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TRANSCRIPT
Positively Innovative
Durable fluoropolymer coating base
ZEFFLE for PV 25 08
2015
法律声明:本讲义只作交流学习之用,内容仅供参考,转载需经原作者同意并注明出处,本组委会保留一切法律追诉的权利,此活动的最终解释权归亚洲光伏创新论坛所有。
・Daikin Industries ・Fluorochemicals ・Fluorocoating ZEFFLE GK ・ZEFFLE GK application example ・ZEFFLE GK for PV backsheet
法律声明:本讲义只作交流学习之用,内容仅供参考,转载需经原作者同意并注明出处,本组委会保留一切法律追诉的权利,此活动的最终解释权归亚洲光伏创新论坛所有。
3
Daikin Industries
Corporate Data
Company Name Daikin Industries, Ltd.
(Head Office: Osaka , Japan)
Incorporated 1934(founded in 1924)
Capital 85 billion yen
Sales 1,783 billion yen (fiscal 2013:consolidated)
Number of
Employees 56,240 (March, 2014:consolidated)
Number of Group
Companies
209 consolidated subsidiaries (28 in Japan; 181 overseas) (March, 2014)
法律声明:本讲义只作交流学习之用,内容仅供参考,转载需经原作者同意并注明出处,本组委会保留一切法律追诉的权利,此活动的最终解释权归亚洲光伏创新论坛所有。
4
Daikin Industries
Daikin Group Companies : 209 companies (March,2014)
Ratio of Overseas Sales 71%
(fiscal 2013:consolidated)
Japan 5,128 (29%)
Overseas 12,703
(71%)
Japan 29%
China 18% Asia &
Oceania 13%
Europe 14%
Americas 20%
Other
(hundred million yen)
Sales Breakdown by Global Region
法律声明:本讲义只作交流学习之用,内容仅供参考,转载需经原作者同意并注明出处,本组委会保留一切法律追诉的权利,此活动的最终解释权归亚洲光伏创新论坛所有。
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Properties of Fluorine Compounds
Unique properties of Fluorine Compounds
Chemical
resistance
Low gas
permeability
Heat
resistance
Water and Oil proof
Non- stick Anti-fouling
Lubricity
Weather
resistance
Insulation
performance
Flame
resistance
Low
refractive
index
We are driven to give innovative solutions for our partners based on these properties and our core technologies.
法律声明:本讲义只作交流学习之用,内容仅供参考,转载需经原作者同意并注明出处,本组委会保留一切法律追诉的权利,此活动的最终解释权归亚洲光伏创新论坛所有。
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Fluorochemical Manufacturing Process
A wide variety of Fluorochemical products
Offering a wide variety of Fluorochemicals deriving from fluorspar.
Monomer
Sulfuric
acid
H2SO4
Anhydrous fluoric acid
HF
fluorspar
Fluorocarbon gas
Fluoropolymers
Fluoropolymer Films
Fluoroelastomers
Fluoro Coatings
Water and oil repellents
Fluorinated anti-
fingerprint Coatings
Mold release agents
Additives
Fluorinated intermediates
Fluorinated oils, etc.
Chloro-
form etc. Etching agents
法律声明:本讲义只作交流学习之用,内容仅供参考,转载需经原作者同意并注明出处,本组委会保留一切法律追诉的权利,此活动的最终解释权归亚洲光伏创新论坛所有。
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base monomer weather ability
bake or
cure
onsite paint
chemical resistance
soil remove ability
chlorine
2F base excellent high temp.
bake unable bad fair free
3FCl base fair rt~ cure
able fair fair chlorine
4F base ZEFFLE GK excellent
rt~ cure
able excellent excellent free
Fluoropolymer transition for various exterior coating
year
1970 1980 1990
Coating material developing history
法律声明:本讲义只作交流学习之用,内容仅供参考,转载需经原作者同意并注明出处,本组委会保留一切法律追诉的权利,此活动的最终解释权归亚洲光伏创新论坛所有。
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Chemical structure of ZEFFLE GK (4F type)
Tetra fluoro ethylene
Polyflon Teflon
PTFE
C C
F F
F F
Feature: Weatherability Chemical resistance Heat resistance
Fault: Poor solvent solubility High temp bake No compatibility
Resolving fault as it leaves the feature
Modifying
C C
H H
Y H
OH
C C
H H
Z H
C C
F F
F F F F
C C
F F
TFE
Cross-linkage
Coatability Compatibility with additives
TFE
Weatherability Chemical stability Heat resistance
法律声明:本讲义只作交流学习之用,内容仅供参考,转载需经原作者同意并注明出处,本组委会保留一切法律追诉的权利,此活动的最终解释权归亚洲光伏创新论坛所有。
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ZEFFLE GK Conventional Acrylic urethane
3 Y 6 Y
Coating surface after exposure (By SEM)
Gloss retention White panel (TiO2), exposure slope: 30°facing south
0
20
40
60
80
100
120
0 1 2 3 4 5 6
%
Glo
ss
R
ete
nti
on
ZEFFLE GK
Acrylic urethane
0
20
40
60
80
100
120
0 1 2 3 4 5 6 7 8 9 10
Years of Exposure
% G
loss
Rete
nti
on
ZEFFLE GK (Clear)
Acrylic
in Okinawa
in Florida
ZEFFLE GK
Acrylic
urethane
Weather Resistance test for ZEFFLE coating
法律声明:本讲义只作交流学习之用,内容仅供参考,转载需经原作者同意并注明出处,本组委会保留一切法律追诉的权利,此活动的最终解释权归亚洲光伏创新论坛所有。
10
Machine Supplier Light Source Test Condition
QUV QUV/se Q-Panel Lab
Products
UVB-313 ASTM D4587
4hours UV/60℃
4hours condensation/50℃
The Accelerated Weathering Test Condition
Accelerated durability Test for ZEFFLE coating
ZEFFLE GK
Acrylic
法律声明:本讲义只作交流学习之用,内容仅供参考,转载需经原作者同意并注明出处,本组委会保留一切法律追诉的权利,此活动的最终解释权归亚洲光伏创新论坛所有。
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ZEFFLE GK(±0u)
initial 45μm
QUV-2000h 45μm
Polyurethane (-14u)
initial 45μm
QUV-2000h 31μm
QUV-test (2000h)
45μ 45μ 31μ
45μ
Accelerated durability Test for ZEFFLE coating
法律声明:本讲义只作交流学习之用,内容仅供参考,转载需经原作者同意并注明出处,本组委会保留一切法律追诉的权利,此活动的最终解释权归亚洲光伏创新论坛所有。
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・Bond energy C-F: 485kJ/mol (strong) C-Cl: 326kJ/mol (weak) ・MAX UV energy -------- 411kJ/mol
⇒C-Cl: bond cleavage
weak
CTFE
Cl
ZEFFLE 4F:TFE
TFE
very strong
CTFE
Cl
UV
Cl -
3FCL:CTFE
C C
F F
F F
C C
F F
Cl F
Advantage of ZEFFLE 4F
法律声明:本讲义只作交流学习之用,内容仅供参考,转载需经原作者同意并注明出处,本组委会保留一切法律追诉的权利,此活动的最终解释权归亚洲光伏创新论坛所有。
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Advantage of ZEFFLE 4F ~Dispersibility~
0
1
2
3
4
5
370 390 410 430 450
%T
nm
Light transmittance ZEFFLE
4F B
Light transmitta
nce
25μ
2.67% (450nm)
4.06% (450nm)
P/B (TiO2/Resin) = 0.83, Solid cont.=58%
0
10
20
30
40
50
60
0 50 100
Dis
pe
rsib
ilit
y
20°
Gro
ss
Disper time(min)
Daikin ZEFFLE 4F Fluorocoating A Fluorocoating B
法律声明:本讲义只作交流学习之用,内容仅供参考,转载需经原作者同意并注明出处,本组委会保留一切法律追诉的权利,此活动的最终解释权归亚洲光伏创新论坛所有。
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S-UV 1000h ※clear paint on white board
ZEFFLE 4F Fluorocoating 3F Acrylic type
Advantage of ZEFFLE 4F ~Weatherability~
法律声明:本讲义只作交流学习之用,内容仅供参考,转载需经原作者同意并注明出处,本组委会保留一切法律追诉的权利,此活动的最终解释权归亚洲光伏创新论坛所有。
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ZEFFLE GK application example
Monorail in Okinawa
青岛海湾大桥
武汉天兴州大桥
法律声明:本讲义只作交流学习之用,内容仅供参考,转载需经原作者同意并注明出处,本组委会保留一切法律追诉的权利,此活动的最终解释权归亚洲光伏创新论坛所有。
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南京
大胜关
长江大桥
苏通
长江大桥
嘉绍跨江
大桥
杭州湾
大桥
辽河
特大桥
泸州泰安
长江大桥
ZEFFLE GK application example
法律声明:本讲义只作交流学习之用,内容仅供参考,转载需经原作者同意并注明出处,本组委会保留一切法律追诉的权利,此活动的最终解释权归亚洲光伏创新论坛所有。
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港珠澳大桥 海中桥隧工程总长约35.6km,其中香港段长约6km,粤港澳三地共同建设的主体工程长约29.6km。主体工程分为桥梁工程和岛隧工程两部分,其中桥梁工程长约22.9km.
钢箱梁涂装面积为570万平方米,氟碳树脂用量在280T左右。
ZEFFLE GK application example
法律声明:本讲义只作交流学习之用,内容仅供参考,转载需经原作者同意并注明出处,本组委会保留一切法律追诉的权利,此活动的最终解释权归亚洲光伏创新论坛所有。
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Coating
Coating
Film
Film EVA side
EVA side
PET
PET
Adhesive
C C
F F
Cl F
C C
F F
F F
C C
H F
H H
PVF type (1F) F: 41wt%
C C
H F
H F
PVDF type (2F) F: 59wt%
TFE type (4F ZEFFLE GK) F: 76wt%
CTFE type (3FCl) F: 49wt%
F-Film type backsheet
F-Coat type backsheet
PET polyethylene terephthalate
F-type Backsheets of various kinds
法律声明:本讲义只作交流学习之用,内容仅供参考,转载需经原作者同意并注明出处,本组委会保留一切法律追诉的权利,此活动的最终解释权归亚洲光伏创新论坛所有。
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ZEFFLE GK
ZEFFLE GK
F-Film
F-Film
PET Film layer
F-Film layer
38~20μm
ZEFFLE Coating
ゼッフル塗膜層
PET Film layer
10~13μm
No adhesive between ZEFFLE and PET/EVA.
Reduction in fluoro-layer thickness by more than half
F-Film EVA side EVA side
Polyester Polyester
Adhesive
ZEFFLE coating layer
Advantage of ZEFFLE Backsheet
法律声明:本讲义只作交流学习之用,内容仅供参考,转载需经原作者同意并注明出处,本组委会保留一切法律追诉的权利,此活动的最终解释权归亚洲光伏创新论坛所有。
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Backsheet Technical Data ~Weatherability~
Test with S-UV Tester (UV 100mW/cm2 :12hrs ⇔ 95%RH :12hrs)
100/100 (0hr) 100/100 (600hrs)
40
60
80
100
0 200 400 600
(%)
(hr)
F-film type (38μ)
F-coat type (10μ)
PET
Nylon type
PET multilayer (containing barrier layer)
ZEFFLE GK / PET / ZEFFLE GK (10μ)
Retention of Tensile Strength
Adhesion of ZEFFLE (cross-cut test)
tape
peel
substrate
法律声明:本讲义只作交流学习之用,内容仅供参考,转载需经原作者同意并注明出处,本组委会保留一切法律追诉的权利,此活动的最终解释权归亚洲光伏创新论坛所有。
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Backsheet Technical Data ~Weatherability~ 試験機 : サンシャインウェザーメーター サンプルサイズ:60×50mm
フィルタ条件 : #255放射照度 : 78.5 W/㎡ (300-400nm)BPT : 63℃槽内湿度 : 50%rhスプレー : 120分中18分
倍率:100倍0h 1000h
B-1
KPT
B-2
TPE
B-3
ZPE
B-4
PPE
KPX
TPX
ZPX
PPX
0h 1000h
BS photo after
SWOM 1000h
78.5W/m2(300-400nm) 63℃、50%RH shower:18min/120min
Results of collaborative research with
Suga Weathering Technology Foundation スガウェザリング技術振興財団
法律声明:本讲义只作交流学习之用,内容仅供参考,转载需经原作者同意并注明出处,本组委会保留一切法律追诉的权利,此活动的最终解释权归亚洲光伏创新论坛所有。
22
Backsheet Technical Data ~Weatherability~
Sunshine WOM 78.5W/m2(300-400nm) 63℃、50%RH shower:18min/120min
Super Xenon WOM 180W/m2(300-400nm) 63℃、50%RH shower:18min/120min
Results of collaborative research with Suga WeatheringTechnology Foundation
スガウェザリング技術振興財団
法律声明:本讲义只作交流学习之用,内容仅供参考,转载需经原作者同意并注明出处,本组委会保留一切法律追诉的权利,此活动的最终解释权归亚洲光伏创新论坛所有。
23
Backsheet Technical Data ~Weatherability~
Results of collaborative research with Suga WeatheringTechnology Foundation
スガウェザリング技術振興財団
KPX TPX ZPX PPX
Outdoor-exposure test for 18months at Suga Test Instruments (東京新宿)
⊿E 5.64 8.00 2.29 8.60 ⊿YI 6.56 4.36 1.96 4.43
法律声明:本讲义只作交流学习之用,内容仅供参考,转载需经原作者同意并注明出处,本组委会保留一切法律追诉的权利,此活动的最终解释权归亚洲光伏创新论坛所有。
24
Module Technical Data ~Weatherability~
Results of collaborative research with AIST consortium 産総研コンソーシアム
Retention of generating efficiency after Damp heat 3500hrs
DH elapsed time [hrs]
Pow
er
gen
era
tion
eff
icie
ncy
keep
ing
rati
o
Film BS
(FFC-30)
法律声明:本讲义只作交流学习之用,内容仅供参考,转载需经原作者同意并注明出处,本组委会保留一切法律追诉的权利,此活动的最终解释权归亚洲光伏创新论坛所有。
25
Module Technical Data ~Weatherability~
Pmax: 96.4%
Pmax: 27.0%
Pmax: 45.8%
Pmax: 15.7%
ZPE Coating BS
DH4000 initial
uncorroded
corroded
corroded
corroded
Results of collaborative research with AIST consortium
Film BS
法律声明:本讲义只作交流学习之用,内容仅供参考,转载需经原作者同意并注明出处,本组委会保留一切法律追诉的权利,此活动的最终解释权归亚洲光伏创新论坛所有。
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non-fluorinetype
Film type Coating type Film type
Disperse pigment ★ ★★★ ★
UV shielding ★ ★★★ ★
Weatherability ★★★ ★★★ ★
Thickness 20~40μm 10~30μm 30~50μm
Adhesive necessary unnecessary necessary
Cost ★ ★★ ★★★
Cost performance ★★ ★★★ ★★
fluorine type
ZEFFLE
Advantage of ZEFFLE Backsheet ~Conclusions~
法律声明:本讲义只作交流学习之用,内容仅供参考,转载需经原作者同意并注明出处,本组委会保留一切法律追诉的权利,此活动的最终解释权归亚洲光伏创新论坛所有。
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南非lesedi 155MW 高沙窝50MW
And more・・・
法律声明:本讲义只作交流学习之用,内容仅供参考,转载需经原作者同意并注明出处,本组委会保留一切法律追诉的权利,此活动的最终解释权归亚洲光伏创新论坛所有。