolonLED2045/ LED2245**
MakrolonLED2245
Makrolon AL2447/AL2647
MakrolonLQ2647
Makrolon LQ3187
Color code 000000 000000 550207 550396 550115 550131
Color Non tinted Non tinted Ice color Crystal clear Crystal clear Crystal clear
MVR (cm3/10 min @ 300°C)*
61 61/36 36 19 / 12 12 6
Transmission (4 mm)*
90 % 90 % 89~90% 88 % 88 % 86 %
Transmission (20 mm)*
88-89 % 88-89 % 85-87 % 83 % 83 % tbd
Application CD/DVD Light guide Lenses Light guide
Head lamp lenses
Opthalmics, visors
Opthalmics, visors
UV-protected no no no yes UVcut 380 UVcut 400
* Typical values, no specification** Availability depends on region
new
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Optical properties of standard, optical and LED Makrolon® grades
� LED grades: enhanced transmission, decreasedyellowness index and improved LED light stability
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LED Auto lighting
68
Makrolon® LED2245 000000
Audi A8
Makrolon® 2405 MAS048 901510 Makrolon® AL2447 550396
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Makrolon light guides in door panels (Audi A6)
LEDPage 69
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LED internal lighting(Audi A8)
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Audi A8
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LED Grade Ice Color
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Makrolon ®LED2245 ice color
Counter grade material
• High transmission (>89%, 4mm)
• Low YI (<M.LED2245 000000)
• Low haze (<M.LED2245 000000)
Makrolon ®LED 2245 550207
Ice color
Audi A7
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Collimator lenses
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Makrolon/Apec are the right material for all these complex lenses
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Thank you!
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Forward-Looking Statements
This presentation may contain forward-looking statements based on current assumptions and forecasts made by Bayer Group or subgroup management.
Various known and unknown risks, uncertainties and other factors could lead to material differences between the actual future results, financial situation, development or performance of the company and the estimates given here. These factors include those discussed in Bayer’s public reports which are available on the Bayer website at www.bayer.com.
The company assumes no liability whatsoever to update these forward-looking statements or to conform them to future events or developments.
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