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Quantum Mechanica Peter van der Straten Universiteit Utrecht Peter van der Straten (Atom Optics) Quantum Mechanica December 4, 2012 1 / 12

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Page 1: Quantum Mechanica - Quantum Mechanica, 2012 …strat102/qm/week12.pdfgraph of the beam splitting, with the message, in transla-tion: Attached [is] the exper-imental proof of directional

Quantum Mechanica

Peter van der StratenUniversiteit Utrecht

Peter van der Straten (Atom Optics) Quantum Mechanica December 4, 2012 1 / 12

Page 2: Quantum Mechanica - Quantum Mechanica, 2012 …strat102/qm/week12.pdfgraph of the beam splitting, with the message, in transla-tion: Attached [is] the exper-imental proof of directional

Overzicht van het college

1 Stern-Gerlach experiment (1922)

2 Spin operatoren

3 Meting van Sz4 Meting van Sy5 Elektron in een magneetveld

6 Stern-Gerlach experiment (revisited)

7 Optellen van impulsmomenten

8 Spin drag (dreggen)

Peter van der Straten (Atom Optics) Quantum Mechanica December 4, 2012 2 / 12

Page 3: Quantum Mechanica - Quantum Mechanica, 2012 …strat102/qm/week12.pdfgraph of the beam splitting, with the message, in transla-tion: Attached [is] the exper-imental proof of directional

Stern-Gerlach experiment (1922)

Peter van der Straten (Atom Optics) Quantum Mechanica December 4, 2012 3 / 12

Page 4: Quantum Mechanica - Quantum Mechanica, 2012 …strat102/qm/week12.pdfgraph of the beam splitting, with the message, in transla-tion: Attached [is] the exper-imental proof of directional

Stern-Gerlach experiment (1922)

and classical views.”8

From Gedanken to DankenAfter hatching his idea in a warm bed, Stern hastened toBorn, but met a cool reception. In his autobiography, Bornsaid,

It took me quite a time before I took this ideaseriously. I thought always that [space] quan-tization was a kind of symbolic expression forsomething which you don’t understand. But totake this literally like Stern did, this was hisown idea. . . . I tried to persuade Stern thatthere was no sense [in it], but then he told methat it was worth a try.9

Happily, Stern found an eager recruit in Gerlach, who untilthen had not heard of space quantization.10

Despite Stern’s careful design and feasibility calcula-tions, the experiment took more than a year to accomplish.In the final form of the apparatus, a beam of silver atoms(produced by effusion of metallic vapor from an ovenheated to 1000°C) was collimated by two narrow slits (0.03mm wide) and traversed a deflecting magnet 3.5 cm longwith field strength about 0.1 tesla and gradient 10 tesla/cm. The splitting of the silver beam achieved wasonly 0.2 mm. Accordingly, misalignments of collimatingslits or the magnet by more than 0.01 mm were enough tospoil an experimental run. The attainable operating timewas usually only a few hours between breakdowns of theapparatus. Thus, only a meager film of silver atoms, toothin to be visible to an unaided eye, was deposited on thecollector plate. Stern described an early episode:

After venting to release the vacuum, Gerlachremoved the detector flange. But he could seeno trace of the silver atom beam and handedthe flange to me. With Gerlach looking overmy shoulder as I peered closely at the plate,we were surprised to see gradually emerge thetrace of the beam. . . . Finally we realizedwhat [had happened]. I was then the equiva-lent of an assistant professor. My salary wastoo low to afford good cigars, so I smoked badcigars. These had a lot of sulfur in them, so my

breath on the plateturned the silver intosilver sulfide, which isjet black, so easily vis-ible. It was like devel-oping a photographicfilm.7

After that episode, Gerlachand Stern began using a pho-

tographic development process, although both continuedpuffing cigars in the lab. Still, recalcitrant difficulties per-sisted. As inconclusive efforts continued for months,Stern’s assessment of space quantization wavered betweenconviction and rejection. Gerlach also encountered doubt-ful colleagues, including Debye, who said, “But surely youdon’t believe that the [spatial] orientation of atoms issomething physically real; that is [only] a timetable for theelectrons.”10

Another handicap was the financial disarray thatbegan to beset Germany. Born was unstinting in efforts toraise funds to support the SGE. He took advantage of thegreat interest in Einstein and relativity theory by pre-senting a series of public lectures “in the biggest lecture-hall of the University . . . and charged an entrance fee. . . .The money thus earned helped us for some months, but asinflation got worse . . . new means had to be found.”8 Bornmentioned this situation “jokingly” to a friend who was de-parting on a trip to New York; he was incredulous when,a few weeks later, a postcard arrived simply saying thathe should write to Henry Goldman and giving the address:

At first I took it for another joke, but on re-flection I decided that an attempt should bemade. . . . [A] nice letter was composed and dis-patched, and soon a most charming reply ar-rived and a cheque for some hundreds of dol-lars. . . . After Goldman’s cheque had saved ourexperiments, the work [on the Stern–Gerlachexperiment] went on successfully.9

Goldman, a founder of the investment firm Goldman Sachsand progenitor of Woolworth Co stores, had family roots inFrankfurt.

Meanwhile, Stern had moved to the University of Ro-stock as a professor of theoretical physics. In early 1922,he and Gerlach met in Göttingen to review the situationand decided to give up. However, a railroad strike delayedGerlach’s return to Frankfurt, giving him a long day to goover all the details again. He decided to continue, im-proved the alignment, and soon achieved a clear splittinginto two beams.5 Stern recalled that his own surprise andexcitement were overwhelming when he received atelegram from Gerlach with the terse message: “Bohr isright after all.”11 Gerlach also sent a postcard to Bohr with

56 December 2003 Physics Today http://www.physicstoday.org

Figure 4. Gerlach’s postcard,dated 8 February 1922, toNiels Bohr. It shows a photo-graph of the beam splitting,with the message, in transla-tion: “Attached [is] the exper-imental proof of directionalquantization. We congratu-late [you] on the confirma-tion of your theory.” (Cour-tesy AIP Emilio Segrè VisualArchives.)

Peter van der Straten (Atom Optics) Quantum Mechanica December 4, 2012 4 / 12

Page 5: Quantum Mechanica - Quantum Mechanica, 2012 …strat102/qm/week12.pdfgraph of the beam splitting, with the message, in transla-tion: Attached [is] the exper-imental proof of directional

Stern-Gerlach experiment

Peter van der Straten (Atom Optics) Quantum Mechanica December 4, 2012 5 / 12

Page 6: Quantum Mechanica - Quantum Mechanica, 2012 …strat102/qm/week12.pdfgraph of the beam splitting, with the message, in transla-tion: Attached [is] the exper-imental proof of directional

Stern-Gerlach experiment

Peter van der Straten (Atom Optics) Quantum Mechanica December 4, 2012 5 / 12

Page 7: Quantum Mechanica - Quantum Mechanica, 2012 …strat102/qm/week12.pdfgraph of the beam splitting, with the message, in transla-tion: Attached [is] the exper-imental proof of directional

Stern-Gerlach experiment

Peter van der Straten (Atom Optics) Quantum Mechanica December 4, 2012 5 / 12

Page 8: Quantum Mechanica - Quantum Mechanica, 2012 …strat102/qm/week12.pdfgraph of the beam splitting, with the message, in transla-tion: Attached [is] the exper-imental proof of directional

Spin drag

Equal mixture spin up and down

Peter van der Straten (Atom Optics) Quantum Mechanica December 4, 2012 6 / 12

Page 9: Quantum Mechanica - Quantum Mechanica, 2012 …strat102/qm/week12.pdfgraph of the beam splitting, with the message, in transla-tion: Attached [is] the exper-imental proof of directional

Spin drag

F↑

Apply force on spin up

Peter van der Straten (Atom Optics) Quantum Mechanica December 4, 2012 6 / 12

Page 10: Quantum Mechanica - Quantum Mechanica, 2012 …strat102/qm/week12.pdfgraph of the beam splitting, with the message, in transla-tion: Attached [is] the exper-imental proof of directional

Spin drag

F↑

No drag - acceleration

Peter van der Straten (Atom Optics) Quantum Mechanica December 4, 2012 6 / 12

Page 11: Quantum Mechanica - Quantum Mechanica, 2012 …strat102/qm/week12.pdfgraph of the beam splitting, with the message, in transla-tion: Attached [is] the exper-imental proof of directional

Spin drag

F↑

F↑

Drag - constant velocity difference

Peter van der Straten (Atom Optics) Quantum Mechanica December 4, 2012 6 / 12

Page 12: Quantum Mechanica - Quantum Mechanica, 2012 …strat102/qm/week12.pdfgraph of the beam splitting, with the message, in transla-tion: Attached [is] the exper-imental proof of directional

Condensed matter vs. cold atoms

Condensed matter Cold atoms

electrons atomscharge masselectric field magnetic field gradientelectron spin pseudo-spin 1/2e-e interactions atom-atom interactionse-photon interactions -e-impurities interactions -current absorption imaging

Peter van der Straten (Atom Optics) Quantum Mechanica December 4, 2012 7 / 12

Page 13: Quantum Mechanica - Quantum Mechanica, 2012 …strat102/qm/week12.pdfgraph of the beam splitting, with the message, in transla-tion: Attached [is] the exper-imental proof of directional

Spin drag

Js

Jm

y

x

Js

Charge or mass current conserved

Spin current switched direction

Strong damping

Peter van der Straten (Atom Optics) Quantum Mechanica December 4, 2012 8 / 12

Page 14: Quantum Mechanica - Quantum Mechanica, 2012 …strat102/qm/week12.pdfgraph of the beam splitting, with the message, in transla-tion: Attached [is] the exper-imental proof of directional

Spin drag

Js

Jm

y

x

Js

Charge or mass current conserved

Spin current switched direction

Strong damping

Peter van der Straten (Atom Optics) Quantum Mechanica December 4, 2012 8 / 12

Page 15: Quantum Mechanica - Quantum Mechanica, 2012 …strat102/qm/week12.pdfgraph of the beam splitting, with the message, in transla-tion: Attached [is] the exper-imental proof of directional

Spin drag

Js

Jm

y

x

Js

Charge or mass current conserved

Spin current switched direction

Strong damping

Peter van der Straten (Atom Optics) Quantum Mechanica December 4, 2012 8 / 12

Page 16: Quantum Mechanica - Quantum Mechanica, 2012 …strat102/qm/week12.pdfgraph of the beam splitting, with the message, in transla-tion: Attached [is] the exper-imental proof of directional

Spin drag

Js

Jm

y

x

Js

Charge or mass current conserved

Spin current switched direction

Strong damping

Peter van der Straten (Atom Optics) Quantum Mechanica December 4, 2012 8 / 12

Page 17: Quantum Mechanica - Quantum Mechanica, 2012 …strat102/qm/week12.pdfgraph of the beam splitting, with the message, in transla-tion: Attached [is] the exper-imental proof of directional

Measurement – Constant force

0.0

0.3

0.6

0.9

1.2

1.5

[mm

]

0 1 2 3 4 5 6[mm]

0 1 2 3 4 5 6[mm]

0.2

0.4

0.6

0.8

1.0

1.2

Tra

nsm

issi

on

Peter van der Straten (Atom Optics) Quantum Mechanica December 4, 2012 9 / 12

Page 18: Quantum Mechanica - Quantum Mechanica, 2012 …strat102/qm/week12.pdfgraph of the beam splitting, with the message, in transla-tion: Attached [is] the exper-imental proof of directional

Drag rate – Constant force

0 20 40 60 80 100t[ms]

−0.4

−0.3

−0.2

−0.1

0.0

0.1

0.2

0.3

0.4

∆x

[mm

]

(Coll. rate: 137± 18 Hz)

Drag rate: 88± 6 Hz

Peter van der Straten (Atom Optics) Quantum Mechanica December 4, 2012 10 / 12

Page 19: Quantum Mechanica - Quantum Mechanica, 2012 …strat102/qm/week12.pdfgraph of the beam splitting, with the message, in transla-tion: Attached [is] the exper-imental proof of directional

Drag rate vs. Collision rate (Classical)

0 50 100 150 200γ↑↓ [Hz]

0

50

100

150

200γ

[Hz]

Ratio γ/γ↑↓ = 2/3 independent of temperatureL. Vichi, S. Stringari, Phys. Rev. A 60, 4734 (1999)

Peter van der Straten (Atom Optics) Quantum Mechanica December 4, 2012 11 / 12

Page 20: Quantum Mechanica - Quantum Mechanica, 2012 …strat102/qm/week12.pdfgraph of the beam splitting, with the message, in transla-tion: Attached [is] the exper-imental proof of directional

Drag rate vs. Collision rate (Classical)

0 50 100 150 200γ↑↓ [Hz]

0

50

100

150

200γ

[Hz]

Ratio γ/γ↑↓ = 2/3 independent of temperatureL. Vichi, S. Stringari, Phys. Rev. A 60, 4734 (1999)

Peter van der Straten (Atom Optics) Quantum Mechanica December 4, 2012 11 / 12

Page 21: Quantum Mechanica - Quantum Mechanica, 2012 …strat102/qm/week12.pdfgraph of the beam splitting, with the message, in transla-tion: Attached [is] the exper-imental proof of directional

Drag rate vs. Fugacity (Quantum regime)

0.0 0.2 0.4 0.6 0.8 1.0Exp(µ/(kBT ))

0

10

20

30

40

50

60

70

80

90

γ/T

2[H

z/µ

K2]

Bose enhancement → precursor of the phase transition

Predicted by ab initio theory - no fitted parameters

H.J. van Driel, R.A. Duine, & H.T.C. Stoof, Phys. Rev. Lett. 105, 155301 (2010)

Peter van der Straten (Atom Optics) Quantum Mechanica December 4, 2012 12 / 12

Page 22: Quantum Mechanica - Quantum Mechanica, 2012 …strat102/qm/week12.pdfgraph of the beam splitting, with the message, in transla-tion: Attached [is] the exper-imental proof of directional

Drag rate vs. Fugacity (Quantum regime)

0.0 0.2 0.4 0.6 0.8 1.0Exp(µ/(kBT ))

0

10

20

30

40

50

60

70

80

90

γ/T

2[H

z/µ

K2]

Bose enhancement

→ precursor of the phase transition

Predicted by ab initio theory - no fitted parameters

H.J. van Driel, R.A. Duine, & H.T.C. Stoof, Phys. Rev. Lett. 105, 155301 (2010)

Peter van der Straten (Atom Optics) Quantum Mechanica December 4, 2012 12 / 12

Page 23: Quantum Mechanica - Quantum Mechanica, 2012 …strat102/qm/week12.pdfgraph of the beam splitting, with the message, in transla-tion: Attached [is] the exper-imental proof of directional

Drag rate vs. Fugacity (Quantum regime)

0.0 0.2 0.4 0.6 0.8 1.0Exp(µ/(kBT ))

0

10

20

30

40

50

60

70

80

90

γ/T

2[H

z/µ

K2]

Bose enhancement → precursor of the phase transition

Predicted by ab initio theory - no fitted parameters

H.J. van Driel, R.A. Duine, & H.T.C. Stoof, Phys. Rev. Lett. 105, 155301 (2010)

Peter van der Straten (Atom Optics) Quantum Mechanica December 4, 2012 12 / 12

Page 24: Quantum Mechanica - Quantum Mechanica, 2012 …strat102/qm/week12.pdfgraph of the beam splitting, with the message, in transla-tion: Attached [is] the exper-imental proof of directional

Drag rate vs. Fugacity (Quantum regime)

0.0 0.2 0.4 0.6 0.8 1.0Exp(µ/(kBT ))

0

10

20

30

40

50

60

70

80

90

γ/T

2[H

z/µ

K2]

Bose enhancement → precursor of the phase transition

Predicted by ab initio theory - no fitted parameters

H.J. van Driel, R.A. Duine, & H.T.C. Stoof, Phys. Rev. Lett. 105, 155301 (2010)

Peter van der Straten (Atom Optics) Quantum Mechanica December 4, 2012 12 / 12

Page 25: Quantum Mechanica - Quantum Mechanica, 2012 …strat102/qm/week12.pdfgraph of the beam splitting, with the message, in transla-tion: Attached [is] the exper-imental proof of directional

Drag rate vs. Fugacity (Quantum regime)

0.0 0.2 0.4 0.6 0.8 1.0Exp(µ/(kBT ))

0

10

20

30

40

50

60

70

80

90

γ/T

2[H

z/µ

K2]

Bose enhancement → precursor of the phase transition

Predicted by ab initio theory - no fitted parameters

H.J. van Driel, R.A. Duine, & H.T.C. Stoof, Phys. Rev. Lett. 105, 155301 (2010)

Peter van der Straten (Atom Optics) Quantum Mechanica December 4, 2012 12 / 12