processing factors and emulsion characteristics...

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PROCESSING FACTORS AND EMULSION CHARACTERISTICS D 22 William L.Sulzbacher and Clifton E.Swift * M: Emulsion type sausages are a major product of the united 6s meat industry, amounting to over 2.5 x 10^ pounds of pro per year. This Laboratory has been concerned for a decade the characteristics of meat emulsions and the scientific ctples underlying their formation. A review of some of our , APal findings for the benefit of this meeting seems especial- •^e emulsion sausage is actually a mixture of a true emulsion N „ i ai"ticles of unemulsified muscle and fat. The more stable the \ en>uision part of the mixture, the more stable w ill be the age as a whole. The emulsion is composed of fat globules en- iu a matrix of denatured protein (Hansen, i 960 ). In ion- S thi H 18 emulsion, the ability of the meat protein to for* the S&ry ®atrix is critical to successful sausage making. There- the very beginning of our work we devised (swift ejt a l., a technique for measuring the emulsifying capacity of vari- ats, and other sausage ingredients, which has become a stand- 0 <a6 for hsi this purpose in the united states, k ~ lng the Swift technique for determining emulsifying capaci- ’ ve v t. "ere able to elucidate several basic principles of emulsion % ^8 l°h. por example, we showed that the amount of fat emulsifi- ^ directly proportional to the rate at which fat was added the m ^ ^ture and that the higher the temperature attained during ’ the less fat was emulsified. Both salt-soluble and water- df Proteins were used in emulsification, and the efficiency 8°luble proteins as emulsifiers was much more concentra- - 1027 -

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Page 1: PROCESSING FACTORS AND EMULSION CHARACTERISTICS …icomst-proceedings.helsinki.fi/papers/1970_04_22.pdf · PROCESSING FACTORS AND EMULSION CHARACTERISTICS ... beef and pork fats were

PROCESSING FACTORS AND EMULSION CHARACTERISTICSD 22

W illiam L .Su lzbach er and C lifto n E .Sw ift

*

M:

Emulsion type sau sages are a major product o f the united

6s meat in d u stry , amounting to over 2.5 x 10 ̂ pounds of pro­

per y ear . This Laboratory has been concerned fo r a decade

the c h a r a c te r is t ic s o f meat em ulsions and the s c ie n t i f i c

ctp le s underlying th e ir form ation. A review o f some o f our

, APal f in d in g s fo r the b e n e fit o f th is meeting seems e sp e c ia l-

•^e emulsion sausage i s a c tu a lly a mixture o f a true emulsionN „i ai" t ic le s o f unem ulsified muscle and f a t . The more sta b le the

\en>uision p art o f the m ixture, the more s ta b le w ill be the

age as a whole. The emulsion i s composed o f f a t g lob u les en-

iu a m atrix o f denatured p ro te in (Hansen, i 960) . In ion-S thiH 18 em ulsion, the a b i l i t y o f the meat p ro te in to fo r * the

S&ry ®a t r i x i s c r i t i c a l to su c c e ssfu l sausage making. There-

’ the very beginning o f our work we devised (sw ift ejt a l . ,

a technique fo r measuring the em ulsifying cap ac ity of v a r i-

at s , and o ther sausage in g re d ie n ts , which has become a stand-

0

<a6

for

hsith is purpose in the united s t a t e s ,

k ~ lng the Sw ift technique fo r determining em ulsifying capac i- ’ ve vt. " ere ab le to e lu c id a te se v e ra l b a s ic p r in c ip le s o f emulsion

%

^8l °h . por example, we showed th at the amount o f f a t e m u ls ifi-

^ d ire c t ly proportion al to the ra te a t which f a t was added the m •^ ^ t u r e and th at the higher the temperature a tta in e d during

’ the le s s f a t was em u lsifie d . Both s a lt - s o lu b le and w ater-

df Proteins were used in e m u ls ific a tio n , and the e ff ic ie n c y

8°lu b le p ro te in s as e m u ls ifie r s was much more concentra-

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Page 2: PROCESSING FACTORS AND EMULSION CHARACTERISTICS …icomst-proceedings.helsinki.fi/papers/1970_04_22.pdf · PROCESSING FACTORS AND EMULSION CHARACTERISTICS ... beef and pork fats were

e# J

t io n -se n s it iv e than was that o f the w ater-so lub le p ro te in s (S *-3

• t a l . , 1 9 6 l) .In fu rth er stu d ies o f the e f fe c t o f p ro te in s on emulsion»»

c$showed in 1963 (Sw ift and su lzbacber) th at a t three d iffe re n t

le v e ls , em ulsifying cap ac ity o f the w ater-so lub le p ro te in s wa»

ouch g re a te r a t a pH o f about 5 .2 than a t e ith e r more a lk a lin e

more ac id con d ition s. For the sa lt - s o lu b le p ro te in s , however#

s ify in g capacity increased rap id ly from pH 5 to PH 6 and remai

a t a high le v e l up to pH 8. Furthermore, the em ulsify ing cap®c

o f the s a lt - s o lu b le p ro te in s improved s l ig h t ly with in crease»

sodium ch loride ( io n ic stren gth ) content.

Ve next turned our a tten tio n to the f a t component o f the

sion and, using d i f f e r e n t ia l thermal a n a ly s is , we were ab le to

analyze the m elting c h a r a c te r is t ic s o f the pork and beef fa t»

n e ra lly found in sausage m ateria ls (Townsend ejt a l . , 1963)*

beef and pork f a t s were found to melt in two ran ges, from 3°

14«C and from 18® to 30°C fo r beef f a t s ; and from 8° to i 4 ° c

18® to 30®C fo r pork f a t s . S tab le em ulsions were e a s i ly prep

with a l l these f a t s a t le v e ls o f 12$ added f a t . At f a t le v e l8

* si*! v

to

y

a ei

22$, s t a b i l i t y was re la te d to the m elting point o f the f a t .I t i J^

to

high m elting f a t s y ie ld ed s ta b le em ulsions while those me

low temperature did not. Chopping tem perature a lso affecteds t a b i l i t y o f the em ulsions, high tem peratures tending more

s t a b i l i t y (sw ift e t a l . , 1968) .

Our most recent in te r e s t in th is a rea has been an inve». ar

tion of the e f f e c t s o f chopping speeds on the p rocessin g cn

i s t i c s o f fra n k fu rte rs (Townsend et a l . , 1970) . Emulsions *eI

tbei f

t i i1V

stechopped in a sp e c ia l ly m odified s i le n t c u tte r so th at k n iie ,te0pef

o f 1500, 2500, and 5000 rpm were a tta in e d . F in al chopping

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Page 3: PROCESSING FACTORS AND EMULSION CHARACTERISTICS …icomst-proceedings.helsinki.fi/papers/1970_04_22.pdf · PROCESSING FACTORS AND EMULSION CHARACTERISTICS ... beef and pork fats were

8 from 7,2®C to 29.*i*C were in v e st ig a te d . The ra te o f tempera-

r is e was found to be dependent on chopping speed, as n ight be

'ected . T h irty minutes chopping a t 1500 rpm was required to ob-

the same tem perature r i s e as three minutes a t 5000 rpm. «hen

®Ped to 7 .2 °C , em ulsions prepared with beef or pork fa t bad

^ e r v i s c o s i t i e s than those prepared with cottonseed o i l . From*? o'S°C to 29.4°C there was very l i t t l e d iffe re n ce in v i s c o s i t y ,

^ °h g h the b eef and cottonseed o i l tended to be h igher than pork

* Also the v i s c o s i t y v a lu e s d id not seem to be r e la te d to enrul-

at a b i l i t y shrinkage in the smokehouse, an important p r a c t ic ­al

^krameter, was not re la te d to chopping speed but was re la te d

ei>8e ly to the t o t a l f a t content and to the type o f f a t . Fat

*e re noted only in fra n k fu rte rs which received in su ff ic ie n t

kPlng. G reater s t a b i l i t y was obtained by chopping a t f a s t e r&vi6<is to h igher tem peratures than was obtained a t slow speed and

tem perature. The optimum temperature fo r emulBion formation

®h8ed with in creasin g kn ife speed.

Ah important p r a c t ic a l con sid eration i s the ease with which ^ h ish ed fra n k fu rte r can be p eeled , in th is work (Townsend et

' *970)., poor p e e lin g , when i t was observed, was a sso c ia te d

to p p in g to high tem perature. Skin stren g th , another p rac tic-

%

k

f8-meter, was observed to he g re a te s t in fran k fu rte rs prepared

. “Pping a t slow speeds or too low tem peratures, or both. This

< r e s u l t s from g re a te r m igration o f p ro te in to the denatur­es

8Urfaced during cooking in those sau sages with the weakest

work reviewed has been noteworthy in both i t s p ra c t ic a l

» Cations and the fundamental nature o f the in sig h t i t has

the p rocess o f em u ls ific a tio n in meat products.

Page 4: PROCESSING FACTORS AND EMULSION CHARACTERISTICS …icomst-proceedings.helsinki.fi/papers/1970_04_22.pdf · PROCESSING FACTORS AND EMULSION CHARACTERISTICS ... beef and pork fats were

REFERENCES

Hansen, L.

swift, C.E

Swift, C.E

Swift, C.E

Swift, C.E

Townsend,

Townsend,

I. i960. Em ulsion fo rm atio n in f in e ly comminuted s®

age. Food Technol. ¿4 , 565., c .Lockett, and A .J .F ry a r . 1961. Comminuted meat

emulsions - The cap ac ity o f meats fo r e m u lsify iD̂

Food Technol. 15, '168.

. and V. L . Su lzbach er. 1963. Comminuted meat em uis*0

Factors a f fe c t in g meat p ro te in s as emulsion s ta

e r s . Food Technol. JL2, 106.

1965. The em ulsify ing p ro p e rtie s o f meat protei11proc. Meat Industry Research Conference, Chicag0'March 1965, P-78. J

d ^, V.E.Townsend, and L .P .W itnauer. 1968. Comminute

• t i cSem ulsions: R elation o f the m elting characteri®i 4

of fa t to emulsion s t a b i l i t y . Food Technol. 2j2’

I.E., L.P.W itnauer, J .A .R i lo f f , and C .E .S w ift. l9^8

Comminuted meat em ulsions: D if fe r e n t ia l tberma<jl>

a n a ly s is o f f a t t r a n s i t io n s . Food Technol. 22 'a r i**f .E . , S.A.Ackerman, L.P.W itnauer, W.E.Palm, ana

iS tSlS w ift. 1970. P re s, in s t i t u t e o f Food Technol0^San F ran cisco , May 2^-28, 1970.

i i l '

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